# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2023

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
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data_cluster1
_database_code_depnum_ccdc_archive 'CCDC 2231764'
loop_
_audit_author_name
_audit_author_address
'Saikat Das'
;Tokyo University of Science
Japan
;
_audit_update_record             
;
2022-12-20 deposited with the CCDC.	2023-02-27 downloaded from the CCDC.
;
_audit_creation_date             2022-10-24
_audit_creation_method           
;
Olex2 1.5
(compiled 2022.04.07 svn.rca3783a0 for OlexSys, GUI svn.r6498)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        'Cluster 1'
_chemical_formula_moiety         'C72 H106 Ag14 F12 N4 O8 S10'
_chemical_formula_sum            'C72 H106 Ag14 F12 N4 O8 S10'
_chemical_formula_weight         3214.38
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'C 1 2/c 1'
_space_group_name_Hall           '-C 2yc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   23.2587(6)
_cell_length_b                   14.7272(4)
_cell_length_c                   30.0370(8)
_cell_angle_alpha                90
_cell_angle_beta                 102.5260(10)
_cell_angle_gamma                90
_cell_volume                     10043.8(5)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9663
_cell_measurement_temperature    100.15
_cell_measurement_theta_max      25.36
_cell_measurement_theta_min      2.28
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    2.940
_exptl_absorpt_correction_T_max  0.7452
_exptl_absorpt_correction_T_min  0.5220
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1250 before and 0.0571 after correction.
The Ratio of minimum to maximum transmission is 0.7005.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear light green'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    green
_exptl_crystal_density_diffrn    2.126
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             6224
_exptl_crystal_size_max          0.8
_exptl_crystal_size_mid          0.6
_exptl_crystal_size_min          0.2
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0402
_diffrn_reflns_av_unetI/netI     0.0194
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       28
_diffrn_reflns_limit_h_min       -28
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       36
_diffrn_reflns_limit_l_min       -36
_diffrn_reflns_number            84924
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.390
_diffrn_reflns_theta_min         2.278
_diffrn_ambient_temperature      100.15
_diffrn_detector                 'Bruker APEX2 area detector'
_diffrn_detector_area_resol_mean 7.9
_diffrn_detector_type            'CCD area detector'
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device       'three-circle diffractometer'
_diffrn_measurement_device_type  'Bruker SMART APEX2 area detector'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_monochromator  'mirror optics'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'microfocus sealed X-ray tube'
_diffrn_source_current           0.0
_diffrn_source_power             0.0
_diffrn_source_type              'Incoatec I\ms'
_diffrn_source_voltage           0.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                8709
_reflns_number_total             9234
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.40A (Bruker, 2019)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.40A (Bruker, 2019)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_refine_diff_density_max         1.575
_refine_diff_density_min         -1.447
_refine_diff_density_rms         0.072
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.082
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     556
_refine_ls_number_reflns         9234
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0214
_refine_ls_R_factor_gt           0.0195
_refine_ls_restrained_S_all      1.082
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0029P)²+36.1936P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0396
_refine_ls_wR_factor_ref         0.0403
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C6(H6), C10(H10), C12(H12), C34(H34), C9(H9), C11(H11), C25(H25), C7(H7)
2.b Idealised Me refined as rotating group:
 C14(H14A,H14B,H14C), C18(H18A,H18B,H18C), C26(H26A,H26B,H26C), C32(H32A,H32B,
 H32C), C36(H36A,H36B,H36C), C21(H21A,H21B,H21C), C23(H23A,H23B,H23C), C13(H13A,
 H13B,H13C), C27(H27A,H27B,H27C), C15(H15A,H15B,H15C), C31(H31A,H31B,H31C),
 C2(H2A,H2B,H2C), C33(H33A,H33B,H33C), C17(H17A,H17B,H17C), C35(H35A,H35B,H35C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.25794(2) 0.39872(2) 0.61678(2) 0.01675(5) Uani 1 1 d . . . . .
Ag4 Ag 0.21880(2) 0.25054(2) 0.54931(2) 0.01785(5) Uani 1 1 d . . . . .
Ag6 Ag 0.61851(2) 1.34926(2) 0.84347(2) 0.02149(5) Uani 1 1 d . . . . .
Ag7 Ag 0.19062(2) 0.39399(2) 0.44634(2) 0.02089(5) Uani 1 1 d . . . . .
Ag2 Ag 0.22452(2) 0.50088(2) 0.53006(2) 0.02145(5) Uani 1 1 d . . . . .
Ag5 Ag 0.33054(2) 0.55046(2) 0.66944(2) 0.02346(5) Uani 1 1 d . . . . .
Ag3 Ag 0.35168(2) 0.40806(2) 0.55070(2) 0.02749(6) Uani 1 1 d . . . . .
S008 S 0.28508(3) 0.24134(4) 0.62389(2) 0.01604(13) Uani 1 1 d . . . . .
S009 S 0.15043(3) 0.25647(4) 0.47741(2) 0.01714(13) Uani 1 1 d . . . . .
S00A S 0.23433(3) 0.55680(4) 0.60796(2) 0.01686(13) Uani 1 1 d . . . . .
S00B S 0.28973(3) 0.46816(5) 0.47628(2) 0.01932(14) Uani 1 1 d . . . . .
S00C S 0.39415(3) 0.49551(5) 0.61833(2) 0.02076(14) Uani 1 1 d . . . . .
F1 F 0.34975(8) 0.46246(12) 0.83165(5) 0.0306(4) Uani 1 1 d . . . . .
O00E O 0.12411(9) 0.50520(13) 0.41472(7) 0.0268(5) Uani 1 1 d . . . . .
F4 F 0.37717(9) 0.32600(12) 0.82419(6) 0.0403(5) Uani 1 1 d . . . . .
O00G O 0.38227(8) 0.36129(13) 0.73874(6) 0.0232(4) Uani 1 1 d . . . . .
O00H O 0.32986(10) 0.48933(14) 0.74120(7) 0.0326(5) Uani 1 1 d . . . . .
F6 F 0.06008(9) 0.69578(13) 0.45230(7) 0.0429(5) Uani 1 1 d . . . . .
F3 F 0.28653(8) 0.36355(15) 0.79990(6) 0.0434(5) Uani 1 1 d . . . . .
O00K O 0.13512(9) 0.56645(15) 0.48506(7) 0.0301(5) Uani 1 1 d . . . . .
N1 N 0.54917(10) 1.23414(15) 0.82806(7) 0.0193(5) Uani 1 1 d . . . . .
N2 N 0.35153(10) 0.69017(15) 0.70481(8) 0.0206(5) Uani 1 1 d . . . . .
C1 C 0.07689(11) 0.27709(19) 0.49106(9) 0.0189(6) Uani 1 1 d . . . . .
C4 C 0.47406(11) 0.52003(19) 0.63243(9) 0.0211(6) Uani 1 1 d . . . . .
C6 C 0.56639(12) 1.14879(19) 0.83982(9) 0.0223(6) Uani 1 1 d . . . . .
H6 H 0.603573 1.140013 0.858313 0.027 Uiso 1 1 calc R U . . .
C8 C 0.24425(12) 0.18874(19) 0.66479(9) 0.0207(6) Uani 1 1 d . . . . .
C10 C 0.45695(12) 1.17389(19) 0.78713(9) 0.0197(6) Uani 1 1 d . . . . .
H10 H 0.419366 1.184779 0.769734 0.024 Uiso 1 1 calc R U . . .
C12 C 0.49449(12) 1.24497(18) 0.80266(9) 0.0196(6) Uani 1 1 d . . . . .
H12 H 0.481212 1.303723 0.795144 0.024 Uiso 1 1 calc R U . . .
C14 C 0.08214(13) 0.3552(2) 0.52467(10) 0.0265(6) Uani 1 1 d . . . . .
H14A H 0.043969 0.369285 0.530153 0.040 Uiso 1 1 calc R U . . .
H14B H 0.097659 0.407577 0.512256 0.040 Uiso 1 1 calc R U . . .
H14C H 0.108116 0.338289 0.552836 0.040 Uiso 1 1 calc R U . . .
F2 F 0.02686(14) 0.6146(2) 0.39655(11) 0.1233(16) Uani 1 1 d . . . . .
C16 C 0.35317(11) 0.41648(18) 0.75552(9) 0.0190(6) Uani 1 1 d . . . . .
C18 C 0.49583(13) 0.5168(2) 0.68395(10) 0.0275(7) Uani 1 1 d . . . . .
H18A H 0.487768 0.458079 0.695024 0.041 Uiso 1 1 calc R U . . .
H18B H 0.475974 0.562516 0.697782 0.041 Uiso 1 1 calc R U . . .
H18C H 0.537490 0.527902 0.691569 0.041 Uiso 1 1 calc R U . . .
C20 C 0.16678(12) 0.57632(19) 0.63024(9) 0.0203(6) Uani 1 1 d . . . . .
C22 C 0.34212(12) 0.39155(19) 0.80318(10) 0.0233(6) Uani 1 1 d . . . . .
C24 C 0.39421(12) 0.85574(19) 0.74374(9) 0.0213(6) Uani 1 1 d . . . . .
C26 C 0.24938(15) 0.2493(2) 0.70621(10) 0.0351(8) Uani 1 1 d . . . . .
H26A H 0.290200 0.260305 0.719401 0.053 Uiso 1 1 calc R U . . .
H26B H 0.231306 0.219963 0.728240 0.053 Uiso 1 1 calc R U . . .
H26C H 0.229885 0.305950 0.697255 0.053 Uiso 1 1 calc R U . . .
C28 C 0.11578(12) 0.56212(19) 0.44339(10) 0.0227(6) Uani 1 1 d . . . . .
C30 C 0.47628(12) 1.08543(18) 0.79794(9) 0.0192(6) Uani 1 1 d . . . . .
C32 C 0.05767(13) 0.1907(2) 0.51174(10) 0.0261(6) Uani 1 1 d . . . . .
H32A H 0.086075 0.175468 0.538980 0.039 Uiso 1 1 calc R U . . .
H32B H 0.054893 0.141847 0.490193 0.039 Uiso 1 1 calc R U . . .
H32C H 0.019950 0.200259 0.519054 0.039 Uiso 1 1 calc R U . . .
C34 C 0.53210(12) 1.07386(19) 0.82605(9) 0.0220(6) Uani 1 1 d . . . . .
H34 H 0.545834 1.016079 0.835315 0.026 Uiso 1 1 calc R U . . .
C36 C 0.18017(12) 0.1732(2) 0.64110(10) 0.0265(6) Uani 1 1 d . . . . .
H36A H 0.161952 0.230384 0.631311 0.040 Uiso 1 1 calc R U . . .
H36B H 0.159741 0.144837 0.661953 0.040 Uiso 1 1 calc R U . . .
H36C H 0.178441 0.134533 0.615108 0.040 Uiso 1 1 calc R U . . .
C9 C 0.33610(13) 0.7688(2) 0.68358(10) 0.0268(6) Uani 1 1 d . . . . .
H9 H 0.310775 0.767275 0.655002 0.032 Uiso 1 1 calc R U . . .
C19 C 0.30831(12) 0.5867(2) 0.46174(10) 0.0235(6) Uani 1 1 d . . . . .
C5 C 0.44251(12) 1.00749(19) 0.77952(9) 0.0214(6) Uani 1 1 d . . . . .
C21 C 0.03423(13) 0.3014(2) 0.44667(10) 0.0291(7) Uani 1 1 d . . . . .
H21A H -0.004511 0.309596 0.452316 0.044 Uiso 1 1 calc R U . . .
H21B H 0.033471 0.253216 0.424997 0.044 Uiso 1 1 calc R U . . .
H21C H 0.046813 0.356545 0.434688 0.044 Uiso 1 1 calc R U . . .
C11 C 0.41023(14) 0.7739(2) 0.76624(10) 0.0278(7) Uani 1 1 d . . . . .
H11 H 0.435781 0.773307 0.794724 0.033 Uiso 1 1 calc R U . . .
C23 C 0.27489(14) 0.0975(2) 0.67858(11) 0.0339(7) Uani 1 1 d . . . . .
H23A H 0.272716 0.060561 0.651921 0.051 Uiso 1 1 calc R U . . .
H23B H 0.255689 0.066859 0.699546 0.051 Uiso 1 1 calc R U . . .
H23C H 0.315427 0.107956 0.692881 0.051 Uiso 1 1 calc R U . . .
C3 C 0.41878(12) 0.9395(2) 0.76323(10) 0.0236(6) Uani 1 1 d . . . . .
C25 C 0.38795(14) 0.6938(2) 0.74596(10) 0.0279(7) Uani 1 1 d . . . . .
H25 H 0.398663 0.639724 0.761535 0.033 Uiso 1 1 calc R U . . .
C13 C 0.18661(13) 0.5984(2) 0.68062(10) 0.0314(7) Uani 1 1 d . . . . .
H13A H 0.206570 0.546911 0.696436 0.047 Uiso 1 1 calc R U . . .
H13B H 0.152895 0.612934 0.692887 0.047 Uiso 1 1 calc R U . . .
H13C H 0.212902 0.649477 0.684379 0.047 Uiso 1 1 calc R U . . .
C27 C 0.50590(13) 0.4500(3) 0.60954(11) 0.0368(8) Uani 1 1 d . . . . .
H27A H 0.547412 0.462426 0.616802 0.055 Uiso 1 1 calc R U . . .
H27B H 0.491554 0.452909 0.577100 0.055 Uiso 1 1 calc R U . . .
H27C H 0.498884 0.390492 0.620244 0.055 Uiso 1 1 calc R U . . .
F5 F 0.10400(17) 0.6937(2) 0.39854(13) 0.1345(18) Uani 1 1 d . . . . .
C7 C 0.35556(13) 0.8521(2) 0.70157(10) 0.0271(6) Uani 1 1 d . . . . .
H7 H 0.342948 0.905176 0.685646 0.032 Uiso 1 1 calc R U . . .
C29 C 0.07588(16) 0.6420(2) 0.42249(11) 0.0380(8) Uani 1 1 d . . . . .
C15 C 0.12659(15) 0.4948(2) 0.62258(13) 0.0437(9) Uani 1 1 d . . . . .
H15A H 0.116420 0.480813 0.590621 0.066 Uiso 1 1 calc R U . . .
H15B H 0.091436 0.507917 0.633230 0.066 Uiso 1 1 calc R U . . .
H15C H 0.146341 0.443752 0.639030 0.066 Uiso 1 1 calc R U . . .
C31 C 0.30876(19) 0.6507(2) 0.50122(13) 0.0465(9) Uani 1 1 d . . . . .
H31A H 0.322111 0.709459 0.494042 0.070 Uiso 1 1 calc R U . . .
H31B H 0.334790 0.627511 0.528073 0.070 Uiso 1 1 calc R U . . .
H31C H 0.269674 0.655621 0.506590 0.070 Uiso 1 1 calc R U . . .
C2 C 0.48220(17) 0.6150(2) 0.61490(14) 0.0490(10) Uani 1 1 d . . . . .
H2A H 0.459616 0.657452 0.628319 0.073 Uiso 1 1 calc R U . . .
H2B H 0.469009 0.616140 0.582323 0.073 Uiso 1 1 calc R U . . .
H2C H 0.523104 0.631267 0.622982 0.073 Uiso 1 1 calc R U . . .
C33 C 0.26418(16) 0.6174(3) 0.41942(13) 0.0506(11) Uani 1 1 d . . . . .
H33A H 0.225273 0.616567 0.425386 0.076 Uiso 1 1 calc R U . . .
H33B H 0.265757 0.577116 0.394591 0.076 Uiso 1 1 calc R U . . .
H33C H 0.273635 0.677943 0.411554 0.076 Uiso 1 1 calc R U . . .
C17 C 0.13600(15) 0.6581(2) 0.60433(12) 0.0408(8) Uani 1 1 d . . . . .
H17A H 0.162057 0.709450 0.609185 0.061 Uiso 1 1 calc R U . . .
H17B H 0.101086 0.672025 0.615164 0.061 Uiso 1 1 calc R U . . .
H17C H 0.125481 0.644383 0.572355 0.061 Uiso 1 1 calc R U . . .
C35 C 0.36957(14) 0.5816(3) 0.45187(13) 0.0421(9) Uani 1 1 d . . . . .
H35A H 0.380423 0.640089 0.442240 0.063 Uiso 1 1 calc R U . . .
H35B H 0.369759 0.537953 0.428154 0.063 Uiso 1 1 calc R U . . .
H35C H 0.397261 0.563457 0.478983 0.063 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 Ag4 2.9831(3) . ?
Ag1 Ag6 2.9540(3) 2_646 ?
Ag1 Ag2 2.9622(3) . ?
Ag1 Ag5 3.0312(3) . ?
Ag1 Ag3 3.2541(3) . ?
Ag1 S008 2.3996(7) . ?
Ag1 S00A 2.3933(7) . ?
Ag4 Ag7 2.9778(3) 7_556 ?
Ag4 S008 2.4323(7) . ?
Ag4 S009 2.3898(7) . ?
Ag6 Ag5 3.2457(3) 2_666 ?
Ag6 Ag3 3.2219(3) 2_666 ?
Ag6 S008 2.7500(7) 2_666 ?
Ag6 S00C 2.4877(8) 2_666 ?
Ag6 O00G 2.4716(18) 2_666 ?
Ag6 N1 2.316(2) . ?
Ag7 Ag2 2.9263(3) . ?
Ag7 S009 2.4950(7) . ?
Ag7 S00B 2.5330(7) . ?
Ag7 O00E 2.3109(19) . ?
Ag2 Ag3 3.1946(3) . ?
Ag2 S00A 2.4441(7) . ?
Ag2 S00B 2.4908(7) . ?
Ag2 O00K 2.422(2) . ?
Ag5 S00A 2.5756(7) . ?
Ag5 S00C 2.4873(7) . ?
Ag5 O00H 2.339(2) . ?
Ag5 N2 2.318(2) . ?
Ag3 S009 2.5629(7) 7_556 ?
Ag3 S00B 2.5414(7) . ?
Ag3 S00C 2.4270(7) . ?
S008 C8 1.875(3) . ?
S009 C1 1.868(3) . ?
S00A C20 1.859(3) . ?
S00B C19 1.873(3) . ?
S00C C4 1.850(3) . ?
F1 C22 1.337(3) . ?
O00E C28 1.247(3) . ?
F4 C22 1.331(3) . ?
O00G C16 1.233(3) . ?
O00H C16 1.237(3) . ?
F6 C29 1.307(4) . ?
F3 C22 1.340(3) . ?
O00K C28 1.237(3) . ?
N1 C6 1.343(4) . ?
N1 C12 1.343(3) . ?
N2 C9 1.333(4) . ?
N2 C25 1.339(4) . ?
C1 C14 1.518(4) . ?
C1 C32 1.525(4) . ?
C1 C21 1.522(4) . ?
C4 C18 1.521(4) . ?
C4 C27 1.518(4) . ?
C4 C2 1.520(4) . ?
C6 H6 0.9300 . ?
C6 C34 1.372(4) . ?
C8 C26 1.514(4) . ?
C8 C36 1.523(4) . ?
C8 C23 1.536(4) . ?
C10 H10 0.9300 . ?
C10 C12 1.378(4) . ?
C10 C30 1.393(4) . ?
C12 H12 0.9300 . ?
C14 H14A 0.9600 . ?
C14 H14B 0.9600 . ?
C14 H14C 0.9600 . ?
F2 C29 1.298(5) . ?
C16 C22 1.552(4) . ?
C18 H18A 0.9600 . ?
C18 H18B 0.9600 . ?
C18 H18C 0.9600 . ?
C20 C13 1.519(4) . ?
C20 C15 1.508(4) . ?
C20 C17 1.526(4) . ?
C24 C11 1.393(4) . ?
C24 C3 1.431(4) . ?
C24 C7 1.386(4) . ?
C26 H26A 0.9600 . ?
C26 H26B 0.9600 . ?
C26 H26C 0.9600 . ?
C28 C29 1.544(4) . ?
C30 C34 1.397(4) . ?
C30 C5 1.433(4) . ?
C32 H32A 0.9600 . ?
C32 H32B 0.9600 . ?
C32 H32C 0.9600 . ?
C34 H34 0.9300 . ?
C36 H36A 0.9600 . ?
C36 H36B 0.9600 . ?
C36 H36C 0.9600 . ?
C9 H9 0.9300 . ?
C9 C7 1.377(4) . ?
C19 C31 1.513(4) . ?
C19 C33 1.519(4) . ?
C19 C35 1.519(4) . ?
C5 C3 1.195(4) . ?
C21 H21A 0.9600 . ?
C21 H21B 0.9600 . ?
C21 H21C 0.9600 . ?
C11 H11 0.9300 . ?
C11 C25 1.376(4) . ?
C23 H23A 0.9600 . ?
C23 H23B 0.9600 . ?
C23 H23C 0.9600 . ?
C25 H25 0.9300 . ?
C13 H13A 0.9600 . ?
C13 H13B 0.9600 . ?
C13 H13C 0.9600 . ?
C27 H27A 0.9600 . ?
C27 H27B 0.9600 . ?
C27 H27C 0.9600 . ?
F5 C29 1.315(4) . ?
C7 H7 0.9300 . ?
C15 H15A 0.9600 . ?
C15 H15B 0.9600 . ?
C15 H15C 0.9600 . ?
C31 H31A 0.9600 . ?
C31 H31B 0.9600 . ?
C31 H31C 0.9600 . ?
C2 H2A 0.9600 . ?
C2 H2B 0.9600 . ?
C2 H2C 0.9600 . ?
C33 H33A 0.9600 . ?
C33 H33B 0.9600 . ?
C33 H33C 0.9600 . ?
C17 H17A 0.9600 . ?
C17 H17B 0.9600 . ?
C17 H17C 0.9600 . ?
C35 H35A 0.9600 . ?
C35 H35B 0.9600 . ?
C35 H35C 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ag4 Ag1 Ag5 161.312(9) . . ?
Ag4 Ag1 Ag3 76.270(7) . . ?
Ag6 Ag1 Ag4 102.771(8) 2_646 . ?
Ag6 Ag1 Ag2 121.836(9) 2_646 . ?
Ag6 Ag1 Ag5 65.666(7) 2_646 . ?
Ag6 Ag1 Ag3 62.307(7) 2_646 . ?
Ag2 Ag1 Ag4 77.930(8) . . ?
Ag2 Ag1 Ag5 95.436(8) . . ?
Ag2 Ag1 Ag3 61.637(7) . . ?
Ag5 Ag1 Ag3 85.189(8) . . ?
S008 Ag1 Ag4 52.370(16) . . ?
S008 Ag1 Ag6 60.776(16) . 2_646 ?
S008 Ag1 Ag2 125.637(17) . . ?
S008 Ag1 Ag5 124.034(17) . . ?
S008 Ag1 Ag3 84.087(17) . . ?
S00A Ag1 Ag4 127.406(17) . . ?
S00A Ag1 Ag6 117.670(18) . 2_646 ?
S00A Ag1 Ag2 53.020(16) . . ?
S00A Ag1 Ag5 55.191(16) . . ?
S00A Ag1 Ag3 93.404(17) . . ?
S00A Ag1 S008 177.46(2) . . ?
Ag7 Ag4 Ag1 112.602(8) 7_556 . ?
S008 Ag4 Ag1 51.384(16) . . ?
S008 Ag4 Ag7 67.581(16) . 7_556 ?
S009 Ag4 Ag1 129.233(18) . . ?
S009 Ag4 Ag7 113.054(18) . 7_556 ?
S009 Ag4 S008 177.50(2) . . ?
Ag1 Ag6 Ag5 58.314(7) 2_666 2_666 ?
Ag1 Ag6 Ag3 63.422(7) 2_666 2_666 ?
Ag3 Ag6 Ag5 82.329(8) 2_666 2_666 ?
S008 Ag6 Ag1 49.599(14) 2_666 2_666 ?
S008 Ag6 Ag5 106.238(15) 2_666 2_666 ?
S008 Ag6 Ag3 79.580(15) 2_666 2_666 ?
S00C Ag6 Ag1 78.585(17) 2_666 2_666 ?
S00C Ag6 Ag5 49.269(16) 2_666 2_666 ?
S00C Ag6 Ag3 48.232(16) 2_666 2_666 ?
S00C Ag6 S008 120.32(2) 2_666 2_666 ?
O00G Ag6 Ag1 100.48(4) 2_666 2_666 ?
O00G Ag6 Ag5 74.87(5) 2_666 2_666 ?
O00G Ag6 Ag3 156.90(5) 2_666 2_666 ?
O00G Ag6 S008 103.08(5) 2_666 2_666 ?
O00G Ag6 S00C 115.01(5) 2_666 2_666 ?
N1 Ag6 Ag1 146.65(6) . 2_666 ?
N1 Ag6 Ag5 154.26(6) . 2_666 ?
N1 Ag6 Ag3 112.67(5) . 2_666 ?
N1 Ag6 S008 97.28(6) . 2_666 ?
N1 Ag6 S00C 125.38(6) . 2_666 ?
N1 Ag6 O00G 89.93(7) . 2_666 ?
Ag2 Ag7 Ag4 106.892(9) . 7_556 ?
S009 Ag7 Ag4 73.872(16) . 7_556 ?
S009 Ag7 Ag2 99.682(17) . . ?
S009 Ag7 S00B 127.10(2) . . ?
S00B Ag7 Ag4 73.260(17) . 7_556 ?
S00B Ag7 Ag2 53.706(16) . . ?
O00E Ag7 Ag4 158.26(5) . 7_556 ?
O00E Ag7 Ag2 90.20(5) . . ?
O00E Ag7 S009 117.21(5) . . ?
O00E Ag7 S00B 108.47(5) . . ?
Ag1 Ag2 Ag3 63.683(7) . . ?
Ag7 Ag2 Ag1 116.930(9) . . ?
Ag7 Ag2 Ag3 90.123(8) . . ?
S00A Ag2 Ag1 51.468(16) . . ?
S00A Ag2 Ag7 162.895(18) . . ?
S00A Ag2 Ag3 93.905(17) . . ?
S00A Ag2 S00B 137.94(2) . . ?
S00B Ag2 Ag1 113.043(18) . . ?
S00B Ag2 Ag7 55.049(16) . . ?
S00B Ag2 Ag3 51.298(16) . . ?
O00K Ag2 Ag1 136.31(5) . . ?
O00K Ag2 Ag7 72.31(5) . . ?
O00K Ag2 Ag3 157.78(5) . . ?
O00K Ag2 S00A 106.89(5) . . ?
O00K Ag2 S00B 106.57(5) . . ?
Ag1 Ag5 Ag6 56.022(7) . 2_646 ?
S00A Ag5 Ag1 49.726(15) . . ?
S00A Ag5 Ag6 103.319(16) . 2_646 ?
S00C Ag5 Ag1 77.088(17) . . ?
S00C Ag5 Ag6 49.283(18) . 2_646 ?
S00C Ag5 S00A 96.30(2) . . ?
O00H Ag5 Ag1 94.75(6) . . ?
O00H Ag5 Ag6 80.46(5) . 2_646 ?
O00H Ag5 S00A 119.75(6) . . ?
O00H Ag5 S00C 124.56(5) . . ?
N2 Ag5 Ag1 158.67(6) . . ?
N2 Ag5 Ag6 144.97(6) . 2_646 ?
N2 Ag5 S00A 111.12(6) . . ?
N2 Ag5 S00C 118.51(6) . . ?
N2 Ag5 O00H 87.83(8) . . ?
Ag6 Ag3 Ag1 54.274(6) 2_646 . ?
Ag2 Ag3 Ag1 54.680(6) . . ?
Ag2 Ag3 Ag6 107.371(8) . 2_646 ?
S009 Ag3 Ag1 101.157(16) 7_556 . ?
S009 Ag3 Ag6 93.184(16) 7_556 2_646 ?
S009 Ag3 Ag2 112.947(17) 7_556 . ?
S00B Ag3 Ag1 102.950(17) . . ?
S00B Ag3 Ag6 157.080(17) . 2_646 ?
S00B Ag3 Ag2 49.896(16) . . ?
S00B Ag3 S009 94.18(2) . 7_556 ?
S00C Ag3 Ag1 73.545(17) . . ?
S00C Ag3 Ag6 49.859(18) . 2_646 ?
S00C Ag3 Ag2 97.293(18) . . ?
S00C Ag3 S009 138.82(2) . 7_556 ?
S00C Ag3 S00B 126.98(3) . . ?
Ag1 S008 Ag4 76.25(2) . . ?
Ag1 S008 Ag6 69.626(18) . 2_646 ?
Ag4 S008 Ag6 126.95(3) . 2_646 ?
C8 S008 Ag1 107.24(9) . . ?
C8 S008 Ag4 108.45(9) . . ?
C8 S008 Ag6 119.66(9) . 2_646 ?
Ag4 S009 Ag7 97.92(2) . . ?
Ag4 S009 Ag3 102.97(2) . 7_556 ?
Ag7 S009 Ag3 128.77(3) . 7_556 ?
C1 S009 Ag4 105.60(9) . . ?
C1 S009 Ag7 112.67(9) . . ?
C1 S009 Ag3 105.84(9) . 7_556 ?
Ag1 S00A Ag2 75.51(2) . . ?
Ag1 S00A Ag5 75.083(19) . . ?
Ag2 S00A Ag5 124.09(3) . . ?
C20 S00A Ag1 107.59(9) . . ?
C20 S00A Ag2 119.08(9) . . ?
C20 S00A Ag5 114.72(9) . . ?
Ag7 S00B Ag3 117.44(3) . . ?
Ag2 S00B Ag7 71.245(19) . . ?
Ag2 S00B Ag3 78.81(2) . . ?
C19 S00B Ag7 123.88(9) . . ?
C19 S00B Ag2 100.07(9) . . ?
C19 S00B Ag3 114.48(9) . . ?
Ag5 S00C Ag6 81.45(2) . 2_646 ?
Ag3 S00C Ag6 81.91(2) . 2_646 ?
Ag3 S00C Ag5 120.05(3) . . ?
C4 S00C Ag6 106.07(9) . 2_646 ?
C4 S00C Ag5 119.85(9) . . ?
C4 S00C Ag3 120.10(9) . . ?
C28 O00E Ag7 112.53(17) . . ?
C16 O00G Ag6 124.74(17) . 2_646 ?
C16 O00H Ag5 124.37(18) . . ?
C28 O00K Ag2 128.62(18) . . ?
C6 N1 Ag6 118.53(18) . . ?
C6 N1 C12 116.9(2) . . ?
C12 N1 Ag6 123.99(18) . . ?
C9 N2 Ag5 122.92(18) . . ?
C9 N2 C25 117.2(2) . . ?
C25 N2 Ag5 119.11(18) . . ?
C14 C1 S009 108.88(19) . . ?
C14 C1 C32 110.5(2) . . ?
C14 C1 C21 110.3(2) . . ?
C32 C1 S009 108.47(19) . . ?
C21 C1 S009 107.44(19) . . ?
C21 C1 C32 111.1(2) . . ?
C18 C4 S00C 108.86(19) . . ?
C27 C4 S00C 109.2(2) . . ?
C27 C4 C18 110.6(2) . . ?
C27 C4 C2 111.0(3) . . ?
C2 C4 S00C 107.1(2) . . ?
C2 C4 C18 110.0(3) . . ?
N1 C6 H6 118.2 . . ?
N1 C6 C34 123.6(3) . . ?
C34 C6 H6 118.2 . . ?
C26 C8 S008 109.53(19) . . ?
C26 C8 C36 111.5(2) . . ?
C26 C8 C23 110.1(3) . . ?
C36 C8 S008 109.84(18) . . ?
C36 C8 C23 110.1(2) . . ?
C23 C8 S008 105.5(2) . . ?
C12 C10 H10 120.6 . . ?
C12 C10 C30 118.9(3) . . ?
C30 C10 H10 120.6 . . ?
N1 C12 C10 123.7(3) . . ?
N1 C12 H12 118.2 . . ?
C10 C12 H12 118.2 . . ?
C1 C14 H14A 109.5 . . ?
C1 C14 H14B 109.5 . . ?
C1 C14 H14C 109.5 . . ?
H14A C14 H14B 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
O00G C16 O00H 131.9(3) . . ?
O00G C16 C22 115.9(2) . . ?
O00H C16 C22 112.2(2) . . ?
C4 C18 H18A 109.5 . . ?
C4 C18 H18B 109.5 . . ?
C4 C18 H18C 109.5 . . ?
H18A C18 H18B 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C13 C20 S00A 107.11(19) . . ?
C13 C20 C17 110.3(3) . . ?
C15 C20 S00A 111.48(19) . . ?
C15 C20 C13 111.5(3) . . ?
C15 C20 C17 110.1(3) . . ?
C17 C20 S00A 106.2(2) . . ?
F1 C22 F3 106.2(2) . . ?
F1 C22 C16 112.3(2) . . ?
F4 C22 F1 106.3(2) . . ?
F4 C22 F3 107.1(2) . . ?
F4 C22 C16 113.7(2) . . ?
F3 C22 C16 110.8(2) . . ?
C11 C24 C3 120.5(3) . . ?
C7 C24 C11 117.5(3) . . ?
C7 C24 C3 122.0(3) . . ?
C8 C26 H26A 109.5 . . ?
C8 C26 H26B 109.5 . . ?
C8 C26 H26C 109.5 . . ?
H26A C26 H26B 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
O00E C28 C29 113.6(3) . . ?
O00K C28 O00E 131.1(3) . . ?
O00K C28 C29 115.3(3) . . ?
C10 C30 C34 117.7(3) . . ?
C10 C30 C5 122.5(3) . . ?
C34 C30 C5 119.7(3) . . ?
C1 C32 H32A 109.5 . . ?
C1 C32 H32B 109.5 . . ?
C1 C32 H32C 109.5 . . ?
H32A C32 H32B 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
C6 C34 C30 119.2(3) . . ?
C6 C34 H34 120.4 . . ?
C30 C34 H34 120.4 . . ?
C8 C36 H36A 109.5 . . ?
C8 C36 H36B 109.5 . . ?
C8 C36 H36C 109.5 . . ?
H36A C36 H36B 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
N2 C9 H9 118.2 . . ?
N2 C9 C7 123.7(3) . . ?
C7 C9 H9 118.2 . . ?
C31 C19 S00B 111.1(2) . . ?
C31 C19 C33 111.0(3) . . ?
C31 C19 C35 109.7(3) . . ?
C33 C19 S00B 108.9(2) . . ?
C35 C19 S00B 105.9(2) . . ?
C35 C19 C33 110.1(3) . . ?
C3 C5 C30 174.2(3) . . ?
C1 C21 H21A 109.5 . . ?
C1 C21 H21B 109.5 . . ?
C1 C21 H21C 109.5 . . ?
H21A C21 H21B 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C24 C11 H11 120.3 . . ?
C25 C11 C24 119.4(3) . . ?
C25 C11 H11 120.3 . . ?
C8 C23 H23A 109.5 . . ?
C8 C23 H23B 109.5 . . ?
C8 C23 H23C 109.5 . . ?
H23A C23 H23B 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C5 C3 C24 176.1(3) . . ?
N2 C25 C11 123.0(3) . . ?
N2 C25 H25 118.5 . . ?
C11 C25 H25 118.5 . . ?
C20 C13 H13A 109.5 . . ?
C20 C13 H13B 109.5 . . ?
C20 C13 H13C 109.5 . . ?
H13A C13 H13B 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
C4 C27 H27A 109.5 . . ?
C4 C27 H27B 109.5 . . ?
C4 C27 H27C 109.5 . . ?
H27A C27 H27B 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
C24 C7 H7 120.5 . . ?
C9 C7 C24 119.1(3) . . ?
C9 C7 H7 120.5 . . ?
F6 C29 C28 114.6(3) . . ?
F6 C29 F5 105.7(3) . . ?
F2 C29 F6 105.0(3) . . ?
F2 C29 C28 112.3(3) . . ?
F2 C29 F5 109.1(4) . . ?
F5 C29 C28 109.7(3) . . ?
C20 C15 H15A 109.5 . . ?
C20 C15 H15B 109.5 . . ?
C20 C15 H15C 109.5 . . ?
H15A C15 H15B 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C19 C31 H31A 109.5 . . ?
C19 C31 H31B 109.5 . . ?
C19 C31 H31C 109.5 . . ?
H31A C31 H31B 109.5 . . ?
H31A C31 H31C 109.5 . . ?
H31B C31 H31C 109.5 . . ?
C4 C2 H2A 109.5 . . ?
C4 C2 H2B 109.5 . . ?
C4 C2 H2C 109.5 . . ?
H2A C2 H2B 109.5 . . ?
H2A C2 H2C 109.5 . . ?
H2B C2 H2C 109.5 . . ?
C19 C33 H33A 109.5 . . ?
C19 C33 H33B 109.5 . . ?
C19 C33 H33C 109.5 . . ?
H33A C33 H33B 109.5 . . ?
H33A C33 H33C 109.5 . . ?
H33B C33 H33C 109.5 . . ?
C20 C17 H17A 109.5 . . ?
C20 C17 H17B 109.5 . . ?
C20 C17 H17C 109.5 . . ?
H17A C17 H17B 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C19 C35 H35A 109.5 . . ?
C19 C35 H35B 109.5 . . ?
C19 C35 H35C 109.5 . . ?
H35A C35 H35B 109.5 . . ?
H35A C35 H35C 109.5 . . ?
H35B C35 H35C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ag1 S008 C8 C26 -46.3(2) . . . . ?
Ag1 S008 C8 C36 76.6(2) . . . . ?
Ag1 S008 C8 C23 -164.78(17) . . . . ?
Ag1 S00A C20 C13 89.8(2) . . . . ?
Ag1 S00A C20 C15 -32.5(2) . . . . ?
Ag1 S00A C20 C17 -152.41(19) . . . . ?
Ag4 S008 C8 C26 -127.1(2) . . . . ?
Ag4 S008 C8 C36 -4.3(2) . . . . ?
Ag4 S008 C8 C23 114.37(18) . . . . ?
Ag4 S009 C1 C14 48.7(2) . . . . ?
Ag4 S009 C1 C32 -71.66(19) . . . . ?
Ag4 S009 C1 C21 168.17(17) . . . . ?
Ag6 S008 C8 C26 29.7(2) 2_646 . . . ?
Ag6 S008 C8 C36 152.52(17) 2_646 . . . ?
Ag6 S008 C8 C23 -88.83(19) 2_646 . . . ?
Ag6 S00C C4 C18 -53.7(2) 2_646 . . . ?
Ag6 S00C C4 C27 67.2(2) 2_646 . . . ?
Ag6 S00C C4 C2 -172.6(2) 2_646 . . . ?
Ag6 O00G C16 O00H -20.3(4) 2_646 . . . ?
Ag6 O00G C16 C22 158.69(17) 2_646 . . . ?
Ag6 N1 C6 C34 -169.2(2) . . . . ?
Ag6 N1 C12 C10 168.5(2) . . . . ?
Ag7 S009 C1 C14 -57.1(2) . . . . ?
Ag7 S009 C1 C32 -177.43(16) . . . . ?
Ag7 S009 C1 C21 62.4(2) . . . . ?
Ag7 S00B C19 C31 104.7(2) . . . . ?
Ag7 S00B C19 C33 -17.9(3) . . . . ?
Ag7 S00B C19 C35 -136.26(19) . . . . ?
Ag7 O00E C28 O00K -3.1(4) . . . . ?
Ag7 O00E C28 C29 174.8(2) . . . . ?
Ag2 S00A C20 C13 172.67(17) . . . . ?
Ag2 S00A C20 C15 50.4(3) . . . . ?
Ag2 S00A C20 C17 -69.5(2) . . . . ?
Ag2 S00B C19 C31 30.7(2) . . . . ?
Ag2 S00B C19 C33 -92.0(2) . . . . ?
Ag2 S00B C19 C35 149.6(2) . . . . ?
Ag2 O00K C28 O00E 24.5(5) . . . . ?
Ag2 O00K C28 C29 -153.4(2) . . . . ?
Ag5 S00A C20 C13 8.5(2) . . . . ?
Ag5 S00A C20 C15 -113.8(2) . . . . ?
Ag5 S00A C20 C17 126.30(19) . . . . ?
Ag5 S00C C4 C18 35.6(2) . . . . ?
Ag5 S00C C4 C27 156.45(18) . . . . ?
Ag5 S00C C4 C2 -83.3(2) . . . . ?
Ag5 O00H C16 O00G 2.4(4) . . . . ?
Ag5 O00H C16 C22 -176.68(17) . . . . ?
Ag5 N2 C9 C7 -169.9(2) . . . . ?
Ag5 N2 C25 C11 169.4(2) . . . . ?
Ag3 S009 C1 C14 157.41(17) 7_556 . . . ?
Ag3 S009 C1 C32 37.09(19) 7_556 . . . ?
Ag3 S009 C1 C21 -83.07(19) 7_556 . . . ?
Ag3 S00B C19 C31 -51.5(3) . . . . ?
Ag3 S00B C19 C33 -174.2(2) . . . . ?
Ag3 S00B C19 C35 67.4(2) . . . . ?
Ag3 S00C C4 C18 -143.53(16) . . . . ?
Ag3 S00C C4 C27 -22.7(2) . . . . ?
Ag3 S00C C4 C2 97.6(2) . . . . ?
O00E C28 C29 F6 171.2(3) . . . . ?
O00E C28 C29 F2 51.5(4) . . . . ?
O00E C28 C29 F5 -70.1(4) . . . . ?
O00G C16 C22 F1 136.3(2) . . . . ?
O00G C16 C22 F4 15.6(4) . . . . ?
O00G C16 C22 F3 -105.1(3) . . . . ?
O00H C16 C22 F1 -44.4(3) . . . . ?
O00H C16 C22 F4 -165.2(2) . . . . ?
O00H C16 C22 F3 74.2(3) . . . . ?
O00K C28 C29 F6 -10.6(4) . . . . ?
O00K C28 C29 F2 -130.3(3) . . . . ?
O00K C28 C29 F5 108.2(4) . . . . ?
N1 C6 C34 C30 0.6(4) . . . . ?
N2 C9 C7 C24 1.2(5) . . . . ?
C6 N1 C12 C10 -2.4(4) . . . . ?
C10 C30 C34 C6 -3.2(4) . . . . ?
C12 N1 C6 C34 2.3(4) . . . . ?
C12 C10 C30 C34 3.1(4) . . . . ?
C12 C10 C30 C5 -173.7(2) . . . . ?
C24 C11 C25 N2 0.8(5) . . . . ?
C30 C10 C12 N1 -0.3(4) . . . . ?
C9 N2 C25 C11 -1.1(4) . . . . ?
C5 C30 C34 C6 173.6(3) . . . . ?
C11 C24 C7 C9 -1.5(4) . . . . ?
C3 C24 C11 C25 -177.3(3) . . . . ?
C3 C24 C7 C9 176.3(3) . . . . ?
C25 N2 C9 C7 0.1(4) . . . . ?
C7 C24 C11 C25 0.6(4) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_Cluster2
_database_code_depnum_ccdc_archive 'CCDC 2231770'
loop_
_audit_author_name
_audit_author_address
'Saikat Das'
;Tokyo University of Science
Japan
;
_audit_update_record             
;
2022-12-20 deposited with the CCDC.	2023-02-27 downloaded from the CCDC.
;
_audit_creation_date             2022-10-24
_audit_creation_method           
;
Olex2 1.5
(compiled 2022.04.07 svn.rca3783a0 for OlexSys, GUI svn.r6498)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        'Cluster 2 Ag12bpeb'
_chemical_formula_moiety         'C96 H90 Ag12 F18 N6 O12 S6'
_chemical_formula_sum            'C96 H90 Ag12 F18 N6 O12 S6'
_chemical_formula_weight         3348.53
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      trigonal
_space_group_IT_number           166
_space_group_name_H-M_alt        'R -3 m'
_space_group_name_Hall           '-R 3 2"'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'y, x, -z'
'x-y, -y, -z'
'-x, -x+y, -z'
'x+2/3, y+1/3, z+1/3'
'-y+2/3, x-y+1/3, z+1/3'
'-x+y+2/3, -x+1/3, z+1/3'
'y+2/3, x+1/3, -z+1/3'
'x-y+2/3, -y+1/3, -z+1/3'
'-x+2/3, -x+y+1/3, -z+1/3'
'x+1/3, y+2/3, z+2/3'
'-y+1/3, x-y+2/3, z+2/3'
'-x+y+1/3, -x+2/3, z+2/3'
'y+1/3, x+2/3, -z+2/3'
'x-y+1/3, -y+2/3, -z+2/3'
'-x+1/3, -x+y+2/3, -z+2/3'
'-x, -y, -z'
'y, -x+y, -z'
'x-y, x, -z'
'-y, -x, z'
'-x+y, y, z'
'x, x-y, z'
'-x+2/3, -y+1/3, -z+1/3'
'y+2/3, -x+y+1/3, -z+1/3'
'x-y+2/3, x+1/3, -z+1/3'
'-y+2/3, -x+1/3, z+1/3'
'-x+y+2/3, y+1/3, z+1/3'
'x+2/3, x-y+1/3, z+1/3'
'-x+1/3, -y+2/3, -z+2/3'
'y+1/3, -x+y+2/3, -z+2/3'
'x-y+1/3, x+2/3, -z+2/3'
'-y+1/3, -x+2/3, z+2/3'
'-x+y+1/3, y+2/3, z+2/3'
'x+1/3, x-y+2/3, z+2/3'

_cell_length_a                   28.808(2)
_cell_length_b                   28.808(2)
_cell_length_c                   11.3966(14)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_volume                     8190.8(16)
_cell_formula_units_Z            3
_cell_measurement_reflns_used    2167
_cell_measurement_temperature    100.15
_cell_measurement_theta_max      23.77
_cell_measurement_theta_min      2.42
_shelx_estimated_absorpt_T_max   0.339
_shelx_estimated_absorpt_T_min   0.339
_exptl_absorpt_coefficient_mu    2.304
_exptl_absorpt_correction_T_max  0.7450
_exptl_absorpt_correction_T_min  0.3772
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1658 before and 0.0855 after correction.
The Ratio of minimum to maximum transmission is 0.5063.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    2.037
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       rhombohedral
_exptl_crystal_F_000             4878
_exptl_crystal_size_max          0.6
_exptl_crystal_size_mid          0.6
_exptl_crystal_size_min          0.6
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.1184
_diffrn_reflns_av_unetI/netI     0.0709
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       30
_diffrn_reflns_limit_h_min       -32
_diffrn_reflns_limit_k_max       32
_diffrn_reflns_limit_k_min       -29
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_number            9122
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        23.840
_diffrn_reflns_theta_max         23.840
_diffrn_reflns_theta_min         1.965
_diffrn_ambient_temperature      100.15
_diffrn_detector                 'Bruker APEX2 area detector'
_diffrn_detector_area_resol_mean 7.9
_diffrn_detector_type            'CCD area detector'
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device       'three-circle diffractometer'
_diffrn_measurement_device_type  'Bruker SMART APEX2 area detector'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_monochromator  'mirror optics'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'microfocus sealed X-ray tube'
_diffrn_source_current           1.4
_diffrn_source_power             0.07
_diffrn_source_type              'Incoatec I\ms'
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                1243
_reflns_number_total             1508
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.40A (Bruker, 2019)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.40A (Bruker, 2019)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_refine_diff_density_max         1.904
_refine_diff_density_min         -1.754
_refine_diff_density_rms         0.239
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.040
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     129
_refine_ls_number_reflns         1508
_refine_ls_number_restraints     90
_refine_ls_R_factor_all          0.0615
_refine_ls_R_factor_gt           0.0502
_refine_ls_restrained_S_all      1.009
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0789P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1248
_refine_ls_wR_factor_ref         0.1321
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Uiso/Uaniso restraints and constraints
C4: within 1.7A with sigma of 0.04 and sigma for terminal atoms of 0.08 within
1.7A
C1 \\sim C2 \\sim C3 \\sim C5 \\sim C6 \\sim C7 \\sim C8 \\sim C9 \\sim C10
\\sim C11 \\sim C12: within 1.7A with sigma of 0.04 and sigma for terminal
atoms of 0.08 within 1.7A
3. Rigid body (RIGU) restrains
 C4
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
 C1, C2, C3, C5, C6, C7, C8, C9, C10, C11, C12
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
4. Others
 Fixed Sof: H1A(0.5) H1B(0.5) H1C(0.5)
5.a Aromatic/amide H refined with riding coordinates:
 C8(H8), C7(H7), C2(H2)
5.b Idealised Me refined as rotating group:
 C1(H1A,H1B,H1C), C12(H12A,H12B,H12C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag01 Ag 0.63242(2) 0.36758(2) 0.50145(7) 0.0147(3) Uani 1 2 d S T P . .
Ag02 Ag 0.53353(3) 0.20020(3) 0.333333 0.0202(3) Uani 1 2 d S T P . .
S003 S 0.55398(10) 0.27699(5) 0.4737(2) 0.0124(6) Uani 1 2 d S T P . .
O1 O 0.57029(15) 0.42971(15) 0.4619(7) 0.0231(18) Uani 1 2 d S T P . .
O2 O 0.59398(14) 0.40602(14) 0.6298(7) 0.0190(17) Uani 1 2 d S T P . .
F1 F 0.52475(13) 0.47525(13) 0.5814(7) 0.042(2) Uani 1 2 d S T P . .
F2 F 0.5834(2) 0.4908(2) 0.7141(6) 0.0539(18) Uani 1 1 d . . . . .
N1 N 0.4541(3) 0.1207(3) 0.333333 0.017(2) Uani 1 2 d S T P . .
C1 C 0.5510(4) 0.2755(2) 0.7187(9) 0.018(2) Uani 1 2 d S TU P . .
H1A H 0.581417 0.270122 0.702952 0.028 Uiso 0.5 1 calc R U P A -1
H1B H 0.531636 0.254812 0.788137 0.028 Uiso 0.5 1 calc R U P A -1
H1C H 0.564074 0.313629 0.732629 0.028 Uiso 0.5 1 calc R U P A -1
C4 C 0.5734(2) 0.4266(2) 0.5699(10) 0.018(2) Uiso 1 2 d S . P . .
C6 C 0.5136(4) 0.2568(2) 0.6138(9) 0.017(2) Uani 1 2 d S TU P . .
C8 C 0.4075(3) 0.1183(3) 0.3065(7) 0.0201(17) Uani 1 1 d . U . . .
H8 H 0.408223 0.150655 0.286032 0.024 Uiso 1 1 calc R U . . .
C10 C 0.3071(4) -0.0263(4) 0.333333 0.022(2) Uani 1 2 d S TU P . .
C12 C 0.4782(3) 0.1954(3) 0.6135(8) 0.0218(18) Uani 1 1 d . U . . .
H12A H 0.455733 0.184031 0.542918 0.033 Uiso 1 1 calc R U . . .
H12B H 0.455277 0.183898 0.683336 0.033 Uiso 1 1 calc R U . . .
H12C H 0.500995 0.179100 0.613956 0.033 Uiso 1 1 calc R U . . .
C3 C 0.2155(4) -0.1178(4) 0.333333 0.017(2) Uani 1 2 d S TU P . .
C7 C 0.1916(3) -0.1443(3) 0.4376(7) 0.0204(17) Uani 1 1 d . U . . .
H7 H 0.208693 -0.129060 0.510155 0.024 Uiso 1 1 calc R U . . .
C2 C 0.3589(3) 0.0715(3) 0.3072(7) 0.0195(16) Uani 1 1 d . U . . .
H2 H 0.326997 0.072221 0.289738 0.023 Uiso 1 1 calc R U . . .
C9 C 0.2651(4) -0.0682(4) 0.333333 0.026(3) Uani 1 2 d S TU P . .
C5 C 0.3562(4) 0.0229(4) 0.333333 0.020(2) Uani 1 2 d S TU P . .
C11 C 0.5476(2) 0.4524(2) 0.6447(11) 0.026(3) Uani 1 2 d S T P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag01 Ag01 2.9595(13) 3_665 ?
Ag01 Ag01 2.9595(14) 2_655 ?
Ag01 Ag02 3.1543(9) 32 ?
Ag01 Ag02 3.1544(9) 3_665 ?
Ag01 S003 2.474(2) . ?
Ag01 S003 2.474(2) 3_665 ?
Ag01 O2 2.412(7) . ?
Ag02 S003 2.5491(17) 33_545 ?
Ag02 S003 2.5490(17) . ?
Ag02 N1 2.289(8) . ?
S003 C6 1.889(11) . ?
O1 C4 1.240(13) . ?
O2 C4 1.235(13) . ?
F1 C11 1.350(14) . ?
F2 C11 1.332(9) . ?
N1 C8 1.343(9) . ?
N1 C8 1.343(9) 16_545 ?
C1 H1A 0.9800 . ?
C1 H1B 0.9800 . ?
C1 H1C 0.9800 . ?
C1 C6 1.516(15) . ?
C4 C11 1.542(15) . ?
C6 C12 1.537(10) . ?
C6 C12 1.538(10) 24 ?
C8 H8 0.9500 . ?
C8 C2 1.377(11) . ?
C10 C9 1.208(16) . ?
C10 C5 1.416(16) . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
C3 C7 1.393(10) . ?
C3 C7 1.393(10) 16_545 ?
C3 C9 1.430(15) . ?
C7 C7 1.363(15) 22 ?
C7 H7 0.9500 . ?
C2 H2 0.9500 . ?
C2 C5 1.396(9) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ag01 Ag01 Ag01 59.997(1) 2_655 3_665 ?
Ag01 Ag01 Ag02 97.981(13) 3_665 3_665 ?
Ag01 Ag01 Ag02 97.981(13) 2_655 32 ?
Ag01 Ag01 Ag02 138.312(17) 2_655 3_665 ?
Ag01 Ag01 Ag02 138.311(17) 3_665 32 ?
Ag02 Ag01 Ag02 74.883(18) 32 3_665 ?
S003 Ag01 Ag01 53.27(4) 3_665 3_665 ?
S003 Ag01 Ag01 112.71(4) . 3_665 ?
S003 Ag01 Ag01 112.71(4) 3_665 2_655 ?
S003 Ag01 Ag01 53.26(4) . 2_655 ?
S003 Ag01 Ag02 52.17(5) . 32 ?
S003 Ag01 Ag02 125.69(6) . 3_665 ?
S003 Ag01 Ag02 125.68(6) 3_665 32 ?
S003 Ag01 Ag02 52.16(5) 3_665 3_665 ?
S003 Ag01 S003 159.61(11) 3_665 . ?
O2 Ag01 Ag01 133.53(13) . 3_665 ?
O2 Ag01 Ag01 133.53(13) . 2_655 ?
O2 Ag01 Ag02 87.80(15) . 32 ?
O2 Ag01 Ag02 87.80(15) . 3_665 ?
O2 Ag01 S003 100.07(5) . 3_665 ?
O2 Ag01 S003 100.07(5) . . ?
Ag01 Ag02 Ag01 83.37(3) 33_545 2_655 ?
S003 Ag02 Ag01 50.04(5) . 2_655 ?
S003 Ag02 Ag01 79.72(6) . 33_545 ?
S003 Ag02 Ag01 79.71(6) 33_545 2_655 ?
S003 Ag02 Ag01 50.04(5) 33_545 33_545 ?
S003 Ag02 S003 113.33(12) . 33_545 ?
N1 Ag02 Ag01 138.314(17) . 33_545 ?
N1 Ag02 Ag01 138.314(17) . 2_655 ?
N1 Ag02 S003 123.33(6) . 33_545 ?
N1 Ag02 S003 123.33(6) . . ?
Ag01 S003 Ag01 73.48(8) . 2_655 ?
Ag01 S003 Ag02 77.79(4) 2_655 . ?
Ag01 S003 Ag02 133.52(11) 2_655 32 ?
Ag01 S003 Ag02 77.79(4) . 32 ?
Ag01 S003 Ag02 133.52(11) . . ?
Ag02 S003 Ag02 97.59(9) 32 . ?
C6 S003 Ag01 108.3(3) . . ?
C6 S003 Ag01 108.3(3) . 2_655 ?
C6 S003 Ag02 115.1(2) . 32 ?
C6 S003 Ag02 115.1(2) . . ?
C4 O2 Ag01 109.1(7) . . ?
C8 N1 Ag02 121.7(5) . . ?
C8 N1 Ag02 121.7(5) 16_545 . ?
C8 N1 C8 116.7(9) 16_545 . ?
H1A C1 H1B 109.5 . . ?
H1A C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
C6 C1 H1A 109.5 . . ?
C6 C1 H1B 109.5 . . ?
C6 C1 H1C 109.5 . . ?
O1 C4 C11 116.5(10) . . ?
O2 C4 O1 130.7(10) . . ?
O2 C4 C11 112.9(10) . . ?
C1 C6 S003 109.7(7) . . ?
C1 C6 C12 110.8(6) . . ?
C1 C6 C12 110.8(6) . 24 ?
C12 C6 S003 107.7(6) 24 . ?
C12 C6 S003 107.7(6) . . ?
C12 C6 C12 110.0(9) . 24 ?
N1 C8 H8 118.3 . . ?
N1 C8 C2 123.4(8) . . ?
C2 C8 H8 118.3 . . ?
C9 C10 C5 180(2) . . ?
C6 C12 H12A 109.5 . . ?
C6 C12 H12B 109.5 . . ?
C6 C12 H12C 109.5 . . ?
H12A C12 H12B 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
C7 C3 C7 117.3(10) . 16_545 ?
C7 C3 C9 121.4(5) 16_545 . ?
C7 C3 C9 121.4(5) . . ?
C3 C7 H7 119.3 . . ?
C7 C7 C3 121.4(5) 22 . ?
C7 C7 H7 119.3 22 . ?
C8 C2 H2 119.9 . . ?
C8 C2 C5 120.2(8) . . ?
C5 C2 H2 119.9 . . ?
C10 C9 C3 180(2) . . ?
C2 C5 C10 121.9(5) 16_545 . ?
C2 C5 C10 121.9(5) . . ?
C2 C5 C2 116.1(10) . 16_545 ?
F1 C11 C4 114.1(10) . . ?
F2 C11 F1 106.0(7) 22_665 . ?
F2 C11 F1 106.0(7) . . ?
F2 C11 F2 106.9(11) 22_665 . ?
F2 C11 C4 111.7(6) . . ?
F2 C11 C4 111.7(6) 22_665 . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ag01 S003 C6 C1 -39.06(9) . . . . ?
Ag01 S003 C6 C1 39.06(9) 2_655 . . . ?
Ag01 S003 C6 C12 -81.7(6) 2_655 . . . ?
Ag01 S003 C6 C12 81.7(6) . . . 24 ?
Ag01 S003 C6 C12 -159.8(5) . . . . ?
Ag01 S003 C6 C12 159.8(5) 2_655 . . 24 ?
Ag01 O2 C4 O1 0.000(7) . . . . ?
Ag01 O2 C4 C11 180.000(4) . . . . ?
Ag02 S003 C6 C1 -123.84(16) 32 . . . ?
Ag02 S003 C6 C1 123.84(15) . . . . ?
Ag02 S003 C6 C12 115.4(5) 32 . . . ?
Ag02 S003 C6 C12 3.1(7) . . . . ?
Ag02 S003 C6 C12 -3.1(7) 32 . . 24 ?
Ag02 S003 C6 C12 -115.4(5) . . . 24 ?
Ag02 N1 C8 C2 -179.0(6) . . . . ?
O1 C4 C11 F1 0.000(7) . . . . ?
O1 C4 C11 F2 120.2(8) . . . 22_665 ?
O1 C4 C11 F2 -120.2(8) . . . . ?
O2 C4 C11 F1 180.000(5) . . . . ?
O2 C4 C11 F2 59.8(8) . . . . ?
O2 C4 C11 F2 -59.8(8) . . . 22_665 ?
N1 C8 C2 C5 -1.9(11) . . . . ?
C8 N1 C8 C2 1.0(6) 16_545 . . . ?
C8 C2 C5 C10 -179.1(5) . . . . ?
C8 C2 C5 C2 0.9(5) . . . 16_545 ?
C7 C3 C7 C7 -0.006(1) 16_545 . . 22 ?
C9 C3 C7 C7 180.000(1) . . . 22 ?

_olex2_submission_special_instructions 'No special instructions were received'
