# Electronic Supplementary Material (ESI) for CrystEngComm.
# This journal is © The Royal Society of Chemistry 2022

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 2203855'
loop_
_audit_author_name
_audit_author_address
'Chao-Ying Gao'
;Inner Mongolia University for the Nationalities
China
;
_audit_update_record             
;
2022-08-28 deposited with the CCDC.	2022-11-10 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C3.88 H2.88 Ag0.62 N0.12 O1.62 P0.50'
_chemical_formula_weight         160.09

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   10.7786(6)
_cell_length_b                   12.6891(7)
_cell_length_c                   14.2722(8)
_cell_angle_alpha                77.4970(10)
_cell_angle_beta                 86.2210(10)
_cell_angle_gamma                67.3010(10)
_cell_volume                     1757.78(17)
_cell_formula_units_Z            16
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    6915
_cell_measurement_theta_min      1.778
_cell_measurement_theta_max      26.139

_exptl_crystal_description       block
_exptl_crystal_colour            yellow
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    2.420
_exptl_crystal_F_000             1230
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.42
_exptl_crystal_size_mid          0.31
_exptl_crystal_size_min          0.27
_exptl_absorpt_coefficient_mu    2.987
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.342
_exptl_absorpt_correction_T_max  0.446
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            10508
_diffrn_reflns_av_unetI/netI     0.0318
_diffrn_reflns_av_R_equivalents  0.0167
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_theta_min         1.778
_diffrn_reflns_theta_max         26.139
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.983
_diffrn_measured_fraction_theta_full 0.984
_diffrn_reflns_Laue_measured_fraction_max 0.983
_diffrn_reflns_Laue_measured_fraction_full 0.984
_diffrn_reflns_point_group_measured_fraction_max 0.983
_diffrn_reflns_point_group_measured_fraction_full 0.984
_reflns_number_total             6895
_reflns_number_gt                6265
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0376P)²+7.3056P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         6895
_refine_ls_number_parameters     494
_refine_ls_number_restraints     8
_refine_ls_R_factor_all          0.0307
_refine_ls_R_factor_gt           0.0268
_refine_ls_wR_factor_ref         0.0748
_refine_ls_wR_factor_gt          0.0702
_refine_ls_goodness_of_fit_ref   0.955
_refine_ls_restrained_S_all      11.693
_refine_ls_shift/su_max          0.089
_refine_ls_shift/su_mean         0.002

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.37768(3) -0.40693(3) 0.45075(2) 0.01766(8) Uani 1 1 d . . . . .
Ag2 Ag 0.40179(3) 0.26090(4) 0.46157(3) 0.03128(10) Uani 1 1 d . . . . .
Ag3 Ag 0.63249(3) 0.43661(3) 0.29301(2) 0.01405(8) Uani 1 1 d . . . . .
Ag4 Ag 0.93594(3) 0.27662(3) 0.46910(2) 0.01753(8) Uani 1 1 d . . . . .
Ag5 Ag 1.06763(3) 0.44643(3) 0.41609(2) 0.01417(8) Uani 1 1 d . . . . .
P1 P 0.71079(10) 0.47478(8) -0.26758(7) 0.00933(19) Uani 1 1 d . . . . .
P2 P 0.77052(10) -0.15684(9) -0.35284(7) 0.0109(2) Uani 1 1 d . . . . .
P3 P 0.74600(10) -0.41861(9) 0.38693(7) 0.0099(2) Uani 1 1 d . . . . .
P4 P 0.72163(10) 0.15837(8) 0.46061(7) 0.00903(19) Uani 1 1 d . . . . .
O1 O 0.6993(3) 0.5760(2) -0.2155(2) 0.0165(6) Uani 1 1 d . . . . .
H1 H 0.7221 0.6244 -0.2521 0.025 Uiso 1 1 calc R U . . .
O2 O 0.5919(3) 0.5161(3) -0.3364(2) 0.0147(6) Uani 1 1 d . . . . .
O3 O 0.8456(3) 0.4296(3) -0.3123(2) 0.0180(6) Uani 1 1 d D . . . .
O4 O 0.6301(3) -0.0771(3) -0.4037(2) 0.0170(6) Uani 1 1 d . . . . .
H4 H 0.6268 -0.0102 -0.4222 0.026 Uiso 1 1 calc R U . . .
O5 O 0.8844(3) -0.1327(2) -0.4084(2) 0.0139(6) Uani 1 1 d . . . . .
O6 O 0.7760(3) -0.2804(3) -0.3381(2) 0.0181(6) Uani 1 1 d . . . . .
O7 O 0.8616(3) -0.5315(2) 0.3749(2) 0.0133(6) Uani 1 1 d . . . . .
O8 O 0.6125(3) -0.4337(2) 0.4024(2) 0.0134(6) Uani 1 1 d . . . . .
O9 O 0.7789(3) -0.3652(2) 0.4640(2) 0.0154(6) Uani 1 1 d . . . . .
O10 O 0.8590(3) 0.0777(2) 0.5127(2) 0.0126(6) Uani 1 1 d . . . . .
H10A H 0.8602 0.0115 0.5317 0.019 Uiso 1 1 calc R U . . .
O11 O 0.6065(3) 0.1340(2) 0.5137(2) 0.0133(6) Uani 1 1 d . . . . .
O12 O 0.7105(3) 0.2841(2) 0.44823(19) 0.0120(6) Uani 1 1 d . . . . .
O14 O 1.0262(4) 0.2473(3) 0.6193(2) 0.0265(7) Uani 1 1 d D . . . .
C1 C 0.7019(4) 0.3616(3) -0.1699(3) 0.0102(8) Uani 1 1 d . . . . .
C2 C 0.7918(4) 0.3263(4) -0.0923(3) 0.0142(8) Uani 1 1 d . . . . .
H2 H 0.8478 0.3661 -0.0901 0.017 Uiso 1 1 calc R U . . .
C3 C 0.7983(4) 0.2334(4) -0.0192(3) 0.0135(8) Uani 1 1 d . . . . .
H3 H 0.8569 0.2126 0.0327 0.016 Uiso 1 1 calc R U . . .
C4 C 0.7174(4) 0.1696(3) -0.0220(3) 0.0110(8) Uani 1 1 d . . . . .
C5 C 0.6263(4) 0.2071(3) -0.0981(3) 0.0126(8) Uani 1 1 d . . . . .
H5 H 0.5688 0.1686 -0.0998 0.015 Uiso 1 1 calc R U . . .
C6 C 0.6194(4) 0.3012(4) -0.1719(3) 0.0125(8) Uani 1 1 d . . . . .
H6 H 0.5589 0.3236 -0.2229 0.015 Uiso 1 1 calc R U . . .
C7 C 0.8481(4) -0.0695(3) -0.2125(3) 0.0137(8) Uani 1 1 d . . . . .
H7 H 0.9084 -0.0527 -0.2570 0.016 Uiso 1 1 calc R U . . .
C8 C 0.8414(4) -0.0423(3) -0.1225(3) 0.0122(8) Uani 1 1 d . . . . .
H8 H 0.8975 -0.0078 -0.1074 0.015 Uiso 1 1 calc R U . . .
C9 C 0.7509(4) -0.0664(3) -0.0544(3) 0.0103(7) Uani 1 1 d . U . . .
C10 C 0.6717(4) -0.1223(3) -0.0786(3) 0.0124(8) Uani 1 1 d . . . . .
H10 H 0.6134 -0.1418 -0.0338 0.015 Uiso 1 1 calc R U . . .
C11 C 0.6791(4) -0.1485(3) -0.1679(3) 0.0123(8) Uani 1 1 d . . . . .
H11 H 0.6251 -0.1851 -0.1826 0.015 Uiso 1 1 calc R U . . .
C12 C 0.7660(4) -0.1215(3) -0.2369(3) 0.0108(8) Uani 1 1 d . . . . .
C13 C 0.7338(4) -0.1315(3) 0.1228(3) 0.0096(7) Uani 1 1 d . . . . .
C14 C 0.8342(4) -0.2430(4) 0.1335(3) 0.0127(8) Uani 1 1 d . . . . .
H14 H 0.9009 -0.2588 0.0879 0.015 Uiso 1 1 calc R U . . .
C15 C 0.8357(4) -0.3304(3) 0.2109(3) 0.0119(8) Uani 1 1 d . . . . .
H15 H 0.9054 -0.4034 0.2181 0.014 Uiso 1 1 calc R U . . .
C16 C 0.7347(4) -0.3110(3) 0.2784(3) 0.0112(8) Uani 1 1 d . . . . .
C17 C 0.6306(4) -0.2008(3) 0.2656(3) 0.0126(8) Uani 1 1 d . . . . .
H17 H 0.5603 -0.1868 0.3087 0.015 Uiso 1 1 calc R U . . .
C18 C 0.6310(4) -0.1123(3) 0.1897(3) 0.0135(8) Uani 1 1 d . . . . .
H18 H 0.5620 -0.0390 0.1831 0.016 Uiso 1 1 calc R U . . .
C19 C 0.7330(4) 0.0890(3) 0.1557(3) 0.0104(8) Uani 1 1 d . . . . .
C20 C 0.8314(4) 0.0128(3) 0.2240(3) 0.0120(8) Uani 1 1 d . . . . .
H20 H 0.8983 -0.0530 0.2081 0.014 Uiso 1 1 calc R U . . .
C21 C 0.8306(4) 0.0342(3) 0.3155(3) 0.0117(8) Uani 1 1 d . . . . .
H21 H 0.8986 -0.0159 0.3596 0.014 Uiso 1 1 calc R U . . .
C22 C 0.7292(4) 0.1294(3) 0.3415(3) 0.0113(8) Uani 1 1 d . . . . .
C23 C 0.6297(4) 0.2057(3) 0.2739(3) 0.0115(8) Uani 1 1 d . . . . .
H23 H 0.5608 0.2696 0.2910 0.014 Uiso 1 1 calc R U . . .
C24 C 0.6328(4) 0.1870(3) 0.1816(3) 0.0129(8) Uani 1 1 d . . . . .
H24 H 0.5679 0.2399 0.1365 0.016 Uiso 1 1 calc R U . . .
C25 C 0.7303(4) 0.0672(3) 0.0570(3) 0.0115(8) Uani 1 1 d . . . . .
C26 C 0.7383(4) -0.0363(3) 0.0419(3) 0.0119(8) Uani 1 1 d . . . . .
C27 C 0.8965(5) 0.3771(4) 0.1794(3) 0.0230(10) Uani 1 1 d . . . . .
H27 H 0.9264 0.3177 0.2336 0.028 Uiso 1 1 calc R U . . .
C28 C 0.9915(5) 0.3973(4) 0.1160(3) 0.0255(11) Uani 1 1 d . . . . .
H28 H 1.0825 0.3520 0.1280 0.031 Uiso 1 1 calc R U . . .
C29 C 0.9503(4) 0.4859(3) 0.0342(3) 0.0133(8) Uani 1 1 d . . . . .
C30 C 0.8128(4) 0.5460(4) 0.0190(3) 0.0164(8) Uani 1 1 d . . . . .
H30 H 0.7801 0.6034 -0.0361 0.020 Uiso 1 1 calc R U . . .
C31 C 0.7239(4) 0.5199(4) 0.0865(3) 0.0179(9) Uani 1 1 d . . . . .
H31 H 0.6321 0.5613 0.0752 0.021 Uiso 1 1 calc R U . . .
N1 N 0.7654(4) 0.4374(3) 0.1674(2) 0.0160(7) Uani 1 1 d . . . . .
H32 H 0.977(4) 0.299(3) 0.645(3) 0.018(13) Uiso 1 1 d D . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 O12 2.250(3) 2_656 ?
Ag1 O2 2.291(3) 2_655 ?
Ag1 O8 2.491(3) . ?
Ag1 O8 2.554(3) 2_646 ?
Ag1 Ag1 2.9585(7) 2_646 ?
Ag2 O11 2.229(3) . ?
Ag2 O9 2.240(3) 2_656 ?
Ag2 O6 2.594(3) 2_655 ?
Ag3 N1 2.221(3) . ?
Ag3 O2 2.332(3) 2_665 ?
Ag3 O8 2.446(3) 1_565 ?
Ag3 O12 2.548(3) . ?
Ag4 O14 2.309(3) . ?
Ag4 O5 2.361(3) 2_755 ?
Ag4 O7 2.365(3) 1_565 ?
Ag4 O12 2.430(3) . ?
Ag4 Ag5 2.9569(5) . ?
Ag5 O7 2.231(3) 1_565 ?
Ag5 O9 2.240(3) 2_756 ?
Ag5 O3 2.343(3) 2_765 ?
Ag5 O6 2.559(3) 2_755 ?
Ag5 Ag5 3.0216(6) 2_766 ?
P1 O3 1.497(3) . ?
P1 O2 1.519(3) . ?
P1 O1 1.580(3) . ?
P1 C1 1.799(4) . ?
P2 O5 1.512(3) . ?
P2 O6 1.514(3) . ?
P2 O4 1.577(3) . ?
P2 C12 1.799(4) . ?
P3 O8 1.519(3) . ?
P3 O7 1.528(3) . ?
P3 O9 1.534(3) . ?
P3 C16 1.805(4) . ?
P4 O11 1.510(3) . ?
P4 O12 1.524(3) . ?
P4 O10 1.562(3) . ?
P4 C22 1.805(4) . ?
O2 Ag1 2.291(3) 2_655 ?
O2 Ag3 2.332(3) 2_665 ?
O3 Ag5 2.343(3) 2_765 ?
O5 Ag4 2.361(3) 2_755 ?
O6 Ag5 2.558(3) 2_755 ?
O6 Ag2 2.594(3) 2_655 ?
O7 Ag5 2.231(3) 1_545 ?
O7 Ag4 2.365(3) 1_545 ?
O8 Ag3 2.446(3) 1_545 ?
O8 Ag1 2.554(3) 2_646 ?
O9 Ag5 2.240(3) 2_756 ?
O9 Ag2 2.240(3) 2_656 ?
O12 Ag1 2.250(3) 2_656 ?
C1 C6 1.386(5) . ?
C1 C2 1.399(6) . ?
C2 C3 1.378(6) . ?
C3 C4 1.407(5) . ?
C4 C5 1.388(6) . ?
C4 C25 1.492(5) . ?
C5 C6 1.391(5) . ?
C7 C12 1.389(6) . ?
C7 C8 1.391(6) . ?
C8 C9 1.403(5) . ?
C9 C10 1.402(5) . ?
C9 C26 1.489(5) . ?
C10 C11 1.376(6) . ?
C11 C12 1.394(5) . ?
C13 C18 1.397(5) . ?
C13 C14 1.394(6) . ?
C13 C26 1.494(5) . ?
C14 C15 1.382(5) . ?
C15 C16 1.389(5) . ?
C16 C17 1.398(6) . ?
C17 C18 1.382(5) . ?
C19 C20 1.395(5) . ?
C19 C24 1.399(6) . ?
C19 C25 1.499(5) . ?
C20 C21 1.388(5) . ?
C21 C22 1.384(6) . ?
C22 C23 1.396(6) . ?
C23 C24 1.384(6) . ?
C25 C26 1.345(6) . ?
C27 N1 1.323(6) . ?
C27 C28 1.383(6) . ?
C28 C29 1.392(6) . ?
C29 C30 1.387(6) . ?
C29 C29 1.495(8) 2_765 ?
C30 C31 1.393(6) . ?
C31 N1 1.346(5) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O12 Ag1 O2 164.60(10) 2_656 2_655 ?
O12 Ag1 O8 114.68(10) 2_656 . ?
O2 Ag1 O8 79.18(10) 2_655 . ?
O12 Ag1 O8 84.70(9) 2_656 2_646 ?
O2 Ag1 O8 97.63(10) 2_655 2_646 ?
O8 Ag1 O8 108.21(7) . 2_646 ?
O12 Ag1 Ag1 105.77(7) 2_656 2_646 ?
O2 Ag1 Ag1 87.51(7) 2_655 2_646 ?
O8 Ag1 Ag1 55.08(6) . 2_646 ?
O8 Ag1 Ag1 53.13(6) 2_646 2_646 ?
O11 Ag2 O9 132.90(10) . 2_656 ?
O11 Ag2 O6 137.03(10) . 2_655 ?
O9 Ag2 O6 83.41(10) 2_656 2_655 ?
N1 Ag3 O2 142.99(12) . 2_665 ?
N1 Ag3 O8 119.14(11) . 1_565 ?
O2 Ag3 O8 79.34(10) 2_665 1_565 ?
N1 Ag3 O12 121.86(11) . . ?
O2 Ag3 O12 91.07(9) 2_665 . ?
O8 Ag3 O12 80.97(9) 1_565 . ?
O14 Ag4 O5 98.64(11) . 2_755 ?
O14 Ag4 O7 117.23(11) . 1_565 ?
O5 Ag4 O7 116.60(9) 2_755 1_565 ?
O14 Ag4 O12 121.68(11) . . ?
O5 Ag4 O12 117.36(10) 2_755 . ?
O7 Ag4 O12 86.89(9) 1_565 . ?
O14 Ag4 Ag5 83.48(9) . . ?
O5 Ag4 Ag5 91.67(7) 2_755 . ?
O7 Ag4 Ag5 47.99(7) 1_565 . ?
O12 Ag4 Ag5 134.63(6) . . ?
O7 Ag5 O9 142.90(10) 1_565 2_756 ?
O7 Ag5 O3 113.96(10) 1_565 2_765 ?
O9 Ag5 O3 102.30(11) 2_756 2_765 ?
O7 Ag5 O6 104.11(10) 1_565 2_755 ?
O9 Ag5 O6 84.23(10) 2_756 2_755 ?
O3 Ag5 O6 87.74(10) 2_765 2_755 ?
O7 Ag5 Ag4 51.99(7) 1_565 . ?
O9 Ag5 Ag4 95.98(8) 2_756 . ?
O3 Ag5 Ag4 156.32(8) 2_765 . ?
O6 Ag5 Ag4 79.17(7) 2_755 . ?
O7 Ag5 Ag5 85.19(7) 1_565 2_766 ?
O9 Ag5 Ag5 74.60(7) 2_756 2_766 ?
O3 Ag5 Ag5 110.66(8) 2_765 2_766 ?
O6 Ag5 Ag5 154.28(7) 2_755 2_766 ?
Ag4 Ag5 Ag5 88.537(14) . 2_766 ?
O3 P1 O2 114.66(17) . . ?
O3 P1 O1 110.74(17) . . ?
O2 P1 O1 109.51(17) . . ?
O3 P1 C1 107.87(17) . . ?
O2 P1 C1 110.51(17) . . ?
O1 P1 C1 102.89(17) . . ?
O5 P2 O6 116.27(17) . . ?
O5 P2 O4 111.49(16) . . ?
O6 P2 O4 105.06(17) . . ?
O5 P2 C12 108.40(17) . . ?
O6 P2 C12 108.26(17) . . ?
O4 P2 C12 106.94(17) . . ?
O8 P3 O7 112.25(16) . . ?
O8 P3 O9 113.03(16) . . ?
O7 P3 O9 111.73(16) . . ?
O8 P3 C16 109.21(17) . . ?
O7 P3 C16 107.15(17) . . ?
O9 P3 C16 102.85(17) . . ?
O11 P4 O12 114.28(16) . . ?
O11 P4 O10 111.11(16) . . ?
O12 P4 O10 107.37(16) . . ?
O11 P4 C22 109.53(17) . . ?
O12 P4 C22 106.66(17) . . ?
O10 P4 C22 107.59(17) . . ?
P1 O2 Ag1 114.33(16) . 2_655 ?
P1 O2 Ag3 125.69(16) . 2_665 ?
Ag1 O2 Ag3 105.09(11) 2_655 2_665 ?
P1 O3 Ag5 122.08(16) . 2_765 ?
P2 O5 Ag4 123.17(16) . 2_755 ?
P2 O6 Ag5 128.32(16) . 2_755 ?
P2 O6 Ag2 102.79(15) . 2_655 ?
Ag5 O6 Ag2 84.66(9) 2_755 2_655 ?
P3 O7 Ag5 117.15(16) . 1_545 ?
P3 O7 Ag4 131.95(16) . 1_545 ?
Ag5 O7 Ag4 80.02(9) 1_545 1_545 ?
P3 O8 Ag3 100.81(14) . 1_545 ?
P3 O8 Ag1 162.64(18) . . ?
Ag3 O8 Ag1 96.00(10) 1_545 . ?
P3 O8 Ag1 111.67(15) . 2_646 ?
Ag3 O8 Ag1 91.86(9) 1_545 2_646 ?
Ag1 O8 Ag1 71.79(7) . 2_646 ?
P3 O9 Ag5 130.40(16) . 2_756 ?
P3 O9 Ag2 114.07(15) . 2_656 ?
Ag5 O9 Ag2 101.50(11) 2_756 2_656 ?
P4 O11 Ag2 115.21(15) . . ?
P4 O12 Ag1 128.32(16) . 2_656 ?
P4 O12 Ag4 106.97(14) . . ?
Ag1 O12 Ag4 92.61(10) 2_656 . ?
P4 O12 Ag3 123.79(15) . . ?
Ag1 O12 Ag3 96.80(10) 2_656 . ?
Ag4 O12 Ag3 101.57(9) . . ?
C6 C1 C2 118.7(3) . . ?
C6 C1 P1 123.2(3) . . ?
C2 C1 P1 117.9(3) . . ?
C3 C2 C1 120.8(4) . . ?
C2 C3 C4 120.8(4) . . ?
C5 C4 C3 117.9(4) . . ?
C5 C4 C25 122.8(4) . . ?
C3 C4 C25 119.3(4) . . ?
C4 C5 C6 121.3(4) . . ?
C5 C6 C1 120.4(4) . . ?
C12 C7 C8 120.9(4) . . ?
C7 C8 C9 120.6(4) . . ?
C10 C9 C8 118.0(4) . . ?
C10 C9 C26 119.7(3) . . ?
C8 C9 C26 122.3(4) . . ?
C11 C10 C9 120.8(4) . . ?
C10 C11 C12 121.4(4) . . ?
C11 C12 C7 118.3(4) . . ?
C11 C12 P2 119.4(3) . . ?
C7 C12 P2 122.3(3) . . ?
C18 C13 C14 118.2(3) . . ?
C18 C13 C26 121.7(4) . . ?
C14 C13 C26 120.1(3) . . ?
C15 C14 C13 120.8(4) . . ?
C14 C15 C16 121.1(4) . . ?
C15 C16 C17 118.3(4) . . ?
C15 C16 P3 121.3(3) . . ?
C17 C16 P3 120.1(3) . . ?
C18 C17 C16 120.7(4) . . ?
C17 C18 C13 120.9(4) . . ?
C20 C19 C24 118.6(4) . . ?
C20 C19 C25 121.8(3) . . ?
C24 C19 C25 119.6(4) . . ?
C21 C20 C19 120.7(4) . . ?
C22 C21 C20 120.4(4) . . ?
C21 C22 C23 119.2(4) . . ?
C21 C22 P4 121.9(3) . . ?
C23 C22 P4 118.8(3) . . ?
C24 C23 C22 120.5(4) . . ?
C23 C24 C19 120.5(4) . . ?
C26 C25 C4 123.5(4) . . ?
C26 C25 C19 122.3(3) . . ?
C4 C25 C19 114.2(3) . . ?
C25 C26 C9 124.2(3) . . ?
C25 C26 C13 121.6(4) . . ?
C9 C26 C13 114.1(3) . . ?
N1 C27 C28 123.9(4) . . ?
C27 C28 C29 119.6(4) . . ?
C30 C29 C28 116.8(4) . . ?
C30 C29 C29 121.7(5) . 2_765 ?
C28 C29 C29 121.5(5) . 2_765 ?
C29 C30 C31 119.8(4) . . ?
N1 C31 C30 122.7(4) . . ?
C27 N1 C31 117.1(4) . . ?
C27 N1 Ag3 119.3(3) . . ?
C31 N1 Ag3 121.2(3) . . ?

_refine_diff_density_max         0.681
_refine_diff_density_min         -1.261
_refine_diff_density_rms         0.129



