# Electronic Supplementary Material (ESI) for CrystEngComm.
# This journal is © The Royal Society of Chemistry 2022

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_20211126-LDF-351-233K
_database_code_depnum_ccdc_archive 'CCDC 2206262'
loop_
_audit_author_name
_audit_author_address
'yan sui'
;School of Chemistry and Chemical Engineering, Jinggangshan University
China
;
_audit_update_record             
;
2022-09-09 deposited with the CCDC.	2022-10-31 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'Eu K N8 O24, 4(C7 H14 N)'
_chemical_formula_sum            'C28 H56 Eu K N12 O24'
_chemical_formula_weight         1135.90

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
K K 0.2009 0.2494 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'I 2/a'
_space_group_name_Hall           '-I 2ya'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y, -z'
'x+1/2, y+1/2, z+1/2'
'-x+1, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y, z'
'-x+1/2, -y+1/2, -z+1/2'
'x, -y+1/2, z+1/2'

_cell_length_a                   19.4896(6)
_cell_length_b                   9.8579(3)
_cell_length_c                   23.1307(7)
_cell_angle_alpha                90
_cell_angle_beta                 90.091(3)
_cell_angle_gamma                90
_cell_volume                     4444.0(2)
_cell_formula_units_Z            4
_cell_measurement_temperature    233(2)
_cell_measurement_reflns_used    4073
_cell_measurement_theta_min      3.5300
_cell_measurement_theta_max      28.8140

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.698
_exptl_crystal_F_000             2328
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.200
_exptl_crystal_size_mid          0.180
_exptl_crystal_size_min          0.150
_exptl_absorpt_coefficient_mu    1.604
_shelx_estimated_absorpt_T_min   0.740
_shelx_estimated_absorpt_T_max   0.795
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.80868
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.40.53 (Rigaku Oxford Diffraction, 2019)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      233(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_measurement_device_type  'SuperNova, Single source at offset/far, EosS2'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            5332
_diffrn_reflns_av_unetI/netI     0.0319
_diffrn_reflns_av_R_equivalents  0.0201
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_k_max       7
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_theta_min         3.354
_diffrn_reflns_theta_max         24.499
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.865
_diffrn_measured_fraction_theta_full 0.799
_diffrn_reflns_Laue_measured_fraction_max 0.865
_diffrn_reflns_Laue_measured_fraction_full 0.799
_diffrn_reflns_point_group_measured_fraction_max 0.865
_diffrn_reflns_point_group_measured_fraction_full 0.799
_reflns_number_total             3215
_reflns_number_gt                2740
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'CrysAlisPro 1.171.40.53 (Rigaku OD, 2019)'
_computing_cell_refinement       'CrysAlisPro 1.171.40.53 (Rigaku OD, 2019)'
_computing_data_reduction        'CrysAlisPro 1.171.40.53 (Rigaku OD, 2019)'
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2014 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
;
 ?
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0271P)²+12.1827P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         3215
_refine_ls_number_parameters     300
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0350
_refine_ls_R_factor_gt           0.0293
_refine_ls_wR_factor_ref         0.0743
_refine_ls_wR_factor_gt          0.0717
_refine_ls_goodness_of_fit_ref   1.106
_refine_ls_restrained_S_all      1.106
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.0000 1.0000 0.5000 0.01650(10) Uani 1 2 d S . P . .
K1 K 0.2500 0.49596(11) 0.5000 0.0271(3) Uani 1 2 d S T P . .
O1 O 0.23249(16) 0.3710(4) 0.38854(14) 0.0494(9) Uani 1 1 d . . . . .
N1 N 0.2839(2) 0.4214(4) 0.36545(16) 0.0373(9) Uani 1 1 d . . . . .
O2 O 0.31371(19) 0.3597(4) 0.32572(14) 0.0565(10) Uani 1 1 d . . . . .
N2 N 0.10728(17) 0.7834(3) 0.50431(14) 0.0274(8) Uani 1 1 d . . . . .
O3 O 0.3079(2) 0.5307(3) 0.38305(16) 0.0535(9) Uani 1 1 d . . . . .
N3 N 0.0122(2) 1.0194(4) 0.37111(15) 0.0339(9) Uani 1 1 d . . . . .
O4 O 0.14979(16) 0.6931(3) 0.50728(15) 0.0471(9) Uani 1 1 d . . . . .
N4 N 0.11008(18) 1.2092(4) 0.51563(15) 0.0317(8) Uani 1 1 d . . . . .
O5 O 0.12304(15) 0.9064(3) 0.50856(12) 0.0342(7) Uani 1 1 d . . . . .
O6 O 0.04465(15) 0.7565(3) 0.49672(13) 0.0357(7) Uani 1 1 d . . . . .
O7 O 0.04865(16) 0.9390(3) 0.39979(12) 0.0378(7) Uani 1 1 d . . . . .
O8 O 0.0153(2) 1.0255(4) 0.31818(13) 0.0595(11) Uani 1 1 d . . . . .
O9 O -0.02826(16) 1.0945(3) 0.39894(12) 0.0385(8) Uani 1 1 d . . . . .
O10 O 0.07924(15) 1.1577(3) 0.55789(12) 0.0355(7) Uani 1 1 d . . . . .
O11 O 0.1550(2) 1.2937(4) 0.52323(17) 0.0723(12) Uani 1 1 d . . . . .
O12 O 0.09202(15) 1.1710(3) 0.46628(12) 0.0387(7) Uani 1 1 d . . . . .
N6 N 0.25435(19) 1.0846(4) 0.35814(16) 0.0393(9) Uani 1 1 d . . . . .
H6 H 0.2593 1.1801 0.3692 0.047 Uiso 1 1 calc R U . . .
C8 C 0.1972(3) 1.0728(5) 0.3166(2) 0.0516(14) Uani 1 1 d . . . . .
H8A H 0.2051 1.1330 0.2841 0.062 Uiso 1 1 calc R U . . .
H8B H 0.1547 1.0994 0.3350 0.062 Uiso 1 1 calc R U . . .
C9 C 0.1918(3) 0.9283(5) 0.2955(2) 0.0502(13) Uani 1 1 d . . . . .
H9A H 0.2026 0.9241 0.2546 0.060 Uiso 1 1 calc R U . . .
H9B H 0.1454 0.8953 0.3008 0.060 Uiso 1 1 calc R U . . .
C10 C 0.2420(2) 0.8401(5) 0.3295(2) 0.0410(11) Uani 1 1 d . . . . .
H10 H 0.2368 0.7447 0.3184 0.049 Uiso 1 1 calc R U . . .
C11 C 0.3137(3) 0.8873(6) 0.3174(3) 0.0653(16) Uani 1 1 d . . . . .
H11A H 0.3244 0.8731 0.2769 0.078 Uiso 1 1 calc R U . . .
H11B H 0.3460 0.8355 0.3404 0.078 Uiso 1 1 calc R U . . .
C12 C 0.3200(3) 1.0377(6) 0.3320(3) 0.0648(17) Uani 1 1 d . . . . .
H12A H 0.3574 1.0517 0.3591 0.078 Uiso 1 1 calc R U . . .
H12B H 0.3296 1.0893 0.2973 0.078 Uiso 1 1 calc R U . . .
C13 C 0.2264(3) 0.8578(5) 0.3931(2) 0.0540(14) Uani 1 1 d . . . . .
H13A H 0.2547 0.7969 0.4157 0.065 Uiso 1 1 calc R U . . .
H13B H 0.1786 0.8357 0.4003 0.065 Uiso 1 1 calc R U . . .
C14 C 0.2404(3) 1.0038(5) 0.4108(2) 0.0579(16) Uani 1 1 d . . . . .
H14A H 0.2010 1.0406 0.4310 0.070 Uiso 1 1 calc R U . . .
H14B H 0.2797 1.0073 0.4366 0.070 Uiso 1 1 calc R U . . .
C1 C -0.0298(3) 0.3885(5) 0.3168(2) 0.0524(14) Uani 1 1 d . . . . .
H1A H -0.0543 0.3952 0.2804 0.063 Uiso 1 1 calc R U . . .
H1B H -0.0442 0.3060 0.3362 0.063 Uiso 1 1 calc R U . . .
C2 C 0.0467(3) 0.3846(5) 0.3060(2) 0.0537(14) Uani 1 1 d . . . . .
H2A H 0.0655 0.2993 0.3197 0.064 Uiso 1 1 calc R U . . .
H2B H 0.0556 0.3916 0.2648 0.064 Uiso 1 1 calc R U . . .
C3 C 0.0799(3) 0.5006(5) 0.3372(2) 0.0490(13) Uani 1 1 d . . . . .
H3 H 0.1296 0.4981 0.3305 0.059 Uiso 1 1 calc R U . . .
C4 C 0.0513(3) 0.6329(5) 0.3150(2) 0.0580(15) Uani 1 1 d . . . . .
H4A H 0.0726 0.7082 0.3352 0.070 Uiso 1 1 calc R U . . .
H4B H 0.0613 0.6421 0.2741 0.070 Uiso 1 1 calc R U . . .
N5 N -0.0455(2) 0.5095(4) 0.35397(17) 0.0401(10) Uani 1 1 d . . . . .
H5 H -0.0950 0.5128 0.3609 0.048 Uiso 1 1 calc R U . . .
C5 C -0.0244(3) 0.6356(5) 0.3244(2) 0.0521(14) Uani 1 1 d . . . . .
H5A H -0.0367 0.7135 0.3478 0.063 Uiso 1 1 calc R U . . .
H5B H -0.0480 0.6430 0.2875 0.063 Uiso 1 1 calc R U . . .
C6 C 0.0662(4) 0.4876(6) 0.4007(2) 0.0695(19) Uani 1 1 d . . . . .
H6A H 0.0831 0.4009 0.4146 0.083 Uiso 1 1 calc R U . . .
H6B H 0.0900 0.5590 0.4215 0.083 Uiso 1 1 calc R U . . .
C7 C -0.0089(4) 0.4977(6) 0.4113(2) 0.0629(17) Uani 1 1 d . . . . .
H7A H -0.0187 0.5767 0.4349 0.076 Uiso 1 1 calc R U . . .
H7B H -0.0248 0.4178 0.4317 0.076 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O6 2.554(3) 5_576 ?
Eu1 O6 2.554(3) . ?
Eu1 O10 2.567(3) 5_576 ?
Eu1 O10 2.567(3) . ?
Eu1 O9 2.575(3) 5_576 ?
Eu1 O9 2.575(3) . ?
Eu1 O5 2.577(3) . ?
Eu1 O5 2.577(3) 5_576 ?
Eu1 O7 2.577(3) 5_576 ?
Eu1 O7 2.577(3) . ?
Eu1 O12 2.582(3) 5_576 ?
Eu1 O12 2.583(3) . ?
K1 O4 2.760(3) 2_556 ?
K1 O4 2.760(3) . ?
K1 O11 2.775(4) 1_545 ?
K1 O11 2.775(4) 2_546 ?
K1 O1 2.877(3) 2_556 ?
K1 O1 2.877(3) . ?
K1 O3 2.953(4) 2_556 ?
K1 O3 2.953(4) . ?
K1 N1 3.266(4) . ?
K1 N1 3.266(4) 2_556 ?
O1 N1 1.240(5) . ?
N1 O3 1.244(5) . ?
N1 O2 1.246(5) . ?
N2 O4 1.218(4) . ?
N2 O5 1.254(4) . ?
N2 O6 1.261(4) . ?
N3 O8 1.227(5) . ?
N3 O7 1.254(4) . ?
N3 O9 1.259(4) . ?
N4 O11 1.220(4) . ?
N4 O12 1.252(4) . ?
N4 O10 1.256(4) . ?
O11 K1 2.775(4) 1_565 ?
N6 C8 1.474(5) . ?
N6 C14 1.481(6) . ?
N6 C12 1.489(7) . ?
N6 H6 0.9800 . ?
C8 C9 1.509(7) . ?
C8 H8A 0.9700 . ?
C8 H8B 0.9700 . ?
C9 C10 1.527(6) . ?
C9 H9A 0.9700 . ?
C9 H9B 0.9700 . ?
C10 C11 1.499(7) . ?
C10 C13 1.511(6) . ?
C10 H10 0.9800 . ?
C11 C12 1.526(8) . ?
C11 H11A 0.9700 . ?
C11 H11B 0.9700 . ?
C12 H12A 0.9700 . ?
C12 H12B 0.9700 . ?
C13 C14 1.522(7) . ?
C13 H13A 0.9700 . ?
C13 H13B 0.9700 . ?
C14 H14A 0.9700 . ?
C14 H14B 0.9700 . ?
C1 N5 1.502(6) . ?
C1 C2 1.512(7) . ?
C1 H1A 0.9700 . ?
C1 H1B 0.9700 . ?
C2 C3 1.499(7) . ?
C2 H2A 0.9700 . ?
C2 H2B 0.9700 . ?
C3 C6 1.500(8) . ?
C3 C4 1.509(7) . ?
C3 H3 0.9800 . ?
C4 C5 1.494(7) . ?
C4 H4A 0.9700 . ?
C4 H4B 0.9700 . ?
N5 C5 1.477(6) . ?
N5 C7 1.509(6) . ?
N5 H5 0.9800 . ?
C5 H5A 0.9700 . ?
C5 H5B 0.9700 . ?
C6 C7 1.488(9) . ?
C6 H6A 0.9700 . ?
C6 H6B 0.9700 . ?
C7 H7A 0.9700 . ?
C7 H7B 0.9700 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O6 Eu1 O6 180.0 5_576 . ?
O6 Eu1 O10 112.33(9) 5_576 5_576 ?
O6 Eu1 O10 67.67(9) . 5_576 ?
O6 Eu1 O10 67.67(9) 5_576 . ?
O6 Eu1 O10 112.33(9) . . ?
O10 Eu1 O10 180.00(10) 5_576 . ?
O6 Eu1 O9 112.67(10) 5_576 5_576 ?
O6 Eu1 O9 67.33(10) . 5_576 ?
O10 Eu1 O9 112.46(10) 5_576 5_576 ?
O10 Eu1 O9 67.54(10) . 5_576 ?
O6 Eu1 O9 67.33(10) 5_576 . ?
O6 Eu1 O9 112.67(10) . . ?
O10 Eu1 O9 67.54(10) 5_576 . ?
O10 Eu1 O9 112.46(10) . . ?
O9 Eu1 O9 180.0 5_576 . ?
O6 Eu1 O5 130.64(9) 5_576 . ?
O6 Eu1 O5 49.36(9) . . ?
O10 Eu1 O5 112.47(9) 5_576 . ?
O10 Eu1 O5 67.53(9) . . ?
O9 Eu1 O5 66.61(10) 5_576 . ?
O9 Eu1 O5 113.39(10) . . ?
O6 Eu1 O5 49.36(9) 5_576 5_576 ?
O6 Eu1 O5 130.64(9) . 5_576 ?
O10 Eu1 O5 67.53(9) 5_576 5_576 ?
O10 Eu1 O5 112.47(9) . 5_576 ?
O9 Eu1 O5 113.39(10) 5_576 5_576 ?
O9 Eu1 O5 66.61(10) . 5_576 ?
O5 Eu1 O5 180.0 . 5_576 ?
O6 Eu1 O7 68.17(10) 5_576 5_576 ?
O6 Eu1 O7 111.83(10) . 5_576 ?
O10 Eu1 O7 112.87(10) 5_576 5_576 ?
O10 Eu1 O7 67.13(10) . 5_576 ?
O9 Eu1 O7 49.19(10) 5_576 5_576 ?
O9 Eu1 O7 130.81(10) . 5_576 ?
O5 Eu1 O7 110.99(9) . 5_576 ?
O5 Eu1 O7 69.01(9) 5_576 5_576 ?
O6 Eu1 O7 111.83(10) 5_576 . ?
O6 Eu1 O7 68.17(10) . . ?
O10 Eu1 O7 67.13(10) 5_576 . ?
O10 Eu1 O7 112.87(10) . . ?
O9 Eu1 O7 130.81(10) 5_576 . ?
O9 Eu1 O7 49.19(10) . . ?
O5 Eu1 O7 69.02(9) . . ?
O5 Eu1 O7 110.99(9) 5_576 . ?
O7 Eu1 O7 180.0 5_576 . ?
O6 Eu1 O12 111.56(9) 5_576 5_576 ?
O6 Eu1 O12 68.44(9) . 5_576 ?
O10 Eu1 O12 49.07(9) 5_576 5_576 ?
O10 Eu1 O12 130.93(9) . 5_576 ?
O9 Eu1 O12 68.73(10) 5_576 5_576 ?
O9 Eu1 O12 111.27(10) . 5_576 ?
O5 Eu1 O12 112.93(9) . 5_576 ?
O5 Eu1 O12 67.07(9) 5_576 5_576 ?
O7 Eu1 O12 67.91(10) 5_576 5_576 ?
O7 Eu1 O12 112.09(10) . 5_576 ?
O6 Eu1 O12 68.44(9) 5_576 . ?
O6 Eu1 O12 111.56(9) . . ?
O10 Eu1 O12 130.93(9) 5_576 . ?
O10 Eu1 O12 49.07(9) . . ?
O9 Eu1 O12 111.27(10) 5_576 . ?
O9 Eu1 O12 68.73(10) . . ?
O5 Eu1 O12 67.07(9) . . ?
O5 Eu1 O12 112.93(9) 5_576 . ?
O7 Eu1 O12 112.09(10) 5_576 . ?
O7 Eu1 O12 67.91(10) . . ?
O12 Eu1 O12 180.0 5_576 . ?
O4 K1 O4 90.52(14) 2_556 . ?
O4 K1 O11 172.01(10) 2_556 1_545 ?
O4 K1 O11 91.23(13) . 1_545 ?
O4 K1 O11 91.23(13) 2_556 2_546 ?
O4 K1 O11 172.01(10) . 2_546 ?
O11 K1 O11 88.11(19) 1_545 2_546 ?
O4 K1 O1 105.85(10) 2_556 2_556 ?
O4 K1 O1 109.24(10) . 2_556 ?
O11 K1 O1 66.24(11) 1_545 2_556 ?
O11 K1 O1 77.74(11) 2_546 2_556 ?
O4 K1 O1 109.24(10) 2_556 . ?
O4 K1 O1 105.84(10) . . ?
O11 K1 O1 77.74(11) 1_545 . ?
O11 K1 O1 66.24(10) 2_546 . ?
O1 K1 O1 129.32(15) 2_556 . ?
O4 K1 O3 104.22(10) 2_556 2_556 ?
O4 K1 O3 65.85(10) . 2_556 ?
O11 K1 O3 69.50(11) 1_545 2_556 ?
O11 K1 O3 121.14(11) 2_546 2_556 ?
O1 K1 O3 43.42(9) 2_556 2_556 ?
O1 K1 O3 145.66(10) . 2_556 ?
O4 K1 O3 65.85(10) 2_556 . ?
O4 K1 O3 104.22(10) . . ?
O11 K1 O3 121.14(11) 1_545 . ?
O11 K1 O3 69.50(11) 2_546 . ?
O1 K1 O3 145.66(10) 2_556 . ?
O1 K1 O3 43.42(9) . . ?
O3 K1 O3 166.66(13) 2_556 . ?
O4 K1 N1 87.49(10) 2_556 . ?
O4 K1 N1 111.15(10) . . ?
O11 K1 N1 99.14(11) 1_545 . ?
O11 K1 N1 61.16(10) 2_546 . ?
O1 K1 N1 137.19(10) 2_556 . ?
O1 K1 N1 22.13(9) . . ?
O3 K1 N1 167.74(11) 2_556 . ?
O3 K1 N1 22.34(9) . . ?
O4 K1 N1 111.15(10) 2_556 2_556 ?
O4 K1 N1 87.49(10) . 2_556 ?
O11 K1 N1 61.16(10) 1_545 2_556 ?
O11 K1 N1 99.14(11) 2_546 2_556 ?
O1 K1 N1 22.13(9) 2_556 2_556 ?
O1 K1 N1 137.19(10) . 2_556 ?
O3 K1 N1 22.34(9) 2_556 2_556 ?
O3 K1 N1 167.74(10) . 2_556 ?
N1 K1 N1 153.99(14) . 2_556 ?
N1 O1 K1 96.9(2) . . ?
O1 N1 O3 120.7(4) . . ?
O1 N1 O2 120.0(4) . . ?
O3 N1 O2 119.2(4) . . ?
O1 N1 K1 61.0(2) . . ?
O3 N1 K1 64.5(2) . . ?
O2 N1 K1 155.2(3) . . ?
O4 N2 O5 122.4(3) . . ?
O4 N2 O6 120.8(3) . . ?
O5 N2 O6 116.8(3) . . ?
O4 N2 Eu1 178.0(3) . . ?
O5 N2 Eu1 58.90(19) . . ?
O6 N2 Eu1 57.91(18) . . ?
N1 O3 K1 93.1(3) . . ?
O8 N3 O7 122.0(4) . . ?
O8 N3 O9 120.9(4) . . ?
O7 N3 O9 117.1(3) . . ?
O8 N3 Eu1 178.1(3) . . ?
O7 N3 Eu1 58.60(19) . . ?
O9 N3 Eu1 58.56(18) . . ?
N2 O4 K1 172.9(3) . . ?
O11 N4 O12 122.5(4) . . ?
O11 N4 O10 120.5(4) . . ?
O12 N4 O10 117.0(3) . . ?
O11 N4 Eu1 178.6(3) . . ?
O12 N4 Eu1 58.84(19) . . ?
O10 N4 Eu1 58.13(18) . . ?
N2 O5 Eu1 96.5(2) . . ?
N2 O6 Eu1 97.4(2) . . ?
N3 O7 Eu1 96.8(2) . . ?
N3 O9 Eu1 96.8(2) . . ?
N4 O10 Eu1 97.3(2) . . ?
N4 O11 K1 160.2(3) . 1_565 ?
N4 O12 Eu1 96.6(2) . . ?
C8 N6 C14 110.8(4) . . ?
C8 N6 C12 111.0(4) . . ?
C14 N6 C12 109.0(4) . . ?
C8 N6 H6 108.6 . . ?
C14 N6 H6 108.6 . . ?
C12 N6 H6 108.6 . . ?
N6 C8 C9 109.7(4) . . ?
N6 C8 H8A 109.7 . . ?
C9 C8 H8A 109.7 . . ?
N6 C8 H8B 109.7 . . ?
C9 C8 H8B 109.7 . . ?
H8A C8 H8B 108.2 . . ?
C8 C9 C10 109.1(4) . . ?
C8 C9 H9A 109.9 . . ?
C10 C9 H9A 109.9 . . ?
C8 C9 H9B 109.9 . . ?
C10 C9 H9B 109.9 . . ?
H9A C9 H9B 108.3 . . ?
C11 C10 C13 109.6(4) . . ?
C11 C10 C9 108.8(4) . . ?
C13 C10 C9 107.8(4) . . ?
C11 C10 H10 110.2 . . ?
C13 C10 H10 110.2 . . ?
C9 C10 H10 110.2 . . ?
C10 C11 C12 109.6(4) . . ?
C10 C11 H11A 109.8 . . ?
C12 C11 H11A 109.8 . . ?
C10 C11 H11B 109.8 . . ?
C12 C11 H11B 109.8 . . ?
H11A C11 H11B 108.2 . . ?
N6 C12 C11 108.8(4) . . ?
N6 C12 H12A 109.9 . . ?
C11 C12 H12A 109.9 . . ?
N6 C12 H12B 109.9 . . ?
C11 C12 H12B 109.9 . . ?
H12A C12 H12B 108.3 . . ?
C10 C13 C14 109.6(4) . . ?
C10 C13 H13A 109.7 . . ?
C14 C13 H13A 109.7 . . ?
C10 C13 H13B 109.7 . . ?
C14 C13 H13B 109.7 . . ?
H13A C13 H13B 108.2 . . ?
N6 C14 C13 108.6(4) . . ?
N6 C14 H14A 110.0 . . ?
C13 C14 H14A 110.0 . . ?
N6 C14 H14B 110.0 . . ?
C13 C14 H14B 110.0 . . ?
H14A C14 H14B 108.3 . . ?
N5 C1 C2 108.5(4) . . ?
N5 C1 H1A 110.0 . . ?
C2 C1 H1A 110.0 . . ?
N5 C1 H1B 110.0 . . ?
C2 C1 H1B 110.0 . . ?
H1A C1 H1B 108.4 . . ?
C3 C2 C1 109.0(4) . . ?
C3 C2 H2A 109.9 . . ?
C1 C2 H2A 109.9 . . ?
C3 C2 H2B 109.9 . . ?
C1 C2 H2B 109.9 . . ?
H2A C2 H2B 108.3 . . ?
C2 C3 C6 109.2(5) . . ?
C2 C3 C4 109.6(4) . . ?
C6 C3 C4 110.0(5) . . ?
C2 C3 H3 109.3 . . ?
C6 C3 H3 109.3 . . ?
C4 C3 H3 109.3 . . ?
C5 C4 C3 109.3(4) . . ?
C5 C4 H4A 109.8 . . ?
C3 C4 H4A 109.8 . . ?
C5 C4 H4B 109.8 . . ?
C3 C4 H4B 109.8 . . ?
H4A C4 H4B 108.3 . . ?
C5 N5 C1 110.3(4) . . ?
C5 N5 C7 109.9(4) . . ?
C1 N5 C7 110.2(4) . . ?
C5 N5 H5 108.8 . . ?
C1 N5 H5 108.8 . . ?
C7 N5 H5 108.8 . . ?
N5 C5 C4 109.1(4) . . ?
N5 C5 H5A 109.9 . . ?
C4 C5 H5A 109.9 . . ?
N5 C5 H5B 109.9 . . ?
C4 C5 H5B 109.9 . . ?
H5A C5 H5B 108.3 . . ?
C7 C6 C3 109.4(5) . . ?
C7 C6 H6A 109.8 . . ?
C3 C6 H6A 109.8 . . ?
C7 C6 H6B 109.8 . . ?
C3 C6 H6B 109.8 . . ?
H6A C6 H6B 108.2 . . ?
C6 C7 N5 109.0(4) . . ?
C6 C7 H7A 109.9 . . ?
N5 C7 H7A 109.9 . . ?
C6 C7 H7B 109.9 . . ?
N5 C7 H7B 109.9 . . ?
H7A C7 H7B 108.3 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
K1 O1 N1 O3 -25.7(4) . . . . ?
K1 O1 N1 O2 151.4(3) . . . . ?
O1 N1 O3 K1 24.8(4) . . . . ?
O2 N1 O3 K1 -152.3(3) . . . . ?
O4 N2 O5 Eu1 -178.2(3) . . . . ?
O6 N2 O5 Eu1 1.7(4) . . . . ?
O4 N2 O6 Eu1 178.2(3) . . . . ?
O5 N2 O6 Eu1 -1.8(4) . . . . ?
O8 N3 O7 Eu1 -177.9(4) . . . . ?
O9 N3 O7 Eu1 2.1(4) . . . . ?
O8 N3 O9 Eu1 177.9(4) . . . . ?
O7 N3 O9 Eu1 -2.1(4) . . . . ?
O11 N4 O10 Eu1 -179.6(4) . . . . ?
O12 N4 O10 Eu1 1.1(4) . . . . ?
O12 N4 O11 K1 12.0(13) . . . 1_565 ?
O10 N4 O11 K1 -167.2(8) . . . 1_565 ?
O11 N4 O12 Eu1 179.6(4) . . . . ?
O10 N4 O12 Eu1 -1.1(4) . . . . ?
C14 N6 C8 C9 -64.9(5) . . . . ?
C12 N6 C8 C9 56.5(6) . . . . ?
N6 C8 C9 C10 6.4(6) . . . . ?
C8 C9 C10 C11 -63.2(5) . . . . ?
C8 C9 C10 C13 55.5(6) . . . . ?
C13 C10 C11 C12 -61.4(6) . . . . ?
C9 C10 C11 C12 56.2(6) . . . . ?
C8 N6 C12 C11 -63.2(6) . . . . ?
C14 N6 C12 C11 59.1(6) . . . . ?
C10 C11 C12 N6 4.7(7) . . . . ?
C11 C10 C13 C14 53.8(6) . . . . ?
C9 C10 C13 C14 -64.4(6) . . . . ?
C8 N6 C14 C13 55.7(6) . . . . ?
C12 N6 C14 C13 -66.8(6) . . . . ?
C10 C13 C14 N6 8.7(6) . . . . ?
N5 C1 C2 C3 1.4(6) . . . . ?
C1 C2 C3 C6 60.0(6) . . . . ?
C1 C2 C3 C4 -60.5(6) . . . . ?
C2 C3 C4 C5 59.3(6) . . . . ?
C6 C3 C4 C5 -60.8(6) . . . . ?
C2 C1 N5 C5 60.4(5) . . . . ?
C2 C1 N5 C7 -61.1(5) . . . . ?
C1 N5 C5 C4 -62.2(5) . . . . ?
C7 N5 C5 C4 59.5(5) . . . . ?
C3 C4 C5 N5 1.8(6) . . . . ?
C2 C3 C6 C7 -63.0(6) . . . . ?
C4 C3 C6 C7 57.3(6) . . . . ?
C3 C6 C7 N5 3.2(6) . . . . ?
C5 N5 C7 C6 -63.0(6) . . . . ?
C1 N5 C7 C6 58.7(6) . . . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
N5 H5 O3 0.98 2.01 2.963(6) 164.7 6_565
N6 H6 O1 0.98 2.00 2.941(5) 159.2 1_565
N6 H6 N1 0.98 2.43 3.374(5) 162.0 1_565
N6 H6 O2 0.98 2.30 3.043(5) 132.2 1_565
C8 H8A O2 0.97 2.57 3.364(6) 139.6 7_565
C12 H12A O10 0.97 2.51 3.424(6) 157.1 2_556
C14 H14A O12 0.97 2.61 3.569(7) 168.1 .
C14 H14B O5 0.97 2.49 3.386(7) 154.0 2_556
C1 H1B O9 0.97 2.56 3.465(6) 155.5 1_545
N5 H5 N1 0.98 2.45 3.406(6) 164.9 6_565
N5 H5 O2 0.98 2.32 3.101(5) 135.6 6_565
N5 H5 O3 0.98 2.01 2.963(6) 164.7 6_565
C5 H5A O10 0.97 2.66 3.566(6) 156.0 5_576
C6 H6A O12 0.97 2.57 3.506(7) 162.5 1_545
C6 H6B O4 0.97 2.65 3.580(7) 160.4 .
C7 H7A O6 0.97 2.59 3.391(6) 140.0 .
C7 H7B O6 0.97 2.42 3.361(6) 164.3 5_566
N6 H6 O1 0.98 2.00 2.941(5) 159.2 1_565
N6 H6 N1 0.98 2.43 3.374(5) 162.0 1_565
N6 H6 O2 0.98 2.30 3.043(5) 132.2 1_565
C8 H8A O2 0.97 2.57 3.364(6) 139.6 7_565
C12 H12A O10 0.97 2.51 3.424(6) 157.1 2_556
C14 H14A O12 0.97 2.61 3.569(7) 168.1 .
C14 H14B O5 0.97 2.49 3.386(7) 154.0 2_556
C1 H1B O9 0.97 2.56 3.465(6) 155.5 1_545
N5 H5 N1 0.98 2.45 3.406(6) 164.9 6_565
N5 H5 O2 0.98 2.32 3.101(5) 135.6 6_565
N5 H5 O3 0.98 2.01 2.963(6) 164.7 6_565
C6 H6A O12 0.97 2.57 3.506(7) 162.5 1_545
C6 H6B O4 0.97 2.65 3.580(7) 160.4 .
C7 H7A O6 0.97 2.59 3.391(6) 140.0 .
C7 H7B O6 0.97 2.42 3.361(6) 164.3 5_566

_refine_diff_density_max         0.528
_refine_diff_density_min         -0.386
_refine_diff_density_rms         0.076

_shelxl_version_number           2014-3



####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_20211126-LDF-351-273K
_database_code_depnum_ccdc_archive 'CCDC 2206263'
loop_
_audit_author_name
_audit_author_address
'yan sui'
;School of Chemistry and Chemical Engineering, Jinggangshan University
China
;
_audit_update_record             
;
2022-09-09 deposited with the CCDC.	2022-10-31 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'Eu K N8 O24, 4(C7 H14 N)'
_chemical_formula_sum            'C28 H56 Eu K N12 O24'
_chemical_formula_weight         1135.90

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
K K 0.2009 0.2494 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   9.7896(5)
_cell_length_b                   9.8968(5)
_cell_length_c                   12.6080(11)
_cell_angle_alpha                67.444(6)
_cell_angle_beta                 89.728(5)
_cell_angle_gamma                89.703(4)
_cell_volume                     1128.07(14)
_cell_formula_units_Z            1
_cell_measurement_temperature    273(2)
_cell_measurement_reflns_used    2493
_cell_measurement_theta_min      4.4500
_cell_measurement_theta_max      28.3310

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.672
_exptl_crystal_F_000             582
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.220
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.180
_exptl_absorpt_coefficient_mu    1.580
_shelx_estimated_absorpt_T_min   0.723
_shelx_estimated_absorpt_T_max   0.764
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.79973
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.40.53 (Rigaku Oxford Diffraction, 2019)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      273(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_measurement_device_type  'SuperNova, Single source at offset/far, EosS2'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            2762
_diffrn_reflns_av_unetI/netI     0.0299
_diffrn_reflns_av_R_equivalents  0.0106
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_theta_min         3.351
_diffrn_reflns_theta_max         23.998
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.651
_diffrn_measured_fraction_theta_full 0.565
_diffrn_reflns_Laue_measured_fraction_max 0.651
_diffrn_reflns_Laue_measured_fraction_full 0.565
_diffrn_reflns_point_group_measured_fraction_max 0.651
_diffrn_reflns_point_group_measured_fraction_full 0.565
_reflns_number_total             2307
_reflns_number_gt                2306
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'CrysAlisPro 1.171.40.53 (Rigaku OD, 2019)'
_computing_cell_refinement       'CrysAlisPro 1.171.40.53 (Rigaku OD, 2019)'
_computing_data_reduction        'CrysAlisPro 1.171.40.53 (Rigaku OD, 2019)'
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2014 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
;
 ?
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0324P)²+1.5031P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     SHELXL
_refine_ls_extinction_coef       0.0012(6)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         2307
_refine_ls_number_parameters     359
_refine_ls_number_restraints     18
_refine_ls_R_factor_all          0.0268
_refine_ls_R_factor_gt           0.0268
_refine_ls_wR_factor_ref         0.0660
_refine_ls_wR_factor_gt          0.0660
_refine_ls_goodness_of_fit_ref   1.057
_refine_ls_restrained_S_all      1.052
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.5000 0.5000 0.5000 0.02519(15) Uani 1 2 d S . P A .
K1 K 1.0000 0.0000 0.5000 0.0379(4) Uani 1 2 d S . P . .
O1 O 0.8857(6) 0.0831(5) 0.2693(5) 0.0884(17) Uani 1 1 d . . . . .
N1 N 0.9332(6) 0.2074(7) 0.2305(6) 0.0611(16) Uani 1 1 d . . . . .
O2 O 0.8672(7) 0.3073(6) 0.1534(5) 0.0927(17) Uani 1 1 d . . . . .
N2 N 0.7190(5) 0.2982(6) 0.4787(5) 0.0456(13) Uani 1 1 d . . . . .
O3 O 1.0365(5) 0.2375(6) 0.2719(5) 0.0917(18) Uani 1 1 d . . . . .
N3 N 0.2848(5) 0.2835(5) 0.5047(4) 0.0437(14) Uani 1 1 d . . . . .
O4 O 0.8085(5) 0.2166(5) 0.4700(5) 0.0841(17) Uani 1 1 d . . . . .
N4 N 0.5152(5) 0.3687(5) 0.7572(4) 0.0440(13) Uani 1 1 d . . . . .
O5 O 0.6779(5) 0.2927(5) 0.5744(4) 0.0519(16) Uani 0.835(7) 1 d . . P A 1
O6 O 0.6635(5) 0.3914(5) 0.3908(5) 0.0450(15) Uani 0.835(7) 1 d . . P A 1
O7 O 0.4108(4) 0.2578(4) 0.4986(4) 0.0430(15) Uani 0.830(7) 1 d . . P A 1
O8 O 0.1987(4) 0.1944(5) 0.5079(5) 0.0831(18) Uani 1 1 d . . . . .
O9 O 0.2546(4) 0.4043(5) 0.5103(4) 0.0454(15) Uani 0.830(7) 1 d . . P A 1
O10 O 0.4381(5) 0.3166(5) 0.7032(4) 0.0492(15) Uani 0.833(7) 1 d . . P A 1
O11 O 0.5187(6) 0.3188(5) 0.8626(3) 0.0795(16) Uani 1 1 d . . . . .
O12 O 0.5901(5) 0.4731(5) 0.6977(4) 0.0477(15) Uani 0.833(7) 1 d . . P A 1
N6 N 0.9895(6) 0.5571(6) 0.2094(5) 0.0682(17) Uani 1 1 d . . . . .
H6 H 0.9876 0.4595 0.2247 0.082 Uiso 1 1 d R U . . .
C8 C 0.8623(8) 0.6320(10) 0.1506(9) 0.100(3) Uani 1 1 d . . . . .
H8A H 0.8477 0.6126 0.0818 0.120 Uiso 1 1 calc R U . . .
H8B H 0.7843 0.5953 0.2011 0.120 Uiso 1 1 calc R U . . .
C9 C 0.8766(9) 0.7907(9) 0.1204(10) 0.119(4) Uani 1 1 d . . . . .
H9A H 0.8025 0.8252 0.1550 0.142 Uiso 1 1 calc R U . . .
H9B H 0.8707 0.8416 0.0377 0.142 Uiso 1 1 calc R U . . .
C10 C 1.0122(8) 0.8250(7) 0.1621(7) 0.077(2) Uani 1 1 d . . . . .
H10 H 1.0210 0.9302 0.1433 0.092 Uiso 1 1 calc R U . . .
C11 C 1.1198(9) 0.7730(9) 0.1065(8) 0.109(3) Uani 1 1 d . . . . .
H11A H 1.2082 0.7955 0.1300 0.131 Uiso 1 1 calc R U . . .
H11B H 1.1129 0.8240 0.0239 0.131 Uiso 1 1 calc R U . . .
C12 C 1.1105(7) 0.6132(8) 0.1359(7) 0.082(3) Uani 1 1 d . . . . .
H12A H 1.1026 0.5938 0.0664 0.099 Uiso 1 1 calc R U . . .
H12B H 1.1923 0.5649 0.1762 0.099 Uiso 1 1 calc R U . . .
C13 C 0.9967(12) 0.5841(9) 0.3123(6) 0.118(4) Uani 1 1 d . . . . .
H13A H 1.0732 0.5307 0.3581 0.142 Uiso 1 1 calc R U . . .
H13B H 0.9138 0.5497 0.3568 0.142 Uiso 1 1 calc R U . . .
C14 C 1.0136(12) 0.7444(10) 0.2852(8) 0.116(4) Uani 1 1 d . . . . .
H14A H 0.9400 0.7787 0.3204 0.139 Uiso 1 1 calc R U . . .
H14B H 1.0993 0.7609 0.3165 0.139 Uiso 1 1 calc R U . . .
C1 C 0.5692(7) 0.0654(7) 0.1427(6) 0.070(2) Uani 1 1 d . . . . .
H1A H 0.6057 -0.0317 0.1850 0.084 Uiso 1 1 calc R U . . .
H1B H 0.6158 0.1061 0.0692 0.084 Uiso 1 1 calc R U . . .
C2 C 0.4193(7) 0.0568(7) 0.1246(6) 0.066(2) Uani 1 1 d . . . . .
H2A H 0.4001 0.0952 0.0429 0.080 Uiso 1 1 calc R U . . .
H2B H 0.3906 -0.0447 0.1569 0.080 Uiso 1 1 calc R U . . .
C3 C 0.3412(7) 0.1413(7) 0.1793(6) 0.067(2) Uani 1 1 d . . . . .
H3 H 0.2429 0.1346 0.1680 0.080 Uiso 1 1 calc R U . . .
C4 C 0.3871(8) 0.2982(7) 0.1293(7) 0.082(2) Uani 1 1 d . . . . .
H4A H 0.3644 0.3408 0.0483 0.098 Uiso 1 1 calc R U . . .
H4B H 0.3392 0.3533 0.1672 0.098 Uiso 1 1 calc R U . . .
N5 N 0.5915(5) 0.1596(5) 0.2080(5) 0.0613(15) Uani 1 1 d . . . . .
H5 H 0.6831 0.1636 0.2185 0.074 Uiso 1 1 d R U . . .
C5 C 0.5367(9) 0.3091(7) 0.1433(7) 0.080(2) Uani 1 1 d . . . . .
H5A H 0.5549 0.3716 0.1849 0.097 Uiso 1 1 calc R U . . .
H5B H 0.5805 0.3512 0.0687 0.097 Uiso 1 1 calc R U . . .
C6 C 0.5227(10) 0.0988(9) 0.3217(6) 0.090(3) Uani 1 1 d . . . . .
H6A H 0.5634 0.0053 0.3680 0.108 Uiso 1 1 calc R U . . .
H6B H 0.5349 0.1647 0.3614 0.108 Uiso 1 1 calc R U . . .
C7 C 0.3757(10) 0.0796(9) 0.3069(7) 0.094(3) Uani 1 1 d . . . . .
H7A H 0.3227 0.1301 0.3457 0.113 Uiso 1 1 calc R U . . .
H7B H 0.3529 -0.0235 0.3407 0.113 Uiso 1 1 calc R U . . .
O5A O 0.7467(18) 0.420(2) 0.4842(16) 0.029(5) Uani 0.165(7) 1 d . U P A 2
O6A O 0.598(2) 0.262(2) 0.492(2) 0.044(8) Uani 0.165(7) 1 d . . P A 2
O7A O 0.326(2) 0.378(2) 0.4101(19) 0.039(7) Uani 0.170(7) 1 d . U P A 2
O9A O 0.341(2) 0.281(2) 0.5957(17) 0.035(6) Uani 0.170(7) 1 d . . P A 2
O12A O 0.432(2) 0.475(2) 0.7028(16) 0.033(6) Uani 0.167(7) 1 d . . P A 2
O10A O 0.586(2) 0.325(2) 0.6927(17) 0.039(7) Uani 0.167(7) 1 d . U P A 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O10A 2.53(2) 2_666 ?
Eu1 O10A 2.53(2) . ?
Eu1 O12A 2.557(16) 2_666 ?
Eu1 O12A 2.557(16) . ?
Eu1 O7 2.562(4) 2_666 ?
Eu1 O7 2.562(4) . ?
Eu1 O9A 2.562(17) 2_666 ?
Eu1 O9A 2.562(17) . ?
Eu1 O12 2.564(5) 2_666 ?
Eu1 O12 2.564(5) . ?
Eu1 O9 2.571(4) 2_666 ?
Eu1 O9 2.571(4) . ?
Eu1 O5A 2.568(18) . ?
Eu1 O5A 2.568(18) 2_666 ?
Eu1 O5 2.573(5) 2_666 ?
Eu1 O5 2.573(5) . ?
Eu1 O10 2.579(4) . ?
Eu1 O10 2.579(4) 2_666 ?
Eu1 O6A 2.579(18) 2_666 ?
Eu1 O6A 2.579(18) . ?
Eu1 O6 2.590(4) 2_666 ?
Eu1 O6 2.590(4) . ?
Eu1 O7A 2.596(19) 2_666 ?
Eu1 O7A 2.596(19) . ?
K1 O4 2.756(4) 2_756 ?
K1 O4 2.756(4) . ?
K1 O8 2.771(4) 2_656 ?
K1 O8 2.771(4) 1_655 ?
K1 O1 2.928(5) . ?
K1 O1 2.928(5) 2_756 ?
K1 O3 2.955(6) . ?
K1 O3 2.955(6) 2_756 ?
K1 N1 3.293(7) . ?
K1 N1 3.293(7) 2_756 ?
O1 N1 1.229(6) . ?
N1 O3 1.230(7) . ?
N1 O2 1.265(8) . ?
N2 O4 1.220(6) . ?
N2 O6A 1.23(2) . ?
N2 O5 1.252(6) . ?
N2 O6 1.261(7) . ?
N2 O5A 1.264(17) . ?
N3 O8 1.213(5) . ?
N3 O9 1.258(6) . ?
N3 O7 1.265(6) . ?
N3 O7A 1.27(2) . ?
N3 O9A 1.27(2) . ?
N4 O11 1.228(6) . ?
N4 O12 1.255(6) . ?
N4 O10 1.257(6) . ?
N4 O10A 1.263(17) . ?
N4 O12A 1.30(2) . ?
O8 K1 2.771(4) 1_455 ?
N6 C13 1.424(9) . ?
N6 C12 1.474(7) . ?
N6 C8 1.492(10) . ?
N6 H6 0.9100 . ?
C8 C9 1.475(11) . ?
C8 H8A 0.9700 . ?
C8 H8B 0.9700 . ?
C9 C10 1.517(12) . ?
C9 H9A 0.9700 . ?
C9 H9B 0.9700 . ?
C10 C14 1.448(11) . ?
C10 C11 1.460(9) . ?
C10 H10 0.9800 . ?
C11 C12 1.482(10) . ?
C11 H11A 0.9700 . ?
C11 H11B 0.9700 . ?
C12 H12A 0.9700 . ?
C12 H12B 0.9700 . ?
C13 C14 1.498(11) . ?
C13 H13A 0.9700 . ?
C13 H13B 0.9700 . ?
C14 H14A 0.9700 . ?
C14 H14B 0.9700 . ?
C1 N5 1.479(7) . ?
C1 C2 1.494(9) . ?
C1 H1A 0.9700 . ?
C1 H1B 0.9700 . ?
C2 C3 1.480(8) . ?
C2 H2A 0.9700 . ?
C2 H2B 0.9700 . ?
C3 C4 1.505(9) . ?
C3 C7 1.524(11) . ?
C3 H3 0.9800 . ?
C4 C5 1.485(11) . ?
C4 H4A 0.9700 . ?
C4 H4B 0.9700 . ?
N5 C6 1.484(8) . ?
N5 C5 1.487(9) . ?
N5 H5 0.9100 . ?
C5 H5A 0.9700 . ?
C5 H5B 0.9700 . ?
C6 C7 1.474(12) . ?
C6 H6A 0.9700 . ?
C6 H6B 0.9700 . ?
C7 H7A 0.9700 . ?
C7 H7B 0.9700 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O10A Eu1 O10A 180.0 2_666 . ?
O10A Eu1 O12A 50.0(6) 2_666 2_666 ?
O10A Eu1 O12A 130.0(6) . 2_666 ?
O10A Eu1 O12A 130.0(6) 2_666 . ?
O10A Eu1 O12A 50.0(6) . . ?
O12A Eu1 O12A 180.0 2_666 . ?
O7 Eu1 O7 180.0 2_666 . ?
O10A Eu1 O9A 66.9(7) 2_666 2_666 ?
O10A Eu1 O9A 113.1(7) . 2_666 ?
O12A Eu1 O9A 68.5(6) 2_666 2_666 ?
O12A Eu1 O9A 111.5(6) . 2_666 ?
O10A Eu1 O9A 113.1(7) 2_666 . ?
O10A Eu1 O9A 66.9(7) . . ?
O12A Eu1 O9A 111.5(6) 2_666 . ?
O12A Eu1 O9A 68.5(6) . . ?
O9A Eu1 O9A 180.0 2_666 . ?
O7 Eu1 O12 112.24(16) 2_666 2_666 ?
O7 Eu1 O12 67.76(16) . 2_666 ?
O7 Eu1 O12 67.76(16) 2_666 . ?
O7 Eu1 O12 112.24(16) . . ?
O12 Eu1 O12 180.0 2_666 . ?
O7 Eu1 O9 49.38(13) 2_666 2_666 ?
O7 Eu1 O9 130.62(13) . 2_666 ?
O12 Eu1 O9 112.20(15) 2_666 2_666 ?
O12 Eu1 O9 67.80(15) . 2_666 ?
O7 Eu1 O9 130.62(13) 2_666 . ?
O7 Eu1 O9 49.38(13) . . ?
O12 Eu1 O9 67.80(15) 2_666 . ?
O12 Eu1 O9 112.20(15) . . ?
O9 Eu1 O9 180.0 2_666 . ?
O10A Eu1 O5A 111.0(6) 2_666 . ?
O10A Eu1 O5A 69.0(6) . . ?
O12A Eu1 O5A 66.3(6) 2_666 . ?
O12A Eu1 O5A 113.7(6) . . ?
O9A Eu1 O5A 67.9(6) 2_666 . ?
O9A Eu1 O5A 112.1(6) . . ?
O10A Eu1 O5A 69.0(6) 2_666 2_666 ?
O10A Eu1 O5A 111.0(6) . 2_666 ?
O12A Eu1 O5A 113.7(6) 2_666 2_666 ?
O12A Eu1 O5A 66.3(6) . 2_666 ?
O9A Eu1 O5A 112.1(6) 2_666 2_666 ?
O9A Eu1 O5A 67.9(6) . 2_666 ?
O5A Eu1 O5A 180.0 . 2_666 ?
O7 Eu1 O5 67.58(15) 2_666 2_666 ?
O7 Eu1 O5 112.42(15) . 2_666 ?
O12 Eu1 O5 68.90(15) 2_666 2_666 ?
O12 Eu1 O5 111.10(15) . 2_666 ?
O9 Eu1 O5 112.70(14) 2_666 2_666 ?
O9 Eu1 O5 67.30(14) . 2_666 ?
O7 Eu1 O5 112.42(15) 2_666 . ?
O7 Eu1 O5 67.57(15) . . ?
O12 Eu1 O5 111.10(15) 2_666 . ?
O12 Eu1 O5 68.90(15) . . ?
O9 Eu1 O5 67.31(14) 2_666 . ?
O9 Eu1 O5 112.70(14) . . ?
O5 Eu1 O5 180.0 2_666 . ?
O7 Eu1 O10 112.23(14) 2_666 . ?
O7 Eu1 O10 67.77(14) . . ?
O12 Eu1 O10 130.93(15) 2_666 . ?
O12 Eu1 O10 49.07(15) . . ?
O9 Eu1 O10 111.99(17) 2_666 . ?
O9 Eu1 O10 68.01(17) . . ?
O5 Eu1 O10 111.30(14) 2_666 . ?
O5 Eu1 O10 68.70(14) . . ?
O7 Eu1 O10 67.77(14) 2_666 2_666 ?
O7 Eu1 O10 112.23(14) . 2_666 ?
O12 Eu1 O10 49.07(15) 2_666 2_666 ?
O12 Eu1 O10 130.93(15) . 2_666 ?
O9 Eu1 O10 68.01(17) 2_666 2_666 ?
O9 Eu1 O10 111.99(17) . 2_666 ?
O5 Eu1 O10 68.70(14) 2_666 2_666 ?
O5 Eu1 O10 111.30(14) . 2_666 ?
O10 Eu1 O10 180.0 . 2_666 ?
O10A Eu1 O6A 67.2(7) 2_666 2_666 ?
O10A Eu1 O6A 112.8(7) . 2_666 ?
O12A Eu1 O6A 113.1(7) 2_666 2_666 ?
O12A Eu1 O6A 66.9(7) . 2_666 ?
O9A Eu1 O6A 67.8(6) 2_666 2_666 ?
O9A Eu1 O6A 112.2(6) . 2_666 ?
O5A Eu1 O6A 131.5(6) . 2_666 ?
O5A Eu1 O6A 48.5(6) 2_666 2_666 ?
O10A Eu1 O6A 112.8(7) 2_666 . ?
O10A Eu1 O6A 67.2(7) . . ?
O12A Eu1 O6A 66.9(7) 2_666 . ?
O12A Eu1 O6A 113.1(7) . . ?
O9A Eu1 O6A 112.2(6) 2_666 . ?
O9A Eu1 O6A 67.8(6) . . ?
O5A Eu1 O6A 48.5(6) . . ?
O5A Eu1 O6A 131.5(6) 2_666 . ?
O6A Eu1 O6A 180.0 2_666 . ?
O7 Eu1 O6 68.20(12) 2_666 2_666 ?
O7 Eu1 O6 111.80(12) . 2_666 ?
O12 Eu1 O6 113.19(16) 2_666 2_666 ?
O12 Eu1 O6 66.81(16) . 2_666 ?
O9 Eu1 O6 112.39(12) 2_666 2_666 ?
O9 Eu1 O6 67.61(12) . 2_666 ?
O5 Eu1 O6 49.07(17) 2_666 2_666 ?
O5 Eu1 O6 130.93(17) . 2_666 ?
O10 Eu1 O6 66.81(16) . 2_666 ?
O10 Eu1 O6 113.19(16) 2_666 2_666 ?
O7 Eu1 O6 111.80(12) 2_666 . ?
O7 Eu1 O6 68.20(12) . . ?
O12 Eu1 O6 66.81(16) 2_666 . ?
O12 Eu1 O6 113.19(16) . . ?
O9 Eu1 O6 67.61(12) 2_666 . ?
O9 Eu1 O6 112.39(12) . . ?
O5 Eu1 O6 130.93(17) 2_666 . ?
O5 Eu1 O6 49.07(17) . . ?
O10 Eu1 O6 113.19(16) . . ?
O10 Eu1 O6 66.81(16) 2_666 . ?
O6 Eu1 O6 180.00(16) 2_666 . ?
O10A Eu1 O7A 112.3(7) 2_666 2_666 ?
O10A Eu1 O7A 67.7(7) . 2_666 ?
O12A Eu1 O7A 112.6(6) 2_666 2_666 ?
O12A Eu1 O7A 67.4(6) . 2_666 ?
O9A Eu1 O7A 49.7(7) 2_666 2_666 ?
O9A Eu1 O7A 130.3(7) . 2_666 ?
O5A Eu1 O7A 67.7(6) . 2_666 ?
O5A Eu1 O7A 112.3(6) 2_666 2_666 ?
O6A Eu1 O7A 69.1(7) 2_666 2_666 ?
O6A Eu1 O7A 110.9(7) . 2_666 ?
O10A Eu1 O7A 67.7(7) 2_666 . ?
O10A Eu1 O7A 112.3(7) . . ?
O12A Eu1 O7A 67.4(6) 2_666 . ?
O12A Eu1 O7A 112.6(6) . . ?
O9A Eu1 O7A 130.3(7) 2_666 . ?
O9A Eu1 O7A 49.7(7) . . ?
O5A Eu1 O7A 112.3(6) . . ?
O5A Eu1 O7A 67.7(6) 2_666 . ?
O6A Eu1 O7A 110.9(7) 2_666 . ?
O6A Eu1 O7A 69.1(7) . . ?
O7A Eu1 O7A 180.0 2_666 . ?
O4 K1 O4 180.00(14) 2_756 . ?
O4 K1 O8 88.18(15) 2_756 2_656 ?
O4 K1 O8 91.82(15) . 2_656 ?
O4 K1 O8 91.82(15) 2_756 1_655 ?
O4 K1 O8 88.18(15) . 1_655 ?
O8 K1 O8 180.00(15) 2_656 1_655 ?
O4 K1 O1 107.73(15) 2_756 . ?
O4 K1 O1 72.27(15) . . ?
O8 K1 O1 68.09(16) 2_656 . ?
O8 K1 O1 111.91(16) 1_655 . ?
O4 K1 O1 72.27(15) 2_756 2_756 ?
O4 K1 O1 107.73(15) . 2_756 ?
O8 K1 O1 111.91(16) 2_656 2_756 ?
O8 K1 O1 68.09(16) 1_655 2_756 ?
O1 K1 O1 180.0 . 2_756 ?
O4 K1 O3 109.78(15) 2_756 . ?
O4 K1 O3 70.22(15) . . ?
O8 K1 O3 110.73(16) 2_656 . ?
O8 K1 O3 69.27(16) 1_655 . ?
O1 K1 O3 42.65(15) . . ?
O1 K1 O3 137.35(15) 2_756 . ?
O4 K1 O3 70.22(15) 2_756 2_756 ?
O4 K1 O3 109.78(15) . 2_756 ?
O8 K1 O3 69.27(16) 2_656 2_756 ?
O8 K1 O3 110.73(16) 1_655 2_756 ?
O1 K1 O3 137.35(15) . 2_756 ?
O1 K1 O3 42.65(15) 2_756 2_756 ?
O3 K1 O3 180.00(19) . 2_756 ?
O4 K1 N1 114.91(14) 2_756 . ?
O4 K1 N1 65.09(14) . . ?
O8 K1 N1 89.32(16) 2_656 . ?
O8 K1 N1 90.68(16) 1_655 . ?
O1 K1 N1 21.78(12) . . ?
O1 K1 N1 158.22(12) 2_756 . ?
O3 K1 N1 21.85(13) . . ?
O3 K1 N1 158.15(13) 2_756 . ?
O4 K1 N1 65.09(14) 2_756 2_756 ?
O4 K1 N1 114.91(14) . 2_756 ?
O8 K1 N1 90.68(16) 2_656 2_756 ?
O8 K1 N1 89.32(16) 1_655 2_756 ?
O1 K1 N1 158.22(12) . 2_756 ?
O1 K1 N1 21.78(12) 2_756 2_756 ?
O3 K1 N1 158.15(13) . 2_756 ?
O3 K1 N1 21.85(13) 2_756 2_756 ?
N1 K1 N1 180.0 . 2_756 ?
N1 O1 K1 96.1(4) . . ?
O1 N1 O3 120.9(8) . . ?
O1 N1 O2 118.6(7) . . ?
O3 N1 O2 120.2(7) . . ?
O1 N1 K1 62.2(4) . . ?
O3 N1 K1 63.4(4) . . ?
O2 N1 K1 152.7(4) . . ?
O4 N2 O6A 122.0(10) . . ?
O4 N2 O5 121.8(7) . . ?
O4 N2 O6 121.0(5) . . ?
O5 N2 O6 117.2(4) . . ?
O4 N2 O5A 121.7(9) . . ?
O6A N2 O5A 116.0(12) . . ?
O4 N2 Eu1 179.7(4) . . ?
O6A N2 Eu1 58.3(9) . . ?
O5 N2 Eu1 58.2(3) . . ?
O6 N2 Eu1 59.0(2) . . ?
O5A N2 Eu1 58.0(8) . . ?
N1 O3 K1 94.7(4) . . ?
O8 N3 O9 122.1(5) . . ?
O8 N3 O7 121.5(4) . . ?
O9 N3 O7 116.4(4) . . ?
O8 N3 O7A 121.2(10) . . ?
O8 N3 O9A 121.1(9) . . ?
O7A N3 O9A 117.6(12) . . ?
O8 N3 Eu1 179.1(5) . . ?
O9 N3 Eu1 58.4(3) . . ?
O7 N3 Eu1 58.0(2) . . ?
O7A N3 Eu1 59.6(9) . . ?
O9A N3 Eu1 58.1(8) . . ?
N2 O4 K1 167.7(5) . . ?
O11 N4 O12 121.7(5) . . ?
O11 N4 O10 121.8(5) . . ?
O12 N4 O10 116.5(5) . . ?
O11 N4 O10A 125.8(12) . . ?
O11 N4 O12A 120.0(8) . . ?
O10A N4 O12A 114.2(13) . . ?
O11 N4 Eu1 177.8(4) . . ?
O12 N4 Eu1 57.9(3) . . ?
O10 N4 Eu1 58.7(3) . . ?
O10A N4 Eu1 56.3(11) . . ?
O12A N4 Eu1 57.9(7) . . ?
N2 O5 Eu1 97.4(4) . . ?
N2 O6 Eu1 96.3(3) . . ?
N3 O7 Eu1 97.2(3) . . ?
N3 O8 K1 176.3(5) . 1_455 ?
N3 O9 Eu1 97.0(3) . . ?
N4 O10 Eu1 96.7(3) . . ?
N4 O12 Eu1 97.6(3) . . ?
C13 N6 C12 111.8(6) . . ?
C13 N6 C8 105.5(7) . . ?
C12 N6 C8 111.3(6) . . ?
C13 N6 H6 111.3 . . ?
C12 N6 H6 105.5 . . ?
C8 N6 H6 111.7 . . ?
C9 C8 N6 108.8(6) . . ?
C9 C8 H8A 109.9 . . ?
N6 C8 H8A 109.9 . . ?
C9 C8 H8B 109.9 . . ?
N6 C8 H8B 109.9 . . ?
H8A C8 H8B 108.3 . . ?
C8 C9 C10 110.8(8) . . ?
C8 C9 H9A 109.5 . . ?
C10 C9 H9A 109.5 . . ?
C8 C9 H9B 109.5 . . ?
C10 C9 H9B 109.5 . . ?
H9A C9 H9B 108.1 . . ?
C14 C10 C11 110.9(9) . . ?
C14 C10 C9 106.1(8) . . ?
C11 C10 C9 107.3(7) . . ?
C14 C10 H10 110.8 . . ?
C11 C10 H10 110.8 . . ?
C9 C10 H10 110.8 . . ?
C10 C11 C12 111.8(5) . . ?
C10 C11 H11A 109.3 . . ?
C12 C11 H11A 109.3 . . ?
C10 C11 H11B 109.3 . . ?
C12 C11 H11B 109.3 . . ?
H11A C11 H11B 107.9 . . ?
N6 C12 C11 108.6(5) . . ?
N6 C12 H12A 110.0 . . ?
C11 C12 H12A 110.0 . . ?
N6 C12 H12B 110.0 . . ?
C11 C12 H12B 110.0 . . ?
H12A C12 H12B 108.4 . . ?
N6 C13 C14 110.5(6) . . ?
N6 C13 H13A 109.5 . . ?
C14 C13 H13A 109.5 . . ?
N6 C13 H13B 109.5 . . ?
C14 C13 H13B 109.5 . . ?
H13A C13 H13B 108.1 . . ?
C10 C14 C13 110.1(6) . . ?
C10 C14 H14A 109.6 . . ?
C13 C14 H14A 109.6 . . ?
C10 C14 H14B 109.6 . . ?
C13 C14 H14B 109.7 . . ?
H14A C14 H14B 108.2 . . ?
N5 C1 C2 108.8(4) . . ?
N5 C1 H1A 109.9 . . ?
C2 C1 H1A 109.9 . . ?
N5 C1 H1B 109.9 . . ?
C2 C1 H1B 109.9 . . ?
H1A C1 H1B 108.3 . . ?
C3 C2 C1 110.8(5) . . ?
C3 C2 H2A 109.5 . . ?
C1 C2 H2A 109.5 . . ?
C3 C2 H2B 109.5 . . ?
C1 C2 H2B 109.5 . . ?
H2A C2 H2B 108.1 . . ?
C2 C3 C4 109.1(5) . . ?
C2 C3 C7 108.0(7) . . ?
C4 C3 C7 107.8(6) . . ?
C2 C3 H3 110.6 . . ?
C4 C3 H3 110.6 . . ?
C7 C3 H3 110.6 . . ?
C5 C4 C3 111.0(6) . . ?
C5 C4 H4A 109.4 . . ?
C3 C4 H4A 109.4 . . ?
C5 C4 H4B 109.4 . . ?
C3 C4 H4B 109.4 . . ?
H4A C4 H4B 108.0 . . ?
C1 N5 C6 111.1(5) . . ?
C1 N5 C5 110.3(6) . . ?
C6 N5 C5 108.5(5) . . ?
C1 N5 H5 107.7 . . ?
C6 N5 H5 109.2 . . ?
C5 N5 H5 110.1 . . ?
C4 C5 N5 108.5(5) . . ?
C4 C5 H5A 110.0 . . ?
N5 C5 H5A 110.0 . . ?
C4 C5 H5B 110.0 . . ?
N5 C5 H5B 110.0 . . ?
H5A C5 H5B 108.4 . . ?
C7 C6 N5 110.1(7) . . ?
C7 C6 H6A 109.6 . . ?
N5 C6 H6A 109.6 . . ?
C7 C6 H6B 109.6 . . ?
N5 C6 H6B 109.6 . . ?
H6A C6 H6B 108.2 . . ?
C6 C7 C3 109.5(6) . . ?
C6 C7 H7A 109.8 . . ?
C3 C7 H7A 109.8 . . ?
C6 C7 H7B 109.8 . . ?
C3 C7 H7B 109.8 . . ?
H7A C7 H7B 108.2 . . ?
N2 O5A Eu1 97.3(10) . . ?
N2 O6A Eu1 97.8(10) . . ?
N3 O7A Eu1 95.6(11) . . ?
N3 O9A Eu1 97.1(10) . . ?
N4 O12A Eu1 96.7(8) . . ?
N4 O10A Eu1 99.1(13) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
K1 O1 N1 O3 24.9(6) . . . . ?
K1 O1 N1 O2 -149.0(4) . . . . ?
O1 N1 O3 K1 -24.6(6) . . . . ?
O2 N1 O3 K1 149.2(5) . . . . ?
O6A N2 O4 K1 -71(3) . . . . ?
O5 N2 O4 K1 14(2) . . . . ?
O6 N2 O4 K1 -166.1(17) . . . . ?
O5A N2 O4 K1 102(2) . . . . ?
O4 N2 O5 Eu1 179.7(5) . . . . ?
O6A N2 O5 Eu1 -64.4(11) . . . . ?
O6 N2 O5 Eu1 -0.7(5) . . . . ?
O5A N2 O5 Eu1 62.5(10) . . . . ?
O4 N2 O6 Eu1 -179.7(5) . . . . ?
O6A N2 O6 Eu1 60.3(9) . . . . ?
O5 N2 O6 Eu1 0.7(5) . . . . ?
O5A N2 O6 Eu1 -61.0(8) . . . . ?
O8 N3 O7 Eu1 -179.1(5) . . . . ?
O9 N3 O7 Eu1 -1.0(6) . . . . ?
O7A N3 O7 Eu1 63.5(9) . . . . ?
O9A N3 O7 Eu1 -63.0(9) . . . . ?
O8 N3 O9 Eu1 179.1(5) . . . . ?
O7 N3 O9 Eu1 1.0(6) . . . . ?
O7A N3 O9 Eu1 -63.0(10) . . . . ?
O9A N3 O9 Eu1 61.5(8) . . . . ?
O11 N4 O10 Eu1 177.5(5) . . . . ?
O12 N4 O10 Eu1 -3.6(5) . . . . ?
O10A N4 O10 Eu1 -61.7(10) . . . . ?
O12A N4 O10 Eu1 60.8(8) . . . . ?
O11 N4 O12 Eu1 -177.5(5) . . . . ?
O10 N4 O12 Eu1 3.6(5) . . . . ?
O10A N4 O12 Eu1 60.7(12) . . . . ?
O12A N4 O12 Eu1 -61.4(8) . . . . ?
C13 N6 C8 C9 63.3(9) . . . . ?
C12 N6 C8 C9 -58.1(9) . . . . ?
N6 C8 C9 C10 -1.9(11) . . . . ?
C8 C9 C10 C14 -58.6(10) . . . . ?
C8 C9 C10 C11 60.0(11) . . . . ?
C14 C10 C11 C12 55.1(11) . . . . ?
C9 C10 C11 C12 -60.3(11) . . . . ?
C13 N6 C12 C11 -59.3(9) . . . . ?
C8 N6 C12 C11 58.3(9) . . . . ?
C10 C11 C12 N6 2.6(11) . . . . ?
C12 N6 C13 C14 56.8(11) . . . . ?
C8 N6 C13 C14 -64.3(10) . . . . ?
C11 C10 C14 C13 -57.8(11) . . . . ?
C9 C10 C14 C13 58.3(10) . . . . ?
N6 C13 C14 C10 2.3(13) . . . . ?
N5 C1 C2 C3 -1.3(8) . . . . ?
C1 C2 C3 C4 58.7(9) . . . . ?
C1 C2 C3 C7 -58.2(8) . . . . ?
C2 C3 C4 C5 -56.6(9) . . . . ?
C7 C3 C4 C5 60.4(8) . . . . ?
C2 C1 N5 C6 60.3(8) . . . . ?
C2 C1 N5 C5 -60.0(7) . . . . ?
C3 C4 C5 N5 -2.6(9) . . . . ?
C1 N5 C5 C4 62.0(7) . . . . ?
C6 N5 C5 C4 -59.8(8) . . . . ?
C1 N5 C6 C7 -56.5(9) . . . . ?
C5 N5 C6 C7 64.8(8) . . . . ?
N5 C6 C7 C3 -5.0(10) . . . . ?
C2 C3 C7 C6 62.1(8) . . . . ?
C4 C3 C7 C6 -55.7(9) . . . . ?
O4 N2 O5A Eu1 180.0(6) . . . . ?
O6A N2 O5A Eu1 -6.0(17) . . . . ?
O5 N2 O5A Eu1 -62.7(5) . . . . ?
O6 N2 O5A Eu1 62.2(6) . . . . ?
O4 N2 O6A Eu1 180.0(6) . . . . ?
O5 N2 O6A Eu1 64.2(6) . . . . ?
O6 N2 O6A Eu1 -61.0(7) . . . . ?
O5A N2 O6A Eu1 6.0(17) . . . . ?
O8 N3 O7A Eu1 -179.4(4) . . . . ?
O9 N3 O7A Eu1 61.6(5) . . . . ?
O7 N3 O7A Eu1 -61.7(6) . . . . ?
O9A N3 O7A Eu1 -2.2(15) . . . . ?
O8 N3 O9A Eu1 179.4(4) . . . . ?
O9 N3 O9A Eu1 -61.9(6) . . . . ?
O7 N3 O9A Eu1 63.0(6) . . . . ?
O7A N3 O9A Eu1 2.2(15) . . . . ?
O11 N4 O12A Eu1 179.6(5) . . . . ?
O12 N4 O12A Eu1 61.5(5) . . . . ?
O10 N4 O12A Eu1 -61.7(5) . . . . ?
O10A N4 O12A Eu1 -1.0(14) . . . . ?
O11 N4 O10A Eu1 -179.6(5) . . . . ?
O12 N4 O10A Eu1 -62.6(6) . . . . ?
O10 N4 O10A Eu1 64.7(7) . . . . ?
O12A N4 O10A Eu1 1.0(15) . . . . ?

_refine_diff_density_max         0.386
_refine_diff_density_min         -0.339
_refine_diff_density_rms         0.058

_shelxl_version_number           2014-3



####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_20211126-LDF-351-313K
_database_code_depnum_ccdc_archive 'CCDC 2206264'
loop_
_audit_author_name
_audit_author_address
'yan sui'
;School of Chemistry and Chemical Engineering, Jinggangshan University
China
;
_audit_update_record             
;
2022-10-11 deposited with the CCDC.	2022-10-31 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C28 H56 Eu K N12 O24'
_chemical_formula_sum            'C28 H56 Eu K N12 O24'
_chemical_formula_weight         1135.90

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
K K 0.2009 0.2494 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      orthorhombic
_space_group_IT_number           51
_space_group_name_H-M_alt        'P m m a'
_space_group_name_Hall           '-P 2a 2a'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z'
'-x, y, -z'
'x+1/2, -y, -z'
'-x, -y, -z'
'x-1/2, y, -z'
'x, -y, z'
'-x-1/2, y, z'

_cell_length_a                   23.6915(11)
_cell_length_b                   9.7624(3)
_cell_length_c                   9.9066(4)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     2291.26(16)
_cell_formula_units_Z            2
_cell_measurement_temperature    313(2)
_cell_measurement_reflns_used    2605
_cell_measurement_theta_min      3.9960
_cell_measurement_theta_max      27.2630

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.646
_exptl_crystal_F_000             1164
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.200
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.180
_exptl_absorpt_coefficient_mu    1.556
_shelx_estimated_absorpt_T_min   0.746
_shelx_estimated_absorpt_T_max   0.767
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.88984
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.40.53 (Rigaku Oxford Diffraction, 2019)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      313(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_measurement_device_type  'SuperNova, Single source at offset/far, EosS2'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            6011
_diffrn_reflns_av_unetI/netI     0.0302
_diffrn_reflns_av_R_equivalents  0.0227
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_h_max       28
_diffrn_reflns_limit_k_min       -8
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_l_min       -11
_diffrn_reflns_limit_l_max       11
_diffrn_reflns_theta_min         3.299
_diffrn_reflns_theta_max         25.027
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measured_fraction_theta_full 0.978
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_Laue_measured_fraction_full 0.978
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_point_group_measured_fraction_full 0.978
_reflns_number_total             2215
_reflns_number_gt                1852
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'CrysAlisPro 1.171.40.53 (Rigaku OD, 2019)'
_computing_cell_refinement       'CrysAlisPro 1.171.40.53 (Rigaku OD, 2019)'
_computing_data_reduction        'CrysAlisPro 1.171.40.53 (Rigaku OD, 2019)'
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2014 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
;
 ?
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0851P)²+6.5522P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   .
_refine_ls_hydrogen_treatment    undef
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         2215
_refine_ls_number_parameters     211
_refine_ls_number_restraints     40
_refine_ls_R_factor_all          0.0654
_refine_ls_R_factor_gt           0.0549
_refine_ls_wR_factor_ref         0.1523
_refine_ls_wR_factor_gt          0.1426
_refine_ls_goodness_of_fit_ref   1.057
_refine_ls_restrained_S_all      1.072
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.0718(6) 0.0764(12) 0.8696(11) 0.129(4) Uani 1 1 d D . . . .
C2 C 0.1566(9) 0.063(2) 0.7383(12) 0.183(8) Uani 1 1 d . U . . .
C3 C 0.0688(6) 0.0743(15) 0.6214(11) 0.163(7) Uani 1 1 d D . . . .
C4 C 0.0744(5) 0.3736(10) 0.3091(11) 0.106(3) Uani 1 1 d . . . . .
C5 C 0.0602(6) 0.3717(11) 0.1598(12) 0.129(5) Uani 1 1 d . . . . .
C6 C 0.0799(7) 0.5000 0.0909(12) 0.102(5) Uani 1 2 d S T P . .
C7 C 0.1413(9) 0.5000 0.1042(19) 0.134(6) Uani 1 2 d S TU P . .
C8 C 0.1566(7) 0.5000 0.2537(15) 0.137(9) Uani 1 2 d S T P . .
Eu1 Eu 0.2500 0.0000 0.24342(4) 0.0323(2) Uani 1 4 d S T P A .
K1 K 0.2500 0.5000 0.7426(2) 0.0431(6) Uani 1 4 d S T P . .
N1 N 0.3947(10) 0.408(2) 0.663(2) 0.209(12) Uani 0.5 1 d D U P . .
N2 N 0.2500 0.2171(9) 0.4585(8) 0.062(2) Uani 1 2 d S T P . .
N3 N 0.1242(3) 0.0000 0.2436(7) 0.051(2) Uani 1 2 d S T P . .
N4 N 0.2500 -0.2162(9) 0.0281(8) 0.055(2) Uani 1 2 d S T P . .
N5 N 0.1060(5) 0.5000 0.3391(10) 0.087(3) Uani 1 2 d S T P . .
N6 N 0.0992(8) 0.1279(19) 0.7456(10) 0.177(6) Uani 1 1 d D U . . .
O1 O 0.3675(8) 0.419(2) 0.7756(19) 0.141(6) Uani 0.5 1 d D U P . .
O2 O 0.3615(7) 0.5000 0.6250(16) 0.192(7) Uani 1 2 d DS TU P . .
O3 O 0.4299(14) 0.5000 0.652(4) 0.390(19) Uiso 1 2 d DS . P . .
O4 O 0.2500 0.3031(11) 0.5450(10) 0.142(5) Uani 1 2 d S T P A .
O7 O 0.1506(4) 0.0746(10) 0.3214(9) 0.056(2) Uani 0.5 1 d . . P A .
O8 O 0.1515(4) -0.0802(10) 0.1681(9) 0.056(2) Uani 0.5 1 d . . P A .
O9 O 0.0723(3) 0.0000 0.2448(7) 0.090(3) Uani 1 2 d S T P A .
O12 O 0.2500 -0.3023(9) -0.0607(8) 0.099(3) Uani 1 2 d S T P A .
O5A O 0.2500 0.2459(12) 0.3351(12) 0.049(3) Uani 0.475(10) 2 d S T P A 1
O10A O 0.2500 -0.0907(14) 0.0000(11) 0.052(4) Uani 0.475(10) 2 d S T P A 1
O5B O 0.2500 0.0914(13) 0.4879(11) 0.051(4) Uani 0.475(10) 2 d S T P A 1
O10B O 0.2500 -0.2478(13) 0.1498(12) 0.057(4) Uani 0.475(10) 2 d S T P A 1
O6 O 0.2045(4) 0.1721(10) 0.4110(9) 0.064(3) Uani 0.525(10) 1 d . . P A 2
O11 O 0.2050(4) -0.1683(10) 0.0772(8) 0.061(3) Uani 0.525(10) 1 d . . P A 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 N6 1.478(15) . ?
C1 C1 1.49(2) 7 ?
C2 C2 1.22(5) 7 ?
C2 N6 1.50(2) . ?
C3 C3 1.45(3) 7 ?
C3 N6 1.519(16) . ?
C4 N5 1.475(11) . ?
C4 C5 1.517(16) . ?
C5 C6 1.501(12) . ?
C6 C7 1.46(2) . ?
C6 C5 1.501(12) 7_565 ?
C7 C8 1.52(2) . ?
C8 N5 1.466(19) . ?
Eu1 O11 2.559(8) 8_655 ?
Eu1 O11 2.559(8) 7 ?
Eu1 O11 2.559(8) 2 ?
Eu1 O11 2.559(8) . ?
Eu1 O5A 2.567(12) 2 ?
Eu1 O5A 2.567(12) . ?
Eu1 O10A 2.569(11) 2 ?
Eu1 O10A 2.569(11) . ?
Eu1 O8 2.571(8) 7 ?
Eu1 O8 2.571(8) 2 ?
Eu1 O8 2.571(8) 8_655 ?
Eu1 O8 2.571(8) . ?
K1 O12 2.742(7) 1_566 ?
K1 O12 2.742(7) 2_556 ?
K1 O4 2.743(8) 2_565 ?
K1 O4 2.743(8) . ?
K1 O2 2.887(12) 2_565 ?
K1 O2 2.887(12) . ?
K1 O1 2.91(2) . ?
K1 O1 2.91(2) 7_565 ?
K1 O1 2.91(2) 8_655 ?
K1 O1 2.91(2) 2_565 ?
N1 O3 1.231(18) . ?
N1 O2 1.252(17) . ?
N1 O1 1.291(18) . ?
N1 N1 1.80(5) 7_565 ?
N2 O4 1.201(11) . ?
N2 O5A 1.254(14) . ?
N2 O6 1.255(10) 8_655 ?
N2 O6 1.255(10) . ?
N2 O5B 1.261(15) . ?
N3 O9 1.228(12) . ?
N3 O7 1.232(10) . ?
N3 O7 1.232(10) 7 ?
N3 O8 1.262(10) . ?
N3 O8 1.262(10) 7 ?
N4 O12 1.217(10) . ?
N4 O10B 1.244(14) . ?
N4 O10A 1.256(15) . ?
N4 O11 1.262(10) 8_655 ?
N4 O11 1.262(10) . ?
N5 C4 1.475(11) 7_565 ?
O1 O1 1.57(4) 7_565 ?
O2 N1 1.252(17) 7_565 ?
O2 O1 1.69(2) 7_565 ?
O3 N1 1.231(18) 7_565 ?
O7 O7 1.457(19) 7 ?
O7 O8 1.520(14) 7 ?
O8 O7 1.520(14) 7 ?
O8 O8 1.565(19) 7 ?
O12 K1 2.742(7) 1_544 ?
O10A O10A 1.77(3) 2 ?
O5B O5B 1.78(3) 2 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N6 C1 C1 109.9(9) . 7 ?
C2 C2 N6 115.1(12) 7 . ?
C3 C3 N6 110.2(10) 7 . ?
N5 C4 C5 108.6(8) . . ?
C6 C5 C4 111.4(9) . . ?
C7 C6 C5 105.6(10) . . ?
C7 C6 C5 105.6(10) . 7_565 ?
C5 C6 C5 113.1(13) . 7_565 ?
C6 C7 C8 108.9(15) . . ?
N5 C8 C7 111.4(14) . . ?
O11 Eu1 O11 99.9(4) 8_655 7 ?
O11 Eu1 O11 79.9(4) 8_655 2 ?
O11 Eu1 O11 49.2(4) 7 2 ?
O11 Eu1 O11 49.2(4) 8_655 . ?
O11 Eu1 O11 79.9(4) 7 . ?
O11 Eu1 O11 99.9(4) 2 . ?
O5A Eu1 O5A 138.5(5) 2 . ?
O5A Eu1 O10A 130.9(4) 2 2 ?
O5A Eu1 O10A 90.6(4) . 2 ?
O5A Eu1 O10A 90.6(4) 2 . ?
O5A Eu1 O10A 130.9(4) . . ?
O10A Eu1 O10A 40.3(6) 2 . ?
O11 Eu1 O8 112.8(3) 8_655 7 ?
O11 Eu1 O8 40.5(3) 7 7 ?
O11 Eu1 O8 89.8(3) 2 7 ?
O11 Eu1 O8 68.3(3) . 7 ?
O5A Eu1 O8 112.8(2) 2 7 ?
O5A Eu1 O8 79.5(2) . 7 ?
O10A Eu1 O8 67.8(2) 2 7 ?
O10A Eu1 O8 80.4(2) . 7 ?
O11 Eu1 O8 68.3(3) 8_655 2 ?
O11 Eu1 O8 89.8(3) 7 2 ?
O11 Eu1 O8 40.5(3) 2 2 ?
O11 Eu1 O8 112.8(3) . 2 ?
O5A Eu1 O8 112.8(2) 2 2 ?
O5A Eu1 O8 79.5(2) . 2 ?
O10A Eu1 O8 67.8(2) 2 2 ?
O10A Eu1 O8 80.4(2) . 2 ?
O8 Eu1 O8 130.3(4) 7 2 ?
O11 Eu1 O8 40.5(3) 8_655 8_655 ?
O11 Eu1 O8 112.8(3) 7 8_655 ?
O11 Eu1 O8 68.3(3) 2 8_655 ?
O11 Eu1 O8 89.8(3) . 8_655 ?
O5A Eu1 O8 79.5(2) 2 8_655 ?
O5A Eu1 O8 112.8(2) . 8_655 ?
O10A Eu1 O8 80.4(2) 2 8_655 ?
O10A Eu1 O8 67.8(2) . 8_655 ?
O8 Eu1 O8 146.3(4) 7 8_655 ?
O8 Eu1 O8 35.5(4) 2 8_655 ?
O11 Eu1 O8 89.8(3) 8_655 . ?
O11 Eu1 O8 68.3(3) 7 . ?
O11 Eu1 O8 112.8(3) 2 . ?
O11 Eu1 O8 40.5(3) . . ?
O5A Eu1 O8 79.5(2) 2 . ?
O5A Eu1 O8 112.8(2) . . ?
O10A Eu1 O8 80.4(2) 2 . ?
O10A Eu1 O8 67.8(2) . . ?
O8 Eu1 O8 35.5(4) 7 . ?
O8 Eu1 O8 146.3(4) 2 . ?
O8 Eu1 O8 130.3(4) 8_655 . ?
O12 K1 O12 89.4(4) 1_566 2_556 ?
O12 K1 O4 90.8(4) 1_566 2_565 ?
O12 K1 O4 179.8(3) 2_556 2_565 ?
O12 K1 O4 179.8(3) 1_566 . ?
O12 K1 O4 90.8(4) 2_556 . ?
O4 K1 O4 88.9(5) 2_565 . ?
O12 K1 O2 106.7(3) 1_566 2_565 ?
O12 K1 O2 106.7(3) 2_556 2_565 ?
O4 K1 O2 73.3(3) 2_565 2_565 ?
O4 K1 O2 73.3(3) . 2_565 ?
O12 K1 O2 106.7(3) 1_566 . ?
O12 K1 O2 106.7(3) 2_556 . ?
O4 K1 O2 73.3(3) 2_565 . ?
O4 K1 O2 73.3(3) . . ?
O2 K1 O2 132.4(7) 2_565 . ?
O12 K1 O1 96.3(4) 1_566 . ?
O12 K1 O1 74.4(4) 2_556 . ?
O4 K1 O1 105.6(4) 2_565 . ?
O4 K1 O1 83.7(4) . . ?
O2 K1 O1 157.0(5) 2_565 . ?
O2 K1 O1 33.9(5) . . ?
O12 K1 O1 74.4(4) 1_566 7_565 ?
O12 K1 O1 96.3(4) 2_556 7_565 ?
O4 K1 O1 83.7(4) 2_565 7_565 ?
O4 K1 O1 105.6(4) . 7_565 ?
O2 K1 O1 157.0(5) 2_565 7_565 ?
O2 K1 O1 33.9(5) . 7_565 ?
O1 K1 O1 31.3(8) . 7_565 ?
O12 K1 O1 96.3(4) 1_566 8_655 ?
O12 K1 O1 74.4(4) 2_556 8_655 ?
O4 K1 O1 105.6(4) 2_565 8_655 ?
O4 K1 O1 83.7(4) . 8_655 ?
O2 K1 O1 33.9(5) 2_565 8_655 ?
O2 K1 O1 157.0(5) . 8_655 ?
O1 K1 O1 146.0(8) . 8_655 ?
O1 K1 O1 167.1(7) 7_565 8_655 ?
O12 K1 O1 74.4(4) 1_566 2_565 ?
O12 K1 O1 96.3(4) 2_556 2_565 ?
O4 K1 O1 83.7(4) 2_565 2_565 ?
O4 K1 O1 105.6(4) . 2_565 ?
O2 K1 O1 33.9(5) 2_565 2_565 ?
O2 K1 O1 157.0(5) . 2_565 ?
O1 K1 O1 167.1(7) . 2_565 ?
O1 K1 O1 146.0(8) 7_565 2_565 ?
O1 K1 O1 31.3(8) 8_655 2_565 ?
O3 N1 O2 83(2) . . ?
O3 N1 O1 111(3) . . ?
O2 N1 O1 83.4(19) . . ?
O3 N1 N1 43.2(15) . 7_565 ?
O2 N1 N1 44.2(13) . 7_565 ?
O1 N1 N1 85.0(13) . 7_565 ?
O4 N2 O5A 122.6(11) . . ?
O4 N2 O6 120.8(5) . 8_655 ?
O4 N2 O6 120.8(5) . . ?
O6 N2 O6 118.3(10) 8_655 . ?
O4 N2 O5B 121.0(11) . . ?
O5A N2 O5B 116.4(10) . . ?
O4 N2 Eu1 179.6(9) . . ?
O5A N2 Eu1 57.8(6) . . ?
O6 N2 Eu1 59.2(5) 8_655 . ?
O6 N2 Eu1 59.2(5) . . ?
O5B N2 Eu1 58.5(6) . . ?
O9 N3 O7 120.2(7) . . ?
O9 N3 O7 120.2(7) . 7 ?
O7 N3 O7 72.5(10) . 7 ?
O9 N3 O8 121.3(7) . . ?
O7 N3 O8 118.4(9) . . ?
O7 N3 O8 75.1(7) 7 . ?
O9 N3 O8 121.3(7) . 7 ?
O7 N3 O8 75.1(7) . 7 ?
O7 N3 O8 118.4(9) 7 7 ?
O8 N3 O8 76.7(9) . 7 ?
O9 N3 Eu1 179.5(6) . . ?
O7 N3 Eu1 59.4(5) . . ?
O7 N3 Eu1 59.4(5) 7 . ?
O8 N3 Eu1 59.0(5) . . ?
O8 N3 Eu1 59.0(5) 7 . ?
O12 N4 O10B 122.0(11) . . ?
O12 N4 O10A 120.9(10) . . ?
O10B N4 O10A 117.2(10) . . ?
O12 N4 O11 122.3(5) . 8_655 ?
O12 N4 O11 122.3(5) . . ?
O11 N4 O11 115.3(10) 8_655 . ?
O12 N4 Eu1 179.0(8) . . ?
O10B N4 Eu1 59.0(7) . . ?
O10A N4 Eu1 58.1(6) . . ?
O11 N4 Eu1 57.7(5) 8_655 . ?
O11 N4 Eu1 57.7(5) . . ?
C8 N5 C4 107.4(7) . . ?
C8 N5 C4 107.5(7) . 7_565 ?
C4 N5 C4 113.6(12) . 7_565 ?
C1 N6 C2 107.1(13) . . ?
C1 N6 C3 110.3(16) . . ?
C2 N6 C3 104.1(13) . . ?
N1 O1 O1 95.0(13) . 7_565 ?
N1 O1 K1 113.8(15) . . ?
O1 O1 K1 74.3(4) 7_565 . ?
N1 O2 N1 92(3) 7_565 . ?
N1 O2 O1 49.3(12) 7_565 7_565 ?
N1 O2 O1 90.8(17) . 7_565 ?
N1 O2 K1 116.9(12) 7_565 . ?
N1 O2 K1 116.9(12) . . ?
O1 O2 K1 73.8(7) 7_565 . ?
N1 O3 N1 94(3) . 7_565 ?
N2 O4 K1 180.0(10) . . ?
N3 O7 O7 53.7(5) . 7 ?
N3 O7 O8 53.4(5) . 7 ?
O7 O7 O8 92.0(4) 7 7 ?
N3 O7 Eu1 96.3(6) . . ?
O7 O7 Eu1 73.6(2) 7 . ?
O8 O7 Eu1 72.4(4) 7 . ?
N3 O8 O7 51.6(5) . 7 ?
N3 O8 O8 51.7(5) . 7 ?
O7 O8 O8 88.0(4) 7 7 ?
N3 O8 Eu1 96.1(6) . . ?
O7 O8 Eu1 73.3(4) 7 . ?
O8 O8 Eu1 72.3(2) 7 . ?
N4 O12 K1 179.0(8) . 1_544 ?
N2 O5A Eu1 97.8(8) . . ?
N4 O10A O10A 167.2(6) . 2 ?
N4 O10A Eu1 97.3(7) . . ?
O10A O10A Eu1 69.8(3) 2 . ?
N2 O5B O5B 166.6(6) . 2 ?
N2 O5B Eu1 96.8(7) . . ?
O5B O5B Eu1 69.8(3) 2 . ?
N4 O10B Eu1 96.6(8) . . ?
N2 O6 Eu1 96.3(6) . . ?
N4 O11 Eu1 97.7(6) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N5 C4 C5 C6 -2.7(14) . . . . ?
C4 C5 C6 C7 63.0(13) . . . . ?
C4 C5 C6 C5 -52.0(19) . . . 7_565 ?
C5 C6 C7 C8 -60.0(8) . . . . ?
C5 C6 C7 C8 60.0(8) 7_565 . . . ?
C6 C7 C8 N5 0.000(1) . . . . ?
C7 C8 N5 C4 61.3(7) . . . . ?
C7 C8 N5 C4 -61.3(7) . . . 7_565 ?
C5 C4 N5 C8 -58.1(11) . . . . ?
C5 C4 N5 C4 60.6(15) . . . 7_565 ?
C1 C1 N6 C2 -54.3(14) 7 . . . ?
C1 C1 N6 C3 58.3(16) 7 . . . ?
C2 C2 N6 C1 57.5(12) 7 . . . ?
C2 C2 N6 C3 -59.3(12) 7 . . . ?
C3 C3 N6 C1 -58.5(15) 7 . . . ?
C3 C3 N6 C2 56.1(13) 7 . . . ?
O3 N1 O1 O1 35(2) . . . 7_565 ?
O2 N1 O1 O1 -44.4(13) . . . 7_565 ?
N1 N1 O1 O1 -0.004(6) 7_565 . . 7_565 ?
O3 N1 O1 K1 110(2) . . . . ?
O2 N1 O1 K1 30.7(18) . . . . ?
N1 N1 O1 K1 75.1(9) 7_565 . . . ?
O3 N1 O2 N1 -22(3) . . . 7_565 ?
O1 N1 O2 N1 89.6(18) . . . 7_565 ?
O3 N1 O2 O1 -72(2) . . . 7_565 ?
O1 N1 O2 O1 40.3(15) . . . 7_565 ?
N1 N1 O2 O1 -49.3(12) 7_565 . . 7_565 ?
O3 N1 O2 K1 -144(2) . . . . ?
O1 N1 O2 K1 -32(2) . . . . ?
N1 N1 O2 K1 -121.5(19) 7_565 . . . ?
O2 N1 O3 N1 23(3) . . . 7_565 ?
O1 N1 O3 N1 -57(4) . . . 7_565 ?
O9 N3 O7 O7 115.3(8) . . . 7 ?
O8 N3 O7 O7 -61.5(6) . . . 7 ?
O8 N3 O7 O7 -126.9(7) 7 . . 7 ?
Eu1 N3 O7 O7 -64.3(5) . . . 7 ?
O9 N3 O7 O8 -117.8(7) . . . 7 ?
O7 N3 O7 O8 126.9(7) 7 . . 7 ?
O8 N3 O7 O8 65.4(9) . . . 7 ?
Eu1 N3 O7 O8 62.6(5) . . . 7 ?
O9 N3 O7 Eu1 179.6(5) . . . . ?
O7 N3 O7 Eu1 64.3(5) 7 . . . ?
O8 N3 O7 Eu1 2.9(7) . . . . ?
O8 N3 O7 Eu1 -62.6(5) 7 . . . ?
O9 N3 O8 O7 -116.6(7) . . . 7 ?
O7 N3 O8 O7 60.1(9) . . . 7 ?
O8 N3 O8 O7 124.7(7) 7 . . 7 ?
Eu1 N3 O8 O7 63.0(5) . . . 7 ?
O9 N3 O8 O8 118.7(9) . . . 7 ?
O7 N3 O8 O8 -64.6(6) . . . 7 ?
O7 N3 O8 O8 -124.7(7) 7 . . 7 ?
Eu1 N3 O8 O8 -61.7(6) . . . 7 ?
O9 N3 O8 Eu1 -179.6(5) . . . . ?
O7 N3 O8 Eu1 -2.9(7) . . . . ?
O7 N3 O8 Eu1 -63.0(5) 7 . . . ?
O8 N3 O8 Eu1 61.7(6) 7 . . . ?
O4 N2 O5A Eu1 180.000(2) . . . . ?
O6 N2 O5A Eu1 63.7(5) 8_655 . . . ?
O6 N2 O5A Eu1 -63.7(5) . . . . ?
O5B N2 O5A Eu1 0.000(2) . . . . ?
O12 N4 O10A O10A 180.000(3) . . . 2 ?
O10B N4 O10A O10A 0.000(4) . . . 2 ?
O11 N4 O10A O10A -61.5(5) 8_655 . . 2 ?
O11 N4 O10A O10A 61.5(5) . . . 2 ?
Eu1 N4 O10A O10A 0.000(3) . . . 2 ?
O12 N4 O10A Eu1 180.000(1) . . . . ?
O10B N4 O10A Eu1 0.000(1) . . . . ?
O11 N4 O10A Eu1 -61.5(5) 8_655 . . . ?
O11 N4 O10A Eu1 61.5(5) . . . . ?
O4 N2 O5B O5B 180.000(10) . . . 2 ?
O5A N2 O5B O5B 0.000(11) . . . 2 ?
O6 N2 O5B O5B -62.6(5) 8_655 . . 2 ?
O6 N2 O5B O5B 62.6(5) . . . 2 ?
Eu1 N2 O5B O5B 0.000(10) . . . 2 ?
O4 N2 O5B Eu1 180.000(2) . . . . ?
O5A N2 O5B Eu1 0.000(2) . . . . ?
O6 N2 O5B Eu1 -62.6(5) 8_655 . . . ?
O6 N2 O5B Eu1 62.6(5) . . . . ?
O12 N4 O10B Eu1 180.000(1) . . . . ?
O10A N4 O10B Eu1 0.000(1) . . . . ?
O11 N4 O10B Eu1 61.7(5) 8_655 . . . ?
O11 N4 O10B Eu1 -61.7(5) . . . . ?
O4 N2 O6 Eu1 -179.5(10) . . . . ?
O5A N2 O6 Eu1 62.0(6) . . . . ?
O6 N2 O6 Eu1 2.2(13) 8_655 . . . ?
O5B N2 O6 Eu1 -61.8(6) . . . . ?
O12 N4 O11 Eu1 -178.8(9) . . . . ?
O10B N4 O11 Eu1 63.3(7) . . . . ?
O10A N4 O11 Eu1 -62.1(6) . . . . ?
O11 N4 O11 Eu1 1.0(12) 8_655 . . . ?

_refine_diff_density_max         1.232
_refine_diff_density_min         -0.879
_refine_diff_density_rms         0.125

_shelxl_version_number           2014-3



