# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2022

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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data_C87H88F9N8O17Rh4S3
_database_code_depnum_ccdc_archive 'CCDC 2165001'
loop_
_audit_author_name
_audit_author_address
'YingFeng Han'
;Northwest univeristy
China
;
_audit_update_record             
;
2022-04-07 deposited with the CCDC.	2022-05-10 downloaded from the CCDC.
;
_audit_creation_date             2022-04-07
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.06.28 svn.raecde09e for OlexSys, GUI svn.r6132)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C84 H88 N8 O8 Rh4, 1.5(C2 F6 O6 S2)'
_chemical_formula_sum            'C87 H88 F9 N8 O17 Rh4 S3'
_chemical_formula_weight         2196.47
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'C 1 2/c 1'
_space_group_name_Hall           '-C 2yc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   30.7296(12)
_cell_length_b                   19.6924(8)
_cell_length_c                   23.9910(8)
_cell_angle_alpha                90
_cell_angle_beta                 126.9440(10)
_cell_angle_gamma                90
_cell_volume                     11603.0(8)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9903
_cell_measurement_temperature    150.0
_cell_measurement_theta_max      25.21
_cell_measurement_theta_min      2.28
_shelx_estimated_absorpt_T_max   0.870
_shelx_estimated_absorpt_T_min   0.848
_exptl_absorpt_coefficient_mu    0.682
_exptl_absorpt_correction_T_max  0.7452
_exptl_absorpt_correction_T_min  0.6591
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.0638 before and 0.0451 after correction.
The Ratio of minimum to maximum transmission is 0.8845.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.257
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             4444
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.21
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0380
_diffrn_reflns_av_unetI/netI     0.0428
_diffrn_reflns_Laue_measured_fraction_full 0.981
_diffrn_reflns_Laue_measured_fraction_max 0.978
_diffrn_reflns_limit_h_max       36
_diffrn_reflns_limit_h_min       -36
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            37812
_diffrn_reflns_point_group_measured_fraction_full 0.981
_diffrn_reflns_point_group_measured_fraction_max 0.978
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.378
_diffrn_reflns_theta_min         2.325
_diffrn_ambient_temperature      150.0
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.981
_diffrn_measured_fraction_theta_max 0.978
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           1.4
_diffrn_source_power             0.07
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                6944
_reflns_number_total             10418
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.38A (Bruker, 2018)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.38A (Bruker, 2018)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'olex2.solve 1.3 (Bourhis et al., 2015)'
_refine_diff_density_max         1.472
_refine_diff_density_min         -1.399
_refine_diff_density_rms         0.120
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.043
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     606
_refine_ls_number_reflns         10418
_refine_ls_number_restraints     278
_refine_ls_R_factor_all          0.1206
_refine_ls_R_factor_gt           0.0887
_refine_ls_restrained_S_all      1.090
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1604P)²+61.1721P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2470
_refine_ls_wR_factor_ref         0.2802
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 S1-C23
 1.83 with sigma of 0.02
 S0AA-C27
 1.7 with sigma of 0.02
 S0AA-O8
 1.39 with sigma of 0.01
 F9-C23 = F43-C23 = F15-C23
 1.39 with sigma of 0.01
 S1-O33 = S1-O9 = S1-O7
 1.43 with sigma of 0.01
 F0AA-F14 \\sim F0AA-F4 \\sim F14-F4
 with sigma of 0.05
 F0AA-C27 \\sim F14-C27 \\sim F4-C27
 with sigma of 0.05
 S0AA-F0AA \\sim S0AA-F14 \\sim S0AA-F4
 with sigma of 0.05
 O8-O6 \\sim O8-O16 \\sim O6-O16
 with sigma of 0.05
 S0AA-O8 \\sim S0AA-O6 \\sim S0AA-O16
 with sigma of 0.05
 C27-O8 \\sim C27-O6 \\sim C27-O16
 with sigma of 0.05
 F9-F15 \\sim F9-F43 \\sim F15-F43
 with sigma of 0.05
 F9-C23 \\sim F15-C23 \\sim F43-C23
 with sigma of 0.05
 O33-O7 \\sim O33-O9 \\sim O7-O9
 with sigma of 0.05
 C23-O33 \\sim C23-O7 \\sim C23-O9
 with sigma of 0.05
 S1-O33 \\sim S1-O7 \\sim S1-O9
 with sigma of 0.05
 S1-F9 \\sim S1-F15 \\sim S1-F43
 with sigma of 0.05
3. Rigid bond restraints
 C10, C01G, C2, C16, C7
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.01
 C7, C16, C2, C01G, C10
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.01
 F0AA, F4, F14
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.01
 C27, F4, F14, F0AA
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.01
 S0AA, C27
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.01
 S0AA, O16
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.01
 C019, C01H, C01H, C013, S0AA, O6
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.01
 F9, S1, O7, O9, C23, F15, F43
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.02
 O9, S1
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.001
 S1, O33
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.001
 S1, C23, O7, O9, F9, F15, S0AA, O8
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.01
4. Uiso/Uaniso restraints and constraints
F0AA \\sim S0AA \\sim O8 \\sim O16 \\sim C27 \\sim O6 \\sim F4 \\sim F14:
within 2A with sigma of 0.01 and sigma for terminal atoms of 0.01 within 2A
O9 \\sim S1 \\sim O7 \\sim C23 \\sim O33 \\sim F15 \\sim F9 \\sim F43: within
2A with sigma of 0.01 and sigma for terminal atoms of 0.01 within 2A
Uanis(C7) \\sim Ueq, Uanis(C10) \\sim Ueq, Uanis(C2) \\sim Ueq, Uanis(C16)
\\sim Ueq, Uanis(C019) \\sim Ueq, Uanis(C016) \\sim Ueq: with sigma of 0.01 and
sigma for terminal atoms of 0.02
Uanis(F14) \\sim Ueq, Uanis(F0AA) \\sim Ueq, Uanis(F4) \\sim Ueq, Uanis(C27)
\\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(C27) \\sim Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.002
Uanis(S1) \\sim Ueq, Uanis(S0AA) \\sim Ueq: with sigma of 0.005 and sigma for
terminal atoms of 0.01
Uanis(O9) \\sim Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.002
Uanis(O33) \\sim Ueq, Uanis(C23) \\sim Ueq, Uanis(F15) \\sim Ueq, Uanis(F43)
\\sim Ueq, Uanis(O7) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms
of 0.02
Uanis(S1) \\sim Ueq, Uanis(O9) \\sim Ueq: with sigma of 0.001 and sigma for
terminal atoms of 0.002
5. Others
 Fixed Sof: O7(0.5) O9(0.5) F15(0.5) O33(0.5) F9(0.5) F43(0.5)
6.a Ternary CH refined with riding coordinates:
 C00H(H00H), C00P(H00P)
6.b Aromatic/amide H refined with riding coordinates:
 C00E(H00E), C00G(H00G), C00I(H00I), C00O(H00O), C00Q(H00Q), C00S(H00S),
 C00T(H00T), C00U(H00U), C00V(H00V), C00W(H00W), C00X(H00X), C00Z(H00Z)
6.c Fitted pentagon refined as free rotating group:
 C016(C019,C01H,C013,C015)
6.d Idealised Me refined as rotating group:
 C00Y(H00A,H00B,H00C), C017(H01A,H01B,H01C), C01D(H01D,H01E,H01F), C01E(H01G,
 H01H,H01I), C01G(H01J,H01K,H01L), C01K(H01M,H01N,H01O), C2(H2A,H2B,H2C),
 C7(H7A,H7B,H7C), C16(H16A,H16B,H16C), C10(H10A,H10B,H10C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     iterative
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh01 Rh 0.28719(2) 0.12642(3) 0.45123(3) 0.0628(3) Uani 1 1 d . . . . .
Rh02 Rh 0.84527(2) 0.70206(4) 0.77267(3) 0.0686(3) Uani 1 1 d . . . . .
O004 O 0.7683(2) 0.7895(3) 0.5799(3) 0.0591(12) Uani 1 1 d . . . . .
O005 O 0.8188(2) 0.7165(3) 0.6674(3) 0.0594(13) Uani 1 1 d . . . . .
O006 O 0.7232(2) 0.8359(3) 0.6401(3) 0.0718(15) Uani 1 1 d . . . . .
O007 O 0.7722(2) 0.7615(3) 0.7257(3) 0.0685(15) Uani 1 1 d . . . . .
N008 N 0.4121(2) 0.2730(3) 0.5335(3) 0.0572(15) Uani 1 1 d . . . . .
N009 N 0.7942(3) 0.6164(4) 0.7356(3) 0.0672(18) Uani 1 1 d . . . . .
N00A N 0.3492(3) 0.1997(3) 0.5072(3) 0.0610(16) Uani 1 1 d . . . . .
N00B N 0.7196(2) 0.5559(4) 0.6865(3) 0.0614(16) Uani 1 1 d . . . . .
C00C C 0.5788(3) 0.4901(4) 0.5679(4) 0.0552(18) Uani 1 1 d . . . . .
C00D C 0.4864(3) 0.4248(4) 0.5410(4) 0.0551(17) Uani 1 1 d . . . . .
C00E C 0.4547(3) 0.3821(4) 0.5492(3) 0.0533(17) Uani 1 1 d . . . . .
H00E H 0.438696 0.398297 0.570291 0.064 Uiso 1 1 calc R U . . .
C00F C 0.5568(3) 0.5129(4) 0.5999(3) 0.0528(17) Uani 1 1 d . . . . .
C00G C 0.4014(3) 0.2814(4) 0.5812(4) 0.0584(18) Uani 1 1 d . . . . .
H00G H 0.417302 0.313829 0.617811 0.070 Uiso 1 1 calc R U . . .
C00H C 0.4970(3) 0.4984(4) 0.5641(4) 0.0559(18) Uani 1 1 d . . . . .
H00H H 0.489473 0.504444 0.599021 0.067 Uiso 1 1 calc R U . . .
C00I C 0.6336(3) 0.5023(4) 0.5964(4) 0.0580(18) Uani 1 1 d . . . . .
H00I H 0.649206 0.485310 0.575010 0.070 Uiso 1 1 calc R U . . .
C00J C 0.7838(3) 0.7634(4) 0.6362(4) 0.0566(18) Uani 1 1 d . . . . .
C00K C 0.7575(3) 0.7892(4) 0.6707(4) 0.0588(19) Uani 1 1 d . . . . .
C00M C 0.5099(3) 0.4009(4) 0.5091(3) 0.0553(17) Uani 1 1 d . . . . .
C00N C 0.4469(3) 0.3166(4) 0.5266(4) 0.0573(19) Uani 1 1 d . . . . .
C00O C 0.3636(3) 0.2341(4) 0.5652(4) 0.0621(19) Uani 1 1 d . . . . .
H00O H 0.349406 0.226170 0.590516 0.075 Uiso 1 1 calc R U . . .
C00P C 0.5418(3) 0.4505(4) 0.5000(4) 0.0564(18) Uani 1 1 d . . . . .
H00P H 0.565036 0.424930 0.490866 0.068 Uiso 1 1 calc R U . . .
C00Q C 0.5882(3) 0.5495(4) 0.6609(4) 0.0601(19) Uani 1 1 d . . . . .
H00Q H 0.572773 0.564778 0.683066 0.072 Uiso 1 1 calc R U . . .
C00R C 0.6642(3) 0.5406(4) 0.6582(4) 0.0597(19) Uani 1 1 d . . . . .
C00S C 0.5009(3) 0.3336(4) 0.4863(4) 0.0596(19) Uani 1 1 d . . . . .
H00S H 0.515447 0.317402 0.463315 0.072 Uiso 1 1 calc R U . . .
C00T C 0.7441(3) 0.6157(5) 0.7160(4) 0.065(2) Uani 1 1 d . . . . .
H00T H 0.727230 0.652603 0.721835 0.078 Uiso 1 1 calc R U . . .
C00U C 0.4705(3) 0.2895(5) 0.4969(4) 0.0596(19) Uani 1 1 d . . . . .
H00U H 0.466203 0.242886 0.484332 0.072 Uiso 1 1 calc R U . . .
C00V C 0.6435(3) 0.5647(5) 0.6912(4) 0.063(2) Uani 1 1 d . . . . .
H00V H 0.665230 0.590717 0.732748 0.075 Uiso 1 1 calc R U . . .
C00W C 0.3794(3) 0.2232(5) 0.4893(4) 0.064(2) Uani 1 1 d . . . . .
H00W H 0.378190 0.207436 0.450997 0.077 Uiso 1 1 calc R U . . .
C00X C 0.8029(3) 0.5545(5) 0.7203(5) 0.075(3) Uani 1 1 d . . . . .
H00X H 0.836245 0.539504 0.730047 0.091 Uiso 1 1 calc R U . . .
C00Y C 0.3539(4) 0.0717(5) 0.6115(5) 0.085(3) Uani 1 1 d . . . . .
H00A H 0.388185 0.089277 0.622764 0.128 Uiso 1 1 calc R U . . .
H00B H 0.360919 0.029541 0.637358 0.128 Uiso 1 1 calc R U . . .
H00C H 0.338004 0.105386 0.624577 0.128 Uiso 1 1 calc R U . . .
C00Z C 0.7565(3) 0.5164(5) 0.6887(5) 0.077(2) Uani 1 1 d . . . . .
H00Z H 0.751323 0.471333 0.671676 0.092 Uiso 1 1 calc R U . . .
C010 C 0.3148(3) 0.0578(4) 0.5343(5) 0.070(2) Uani 1 1 d . . . . .
C011 C 0.2573(4) 0.0635(5) 0.4938(6) 0.090(3) Uani 1 1 d . . . . .
C014 C 0.2355(5) 0.0407(5) 0.4231(6) 0.102(4) Uani 1 1 d . . . . .
C016 C 0.8862(3) 0.7534(5) 0.8692(4) 0.093(3) Uani 1 1 d G U . . .
C019 C 0.9003(3) 0.6834(5) 0.8804(4) 0.112(4) Uani 1 1 d G U . . .
C01H C 0.9260(3) 0.6681(4) 0.8488(4) 0.109(4) Uani 1 1 d G U . . .
C013 C 0.9279(3) 0.7287(5) 0.8181(3) 0.095(3) Uani 1 1 d G U . . .
C015 C 0.9033(3) 0.7813(4) 0.8307(4) 0.096(3) Uani 1 1 d G . . . .
C017 C 0.2253(5) 0.0890(6) 0.5172(7) 0.108(4) Uani 1 1 d . . . . .
H01A H 0.249565 0.112356 0.561964 0.162 Uiso 1 1 calc R U . . .
H01B H 0.207725 0.050678 0.522545 0.162 Uiso 1 1 calc R U . . .
H01C H 0.197431 0.120667 0.482399 0.162 Uiso 1 1 calc R U . . .
C018 C 0.3295(4) 0.0325(5) 0.4898(5) 0.085(3) Uani 1 1 d . . . . .
C01D C 0.3856(4) 0.0172(6) 0.5134(6) 0.101(4) Uani 1 1 d . . . . .
H01D H 0.392761 -0.031500 0.523062 0.151 Uiso 1 1 calc R U . . .
H01E H 0.411846 0.042955 0.556001 0.151 Uiso 1 1 calc R U . . .
H01F H 0.389150 0.030069 0.476901 0.151 Uiso 1 1 calc R U . . .
C01E C 0.2755(7) 0.0009(7) 0.3594(6) 0.131(5) Uani 1 1 d . . . . .
H01G H 0.242807 0.021064 0.317671 0.196 Uiso 1 1 calc R U . . .
H01H H 0.273106 -0.048718 0.355373 0.196 Uiso 1 1 calc R U . . .
H01I H 0.307759 0.016460 0.363915 0.196 Uiso 1 1 calc R U . . .
C01F C 0.2797(5) 0.0216(5) 0.4211(5) 0.087(3) Uani 1 1 d . . . . .
C01G C 0.9503(5) 0.7369(9) 0.7776(6) 0.119(5) Uani 1 1 d . . . . .
H01J H 0.965235 0.693452 0.776298 0.178 Uiso 1 1 calc R U . . .
H01K H 0.979126 0.771229 0.800095 0.178 Uiso 1 1 calc R U . . .
H01L H 0.921077 0.751274 0.729912 0.178 Uiso 1 1 calc R U . . .
C01K C 0.1757(5) 0.0373(8) 0.3641(8) 0.153(7) Uani 1 1 d . . . . .
H01M H 0.155475 0.064601 0.375722 0.229 Uiso 1 1 calc R U . . .
H01N H 0.163362 -0.009962 0.356523 0.229 Uiso 1 1 calc R U . . .
H01O H 0.169178 0.055140 0.321522 0.229 Uiso 1 1 calc R U . . .
C2 C 0.8953(8) 0.8498(9) 0.8046(8) 0.162(7) Uani 1 1 d . U . . .
H2A H 0.925828 0.878323 0.840085 0.243 Uiso 1 1 calc R U . . .
H2B H 0.861278 0.868023 0.793789 0.243 Uiso 1 1 calc R U . . .
H2C H 0.893233 0.849636 0.762249 0.243 Uiso 1 1 calc R U . . .
C7 C 0.8915(8) 0.6293(12) 0.9188(9) 0.191(8) Uani 1 1 d . U . . .
H7A H 0.861577 0.599192 0.884719 0.286 Uiso 1 1 calc R U . . .
H7B H 0.882323 0.651494 0.947118 0.286 Uiso 1 1 calc R U . . .
H7C H 0.924852 0.602631 0.949110 0.286 Uiso 1 1 calc R U . . .
C16 C 0.8570(6) 0.7915(11) 0.8910(8) 0.158(6) Uani 1 1 d . U . . .
H16A H 0.821734 0.770034 0.870998 0.237 Uiso 1 1 calc R U . . .
H16B H 0.851327 0.838493 0.874433 0.237 Uiso 1 1 calc R U . . .
H16C H 0.878804 0.791254 0.942008 0.237 Uiso 1 1 calc R U . . .
S1 S 1.000000 0.9241(3) 0.750000 0.1317(16) Uani 1 2 d DS TU P . .
O7 O 0.9466(5) 0.9105(11) 0.6869(7) 0.131(4) Uani 0.5 1 d D U P . .
O9 O 1.0329(8) 0.8923(10) 0.8150(7) 0.130(2) Uani 0.5 1 d D U P . .
F15 F 1.0193(9) 1.0490(10) 0.8106(8) 0.159(5) Uani 0.5 1 d D U P . .
C23 C 1.000000 1.0154(8) 0.750000 0.141(3) Uani 1 2 d DS TU P . .
O33 O 1.0358(7) 0.9261(11) 0.7265(10) 0.139(3) Uani 0.5 1 d D U P . .
F9 F 1.0422(5) 1.0221(9) 0.7436(9) 0.142(4) Uani 0.5 1 d D U P . .
F43 F 0.9516(5) 1.0293(10) 0.6847(7) 0.151(5) Uani 0.5 1 d D U P . .
C10 C 0.9507(6) 0.6032(10) 0.8490(10) 0.171(7) Uani 1 1 d . U . . .
H10A H 0.936244 0.591187 0.801051 0.256 Uiso 1 1 calc R U . . .
H10B H 0.941731 0.567204 0.868762 0.256 Uiso 1 1 calc R U . . .
H10C H 0.990305 0.608279 0.877167 0.256 Uiso 1 1 calc R U . . .
S0AA S 0.9576(5) 0.4220(6) 0.9163(6) 0.248(3) Uani 1 1 d D U . . .
F4 F 0.9719(8) 0.4422(10) 0.8129(10) 0.276(5) Uani 1 1 d D U . . .
O8 O 0.9954(8) 0.4725(9) 0.9616(10) 0.284(8) Uani 1 1 d D U . A 1
F14 F 0.9503(9) 0.3514(11) 0.8166(11) 0.304(6) Uani 1 1 d D U . . .
O16 O 0.9029(8) 0.4536(11) 0.8665(11) 0.281(7) Uani 1 1 d D U . . .
C27 C 0.9803(12) 0.4050(16) 0.8676(14) 0.279(4) Uani 1 1 d D U . . .
O6 O 0.9527(8) 0.3823(10) 0.9579(10) 0.241(5) Uani 1 1 d D U . . .
F0AA F 1.0272(8) 0.3749(11) 0.8977(11) 0.315(7) Uani 1 1 d D U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh01 O004 2.162(5) 5_666 ?
Rh01 O006 2.148(6) 5_666 ?
Rh01 N00A 2.107(6) . ?
Rh01 C010 2.117(8) . ?
Rh01 C011 2.134(10) . ?
Rh01 C014 2.131(10) . ?
Rh01 C018 2.126(9) . ?
Rh01 C01F 2.153(9) . ?
Rh02 O005 2.156(5) . ?
Rh02 O007 2.154(6) . ?
Rh02 N009 2.102(7) . ?
Rh02 C016 2.113(7) . ?
Rh02 C019 2.102(7) . ?
Rh02 C01H 2.119(7) . ?
Rh02 C013 2.141(6) . ?
Rh02 C015 2.138(7) . ?
O004 C00J 1.241(9) . ?
O005 C00J 1.267(9) . ?
O006 C00K 1.252(10) . ?
O007 C00K 1.235(10) . ?
N008 C00G 1.378(10) . ?
N008 C00N 1.455(10) . ?
N008 C00W 1.348(10) . ?
N009 C00T 1.314(10) . ?
N009 C00X 1.345(12) . ?
N00A C00O 1.362(11) . ?
N00A C00W 1.316(10) . ?
N00B C00R 1.435(9) . ?
N00B C00T 1.346(11) . ?
N00B C00Z 1.350(12) . ?
C00C C00F 1.370(11) . ?
C00C C00I 1.406(10) . ?
C00C C00P 1.524(10) . ?
C00D C00E 1.386(10) . ?
C00D C00H 1.515(12) . ?
C00D C00M 1.413(10) . ?
C00E H00E 0.9500 . ?
C00E C00N 1.363(11) . ?
C00F C00H 1.516(9) . ?
C00F C00Q 1.376(11) . ?
C00G H00G 0.9500 . ?
C00G C00O 1.351(11) . ?
C00H H00H 1.0000 . ?
C00H C00P 1.612(11) 5_666 ?
C00I H00I 0.9500 . ?
C00I C00R 1.405(11) . ?
C00J C00K 1.548(12) . ?
C00M C00P 1.490(10) . ?
C00M C00S 1.397(12) . ?
C00N C00U 1.392(11) . ?
C00O H00O 0.9500 . ?
C00P H00P 1.0000 . ?
C00Q H00Q 0.9500 . ?
C00Q C00V 1.422(10) . ?
C00R C00V 1.364(11) . ?
C00S H00S 0.9500 . ?
C00S C00U 1.407(11) . ?
C00T H00T 0.9500 . ?
C00U H00U 0.9500 . ?
C00V H00V 0.9500 . ?
C00W H00W 0.9500 . ?
C00X H00X 0.9500 . ?
C00X C00Z 1.367(13) . ?
C00Y H00A 0.9800 . ?
C00Y H00B 0.9800 . ?
C00Y H00C 0.9800 . ?
C00Y C010 1.508(13) . ?
C00Z H00Z 0.9500 . ?
C010 C011 1.420(13) . ?
C010 C018 1.474(15) . ?
C011 C014 1.472(17) . ?
C011 C017 1.481(17) . ?
C014 C01F 1.435(18) . ?
C014 C01K 1.503(15) . ?
C016 C019 1.4200 . ?
C016 C015 1.4200 . ?
C016 C16 1.485(16) . ?
C019 C01H 1.4200 . ?
C019 C7 1.536(16) . ?
C01H C013 1.4200 . ?
C01H C10 1.485(19) . ?
C013 C015 1.4200 . ?
C013 C01G 1.497(12) . ?
C015 C2 1.445(19) . ?
C017 H01A 0.9800 . ?
C017 H01B 0.9800 . ?
C017 H01C 0.9800 . ?
C018 C01D 1.486(15) . ?
C018 C01F 1.439(13) . ?
C01D H01D 0.9800 . ?
C01D H01E 0.9800 . ?
C01D H01F 0.9800 . ?
C01E H01G 0.9800 . ?
C01E H01H 0.9800 . ?
C01E H01I 0.9800 . ?
C01E C01F 1.465(17) . ?
C01G H01J 0.9800 . ?
C01G H01K 0.9800 . ?
C01G H01L 0.9800 . ?
C01K H01M 0.9800 . ?
C01K H01N 0.9800 . ?
C01K H01O 0.9800 . ?
C2 H2A 0.9800 . ?
C2 H2B 0.9800 . ?
C2 H2C 0.9800 . ?
C7 H7A 0.9800 . ?
C7 H7B 0.9800 . ?
C7 H7C 0.9800 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
S1 O7 1.438(9) . ?
S1 O7 1.438(9) 2_756 ?
S1 O9 1.396(9) . ?
S1 O9 1.396(9) 2_756 ?
S1 C23 1.800(16) . ?
S1 O33 1.509(9) 2_756 ?
S1 O33 1.509(9) . ?
O7 O9 0.75(2) 2_756 ?
F15 C23 1.366(9) . ?
F15 F9 1.61(2) 2_756 ?
F15 F43 0.92(2) 2_756 ?
C23 F9 1.400(9) . ?
C23 F9 1.400(9) 2_756 ?
C23 F43 1.393(9) . ?
C23 F43 1.393(9) 2_756 ?
F9 F43 1.62(2) 2_756 ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
S0AA O8 1.415(9) . ?
S0AA O16 1.490(18) . ?
S0AA C27 1.715(19) . ?
S0AA O6 1.345(17) . ?
F4 C27 1.39(2) . ?
F14 C27 1.45(3) . ?
C27 F0AA 1.30(3) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O006 Rh01 O004 77.3(2) 5_666 5_666 ?
O006 Rh01 C01F 93.9(4) 5_666 . ?
N00A Rh01 O004 85.4(2) . 5_666 ?
N00A Rh01 O006 86.3(2) . 5_666 ?
N00A Rh01 C010 98.1(3) . . ?
N00A Rh01 C011 125.3(4) . . ?
N00A Rh01 C014 163.9(4) . . ?
N00A Rh01 C018 103.7(3) . . ?
N00A Rh01 C01F 138.0(4) . . ?
C010 Rh01 O004 126.9(3) . 5_666 ?
C010 Rh01 O006 155.5(3) . 5_666 ?
C010 Rh01 C011 39.0(4) . . ?
C010 Rh01 C014 66.0(4) . . ?
C010 Rh01 C018 40.7(4) . . ?
C010 Rh01 C01F 66.8(4) . . ?
C011 Rh01 O004 97.6(3) . 5_666 ?
C011 Rh01 O006 147.8(3) . 5_666 ?
C011 Rh01 C01F 67.3(5) . . ?
C014 Rh01 O004 102.4(4) . 5_666 ?
C014 Rh01 O006 108.9(4) . 5_666 ?
C014 Rh01 C011 40.4(5) . . ?
C014 Rh01 C01F 39.1(5) . . ?
C018 Rh01 O004 164.9(4) . 5_666 ?
C018 Rh01 O006 114.9(4) . 5_666 ?
C018 Rh01 C011 67.2(4) . . ?
C018 Rh01 C014 66.0(4) . . ?
C018 Rh01 C01F 39.3(4) . . ?
C01F Rh01 O004 135.6(3) . 5_666 ?
O007 Rh02 O005 77.0(2) . . ?
N009 Rh02 O005 87.1(2) . . ?
N009 Rh02 O007 86.4(3) . . ?
N009 Rh02 C016 130.4(3) . . ?
N009 Rh02 C01H 107.5(3) . . ?
N009 Rh02 C013 140.1(3) . . ?
N009 Rh02 C015 168.4(3) . . ?
C016 Rh02 O005 141.1(3) . . ?
C016 Rh02 O007 93.4(3) . . ?
C016 Rh02 C01H 65.75(14) . . ?
C016 Rh02 C013 65.37(13) . . ?
C016 Rh02 C015 39.03(12) . . ?
C019 Rh02 O005 157.1(3) . . ?
C019 Rh02 O007 123.6(3) . . ?
C019 Rh02 N009 103.0(3) . . ?
C019 Rh02 C016 39.37(12) . . ?
C019 Rh02 C01H 39.31(12) . . ?
C019 Rh02 C013 65.56(14) . . ?
C019 Rh02 C015 65.63(14) . . ?
C01H Rh02 O005 118.2(3) . . ?
C01H Rh02 O007 159.2(3) . . ?
C01H Rh02 C013 38.93(11) . . ?
C01H Rh02 C015 65.33(13) . . ?
C013 Rh02 O005 93.5(2) . . ?
C013 Rh02 O007 132.7(3) . . ?
C015 Rh02 O005 104.3(2) . . ?
C015 Rh02 O007 98.2(3) . . ?
C015 Rh02 C013 38.76(10) . . ?
C00J O004 Rh01 113.6(5) . 5_666 ?
C00J O005 Rh02 112.2(5) . . ?
C00K O006 Rh01 114.0(5) . 5_666 ?
C00K O007 Rh02 113.3(5) . . ?
C00G N008 C00N 125.6(7) . . ?
C00W N008 C00G 107.6(6) . . ?
C00W N008 C00N 126.3(6) . . ?
C00T N009 Rh02 125.2(7) . . ?
C00T N009 C00X 106.0(7) . . ?
C00X N009 Rh02 128.5(6) . . ?
C00O N00A Rh01 127.3(5) . . ?
C00W N00A Rh01 125.3(6) . . ?
C00W N00A C00O 107.3(7) . . ?
C00T N00B C00R 124.1(7) . . ?
C00T N00B C00Z 107.1(7) . . ?
C00Z N00B C00R 128.8(8) . . ?
C00F C00C C00I 121.4(7) . . ?
C00F C00C C00P 117.7(6) . . ?
C00I C00C C00P 120.9(7) . . ?
C00E C00D C00H 122.9(7) . . ?
C00E C00D C00M 120.3(7) . . ?
C00M C00D C00H 116.7(6) . . ?
C00D C00E H00E 120.3 . . ?
C00N C00E C00D 119.4(7) . . ?
C00N C00E H00E 120.3 . . ?
C00C C00F C00H 117.3(6) . . ?
C00C C00F C00Q 120.0(6) . . ?
C00Q C00F C00H 122.6(7) . . ?
N008 C00G H00G 127.0 . . ?
C00O C00G N008 106.0(7) . . ?
C00O C00G H00G 127.0 . . ?
C00D C00H C00F 108.0(6) . . ?
C00D C00H H00H 108.3 . . ?
C00D C00H C00P 112.0(6) . 5_666 ?
C00F C00H H00H 108.3 . . ?
C00F C00H C00P 111.8(6) . 5_666 ?
C00P C00H H00H 108.3 5_666 . ?
C00C C00I H00I 121.5 . . ?
C00R C00I C00C 116.9(7) . . ?
C00R C00I H00I 121.5 . . ?
O004 C00J O005 125.4(7) . . ?
O004 C00J C00K 117.7(7) . . ?
O005 C00J C00K 117.0(7) . . ?
O006 C00K C00J 117.0(7) . . ?
O007 C00K O006 126.0(8) . . ?
O007 C00K C00J 116.9(7) . . ?
C00D C00M C00P 117.2(7) . . ?
C00S C00M C00D 118.8(7) . . ?
C00S C00M C00P 124.0(7) . . ?
C00E C00N N008 118.7(7) . . ?
C00E C00N C00U 122.9(7) . . ?
C00U C00N N008 118.4(7) . . ?
N00A C00O H00O 125.4 . . ?
C00G C00O N00A 109.2(7) . . ?
C00G C00O H00O 125.4 . . ?
C00C C00P C00H 110.4(7) . 5_666 ?
C00C C00P H00P 108.7 . . ?
C00H C00P H00P 108.7 5_666 . ?
C00M C00P C00C 108.2(6) . . ?
C00M C00P C00H 112.0(6) . 5_666 ?
C00M C00P H00P 108.7 . . ?
C00F C00Q H00Q 119.6 . . ?
C00F C00Q C00V 120.9(7) . . ?
C00V C00Q H00Q 119.6 . . ?
C00I C00R N00B 117.7(7) . . ?
C00V C00R N00B 119.1(7) . . ?
C00V C00R C00I 123.2(7) . . ?
C00M C00S H00S 119.6 . . ?
C00M C00S C00U 120.8(7) . . ?
C00U C00S H00S 119.6 . . ?
N009 C00T N00B 111.2(8) . . ?
N009 C00T H00T 124.4 . . ?
N00B C00T H00T 124.4 . . ?
C00N C00U C00S 117.6(8) . . ?
C00N C00U H00U 121.2 . . ?
C00S C00U H00U 121.2 . . ?
C00Q C00V H00V 121.3 . . ?
C00R C00V C00Q 117.5(7) . . ?
C00R C00V H00V 121.3 . . ?
N008 C00W H00W 125.1 . . ?
N00A C00W N008 109.8(7) . . ?
N00A C00W H00W 125.1 . . ?
N009 C00X H00X 125.2 . . ?
N009 C00X C00Z 109.6(8) . . ?
C00Z C00X H00X 125.2 . . ?
H00A C00Y H00B 109.5 . . ?
H00A C00Y H00C 109.5 . . ?
H00B C00Y H00C 109.5 . . ?
C010 C00Y H00A 109.5 . . ?
C010 C00Y H00B 109.5 . . ?
C010 C00Y H00C 109.5 . . ?
N00B C00Z C00X 106.1(9) . . ?
N00B C00Z H00Z 127.0 . . ?
C00X C00Z H00Z 127.0 . . ?
C00Y C010 Rh01 127.8(6) . . ?
C011 C010 Rh01 71.1(5) . . ?
C011 C010 C00Y 124.8(10) . . ?
C011 C010 C018 109.2(9) . . ?
C018 C010 Rh01 70.0(5) . . ?
C018 C010 C00Y 125.9(8) . . ?
C010 C011 Rh01 69.9(6) . . ?
C010 C011 C014 106.3(10) . . ?
C010 C011 C017 127.2(11) . . ?
C014 C011 Rh01 69.7(6) . . ?
C014 C011 C017 126.5(10) . . ?
C017 C011 Rh01 124.0(7) . . ?
C011 C014 Rh01 69.9(5) . . ?
C011 C014 C01K 123.4(14) . . ?
C01F C014 Rh01 71.2(6) . . ?
C01F C014 C011 109.5(9) . . ?
C01F C014 C01K 127.1(14) . . ?
C01K C014 Rh01 126.1(8) . . ?
C019 C016 Rh02 69.9(3) . . ?
C019 C016 C16 127.2(11) . . ?
C015 C016 Rh02 71.4(3) . . ?
C015 C016 C019 108.0 . . ?
C015 C016 C16 124.8(11) . . ?
C16 C016 Rh02 122.7(7) . . ?
C016 C019 Rh02 70.7(3) . . ?
C016 C019 C7 130.0(12) . . ?
C01H C019 Rh02 71.0(3) . . ?
C01H C019 C016 108.0 . . ?
C01H C019 C7 122.0(12) . . ?
C7 C019 Rh02 123.9(8) . . ?
C019 C01H Rh02 69.7(3) . . ?
C019 C01H C013 108.0 . . ?
C019 C01H C10 128.9(11) . . ?
C013 C01H Rh02 71.4(3) . . ?
C013 C01H C10 123.0(11) . . ?
C10 C01H Rh02 127.2(8) . . ?
C01H C013 Rh02 69.7(3) . . ?
C01H C013 C015 108.0 . . ?
C01H C013 C01G 127.2(9) . . ?
C015 C013 Rh02 70.5(3) . . ?
C015 C013 C01G 124.8(9) . . ?
C01G C013 Rh02 124.3(6) . . ?
C016 C015 Rh02 69.6(3) . . ?
C016 C015 C013 108.0 . . ?
C016 C015 C2 127.6(11) . . ?
C013 C015 Rh02 70.8(3) . . ?
C013 C015 C2 124.3(11) . . ?
C2 C015 Rh02 122.8(8) . . ?
C011 C017 H01A 109.5 . . ?
C011 C017 H01B 109.5 . . ?
C011 C017 H01C 109.5 . . ?
H01A C017 H01B 109.5 . . ?
H01A C017 H01C 109.5 . . ?
H01B C017 H01C 109.5 . . ?
C010 C018 Rh01 69.3(5) . . ?
C010 C018 C01D 125.5(8) . . ?
C01D C018 Rh01 127.4(8) . . ?
C01F C018 Rh01 71.4(5) . . ?
C01F C018 C010 107.5(9) . . ?
C01F C018 C01D 126.8(10) . . ?
C018 C01D H01D 109.5 . . ?
C018 C01D H01E 109.5 . . ?
C018 C01D H01F 109.5 . . ?
H01D C01D H01E 109.5 . . ?
H01D C01D H01F 109.5 . . ?
H01E C01D H01F 109.5 . . ?
H01G C01E H01H 109.5 . . ?
H01G C01E H01I 109.5 . . ?
H01H C01E H01I 109.5 . . ?
C01F C01E H01G 109.5 . . ?
C01F C01E H01H 109.5 . . ?
C01F C01E H01I 109.5 . . ?
C014 C01F Rh01 69.6(6) . . ?
C014 C01F C018 107.5(10) . . ?
C014 C01F C01E 126.5(11) . . ?
C018 C01F Rh01 69.4(5) . . ?
C018 C01F C01E 125.8(12) . . ?
C01E C01F Rh01 122.2(9) . . ?
C013 C01G H01J 109.5 . . ?
C013 C01G H01K 109.5 . . ?
C013 C01G H01L 109.5 . . ?
H01J C01G H01K 109.5 . . ?
H01J C01G H01L 109.5 . . ?
H01K C01G H01L 109.5 . . ?
C014 C01K H01M 109.5 . . ?
C014 C01K H01N 109.5 . . ?
C014 C01K H01O 109.5 . . ?
H01M C01K H01N 109.5 . . ?
H01M C01K H01O 109.5 . . ?
H01N C01K H01O 109.5 . . ?
C015 C2 H2A 109.5 . . ?
C015 C2 H2B 109.5 . . ?
C015 C2 H2C 109.5 . . ?
H2A C2 H2B 109.5 . . ?
H2A C2 H2C 109.5 . . ?
H2B C2 H2C 109.5 . . ?
C019 C7 H7A 109.5 . . ?
C019 C7 H7B 109.5 . . ?
C019 C7 H7C 109.5 . . ?
H7A C7 H7B 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
C016 C16 H16A 109.5 . . ?
C016 C16 H16B 109.5 . . ?
C016 C16 H16C 109.5 . . ?
H16A C16 H16B 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
O7 S1 O7 158.7(18) 2_756 . ?
O7 S1 C23 100.7(9) . . ?
O7 S1 C23 100.7(9) 2_756 . ?
O7 S1 O33 76.8(10) . 2_756 ?
O7 S1 O33 103.8(10) . . ?
O7 S1 O33 76.8(10) 2_756 . ?
O7 S1 O33 103.8(10) 2_756 2_756 ?
O9 S1 O7 134.0(12) 2_756 2_756 ?
O9 S1 O7 134.0(12) . . ?
O9 S1 O7 30.6(10) 2_756 . ?
O9 S1 O7 30.6(10) . 2_756 ?
O9 S1 O9 126.8(19) 2_756 . ?
O9 S1 C23 116.6(10) . . ?
O9 S1 C23 116.6(10) 2_756 . ?
O9 S1 O33 103.1(11) 2_756 2_756 ?
O9 S1 O33 103.1(11) . . ?
O9 S1 O33 78.3(11) . 2_756 ?
O9 S1 O33 78.2(11) 2_756 . ?
O33 S1 C23 88.5(8) . . ?
O33 S1 C23 88.5(8) 2_756 . ?
O33 S1 O33 177.0(17) . 2_756 ?
O9 O7 S1 71.6(10) 2_756 . ?
O7 O9 S1 77.8(11) 2_756 . ?
C23 F15 F9 55.4(6) . 2_756 ?
F43 F15 C23 72.2(9) 2_756 . ?
F43 F15 F9 123.0(14) 2_756 2_756 ?
F15 C23 S1 119.0(11) 2_756 . ?
F15 C23 S1 119.0(11) . . ?
F15 C23 F15 122(2) 2_756 . ?
F15 C23 F9 103.4(12) 2_756 2_756 ?
F15 C23 F9 71.1(11) . 2_756 ?
F15 C23 F9 71.1(11) 2_756 . ?
F15 C23 F9 103.5(12) . . ?
F15 C23 F43 38.8(10) 2_756 . ?
F15 C23 F43 38.8(10) . 2_756 ?
F15 C23 F43 126.1(15) . . ?
F15 C23 F43 126.1(15) 2_756 2_756 ?
F9 C23 S1 95.4(10) . . ?
F9 C23 S1 95.4(10) 2_756 . ?
F9 C23 F9 169(2) . 2_756 ?
F43 C23 S1 101.3(11) . . ?
F43 C23 S1 101.3(11) 2_756 . ?
F43 C23 F9 70.8(10) 2_756 . ?
F43 C23 F9 106.9(10) . . ?
F43 C23 F9 70.8(10) . 2_756 ?
F43 C23 F9 106.9(10) 2_756 2_756 ?
F43 C23 F43 157(2) . 2_756 ?
F15 F9 F43 99.2(10) 2_756 2_756 ?
C23 F9 F15 53.4(7) . 2_756 ?
C23 F9 F43 54.4(6) . 2_756 ?
F15 F43 C23 68.9(9) 2_756 . ?
F15 F43 F9 114.9(16) 2_756 2_756 ?
C23 F43 F9 54.8(6) . 2_756 ?
C01H C10 H10A 109.5 . . ?
C01H C10 H10B 109.5 . . ?
C01H C10 H10C 109.5 . . ?
H10A C10 H10B 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
O8 S0AA O16 109.4(14) . . ?
O8 S0AA C27 100.3(15) . . ?
O16 S0AA C27 105.1(13) . . ?
O6 S0AA O8 104.2(14) . . ?
O6 S0AA O16 105.2(15) . . ?
O6 S0AA C27 131.6(15) . . ?
F4 C27 S0AA 128(2) . . ?
F4 C27 F14 85.6(18) . . ?
F14 C27 S0AA 113.8(19) . . ?
F0AA C27 S0AA 119(2) . . ?
F0AA C27 F4 106(2) . . ?
F0AA C27 F14 94(2) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Rh01 O004 C00J O005 -175.3(5) 5_666 . . . ?
Rh01 O004 C00J C00K 5.8(8) 5_666 . . . ?
Rh01 O006 C00K O007 176.6(6) 5_666 . . . ?
Rh01 O006 C00K C00J -3.6(8) 5_666 . . . ?
Rh01 N00A C00O C00G -173.8(5) . . . . ?
Rh01 N00A C00W N008 175.3(5) . . . . ?
Rh01 C010 C011 C014 60.5(6) . . . . ?
Rh01 C010 C011 C017 -118.0(10) . . . . ?
Rh01 C010 C018 C01D 121.9(11) . . . . ?
Rh01 C010 C018 C01F -61.5(7) . . . . ?
Rh01 C011 C014 C01F 60.5(7) . . . . ?
Rh01 C011 C014 C01K -120.7(11) . . . . ?
Rh01 C014 C01F C018 59.2(7) . . . . ?
Rh01 C014 C01F C01E -115.6(12) . . . . ?
Rh01 C018 C01F C014 -59.4(7) . . . . ?
Rh01 C018 C01F C01E 115.4(11) . . . . ?
Rh02 O005 C00J O004 167.8(6) . . . . ?
Rh02 O005 C00J C00K -13.4(7) . . . . ?
Rh02 O007 C00K O006 -165.6(6) . . . . ?
Rh02 O007 C00K C00J 14.6(8) . . . . ?
Rh02 N009 C00T N00B 172.0(5) . . . . ?
Rh02 N009 C00X C00Z -171.6(6) . . . . ?
Rh02 C016 C019 C01H 61.6(3) . . . . ?
Rh02 C016 C019 C7 -118.6(11) . . . . ?
Rh02 C016 C015 C013 -60.6(3) . . . . ?
Rh02 C016 C015 C2 116.2(10) . . . . ?
Rh02 C019 C01H C013 61.4(3) . . . . ?
Rh02 C019 C01H C10 -122.0(11) . . . . ?
Rh02 C01H C013 C015 60.3(3) . . . . ?
Rh02 C01H C013 C01G -118.2(8) . . . . ?
Rh02 C013 C015 C016 59.8(3) . . . . ?
Rh02 C013 C015 C2 -117.1(10) . . . . ?
O004 C00J C00K O006 -1.6(10) . . . . ?
O004 C00J C00K O007 178.2(7) . . . . ?
O005 C00J C00K O006 179.4(7) . . . . ?
O005 C00J C00K O007 -0.8(10) . . . . ?
N008 C00G C00O N00A -3.0(9) . . . . ?
N008 C00N C00U C00S 175.7(6) . . . . ?
N009 C00X C00Z N00B -1.5(10) . . . . ?
N00B C00R C00V C00Q 178.9(7) . . . . ?
C00C C00F C00H C00D 45.6(9) . . . . ?
C00C C00F C00H C00P -78.0(9) . . . 5_666 ?
C00C C00F C00Q C00V 0.6(12) . . . . ?
C00C C00I C00R N00B -177.4(7) . . . . ?
C00C C00I C00R C00V 1.2(12) . . . . ?
C00D C00E C00N N008 -178.0(6) . . . . ?
C00D C00E C00N C00U 1.7(11) . . . . ?
C00D C00M C00P C00C 45.1(9) . . . . ?
C00D C00M C00P C00H -76.9(8) . . . 5_666 ?
C00D C00M C00S C00U -2.2(11) . . . . ?
C00E C00D C00H C00F 136.7(7) . . . . ?
C00E C00D C00H C00P -99.7(8) . . . 5_666 ?
C00E C00D C00M C00P 178.0(6) . . . . ?
C00E C00D C00M C00S -0.2(10) . . . . ?
C00E C00N C00U C00S -4.0(11) . . . . ?
C00F C00C C00I C00R -1.9(12) . . . . ?
C00F C00C C00P C00H 78.7(8) . . . 5_666 ?
C00F C00C C00P C00M -44.2(9) . . . . ?
C00F C00Q C00V C00R -1.2(12) . . . . ?
C00G N008 C00N C00E -24.6(10) . . . . ?
C00G N008 C00N C00U 155.7(7) . . . . ?
C00G N008 C00W N00A -0.6(9) . . . . ?
C00H C00D C00E C00N 179.6(6) . . . . ?
C00H C00D C00M C00P -1.2(9) . . . . ?
C00H C00D C00M C00S -179.4(6) . . . . ?
C00H C00F C00Q C00V -177.1(7) . . . . ?
C00I C00C C00F C00H 178.8(7) . . . . ?
C00I C00C C00F C00Q 1.0(12) . . . . ?
C00I C00C C00P C00H -101.6(8) . . . 5_666 ?
C00I C00C C00P C00M 135.4(7) . . . . ?
C00I C00R C00V C00Q 0.3(12) . . . . ?
C00M C00D C00E C00N 0.5(10) . . . . ?
C00M C00D C00H C00F -44.1(8) . . . . ?
C00M C00D C00H C00P 79.4(7) . . . 5_666 ?
C00M C00S C00U C00N 4.2(11) . . . . ?
C00N N008 C00G C00O 174.4(7) . . . . ?
C00N N008 C00W N00A -172.7(7) . . . . ?
C00O N00A C00W N008 -1.3(9) . . . . ?
C00P C00C C00F C00H -1.5(11) . . . . ?
C00P C00C C00F C00Q -179.3(7) . . . . ?
C00P C00C C00I C00R 178.5(7) . . . . ?
C00P C00M C00S C00U 179.7(7) . . . . ?
C00Q C00F C00H C00D -136.7(8) . . . . ?
C00Q C00F C00H C00P 99.7(8) . . . 5_666 ?
C00R N00B C00T N009 -178.3(6) . . . . ?
C00R N00B C00Z C00X 179.6(7) . . . . ?
C00S C00M C00P C00C -136.7(7) . . . . ?
C00S C00M C00P C00H 101.3(8) . . . 5_666 ?
C00T N009 C00X C00Z 2.1(10) . . . . ?
C00T N00B C00R C00I 141.4(8) . . . . ?
C00T N00B C00R C00V -37.4(11) . . . . ?
C00T N00B C00Z C00X 0.2(9) . . . . ?
C00W N008 C00G C00O 2.2(9) . . . . ?
C00W N008 C00N C00E 146.2(8) . . . . ?
C00W N008 C00N C00U -33.6(11) . . . . ?
C00W N00A C00O C00G 2.7(9) . . . . ?
C00X N009 C00T N00B -2.0(9) . . . . ?
C00Y C010 C011 Rh01 123.5(9) . . . . ?
C00Y C010 C011 C014 -176.0(8) . . . . ?
C00Y C010 C011 C017 5.4(15) . . . . ?
C00Y C010 C018 Rh01 -122.8(9) . . . . ?
C00Y C010 C018 C01D -0.9(16) . . . . ?
C00Y C010 C018 C01F 175.7(8) . . . . ?
C00Z N00B C00R C00I -37.9(11) . . . . ?
C00Z N00B C00R C00V 143.4(9) . . . . ?
C00Z N00B C00T N009 1.1(9) . . . . ?
C010 C011 C014 Rh01 -60.6(6) . . . . ?
C010 C011 C014 C01F -0.2(11) . . . . ?
C010 C011 C014 C01K 178.6(10) . . . . ?
C010 C018 C01F Rh01 60.2(6) . . . . ?
C010 C018 C01F C014 0.8(11) . . . . ?
C010 C018 C01F C01E 175.6(10) . . . . ?
C011 C010 C018 Rh01 60.6(6) . . . . ?
C011 C010 C018 C01D -177.5(10) . . . . ?
C011 C010 C018 C01F -0.9(11) . . . . ?
C011 C014 C01F Rh01 -59.7(7) . . . . ?
C011 C014 C01F C018 -0.4(11) . . . . ?
C011 C014 C01F C01E -175.2(11) . . . . ?
C016 C019 C01H Rh02 -61.4(3) . . . . ?
C016 C019 C01H C013 0.0 . . . . ?
C016 C019 C01H C10 176.6(11) . . . . ?
C019 C016 C015 Rh02 60.6(3) . . . . ?
C019 C016 C015 C013 0.0 . . . . ?
C019 C016 C015 C2 176.8(11) . . . . ?
C019 C01H C013 Rh02 -60.3(3) . . . . ?
C019 C01H C013 C015 0.0 . . . . ?
C019 C01H C013 C01G -178.5(8) . . . . ?
C01H C013 C015 Rh02 -59.8(3) . . . . ?
C01H C013 C015 C016 0.0 . . . . ?
C01H C013 C015 C2 -177.0(10) . . . . ?
C015 C016 C019 Rh02 -61.6(3) . . . . ?
C015 C016 C019 C01H 0.0 . . . . ?
C015 C016 C019 C7 179.9(12) . . . . ?
C017 C011 C014 Rh01 117.9(10) . . . . ?
C017 C011 C014 C01F 178.4(9) . . . . ?
C017 C011 C014 C01K -2.8(16) . . . . ?
C018 C010 C011 Rh01 -59.9(6) . . . . ?
C018 C010 C011 C014 0.6(10) . . . . ?
C018 C010 C011 C017 -177.9(9) . . . . ?
C01D C018 C01F Rh01 -123.3(11) . . . . ?
C01D C018 C01F C014 177.3(10) . . . . ?
C01D C018 C01F C01E -7.8(18) . . . . ?
C01G C013 C015 Rh02 118.7(7) . . . . ?
C01G C013 C015 C016 178.6(8) . . . . ?
C01G C013 C015 C2 1.6(12) . . . . ?
C01K C014 C01F Rh01 121.6(11) . . . . ?
C01K C014 C01F C018 -179.1(10) . . . . ?
C01K C014 C01F C01E 6.1(19) . . . . ?
C7 C019 C01H Rh02 118.7(10) . . . . ?
C7 C019 C01H C013 -179.9(11) . . . . ?
C7 C019 C01H C10 -3.3(14) . . . . ?
C16 C016 C019 Rh02 116.4(9) . . . . ?
C16 C016 C019 C01H 178.0(10) . . . . ?
C16 C016 C019 C7 -2.1(14) . . . . ?
C16 C016 C015 Rh02 -117.4(9) . . . . ?
C16 C016 C015 C013 -178.1(10) . . . . ?
C16 C016 C015 C2 -1.2(13) . . . . ?
S1 C23 F9 F15 118.8(11) . . . 2_756 ?
S1 C23 F9 F43 -100.1(10) . . . 2_756 ?
S1 C23 F43 F15 -123(2) . . . 2_756 ?
S1 C23 F43 F9 91.8(9) . . . 2_756 ?
O7 S1 O7 O9 -55(3) 2_756 . . 2_756 ?
O7 S1 O9 O7 156(2) . . . 2_756 ?
O7 S1 C23 F15 -44.7(14) 2_756 . . . ?
O7 S1 C23 F15 135.3(14) . . . . ?
O7 S1 C23 F15 135.3(14) 2_756 . . 2_756 ?
O7 S1 C23 F15 -44.7(14) . . . 2_756 ?
O7 S1 C23 F9 63.9(11) . . . 2_756 ?
O7 S1 C23 F9 -116.1(11) 2_756 . . 2_756 ?
O7 S1 C23 F9 -116.1(11) . . . . ?
O7 S1 C23 F9 63.9(11) 2_756 . . . ?
O7 S1 C23 F43 -7.6(12) . . . . ?
O7 S1 C23 F43 172.4(12) 2_756 . . . ?
O7 S1 C23 F43 -7.6(12) 2_756 . . 2_756 ?
O7 S1 C23 F43 172.4(12) . . . 2_756 ?
O9 S1 O7 O9 -90(4) . . . 2_756 ?
O9 S1 O9 O7 116(3) 2_756 . . 2_756 ?
O9 S1 C23 F15 163.0(15) 2_756 . . . ?
O9 S1 C23 F15 163.0(15) . . . 2_756 ?
O9 S1 C23 F15 -17.0(15) 2_756 . . 2_756 ?
O9 S1 C23 F15 -17.0(15) . . . . ?
O9 S1 C23 F9 -88.4(12) 2_756 . . . ?
O9 S1 C23 F9 -88.4(12) . . . 2_756 ?
O9 S1 C23 F9 91.6(12) 2_756 . . 2_756 ?
O9 S1 C23 F9 91.6(12) . . . . ?
O9 S1 C23 F43 20.1(13) 2_756 . . . ?
O9 S1 C23 F43 -159.9(13) 2_756 . . 2_756 ?
O9 S1 C23 F43 -159.9(13) . . . . ?
O9 S1 C23 F43 20.1(13) . . . 2_756 ?
F15 C23 F9 F15 -120(2) . . . 2_756 ?
F15 C23 F9 F43 21.4(14) . . . 2_756 ?
F15 C23 F9 F43 141.0(16) 2_756 . . 2_756 ?
F15 C23 F43 F15 98(3) . . . 2_756 ?
F15 C23 F43 F9 -47.4(15) . . . 2_756 ?
F15 C23 F43 F9 -146(2) 2_756 . . 2_756 ?
C23 S1 O7 O9 125(3) . . . 2_756 ?
C23 S1 O9 O7 -64(3) . . . 2_756 ?
O33 S1 O7 O9 34(3) . . . 2_756 ?
O33 S1 O7 O9 -149(3) 2_756 . . 2_756 ?
O33 S1 O9 O7 31(3) . . . 2_756 ?
O33 S1 O9 O7 -146(3) 2_756 . . 2_756 ?
O33 S1 C23 F15 59.0(13) 2_756 . . . ?
O33 S1 C23 F15 59.1(13) . . . 2_756 ?
O33 S1 C23 F15 -120.9(13) 2_756 . . 2_756 ?
O33 S1 C23 F15 -121.0(13) . . . . ?
O33 S1 C23 F9 167.7(10) . . . 2_756 ?
O33 S1 C23 F9 -12.3(10) . . . . ?
O33 S1 C23 F9 -12.3(10) 2_756 . . 2_756 ?
O33 S1 C23 F9 167.7(10) 2_756 . . . ?
O33 S1 C23 F43 96.2(12) . . . . ?
O33 S1 C23 F43 96.2(12) 2_756 . . 2_756 ?
O33 S1 C23 F43 -83.8(12) . . . 2_756 ?
O33 S1 C23 F43 -83.8(12) 2_756 . . . ?
F9 F15 C23 S1 -85.6(10) 2_756 . . . ?
F9 F15 C23 F15 94.4(10) 2_756 . . 2_756 ?
F9 F15 C23 F9 170.3(17) 2_756 . . . ?
F9 F15 C23 F43 -156(2) 2_756 . . 2_756 ?
F9 F15 C23 F43 47.3(16) 2_756 . . . ?
F9 C23 F9 F15 -61.2(11) 2_756 . . 2_756 ?
F9 C23 F9 F43 79.9(10) 2_756 . . 2_756 ?
F9 C23 F43 F15 146(2) 2_756 . . 2_756 ?
F9 C23 F43 F15 -23(2) . . . 2_756 ?
F9 C23 F43 F9 -169(2) . . . 2_756 ?
F43 F15 C23 S1 71(2) 2_756 . . . ?
F43 F15 C23 F15 -109(2) 2_756 . . 2_756 ?
F43 F15 C23 F9 156(2) 2_756 . . 2_756 ?
F43 F15 C23 F9 -33(2) 2_756 . . . ?
F43 F15 C23 F43 -156(2) 2_756 . . . ?
F43 C23 F9 F15 15.3(15) . . . 2_756 ?
F43 C23 F9 F15 -141.0(16) 2_756 . . 2_756 ?
F43 C23 F9 F43 156(2) . . . 2_756 ?
F43 C23 F43 F15 57(2) 2_756 . . 2_756 ?
F43 C23 F43 F9 -88.2(9) 2_756 . . 2_756 ?
C10 C01H C013 Rh02 122.8(10) . . . . ?
C10 C01H C013 C015 -176.8(10) . . . . ?
C10 C01H C013 C01G 4.6(12) . . . . ?
O8 S0AA C27 F4 -78(3) . . . . ?
O8 S0AA C27 F14 178(2) . . . . ?
O8 S0AA C27 F0AA 69(3) . . . . ?
O16 S0AA C27 F4 35(3) . . . . ?
O16 S0AA C27 F14 -69(2) . . . . ?
O16 S0AA C27 F0AA -178(2) . . . . ?
O6 S0AA C27 F4 162(2) . . . . ?
O6 S0AA C27 F14 58(3) . . . . ?
O6 S0AA C27 F0AA -51(3) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_C94H102F12N10O22Rh4S4
_database_code_depnum_ccdc_archive 'CCDC 2165005'
loop_
_audit_author_name
_audit_author_address
'YingFeng Han'
;Northwest univeristy
China
;
_audit_update_record             
;
2022-04-07 deposited with the CCDC.	2022-05-10 downloaded from the CCDC.
;
_audit_creation_date             2022-04-07
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.06.28 svn.raecde09e for OlexSys, GUI svn.r6132)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         
'2(C42 H44 N4 O4 Rh2), 4(C F3 O3 S), 2(C3 H7 N O)'
_chemical_formula_sum            'C94 H102 F12 N10 O22 Rh4 S4'
_chemical_formula_weight         2491.73
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   23.3105(9)
_cell_length_b                   22.2812(8)
_cell_length_c                   22.7128(7)
_cell_angle_alpha                90
_cell_angle_beta                 100.3480(10)
_cell_angle_gamma                90
_cell_volume                     11604.8(7)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9339
_cell_measurement_temperature    199.99
_cell_measurement_theta_max      25.08
_cell_measurement_theta_min      2.29
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    0.716
_exptl_absorpt_correction_T_max  0.2590
_exptl_absorpt_correction_T_min  0.2224
_exptl_absorpt_correction_type   none
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1103 before and 0.0547 after correction.
The Ratio of minimum to maximum transmission is 0.8587.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear light yellow'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.426
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             5056
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.15
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0703
_diffrn_reflns_av_unetI/netI     0.0623
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_limit_h_max       28
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_k_min       -26
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            103665
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.366
_diffrn_reflns_theta_min         2.161
_diffrn_ambient_temperature      199.99
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           1.4
_diffrn_source_power             0.07
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                14057
_reflns_number_total             21199
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.38A (Bruker, 2018)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.38A (Bruker, 2018)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'olex2.solve 1.3 (Bourhis et al., 2015)'
_refine_diff_density_max         2.048
_refine_diff_density_min         -0.863
_refine_diff_density_rms         0.095
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.027
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1356
_refine_ls_number_reflns         21199
_refine_ls_number_restraints     199
_refine_ls_R_factor_all          0.0964
_refine_ls_R_factor_gt           0.0590
_refine_ls_restrained_S_all      1.065
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0806P)²+20.3665P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1476
_refine_ls_wR_factor_ref         0.1665
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 N9-C90 = N9-C89
 1.36 with sigma of 0.01
 C18-C13
 1.54 with sigma of 0.02
 S4-C88 = S5-C88
 1.8 with sigma of 0.02
 S4-O20 = S4-O19 = S5-O19 = S4-O18 = S5-O18 = S5-O21
 1.4 with sigma of 0.02
 F10-C88 \\sim F11-C88 \\sim F12-C88
 with sigma of 0.05
3. Rigid bond restraints
 F3, C86, C12
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.02
 C1, C2, C2, C3
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.02
 F10, C88
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.02
4. Uiso/Uaniso restraints and constraints
C89 \\sim N9 \\sim C90: within 2A with sigma of 0.01 and sigma for terminal
atoms of 0.02 within 2A
O23 \\sim C94 \\sim N10 \\sim C93 \\sim C92: within 2A with sigma of 0.01 and
sigma for terminal atoms of 0.02 within 2A
C85 \\sim F9 \\sim F7 \\sim F8: within 2A with sigma of 0.01 and sigma for
terminal atoms of 0.02 within 2A
C88 \\sim F10 \\sim F12 \\sim F11: within 2A with sigma of 0.01 and sigma for
terminal atoms of 0.02 within 2A
S5 \\sim S4 \\sim O18 \\sim O20 \\sim O19 \\sim O21: within 2A with sigma of
0.01 and sigma for terminal atoms of 0.02 within 2A
Uanis(C89) \\sim Ueq: with sigma of 0.005 and sigma for terminal atoms of 0.01
Uanis(O23) \\sim Ueq, Uanis(C94) \\sim Ueq, Uanis(C93) \\sim Ueq, Uanis(C92)
\\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(F7) \\sim Ueq, Uanis(C85) \\sim Ueq, Uanis(F9) \\sim Ueq, Uanis(F8) \\sim
Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(C88) \\sim Ueq: with sigma of 0.005 and sigma for terminal atoms of 0.01
Uanis(O21) \\sim Ueq: with sigma of 0.005 and sigma for terminal atoms of 0.01
5. Others
 Fixed Sof: S4(0.6) S5(0.4) O20(0.6) O21(0.4)
6.a Me refined with riding coordinates:
 C18(H18A,H18B,H18C)
6.b Aromatic/amide H refined with riding coordinates:
 C30(H30), C65(H65), C32(H32), C66(H66), C40(H40), C81(H81), C69(H69),
 C37(H37), C72(H72), C70(H70), C67(H67), C74(H74), C79(H79), C34(H34), C42(H42),
  C39(H39), C23(H23), C41(H41), C28(H28), C82(H82), C84(H84), C35(H35),
 C83(H83), C27(H27), C25(H25), C24(H24), C77(H77), C76(H76), C91(H91), C94(H94)
6.c Idealised Me refined as rotating group:
 C64(H64A,H64B,H64C), C62(H62A,H62B,H62C), C61(H61A,H61B,H61C), C63(H63A,H63B,
 H63C), C21(H21A,H21B,H21C), C60(H60A,H60B,H60C), C22(H22A,H22B,H22C), C54(H54A,
 H54B,H54C), C20(H20A,H20B,H20C), C53(H53A,H53B,H53C), C19(H19A,H19B,H19C),
 C51(H51A,H51B,H51C), C50(H50A,H50B,H50C), C90(H90A,H90B,H90C), C52(H52A,H52B,
 H52C), C10(H10A,H10B,H10C), C6(H6A,H6B,H6C), C8(H8A,H8B,H8C), C9(H9A,H9B,H9C),
 C7(H7A,H7B,H7C), C92(H92A,H92B,H92C), C93(H93A,H93B,H93C), C89(H89A,H89B,H89C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     iterative
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh3 Rh 0.39155(2) 0.61680(2) 0.48144(2) 0.03312(12) Uani 1 1 d . . . . .
Rh2 Rh -0.12558(2) 0.91584(2) 0.47648(2) 0.04015(13) Uani 1 1 d . . . . .
Rh4 Rh 0.49189(2) 0.64326(2) 0.71949(2) 0.04214(14) Uani 1 1 d . . . . .
Rh1 Rh -0.02834(2) 0.85815(2) 0.27887(2) 0.04879(15) Uani 1 1 d . . . . .
S3 S 0.70132(8) 0.74024(9) 0.47553(10) 0.0650(5) Uani 1 1 d . . . . .
S2 S 0.16207(9) 0.63950(13) 0.59354(10) 0.0817(7) Uani 1 1 d . . . . .
S1 S 0.26311(10) 0.84829(12) 0.44398(12) 0.0853(7) Uani 1 1 d . . . . .
O7 O 0.49569(18) 0.58573(17) 0.64482(16) 0.0426(10) Uani 1 1 d . . . . .
O5 O 0.37496(17) 0.65875(18) 0.56211(16) 0.0429(10) Uani 1 1 d . . . . .
O6 O 0.45683(17) 0.57726(17) 0.54860(16) 0.0402(9) Uani 1 1 d . . . . .
O8 O 0.41910(18) 0.67327(19) 0.65617(16) 0.0463(10) Uani 1 1 d . . . . .
O3 O -0.05549(17) 0.94117(18) 0.43305(17) 0.0443(10) Uani 1 1 d . . . . .
O2 O -0.01650(18) 0.91848(19) 0.35388(18) 0.0481(10) Uani 1 1 d . . . . .
N5 N 0.4511(2) 0.6886(2) 0.48149(19) 0.0365(11) Uani 1 1 d . . . . .
O4 O -0.14865(18) 0.87269(18) 0.39052(17) 0.0448(10) Uani 1 1 d . . . . .
O1 O -0.10658(18) 0.84472(18) 0.31404(18) 0.0478(10) Uani 1 1 d . . . . .
N6 N 0.4883(2) 0.7784(2) 0.47354(19) 0.0367(11) Uani 1 1 d . . . . .
N3 N 0.0605(2) 0.2611(2) 0.4869(2) 0.0392(11) Uani 1 1 d . . . . .
N4 N 0.0788(2) 0.1652(2) 0.5006(2) 0.0416(12) Uani 1 1 d . . . . .
O17 O 0.76008(19) 0.7518(2) 0.4687(2) 0.0704(14) Uani 1 1 d . . . . .
N8 N 0.4556(2) 1.2987(2) 0.3228(2) 0.0437(12) Uani 1 1 d . . . . .
N7 N 0.4211(2) 1.2184(2) 0.3604(2) 0.0423(12) Uani 1 1 d . . . . .
C31 C 0.0338(2) 0.4225(3) 0.4493(2) 0.0375(13) Uani 1 1 d . . . . .
N1 N 0.0103(2) 0.7929(2) 0.3410(2) 0.0479(13) Uani 1 1 d . . . . .
C33 C 0.0698(2) 0.3241(3) 0.4810(2) 0.0387(13) Uani 1 1 d . . . . .
N2 N 0.0257(2) 0.7054(2) 0.3862(2) 0.0459(12) Uani 1 1 d . . . . .
C68 C 0.4928(3) 0.8416(3) 0.4610(2) 0.0372(13) Uani 1 1 d . . . . .
C73 C 0.4608(2) 1.0605(3) 0.4063(2) 0.0363(13) Uani 1 1 d . . . . .
C30 C -0.0115(2) 0.4605(3) 0.4244(2) 0.0411(14) Uani 1 1 d . . . . .
H30 H -0.049371 0.444208 0.411560 0.049 Uiso 1 1 calc R U . . .
C65 C 0.4388(3) 0.7461(3) 0.4704(2) 0.0381(13) Uani 1 1 d . . . . .
H65 H 0.400566 0.762330 0.461524 0.046 Uiso 1 1 calc R U . . .
C43 C 0.4589(3) 0.6001(2) 0.5996(2) 0.0359(13) Uani 1 1 d . . . . .
C32 C 0.0254(3) 0.3599(3) 0.4557(2) 0.0405(14) Uani 1 1 d . . . . .
H32 H -0.011950 0.342875 0.441927 0.049 Uiso 1 1 calc R U . . .
C57 C 0.3711(3) 0.5332(3) 0.4358(3) 0.0423(14) Uani 1 1 d . . . . .
C44 C 0.4142(3) 0.6477(3) 0.6059(2) 0.0402(14) Uani 1 1 d . . . . .
C29 C -0.0028(2) 0.5221(3) 0.4177(2) 0.0391(13) Uani 1 1 d . . . . .
O16 O 0.6772(2) 0.7776(2) 0.5141(3) 0.0872(18) Uani 1 1 d . . . . .
C66 C 0.5106(3) 0.6844(3) 0.4923(3) 0.0465(15) Uani 1 1 d . . . . .
H66 H 0.532255 0.648394 0.501517 0.056 Uiso 1 1 calc R U . . .
C71 C 0.5051(2) 0.9628(3) 0.4328(2) 0.0379(13) Uani 1 1 d . . . . .
C58 C 0.3877(3) 0.5776(3) 0.3957(2) 0.0430(14) Uani 1 1 d . . . . .
C40 C 0.1022(3) 0.2184(3) 0.5013(2) 0.0417(14) Uani 1 1 d . . . . .
H40 H 0.142896 0.226190 0.510545 0.050 Uiso 1 1 calc R U . . .
C81 C 0.4450(3) 0.8769(3) 0.4523(2) 0.0410(14) Uani 1 1 d . . . . .
H81 H 0.408377 0.860562 0.456667 0.049 Uiso 1 1 calc R U . . .
C69 C 0.5490(3) 0.8651(3) 0.4574(2) 0.0390(13) Uani 1 1 d . . . . .
H69 H 0.582438 0.839975 0.464507 0.047 Uiso 1 1 calc R U . . .
C37 C 0.0997(2) 0.5085(3) 0.4621(2) 0.0413(14) Uani 1 1 d . . . . .
H37 H 0.137520 0.524873 0.475095 0.050 Uiso 1 1 calc R U . . .
C72 C 0.5093(3) 1.0237(3) 0.4175(2) 0.0404(14) Uani 1 1 d . . . . .
H72 H 0.546430 1.039885 0.414715 0.048 Uiso 1 1 calc R U . . .
C70 C 0.5537(3) 0.9241(3) 0.4435(2) 0.0421(14) Uani 1 1 d . . . . .
H70 H 0.591028 0.939760 0.440856 0.050 Uiso 1 1 calc R U . . .
C80 C 0.4489(3) 0.9388(2) 0.4367(2) 0.0372(13) Uani 1 1 d . . . . .
C36 C 0.0909(2) 0.4476(3) 0.4690(3) 0.0414(14) Uani 1 1 d . . . . .
C38 C 0.0539(2) 0.5467(3) 0.4362(2) 0.0392(13) Uani 1 1 d . . . . .
C12 C -0.0557(3) 0.9145(3) 0.3845(3) 0.0398(14) Uani 1 1 d . . . . .
C14 C -0.1306(3) 1.0016(3) 0.5179(3) 0.0556(18) Uani 1 1 d . . . . .
C78 C 0.4049(3) 1.0366(3) 0.4122(2) 0.0403(14) Uani 1 1 d . . . . .
C67 C 0.5337(3) 0.7393(3) 0.4878(3) 0.0495(16) Uani 1 1 d . . . . .
H67 H 0.574061 0.749005 0.493468 0.059 Uiso 1 1 calc R U . . .
C74 C 0.4648(3) 1.1218(3) 0.3900(2) 0.0423(14) Uani 1 1 d . . . . .
H74 H 0.501810 1.138149 0.386977 0.051 Uiso 1 1 calc R U . . .
C55 C 0.3053(3) 0.6123(3) 0.4295(3) 0.0458(15) Uani 1 1 d . . . . .
C79 C 0.4004(3) 0.9766(3) 0.4274(3) 0.0442(14) Uani 1 1 d . . . . .
H79 H 0.363453 0.960996 0.431693 0.053 Uiso 1 1 calc R U . . .
C26 C 0.0173(3) 0.6435(3) 0.4001(3) 0.0447(14) Uani 1 1 d . . . . .
C34 C 0.1262(3) 0.3487(3) 0.5015(3) 0.0451(15) Uani 1 1 d . . . . .
H34 H 0.157175 0.323480 0.519750 0.054 Uiso 1 1 calc R U . . .
C42 C 0.0194(3) 0.1732(3) 0.4857(3) 0.0530(17) Uani 1 1 d . . . . .
H42 H -0.008715 0.141976 0.481712 0.064 Uiso 1 1 calc R U . . .
C39 C 0.0627(3) 0.6089(3) 0.4266(3) 0.0430(14) Uani 1 1 d . . . . .
H39 H 0.100217 0.626186 0.438572 0.052 Uiso 1 1 calc R U . . .
F9 F 0.6523(2) 0.6509(2) 0.5192(4) 0.135(2) Uani 1 1 d . U . . .
C23 C -0.0106(3) 0.7387(3) 0.3458(3) 0.0479(15) Uani 1 1 d . . . . .
H23 H -0.046643 0.724699 0.323682 0.057 Uiso 1 1 calc R U . . .
C56 C 0.3212(3) 0.5555(3) 0.4579(3) 0.0420(14) Uani 1 1 d . . . . .
C41 C 0.0073(3) 0.2318(3) 0.4775(3) 0.0510(16) Uani 1 1 d . . . . .
H41 H -0.030257 0.249640 0.467387 0.061 Uiso 1 1 calc R U . . .
C28 C -0.0490(3) 0.5610(3) 0.3924(3) 0.0471(15) Uani 1 1 d . . . . .
H28 H -0.087343 0.545390 0.381357 0.057 Uiso 1 1 calc R U . . .
O14 O 0.3097(3) 0.8095(3) 0.4351(3) 0.104(2) Uani 1 1 d . . . . .
C11 C -0.1086(3) 0.8741(3) 0.3619(3) 0.0411(14) Uani 1 1 d . . . . .
C82 C 0.4632(3) 1.2405(3) 0.3322(3) 0.0456(15) Uani 1 1 d . . . . .
H82 H 0.493783 1.217506 0.320918 0.055 Uiso 1 1 calc R U . . .
C84 C 0.4067(3) 1.3146(3) 0.3455(3) 0.0475(15) Uani 1 1 d . . . . .
H84 H 0.390782 1.353883 0.344855 0.057 Uiso 1 1 calc R U . . .
C59 C 0.3453(3) 0.6254(3) 0.3913(2) 0.0423(14) Uani 1 1 d . . . . .
C35 C 0.1356(3) 0.4080(3) 0.4951(3) 0.0477(15) Uani 1 1 d . . . . .
H35 H 0.173659 0.423550 0.508508 0.057 Uiso 1 1 calc R U . . .
C83 C 0.3853(3) 1.2658(3) 0.3686(3) 0.0496(16) Uani 1 1 d . . . . .
H83 H 0.351827 1.264160 0.387020 0.060 Uiso 1 1 calc R U . . .
C27 C -0.0396(3) 0.6188(3) 0.3839(3) 0.0486(15) Uani 1 1 d . . . . .
H27 H -0.071107 0.643992 0.366730 0.058 Uiso 1 1 calc R U . . .
C13 C -0.1817(3) 0.9916(3) 0.4742(3) 0.0581(18) Uani 1 1 d D . . . .
F7 F 0.7241(3) 0.6279(2) 0.4756(4) 0.137(2) Uani 1 1 d . U . . .
C47 C 0.5476(3) 0.6332(4) 0.8032(3) 0.064(2) Uani 1 1 d . . . . .
C15 C -0.1262(3) 0.9544(3) 0.5614(3) 0.0592(18) Uani 1 1 d . . . . .
C45 C 0.4490(3) 0.6512(3) 0.7941(3) 0.0529(17) Uani 1 1 d . . . . .
C48 C 0.5181(4) 0.5784(3) 0.7881(3) 0.0587(19) Uani 1 1 d . . . . .
C75 C 0.4170(3) 1.1571(3) 0.3789(3) 0.0439(15) Uani 1 1 d . . . . .
F8 F 0.7407(3) 0.6689(4) 0.5616(4) 0.157(3) Uani 1 1 d . U . . .
C16 C -0.1768(3) 0.9167(3) 0.5459(3) 0.0551(17) Uani 1 1 d . . . . .
C25 C 0.0728(3) 0.7423(3) 0.4080(3) 0.0564(17) Uani 1 1 d . . . . .
H25 H 0.106033 0.731886 0.436823 0.068 Uiso 1 1 calc R U . . .
C24 C 0.0624(3) 0.7952(3) 0.3807(3) 0.0558(17) Uani 1 1 d . . . . .
H24 H 0.087154 0.829329 0.387579 0.067 Uiso 1 1 calc R U . . .
C49 C 0.4562(3) 0.5896(3) 0.7815(3) 0.0528(17) Uani 1 1 d . . . . .
C46 C 0.5052(3) 0.6783(3) 0.8077(3) 0.0585(19) Uani 1 1 d . . . . .
C64 C 0.3431(3) 0.6795(3) 0.3517(3) 0.065(2) Uani 1 1 d . . . . .
H64A H 0.326133 0.713295 0.370228 0.097 Uiso 1 1 calc R U . . .
H64B H 0.319129 0.670658 0.312678 0.097 Uiso 1 1 calc R U . . .
H64C H 0.382732 0.689889 0.346428 0.097 Uiso 1 1 calc R U . . .
C17 C -0.2104(3) 0.9392(3) 0.4916(3) 0.0557(17) Uani 1 1 d . . . . .
C77 C 0.3557(3) 1.0759(3) 0.4011(3) 0.0518(16) Uani 1 1 d . . . . .
H77 H 0.318326 1.061007 0.404823 0.062 Uiso 1 1 calc R U . . .
C62 C 0.4031(3) 0.4768(3) 0.4545(3) 0.0585(18) Uani 1 1 d . . . . .
H62A H 0.444558 0.482341 0.453082 0.088 Uiso 1 1 calc R U . . .
H62B H 0.387332 0.444275 0.427302 0.088 Uiso 1 1 calc R U . . .
H62C H 0.398624 0.466621 0.495369 0.088 Uiso 1 1 calc R U . . .
C5 C -0.0320(5) 0.8189(4) 0.1936(3) 0.078(2) Uani 1 1 d . . . . .
C3 C 0.0229(4) 0.9018(4) 0.2234(3) 0.065(2) Uani 1 1 d . U . . .
C4 C 0.0246(4) 0.8403(4) 0.2143(3) 0.071(2) Uani 1 1 d . . . . .
N9 N 0.3586(4) 0.8423(4) 0.6489(3) 0.108(3) Uani 1 1 d D U . . .
C61 C 0.2886(3) 0.5230(3) 0.4994(3) 0.066(2) Uani 1 1 d . . . . .
H61A H 0.315521 0.497111 0.526243 0.099 Uiso 1 1 calc R U . . .
H61B H 0.257813 0.498386 0.476002 0.099 Uiso 1 1 calc R U . . .
H61C H 0.271035 0.552206 0.523147 0.099 Uiso 1 1 calc R U . . .
F6 F 0.2699(3) 0.6257(4) 0.6456(4) 0.163(3) Uani 1 1 d . . . . .
O15 O 0.6606(3) 0.7309(4) 0.4191(3) 0.136(3) Uani 1 1 d . . . . .
F4 F 0.2235(3) 0.6922(5) 0.6858(3) 0.183(4) Uani 1 1 d . . . . .
C63 C 0.4367(3) 0.5722(4) 0.3625(3) 0.064(2) Uani 1 1 d . . . . .
H63A H 0.447583 0.612126 0.350210 0.096 Uiso 1 1 calc R U . . .
H63B H 0.424725 0.547088 0.326990 0.096 Uiso 1 1 calc R U . . .
H63C H 0.470238 0.553705 0.388399 0.096 Uiso 1 1 calc R U . . .
O22 O 0.4429(3) 0.8417(4) 0.7111(3) 0.133(3) Uani 1 1 d . . . . .
O9 O 0.1234(3) 0.6918(4) 0.5846(4) 0.142(3) Uani 1 1 d . . . . .
C21 C -0.1916(4) 0.8646(4) 0.5813(3) 0.076(2) Uani 1 1 d . . . . .
H21A H -0.217522 0.837255 0.555023 0.114 Uiso 1 1 calc R U . . .
H21B H -0.211344 0.878781 0.613312 0.114 Uiso 1 1 calc R U . . .
H21C H -0.155839 0.843283 0.598816 0.114 Uiso 1 1 calc R U . . .
O11 O 0.1778(3) 0.6164(5) 0.5428(3) 0.148(4) Uani 1 1 d . . . . .
O12 O 0.2148(3) 0.8217(4) 0.4628(4) 0.136(3) Uani 1 1 d . . . . .
C76 C 0.3614(3) 1.1346(3) 0.3853(3) 0.0523(16) Uani 1 1 d . . . . .
H76 H 0.328279 1.160196 0.378633 0.063 Uiso 1 1 calc R U . . .
C60 C 0.2554(3) 0.6507(3) 0.4391(3) 0.0640(19) Uani 1 1 d . . . . .
H60A H 0.249060 0.645884 0.480363 0.096 Uiso 1 1 calc R U . . .
H60B H 0.220215 0.638645 0.411280 0.096 Uiso 1 1 calc R U . . .
H60C H 0.264279 0.692818 0.432095 0.096 Uiso 1 1 calc R U . . .
C22 C -0.2660(3) 0.9131(4) 0.4578(4) 0.073(2) Uani 1 1 d . . . . .
H22A H -0.267207 0.918157 0.414705 0.110 Uiso 1 1 calc R U . . .
H22B H -0.299363 0.933906 0.469373 0.110 Uiso 1 1 calc R U . . .
H22C H -0.267887 0.870327 0.467140 0.110 Uiso 1 1 calc R U . . .
C1 C -0.0698(4) 0.8673(5) 0.1876(3) 0.084(3) Uani 1 1 d . U . . .
C54 C 0.4096(4) 0.5443(4) 0.7664(3) 0.078(2) Uani 1 1 d . . . . .
H54A H 0.375788 0.562506 0.740707 0.116 Uiso 1 1 calc R U . . .
H54B H 0.398029 0.529574 0.803260 0.116 Uiso 1 1 calc R U . . .
H54C H 0.423914 0.510677 0.745279 0.116 Uiso 1 1 calc R U . . .
O13 O 0.2816(4) 0.9052(4) 0.4717(4) 0.139(3) Uani 1 1 d . . . . .
C20 C -0.0795(4) 0.9490(4) 0.6153(3) 0.086(3) Uani 1 1 d . . . . .
H20A H -0.064811 0.907668 0.618608 0.129 Uiso 1 1 calc R U . . .
H20B H -0.095319 0.959241 0.651144 0.129 Uiso 1 1 calc R U . . .
H20C H -0.047481 0.976449 0.611519 0.129 Uiso 1 1 calc R U . . .
C53 C 0.5466(5) 0.5205(4) 0.7770(3) 0.098(3) Uani 1 1 d . . . . .
H53A H 0.519900 0.496865 0.747603 0.147 Uiso 1 1 calc R U . . .
H53B H 0.556084 0.498036 0.814512 0.147 Uiso 1 1 calc R U . . .
H53C H 0.582396 0.528740 0.761469 0.147 Uiso 1 1 calc R U . . .
F5 F 0.2525(3) 0.7092(4) 0.6047(4) 0.177(3) Uani 1 1 d . . . . .
C2 C -0.0381(4) 0.9205(4) 0.2069(3) 0.076(2) Uani 1 1 d . U . . .
C19 C -0.0883(3) 1.0508(4) 0.5156(4) 0.082(3) Uani 1 1 d . . . . .
H19A H -0.052497 1.042758 0.544370 0.124 Uiso 1 1 calc R U . . .
H19B H -0.105263 1.088854 0.525608 0.124 Uiso 1 1 calc R U . . .
H19C H -0.079152 1.053302 0.475165 0.124 Uiso 1 1 calc R U . . .
C51 C 0.5180(4) 0.7442(4) 0.8227(3) 0.085(3) Uani 1 1 d . . . . .
H51A H 0.554769 0.755594 0.810496 0.127 Uiso 1 1 calc R U . . .
H51B H 0.521172 0.750326 0.865843 0.127 Uiso 1 1 calc R U . . .
H51C H 0.486295 0.769041 0.801212 0.127 Uiso 1 1 calc R U . . .
C91 C 0.3948(5) 0.8584(4) 0.6979(4) 0.088(3) Uani 1 1 d . . . . .
H91 H 0.380733 0.885588 0.724270 0.106 Uiso 1 1 calc R U . . .
N10 N 0.7723(5) 0.7609(5) 0.7821(5) 0.140(3) Uani 1 1 d . U . . .
C50 C 0.3915(4) 0.6827(4) 0.7910(3) 0.082(3) Uani 1 1 d . . . . .
H50A H 0.361133 0.660710 0.764033 0.123 Uiso 1 1 calc R U . . .
H50B H 0.394426 0.723574 0.775782 0.123 Uiso 1 1 calc R U . . .
H50C H 0.381465 0.684469 0.831026 0.123 Uiso 1 1 calc R U . . .
C90 C 0.3726(4) 0.8065(4) 0.6029(4) 0.093(3) Uani 1 1 d D U . . .
H90A H 0.375670 0.831666 0.568297 0.140 Uiso 1 1 calc R U . . .
H90B H 0.341969 0.776347 0.591440 0.140 Uiso 1 1 calc R U . . .
H90C H 0.409896 0.786260 0.616873 0.140 Uiso 1 1 calc R U . . .
F1 F 0.2742(4) 0.9004(5) 0.3459(4) 0.198(4) Uani 1 1 d . . . . .
O10 O 0.1433(4) 0.5983(4) 0.6328(4) 0.155(4) Uani 1 1 d . . . . .
C52 C 0.6128(4) 0.6426(5) 0.8154(4) 0.097(3) Uani 1 1 d . . . . .
H52A H 0.631227 0.613745 0.792145 0.145 Uiso 1 1 calc R U . . .
H52B H 0.627841 0.636746 0.858183 0.145 Uiso 1 1 calc R U . . .
H52C H 0.621657 0.683534 0.803949 0.145 Uiso 1 1 calc R U . . .
F2 F 0.1880(4) 0.9102(5) 0.3730(5) 0.212(5) Uani 1 1 d . . . . .
C85 C 0.7052(4) 0.6678(5) 0.5099(6) 0.102(3) Uani 1 1 d . U . . .
C18 C -0.2025(4) 1.0307(4) 0.4204(4) 0.095(3) Uani 1 1 d D . . . .
H18A H -0.238678 1.014097 0.397473 0.142 Uiso 1 1 calc R U . . .
H18B H -0.209773 1.071407 0.433658 0.142 Uiso 1 1 calc R U . . .
H18C H -0.172652 1.031992 0.395060 0.142 Uiso 1 1 calc R U . . .
C10 C -0.0487(6) 0.7547(5) 0.1769(4) 0.128(4) Uani 1 1 d . . . . .
H10A H -0.027643 0.727562 0.207232 0.193 Uiso 1 1 calc R U . . .
H10B H -0.038642 0.745424 0.137868 0.193 Uiso 1 1 calc R U . . .
H10C H -0.090812 0.749612 0.174869 0.193 Uiso 1 1 calc R U . . .
F3 F 0.2134(4) 0.8294(7) 0.3361(4) 0.232(6) Uani 1 1 d . U . . .
C6 C -0.1356(5) 0.8648(7) 0.1673(4) 0.147(6) Uani 1 1 d . . . . .
H6A H -0.144649 0.849327 0.126297 0.221 Uiso 1 1 calc R U . . .
H6B H -0.152014 0.905186 0.168603 0.221 Uiso 1 1 calc R U . . .
H6C H -0.152668 0.838224 0.193959 0.221 Uiso 1 1 calc R U . . .
C8 C 0.0722(5) 0.9421(5) 0.2454(4) 0.105(4) Uani 1 1 d . . . . .
H8A H 0.093064 0.927510 0.284036 0.157 Uiso 1 1 calc R U . . .
H8B H 0.057453 0.982676 0.250211 0.157 Uiso 1 1 calc R U . . .
H8C H 0.098753 0.942945 0.216512 0.157 Uiso 1 1 calc R U . . .
C9 C 0.0792(5) 0.8019(5) 0.2245(4) 0.111(4) Uani 1 1 d . . . . .
H9A H 0.111405 0.824560 0.248016 0.167 Uiso 1 1 calc R U . . .
H9B H 0.089210 0.790879 0.185867 0.167 Uiso 1 1 calc R U . . .
H9C H 0.072174 0.765428 0.246329 0.167 Uiso 1 1 calc R U . . .
C7 C -0.0631(6) 0.9822(4) 0.2104(5) 0.126(4) Uani 1 1 d . . . . .
H7A H -0.099324 0.979490 0.226451 0.189 Uiso 1 1 calc R U . . .
H7B H -0.071276 0.999910 0.170292 0.189 Uiso 1 1 calc R U . . .
H7C H -0.035021 1.007355 0.236736 0.189 Uiso 1 1 calc R U . . .
C87 C 0.2291(5) 0.6666(7) 0.6369(6) 0.122(4) Uani 1 1 d . . . . .
C86 C 0.2336(5) 0.8720(9) 0.3700(7) 0.154(5) Uani 1 1 d . U . . .
C92 C 0.7627(7) 0.7756(7) 0.7205(7) 0.171(5) Uani 1 1 d . U . . .
H92A H 0.748354 0.816924 0.715036 0.257 Uiso 1 1 calc R U . . .
H92B H 0.733757 0.748133 0.698442 0.257 Uiso 1 1 calc R U . . .
H92C H 0.799411 0.771936 0.705486 0.257 Uiso 1 1 calc R U . . .
C94 C 0.8122(7) 0.7702(7) 0.8270(8) 0.165(4) Uani 1 1 d . U . . .
H94 H 0.813193 0.761521 0.868110 0.198 Uiso 1 1 calc R U . . .
O23 O 0.8589(5) 0.7998(6) 0.7955(7) 0.223(5) Uani 1 1 d . U . . .
C93 C 0.7298(8) 0.7274(9) 0.7963(8) 0.209(6) Uani 1 1 d . U . . .
H93A H 0.696350 0.752874 0.799950 0.313 Uiso 1 1 calc R U . . .
H93B H 0.743647 0.707101 0.834513 0.313 Uiso 1 1 calc R U . . .
H93C H 0.717932 0.697294 0.764981 0.313 Uiso 1 1 calc R U . . .
C89 C 0.3006(5) 0.8569(8) 0.6422(8) 0.205(6) Uani 1 1 d D U . . .
H89A H 0.290666 0.865321 0.681464 0.308 Uiso 1 1 calc R U . . .
H89B H 0.276952 0.823368 0.623446 0.308 Uiso 1 1 calc R U . . .
H89C H 0.292868 0.892605 0.616730 0.308 Uiso 1 1 calc R U . . .
S4 S 0.2854(3) 0.4915(3) 0.2929(3) 0.1212(16) Uani 0.6 1 d D U P . .
S5 S 0.3006(3) 0.4971(3) 0.2585(3) 0.0978(18) Uani 0.4 1 d D U P . .
O19 O 0.3410(3) 0.4572(3) 0.3111(3) 0.1002(18) Uani 1 1 d D U . . .
O18 O 0.2958(3) 0.5557(3) 0.2721(3) 0.116(2) Uani 1 1 d D U . . .
O20 O 0.2427(5) 0.4858(5) 0.3377(4) 0.111(4) Uani 0.6 1 d D U P . .
O21 O 0.3036(10) 0.4984(11) 0.1985(7) 0.117(6) Uani 0.4 1 d D U P . .
F12 F 0.2832(6) 0.4556(6) 0.1954(5) 0.230(5) Uani 1 1 d D U . . .
F11 F 0.2409(6) 0.4013(5) 0.2639(6) 0.264(5) Uani 1 1 d D U . . .
F10 F 0.1931(3) 0.4918(5) 0.2264(5) 0.215(4) Uani 1 1 d D U . . .
C88 C 0.2361(7) 0.4583(9) 0.2382(9) 0.234(6) Uani 1 1 d D U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh3 O5 2.153(4) . ?
Rh3 O6 2.141(4) . ?
Rh3 N5 2.119(5) . ?
Rh3 C57 2.144(6) . ?
Rh3 C58 2.120(5) . ?
Rh3 C55 2.142(6) . ?
Rh3 C56 2.126(6) . ?
Rh3 C59 2.145(6) . ?
Rh2 O3 2.131(4) . ?
Rh2 O4 2.156(4) . ?
Rh2 N4 2.125(5) 3_566 ?
Rh2 C14 2.142(6) . ?
Rh2 C13 2.131(7) . ?
Rh2 C15 2.115(6) . ?
Rh2 C16 2.143(6) . ?
Rh2 C17 2.131(6) . ?
Rh4 O7 2.140(4) . ?
Rh4 O8 2.126(4) . ?
Rh4 N8 2.125(5) 3_676 ?
Rh4 C47 2.112(6) . ?
Rh4 C45 2.125(6) . ?
Rh4 C48 2.131(6) . ?
Rh4 C49 2.128(6) . ?
Rh4 C46 2.120(6) . ?
Rh1 O2 2.149(4) . ?
Rh1 O1 2.139(4) . ?
Rh1 N1 2.112(5) . ?
Rh1 C5 2.113(7) . ?
Rh1 C3 2.122(7) . ?
Rh1 C4 2.116(7) . ?
Rh1 C1 2.134(7) . ?
Rh1 C2 2.126(7) . ?
S3 O17 1.429(5) . ?
S3 O16 1.398(5) . ?
S3 O15 1.466(6) . ?
S3 C85 1.789(11) . ?
S2 O9 1.465(8) . ?
S2 O11 1.372(7) . ?
S2 O10 1.404(8) . ?
S2 C87 1.795(12) . ?
S1 O14 1.430(6) . ?
S1 O12 1.406(7) . ?
S1 O13 1.447(8) . ?
S1 C86 1.777(14) . ?
O7 C43 1.255(6) . ?
O5 C44 1.248(7) . ?
O6 C43 1.258(6) . ?
O8 C44 1.263(7) . ?
O3 C12 1.251(7) . ?
O2 C12 1.249(7) . ?
N5 C65 1.327(7) . ?
N5 C66 1.368(7) . ?
O4 C11 1.231(7) . ?
O1 C11 1.277(7) . ?
N6 C68 1.444(7) . ?
N6 C65 1.350(7) . ?
N6 C67 1.365(7) . ?
N3 C33 1.433(7) . ?
N3 C40 1.357(7) . ?
N3 C41 1.384(7) . ?
N4 C40 1.302(7) . ?
N4 C42 1.377(8) . ?
N8 C82 1.321(7) . ?
N8 C84 1.377(8) . ?
N7 C82 1.356(8) . ?
N7 C83 1.380(8) . ?
N7 C75 1.437(7) . ?
C31 C30 1.393(8) . ?
C31 C32 1.421(8) . ?
C31 C36 1.439(8) . ?
N1 C23 1.314(8) . ?
N1 C24 1.377(8) . ?
C33 C32 1.350(8) . ?
C33 C34 1.422(8) . ?
N2 C26 1.437(8) . ?
N2 C23 1.353(8) . ?
N2 C25 1.390(8) . ?
C68 C81 1.348(8) . ?
C68 C69 1.426(8) . ?
C73 C72 1.384(8) . ?
C73 C78 1.435(8) . ?
C73 C74 1.421(8) . ?
C30 H30 0.9500 . ?
C30 C29 1.399(8) . ?
C65 H65 0.9500 . ?
C43 C44 1.513(8) . ?
C32 H32 0.9500 . ?
C57 C58 1.443(8) . ?
C57 C56 1.435(8) . ?
C57 C62 1.483(9) . ?
C29 C38 1.423(8) . ?
C29 C28 1.421(8) . ?
C66 H66 0.9500 . ?
C66 C67 1.349(8) . ?
C71 C72 1.409(8) . ?
C71 C70 1.409(8) . ?
C71 C80 1.431(8) . ?
C58 C59 1.445(9) . ?
C58 C63 1.484(8) . ?
C40 H40 0.9500 . ?
C81 H81 0.9500 . ?
C81 C80 1.431(8) . ?
C69 H69 0.9500 . ?
C69 C70 1.362(8) . ?
C37 H37 0.9500 . ?
C37 C36 1.385(8) . ?
C37 C38 1.410(8) . ?
C72 H72 0.9500 . ?
C70 H70 0.9500 . ?
C80 C79 1.396(8) . ?
C36 C35 1.412(8) . ?
C38 C39 1.424(8) . ?
C12 C11 1.537(8) . ?
C14 C13 1.425(9) . ?
C14 C15 1.434(10) . ?
C14 C19 1.481(10) . ?
C78 C79 1.389(8) . ?
C78 C77 1.429(9) . ?
C67 H67 0.9500 . ?
C74 H74 0.9500 . ?
C74 C75 1.352(8) . ?
C55 C56 1.439(8) . ?
C55 C59 1.414(8) . ?
C55 C60 1.490(9) . ?
C79 H79 0.9500 . ?
C26 C39 1.358(8) . ?
C26 C27 1.422(9) . ?
C34 H34 0.9500 . ?
C34 C35 1.351(9) . ?
C42 H42 0.9500 . ?
C42 C41 1.342(9) . ?
C39 H39 0.9500 . ?
F9 C85 1.342(10) . ?
C23 H23 0.9500 . ?
C56 C61 1.501(8) . ?
C41 H41 0.9500 . ?
C28 H28 0.9500 . ?
C28 C27 1.327(9) . ?
C82 H82 0.9500 . ?
C84 H84 0.9500 . ?
C84 C83 1.343(9) . ?
C59 C64 1.498(9) . ?
C35 H35 0.9500 . ?
C83 H83 0.9500 . ?
C27 H27 0.9500 . ?
C13 C17 1.436(9) . ?
C13 C18 1.507(10) . ?
F7 C85 1.310(12) . ?
C47 C48 1.413(11) . ?
C47 C46 1.426(10) . ?
C47 C52 1.510(11) . ?
C15 C16 1.439(9) . ?
C15 C20 1.491(10) . ?
C45 C49 1.419(9) . ?
C45 C46 1.425(10) . ?
C45 C50 1.503(10) . ?
C48 C49 1.445(10) . ?
C48 C53 1.493(10) . ?
C75 C76 1.421(9) . ?
F8 C85 1.309(13) . ?
C16 C17 1.428(10) . ?
C16 C21 1.488(10) . ?
C25 H25 0.9500 . ?
C25 C24 1.333(9) . ?
C24 H24 0.9500 . ?
C49 C54 1.478(10) . ?
C46 C51 1.526(10) . ?
C64 H64A 0.9800 . ?
C64 H64B 0.9800 . ?
C64 H64C 0.9800 . ?
C17 C22 1.502(9) . ?
C77 H77 0.9500 . ?
C77 C76 1.369(9) . ?
C62 H62A 0.9800 . ?
C62 H62B 0.9800 . ?
C62 H62C 0.9800 . ?
C5 C4 1.400(12) . ?
C5 C1 1.385(13) . ?
C5 C10 1.512(12) . ?
C3 C4 1.389(11) . ?
C3 C2 1.465(12) . ?
C3 C8 1.471(11) . ?
C4 C9 1.516(12) . ?
N9 C91 1.320(11) . ?
N9 C90 1.398(7) . ?
N9 C89 1.372(9) . ?
C61 H61A 0.9800 . ?
C61 H61B 0.9800 . ?
C61 H61C 0.9800 . ?
F6 C87 1.308(15) . ?
F4 C87 1.274(12) . ?
C63 H63A 0.9800 . ?
C63 H63B 0.9800 . ?
C63 H63C 0.9800 . ?
O22 C91 1.169(10) . ?
C21 H21A 0.9800 . ?
C21 H21B 0.9800 . ?
C21 H21C 0.9800 . ?
C76 H76 0.9500 . ?
C60 H60A 0.9800 . ?
C60 H60B 0.9800 . ?
C60 H60C 0.9800 . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C1 C2 1.424(12) . ?
C1 C6 1.522(13) . ?
C54 H54A 0.9800 . ?
C54 H54B 0.9800 . ?
C54 H54C 0.9800 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C53 H53A 0.9800 . ?
C53 H53B 0.9800 . ?
C53 H53C 0.9800 . ?
F5 C87 1.371(15) . ?
C2 C7 1.499(12) . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C51 H51A 0.9800 . ?
C51 H51B 0.9800 . ?
C51 H51C 0.9800 . ?
C91 H91 0.9500 . ?
N10 C92 1.413(16) . ?
N10 C94 1.268(16) . ?
N10 C93 1.327(16) . ?
C50 H50A 0.9800 . ?
C50 H50B 0.9800 . ?
C50 H50C 0.9800 . ?
C90 H90A 0.9800 . ?
C90 H90B 0.9800 . ?
C90 H90C 0.9800 . ?
F1 C86 1.334(15) . ?
C52 H52A 0.9800 . ?
C52 H52B 0.9800 . ?
C52 H52C 0.9800 . ?
F2 C86 1.373(18) . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
F3 C86 1.26(2) . ?
C6 H6A 0.9800 . ?
C6 H6B 0.9800 . ?
C6 H6C 0.9800 . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
C7 H7A 0.9800 . ?
C7 H7B 0.9800 . ?
C7 H7C 0.9800 . ?
C92 H92A 0.9800 . ?
C92 H92B 0.9800 . ?
C92 H92C 0.9800 . ?
C94 H94 0.9500 . ?
C94 O23 1.552(19) . ?
C93 H93A 0.9800 . ?
C93 H93B 0.9800 . ?
C93 H93C 0.9800 . ?
C89 H89A 0.9800 . ?
C89 H89B 0.9800 . ?
C89 H89C 0.9800 . ?
S4 S5 0.923(7) . ?
S4 O19 1.495(8) . ?
S4 O18 1.540(8) . ?
S4 O20 1.551(9) . ?
S4 C88 1.704(14) . ?
S5 O19 1.641(9) . ?
S5 O18 1.351(9) . ?
S5 O21 1.377(16) . ?
S5 C88 1.725(14) . ?
F12 C88 1.59(2) . ?
F11 C88 1.393(19) . ?
F10 C88 1.239(18) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O6 Rh3 O5 77.62(14) . . ?
O6 Rh3 C57 93.15(19) . . ?
O6 Rh3 C55 148.2(2) . . ?
O6 Rh3 C59 152.7(2) . . ?
N5 Rh3 O5 83.65(16) . . ?
N5 Rh3 O6 85.90(16) . . ?
N5 Rh3 C57 138.2(2) . . ?
N5 Rh3 C58 103.4(2) . . ?
N5 Rh3 C55 125.8(2) . . ?
N5 Rh3 C56 163.9(2) . . ?
N5 Rh3 C59 98.6(2) . . ?
C57 Rh3 O5 136.92(19) . . ?
C57 Rh3 C59 65.6(2) . . ?
C58 Rh3 O5 167.3(2) . . ?
C58 Rh3 O6 113.1(2) . . ?
C58 Rh3 C57 39.6(2) . . ?
C58 Rh3 C55 66.1(2) . . ?
C58 Rh3 C56 66.5(2) . . ?
C58 Rh3 C59 39.6(2) . . ?
C55 Rh3 O5 101.2(2) . . ?
C55 Rh3 C57 65.7(2) . . ?
C55 Rh3 C59 38.5(2) . . ?
C56 Rh3 O5 104.15(19) . . ?
C56 Rh3 O6 109.37(19) . . ?
C56 Rh3 C57 39.3(2) . . ?
C56 Rh3 C55 39.4(2) . . ?
C56 Rh3 C59 65.5(2) . . ?
C59 Rh3 O5 129.6(2) . . ?
O3 Rh2 O4 77.65(15) . . ?
O3 Rh2 C14 94.2(2) . . ?
O3 Rh2 C13 107.3(2) . . ?
O3 Rh2 C16 156.0(2) . . ?
O3 Rh2 C17 145.1(2) . . ?
N4 Rh2 O3 86.35(17) 3_566 . ?
N4 Rh2 O4 82.87(17) 3_566 . ?
N4 Rh2 C14 135.8(2) 3_566 . ?
N4 Rh2 C13 164.8(2) 3_566 . ?
N4 Rh2 C16 99.0(2) 3_566 . ?
N4 Rh2 C17 128.2(2) 3_566 . ?
C14 Rh2 O4 140.4(2) . . ?
C14 Rh2 C16 65.6(3) . . ?
C13 Rh2 O4 106.2(2) . . ?
C13 Rh2 C14 39.0(2) . . ?
C13 Rh2 C16 65.8(3) . . ?
C15 Rh2 O3 116.5(2) . . ?
C15 Rh2 O4 165.0(2) . . ?
C15 Rh2 N4 102.1(2) . 3_566 ?
C15 Rh2 C14 39.4(3) . . ?
C15 Rh2 C13 66.1(3) . . ?
C15 Rh2 C16 39.5(3) . . ?
C15 Rh2 C17 66.1(3) . . ?
C16 Rh2 O4 126.1(2) . . ?
C17 Rh2 O4 99.7(2) . . ?
C17 Rh2 C14 65.5(3) . . ?
C17 Rh2 C13 39.4(3) . . ?
C17 Rh2 C16 39.0(3) . . ?
O8 Rh4 O7 78.10(15) . . ?
O8 Rh4 C48 142.8(3) . . ?
O8 Rh4 C49 105.4(2) . . ?
N8 Rh4 O7 84.11(17) 3_676 . ?
N8 Rh4 O8 87.58(17) 3_676 . ?
N8 Rh4 C45 134.6(2) 3_676 . ?
N8 Rh4 C48 129.0(3) 3_676 . ?
N8 Rh4 C49 165.2(2) 3_676 . ?
C47 Rh4 O7 122.9(2) . . ?
C47 Rh4 O8 158.3(2) . . ?
C47 Rh4 N8 99.2(3) . 3_676 ?
C47 Rh4 C45 66.0(3) . . ?
C47 Rh4 C48 38.9(3) . . ?
C47 Rh4 C49 66.1(3) . . ?
C47 Rh4 C46 39.4(3) . . ?
C45 Rh4 O7 140.7(2) . . ?
C45 Rh4 O8 94.6(2) . . ?
C45 Rh4 C48 65.6(3) . . ?
C45 Rh4 C49 39.0(2) . . ?
C48 Rh4 O7 97.2(2) . . ?
C49 Rh4 O7 105.3(2) . . ?
C49 Rh4 C48 39.7(3) . . ?
C46 Rh4 O7 161.7(2) . . ?
C46 Rh4 O8 119.1(2) . . ?
C46 Rh4 N8 101.8(2) . 3_676 ?
C46 Rh4 C45 39.2(3) . . ?
C46 Rh4 C48 65.4(3) . . ?
C46 Rh4 C49 65.8(3) . . ?
O1 Rh1 O2 77.77(15) . . ?
N1 Rh1 O2 85.54(18) . . ?
N1 Rh1 O1 86.78(18) . . ?
N1 Rh1 C5 105.6(3) . . ?
N1 Rh1 C3 119.6(3) . . ?
N1 Rh1 C4 95.8(3) . . ?
N1 Rh1 C1 141.2(3) . . ?
N1 Rh1 C2 159.7(3) . . ?
C5 Rh1 O2 164.6(3) . . ?
C5 Rh1 O1 112.8(3) . . ?
C5 Rh1 C3 65.2(3) . . ?
C5 Rh1 C4 38.7(3) . . ?
C5 Rh1 C1 38.1(3) . . ?
C5 Rh1 C2 65.5(3) . . ?
C3 Rh1 O2 100.2(2) . . ?
C3 Rh1 O1 153.4(3) . . ?
C3 Rh1 C1 65.5(3) . . ?
C3 Rh1 C2 40.3(3) . . ?
C4 Rh1 O2 131.3(3) . . ?
C4 Rh1 O1 150.9(3) . . ?
C4 Rh1 C3 38.3(3) . . ?
C4 Rh1 C1 64.2(4) . . ?
C4 Rh1 C2 65.5(3) . . ?
C1 Rh1 O2 132.9(3) . . ?
C1 Rh1 O1 96.2(3) . . ?
C2 Rh1 O2 100.4(3) . . ?
C2 Rh1 O1 113.4(3) . . ?
C2 Rh1 C1 39.1(3) . . ?
O17 S3 O15 114.4(4) . . ?
O17 S3 C85 103.6(4) . . ?
O16 S3 O17 117.5(3) . . ?
O16 S3 O15 111.3(4) . . ?
O16 S3 C85 105.0(5) . . ?
O15 S3 C85 103.2(6) . . ?
O9 S2 C87 105.1(6) . . ?
O11 S2 O9 115.7(6) . . ?
O11 S2 O10 116.7(6) . . ?
O11 S2 C87 104.5(5) . . ?
O10 S2 O9 110.7(6) . . ?
O10 S2 C87 102.2(6) . . ?
O14 S1 O13 114.6(5) . . ?
O14 S1 C86 102.8(7) . . ?
O12 S1 O14 117.2(5) . . ?
O12 S1 O13 115.5(5) . . ?
O12 S1 C86 102.6(6) . . ?
O13 S1 C86 100.7(8) . . ?
C43 O7 Rh4 112.1(4) . . ?
C44 O5 Rh3 112.0(4) . . ?
C43 O6 Rh3 113.2(3) . . ?
C44 O8 Rh4 113.7(4) . . ?
C12 O3 Rh2 113.5(4) . . ?
C12 O2 Rh1 113.3(4) . . ?
C65 N5 Rh3 127.6(4) . . ?
C65 N5 C66 106.2(5) . . ?
C66 N5 Rh3 126.2(4) . . ?
C11 O4 Rh2 112.2(4) . . ?
C11 O1 Rh1 114.2(4) . . ?
C65 N6 C68 126.9(5) . . ?
C65 N6 C67 106.9(5) . . ?
C67 N6 C68 126.1(5) . . ?
C40 N3 C33 126.6(5) . . ?
C40 N3 C41 106.9(5) . . ?
C41 N3 C33 126.4(5) . . ?
C40 N4 Rh2 125.1(4) . 3_566 ?
C40 N4 C42 106.6(5) . . ?
C42 N4 Rh2 128.3(4) . 3_566 ?
C82 N8 Rh4 126.8(4) . 3_676 ?
C82 N8 C84 106.8(5) . . ?
C84 N8 Rh4 126.5(4) . 3_676 ?
C82 N7 C83 107.0(5) . . ?
C82 N7 C75 125.2(5) . . ?
C83 N7 C75 127.8(5) . . ?
C30 C31 C32 122.0(5) . . ?
C30 C31 C36 118.9(5) . . ?
C32 C31 C36 119.1(5) . . ?
C23 N1 Rh1 124.6(4) . . ?
C23 N1 C24 106.1(5) . . ?
C24 N1 Rh1 129.1(4) . . ?
C32 C33 N3 120.1(5) . . ?
C32 C33 C34 120.3(6) . . ?
C34 C33 N3 119.6(5) . . ?
C23 N2 C26 125.7(5) . . ?
C23 N2 C25 105.9(5) . . ?
C25 N2 C26 128.3(5) . . ?
C81 C68 N6 120.7(5) . . ?
C81 C68 C69 121.4(5) . . ?
C69 C68 N6 117.9(5) . . ?
C72 C73 C78 119.2(5) . . ?
C72 C73 C74 121.8(5) . . ?
C74 C73 C78 119.0(5) . . ?
C31 C30 H30 119.1 . . ?
C31 C30 C29 121.7(5) . . ?
C29 C30 H30 119.1 . . ?
N5 C65 N6 110.6(5) . . ?
N5 C65 H65 124.7 . . ?
N6 C65 H65 124.7 . . ?
O7 C43 O6 123.9(5) . . ?
O7 C43 C44 118.9(5) . . ?
O6 C43 C44 117.2(5) . . ?
C31 C32 H32 119.5 . . ?
C33 C32 C31 120.9(5) . . ?
C33 C32 H32 119.5 . . ?
C58 C57 Rh3 69.3(3) . . ?
C58 C57 C62 125.6(6) . . ?
C56 C57 Rh3 69.7(3) . . ?
C56 C57 C58 108.0(5) . . ?
C56 C57 C62 126.2(6) . . ?
C62 C57 Rh3 122.7(4) . . ?
O5 C44 O8 124.5(5) . . ?
O5 C44 C43 118.8(5) . . ?
O8 C44 C43 116.7(5) . . ?
C30 C29 C38 119.4(5) . . ?
C30 C29 C28 121.9(5) . . ?
C28 C29 C38 118.7(6) . . ?
N5 C66 H66 125.4 . . ?
C67 C66 N5 109.2(5) . . ?
C67 C66 H66 125.4 . . ?
C72 C71 C70 122.8(5) . . ?
C72 C71 C80 118.7(5) . . ?
C70 C71 C80 118.5(5) . . ?
C57 C58 Rh3 71.1(3) . . ?
C57 C58 C59 107.0(5) . . ?
C57 C58 C63 125.7(6) . . ?
C59 C58 Rh3 71.1(3) . . ?
C59 C58 C63 127.2(6) . . ?
C63 C58 Rh3 126.2(4) . . ?
N3 C40 H40 124.6 . . ?
N4 C40 N3 110.8(5) . . ?
N4 C40 H40 124.6 . . ?
C68 C81 H81 119.6 . . ?
C68 C81 C80 120.7(6) . . ?
C80 C81 H81 119.6 . . ?
C68 C69 H69 120.6 . . ?
C70 C69 C68 118.7(5) . . ?
C70 C69 H69 120.6 . . ?
C36 C37 H37 119.3 . . ?
C36 C37 C38 121.4(5) . . ?
C38 C37 H37 119.3 . . ?
C73 C72 C71 121.7(5) . . ?
C73 C72 H72 119.1 . . ?
C71 C72 H72 119.1 . . ?
C71 C70 H70 118.8 . . ?
C69 C70 C71 122.3(6) . . ?
C69 C70 H70 118.8 . . ?
C71 C80 C81 118.4(5) . . ?
C79 C80 C71 119.4(5) . . ?
C79 C80 C81 122.2(5) . . ?
C37 C36 C31 119.5(5) . . ?
C37 C36 C35 123.1(6) . . ?
C35 C36 C31 117.4(6) . . ?
C29 C38 C39 118.8(5) . . ?
C37 C38 C29 119.0(5) . . ?
C37 C38 C39 122.2(5) . . ?
O3 C12 C11 116.7(5) . . ?
O2 C12 O3 124.7(5) . . ?
O2 C12 C11 118.6(5) . . ?
C13 C14 Rh2 70.1(4) . . ?
C13 C14 C15 108.2(6) . . ?
C13 C14 C19 124.7(7) . . ?
C15 C14 Rh2 69.3(4) . . ?
C15 C14 C19 127.0(7) . . ?
C19 C14 Rh2 123.8(5) . . ?
C79 C78 C73 119.4(6) . . ?
C79 C78 C77 122.6(6) . . ?
C77 C78 C73 118.0(5) . . ?
N6 C67 H67 126.5 . . ?
C66 C67 N6 107.1(5) . . ?
C66 C67 H67 126.5 . . ?
C73 C74 H74 119.5 . . ?
C75 C74 C73 121.1(6) . . ?
C75 C74 H74 119.5 . . ?
C56 C55 Rh3 69.7(3) . . ?
C56 C55 C60 125.8(6) . . ?
C59 C55 Rh3 70.8(3) . . ?
C59 C55 C56 108.1(5) . . ?
C59 C55 C60 126.1(6) . . ?
C60 C55 Rh3 124.9(5) . . ?
C80 C79 H79 119.3 . . ?
C78 C79 C80 121.5(6) . . ?
C78 C79 H79 119.3 . . ?
C39 C26 N2 121.1(6) . . ?
C39 C26 C27 120.8(6) . . ?
C27 C26 N2 118.1(5) . . ?
C33 C34 H34 120.0 . . ?
C35 C34 C33 120.0(6) . . ?
C35 C34 H34 120.0 . . ?
N4 C42 H42 125.1 . . ?
C41 C42 N4 109.8(6) . . ?
C41 C42 H42 125.1 . . ?
C38 C39 H39 120.1 . . ?
C26 C39 C38 119.9(6) . . ?
C26 C39 H39 120.1 . . ?
N1 C23 N2 111.3(6) . . ?
N1 C23 H23 124.3 . . ?
N2 C23 H23 124.3 . . ?
C57 C56 Rh3 71.0(3) . . ?
C57 C56 C55 108.0(5) . . ?
C57 C56 C61 125.9(6) . . ?
C55 C56 Rh3 70.9(3) . . ?
C55 C56 C61 125.9(6) . . ?
C61 C56 Rh3 127.4(5) . . ?
N3 C41 H41 127.0 . . ?
C42 C41 N3 105.9(5) . . ?
C42 C41 H41 127.0 . . ?
C29 C28 H28 119.4 . . ?
C27 C28 C29 121.2(6) . . ?
C27 C28 H28 119.4 . . ?
O4 C11 O1 125.7(6) . . ?
O4 C11 C12 118.5(5) . . ?
O1 C11 C12 115.8(5) . . ?
N8 C82 N7 110.2(6) . . ?
N8 C82 H82 124.9 . . ?
N7 C82 H82 124.9 . . ?
N8 C84 H84 125.4 . . ?
C83 C84 N8 109.2(6) . . ?
C83 C84 H84 125.4 . . ?
C58 C59 Rh3 69.3(3) . . ?
C58 C59 C64 125.7(6) . . ?
C55 C59 Rh3 70.7(3) . . ?
C55 C59 C58 108.8(5) . . ?
C55 C59 C64 125.5(6) . . ?
C64 C59 Rh3 127.0(4) . . ?
C36 C35 H35 118.9 . . ?
C34 C35 C36 122.3(6) . . ?
C34 C35 H35 118.9 . . ?
N7 C83 H83 126.6 . . ?
C84 C83 N7 106.9(6) . . ?
C84 C83 H83 126.6 . . ?
C26 C27 H27 119.7 . . ?
C28 C27 C26 120.5(6) . . ?
C28 C27 H27 119.7 . . ?
C14 C13 Rh2 70.9(4) . . ?
C14 C13 C17 107.8(6) . . ?
C14 C13 C18 125.6(7) . . ?
C17 C13 Rh2 70.3(4) . . ?
C17 C13 C18 126.5(7) . . ?
C18 C13 Rh2 125.8(6) . . ?
C48 C47 Rh4 71.3(4) . . ?
C48 C47 C46 108.2(7) . . ?
C48 C47 C52 126.5(8) . . ?
C46 C47 Rh4 70.6(4) . . ?
C46 C47 C52 125.3(8) . . ?
C52 C47 Rh4 126.0(5) . . ?
C14 C15 Rh2 71.3(4) . . ?
C14 C15 C16 107.8(6) . . ?
C14 C15 C20 125.2(7) . . ?
C16 C15 Rh2 71.3(4) . . ?
C16 C15 C20 126.8(7) . . ?
C20 C15 Rh2 126.3(5) . . ?
C49 C45 Rh4 70.6(4) . . ?
C49 C45 C46 108.4(6) . . ?
C49 C45 C50 125.5(7) . . ?
C46 C45 Rh4 70.2(4) . . ?
C46 C45 C50 126.1(7) . . ?
C50 C45 Rh4 123.0(5) . . ?
C47 C48 Rh4 69.8(4) . . ?
C47 C48 C49 108.1(6) . . ?
C47 C48 C53 125.1(8) . . ?
C49 C48 Rh4 70.0(3) . . ?
C49 C48 C53 126.6(8) . . ?
C53 C48 Rh4 122.7(4) . . ?
C74 C75 N7 120.7(6) . . ?
C74 C75 C76 120.8(6) . . ?
C76 C75 N7 118.4(6) . . ?
C15 C16 Rh2 69.2(4) . . ?
C15 C16 C21 125.7(7) . . ?
C17 C16 Rh2 70.0(4) . . ?
C17 C16 C15 107.6(6) . . ?
C17 C16 C21 126.6(7) . . ?
C21 C16 Rh2 127.2(5) . . ?
N2 C25 H25 126.5 . . ?
C24 C25 N2 107.0(6) . . ?
C24 C25 H25 126.5 . . ?
N1 C24 H24 125.2 . . ?
C25 C24 N1 109.6(6) . . ?
C25 C24 H24 125.2 . . ?
C45 C49 Rh4 70.4(4) . . ?
C45 C49 C48 107.3(6) . . ?
C45 C49 C54 126.8(7) . . ?
C48 C49 Rh4 70.3(4) . . ?
C48 C49 C54 125.9(7) . . ?
C54 C49 Rh4 126.1(4) . . ?
C47 C46 Rh4 70.0(4) . . ?
C47 C46 C51 125.7(8) . . ?
C45 C46 Rh4 70.6(3) . . ?
C45 C46 C47 108.0(7) . . ?
C45 C46 C51 126.3(7) . . ?
C51 C46 Rh4 123.6(5) . . ?
C59 C64 H64A 109.5 . . ?
C59 C64 H64B 109.5 . . ?
C59 C64 H64C 109.5 . . ?
H64A C64 H64B 109.5 . . ?
H64A C64 H64C 109.5 . . ?
H64B C64 H64C 109.5 . . ?
C13 C17 Rh2 70.3(4) . . ?
C13 C17 C22 125.1(7) . . ?
C16 C17 Rh2 70.9(4) . . ?
C16 C17 C13 108.4(6) . . ?
C16 C17 C22 126.5(7) . . ?
C22 C17 Rh2 124.3(5) . . ?
C78 C77 H77 119.4 . . ?
C76 C77 C78 121.2(6) . . ?
C76 C77 H77 119.4 . . ?
C57 C62 H62A 109.5 . . ?
C57 C62 H62B 109.5 . . ?
C57 C62 H62C 109.5 . . ?
H62A C62 H62B 109.5 . . ?
H62A C62 H62C 109.5 . . ?
H62B C62 H62C 109.5 . . ?
C4 C5 Rh1 70.8(4) . . ?
C4 C5 C10 126.2(10) . . ?
C1 C5 Rh1 71.8(5) . . ?
C1 C5 C4 108.2(8) . . ?
C1 C5 C10 125.5(10) . . ?
C10 C5 Rh1 125.9(6) . . ?
C4 C3 Rh1 70.6(4) . . ?
C4 C3 C2 107.1(7) . . ?
C4 C3 C8 127.8(9) . . ?
C2 C3 Rh1 70.0(4) . . ?
C2 C3 C8 125.1(8) . . ?
C8 C3 Rh1 124.5(5) . . ?
C5 C4 Rh1 70.5(4) . . ?
C5 C4 C9 125.0(9) . . ?
C3 C4 Rh1 71.1(4) . . ?
C3 C4 C5 109.7(8) . . ?
C3 C4 C9 125.4(9) . . ?
C9 C4 Rh1 125.3(6) . . ?
C91 N9 C90 125.9(8) . . ?
C91 N9 C89 119.8(10) . . ?
C89 N9 C90 114.2(10) . . ?
C56 C61 H61A 109.5 . . ?
C56 C61 H61B 109.5 . . ?
C56 C61 H61C 109.5 . . ?
H61A C61 H61B 109.5 . . ?
H61A C61 H61C 109.5 . . ?
H61B C61 H61C 109.5 . . ?
C58 C63 H63A 109.5 . . ?
C58 C63 H63B 109.5 . . ?
C58 C63 H63C 109.5 . . ?
H63A C63 H63B 109.5 . . ?
H63A C63 H63C 109.5 . . ?
H63B C63 H63C 109.5 . . ?
C16 C21 H21A 109.5 . . ?
C16 C21 H21B 109.5 . . ?
C16 C21 H21C 109.5 . . ?
H21A C21 H21B 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C75 C76 H76 120.1 . . ?
C77 C76 C75 119.8(6) . . ?
C77 C76 H76 120.1 . . ?
C55 C60 H60A 109.5 . . ?
C55 C60 H60B 109.5 . . ?
C55 C60 H60C 109.5 . . ?
H60A C60 H60B 109.5 . . ?
H60A C60 H60C 109.5 . . ?
H60B C60 H60C 109.5 . . ?
C17 C22 H22A 109.5 . . ?
C17 C22 H22B 109.5 . . ?
C17 C22 H22C 109.5 . . ?
H22A C22 H22B 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C5 C1 Rh1 70.1(4) . . ?
C5 C1 C2 109.4(8) . . ?
C5 C1 C6 126.2(11) . . ?
C2 C1 Rh1 70.2(4) . . ?
C2 C1 C6 124.4(11) . . ?
C6 C1 Rh1 123.2(6) . . ?
C49 C54 H54A 109.5 . . ?
C49 C54 H54B 109.5 . . ?
C49 C54 H54C 109.5 . . ?
H54A C54 H54B 109.5 . . ?
H54A C54 H54C 109.5 . . ?
H54B C54 H54C 109.5 . . ?
C15 C20 H20A 109.5 . . ?
C15 C20 H20B 109.5 . . ?
C15 C20 H20C 109.5 . . ?
H20A C20 H20B 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C48 C53 H53A 109.5 . . ?
C48 C53 H53B 109.5 . . ?
C48 C53 H53C 109.5 . . ?
H53A C53 H53B 109.5 . . ?
H53A C53 H53C 109.5 . . ?
H53B C53 H53C 109.5 . . ?
C3 C2 Rh1 69.7(4) . . ?
C3 C2 C7 128.0(9) . . ?
C1 C2 Rh1 70.7(4) . . ?
C1 C2 C3 105.6(7) . . ?
C1 C2 C7 126.4(10) . . ?
C7 C2 Rh1 123.2(6) . . ?
C14 C19 H19A 109.5 . . ?
C14 C19 H19B 109.5 . . ?
C14 C19 H19C 109.5 . . ?
H19A C19 H19B 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C46 C51 H51A 109.5 . . ?
C46 C51 H51B 109.5 . . ?
C46 C51 H51C 109.5 . . ?
H51A C51 H51B 109.5 . . ?
H51A C51 H51C 109.5 . . ?
H51B C51 H51C 109.5 . . ?
N9 C91 H91 117.7 . . ?
O22 C91 N9 124.6(9) . . ?
O22 C91 H91 117.7 . . ?
C94 N10 C92 136.1(14) . . ?
C94 N10 C93 111.6(15) . . ?
C93 N10 C92 112.3(13) . . ?
C45 C50 H50A 109.5 . . ?
C45 C50 H50B 109.5 . . ?
C45 C50 H50C 109.5 . . ?
H50A C50 H50B 109.5 . . ?
H50A C50 H50C 109.5 . . ?
H50B C50 H50C 109.5 . . ?
N9 C90 H90A 109.5 . . ?
N9 C90 H90B 109.5 . . ?
N9 C90 H90C 109.5 . . ?
H90A C90 H90B 109.5 . . ?
H90A C90 H90C 109.5 . . ?
H90B C90 H90C 109.5 . . ?
C47 C52 H52A 109.5 . . ?
C47 C52 H52B 109.5 . . ?
C47 C52 H52C 109.5 . . ?
H52A C52 H52B 109.5 . . ?
H52A C52 H52C 109.5 . . ?
H52B C52 H52C 109.5 . . ?
F9 C85 S3 110.2(7) . . ?
F7 C85 S3 110.4(8) . . ?
F7 C85 F9 108.7(9) . . ?
F8 C85 S3 110.4(8) . . ?
F8 C85 F9 108.4(10) . . ?
F8 C85 F7 108.7(9) . . ?
C13 C18 H18A 109.5 . . ?
C13 C18 H18B 109.5 . . ?
C13 C18 H18C 109.5 . . ?
H18A C18 H18B 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C5 C10 H10A 109.5 . . ?
C5 C10 H10B 109.5 . . ?
C5 C10 H10C 109.5 . . ?
H10A C10 H10B 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
C1 C6 H6A 109.5 . . ?
C1 C6 H6B 109.5 . . ?
C1 C6 H6C 109.5 . . ?
H6A C6 H6B 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
C3 C8 H8A 109.5 . . ?
C3 C8 H8B 109.5 . . ?
C3 C8 H8C 109.5 . . ?
H8A C8 H8B 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
C4 C9 H9A 109.5 . . ?
C4 C9 H9B 109.5 . . ?
C4 C9 H9C 109.5 . . ?
H9A C9 H9B 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
C2 C7 H7A 109.5 . . ?
C2 C7 H7B 109.5 . . ?
C2 C7 H7C 109.5 . . ?
H7A C7 H7B 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
F6 C87 S2 112.7(9) . . ?
F6 C87 F5 102.4(9) . . ?
F4 C87 S2 114.4(8) . . ?
F4 C87 F6 111.5(14) . . ?
F4 C87 F5 105.5(12) . . ?
F5 C87 S2 109.3(10) . . ?
F1 C86 S1 110.3(8) . . ?
F1 C86 F2 109.8(15) . . ?
F2 C86 S1 108.0(13) . . ?
F3 C86 S1 113.1(14) . . ?
F3 C86 F1 108.7(17) . . ?
F3 C86 F2 106.8(11) . . ?
N10 C92 H92A 109.5 . . ?
N10 C92 H92B 109.5 . . ?
N10 C92 H92C 109.5 . . ?
H92A C92 H92B 109.5 . . ?
H92A C92 H92C 109.5 . . ?
H92B C92 H92C 109.5 . . ?
N10 C94 H94 130.0 . . ?
N10 C94 O23 99.9(14) . . ?
O23 C94 H94 130.0 . . ?
N10 C93 H93A 109.5 . . ?
N10 C93 H93B 109.5 . . ?
N10 C93 H93C 109.5 . . ?
H93A C93 H93B 109.5 . . ?
H93A C93 H93C 109.5 . . ?
H93B C93 H93C 109.5 . . ?
N9 C89 H89A 109.5 . . ?
N9 C89 H89B 109.5 . . ?
N9 C89 H89C 109.5 . . ?
H89A C89 H89B 109.5 . . ?
H89A C89 H89C 109.5 . . ?
H89B C89 H89C 109.5 . . ?
S5 S4 O19 81.8(7) . . ?
S5 S4 O18 60.6(6) . . ?
S5 S4 O20 162.9(9) . . ?
S5 S4 C88 75.7(8) . . ?
O19 S4 O18 112.6(6) . . ?
O19 S4 O20 113.8(7) . . ?
O19 S4 C88 114.7(8) . . ?
O18 S4 O20 115.6(7) . . ?
O18 S4 C88 107.5(8) . . ?
O20 S4 C88 90.8(9) . . ?
S4 S5 O19 64.4(6) . . ?
S4 S5 O18 82.9(6) . . ?
S4 S5 O21 159.5(13) . . ?
S4 S5 C88 73.1(8) . . ?
O19 S5 C88 106.4(8) . . ?
O18 S5 O19 114.7(5) . . ?
O18 S5 O21 103.0(11) . . ?
O18 S5 C88 116.1(10) . . ?
O21 S5 O19 127.4(12) . . ?
O21 S5 C88 86.7(12) . . ?
S4 O19 S5 33.8(3) . . ?
S5 O18 S4 36.5(3) . . ?
S4 C88 S5 31.2(3) . . ?
F12 C88 S4 90.7(10) . . ?
F12 C88 S5 61.2(8) . . ?
F11 C88 S4 95.5(12) . . ?
F11 C88 S5 110.1(12) . . ?
F11 C88 F12 102.0(15) . . ?
F10 C88 S4 108.0(14) . . ?
F10 C88 S5 112.8(14) . . ?
F10 C88 F12 120.6(17) . . ?
F10 C88 F11 129.9(17) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Rh3 O5 C44 O8 169.9(5) . . . . ?
Rh3 O5 C44 C43 -11.0(6) . . . . ?
Rh3 O6 C43 O7 -176.4(4) . . . . ?
Rh3 O6 C43 C44 3.3(6) . . . . ?
Rh3 N5 C65 N6 -178.9(3) . . . . ?
Rh3 N5 C66 C67 179.3(4) . . . . ?
Rh3 C57 C58 C59 -62.4(4) . . . . ?
Rh3 C57 C58 C63 121.5(6) . . . . ?
Rh3 C57 C56 C55 61.6(4) . . . . ?
Rh3 C57 C56 C61 -123.0(6) . . . . ?
Rh3 C58 C59 C55 -59.8(4) . . . . ?
Rh3 C58 C59 C64 121.3(6) . . . . ?
Rh3 C55 C56 C57 -61.7(4) . . . . ?
Rh3 C55 C56 C61 122.9(6) . . . . ?
Rh3 C55 C59 C58 59.0(4) . . . . ?
Rh3 C55 C59 C64 -122.2(6) . . . . ?
Rh2 O3 C12 O2 -173.9(5) . . . . ?
Rh2 O3 C12 C11 6.1(6) . . . . ?
Rh2 O4 C11 O1 168.9(5) . . . . ?
Rh2 O4 C11 C12 -11.2(6) . . . . ?
Rh2 N4 C40 N3 -177.4(3) 3_566 . . . ?
Rh2 N4 C42 C41 176.6(4) 3_566 . . . ?
Rh2 C14 C13 C17 60.9(5) . . . . ?
Rh2 C14 C13 C18 -120.9(8) . . . . ?
Rh2 C14 C15 C16 -62.3(5) . . . . ?
Rh2 C14 C15 C20 121.7(7) . . . . ?
Rh2 C13 C17 C16 61.1(5) . . . . ?
Rh2 C13 C17 C22 -118.7(7) . . . . ?
Rh2 C15 C16 C17 -59.7(5) . . . . ?
Rh2 C15 C16 C21 121.6(7) . . . . ?
Rh2 C16 C17 C13 -60.7(5) . . . . ?
Rh2 C16 C17 C22 119.1(7) . . . . ?
Rh4 O7 C43 O6 172.0(4) . . . . ?
Rh4 O7 C43 C44 -7.7(6) . . . . ?
Rh4 O8 C44 O5 -179.5(5) . . . . ?
Rh4 O8 C44 C43 1.5(7) . . . . ?
Rh4 N8 C82 N7 180.0(3) 3_676 . . . ?
Rh4 N8 C84 C83 179.9(4) 3_676 . . . ?
Rh4 C47 C48 C49 -59.8(4) . . . . ?
Rh4 C47 C48 C53 116.4(6) . . . . ?
Rh4 C47 C46 C45 60.6(4) . . . . ?
Rh4 C47 C46 C51 -117.7(6) . . . . ?
Rh4 C45 C49 C48 60.9(4) . . . . ?
Rh4 C45 C49 C54 -121.0(6) . . . . ?
Rh4 C45 C46 C47 -60.3(4) . . . . ?
Rh4 C45 C46 C51 118.0(6) . . . . ?
Rh4 C48 C49 C45 -61.0(4) . . . . ?
Rh4 C48 C49 C54 120.9(6) . . . . ?
Rh1 O2 C12 O3 173.5(5) . . . . ?
Rh1 O2 C12 C11 -6.5(6) . . . . ?
Rh1 O1 C11 O4 -178.7(5) . . . . ?
Rh1 O1 C11 C12 1.4(6) . . . . ?
Rh1 N1 C23 N2 175.3(4) . . . . ?
Rh1 N1 C24 C25 -174.5(5) . . . . ?
Rh1 C5 C4 C3 -60.6(5) . . . . ?
Rh1 C5 C4 C9 120.1(7) . . . . ?
Rh1 C5 C1 C2 59.4(5) . . . . ?
Rh1 C5 C1 C6 -117.2(8) . . . . ?
Rh1 C3 C4 C5 60.2(5) . . . . ?
Rh1 C3 C4 C9 -120.4(7) . . . . ?
Rh1 C3 C2 C1 -62.1(5) . . . . ?
Rh1 C3 C2 C7 116.8(8) . . . . ?
Rh1 C1 C2 C3 61.4(5) . . . . ?
Rh1 C1 C2 C7 -117.6(8) . . . . ?
O7 C43 C44 O5 -174.7(5) . . . . ?
O7 C43 C44 O8 4.5(8) . . . . ?
O6 C43 C44 O5 5.6(8) . . . . ?
O6 C43 C44 O8 -175.3(5) . . . . ?
O3 C12 C11 O4 3.8(8) . . . . ?
O3 C12 C11 O1 -176.3(5) . . . . ?
O2 C12 C11 O4 -176.2(5) . . . . ?
O2 C12 C11 O1 3.7(8) . . . . ?
N5 C66 C67 N6 -0.5(7) . . . . ?
N6 C68 C81 C80 -176.5(5) . . . . ?
N6 C68 C69 C70 177.6(5) . . . . ?
N3 C33 C32 C31 -179.9(5) . . . . ?
N3 C33 C34 C35 178.8(5) . . . . ?
N4 C42 C41 N3 0.8(8) . . . . ?
O17 S3 C85 F9 179.9(8) . . . . ?
O17 S3 C85 F7 -60.0(9) . . . . ?
O17 S3 C85 F8 60.2(8) . . . . ?
N8 C84 C83 N7 0.1(7) . . . . ?
N7 C75 C76 C77 178.1(6) . . . . ?
C31 C30 C29 C38 0.7(8) . . . . ?
C31 C30 C29 C28 -179.9(5) . . . . ?
C31 C36 C35 C34 0.2(9) . . . . ?
C33 N3 C40 N4 -177.6(5) . . . . ?
C33 N3 C41 C42 177.5(5) . . . . ?
C33 C34 C35 C36 0.9(10) . . . . ?
N2 C26 C39 C38 -175.9(5) . . . . ?
N2 C26 C27 C28 176.0(6) . . . . ?
N2 C25 C24 N1 -1.2(8) . . . . ?
C68 N6 C65 N5 176.3(5) . . . . ?
C68 N6 C67 C66 -176.3(5) . . . . ?
C68 C81 C80 C71 -2.4(8) . . . . ?
C68 C81 C80 C79 -179.9(5) . . . . ?
C68 C69 C70 C71 0.2(8) . . . . ?
C73 C78 C79 C80 -0.6(8) . . . . ?
C73 C78 C77 C76 0.1(9) . . . . ?
C73 C74 C75 N7 -177.7(5) . . . . ?
C73 C74 C75 C76 2.5(9) . . . . ?
C30 C31 C32 C33 -178.8(5) . . . . ?
C30 C31 C36 C37 -0.8(8) . . . . ?
C30 C31 C36 C35 178.9(5) . . . . ?
C30 C29 C38 C37 -1.4(8) . . . . ?
C30 C29 C38 C39 177.0(5) . . . . ?
C30 C29 C28 C27 -176.9(6) . . . . ?
C65 N5 C66 C67 0.1(7) . . . . ?
C65 N6 C68 C81 9.3(8) . . . . ?
C65 N6 C68 C69 -169.8(5) . . . . ?
C65 N6 C67 C66 0.6(7) . . . . ?
C32 C31 C30 C29 -179.3(5) . . . . ?
C32 C31 C36 C37 178.9(5) . . . . ?
C32 C31 C36 C35 -1.3(8) . . . . ?
C32 C33 C34 C35 -0.8(9) . . . . ?
C57 C58 C59 Rh3 62.4(4) . . . . ?
C57 C58 C59 C55 2.6(6) . . . . ?
C57 C58 C59 C64 -176.2(5) . . . . ?
C29 C38 C39 C26 0.0(8) . . . . ?
C29 C28 C27 C26 -0.2(10) . . . . ?
O16 S3 C85 F9 56.1(10) . . . . ?
O16 S3 C85 F7 176.2(7) . . . . ?
O16 S3 C85 F8 -63.6(8) . . . . ?
C66 N5 C65 N6 0.3(6) . . . . ?
C71 C80 C79 C78 2.6(8) . . . . ?
C58 C57 C56 Rh3 -59.0(4) . . . . ?
C58 C57 C56 C55 2.7(6) . . . . ?
C58 C57 C56 C61 178.0(6) . . . . ?
C40 N3 C33 C32 167.5(5) . . . . ?
C40 N3 C33 C34 -12.1(8) . . . . ?
C40 N3 C41 C42 -1.0(7) . . . . ?
C40 N4 C42 C41 -0.2(7) . . . . ?
C81 C68 C69 C70 -1.5(8) . . . . ?
C81 C80 C79 C78 -179.9(5) . . . . ?
C69 C68 C81 C80 2.6(8) . . . . ?
C37 C36 C35 C34 179.9(6) . . . . ?
C37 C38 C39 C26 178.4(5) . . . . ?
C72 C73 C78 C79 -1.7(8) . . . . ?
C72 C73 C78 C77 179.2(5) . . . . ?
C72 C73 C74 C75 179.6(5) . . . . ?
C72 C71 C70 C69 -179.0(5) . . . . ?
C72 C71 C80 C81 -179.9(5) . . . . ?
C72 C71 C80 C79 -2.4(8) . . . . ?
C70 C71 C72 C73 179.0(5) . . . . ?
C70 C71 C80 C81 1.2(7) . . . . ?
C70 C71 C80 C79 178.7(5) . . . . ?
C80 C71 C72 C73 0.1(8) . . . . ?
C80 C71 C70 C69 -0.1(8) . . . . ?
C36 C31 C30 C29 0.4(8) . . . . ?
C36 C31 C32 C33 1.4(8) . . . . ?
C36 C37 C38 C29 1.0(8) . . . . ?
C36 C37 C38 C39 -177.4(6) . . . . ?
C38 C29 C28 C27 2.5(9) . . . . ?
C38 C37 C36 C31 0.1(9) . . . . ?
C38 C37 C36 C35 -179.6(5) . . . . ?
C14 C13 C17 Rh2 -61.3(5) . . . . ?
C14 C13 C17 C16 -0.3(8) . . . . ?
C14 C13 C17 C22 180.0(7) . . . . ?
C14 C15 C16 Rh2 62.3(5) . . . . ?
C14 C15 C16 C17 2.6(8) . . . . ?
C14 C15 C16 C21 -176.1(7) . . . . ?
C78 C73 C72 C71 1.9(8) . . . . ?
C78 C73 C74 C75 -1.5(8) . . . . ?
C78 C77 C76 C75 0.8(10) . . . . ?
C67 N6 C68 C81 -174.4(5) . . . . ?
C67 N6 C68 C69 6.5(8) . . . . ?
C67 N6 C65 N5 -0.6(6) . . . . ?
C74 C73 C72 C71 -179.2(5) . . . . ?
C74 C73 C78 C79 179.4(5) . . . . ?
C74 C73 C78 C77 0.2(8) . . . . ?
C74 C75 C76 C77 -2.1(9) . . . . ?
C79 C78 C77 C76 -179.0(6) . . . . ?
C26 N2 C23 N1 -176.8(5) . . . . ?
C26 N2 C25 C24 177.4(6) . . . . ?
C34 C33 C32 C31 -0.4(8) . . . . ?
C42 N4 C40 N3 -0.4(7) . . . . ?
C39 C26 C27 C28 -2.3(9) . . . . ?
C23 N1 C24 C25 1.2(8) . . . . ?
C23 N2 C26 C39 159.7(6) . . . . ?
C23 N2 C26 C27 -18.6(9) . . . . ?
C23 N2 C25 C24 0.8(7) . . . . ?
C56 C57 C58 Rh3 59.2(4) . . . . ?
C56 C57 C58 C59 -3.2(6) . . . . ?
C56 C57 C58 C63 -179.3(6) . . . . ?
C56 C55 C59 Rh3 -60.0(4) . . . . ?
C56 C55 C59 C58 -1.0(6) . . . . ?
C56 C55 C59 C64 177.9(6) . . . . ?
C41 N3 C33 C32 -10.7(9) . . . . ?
C41 N3 C33 C34 169.7(6) . . . . ?
C41 N3 C40 N4 0.9(7) . . . . ?
C28 C29 C38 C37 179.2(5) . . . . ?
C28 C29 C38 C39 -2.4(8) . . . . ?
O14 S1 C86 F1 -59.9(15) . . . . ?
O14 S1 C86 F2 -179.8(11) . . . . ?
O14 S1 C86 F3 62.1(13) . . . . ?
C82 N8 C84 C83 0.1(7) . . . . ?
C82 N7 C83 C84 -0.2(7) . . . . ?
C82 N7 C75 C74 25.0(8) . . . . ?
C82 N7 C75 C76 -155.2(6) . . . . ?
C84 N8 C82 N7 -0.2(6) . . . . ?
C59 C55 C56 Rh3 60.7(4) . . . . ?
C59 C55 C56 C57 -1.0(6) . . . . ?
C59 C55 C56 C61 -176.4(6) . . . . ?
C83 N7 C82 N8 0.2(7) . . . . ?
C83 N7 C75 C74 -153.3(6) . . . . ?
C83 N7 C75 C76 26.5(9) . . . . ?
C27 C26 C39 C38 2.3(9) . . . . ?
C13 C14 C15 Rh2 59.5(5) . . . . ?
C13 C14 C15 C16 -2.8(8) . . . . ?
C13 C14 C15 C20 -178.8(7) . . . . ?
C47 C48 C49 Rh4 59.7(4) . . . . ?
C47 C48 C49 C45 -1.3(7) . . . . ?
C47 C48 C49 C54 -179.4(6) . . . . ?
C15 C14 C13 Rh2 -59.0(5) . . . . ?
C15 C14 C13 C17 1.9(8) . . . . ?
C15 C14 C13 C18 -179.9(7) . . . . ?
C15 C16 C17 Rh2 59.2(5) . . . . ?
C15 C16 C17 C13 -1.5(8) . . . . ?
C15 C16 C17 C22 178.3(7) . . . . ?
C48 C47 C46 Rh4 -61.7(4) . . . . ?
C48 C47 C46 C45 -1.1(7) . . . . ?
C48 C47 C46 C51 -179.4(6) . . . . ?
C75 N7 C82 N8 -178.4(5) . . . . ?
C75 N7 C83 C84 178.4(5) . . . . ?
C25 N2 C26 C39 -16.4(9) . . . . ?
C25 N2 C26 C27 165.3(6) . . . . ?
C25 N2 C23 N1 0.0(7) . . . . ?
C24 N1 C23 N2 -0.7(7) . . . . ?
C49 C45 C46 Rh4 60.6(4) . . . . ?
C49 C45 C46 C47 0.3(7) . . . . ?
C49 C45 C46 C51 178.6(6) . . . . ?
C46 C47 C48 Rh4 61.3(4) . . . . ?
C46 C47 C48 C49 1.5(7) . . . . ?
C46 C47 C48 C53 177.7(6) . . . . ?
C46 C45 C49 Rh4 -60.3(4) . . . . ?
C46 C45 C49 C48 0.6(7) . . . . ?
C46 C45 C49 C54 178.7(6) . . . . ?
C77 C78 C79 C80 178.5(5) . . . . ?
C62 C57 C58 Rh3 -116.1(6) . . . . ?
C62 C57 C58 C59 -178.6(5) . . . . ?
C62 C57 C58 C63 5.4(9) . . . . ?
C62 C57 C56 Rh3 116.3(6) . . . . ?
C62 C57 C56 C55 177.9(5) . . . . ?
C62 C57 C56 C61 -6.7(10) . . . . ?
C5 C1 C2 Rh1 -59.4(5) . . . . ?
C5 C1 C2 C3 2.0(8) . . . . ?
C5 C1 C2 C7 -176.9(7) . . . . ?
C4 C5 C1 Rh1 -61.8(5) . . . . ?
C4 C5 C1 C2 -2.4(9) . . . . ?
C4 C5 C1 C6 -178.9(7) . . . . ?
C4 C3 C2 Rh1 61.2(5) . . . . ?
C4 C3 C2 C1 -0.9(8) . . . . ?
C4 C3 C2 C7 178.0(7) . . . . ?
O15 S3 C85 F9 -60.5(10) . . . . ?
O15 S3 C85 F7 59.6(8) . . . . ?
O15 S3 C85 F8 179.8(7) . . . . ?
C63 C58 C59 Rh3 -121.6(6) . . . . ?
C63 C58 C59 C55 178.6(6) . . . . ?
C63 C58 C59 C64 -0.3(10) . . . . ?
O9 S2 C87 F6 -175.9(10) . . . . ?
O9 S2 C87 F4 55.4(14) . . . . ?
O9 S2 C87 F5 -62.7(10) . . . . ?
C21 C16 C17 Rh2 -122.1(7) . . . . ?
C21 C16 C17 C13 177.2(7) . . . . ?
C21 C16 C17 C22 -3.0(12) . . . . ?
O11 S2 C87 F6 -53.7(13) . . . . ?
O11 S2 C87 F4 177.6(12) . . . . ?
O11 S2 C87 F5 59.5(11) . . . . ?
O12 S1 C86 F1 178.1(13) . . . . ?
O12 S1 C86 F2 58.1(14) . . . . ?
O12 S1 C86 F3 -59.9(14) . . . . ?
C60 C55 C56 Rh3 -119.0(6) . . . . ?
C60 C55 C56 C57 179.2(6) . . . . ?
C60 C55 C56 C61 3.9(10) . . . . ?
C60 C55 C59 Rh3 119.8(6) . . . . ?
C60 C55 C59 C58 178.7(6) . . . . ?
C60 C55 C59 C64 -2.4(10) . . . . ?
C1 C5 C4 Rh1 62.4(5) . . . . ?
C1 C5 C4 C3 1.8(9) . . . . ?
C1 C5 C4 C9 -177.5(7) . . . . ?
O13 S1 C86 F1 58.7(15) . . . . ?
O13 S1 C86 F2 -61.3(12) . . . . ?
O13 S1 C86 F3 -179.3(12) . . . . ?
C20 C15 C16 Rh2 -121.8(8) . . . . ?
C20 C15 C16 C17 178.5(7) . . . . ?
C20 C15 C16 C21 -0.2(12) . . . . ?
C53 C48 C49 Rh4 -116.5(6) . . . . ?
C53 C48 C49 C45 -177.5(6) . . . . ?
C53 C48 C49 C54 4.5(10) . . . . ?
C2 C3 C4 Rh1 -60.8(5) . . . . ?
C2 C3 C4 C5 -0.6(8) . . . . ?
C2 C3 C4 C9 178.8(7) . . . . ?
C19 C14 C13 Rh2 117.9(7) . . . . ?
C19 C14 C13 C17 178.8(7) . . . . ?
C19 C14 C13 C18 -2.9(12) . . . . ?
C19 C14 C15 Rh2 -117.3(7) . . . . ?
C19 C14 C15 C16 -179.7(7) . . . . ?
C19 C14 C15 C20 4.3(12) . . . . ?
C50 C45 C49 Rh4 117.2(6) . . . . ?
C50 C45 C49 C48 178.2(6) . . . . ?
C50 C45 C49 C54 -3.8(10) . . . . ?
C50 C45 C46 Rh4 -116.9(6) . . . . ?
C50 C45 C46 C47 -177.2(6) . . . . ?
C50 C45 C46 C51 1.1(10) . . . . ?
C90 N9 C91 O22 -5.0(19) . . . . ?
O10 S2 C87 F6 68.4(12) . . . . ?
O10 S2 C87 F4 -60.4(14) . . . . ?
O10 S2 C87 F5 -178.4(9) . . . . ?
C52 C47 C48 Rh4 -121.4(7) . . . . ?
C52 C47 C48 C49 178.8(6) . . . . ?
C52 C47 C48 C53 -5.0(10) . . . . ?
C52 C47 C46 Rh4 120.9(7) . . . . ?
C52 C47 C46 C45 -178.5(6) . . . . ?
C52 C47 C46 C51 3.2(10) . . . . ?
C18 C13 C17 Rh2 120.5(8) . . . . ?
C18 C13 C17 C16 -178.5(7) . . . . ?
C18 C13 C17 C22 1.7(12) . . . . ?
C10 C5 C4 Rh1 -121.0(8) . . . . ?
C10 C5 C4 C3 178.4(7) . . . . ?
C10 C5 C4 C9 -0.9(12) . . . . ?
C10 C5 C1 Rh1 121.6(8) . . . . ?
C10 C5 C1 C2 -179.0(7) . . . . ?
C10 C5 C1 C6 4.4(13) . . . . ?
C6 C1 C2 Rh1 117.3(8) . . . . ?
C6 C1 C2 C3 178.6(7) . . . . ?
C6 C1 C2 C7 -0.3(12) . . . . ?
C8 C3 C4 Rh1 119.2(7) . . . . ?
C8 C3 C4 C5 179.4(7) . . . . ?
C8 C3 C4 C9 -1.3(12) . . . . ?
C8 C3 C2 Rh1 -118.8(7) . . . . ?
C8 C3 C2 C1 179.2(7) . . . . ?
C8 C3 C2 C7 -1.9(12) . . . . ?
C92 N10 C94 O23 -7(2) . . . . ?
C93 N10 C94 O23 170.8(14) . . . . ?
C89 N9 C91 O22 169.9(14) . . . . ?
S4 S5 C88 F12 -159.1(11) . . . . ?
S4 S5 C88 F11 -66.1(15) . . . . ?
S4 S5 C88 F10 87.4(17) . . . . ?
S5 S4 C88 F12 18.2(10) . . . . ?
S5 S4 C88 F11 120.4(14) . . . . ?
S5 S4 C88 F10 -104.4(16) . . . . ?
O19 S4 S5 O18 -121.8(5) . . . . ?
O19 S4 S5 O21 130(4) . . . . ?
O19 S4 S5 C88 118.2(8) . . . . ?
O19 S4 O18 S5 65.7(8) . . . . ?
O19 S4 C88 S5 -73.8(9) . . . . ?
O19 S4 C88 F12 -55.5(12) . . . . ?
O19 S4 C88 F11 46.6(15) . . . . ?
O19 S4 C88 F10 -178.2(12) . . . . ?
O19 S5 O18 S4 -57.6(6) . . . . ?
O19 S5 C88 S4 56.0(7) . . . . ?
O19 S5 C88 F12 -103.1(8) . . . . ?
O19 S5 C88 F11 -10.1(17) . . . . ?
O19 S5 C88 F10 143.3(14) . . . . ?
O18 S4 S5 O19 121.8(5) . . . . ?
O18 S4 S5 O21 -109(4) . . . . ?
O18 S4 S5 C88 -120.1(9) . . . . ?
O18 S4 O19 S5 -53.3(6) . . . . ?
O18 S4 C88 S5 52.2(7) . . . . ?
O18 S4 C88 F12 70.4(11) . . . . ?
O18 S4 C88 F11 172.6(10) . . . . ?
O18 S4 C88 F10 -52.2(17) . . . . ?
O18 S5 O19 S4 68.3(7) . . . . ?
O18 S5 C88 S4 -73.0(8) . . . . ?
O18 S5 C88 F12 127.9(9) . . . . ?
O18 S5 C88 F11 -139.1(13) . . . . ?
O18 S5 C88 F10 14.3(19) . . . . ?
O20 S4 S5 O19 -157(3) . . . . ?
O20 S4 S5 O18 82(3) . . . . ?
O20 S4 S5 O21 -27(6) . . . . ?
O20 S4 S5 C88 -38(3) . . . . ?
O20 S4 O19 S5 172.6(9) . . . . ?
O20 S4 O18 S5 -161.2(10) . . . . ?
O20 S4 C88 S5 169.5(10) . . . . ?
O20 S4 C88 F12 -172.3(11) . . . . ?
O20 S4 C88 F11 -70.2(13) . . . . ?
O20 S4 C88 F10 65.1(16) . . . . ?
O21 S5 O19 S4 -160.1(15) . . . . ?
O21 S5 O18 S4 160.0(14) . . . . ?
O21 S5 C88 S4 -176.0(14) . . . . ?
O21 S5 C88 F12 24.9(13) . . . . ?
O21 S5 C88 F11 117.9(18) . . . . ?
O21 S5 C88 F10 -88.6(18) . . . . ?
C88 S4 S5 O19 -118.2(9) . . . . ?
C88 S4 S5 O18 120.1(9) . . . . ?
C88 S4 S5 O21 12(4) . . . . ?
C88 S4 O19 S5 70.0(9) . . . . ?
C88 S4 O18 S5 -61.5(10) . . . . ?
C88 S5 O19 S4 -61.6(9) . . . . ?
C88 S5 O18 S4 67.3(9) . . . . ?

_platon_squeeze_details          ?
_platon_squeeze_special_details  ?
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 0.116 0.098 0.238 455 154 ' '
2 0.884 -0.098 0.762 455 154 ' '
3 0.650 0.024 0.416 9 3 ' '
4 1.116 0.402 0.738 455 154 ' '
5 0.884 0.598 0.262 455 154 ' '
6 0.650 0.476 0.916 9 3 ' '
7 0.350 0.524 0.084 9 3 ' '
8 0.350 0.976 0.584 9 3 ' '

_platon_squeeze_void_probe_radius 1.20
_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_C96H98F24N6O8P4Rh4
_database_code_depnum_ccdc_archive 'CCDC 2165004'
loop_
_audit_author_name
_audit_author_address
'YingFeng Han'
;Northwest univeristy
China
;
_audit_update_record             
;
2022-04-07 deposited with the CCDC.	2022-05-10 downloaded from the CCDC.
;
_audit_creation_date             2022-04-07
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.06.28 svn.raecde09e for OlexSys, GUI svn.r6132)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C92 H92 N4 O8 Rh4, 4(F6 P), 2(C2 H3 N)'
_chemical_formula_sum            'C96 H98 F24 N6 O8 P4 Rh4'
_chemical_formula_weight         2455.32
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           61
_space_group_name_H-M_alt        'P b c a'
_space_group_name_Hall           '-P 2ac 2ab'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z-1/2'
'-x-1/2, y-1/2, z'

_cell_length_a                   24.277(7)
_cell_length_b                   22.228(6)
_cell_length_c                   41.74(3)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     22522(18)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    9774
_cell_measurement_temperature    192.0
_cell_measurement_theta_max      24.75
_cell_measurement_theta_min      2.32
_shelx_estimated_absorpt_T_max   0.931
_shelx_estimated_absorpt_T_min   0.869
_exptl_absorpt_coefficient_mu    0.724
_exptl_absorpt_correction_T_max  0.7453
_exptl_absorpt_correction_T_min  0.6347
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.0860 before and 0.0576 after correction.
The Ratio of minimum to maximum transmission is 0.8516.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear yellowish yellow'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   yellowish
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.448
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             9888
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.1
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0750
_diffrn_reflns_av_unetI/netI     0.0554
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       27
_diffrn_reflns_limit_h_min       -29
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_k_min       -27
_diffrn_reflns_limit_l_max       50
_diffrn_reflns_limit_l_min       -50
_diffrn_reflns_number            145730
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.685
_diffrn_reflns_theta_min         2.239
_diffrn_ambient_temperature      192.0
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           1.4
_diffrn_source_power             0.07
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                13197
_reflns_number_total             21326
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.38A (Bruker, 2018)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.38A (Bruker, 2018)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'olex2.refine 1.3 (Bourhis et al., 2015)'
_computing_structure_solution    'olex2.solve 1.3 (Bourhis et al., 2015)'
_refine_diff_density_max         1.009
_refine_diff_density_min         -0.672
_refine_diff_density_rms         0.093
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.014
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1301
_refine_ls_number_reflns         21326
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1030
_refine_ls_R_factor_gt           0.0596
_refine_ls_restrained_S_all      1.014
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1014P)²+14.6243P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1558
_refine_ls_wR_factor_ref         0.1834
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C00P(H00P), C00Q(H00Q), C00R(H00R), C00V(H00V), C00X(H00X), C00Y(H00Y),
 C00Z(H00Z), C010(H010), C012(H012), C016(H016), C018(H018), C01B(H01B),
 C01C(H01C), C01D(H01D), C01G(H01G), C01P(H01P), C01Q(H01Q), C01R(H01R),
 C022(H022), C023(H023), C024(H024), C028(H028), C029(H029), C02B(H02B),
 C02F(H02F), C02G(H02G), C02I(H02I), C02P(H02P), C02Q(H02Q), C02R(H02R),
 C02T(H02T), C02X(H02X)
2.b Idealised Me refined as rotating group:
 C02Y(H02a,H02c,H02d), C035(H03a,H03b,H03c), C039(H03d,H03e,H03f), C03A(H03g,
 H03h,H03i), C03B(H03j,H03k,H03l), C03D(H03m,H03n,H03o), C03E(H03p,H03q,H03r),
 C03F(H03s,H03t,H03u), C03G(H03v,H03w,H03x), C03H(H03y,H,Ha), C03I(H03z,Hb,Hc),
 C03J(H03,Hd,He), C03M(H1,Hf,Hg), C03N(H2,Hh,Hi), C03O(H3,Hj,Hk), C03P(H4,Hl,
 Hm), C03Q(H5,Hn,Ho), C03R(H6,Hp,Hq), C03S(H7,Hr,Hs), C03V(H8,Ht,Hu), C03W(H10,
 Hv,Hw), C03X(H9,Hx,Hy)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     iterative
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh00 Rh 0.40308(2) 0.69299(2) 0.83027(2) 0.04749(13) Uani 1 1 d . . . . .
Rh1 Rh 0.19212(2) 0.78368(2) 0.82910(2) 0.04998(14) Uani 1 1 d . . . . .
Rh2 Rh 0.64574(2) 0.64185(2) 0.42384(2) 0.05529(15) Uani 1 1 d . . . . .
Rh3 Rh 0.43033(2) 0.56110(2) 0.42978(2) 0.05599(15) Uani 1 1 d . . . . .
P005 P 0.23866(9) 0.33757(13) 0.43892(6) 0.0958(7) Uani 1 1 d . . . . .
P006 P 0.41051(10) 1.03420(10) 0.76961(6) 0.0947(7) Uani 1 1 d . . . . .
P007 P 0.57820(13) 0.92059(11) 0.41655(8) 0.1155(9) Uani 1 1 d . . . . .
P008 P 0.33463(18) 0.60935(13) 0.67538(8) 0.1447(13) Uani 1 1 d . . . . .
O009 O 0.32050(14) 0.66543(17) 0.82003(10) 0.0522(10) Uani 1 1 d . . . . .
O00A O 0.23456(14) 0.70039(16) 0.82145(10) 0.0529(10) Uani 1 1 d . . . . .
O00B O 0.35593(14) 0.76376(17) 0.85210(9) 0.0502(9) Uani 1 1 d . . . . .
O00C O 0.48090(15) 0.62457(18) 0.40534(9) 0.0566(10) Uani 1 1 d . . . . .
O00D O 0.27059(14) 0.80159(16) 0.85056(9) 0.0521(10) Uani 1 1 d . . . . .
O00E O 0.59735(15) 0.57154(19) 0.44612(11) 0.0623(11) Uani 1 1 d . . . . .
O00F O 0.50962(15) 0.54216(18) 0.44998(10) 0.0590(10) Uani 1 1 d . . . . .
O00G O 0.56804(14) 0.6538(2) 0.40115(9) 0.0604(11) Uani 1 1 d . . . . .
N00H N 0.23012(17) 0.8086(2) 0.78573(12) 0.0500(11) Uani 1 1 d . . . . .
N00I N 0.61208(17) 0.6964(2) 0.46084(12) 0.0531(12) Uani 1 1 d . . . . .
N00J N 0.39930(17) 0.7457(2) 0.78795(11) 0.0502(11) Uani 1 1 d . . . . .
N00K N 0.42410(18) 0.6281(2) 0.46561(12) 0.0581(13) Uani 1 1 d . . . . .
F00L F 0.3878(2) 1.0947(2) 0.75442(12) 0.1098(15) Uani 1 1 d . . . . .
C00M C 0.44395(19) 0.8330(3) 0.70028(13) 0.0472(13) Uani 1 1 d . . . . .
F00N F 0.3746(3) 1.0449(3) 0.79995(13) 0.135(2) Uani 1 1 d . . . . .
C00O C 0.2737(2) 0.8401(3) 0.72589(14) 0.0502(14) Uani 1 1 d . . . . .
C00P C 0.3100(2) 0.8125(3) 0.67224(14) 0.0502(14) Uani 1 1 d . . . . .
H00P H 0.305320 0.771543 0.678091 0.060 Uiso 1 1 calc R U . . .
C00Q C 0.4331(2) 0.8329(3) 0.76023(14) 0.0539(14) Uani 1 1 d . . . . .
H00Q H 0.446722 0.872927 0.761351 0.065 Uiso 1 1 calc R U . . .
C00R C 0.5328(2) 0.7801(3) 0.56527(13) 0.0465(13) Uani 1 1 d . . . . .
H00R H 0.531895 0.737533 0.567064 0.056 Uiso 1 1 calc R U . . .
C00S C 0.5155(2) 0.8152(2) 0.59128(14) 0.0470(13) Uani 1 1 d . . . . .
C00T C 0.4261(2) 0.8045(3) 0.73033(14) 0.0478(13) Uani 1 1 d . . . . .
F00U F 0.3636(3) 0.9975(3) 0.75224(17) 0.155(2) Uani 1 1 d . . . . .
C00V C 0.2822(2) 0.8755(3) 0.75327(15) 0.0572(15) Uani 1 1 d . . . . .
H00V H 0.303686 0.911108 0.751932 0.069 Uiso 1 1 calc R U . . .
F00W F 0.2309(3) 0.4051(3) 0.42653(16) 0.158(2) Uani 1 1 d . . . . .
C00X C 0.4012(2) 0.7473(3) 0.73066(14) 0.0533(14) Uani 1 1 d . . . . .
H00X H 0.392892 0.727467 0.711099 0.064 Uiso 1 1 calc R U . . .
C00Y C 0.2424(2) 0.7876(3) 0.73014(15) 0.0575(15) Uani 1 1 d . . . . .
H00Y H 0.235673 0.761584 0.712537 0.069 Uiso 1 1 calc R U . . .
C00Z C 0.46041(19) 0.7979(3) 0.67484(13) 0.0456(13) Uani 1 1 d . . . . .
H00Z H 0.458744 0.755348 0.676546 0.055 Uiso 1 1 calc R U . . .
C010 C 0.4198(2) 0.8018(3) 0.78807(14) 0.0542(15) Uani 1 1 d . . . . .
H010 H 0.425460 0.821152 0.808103 0.065 Uiso 1 1 calc R U . . .
F011 F 0.5714(3) 0.9853(2) 0.43208(15) 0.148(2) Uani 1 1 d . . . . .
C012 C 0.4968(2) 0.7893(3) 0.62002(14) 0.0468(13) Uani 1 1 d . . . . .
H012 H 0.495660 0.746761 0.621887 0.056 Uiso 1 1 calc R U . . .
C013 C 0.3313(2) 0.8258(3) 0.64158(14) 0.0491(14) Uani 1 1 d . . . . .
C014 C 0.2959(2) 0.8558(3) 0.69380(15) 0.0514(14) Uani 1 1 d . . . . .
C015 C 0.47991(19) 0.8247(3) 0.64596(14) 0.0472(13) Uani 1 1 d . . . . .
C016 C 0.3471(2) 0.7814(3) 0.62020(14) 0.0487(13) Uani 1 1 d . . . . .
H016 H 0.343883 0.740340 0.626262 0.058 Uiso 1 1 calc R U . . .
C017 C 0.1237(2) 0.7487(3) 0.85554(17) 0.0573(16) Uani 1 1 d . . . . .
C018 C 0.2218(2) 0.7742(3) 0.75973(15) 0.0563(15) Uani 1 1 d . . . . .
H018 H 0.200491 0.738635 0.762041 0.068 Uiso 1 1 calc R U . . .
F019 F 0.4593(2) 1.0715(2) 0.78550(16) 0.140(2) Uani 1 1 d . . . . .
C01A C 0.5475(2) 0.5742(3) 0.43800(14) 0.0518(14) Uani 1 1 d . . . . .
C01B C 0.2596(2) 0.8586(3) 0.78190(15) 0.0547(15) Uani 1 1 d . . . . .
H01B H 0.265268 0.883810 0.799983 0.066 Uiso 1 1 calc R U . . .
C01C C 0.3891(2) 0.7203(3) 0.75949(15) 0.0530(14) Uani 1 1 d . . . . .
H01C H 0.372588 0.681528 0.759164 0.064 Uiso 1 1 calc R U . . .
C01D C 0.5506(2) 0.8699(3) 0.53421(16) 0.0584(15) Uani 1 1 d . . . . .
H01D H 0.561765 0.888023 0.514661 0.070 Uiso 1 1 calc R U . . .
C01E C 0.2848(2) 0.7043(2) 0.82728(14) 0.0486(14) Uani 1 1 d . . . . .
C01F C 0.5715(2) 0.7676(3) 0.51062(14) 0.0484(13) Uani 1 1 d . . . . .
C01G C 0.5598(2) 0.7809(3) 0.47861(14) 0.0545(15) Uani 1 1 d . . . . .
H01G H 0.537314 0.814394 0.473343 0.065 Uiso 1 1 calc R U . . .
C01H C 0.5511(2) 0.8057(3) 0.53716(15) 0.0527(14) Uani 1 1 d . . . . .
F01I F 0.4489(3) 1.0236(3) 0.73981(16) 0.172(3) Uani 1 1 d . . . . .
F01J F 0.2388(3) 0.3160(3) 0.40380(14) 0.159(2) Uani 1 1 d . . . . .
C01K C 0.5303(2) 0.6212(3) 0.41272(14) 0.0522(14) Uani 1 1 d . . . . .
C01L C 0.4536(2) 0.6728(3) 0.87072(15) 0.0590(16) Uani 1 1 d . . . . .
F01M F 0.3023(2) 0.3466(4) 0.43667(18) 0.169(3) Uani 1 1 d . . . . .
F01N F 0.3770(3) 0.5620(3) 0.66054(16) 0.155(2) Uani 1 1 d . . . . .
C01O C 0.4459(3) 0.6104(3) 0.82741(18) 0.0659(18) Uani 1 1 d . . . . .
C01P C 0.4647(2) 0.9231(3) 0.67000(16) 0.0558(15) Uani 1 1 d . . . . .
H01P H 0.464911 0.965774 0.668572 0.067 Uiso 1 1 calc R U . . .
C01Q C 0.4470(2) 0.8966(3) 0.69746(16) 0.0563(15) Uani 1 1 d . . . . .
H01Q H 0.436529 0.921078 0.715101 0.068 Uiso 1 1 calc R U . . .
C01R C 0.3023(2) 0.9176(3) 0.68463(16) 0.0585(15) Uani 1 1 d . . . . .
H01R H 0.292054 0.948429 0.699216 0.070 Uiso 1 1 calc R U . . .
F01S F 0.3766(4) 0.6633(2) 0.66442(16) 0.179(3) Uani 1 1 d . . . . .
C01T C 0.4104(2) 0.7177(3) 0.51224(15) 0.0595(16) Uani 1 1 d . . . . .
C01U C 0.4825(2) 0.6565(3) 0.81858(17) 0.0638(17) Uani 1 1 d . . . . .
C01V C 0.3997(2) 0.7653(3) 0.53665(15) 0.0539(15) Uani 1 1 d . . . . .
C01W C 0.4282(2) 0.6195(3) 0.86007(17) 0.0626(17) Uani 1 1 d . . . . .
C01X C 0.1083(2) 0.7619(3) 0.82327(17) 0.0629(18) Uani 1 1 d . . . . .
C01Y C 0.4830(2) 0.8888(3) 0.64339(15) 0.0508(14) Uani 1 1 d . . . . .
C01Z C 0.5175(2) 0.8796(3) 0.58836(15) 0.0518(14) Uani 1 1 d . . . . .
C020 C 0.4047(3) 0.4700(3) 0.42609(19) 0.074(2) Uani 1 1 d . . . . .
C021 C 0.3732(2) 0.8577(3) 0.58103(15) 0.0543(15) Uani 1 1 d . . . . .
C022 C 0.5815(2) 0.7446(3) 0.45445(16) 0.0582(16) Uani 1 1 d . . . . .
H022 H 0.574138 0.754566 0.432736 0.070 Uiso 1 1 calc R U . . .
C023 C 0.6228(2) 0.6835(3) 0.49180(15) 0.0562(15) Uani 1 1 d . . . . .
H023 H 0.644747 0.649188 0.496451 0.067 Uiso 1 1 calc R U . . .
C024 C 0.4035(2) 0.6822(3) 0.45869(16) 0.0610(16) Uani 1 1 d . . . . .
H024 H 0.393003 0.689538 0.437112 0.073 Uiso 1 1 calc R U . . .
F025 F 0.5791(3) 0.8567(2) 0.40118(19) 0.155(2) Uani 1 1 d . . . . .
C026 C 0.3383(2) 0.8883(3) 0.63289(14) 0.0508(14) Uani 1 1 d . . . . .
C027 C 0.3058(2) 0.7608(3) 0.84489(14) 0.0473(13) Uani 1 1 d . . . . .
C028 C 0.5006(2) 0.9138(3) 0.61460(15) 0.0531(15) Uani 1 1 d . . . . .
H028 H 0.501170 0.956433 0.612732 0.064 Uiso 1 1 calc R U . . .
C029 C 0.5344(2) 0.9047(3) 0.55874(15) 0.0550(15) Uani 1 1 d . . . . .
H029 H 0.534232 0.947206 0.556177 0.066 Uiso 1 1 calc R U . . .
F02A F 0.4340(3) 0.9741(2) 0.78456(19) 0.169(3) Uani 1 1 d . . . . .
C02B C 0.6039(2) 0.7172(3) 0.51673(15) 0.0530(14) Uani 1 1 d . . . . .
H02B H 0.612659 0.706360 0.538144 0.064 Uiso 1 1 calc R U . . .
C02C C 0.3679(2) 0.7959(3) 0.58962(15) 0.0521(14) Uani 1 1 d . . . . .
C02D C 0.1419(2) 0.8025(3) 0.87020(18) 0.0642(18) Uani 1 1 d . . . . .
F02E F 0.1765(2) 0.3343(4) 0.4416(2) 0.199(4) Uani 1 1 d . . . . .
C02F C 0.4383(2) 0.6187(3) 0.49660(16) 0.0634(17) Uani 1 1 d . . . . .
H02F H 0.453206 0.580724 0.502390 0.076 Uiso 1 1 calc R U . . .
C02G C 0.3227(2) 0.9327(3) 0.65544(16) 0.0608(16) Uani 1 1 d . . . . .
H02G H 0.326664 0.974030 0.650037 0.073 Uiso 1 1 calc R U . . .
F02H F 0.3657(3) 0.6048(3) 0.70928(14) 0.153(2) Uani 1 1 d . . . . .
C02I C 0.3964(2) 0.7280(3) 0.48013(16) 0.0616(16) Uani 1 1 d . . . . .
H02I H 0.382237 0.765809 0.473460 0.074 Uiso 1 1 calc R U . . .
F02J F 0.5224(3) 0.9015(3) 0.4335(2) 0.176(3) Uani 1 1 d . . . . .
C02K C 0.4863(2) 0.6970(3) 0.84531(17) 0.0610(16) Uani 1 1 d . . . . .
C02L C 0.4148(3) 0.4934(3) 0.3946(2) 0.081(2) Uani 1 1 d . . . . .
C02M C 0.1372(2) 0.8496(3) 0.8472(2) 0.0675(19) Uani 1 1 d . . . . .
C02N C 0.7060(3) 0.5894(4) 0.3988(2) 0.078(2) Uani 1 1 d . . . . .
C02O C 0.7277(2) 0.6736(3) 0.42871(16) 0.0614(17) Uani 1 1 d . . . . .
C02P C 0.3935(2) 0.8716(3) 0.54953(16) 0.0643(17) Uani 1 1 d . . . . .
H02P H 0.398383 0.912442 0.543367 0.077 Uiso 1 1 calc R U . . .
C02Q C 0.4059(2) 0.8267(3) 0.52837(17) 0.0637(17) Uani 1 1 d . . . . .
H02Q H 0.419041 0.836857 0.507623 0.076 Uiso 1 1 calc R U . . .
C02R C 0.3822(2) 0.7500(3) 0.56709(15) 0.0559(15) Uani 1 1 d . . . . .
H02R H 0.379615 0.708839 0.573069 0.067 Uiso 1 1 calc R U . . .
C02S C 0.6928(2) 0.6406(4) 0.38053(17) 0.074(2) Uani 1 1 d . . . . .
C02T C 0.3587(2) 0.9025(3) 0.60297(15) 0.0568(15) Uani 1 1 d . . . . .
H02T H 0.362998 0.943548 0.597175 0.068 Uiso 1 1 calc R U . . .
F02U F 0.5474(4) 0.9436(3) 0.38589(17) 0.181(3) Uani 1 1 d . . . . .
C02V C 0.7049(2) 0.6927(3) 0.39896(18) 0.0659(18) Uani 1 1 d . . . . .
C02W C 0.1149(2) 0.8254(3) 0.8186(2) 0.070(2) Uani 1 1 d . . . . .
C02X C 0.4320(2) 0.6616(3) 0.52005(17) 0.0674(18) Uani 1 1 d . . . . .
H02X H 0.442295 0.652918 0.541514 0.081 Uiso 1 1 calc R U . . .
C02Y C 0.4457(3) 0.7018(3) 0.90269(17) 0.083(2) Uani 1 1 d . . . . .
H02A H 0.443056 0.745539 0.899974 0.124 Uiso 1 1 calc R U . . .
H02C H 0.477095 0.692315 0.916550 0.124 Uiso 1 1 calc R U . . .
H02D H 0.411743 0.686714 0.912506 0.124 Uiso 1 1 calc R U . . .
F02Z F 0.2954(3) 0.5566(3) 0.6857(2) 0.192(3) Uani 1 1 d . . . . .
C030 C 0.7275(2) 0.6100(3) 0.42925(17) 0.0673(18) Uani 1 1 d . . . . .
F031 F 0.6347(3) 0.9379(3) 0.40042(19) 0.171(3) Uani 1 1 d . . . . .
F032 F 0.2484(4) 0.2741(3) 0.4518(2) 0.205(4) Uani 1 1 d . . . . .
F033 F 0.6104(3) 0.8954(4) 0.4468(2) 0.203(4) Uani 1 1 d . . . . .
F034 F 0.2421(4) 0.3667(5) 0.47283(16) 0.226(4) Uani 1 1 d . . . . .
C035 C 0.1228(3) 0.6876(3) 0.8706(2) 0.081(2) Uani 1 1 d . . . . .
H03A H 0.134957 0.657625 0.854911 0.121 Uiso 1 1 calc R U . . .
H03B H 0.085250 0.678182 0.877592 0.121 Uiso 1 1 calc R U . . .
H03C H 0.147591 0.687133 0.889106 0.121 Uiso 1 1 calc R U . . .
C036 C 0.3782(3) 0.5425(3) 0.3894(2) 0.081(2) Uani 1 1 d . . . . .
C037 C 0.3631(3) 0.5045(4) 0.4408(2) 0.086(2) Uani 1 1 d . . . . .
F038 F 0.2921(4) 0.6580(3) 0.6903(2) 0.191(3) Uani 1 1 d . . . . .
C039 C 0.4573(4) 0.4711(4) 0.3698(2) 0.107(3) Uani 1 1 d . . . . .
H03D H 0.479025 0.505323 0.361999 0.160 Uiso 1 1 calc R U . . .
H03E H 0.438112 0.452220 0.351799 0.160 Uiso 1 1 calc R U . . .
H03F H 0.481915 0.441736 0.379904 0.160 Uiso 1 1 calc R U . . .
C03A C 0.4349(4) 0.4192(3) 0.4406(2) 0.091(2) Uani 1 1 d . . . . .
H03G H 0.470257 0.414017 0.429553 0.137 Uiso 1 1 calc R U . . .
H03H H 0.413042 0.382379 0.438427 0.137 Uiso 1 1 calc R U . . .
H03I H 0.441489 0.427522 0.463295 0.137 Uiso 1 1 calc R U . . .
C03B C 0.1650(3) 0.8086(4) 0.90369(19) 0.093(3) Uani 1 1 d . . . . .
H03J H 0.180071 0.769913 0.910665 0.140 Uiso 1 1 calc R U . . .
H03K H 0.135573 0.821021 0.918374 0.140 Uiso 1 1 calc R U . . .
H03L H 0.194237 0.839018 0.903745 0.140 Uiso 1 1 calc R U . . .
C03C C 0.3460(3) 0.5513(4) 0.4171(2) 0.086(2) Uani 1 1 d . . . . .
C03D C 0.5096(3) 0.6649(4) 0.78638(19) 0.101(3) Uani 1 1 d . . . . .
H03M H 0.486207 0.647338 0.769667 0.152 Uiso 1 1 calc R U . . .
H03N H 0.545532 0.644914 0.786334 0.152 Uiso 1 1 calc R U . . .
H03O H 0.514494 0.707957 0.782208 0.152 Uiso 1 1 calc R U . . .
C03E C 0.3916(3) 0.5789(3) 0.8787(2) 0.092(2) Uani 1 1 d . . . . .
H03P H 0.370035 0.602547 0.893975 0.138 Uiso 1 1 calc R U . . .
H03Q H 0.414005 0.549361 0.890265 0.138 Uiso 1 1 calc R U . . .
H03R H 0.366653 0.557860 0.863976 0.138 Uiso 1 1 calc R U . . .
C03F C 0.0866(3) 0.7171(4) 0.7994(2) 0.096(3) Uani 1 1 d . . . . .
H03S H 0.087280 0.734775 0.777925 0.143 Uiso 1 1 calc R U . . .
H03T H 0.048677 0.706256 0.805043 0.143 Uiso 1 1 calc R U . . .
H03U H 0.109702 0.680900 0.799763 0.143 Uiso 1 1 calc R U . . .
C03G C 0.7465(3) 0.5683(4) 0.4552(2) 0.102(3) Uani 1 1 d . . . . .
H03V H 0.751985 0.591092 0.475078 0.153 Uiso 1 1 calc R U . . .
H03W H 0.781223 0.549350 0.448871 0.153 Uiso 1 1 calc R U . . .
H03X H 0.718529 0.537137 0.458773 0.153 Uiso 1 1 calc R U . . .
C03H C 0.7471(3) 0.7138(4) 0.45475(19) 0.094(3) Uani 1 1 d . . . . .
H03Y H 0.727455 0.752304 0.453506 0.141 Uiso 1 1 calc R U . . .
H H 0.786724 0.720858 0.452392 0.141 Uiso 1 1 calc R U . . .
HA H 0.739834 0.694962 0.475546 0.141 Uiso 1 1 calc R U . . .
C03I C 0.3767(4) 0.5810(4) 0.3596(2) 0.103(3) Uani 1 1 d . . . . .
H03Z H 0.356970 0.618504 0.364104 0.155 Uiso 1 1 calc R U . . .
HB H 0.357662 0.559140 0.342412 0.155 Uiso 1 1 calc R U . . .
HC H 0.414384 0.590235 0.352777 0.155 Uiso 1 1 calc R U . . .
C03J C 0.6663(3) 0.6393(5) 0.34822(19) 0.125(4) Uani 1 1 d . . . . .
H03 H 0.644747 0.602251 0.345967 0.188 Uiso 1 1 calc R U . . .
HD H 0.694847 0.640502 0.331612 0.188 Uiso 1 1 calc R U . . .
HE H 0.642002 0.674186 0.345880 0.188 Uiso 1 1 calc R U . . .
F03K F 0.3085(4) 0.6151(3) 0.64049(18) 0.205(4) Uani 1 1 d . . . . .
C03L C 0.3462(5) 1.1549(6) 0.6884(3) 0.123(4) Uani 1 1 d . . . . .
C03M C 0.3383(3) 0.4950(5) 0.4735(2) 0.121(3) Uani 1 1 d . . . . .
H1 H 0.363264 0.470498 0.486500 0.181 Uiso 1 1 calc R U . . .
HF H 0.302830 0.474389 0.471327 0.181 Uiso 1 1 calc R U . . .
HG H 0.332702 0.534097 0.483863 0.181 Uiso 1 1 calc R U . . .
C03N C 0.5218(3) 0.7523(4) 0.8468(2) 0.088(2) Uani 1 1 d . . . . .
H2 H 0.532714 0.763901 0.825018 0.133 Uiso 1 1 calc R U . . .
HH H 0.554723 0.743906 0.859557 0.133 Uiso 1 1 calc R U . . .
HI H 0.500977 0.785233 0.856647 0.133 Uiso 1 1 calc R U . . .
C03O C 0.1509(3) 0.9150(3) 0.8530(3) 0.106(3) Uani 1 1 d . . . . .
H3 H 0.175347 0.918332 0.871562 0.159 Uiso 1 1 calc R U . . .
HJ H 0.116898 0.937440 0.857042 0.159 Uiso 1 1 calc R U . . .
HK H 0.169348 0.931534 0.834030 0.159 Uiso 1 1 calc R U . . .
C03P C 0.3007(3) 0.5946(5) 0.4222(3) 0.120(4) Uani 1 1 d . . . . .
H4 H 0.299330 0.606071 0.444851 0.180 Uiso 1 1 calc R U . . .
HL H 0.265689 0.576003 0.416025 0.180 Uiso 1 1 calc R U . . .
HM H 0.307050 0.630521 0.409066 0.180 Uiso 1 1 calc R U . . .
C03Q C 0.1017(3) 0.8601(4) 0.7876(2) 0.114(3) Uani 1 1 d . . . . .
H5 H 0.127178 0.894033 0.785356 0.172 Uiso 1 1 calc R U . . .
HN H 0.063782 0.875244 0.788563 0.172 Uiso 1 1 calc R U . . .
HO H 0.105597 0.833199 0.769140 0.172 Uiso 1 1 calc R U . . .
C03R C 0.4286(3) 0.5581(3) 0.8058(2) 0.101(3) Uani 1 1 d . . . . .
H6 H 0.390820 0.546096 0.811074 0.151 Uiso 1 1 calc R U . . .
HP H 0.453484 0.524024 0.809213 0.151 Uiso 1 1 calc R U . . .
HQ H 0.430366 0.570833 0.783368 0.151 Uiso 1 1 calc R U . . .
C03S C 0.7000(4) 0.5231(4) 0.3905(3) 0.130(4) Uani 1 1 d . . . . .
H7 H 0.687725 0.501001 0.409536 0.195 Uiso 1 1 calc R U . . .
HR H 0.735650 0.507260 0.383420 0.195 Uiso 1 1 calc R U . . .
HS H 0.672873 0.518442 0.373352 0.195 Uiso 1 1 calc R U . . .
N03U N 0.3531(4) 1.2046(5) 0.6988(3) 0.164(5) Uani 1 1 d . . . . .
C03V C 0.6985(3) 0.7568(4) 0.3887(3) 0.115(3) Uani 1 1 d . . . . .
H8 H 0.665693 0.760770 0.375244 0.172 Uiso 1 1 calc R U . . .
HT H 0.731113 0.769265 0.376563 0.172 Uiso 1 1 calc R U . . .
HU H 0.694610 0.782455 0.407709 0.172 Uiso 1 1 calc R U . . .
C03W C 0.2543(4) 0.5859(4) 0.7610(3) 0.129(4) Uani 1 1 d . . . . .
H10 H 0.266675 0.600832 0.740153 0.193 Uiso 1 1 calc R U . . .
HV H 0.260597 0.616869 0.777366 0.193 Uiso 1 1 calc R U . . .
HW H 0.214892 0.576480 0.760023 0.193 Uiso 1 1 calc R U . . .
C03X C 0.3427(5) 1.0956(5) 0.6776(3) 0.136(4) Uani 1 1 d . . . . .
H9 H 0.358236 1.092793 0.655975 0.205 Uiso 1 1 calc R U . . .
HX H 0.303988 1.083035 0.677131 0.205 Uiso 1 1 calc R U . . .
HY H 0.363359 1.069248 0.692088 0.205 Uiso 1 1 calc R U . . .
C03Y C 0.2841(5) 0.5335(5) 0.7691(3) 0.143(5) Uani 1 1 d . . . . .
N03Z N 0.3077(4) 0.4918(5) 0.7748(4) 0.227(8) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh00 O009 2.139(4) . ?
Rh00 O00B 2.148(3) . ?
Rh00 N00J 2.122(5) . ?
Rh00 C01L 2.135(6) . ?
Rh00 C01O 2.114(6) . ?
Rh00 C01U 2.149(5) . ?
Rh00 C01W 2.141(7) . ?
Rh00 C02K 2.118(6) . ?
Rh1 O00A 2.143(4) . ?
Rh1 O00D 2.142(4) . ?
Rh1 N00H 2.106(5) . ?
Rh1 C017 2.142(5) . ?
Rh1 C01X 2.105(6) . ?
Rh1 C02D 2.146(6) . ?
Rh1 C02M 2.120(6) . ?
Rh1 C02W 2.137(6) . ?
Rh2 O00E 2.165(4) . ?
Rh2 O00G 2.127(4) . ?
Rh2 N00I 2.127(5) . ?
Rh2 C02N 2.144(7) . ?
Rh2 C02O 2.121(6) . ?
Rh2 C02S 2.139(6) . ?
Rh2 C02V 2.102(6) . ?
Rh2 C030 2.120(6) . ?
Rh3 O00C 2.130(4) . ?
Rh3 O00F 2.143(4) . ?
Rh3 N00K 2.117(5) . ?
Rh3 C020 2.124(7) . ?
Rh3 C02L 2.135(8) . ?
Rh3 C036 2.147(8) . ?
Rh3 C037 2.112(6) . ?
Rh3 C03C 2.125(6) . ?
P005 F00W 1.599(7) . ?
P005 F01J 1.542(6) . ?
P005 F01M 1.561(6) . ?
P005 F02E 1.514(6) . ?
P005 F032 1.529(7) . ?
P005 F034 1.558(7) . ?
P006 F00L 1.586(6) . ?
P006 F00N 1.555(5) . ?
P006 F00U 1.576(6) . ?
P006 F019 1.592(6) . ?
P006 F01I 1.571(6) . ?
P006 F02A 1.581(7) . ?
P007 F011 1.586(6) . ?
P007 F025 1.559(6) . ?
P007 F02J 1.587(7) . ?
P007 F02U 1.568(7) . ?
P007 F031 1.576(7) . ?
P007 F033 1.585(7) . ?
P008 F01N 1.596(7) . ?
P008 F01S 1.638(9) . ?
P008 F02H 1.606(7) . ?
P008 F02Z 1.571(8) . ?
P008 F038 1.620(8) . ?
P008 F03K 1.594(7) . ?
O009 C01E 1.261(6) . ?
O00A C01E 1.247(6) . ?
O00B C027 1.254(6) . ?
O00C C01K 1.240(6) . ?
O00D C027 1.269(6) . ?
O00E C01A 1.259(7) . ?
O00F C01A 1.266(6) . ?
O00G C01K 1.263(6) . ?
N00H C018 1.342(7) . ?
N00H C01B 1.332(7) . ?
N00I C022 1.330(7) . ?
N00I C023 1.349(7) . ?
N00J C010 1.342(8) . ?
N00J C01C 1.339(7) . ?
N00K C024 1.334(8) . ?
N00K C02F 1.355(8) . ?
C00M C00T 1.470(8) . ?
C00M C00Z 1.376(7) . ?
C00M C01Q 1.422(8) . ?
C00O C00V 1.402(8) . ?
C00O C00Y 1.403(8) . ?
C00O C014 1.485(8) . ?
C00P H00P 0.9500 . ?
C00P C013 1.411(8) . ?
C00P C014 1.361(8) . ?
C00Q H00Q 0.9500 . ?
C00Q C00T 1.408(8) . ?
C00Q C010 1.390(8) . ?
C00R H00R 0.9500 . ?
C00R C00S 1.402(8) . ?
C00R C01H 1.377(8) . ?
C00S C012 1.405(8) . ?
C00S C01Z 1.437(8) . ?
C00T C00X 1.408(8) . ?
C00V H00V 0.9500 . ?
C00V C01B 1.367(8) . ?
C00X H00X 0.9500 . ?
C00X C01C 1.377(8) . ?
C00Y H00Y 0.9500 . ?
C00Y C018 1.366(8) . ?
C00Z H00Z 0.9500 . ?
C00Z C015 1.426(8) . ?
C010 H010 0.9500 . ?
C012 H012 0.9500 . ?
C012 C015 1.400(8) . ?
C013 C016 1.385(8) . ?
C013 C026 1.445(8) . ?
C014 C01R 1.434(8) . ?
C015 C01Y 1.429(8) . ?
C016 H016 0.9500 . ?
C016 C02C 1.410(8) . ?
C017 C01X 1.428(9) . ?
C017 C02D 1.415(9) . ?
C017 C035 1.494(9) . ?
C018 H018 0.9500 . ?
C01A C01K 1.542(8) . ?
C01B H01B 0.9500 . ?
C01C H01C 0.9500 . ?
C01D H01D 0.9500 . ?
C01D C01H 1.431(8) . ?
C01D C029 1.342(8) . ?
C01E C027 1.541(8) . ?
C01F C01G 1.398(8) . ?
C01F C01H 1.480(8) . ?
C01F C02B 1.391(8) . ?
C01G H01G 0.9500 . ?
C01G C022 1.394(8) . ?
C01L C01W 1.407(9) . ?
C01L C02K 1.429(9) . ?
C01L C02Y 1.495(9) . ?
C01O C01U 1.406(9) . ?
C01O C01W 1.443(9) . ?
C01O C03R 1.528(9) . ?
C01P H01P 0.9500 . ?
C01P C01Q 1.358(8) . ?
C01P C01Y 1.419(8) . ?
C01Q H01Q 0.9500 . ?
C01R H01R 0.9500 . ?
C01R C02G 1.358(9) . ?
C01T C01V 1.492(8) . ?
C01T C02I 1.402(9) . ?
C01T C02X 1.391(9) . ?
C01U C02K 1.437(9) . ?
C01U C03D 1.507(10) . ?
C01V C02Q 1.416(9) . ?
C01V C02R 1.382(8) . ?
C01W C03E 1.486(10) . ?
C01X C02W 1.434(9) . ?
C01X C03F 1.504(9) . ?
C01Y C028 1.392(8) . ?
C01Z C028 1.395(8) . ?
C01Z C029 1.417(8) . ?
C020 C02L 1.435(10) . ?
C020 C037 1.410(11) . ?
C020 C03A 1.474(10) . ?
C021 C02C 1.427(8) . ?
C021 C02P 1.438(9) . ?
C021 C02T 1.398(9) . ?
C022 H022 0.9500 . ?
C023 H023 0.9500 . ?
C023 C02B 1.362(8) . ?
C024 H024 0.9500 . ?
C024 C02I 1.365(9) . ?
C026 C02G 1.416(9) . ?
C026 C02T 1.380(8) . ?
C028 H028 0.9500 . ?
C029 H029 0.9500 . ?
C02B H02B 0.9500 . ?
C02C C02R 1.429(8) . ?
C02D C02M 1.426(10) . ?
C02D C03B 1.512(10) . ?
C02F H02F 0.9500 . ?
C02F C02X 1.374(9) . ?
C02G H02G 0.9500 . ?
C02I H02I 0.9500 . ?
C02K C03N 1.502(9) . ?
C02L C036 1.424(10) . ?
C02L C039 1.543(11) . ?
C02M C02W 1.418(10) . ?
C02M C03O 1.509(9) . ?
C02N C02S 1.407(11) . ?
C02N C030 1.449(10) . ?
C02N C03S 1.519(11) . ?
C02O C02V 1.425(9) . ?
C02O C030 1.413(9) . ?
C02O C03H 1.485(9) . ?
C02P H02P 0.9500 . ?
C02P C02Q 1.367(9) . ?
C02Q H02Q 0.9500 . ?
C02R H02R 0.9500 . ?
C02S C02V 1.421(10) . ?
C02S C03J 1.495(10) . ?
C02T H02T 0.9500 . ?
C02V C03V 1.495(10) . ?
C02W C03Q 1.539(11) . ?
C02X H02X 0.9500 . ?
C02Y H02A 0.9800 . ?
C02Y H02C 0.9800 . ?
C02Y H02D 0.9800 . ?
C030 C03G 1.499(10) . ?
C035 H03A 0.9800 . ?
C035 H03B 0.9800 . ?
C035 H03C 0.9800 . ?
C036 C03C 1.408(11) . ?
C036 C03I 1.512(11) . ?
C037 C03C 1.494(11) . ?
C037 C03M 1.505(12) . ?
C039 H03D 0.9800 . ?
C039 H03E 0.9800 . ?
C039 H03F 0.9800 . ?
C03A H03G 0.9800 . ?
C03A H03H 0.9800 . ?
C03A H03I 0.9800 . ?
C03B H03J 0.9800 . ?
C03B H03K 0.9800 . ?
C03B H03L 0.9800 . ?
C03C C03P 1.478(11) . ?
C03D H03M 0.9800 . ?
C03D H03N 0.9800 . ?
C03D H03O 0.9800 . ?
C03E H03P 0.9800 . ?
C03E H03Q 0.9800 . ?
C03E H03R 0.9800 . ?
C03F H03S 0.9800 . ?
C03F H03T 0.9800 . ?
C03F H03U 0.9800 . ?
C03G H03V 0.9800 . ?
C03G H03W 0.9800 . ?
C03G H03X 0.9800 . ?
C03H H03Y 0.9800 . ?
C03H H 0.9800 . ?
C03H HA 0.9800 . ?
C03I H03Z 0.9800 . ?
C03I HB 0.9800 . ?
C03I HC 0.9800 . ?
C03J H03 0.9800 . ?
C03J HD 0.9800 . ?
C03J HE 0.9800 . ?
C03L N03U 1.201(13) . ?
C03L C03X 1.395(14) . ?
C03M H1 0.9800 . ?
C03M HF 0.9800 . ?
C03M HG 0.9800 . ?
C03N H2 0.9800 . ?
C03N HH 0.9800 . ?
C03N HI 0.9800 . ?
C03O H3 0.9800 . ?
C03O HJ 0.9800 . ?
C03O HK 0.9800 . ?
C03P H4 0.9800 . ?
C03P HL 0.9800 . ?
C03P HM 0.9800 . ?
C03Q H5 0.9800 . ?
C03Q HN 0.9800 . ?
C03Q HO 0.9800 . ?
C03R H6 0.9800 . ?
C03R HP 0.9800 . ?
C03R HQ 0.9800 . ?
C03S H7 0.9800 . ?
C03S HR 0.9800 . ?
C03S HS 0.9800 . ?
C03V H8 0.9800 . ?
C03V HT 0.9800 . ?
C03V HU 0.9800 . ?
C03W H10 0.9800 . ?
C03W HV 0.9800 . ?
C03W HW 0.9800 . ?
C03W C03Y 1.411(13) . ?
C03X H9 0.9800 . ?
C03X HX 0.9800 . ?
C03X HY 0.9800 . ?
C03Y N03Z 1.116(12) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O009 Rh00 O00B 78.18(13) . . ?
O009 Rh00 C01U 133.4(2) . . ?
O009 Rh00 C01W 99.5(2) . . ?
O00B Rh00 C01U 148.3(2) . . ?
N00J Rh00 O009 87.21(16) . . ?
N00J Rh00 O00B 85.73(16) . . ?
N00J Rh00 C01L 143.1(2) . . ?
N00J Rh00 C01U 93.4(2) . . ?
N00J Rh00 C01W 156.5(2) . . ?
C01L Rh00 O009 129.5(2) . . ?
C01L Rh00 O00B 97.18(19) . . ?
C01L Rh00 C01U 65.4(2) . . ?
C01L Rh00 C01W 38.4(2) . . ?
C01O Rh00 O009 101.6(2) . . ?
C01O Rh00 O00B 157.2(2) . . ?
C01O Rh00 N00J 117.0(2) . . ?
C01O Rh00 C01L 65.1(2) . . ?
C01O Rh00 C01U 38.5(3) . . ?
C01O Rh00 C01W 39.7(2) . . ?
C01O Rh00 C02K 65.4(2) . . ?
C01W Rh00 O00B 117.6(2) . . ?
C01W Rh00 C01U 65.7(3) . . ?
C02K Rh00 O009 164.9(2) . . ?
C02K Rh00 O00B 110.6(2) . . ?
C02K Rh00 N00J 105.4(2) . . ?
C02K Rh00 C01L 39.3(2) . . ?
C02K Rh00 C01U 39.3(2) . . ?
C02K Rh00 C01W 65.7(2) . . ?
O00A Rh1 C02D 124.1(2) . . ?
O00D Rh1 O00A 78.18(14) . . ?
O00D Rh1 C02D 97.8(2) . . ?
N00H Rh1 O00A 83.59(16) . . ?
N00H Rh1 O00D 85.47(17) . . ?
N00H Rh1 C017 151.5(2) . . ?
N00H Rh1 C02D 152.3(2) . . ?
N00H Rh1 C02M 113.6(2) . . ?
N00H Rh1 C02W 95.4(2) . . ?
C017 Rh1 O00A 97.81(19) . . ?
C017 Rh1 O00D 122.8(2) . . ?
C017 Rh1 C02D 38.5(2) . . ?
C01X Rh1 O00A 104.4(2) . . ?
C01X Rh1 O00D 161.9(2) . . ?
C01X Rh1 N00H 112.6(2) . . ?
C01X Rh1 C017 39.3(2) . . ?
C01X Rh1 C02D 65.7(3) . . ?
C01X Rh1 C02M 66.0(3) . . ?
C01X Rh1 C02W 39.5(3) . . ?
C02M Rh1 O00A 162.3(2) . . ?
C02M Rh1 O00D 106.4(2) . . ?
C02M Rh1 C017 65.2(2) . . ?
C02M Rh1 C02D 39.1(3) . . ?
C02M Rh1 C02W 38.9(3) . . ?
C02W Rh1 O00A 140.0(2) . . ?
C02W Rh1 O00D 141.7(2) . . ?
C02W Rh1 C017 65.4(3) . . ?
C02W Rh1 C02D 65.3(3) . . ?
O00G Rh2 O00E 78.47(15) . . ?
O00G Rh2 C02N 117.1(3) . . ?
O00G Rh2 C02S 95.7(2) . . ?
N00I Rh2 O00E 83.75(17) . . ?
N00I Rh2 O00G 84.91(17) . . ?
N00I Rh2 C02N 157.9(3) . . ?
N00I Rh2 C02S 145.7(3) . . ?
C02N Rh2 O00E 100.8(2) . . ?
C02O Rh2 O00E 135.1(2) . . ?
C02O Rh2 O00G 146.4(2) . . ?
C02O Rh2 N00I 95.8(2) . . ?
C02O Rh2 C02N 65.6(2) . . ?
C02O Rh2 C02S 65.4(2) . . ?
C02S Rh2 O00E 130.1(3) . . ?
C02S Rh2 C02N 38.3(3) . . ?
C02V Rh2 O00E 166.2(2) . . ?
C02V Rh2 O00G 108.6(2) . . ?
C02V Rh2 N00I 108.3(2) . . ?
C02V Rh2 C02N 65.5(3) . . ?
C02V Rh2 C02O 39.4(3) . . ?
C02V Rh2 C02S 39.1(3) . . ?
C02V Rh2 C030 66.0(3) . . ?
C030 Rh2 O00E 102.8(2) . . ?
C030 Rh2 O00G 156.9(2) . . ?
C030 Rh2 N00I 118.2(2) . . ?
C030 Rh2 C02N 39.7(3) . . ?
C030 Rh2 C02O 38.9(3) . . ?
C030 Rh2 C02S 65.5(3) . . ?
O00C Rh3 O00F 78.51(15) . . ?
O00C Rh3 C02L 103.8(2) . . ?
O00C Rh3 C036 95.2(2) . . ?
O00F Rh3 C036 143.2(3) . . ?
N00K Rh3 O00C 85.02(18) . . ?
N00K Rh3 O00F 85.67(17) . . ?
N00K Rh3 C020 134.6(3) . . ?
N00K Rh3 C02L 165.7(3) . . ?
N00K Rh3 C036 130.4(3) . . ?
N00K Rh3 C03C 100.3(3) . . ?
C020 Rh3 O00C 139.9(2) . . ?
C020 Rh3 O00F 96.0(2) . . ?
C020 Rh3 C02L 39.4(3) . . ?
C020 Rh3 C036 65.6(3) . . ?
C020 Rh3 C03C 66.6(3) . . ?
C02L Rh3 O00F 106.9(2) . . ?
C02L Rh3 C036 38.8(3) . . ?
C037 Rh3 O00C 160.8(3) . . ?
C037 Rh3 O00F 119.4(3) . . ?
C037 Rh3 N00K 102.2(3) . . ?
C037 Rh3 C020 38.9(3) . . ?
C037 Rh3 C02L 66.0(3) . . ?
C037 Rh3 C036 66.4(3) . . ?
C037 Rh3 C03C 41.3(3) . . ?
C03C Rh3 O00C 120.2(3) . . ?
C03C Rh3 O00F 160.5(3) . . ?
C03C Rh3 C02L 65.6(3) . . ?
C03C Rh3 C036 38.5(3) . . ?
F01J P005 F00W 89.1(4) . . ?
F01J P005 F01M 88.9(4) . . ?
F01J P005 F034 172.8(5) . . ?
F01M P005 F00W 88.7(4) . . ?
F02E P005 F00W 87.2(4) . . ?
F02E P005 F01J 93.3(5) . . ?
F02E P005 F01M 175.3(5) . . ?
F02E P005 F032 94.9(5) . . ?
F02E P005 F034 90.3(5) . . ?
F032 P005 F00W 177.2(5) . . ?
F032 P005 F01J 92.7(5) . . ?
F032 P005 F01M 89.2(5) . . ?
F032 P005 F034 93.2(5) . . ?
F034 P005 F00W 84.8(5) . . ?
F034 P005 F01M 87.1(5) . . ?
F00L P006 F019 89.1(3) . . ?
F00N P006 F00L 90.0(3) . . ?
F00N P006 F00U 92.8(4) . . ?
F00N P006 F019 89.9(4) . . ?
F00N P006 F01I 177.7(4) . . ?
F00N P006 F02A 90.6(3) . . ?
F00U P006 F00L 90.2(3) . . ?
F00U P006 F019 177.2(4) . . ?
F00U P006 F02A 90.3(4) . . ?
F01I P006 F00L 91.0(4) . . ?
F01I P006 F00U 89.2(4) . . ?
F01I P006 F019 88.1(3) . . ?
F01I P006 F02A 88.4(4) . . ?
F02A P006 F00L 179.2(4) . . ?
F02A P006 F019 90.4(4) . . ?
F011 P007 F033 92.6(5) . . ?
F025 P007 F011 174.9(4) . . ?
F025 P007 F02J 87.2(4) . . ?
F025 P007 F02U 88.2(4) . . ?
F025 P007 F031 92.0(4) . . ?
F025 P007 F033 89.9(4) . . ?
F02J P007 F011 88.4(4) . . ?
F02J P007 F033 88.4(4) . . ?
F02U P007 F011 89.4(4) . . ?
F02U P007 F02J 92.5(5) . . ?
F02U P007 F031 89.3(5) . . ?
F02U P007 F033 177.8(5) . . ?
F031 P007 F011 92.5(4) . . ?
F031 P007 F02J 178.0(4) . . ?
F031 P007 F033 89.8(5) . . ?
F01N P008 F01S 88.5(5) . . ?
F01N P008 F02H 89.9(4) . . ?
F01N P008 F038 179.3(6) . . ?
F02H P008 F01S 90.0(4) . . ?
F02H P008 F038 90.2(4) . . ?
F02Z P008 F01N 90.2(4) . . ?
F02Z P008 F01S 178.7(5) . . ?
F02Z P008 F02H 89.8(4) . . ?
F02Z P008 F038 90.4(5) . . ?
F02Z P008 F03K 93.9(5) . . ?
F038 P008 F01S 90.9(4) . . ?
F03K P008 F01N 87.4(4) . . ?
F03K P008 F01S 86.2(5) . . ?
F03K P008 F02H 175.5(6) . . ?
F03K P008 F038 92.4(5) . . ?
C01E O009 Rh00 113.5(3) . . ?
C01E O00A Rh1 112.4(3) . . ?
C027 O00B Rh00 112.1(3) . . ?
C01K O00C Rh3 113.5(4) . . ?
C027 O00D Rh1 112.9(3) . . ?
C01A O00E Rh2 111.8(4) . . ?
C01A O00F Rh3 112.7(4) . . ?
C01K O00G Rh2 113.7(4) . . ?
C018 N00H Rh1 118.7(4) . . ?
C01B N00H Rh1 123.9(4) . . ?
C01B N00H C018 117.3(5) . . ?
C022 N00I Rh2 121.9(4) . . ?
C022 N00I C023 118.1(5) . . ?
C023 N00I Rh2 120.0(4) . . ?
C010 N00J Rh00 119.6(4) . . ?
C01C N00J Rh00 120.9(4) . . ?
C01C N00J C010 117.7(5) . . ?
C024 N00K Rh3 120.6(4) . . ?
C024 N00K C02F 116.2(6) . . ?
C02F N00K Rh3 123.2(4) . . ?
C00Z C00M C00T 120.0(5) . . ?
C00Z C00M C01Q 119.0(5) . . ?
C01Q C00M C00T 120.9(5) . . ?
C00V C00O C014 123.4(5) . . ?
C00Y C00O C00V 116.3(5) . . ?
C00Y C00O C014 120.3(5) . . ?
C013 C00P H00P 118.5 . . ?
C014 C00P H00P 118.5 . . ?
C014 C00P C013 123.0(6) . . ?
C00T C00Q H00Q 120.3 . . ?
C010 C00Q H00Q 120.3 . . ?
C010 C00Q C00T 119.3(5) . . ?
C00S C00R H00R 119.1 . . ?
C01H C00R H00R 119.1 . . ?
C01H C00R C00S 121.8(5) . . ?
C00R C00S C012 122.0(5) . . ?
C00R C00S C01Z 118.6(5) . . ?
C012 C00S C01Z 119.4(5) . . ?
C00Q C00T C00M 121.8(5) . . ?
C00Q C00T C00X 116.6(5) . . ?
C00X C00T C00M 121.6(5) . . ?
C00O C00V H00V 120.0 . . ?
C01B C00V C00O 120.0(5) . . ?
C01B C00V H00V 120.0 . . ?
C00T C00X H00X 120.2 . . ?
C01C C00X C00T 119.7(5) . . ?
C01C C00X H00X 120.2 . . ?
C00O C00Y H00Y 120.2 . . ?
C018 C00Y C00O 119.6(6) . . ?
C018 C00Y H00Y 120.2 . . ?
C00M C00Z H00Z 119.6 . . ?
C00M C00Z C015 120.8(5) . . ?
C015 C00Z H00Z 119.6 . . ?
N00J C010 C00Q 123.0(5) . . ?
N00J C010 H010 118.5 . . ?
C00Q C010 H010 118.5 . . ?
C00S C012 H012 119.2 . . ?
C015 C012 C00S 121.6(5) . . ?
C015 C012 H012 119.2 . . ?
C00P C013 C026 118.1(5) . . ?
C016 C013 C00P 122.5(6) . . ?
C016 C013 C026 119.4(5) . . ?
C00P C014 C00O 121.5(5) . . ?
C00P C014 C01R 118.2(6) . . ?
C01R C014 C00O 120.3(6) . . ?
C00Z C015 C01Y 119.8(5) . . ?
C012 C015 C00Z 121.1(5) . . ?
C012 C015 C01Y 119.1(5) . . ?
C013 C016 H016 119.3 . . ?
C013 C016 C02C 121.3(5) . . ?
C02C C016 H016 119.3 . . ?
C01X C017 Rh1 69.0(3) . . ?
C01X C017 C035 125.4(6) . . ?
C02D C017 Rh1 70.9(3) . . ?
C02D C017 C01X 108.4(6) . . ?
C02D C017 C035 126.2(7) . . ?
C035 C017 Rh1 123.9(4) . . ?
N00H C018 C00Y 123.5(5) . . ?
N00H C018 H018 118.3 . . ?
C00Y C018 H018 118.3 . . ?
O00E C01A O00F 124.4(6) . . ?
O00E C01A C01K 118.5(5) . . ?
O00F C01A C01K 117.1(5) . . ?
N00H C01B C00V 123.3(6) . . ?
N00H C01B H01B 118.3 . . ?
C00V C01B H01B 118.3 . . ?
N00J C01C C00X 123.4(5) . . ?
N00J C01C H01C 118.3 . . ?
C00X C01C H01C 118.3 . . ?
C01H C01D H01D 119.6 . . ?
C029 C01D H01D 119.6 . . ?
C029 C01D C01H 120.8(6) . . ?
O009 C01E C027 116.4(5) . . ?
O00A C01E O009 125.3(5) . . ?
O00A C01E C027 118.3(5) . . ?
C01G C01F C01H 121.8(5) . . ?
C02B C01F C01G 117.4(5) . . ?
C02B C01F C01H 120.9(5) . . ?
C01F C01G H01G 120.2 . . ?
C022 C01G C01F 119.5(6) . . ?
C022 C01G H01G 120.2 . . ?
C00R C01H C01D 118.8(6) . . ?
C00R C01H C01F 120.5(5) . . ?
C01D C01H C01F 120.7(5) . . ?
O00C C01K O00G 124.9(6) . . ?
O00C C01K C01A 118.1(5) . . ?
O00G C01K C01A 117.0(5) . . ?
C01W C01L Rh00 71.0(4) . . ?
C01W C01L C02K 109.0(6) . . ?
C01W C01L C02Y 126.1(6) . . ?
C02K C01L Rh00 69.7(3) . . ?
C02K C01L C02Y 124.8(6) . . ?
C02Y C01L Rh00 122.7(4) . . ?
C01U C01O Rh00 72.1(3) . . ?
C01U C01O C01W 109.4(6) . . ?
C01U C01O C03R 125.0(7) . . ?
C01W C01O Rh00 71.2(3) . . ?
C01W C01O C03R 125.6(7) . . ?
C03R C01O Rh00 123.9(5) . . ?
C01Q C01P H01P 119.1 . . ?
C01Q C01P C01Y 121.7(6) . . ?
C01Y C01P H01P 119.1 . . ?
C00M C01Q H01Q 119.4 . . ?
C01P C01Q C00M 121.2(6) . . ?
C01P C01Q H01Q 119.4 . . ?
C014 C01R H01R 119.4 . . ?
C02G C01R C014 121.1(6) . . ?
C02G C01R H01R 119.4 . . ?
C02I C01T C01V 119.6(6) . . ?
C02X C01T C01V 122.8(6) . . ?
C02X C01T C02I 117.5(6) . . ?
C01O C01U Rh00 69.4(3) . . ?
C01O C01U C02K 107.1(6) . . ?
C01O C01U C03D 126.9(7) . . ?
C02K C01U Rh00 69.2(3) . . ?
C02K C01U C03D 125.9(7) . . ?
C03D C01U Rh00 123.1(5) . . ?
C02Q C01V C01T 119.9(6) . . ?
C02R C01V C01T 120.5(6) . . ?
C02R C01V C02Q 119.6(6) . . ?
C01L C01W Rh00 70.5(4) . . ?
C01L C01W C01O 106.7(6) . . ?
C01L C01W C03E 127.5(7) . . ?
C01O C01W Rh00 69.2(4) . . ?
C01O C01W C03E 125.8(7) . . ?
C03E C01W Rh00 126.6(4) . . ?
C017 C01X Rh1 71.7(3) . . ?
C017 C01X C02W 107.6(6) . . ?
C017 C01X C03F 125.4(7) . . ?
C02W C01X Rh1 71.4(3) . . ?
C02W C01X C03F 126.9(7) . . ?
C03F C01X Rh1 124.6(4) . . ?
C01P C01Y C015 117.5(5) . . ?
C028 C01Y C015 118.7(5) . . ?
C028 C01Y C01P 123.8(6) . . ?
C028 C01Z C00S 117.8(5) . . ?
C028 C01Z C029 123.7(5) . . ?
C029 C01Z C00S 118.4(5) . . ?
C02L C020 Rh3 70.7(4) . . ?
C02L C020 C03A 124.6(8) . . ?
C037 C020 Rh3 70.1(4) . . ?
C037 C020 C02L 108.9(7) . . ?
C037 C020 C03A 126.5(8) . . ?
C03A C020 Rh3 123.7(5) . . ?
C02C C021 C02P 117.9(6) . . ?
C02T C021 C02C 119.9(6) . . ?
C02T C021 C02P 122.2(6) . . ?
N00I C022 C01G 122.1(6) . . ?
N00I C022 H022 118.9 . . ?
C01G C022 H022 118.9 . . ?
N00I C023 H023 118.3 . . ?
N00I C023 C02B 123.3(6) . . ?
C02B C023 H023 118.3 . . ?
N00K C024 H024 117.4 . . ?
N00K C024 C02I 125.2(6) . . ?
C02I C024 H024 117.4 . . ?
C02G C026 C013 118.2(5) . . ?
C02T C026 C013 119.3(6) . . ?
C02T C026 C02G 122.5(6) . . ?
O00B C027 O00D 124.8(5) . . ?
O00B C027 C01E 118.6(5) . . ?
O00D C027 C01E 116.6(5) . . ?
C01Y C028 C01Z 123.3(5) . . ?
C01Y C028 H028 118.3 . . ?
C01Z C028 H028 118.3 . . ?
C01D C029 C01Z 121.5(6) . . ?
C01D C029 H029 119.3 . . ?
C01Z C029 H029 119.3 . . ?
C01F C02B H02B 120.2 . . ?
C023 C02B C01F 119.6(6) . . ?
C023 C02B H02B 120.2 . . ?
C016 C02C C021 118.7(6) . . ?
C016 C02C C02R 121.3(6) . . ?
C021 C02C C02R 120.0(6) . . ?
C017 C02D Rh1 70.6(3) . . ?
C017 C02D C02M 107.8(7) . . ?
C017 C02D C03B 126.3(7) . . ?
C02M C02D Rh1 69.5(4) . . ?
C02M C02D C03B 125.8(7) . . ?
C03B C02D Rh1 123.1(4) . . ?
N00K C02F H02F 118.5 . . ?
N00K C02F C02X 123.0(6) . . ?
C02X C02F H02F 118.5 . . ?
C01R C02G C026 121.4(6) . . ?
C01R C02G H02G 119.3 . . ?
C026 C02G H02G 119.3 . . ?
C01T C02I H02I 120.9 . . ?
C024 C02I C01T 118.3(6) . . ?
C024 C02I H02I 120.9 . . ?
C01L C02K Rh00 71.0(3) . . ?
C01L C02K C01U 107.7(6) . . ?
C01L C02K C03N 126.6(6) . . ?
C01U C02K Rh00 71.5(3) . . ?
C01U C02K C03N 125.5(6) . . ?
C03N C02K Rh00 126.3(5) . . ?
C020 C02L Rh3 69.9(4) . . ?
C020 C02L C039 127.7(7) . . ?
C036 C02L Rh3 71.0(4) . . ?
C036 C02L C020 108.1(8) . . ?
C036 C02L C039 124.2(8) . . ?
C039 C02L Rh3 124.7(5) . . ?
C02D C02M Rh1 71.5(3) . . ?
C02D C02M C03O 125.6(8) . . ?
C02W C02M Rh1 71.2(3) . . ?
C02W C02M C02D 108.6(6) . . ?
C02W C02M C03O 125.7(8) . . ?
C03O C02M Rh1 125.7(4) . . ?
C02S C02N Rh2 70.6(4) . . ?
C02S C02N C030 107.5(6) . . ?
C02S C02N C03S 129.8(9) . . ?
C030 C02N Rh2 69.2(4) . . ?
C030 C02N C03S 122.6(9) . . ?
C03S C02N Rh2 124.9(5) . . ?
C02V C02O Rh2 69.6(3) . . ?
C02V C02O C03H 125.5(7) . . ?
C030 C02O Rh2 70.5(3) . . ?
C030 C02O C02V 108.2(6) . . ?
C030 C02O C03H 126.3(7) . . ?
C03H C02O Rh2 124.6(4) . . ?
C021 C02P H02P 119.7 . . ?
C02Q C02P C021 120.6(6) . . ?
C02Q C02P H02P 119.7 . . ?
C01V C02Q H02Q 119.2 . . ?
C02P C02Q C01V 121.6(6) . . ?
C02P C02Q H02Q 119.2 . . ?
C01V C02R C02C 120.2(6) . . ?
C01V C02R H02R 119.9 . . ?
C02C C02R H02R 119.9 . . ?
C02N C02S Rh2 71.0(4) . . ?
C02N C02S C02V 108.7(6) . . ?
C02N C02S C03J 124.8(8) . . ?
C02V C02S Rh2 69.0(4) . . ?
C02V C02S C03J 126.4(9) . . ?
C03J C02S Rh2 122.2(4) . . ?
C021 C02T H02T 119.3 . . ?
C026 C02T C021 121.4(6) . . ?
C026 C02T H02T 119.3 . . ?
C02O C02V Rh2 71.0(3) . . ?
C02O C02V C03V 125.0(8) . . ?
C02S C02V Rh2 71.8(4) . . ?
C02S C02V C02O 107.9(6) . . ?
C02S C02V C03V 126.9(8) . . ?
C03V C02V Rh2 125.7(4) . . ?
C01X C02W Rh1 69.1(3) . . ?
C01X C02W C03Q 125.8(8) . . ?
C02M C02W Rh1 69.9(4) . . ?
C02M C02W C01X 107.5(6) . . ?
C02M C02W C03Q 126.7(7) . . ?
C03Q C02W Rh1 125.0(5) . . ?
C01T C02X H02X 120.1 . . ?
C02F C02X C01T 119.8(7) . . ?
C02F C02X H02X 120.1 . . ?
C01L C02Y H02A 109.5 . . ?
C01L C02Y H02C 109.5 . . ?
C01L C02Y H02D 109.5 . . ?
H02A C02Y H02C 109.5 . . ?
H02A C02Y H02D 109.5 . . ?
H02C C02Y H02D 109.5 . . ?
C02N C030 Rh2 71.0(4) . . ?
C02N C030 C03G 123.4(8) . . ?
C02O C030 Rh2 70.6(3) . . ?
C02O C030 C02N 107.6(6) . . ?
C02O C030 C03G 129.0(7) . . ?
C03G C030 Rh2 124.8(5) . . ?
C017 C035 H03A 109.5 . . ?
C017 C035 H03B 109.5 . . ?
C017 C035 H03C 109.5 . . ?
H03A C035 H03B 109.5 . . ?
H03A C035 H03C 109.5 . . ?
H03B C035 H03C 109.5 . . ?
C02L C036 Rh3 70.1(4) . . ?
C02L C036 C03I 125.0(8) . . ?
C03C C036 Rh3 69.9(4) . . ?
C03C C036 C02L 109.1(8) . . ?
C03C C036 C03I 125.8(8) . . ?
C03I C036 Rh3 123.6(5) . . ?
C020 C037 Rh3 71.0(4) . . ?
C020 C037 C03C 106.8(7) . . ?
C020 C037 C03M 127.3(8) . . ?
C03C C037 Rh3 69.8(4) . . ?
C03C C037 C03M 125.9(9) . . ?
C03M C037 Rh3 126.1(6) . . ?
C02L C039 H03D 109.5 . . ?
C02L C039 H03E 109.5 . . ?
C02L C039 H03F 109.5 . . ?
H03D C039 H03E 109.5 . . ?
H03D C039 H03F 109.5 . . ?
H03E C039 H03F 109.5 . . ?
C020 C03A H03G 109.5 . . ?
C020 C03A H03H 109.5 . . ?
C020 C03A H03I 109.5 . . ?
H03G C03A H03H 109.5 . . ?
H03G C03A H03I 109.5 . . ?
H03H C03A H03I 109.5 . . ?
C02D C03B H03J 109.5 . . ?
C02D C03B H03K 109.5 . . ?
C02D C03B H03L 109.5 . . ?
H03J C03B H03K 109.5 . . ?
H03J C03B H03L 109.5 . . ?
H03K C03B H03L 109.5 . . ?
C036 C03C Rh3 71.6(4) . . ?
C036 C03C C037 107.0(7) . . ?
C036 C03C C03P 128.4(9) . . ?
C037 C03C Rh3 68.9(4) . . ?
C03P C03C Rh3 127.9(6) . . ?
C03P C03C C037 124.4(9) . . ?
C01U C03D H03M 109.5 . . ?
C01U C03D H03N 109.5 . . ?
C01U C03D H03O 109.5 . . ?
H03M C03D H03N 109.5 . . ?
H03M C03D H03O 109.5 . . ?
H03N C03D H03O 109.5 . . ?
C01W C03E H03P 109.5 . . ?
C01W C03E H03Q 109.5 . . ?
C01W C03E H03R 109.5 . . ?
H03P C03E H03Q 109.5 . . ?
H03P C03E H03R 109.5 . . ?
H03Q C03E H03R 109.5 . . ?
C01X C03F H03S 109.5 . . ?
C01X C03F H03T 109.5 . . ?
C01X C03F H03U 109.5 . . ?
H03S C03F H03T 109.5 . . ?
H03S C03F H03U 109.5 . . ?
H03T C03F H03U 109.5 . . ?
C030 C03G H03V 109.5 . . ?
C030 C03G H03W 109.5 . . ?
C030 C03G H03X 109.5 . . ?
H03V C03G H03W 109.5 . . ?
H03V C03G H03X 109.5 . . ?
H03W C03G H03X 109.5 . . ?
C02O C03H H03Y 109.5 . . ?
C02O C03H H 109.5 . . ?
C02O C03H HA 109.5 . . ?
H03Y C03H H 109.5 . . ?
H03Y C03H HA 109.5 . . ?
H C03H HA 109.5 . . ?
C036 C03I H03Z 109.5 . . ?
C036 C03I HB 109.5 . . ?
C036 C03I HC 109.5 . . ?
H03Z C03I HB 109.5 . . ?
H03Z C03I HC 109.5 . . ?
HB C03I HC 109.5 . . ?
C02S C03J H03 109.5 . . ?
C02S C03J HD 109.5 . . ?
C02S C03J HE 109.5 . . ?
H03 C03J HD 109.5 . . ?
H03 C03J HE 109.5 . . ?
HD C03J HE 109.5 . . ?
N03U C03L C03X 174.8(14) . . ?
C037 C03M H1 109.5 . . ?
C037 C03M HF 109.5 . . ?
C037 C03M HG 109.5 . . ?
H1 C03M HF 109.5 . . ?
H1 C03M HG 109.5 . . ?
HF C03M HG 109.5 . . ?
C02K C03N H2 109.5 . . ?
C02K C03N HH 109.5 . . ?
C02K C03N HI 109.5 . . ?
H2 C03N HH 109.5 . . ?
H2 C03N HI 109.5 . . ?
HH C03N HI 109.5 . . ?
C02M C03O H3 109.5 . . ?
C02M C03O HJ 109.5 . . ?
C02M C03O HK 109.5 . . ?
H3 C03O HJ 109.5 . . ?
H3 C03O HK 109.5 . . ?
HJ C03O HK 109.5 . . ?
C03C C03P H4 109.5 . . ?
C03C C03P HL 109.5 . . ?
C03C C03P HM 109.5 . . ?
H4 C03P HL 109.5 . . ?
H4 C03P HM 109.5 . . ?
HL C03P HM 109.5 . . ?
C02W C03Q H5 109.5 . . ?
C02W C03Q HN 109.5 . . ?
C02W C03Q HO 109.5 . . ?
H5 C03Q HN 109.5 . . ?
H5 C03Q HO 109.5 . . ?
HN C03Q HO 109.5 . . ?
C01O C03R H6 109.5 . . ?
C01O C03R HP 109.5 . . ?
C01O C03R HQ 109.5 . . ?
H6 C03R HP 109.5 . . ?
H6 C03R HQ 109.5 . . ?
HP C03R HQ 109.5 . . ?
C02N C03S H7 109.5 . . ?
C02N C03S HR 109.5 . . ?
C02N C03S HS 109.5 . . ?
H7 C03S HR 109.5 . . ?
H7 C03S HS 109.5 . . ?
HR C03S HS 109.5 . . ?
C02V C03V H8 109.5 . . ?
C02V C03V HT 109.5 . . ?
C02V C03V HU 109.5 . . ?
H8 C03V HT 109.5 . . ?
H8 C03V HU 109.5 . . ?
HT C03V HU 109.5 . . ?
H10 C03W HV 109.5 . . ?
H10 C03W HW 109.5 . . ?
HV C03W HW 109.5 . . ?
C03Y C03W H10 109.5 . . ?
C03Y C03W HV 109.5 . . ?
C03Y C03W HW 109.5 . . ?
C03L C03X H9 109.5 . . ?
C03L C03X HX 109.5 . . ?
C03L C03X HY 109.5 . . ?
H9 C03X HX 109.5 . . ?
H9 C03X HY 109.5 . . ?
HX C03X HY 109.5 . . ?
N03Z C03Y C03W 178.4(19) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Rh00 O009 C01E O00A 174.5(5) . . . . ?
Rh00 O009 C01E C027 -5.8(6) . . . . ?
Rh00 O00B C027 O00D -169.1(5) . . . . ?
Rh00 O00B C027 C01E 9.8(6) . . . . ?
Rh00 N00J C010 C00Q 161.5(4) . . . . ?
Rh00 N00J C01C C00X -160.8(4) . . . . ?
Rh00 C01L C01W C01O 60.0(4) . . . . ?
Rh00 C01L C01W C03E -121.8(7) . . . . ?
Rh00 C01L C02K C01U -62.4(4) . . . . ?
Rh00 C01L C02K C03N 121.7(6) . . . . ?
Rh00 C01O C01U C02K 59.2(4) . . . . ?
Rh00 C01O C01U C03D -116.6(7) . . . . ?
Rh00 C01O C01W C01L -60.9(4) . . . . ?
Rh00 C01O C01W C03E 120.8(6) . . . . ?
Rh00 C01U C02K C01L 62.1(4) . . . . ?
Rh00 C01U C02K C03N -121.9(7) . . . . ?
Rh1 O00A C01E O009 -168.1(5) . . . . ?
Rh1 O00A C01E C027 12.1(6) . . . . ?
Rh1 O00D C027 O00B 172.6(5) . . . . ?
Rh1 O00D C027 C01E -6.2(6) . . . . ?
Rh1 N00H C018 C00Y 177.0(5) . . . . ?
Rh1 N00H C01B C00V -177.2(4) . . . . ?
Rh1 C017 C01X C02W -62.8(4) . . . . ?
Rh1 C017 C01X C03F 119.9(6) . . . . ?
Rh1 C017 C02D C02M 59.8(4) . . . . ?
Rh1 C017 C02D C03B -117.3(6) . . . . ?
Rh1 C01X C02W C02M -59.5(4) . . . . ?
Rh1 C01X C02W C03Q 118.8(6) . . . . ?
Rh1 C02D C02M C02W 61.9(4) . . . . ?
Rh1 C02D C02M C03O -121.2(6) . . . . ?
Rh1 C02M C02W C01X 59.0(4) . . . . ?
Rh1 C02M C02W C03Q -119.3(6) . . . . ?
Rh2 O00E C01A O00F -172.8(5) . . . . ?
Rh2 O00E C01A C01K 4.7(6) . . . . ?
Rh2 O00G C01K O00C 173.0(5) . . . . ?
Rh2 O00G C01K C01A -6.7(6) . . . . ?
Rh2 N00I C022 C01G -179.3(4) . . . . ?
Rh2 N00I C023 C02B 178.4(4) . . . . ?
Rh2 C02N C02S C02V 59.0(4) . . . . ?
Rh2 C02N C02S C03J -116.6(6) . . . . ?
Rh2 C02N C030 C02O -61.4(4) . . . . ?
Rh2 C02N C030 C03G 119.8(6) . . . . ?
Rh2 C02O C02V C02S -62.7(4) . . . . ?
Rh2 C02O C02V C03V 120.8(6) . . . . ?
Rh2 C02O C030 C02N 61.7(4) . . . . ?
Rh2 C02O C030 C03G -119.6(7) . . . . ?
Rh2 C02S C02V C02O 62.2(4) . . . . ?
Rh2 C02S C02V C03V -121.4(6) . . . . ?
Rh3 O00C C01K O00G 179.3(5) . . . . ?
Rh3 O00C C01K C01A -1.0(7) . . . . ?
Rh3 O00F C01A O00E 179.6(5) . . . . ?
Rh3 O00F C01A C01K 2.0(6) . . . . ?
Rh3 N00K C024 C02I 178.2(5) . . . . ?
Rh3 N00K C02F C02X -177.2(5) . . . . ?
Rh3 C020 C02L C036 -61.0(5) . . . . ?
Rh3 C020 C02L C039 118.9(8) . . . . ?
Rh3 C020 C037 C03C 60.9(4) . . . . ?
Rh3 C020 C037 C03M -121.3(8) . . . . ?
Rh3 C02L C036 C03C -59.2(5) . . . . ?
Rh3 C02L C036 C03I 117.7(7) . . . . ?
Rh3 C036 C03C C037 -60.1(4) . . . . ?
Rh3 C036 C03C C03P 124.3(8) . . . . ?
Rh3 C037 C03C C036 61.9(5) . . . . ?
Rh3 C037 C03C C03P -122.3(8) . . . . ?
O009 C01E C027 O00B -2.9(8) . . . . ?
O009 C01E C027 O00D 176.0(5) . . . . ?
O00A C01E C027 O00B 176.8(5) . . . . ?
O00A C01E C027 O00D -4.2(8) . . . . ?
O00E C01A C01K O00C -178.4(5) . . . . ?
O00E C01A C01K O00G 1.3(8) . . . . ?
O00F C01A C01K O00C -0.7(8) . . . . ?
O00F C01A C01K O00G 179.0(5) . . . . ?
N00I C023 C02B C01F 0.2(9) . . . . ?
N00K C024 C02I C01T -1.5(9) . . . . ?
N00K C02F C02X C01T -0.3(10) . . . . ?
C00M C00T C00X C01C 174.9(5) . . . . ?
C00M C00Z C015 C012 179.9(5) . . . . ?
C00M C00Z C015 C01Y 0.6(7) . . . . ?
C00O C00V C01B N00H 1.5(9) . . . . ?
C00O C00Y C018 N00H -0.6(9) . . . . ?
C00O C014 C01R C02G 179.7(5) . . . . ?
C00P C013 C016 C02C 179.5(5) . . . . ?
C00P C013 C026 C02G -0.8(7) . . . . ?
C00P C013 C026 C02T -179.6(5) . . . . ?
C00P C014 C01R C02G -1.1(8) . . . . ?
C00Q C00T C00X C01C -4.9(8) . . . . ?
C00R C00S C012 C015 179.6(5) . . . . ?
C00R C00S C01Z C028 -179.3(5) . . . . ?
C00R C00S C01Z C029 3.0(7) . . . . ?
C00S C00R C01H C01D -2.2(8) . . . . ?
C00S C00R C01H C01F 177.3(5) . . . . ?
C00S C012 C015 C00Z 179.2(5) . . . . ?
C00S C012 C015 C01Y -1.5(7) . . . . ?
C00S C01Z C028 C01Y 1.1(8) . . . . ?
C00S C01Z C029 C01D -2.9(8) . . . . ?
C00T C00M C00Z C015 -177.5(4) . . . . ?
C00T C00M C01Q C01P 178.4(5) . . . . ?
C00T C00Q C010 N00J -1.4(8) . . . . ?
C00T C00X C01C N00J 0.5(8) . . . . ?
C00V C00O C00Y C018 0.9(8) . . . . ?
C00V C00O C014 C00P 148.9(6) . . . . ?
C00V C00O C014 C01R -31.9(8) . . . . ?
C00Y C00O C00V C01B -1.3(8) . . . . ?
C00Y C00O C014 C00P -30.9(8) . . . . ?
C00Y C00O C014 C01R 148.3(5) . . . . ?
C00Z C00M C00T C00Q 150.2(5) . . . . ?
C00Z C00M C00T C00X -29.6(7) . . . . ?
C00Z C00M C01Q C01P 1.4(8) . . . . ?
C00Z C015 C01Y C01P -1.6(7) . . . . ?
C00Z C015 C01Y C028 -178.1(5) . . . . ?
C010 N00J C01C C00X 3.6(8) . . . . ?
C010 C00Q C00T C00M -174.5(5) . . . . ?
C010 C00Q C00T C00X 5.3(8) . . . . ?
C012 C00S C01Z C028 0.1(7) . . . . ?
C012 C00S C01Z C029 -177.6(5) . . . . ?
C012 C015 C01Y C01P 179.1(5) . . . . ?
C012 C015 C01Y C028 2.6(7) . . . . ?
C013 C00P C014 C00O -179.9(5) . . . . ?
C013 C00P C014 C01R 0.9(8) . . . . ?
C013 C016 C02C C021 0.9(8) . . . . ?
C013 C016 C02C C02R -177.5(5) . . . . ?
C013 C026 C02G C01R 0.7(8) . . . . ?
C013 C026 C02T C021 -0.6(8) . . . . ?
C014 C00O C00V C01B 178.9(5) . . . . ?
C014 C00O C00Y C018 -179.3(5) . . . . ?
C014 C00P C013 C016 178.0(5) . . . . ?
C014 C00P C013 C026 0.0(8) . . . . ?
C014 C01R C02G C026 0.3(9) . . . . ?
C015 C01Y C028 C01Z -2.5(8) . . . . ?
C016 C013 C026 C02G -178.9(5) . . . . ?
C016 C013 C026 C02T 2.4(7) . . . . ?
C016 C02C C02R C01V 176.5(5) . . . . ?
C017 C01X C02W Rh1 63.0(4) . . . . ?
C017 C01X C02W C02M 3.5(6) . . . . ?
C017 C01X C02W C03Q -178.2(6) . . . . ?
C017 C02D C02M Rh1 -60.5(4) . . . . ?
C017 C02D C02M C02W 1.4(6) . . . . ?
C017 C02D C02M C03O 178.4(5) . . . . ?
C018 N00H C01B C00V -1.2(8) . . . . ?
C01B N00H C018 C00Y 0.7(8) . . . . ?
C01C N00J C010 C00Q -3.1(8) . . . . ?
C01F C01G C022 N00I 1.6(9) . . . . ?
C01G C01F C01H C00R 140.9(6) . . . . ?
C01G C01F C01H C01D -39.6(8) . . . . ?
C01G C01F C02B C023 0.3(8) . . . . ?
C01H C00R C00S C012 -179.9(5) . . . . ?
C01H C00R C00S C01Z -0.5(8) . . . . ?
C01H C01D C029 C01Z 0.2(9) . . . . ?
C01H C01F C01G C022 177.9(5) . . . . ?
C01H C01F C02B C023 -178.8(5) . . . . ?
C01O C01U C02K Rh00 -59.3(4) . . . . ?
C01O C01U C02K C01L 2.8(7) . . . . ?
C01O C01U C02K C03N 178.8(6) . . . . ?
C01P C01Y C028 C01Z -178.7(5) . . . . ?
C01Q C00M C00T C00Q -26.8(7) . . . . ?
C01Q C00M C00T C00X 153.4(5) . . . . ?
C01Q C00M C00Z C015 -0.4(7) . . . . ?
C01Q C01P C01Y C015 2.6(8) . . . . ?
C01Q C01P C01Y C028 178.9(5) . . . . ?
C01T C01V C02Q C02P 176.4(5) . . . . ?
C01T C01V C02R C02C -175.2(5) . . . . ?
C01U C01O C01W Rh00 62.3(4) . . . . ?
C01U C01O C01W C01L 1.4(7) . . . . ?
C01U C01O C01W C03E -176.9(6) . . . . ?
C01V C01T C02I C024 -176.0(5) . . . . ?
C01V C01T C02X C02F 176.7(5) . . . . ?
C01W C01L C02K Rh00 60.4(4) . . . . ?
C01W C01L C02K C01U -2.0(7) . . . . ?
C01W C01L C02K C03N -177.9(6) . . . . ?
C01W C01O C01U Rh00 -61.8(4) . . . . ?
C01W C01O C01U C02K -2.6(7) . . . . ?
C01W C01O C01U C03D -178.3(6) . . . . ?
C01X C017 C02D Rh1 -59.0(4) . . . . ?
C01X C017 C02D C02M 0.8(6) . . . . ?
C01X C017 C02D C03B -176.3(5) . . . . ?
C01Y C01P C01Q C00M -2.5(8) . . . . ?
C01Z C00S C012 C015 0.2(7) . . . . ?
C020 C02L C036 Rh3 60.3(5) . . . . ?
C020 C02L C036 C03C 1.1(8) . . . . ?
C020 C02L C036 C03I 178.0(7) . . . . ?
C020 C037 C03C Rh3 -61.7(5) . . . . ?
C020 C037 C03C C036 0.1(8) . . . . ?
C020 C037 C03C C03P 176.0(7) . . . . ?
C021 C02C C02R C01V -1.8(8) . . . . ?
C021 C02P C02Q C01V -0.4(9) . . . . ?
C022 N00I C023 C02B 0.1(8) . . . . ?
C023 N00I C022 C01G -1.1(8) . . . . ?
C024 N00K C02F C02X 0.3(9) . . . . ?
C026 C013 C016 C02C -2.5(7) . . . . ?
C028 C01Z C029 C01D 179.6(5) . . . . ?
C029 C01D C01H C00R 2.4(8) . . . . ?
C029 C01D C01H C01F -177.1(5) . . . . ?
C029 C01Z C028 C01Y 178.6(5) . . . . ?
C02B C01F C01G C022 -1.2(8) . . . . ?
C02B C01F C01H C00R -40.0(8) . . . . ?
C02B C01F C01H C01D 139.5(6) . . . . ?
C02C C021 C02P C02Q 1.6(8) . . . . ?
C02C C021 C02T C026 -1.1(8) . . . . ?
C02D C017 C01X Rh1 60.2(4) . . . . ?
C02D C017 C01X C02W -2.6(6) . . . . ?
C02D C017 C01X C03F -179.9(5) . . . . ?
C02D C02M C02W Rh1 -62.1(4) . . . . ?
C02D C02M C02W C01X -3.0(6) . . . . ?
C02D C02M C02W C03Q 178.7(6) . . . . ?
C02F N00K C024 C02I 0.6(9) . . . . ?
C02G C026 C02T C021 -179.3(5) . . . . ?
C02I C01T C01V C02Q -35.9(8) . . . . ?
C02I C01T C01V C02R 142.4(6) . . . . ?
C02I C01T C02X C02F -0.5(9) . . . . ?
C02K C01L C01W Rh00 -59.6(4) . . . . ?
C02K C01L C01W C01O 0.4(7) . . . . ?
C02K C01L C01W C03E 178.6(6) . . . . ?
C02L C020 C037 Rh3 -60.4(5) . . . . ?
C02L C020 C037 C03C 0.5(8) . . . . ?
C02L C020 C037 C03M 178.3(7) . . . . ?
C02L C036 C03C Rh3 59.3(5) . . . . ?
C02L C036 C03C C037 -0.8(8) . . . . ?
C02L C036 C03C C03P -176.4(7) . . . . ?
C02N C02S C02V Rh2 -60.2(4) . . . . ?
C02N C02S C02V C02O 2.0(7) . . . . ?
C02N C02S C02V C03V 178.4(6) . . . . ?
C02P C021 C02C C016 -178.9(5) . . . . ?
C02P C021 C02C C02R -0.5(8) . . . . ?
C02P C021 C02T C026 178.7(5) . . . . ?
C02Q C01V C02R C02C 3.0(8) . . . . ?
C02R C01V C02Q C02P -1.9(8) . . . . ?
C02S C02N C030 Rh2 60.5(4) . . . . ?
C02S C02N C030 C02O -0.9(7) . . . . ?
C02S C02N C030 C03G -179.7(6) . . . . ?
C02T C021 C02C C016 1.0(8) . . . . ?
C02T C021 C02C C02R 179.3(5) . . . . ?
C02T C021 C02P C02Q -178.2(6) . . . . ?
C02T C026 C02G C01R 179.4(5) . . . . ?
C02V C02O C030 Rh2 -59.6(4) . . . . ?
C02V C02O C030 C02N 2.1(6) . . . . ?
C02V C02O C030 C03G -179.2(6) . . . . ?
C02X C01T C01V C02Q 147.0(6) . . . . ?
C02X C01T C01V C02R -34.8(8) . . . . ?
C02X C01T C02I C024 1.3(8) . . . . ?
C02Y C01L C01W Rh00 117.2(6) . . . . ?
C02Y C01L C01W C01O 177.2(6) . . . . ?
C02Y C01L C01W C03E -4.5(10) . . . . ?
C02Y C01L C02K Rh00 -116.5(6) . . . . ?
C02Y C01L C02K C01U -178.9(6) . . . . ?
C02Y C01L C02K C03N 5.2(10) . . . . ?
C030 C02N C02S Rh2 -59.6(4) . . . . ?
C030 C02N C02S C02V -0.7(7) . . . . ?
C030 C02N C02S C03J -176.2(6) . . . . ?
C030 C02O C02V Rh2 60.2(4) . . . . ?
C030 C02O C02V C02S -2.5(6) . . . . ?
C030 C02O C02V C03V -179.1(6) . . . . ?
C035 C017 C01X Rh1 -117.3(5) . . . . ?
C035 C017 C01X C02W 179.8(5) . . . . ?
C035 C017 C01X C03F 2.6(9) . . . . ?
C035 C017 C02D Rh1 118.5(6) . . . . ?
C035 C017 C02D C02M 178.3(5) . . . . ?
C035 C017 C02D C03B 1.2(9) . . . . ?
C037 C020 C02L Rh3 60.0(5) . . . . ?
C037 C020 C02L C036 -1.0(8) . . . . ?
C037 C020 C02L C039 178.9(7) . . . . ?
C039 C02L C036 Rh3 -119.6(7) . . . . ?
C039 C02L C036 C03C -178.8(7) . . . . ?
C039 C02L C036 C03I -1.9(11) . . . . ?
C03A C020 C02L Rh3 -118.2(7) . . . . ?
C03A C020 C02L C036 -179.3(7) . . . . ?
C03A C020 C02L C039 0.7(12) . . . . ?
C03A C020 C037 Rh3 117.8(7) . . . . ?
C03A C020 C037 C03C 178.7(7) . . . . ?
C03A C020 C037 C03M -3.5(12) . . . . ?
C03B C02D C02M Rh1 116.6(6) . . . . ?
C03B C02D C02M C02W 178.5(5) . . . . ?
C03B C02D C02M C03O -4.5(9) . . . . ?
C03D C01U C02K Rh00 116.5(6) . . . . ?
C03D C01U C02K C01L 178.6(6) . . . . ?
C03D C01U C02K C03N -5.4(10) . . . . ?
C03F C01X C02W Rh1 -119.8(6) . . . . ?
C03F C01X C02W C02M -179.3(5) . . . . ?
C03F C01X C02W C03Q -1.0(9) . . . . ?
C03H C02O C02V Rh2 -118.6(6) . . . . ?
C03H C02O C02V C02S 178.7(5) . . . . ?
C03H C02O C02V C03V 2.2(9) . . . . ?
C03H C02O C030 Rh2 119.1(6) . . . . ?
C03H C02O C030 C02N -179.1(6) . . . . ?
C03H C02O C030 C03G -0.4(10) . . . . ?
C03I C036 C03C Rh3 -117.5(7) . . . . ?
C03I C036 C03C C037 -177.6(7) . . . . ?
C03I C036 C03C C03P 6.8(12) . . . . ?
C03J C02S C02V Rh2 115.2(6) . . . . ?
C03J C02S C02V C02O 177.4(6) . . . . ?
C03J C02S C02V C03V -6.1(10) . . . . ?
C03M C037 C03C Rh3 120.5(8) . . . . ?
C03M C037 C03C C036 -177.6(7) . . . . ?
C03M C037 C03C C03P -1.8(12) . . . . ?
C03O C02M C02W Rh1 121.0(6) . . . . ?
C03O C02M C02W C01X -180.0(5) . . . . ?
C03O C02M C02W C03Q 1.7(10) . . . . ?
C03R C01O C01U Rh00 119.3(6) . . . . ?
C03R C01O C01U C02K 178.5(6) . . . . ?
C03R C01O C01U C03D 2.7(10) . . . . ?
C03R C01O C01W Rh00 -118.8(6) . . . . ?
C03R C01O C01W C01L -179.7(6) . . . . ?
C03R C01O C01W C03E 2.1(10) . . . . ?
C03S C02N C02S Rh2 119.8(7) . . . . ?
C03S C02N C02S C02V 178.7(6) . . . . ?
C03S C02N C02S C03J 3.2(11) . . . . ?
C03S C02N C030 Rh2 -118.9(6) . . . . ?
C03S C02N C030 C02O 179.6(6) . . . . ?
C03S C02N C030 C03G 0.9(9) . . . . ?

_platon_squeeze_details          ?
_platon_squeeze_special_details  ?
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 0.000 0.000 0.000 552 198 ' '
2 0.733 -0.035 0.147 59 13 ' '
3 0.425 0.074 0.208 110 46 ' '
4 0.925 0.074 0.292 110 46 ' '
5 0.233 -0.035 0.353 59 13 ' '
6 0.500 0.000 0.500 552 198 ' '
7 0.767 0.035 0.647 59 13 ' '
8 0.075 -0.074 0.708 110 46 ' '
9 0.575 -0.074 0.792 110 46 ' '
10 0.267 0.035 0.853 59 13 ' '
11 0.010 0.136 0.660 11 4 ' '
12 0.510 0.136 0.840 11 4 ' '
13 1.000 0.500 0.500 553 198 ' '
14 0.500 0.500 1.000 552 198 ' '
15 0.425 0.426 0.708 110 46 ' '
16 0.925 0.426 0.792 110 46 ' '
17 0.010 0.364 0.160 11 4 ' '
18 0.510 0.364 0.340 11 4 ' '
19 0.767 0.465 0.147 59 13 ' '
20 0.267 0.465 0.353 59 13 ' '
21 0.733 0.535 0.647 59 13 ' '
22 0.233 0.535 0.853 58 13 ' '
23 0.075 0.574 0.208 109 46 ' '
24 0.575 0.574 0.292 109 46 ' '
25 0.490 0.636 0.660 12 4 ' '
26 0.990 0.636 0.840 12 4 ' '
27 0.490 0.864 0.160 12 4 ' '
28 -0.010 0.864 0.340 12 4 ' '

_platon_squeeze_void_probe_radius 1.20
_olex2_submission_special_instructions 'No special instructions were received'
