# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2022

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_a
_database_code_depnum_ccdc_archive 'CCDC 2156753'
loop_
_audit_author_name
_audit_author_address
TeLnNb
;Fuzhou University
China
;
_audit_update_record             
;
2022-03-08 deposited with the CCDC.	2022-06-20 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C20 H121 Cu5 Eu N20 Nb18 O84 Te6'
_chemical_formula_weight         4894.00

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Nb Nb -2.0727 0.6215 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Te Te -0.5308 1.6751 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           11
_space_group_name_H-M_alt        'P 21/m'
_space_group_name_Hall           '-P 2yb'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z'
'-x, -y, -z'
'x, -y-1/2, z'

_cell_length_a                   13.7123(7)
_cell_length_b                   34.3657(15)
_cell_length_c                   19.9008(10)
_cell_angle_alpha                90
_cell_angle_beta                 92.736(2)
_cell_angle_gamma                90
_cell_volume                     9367.2(8)
_cell_formula_units_Z            2
_cell_measurement_temperature    150(2)
_cell_measurement_reflns_used    185273
_cell_measurement_theta_min      2.474
_cell_measurement_theta_max      25.086

_exptl_crystal_description       BLOCK
_exptl_crystal_colour            PURPLE
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.735
_exptl_crystal_F_000             4622
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.3
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.2
_exptl_absorpt_coefficient_mu    2.921
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   EMPIRICAL
_exptl_absorpt_correction_T_min  0.6241
_exptl_absorpt_correction_T_max  0.7452
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      150(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            184527
_diffrn_reflns_av_unetI/netI     0.0208
_diffrn_reflns_av_R_equivalents  0.0505
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_k_min       -40
_diffrn_reflns_limit_k_max       40
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_theta_min         1.901
_diffrn_reflns_theta_max         25.101
_diffrn_reflns_theta_full        25.101
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measured_fraction_theta_full 0.995
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_Laue_measured_fraction_full 0.995
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_point_group_measured_fraction_full 0.995
_reflns_number_total             16908
_reflns_number_gt                14664
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0612P)²+105.4588P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         16908
_refine_ls_number_parameters     706
_refine_ls_number_restraints     7
_refine_ls_R_factor_all          0.0610
_refine_ls_R_factor_gt           0.0541
_refine_ls_wR_factor_ref         0.1415
_refine_ls_wR_factor_gt          0.1372
_refine_ls_goodness_of_fit_ref   1.064
_refine_ls_restrained_S_all      1.067
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.87286(4) 0.750000 0.31431(3) 0.03291(14) Uani 1 2 d S T P . .
Te1 Te 1.01201(3) 0.65035(2) 0.22980(2) 0.02527(11) Uani 1 1 d . . . . .
Te2 Te 1.28440(4) 0.70005(2) 0.28574(3) 0.03580(14) Uani 1 1 d . . . . .
Te3 Te 0.95524(5) 0.69959(2) 0.03752(3) 0.04101(15) Uani 1 1 d . . . . .
Nb1 Nb 0.92974(6) 0.65681(2) 0.40125(4) 0.03754(18) Uani 1 1 d . . . . .
Nb2 Nb 0.81467(6) 0.63007(2) 0.09111(4) 0.03882(19) Uani 1 1 d . . . . .
Nb3 Nb 0.86358(5) 0.57126(2) 0.32341(4) 0.03486(17) Uani 1 1 d . . . . .
Nb4 Nb 0.75581(5) 0.65587(2) 0.26983(4) 0.03694(18) Uani 1 1 d . . . . .
Nb5 Nb 1.25754(5) 0.61710(2) 0.20888(4) 0.03106(16) Uani 1 1 d . . . . .
Nb6 Nb 1.12369(5) 0.54992(2) 0.29069(3) 0.02856(15) Uani 1 1 d . . . . .
Nb7 Nb 1.06502(6) 0.61631(2) 0.06256(4) 0.03381(17) Uani 1 1 d . . . . .
Nb8 Nb 0.93482(5) 0.54861(2) 0.15040(4) 0.03219(16) Uani 1 1 d . . . . .
Nb9 Nb 1.19594(6) 0.63193(2) 0.37931(4) 0.03439(17) Uani 1 1 d . . . . .
Cu1 Cu 0.58193(8) 0.56611(4) 0.27842(8) 0.0575(3) Uani 1 1 d . . . . .
Cu2 Cu 1.17921(8) 0.45675(3) 0.10973(6) 0.0472(3) Uani 1 1 d . . . . .
Cu3 Cu 1.000000 0.500000 0.500000 0.0410(4) Uani 1 2 d S . P . .
O1W O 1.0416(5) 0.4662(2) 0.0444(3) 0.0554(17) Uani 1 1 d . . . . .
O1 O 0.9144(6) 0.6768(2) 0.4820(3) 0.063(2) Uani 1 1 d . . . . .
O2 O 1.2459(4) 0.56521(15) 0.2395(3) 0.0316(12) Uani 1 1 d . . . . .
O2W O 1.5076(5) 0.750000 0.0067(4) 0.0379(18) Uani 1 2 d S TU P . .
O3 O 1.0003(4) 0.55736(15) 0.3329(3) 0.0331(12) Uani 1 1 d . . . . .
O3W O 1.3047(5) 0.5300(2) 0.4547(3) 0.0528(17) Uani 1 1 d . . . . .
O4 O 1.0248(4) 0.56431(16) 0.0733(3) 0.0369(13) Uani 1 1 d . . . . .
O4W O 0.8146(6) 0.4305(2) 0.1184(4) 0.069(2) Uani 1 1 d . . . . .
O5 O 1.1138(4) 0.61855(15) 0.2670(3) 0.0277(11) Uani 1 1 d . . . . .
O5W O 0.8185(6) 0.5248(3) 0.4980(4) 0.075(2) Uani 1 1 d . . . . .
O6 O 1.1935(4) 0.57698(16) 0.3708(3) 0.0353(12) Uani 1 1 d . . . . .
O6W O 0.4132(5) 0.5246(2) 0.2620(5) 0.072(2) Uani 1 1 d . . . . .
O7 O 0.9669(4) 0.61837(15) 0.1576(3) 0.0294(11) Uani 1 1 d . . . . .
O7W O 0.4316(6) 0.4844(3) 0.3879(5) 0.077(2) Uani 1 1 d . . . . .
O8 O 0.8617(4) 0.68879(16) 0.1002(3) 0.0392(13) Uani 1 1 d . . . . .
O9 O 0.9184(4) 0.63244(14) 0.2880(3) 0.0297(11) Uani 1 1 d . . . . .
O10 O 0.9810(7) 0.750000 0.0851(4) 0.043(2) Uani 1 2 d S T P . .
O11 O 1.2981(4) 0.63671(15) 0.3046(3) 0.0346(12) Uani 1 1 d . . . . .
O12 O 0.8614(4) 0.55547(17) 0.2301(3) 0.0383(13) Uani 1 1 d . . . . .
O13 O 1.0554(4) 0.54241(15) 0.2052(3) 0.0330(12) Uani 1 1 d . . . . .
O14 O 1.2194(6) 0.750000 0.2605(5) 0.044(2) Uani 1 2 d S T P . .
O15 O 1.2313(4) 0.67832(15) 0.2062(3) 0.0336(12) Uani 1 1 d . . . . .
O16 O 0.6881(7) 0.750000 0.3134(5) 0.053(2) Uani 1 2 d S T P . .
O17 O 1.1545(4) 0.50138(15) 0.3137(3) 0.0362(12) Uani 1 1 d . . . . .
O18 O 1.1852(4) 0.69037(15) 0.3452(3) 0.0363(13) Uani 1 1 d . . . . .
O19 O 1.0120(5) 0.750000 0.2284(4) 0.0307(16) Uani 1 2 d S T P . .
O20 O 1.0671(4) 0.67803(16) 0.0804(3) 0.0384(13) Uani 1 1 d . . . . .
O21 O 1.3742(4) 0.61783(17) 0.1741(3) 0.0452(15) Uani 1 1 d . . . . .
O22 O 0.9899(4) 0.70389(15) 0.3505(3) 0.0352(12) Uani 1 1 d . . . . .
O23 O 0.8337(4) 0.70254(16) 0.2318(3) 0.0371(13) Uani 1 1 d . . . . .
O24 O 1.1721(4) 0.61627(15) 0.1296(3) 0.0352(12) Uani 1 1 d . . . . .
O25 O 0.9293(5) 0.63487(16) 0.0269(3) 0.0413(14) Uani 1 1 d . . . . .
O26 O 1.0675(4) 0.64025(17) 0.4076(3) 0.0394(13) Uani 1 1 d . . . . .
O27 O 0.7422(4) 0.60442(17) 0.3031(4) 0.0460(15) Uani 1 1 d . . . . .
O28 O 0.8078(4) 0.67931(17) 0.3561(3) 0.0376(13) Uani 1 1 d . . . . .
O29 O 0.9102(4) 0.49978(16) 0.1275(3) 0.0411(14) Uani 1 1 d . . . . .
O30 O 0.7564(4) 0.63845(17) 0.1750(3) 0.0417(14) Uani 1 1 d . . . . .
O31 O 0.8297(4) 0.57526(16) 0.0936(3) 0.0422(14) Uani 1 1 d . . . . .
O32 O 0.8790(4) 0.60509(17) 0.4076(3) 0.0422(14) Uani 1 1 d . . . . .
O33 O 0.8089(4) 0.52965(17) 0.3607(3) 0.0445(14) Uani 1 1 d . . . . .
O34 O 1.2684(5) 0.63917(19) 0.4541(4) 0.0582(19) Uani 1 1 d . . . . .
O35 O 1.1278(5) 0.61580(17) -0.0127(3) 0.0500(17) Uani 1 1 d . . . . .
O36 O 0.8465(8) 0.750000 0.4392(5) 0.055(2) Uani 1 2 d S T P . .
O37 O 0.6353(4) 0.67543(18) 0.2719(4) 0.0533(17) Uani 1 1 d . . . . .
O38 O 0.7175(5) 0.6359(2) 0.0305(4) 0.063(2) Uani 1 1 d . . . . .
N1 N 0.6454(7) 0.5198(3) 0.2342(7) 0.084(4) Uani 1 1 d D . . . .
H1A H 0.708742 0.518988 0.246162 0.101 Uiso 1 1 calc R U . . .
H1B H 0.618087 0.497776 0.247630 0.101 Uiso 1 1 calc R U . . .
N2 N 0.5668(6) 0.5856(3) 0.1840(5) 0.062(2) Uani 1 1 d . . . . .
H2A H 0.507047 0.595230 0.176664 0.075 Uiso 1 1 calc R U . . .
H2B H 0.609446 0.604668 0.178075 0.075 Uiso 1 1 calc R U . . .
N3 N 0.5984(6) 0.5457(3) 0.3713(6) 0.071(3) Uani 1 1 d . . . . .
H3A H 0.555989 0.526524 0.376841 0.085 Uiso 1 1 calc R U . . .
H3B H 0.658293 0.536090 0.377871 0.085 Uiso 1 1 calc R U . . .
N4 N 0.5118(5) 0.6104(2) 0.3222(5) 0.055(2) Uani 1 1 d . . . . .
H4A H 0.545676 0.632329 0.318637 0.066 Uiso 1 1 calc R U . . .
H4B H 0.453164 0.613823 0.301951 0.066 Uiso 1 1 calc R U . . .
N5 N 1.2648(7) 0.4579(3) 0.0301(5) 0.073(3) Uani 1 1 d . . . . .
H5A H 1.323774 0.448514 0.041484 0.088 Uiso 1 1 calc R U . . .
H5B H 1.238625 0.443680 -0.003425 0.088 Uiso 1 1 calc R U . . .
N6 N 1.1586(8) 0.3979(3) 0.1072(5) 0.070(3) Uani 1 1 d . . . . .
H6A H 1.149340 0.389743 0.064904 0.084 Uiso 1 1 calc R U . . .
H6B H 1.210486 0.385717 0.125713 0.084 Uiso 1 1 calc R U . . .
N7 N 1.2036(6) 0.5142(2) 0.1146(4) 0.050(2) Uani 1 1 d . . . . .
H7A H 1.148632 0.527001 0.103623 0.060 Uiso 1 1 calc R U . . .
H7B H 1.222611 0.520820 0.156452 0.060 Uiso 1 1 calc R U . . .
N8 N 1.0957(7) 0.4537(2) 0.1904(4) 0.058(2) Uani 1 1 d . . . . .
H8A H 1.125118 0.466272 0.224812 0.070 Uiso 1 1 calc R U . . .
H8B H 1.038617 0.465304 0.180817 0.070 Uiso 1 1 calc R U . . .
N9 N 0.9901(6) 0.4810(2) 0.4032(3) 0.0419(17) Uani 1 1 d . . . . .
H9A H 0.937963 0.491404 0.381809 0.050 Uiso 1 1 calc R U . . .
H9B H 1.042868 0.488204 0.382041 0.050 Uiso 1 1 calc R U . . .
N10 N 1.0414(6) 0.5547(2) 0.4785(3) 0.0431(17) Uani 1 1 d . . . . .
H10A H 1.085652 0.554165 0.447204 0.052 Uiso 1 1 calc R U . . .
H10B H 0.990111 0.568238 0.462460 0.052 Uiso 1 1 calc R U . . .
C1 C 0.6325(15) 0.5234(6) 0.1614(7) 0.140(8) Uani 1 1 d D . . . .
H1C H 0.696955 0.523622 0.143331 0.168 Uiso 1 1 calc R U . . .
H1D H 0.599944 0.500037 0.144768 0.168 Uiso 1 1 calc R U . . .
C2 C 0.5831(11) 0.5540(4) 0.1350(8) 0.096(5) Uani 1 1 d . . . . .
H2C H 0.520349 0.545120 0.116433 0.116 Uiso 1 1 calc R U . . .
H2D H 0.618985 0.564537 0.098198 0.116 Uiso 1 1 calc R U . . .
C3 C 0.5828(12) 0.5764(5) 0.4211(8) 0.097(5) Uani 1 1 d . . . . .
H3C H 0.641542 0.591751 0.428822 0.116 Uiso 1 1 calc R U . . .
H3D H 0.565080 0.565076 0.463504 0.116 Uiso 1 1 calc R U . . .
C4 C 0.5019(11) 0.6009(5) 0.3922(8) 0.093(5) Uani 1 1 d . . . . .
H4C H 0.440548 0.587330 0.396838 0.111 Uiso 1 1 calc R U . . .
H4D H 0.499233 0.624876 0.417800 0.111 Uiso 1 1 calc R U . . .
C5 C 1.2722(11) 0.5012(5) 0.0085(7) 0.094(5) Uani 1 1 d . . . . .
H5C H 1.329468 0.504982 -0.017577 0.113 Uiso 1 1 calc R U . . .
H5D H 1.214987 0.508444 -0.019246 0.113 Uiso 1 1 calc R U . . .
C6 C 1.0689(13) 0.3896(4) 0.1467(6) 0.091(5) Uani 1 1 d . . . . .
H6C H 1.010087 0.396770 0.120621 0.109 Uiso 1 1 calc R U . . .
H6D H 1.065525 0.362220 0.157868 0.109 Uiso 1 1 calc R U . . .
C7 C 1.2791(10) 0.5252(4) 0.0686(7) 0.074(3) Uani 1 1 d . . . . .
H7C H 1.271411 0.552350 0.056179 0.089 Uiso 1 1 calc R U . . .
H7D H 1.343024 0.521980 0.090916 0.089 Uiso 1 1 calc R U . . .
C8 C 1.0791(12) 0.4136(4) 0.2091(7) 0.082(4) Uani 1 1 d . . . . .
H8C H 1.020280 0.411637 0.234047 0.098 Uiso 1 1 calc R U . . .
H8D H 1.133581 0.404190 0.237515 0.098 Uiso 1 1 calc R U . . .
C9 C 0.9818(9) 0.4379(3) 0.4026(5) 0.058(3) Uani 1 1 d . . . . .
H9C H 1.045790 0.426089 0.409473 0.070 Uiso 1 1 calc R U . . .
H9D H 0.953128 0.429023 0.359842 0.070 Uiso 1 1 calc R U . . .
C10 C 0.9167(10) 0.4266(3) 0.4597(5) 0.060(3) Uani 1 1 d . . . . .
H10C H 0.850449 0.435620 0.450151 0.073 Uiso 1 1 calc R U . . .
H10D H 0.915513 0.398563 0.465153 0.073 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O22 2.344(5) 4_575 ?
Eu1 O22 2.344(5) . ?
Eu1 O23 2.358(6) . ?
Eu1 O23 2.358(6) 4_575 ?
Eu1 O36 2.528(9) . ?
Eu1 O16 2.533(9) . ?
Eu1 O19 2.622(7) . ?
Eu1 O28 2.732(6) 4_575 ?
Eu1 O28 2.732(6) . ?
Eu1 Nb4 3.6997(8) . ?
Eu1 Nb4 3.6998(8) 4_575 ?
Eu1 Nb1 3.7053(8) 4_575 ?
Te1 O9 1.873(5) . ?
Te1 O7 1.890(5) . ?
Te1 O5 1.895(5) . ?
Te2 O15 1.867(5) . ?
Te2 O18 1.875(6) . ?
Te2 O14 1.988(4) . ?
Te2 O11 2.215(5) . ?
Te2 Nb5 3.2479(9) . ?
Te2 Nb9 3.2613(9) . ?
Te3 O8 1.870(6) . ?
Te3 O20 1.872(6) . ?
Te3 O10 1.997(4) . ?
Te3 O25 2.261(5) . ?
Te3 Nb7 3.2611(9) . ?
Te3 Nb2 3.2800(10) . ?
Nb1 O1 1.769(6) . ?
Nb1 O32 1.915(6) . ?
Nb1 O26 1.971(6) . ?
Nb1 O28 2.014(6) . ?
Nb1 O22 2.097(5) . ?
Nb1 O9 2.403(5) . ?
Nb2 O38 1.766(6) . ?
Nb2 O31 1.895(6) . ?
Nb2 O30 1.907(6) . ?
Nb2 O25 2.079(7) . ?
Nb2 O8 2.124(6) . ?
Nb2 O7 2.451(5) . ?
Nb3 O33 1.792(6) . ?
Nb3 O12 1.933(6) . ?
Nb3 O3 1.935(6) . ?
Nb3 O32 2.041(6) . ?
Nb3 O27 2.041(6) . ?
Nb3 O9 2.353(5) . ?
Nb4 O37 1.786(6) . ?
Nb4 O27 1.900(6) . ?
Nb4 O30 1.980(6) . ?
Nb4 O28 1.998(6) . ?
Nb4 O23 2.089(5) . ?
Nb4 O9 2.382(5) . ?
Nb5 O21 1.774(6) . ?
Nb5 O2 1.894(5) . ?
Nb5 O24 1.921(6) . ?
Nb5 O11 2.071(6) . ?
Nb5 O15 2.135(5) . ?
Nb5 O5 2.333(5) . ?
Nb6 O17 1.775(5) . ?
Nb6 O13 1.920(5) . ?
Nb6 O3 1.941(5) . ?
Nb6 O6 2.044(5) . ?
Nb6 O2 2.070(5) . ?
Nb6 O5 2.408(5) . ?
Nb7 O35 1.763(6) . ?
Nb7 O4 1.885(5) . ?
Nb7 O24 1.935(6) . ?
Nb7 O25 2.061(6) . ?
Nb7 O20 2.150(6) . ?
Nb7 O7 2.373(5) . ?
Nb8 O29 1.767(5) . ?
Nb8 O12 1.934(6) . ?
Nb8 O13 1.949(5) . ?
Nb8 O31 2.010(6) . ?
Nb8 O4 2.085(6) . ?
Nb8 O7 2.440(5) . ?
Nb9 O34 1.767(6) . ?
Nb9 O6 1.896(5) . ?
Nb9 O26 1.897(6) . ?
Nb9 O11 2.098(6) . ?
Nb9 O18 2.123(5) . ?
Nb9 O5 2.497(5) . ?
Cu1 N3 1.980(11) . ?
Cu1 N2 1.997(10) . ?
Cu1 N4 2.020(8) . ?
Cu1 N1 2.035(10) . ?
Cu2 N7 2.006(8) . ?
Cu2 N5 2.017(10) . ?
Cu2 N8 2.018(9) . ?
Cu2 N6 2.043(9) . ?
Cu2 O1W 2.263(7) . ?
Cu3 N10 2.015(7) . ?
Cu3 N10 2.015(7) 3_766 ?
Cu3 N9 2.033(7) 3_766 ?
Cu3 N9 2.033(7) . ?
N1 C1 1.456(9) . ?
N1 H1A 0.8900 . ?
N1 H1B 0.8900 . ?
N2 C2 1.482(15) . ?
N2 H2A 0.8900 . ?
N2 H2B 0.8900 . ?
N3 C3 1.468(17) . ?
N3 H3A 0.8900 . ?
N3 H3B 0.8900 . ?
N4 C4 1.442(17) . ?
N4 H4A 0.8900 . ?
N4 H4B 0.8900 . ?
N5 C5 1.552(19) . ?
N5 H5A 0.8900 . ?
N5 H5B 0.8900 . ?
N6 C6 1.518(18) . ?
N6 H6A 0.8900 . ?
N6 H6B 0.8900 . ?
N7 C7 1.464(14) . ?
N7 H7A 0.8900 . ?
N7 H7B 0.8900 . ?
N8 C8 1.450(15) . ?
N8 H8A 0.8900 . ?
N8 H8B 0.8900 . ?
N9 C9 1.485(11) . ?
N9 H9A 0.8900 . ?
N9 H9B 0.8900 . ?
N10 C10 1.479(12) 3_766 ?
N10 H10A 0.8900 . ?
N10 H10B 0.8900 . ?
C1 C2 1.34(2) . ?
C1 H1C 0.9700 . ?
C1 H1D 0.9700 . ?
C2 H2C 0.9700 . ?
C2 H2D 0.9700 . ?
C3 C4 1.49(2) . ?
C3 H3C 0.9700 . ?
C3 H3D 0.9700 . ?
C4 H4C 0.9700 . ?
C4 H4D 0.9700 . ?
C5 C7 1.452(17) . ?
C5 H5C 0.9700 . ?
C5 H5D 0.9700 . ?
C6 C8 1.490(17) . ?
C6 H6C 0.9700 . ?
C6 H6D 0.9700 . ?
C7 H7C 0.9700 . ?
C7 H7D 0.9700 . ?
C8 H8C 0.9700 . ?
C8 H8D 0.9700 . ?
C9 C10 1.528(14) . ?
C9 H9C 0.9700 . ?
C9 H9D 0.9700 . ?
C10 H10C 0.9700 . ?
C10 H10D 0.9700 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O22 Eu1 O22 85.1(3) 4_575 . ?
O22 Eu1 O23 144.2(2) 4_575 . ?
O22 Eu1 O23 82.88(19) . . ?
O22 Eu1 O23 82.88(19) 4_575 4_575 ?
O22 Eu1 O23 144.2(2) . 4_575 ?
O23 Eu1 O23 87.5(3) . 4_575 ?
O22 Eu1 O36 80.0(2) 4_575 . ?
O22 Eu1 O36 80.0(2) . . ?
O23 Eu1 O36 130.24(18) . . ?
O23 Eu1 O36 130.24(17) 4_575 . ?
O22 Eu1 O16 132.22(17) 4_575 . ?
O22 Eu1 O16 132.22(17) . . ?
O23 Eu1 O16 78.5(2) . . ?
O23 Eu1 O16 78.5(2) 4_575 . ?
O36 Eu1 O16 79.5(3) . . ?
O22 Eu1 O19 72.04(18) 4_575 . ?
O22 Eu1 O19 72.04(18) . . ?
O23 Eu1 O19 72.21(18) . . ?
O23 Eu1 O19 72.21(18) 4_575 . ?
O36 Eu1 O19 141.6(3) . . ?
O16 Eu1 O19 139.0(3) . . ?
O22 Eu1 O28 62.22(18) 4_575 4_575 ?
O22 Eu1 O28 137.42(18) . 4_575 ?
O23 Eu1 O28 139.51(19) . 4_575 ?
O23 Eu1 O28 61.98(18) 4_575 4_575 ?
O36 Eu1 O28 68.67(14) . 4_575 ?
O16 Eu1 O28 70.18(14) . 4_575 ?
O19 Eu1 O28 117.21(11) . 4_575 ?
O22 Eu1 O28 137.42(18) 4_575 . ?
O22 Eu1 O28 62.22(18) . . ?
O23 Eu1 O28 61.98(18) . . ?
O23 Eu1 O28 139.52(19) 4_575 . ?
O36 Eu1 O28 68.67(14) . . ?
O16 Eu1 O28 70.18(14) . . ?
O19 Eu1 O28 117.21(11) . . ?
O28 Eu1 O28 125.6(2) 4_575 . ?
O22 Eu1 Nb4 161.33(13) 4_575 . ?
O22 Eu1 Nb4 76.42(13) . . ?
O23 Eu1 Nb4 31.44(14) . . ?
O23 Eu1 Nb4 110.89(14) 4_575 . ?
O36 Eu1 Nb4 98.89(12) . . ?
O16 Eu1 Nb4 64.91(6) . . ?
O19 Eu1 Nb4 99.49(7) . . ?
O28 Eu1 Nb4 134.93(12) 4_575 . ?
O28 Eu1 Nb4 31.90(12) . . ?
O22 Eu1 Nb4 76.42(13) 4_575 4_575 ?
O22 Eu1 Nb4 161.34(14) . 4_575 ?
O23 Eu1 Nb4 110.89(14) . 4_575 ?
O23 Eu1 Nb4 31.45(14) 4_575 4_575 ?
O36 Eu1 Nb4 98.89(12) . 4_575 ?
O16 Eu1 Nb4 64.91(6) . 4_575 ?
O19 Eu1 Nb4 99.49(7) . 4_575 ?
O28 Eu1 Nb4 31.90(12) 4_575 4_575 ?
O28 Eu1 Nb4 134.93(12) . 4_575 ?
Nb4 Eu1 Nb4 121.93(3) . 4_575 ?
O22 Eu1 Nb1 31.40(14) 4_575 4_575 ?
O22 Eu1 Nb1 108.37(13) . 4_575 ?
O23 Eu1 Nb1 163.51(14) . 4_575 ?
O23 Eu1 Nb1 76.30(14) 4_575 4_575 ?
O36 Eu1 Nb1 65.02(8) . 4_575 ?
O16 Eu1 Nb1 101.03(11) . 4_575 ?
O19 Eu1 Nb1 99.27(8) . 4_575 ?
O28 Eu1 Nb1 32.18(12) 4_575 4_575 ?
O28 Eu1 Nb1 133.70(12) . 4_575 ?
Nb4 Eu1 Nb1 161.20(2) . 4_575 ?
Nb4 Eu1 Nb1 55.617(18) 4_575 4_575 ?
O9 Te1 O7 94.0(2) . . ?
O9 Te1 O5 94.7(2) . . ?
O7 Te1 O5 99.8(2) . . ?
O15 Te2 O18 101.5(2) . . ?
O15 Te2 O14 88.8(3) . . ?
O18 Te2 O14 89.0(3) . . ?
O15 Te2 O11 77.1(2) . . ?
O18 Te2 O11 77.1(2) . . ?
O14 Te2 O11 157.6(3) . . ?
O15 Te2 Nb5 38.61(16) . . ?
O18 Te2 Nb5 94.13(17) . . ?
O14 Te2 Nb5 126.8(2) . . ?
O11 Te2 Nb5 39.11(14) . . ?
O15 Te2 Nb9 93.24(17) . . ?
O18 Te2 Nb9 37.95(16) . . ?
O14 Te2 Nb9 126.2(3) . . ?
O11 Te2 Nb9 39.54(15) . . ?
Nb5 Te2 Nb9 66.54(2) . . ?
O8 Te3 O20 101.0(3) . . ?
O8 Te3 O10 88.1(3) . . ?
O20 Te3 O10 90.3(3) . . ?
O8 Te3 O25 75.9(2) . . ?
O20 Te3 O25 77.0(2) . . ?
O10 Te3 O25 157.1(2) . . ?
O8 Te3 Nb7 92.88(17) . . ?
O20 Te3 Nb7 38.80(17) . . ?
O10 Te3 Nb7 128.3(2) . . ?
O25 Te3 Nb7 38.75(16) . . ?
O8 Te3 Nb2 37.39(17) . . ?
O20 Te3 Nb2 92.58(18) . . ?
O10 Te3 Nb2 124.8(3) . . ?
O25 Te3 Nb2 38.86(16) . . ?
Nb7 Te3 Nb2 65.49(2) . . ?
O1 Nb1 O32 104.0(3) . . ?
O1 Nb1 O26 102.1(3) . . ?
O32 Nb1 O26 94.4(3) . . ?
O1 Nb1 O28 97.1(3) . . ?
O32 Nb1 O28 95.1(3) . . ?
O26 Nb1 O28 155.8(2) . . ?
O1 Nb1 O22 101.8(3) . . ?
O32 Nb1 O22 154.2(2) . . ?
O26 Nb1 O22 81.7(2) . . ?
O28 Nb1 O22 80.0(2) . . ?
O1 Nb1 O9 169.2(3) . . ?
O32 Nb1 O9 74.4(2) . . ?
O26 Nb1 O9 88.8(2) . . ?
O28 Nb1 O9 72.6(2) . . ?
O22 Nb1 O9 79.99(19) . . ?
O1 Nb1 Eu1 93.3(2) . . ?
O32 Nb1 Eu1 139.81(19) . . ?
O26 Nb1 Eu1 117.34(17) . . ?
O28 Nb1 Eu1 46.24(16) . . ?
O22 Nb1 Eu1 35.61(16) . . ?
O9 Nb1 Eu1 81.97(12) . . ?
O38 Nb2 O31 102.0(3) . . ?
O38 Nb2 O30 104.3(3) . . ?
O31 Nb2 O30 100.2(3) . . ?
O38 Nb2 O25 98.0(3) . . ?
O31 Nb2 O25 90.6(3) . . ?
O30 Nb2 O25 152.4(2) . . ?
O38 Nb2 O8 99.6(3) . . ?
O31 Nb2 O8 155.5(2) . . ?
O30 Nb2 O8 85.4(2) . . ?
O25 Nb2 O8 75.0(2) . . ?
O38 Nb2 O7 169.4(3) . . ?
O31 Nb2 O7 74.6(2) . . ?
O30 Nb2 O7 86.2(2) . . ?
O25 Nb2 O7 72.2(2) . . ?
O8 Nb2 O7 82.1(2) . . ?
O38 Nb2 Te3 97.6(3) . . ?
O31 Nb2 Te3 131.9(2) . . ?
O30 Nb2 Te3 116.86(18) . . ?
O25 Nb2 Te3 43.03(15) . . ?
O8 Nb2 Te3 32.32(16) . . ?
O7 Nb2 Te3 78.24(12) . . ?
O33 Nb3 O12 100.7(3) . . ?
O33 Nb3 O3 100.7(3) . . ?
O12 Nb3 O3 89.7(2) . . ?
O33 Nb3 O32 98.3(3) . . ?
O12 Nb3 O32 160.7(2) . . ?
O3 Nb3 O32 89.9(2) . . ?
O33 Nb3 O27 100.0(3) . . ?
O12 Nb3 O27 89.5(3) . . ?
O3 Nb3 O27 159.0(2) . . ?
O32 Nb3 O27 84.1(3) . . ?
O33 Nb3 O9 169.6(2) . . ?
O12 Nb3 O9 87.3(2) . . ?
O3 Nb3 O9 85.9(2) . . ?
O32 Nb3 O9 73.4(2) . . ?
O27 Nb3 O9 73.2(2) . . ?
O37 Nb4 O27 103.7(3) . . ?
O37 Nb4 O30 100.5(3) . . ?
O27 Nb4 O30 93.2(3) . . ?
O37 Nb4 O28 97.0(3) . . ?
O27 Nb4 O28 96.5(3) . . ?
O30 Nb4 O28 157.5(2) . . ?
O37 Nb4 O23 102.1(3) . . ?
O27 Nb4 O23 154.3(2) . . ?
O30 Nb4 O23 82.0(2) . . ?
O28 Nb4 O23 80.5(2) . . ?
O37 Nb4 O9 169.8(3) . . ?
O27 Nb4 O9 74.9(2) . . ?
O30 Nb4 O9 89.8(2) . . ?
O28 Nb4 O9 73.3(2) . . ?
O23 Nb4 O9 79.8(2) . . ?
O37 Nb4 Eu1 93.3(2) . . ?
O27 Nb4 Eu1 141.2(2) . . ?
O30 Nb4 Eu1 118.09(18) . . ?
O28 Nb4 Eu1 46.28(17) . . ?
O23 Nb4 Eu1 36.08(16) . . ?
O9 Nb4 Eu1 82.36(12) . . ?
O21 Nb5 O2 103.3(2) . . ?
O21 Nb5 O24 101.9(3) . . ?
O2 Nb5 O24 101.1(2) . . ?
O21 Nb5 O11 98.4(3) . . ?
O2 Nb5 O11 91.9(2) . . ?
O24 Nb5 O11 152.5(2) . . ?
O21 Nb5 O15 97.5(2) . . ?
O2 Nb5 O15 156.9(2) . . ?
O24 Nb5 O15 84.2(2) . . ?
O11 Nb5 O15 74.9(2) . . ?
O21 Nb5 O5 173.0(3) . . ?
O2 Nb5 O5 77.0(2) . . ?
O24 Nb5 O5 84.9(2) . . ?
O11 Nb5 O5 74.54(19) . . ?
O15 Nb5 O5 81.15(19) . . ?
O21 Nb5 Te2 95.0(2) . . ?
O2 Nb5 Te2 133.19(17) . . ?
O24 Nb5 Te2 116.81(16) . . ?
O11 Nb5 Te2 42.42(15) . . ?
O15 Nb5 Te2 33.07(15) . . ?
O5 Nb5 Te2 80.05(12) . . ?
O17 Nb6 O13 101.7(2) . . ?
O17 Nb6 O3 102.4(2) . . ?
O13 Nb6 O3 90.1(2) . . ?
O17 Nb6 O6 97.4(2) . . ?
O13 Nb6 O6 160.5(2) . . ?
O3 Nb6 O6 89.3(2) . . ?
O17 Nb6 O2 100.2(2) . . ?
O13 Nb6 O2 88.3(2) . . ?
O3 Nb6 O2 157.2(2) . . ?
O6 Nb6 O2 84.7(2) . . ?
O17 Nb6 O5 168.9(2) . . ?
O13 Nb6 O5 86.42(19) . . ?
O3 Nb6 O5 85.0(2) . . ?
O6 Nb6 O5 74.15(19) . . ?
O2 Nb6 O5 72.21(19) . . ?
O35 Nb7 O4 104.1(3) . . ?
O35 Nb7 O24 101.5(3) . . ?
O4 Nb7 O24 97.9(2) . . ?
O35 Nb7 O25 100.4(3) . . ?
O4 Nb7 O25 93.9(2) . . ?
O24 Nb7 O25 151.6(2) . . ?
O35 Nb7 O20 98.4(2) . . ?
O4 Nb7 O20 156.6(2) . . ?
O24 Nb7 O20 83.3(2) . . ?
O25 Nb7 O20 75.9(2) . . ?
O35 Nb7 O7 174.6(3) . . ?
O4 Nb7 O7 76.0(2) . . ?
O24 Nb7 O7 83.8(2) . . ?
O25 Nb7 O7 74.2(2) . . ?
O20 Nb7 O7 81.0(2) . . ?
O35 Nb7 Te3 96.9(2) . . ?
O4 Nb7 Te3 135.56(18) . . ?
O24 Nb7 Te3 115.80(16) . . ?
O25 Nb7 Te3 43.37(15) . . ?
O20 Nb7 Te3 33.06(15) . . ?
O7 Nb7 Te3 79.66(12) . . ?
O29 Nb8 O12 103.1(3) . . ?
O29 Nb8 O13 100.8(2) . . ?
O12 Nb8 O13 90.8(2) . . ?
O29 Nb8 O31 99.5(2) . . ?
O12 Nb8 O31 91.1(3) . . ?
O13 Nb8 O31 158.7(2) . . ?
O29 Nb8 O4 99.7(3) . . ?
O12 Nb8 O4 157.2(2) . . ?
O13 Nb8 O4 85.6(2) . . ?
O31 Nb8 O4 84.4(2) . . ?
O29 Nb8 O7 168.4(2) . . ?
O12 Nb8 O7 86.1(2) . . ?
O13 Nb8 O7 85.92(19) . . ?
O31 Nb8 O7 73.0(2) . . ?
O4 Nb8 O7 71.19(19) . . ?
O34 Nb9 O6 102.8(3) . . ?
O34 Nb9 O26 102.8(3) . . ?
O6 Nb9 O26 99.4(3) . . ?
O34 Nb9 O11 102.6(3) . . ?
O6 Nb9 O11 91.4(2) . . ?
O26 Nb9 O11 149.3(2) . . ?
O34 Nb9 O18 99.4(3) . . ?
O6 Nb9 O18 155.9(2) . . ?
O26 Nb9 O18 84.3(2) . . ?
O11 Nb9 O18 74.8(2) . . ?
O34 Nb9 O5 172.4(3) . . ?
O6 Nb9 O5 74.42(19) . . ?
O26 Nb9 O5 84.7(2) . . ?
O11 Nb9 O5 70.61(18) . . ?
O18 Nb9 O5 82.33(19) . . ?
O34 Nb9 Te2 99.8(3) . . ?
O6 Nb9 Te2 132.02(18) . . ?
O26 Nb9 Te2 115.93(17) . . ?
O11 Nb9 Te2 42.24(15) . . ?
O18 Nb9 Te2 32.90(16) . . ?
O5 Nb9 Te2 77.61(12) . . ?
N3 Cu1 N2 178.7(4) . . ?
N3 Cu1 N4 84.2(4) . . ?
N2 Cu1 N4 97.1(4) . . ?
N3 Cu1 N1 95.5(5) . . ?
N2 Cu1 N1 83.2(5) . . ?
N4 Cu1 N1 176.8(4) . . ?
N7 Cu2 N5 85.2(4) . . ?
N7 Cu2 N8 96.4(3) . . ?
N5 Cu2 N8 178.0(4) . . ?
N7 Cu2 N6 177.9(4) . . ?
N5 Cu2 N6 94.9(4) . . ?
N8 Cu2 N6 83.4(4) . . ?
N7 Cu2 O1W 91.1(3) . . ?
N5 Cu2 O1W 92.7(3) . . ?
N8 Cu2 O1W 88.6(3) . . ?
N6 Cu2 O1W 91.0(3) . . ?
N10 Cu3 N10 180.0 . 3_766 ?
N10 Cu3 N9 83.9(3) . 3_766 ?
N10 Cu3 N9 96.1(3) 3_766 3_766 ?
N10 Cu3 N9 96.1(3) . . ?
N10 Cu3 N9 83.9(3) 3_766 . ?
N9 Cu3 N9 180.0 3_766 . ?
Nb5 O2 Nb6 118.7(3) . . ?
Nb3 O3 Nb6 148.3(3) . . ?
Nb7 O4 Nb8 121.0(3) . . ?
Te1 O5 Nb5 116.3(2) . . ?
Te1 O5 Nb6 132.5(2) . . ?
Nb5 O5 Nb6 92.00(18) . . ?
Te1 O5 Nb9 122.4(2) . . ?
Nb5 O5 Nb9 95.27(17) . . ?
Nb6 O5 Nb9 89.22(16) . . ?
Nb9 O6 Nb6 121.9(3) . . ?
Te1 O7 Nb7 116.5(2) . . ?
Te1 O7 Nb8 131.9(3) . . ?
Nb7 O7 Nb8 91.81(18) . . ?
Te1 O7 Nb2 123.7(2) . . ?
Nb7 O7 Nb2 94.34(18) . . ?
Nb8 O7 Nb2 89.03(16) . . ?
Te3 O8 Nb2 110.3(3) . . ?
Te1 O9 Nb3 135.8(3) . . ?
Te1 O9 Nb4 117.4(2) . . ?
Nb3 O9 Nb4 92.14(18) . . ?
Te1 O9 Nb1 116.7(2) . . ?
Nb3 O9 Nb1 92.15(18) . . ?
Nb4 O9 Nb1 92.44(19) . . ?
Te3 O10 Te3 120.3(4) . 4_575 ?
Nb5 O11 Nb9 117.9(2) . . ?
Nb5 O11 Te2 98.5(2) . . ?
Nb9 O11 Te2 98.2(2) . . ?
Nb3 O12 Nb8 146.9(3) . . ?
Nb6 O13 Nb8 147.8(3) . . ?
Te2 O14 Te2 119.5(4) 4_575 . ?
Te2 O15 Nb5 108.3(3) . . ?
Te2 O18 Nb9 109.2(3) . . ?
Te3 O20 Nb7 108.1(3) . . ?
Nb1 O22 Eu1 113.0(3) . . ?
Nb4 O23 Eu1 112.5(3) . . ?
Nb5 O24 Nb7 168.3(3) . . ?
Nb7 O25 Nb2 117.5(3) . . ?
Nb7 O25 Te3 97.9(2) . . ?
Nb2 O25 Te3 98.1(2) . . ?
Nb9 O26 Nb1 157.7(3) . . ?
Nb4 O27 Nb3 119.7(3) . . ?
Nb4 O28 Nb1 118.9(3) . . ?
Nb4 O28 Eu1 101.8(2) . . ?
Nb1 O28 Eu1 101.6(2) . . ?
Nb2 O30 Nb4 154.3(3) . . ?
Nb2 O31 Nb8 122.8(3) . . ?
Nb1 O32 Nb3 119.9(3) . . ?
C1 N1 Cu1 109.2(8) . . ?
C1 N1 H1A 109.8 . . ?
Cu1 N1 H1A 109.8 . . ?
C1 N1 H1B 109.8 . . ?
Cu1 N1 H1B 109.8 . . ?
H1A N1 H1B 108.3 . . ?
C2 N2 Cu1 111.3(9) . . ?
C2 N2 H2A 109.4 . . ?
Cu1 N2 H2A 109.4 . . ?
C2 N2 H2B 109.4 . . ?
Cu1 N2 H2B 109.4 . . ?
H2A N2 H2B 108.0 . . ?
C3 N3 Cu1 111.3(8) . . ?
C3 N3 H3A 109.4 . . ?
Cu1 N3 H3A 109.4 . . ?
C3 N3 H3B 109.4 . . ?
Cu1 N3 H3B 109.4 . . ?
H3A N3 H3B 108.0 . . ?
C4 N4 Cu1 108.4(7) . . ?
C4 N4 H4A 110.0 . . ?
Cu1 N4 H4A 110.0 . . ?
C4 N4 H4B 110.0 . . ?
Cu1 N4 H4B 110.0 . . ?
H4A N4 H4B 108.4 . . ?
C5 N5 Cu2 106.6(7) . . ?
C5 N5 H5A 110.4 . . ?
Cu2 N5 H5A 110.4 . . ?
C5 N5 H5B 110.4 . . ?
Cu2 N5 H5B 110.4 . . ?
H5A N5 H5B 108.6 . . ?
C6 N6 Cu2 106.6(7) . . ?
C6 N6 H6A 110.4 . . ?
Cu2 N6 H6A 110.4 . . ?
C6 N6 H6B 110.4 . . ?
Cu2 N6 H6B 110.4 . . ?
H6A N6 H6B 108.6 . . ?
C7 N7 Cu2 110.1(7) . . ?
C7 N7 H7A 109.6 . . ?
Cu2 N7 H7A 109.6 . . ?
C7 N7 H7B 109.6 . . ?
Cu2 N7 H7B 109.6 . . ?
H7A N7 H7B 108.1 . . ?
C8 N8 Cu2 110.8(8) . . ?
C8 N8 H8A 109.5 . . ?
Cu2 N8 H8A 109.5 . . ?
C8 N8 H8B 109.5 . . ?
Cu2 N8 H8B 109.5 . . ?
H8A N8 H8B 108.1 . . ?
C9 N9 Cu3 109.2(5) . . ?
C9 N9 H9A 109.8 . . ?
Cu3 N9 H9A 109.8 . . ?
C9 N9 H9B 109.8 . . ?
Cu3 N9 H9B 109.8 . . ?
H9A N9 H9B 108.3 . . ?
C10 N10 Cu3 109.3(5) 3_766 . ?
C10 N10 H10A 109.8 3_766 . ?
Cu3 N10 H10A 109.8 . . ?
C10 N10 H10B 109.8 3_766 . ?
Cu3 N10 H10B 109.8 . . ?
H10A N10 H10B 108.3 . . ?
C2 C1 N1 119.5(13) . . ?
C2 C1 H1C 107.5 . . ?
N1 C1 H1C 107.5 . . ?
C2 C1 H1D 107.5 . . ?
N1 C1 H1D 107.5 . . ?
H1C C1 H1D 107.0 . . ?
C1 C2 N2 113.8(13) . . ?
C1 C2 H2C 108.8 . . ?
N2 C2 H2C 108.8 . . ?
C1 C2 H2D 108.8 . . ?
N2 C2 H2D 108.8 . . ?
H2C C2 H2D 107.7 . . ?
N3 C3 C4 106.0(13) . . ?
N3 C3 H3C 110.5 . . ?
C4 C3 H3C 110.5 . . ?
N3 C3 H3D 110.5 . . ?
C4 C3 H3D 110.5 . . ?
H3C C3 H3D 108.7 . . ?
N4 C4 C3 113.5(10) . . ?
N4 C4 H4C 108.9 . . ?
C3 C4 H4C 108.9 . . ?
N4 C4 H4D 108.9 . . ?
C3 C4 H4D 108.9 . . ?
H4C C4 H4D 107.7 . . ?
C7 C5 N5 108.5(12) . . ?
C7 C5 H5C 110.0 . . ?
N5 C5 H5C 110.0 . . ?
C7 C5 H5D 110.0 . . ?
N5 C5 H5D 110.0 . . ?
H5C C5 H5D 108.4 . . ?
C8 C6 N6 106.4(12) . . ?
C8 C6 H6C 110.4 . . ?
N6 C6 H6C 110.4 . . ?
C8 C6 H6D 110.4 . . ?
N6 C6 H6D 110.4 . . ?
H6C C6 H6D 108.6 . . ?
C5 C7 N7 110.5(11) . . ?
C5 C7 H7C 109.6 . . ?
N7 C7 H7C 109.6 . . ?
C5 C7 H7D 109.6 . . ?
N7 C7 H7D 109.6 . . ?
H7C C7 H7D 108.1 . . ?
N8 C8 C6 108.7(11) . . ?
N8 C8 H8C 109.9 . . ?
C6 C8 H8C 109.9 . . ?
N8 C8 H8D 109.9 . . ?
C6 C8 H8D 109.9 . . ?
H8C C8 H8D 108.3 . . ?
N9 C9 C10 107.1(8) . . ?
N9 C9 H9C 110.3 . . ?
C10 C9 H9C 110.3 . . ?
N9 C9 H9D 110.3 . . ?
C10 C9 H9D 110.3 . . ?
H9C C9 H9D 108.5 . . ?
N10 C10 C9 106.9(9) 3_766 . ?
N10 C10 H10C 110.3 3_766 . ?
C9 C10 H10C 110.3 . . ?
N10 C10 H10D 110.3 3_766 . ?
C9 C10 H10D 110.3 . . ?
H10C C10 H10D 108.6 . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
_geom_hbond_publ_flag
N1 H1A O12 0.89 2.47 3.211(12) 140.5 . yes
N1 H1A O33 0.89 2.63 3.308(13) 133.7 . yes
N2 H2A O21 0.89 1.98 2.863(11) 172.1 1_455 yes
N2 H2B O30 0.89 2.33 3.184(10) 160.9 . yes
N3 H3A O7W 0.89 2.26 3.140(12) 171.7 . yes
N3 H3B O33 0.89 2.12 2.956(11) 156.2 . yes
N4 H4A O37 0.89 2.16 3.005(11) 157.5 . yes
N4 H4B O11 0.89 2.27 3.071(9) 149.6 1_455 yes
N5 H5B O31 0.89 2.09 2.956(11) 164.7 3_765 yes
N6 H6A O25 0.89 2.24 3.088(10) 158.5 3_765 yes
N7 H7A O4 0.89 2.19 3.074(10) 173.0 . yes
N7 H7A O13 0.89 2.50 2.944(10) 111.4 . yes
N7 H7B O2 0.89 2.26 3.073(9) 151.7 . yes
N8 H8A O17 0.89 2.16 3.028(10) 163.7 . yes
N8 H8B O29 0.89 2.34 3.199(11) 163.7 . yes
N9 H9A O33 0.89 2.23 3.081(10) 160.2 . yes
N9 H9B O17 0.89 2.14 3.022(9) 168.7 . yes
N10 H10A O6 0.89 2.31 3.155(9) 159.0 . yes
N10 H10B O32 0.89 2.23 3.106(10) 169.7 . yes

_refine_diff_density_max         2.813
_refine_diff_density_min         -2.712
_refine_diff_density_rms         0.173


# SQUEEZE RESULTS (APPEND TO CIF)
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
1 -0.067 0.250 0.244 2109.1 197.5
2 0.006 0.750 0.755 2107.1 197.9
_platon_squeeze_details          
; ?
;



