####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_mo_d8v4688_0m
_database_code_depnum_ccdc_archive 'CCDC 2070452'
loop_
_audit_author_name
_audit_author_address
'Maria Storm Thomsen'
;University of Copenhagen
Denmark
;
_audit_update_record             
;
2022-03-04 deposited with the CCDC.	2022-05-19 downloaded from the CCDC.
;
_audit_creation_date             2022-03-04
_audit_creation_method           
;
Olex2 1.5
(compiled 2021.12.09 svn.r5202d8cf for OlexSys, GUI svn.r6439)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'Eu2 K5 Na O24 S6'
_chemical_formula_sum            'Eu2 K5 Na O24 S6'
_chemical_formula_weight         1098.77
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
K K 0.2009 0.2494 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Na Na 0.0362 0.0249 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           12
_space_group_name_H-M_alt        'C 1 2/m 1'
_space_group_name_Hall           '-C 2y'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'

_cell_length_a                   9.1004(9)
_cell_length_b                   16.1318(15)
_cell_length_c                   7.6365(7)
_cell_angle_alpha                90
_cell_angle_beta                 110.614(2)
_cell_angle_gamma                90
_cell_volume                     1049.30(17)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    9954
_cell_measurement_temperature    120.0
_cell_measurement_theta_max      45.39
_cell_measurement_theta_min      2.53
_shelx_estimated_absorpt_T_max   0.509
_shelx_estimated_absorpt_T_min   0.217
_exptl_absorpt_coefficient_mu    7.650
_exptl_absorpt_correction_T_max  0.7489
_exptl_absorpt_correction_T_min  0.5642
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1080 before and 0.0523 after correction.
The Ratio of minimum to maximum transmission is 0.7534.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear whiteish colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   whiteish
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    3.478
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       rhombohedral
_exptl_crystal_F_000             1040
_exptl_crystal_size_max          0.287
_exptl_crystal_size_mid          0.162
_exptl_crystal_size_min          0.102
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0327
_diffrn_reflns_av_unetI/netI     0.0190
_diffrn_reflns_Laue_measured_fraction_full 0.995
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       29
_diffrn_reflns_limit_k_min       -29
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            25194
_diffrn_reflns_point_group_measured_fraction_full 0.995
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         40.243
_diffrn_reflns_theta_min         2.525
_diffrn_ambient_temperature      120.0
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           1.0
_diffrn_source_power             0.05
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                3261
_reflns_number_total             3385
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.40A (Bruker, 2019)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.40A (Bruker, 2019)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         0.867
_refine_diff_density_min         -1.315
_refine_diff_density_rms         0.176
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.144
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     95
_refine_ls_number_reflns         3385
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0147
_refine_ls_R_factor_gt           0.0137
_refine_ls_restrained_S_all      1.144
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0129P)²+1.3684P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0340
_refine_ls_wR_factor_ref         0.0343
_refine_special_details          ?
_olex2_refinement_description    
;
;
_atom_sites_solution_hydrogens   .
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.500000 0.14243(2) 0.500000 0.00240(2) Uani 1 2 d S T P . .
K1 K 0.500000 0.500000 0.500000 0.01337(9) Uani 1 4 d S T P . .
K2 K 0.77793(3) 0.34353(2) 0.88373(3) 0.00631(3) Uani 1 1 d . . . . .
S1 S 0.37114(3) 0.33440(2) 0.67738(4) 0.00316(4) Uani 1 1 d . . . . .
S2 S 0.09574(4) 0.500000 0.80215(5) 0.00274(5) Uani 1 2 d S T P . .
Na1 Na 0.500000 0.500000 1.000000 0.00505(14) Uani 1 4 d S T P . .
O1 O 0.23004(13) 0.500000 0.97659(16) 0.00538(16) Uani 1 2 d S T P . .
O4 O 0.45843(10) 0.25648(5) 0.68042(12) 0.00694(12) Uani 1 1 d . . . . .
O6 O 0.14347(14) 0.500000 0.63426(16) 0.00561(16) Uani 1 2 d S T P . .
O7 O 0.28436(11) 0.36222(5) 0.48375(12) 0.00692(12) Uani 1 1 d . . . . .
O2 O 0.24896(10) 0.31843(5) 0.76172(12) 0.00592(12) Uani 1 1 d . . . . .
O5 O -0.00099(10) 0.42429(5) 0.78739(11) 0.00488(11) Uani 1 1 d . . . . .
O3 O 0.48242(10) 0.39764(5) 0.78106(12) 0.00612(12) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 S2 3.1538(3) 3_545 ?
Eu1 S2 3.1538(3) 7_556 ?
Eu1 O4 2.4069(8) 2_656 ?
Eu1 O4 2.4070(8) . ?
Eu1 O6 2.6631(6) 7_556 ?
Eu1 O6 2.6631(6) 3_545 ?
Eu1 O7 2.6352(9) 8 ?
Eu1 O7 2.6352(9) 7_556 ?
Eu1 O2 2.5175(9) 7_556 ?
Eu1 O2 2.5175(9) 8 ?
Eu1 O5 2.4473(8) 7_556 ?
Eu1 O5 2.4473(8) 8 ?
K1 S1 3.3860(3) . ?
K1 S1 3.3860(3) 6_565 ?
K1 S1 3.3860(3) 2_656 ?
K1 S1 3.3860(3) 5_666 ?
K1 O7 2.9385(9) . ?
K1 O7 2.9385(9) 5_666 ?
K1 O7 2.9385(9) 2_656 ?
K1 O7 2.9385(9) 6_565 ?
K1 O3 2.7569(9) . ?
K1 O3 2.7569(9) 5_666 ?
K1 O3 2.7569(9) 6_565 ?
K1 O3 2.7569(9) 2_656 ?
K2 S1 3.5189(4) 8 ?
K2 S1 3.4788(5) . ?
K2 S2 3.3920(4) 5_667 ?
K2 O1 2.7511(6) 5_667 ?
K2 O4 3.1077(9) . ?
K2 O4 3.0833(9) 8 ?
K2 O7 2.6771(9) 2_656 ?
K2 O2 2.7552(9) 8 ?
K2 O2 2.8322(9) 2_657 ?
K2 O5 2.9216(9) 2_657 ?
K2 O5 2.7071(8) 1_655 ?
K2 O3 2.6691(9) . ?
S1 O4 1.4829(8) . ?
S1 O7 1.4796(9) . ?
S1 O2 1.4905(8) . ?
S1 O3 1.4590(8) . ?
S2 O1 1.4567(12) . ?
S2 O6 1.4915(12) . ?
S2 O5 1.4863(8) 6_565 ?
S2 O5 1.4863(8) . ?
Na1 O1 2.3997(12) . ?
Na1 O1 2.3996(12) 5_667 ?
Na1 O3 2.3150(8) 5_667 ?
Na1 O3 2.3150(8) . ?
Na1 O3 2.3150(8) 6_565 ?
Na1 O3 2.3150(8) 2_657 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
S2 Eu1 S2 86.475(12) 7_556 3_545 ?
O4 Eu1 S2 101.34(2) 2_656 7_556 ?
O4 Eu1 S2 156.50(2) . 7_556 ?
O4 Eu1 S2 101.34(2) . 3_545 ?
O4 Eu1 S2 156.50(2) 2_656 3_545 ?
O4 Eu1 O4 80.30(4) 2_656 . ?
O4 Eu1 O6 136.49(3) 2_656 3_545 ?
O4 Eu1 O6 126.42(3) . 3_545 ?
O4 Eu1 O6 126.42(3) 2_656 7_556 ?
O4 Eu1 O6 136.49(3) . 7_556 ?
O4 Eu1 O7 68.89(3) 2_656 8 ?
O4 Eu1 O7 113.80(3) 2_656 7_556 ?
O4 Eu1 O7 113.80(3) . 8 ?
O4 Eu1 O7 68.90(3) . 7_556 ?
O4 Eu1 O2 89.07(3) 2_656 8 ?
O4 Eu1 O2 68.45(3) . 8 ?
O4 Eu1 O2 68.45(3) 2_656 7_556 ?
O4 Eu1 O2 89.07(3) . 7_556 ?
O4 Eu1 O5 154.22(3) 2_656 8 ?
O4 Eu1 O5 154.22(3) . 7_556 ?
O4 Eu1 O5 76.82(3) . 8 ?
O4 Eu1 O5 76.81(3) 2_656 7_556 ?
O6 Eu1 S2 67.97(2) 7_556 3_545 ?
O6 Eu1 S2 28.13(2) 3_545 3_545 ?
O6 Eu1 S2 28.13(2) 7_556 7_556 ?
O6 Eu1 S2 67.97(2) 3_545 7_556 ?
O6 Eu1 O6 60.75(4) 7_556 3_545 ?
O7 Eu1 S2 89.47(2) 8 3_545 ?
O7 Eu1 S2 89.47(2) 7_556 7_556 ?
O7 Eu1 S2 88.152(19) 7_556 3_545 ?
O7 Eu1 S2 88.152(19) 8 7_556 ?
O7 Eu1 O6 68.72(3) 7_556 7_556 ?
O7 Eu1 O6 68.72(3) 8 3_545 ?
O7 Eu1 O6 108.29(3) 8 7_556 ?
O7 Eu1 O6 108.29(3) 7_556 3_545 ?
O7 Eu1 O7 176.74(4) 8 7_556 ?
O2 Eu1 S2 70.26(2) 7_556 7_556 ?
O2 Eu1 S2 134.680(19) 8 7_556 ?
O2 Eu1 S2 134.68(2) 7_556 3_545 ?
O2 Eu1 S2 70.26(2) 8 3_545 ?
O2 Eu1 O6 74.25(3) 8 3_545 ?
O2 Eu1 O6 134.77(3) 7_556 3_545 ?
O2 Eu1 O6 74.25(3) 7_556 7_556 ?
O2 Eu1 O6 134.77(3) 8 7_556 ?
O2 Eu1 O7 126.44(3) 7_556 8 ?
O2 Eu1 O7 126.44(3) 8 7_556 ?
O2 Eu1 O7 54.57(3) 7_556 7_556 ?
O2 Eu1 O7 54.57(3) 8 8 ?
O2 Eu1 O2 150.95(4) 8 7_556 ?
O5 Eu1 S2 27.225(19) 8 3_545 ?
O5 Eu1 S2 104.38(2) 7_556 3_545 ?
O5 Eu1 S2 27.225(19) 7_556 7_556 ?
O5 Eu1 S2 104.38(2) 8 7_556 ?
O5 Eu1 O6 79.03(3) 7_556 3_545 ?
O5 Eu1 O6 55.35(3) 7_556 7_556 ?
O5 Eu1 O6 55.35(3) 8 3_545 ?
O5 Eu1 O6 79.03(3) 8 7_556 ?
O5 Eu1 O7 68.38(3) 8 7_556 ?
O5 Eu1 O7 110.09(3) 7_556 7_556 ?
O5 Eu1 O7 110.09(3) 8 8 ?
O5 Eu1 O7 68.38(3) 7_556 8 ?
O5 Eu1 O2 71.63(3) 7_556 7_556 ?
O5 Eu1 O2 122.40(3) 8 7_556 ?
O5 Eu1 O2 122.40(3) 7_556 8 ?
O5 Eu1 O2 71.63(3) 8 8 ?
O5 Eu1 O5 127.82(4) 7_556 8 ?
S1 K1 S1 180.0 6_565 2_656 ?
S1 K1 S1 180.0 . 5_666 ?
S1 K1 S1 104.176(10) 2_656 5_666 ?
S1 K1 S1 104.175(11) . 6_565 ?
S1 K1 S1 75.825(11) . 2_656 ?
S1 K1 S1 75.824(10) 6_565 5_666 ?
O7 K1 S1 154.164(18) 2_656 6_565 ?
O7 K1 S1 72.935(19) 6_565 5_666 ?
O7 K1 S1 72.936(19) 2_656 . ?
O7 K1 S1 154.164(18) 6_565 2_656 ?
O7 K1 S1 154.164(17) . 5_666 ?
O7 K1 S1 25.836(17) 6_565 6_565 ?
O7 K1 S1 72.935(19) 5_666 6_565 ?
O7 K1 S1 25.836(17) 5_666 5_666 ?
O7 K1 S1 25.836(17) 2_656 2_656 ?
O7 K1 S1 107.064(19) 6_565 . ?
O7 K1 S1 107.065(19) 5_666 2_656 ?
O7 K1 S1 72.936(18) . 2_656 ?
O7 K1 S1 107.064(18) . 6_565 ?
O7 K1 S1 107.065(19) 2_656 5_666 ?
O7 K1 S1 25.836(17) . . ?
O7 K1 S1 154.164(17) 5_666 . ?
O7 K1 O7 81.71(3) 5_666 6_565 ?
O7 K1 O7 98.29(3) 6_565 . ?
O7 K1 O7 98.29(3) 5_666 2_656 ?
O7 K1 O7 180.00(3) 5_666 . ?
O7 K1 O7 81.71(3) 2_656 . ?
O7 K1 O7 180.0 6_565 2_656 ?
O3 K1 S1 92.172(18) . 6_565 ?
O3 K1 S1 24.882(17) 5_666 5_666 ?
O3 K1 S1 155.119(17) 2_656 6_565 ?
O3 K1 S1 24.881(17) . . ?
O3 K1 S1 155.119(17) 6_565 2_656 ?
O3 K1 S1 24.882(17) 2_656 2_656 ?
O3 K1 S1 87.829(19) 2_656 . ?
O3 K1 S1 92.171(18) 2_656 5_666 ?
O3 K1 S1 155.119(17) . 5_666 ?
O3 K1 S1 87.828(18) . 2_656 ?
O3 K1 S1 87.829(19) 5_666 6_565 ?
O3 K1 S1 24.881(17) 6_565 6_565 ?
O3 K1 S1 92.171(19) 6_565 . ?
O3 K1 S1 155.118(17) 5_666 . ?
O3 K1 S1 87.829(18) 6_565 5_666 ?
O3 K1 S1 92.171(18) 5_666 2_656 ?
O3 K1 O7 105.37(2) 5_666 2_656 ?
O3 K1 O7 50.13(2) 6_565 6_565 ?
O3 K1 O7 74.63(2) . 2_656 ?
O3 K1 O7 129.87(2) 2_656 6_565 ?
O3 K1 O7 105.37(2) 6_565 . ?
O3 K1 O7 74.63(2) 5_666 6_565 ?
O3 K1 O7 74.63(2) 6_565 5_666 ?
O3 K1 O7 105.37(2) . 6_565 ?
O3 K1 O7 50.13(2) 5_666 5_666 ?
O3 K1 O7 105.37(2) 2_656 5_666 ?
O3 K1 O7 129.87(2) 5_666 . ?
O3 K1 O7 50.13(2) . . ?
O3 K1 O7 129.87(2) . 5_666 ?
O3 K1 O7 74.63(2) 2_656 . ?
O3 K1 O7 129.87(2) 6_565 2_656 ?
O3 K1 O7 50.13(2) 2_656 2_656 ?
O3 K1 O3 180.0 6_565 2_656 ?
O3 K1 O3 73.59(3) 6_565 . ?
O3 K1 O3 106.41(3) 2_656 . ?
O3 K1 O3 73.59(3) 2_656 5_666 ?
O3 K1 O3 180.0 5_666 . ?
O3 K1 O3 106.41(3) 6_565 5_666 ?
S1 K2 S1 98.539(9) . 8 ?
S2 K2 S1 113.172(9) 5_667 . ?
S2 K2 S1 148.058(11) 5_667 8 ?
O1 K2 S1 92.60(3) 5_667 . ?
O1 K2 S1 164.89(3) 5_667 8 ?
O1 K2 S2 24.73(2) 5_667 5_667 ?
O1 K2 O4 117.42(3) 5_667 . ?
O1 K2 O4 140.06(3) 5_667 8 ?
O1 K2 O2 74.79(3) 5_667 2_657 ?
O1 K2 O2 171.38(3) 5_667 8 ?
O1 K2 O5 50.41(3) 5_667 2_657 ?
O4 K2 S1 25.221(15) . . ?
O4 K2 S1 24.850(15) 8 8 ?
O4 K2 S1 114.859(19) 8 . ?
O4 K2 S1 74.830(17) . 8 ?
O4 K2 S2 135.570(18) . 5_667 ?
O4 K2 S2 129.603(19) 8 5_667 ?
O4 K2 O4 94.738(19) 8 . ?
O7 K2 S1 67.539(19) 2_656 8 ?
O7 K2 S1 74.40(2) 2_656 . ?
O7 K2 S2 123.47(2) 2_656 5_667 ?
O7 K2 O1 106.16(3) 2_656 5_667 ?
O7 K2 O4 58.99(3) 2_656 8 ?
O7 K2 O4 73.24(3) 2_656 . ?
O7 K2 O2 163.84(3) 2_656 2_657 ?
O7 K2 O2 78.03(3) 2_656 8 ?
O7 K2 O5 64.17(3) 2_656 1_655 ?
O7 K2 O5 132.65(3) 2_656 2_657 ?
O2 K2 S1 89.462(19) 2_657 . ?
O2 K2 S1 23.722(17) 8 8 ?
O2 K2 S1 115.281(19) 2_657 8 ?
O2 K2 S1 81.188(19) 8 . ?
O2 K2 S2 63.394(19) 2_657 5_667 ?
O2 K2 S2 155.94(2) 8 5_667 ?
O2 K2 O4 130.33(2) 2_657 8 ?
O2 K2 O4 48.55(2) 8 8 ?
O2 K2 O4 56.03(2) 8 . ?
O2 K2 O4 91.86(2) 2_657 . ?
O2 K2 O2 99.06(2) 8 2_657 ?
O2 K2 O5 60.64(2) 2_657 2_657 ?
O2 K2 O5 131.94(3) 8 2_657 ?
O5 K2 S1 87.222(19) 1_655 8 ?
O5 K2 S1 132.18(2) 1_655 . ?
O5 K2 S1 135.623(18) 2_657 . ?
O5 K2 S1 123.000(18) 2_657 8 ?
O5 K2 S2 25.881(16) 2_657 5_667 ?
O5 K2 S2 74.619(19) 1_655 5_667 ?
O5 K2 O1 77.72(3) 1_655 5_667 ?
O5 K2 O4 109.52(2) 2_657 8 ?
O5 K2 O4 137.38(3) 1_655 . ?
O5 K2 O4 62.38(2) 1_655 8 ?
O5 K2 O4 151.12(2) 2_657 . ?
O5 K2 O2 110.87(3) 1_655 8 ?
O5 K2 O2 130.63(3) 1_655 2_657 ?
O5 K2 O5 70.19(3) 1_655 2_657 ?
O3 K2 S1 22.974(18) . . ?
O3 K2 S1 120.797(19) . 8 ?
O3 K2 S2 91.143(19) . 5_667 ?
O3 K2 O1 69.66(3) . 5_667 ?
O3 K2 O4 133.12(3) . 8 ?
O3 K2 O4 48.11(2) . . ?
O3 K2 O7 80.54(3) . 2_656 ?
O3 K2 O2 84.85(3) . 2_657 ?
O3 K2 O2 104.14(3) . 8 ?
O3 K2 O5 122.08(3) . 1_655 ?
O3 K2 O5 115.46(2) . 2_657 ?
Eu1 S1 K1 101.648(8) 7_556 . ?
Eu1 S1 K2 170.720(9) 7_556 . ?
Eu1 S1 K2 84.235(8) 7_556 8_455 ?
K1 S1 K2 71.615(7) . . ?
K1 S1 K2 174.113(9) . 8_455 ?
K2 S1 K2 102.563(9) . 8_455 ?
O4 S1 Eu1 126.00(4) . 7_556 ?
O4 S1 K1 114.58(4) . . ?
O4 S1 K2 60.91(4) . 8_455 ?
O4 S1 K2 63.25(3) . . ?
O4 S1 O2 108.89(5) . . ?
O7 S1 Eu1 55.03(4) . 7_556 ?
O7 S1 K1 59.94(3) . . ?
O7 S1 K2 124.54(4) . 8_455 ?
O7 S1 K2 123.25(4) . . ?
O7 S1 O4 111.54(5) . . ?
O7 S1 O2 105.51(5) . . ?
O2 S1 Eu1 50.50(3) . 7_556 ?
O2 S1 K1 136.50(3) . . ?
O2 S1 K2 130.42(4) . . ?
O2 S1 K2 48.04(3) . 8_455 ?
O3 S1 Eu1 125.30(4) . 7_556 ?
O3 S1 K1 52.66(3) . . ?
O3 S1 K2 45.56(3) . . ?
O3 S1 K2 123.92(4) . 8_455 ?
O3 S1 O4 108.57(5) . . ?
O3 S1 O7 110.77(5) . . ?
O3 S1 O2 111.55(5) . . ?
Eu1 S2 Eu1 93.526(12) 7_556 3_455 ?
Eu1 S2 K2 84.998(9) 3_455 5_667 ?
Eu1 S2 K2 175.619(12) 7_556 5_667 ?
Eu1 S2 K2 84.998(9) 7_556 2_657 ?
Eu1 S2 K2 175.619(12) 3_455 2_657 ?
K2 S2 K2 96.173(14) 5_667 2_657 ?
O1 S2 Eu1 126.57(2) . 7_556 ?
O1 S2 Eu1 126.57(2) . 3_455 ?
O1 S2 K2 52.188(17) . 5_667 ?
O1 S2 K2 52.188(18) . 2_657 ?
O1 S2 O6 112.43(7) . . ?
O1 S2 O5 110.68(4) . 6_565 ?
O1 S2 O5 110.68(4) . . ?
O6 S2 Eu1 57.33(2) . 3_455 ?
O6 S2 Eu1 57.33(2) . 7_556 ?
O6 S2 K2 118.63(3) . 2_657 ?
O6 S2 K2 118.63(3) . 5_667 ?
O5 S2 Eu1 48.87(3) 6_565 3_455 ?
O5 S2 Eu1 48.87(3) . 7_556 ?
O5 S2 Eu1 122.65(4) . 3_455 ?
O5 S2 Eu1 122.65(4) 6_565 7_556 ?
O5 S2 K2 59.10(3) 6_565 5_667 ?
O5 S2 K2 135.17(4) 6_565 2_657 ?
O5 S2 K2 135.18(4) . 5_667 ?
O5 S2 K2 59.09(3) . 2_657 ?
O5 S2 O6 106.19(4) . . ?
O5 S2 O6 106.19(4) 6_565 . ?
O5 S2 O5 110.50(7) 6_565 . ?
K1 Na1 K1 180.0 . 1_556 ?
K1 Na1 K2 62.801(5) 1_556 2_657 ?
K1 Na1 K2 117.199(4) 1_556 . ?
K1 Na1 K2 62.801(4) . 6_565 ?
K1 Na1 K2 117.199(4) 1_556 6_565 ?
K1 Na1 K2 117.199(4) . 5_667 ?
K1 Na1 K2 62.801(4) . . ?
K1 Na1 K2 62.801(4) 1_556 5_667 ?
K1 Na1 K2 117.199(5) . 2_657 ?
K2 Na1 K2 80.894(10) . 6_565 ?
K2 Na1 K2 180.0 6_565 2_657 ?
K2 Na1 K2 99.106(10) . 2_657 ?
K2 Na1 K2 80.894(10) 2_657 5_667 ?
K2 Na1 K2 180.0 . 5_667 ?
K2 Na1 K2 99.106(10) 6_565 5_667 ?
O1 Na1 K1 106.62(3) . . ?
O1 Na1 K1 106.62(3) 5_667 1_556 ?
O1 Na1 K1 73.38(3) . 1_556 ?
O1 Na1 K1 73.38(3) 5_667 . ?
O1 Na1 K2 135.541(12) . 6_565 ?
O1 Na1 K2 135.541(12) . . ?
O1 Na1 K2 135.541(12) 5_667 5_667 ?
O1 Na1 K2 44.459(12) . 2_657 ?
O1 Na1 K2 44.459(12) 5_667 . ?
O1 Na1 K2 135.541(12) 5_667 2_657 ?
O1 Na1 K2 44.459(12) . 5_667 ?
O1 Na1 K2 44.459(12) 5_667 6_565 ?
O1 Na1 O1 180.0 5_667 . ?
O3 Na1 K1 45.74(2) 5_667 1_556 ?
O3 Na1 K1 45.74(2) . . ?
O3 Na1 K1 134.26(2) 6_565 1_556 ?
O3 Na1 K1 45.74(2) 2_657 1_556 ?
O3 Na1 K1 134.26(2) . 1_556 ?
O3 Na1 K1 45.74(2) 6_565 . ?
O3 Na1 K1 134.26(2) 5_667 . ?
O3 Na1 K1 134.26(2) 2_657 . ?
O3 Na1 K2 137.93(2) 5_667 . ?
O3 Na1 K2 79.45(2) . 2_657 ?
O3 Na1 K2 100.55(2) 6_565 . ?
O3 Na1 K2 100.55(2) 2_657 5_667 ?
O3 Na1 K2 137.93(2) . 5_667 ?
O3 Na1 K2 137.93(2) 6_565 2_657 ?
O3 Na1 K2 42.07(2) 6_565 6_565 ?
O3 Na1 K2 42.07(2) 2_657 2_657 ?
O3 Na1 K2 42.07(2) . . ?
O3 Na1 K2 100.55(2) . 6_565 ?
O3 Na1 K2 79.45(2) 6_565 5_667 ?
O3 Na1 K2 100.55(2) 5_667 2_657 ?
O3 Na1 K2 79.45(2) 5_667 6_565 ?
O3 Na1 K2 42.07(2) 5_667 5_667 ?
O3 Na1 K2 137.93(2) 2_657 6_565 ?
O3 Na1 K2 79.45(2) 2_657 . ?
O3 Na1 O1 97.91(3) 5_667 5_667 ?
O3 Na1 O1 82.09(3) . 5_667 ?
O3 Na1 O1 82.09(3) 6_565 5_667 ?
O3 Na1 O1 97.91(3) 2_657 5_667 ?
O3 Na1 O1 97.91(3) . . ?
O3 Na1 O1 82.09(3) 5_667 . ?
O3 Na1 O1 82.09(3) 2_657 . ?
O3 Na1 O1 97.91(3) 6_565 . ?
O3 Na1 O3 91.00(4) 6_565 . ?
O3 Na1 O3 91.00(4) 5_667 2_657 ?
O3 Na1 O3 180.0 6_565 2_657 ?
O3 Na1 O3 89.00(4) 2_657 . ?
O3 Na1 O3 89.00(4) 5_667 6_565 ?
O3 Na1 O3 180.00(4) 5_667 . ?
K2 O1 K2 133.12(5) 5_667 2_657 ?
S2 O1 K2 103.09(3) . 5_667 ?
S2 O1 K2 103.09(3) . 2_657 ?
S2 O1 Na1 125.13(7) . . ?
Na1 O1 K2 97.89(3) . 5_667 ?
Na1 O1 K2 97.89(3) . 2_657 ?
Eu1 O4 K2 108.87(3) . . ?
Eu1 O4 K2 96.15(3) . 8_455 ?
K2 O4 K2 123.74(3) 8_455 . ?
S1 O4 Eu1 146.13(5) . . ?
S1 O4 K2 91.52(4) . . ?
S1 O4 K2 94.24(4) . 8_455 ?
Eu1 O6 Eu1 119.25(4) 7_556 3_455 ?
S2 O6 Eu1 94.54(3) . 3_455 ?
S2 O6 Eu1 94.54(3) . 7_556 ?
Eu1 O7 K1 132.21(3) 7_556 . ?
Eu1 O7 K2 101.37(3) 7_556 2_656 ?
K2 O7 K1 91.22(3) 2_656 . ?
S1 O7 Eu1 97.57(4) . 7_556 ?
S1 O7 K1 94.23(4) . . ?
S1 O7 K2 148.76(5) . 2_656 ?
Eu1 O2 K2 117.29(3) 7_556 8_455 ?
Eu1 O2 K2 111.51(3) 7_556 2_657 ?
K2 O2 K2 80.94(2) 8_455 2_657 ?
S1 O2 Eu1 102.32(4) . 7_556 ?
S1 O2 K2 108.23(4) . 8_455 ?
S1 O2 K2 135.81(5) . 2_657 ?
Eu1 O5 K2 110.73(3) 7_556 2_657 ?
Eu1 O5 K2 105.65(3) 7_556 1_455 ?
K2 O5 K2 84.82(2) 1_455 2_657 ?
S2 O5 Eu1 103.90(4) . 7_556 ?
S2 O5 K2 95.02(4) . 2_657 ?
S2 O5 K2 148.41(5) . 1_455 ?
K2 O3 K1 95.51(3) . . ?
S1 O3 K1 102.46(4) . . ?
S1 O3 K2 111.46(4) . . ?
S1 O3 Na1 138.50(5) . . ?
Na1 O3 K1 97.29(3) . . ?
Na1 O3 K2 102.41(3) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Eu1 S1 O4 Eu1 50.78(11) 7_556 . . . ?
Eu1 S1 O4 K2 179.114(15) 7_556 . . . ?
Eu1 S1 O4 K2 -56.89(4) 7_556 . . 8_455 ?
Eu1 S1 O7 K1 133.58(4) 7_556 . . . ?
Eu1 S1 O7 K2 -127.04(11) 7_556 . . 2_656 ?
Eu1 S1 O2 K2 -139.73(8) 7_556 . . 2_657 ?
Eu1 S1 O2 K2 124.48(5) 7_556 . . 8_455 ?
Eu1 S1 O3 K1 -76.76(4) 7_556 . . . ?
Eu1 S1 O3 K2 -177.854(13) 7_556 . . . ?
Eu1 S1 O3 Na1 39.71(9) 7_556 . . . ?
Eu1 S2 O1 K2 44.51(7) 3_455 . . 5_667 ?
Eu1 S2 O1 K2 -44.51(7) 7_556 . . 2_657 ?
Eu1 S2 O1 K2 -174.726(14) 3_455 . . 2_657 ?
Eu1 S2 O1 K2 174.726(14) 7_556 . . 5_667 ?
Eu1 S2 O1 Na1 -65.11(4) 3_455 . . . ?
Eu1 S2 O1 Na1 65.11(4) 7_556 . . . ?
Eu1 S2 O6 Eu1 119.87(5) 7_556 . . 3_455 ?
Eu1 S2 O6 Eu1 -119.87(5) 3_455 . . 7_556 ?
Eu1 S2 O5 Eu1 62.45(4) 3_455 . . 7_556 ?
Eu1 S2 O5 K2 112.82(4) 7_556 . . 2_657 ?
Eu1 S2 O5 K2 -158.91(11) 7_556 . . 1_455 ?
Eu1 S2 O5 K2 175.271(14) 3_455 . . 2_657 ?
Eu1 S2 O5 K2 -96.46(9) 3_455 . . 1_455 ?
K1 S1 O4 Eu1 -76.57(9) . . . . ?
K1 S1 O4 K2 51.76(3) . . . . ?
K1 S1 O4 K2 175.763(10) . . . 8_455 ?
K1 S1 O7 Eu1 -133.58(4) . . . 7_556 ?
K1 S1 O7 K2 99.38(10) . . . 2_656 ?
K1 S1 O2 Eu1 60.76(6) . . . 7_556 ?
K1 S1 O2 K2 -78.97(7) . . . 2_657 ?
K1 S1 O2 K2 -174.768(15) . . . 8_455 ?
K1 S1 O3 K2 -101.10(5) . . . . ?
K1 S1 O3 Na1 116.47(9) . . . . ?
K2 S1 O4 Eu1 -128.34(10) . . . . ?
K2 S1 O4 Eu1 107.67(9) 8_455 . . . ?
K2 S1 O4 K2 124.00(3) . . . 8_455 ?
K2 S1 O4 K2 -124.00(3) 8_455 . . . ?
K2 S1 O7 Eu1 -168.979(12) . . . 7_556 ?
K2 S1 O7 Eu1 50.94(4) 8_455 . . 7_556 ?
K2 S1 O7 K1 -175.473(12) 8_455 . . . ?
K2 S1 O7 K1 -35.40(4) . . . . ?
K2 S1 O7 K2 63.98(11) . . . 2_656 ?
K2 S1 O7 K2 -76.10(11) 8_455 . . 2_656 ?
K2 S1 O2 Eu1 167.942(14) . . . 7_556 ?
K2 S1 O2 Eu1 -124.48(5) 8_455 . . 7_556 ?
K2 S1 O2 K2 -67.58(5) . . . 8_455 ?
K2 S1 O2 K2 28.21(8) . . . 2_657 ?
K2 S1 O2 K2 95.79(7) 8_455 . . 2_657 ?
K2 S1 O3 K1 174.103(11) 8_455 . . . ?
K2 S1 O3 K1 101.10(5) . . . . ?
K2 S1 O3 K2 73.01(5) 8_455 . . . ?
K2 S1 O3 Na1 -142.43(10) . . . . ?
K2 S1 O3 Na1 -69.43(8) 8_455 . . . ?
K2 S2 O1 K2 140.76(7) 5_667 . . 2_657 ?
K2 S2 O1 K2 -140.76(7) 2_657 . . 5_667 ?
K2 S2 O1 Na1 109.62(3) 2_657 . . . ?
K2 S2 O1 Na1 -109.62(3) 5_667 . . . ?
K2 S2 O6 Eu1 178.038(13) 5_667 . . 7_556 ?
K2 S2 O6 Eu1 -62.09(5) 5_667 . . 3_455 ?
K2 S2 O6 Eu1 62.09(5) 2_657 . . 7_556 ?
K2 S2 O6 Eu1 -178.038(13) 2_657 . . 3_455 ?
K2 S2 O5 Eu1 -177.700(17) 5_667 . . 7_556 ?
K2 S2 O5 Eu1 -112.82(4) 2_657 . . 7_556 ?
K2 S2 O5 K2 23.39(12) 5_667 . . 1_455 ?
K2 S2 O5 K2 -64.88(5) 5_667 . . 2_657 ?
K2 S2 O5 K2 88.27(9) 2_657 . . 1_455 ?
O1 S2 O6 Eu1 120.06(3) . . . 7_556 ?
O1 S2 O6 Eu1 -120.06(3) . . . 3_455 ?
O1 S2 O5 Eu1 -121.05(5) . . . 7_556 ?
O1 S2 O5 K2 -8.23(6) . . . 2_657 ?
O1 S2 O5 K2 80.04(10) . . . 1_455 ?
O4 S1 O7 Eu1 119.67(4) . . . 7_556 ?
O4 S1 O7 K1 -106.75(4) . . . . ?
O4 S1 O7 K2 -7.38(12) . . . 2_656 ?
O4 S1 O2 Eu1 -121.53(4) . . . 7_556 ?
O4 S1 O2 K2 98.74(7) . . . 2_657 ?
O4 S1 O2 K2 2.95(6) . . . 8_455 ?
O4 S1 O3 K1 107.19(5) . . . . ?
O4 S1 O3 K2 6.10(6) . . . . ?
O4 S1 O3 Na1 -136.34(7) . . . . ?
O6 S2 O1 K2 109.62(3) . . . 5_667 ?
O6 S2 O1 K2 -109.62(3) . . . 2_657 ?
O6 S2 O1 Na1 0.000(0) . . . . ?
O6 S2 O5 Eu1 1.24(6) . . . 7_556 ?
O6 S2 O5 K2 114.06(5) . . . 2_657 ?
O6 S2 O5 K2 -157.67(9) . . . 1_455 ?
O7 S1 O4 Eu1 -10.88(11) . . . . ?
O7 S1 O4 K2 -118.54(4) . . . 8_455 ?
O7 S1 O4 K2 117.46(4) . . . . ?
O7 S1 O2 Eu1 -1.68(5) . . . 7_556 ?
O7 S1 O2 K2 -141.41(6) . . . 2_657 ?
O7 S1 O2 K2 122.80(4) . . . 8_455 ?
O7 S1 O3 K1 -15.61(5) . . . . ?
O7 S1 O3 K2 -116.70(5) . . . . ?
O7 S1 O3 Na1 100.86(8) . . . . ?
O2 S1 O4 Eu1 105.16(9) . . . . ?
O2 S1 O4 K2 -126.51(4) . . . . ?
O2 S1 O4 K2 -2.51(5) . . . 8_455 ?
O2 S1 O7 Eu1 1.58(5) . . . 7_556 ?
O2 S1 O7 K1 135.16(4) . . . . ?
O2 S1 O7 K2 -125.46(9) . . . 2_656 ?
O2 S1 O3 K1 -132.82(4) . . . . ?
O2 S1 O3 K2 126.09(5) . . . . ?
O2 S1 O3 Na1 -16.34(9) . . . . ?
O5 S2 O1 K2 -131.81(4) . . . 5_667 ?
O5 S2 O1 K2 8.95(6) . . . 2_657 ?
O5 S2 O1 K2 131.81(4) 6_565 . . 2_657 ?
O5 S2 O1 K2 -8.95(6) 6_565 . . 5_667 ?
O5 S2 O1 Na1 -118.57(4) 6_565 . . . ?
O5 S2 O1 Na1 118.57(4) . . . . ?
O5 S2 O6 Eu1 1.11(5) 6_565 . . 3_455 ?
O5 S2 O6 Eu1 -1.11(5) . . . 7_556 ?
O5 S2 O6 Eu1 118.76(4) . . . 3_455 ?
O5 S2 O6 Eu1 -118.76(4) 6_565 . . 7_556 ?
O5 S2 O5 Eu1 115.98(4) 6_565 . . 7_556 ?
O5 S2 O5 K2 -42.93(13) 6_565 . . 1_455 ?
O5 S2 O5 K2 -131.20(4) 6_565 . . 2_657 ?
O3 S1 O4 Eu1 -133.21(9) . . . . ?
O3 S1 O4 K2 -4.87(5) . . . . ?
O3 S1 O4 K2 119.13(4) . . . 8_455 ?
O3 S1 O7 Eu1 -119.27(4) . . . 7_556 ?
O3 S1 O7 K1 14.31(5) . . . . ?
O3 S1 O7 K2 113.68(10) . . . 2_656 ?
O3 S1 O2 Eu1 118.66(5) . . . 7_556 ?
O3 S1 O2 K2 -21.06(8) . . . 2_657 ?
O3 S1 O2 K2 -116.86(5) . . . 8_455 ?

_olex2_submission_special_instructions 'No special instructions were received'
