# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2022

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1008g2s
_database_code_depnum_ccdc_archive 'CCDC 2170156'
loop_
_audit_author_name
_audit_author_address
'Andreas Schnepf'
;University Tuebingen
Germany
;
_audit_update_record             
;
2022-05-03 deposited with the CCDC.	2022-08-05 downloaded from the CCDC.
;
_audit_creation_date             2021-08-27
_audit_creation_method           
;
Olex2 1.5
(compiled 2021.08.20 svn.r13c46975 for OlexSys, GUI svn.r6392)
;
_shelx_SHELXL_version_number     2014/7
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C84 H216 Au4 Ge18 P4 Si16'
_chemical_formula_sum            'C84 H216 Au4 Ge18 P4 Si16'
_chemical_formula_weight         3894.36
_chemical_melting_point          ?
_chemical_oxdiff_formula         C82H212Au4Ge18P4Si16
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/n 1'
_space_group_name_Hall           '-P 2yn'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   18.2022(2)
_cell_length_b                   15.1707(2)
_cell_length_c                   27.4875(3)
_cell_angle_alpha                90
_cell_angle_beta                 101.1190(10)
_cell_angle_gamma                90
_cell_volume                     7447.92(15)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    77581
_cell_measurement_temperature    100.00(11)
_cell_measurement_theta_max      38.2050
_cell_measurement_theta_min      2.0110
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    7.695
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.502
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.41.116a (Rigaku Oxford Diffraction, 2021)
Numerical absorption correction based on gaussian integration over
a multifaceted crystal model
Spherical absorption correction
using equivalent radius and absorption coefficient.
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            black
_exptl_crystal_colour_primary    black
_exptl_crystal_density_diffrn    1.737
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       irregular
_exptl_crystal_F_000             3792
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
1 -2 2 0.0265
-1 2 -2 0.0262
1 -1 -1 0.0751
0 -1 -1 0.0591
1 0 1 0.0535
-2 -1 0 0.0564
-1 -1 2 0.0306
2 1 -2 0.0504
-1 0 2 0.0488
0 0 1 0.0667
0 1 2 0.0575
-1 1 2 0.0630
-1 -1 -1 0.0729

_exptl_crystal_size_max          0.154
_exptl_crystal_size_mid          0.123
_exptl_crystal_size_min          0.053
loop_
_exptl_oxdiff_crystal_face_indexfrac_h
_exptl_oxdiff_crystal_face_indexfrac_k
_exptl_oxdiff_crystal_face_indexfrac_l
_exptl_oxdiff_crystal_face_x
_exptl_oxdiff_crystal_face_y
_exptl_oxdiff_crystal_face_z
0.9982 -1.9934 2.0034 0.0128 -0.1058 -0.0497
-0.9982 1.9934 -2.0034 -0.0128 0.1058 0.0497
0.9971 -0.9997 -0.9970 -0.0437 -0.0373 -0.0272
-0.0032 -0.9996 -0.9968 -0.0376 -0.0363 0.0120
1.0013 0.0014 0.9991 0.0174 -0.0090 -0.0478
-2.0026 -0.9979 0.0030 -0.0018 -0.0424 0.0818
-1.0002 -0.9950 2.0014 0.0391 -0.0595 0.0254
2.0004 0.9949 -2.0016 -0.0452 0.0585 -0.0646
-0.9981 0.0031 1.9988 0.0531 -0.0151 0.0220
0.0011 0.0015 0.9993 0.0235 -0.0080 -0.0086
0.0042 1.0011 1.9961 0.0610 0.0283 -0.0206
-0.9960 1.0012 1.9963 0.0672 0.0293 0.0186
-1.0034 -0.9995 -0.9966 -0.0314 -0.0353 0.0512

_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0508
_diffrn_reflns_av_unetI/netI     0.0208
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_h_min       -22
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       33
_diffrn_reflns_limit_l_min       -33
_diffrn_reflns_number            174242
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.999
_diffrn_reflns_theta_min         2.001
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      100.00(11)
_diffrn_detector                 'Hybrid Pixel Array Detector'
_diffrn_detector_area_resol_mean 10.0000
_diffrn_detector_type            HyPix
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω     24.00  88.00   0.50   30.00    --   31.72-145.00-133.00  128
  2  ω     13.00  76.00   0.50   30.00    --   31.72-125.00  33.00  126
  3  ω    -49.00  43.00   0.50   30.00    --  -29.22  77.00 120.00  184
  4  ω    -27.00   1.00   0.50   30.00    --  -29.22 -98.00 171.15   56
  5  ω   -101.00 -10.00   0.50   30.00    --  -29.22 -77.00  60.00  182
  6  ω    -34.00  -2.00   0.50   30.00    --  -29.22 -93.00 -40.76   64
  7  ω    -42.00  -8.00   0.50   30.00    --  -29.22 -81.00 118.75   68
  8  ω    -40.00   5.00   0.50   30.00    --   31.72 -19.00-150.00   90
  9  ω     39.00 103.00   0.50   30.00    --   31.72-178.00 150.00  128
 10  ω    -39.00  21.00   0.50   30.00    --   31.72 -37.00 120.00  120
 11  ω     16.00  79.00   0.50   30.00    --   31.72-130.00-101.65  126
 12  ω      7.00  72.00   0.50   30.00    --   31.72-116.00  18.42  130
 13  ω    -40.00   5.00   0.50   30.00    --   31.72 -19.00  30.00   90
 14  ω     15.00  78.00   0.50   30.00    --   31.72-128.00  71.08  126
 15  ω    -17.00  38.00   0.50   30.00    --   31.72   0.00 -90.00  110
 16  ω     42.00 102.00   0.50   30.00    --   31.72 178.00 -30.00  120
 17  ω    -23.00  62.00   0.50   30.00    --   31.72 -99.00 120.00  170
 18  ω    -40.00   5.00   0.50   30.00    --   31.72 -19.00 150.00   90
 19  ω    -39.00  21.00   0.50   30.00    --   31.72 -37.00 -90.00  120
 20  ω    -40.00   5.00   0.50   30.00    --   31.72 -19.00  60.00   90
 21  ω     12.00  37.00   0.50   30.00    --   31.72  77.00-120.00   50
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'XtaLAB Synergy, Dualflex, HyPix'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.0061089000
_diffrn_orient_matrix_UB_12      0.0141535000
_diffrn_orient_matrix_UB_13      0.0234978000
_diffrn_orient_matrix_UB_21      -0.0009851000
_diffrn_orient_matrix_UB_22      0.0444453000
_diffrn_orient_matrix_UB_23      -0.0081173000
_diffrn_orient_matrix_UB_31      -0.0392154000
_diffrn_orient_matrix_UB_32      -0.0033198000
_diffrn_orient_matrix_UB_33      -0.0085798000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'PhotonJet (Mo) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                12563
_reflns_number_total             14643
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.41.116a (Rigaku OD, 2021)'
_computing_data_collection       'CrysAlisPro 1.171.41.116a (Rigaku OD, 2021)'
_computing_data_reduction        'CrysAlisPro 1.171.41.116a (Rigaku OD, 2021)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2014/7 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT  (Sheldrick, 2015)'
_refine_diff_density_max         3.312
_refine_diff_density_min         -2.380
_refine_diff_density_rms         0.120
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.040
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     642
_refine_ls_number_reflns         14643
_refine_ls_number_restraints     48
_refine_ls_R_factor_all          0.0375
_refine_ls_R_factor_gt           0.0278
_refine_ls_restrained_S_all      1.043
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0279P)²+31.7513P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0633
_refine_ls_wR_factor_ref         0.0692
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 C110-C109 = C114-C113 = C115-C114 = C111-C110 = C112-C111 = C116-C115
 1.54 with sigma of 0.02
 C214-C213 = C210-C209 = C214-C215 = C211-C210 = C216-C215 = C211-C212
 1.54 with sigma of 0.02
3. Uiso/Uaniso restraints and constraints
C110 \\sim C114: within 2A with sigma of 0.01 and sigma for terminal atoms of
0.02 within 2A
C111 \\sim C115: within 2A with sigma of 0.01 and sigma for terminal atoms of
0.02 within 2A
C109 \\sim C113: within 2A with sigma of 0.01 and sigma for terminal atoms of
0.02 within 2A
C209 \\sim C213: within 2A with sigma of 0.01 and sigma for terminal atoms of
0.02 within 2A
Uanis(C116) \\sim Ueq, Uanis(C112) \\sim Ueq: with sigma of 0.01 and sigma for
terminal atoms of 0.02
4. Others
 Sof(C213)=Sof(H21H)=Sof(H21I)=Sof(C214)=Sof(H21J)=Sof(H21K)=Sof(C215)=
 Sof(H21L)=Sof(H21M)=Sof(C216)=Sof(H21N)=Sof(H21O)=Sof(H21P)=1-FVAR(1)
 Sof(C209)=Sof(H20S)=Sof(H20T)=Sof(C210)=Sof(H21A)=Sof(H21B)=Sof(C211)=
 Sof(H21C)=Sof(H21D)=Sof(C212)=Sof(H21E)=Sof(H21F)=Sof(H21G)=FVAR(1)
 Sof(C113)=Sof(H11H)=Sof(H11I)=Sof(C114)=Sof(H11J)=Sof(H11K)=Sof(C115)=
 Sof(H11L)=Sof(H11M)=Sof(C116)=Sof(H11N)=Sof(H11O)=Sof(H11P)=1-FVAR(2)
 Sof(C109)=Sof(H10S)=Sof(H10T)=Sof(C110)=Sof(H11A)=Sof(H11B)=Sof(C111)=
 Sof(H11C)=Sof(H11D)=Sof(C112)=Sof(H11E)=Sof(H11F)=Sof(H11G)=FVAR(2)
5.a Secondary CH2 refined with riding coordinates:
 C101(H10A,H10B), C102(H10C,H10D), C103(H10E,H10F), C105(H10J,H10K), C106(H10L,
 H10M), C107(H10N,H10O), C109(H10S,H10T), C110(H11A,H11B), C111(H11C,H11D),
 C113(H11H,H11I), C114(H11J,H11K), C115(H11L,H11M), C201(H20A,H20B), C202(H20C,
 H20D), C203(H20E,H20F), C205(H20J,H20K), C206(H20L,H20M), C207(H20N,H20O),
 C209(H20S,H20T), C210(H21A,H21B), C211(H21C,H21D), C213(H21H,H21I), C214(H21J,
 H21K), C215(H21L,H21M)
5.b Me refined with riding coordinates:
 C104(H10G,H10H,H10I), C108(H10P,H10Q,H10R), C112(H11E,H11F,H11G), C116(H11N,
 H11O,H11P), C204(H20G,H20H,H20I), C208(H20P,H20Q,H20R), C212(H21E,H21F,H21G),
 C216(H21N,H21O,H21P), C411(H41A,H41B,H41C), C412(H41D,H41E,H41F), C413(H41G,
 H41H,H41I), C421(H42A,H42B,H42C), C422(H42D,H42E,H42F), C423(H42G,H42H,H42I),
 C431(H43A,H43B,H43C), C432(H43D,H43E,H43F), C433(H43G,H43H,H43I), C511(H51A,
 H51B,H51C), C512(H51D,H51E,H51F), C513(H51G,H51H,H51I), C521(H52A,H52B,H52C),
 C522(H52D,H52E,H52F), C523(H52G,H52H,H52I), C531(H53A,H53B,H53C), C532(H53D,
 H53E,H53F), C533(H53G,H53H,H53I)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.26725(2) 0.33210(2) 0.60896(2) 0.02872(5) Uani 1 1 d . . . . .
Au2 Au 0.54023(2) 0.65868(2) 0.55348(2) 0.02088(5) Uani 1 1 d . . . . .
Ge1 Ge 0.29163(2) 0.43862(3) 0.53780(2) 0.02289(10) Uani 1 1 d . . . . .
Ge2 Ge 0.31651(2) 0.48135(3) 0.64833(2) 0.02412(10) Uani 1 1 d . . . . .
Ge3 Ge 0.40925(2) 0.34952(3) 0.60603(2) 0.02275(10) Uani 1 1 d . . . . .
Ge4 Ge 0.31725(2) 0.58756(3) 0.57935(2) 0.02201(10) Uani 1 1 d . . . . .
Ge5 Ge 0.45574(2) 0.48389(3) 0.65812(2) 0.02197(10) Uani 1 1 d . . . . .
Ge6 Ge 0.42173(2) 0.41065(3) 0.52191(2) 0.02166(10) Uani 1 1 d . . . . .
Ge7 Ge 0.40914(2) 0.57854(3) 0.51882(2) 0.01986(9) Uani 1 1 d . . . . .
Ge8 Ge 0.45042(2) 0.63693(3) 0.61802(2) 0.02209(10) Uani 1 1 d . . . . .
Ge9 Ge 0.52234(2) 0.49232(3) 0.58325(2) 0.02005(9) Uani 1 1 d . . . . .
P1 P 0.17836(7) 0.22515(10) 0.61393(5) 0.0345(3) Uani 1 1 d . . . . .
P2 P 0.61106(8) 0.78647(8) 0.57412(5) 0.0358(3) Uani 1 1 d . . . . .
Si4 Si 0.22100(7) 0.69430(8) 0.55705(4) 0.0232(2) Uani 1 1 d . . . . .
Si5 Si 0.54536(7) 0.43458(9) 0.72790(4) 0.0234(3) Uani 1 1 d . . . . .
Si41 Si 0.10868(7) 0.62756(10) 0.56848(5) 0.0294(3) Uani 1 1 d . . . . .
Si42 Si 0.21731(8) 0.73889(10) 0.47481(5) 0.0340(3) Uani 1 1 d . . . . .
Si43 Si 0.25230(8) 0.80983(9) 0.61387(5) 0.0300(3) Uani 1 1 d . . . . .
Si51 Si 0.48683(8) 0.32946(10) 0.77042(5) 0.0348(3) Uani 1 1 d . . . . .
Si52 Si 0.65023(7) 0.37011(10) 0.70415(5) 0.0319(3) Uani 1 1 d . . . . .
Si53 Si 0.58085(8) 0.55735(10) 0.77850(5) 0.0351(3) Uani 1 1 d . . . . .
C101 C 0.0835(3) 0.2688(4) 0.6091(2) 0.0479(15) Uani 1 1 d . . . . .
H10A H 0.0694 0.3000 0.5770 0.057 Uiso 1 1 calc R U . . .
H10B H 0.0486 0.2186 0.6086 0.057 Uiso 1 1 calc R U . . .
C102 C 0.0732(3) 0.3304(5) 0.6497(2) 0.0554(17) Uani 1 1 d . . . . .
H10C H 0.1069 0.3816 0.6500 0.067 Uiso 1 1 calc R U . . .
H10D H 0.0870 0.2998 0.6820 0.067 Uiso 1 1 calc R U . . .
C103 C -0.0080(4) 0.3629(6) 0.6430(3) 0.078(2) Uani 1 1 d . . . . .
H10E H -0.0173 0.4041 0.6145 0.094 Uiso 1 1 calc R U . . .
H10F H -0.0416 0.3117 0.6341 0.094 Uiso 1 1 calc R U . . .
C104 C -0.0285(5) 0.4054(8) 0.6838(4) 0.106(4) Uani 1 1 d . . . . .
H10G H -0.0812 0.4231 0.6752 0.159 Uiso 1 1 calc R U . . .
H10H H -0.0215 0.3649 0.7121 0.159 Uiso 1 1 calc R U . . .
H10I H 0.0029 0.4577 0.6924 0.159 Uiso 1 1 calc R U . . .
C105 C 0.1926(3) 0.1596(4) 0.6704(2) 0.0451(14) Uani 1 1 d . . . . .
H10J H 0.1879 0.1985 0.6985 0.054 Uiso 1 1 calc R U . . .
H10K H 0.1524 0.1148 0.6673 0.054 Uiso 1 1 calc R U . . .
C106 C 0.2681(3) 0.1130(4) 0.6822(2) 0.0439(13) Uani 1 1 d . . . . .
H10L H 0.3085 0.1576 0.6876 0.053 Uiso 1 1 calc R U . . .
H10M H 0.2743 0.0764 0.6534 0.053 Uiso 1 1 calc R U . . .
C107 C 0.2755(4) 0.0545(5) 0.7280(2) 0.0543(16) Uani 1 1 d . . . . .
H10N H 0.2713 0.0917 0.7569 0.065 Uiso 1 1 calc R U . . .
H10O H 0.2334 0.0120 0.7230 0.065 Uiso 1 1 calc R U . . .
C108 C 0.3476(4) 0.0045(5) 0.7392(2) 0.0586(17) Uani 1 1 d . . . . .
H10P H 0.3488 -0.0316 0.7689 0.088 Uiso 1 1 calc R U . . .
H10Q H 0.3517 -0.0337 0.7111 0.088 Uiso 1 1 calc R U . . .
H10R H 0.3896 0.0461 0.7450 0.088 Uiso 1 1 calc R U . . .
C109 C 0.1692(5) 0.1333(5) 0.5678(3) 0.0272(18) Uani 0.630(7) 1 d D U P A 1
H10S H 0.2155 0.0975 0.5737 0.033 Uiso 0.630(7) 1 calc R U P A 1
H10T H 0.1269 0.0947 0.5717 0.033 Uiso 0.630(7) 1 calc R U P A 1
C110 C 0.1555(5) 0.1711(5) 0.5148(3) 0.0320(18) Uani 0.630(7) 1 d D U P A 1
H11A H 0.1987 0.2084 0.5110 0.038 Uiso 0.630(7) 1 calc R U P A 1
H11B H 0.1105 0.2091 0.5098 0.038 Uiso 0.630(7) 1 calc R U P A 1
C111 C 0.1446(6) 0.0985(6) 0.4745(3) 0.046(2) Uani 0.630(7) 1 d D U P A 1
H11C H 0.0994 0.0636 0.4767 0.055 Uiso 0.630(7) 1 calc R U P A 1
H11D H 0.1365 0.1265 0.4413 0.055 Uiso 0.630(7) 1 calc R U P A 1
C112 C 0.2130(9) 0.0365(10) 0.4803(6) 0.116(6) Uani 0.630(7) 1 d D U P A 1
H11E H 0.2042 -0.0085 0.4543 0.174 Uiso 0.630(7) 1 calc R U P A 1
H11F H 0.2577 0.0707 0.4775 0.174 Uiso 0.630(7) 1 calc R U P A 1
H11G H 0.2206 0.0079 0.5129 0.174 Uiso 0.630(7) 1 calc R U P A 1
C113 C 0.1627(10) 0.1727(13) 0.5522(8) 0.052(4) Uani 0.370(7) 1 d D U P A 2
H11H H 0.1601 0.2201 0.5272 0.063 Uiso 0.370(7) 1 calc R U P A 2
H11I H 0.2075 0.1368 0.5503 0.063 Uiso 0.370(7) 1 calc R U P A 2
C114 C 0.0953(9) 0.1152(11) 0.5370(6) 0.057(4) Uani 0.370(7) 1 d D U P A 2
H11J H 0.0495 0.1504 0.5366 0.068 Uiso 0.370(7) 1 calc R U P A 2
H11K H 0.0963 0.0672 0.5615 0.068 Uiso 0.370(7) 1 calc R U P A 2
C115 C 0.0926(13) 0.0740(12) 0.4843(6) 0.063(4) Uani 0.370(7) 1 d D U P A 2
H11L H 0.0891 0.1218 0.4594 0.076 Uiso 0.370(7) 1 calc R U P A 2
H11M H 0.1395 0.0409 0.4841 0.076 Uiso 0.370(7) 1 calc R U P A 2
C116 C 0.0309(13) 0.0168(15) 0.4711(9) 0.099(8) Uani 0.370(7) 1 d D U P A 2
H11N H 0.0306 -0.0078 0.4382 0.148 Uiso 0.370(7) 1 calc R U P A 2
H11O H 0.0347 -0.0311 0.4954 0.148 Uiso 0.370(7) 1 calc R U P A 2
H11P H -0.0156 0.0497 0.4707 0.148 Uiso 0.370(7) 1 calc R U P A 2
C201 C 0.5829(4) 0.8789(4) 0.5309(2) 0.0449(14) Uani 1 1 d . . . . .
H20A H 0.5323 0.8989 0.5341 0.054 Uiso 1 1 calc R U . . .
H20B H 0.6179 0.9287 0.5405 0.054 Uiso 1 1 calc R U . . .
C202 C 0.5819(4) 0.8558(4) 0.4772(2) 0.0478(14) Uani 1 1 d . . . . .
H20C H 0.5498 0.8034 0.4683 0.057 Uiso 1 1 calc R U . . .
H20D H 0.6333 0.8401 0.4735 0.057 Uiso 1 1 calc R U . . .
C203 C 0.5534(4) 0.9301(4) 0.4416(2) 0.0497(15) Uani 1 1 d . . . . .
H20E H 0.5009 0.9433 0.4440 0.060 Uiso 1 1 calc R U . . .
H20F H 0.5835 0.9836 0.4520 0.060 Uiso 1 1 calc R U . . .
C204 C 0.5566(4) 0.9101(4) 0.3891(2) 0.0575(17) Uani 1 1 d . . . . .
H20G H 0.5374 0.9605 0.3682 0.086 Uiso 1 1 calc R U . . .
H20H H 0.6086 0.8984 0.3863 0.086 Uiso 1 1 calc R U . . .
H20I H 0.5259 0.8580 0.3783 0.086 Uiso 1 1 calc R U . . .
C205 C 0.7086(3) 0.7678(4) 0.5714(3) 0.063(2) Uani 1 1 d . . . . .
H20J H 0.7126 0.7575 0.5365 0.075 Uiso 1 1 calc R U . . .
H20K H 0.7374 0.8218 0.5828 0.075 Uiso 1 1 calc R U . . .
C206 C 0.7439(3) 0.6903(4) 0.6026(3) 0.0540(16) Uani 1 1 d . . . . .
H20L H 0.7105 0.6384 0.5957 0.065 Uiso 1 1 calc R U . . .
H20M H 0.7490 0.7051 0.6382 0.065 Uiso 1 1 calc R U . . .
C207 C 0.8216(4) 0.6668(4) 0.5916(3) 0.0620(19) Uani 1 1 d . . . . .
H20N H 0.8155 0.6474 0.5566 0.074 Uiso 1 1 calc R U . . .
H20O H 0.8532 0.7204 0.5955 0.074 Uiso 1 1 calc R U . . .
C208 C 0.8608(4) 0.5959(4) 0.6244(3) 0.067(2) Uani 1 1 d . . . . .
H20P H 0.9096 0.5841 0.6156 0.100 Uiso 1 1 calc R U . . .
H20Q H 0.8682 0.6151 0.6591 0.100 Uiso 1 1 calc R U . . .
H20R H 0.8305 0.5421 0.6201 0.100 Uiso 1 1 calc R U . . .
C209 C 0.5936(8) 0.8335(8) 0.6365(5) 0.031(3) Uani 0.498(10) 1 d D U P B 1
H20S H 0.5391 0.8335 0.6358 0.037 Uiso 0.498(10) 1 calc R U P B 1
H20T H 0.6172 0.7936 0.6636 0.037 Uiso 0.498(10) 1 calc R U P B 1
C210 C 0.6238(6) 0.9268(6) 0.6484(4) 0.034(3) Uani 0.498(10) 1 d D . P B 1
H21A H 0.5969 0.9687 0.6235 0.041 Uiso 0.498(10) 1 calc R U P B 1
H21B H 0.6777 0.9289 0.6470 0.041 Uiso 0.498(10) 1 calc R U P B 1
C211 C 0.6126(12) 0.9535(9) 0.7007(6) 0.041(4) Uani 0.498(10) 1 d D . P B 1
H21C H 0.5590 0.9479 0.7026 0.049 Uiso 0.498(10) 1 calc R U P B 1
H21D H 0.6416 0.9133 0.7256 0.049 Uiso 0.498(10) 1 calc R U P B 1
C212 C 0.6385(9) 1.0494(9) 0.7126(5) 0.055(4) Uani 0.498(10) 1 d D . P B 1
H21E H 0.6310 1.0650 0.7459 0.082 Uiso 0.498(10) 1 calc R U P B 1
H21F H 0.6917 1.0547 0.7112 0.082 Uiso 0.498(10) 1 calc R U P B 1
H21G H 0.6093 1.0893 0.6882 0.082 Uiso 0.498(10) 1 calc R U P B 1
C213 C 0.6282(7) 0.8374(9) 0.6329(6) 0.035(3) Uani 0.502(10) 1 d D U P B 2
H21H H 0.6492 0.7938 0.6587 0.042 Uiso 0.502(10) 1 calc R U P B 2
H21I H 0.6651 0.8855 0.6336 0.042 Uiso 0.502(10) 1 calc R U P B 2
C214 C 0.5550(6) 0.8746(8) 0.6437(4) 0.041(3) Uani 0.502(10) 1 d D . P B 2
H21J H 0.5372 0.9217 0.6193 0.049 Uiso 0.502(10) 1 calc R U P B 2
H21K H 0.5169 0.8272 0.6387 0.049 Uiso 0.502(10) 1 calc R U P B 2
C215 C 0.5606(10) 0.9122(9) 0.6958(4) 0.060(4) Uani 0.502(10) 1 d D . P B 2
H21L H 0.5100 0.9284 0.7009 0.072 Uiso 0.502(10) 1 calc R U P B 2
H21M H 0.5806 0.8663 0.7205 0.072 Uiso 0.502(10) 1 calc R U P B 2
C216 C 0.6108(13) 0.9924(13) 0.7042(9) 0.075(7) Uani 0.502(10) 1 d D . P B 2
H21N H 0.6129 1.0145 0.7380 0.112 Uiso 0.502(10) 1 calc R U P B 2
H21O H 0.6612 0.9763 0.6999 0.112 Uiso 0.502(10) 1 calc R U P B 2
H21P H 0.5906 1.0383 0.6803 0.112 Uiso 0.502(10) 1 calc R U P B 2
C411 C 0.0254(3) 0.6956(4) 0.5396(2) 0.0456(14) Uani 1 1 d . . . . .
H41A H 0.0246 0.7022 0.5041 0.068 Uiso 1 1 calc R U . . .
H41B H -0.0206 0.6662 0.5445 0.068 Uiso 1 1 calc R U . . .
H41C H 0.0288 0.7539 0.5553 0.068 Uiso 1 1 calc R U . . .
C412 C 0.0958(3) 0.5140(4) 0.5410(2) 0.0462(14) Uani 1 1 d . . . . .
H41D H 0.0957 0.5172 0.5053 0.069 Uiso 1 1 calc R U . . .
H41E H 0.1369 0.4760 0.5570 0.069 Uiso 1 1 calc R U . . .
H41F H 0.0480 0.4896 0.5461 0.069 Uiso 1 1 calc R U . . .
C413 C 0.1083(3) 0.6165(4) 0.63606(19) 0.0394(12) Uani 1 1 d . . . . .
H41G H 0.1514 0.5812 0.6519 0.059 Uiso 1 1 calc R U . . .
H41H H 0.1113 0.6752 0.6513 0.059 Uiso 1 1 calc R U . . .
H41I H 0.0619 0.5875 0.6405 0.059 Uiso 1 1 calc R U . . .
C421 C 0.2081(3) 0.6398(4) 0.43336(19) 0.0451(14) Uani 1 1 d . . . . .
H42A H 0.1632 0.6065 0.4367 0.068 Uiso 1 1 calc R U . . .
H42B H 0.2040 0.6588 0.3989 0.068 Uiso 1 1 calc R U . . .
H42C H 0.2523 0.6021 0.4428 0.068 Uiso 1 1 calc R U . . .
C422 C 0.1338(4) 0.8126(4) 0.4540(2) 0.0526(16) Uani 1 1 d . . . . .
H42D H 0.1379 0.8648 0.4754 0.079 Uiso 1 1 calc R U . . .
H42E H 0.1322 0.8310 0.4197 0.079 Uiso 1 1 calc R U . . .
H42F H 0.0878 0.7804 0.4562 0.079 Uiso 1 1 calc R U . . .
C423 C 0.3035(3) 0.8016(4) 0.4679(2) 0.0482(14) Uani 1 1 d . . . . .
H42G H 0.3087 0.8536 0.4895 0.072 Uiso 1 1 calc R U . . .
H42H H 0.3475 0.7637 0.4773 0.072 Uiso 1 1 calc R U . . .
H42I H 0.2992 0.8203 0.4333 0.072 Uiso 1 1 calc R U . . .
C431 C 0.1697(3) 0.8861(4) 0.6105(2) 0.0456(14) Uani 1 1 d . . . . .
H43A H 0.1550 0.9091 0.5767 0.068 Uiso 1 1 calc R U . . .
H43B H 0.1276 0.8536 0.6194 0.068 Uiso 1 1 calc R U . . .
H43C H 0.1834 0.9352 0.6336 0.068 Uiso 1 1 calc R U . . .
C432 C 0.2813(3) 0.7651(4) 0.67800(18) 0.0357(12) Uani 1 1 d . . . . .
H43D H 0.2403 0.7302 0.6865 0.053 Uiso 1 1 calc R U . . .
H43E H 0.3256 0.7277 0.6796 0.053 Uiso 1 1 calc R U . . .
H43F H 0.2932 0.8140 0.7015 0.053 Uiso 1 1 calc R U . . .
C433 C 0.3325(4) 0.8758(4) 0.5996(2) 0.0512(16) Uani 1 1 d . . . . .
H43G H 0.3189 0.9002 0.5660 0.077 Uiso 1 1 calc R U . . .
H43H H 0.3441 0.9241 0.6235 0.077 Uiso 1 1 calc R U . . .
H43I H 0.3765 0.8377 0.6016 0.077 Uiso 1 1 calc R U . . .
C511 C 0.3855(3) 0.3544(5) 0.7664(2) 0.0582(19) Uani 1 1 d . . . . .
H51A H 0.3801 0.4133 0.7799 0.087 Uiso 1 1 calc R U . . .
H51B H 0.3597 0.3523 0.7317 0.087 Uiso 1 1 calc R U . . .
H51C H 0.3635 0.3106 0.7856 0.087 Uiso 1 1 calc R U . . .
C512 C 0.4938(4) 0.2167(4) 0.7443(2) 0.0559(16) Uani 1 1 d . . . . .
H51D H 0.5465 0.2017 0.7459 0.084 Uiso 1 1 calc R U . . .
H51E H 0.4711 0.1738 0.7636 0.084 Uiso 1 1 calc R U . . .
H51F H 0.4673 0.2154 0.7097 0.084 Uiso 1 1 calc R U . . .
C513 C 0.5347(3) 0.3281(4) 0.8377(2) 0.0471(15) Uani 1 1 d . . . . .
H51G H 0.5880 0.3151 0.8401 0.071 Uiso 1 1 calc R U . . .
H51H H 0.5291 0.3859 0.8525 0.071 Uiso 1 1 calc R U . . .
H51I H 0.5118 0.2828 0.8553 0.071 Uiso 1 1 calc R U . . .
C521 C 0.6242(3) 0.2890(4) 0.6529(2) 0.0426(13) Uani 1 1 d . . . . .
H52A H 0.5914 0.2438 0.6628 0.064 Uiso 1 1 calc R U . . .
H52B H 0.5978 0.3193 0.6232 0.064 Uiso 1 1 calc R U . . .
H52C H 0.6695 0.2611 0.6459 0.064 Uiso 1 1 calc R U . . .
C522 C 0.7045(3) 0.3095(4) 0.7596(2) 0.0469(15) Uani 1 1 d . . . . .
H52D H 0.7190 0.3509 0.7872 0.070 Uiso 1 1 calc R U . . .
H52E H 0.6732 0.2628 0.7694 0.070 Uiso 1 1 calc R U . . .
H52F H 0.7496 0.2834 0.7510 0.070 Uiso 1 1 calc R U . . .
C523 C 0.7129(3) 0.4560(4) 0.6846(2) 0.0454(14) Uani 1 1 d . . . . .
H52G H 0.7270 0.4990 0.7114 0.068 Uiso 1 1 calc R U . . .
H52H H 0.7581 0.4277 0.6775 0.068 Uiso 1 1 calc R U . . .
H52I H 0.6864 0.4860 0.6548 0.068 Uiso 1 1 calc R U . . .
C531 C 0.6611(4) 0.5313(5) 0.8306(2) 0.0575(18) Uani 1 1 d . . . . .
H53A H 0.6472 0.4822 0.8501 0.086 Uiso 1 1 calc R U . . .
H53B H 0.7050 0.5148 0.8169 0.086 Uiso 1 1 calc R U . . .
H53C H 0.6729 0.5833 0.8518 0.086 Uiso 1 1 calc R U . . .
C532 C 0.6101(3) 0.6508(4) 0.7425(2) 0.0504(15) Uani 1 1 d . . . . .
H53D H 0.5691 0.6658 0.7150 0.076 Uiso 1 1 calc R U . . .
H53E H 0.6221 0.7021 0.7642 0.076 Uiso 1 1 calc R U . . .
H53F H 0.6543 0.6336 0.7293 0.076 Uiso 1 1 calc R U . . .
C533 C 0.4986(4) 0.5947(5) 0.8057(3) 0.0641(19) Uani 1 1 d . . . . .
H53G H 0.4823 0.5464 0.8248 0.096 Uiso 1 1 calc R U . . .
H53H H 0.5134 0.6453 0.8275 0.096 Uiso 1 1 calc R U . . .
H53I H 0.4573 0.6117 0.7789 0.096 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 Ge1 2.6400(5) . ?
Au1 Ge2 2.5937(5) . ?
Au1 Ge3 2.6149(5) . ?
Au1 P1 2.3140(13) . ?
Au2 Ge6 2.5364(5) 3_666 ?
Au2 Ge7 2.6838(5) . ?
Au2 Ge8 2.6547(5) . ?
Au2 Ge9 2.6923(5) . ?
Au2 P2 2.3368(13) . ?
Ge1 Ge3 2.8949(6) . ?
Ge1 Ge4 2.5343(7) . ?
Ge1 Ge6 2.5254(6) . ?
Ge2 Ge4 2.4902(7) . ?
Ge2 Ge5 2.4967(6) . ?
Ge3 Ge5 2.5405(7) . ?
Ge3 Ge6 2.5417(6) . ?
Ge4 Ge7 2.5803(6) . ?
Ge4 Ge8 2.5638(6) . ?
Ge4 Si4 2.3776(13) . ?
Ge5 Ge8 2.5638(7) . ?
Ge5 Ge9 2.5851(6) . ?
Ge5 Si5 2.3860(12) . ?
Ge6 Au2 2.5364(5) 3_666 ?
Ge6 Ge7 2.5574(6) . ?
Ge6 Ge9 2.5575(6) . ?
Ge7 Ge8 2.8274(6) . ?
Ge7 Ge9 2.7724(6) . ?
Ge8 Ge9 2.8147(6) . ?
P1 C101 1.830(6) . ?
P1 C105 1.820(6) . ?
P1 C109 1.870(8) . ?
P1 C113 1.85(2) . ?
P2 C201 1.845(6) . ?
P2 C205 1.813(7) . ?
P2 C209 1.939(13) . ?
P2 C213 1.765(14) . ?
Si4 Si41 2.3561(18) . ?
Si4 Si42 2.3480(18) . ?
Si4 Si43 2.3436(18) . ?
Si5 Si51 2.3505(19) . ?
Si5 Si52 2.3467(17) . ?
Si5 Si53 2.3398(19) . ?
Si41 C411 1.878(5) . ?
Si41 C412 1.878(6) . ?
Si41 C413 1.867(5) . ?
Si42 C421 1.875(6) . ?
Si42 C422 1.886(6) . ?
Si42 C423 1.875(6) . ?
Si43 C431 1.886(6) . ?
Si43 C432 1.867(5) . ?
Si43 C433 1.873(6) . ?
Si51 C511 1.865(6) . ?
Si51 C512 1.869(7) . ?
Si51 C513 1.885(5) . ?
Si52 C521 1.861(6) . ?
Si52 C522 1.888(5) . ?
Si52 C523 1.877(6) . ?
Si53 C531 1.879(6) . ?
Si53 C532 1.864(6) . ?
Si53 C533 1.885(6) . ?
C101 H10A 0.9900 . ?
C101 H10B 0.9900 . ?
C101 C102 1.495(9) . ?
C102 H10C 0.9900 . ?
C102 H10D 0.9900 . ?
C102 C103 1.536(8) . ?
C103 H10E 0.9900 . ?
C103 H10F 0.9900 . ?
C103 C104 1.404(12) . ?
C104 H10G 0.9800 . ?
C104 H10H 0.9800 . ?
C104 H10I 0.9800 . ?
C105 H10J 0.9900 . ?
C105 H10K 0.9900 . ?
C105 C106 1.524(8) . ?
C106 H10L 0.9900 . ?
C106 H10M 0.9900 . ?
C106 C107 1.525(8) . ?
C107 H10N 0.9900 . ?
C107 H10O 0.9900 . ?
C107 C108 1.496(9) . ?
C108 H10P 0.9800 . ?
C108 H10Q 0.9800 . ?
C108 H10R 0.9800 . ?
C109 H10S 0.9900 . ?
C109 H10T 0.9900 . ?
C109 C110 1.540(9) . ?
C110 H11A 0.9900 . ?
C110 H11B 0.9900 . ?
C110 C111 1.547(10) . ?
C111 H11C 0.9900 . ?
C111 H11D 0.9900 . ?
C111 C112 1.545(14) . ?
C112 H11E 0.9800 . ?
C112 H11F 0.9800 . ?
C112 H11G 0.9800 . ?
C113 H11H 0.9900 . ?
C113 H11I 0.9900 . ?
C113 C114 1.498(16) . ?
C114 H11J 0.9900 . ?
C114 H11K 0.9900 . ?
C114 C115 1.569(16) . ?
C115 H11L 0.9900 . ?
C115 H11M 0.9900 . ?
C115 C116 1.410(18) . ?
C116 H11N 0.9800 . ?
C116 H11O 0.9800 . ?
C116 H11P 0.9800 . ?
C201 H20A 0.9900 . ?
C201 H20B 0.9900 . ?
C201 C202 1.513(8) . ?
C202 H20C 0.9900 . ?
C202 H20D 0.9900 . ?
C202 C203 1.517(8) . ?
C203 H20E 0.9900 . ?
C203 H20F 0.9900 . ?
C203 C204 1.487(9) . ?
C204 H20G 0.9800 . ?
C204 H20H 0.9800 . ?
C204 H20I 0.9800 . ?
C205 H20J 0.9900 . ?
C205 H20K 0.9900 . ?
C205 C206 1.523(9) . ?
C206 H20L 0.9900 . ?
C206 H20M 0.9900 . ?
C206 C207 1.544(10) . ?
C207 H20N 0.9900 . ?
C207 H20O 0.9900 . ?
C207 C208 1.495(9) . ?
C208 H20P 0.9800 . ?
C208 H20Q 0.9800 . ?
C208 H20R 0.9800 . ?
C209 H20S 0.9900 . ?
C209 H20T 0.9900 . ?
C209 C210 1.531(13) . ?
C210 H21A 0.9900 . ?
C210 H21B 0.9900 . ?
C210 C211 1.545(14) . ?
C211 H21C 0.9900 . ?
C211 H21D 0.9900 . ?
C211 C212 1.545(13) . ?
C212 H21E 0.9800 . ?
C212 H21F 0.9800 . ?
C212 H21G 0.9800 . ?
C213 H21H 0.9900 . ?
C213 H21I 0.9900 . ?
C213 C214 1.527(13) . ?
C214 H21J 0.9900 . ?
C214 H21K 0.9900 . ?
C214 C215 1.527(13) . ?
C215 H21L 0.9900 . ?
C215 H21M 0.9900 . ?
C215 C216 1.512(16) . ?
C216 H21N 0.9800 . ?
C216 H21O 0.9800 . ?
C216 H21P 0.9800 . ?
C411 H41A 0.9800 . ?
C411 H41B 0.9800 . ?
C411 H41C 0.9800 . ?
C412 H41D 0.9800 . ?
C412 H41E 0.9800 . ?
C412 H41F 0.9800 . ?
C413 H41G 0.9800 . ?
C413 H41H 0.9800 . ?
C413 H41I 0.9800 . ?
C421 H42A 0.9800 . ?
C421 H42B 0.9800 . ?
C421 H42C 0.9800 . ?
C422 H42D 0.9800 . ?
C422 H42E 0.9800 . ?
C422 H42F 0.9800 . ?
C423 H42G 0.9800 . ?
C423 H42H 0.9800 . ?
C423 H42I 0.9800 . ?
C431 H43A 0.9800 . ?
C431 H43B 0.9800 . ?
C431 H43C 0.9800 . ?
C432 H43D 0.9800 . ?
C432 H43E 0.9800 . ?
C432 H43F 0.9800 . ?
C433 H43G 0.9800 . ?
C433 H43H 0.9800 . ?
C433 H43I 0.9800 . ?
C511 H51A 0.9800 . ?
C511 H51B 0.9800 . ?
C511 H51C 0.9800 . ?
C512 H51D 0.9800 . ?
C512 H51E 0.9800 . ?
C512 H51F 0.9800 . ?
C513 H51G 0.9800 . ?
C513 H51H 0.9800 . ?
C513 H51I 0.9800 . ?
C521 H52A 0.9800 . ?
C521 H52B 0.9800 . ?
C521 H52C 0.9800 . ?
C522 H52D 0.9800 . ?
C522 H52E 0.9800 . ?
C522 H52F 0.9800 . ?
C523 H52G 0.9800 . ?
C523 H52H 0.9800 . ?
C523 H52I 0.9800 . ?
C531 H53A 0.9800 . ?
C531 H53B 0.9800 . ?
C531 H53C 0.9800 . ?
C532 H53D 0.9800 . ?
C532 H53E 0.9800 . ?
C532 H53F 0.9800 . ?
C533 H53G 0.9800 . ?
C533 H53H 0.9800 . ?
C533 H53I 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ge2 Au1 Ge1 71.387(15) . . ?
Ge2 Au1 Ge3 70.151(15) . . ?
Ge3 Au1 Ge1 66.855(14) . . ?
P1 Au1 Ge1 133.81(4) . . ?
P1 Au1 Ge2 140.98(4) . . ?
P1 Au1 Ge3 141.19(4) . . ?
Ge6 Au2 Ge7 83.471(15) 3_666 . ?
Ge6 Au2 Ge8 142.634(16) 3_666 . ?
Ge6 Au2 Ge9 85.855(15) 3_666 . ?
Ge7 Au2 Ge9 62.087(14) . . ?
Ge8 Au2 Ge7 63.958(14) . . ?
Ge8 Au2 Ge9 63.522(14) . . ?
P2 Au2 Ge6 108.52(4) . 3_666 ?
P2 Au2 Ge7 150.83(4) . . ?
P2 Au2 Ge8 108.84(4) . . ?
P2 Au2 Ge9 142.88(4) . . ?
Au1 Ge1 Ge3 56.159(13) . . ?
Ge4 Ge1 Au1 104.736(19) . . ?
Ge4 Ge1 Ge3 94.329(19) . . ?
Ge6 Ge1 Au1 108.81(2) . . ?
Ge6 Ge1 Ge3 55.424(16) . . ?
Ge6 Ge1 Ge4 97.50(2) . . ?
Ge4 Ge2 Au1 107.42(2) . . ?
Ge4 Ge2 Ge5 85.28(2) . . ?
Ge5 Ge2 Au1 108.69(2) . . ?
Au1 Ge3 Ge1 56.986(13) . . ?
Ge5 Ge3 Au1 106.71(2) . . ?
Ge5 Ge3 Ge1 96.59(2) . . ?
Ge5 Ge3 Ge6 98.13(2) . . ?
Ge6 Ge3 Au1 109.10(2) . . ?
Ge6 Ge3 Ge1 54.895(16) . . ?
Ge1 Ge4 Ge7 75.398(19) . . ?
Ge1 Ge4 Ge8 121.63(2) . . ?
Ge2 Ge4 Ge1 74.85(2) . . ?
Ge2 Ge4 Ge7 123.78(2) . . ?
Ge2 Ge4 Ge8 90.97(2) . . ?
Ge8 Ge4 Ge7 66.684(18) . . ?
Si4 Ge4 Ge1 115.38(4) . . ?
Si4 Ge4 Ge2 121.68(4) . . ?
Si4 Ge4 Ge7 114.01(4) . . ?
Si4 Ge4 Ge8 119.92(4) . . ?
Ge2 Ge5 Ge3 72.907(19) . . ?
Ge2 Ge5 Ge8 90.82(2) . . ?
Ge2 Ge5 Ge9 122.48(2) . . ?
Ge3 Ge5 Ge8 120.23(2) . . ?
Ge3 Ge5 Ge9 75.369(19) . . ?
Ge8 Ge5 Ge9 66.275(18) . . ?
Si5 Ge5 Ge2 127.17(4) . . ?
Si5 Ge5 Ge3 107.65(4) . . ?
Si5 Ge5 Ge8 126.35(4) . . ?
Si5 Ge5 Ge9 107.61(3) . . ?
Au2 Ge6 Ge3 132.71(2) 3_666 . ?
Au2 Ge6 Ge7 115.00(2) 3_666 . ?
Au2 Ge6 Ge9 117.77(2) 3_666 . ?
Ge1 Ge6 Au2 128.59(2) . 3_666 ?
Ge1 Ge6 Ge3 69.681(18) . . ?
Ge1 Ge6 Ge7 75.957(19) . . ?
Ge1 Ge6 Ge9 112.38(2) . . ?
Ge3 Ge6 Ge7 111.74(2) . . ?
Ge3 Ge6 Ge9 75.834(19) . . ?
Ge7 Ge6 Ge9 65.644(18) . . ?
Au2 Ge7 Ge8 57.522(13) . . ?
Au2 Ge7 Ge9 59.108(13) . . ?
Ge4 Ge7 Au2 112.931(19) . . ?
Ge4 Ge7 Ge8 56.378(16) . . ?
Ge4 Ge7 Ge9 96.168(19) . . ?
Ge6 Ge7 Au2 111.809(19) . . ?
Ge6 Ge7 Ge4 95.54(2) . . ?
Ge6 Ge7 Ge8 105.93(2) . . ?
Ge6 Ge7 Ge9 57.180(17) . . ?
Ge9 Ge7 Ge8 60.341(16) . . ?
Au2 Ge8 Ge7 58.520(13) . . ?
Au2 Ge8 Ge9 58.890(13) . . ?
Ge4 Ge8 Au2 114.46(2) . . ?
Ge4 Ge8 Ge5 82.41(2) . . ?
Ge4 Ge8 Ge7 56.938(16) . . ?
Ge4 Ge8 Ge9 95.51(2) . . ?
Ge5 Ge8 Au2 115.01(2) . . ?
Ge5 Ge8 Ge7 96.42(2) . . ?
Ge5 Ge8 Ge9 57.226(17) . . ?
Ge9 Ge8 Ge7 58.861(16) . . ?
Au2 Ge9 Ge7 58.805(13) . . ?
Au2 Ge9 Ge8 57.589(14) . . ?
Ge5 Ge9 Au2 113.02(2) . . ?
Ge5 Ge9 Ge7 97.296(19) . . ?
Ge5 Ge9 Ge8 56.499(17) . . ?
Ge6 Ge9 Au2 111.527(19) . . ?
Ge6 Ge9 Ge5 96.59(2) . . ?
Ge6 Ge9 Ge7 57.177(17) . . ?
Ge6 Ge9 Ge8 106.30(2) . . ?
Ge7 Ge9 Ge8 60.798(16) . . ?
C101 P1 Au1 113.7(2) . . ?
C101 P1 C109 105.1(3) . . ?
C101 P1 C113 96.5(7) . . ?
C105 P1 Au1 116.6(2) . . ?
C105 P1 C101 103.7(3) . . ?
C105 P1 C109 98.7(3) . . ?
C105 P1 C113 121.3(7) . . ?
C109 P1 Au1 117.0(3) . . ?
C113 P1 Au1 103.5(6) . . ?
C201 P2 Au2 113.72(19) . . ?
C201 P2 C209 102.6(5) . . ?
C205 P2 Au2 111.0(2) . . ?
C205 P2 C201 104.2(3) . . ?
C205 P2 C209 115.0(5) . . ?
C209 P2 Au2 110.1(4) . . ?
C213 P2 Au2 125.3(5) . . ?
C213 P2 C201 103.6(5) . . ?
C213 P2 C205 96.0(5) . . ?
Si41 Si4 Ge4 106.74(6) . . ?
Si42 Si4 Ge4 109.11(6) . . ?
Si42 Si4 Si41 112.81(7) . . ?
Si43 Si4 Ge4 105.38(6) . . ?
Si43 Si4 Si41 109.77(7) . . ?
Si43 Si4 Si42 112.60(7) . . ?
Si51 Si5 Ge5 107.89(6) . . ?
Si52 Si5 Ge5 111.95(6) . . ?
Si52 Si5 Si51 109.06(7) . . ?
Si53 Si5 Ge5 107.22(6) . . ?
Si53 Si5 Si51 110.13(7) . . ?
Si53 Si5 Si52 110.55(7) . . ?
C411 Si41 Si4 111.0(2) . . ?
C411 Si41 C412 107.8(3) . . ?
C412 Si41 Si4 112.63(18) . . ?
C413 Si41 Si4 109.95(17) . . ?
C413 Si41 C411 108.1(3) . . ?
C413 Si41 C412 107.1(3) . . ?
C421 Si42 Si4 109.7(2) . . ?
C421 Si42 C422 108.6(3) . . ?
C421 Si42 C423 108.9(3) . . ?
C422 Si42 Si4 109.5(2) . . ?
C423 Si42 Si4 112.0(2) . . ?
C423 Si42 C422 108.0(3) . . ?
C431 Si43 Si4 109.7(2) . . ?
C432 Si43 Si4 110.22(18) . . ?
C432 Si43 C431 110.3(3) . . ?
C432 Si43 C433 107.6(3) . . ?
C433 Si43 Si4 111.0(2) . . ?
C433 Si43 C431 108.0(3) . . ?
C511 Si51 Si5 111.8(2) . . ?
C511 Si51 C512 107.6(3) . . ?
C511 Si51 C513 108.9(3) . . ?
C512 Si51 Si5 111.1(2) . . ?
C512 Si51 C513 108.3(3) . . ?
C513 Si51 Si5 109.1(2) . . ?
C521 Si52 Si5 112.56(18) . . ?
C521 Si52 C522 107.8(3) . . ?
C521 Si52 C523 108.8(3) . . ?
C522 Si52 Si5 107.80(19) . . ?
C523 Si52 Si5 111.2(2) . . ?
C523 Si52 C522 108.4(3) . . ?
C531 Si53 Si5 111.7(2) . . ?
C531 Si53 C533 108.7(3) . . ?
C532 Si53 Si5 111.3(2) . . ?
C532 Si53 C531 107.8(3) . . ?
C532 Si53 C533 108.2(3) . . ?
C533 Si53 Si5 109.0(2) . . ?
P1 C101 H10A 108.5 . . ?
P1 C101 H10B 108.5 . . ?
H10A C101 H10B 107.5 . . ?
C102 C101 P1 115.1(4) . . ?
C102 C101 H10A 108.5 . . ?
C102 C101 H10B 108.5 . . ?
C101 C102 H10C 109.3 . . ?
C101 C102 H10D 109.3 . . ?
C101 C102 C103 111.6(6) . . ?
H10C C102 H10D 108.0 . . ?
C103 C102 H10C 109.3 . . ?
C103 C102 H10D 109.3 . . ?
C102 C103 H10E 108.1 . . ?
C102 C103 H10F 108.1 . . ?
H10E C103 H10F 107.3 . . ?
C104 C103 C102 116.7(7) . . ?
C104 C103 H10E 108.1 . . ?
C104 C103 H10F 108.1 . . ?
C103 C104 H10G 109.5 . . ?
C103 C104 H10H 109.5 . . ?
C103 C104 H10I 109.5 . . ?
H10G C104 H10H 109.5 . . ?
H10G C104 H10I 109.5 . . ?
H10H C104 H10I 109.5 . . ?
P1 C105 H10J 108.7 . . ?
P1 C105 H10K 108.7 . . ?
H10J C105 H10K 107.6 . . ?
C106 C105 P1 114.1(4) . . ?
C106 C105 H10J 108.7 . . ?
C106 C105 H10K 108.7 . . ?
C105 C106 H10L 109.2 . . ?
C105 C106 H10M 109.2 . . ?
C105 C106 C107 112.2(5) . . ?
H10L C106 H10M 107.9 . . ?
C107 C106 H10L 109.2 . . ?
C107 C106 H10M 109.2 . . ?
C106 C107 H10N 108.8 . . ?
C106 C107 H10O 108.8 . . ?
H10N C107 H10O 107.7 . . ?
C108 C107 C106 113.6(6) . . ?
C108 C107 H10N 108.8 . . ?
C108 C107 H10O 108.8 . . ?
C107 C108 H10P 109.5 . . ?
C107 C108 H10Q 109.5 . . ?
C107 C108 H10R 109.5 . . ?
H10P C108 H10Q 109.5 . . ?
H10P C108 H10R 109.5 . . ?
H10Q C108 H10R 109.5 . . ?
P1 C109 H10S 109.7 . . ?
P1 C109 H10T 109.7 . . ?
H10S C109 H10T 108.2 . . ?
C110 C109 P1 110.0(5) . . ?
C110 C109 H10S 109.7 . . ?
C110 C109 H10T 109.7 . . ?
C109 C110 H11A 109.0 . . ?
C109 C110 H11B 109.0 . . ?
C109 C110 C111 112.8(6) . . ?
H11A C110 H11B 107.8 . . ?
C111 C110 H11A 109.0 . . ?
C111 C110 H11B 109.0 . . ?
C110 C111 H11C 109.3 . . ?
C110 C111 H11D 109.3 . . ?
H11C C111 H11D 107.9 . . ?
C112 C111 C110 111.7(9) . . ?
C112 C111 H11C 109.3 . . ?
C112 C111 H11D 109.3 . . ?
C111 C112 H11E 109.5 . . ?
C111 C112 H11F 109.5 . . ?
C111 C112 H11G 109.5 . . ?
H11E C112 H11F 109.5 . . ?
H11E C112 H11G 109.5 . . ?
H11F C112 H11G 109.5 . . ?
P1 C113 H11H 107.6 . . ?
P1 C113 H11I 107.6 . . ?
H11H C113 H11I 107.1 . . ?
C114 C113 P1 118.8(14) . . ?
C114 C113 H11H 107.6 . . ?
C114 C113 H11I 107.6 . . ?
C113 C114 H11J 109.3 . . ?
C113 C114 H11K 109.3 . . ?
C113 C114 C115 111.6(17) . . ?
H11J C114 H11K 108.0 . . ?
C115 C114 H11J 109.3 . . ?
C115 C114 H11K 109.3 . . ?
C114 C115 H11L 109.4 . . ?
C114 C115 H11M 109.4 . . ?
H11L C115 H11M 108.0 . . ?
C116 C115 C114 111.2(18) . . ?
C116 C115 H11L 109.4 . . ?
C116 C115 H11M 109.4 . . ?
C115 C116 H11N 109.5 . . ?
C115 C116 H11O 109.5 . . ?
C115 C116 H11P 109.5 . . ?
H11N C116 H11O 109.5 . . ?
H11N C116 H11P 109.5 . . ?
H11O C116 H11P 109.5 . . ?
P2 C201 H20A 108.8 . . ?
P2 C201 H20B 108.8 . . ?
H20A C201 H20B 107.7 . . ?
C202 C201 P2 113.7(4) . . ?
C202 C201 H20A 108.8 . . ?
C202 C201 H20B 108.8 . . ?
C201 C202 H20C 108.9 . . ?
C201 C202 H20D 108.9 . . ?
C201 C202 C203 113.2(5) . . ?
H20C C202 H20D 107.7 . . ?
C203 C202 H20C 108.9 . . ?
C203 C202 H20D 108.9 . . ?
C202 C203 H20E 108.8 . . ?
C202 C203 H20F 108.8 . . ?
H20E C203 H20F 107.7 . . ?
C204 C203 C202 113.6(5) . . ?
C204 C203 H20E 108.8 . . ?
C204 C203 H20F 108.8 . . ?
C203 C204 H20G 109.5 . . ?
C203 C204 H20H 109.5 . . ?
C203 C204 H20I 109.5 . . ?
H20G C204 H20H 109.5 . . ?
H20G C204 H20I 109.5 . . ?
H20H C204 H20I 109.5 . . ?
P2 C205 H20J 108.7 . . ?
P2 C205 H20K 108.7 . . ?
H20J C205 H20K 107.6 . . ?
C206 C205 P2 114.1(5) . . ?
C206 C205 H20J 108.7 . . ?
C206 C205 H20K 108.7 . . ?
C205 C206 H20L 109.3 . . ?
C205 C206 H20M 109.3 . . ?
C205 C206 C207 111.8(6) . . ?
H20L C206 H20M 107.9 . . ?
C207 C206 H20L 109.3 . . ?
C207 C206 H20M 109.3 . . ?
C206 C207 H20N 108.9 . . ?
C206 C207 H20O 108.9 . . ?
H20N C207 H20O 107.7 . . ?
C208 C207 C206 113.4(6) . . ?
C208 C207 H20N 108.9 . . ?
C208 C207 H20O 108.9 . . ?
C207 C208 H20P 109.5 . . ?
C207 C208 H20Q 109.5 . . ?
C207 C208 H20R 109.5 . . ?
H20P C208 H20Q 109.5 . . ?
H20P C208 H20R 109.5 . . ?
H20Q C208 H20R 109.5 . . ?
P2 C209 H20S 108.6 . . ?
P2 C209 H20T 108.6 . . ?
H20S C209 H20T 107.6 . . ?
C210 C209 P2 114.6(8) . . ?
C210 C209 H20S 108.6 . . ?
C210 C209 H20T 108.6 . . ?
C209 C210 H21A 109.8 . . ?
C209 C210 H21B 109.8 . . ?
C209 C210 C211 109.6(10) . . ?
H21A C210 H21B 108.2 . . ?
C211 C210 H21A 109.8 . . ?
C211 C210 H21B 109.8 . . ?
C210 C211 H21C 109.5 . . ?
C210 C211 H21D 109.5 . . ?
H21C C211 H21D 108.1 . . ?
C212 C211 C210 110.7(12) . . ?
C212 C211 H21C 109.5 . . ?
C212 C211 H21D 109.5 . . ?
C211 C212 H21E 109.5 . . ?
C211 C212 H21F 109.5 . . ?
C211 C212 H21G 109.5 . . ?
H21E C212 H21F 109.5 . . ?
H21E C212 H21G 109.5 . . ?
H21F C212 H21G 109.5 . . ?
P2 C213 H21H 109.8 . . ?
P2 C213 H21I 109.8 . . ?
H21H C213 H21I 108.2 . . ?
C214 C213 P2 109.4(8) . . ?
C214 C213 H21H 109.8 . . ?
C214 C213 H21I 109.8 . . ?
C213 C214 H21J 108.6 . . ?
C213 C214 H21K 108.6 . . ?
H21J C214 H21K 107.6 . . ?
C215 C214 C213 114.6(11) . . ?
C215 C214 H21J 108.6 . . ?
C215 C214 H21K 108.6 . . ?
C214 C215 H21L 109.2 . . ?
C214 C215 H21M 109.2 . . ?
H21L C215 H21M 107.9 . . ?
C216 C215 C214 111.9(14) . . ?
C216 C215 H21L 109.2 . . ?
C216 C215 H21M 109.2 . . ?
C215 C216 H21N 109.5 . . ?
C215 C216 H21O 109.5 . . ?
C215 C216 H21P 109.5 . . ?
H21N C216 H21O 109.5 . . ?
H21N C216 H21P 109.5 . . ?
H21O C216 H21P 109.5 . . ?
Si41 C411 H41A 109.5 . . ?
Si41 C411 H41B 109.5 . . ?
Si41 C411 H41C 109.5 . . ?
H41A C411 H41B 109.5 . . ?
H41A C411 H41C 109.5 . . ?
H41B C411 H41C 109.5 . . ?
Si41 C412 H41D 109.5 . . ?
Si41 C412 H41E 109.5 . . ?
Si41 C412 H41F 109.5 . . ?
H41D C412 H41E 109.5 . . ?
H41D C412 H41F 109.5 . . ?
H41E C412 H41F 109.5 . . ?
Si41 C413 H41G 109.5 . . ?
Si41 C413 H41H 109.5 . . ?
Si41 C413 H41I 109.5 . . ?
H41G C413 H41H 109.5 . . ?
H41G C413 H41I 109.5 . . ?
H41H C413 H41I 109.5 . . ?
Si42 C421 H42A 109.5 . . ?
Si42 C421 H42B 109.5 . . ?
Si42 C421 H42C 109.5 . . ?
H42A C421 H42B 109.5 . . ?
H42A C421 H42C 109.5 . . ?
H42B C421 H42C 109.5 . . ?
Si42 C422 H42D 109.5 . . ?
Si42 C422 H42E 109.5 . . ?
Si42 C422 H42F 109.5 . . ?
H42D C422 H42E 109.5 . . ?
H42D C422 H42F 109.5 . . ?
H42E C422 H42F 109.5 . . ?
Si42 C423 H42G 109.5 . . ?
Si42 C423 H42H 109.5 . . ?
Si42 C423 H42I 109.5 . . ?
H42G C423 H42H 109.5 . . ?
H42G C423 H42I 109.5 . . ?
H42H C423 H42I 109.5 . . ?
Si43 C431 H43A 109.5 . . ?
Si43 C431 H43B 109.5 . . ?
Si43 C431 H43C 109.5 . . ?
H43A C431 H43B 109.5 . . ?
H43A C431 H43C 109.5 . . ?
H43B C431 H43C 109.5 . . ?
Si43 C432 H43D 109.5 . . ?
Si43 C432 H43E 109.5 . . ?
Si43 C432 H43F 109.5 . . ?
H43D C432 H43E 109.5 . . ?
H43D C432 H43F 109.5 . . ?
H43E C432 H43F 109.5 . . ?
Si43 C433 H43G 109.5 . . ?
Si43 C433 H43H 109.5 . . ?
Si43 C433 H43I 109.5 . . ?
H43G C433 H43H 109.5 . . ?
H43G C433 H43I 109.5 . . ?
H43H C433 H43I 109.5 . . ?
Si51 C511 H51A 109.5 . . ?
Si51 C511 H51B 109.5 . . ?
Si51 C511 H51C 109.5 . . ?
H51A C511 H51B 109.5 . . ?
H51A C511 H51C 109.5 . . ?
H51B C511 H51C 109.5 . . ?
Si51 C512 H51D 109.5 . . ?
Si51 C512 H51E 109.5 . . ?
Si51 C512 H51F 109.5 . . ?
H51D C512 H51E 109.5 . . ?
H51D C512 H51F 109.5 . . ?
H51E C512 H51F 109.5 . . ?
Si51 C513 H51G 109.5 . . ?
Si51 C513 H51H 109.5 . . ?
Si51 C513 H51I 109.5 . . ?
H51G C513 H51H 109.5 . . ?
H51G C513 H51I 109.5 . . ?
H51H C513 H51I 109.5 . . ?
Si52 C521 H52A 109.5 . . ?
Si52 C521 H52B 109.5 . . ?
Si52 C521 H52C 109.5 . . ?
H52A C521 H52B 109.5 . . ?
H52A C521 H52C 109.5 . . ?
H52B C521 H52C 109.5 . . ?
Si52 C522 H52D 109.5 . . ?
Si52 C522 H52E 109.5 . . ?
Si52 C522 H52F 109.5 . . ?
H52D C522 H52E 109.5 . . ?
H52D C522 H52F 109.5 . . ?
H52E C522 H52F 109.5 . . ?
Si52 C523 H52G 109.5 . . ?
Si52 C523 H52H 109.5 . . ?
Si52 C523 H52I 109.5 . . ?
H52G C523 H52H 109.5 . . ?
H52G C523 H52I 109.5 . . ?
H52H C523 H52I 109.5 . . ?
Si53 C531 H53A 109.5 . . ?
Si53 C531 H53B 109.5 . . ?
Si53 C531 H53C 109.5 . . ?
H53A C531 H53B 109.5 . . ?
H53A C531 H53C 109.5 . . ?
H53B C531 H53C 109.5 . . ?
Si53 C532 H53D 109.5 . . ?
Si53 C532 H53E 109.5 . . ?
Si53 C532 H53F 109.5 . . ?
H53D C532 H53E 109.5 . . ?
H53D C532 H53F 109.5 . . ?
H53E C532 H53F 109.5 . . ?
Si53 C533 H53G 109.5 . . ?
Si53 C533 H53H 109.5 . . ?
Si53 C533 H53I 109.5 . . ?
H53G C533 H53H 109.5 . . ?
H53G C533 H53I 109.5 . . ?
H53H C533 H53I 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Au1 P1 C101 C102 -63.1(5) . . . . ?
Au1 P1 C105 C106 -55.9(5) . . . . ?
Au1 P1 C109 C110 -54.7(6) . . . . ?
Au1 P1 C113 C114 -165.1(15) . . . . ?
Au2 P2 C201 C202 -54.0(5) . . . . ?
Au2 P2 C205 C206 -54.3(6) . . . . ?
Au2 P2 C213 C214 -67.1(11) . . . . ?
P1 C101 C102 C103 -179.4(5) . . . . ?
P1 C105 C106 C107 -176.5(4) . . . . ?
P1 C109 C110 C111 -178.0(6) . . . . ?
P1 C113 C114 C115 -178.2(13) . . . . ?
P2 C201 C202 C203 175.9(5) . . . . ?
P2 C205 C206 C207 169.5(5) . . . . ?
P2 C209 C210 C211 -175.2(10) . . . . ?
P2 C213 C214 C215 174.0(10) . . . . ?
C101 P1 C105 C106 178.2(4) . . . . ?
C101 P1 C109 C110 72.6(6) . . . . ?
C101 P1 C113 C114 -48.8(17) . . . . ?
C101 C102 C103 C104 166.7(8) . . . . ?
C105 P1 C101 C102 64.5(5) . . . . ?
C105 P1 C109 C110 179.5(6) . . . . ?
C105 P1 C113 C114 61.6(18) . . . . ?
C105 C106 C107 C108 177.4(5) . . . . ?
C109 P1 C101 C102 167.6(5) . . . . ?
C109 P1 C105 C106 70.3(5) . . . . ?
C109 C110 C111 C112 -58.5(12) . . . . ?
C113 P1 C101 C102 -171.0(8) . . . . ?
C113 P1 C105 C106 71.7(8) . . . . ?
C113 C114 C115 C116 177.4(17) . . . . ?
C201 P2 C205 C206 -177.1(5) . . . . ?
C201 P2 C213 C214 65.6(10) . . . . ?
C201 C202 C203 C204 176.5(6) . . . . ?
C205 P2 C201 C202 67.0(5) . . . . ?
C205 P2 C213 C214 171.8(9) . . . . ?
C205 C206 C207 C208 175.2(6) . . . . ?
C209 P2 C201 C202 -172.9(6) . . . . ?
C209 P2 C205 C206 71.5(7) . . . . ?
C209 C210 C211 C212 -176.9(12) . . . . ?
C213 P2 C201 C202 166.9(6) . . . . ?
C213 P2 C205 C206 77.2(7) . . . . ?
C213 C214 C215 C216 65.3(17) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.486
_oxdiff_exptl_absorpt_empirical_full_min 0.758
_oxdiff_exptl_absorpt_spherical_max 0.575
_oxdiff_exptl_absorpt_spherical_min 0.559
_exptl_crystal_recrystallization_method 
'Re-crystallisation from solvent: thf, toluene, pentane'
_chemical_properties_physical    Air-sensitive,Moisture-sensitive
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_38
_database_code_depnum_ccdc_archive 'CCDC 2170158'
loop_
_audit_author_name
_audit_author_address
'Andreas Schnepf'
;University Tuebingen
Germany
;
_audit_update_record             
;
2022-05-03 deposited with the CCDC.	2022-08-05 downloaded from the CCDC.
;
_audit_creation_date             2021-04-28
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2014/7
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C18 H32 O2 P2'
_chemical_formula_sum            'C18 H32 O2 P2'
_chemical_formula_weight         342.37
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   5.6229(12)
_cell_length_b                   7.5296(16)
_cell_length_c                   11.956(3)
_cell_angle_alpha                85.464(3)
_cell_angle_beta                 80.159(3)
_cell_angle_gamma                79.593(3)
_cell_volume                     489.92(18)
_cell_formula_units_Z            1
_cell_measurement_reflns_used    3371
_cell_measurement_temperature    100
_cell_measurement_theta_max      28.319
_cell_measurement_theta_min      2.754
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    0.227
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_correction_T_min  0.6999
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
'SADABS-2016/2 (Bruker,2016/2) was used for absorption correction. wR2(int) was 0.0868 before and 0.0442 after correction. The Ratio of minimum to maximum transmission is 0.9386. The λ/2 correction factor is Not present.'
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.160
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             186
_exptl_crystal_size_max          0.389
_exptl_crystal_size_mid          0.183
_exptl_crystal_size_min          0.106
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0320
_diffrn_reflns_av_unetI/netI     0.0326
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       7
_diffrn_reflns_limit_h_min       -7
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            7786
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.366
_diffrn_reflns_theta_min         2.754
_diffrn_ambient_temperature      100
_diffrn_detector                 'Bruker APEX2 area detector'
_diffrn_detector_area_resol_mean 7.9
_diffrn_detector_type            'CCD area detector'
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device       'three-circle diffractometer'
_diffrn_measurement_device_type  'Bruker SMART APEX2 area detector'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_monochromator  'mirror optics'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'microfocus sealed X-ray tube'
_diffrn_source_type              'Incoatec I\ms'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                2190
_reflns_number_total             2457
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.40B (?, 2016)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.40B (?, 2016)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         0.405
_refine_diff_density_min         -0.217
_refine_diff_density_rms         0.049
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.036
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     104
_refine_ls_number_reflns         2457
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0372
_refine_ls_R_factor_gt           0.0326
_refine_ls_restrained_S_all      1.036
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0420P)²+0.2527P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0818
_refine_ls_wR_factor_ref         0.0858
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Ternary CH refined with riding coordinates:
 C111(H111), C121(H121)
2.b Aromatic/amide H refined with riding coordinates:
 C2(H2), C3(H3)
2.c Idealised Me refined as rotating group:
 C112(H11A,H11B,H11C), C113(H11D,H11E,H11F), C122(H12A,H12B,H12C), C123(H12D,
 H12E,H12F)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
P1 P 0.73969(6) 0.36585(4) 0.27921(3) 0.01484(11) Uani 1 1 d . . . . .
O1 O 0.55118(17) 0.21325(13) 0.30017(8) 0.0168(2) Uani 1 1 d . . . . .
C1 C 0.5300(2) 0.10850(17) 0.40108(10) 0.0142(2) Uani 1 1 d . . . . .
C2 C 0.2991(2) 0.11594(17) 0.46628(11) 0.0161(3) Uani 1 1 d . . . . .
H2 H 0.1624 0.1950 0.4433 0.019 Uiso 1 1 calc R . . . .
C3 C 0.2694(2) 0.00679(17) 0.56564(11) 0.0158(3) Uani 1 1 d . . . . .
H3 H 0.1121 0.0112 0.6106 0.019 Uiso 1 1 calc R . . . .
C111 C 0.9082(2) 0.30052(18) 0.13717(11) 0.0173(3) Uani 1 1 d . . . . .
H111 H 1.0064 0.3972 0.1071 0.021 Uiso 1 1 calc R . . . .
C112 C 0.7478(3) 0.2823(2) 0.04915(12) 0.0252(3) Uani 1 1 d . . . . .
H11A H 0.6403 0.1944 0.0782 0.038 Uiso 1 1 calc GR . . . .
H11B H 0.8520 0.2409 -0.0215 0.038 Uiso 1 1 calc GR . . . .
H11C H 0.6480 0.3999 0.0342 0.038 Uiso 1 1 calc GR . . . .
C113 C 1.0897(3) 0.12512(19) 0.15098(12) 0.0218(3) Uani 1 1 d . . . . .
H11D H 1.1914 0.1395 0.2075 0.033 Uiso 1 1 calc GR . . . .
H11E H 1.1945 0.0981 0.0779 0.033 Uiso 1 1 calc GR . . . .
H11F H 0.9993 0.0256 0.1764 0.033 Uiso 1 1 calc GR . . . .
C121 C 0.5142(2) 0.56410(18) 0.24399(11) 0.0192(3) Uani 1 1 d . . . . .
H121 H 0.4161 0.5286 0.1897 0.023 Uiso 1 1 calc R . . . .
C122 C 0.3416(3) 0.6244(2) 0.35327(13) 0.0276(3) Uani 1 1 d . . . . .
H12A H 0.2620 0.5236 0.3884 0.041 Uiso 1 1 calc GR . . . .
H12B H 0.2167 0.7261 0.3349 0.041 Uiso 1 1 calc GR . . . .
H12C H 0.4358 0.6619 0.4063 0.041 Uiso 1 1 calc GR . . . .
C123 C 0.6460(3) 0.7173(2) 0.18790(14) 0.0286(3) Uani 1 1 d . . . . .
H12D H 0.7626 0.7398 0.2352 0.043 Uiso 1 1 calc GR . . . .
H12E H 0.5256 0.8273 0.1800 0.043 Uiso 1 1 calc GR . . . .
H12F H 0.7340 0.6829 0.1126 0.043 Uiso 1 1 calc GR . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
P1 O1 1.6764(10) . ?
P1 C111 1.8539(14) . ?
P1 C121 1.8472(14) . ?
O1 C1 1.3879(14) . ?
C1 C2 1.3895(18) . ?
C1 C3 1.3888(18) 2_656 ?
C2 H2 0.9500 . ?
C2 C3 1.3935(17) . ?
C3 C1 1.3888(18) 2_656 ?
C3 H3 0.9500 . ?
C111 H111 1.0000 . ?
C111 C112 1.527(2) . ?
C111 C113 1.5329(19) . ?
C112 H11A 0.9800 . ?
C112 H11B 0.9800 . ?
C112 H11C 0.9800 . ?
C113 H11D 0.9800 . ?
C113 H11E 0.9800 . ?
C113 H11F 0.9800 . ?
C121 H121 1.0000 . ?
C121 C122 1.5351(19) . ?
C121 C123 1.5316(19) . ?
C122 H12A 0.9800 . ?
C122 H12B 0.9800 . ?
C122 H12C 0.9800 . ?
C123 H12D 0.9800 . ?
C123 H12E 0.9800 . ?
C123 H12F 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 P1 C111 98.78(6) . . ?
O1 P1 C121 97.60(6) . . ?
C121 P1 C111 102.42(6) . . ?
C1 O1 P1 119.95(8) . . ?
O1 C1 C2 118.08(11) . . ?
O1 C1 C3 121.43(11) . 2_656 ?
C3 C1 C2 120.43(11) 2_656 . ?
C1 C2 H2 120.2 . . ?
C1 C2 C3 119.61(12) . . ?
C3 C2 H2 120.2 . . ?
C1 C3 C2 119.96(11) 2_656 . ?
C1 C3 H3 120.0 2_656 . ?
C2 C3 H3 120.0 . . ?
P1 C111 H111 107.2 . . ?
C112 C111 P1 115.25(9) . . ?
C112 C111 H111 107.2 . . ?
C112 C111 C113 110.62(12) . . ?
C113 C111 P1 108.91(9) . . ?
C113 C111 H111 107.2 . . ?
C111 C112 H11A 109.5 . . ?
C111 C112 H11B 109.5 . . ?
C111 C112 H11C 109.5 . . ?
H11A C112 H11B 109.5 . . ?
H11A C112 H11C 109.5 . . ?
H11B C112 H11C 109.5 . . ?
C111 C113 H11D 109.5 . . ?
C111 C113 H11E 109.5 . . ?
C111 C113 H11F 109.5 . . ?
H11D C113 H11E 109.5 . . ?
H11D C113 H11F 109.5 . . ?
H11E C113 H11F 109.5 . . ?
P1 C121 H121 108.9 . . ?
C122 C121 P1 108.89(9) . . ?
C122 C121 H121 108.9 . . ?
C123 C121 P1 110.17(10) . . ?
C123 C121 H121 108.9 . . ?
C123 C121 C122 110.98(12) . . ?
C121 C122 H12A 109.5 . . ?
C121 C122 H12B 109.5 . . ?
C121 C122 H12C 109.5 . . ?
H12A C122 H12B 109.5 . . ?
H12A C122 H12C 109.5 . . ?
H12B C122 H12C 109.5 . . ?
C121 C123 H12D 109.5 . . ?
C121 C123 H12E 109.5 . . ?
C121 C123 H12F 109.5 . . ?
H12D C123 H12E 109.5 . . ?
H12D C123 H12F 109.5 . . ?
H12E C123 H12F 109.5 . . ?

_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_42_sq
_database_code_depnum_ccdc_archive 'CCDC 2170157'
loop_
_audit_author_name
_audit_author_address
'Andreas Schnepf'
;University Tuebingen
Germany
;
_audit_update_record             
;
2022-05-03 deposited with the CCDC.	2022-08-05 downloaded from the CCDC.
;
_audit_creation_date             2021-09-06
_audit_creation_method           
;
Olex2 1.5
(compiled 2021.08.20 svn.r13c46975 for OlexSys, GUI svn.r6394)
;
_shelx_SHELXL_version_number     2014/7
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C72 H172 Au4 Ge18 O4 P4 Si16'
_chemical_formula_sum            'C72 H172 Au4 Ge18 O4 P4 Si16'
_chemical_formula_weight         3769.89
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'C 1 2/c 1'
_space_group_name_Hall           '-C 2yc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   15.7399(19)
_cell_length_b                   24.623(3)
_cell_length_c                   35.814(4)
_cell_angle_alpha                90
_cell_angle_beta                 96.305(2)
_cell_angle_gamma                90
_cell_volume                     13796(3)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9787
_cell_measurement_temperature    100
_cell_measurement_theta_max      30.165
_cell_measurement_theta_min      2.384
_shelx_estimated_absorpt_T_max   0.389
_shelx_estimated_absorpt_T_min   0.268
_exptl_absorpt_coefficient_mu    8.307
_exptl_absorpt_correction_T_max  0.7461
_exptl_absorpt_correction_T_min  0.4931
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1066 before and 0.0712 after correction.
The Ratio of minimum to maximum transmission is 0.6609.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            black
_exptl_crystal_colour_primary    black
_exptl_crystal_density_diffrn    1.815
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       rhombohedral
_exptl_crystal_F_000             7248
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
1.00 -1.00 -1.00 0.0590
-1.00 1.00 1.00 0.0550
0.00 0.00 -1.00 0.0640
0.00 0.00 1.00 0.0750
0.00 -1.00 0.00 0.0700
0.00 1.00 0.00 0.0570
1.00 0.00 1.00 0.1150
-1.00 -1.00 -1.00 0.1120
1.00 1.00 1.00 0.1130
-1.00 -1.00 2.00 0.1050
1.00 1.00 -2.00 0.0820

_exptl_crystal_size_max          0.215
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.14
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0685
_diffrn_reflns_av_unetI/netI     0.0588
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_h_min       -22
_diffrn_reflns_limit_k_max       35
_diffrn_reflns_limit_k_min       -35
_diffrn_reflns_limit_l_max       38
_diffrn_reflns_limit_l_min       -51
_diffrn_reflns_number            97050
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         30.594
_diffrn_reflns_theta_min         2.004
_diffrn_ambient_temperature      100
_diffrn_detector                 'Bruker APEX2 area detector'
_diffrn_detector_area_resol_mean 7.9
_diffrn_detector_type            'CCD area detector'
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device       'three-circle diffractometer'
_diffrn_measurement_device_type  'Bruker SMART APEX2 area detector'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_monochromator  'mirror optics'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'microfocus sealed X-ray tube'
_diffrn_source_current           0.6
_diffrn_source_power             0.03
_diffrn_source_type              'Incoatec I\ms'
_diffrn_source_voltage           50.0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                16272
_reflns_number_total             21106
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.40B (?, 2016)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.40B (?, 2016)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2014/7 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_refine_diff_density_max         1.230
_refine_diff_density_min         -1.077
_refine_diff_density_rms         0.164
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.013
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     598
_refine_ls_number_reflns         21106
_refine_ls_number_restraints     12
_refine_ls_R_factor_all          0.0555
_refine_ls_R_factor_gt           0.0350
_refine_ls_restrained_S_all      1.013
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0179P)²+40.5504P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0707
_refine_ls_wR_factor_ref         0.0774
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Uiso/Uaniso restraints and constraints
C531 \\sim C541: within 2A with sigma of 0.01 and sigma for terminal atoms of
0.02 within 2A
C533 \\sim C543: within 2A with sigma of 0.01 and sigma for terminal atoms of
0.02 within 2A
3. Others
 Sof(Si54)=Sof(C541)=Sof(H54A)=Sof(H54B)=Sof(H54C)=Sof(C542)=Sof(H54D)=
 Sof(H54E)=Sof(H54F)=Sof(C543)=Sof(H54G)=Sof(H54H)=Sof(H54I)=1-FVAR(1)
 Sof(Si53)=Sof(C531)=Sof(H53A)=Sof(H53B)=Sof(H53C)=Sof(C532)=Sof(H53D)=
 Sof(H53E)=Sof(H53F)=Sof(C533)=Sof(H53G)=Sof(H53H)=Sof(H53I)=FVAR(1)
4.a Ternary CH refined with riding coordinates:
 C101(H101), C104(H104), C201(H201), C204(H204)
4.b Aromatic/amide H refined with riding coordinates:
 C109(H109), C110(H110), C209(H209), C210(H210)
4.c Idealised Me refined as rotating group:
 C102(H10A,H10B,H10C), C103(H10D,H10E,H10F), C105(H10G,H10H,H10I), C106(H10J,
 H10K,H10L), C202(H20A,H20B,H20C), C203(H20D,H20E,H20F), C205(H20G,H20H,H20I),
 C206(H20J,H20K,H20L), C411(H41A,H41B,H41C), C412(H41D,H41E,H41F), C413(H41G,
 H41H,H41I), C421(H42A,H42B,H42C), C422(H42D,H42E,H42F), C423(H42G,H42H,H42I),
 C431(H43A,H43B,H43C), C432(H43D,H43E,H43F), C433(H43G,H43H,H43I), C511(H51A,
 H51B,H51C), C512(H51D,H51E,H51F), C513(H51G,H51H,H51I), C521(H52A,H52B,H52C),
 C522(H52D,H52E,H52F), C523(H52G,H52H,H52I), C531(H53A,H53B,H53C), C532(H53D,
 H53E,H53F), C533(H53G,H53H,H53I), C541(H54A,H54B,H54C), C542(H54D,H54E,H54F),
 C543(H54G,H54H,H54I)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.58461(2) 0.26116(2) 0.52785(2) 0.01960(4) Uani 1 1 d . . . . .
Au2 Au 0.49062(2) 0.22065(2) 0.35729(2) 0.02042(4) Uani 1 1 d . . . . .
Ge1 Ge 0.74002(2) 0.32181(2) 0.54112(2) 0.01928(9) Uani 1 1 d . . . . .
Ge2 Ge 0.65285(2) 0.27775(2) 0.59932(2) 0.02394(10) Uani 1 1 d . . . . .
Ge3 Ge 0.72968(2) 0.21109(2) 0.55122(2) 0.01869(9) Uani 1 1 d . . . . .
Ge4 Ge 0.77349(2) 0.34886(2) 0.61054(2) 0.02152(9) Uani 1 1 d . . . . .
Ge5 Ge 0.77230(2) 0.21097(2) 0.62329(2) 0.02174(9) Uani 1 1 d . . . . .
Ge6 Ge 0.86751(2) 0.25769(2) 0.53615(2) 0.01762(8) Uani 1 1 d . . . . .
Ge7 Ge 0.91504(2) 0.32845(2) 0.58526(2) 0.01882(9) Uani 1 1 d . . . . .
Ge8 Ge 0.85391(2) 0.28634(2) 0.65654(2) 0.01975(9) Uani 1 1 d . . . . .
Ge9 Ge 0.91632(2) 0.21296(2) 0.59857(2) 0.01827(8) Uani 1 1 d . . . . .
P1 P 0.44267(6) 0.28945(5) 0.52491(3) 0.0261(2) Uani 1 1 d . . . . .
P2 P 0.34756(6) 0.21205(4) 0.33693(3) 0.0201(2) Uani 1 1 d . . . . .
Si4 Si 0.76618(7) 0.44568(5) 0.61662(3) 0.0274(3) Uani 1 1 d . . . . .
Si5 Si 0.75252(8) 0.12340(6) 0.64977(3) 0.0331(3) Uani 1 1 d . . . . .
Si41 Si 0.62829(9) 0.47581(6) 0.59581(4) 0.0434(4) Uani 1 1 d . . . . .
Si42 Si 0.86420(10) 0.48706(6) 0.58041(4) 0.0413(3) Uani 1 1 d . . . . .
Si43 Si 0.80348(8) 0.46589(5) 0.68041(3) 0.0295(3) Uani 1 1 d . . . . .
Si51 Si 0.62442(10) 0.12366(9) 0.67688(4) 0.0607(5) Uani 1 1 d . . . . .
Si52 Si 0.86609(9) 0.10781(6) 0.69703(4) 0.0332(3) Uani 1 1 d . . . . .
Si53 Si 0.7711(4) 0.0523(2) 0.60332(11) 0.0247(10) Uani 0.499(16) 1 d . . P A 1
Si54 Si 0.7360(6) 0.0654(2) 0.60034(12) 0.0346(15) Uani 0.501(16) 1 d . . P A 2
O107 O 0.37558(17) 0.26976(13) 0.48907(9) 0.0318(7) Uani 1 1 d . . . . .
O207 O 0.29258(16) 0.19066(14) 0.37026(8) 0.0286(7) Uani 1 1 d . . . . .
C101 C 0.4345(2) 0.3627(2) 0.51680(13) 0.0321(10) Uani 1 1 d . . . . .
H101 H 0.4694 0.3809 0.5382 0.039 Uiso 1 1 calc R U . . .
C102 C 0.4745(3) 0.3770(2) 0.48100(13) 0.0349(11) Uani 1 1 d . . . . .
H10A H 0.5335 0.3637 0.4831 0.052 Uiso 1 1 calc R U . . .
H10B H 0.4740 0.4165 0.4776 0.052 Uiso 1 1 calc R U . . .
H10C H 0.4415 0.3599 0.4593 0.052 Uiso 1 1 calc R U . . .
C103 C 0.3427(3) 0.3856(2) 0.51523(15) 0.0492(14) Uani 1 1 d . . . . .
H10D H 0.3059 0.3673 0.4952 0.074 Uiso 1 1 calc R U . . .
H10E H 0.3436 0.4247 0.5101 0.074 Uiso 1 1 calc R U . . .
H10F H 0.3205 0.3794 0.5394 0.074 Uiso 1 1 calc R U . . .
C104 C 0.3787(2) 0.2764(2) 0.56378(12) 0.0343(11) Uani 1 1 d . . . . .
H104 H 0.3195 0.2897 0.5558 0.041 Uiso 1 1 calc R U . . .
C105 C 0.4122(3) 0.3077(3) 0.59889(13) 0.0445(14) Uani 1 1 d . . . . .
H10G H 0.4704 0.2956 0.6075 0.067 Uiso 1 1 calc R U . . .
H10H H 0.3751 0.3010 0.6187 0.067 Uiso 1 1 calc R U . . .
H10I H 0.4126 0.3466 0.5932 0.067 Uiso 1 1 calc R U . . .
C106 C 0.3726(3) 0.2159(2) 0.57116(14) 0.0445(14) Uani 1 1 d . . . . .
H10J H 0.3373 0.1987 0.5502 0.067 Uiso 1 1 calc R U . . .
H10K H 0.3467 0.2101 0.5945 0.067 Uiso 1 1 calc R U . . .
H10L H 0.4300 0.2000 0.5735 0.067 Uiso 1 1 calc R U . . .
C108 C 0.3776(2) 0.2237(2) 0.46721(12) 0.0273(10) Uani 1 1 d . . . . .
C109 C 0.4072(2) 0.1736(2) 0.48035(12) 0.0299(10) Uani 1 1 d . . . . .
H109 H 0.4337 0.1697 0.5053 0.036 Uiso 1 1 calc R U . . .
C110 C 0.3976(3) 0.1295(2) 0.45680(13) 0.0331(11) Uani 1 1 d . . . . .
H110 H 0.4175 0.0949 0.4658 0.040 Uiso 1 1 calc R U . . .
C201 C 0.2935(3) 0.2743(2) 0.32068(14) 0.0332(11) Uani 1 1 d . . . . .
H201 H 0.3169 0.2848 0.2969 0.040 Uiso 1 1 calc R U . . .
C202 C 0.3139(4) 0.3211(2) 0.34833(16) 0.0519(15) Uani 1 1 d . . . . .
H20A H 0.2772 0.3186 0.3686 0.078 Uiso 1 1 calc R U . . .
H20B H 0.3037 0.3558 0.3352 0.078 Uiso 1 1 calc R U . . .
H20C H 0.3740 0.3189 0.3589 0.078 Uiso 1 1 calc R U . . .
C203 C 0.1967(3) 0.2684(3) 0.31122(15) 0.0531(16) Uani 1 1 d . . . . .
H20D H 0.1847 0.2430 0.2902 0.080 Uiso 1 1 calc R U . . .
H20E H 0.1717 0.3039 0.3042 0.080 Uiso 1 1 calc R U . . .
H20F H 0.1716 0.2546 0.3332 0.080 Uiso 1 1 calc R U . . .
C204 C 0.3178(3) 0.16235(18) 0.30001(12) 0.0287(9) Uani 1 1 d . . . . .
H204 H 0.2541 0.1596 0.2962 0.034 Uiso 1 1 calc R U . . .
C205 C 0.3494(4) 0.1810(2) 0.26345(14) 0.0519(15) Uani 1 1 d . . . . .
H20G H 0.3381 0.1526 0.2444 0.078 Uiso 1 1 calc R U . . .
H20H H 0.4110 0.1881 0.2676 0.078 Uiso 1 1 calc R U . . .
H20I H 0.3194 0.2143 0.2548 0.078 Uiso 1 1 calc R U . . .
C206 C 0.3542(4) 0.1072(2) 0.31194(14) 0.0436(13) Uani 1 1 d . . . . .
H20J H 0.4164 0.1099 0.3175 0.065 Uiso 1 1 calc R U . . .
H20K H 0.3403 0.0810 0.2916 0.065 Uiso 1 1 calc R U . . .
H20L H 0.3293 0.0950 0.3344 0.065 Uiso 1 1 calc R U . . .
C208 C 0.3323(2) 0.18479(19) 0.40726(11) 0.0256(9) Uani 1 1 d . . . . .
C209 C 0.3595(2) 0.1345(2) 0.42015(12) 0.0310(10) Uani 1 1 d . . . . .
H209 H 0.3524 0.1036 0.4042 0.037 Uiso 1 1 calc R U . . .
C210 C 0.3413(2) 0.2295(2) 0.43038(12) 0.0275(10) Uani 1 1 d . . . . .
H210 H 0.3228 0.2642 0.4211 0.033 Uiso 1 1 calc R U . . .
C411 C 0.6179(4) 0.5496(2) 0.60853(18) 0.0591(18) Uani 1 1 d . . . . .
H41A H 0.6244 0.5534 0.6359 0.089 Uiso 1 1 calc R U . . .
H41B H 0.5615 0.5630 0.5983 0.089 Uiso 1 1 calc R U . . .
H41C H 0.6625 0.5707 0.5980 0.089 Uiso 1 1 calc R U . . .
C412 C 0.6086(4) 0.4689(2) 0.54357(16) 0.0539(16) Uani 1 1 d . . . . .
H41D H 0.6474 0.4930 0.5318 0.081 Uiso 1 1 calc R U . . .
H41E H 0.5493 0.4788 0.5351 0.081 Uiso 1 1 calc R U . . .
H41F H 0.6188 0.4312 0.5364 0.081 Uiso 1 1 calc R U . . .
C413 C 0.5473(3) 0.4354(3) 0.61785(19) 0.0651(19) Uani 1 1 d . . . . .
H41G H 0.5571 0.3966 0.6138 0.098 Uiso 1 1 calc R U . . .
H41H H 0.4900 0.4452 0.6065 0.098 Uiso 1 1 calc R U . . .
H41I H 0.5523 0.4429 0.6449 0.098 Uiso 1 1 calc R U . . .
C421 C 0.8440(5) 0.5623(2) 0.57621(18) 0.0677(19) Uani 1 1 d . . . . .
H42A H 0.7870 0.5687 0.5631 0.102 Uiso 1 1 calc R U . . .
H42B H 0.8871 0.5790 0.5620 0.102 Uiso 1 1 calc R U . . .
H42C H 0.8477 0.5785 0.6013 0.102 Uiso 1 1 calc R U . . .
C422 C 0.8584(4) 0.4601(2) 0.53148(14) 0.0535(15) Uani 1 1 d . . . . .
H42D H 0.8743 0.4216 0.5322 0.080 Uiso 1 1 calc R U . . .
H42E H 0.8979 0.4804 0.5174 0.080 Uiso 1 1 calc R U . . .
H42F H 0.8000 0.4641 0.5192 0.080 Uiso 1 1 calc R U . . .
C423 C 0.9754(3) 0.4769(2) 0.60329(16) 0.0500(14) Uani 1 1 d . . . . .
H42G H 0.9840 0.4986 0.6263 0.075 Uiso 1 1 calc R U . . .
H42H H 1.0163 0.4885 0.5861 0.075 Uiso 1 1 calc R U . . .
H42I H 0.9844 0.4385 0.6095 0.075 Uiso 1 1 calc R U . . .
C431 C 0.8120(4) 0.5415(2) 0.68780(16) 0.0522(15) Uani 1 1 d . . . . .
H43A H 0.8524 0.5567 0.6716 0.078 Uiso 1 1 calc R U . . .
H43B H 0.8322 0.5491 0.7142 0.078 Uiso 1 1 calc R U . . .
H43C H 0.7557 0.5582 0.6815 0.078 Uiso 1 1 calc R U . . .
C432 C 0.7197(3) 0.4375(3) 0.70789(15) 0.0496(14) Uani 1 1 d . . . . .
H43D H 0.6655 0.4565 0.7010 0.074 Uiso 1 1 calc R U . . .
H43E H 0.7372 0.4424 0.7348 0.074 Uiso 1 1 calc R U . . .
H43F H 0.7123 0.3987 0.7023 0.074 Uiso 1 1 calc R U . . .
C433 C 0.9096(3) 0.43654(19) 0.69831(13) 0.0325(10) Uani 1 1 d . . . . .
H43G H 0.9099 0.3976 0.6928 0.049 Uiso 1 1 calc R U . . .
H43H H 0.9201 0.4421 0.7255 0.049 Uiso 1 1 calc R U . . .
H43I H 0.9546 0.4546 0.6860 0.049 Uiso 1 1 calc R U . . .
C511 C 0.6337(4) 0.1704(4) 0.7176(2) 0.102(3) Uani 1 1 d . . . . .
H51A H 0.6840 0.1607 0.7349 0.153 Uiso 1 1 calc R U . . .
H51B H 0.5823 0.1676 0.7307 0.153 Uiso 1 1 calc R U . . .
H51C H 0.6398 0.2078 0.7088 0.153 Uiso 1 1 calc R U . . .
C512 C 0.5994(4) 0.0535(4) 0.6940(2) 0.094(3) Uani 1 1 d . . . . .
H51D H 0.5892 0.0288 0.6725 0.141 Uiso 1 1 calc R U . . .
H51E H 0.5482 0.0551 0.7073 0.141 Uiso 1 1 calc R U . . .
H51F H 0.6477 0.0402 0.7111 0.141 Uiso 1 1 calc R U . . .
C513 C 0.5331(4) 0.1453(3) 0.6422(2) 0.076(2) Uani 1 1 d . . . . .
H51G H 0.5415 0.1830 0.6348 0.115 Uiso 1 1 calc R U . . .
H51H H 0.4796 0.1423 0.6537 0.115 Uiso 1 1 calc R U . . .
H51I H 0.5303 0.1218 0.6200 0.115 Uiso 1 1 calc R U . . .
C521 C 0.8436(4) 0.0474(3) 0.72587(18) 0.0653(18) Uani 1 1 d . . . . .
H52A H 0.7947 0.0551 0.7398 0.098 Uiso 1 1 calc R U . . .
H52B H 0.8939 0.0393 0.7436 0.098 Uiso 1 1 calc R U . . .
H52C H 0.8305 0.0161 0.7093 0.098 Uiso 1 1 calc R U . . .
C522 C 0.9677(4) 0.0941(3) 0.67683(17) 0.0587(16) Uani 1 1 d . . . . .
H52D H 0.9609 0.0618 0.6608 0.088 Uiso 1 1 calc R U . . .
H52E H 1.0135 0.0879 0.6972 0.088 Uiso 1 1 calc R U . . .
H52F H 0.9822 0.1254 0.6618 0.088 Uiso 1 1 calc R U . . .
C523 C 0.8825(4) 0.1681(3) 0.72876(17) 0.0636(19) Uani 1 1 d . . . . .
H52G H 0.9067 0.1980 0.7153 0.095 Uiso 1 1 calc R U . . .
H52H H 0.9219 0.1585 0.7509 0.095 Uiso 1 1 calc R U . . .
H52I H 0.8275 0.1793 0.7367 0.095 Uiso 1 1 calc R U . . .
C531 C 0.8584(9) 0.0664(10) 0.5743(7) 0.033(3) Uani 0.499(16) 1 d . U P A 1
H53A H 0.8443 0.0988 0.5589 0.050 Uiso 0.499(16) 1 calc R U P A 1
H53B H 0.8655 0.0353 0.5578 0.050 Uiso 0.499(16) 1 calc R U P A 1
H53C H 0.9116 0.0726 0.5906 0.050 Uiso 0.499(16) 1 calc R U P A 1
C532 C 0.7965(9) -0.0147(4) 0.6272(3) 0.036(3) Uani 0.499(16) 1 d . . P A 1
H53D H 0.8525 -0.0126 0.6421 0.055 Uiso 0.499(16) 1 calc R U P A 1
H53E H 0.7976 -0.0433 0.6082 0.055 Uiso 0.499(16) 1 calc R U P A 1
H53F H 0.7527 -0.0232 0.6437 0.055 Uiso 0.499(16) 1 calc R U P A 1
C533 C 0.6684(8) 0.0467(7) 0.5739(3) 0.046(4) Uani 0.499(16) 1 d . U P A 1
H53G H 0.6227 0.0400 0.5898 0.069 Uiso 0.499(16) 1 calc R U P A 1
H53H H 0.6709 0.0165 0.5562 0.069 Uiso 0.499(16) 1 calc R U P A 1
H53I H 0.6567 0.0806 0.5599 0.069 Uiso 0.499(16) 1 calc R U P A 1
C541 C 0.8295(10) 0.0718(8) 0.5707(6) 0.032(3) Uani 0.501(16) 1 d . U P A 2
H54A H 0.8303 0.1085 0.5602 0.048 Uiso 0.501(16) 1 calc R U P A 2
H54B H 0.8229 0.0452 0.5503 0.048 Uiso 0.501(16) 1 calc R U P A 2
H54C H 0.8833 0.0651 0.5866 0.048 Uiso 0.501(16) 1 calc R U P A 2
C542 C 0.7400(12) -0.0054(5) 0.6203(4) 0.054(4) Uani 0.501(16) 1 d . . P A 2
H54D H 0.6895 -0.0116 0.6335 0.082 Uiso 0.501(16) 1 calc R U P A 2
H54E H 0.7917 -0.0096 0.6380 0.082 Uiso 0.501(16) 1 calc R U P A 2
H54F H 0.7409 -0.0318 0.5999 0.082 Uiso 0.501(16) 1 calc R U P A 2
C543 C 0.6341(9) 0.0730(8) 0.5683(4) 0.054(4) Uani 0.501(16) 1 d . U P A 2
H54G H 0.5856 0.0740 0.5832 0.080 Uiso 0.501(16) 1 calc R U P A 2
H54H H 0.6276 0.0422 0.5509 0.080 Uiso 0.501(16) 1 calc R U P A 2
H54I H 0.6359 0.1068 0.5540 0.080 Uiso 0.501(16) 1 calc R U P A 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 Ge1 2.8607(5) . ?
Au1 Ge2 2.6962(5) . ?
Au1 Ge3 2.6485(5) . ?
Au1 Ge6 2.5329(5) 7_656 ?
Au1 P1 2.3317(10) . ?
Au2 Ge7 2.6886(5) 7_656 ?
Au2 Ge8 2.5553(5) 7_656 ?
Au2 Ge9 2.6092(5) 7_656 ?
Au2 P2 2.2992(9) . ?
Ge1 Ge2 2.8343(6) . ?
Ge1 Ge3 2.7573(7) . ?
Ge1 Ge4 2.5721(6) . ?
Ge1 Ge6 2.5747(6) . ?
Ge2 Ge3 2.7535(6) . ?
Ge2 Ge4 2.5818(6) . ?
Ge2 Ge5 2.5732(6) . ?
Ge3 Ge5 2.5946(6) . ?
Ge3 Ge6 2.5636(6) . ?
Ge4 Ge7 2.5453(6) . ?
Ge4 Ge8 2.4955(6) . ?
Ge4 Si4 2.3978(14) . ?
Ge5 Ge8 2.4852(6) . ?
Ge5 Ge9 2.5231(6) . ?
Ge5 Si5 2.3896(14) . ?
Ge6 Au1 2.5329(5) 7_656 ?
Ge6 Ge7 2.5298(6) . ?
Ge6 Ge9 2.5345(6) . ?
Ge7 Au2 2.6885(5) 7_656 ?
Ge7 Ge9 2.8831(7) . ?
Ge8 Au2 2.5553(5) 7_656 ?
Ge9 Au2 2.6091(5) 7_656 ?
P1 O107 1.643(3) . ?
P1 C101 1.829(5) . ?
P1 C104 1.834(4) . ?
P2 O207 1.636(3) . ?
P2 C201 1.819(5) . ?
P2 C204 1.824(4) . ?
Si4 Si41 2.3369(17) . ?
Si4 Si42 2.354(2) . ?
Si4 Si43 2.3489(17) . ?
Si5 Si51 2.332(2) . ?
Si5 Si52 2.3544(19) . ?
Si5 Si53 2.455(5) . ?
Si5 Si54 2.267(4) . ?
Si41 C411 1.884(6) . ?
Si41 C412 1.870(6) . ?
Si41 C413 1.860(7) . ?
Si42 C421 1.884(6) . ?
Si42 C422 1.867(5) . ?
Si42 C423 1.867(6) . ?
Si43 C431 1.884(6) . ?
Si43 C432 1.866(5) . ?
Si43 C433 1.868(4) . ?
Si51 C511 1.852(8) . ?
Si51 C512 1.889(7) . ?
Si51 C513 1.870(6) . ?
Si52 C521 1.867(6) . ?
Si52 C522 1.857(6) . ?
Si52 C523 1.869(6) . ?
Si53 C531 1.85(2) . ?
Si53 C532 1.881(11) . ?
Si53 C533 1.836(11) . ?
Si54 C541 1.91(2) . ?
Si54 C542 1.882(13) . ?
Si54 C543 1.876(12) . ?
O107 C108 1.380(5) . ?
O207 C208 1.409(5) . ?
C101 H101 1.0000 . ?
C101 C102 1.530(6) . ?
C101 C103 1.546(6) . ?
C102 H10A 0.9800 . ?
C102 H10B 0.9800 . ?
C102 H10C 0.9800 . ?
C103 H10D 0.9800 . ?
C103 H10E 0.9800 . ?
C103 H10F 0.9800 . ?
C104 H104 1.0000 . ?
C104 C105 1.519(7) . ?
C104 C106 1.517(7) . ?
C105 H10G 0.9800 . ?
C105 H10H 0.9800 . ?
C105 H10I 0.9800 . ?
C106 H10J 0.9800 . ?
C106 H10K 0.9800 . ?
C106 H10L 0.9800 . ?
C108 C109 1.384(7) . ?
C108 C210 1.386(6) . ?
C109 H109 0.9500 . ?
C109 C110 1.373(7) . ?
C110 H110 0.9500 . ?
C110 C209 1.387(6) . ?
C201 H201 1.0000 . ?
C201 C202 1.530(7) . ?
C201 C203 1.531(6) . ?
C202 H20A 0.9800 . ?
C202 H20B 0.9800 . ?
C202 H20C 0.9800 . ?
C203 H20D 0.9800 . ?
C203 H20E 0.9800 . ?
C203 H20F 0.9800 . ?
C204 H204 1.0000 . ?
C204 C205 1.522(6) . ?
C204 C206 1.517(7) . ?
C205 H20G 0.9800 . ?
C205 H20H 0.9800 . ?
C205 H20I 0.9800 . ?
C206 H20J 0.9800 . ?
C206 H20K 0.9800 . ?
C206 H20L 0.9800 . ?
C208 C209 1.375(6) . ?
C208 C210 1.376(6) . ?
C209 H209 0.9500 . ?
C210 H210 0.9500 . ?
C411 H41A 0.9800 . ?
C411 H41B 0.9800 . ?
C411 H41C 0.9800 . ?
C412 H41D 0.9800 . ?
C412 H41E 0.9800 . ?
C412 H41F 0.9800 . ?
C413 H41G 0.9800 . ?
C413 H41H 0.9800 . ?
C413 H41I 0.9800 . ?
C421 H42A 0.9800 . ?
C421 H42B 0.9800 . ?
C421 H42C 0.9800 . ?
C422 H42D 0.9800 . ?
C422 H42E 0.9800 . ?
C422 H42F 0.9800 . ?
C423 H42G 0.9800 . ?
C423 H42H 0.9800 . ?
C423 H42I 0.9800 . ?
C431 H43A 0.9800 . ?
C431 H43B 0.9800 . ?
C431 H43C 0.9800 . ?
C432 H43D 0.9800 . ?
C432 H43E 0.9800 . ?
C432 H43F 0.9800 . ?
C433 H43G 0.9800 . ?
C433 H43H 0.9800 . ?
C433 H43I 0.9800 . ?
C511 H51A 0.9800 . ?
C511 H51B 0.9800 . ?
C511 H51C 0.9800 . ?
C512 H51D 0.9800 . ?
C512 H51E 0.9800 . ?
C512 H51F 0.9800 . ?
C513 H51G 0.9800 . ?
C513 H51H 0.9800 . ?
C513 H51I 0.9800 . ?
C521 H52A 0.9800 . ?
C521 H52B 0.9800 . ?
C521 H52C 0.9800 . ?
C522 H52D 0.9800 . ?
C522 H52E 0.9800 . ?
C522 H52F 0.9800 . ?
C523 H52G 0.9800 . ?
C523 H52H 0.9800 . ?
C523 H52I 0.9800 . ?
C531 H53A 0.9800 . ?
C531 H53B 0.9800 . ?
C531 H53C 0.9800 . ?
C532 H53D 0.9800 . ?
C532 H53E 0.9800 . ?
C532 H53F 0.9800 . ?
C533 H53G 0.9800 . ?
C533 H53H 0.9800 . ?
C533 H53I 0.9800 . ?
C541 H54A 0.9800 . ?
C541 H54B 0.9800 . ?
C541 H54C 0.9800 . ?
C542 H54D 0.9800 . ?
C542 H54E 0.9800 . ?
C542 H54F 0.9800 . ?
C543 H54G 0.9800 . ?
C543 H54H 0.9800 . ?
C543 H54I 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ge2 Au1 Ge1 61.248(13) . . ?
Ge3 Au1 Ge1 59.917(15) . . ?
Ge3 Au1 Ge2 62.012(13) . . ?
Ge6 Au1 Ge1 84.955(13) 7_656 . ?
Ge6 Au1 Ge2 139.446(14) 7_656 . ?
Ge6 Au1 Ge3 82.466(14) 7_656 . ?
P1 Au1 Ge1 130.47(3) . . ?
P1 Au1 Ge2 106.10(3) . . ?
P1 Au1 Ge3 160.37(3) . . ?
P1 Au1 Ge6 113.13(3) . 7_656 ?
Ge8 Au2 Ge7 69.992(14) 7_656 7_656 ?
Ge8 Au2 Ge9 70.962(14) 7_656 7_656 ?
Ge9 Au2 Ge7 65.925(15) 7_656 7_656 ?
P2 Au2 Ge7 129.84(3) . 7_656 ?
P2 Au2 Ge8 149.06(3) . 7_656 ?
P2 Au2 Ge9 135.64(3) . 7_656 ?
Ge2 Ge1 Au1 56.513(12) . . ?
Ge3 Ge1 Au1 56.217(12) . . ?
Ge3 Ge1 Ge2 58.983(15) . . ?
Ge4 Ge1 Au1 112.113(17) . . ?
Ge4 Ge1 Ge2 56.800(17) . . ?
Ge4 Ge1 Ge3 97.927(19) . . ?
Ge4 Ge1 Ge6 98.457(18) . . ?
Ge6 Ge1 Au1 109.09(2) . . ?
Ge6 Ge1 Ge2 105.07(2) . . ?
Ge6 Ge1 Ge3 57.351(15) . . ?
Au1 Ge2 Ge1 62.239(14) . . ?
Au1 Ge2 Ge3 58.142(13) . . ?
Ge3 Ge2 Ge1 59.114(16) . . ?
Ge4 Ge2 Au1 117.39(2) . . ?
Ge4 Ge2 Ge1 56.475(16) . . ?
Ge4 Ge2 Ge3 97.791(18) . . ?
Ge5 Ge2 Au1 114.845(19) . . ?
Ge5 Ge2 Ge1 95.448(18) . . ?
Ge5 Ge2 Ge3 58.181(16) . . ?
Ge5 Ge2 Ge4 83.307(19) . . ?
Au1 Ge3 Ge1 63.866(13) . . ?
Au1 Ge3 Ge2 59.846(13) . . ?
Ge2 Ge3 Ge1 61.904(17) . . ?
Ge5 Ge3 Au1 115.770(18) . . ?
Ge5 Ge3 Ge1 96.844(19) . . ?
Ge5 Ge3 Ge2 57.427(17) . . ?
Ge6 Ge3 Au1 116.44(2) . . ?
Ge6 Ge3 Ge1 57.742(15) . . ?
Ge6 Ge3 Ge2 107.75(2) . . ?
Ge6 Ge3 Ge5 94.452(18) . . ?
Ge1 Ge4 Ge2 66.725(17) . . ?
Ge7 Ge4 Ge1 72.508(17) . . ?
Ge7 Ge4 Ge2 117.93(2) . . ?
Ge8 Ge4 Ge1 120.91(2) . . ?
Ge8 Ge4 Ge2 89.74(2) . . ?
Ge8 Ge4 Ge7 73.305(17) . . ?
Si4 Ge4 Ge1 109.78(3) . . ?
Si4 Ge4 Ge2 130.28(3) . . ?
Si4 Ge4 Ge7 106.33(3) . . ?
Si4 Ge4 Ge8 125.40(3) . . ?
Ge2 Ge5 Ge3 64.392(16) . . ?
Ge8 Ge5 Ge2 90.17(2) . . ?
Ge8 Ge5 Ge3 122.64(2) . . ?
Ge8 Ge5 Ge9 73.536(17) . . ?
Ge9 Ge5 Ge2 121.48(2) . . ?
Ge9 Ge5 Ge3 78.170(18) . . ?
Si5 Ge5 Ge2 125.93(4) . . ?
Si5 Ge5 Ge3 111.42(4) . . ?
Si5 Ge5 Ge8 124.52(4) . . ?
Si5 Ge5 Ge9 108.54(4) . . ?
Au1 Ge6 Ge1 119.109(19) 7_656 . ?
Au1 Ge6 Ge3 116.824(18) 7_656 . ?
Au1 Ge6 Ge9 128.83(2) 7_656 . ?
Ge3 Ge6 Ge1 64.906(18) . . ?
Ge7 Ge6 Au1 131.352(19) . 7_656 ?
Ge7 Ge6 Ge1 72.716(18) . . ?
Ge7 Ge6 Ge3 110.754(19) . . ?
Ge7 Ge6 Ge9 69.404(18) . . ?
Ge9 Ge6 Ge1 111.63(2) . . ?
Ge9 Ge6 Ge3 78.540(18) . . ?
Au2 Ge7 Ge9 55.715(12) 7_656 . ?
Ge4 Ge7 Au2 104.363(19) . 7_656 ?
Ge4 Ge7 Ge9 97.262(18) . . ?
Ge6 Ge7 Au2 108.58(2) . 7_656 ?
Ge6 Ge7 Ge4 100.353(18) . . ?
Ge6 Ge7 Ge9 55.374(16) . . ?
Ge4 Ge8 Au2 109.917(18) . 7_656 ?
Ge5 Ge8 Au2 108.203(19) . 7_656 ?
Ge5 Ge8 Ge4 86.92(2) . . ?
Au2 Ge9 Ge7 58.360(13) 7_656 . ?
Ge5 Ge9 Au2 105.416(19) . 7_656 ?
Ge5 Ge9 Ge6 96.947(18) . . ?
Ge5 Ge9 Ge7 94.985(18) . . ?
Ge6 Ge9 Au2 110.96(2) . 7_656 ?
Ge6 Ge9 Ge7 55.222(15) . . ?
O107 P1 Au1 118.52(12) . . ?
O107 P1 C101 97.99(19) . . ?
O107 P1 C104 100.48(18) . . ?
C101 P1 Au1 110.62(13) . . ?
C101 P1 C104 105.0(2) . . ?
C104 P1 Au1 121.09(15) . . ?
O207 P2 Au2 112.11(10) . . ?
O207 P2 C201 103.78(19) . . ?
O207 P2 C204 101.46(18) . . ?
C201 P2 Au2 115.57(16) . . ?
C201 P2 C204 105.1(2) . . ?
C204 P2 Au2 117.12(15) . . ?
Si41 Si4 Ge4 109.81(6) . . ?
Si41 Si4 Si42 109.20(8) . . ?
Si41 Si4 Si43 111.53(7) . . ?
Si42 Si4 Ge4 109.85(6) . . ?
Si43 Si4 Ge4 106.83(6) . . ?
Si43 Si4 Si42 109.59(7) . . ?
Ge5 Si5 Si53 110.13(11) . . ?
Si51 Si5 Ge5 108.61(8) . . ?
Si51 Si5 Si52 108.91(7) . . ?
Si51 Si5 Si53 117.20(13) . . ?
Si52 Si5 Ge5 108.10(6) . . ?
Si52 Si5 Si53 103.48(18) . . ?
Si54 Si5 Ge5 105.51(13) . . ?
Si54 Si5 Si51 107.2(2) . . ?
Si54 Si5 Si52 118.1(3) . . ?
C411 Si41 Si4 109.34(18) . . ?
C412 Si41 Si4 109.64(18) . . ?
C412 Si41 C411 108.7(3) . . ?
C413 Si41 Si4 110.50(19) . . ?
C413 Si41 C411 109.4(3) . . ?
C413 Si41 C412 109.3(3) . . ?
C421 Si42 Si4 110.8(2) . . ?
C422 Si42 Si4 113.3(2) . . ?
C422 Si42 C421 106.5(3) . . ?
C422 Si42 C423 108.2(3) . . ?
C423 Si42 Si4 109.91(18) . . ?
C423 Si42 C421 107.9(3) . . ?
C431 Si43 Si4 110.64(18) . . ?
C432 Si43 Si4 108.53(18) . . ?
C432 Si43 C431 109.9(3) . . ?
C432 Si43 C433 109.3(2) . . ?
C433 Si43 Si4 111.74(16) . . ?
C433 Si43 C431 106.7(2) . . ?
C511 Si51 Si5 109.4(2) . . ?
C511 Si51 C512 108.3(4) . . ?
C511 Si51 C513 109.5(4) . . ?
C512 Si51 Si5 110.7(3) . . ?
C513 Si51 Si5 111.2(2) . . ?
C513 Si51 C512 107.6(3) . . ?
C521 Si52 Si5 110.6(2) . . ?
C521 Si52 C523 108.6(3) . . ?
C522 Si52 Si5 111.6(2) . . ?
C522 Si52 C521 107.1(3) . . ?
C522 Si52 C523 108.3(3) . . ?
C523 Si52 Si5 110.55(18) . . ?
C531 Si53 Si5 113.5(7) . . ?
C531 Si53 C532 106.7(7) . . ?
C532 Si53 Si5 110.7(4) . . ?
C533 Si53 Si5 106.2(5) . . ?
C533 Si53 C531 110.7(7) . . ?
C533 Si53 C532 109.0(6) . . ?
C541 Si54 Si5 110.6(6) . . ?
C542 Si54 Si5 106.9(4) . . ?
C542 Si54 C541 106.9(7) . . ?
C543 Si54 Si5 115.6(6) . . ?
C543 Si54 C541 108.1(7) . . ?
C543 Si54 C542 108.4(7) . . ?
C108 O107 P1 129.3(3) . . ?
C208 O207 P2 120.2(2) . . ?
P1 C101 H101 107.3 . . ?
C102 C101 P1 109.4(3) . . ?
C102 C101 H101 107.3 . . ?
C102 C101 C103 110.7(4) . . ?
C103 C101 P1 114.5(4) . . ?
C103 C101 H101 107.3 . . ?
C101 C102 H10A 109.5 . . ?
C101 C102 H10B 109.5 . . ?
C101 C102 H10C 109.5 . . ?
H10A C102 H10B 109.5 . . ?
H10A C102 H10C 109.5 . . ?
H10B C102 H10C 109.5 . . ?
C101 C103 H10D 109.5 . . ?
C101 C103 H10E 109.5 . . ?
C101 C103 H10F 109.5 . . ?
H10D C103 H10E 109.5 . . ?
H10D C103 H10F 109.5 . . ?
H10E C103 H10F 109.5 . . ?
P1 C104 H104 107.3 . . ?
C105 C104 P1 111.7(3) . . ?
C105 C104 H104 107.3 . . ?
C106 C104 P1 110.8(3) . . ?
C106 C104 H104 107.3 . . ?
C106 C104 C105 112.1(4) . . ?
C104 C105 H10G 109.5 . . ?
C104 C105 H10H 109.5 . . ?
C104 C105 H10I 109.5 . . ?
H10G C105 H10H 109.5 . . ?
H10G C105 H10I 109.5 . . ?
H10H C105 H10I 109.5 . . ?
C104 C106 H10J 109.5 . . ?
C104 C106 H10K 109.5 . . ?
C104 C106 H10L 109.5 . . ?
H10J C106 H10K 109.5 . . ?
H10J C106 H10L 109.5 . . ?
H10K C106 H10L 109.5 . . ?
O107 C108 C109 124.6(4) . . ?
O107 C108 C210 115.0(4) . . ?
C109 C108 C210 120.2(4) . . ?
C108 C109 H109 120.4 . . ?
C110 C109 C108 119.1(4) . . ?
C110 C109 H109 120.4 . . ?
C109 C110 H110 119.4 . . ?
C109 C110 C209 121.2(5) . . ?
C209 C110 H110 119.4 . . ?
P2 C201 H201 106.7 . . ?
C202 C201 P2 111.7(3) . . ?
C202 C201 H201 106.7 . . ?
C202 C201 C203 110.4(4) . . ?
C203 C201 P2 114.2(4) . . ?
C203 C201 H201 106.7 . . ?
C201 C202 H20A 109.5 . . ?
C201 C202 H20B 109.5 . . ?
C201 C202 H20C 109.5 . . ?
H20A C202 H20B 109.5 . . ?
H20A C202 H20C 109.5 . . ?
H20B C202 H20C 109.5 . . ?
C201 C203 H20D 109.5 . . ?
C201 C203 H20E 109.5 . . ?
C201 C203 H20F 109.5 . . ?
H20D C203 H20E 109.5 . . ?
H20D C203 H20F 109.5 . . ?
H20E C203 H20F 109.5 . . ?
P2 C204 H204 108.6 . . ?
C205 C204 P2 109.8(3) . . ?
C205 C204 H204 108.6 . . ?
C206 C204 P2 109.8(3) . . ?
C206 C204 H204 108.6 . . ?
C206 C204 C205 111.3(4) . . ?
C204 C205 H20G 109.5 . . ?
C204 C205 H20H 109.5 . . ?
C204 C205 H20I 109.5 . . ?
H20G C205 H20H 109.5 . . ?
H20G C205 H20I 109.5 . . ?
H20H C205 H20I 109.5 . . ?
C204 C206 H20J 109.5 . . ?
C204 C206 H20K 109.5 . . ?
C204 C206 H20L 109.5 . . ?
H20J C206 H20K 109.5 . . ?
H20J C206 H20L 109.5 . . ?
H20K C206 H20L 109.5 . . ?
C209 C208 O207 119.9(4) . . ?
C209 C208 C210 120.8(4) . . ?
C210 C208 O207 119.3(4) . . ?
C110 C209 H209 120.5 . . ?
C208 C209 C110 119.0(4) . . ?
C208 C209 H209 120.5 . . ?
C108 C210 H210 120.2 . . ?
C208 C210 C108 119.7(4) . . ?
C208 C210 H210 120.2 . . ?
Si41 C411 H41A 109.5 . . ?
Si41 C411 H41B 109.5 . . ?
Si41 C411 H41C 109.5 . . ?
H41A C411 H41B 109.5 . . ?
H41A C411 H41C 109.5 . . ?
H41B C411 H41C 109.5 . . ?
Si41 C412 H41D 109.5 . . ?
Si41 C412 H41E 109.5 . . ?
Si41 C412 H41F 109.5 . . ?
H41D C412 H41E 109.5 . . ?
H41D C412 H41F 109.5 . . ?
H41E C412 H41F 109.5 . . ?
Si41 C413 H41G 109.5 . . ?
Si41 C413 H41H 109.5 . . ?
Si41 C413 H41I 109.5 . . ?
H41G C413 H41H 109.5 . . ?
H41G C413 H41I 109.5 . . ?
H41H C413 H41I 109.5 . . ?
Si42 C421 H42A 109.5 . . ?
Si42 C421 H42B 109.5 . . ?
Si42 C421 H42C 109.5 . . ?
H42A C421 H42B 109.5 . . ?
H42A C421 H42C 109.5 . . ?
H42B C421 H42C 109.5 . . ?
Si42 C422 H42D 109.5 . . ?
Si42 C422 H42E 109.5 . . ?
Si42 C422 H42F 109.5 . . ?
H42D C422 H42E 109.5 . . ?
H42D C422 H42F 109.5 . . ?
H42E C422 H42F 109.5 . . ?
Si42 C423 H42G 109.5 . . ?
Si42 C423 H42H 109.5 . . ?
Si42 C423 H42I 109.5 . . ?
H42G C423 H42H 109.5 . . ?
H42G C423 H42I 109.5 . . ?
H42H C423 H42I 109.5 . . ?
Si43 C431 H43A 109.5 . . ?
Si43 C431 H43B 109.5 . . ?
Si43 C431 H43C 109.5 . . ?
H43A C431 H43B 109.5 . . ?
H43A C431 H43C 109.5 . . ?
H43B C431 H43C 109.5 . . ?
Si43 C432 H43D 109.5 . . ?
Si43 C432 H43E 109.5 . . ?
Si43 C432 H43F 109.5 . . ?
H43D C432 H43E 109.5 . . ?
H43D C432 H43F 109.5 . . ?
H43E C432 H43F 109.5 . . ?
Si43 C433 H43G 109.5 . . ?
Si43 C433 H43H 109.5 . . ?
Si43 C433 H43I 109.5 . . ?
H43G C433 H43H 109.5 . . ?
H43G C433 H43I 109.5 . . ?
H43H C433 H43I 109.5 . . ?
Si51 C511 H51A 109.5 . . ?
Si51 C511 H51B 109.5 . . ?
Si51 C511 H51C 109.5 . . ?
H51A C511 H51B 109.5 . . ?
H51A C511 H51C 109.5 . . ?
H51B C511 H51C 109.5 . . ?
Si51 C512 H51D 109.5 . . ?
Si51 C512 H51E 109.5 . . ?
Si51 C512 H51F 109.5 . . ?
H51D C512 H51E 109.5 . . ?
H51D C512 H51F 109.5 . . ?
H51E C512 H51F 109.5 . . ?
Si51 C513 H51G 109.5 . . ?
Si51 C513 H51H 109.5 . . ?
Si51 C513 H51I 109.5 . . ?
H51G C513 H51H 109.5 . . ?
H51G C513 H51I 109.5 . . ?
H51H C513 H51I 109.5 . . ?
Si52 C521 H52A 109.5 . . ?
Si52 C521 H52B 109.5 . . ?
Si52 C521 H52C 109.5 . . ?
H52A C521 H52B 109.5 . . ?
H52A C521 H52C 109.5 . . ?
H52B C521 H52C 109.5 . . ?
Si52 C522 H52D 109.5 . . ?
Si52 C522 H52E 109.5 . . ?
Si52 C522 H52F 109.5 . . ?
H52D C522 H52E 109.5 . . ?
H52D C522 H52F 109.5 . . ?
H52E C522 H52F 109.5 . . ?
Si52 C523 H52G 109.5 . . ?
Si52 C523 H52H 109.5 . . ?
Si52 C523 H52I 109.5 . . ?
H52G C523 H52H 109.5 . . ?
H52G C523 H52I 109.5 . . ?
H52H C523 H52I 109.5 . . ?
Si53 C531 H53A 109.5 . . ?
Si53 C531 H53B 109.5 . . ?
Si53 C531 H53C 109.5 . . ?
H53A C531 H53B 109.5 . . ?
H53A C531 H53C 109.5 . . ?
H53B C531 H53C 109.5 . . ?
Si53 C532 H53D 109.5 . . ?
Si53 C532 H53E 109.5 . . ?
Si53 C532 H53F 109.5 . . ?
H53D C532 H53E 109.5 . . ?
H53D C532 H53F 109.5 . . ?
H53E C532 H53F 109.5 . . ?
Si53 C533 H53G 109.5 . . ?
Si53 C533 H53H 109.5 . . ?
Si53 C533 H53I 109.5 . . ?
H53G C533 H53H 109.5 . . ?
H53G C533 H53I 109.5 . . ?
H53H C533 H53I 109.5 . . ?
Si54 C541 H54A 109.5 . . ?
Si54 C541 H54B 109.5 . . ?
Si54 C541 H54C 109.5 . . ?
H54A C541 H54B 109.5 . . ?
H54A C541 H54C 109.5 . . ?
H54B C541 H54C 109.5 . . ?
Si54 C542 H54D 109.5 . . ?
Si54 C542 H54E 109.5 . . ?
Si54 C542 H54F 109.5 . . ?
H54D C542 H54E 109.5 . . ?
H54D C542 H54F 109.5 . . ?
H54E C542 H54F 109.5 . . ?
Si54 C543 H54G 109.5 . . ?
Si54 C543 H54H 109.5 . . ?
Si54 C543 H54I 109.5 . . ?
H54G C543 H54H 109.5 . . ?
H54G C543 H54I 109.5 . . ?
H54H C543 H54I 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Au1 P1 O107 C108 27.5(4) . . . . ?
Au1 P1 C101 C102 56.2(3) . . . . ?
Au1 P1 C101 C103 -178.8(3) . . . . ?
Au1 P1 C104 C105 66.3(4) . . . . ?
Au1 P1 C104 C106 -59.5(3) . . . . ?
Au2 P2 O207 C208 6.1(4) . . . . ?
Au2 P2 C201 C202 -47.7(4) . . . . ?
Au2 P2 C201 C203 -173.9(3) . . . . ?
Au2 P2 C204 C205 -68.2(4) . . . . ?
Au2 P2 C204 C206 54.5(4) . . . . ?
P1 O107 C108 C109 34.6(6) . . . . ?
P1 O107 C108 C210 -150.0(3) . . . . ?
P2 O207 C208 C209 -98.7(4) . . . . ?
P2 O207 C208 C210 82.9(4) . . . . ?
O107 P1 C101 C102 -68.4(3) . . . . ?
O107 P1 C101 C103 56.6(4) . . . . ?
O107 P1 C104 C105 -161.0(3) . . . . ?
O107 P1 C104 C106 73.2(3) . . . . ?
O107 C108 C109 C110 173.2(4) . . . . ?
O107 C108 C210 C208 -173.5(3) . . . . ?
O207 P2 C201 C202 75.4(4) . . . . ?
O207 P2 C201 C203 -50.8(4) . . . . ?
O207 P2 C204 C205 169.4(4) . . . . ?
O207 P2 C204 C206 -67.9(3) . . . . ?
O207 C208 C209 C110 -179.3(3) . . . . ?
O207 C208 C210 C108 177.8(3) . . . . ?
C101 P1 O107 C108 146.2(4) . . . . ?
C101 P1 C104 C105 -59.7(4) . . . . ?
C101 P1 C104 C106 174.5(3) . . . . ?
C104 P1 O107 C108 -106.8(4) . . . . ?
C104 P1 C101 C102 -171.5(3) . . . . ?
C104 P1 C101 C103 -46.6(4) . . . . ?
C108 C109 C110 C209 0.4(6) . . . . ?
C109 C108 C210 C208 2.1(5) . . . . ?
C109 C110 C209 C208 1.0(6) . . . . ?
C201 P2 O207 C208 -119.3(3) . . . . ?
C201 P2 C204 C205 61.6(4) . . . . ?
C201 P2 C204 C206 -175.7(3) . . . . ?
C204 P2 O207 C208 131.8(3) . . . . ?
C204 P2 C201 C202 -178.5(4) . . . . ?
C204 P2 C201 C203 55.4(4) . . . . ?
C209 C208 C210 C108 -0.6(6) . . . . ?
C210 C108 C109 C110 -2.0(6) . . . . ?
C210 C208 C209 C110 -1.0(6) . . . . ?

_platon_squeeze_details          ?
_platon_squeeze_special_details  ?
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 0.000 0.146 0.250 266 49 ' '
2 0.000 0.854 0.750 266 49 ' '
3 0.500 0.646 0.250 266 49 ' '
4 0.500 0.354 0.750 266 49 ' '

_platon_squeeze_void_probe_radius 1.20
_olex2_submission_special_instructions 'No special instructions were received'
_exptl_crystal_recrystallization_method 
'Re-crystallisation from solvent: pentane, thf, toluene'
_chemical_properties_physical    Air-sensitive,Moisture-sensitive
