# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2022

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_s
_database_code_depnum_ccdc_archive 'CCDC 2195379'
loop_
_audit_author_name
_audit_author_address
'Jiang-Feng Song'
;N Univ China
China
;
_audit_update_record             
;
2022-08-07 deposited with the CCDC.	2022-11-22 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C42 H36 Eu4 N12 O29'
_chemical_formula_weight         1780.67

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   13.1268(16)
_cell_length_b                   11.2985(15)
_cell_length_c                   18.651(2)
_cell_angle_alpha                90
_cell_angle_beta                 98.505(4)
_cell_angle_gamma                90
_cell_volume                     2735.8(6)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    3.138
_cell_measurement_theta_min      27.584
_cell_measurement_theta_max      6316

_exptl_crystal_description       Block
_exptl_crystal_colour            Yellow
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    2.162
_exptl_crystal_F_000             1712
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.340
_exptl_crystal_size_mid          0.280
_exptl_crystal_size_min          0.200
_exptl_absorpt_coefficient_mu    4.626
_shelx_estimated_absorpt_T_min   0.302
_shelx_estimated_absorpt_T_max   0.458
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.23
_exptl_absorpt_correction_T_max  0.396
_exptl_absorpt_process_details   'Higashi, T. (1995).'

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'fine-focus sealed tube'
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            42340
_diffrn_reflns_av_unetI/netI     0.0230
_diffrn_reflns_av_R_equivalents  0.0328
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_theta_min         3.138
_diffrn_reflns_theta_max         27.584
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measured_fraction_theta_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_point_group_measured_fraction_full 0.998
_reflns_number_total             6316
_reflns_number_gt                5712
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker XSCANS'
_computing_cell_refinement       'Bruker XSCANS'
_computing_data_reduction        'Bruker SHELXTL'
_computing_structure_solution    'ShelXS (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-2014 (Sheldrick, 2014)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
;
 ?
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0229P)²+7.8610P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         6316
_refine_ls_number_parameters     417
_refine_ls_number_restraints     5
_refine_ls_R_factor_all          0.0304
_refine_ls_R_factor_gt           0.0248
_refine_ls_wR_factor_ref         0.0601
_refine_ls_wR_factor_gt          0.0585
_refine_ls_goodness_of_fit_ref   1.103
_refine_ls_restrained_S_all      1.104
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
O4W O 0.5195(14) 0.106(2) 0.3566(10) 0.185(8) Uani 0.5 1 d . . P . .
H3 H 0.565(3) 1.080(3) 0.9291(16) 0.026(12) Uiso 1 1 d D . . . .
O9 O 1.0862(2) 0.9284(3) 1.06440(16) 0.0319(7) Uani 1 1 d . . . . .
O7 O 0.7954(3) 0.2155(2) 1.03407(16) 0.0344(7) Uani 1 1 d . . . . .
O8 O 0.6356(2) 0.2774(3) 1.0329(2) 0.0459(9) Uani 1 1 d . . . . .
C20 C 0.7304(3) 0.2947(3) 1.0378(2) 0.0260(8) Uani 1 1 d . . . . .
C15 C 0.7687(3) 0.4197(3) 1.0472(2) 0.0231(8) Uani 1 1 d . . . . .
C14 C 0.8730(3) 0.4383(3) 1.0668(2) 0.0247(8) Uani 1 1 d . . . . .
H14 H 0.9177 0.3742 1.0748 0.030 Uiso 1 1 calc R U . . .
O3W O 0.4324(6) 0.9515(8) 0.2654(6) 0.185(5) Uani 1 1 d D . . . .
Eu1 Eu 0.76079(2) 1.02431(2) 0.98877(2) 0.01585(5) Uani 1 1 d . . . . .
Eu2 Eu 0.47662(2) 0.86407(2) 0.92940(2) 0.01617(5) Uani 1 1 d . . . . .
O11 O 0.57719(18) 1.0406(2) 0.96649(13) 0.0168(5) Uani 1 1 d D . . . .
O4 O 0.6987(2) 0.4687(2) 0.60827(14) 0.0234(6) Uani 1 1 d . . . . .
O2W O 0.7048(3) 1.1594(3) 0.88237(18) 0.0353(7) Uani 1 1 d D . . . .
O3 O 0.5666(2) 0.5250(3) 0.65881(16) 0.0318(7) Uani 1 1 d . . . . .
O10 O 0.9166(2) 0.9496(3) 1.05745(17) 0.0372(8) Uani 1 1 d . . . . .
O2 O 0.6024(2) 0.8215(3) 0.85469(17) 0.0398(8) Uani 1 1 d . . . . .
C10 C 0.6605(3) 0.5323(3) 0.6531(2) 0.0210(7) Uani 1 1 d . . . . .
C21 C 1.0017(3) 0.9660(3) 1.0351(2) 0.0241(8) Uani 1 1 d . . . . .
O6 O 0.5786(3) 0.7204(3) 1.0023(2) 0.0542(10) Uani 1 1 d . . . . .
O1 O 0.7510(3) 0.9144(3) 0.88214(19) 0.0501(10) Uani 1 1 d . . . . .
C19 C 0.6724(3) 0.7357(4) 1.0194(2) 0.0302(9) Uani 1 1 d . . . . .
O5 O 0.7141(3) 0.8343(3) 1.0203(2) 0.0495(9) Uani 1 1 d . . . . .
C5 C 0.6817(3) 0.6885(4) 0.7483(2) 0.0250(8) Uani 1 1 d . . . . .
H5 H 0.6107 0.6875 0.7472 0.030 Uiso 1 1 calc R U . . .
C16 C 0.7018(3) 0.5149(3) 1.0338(2) 0.0255(8) Uani 1 1 d . . . . .
H16 H 0.6315 0.5022 1.0212 0.031 Uiso 1 1 calc R U . . .
C17 C 0.7411(3) 0.6301(3) 1.0395(2) 0.0246(8) Uani 1 1 d . . . . .
C6 C 0.7270(3) 0.6148(3) 0.7026(2) 0.0231(8) Uani 1 1 d . . . . .
C18 C 0.8458(3) 0.6488(3) 1.0603(2) 0.0277(9) Uani 1 1 d . . . . .
H18 H 0.8721 0.7253 1.0647 0.033 Uiso 1 1 calc R U . . .
C7 C 0.8331(3) 0.6148(4) 0.7042(2) 0.0258(8) Uani 1 1 d . . . . .
H7 H 0.8635 0.5659 0.6733 0.031 Uiso 1 1 calc R U . . .
N4 N 1.0226(3) 0.5702(3) 1.0965(2) 0.0307(8) Uani 1 1 d . . . . .
C13 C 0.9109(3) 0.5520(3) 1.0746(2) 0.0243(8) Uani 1 1 d . . . . .
N1 N 1.0040(3) 0.6828(4) 0.7582(2) 0.0386(9) Uani 1 1 d . . . . .
O1W O 0.3882(3) 0.7699(4) 0.8187(2) 0.0575(11) Uani 1 1 d D . . . .
C4 C 0.7421(3) 0.7635(4) 0.7956(2) 0.0251(8) Uani 1 1 d . . . . .
C3 C 0.6942(3) 0.8385(4) 0.8482(2) 0.0272(9) Uani 1 1 d . . . . .
C9 C 0.8484(3) 0.7640(4) 0.7978(2) 0.0306(9) Uani 1 1 d . . . . .
H9 H 0.8893 0.8142 0.8294 0.037 Uiso 1 1 calc R U . . .
N5 N 1.0834(3) 0.4751(4) 1.1061(3) 0.0488(11) Uani 1 1 d . . . . .
C8 C 0.8930(3) 0.6887(4) 0.7525(2) 0.0294(9) Uani 1 1 d . . . . .
C11 C 1.0726(4) 0.6673(5) 1.1041(3) 0.0428(12) Uani 1 1 d . . . . .
H11 H 1.0437 0.7424 1.0980 0.051 Uiso 1 1 calc R U . . .
N2 N 1.0499(3) 0.5789(6) 0.7428(3) 0.0683(16) Uani 1 1 d . . . . .
N6 N 1.1716(3) 0.6443(4) 1.1218(2) 0.0479(11) Uani 1 1 d . . . . .
C12 C 1.1735(4) 0.5250(5) 1.1221(3) 0.0485(13) Uani 1 1 d . . . . .
H12 H 1.2341 0.4818 1.1330 0.058 Uiso 1 1 calc R U . . .
C1 C 1.0728(4) 0.7637(6) 0.7825(3) 0.0588(16) Uani 1 1 d . . . . .
H1 H 1.0591 0.8397 0.7977 0.071 Uiso 1 1 calc R U . . .
N3 N 1.1675(4) 0.7157(6) 0.7815(3) 0.0717(17) Uani 1 1 d . . . . .
C2 C 1.1486(4) 0.6068(8) 0.7558(3) 0.071(2) Uani 1 1 d . . . . .
H2 H 1.2005 0.5547 0.7478 0.085 Uiso 1 1 calc R U . . .
H3WA H 0.3637(17) 0.944(4) 0.267(2) 0.016(10) Uiso 1 1 d D . . . .
H1WA H 0.409(4) 0.704(3) 0.807(3) 0.058(18) Uiso 1 1 d D . . . .
H2WA H 0.745(3) 1.216(3) 0.879(3) 0.048(16) Uiso 1 1 d D . . . .
H2WB H 0.700(6) 1.113(5) 0.846(3) 0.09(3) Uiso 1 1 d D . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
O9 C21 1.236(5) . ?
O9 Eu1 2.428(3) 3_777 ?
O7 C20 1.245(5) . ?
O7 Eu1 2.339(3) 1_545 ?
O8 C20 1.249(5) . ?
O8 Eu2 2.350(3) 3_667 ?
C20 C15 1.501(5) . ?
C20 Eu1 3.230(4) 1_545 ?
C15 C14 1.380(5) . ?
C15 C16 1.388(5) . ?
C14 C13 1.377(5) . ?
Eu1 O5 2.331(3) . ?
Eu1 O1 2.332(3) . ?
Eu1 O7 2.339(3) 1_565 ?
Eu1 O11 2.392(2) . ?
Eu1 O10 2.400(3) . ?
Eu1 O9 2.428(3) 3_777 ?
Eu1 O4 2.485(3) 4_576 ?
Eu1 O2W 2.525(3) . ?
Eu1 C21 3.215(4) 3_777 ?
Eu1 C21 3.221(4) . ?
Eu1 C20 3.230(4) 1_565 ?
Eu1 Eu2 3.8781(4) 3_677 ?
Eu2 O8 2.350(3) 3_667 ?
Eu2 O2 2.362(3) . ?
Eu2 O6 2.395(3) . ?
Eu2 O11 2.415(2) 3_677 ?
Eu2 O11 2.435(2) . ?
Eu2 O1W 2.456(3) . ?
Eu2 O3 2.461(3) 2_656 ?
Eu2 O4 2.590(3) 2_656 ?
Eu2 C10 2.898(4) 2_656 ?
Eu2 Eu1 3.8782(4) 3_677 ?
Eu2 Eu2 4.0335(5) 3_677 ?
O11 Eu2 2.415(2) 3_677 ?
O4 C10 1.261(4) . ?
O4 Eu1 2.485(3) 4_575 ?
O4 Eu2 2.590(3) 2_646 ?
O3 C10 1.256(5) . ?
O3 Eu2 2.461(3) 2_646 ?
O10 C21 1.263(5) . ?
O2 C3 1.244(5) . ?
C10 C6 1.498(5) . ?
C10 Eu2 2.898(4) 2_646 ?
C21 C21 1.514(8) 3_777 ?
C21 Eu1 3.215(4) 3_777 ?
O6 C19 1.237(5) . ?
O1 C3 1.246(5) . ?
C19 O5 1.241(5) . ?
C19 C17 1.509(5) . ?
C5 C4 1.385(5) . ?
C5 C6 1.386(5) . ?
C16 C17 1.398(5) . ?
C17 C18 1.388(6) . ?
C6 C7 1.389(5) . ?
C18 C13 1.389(5) . ?
C7 C8 1.385(6) . ?
N4 C11 1.275(6) . ?
N4 N5 1.335(5) . ?
N4 C13 1.477(5) . ?
N1 C1 1.318(6) . ?
N1 N2 1.370(7) . ?
N1 C8 1.447(5) . ?
C4 C9 1.390(5) . ?
C4 C3 1.503(5) . ?
C9 C8 1.388(6) . ?
N5 C12 1.304(6) . ?
C11 N6 1.318(6) . ?
N2 C2 1.321(7) . ?
N6 C12 1.348(7) . ?
C1 N3 1.360(8) . ?
N3 C2 1.330(9) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C21 O9 Eu1 119.1(2) . 3_777 ?
C20 O7 Eu1 125.9(3) . 1_545 ?
C20 O8 Eu2 138.2(3) . 3_667 ?
O7 C20 O8 124.5(4) . . ?
O7 C20 C15 117.5(4) . . ?
O8 C20 C15 118.0(4) . . ?
O7 C20 Eu1 35.93(19) . 1_545 ?
O8 C20 Eu1 89.7(2) . 1_545 ?
C15 C20 Eu1 150.4(3) . 1_545 ?
C14 C15 C16 120.4(3) . . ?
C14 C15 C20 118.5(3) . . ?
C16 C15 C20 121.1(3) . . ?
C13 C14 C15 119.9(4) . . ?
O5 Eu1 O1 74.99(13) . . ?
O5 Eu1 O7 143.46(12) . 1_565 ?
O1 Eu1 O7 141.54(12) . 1_565 ?
O5 Eu1 O11 79.57(11) . . ?
O1 Eu1 O11 88.04(11) . . ?
O7 Eu1 O11 97.36(10) 1_565 . ?
O5 Eu1 O10 77.09(12) . . ?
O1 Eu1 O10 101.70(13) . . ?
O7 Eu1 O10 91.59(12) 1_565 . ?
O11 Eu1 O10 151.29(9) . . ?
O5 Eu1 O9 124.76(12) . 3_777 ?
O1 Eu1 O9 73.35(11) . 3_777 ?
O7 Eu1 O9 79.41(11) 1_565 3_777 ?
O11 Eu1 O9 141.77(9) . 3_777 ?
O10 Eu1 O9 66.69(9) . 3_777 ?
O5 Eu1 O4 70.73(11) . 4_576 ?
O1 Eu1 O4 142.92(11) . 4_576 ?
O7 Eu1 O4 73.65(10) 1_565 4_576 ?
O11 Eu1 O4 72.40(9) . 4_576 ?
O10 Eu1 O4 84.21(9) . 4_576 ?
O9 Eu1 O4 139.49(10) 3_777 4_576 ?
O5 Eu1 O2W 134.24(12) . . ?
O1 Eu1 O2W 71.26(13) . . ?
O7 Eu1 O2W 75.17(11) 1_565 . ?
O11 Eu1 O2W 69.41(9) . . ?
O10 Eu1 O2W 139.28(10) . . ?
O9 Eu1 O2W 73.02(10) 3_777 . ?
O4 Eu1 O2W 126.15(10) 4_576 . ?
O5 Eu1 C21 111.28(12) . 3_777 ?
O1 Eu1 C21 80.35(11) . 3_777 ?
O7 Eu1 C21 83.01(11) 1_565 3_777 ?
O11 Eu1 C21 161.10(9) . 3_777 ?
O10 Eu1 C21 47.08(10) . 3_777 ?
O9 Eu1 C21 19.64(10) 3_777 3_777 ?
O4 Eu1 C21 125.20(10) 4_576 3_777 ?
O2W Eu1 C21 92.62(10) . 3_777 ?
O5 Eu1 C21 91.63(11) . . ?
O1 Eu1 C21 92.75(12) . . ?
O7 Eu1 C21 87.81(11) 1_565 . ?
O11 Eu1 C21 170.65(9) . . ?
O10 Eu1 C21 19.88(10) . . ?
O9 Eu1 C21 46.82(10) 3_777 . ?
O4 Eu1 C21 101.83(9) 4_576 . ?
O2W Eu1 C21 119.64(10) . . ?
C21 Eu1 C21 27.20(13) 3_777 . ?
O5 Eu1 C20 138.69(12) . 1_565 ?
O1 Eu1 C20 138.72(13) . 1_565 ?
O7 Eu1 C20 18.21(11) 1_565 1_565 ?
O11 Eu1 C20 79.20(9) . 1_565 ?
O10 Eu1 C20 108.24(11) . 1_565 ?
O9 Eu1 C20 92.97(11) 3_777 1_565 ?
O4 Eu1 C20 69.23(9) 4_576 1_565 ?
O2W Eu1 C20 67.49(11) . 1_565 ?
C21 Eu1 C20 99.79(10) 3_777 1_565 ?
C21 Eu1 C20 105.97(10) . 1_565 ?
O5 Eu1 Eu2 86.77(9) . 3_677 ?
O1 Eu1 Eu2 124.24(9) . 3_677 ?
O7 Eu1 Eu2 71.45(8) 1_565 3_677 ?
O11 Eu1 Eu2 36.43(6) . 3_677 ?
O10 Eu1 Eu2 125.12(7) . 3_677 ?
O9 Eu1 Eu2 148.30(7) 3_777 3_677 ?
O4 Eu1 Eu2 41.19(6) 4_576 3_677 ?
O2W Eu1 Eu2 87.45(8) . 3_677 ?
C21 Eu1 Eu2 153.56(7) 3_777 3_677 ?
C21 Eu1 Eu2 140.83(7) . 3_677 ?
C20 Eu1 Eu2 56.00(7) 1_565 3_677 ?
O8 Eu2 O2 124.18(12) 3_667 . ?
O8 Eu2 O6 72.04(12) 3_667 . ?
O2 Eu2 O6 79.41(13) . . ?
O8 Eu2 O11 77.98(11) 3_667 3_677 ?
O2 Eu2 O11 151.40(10) . 3_677 ?
O6 Eu2 O11 92.93(12) . 3_677 ?
O8 Eu2 O11 144.02(11) 3_667 . ?
O2 Eu2 O11 86.42(10) . . ?
O6 Eu2 O11 99.20(11) . . ?
O11 Eu2 O11 67.49(9) 3_677 . ?
O8 Eu2 O1W 73.62(14) 3_667 . ?
O2 Eu2 O1W 72.59(12) . . ?
O6 Eu2 O1W 109.80(15) . . ?
O11 Eu2 O1W 135.29(11) 3_677 . ?
O11 Eu2 O1W 139.69(13) . . ?
O8 Eu2 O3 127.58(10) 3_667 2_656 ?
O2 Eu2 O3 82.42(11) . 2_656 ?
O6 Eu2 O3 159.10(11) . 2_656 ?
O11 Eu2 O3 98.18(9) 3_677 2_656 ?
O11 Eu2 O3 69.29(9) . 2_656 ?
O1W Eu2 O3 74.01(13) . 2_656 ?
O8 Eu2 O4 79.67(10) 3_667 2_656 ?
O2 Eu2 O4 127.11(10) . 2_656 ?
O6 Eu2 O4 149.63(10) . 2_656 ?
O11 Eu2 O4 70.17(8) 3_677 2_656 ?
O11 Eu2 O4 97.22(8) . 2_656 ?
O1W Eu2 O4 71.28(11) . 2_656 ?
O3 Eu2 O4 51.24(8) 2_656 2_656 ?
O8 Eu2 C10 103.73(11) 3_667 2_656 ?
O2 Eu2 C10 104.71(11) . 2_656 ?
O6 Eu2 C10 175.42(11) . 2_656 ?
O11 Eu2 C10 84.36(9) 3_677 2_656 ?
O11 Eu2 C10 83.19(9) . 2_656 ?
O1W Eu2 C10 70.04(13) . 2_656 ?
O3 Eu2 C10 25.47(10) 2_656 2_656 ?
O4 Eu2 C10 25.79(9) 2_656 2_656 ?
O8 Eu2 Eu1 61.82(9) 3_667 3_677 ?
O2 Eu2 Eu1 166.14(9) . 3_677 ?
O6 Eu2 Eu1 114.28(10) . 3_677 ?
O11 Eu2 Eu1 36.01(6) 3_677 3_677 ?
O11 Eu2 Eu1 93.16(6) . 3_677 ?
O1W Eu2 Eu1 99.44(9) . 3_677 ?
O3 Eu2 Eu1 84.48(7) 2_656 3_677 ?
O4 Eu2 Eu1 39.18(6) 2_656 3_677 ?
C10 Eu2 Eu1 61.54(7) 2_656 3_677 ?
O8 Eu2 Eu2 111.34(9) 3_667 3_677 ?
O2 Eu2 Eu2 119.21(8) . 3_677 ?
O6 Eu2 Eu2 97.31(10) . 3_677 ?
O11 Eu2 Eu2 33.90(6) 3_677 3_677 ?
O11 Eu2 Eu2 33.59(6) . 3_677 ?
O1W Eu2 Eu2 152.37(10) . 3_677 ?
O3 Eu2 Eu2 82.63(8) 2_656 3_677 ?
O4 Eu2 Eu2 82.69(6) 2_656 3_677 ?
C10 Eu2 Eu2 82.51(7) 2_656 3_677 ?
Eu1 Eu2 Eu2 63.186(7) 3_677 3_677 ?
Eu1 O11 Eu2 107.56(9) . 3_677 ?
Eu1 O11 Eu2 118.44(10) . . ?
Eu2 O11 Eu2 112.51(9) 3_677 . ?
C10 O4 Eu1 142.3(2) . 4_575 ?
C10 O4 Eu2 90.9(2) . 2_646 ?
Eu1 O4 Eu2 99.63(9) 4_575 2_646 ?
C10 O3 Eu2 97.1(2) . 2_646 ?
C21 O10 Eu1 119.9(3) . . ?
C3 O2 Eu2 142.9(3) . . ?
O3 C10 O4 120.7(3) . . ?
O3 C10 C6 118.6(3) . . ?
O4 C10 C6 120.7(3) . . ?
O3 C10 Eu2 57.43(19) . 2_646 ?
O4 C10 Eu2 63.33(19) . 2_646 ?
C6 C10 Eu2 174.0(3) . 2_646 ?
O9 C21 O10 125.7(4) . . ?
O9 C21 C21 117.9(4) . 3_777 ?
O10 C21 C21 116.4(4) . 3_777 ?
O9 C21 Eu1 41.30(18) . 3_777 ?
O10 C21 Eu1 167.0(3) . 3_777 ?
C21 C21 Eu1 76.6(3) 3_777 3_777 ?
O9 C21 Eu1 165.8(3) . . ?
O10 C21 Eu1 40.25(19) . . ?
C21 C21 Eu1 76.2(3) 3_777 . ?
Eu1 C21 Eu1 152.80(13) 3_777 . ?
C19 O6 Eu2 120.2(3) . . ?
C3 O1 Eu1 138.8(3) . . ?
O6 C19 O5 123.3(4) . . ?
O6 C19 C17 119.3(4) . . ?
O5 C19 C17 117.4(4) . . ?
C19 O5 Eu1 162.9(3) . . ?
C4 C5 C6 120.2(4) . . ?
C15 C16 C17 119.5(4) . . ?
C18 C17 C16 120.0(3) . . ?
C18 C17 C19 118.7(3) . . ?
C16 C17 C19 121.1(4) . . ?
C5 C6 C7 120.4(3) . . ?
C5 C6 C10 119.3(3) . . ?
C7 C6 C10 120.3(3) . . ?
C17 C18 C13 119.3(3) . . ?
C8 C7 C6 119.1(3) . . ?
C11 N4 N5 112.9(4) . . ?
C11 N4 C13 128.6(4) . . ?
N5 N4 C13 118.3(3) . . ?
C14 C13 C18 120.8(4) . . ?
C14 C13 N4 119.2(3) . . ?
C18 C13 N4 120.0(3) . . ?
C1 N1 N2 111.5(5) . . ?
C1 N1 C8 128.7(5) . . ?
N2 N1 C8 119.6(4) . . ?
C5 C4 C9 119.9(3) . . ?
C5 C4 C3 120.4(3) . . ?
C9 C4 C3 119.6(3) . . ?
O2 C3 O1 124.9(4) . . ?
O2 C3 C4 118.8(4) . . ?
O1 C3 C4 116.3(4) . . ?
C8 C9 C4 119.4(4) . . ?
C12 N5 N4 100.8(4) . . ?
C7 C8 C9 121.0(4) . . ?
C7 C8 N1 119.2(4) . . ?
C9 C8 N1 119.6(4) . . ?
N4 C11 N6 109.3(5) . . ?
C2 N2 N1 101.9(5) . . ?
C11 N6 C12 102.4(4) . . ?
N5 C12 N6 114.5(5) . . ?
N1 C1 N3 107.5(6) . . ?
C2 N3 C1 104.6(5) . . ?
N2 C2 N3 114.4(6) . . ?

_refine_diff_density_max         0.869
_refine_diff_density_min         -0.814
_refine_diff_density_rms         0.119

_shelxl_version_number           2014-3



