# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2023

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_[Eu(+pfc)3(p-dpeb)]n
_database_code_depnum_ccdc_archive 'CCDC 2213525'
loop_
_audit_author_name
_audit_author_address
'Makoto Tsurui'
;Hokkaido University
Japan
;
_audit_update_record             
;
2022-10-17 deposited with the CCDC.	2022-12-13 downloaded from the CCDC.
;
_audit_creation_date             2022-04-02
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6408)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C73 H66 Eu F15 O8 P2'
_chemical_formula_sum            'C73 H66 Eu F15 O8 P2'
_chemical_formula_weight         1570.15
_chemical_absolute_configuration ad
_chemical_melting_point          ?
_chemical_oxdiff_formula         'Eu C H O P F'
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           19
_space_group_name_H-M_alt        'P 21 21 21'
_space_group_name_Hall           'P 2ac 2ab'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'

_cell_length_a                   17.7325(3)
_cell_length_b                   19.2862(3)
_cell_length_c                   21.0290(3)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     7191.76(19)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    30980
_cell_measurement_temperature    123.15
_cell_measurement_theta_max      30.3890
_cell_measurement_theta_min      2.1080
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    1.009
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.66375
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.40.69a (Rigaku Oxford Diffraction, 2020)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'light yellow'
_exptl_crystal_density_diffrn    1.450
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             3184
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
-19 -12 14 0.0330
11 11 24 0.0172
14 8 -23 0.0167
-13 -12 -22 0.0336
-2 -9 28 0.0336
-14 22 0 0.0187
15 -22 -1 0.0227

_exptl_crystal_size_max          0.058
_exptl_crystal_size_mid          0.052
_exptl_crystal_size_min          0.043
loop_
_exptl_oxdiff_crystal_face_indexfrac_h
_exptl_oxdiff_crystal_face_indexfrac_k
_exptl_oxdiff_crystal_face_indexfrac_l
_exptl_oxdiff_crystal_face_x
_exptl_oxdiff_crystal_face_y
_exptl_oxdiff_crystal_face_z
-18.7957 -12.0346 14.4945 -0.1694 -0.7086 0.6849
11.0795 10.7605 23.8154 0.1792 0.7439 0.6439
14.4116 7.9211 -22.6439 0.1016 0.4272 -0.8985
-13.1199 -11.9885 -21.5501 -0.1959 -0.8138 -0.5471
-1.5132 -8.5648 28.0798 0.3157 -0.0749 0.9459
-14.3634 22.2756 -0.4375 -0.9684 0.2325 0.0907
14.6642 -22.0070 -1.4478 0.9605 -0.2307 -0.1557

_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0806
_diffrn_reflns_av_unetI/netI     0.0681
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.795
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            67773
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.774
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         31.082
_diffrn_reflns_theta_min         1.836
_diffrn_ambient_temperature      123.15
_diffrn_detector                 'Hybrid Pixel Array Detector'
_diffrn_detector_area_resol_mean 10.0000
_diffrn_detector_type            HyPix
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.795
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω    -80.00   0.00   0.50   42.81    --   -5.96 -20.00 149.00  160
  2  ω    -17.00  28.00   0.50   42.81    --   -5.96 -99.00  90.00   90
  3  ω    -15.00  70.00   0.50   42.81    --   -5.96  20.00 -43.00  170
  4  ω      5.00  30.00   0.50   42.81    --   -5.96  19.00-180.00   50
  5  ω     -1.00  28.00   0.50   42.81    --   -5.96 -99.00 -90.00   58
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'XtaLAB Synergy R, DW system, HyPix'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      0.0289006000
_diffrn_orient_matrix_UB_12      -0.0247329000
_diffrn_orient_matrix_UB_13      0.0052564000
_diffrn_orient_matrix_UB_21      0.0257137000
_diffrn_orient_matrix_UB_22      0.0271566000
_diffrn_orient_matrix_UB_23      0.0070012000
_diffrn_orient_matrix_UB_31      -0.0101442000
_diffrn_orient_matrix_UB_32      -0.0018295000
_diffrn_orient_matrix_UB_33      0.0325814000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'Rotating-anode X-ray tube'
_diffrn_source_type              'Rigaku (Mo) X-ray Source'
_reflns_Friedel_coverage         0.806
_reflns_Friedel_fraction_full    1.000
_reflns_Friedel_fraction_max     0.750
_reflns_number_gt                15079
_reflns_number_total             17870
_reflns_odcompleteness_completeness 99.93
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     26.32
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.40.69a (Rigaku OD, 2020)'
_computing_data_collection       'CrysAlisPro 1.171.40.69a (Rigaku OD, 2020)'
_computing_data_reduction        'CrysAlisPro 1.171.40.69a (Rigaku OD, 2020)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         1.631
_refine_diff_density_min         -1.339
_refine_diff_density_rms         0.120
_refine_ls_abs_structure_details 
;
 Flack x determined using 5673 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   -0.004(7)
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.033
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     901
_refine_ls_number_reflns         17870
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0693
_refine_ls_R_factor_gt           0.0576
_refine_ls_restrained_S_all      1.033
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0922P)²+6.1211P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1494
_refine_ls_wR_factor_ref         0.1546
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Ternary CH refined with riding coordinates:
 C41(H41), C58(H58), C78(H78)
2.b Secondary CH2 refined with riding coordinates:
 C59(H59A,H59B), C60(H60A,H60B), C40(H40A,H40B), C39(H39A,H39B), C80(H80A,
 H80B), C79(H79A,H79B)
2.c Aromatic/amide H refined with riding coordinates:
 C24(H24), C31(H31), C6(H6), C23(H23), C4(H4), C7(H7), C25(H25), C30(H30),
 C3(H3), C21(H21), C16(H16), C22(H22), C17(H17), C28(H28), C36(H36), C29(H29),
 C37(H37), C35(H35), C27(H27), C33(H33), C34(H34), C18(H18), C10(H10), C1(H1)
2.d Idealised Me refined as rotating group:
 C77(H77A,H77B,H77C), C75(H75A,H75B,H75C), C56(H56A,H56B,H56C), C97(H97A,H97B,
 H97C), C57(H57A,H57B,H57C), C76(H76A,H76B,H76C), C55(H55A,H55B,H55C), C96(H96A,
 H96B,H96C), C95(H95A,H95B,H95C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.52472(2) 0.50809(2) 0.52069(2) 0.02462(10) Uani 1 1 d . . . . .
P10 P 0.55070(12) 0.68342(12) 0.44447(9) 0.0299(4) Uani 1 1 d . . . . .
P14 P 0.93668(14) 0.67905(12) 0.00517(10) 0.0357(5) Uani 1 1 d . . . . .
O54 O 0.6572(3) 0.4908(3) 0.4980(2) 0.0284(11) Uani 1 1 d . . . . .
F71 F 0.2548(3) 0.5005(4) 0.3686(3) 0.0570(16) Uani 1 1 d . . . . .
O19 O 0.9671(4) 0.6098(3) -0.0110(3) 0.0370(13) Uani 1 1 d . . . . .
O11 O 0.5549(3) 0.6214(3) 0.4852(3) 0.0367(13) Uani 1 1 d . . . . .
O73 O 0.4036(3) 0.4961(3) 0.4761(2) 0.0355(12) Uani 1 1 d . . . . .
F91 F 0.4381(5) 0.4387(4) 0.7720(3) 0.069(2) Uani 1 1 d . . . . .
F72 F 0.2591(3) 0.5228(4) 0.4696(3) 0.0671(19) Uani 1 1 d . . . . .
O74 O 0.5388(3) 0.5081(3) 0.4041(2) 0.0289(11) Uani 1 1 d . . . . .
F48 F 0.6051(5) 0.5182(4) 0.7412(3) 0.074(2) Uani 1 1 d . . . . .
F88 F 0.3581(6) 0.3447(4) 0.6461(4) 0.091(3) Uani 1 1 d . . . . .
F51 F 0.7361(6) 0.6385(6) 0.6920(3) 0.114(4) Uani 1 1 d . . . . .
F92 F 0.4970(4) 0.3671(5) 0.7044(4) 0.079(2) Uani 1 1 d . . . . .
O53 O 0.5942(4) 0.5470(4) 0.6101(3) 0.0488(18) Uani 1 1 d . . . . .
O94 O 0.4436(4) 0.5881(4) 0.5756(3) 0.0490(17) Uani 1 1 d . . . . .
F50 F 0.7244(6) 0.5162(7) 0.7368(4) 0.119(4) Uani 1 1 d . . . . .
O93 O 0.4778(4) 0.4483(4) 0.6091(3) 0.0498(16) Uani 1 1 d . . . . .
F68 F 0.2807(4) 0.3921(5) 0.4978(4) 0.096(3) Uani 1 1 d . . . . .
F90 F 0.3057(5) 0.4091(5) 0.7169(6) 0.099(3) Uani 1 1 d . . . . .
C43 C 0.7139(4) 0.5179(4) 0.5216(3) 0.0289(14) Uani 1 1 d . . . . .
F52 F 0.6142(7) 0.6523(4) 0.6936(4) 0.099(3) Uani 1 1 d . . . . .
C24 C 0.3255(6) 0.6792(5) 0.4134(5) 0.044(2) Uani 1 1 d . . . . .
H24 H 0.282586 0.657301 0.431483 0.053 Uiso 1 1 calc R U . . .
F70 F 0.2868(5) 0.3650(5) 0.3976(5) 0.095(3) Uani 1 1 d . . . . .
C5 C 0.7770(6) 0.6711(5) 0.1622(4) 0.042(2) Uani 1 1 d . . . . .
C26 C 0.5770(5) 0.7589(4) 0.4895(4) 0.0339(17) Uani 1 1 d . . . . .
F69 F 0.1850(4) 0.4068(6) 0.4365(5) 0.110(3) Uani 1 1 d . . . . .
F89 F 0.3676(6) 0.3158(5) 0.7453(4) 0.106(3) Uani 1 1 d . . . . .
F49 F 0.6681(6) 0.5926(5) 0.7950(3) 0.102(3) Uani 1 1 d . . . . .
C63 C 0.4129(5) 0.4858(5) 0.3642(4) 0.0318(16) Uani 1 1 d . . . . .
C20 C 0.4587(5) 0.6982(4) 0.4107(3) 0.0311(18) Uani 1 1 d . . . . .
C64 C 0.4577(5) 0.4382(5) 0.2671(4) 0.038(2) Uani 1 1 d . . . . .
C31 C 0.6053(6) 0.8196(6) 0.4619(5) 0.050(2) Uani 1 1 d . . . . .
H31 H 0.614200 0.821292 0.417340 0.061 Uiso 1 1 calc R U . . .
C9 C 0.6111(6) 0.6805(5) 0.3781(4) 0.0379(19) Uani 1 1 d . . . . .
C38 C 0.7914(4) 0.5161(5) 0.4921(4) 0.0349(17) Uani 1 1 d . . . . .
C12 C 0.8256(6) 0.6723(5) 0.1087(4) 0.040(2) Uani 1 1 d . . . . .
C6 C 0.8086(7) 0.6488(7) 0.2202(5) 0.059(3) Uani 1 1 d . . . . .
H6 H 0.859769 0.634404 0.221487 0.071 Uiso 1 1 calc R U . . .
C42 C 0.7234(5) 0.5532(5) 0.5815(4) 0.038(2) Uani 1 1 d . . . . .
C41 C 0.8071(6) 0.5696(6) 0.5860(5) 0.049(3) Uani 1 1 d . . . . .
H41 H 0.820832 0.606851 0.616969 0.059 Uiso 1 1 calc R U . . .
C8 C 0.6468(5) 0.6738(5) 0.3308(4) 0.0353(18) Uani 1 1 d . . . . .
C23 C 0.3172(6) 0.7231(6) 0.3621(5) 0.050(2) Uani 1 1 d . . . . .
H23 H 0.268213 0.731630 0.345483 0.061 Uiso 1 1 calc R U . . .
C62 C 0.4935(4) 0.4961(5) 0.3613(3) 0.0314(16) Uani 1 1 d . . . . .
C4 C 0.7017(6) 0.6889(5) 0.1606(4) 0.041(2) Uani 1 1 d . . . . .
H4 H 0.679369 0.701441 0.121192 0.049 Uiso 1 1 calc R U . . .
C7 C 0.7653(6) 0.6474(6) 0.2764(5) 0.048(2) Uani 1 1 d . . . . .
H7 H 0.786493 0.632190 0.315469 0.058 Uiso 1 1 calc R U . . .
C25 C 0.3965(5) 0.6670(5) 0.4387(5) 0.0372(19) Uani 1 1 d . . . . .
H25 H 0.402509 0.637736 0.474624 0.045 Uiso 1 1 calc R U . . .
C61 C 0.5152(4) 0.4925(4) 0.2906(3) 0.0331(16) Uani 1 1 d . . . . .
C77 C 0.5981(5) 0.4820(5) 0.2791(4) 0.0379(19) Uani 1 1 d . . . . .
H77A H 0.615293 0.440704 0.302058 0.057 Uiso 1 1 calc R U . . .
H77B H 0.626057 0.522643 0.294199 0.057 Uiso 1 1 calc R U . . .
H77C H 0.607109 0.475804 0.233447 0.057 Uiso 1 1 calc R U . . .
C2 C 0.6886(5) 0.6697(5) 0.2730(4) 0.0365(19) Uani 1 1 d . . . . .
C59 C 0.3955(6) 0.5514(5) 0.2645(4) 0.047(2) Uani 1 1 d . . . . .
H59A H 0.374132 0.552404 0.221002 0.056 Uiso 1 1 calc R U . . .
H59B H 0.370007 0.586993 0.290819 0.056 Uiso 1 1 calc R U . . .
C65 C 0.3750(4) 0.4873(5) 0.4207(4) 0.0338(17) Uani 1 1 d . . . . .
C45 C 0.6643(6) 0.5633(6) 0.6204(4) 0.047(2) Uani 1 1 d . . . . .
C58 C 0.3883(5) 0.4770(5) 0.2952(4) 0.0361(19) Uani 1 1 d . . . . .
H58 H 0.338592 0.453536 0.288917 0.043 Uiso 1 1 calc R U . . .
C81 C 0.3706(7) 0.6529(7) 0.6564(5) 0.061(3) Uani 1 1 d . . . . .
C13 C 0.8689(6) 0.6765(5) 0.0652(4) 0.040(2) Uani 1 1 d . . . . .
C15 C 0.8902(6) 0.7175(6) -0.0624(4) 0.048(2) Uani 1 1 d . . . . .
C44 C 0.8247(6) 0.5857(6) 0.5160(5) 0.053(3) Uani 1 1 d . . . . .
C75 C 0.4692(7) 0.3667(5) 0.2965(5) 0.049(2) Uani 1 1 d . . . . .
H75A H 0.517341 0.347473 0.282002 0.073 Uiso 1 1 calc R U . . .
H75B H 0.427972 0.336026 0.283455 0.073 Uiso 1 1 calc R U . . .
H75C H 0.469633 0.370799 0.342956 0.073 Uiso 1 1 calc R U . . .
C30 C 0.6203(7) 0.8770(6) 0.4990(5) 0.056(3) Uani 1 1 d . . . . .
H30 H 0.639494 0.918043 0.480020 0.068 Uiso 1 1 calc R U . . .
C56 C 0.7898(5) 0.5040(6) 0.4197(4) 0.041(2) Uani 1 1 d . . . . .
H56A H 0.766494 0.458967 0.410641 0.062 Uiso 1 1 calc R U . . .
H56B H 0.841460 0.504430 0.403102 0.062 Uiso 1 1 calc R U . . .
H56C H 0.760484 0.540822 0.399238 0.062 Uiso 1 1 calc R U . . .
C3 C 0.6580(6) 0.6890(5) 0.2147(4) 0.040(2) Uani 1 1 d . . . . .
H3 H 0.606555 0.702349 0.212254 0.048 Uiso 1 1 calc R U . . .
C78 C 0.3664(7) 0.5647(7) 0.7291(5) 0.055(3) Uani 1 1 d . . . . .
H78 H 0.343973 0.530126 0.759052 0.066 Uiso 1 1 calc R U . . .
C46 C 0.6713(6) 0.6013(7) 0.6867(4) 0.058(3) Uani 1 1 d . . . . .
C66 C 0.2887(5) 0.4798(6) 0.4228(4) 0.046(2) Uani 1 1 d . . . . .
C60 C 0.4810(7) 0.5623(5) 0.2636(4) 0.041(2) Uani 1 1 d . . . . .
H60A H 0.495390 0.602106 0.290673 0.050 Uiso 1 1 calc R U . . .
H60B H 0.498994 0.570880 0.219727 0.050 Uiso 1 1 calc R U . . .
C21 C 0.4504(6) 0.7420(5) 0.3588(4) 0.041(2) Uani 1 1 d . . . . .
H21 H 0.493156 0.763162 0.339798 0.050 Uiso 1 1 calc R U . . .
C40 C 0.8468(5) 0.4976(7) 0.5971(4) 0.056(3) Uani 1 1 d . . . . .
H40A H 0.901150 0.503396 0.606678 0.067 Uiso 1 1 calc R U . . .
H40B H 0.822537 0.471297 0.631952 0.067 Uiso 1 1 calc R U . . .
C32 C 1.0085(6) 0.7358(5) 0.0330(4) 0.045(2) Uani 1 1 d . . . . .
C39 C 0.8347(6) 0.4623(6) 0.5325(4) 0.049(2) Uani 1 1 d . . . . .
H39A H 0.804790 0.419268 0.537385 0.059 Uiso 1 1 calc R U . . .
H39B H 0.883579 0.450619 0.512432 0.059 Uiso 1 1 calc R U . . .
C67 C 0.2594(7) 0.4108(8) 0.4392(8) 0.073(4) Uani 1 1 d . . . . .
C16 C 0.8547(7) 0.6738(7) -0.1039(5) 0.054(3) Uani 1 1 d . . . . .
H16 H 0.854861 0.625354 -0.095647 0.064 Uiso 1 1 calc R U . . .
C22 C 0.3778(7) 0.7545(6) 0.3350(5) 0.052(2) Uani 1 1 d . . . . .
H22 H 0.371082 0.784784 0.299838 0.062 Uiso 1 1 calc R U . . .
C97 C 0.2554(6) 0.5742(6) 0.6463(6) 0.055(3) Uani 1 1 d . . . . .
H97A H 0.256936 0.598249 0.605273 0.082 Uiso 1 1 calc R U . . .
H97B H 0.203690 0.574654 0.662781 0.082 Uiso 1 1 calc R U . . .
H97C H 0.272026 0.526113 0.640666 0.082 Uiso 1 1 calc R U . . .
C17 C 0.8184(8) 0.6986(8) -0.1580(6) 0.075(4) Uani 1 1 d . . . . .
H17 H 0.795138 0.668043 -0.187559 0.090 Uiso 1 1 calc R U . . .
C28 C 0.5797(8) 0.8134(7) 0.5908(6) 0.071(4) Uani 1 1 d . . . . .
H28 H 0.571522 0.811180 0.635394 0.085 Uiso 1 1 calc R U . . .
C36 C 1.1391(8) 0.7678(8) 0.0301(6) 0.070(3) Uani 1 1 d . . . . .
H36 H 1.188711 0.760512 0.014419 0.084 Uiso 1 1 calc R U . . .
C47 C 0.6626(9) 0.5536(9) 0.7395(6) 0.072(4) Uani 1 1 d . . . . .
C29 C 0.6075(7) 0.8749(6) 0.5630(6) 0.064(3) Uani 1 1 d . . . . .
H29 H 0.617173 0.914470 0.588596 0.077 Uiso 1 1 calc R U . . .
C85 C 0.4437(6) 0.4698(6) 0.6598(4) 0.048(2) Uani 1 1 d . . . . .
C37 C 1.0803(7) 0.7265(6) 0.0101(5) 0.057(3) Uani 1 1 d . . . . .
H37 H 1.089574 0.690848 -0.020098 0.069 Uiso 1 1 calc R U . . .
C35 C 1.1245(10) 0.8200(7) 0.0734(6) 0.078(4) Uani 1 1 d . . . . .
H35 H 1.164879 0.848098 0.088146 0.094 Uiso 1 1 calc R U . . .
C57 C 0.7833(9) 0.6506(6) 0.4925(6) 0.074(4) Uani 1 1 d . . . . .
H57A H 0.787816 0.653888 0.446171 0.111 Uiso 1 1 calc R U . . .
H57B H 0.805627 0.691900 0.512129 0.111 Uiso 1 1 calc R U . . .
H57C H 0.729869 0.647635 0.504230 0.111 Uiso 1 1 calc R U . . .
C87 C 0.3700(10) 0.3680(7) 0.7021(8) 0.078(4) Uani 1 1 d . . . . .
C80 C 0.4224(9) 0.6766(7) 0.7067(7) 0.083(5) Uani 1 1 d . . . . .
H80A H 0.407132 0.722752 0.722842 0.099 Uiso 1 1 calc R U . . .
H80B H 0.474714 0.679583 0.690428 0.099 Uiso 1 1 calc R U . . .
C84 C 0.3101(8) 0.6126(7) 0.6956(7) 0.066(3) Uani 1 1 d . . . . .
C83 C 0.4125(7) 0.5336(5) 0.6728(4) 0.048(2) Uani 1 1 d . . . . .
C82 C 0.4135(6) 0.5900(6) 0.6273(4) 0.050(3) Uani 1 1 d . . . . .
C76 C 0.4558(6) 0.4298(6) 0.1946(4) 0.055(3) Uani 1 1 d . . . . .
H76A H 0.442653 0.474217 0.174882 0.082 Uiso 1 1 calc R U . . .
H76B H 0.418116 0.394861 0.183039 0.082 Uiso 1 1 calc R U . . .
H76C H 0.505579 0.414950 0.179503 0.082 Uiso 1 1 calc R U . . .
C27 C 0.5648(7) 0.7578(7) 0.5542(5) 0.057(3) Uani 1 1 d . . . . .
H27 H 0.545375 0.716936 0.573403 0.069 Uiso 1 1 calc R U . . .
C86 C 0.4382(7) 0.4135(7) 0.7102(5) 0.058(3) Uani 1 1 d . . . . .
C33 C 0.9960(9) 0.7896(7) 0.0771(6) 0.079(5) Uani 1 1 d . . . . .
H33 H 0.947070 0.796610 0.094360 0.095 Uiso 1 1 calc R U . . .
C55 C 0.9103(8) 0.5941(10) 0.5035(7) 0.095(6) Uani 1 1 d . . . . .
H55A H 0.937681 0.555843 0.523588 0.143 Uiso 1 1 calc R U . . .
H55B H 0.927620 0.638267 0.521352 0.143 Uiso 1 1 calc R U . . .
H55C H 0.919653 0.593620 0.457559 0.143 Uiso 1 1 calc R U . . .
C96 C 0.3438(10) 0.7029(8) 0.6087(7) 0.087(5) Uani 1 1 d . . . . .
H96A H 0.304828 0.732456 0.627485 0.131 Uiso 1 1 calc R U . . .
H96B H 0.322643 0.677761 0.572264 0.131 Uiso 1 1 calc R U . . .
H96C H 0.386080 0.731633 0.594373 0.131 Uiso 1 1 calc R U . . .
C34 C 1.0544(11) 0.8318(8) 0.0950(7) 0.096(6) Uani 1 1 d . . . . .
H34 H 1.045297 0.869567 0.122955 0.116 Uiso 1 1 calc R U . . .
C79 C 0.4161(11) 0.6208(8) 0.7598(6) 0.087(5) Uani 1 1 d . . . . .
H79A H 0.466274 0.602134 0.771226 0.104 Uiso 1 1 calc R U . . .
H79B H 0.391871 0.640026 0.798397 0.104 Uiso 1 1 calc R U . . .
C95 C 0.2605(8) 0.6555(8) 0.7357(6) 0.076(4) Uani 1 1 d . . . . .
H95A H 0.287727 0.669779 0.774032 0.114 Uiso 1 1 calc R U . . .
H95B H 0.215833 0.628611 0.747752 0.114 Uiso 1 1 calc R U . . .
H95C H 0.244769 0.696765 0.711849 0.114 Uiso 1 1 calc R U . . .
C18 C 0.8847(16) 0.7868(8) -0.0717(8) 0.128(9) Uani 1 1 d . . . . .
H18 H 0.908603 0.817938 -0.043047 0.154 Uiso 1 1 calc R U . . .
C10 C 0.8176(15) 0.7716(11) -0.1672(8) 0.125(8) Uani 1 1 d . . . . .
H10 H 0.797816 0.790720 -0.205356 0.150 Uiso 1 1 calc R U . . .
C1 C 0.844(2) 0.8122(11) -0.1228(10) 0.165(13) Uani 1 1 d . . . . .
H1 H 0.835437 0.860653 -0.125794 0.198 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O54 2.420(5) . ?
Eu1 O19 2.374(6) 2_665 ?
Eu1 O11 2.369(6) . ?
Eu1 O73 2.355(5) . ?
Eu1 O74 2.465(4) . ?
Eu1 O53 2.369(6) . ?
Eu1 O94 2.405(7) . ?
Eu1 O93 2.341(6) . ?
P10 O11 1.474(6) . ?
P10 C26 1.797(9) . ?
P10 C20 1.802(8) . ?
P10 C9 1.760(9) . ?
P14 O19 1.479(6) . ?
P14 C13 1.744(9) . ?
P14 C15 1.802(11) . ?
P14 C32 1.778(10) . ?
O54 C43 1.238(9) . ?
F71 C66 1.348(10) . ?
O73 C65 1.283(9) . ?
F91 C86 1.386(13) . ?
F72 C66 1.391(12) . ?
O74 C62 1.229(9) . ?
F48 C47 1.227(16) . ?
F88 C87 1.278(16) . ?
F51 C46 1.360(14) . ?
F92 C86 1.379(15) . ?
O53 C45 1.300(12) . ?
O94 C82 1.211(11) . ?
F50 C47 1.314(18) . ?
O93 C85 1.294(12) . ?
F68 C67 1.339(16) . ?
F90 C87 1.422(18) . ?
C43 C38 1.507(11) . ?
C43 C42 1.442(11) . ?
F52 C46 1.419(15) . ?
C24 H24 0.9500 . ?
C24 C23 1.380(14) . ?
C24 C25 1.386(14) . ?
F70 C67 1.334(18) . ?
C5 C12 1.417(13) . ?
C5 C6 1.410(14) . ?
C5 C4 1.380(15) . ?
C26 C31 1.400(14) . ?
C26 C27 1.378(13) . ?
F69 C67 1.322(14) . ?
F89 C87 1.356(16) . ?
F49 C47 1.394(15) . ?
C63 C62 1.444(11) . ?
C63 C65 1.366(11) . ?
C63 C58 1.524(10) . ?
C20 C25 1.388(12) . ?
C20 C21 1.386(12) . ?
C64 C61 1.544(12) . ?
C64 C58 1.557(13) . ?
C64 C75 1.524(14) . ?
C64 C76 1.534(11) . ?
C31 H31 0.9500 . ?
C31 C30 1.381(14) . ?
C9 C8 1.187(12) . ?
C38 C44 1.552(13) . ?
C38 C56 1.540(10) . ?
C38 C39 1.545(14) . ?
C12 C13 1.197(13) . ?
C6 H6 0.9500 . ?
C6 C7 1.409(14) . ?
C42 C41 1.520(13) . ?
C42 C45 1.345(13) . ?
C41 H41 1.0000 . ?
C41 C44 1.536(15) . ?
C41 C40 1.574(16) . ?
C8 C2 1.426(12) . ?
C23 H23 0.9500 . ?
C23 C22 1.360(16) . ?
C62 C61 1.537(9) . ?
C4 H4 0.9500 . ?
C4 C3 1.376(12) . ?
C7 H7 0.9500 . ?
C7 C2 1.428(14) . ?
C25 H25 0.9500 . ?
C61 C77 1.504(12) . ?
C61 C60 1.582(12) . ?
C77 H77A 0.9800 . ?
C77 H77B 0.9800 . ?
C77 H77C 0.9800 . ?
C2 C3 1.389(13) . ?
C59 H59A 0.9900 . ?
C59 H59B 0.9900 . ?
C59 C58 1.579(14) . ?
C59 C60 1.531(16) . ?
C65 C66 1.537(12) . ?
C45 C46 1.580(12) . ?
C58 H58 1.0000 . ?
C81 C80 1.47(2) . ?
C81 C84 1.559(16) . ?
C81 C82 1.557(16) . ?
C81 C96 1.470(18) . ?
C15 C16 1.368(16) . ?
C15 C18 1.353(18) . ?
C44 C57 1.534(18) . ?
C44 C55 1.549(16) . ?
C75 H75A 0.9800 . ?
C75 H75B 0.9800 . ?
C75 H75C 0.9800 . ?
C30 H30 0.9500 . ?
C30 C29 1.365(17) . ?
C56 H56A 0.9800 . ?
C56 H56B 0.9800 . ?
C56 H56C 0.9800 . ?
C3 H3 0.9500 . ?
C78 H78 1.0000 . ?
C78 C84 1.533(19) . ?
C78 C83 1.558(14) . ?
C78 C79 1.538(18) . ?
C46 C47 1.448(19) . ?
C66 C67 1.469(18) . ?
C60 H60A 0.9900 . ?
C60 H60B 0.9900 . ?
C21 H21 0.9500 . ?
C21 C22 1.402(14) . ?
C40 H40A 0.9900 . ?
C40 H40B 0.9900 . ?
C40 C39 1.536(12) . ?
C32 C37 1.373(16) . ?
C32 C33 1.408(13) . ?
C39 H39A 0.9900 . ?
C39 H39B 0.9900 . ?
C16 H16 0.9500 . ?
C16 C17 1.393(16) . ?
C22 H22 0.9500 . ?
C97 H97A 0.9800 . ?
C97 H97B 0.9800 . ?
C97 H97C 0.9800 . ?
C97 C84 1.602(19) . ?
C17 H17 0.9500 . ?
C17 C10 1.42(3) . ?
C28 H28 0.9500 . ?
C28 C29 1.411(19) . ?
C28 C27 1.345(16) . ?
C36 H36 0.9500 . ?
C36 C37 1.378(16) . ?
C36 C35 1.382(19) . ?
C29 H29 0.9500 . ?
C85 C83 1.377(15) . ?
C85 C86 1.520(15) . ?
C37 H37 0.9500 . ?
C35 H35 0.9500 . ?
C35 C34 1.34(2) . ?
C57 H57A 0.9800 . ?
C57 H57B 0.9800 . ?
C57 H57C 0.9800 . ?
C87 C86 1.51(2) . ?
C80 H80A 0.9900 . ?
C80 H80B 0.9900 . ?
C80 C79 1.56(2) . ?
C84 C95 1.473(17) . ?
C83 C82 1.449(14) . ?
C76 H76A 0.9800 . ?
C76 H76B 0.9800 . ?
C76 H76C 0.9800 . ?
C27 H27 0.9500 . ?
C33 H33 0.9500 . ?
C33 C34 1.371(19) . ?
C55 H55A 0.9800 . ?
C55 H55B 0.9800 . ?
C55 H55C 0.9800 . ?
C96 H96A 0.9800 . ?
C96 H96B 0.9800 . ?
C96 H96C 0.9800 . ?
C34 H34 0.9500 . ?
C79 H79A 0.9900 . ?
C79 H79B 0.9900 . ?
C95 H95A 0.9800 . ?
C95 H95B 0.9800 . ?
C95 H95C 0.9800 . ?
C18 H18 0.9500 . ?
C18 C1 1.38(3) . ?
C10 H10 0.9500 . ?
C10 C1 1.31(3) . ?
C1 H1 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O54 Eu1 O74 72.84(16) . . ?
O19 Eu1 O54 75.7(2) 2_665 . ?
O19 Eu1 O74 73.44(19) 2_665 . ?
O19 Eu1 O94 141.8(2) 2_665 . ?
O11 Eu1 O54 81.1(2) . . ?
O11 Eu1 O19 141.4(2) . 2_665 ?
O11 Eu1 O74 70.4(2) . . ?
O11 Eu1 O94 72.3(2) . . ?
O73 Eu1 O54 142.48(17) . . ?
O73 Eu1 O19 81.3(2) . 2_665 ?
O73 Eu1 O11 99.9(2) . . ?
O73 Eu1 O74 72.36(17) . . ?
O73 Eu1 O53 145.2(2) . . ?
O73 Eu1 O94 73.1(2) . . ?
O53 Eu1 O54 72.3(2) . . ?
O53 Eu1 O19 119.6(2) . 2_665 ?
O53 Eu1 O11 80.8(3) . . ?
O53 Eu1 O74 137.4(2) . . ?
O53 Eu1 O94 74.1(2) . . ?
O94 Eu1 O54 139.8(2) . . ?
O94 Eu1 O74 122.6(2) . . ?
O93 Eu1 O54 115.7(2) . . ?
O93 Eu1 O19 76.8(2) . 2_665 ?
O93 Eu1 O11 141.7(2) . . ?
O93 Eu1 O73 86.7(2) . . ?
O93 Eu1 O74 145.7(2) . . ?
O93 Eu1 O53 73.2(3) . . ?
O93 Eu1 O94 73.8(3) . . ?
O11 P10 C26 109.8(4) . . ?
O11 P10 C20 113.8(4) . . ?
O11 P10 C9 113.8(4) . . ?
C26 P10 C20 108.3(4) . . ?
C9 P10 C26 106.6(4) . . ?
C9 P10 C20 104.1(4) . . ?
O19 P14 C13 113.1(4) . . ?
O19 P14 C15 111.0(4) . . ?
O19 P14 C32 111.7(4) . . ?
C13 P14 C15 105.5(5) . . ?
C13 P14 C32 105.8(4) . . ?
C32 P14 C15 109.5(5) . . ?
C43 O54 Eu1 130.6(5) . . ?
P14 O19 Eu1 145.3(4) . 2_664 ?
P10 O11 Eu1 156.9(4) . . ?
C65 O73 Eu1 137.3(5) . . ?
C62 O74 Eu1 131.4(5) . . ?
C45 O53 Eu1 135.0(5) . . ?
C82 O94 Eu1 135.6(7) . . ?
C85 O93 Eu1 131.5(7) . . ?
O54 C43 C38 124.4(7) . . ?
O54 C43 C42 130.1(7) . . ?
C42 C43 C38 105.3(7) . . ?
C23 C24 H24 120.0 . . ?
C23 C24 C25 120.1(10) . . ?
C25 C24 H24 120.0 . . ?
C6 C5 C12 116.8(10) . . ?
C4 C5 C12 124.4(9) . . ?
C4 C5 C6 118.7(9) . . ?
C31 C26 P10 123.5(7) . . ?
C27 C26 P10 117.9(8) . . ?
C27 C26 C31 118.6(9) . . ?
C62 C63 C58 105.0(7) . . ?
C65 C63 C62 121.4(7) . . ?
C65 C63 C58 133.6(8) . . ?
C25 C20 P10 118.9(6) . . ?
C21 C20 P10 120.2(7) . . ?
C21 C20 C25 120.8(8) . . ?
C61 C64 C58 94.2(7) . . ?
C75 C64 C61 113.3(7) . . ?
C75 C64 C58 112.8(8) . . ?
C75 C64 C76 108.1(8) . . ?
C76 C64 C61 113.8(8) . . ?
C76 C64 C58 114.3(8) . . ?
C26 C31 H31 119.8 . . ?
C30 C31 C26 120.3(10) . . ?
C30 C31 H31 119.8 . . ?
C8 C9 P10 173.3(9) . . ?
C43 C38 C44 101.1(7) . . ?
C43 C38 C56 113.2(6) . . ?
C43 C38 C39 104.0(7) . . ?
C56 C38 C44 117.3(8) . . ?
C56 C38 C39 116.8(8) . . ?
C39 C38 C44 102.3(8) . . ?
C13 C12 C5 176.0(11) . . ?
C5 C6 H6 119.5 . . ?
C7 C6 C5 121.0(10) . . ?
C7 C6 H6 119.5 . . ?
C43 C42 C41 105.5(7) . . ?
C45 C42 C43 120.6(8) . . ?
C45 C42 C41 133.9(8) . . ?
C42 C41 H41 115.3 . . ?
C42 C41 C44 100.4(8) . . ?
C42 C41 C40 105.3(9) . . ?
C44 C41 H41 115.3 . . ?
C44 C41 C40 103.3(8) . . ?
C40 C41 H41 115.3 . . ?
C9 C8 C2 176.8(10) . . ?
C24 C23 H23 119.5 . . ?
C22 C23 C24 121.1(10) . . ?
C22 C23 H23 119.5 . . ?
O74 C62 C63 130.1(6) . . ?
O74 C62 C61 123.5(7) . . ?
C63 C62 C61 106.4(6) . . ?
C5 C4 H4 119.2 . . ?
C3 C4 C5 121.7(9) . . ?
C3 C4 H4 119.2 . . ?
C6 C7 H7 121.0 . . ?
C6 C7 C2 118.1(9) . . ?
C2 C7 H7 121.0 . . ?
C24 C25 C20 119.1(9) . . ?
C24 C25 H25 120.5 . . ?
C20 C25 H25 120.5 . . ?
C64 C61 C60 102.0(7) . . ?
C62 C61 C64 100.0(6) . . ?
C62 C61 C60 102.3(7) . . ?
C77 C61 C64 120.2(7) . . ?
C77 C61 C62 114.1(6) . . ?
C77 C61 C60 115.6(8) . . ?
C61 C77 H77A 109.5 . . ?
C61 C77 H77B 109.5 . . ?
C61 C77 H77C 109.5 . . ?
H77A C77 H77B 109.5 . . ?
H77A C77 H77C 109.5 . . ?
H77B C77 H77C 109.5 . . ?
C8 C2 C7 117.9(9) . . ?
C3 C2 C8 122.3(9) . . ?
C3 C2 C7 119.8(8) . . ?
H59A C59 H59B 109.2 . . ?
C58 C59 H59A 111.4 . . ?
C58 C59 H59B 111.4 . . ?
C60 C59 H59A 111.4 . . ?
C60 C59 H59B 111.4 . . ?
C60 C59 C58 102.0(7) . . ?
O73 C65 C63 126.8(8) . . ?
O73 C65 C66 112.3(7) . . ?
C63 C65 C66 120.9(7) . . ?
O53 C45 C42 127.5(8) . . ?
O53 C45 C46 109.6(8) . . ?
C42 C45 C46 122.9(9) . . ?
C63 C58 C64 100.9(6) . . ?
C63 C58 C59 105.4(7) . . ?
C63 C58 H58 115.4 . . ?
C64 C58 C59 102.6(8) . . ?
C64 C58 H58 115.4 . . ?
C59 C58 H58 115.4 . . ?
C80 C81 C84 101.8(10) . . ?
C80 C81 C82 102.6(10) . . ?
C82 C81 C84 99.0(10) . . ?
C96 C81 C80 119.2(14) . . ?
C96 C81 C84 117.7(12) . . ?
C96 C81 C82 113.5(10) . . ?
C12 C13 P14 175.9(10) . . ?
C16 C15 P14 117.3(8) . . ?
C18 C15 P14 123.6(11) . . ?
C18 C15 C16 118.9(12) . . ?
C41 C44 C38 93.3(8) . . ?
C41 C44 C55 112.6(10) . . ?
C57 C44 C38 114.8(9) . . ?
C57 C44 C41 112.1(10) . . ?
C57 C44 C55 109.2(11) . . ?
C55 C44 C38 114.1(10) . . ?
C64 C75 H75A 109.5 . . ?
C64 C75 H75B 109.5 . . ?
C64 C75 H75C 109.5 . . ?
H75A C75 H75B 109.5 . . ?
H75A C75 H75C 109.5 . . ?
H75B C75 H75C 109.5 . . ?
C31 C30 H30 119.9 . . ?
C29 C30 C31 120.1(11) . . ?
C29 C30 H30 119.9 . . ?
C38 C56 H56A 109.5 . . ?
C38 C56 H56B 109.5 . . ?
C38 C56 H56C 109.5 . . ?
H56A C56 H56B 109.5 . . ?
H56A C56 H56C 109.5 . . ?
H56B C56 H56C 109.5 . . ?
C4 C3 C2 120.6(9) . . ?
C4 C3 H3 119.7 . . ?
C2 C3 H3 119.7 . . ?
C84 C78 H78 115.6 . . ?
C84 C78 C83 103.0(9) . . ?
C84 C78 C79 98.1(12) . . ?
C83 C78 H78 115.6 . . ?
C79 C78 H78 115.6 . . ?
C79 C78 C83 106.9(10) . . ?
F51 C46 F52 103.1(11) . . ?
F51 C46 C45 112.5(9) . . ?
F51 C46 C47 111.3(10) . . ?
F52 C46 C45 110.8(8) . . ?
F52 C46 C47 106.6(10) . . ?
C47 C46 C45 111.9(11) . . ?
F71 C66 F72 104.6(8) . . ?
F71 C66 C65 113.0(7) . . ?
F71 C66 C67 108.0(10) . . ?
F72 C66 C65 109.9(8) . . ?
F72 C66 C67 103.9(10) . . ?
C67 C66 C65 116.4(9) . . ?
C61 C60 H60A 110.7 . . ?
C61 C60 H60B 110.7 . . ?
C59 C60 C61 105.1(8) . . ?
C59 C60 H60A 110.7 . . ?
C59 C60 H60B 110.7 . . ?
H60A C60 H60B 108.8 . . ?
C20 C21 H21 120.5 . . ?
C20 C21 C22 118.9(9) . . ?
C22 C21 H21 120.5 . . ?
C41 C40 H40A 111.5 . . ?
C41 C40 H40B 111.5 . . ?
H40A C40 H40B 109.3 . . ?
C39 C40 C41 101.3(8) . . ?
C39 C40 H40A 111.5 . . ?
C39 C40 H40B 111.5 . . ?
C37 C32 P14 117.9(7) . . ?
C37 C32 C33 118.3(10) . . ?
C33 C32 P14 123.9(9) . . ?
C38 C39 H39A 110.7 . . ?
C38 C39 H39B 110.7 . . ?
C40 C39 C38 105.0(8) . . ?
C40 C39 H39A 110.7 . . ?
C40 C39 H39B 110.7 . . ?
H39A C39 H39B 108.8 . . ?
F68 C67 C66 111.1(12) . . ?
F70 C67 F68 108.7(12) . . ?
F70 C67 C66 108.5(11) . . ?
F69 C67 F68 107.8(12) . . ?
F69 C67 F70 107.3(14) . . ?
F69 C67 C66 113.3(12) . . ?
C15 C16 H16 119.2 . . ?
C15 C16 C17 121.5(12) . . ?
C17 C16 H16 119.2 . . ?
C23 C22 C21 120.0(9) . . ?
C23 C22 H22 120.0 . . ?
C21 C22 H22 120.0 . . ?
H97A C97 H97B 109.5 . . ?
H97A C97 H97C 109.5 . . ?
H97B C97 H97C 109.5 . . ?
C84 C97 H97A 109.5 . . ?
C84 C97 H97B 109.5 . . ?
C84 C97 H97C 109.5 . . ?
C16 C17 H17 121.4 . . ?
C16 C17 C10 117.1(15) . . ?
C10 C17 H17 121.4 . . ?
C29 C28 H28 120.0 . . ?
C27 C28 H28 120.0 . . ?
C27 C28 C29 120.1(11) . . ?
C37 C36 H36 120.6 . . ?
C37 C36 C35 118.7(13) . . ?
C35 C36 H36 120.6 . . ?
F48 C47 F50 112.8(15) . . ?
F48 C47 F49 109.5(11) . . ?
F48 C47 C46 117.7(12) . . ?
F50 C47 F49 105.8(11) . . ?
F50 C47 C46 103.1(12) . . ?
F49 C47 C46 107.0(12) . . ?
C30 C29 C28 119.4(10) . . ?
C30 C29 H29 120.3 . . ?
C28 C29 H29 120.3 . . ?
O93 C85 C83 129.5(9) . . ?
O93 C85 C86 112.1(9) . . ?
C83 C85 C86 118.3(9) . . ?
C32 C37 C36 121.2(10) . . ?
C32 C37 H37 119.4 . . ?
C36 C37 H37 119.4 . . ?
C36 C35 H35 119.3 . . ?
C34 C35 C36 121.3(13) . . ?
C34 C35 H35 119.3 . . ?
C44 C57 H57A 109.5 . . ?
C44 C57 H57B 109.5 . . ?
C44 C57 H57C 109.5 . . ?
H57A C57 H57B 109.5 . . ?
H57A C57 H57C 109.5 . . ?
H57B C57 H57C 109.5 . . ?
F88 C87 F90 105.4(12) . . ?
F88 C87 F89 110.6(12) . . ?
F88 C87 C86 116.2(14) . . ?
F90 C87 C86 107.1(11) . . ?
F89 C87 F90 104.0(14) . . ?
F89 C87 C86 112.4(11) . . ?
C81 C80 H80A 110.8 . . ?
C81 C80 H80B 110.8 . . ?
C81 C80 C79 104.8(10) . . ?
H80A C80 H80B 108.9 . . ?
C79 C80 H80A 110.8 . . ?
C79 C80 H80B 110.8 . . ?
C81 C84 C97 107.8(11) . . ?
C78 C84 C81 95.5(10) . . ?
C78 C84 C97 114.4(11) . . ?
C95 C84 C81 115.7(11) . . ?
C95 C84 C78 117.8(12) . . ?
C95 C84 C97 105.5(11) . . ?
C85 C83 C78 134.8(9) . . ?
C85 C83 C82 122.4(8) . . ?
C82 C83 C78 102.6(9) . . ?
O94 C82 C81 126.4(10) . . ?
O94 C82 C83 125.0(10) . . ?
C83 C82 C81 108.6(8) . . ?
C64 C76 H76A 109.5 . . ?
C64 C76 H76B 109.5 . . ?
C64 C76 H76C 109.5 . . ?
H76A C76 H76B 109.5 . . ?
H76A C76 H76C 109.5 . . ?
H76B C76 H76C 109.5 . . ?
C26 C27 H27 119.3 . . ?
C28 C27 C26 121.5(12) . . ?
C28 C27 H27 119.3 . . ?
F91 C86 C85 113.8(10) . . ?
F91 C86 C87 108.0(11) . . ?
F92 C86 F91 108.1(9) . . ?
F92 C86 C85 110.7(9) . . ?
F92 C86 C87 102.6(11) . . ?
C87 C86 C85 112.9(10) . . ?
C32 C33 H33 120.0 . . ?
C34 C33 C32 120.0(13) . . ?
C34 C33 H33 120.0 . . ?
C44 C55 H55A 109.5 . . ?
C44 C55 H55B 109.5 . . ?
C44 C55 H55C 109.5 . . ?
H55A C55 H55B 109.5 . . ?
H55A C55 H55C 109.5 . . ?
H55B C55 H55C 109.5 . . ?
C81 C96 H96A 109.5 . . ?
C81 C96 H96B 109.5 . . ?
C81 C96 H96C 109.5 . . ?
H96A C96 H96B 109.5 . . ?
H96A C96 H96C 109.5 . . ?
H96B C96 H96C 109.5 . . ?
C35 C34 C33 120.4(13) . . ?
C35 C34 H34 119.8 . . ?
C33 C34 H34 119.8 . . ?
C78 C79 C80 103.1(11) . . ?
C78 C79 H79A 111.1 . . ?
C78 C79 H79B 111.1 . . ?
C80 C79 H79A 111.1 . . ?
C80 C79 H79B 111.1 . . ?
H79A C79 H79B 109.1 . . ?
C84 C95 H95A 109.5 . . ?
C84 C95 H95B 109.5 . . ?
C84 C95 H95C 109.5 . . ?
H95A C95 H95B 109.5 . . ?
H95A C95 H95C 109.5 . . ?
H95B C95 H95C 109.5 . . ?
C15 C18 H18 120.0 . . ?
C15 C18 C1 119.9(18) . . ?
C1 C18 H18 120.0 . . ?
C17 C10 H10 120.2 . . ?
C1 C10 C17 119.5(16) . . ?
C1 C10 H10 120.2 . . ?
C18 C1 H1 119.0 . . ?
C10 C1 C18 122.1(19) . . ?
C10 C1 H1 119.0 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Eu1 O54 C43 C38 -163.6(6) . . . . ?
Eu1 O54 C43 C42 20.2(13) . . . . ?
Eu1 O73 C65 C63 -4.1(15) . . . . ?
Eu1 O73 C65 C66 177.4(6) . . . . ?
Eu1 O74 C62 C63 8.5(14) . . . . ?
Eu1 O74 C62 C61 -174.4(6) . . . . ?
Eu1 O53 C45 C42 -10.0(19) . . . . ?
Eu1 O53 C45 C46 167.5(8) . . . . ?
Eu1 O94 C82 C81 171.6(9) . . . . ?
Eu1 O94 C82 C83 -7.7(19) . . . . ?
Eu1 O93 C85 C83 12.9(17) . . . . ?
Eu1 O93 C85 C86 -168.2(7) . . . . ?
P10 C26 C31 C30 176.3(9) . . . . ?
P10 C26 C27 C28 -176.9(11) . . . . ?
P10 C20 C25 C24 179.0(7) . . . . ?
P10 C20 C21 C22 -177.7(7) . . . . ?
P14 C15 C16 C17 -178.9(9) . . . . ?
P14 C15 C18 C1 -176(2) . . . . ?
P14 C32 C37 C36 -179.1(10) . . . . ?
P14 C32 C33 C34 -178.8(13) . . . . ?
O54 C43 C38 C44 149.4(8) . . . . ?
O54 C43 C38 C56 23.0(12) . . . . ?
O54 C43 C38 C39 -104.7(9) . . . . ?
O54 C43 C42 C41 175.4(9) . . . . ?
O54 C43 C42 C45 -2.8(15) . . . . ?
F71 C66 C67 F68 -169.5(10) . . . . ?
F71 C66 C67 F70 71.1(11) . . . . ?
F71 C66 C67 F69 -47.9(16) . . . . ?
O19 P14 C15 C16 32.5(10) . . . . ?
O19 P14 C15 C18 -151.9(16) . . . . ?
O19 P14 C32 C37 30.2(10) . . . . ?
O19 P14 C32 C33 -149.8(10) . . . . ?
O11 P10 C26 C31 155.7(8) . . . . ?
O11 P10 C26 C27 -27.8(9) . . . . ?
O11 P10 C20 C25 19.7(8) . . . . ?
O11 P10 C20 C21 -162.4(7) . . . . ?
O73 C65 C66 F71 152.6(8) . . . . ?
O73 C65 C66 F72 36.2(11) . . . . ?
O73 C65 C66 C67 -81.5(12) . . . . ?
F72 C66 C67 F68 -58.7(12) . . . . ?
F72 C66 C67 F70 -178.2(9) . . . . ?
F72 C66 C67 F69 62.8(15) . . . . ?
O74 C62 C61 C64 148.3(8) . . . . ?
O74 C62 C61 C77 18.7(12) . . . . ?
O74 C62 C61 C60 -106.9(9) . . . . ?
F88 C87 C86 F91 174.7(11) . . . . ?
F88 C87 C86 F92 -71.2(13) . . . . ?
F88 C87 C86 C85 47.9(16) . . . . ?
F51 C46 C47 F48 178.0(12) . . . . ?
F51 C46 C47 F50 -57.1(14) . . . . ?
F51 C46 C47 F49 54.3(15) . . . . ?
O53 C45 C46 F51 -160.5(12) . . . . ?
O53 C45 C46 F52 -45.6(14) . . . . ?
O53 C45 C46 C47 73.2(13) . . . . ?
O93 C85 C83 C78 175.6(12) . . . . ?
O93 C85 C83 C82 0(2) . . . . ?
O93 C85 C86 F91 149.8(10) . . . . ?
O93 C85 C86 F92 27.8(13) . . . . ?
O93 C85 C86 C87 -86.6(13) . . . . ?
F90 C87 C86 F91 57.2(14) . . . . ?
F90 C87 C86 F92 171.3(10) . . . . ?
F90 C87 C86 C85 -69.5(14) . . . . ?
C43 C38 C44 C41 53.2(8) . . . . ?
C43 C38 C44 C57 -63.0(10) . . . . ?
C43 C38 C44 C55 169.8(10) . . . . ?
C43 C38 C39 C40 -70.7(9) . . . . ?
C43 C42 C41 C44 36.2(10) . . . . ?
C43 C42 C41 C40 -70.8(9) . . . . ?
C43 C42 C45 O53 -3.2(18) . . . . ?
C43 C42 C45 C46 179.7(10) . . . . ?
F52 C46 C47 F48 66.2(15) . . . . ?
F52 C46 C47 F50 -168.9(10) . . . . ?
F52 C46 C47 F49 -57.5(13) . . . . ?
C24 C23 C22 C21 0.4(17) . . . . ?
C5 C6 C7 C2 -0.3(19) . . . . ?
C5 C4 C3 C2 -1.2(15) . . . . ?
C26 P10 O11 Eu1 152.9(9) . . . . ?
C26 P10 C20 C25 -102.6(7) . . . . ?
C26 P10 C20 C21 75.2(7) . . . . ?
C26 C31 C30 C29 -0.1(18) . . . . ?
F89 C87 C86 F91 -56.4(16) . . . . ?
F89 C87 C86 F92 57.6(15) . . . . ?
F89 C87 C86 C85 176.8(12) . . . . ?
C63 C62 C61 C64 -34.0(9) . . . . ?
C63 C62 C61 C77 -163.6(8) . . . . ?
C63 C62 C61 C60 70.8(9) . . . . ?
C63 C65 C66 F71 -26.0(14) . . . . ?
C63 C65 C66 F72 -142.4(9) . . . . ?
C63 C65 C66 C67 99.8(12) . . . . ?
C20 P10 O11 Eu1 31.3(11) . . . . ?
C20 P10 C26 C31 -79.4(9) . . . . ?
C20 P10 C26 C27 97.1(9) . . . . ?
C20 C21 C22 C23 -0.8(15) . . . . ?
C64 C61 C60 C59 32.4(8) . . . . ?
C31 C26 C27 C28 -0.3(18) . . . . ?
C31 C30 C29 C28 1(2) . . . . ?
C9 P10 O11 Eu1 -87.8(10) . . . . ?
C9 P10 C26 C31 32.0(10) . . . . ?
C9 P10 C26 C27 -151.5(9) . . . . ?
C9 P10 C20 C25 144.2(7) . . . . ?
C9 P10 C20 C21 -37.9(8) . . . . ?
C38 C43 C42 C41 -1.4(10) . . . . ?
C38 C43 C42 C45 -179.5(9) . . . . ?
C12 C5 C6 C7 178.5(11) . . . . ?
C12 C5 C4 C3 -177.8(9) . . . . ?
C6 C5 C4 C3 3.6(16) . . . . ?
C6 C7 C2 C8 -174.8(10) . . . . ?
C6 C7 C2 C3 2.7(16) . . . . ?
C42 C43 C38 C44 -33.6(9) . . . . ?
C42 C43 C38 C56 -160.0(8) . . . . ?
C42 C43 C38 C39 72.3(8) . . . . ?
C42 C41 C44 C38 -53.6(9) . . . . ?
C42 C41 C44 C57 64.9(10) . . . . ?
C42 C41 C44 C55 -171.5(11) . . . . ?
C42 C41 C40 C39 69.1(10) . . . . ?
C42 C45 C46 F51 17.1(18) . . . . ?
C42 C45 C46 F52 132.0(12) . . . . ?
C42 C45 C46 C47 -109.2(14) . . . . ?
C41 C42 C45 O53 179.3(12) . . . . ?
C41 C42 C45 C46 2(2) . . . . ?
C41 C40 C39 C38 0.5(10) . . . . ?
C8 C2 C3 C4 175.4(9) . . . . ?
C23 C24 C25 C20 -1.5(14) . . . . ?
C62 C63 C65 O73 -1.4(15) . . . . ?
C62 C63 C65 C66 177.0(9) . . . . ?
C62 C63 C58 C64 34.6(9) . . . . ?
C62 C63 C58 C59 -71.9(9) . . . . ?
C62 C61 C60 C59 -70.8(8) . . . . ?
C4 C5 C6 C7 -2.8(18) . . . . ?
C7 C2 C3 C4 -2.0(14) . . . . ?
C25 C24 C23 C22 0.8(16) . . . . ?
C25 C20 C21 C22 0.1(13) . . . . ?
C61 C64 C58 C63 -53.5(8) . . . . ?
C61 C64 C58 C59 55.2(7) . . . . ?
C77 C61 C60 C59 164.6(7) . . . . ?
C65 C63 C62 O74 -1.3(16) . . . . ?
C65 C63 C62 C61 -178.8(8) . . . . ?
C65 C63 C58 C64 -147.4(10) . . . . ?
C65 C63 C58 C59 106.1(12) . . . . ?
C65 C66 C67 F68 62.2(14) . . . . ?
C65 C66 C67 F70 -57.2(13) . . . . ?
C65 C66 C67 F69 -176.3(11) . . . . ?
C45 C42 C41 C44 -146.0(12) . . . . ?
C45 C42 C41 C40 107.0(13) . . . . ?
C45 C46 C47 F48 -55.1(17) . . . . ?
C45 C46 C47 F50 69.9(13) . . . . ?
C45 C46 C47 F49 -178.8(10) . . . . ?
C58 C63 C62 O74 176.9(9) . . . . ?
C58 C63 C62 C61 -0.5(9) . . . . ?
C58 C63 C65 O73 -179.1(9) . . . . ?
C58 C63 C65 C66 -0.6(16) . . . . ?
C58 C64 C61 C62 52.4(7) . . . . ?
C58 C64 C61 C77 177.9(7) . . . . ?
C58 C64 C61 C60 -52.7(7) . . . . ?
C58 C59 C60 C61 2.5(8) . . . . ?
C81 C80 C79 C78 6.9(15) . . . . ?
C13 P14 O19 Eu1 -12.7(8) . . . 2_664 ?
C13 P14 C15 C16 -90.3(9) . . . . ?
C13 P14 C15 C18 85.3(17) . . . . ?
C13 P14 C32 C37 153.6(9) . . . . ?
C13 P14 C32 C33 -26.4(12) . . . . ?
C15 P14 O19 Eu1 -131.1(7) . . . 2_664 ?
C15 P14 C32 C37 -93.1(9) . . . . ?
C15 P14 C32 C33 86.9(11) . . . . ?
C15 C16 C17 C10 -2(2) . . . . ?
C15 C18 C1 C10 -8(5) . . . . ?
C44 C38 C39 C40 34.2(9) . . . . ?
C44 C41 C40 C39 -35.7(9) . . . . ?
C75 C64 C61 C62 -64.7(9) . . . . ?
C75 C64 C61 C77 60.9(10) . . . . ?
C75 C64 C61 C60 -169.7(8) . . . . ?
C75 C64 C58 C63 64.0(9) . . . . ?
C75 C64 C58 C59 172.7(7) . . . . ?
C56 C38 C44 C41 176.8(8) . . . . ?
C56 C38 C44 C57 60.6(12) . . . . ?
C56 C38 C44 C55 -66.6(13) . . . . ?
C56 C38 C39 C40 163.8(8) . . . . ?
C78 C83 C82 O94 -179.7(11) . . . . ?
C78 C83 C82 C81 0.9(13) . . . . ?
C60 C59 C58 C63 68.7(8) . . . . ?
C60 C59 C58 C64 -36.5(8) . . . . ?
C21 C20 C25 C24 1.1(13) . . . . ?
C40 C41 C44 C38 55.0(8) . . . . ?
C40 C41 C44 C57 173.5(8) . . . . ?
C40 C41 C44 C55 -62.9(12) . . . . ?
C32 P14 O19 Eu1 106.5(7) . . . 2_664 ?
C32 P14 C15 C16 156.2(8) . . . . ?
C32 P14 C15 C18 -28.1(17) . . . . ?
C32 C33 C34 C35 -3(3) . . . . ?
C39 C38 C44 C41 -53.9(9) . . . . ?
C39 C38 C44 C57 -170.2(9) . . . . ?
C39 C38 C44 C55 62.6(12) . . . . ?
C16 C15 C18 C1 -1(3) . . . . ?
C16 C17 C10 C1 -6(3) . . . . ?
C17 C10 C1 C18 11(5) . . . . ?
C36 C35 C34 C33 3(3) . . . . ?
C29 C28 C27 C26 1(2) . . . . ?
C85 C83 C82 O94 -3(2) . . . . ?
C85 C83 C82 C81 177.7(11) . . . . ?
C37 C32 C33 C34 1(2) . . . . ?
C37 C36 C35 C34 -1(2) . . . . ?
C35 C36 C37 C32 -1(2) . . . . ?
C80 C81 C84 C78 -54.4(12) . . . . ?
C80 C81 C84 C97 -172.1(10) . . . . ?
C80 C81 C84 C95 70.1(15) . . . . ?
C80 C81 C82 O94 -108.4(13) . . . . ?
C80 C81 C82 C83 71.0(12) . . . . ?
C84 C81 C80 C79 29.2(13) . . . . ?
C84 C81 C82 O94 147.2(13) . . . . ?
C84 C81 C82 C83 -33.4(13) . . . . ?
C84 C78 C83 C85 -143.1(14) . . . . ?
C84 C78 C83 C82 33.0(12) . . . . ?
C84 C78 C79 C80 -40.6(13) . . . . ?
C83 C78 C84 C81 -52.4(11) . . . . ?
C83 C78 C84 C97 59.9(12) . . . . ?
C83 C78 C84 C95 -175.3(11) . . . . ?
C83 C78 C79 C80 65.7(14) . . . . ?
C83 C85 C86 F91 -31.1(16) . . . . ?
C83 C85 C86 F92 -153.1(10) . . . . ?
C83 C85 C86 C87 92.5(14) . . . . ?
C82 C81 C80 C79 -72.9(11) . . . . ?
C82 C81 C84 C78 50.7(11) . . . . ?
C82 C81 C84 C97 -67.1(11) . . . . ?
C82 C81 C84 C95 175.1(13) . . . . ?
C76 C64 C61 C62 171.3(8) . . . . ?
C76 C64 C61 C77 -63.1(10) . . . . ?
C76 C64 C61 C60 66.3(9) . . . . ?
C76 C64 C58 C63 -172.0(8) . . . . ?
C76 C64 C58 C59 -63.3(10) . . . . ?
C27 C26 C31 C30 -0.2(16) . . . . ?
C27 C28 C29 C30 -1(2) . . . . ?
C86 C85 C83 C78 -3(2) . . . . ?
C86 C85 C83 C82 -178.8(11) . . . . ?
C33 C32 C37 C36 0.8(18) . . . . ?
C96 C81 C80 C79 160.6(12) . . . . ?
C96 C81 C84 C78 173.4(12) . . . . ?
C96 C81 C84 C97 55.6(15) . . . . ?
C96 C81 C84 C95 -62.2(19) . . . . ?
C96 C81 C82 O94 22(2) . . . . ?
C96 C81 C82 C83 -159.0(13) . . . . ?
C79 C78 C84 C81 57.1(11) . . . . ?
C79 C78 C84 C97 169.4(9) . . . . ?
C79 C78 C84 C95 -65.7(14) . . . . ?
C79 C78 C83 C85 114.1(16) . . . . ?
C79 C78 C83 C82 -69.8(13) . . . . ?
C18 C15 C16 C17 5(2) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.391
_oxdiff_exptl_absorpt_empirical_full_min 0.683
_exptl_crystal_recrystallization_method 'Re-crystallisation from solvent'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_263-1_eu(+hfc)(p-dpeb)
_database_code_depnum_ccdc_archive 'CCDC 2213526'
loop_
_audit_author_name
_audit_author_address
'Makoto Tsurui'
;Hokkaido University
Japan
;
_audit_update_record             
;
2022-10-17 deposited with the CCDC.	2022-12-13 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C76 H66 Eu F21 O8 P2'
_chemical_formula_weight         1720.18

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      orthorhombic
_space_group_IT_number           19
_space_group_name_H-M_alt        'P 21 21 21'
_space_group_name_Hall           'P 2ac 2ab'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'

_cell_length_a                   17.6036(3)
_cell_length_b                   20.5986(5)
_cell_length_c                   20.7174(5)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     7512.3(3)
_cell_formula_units_Z            4
_cell_measurement_temperature    123(2)
_cell_measurement_reflns_used    23454
_cell_measurement_theta_min      2.2130
_cell_measurement_theta_max      27.6700

_exptl_crystal_description       block
_exptl_crystal_colour            'light yellow'
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.521
_exptl_crystal_F_000             3472
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.086
_exptl_crystal_size_mid          0.071
_exptl_crystal_size_min          0.039
_exptl_absorpt_coefficient_mu    0.984
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      123(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'XtaLAB Synergy R, DW system, HyPix'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            57738
_diffrn_reflns_av_unetI/netI     0.0553
_diffrn_reflns_av_R_equivalents  0.0494
_diffrn_reflns_limit_h_min       -22
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_k_min       -27
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_theta_min         2.201
_diffrn_reflns_theta_max         30.989
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.832
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.832
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.795
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             19014
_reflns_number_gt                13236
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.774
_reflns_Friedel_fraction_max     0.752
_reflns_Friedel_fraction_full    1.000

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1239P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_abs_structure_details 
;
 Flack x determined using 4899 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   0.000(6)
_chemical_absolute_configuration ad
_refine_ls_number_reflns         19014
_refine_ls_number_parameters     982
_refine_ls_number_restraints     204
_refine_ls_R_factor_all          0.0953
_refine_ls_R_factor_gt           0.0648
_refine_ls_wR_factor_ref         0.1828
_refine_ls_wR_factor_gt          0.1669
_refine_ls_goodness_of_fit_ref   0.998
_refine_ls_restrained_S_all      0.999
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu01 Eu 0.27631(2) 0.25474(2) 0.26119(2) 0.05402(14) Uani 1 1 d . . . . .
P002 P 0.70169(12) 0.67695(11) 0.40076(12) 0.0600(5) Uani 1 1 d . . . . .
P003 P 0.30116(13) 0.23997(13) 0.43678(12) 0.0680(6) Uani 1 1 d . . . . .
F00C F -0.0048(3) 0.1181(4) 0.2802(6) 0.123(3) Uani 1 1 d . . . . .
F00F F 0.0052(4) 0.2429(5) 0.2351(3) 0.104(2) Uani 1 1 d . . . . .
F00G F 0.0250(4) 0.2748(4) 0.3366(4) 0.107(2) Uani 1 1 d . . . . .
F00I F -0.1284(4) 0.1912(6) 0.2726(8) 0.175(5) Uani 1 1 d . . . . .
F00L F 0.1867(4) 0.3981(5) 0.0712(5) 0.117(3) Uani 1 1 d . . . . .
F00U F 0.0262(4) 0.1532(5) 0.3773(4) 0.115(3) Uani 1 1 d . . . . .
F00W F 0.1477(7) 0.4796(4) 0.1276(4) 0.132(3) Uani 1 1 d . . . . .
F1 F 0.3971(4) 0.4662(3) 0.2228(4) 0.0860(16) Uani 1 1 d . U . . .
F2 F 0.4777(8) 0.3885(7) 0.0895(5) 0.171(5) Uani 1 1 d . U . . .
F02M F 0.0165(8) 0.4765(10) 0.0663(8) 0.236(10) Uani 1 1 d . . . . .
F02R F 0.0454(10) 0.3989(9) 0.0163(7) 0.215(9) Uani 1 1 d . . . . .
F3 F 0.5114(4) 0.4396(4) 0.2012(5) 0.115(3) Uani 1 1 d . U . . .
F4 F 0.4628(19) 0.5157(10) 0.1031(10) 0.282(10) Uani 1 1 d D U . A -1
F5 F 0.3438(7) 0.3838(9) 0.1051(7) 0.196(6) Uani 1 1 d . U . . .
F6 F 0.3392(17) 0.5014(17) 0.1151(11) 0.403(18) Uani 1 1 d D U . A -1
F7 F 0.3849(15) 0.4644(12) 0.0271(6) 0.301(11) Uani 1 1 d D U . A -1
F007 F 0.0276(3) 0.4024(4) 0.1717(3) 0.0899(18) Uani 1 1 d . . . . .
F008 F 0.0786(4) 0.3224(3) 0.1201(3) 0.0912(18) Uani 1 1 d . . . . .
F012 F -0.1081(5) 0.2154(6) 0.3704(7) 0.164(5) Uani 1 1 d . . . . .
F018 F -0.1160(5) 0.2912(6) 0.2987(6) 0.144(4) Uani 1 1 d . . . . .
F019 F 0.1089(6) 0.4832(6) 0.0050(5) 0.139(3) Uani 1 1 d . . . . .
O1 O 0.6938(4) 0.7207(3) 0.3442(3) 0.0698(16) Uani 1 1 d . . . . .
O2 O 0.2802(4) 0.2174(3) 0.3712(3) 0.0687(14) Uani 1 1 d . . . . .
O3 O 0.1494(3) 0.2156(3) 0.2821(4) 0.0730(17) Uani 1 1 d . . . . .
O4 O 0.2788(3) 0.1367(2) 0.2585(3) 0.0613(13) Uani 1 1 d . . . . .
O5 O 0.3552(3) 0.3457(3) 0.2371(3) 0.0638(14) Uani 1 1 d . U . . .
O6 O 0.4079(3) 0.2245(3) 0.2776(3) 0.0601(14) Uani 1 1 d . U . . .
O7 O 0.1929(3) 0.3154(3) 0.1958(3) 0.0655(14) Uani 1 1 d . . . . .
O8 O 0.2379(3) 0.3444(3) 0.3287(3) 0.0673(15) Uani 1 1 d . . . . .
C00H C 0.6469(6) 0.6060(5) 0.3952(5) 0.072(2) Uani 1 1 d . . . . .
C00J C 0.5669(6) 0.4977(4) 0.3986(4) 0.064(2) Uani 1 1 d . . . . .
C00K C 0.1047(7) 0.4652(6) 0.2768(6) 0.087(3) Uani 1 1 d . . . . .
H00K H 0.082531 0.487787 0.238458 0.105 Uiso 1 1 calc R U . . .
C00N C 0.6717(5) 0.7149(4) 0.4734(4) 0.0572(18) Uani 1 1 d . . . . .
C00O C 0.0523(6) 0.4507(6) 0.3270(6) 0.087(3) Uani 1 1 d . . . . .
H00A H 0.019661 0.413396 0.315029 0.104 Uiso 1 1 calc R U . . .
H00B H 0.019548 0.488555 0.336553 0.104 Uiso 1 1 calc R U . . .
C00Q C 0.4670(4) 0.2473(4) 0.2556(4) 0.0607(16) Uani 1 1 d . U . . .
C00R C -0.0026(6) 0.2264(8) 0.3037(8) 0.104(5) Uani 1 1 d . . . . .
C00S C 0.1512(5) 0.3641(5) 0.2058(5) 0.066(2) Uani 1 1 d . . . . .
C00T C -0.0918(7) 0.2323(10) 0.3111(10) 0.125(6) Uani 1 1 d . . . . .
C00V C 0.4794(4) 0.3082(4) 0.2243(4) 0.0593(18) Uani 1 1 d . U . . .
C00X C 0.4755(5) 0.3899(4) 0.4164(4) 0.062(2) Uani 1 1 d . . . . .
C00Y C 0.4234(4) 0.3534(4) 0.2202(4) 0.0571(17) Uani 1 1 d . U . . .
C00Z C 0.2338(5) 0.0952(4) 0.2768(5) 0.063(2) Uani 1 1 d . . . . .
C1 C 0.4219(13) 0.4255(10) 0.1183(8) 0.137(5) Uani 1 1 d . U . . .
C01B C 0.2490(6) 0.0234(5) 0.2804(5) 0.074(2) Uani 1 1 d . . . . .
C01C C 0.5424(7) 0.3951(5) 0.4515(5) 0.078(3) Uani 1 1 d . . . . .
H01C H 0.557074 0.361696 0.480500 0.094 Uiso 1 1 calc R U . . .
C01D C 0.1036(6) 0.4335(8) 0.3865(6) 0.088(3) Uani 1 1 d . . . . .
H01A H 0.090733 0.460872 0.424213 0.106 Uiso 1 1 calc R U . . .
H01B H 0.098091 0.387225 0.398604 0.106 Uiso 1 1 calc R U . . .
C01E C 0.5449(5) 0.2133(5) 0.2603(6) 0.075(3) Uani 1 1 d . . . . .
C01F C 0.6352(8) 0.7781(7) 0.5871(6) 0.098(4) Uani 1 1 d . . . . .
H01F H 0.622764 0.799529 0.626323 0.118 Uiso 1 1 calc R U . . .
C01G C 0.0958(6) 0.3791(5) 0.1505(5) 0.072(2) Uani 1 1 d . . . . .
C01H C 0.2436(7) 0.4565(6) 0.4138(7) 0.092(4) Uani 1 1 d . . . . .
H01D H 0.292321 0.467871 0.393889 0.138 Uiso 1 1 calc R U . . .
H01E H 0.249047 0.415898 0.437988 0.138 Uiso 1 1 calc R U . . .
H01G H 0.227849 0.491271 0.443129 0.138 Uiso 1 1 calc R U . . .
C01I C 0.5868(6) 0.4492(5) 0.4439(6) 0.079(3) Uani 1 1 d . . . . .
H01I H 0.631456 0.454135 0.469208 0.095 Uiso 1 1 calc R U . . .
C01J C 0.6651(8) 0.2183(9) 0.1850(11) 0.138(7) Uani 1 1 d . . . . .
H01H H 0.690820 0.252216 0.160080 0.208 Uiso 1 1 calc R U . . .
H01J H 0.669809 0.176664 0.162415 0.208 Uiso 1 1 calc R U . . .
H01K H 0.688442 0.214870 0.227786 0.208 Uiso 1 1 calc R U . . .
C01K C 0.5390(6) 0.1420(5) 0.2738(8) 0.097(4) Uani 1 1 d . . . . .
H01L H 0.511681 0.120719 0.238450 0.145 Uiso 1 1 calc R U . . .
H01M H 0.511406 0.135269 0.314329 0.145 Uiso 1 1 calc R U . . .
H01N H 0.590086 0.123485 0.277450 0.145 Uiso 1 1 calc R U . . .
C01L C 0.5381(8) 0.2114(9) 0.1349(7) 0.119(5) Uani 1 1 d . . . . .
H01O H 0.485583 0.227172 0.134851 0.178 Uiso 1 1 calc R U . . .
H01P H 0.538263 0.163859 0.135569 0.178 Uiso 1 1 calc R U . . .
H01Q H 0.564125 0.226787 0.095955 0.178 Uiso 1 1 calc R U . . .
C01M C 0.1546(5) 0.1021(5) 0.2931(7) 0.081(3) Uani 1 1 d . . . . .
C01N C 0.0338(6) 0.1657(7) 0.3141(8) 0.095(4) Uani 1 1 d . . . . .
C01O C 0.6063(5) 0.3190(5) 0.2725(6) 0.083(3) Uani 1 1 d . . . . .
H01R H 0.585683 0.356633 0.296453 0.100 Uiso 1 1 calc R U . . .
H01S H 0.661557 0.325132 0.265955 0.100 Uiso 1 1 calc R U . . .
C01P C 0.7976(5) 0.6503(5) 0.4157(5) 0.068(2) Uani 1 1 d . . . . .
C01Q C 0.9438(8) 0.6153(8) 0.4455(7) 0.106(4) Uani 1 1 d . . . . .
H01T H 0.994873 0.606345 0.457493 0.128 Uiso 1 1 calc R U . . .
C01R C 0.1288(7) 0.4257(6) 0.1003(6) 0.082(3) Uani 1 1 d . . . . .
C01S C 0.6125(6) 0.5556(5) 0.3977(6) 0.075(3) Uani 1 1 d . . . . .
C01U C 0.2072(8) -0.0062(6) 0.2206(7) 0.103(4) Uani 1 1 d . . . . .
H01U H 0.217612 0.018946 0.180886 0.124 Uiso 1 1 calc R U . . .
H01V H 0.221697 -0.052112 0.213666 0.124 Uiso 1 1 calc R U . . .
C01V C 0.2246(7) 0.2789(5) 0.4785(5) 0.078(2) Uani 1 1 d . . . . .
C01W C 0.1699(8) 0.5044(6) 0.3138(7) 0.091(3) Uani 1 1 d . . . . .
C01X C 0.3326(6) 0.0055(5) 0.2816(7) 0.086(3) Uani 1 1 d . . . . .
H01W H 0.360262 0.032553 0.250600 0.130 Uiso 1 1 calc R U . . .
H01X H 0.338460 -0.040337 0.269876 0.130 Uiso 1 1 calc R U . . .
H01Y H 0.352940 0.012653 0.325010 0.130 Uiso 1 1 calc R U . . .
C01Y C 0.1915(9) -0.0717(7) 0.3480(10) 0.118(5) Uani 1 1 d . . . . .
H01Z H 0.180867 -0.093558 0.306926 0.176 Uiso 1 1 calc R U . . .
H H 0.149976 -0.080257 0.378361 0.176 Uiso 1 1 calc R U . . .
HA H 0.239213 -0.088236 0.365926 0.176 Uiso 1 1 calc R U . . .
C01Z C 0.1968(5) 0.3926(5) 0.3157(5) 0.066(2) Uani 1 1 d . . . . .
C02A C 0.3758(6) 0.2959(5) 0.4362(5) 0.074(2) Uani 1 1 d . . . . .
C02C C 0.1520(7) 0.2622(7) 0.4599(5) 0.090(3) Uani 1 1 d . . . . .
H02C H 0.143849 0.233755 0.424404 0.108 Uiso 1 1 calc R U . . .
C02D C 0.0716(11) 0.4462(10) 0.0448(8) 0.119(5) Uani 1 1 d . . . . .
C02E C 0.2901(15) 0.1582(8) 0.5413(8) 0.155(8) Uani 1 1 d . . . . .
H02E H 0.244120 0.179070 0.553454 0.186 Uiso 1 1 calc R U . . .
C02F C 0.6199(7) 0.6900(7) 0.5168(7) 0.106(4) Uani 1 1 d . . . . .
H02F H 0.595088 0.649993 0.508220 0.127 Uiso 1 1 calc R U . . .
C02G C 0.2226(10) 0.0349(8) 0.4026(6) 0.109(4) Uani 1 1 d . . . . .
H02A H 0.192236 0.016660 0.437816 0.163 Uiso 1 1 calc R U . . .
H02B H 0.214121 0.081804 0.400055 0.163 Uiso 1 1 calc R U . . .
H02D H 0.276568 0.026352 0.410626 0.163 Uiso 1 1 calc R U . . .
C02H C 0.1983(7) 0.0021(6) 0.3365(7) 0.089(3) Uani 1 1 d . . . . .
C02I C 0.8571(6) 0.6697(7) 0.3774(6) 0.086(3) Uani 1 1 d . . . . .
H02I H 0.848048 0.696643 0.340918 0.104 Uiso 1 1 calc R U . . .
C02K C 0.1241(7) -0.0001(6) 0.2412(9) 0.111(5) Uani 1 1 d . . . . .
H02G H 0.094920 0.026258 0.209869 0.134 Uiso 1 1 calc R U . . .
H02H H 0.100031 -0.043342 0.245215 0.134 Uiso 1 1 calc R U . . .
C02L C 0.1848(6) 0.4480(6) 0.3621(5) 0.080(3) Uani 1 1 d . . . . .
C02N C 0.8856(8) 0.5929(9) 0.4826(10) 0.142(8) Uani 1 1 d . . . . .
H02N H 0.896090 0.566234 0.518881 0.171 Uiso 1 1 calc R U . . .
C02O C 0.3809(19) 0.0737(11) 0.5618(14) 0.181(12) Uani 1 1 d . . . . .
H02O H 0.400712 0.042058 0.590622 0.217 Uiso 1 1 calc R U . . .
C02P C 0.7098(9) 0.7709(8) 0.4891(8) 0.120(5) Uani 1 1 d . . . . .
H02P H 0.750564 0.785767 0.462931 0.144 Uiso 1 1 calc R U . . .
C02S C 0.1401(9) 0.5655(6) 0.3468(8) 0.108(4) Uani 1 1 d . . . . .
H02J H 0.151788 0.563610 0.393003 0.163 Uiso 1 1 calc R U . . .
H02K H 0.084974 0.568299 0.340828 0.163 Uiso 1 1 calc R U . . .
H02L H 0.164393 0.603736 0.327730 0.163 Uiso 1 1 calc R U . . .
C02T C 0.6049(10) 0.7231(6) 0.5712(7) 0.115(5) Uani 1 1 d . . . . .
H02T H 0.569135 0.704720 0.600336 0.137 Uiso 1 1 calc R U . . .
C02U C 0.1770(12) 0.3466(10) 0.5635(8) 0.131(6) Uani 1 1 d . . . . .
H02U H 0.185629 0.374912 0.598905 0.157 Uiso 1 1 calc R U . . .
C3 C 0.4047(17) 0.4796(16) 0.0871(11) 0.212(8) Uani 1 1 d D U . A -1
C4 C 0.4393(6) 0.4201(5) 0.1920(5) 0.075(2) Uani 1 1 d . U . . .
C5 C 0.6887(10) 0.8046(9) 0.5421(9) 0.137(7) Uani 1 1 d . . . . .
H5 H 0.709546 0.846422 0.549678 0.164 Uiso 1 1 calc R U . . .
C7 C 0.3893(10) 0.1362(11) 0.4688(14) 0.171(11) Uani 1 1 d . . . . .
H7 H 0.414191 0.144401 0.428907 0.205 Uiso 1 1 calc R U . . .
C010 C 0.1196(5) 0.1618(5) 0.2943(6) 0.078(3) Uani 1 1 d . . . . .
C011 C 0.5036(5) 0.4892(5) 0.3622(5) 0.068(2) Uani 1 1 d . . . . .
H011 H 0.491168 0.520482 0.330267 0.082 Uiso 1 1 calc R U . . .
C12 C 0.4125(10) 0.0846(15) 0.5060(19) 0.25(2) Uani 1 1 d . . . . .
H12 H 0.451706 0.056804 0.490915 0.295 Uiso 1 1 calc R U . . .
C013 C 0.5778(6) 0.2362(8) 0.1926(7) 0.099(4) Uani 1 1 d . . . . .
C13 C 0.324(3) 0.1063(11) 0.5759(9) 0.25(2) Uani 1 1 d . . . . .
H13 H 0.299363 0.094846 0.615246 0.295 Uiso 1 1 calc R U . . .
C014 C 0.4569(6) 0.4361(5) 0.3706(5) 0.071(2) Uani 1 1 d . . . . .
H014 H 0.412309 0.431388 0.345218 0.085 Uiso 1 1 calc R U . . .
C015 C 0.5657(5) 0.3096(6) 0.2091(6) 0.080(3) Uani 1 1 d . . . . .
H015 H 0.580897 0.340522 0.174229 0.096 Uiso 1 1 calc R U . . .
C016 C 0.1501(5) 0.4025(4) 0.2617(5) 0.066(2) Uani 1 1 d . . . . .
C017 C 0.4230(6) 0.3360(4) 0.4279(5) 0.066(2) Uani 1 1 d . . . . .
C020 C 0.1096(14) 0.3316(10) 0.5464(8) 0.135(6) Uani 1 1 d . . . . .
H020 H 0.069007 0.350718 0.569866 0.162 Uiso 1 1 calc R U . . .
C021 C 0.3331(7) 0.1746(5) 0.4872(6) 0.081(3) Uani 1 1 d . . . . .
C023 C 0.9292(7) 0.6503(8) 0.3917(8) 0.104(4) Uani 1 1 d . . . . .
H023 H 0.969751 0.661501 0.363517 0.125 Uiso 1 1 calc R U . . .
C024 C 0.2349(9) 0.5220(5) 0.2702(7) 0.100(4) Uani 1 1 d . . . . .
H02M H 0.265316 0.556287 0.290356 0.150 Uiso 1 1 calc R U . . .
H02Q H 0.215048 0.537459 0.228776 0.150 Uiso 1 1 calc R U . . .
H02R H 0.266772 0.483638 0.263008 0.150 Uiso 1 1 calc R U . . .
C025 C 0.5896(5) 0.2548(6) 0.3080(6) 0.085(3) Uani 1 1 d . . . . .
H02S H 0.637509 0.232941 0.320350 0.102 Uiso 1 1 calc R U . . .
H02V H 0.559369 0.262968 0.347444 0.102 Uiso 1 1 calc R U . . .
C026 C 0.8115(8) 0.6088(8) 0.4677(9) 0.119(6) Uani 1 1 d . . . . .
H026 H 0.770580 0.591703 0.492303 0.143 Uiso 1 1 calc R U . . .
C027 C 0.1287(7) 0.0321(6) 0.3035(8) 0.096(4) Uani 1 1 d . . . . .
H027 H 0.081041 0.028443 0.329500 0.116 Uiso 1 1 calc R U . . .
C028 C 0.0897(9) 0.2883(9) 0.4948(8) 0.121(5) Uani 1 1 d . . . . .
H028 H 0.038472 0.277868 0.484721 0.145 Uiso 1 1 calc R U . . .
C029 C 0.2348(9) 0.3217(8) 0.5306(6) 0.108(4) Uani 1 1 d . . . . .
H029 H 0.284988 0.333319 0.542766 0.130 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu01 O1 2.352(6) 3_645 ?
Eu01 O7 2.356(6) . ?
Eu01 O5 2.384(6) . ?
Eu01 O2 2.407(7) . ?
Eu01 O3 2.414(6) . ?
Eu01 O8 2.414(6) . ?
Eu01 O6 2.423(5) . ?
Eu01 O4 2.432(5) . ?
P002 O1 1.486(7) . ?
P002 C00H 1.755(10) . ?
P002 C00N 1.777(9) . ?
P002 C01P 1.802(9) . ?
P003 O2 1.482(7) . ?
P003 C02A 1.748(10) . ?
P003 C01V 1.791(12) . ?
P003 C021 1.794(12) . ?
F00C C01N 1.384(15) . ?
F00F C00R 1.468(17) . ?
F00G C00R 1.302(17) . ?
F00I C00T 1.33(2) . ?
F00L C01R 1.315(15) . ?
F00U C01N 1.342(17) . ?
F00W C01R 1.290(15) . ?
F1 C4 1.365(13) . ?
F2 C1 1.38(2) . ?
F02M C02D 1.24(2) . ?
F02R C02D 1.23(2) . ?
F3 C4 1.344(13) . ?
F4 C3 1.31(2) . ?
F5 C1 1.64(3) . ?
F6 C3 1.37(2) . ?
F7 C3 1.33(2) . ?
F007 C01G 1.365(11) . ?
F008 C01G 1.359(12) . ?
F012 C00T 1.31(2) . ?
F018 C00T 1.31(2) . ?
F019 C02D 1.300(19) . ?
O3 C010 1.252(12) . ?
O4 C00Z 1.225(10) . ?
O5 C00Y 1.260(10) . ?
O6 C00Q 1.228(10) . ?
O7 C00S 1.261(12) . ?
O8 C01Z 1.257(11) . ?
C00H C01S 1.203(14) . ?
C00J C011 1.356(14) . ?
C00J C01I 1.415(15) . ?
C00J C01S 1.438(14) . ?
C00K C00O 1.422(18) . ?
C00K C016 1.551(13) . ?
C00K C01W 1.599(18) . ?
C00K H00K 1.0000 . ?
C00N C02P 1.372(15) . ?
C00N C02F 1.379(14) . ?
C00O C01D 1.569(16) . ?
C00O H00A 0.9900 . ?
C00O H00B 0.9900 . ?
C00Q C00V 1.429(12) . ?
C00Q C01E 1.542(12) . ?
C00R C01N 1.42(2) . ?
C00R C00T 1.582(16) . ?
C00S C016 1.404(14) . ?
C00S C01G 1.535(13) . ?
C00V C00Y 1.359(12) . ?
C00V C015 1.552(12) . ?
C00X C014 1.383(15) . ?
C00X C01C 1.388(13) . ?
C00X C017 1.465(13) . ?
C00Y C4 1.519(14) . ?
C00Z C01M 1.442(13) . ?
C00Z C01B 1.504(13) . ?
C1 C3 1.32(3) . ?
C1 C4 1.56(2) . ?
C01B C01X 1.517(15) . ?
C01B C02H 1.530(17) . ?
C01B C01U 1.564(15) . ?
C01C C01I 1.370(14) . ?
C01C H01C 0.9500 . ?
C01D C02L 1.544(17) . ?
C01D H01A 0.9900 . ?
C01D H01B 0.9900 . ?
C01E C01K 1.497(15) . ?
C01E C025 1.526(16) . ?
C01E C013 1.591(18) . ?
C01F C02T 1.294(19) . ?
C01F C5 1.43(2) . ?
C01F H01F 0.9500 . ?
C01G C01R 1.531(17) . ?
C01H C02L 1.499(15) . ?
C01H H01D 0.9800 . ?
C01H H01E 0.9800 . ?
C01H H01G 0.9800 . ?
C01I H01I 0.9500 . ?
C01J C013 1.587(17) . ?
C01J H01H 0.9800 . ?
C01J H01J 0.9800 . ?
C01J H01K 0.9800 . ?
C01K H01L 0.9800 . ?
C01K H01M 0.9800 . ?
C01K H01N 0.9800 . ?
C01L C013 1.48(2) . ?
C01L H01O 0.9800 . ?
C01L H01P 0.9800 . ?
C01L H01Q 0.9800 . ?
C01M C010 1.375(15) . ?
C01M C027 1.527(15) . ?
C01N C010 1.568(15) . ?
C01O C015 1.508(17) . ?
C01O C025 1.540(17) . ?
C01O H01R 0.9900 . ?
C01O H01S 0.9900 . ?
C01P C02I 1.375(14) . ?
C01P C026 1.397(17) . ?
C01Q C023 1.35(2) . ?
C01Q C02N 1.36(2) . ?
C01Q H01T 0.9500 . ?
C01R C02D 1.58(2) . ?
C01U C02K 1.53(2) . ?
C01U H01U 0.9900 . ?
C01U H01V 0.9900 . ?
C01V C02C 1.379(17) . ?
C01V C029 1.405(17) . ?
C01W C024 1.50(2) . ?
C01W C02S 1.524(16) . ?
C01W C02L 1.556(18) . ?
C01X H01W 0.9800 . ?
C01X H01X 0.9800 . ?
C01X H01Y 0.9800 . ?
C01Y C02H 1.544(17) . ?
C01Y H01Z 0.9800 . ?
C01Y H 0.9800 . ?
C01Y HA 0.9800 . ?
C01Z C016 1.404(14) . ?
C01Z C02L 1.508(14) . ?
C02A C017 1.184(13) . ?
C02C C028 1.420(19) . ?
C02C H02C 0.9500 . ?
C02E C021 1.40(2) . ?
C02E C13 1.42(3) . ?
C02E H02E 0.9500 . ?
C02F C02T 1.345(19) . ?
C02F H02F 0.9500 . ?
C02G C02H 1.58(2) . ?
C02G H02A 0.9800 . ?
C02G H02B 0.9800 . ?
C02G H02D 0.9800 . ?
C02H C027 1.534(18) . ?
C02I C023 1.364(16) . ?
C02I H02I 0.9500 . ?
C02K C027 1.45(2) . ?
C02K H02G 0.9900 . ?
C02K H02H 0.9900 . ?
C02N C026 1.381(19) . ?
C02N H02N 0.9500 . ?
C02O C13 1.24(4) . ?
C02O C12 1.30(4) . ?
C02O H02O 0.9500 . ?
C02P C5 1.352(19) . ?
C02P H02P 0.9500 . ?
C02S H02J 0.9800 . ?
C02S H02K 0.9800 . ?
C02S H02L 0.9800 . ?
C02T H02T 0.9500 . ?
C02U C020 1.28(3) . ?
C02U C029 1.33(2) . ?
C02U H02U 0.9500 . ?
C5 H5 0.9500 . ?
C7 C021 1.32(2) . ?
C7 C12 1.37(3) . ?
C7 H7 0.9500 . ?
C011 C014 1.378(13) . ?
C011 H011 0.9500 . ?
C12 H12 0.9500 . ?
C013 C015 1.564(19) . ?
C13 H13 0.9500 . ?
C014 H014 0.9500 . ?
C015 H015 1.0000 . ?
C020 C028 1.43(3) . ?
C020 H020 0.9500 . ?
C023 H023 0.9500 . ?
C024 H02M 0.9800 . ?
C024 H02Q 0.9800 . ?
C024 H02R 0.9800 . ?
C025 H02S 0.9900 . ?
C025 H02V 0.9900 . ?
C026 H026 0.9500 . ?
C027 H027 1.0000 . ?
C028 H028 0.9500 . ?
C029 H029 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Eu01 O7 76.3(2) 3_645 . ?
O1 Eu01 O5 84.8(2) 3_645 . ?
O7 Eu01 O5 80.0(2) . . ?
O1 Eu01 O2 141.0(2) 3_645 . ?
O7 Eu01 O2 137.0(2) . . ?
O5 Eu01 O2 115.6(2) . . ?
O1 Eu01 O3 105.9(2) 3_645 . ?
O7 Eu01 O3 72.8(2) . . ?
O5 Eu01 O3 147.0(2) . . ?
O2 Eu01 O3 75.5(2) . . ?
O1 Eu01 O8 145.9(2) 3_645 . ?
O7 Eu01 O8 75.7(2) . . ?
O5 Eu01 O8 71.6(2) . . ?
O2 Eu01 O8 72.8(2) . . ?
O3 Eu01 O8 83.8(2) . . ?
O1 Eu01 O6 80.8(2) 3_645 . ?
O7 Eu01 O6 144.4(2) . . ?
O5 Eu01 O6 70.99(19) . . ?
O2 Eu01 O6 76.0(2) . . ?
O3 Eu01 O6 140.7(2) . . ?
O8 Eu01 O6 112.5(2) . . ?
O1 Eu01 O4 71.2(2) 3_645 . ?
O7 Eu01 O4 121.9(2) . . ?
O5 Eu01 O4 140.35(18) . . ?
O2 Eu01 O4 72.6(2) . . ?
O3 Eu01 O4 71.7(2) . . ?
O8 Eu01 O4 141.5(2) . . ?
O6 Eu01 O4 74.28(18) . . ?
O1 P002 C00H 113.7(5) . . ?
O1 P002 C00N 111.9(4) . . ?
C00H P002 C00N 105.0(5) . . ?
O1 P002 C01P 114.1(4) . . ?
C00H P002 C01P 105.8(5) . . ?
C00N P002 C01P 105.4(4) . . ?
O2 P003 C02A 112.8(4) . . ?
O2 P003 C01V 113.3(5) . . ?
C02A P003 C01V 105.9(5) . . ?
O2 P003 C021 112.1(5) . . ?
C02A P003 C021 105.2(5) . . ?
C01V P003 C021 106.9(6) . . ?
P002 O1 Eu01 153.2(5) . 3_655 ?
P003 O2 Eu01 140.8(4) . . ?
C010 O3 Eu01 136.0(6) . . ?
C00Z O4 Eu01 132.8(5) . . ?
C00Y O5 Eu01 135.4(6) . . ?
C00Q O6 Eu01 131.2(5) . . ?
C00S O7 Eu01 133.7(6) . . ?
C01Z O8 Eu01 129.8(6) . . ?
C01S C00H P002 173.1(11) . . ?
C011 C00J C01I 118.7(8) . . ?
C011 C00J C01S 123.9(9) . . ?
C01I C00J C01S 117.1(9) . . ?
C00O C00K C016 107.8(10) . . ?
C00O C00K C01W 102.8(10) . . ?
C016 C00K C01W 98.5(8) . . ?
C00O C00K H00K 115.3 . . ?
C016 C00K H00K 115.3 . . ?
C01W C00K H00K 115.3 . . ?
C02P C00N C02F 118.8(11) . . ?
C02P C00N P002 115.2(8) . . ?
C02F C00N P002 125.7(8) . . ?
C00K C00O C01D 104.4(9) . . ?
C00K C00O H00A 110.9 . . ?
C01D C00O H00A 110.9 . . ?
C00K C00O H00B 110.9 . . ?
C01D C00O H00B 110.9 . . ?
H00A C00O H00B 108.9 . . ?
O6 C00Q C00V 129.2(7) . . ?
O6 C00Q C01E 123.8(8) . . ?
C00V C00Q C01E 107.0(7) . . ?
F00G C00R C01N 115.2(12) . . ?
F00G C00R F00F 107.2(12) . . ?
C01N C00R F00F 107.9(11) . . ?
F00G C00R C00T 105.2(11) . . ?
C01N C00R C00T 120.0(14) . . ?
F00F C00R C00T 99.7(13) . . ?
O7 C00S C016 126.3(8) . . ?
O7 C00S C01G 114.1(9) . . ?
C016 C00S C01G 119.6(8) . . ?
F012 C00T F018 111.0(13) . . ?
F012 C00T F00I 106.7(17) . . ?
F018 C00T F00I 108.4(17) . . ?
F012 C00T C00R 106.7(16) . . ?
F018 C00T C00R 112.0(15) . . ?
F00I C00T C00R 111.9(12) . . ?
C00Y C00V C00Q 121.3(7) . . ?
C00Y C00V C015 133.2(8) . . ?
C00Q C00V C015 104.9(7) . . ?
C014 C00X C01C 120.4(8) . . ?
C014 C00X C017 119.0(8) . . ?
C01C C00X C017 120.5(9) . . ?
O5 C00Y C00V 125.9(8) . . ?
O5 C00Y C4 113.4(8) . . ?
C00V C00Y C4 120.7(8) . . ?
O4 C00Z C01M 128.9(9) . . ?
O4 C00Z C01B 126.0(8) . . ?
C01M C00Z C01B 104.9(8) . . ?
C3 C1 F2 114.6(18) . . ?
C3 C1 C4 125.6(19) . . ?
F2 C1 C4 104.1(14) . . ?
C3 C1 F5 100(2) . . ?
F2 C1 F5 103.6(16) . . ?
C4 C1 F5 106.9(13) . . ?
C00Z C01B C01X 114.3(8) . . ?
C00Z C01B C02H 102.5(9) . . ?
C01X C01B C02H 118.9(11) . . ?
C00Z C01B C01U 105.2(9) . . ?
C01X C01B C01U 112.0(11) . . ?
C02H C01B C01U 102.4(9) . . ?
C01I C01C C00X 119.2(10) . . ?
C01I C01C H01C 120.4 . . ?
C00X C01C H01C 120.4 . . ?
C02L C01D C00O 103.5(9) . . ?
C02L C01D H01A 111.1 . . ?
C00O C01D H01A 111.1 . . ?
C02L C01D H01B 111.1 . . ?
C00O C01D H01B 111.1 . . ?
H01A C01D H01B 109.0 . . ?
C01K C01E C025 117.7(11) . . ?
C01K C01E C00Q 113.3(8) . . ?
C025 C01E C00Q 104.2(8) . . ?
C01K C01E C013 118.8(11) . . ?
C025 C01E C013 102.5(9) . . ?
C00Q C01E C013 97.7(8) . . ?
C02T C01F C5 116.0(12) . . ?
C02T C01F H01F 122.0 . . ?
C5 C01F H01F 122.0 . . ?
F008 C01G F007 104.8(8) . . ?
F008 C01G C01R 108.0(9) . . ?
F007 C01G C01R 109.4(9) . . ?
F008 C01G C00S 108.3(8) . . ?
F007 C01G C00S 112.9(8) . . ?
C01R C01G C00S 113.0(9) . . ?
C02L C01H H01D 109.5 . . ?
C02L C01H H01E 109.5 . . ?
H01D C01H H01E 109.5 . . ?
C02L C01H H01G 109.5 . . ?
H01D C01H H01G 109.5 . . ?
H01E C01H H01G 109.5 . . ?
C01C C01I C00J 120.6(9) . . ?
C01C C01I H01I 119.7 . . ?
C00J C01I H01I 119.7 . . ?
C013 C01J H01H 109.5 . . ?
C013 C01J H01J 109.5 . . ?
H01H C01J H01J 109.5 . . ?
C013 C01J H01K 109.5 . . ?
H01H C01J H01K 109.5 . . ?
H01J C01J H01K 109.5 . . ?
C01E C01K H01L 109.5 . . ?
C01E C01K H01M 109.5 . . ?
H01L C01K H01M 109.5 . . ?
C01E C01K H01N 109.5 . . ?
H01L C01K H01N 109.5 . . ?
H01M C01K H01N 109.5 . . ?
C013 C01L H01O 109.5 . . ?
C013 C01L H01P 109.5 . . ?
H01O C01L H01P 109.5 . . ?
C013 C01L H01Q 109.5 . . ?
H01O C01L H01Q 109.5 . . ?
H01P C01L H01Q 109.5 . . ?
C010 C01M C00Z 121.7(9) . . ?
C010 C01M C027 135.0(9) . . ?
C00Z C01M C027 103.2(9) . . ?
F00U C01N F00C 108.1(11) . . ?
F00U C01N C00R 105.7(13) . . ?
F00C C01N C00R 109.0(11) . . ?
F00U C01N C010 109.9(10) . . ?
F00C C01N C010 107.7(11) . . ?
C00R C01N C010 116.2(11) . . ?
C015 C01O C025 102.4(9) . . ?
C015 C01O H01R 111.3 . . ?
C025 C01O H01R 111.3 . . ?
C015 C01O H01S 111.3 . . ?
C025 C01O H01S 111.3 . . ?
H01R C01O H01S 109.2 . . ?
C02I C01P C026 119.3(10) . . ?
C02I C01P P002 121.8(8) . . ?
C026 C01P P002 118.9(8) . . ?
C023 C01Q C02N 120.2(13) . . ?
C023 C01Q H01T 119.9 . . ?
C02N C01Q H01T 119.9 . . ?
F00W C01R F00L 111.9(12) . . ?
F00W C01R C01G 109.9(10) . . ?
F00L C01R C01G 109.6(9) . . ?
F00W C01R C02D 104.7(12) . . ?
F00L C01R C02D 105.9(11) . . ?
C01G C01R C02D 114.8(11) . . ?
C00H C01S C00J 176.1(12) . . ?
C02K C01U C01B 101.4(12) . . ?
C02K C01U H01U 111.5 . . ?
C01B C01U H01U 111.5 . . ?
C02K C01U H01V 111.5 . . ?
C01B C01U H01V 111.5 . . ?
H01U C01U H01V 109.3 . . ?
C02C C01V C029 119.4(12) . . ?
C02C C01V P003 116.7(8) . . ?
C029 C01V P003 123.8(11) . . ?
C024 C01W C02S 109.4(11) . . ?
C024 C01W C02L 116.0(10) . . ?
C02S C01W C02L 112.7(11) . . ?
C024 C01W C00K 112.3(11) . . ?
C02S C01W C00K 112.6(11) . . ?
C02L C01W C00K 93.0(9) . . ?
C01B C01X H01W 109.5 . . ?
C01B C01X H01X 109.5 . . ?
H01W C01X H01X 109.5 . . ?
C01B C01X H01Y 109.5 . . ?
H01W C01X H01Y 109.5 . . ?
H01X C01X H01Y 109.5 . . ?
C02H C01Y H01Z 109.5 . . ?
C02H C01Y H 109.5 . . ?
H01Z C01Y H 109.5 . . ?
C02H C01Y HA 109.5 . . ?
H01Z C01Y HA 109.5 . . ?
H C01Y HA 109.5 . . ?
O8 C01Z C016 128.6(9) . . ?
O8 C01Z C02L 122.8(8) . . ?
C016 C01Z C02L 108.4(8) . . ?
C017 C02A P003 171.3(10) . . ?
C01V C02C C028 118.6(13) . . ?
C01V C02C H02C 120.7 . . ?
C028 C02C H02C 120.7 . . ?
F02R C02D F02M 106(2) . . ?
F02R C02D F019 110.4(16) . . ?
F02M C02D F019 109.1(18) . . ?
F02R C02D C01R 112.2(16) . . ?
F02M C02D C01R 111.8(15) . . ?
F019 C02D C01R 107.2(14) . . ?
C021 C02E C13 111(2) . . ?
C021 C02E H02E 124.4 . . ?
C13 C02E H02E 124.4 . . ?
C02T C02F C00N 119.2(11) . . ?
C02T C02F H02F 120.4 . . ?
C00N C02F H02F 120.4 . . ?
C02H C02G H02A 109.5 . . ?
C02H C02G H02B 109.5 . . ?
H02A C02G H02B 109.5 . . ?
C02H C02G H02D 109.5 . . ?
H02A C02G H02D 109.5 . . ?
H02B C02G H02D 109.5 . . ?
C027 C02H C01B 90.6(9) . . ?
C027 C02H C01Y 113.8(10) . . ?
C01B C02H C01Y 116.4(12) . . ?
C027 C02H C02G 115.5(13) . . ?
C01B C02H C02G 112.1(10) . . ?
C01Y C02H C02G 107.9(12) . . ?
C023 C02I C01P 119.9(11) . . ?
C023 C02I H02I 120.1 . . ?
C01P C02I H02I 120.1 . . ?
C027 C02K C01U 103.4(9) . . ?
C027 C02K H02G 111.1 . . ?
C01U C02K H02G 111.1 . . ?
C027 C02K H02H 111.1 . . ?
C01U C02K H02H 111.1 . . ?
H02G C02K H02H 109.0 . . ?
C01Z C02L C01H 116.5(8) . . ?
C01Z C02L C01D 101.1(10) . . ?
C01H C02L C01D 115.4(10) . . ?
C01Z C02L C01W 100.3(9) . . ?
C01H C02L C01W 119.2(11) . . ?
C01D C02L C01W 101.5(9) . . ?
C01Q C02N C026 120.4(13) . . ?
C01Q C02N H02N 119.8 . . ?
C026 C02N H02N 119.8 . . ?
C13 C02O C12 117(2) . . ?
C13 C02O H02O 121.3 . . ?
C12 C02O H02O 121.3 . . ?
C5 C02P C00N 119.3(12) . . ?
C5 C02P H02P 120.4 . . ?
C00N C02P H02P 120.4 . . ?
C01W C02S H02J 109.5 . . ?
C01W C02S H02K 109.5 . . ?
H02J C02S H02K 109.5 . . ?
C01W C02S H02L 109.5 . . ?
H02J C02S H02L 109.5 . . ?
H02K C02S H02L 109.5 . . ?
C01F C02T C02F 125.1(13) . . ?
C01F C02T H02T 117.4 . . ?
C02F C02T H02T 117.4 . . ?
C020 C02U C029 118.5(17) . . ?
C020 C02U H02U 120.8 . . ?
C029 C02U H02U 120.8 . . ?
F4 C3 F7 125(3) . . ?
F4 C3 F6 111(3) . . ?
F7 C3 F6 105(2) . . ?
F4 C3 C1 100(2) . . ?
F7 C3 C1 109(2) . . ?
F6 C3 C1 105(3) . . ?
F3 C4 F1 103.8(10) . . ?
F3 C4 C00Y 113.0(8) . . ?
F1 C4 C00Y 110.4(8) . . ?
F3 C4 C1 107.6(12) . . ?
F1 C4 C1 107.6(10) . . ?
C00Y C4 C1 113.9(12) . . ?
C02P C5 C01F 120.9(13) . . ?
C02P C5 H5 119.5 . . ?
C01F C5 H5 119.5 . . ?
C021 C7 C12 122(2) . . ?
C021 C7 H7 119.2 . . ?
C12 C7 H7 119.2 . . ?
O3 C010 C01M 126.9(8) . . ?
O3 C010 C01N 114.3(9) . . ?
C01M C010 C01N 118.9(9) . . ?
C00J C011 C014 121.5(9) . . ?
C00J C011 H011 119.2 . . ?
C014 C011 H011 119.2 . . ?
C02O C12 C7 120(3) . . ?
C02O C12 H12 119.8 . . ?
C7 C12 H12 119.8 . . ?
C01L C013 C015 116.6(13) . . ?
C01L C013 C01E 116.0(11) . . ?
C015 C013 C01E 92.5(10) . . ?
C01L C013 C01J 107.3(13) . . ?
C015 C013 C01J 112.3(11) . . ?
C01E C013 C01J 111.8(13) . . ?
C02O C13 C02E 129(3) . . ?
C02O C13 H13 115.6 . . ?
C02E C13 H13 115.6 . . ?
C011 C014 C00X 119.4(9) . . ?
C011 C014 H014 120.3 . . ?
C00X C014 H014 120.3 . . ?
C01O C015 C00V 106.9(9) . . ?
C01O C015 C013 104.5(10) . . ?
C00V C015 C013 99.2(9) . . ?
C01O C015 H015 114.9 . . ?
C00V C015 H015 114.9 . . ?
C013 C015 H015 114.9 . . ?
C01Z C016 C00S 124.6(8) . . ?
C01Z C016 C00K 105.2(9) . . ?
C00S C016 C00K 130.1(9) . . ?
C02A C017 C00X 174.5(11) . . ?
C02U C020 C028 125.7(17) . . ?
C02U C020 H020 117.1 . . ?
C028 C020 H020 117.1 . . ?
C7 C021 C02E 119.5(14) . . ?
C7 C021 P003 121.0(13) . . ?
C02E C021 P003 118.7(12) . . ?
C01Q C023 C02I 120.9(13) . . ?
C01Q C023 H023 119.6 . . ?
C02I C023 H023 119.6 . . ?
C01W C024 H02M 109.5 . . ?
C01W C024 H02Q 109.5 . . ?
H02M C024 H02Q 109.5 . . ?
C01W C024 H02R 109.5 . . ?
H02M C024 H02R 109.5 . . ?
H02Q C024 H02R 109.5 . . ?
C01E C025 C01O 105.7(9) . . ?
C01E C025 H02S 110.6 . . ?
C01O C025 H02S 110.6 . . ?
C01E C025 H02V 110.6 . . ?
C01O C025 H02V 110.6 . . ?
H02S C025 H02V 108.7 . . ?
C02N C026 C01P 118.9(13) . . ?
C02N C026 H026 120.6 . . ?
C01P C026 H026 120.6 . . ?
C02K C027 C02H 104.8(11) . . ?
C02K C027 C01M 108.8(12) . . ?
C02H C027 C01M 101.8(9) . . ?
C02K C027 H027 113.5 . . ?
C02H C027 H027 113.5 . . ?
C01M C027 H027 113.5 . . ?
C020 C028 C02C 115.2(16) . . ?
C020 C028 H028 122.4 . . ?
C02C C028 H028 122.4 . . ?
C02U C029 C01V 122.6(16) . . ?
C02U C029 H029 118.7 . . ?
C01V C029 H029 118.7 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C00H P002 O1 Eu01 -83.1(9) . . . 3_655 ?
C00N P002 O1 Eu01 158.0(8) . . . 3_655 ?
C01P P002 O1 Eu01 38.4(10) . . . 3_655 ?
C02A P003 O2 Eu01 -31.7(8) . . . . ?
C01V P003 O2 Eu01 88.7(7) . . . . ?
C021 P003 O2 Eu01 -150.3(6) . . . . ?
O1 P002 C00N C02P -58.6(11) . . . . ?
C00H P002 C00N C02P 177.5(11) . . . . ?
C01P P002 C00N C02P 65.9(11) . . . . ?
O1 P002 C00N C02F 127.6(11) . . . . ?
C00H P002 C00N C02F 3.7(12) . . . . ?
C01P P002 C00N C02F -107.8(11) . . . . ?
C016 C00K C00O C01D 64.2(12) . . . . ?
C01W C00K C00O C01D -39.2(12) . . . . ?
Eu01 O6 C00Q C00V 15.7(13) . . . . ?
Eu01 O6 C00Q C01E -166.9(7) . . . . ?
Eu01 O7 C00S C016 8.4(14) . . . . ?
Eu01 O7 C00S C01G -169.6(6) . . . . ?
F00G C00R C00T F012 -72.3(18) . . . . ?
C01N C00R C00T F012 60(2) . . . . ?
F00F C00R C00T F012 176.8(13) . . . . ?
F00G C00R C00T F018 49(2) . . . . ?
C01N C00R C00T F018 -178.8(15) . . . . ?
F00F C00R C00T F018 -61.5(18) . . . . ?
F00G C00R C00T F00I 171.3(16) . . . . ?
C01N C00R C00T F00I -57(2) . . . . ?
F00F C00R C00T F00I 60(2) . . . . ?
O6 C00Q C00V C00Y 6.2(14) . . . . ?
C01E C00Q C00V C00Y -171.5(8) . . . . ?
O6 C00Q C00V C015 178.8(9) . . . . ?
C01E C00Q C00V C015 1.1(10) . . . . ?
Eu01 O5 C00Y C00V -16.0(14) . . . . ?
Eu01 O5 C00Y C4 162.8(7) . . . . ?
C00Q C00V C00Y O5 -6.7(14) . . . . ?
C015 C00V C00Y O5 -176.8(10) . . . . ?
C00Q C00V C00Y C4 174.7(8) . . . . ?
C015 C00V C00Y C4 4.6(16) . . . . ?
Eu01 O4 C00Z C01M 16.5(15) . . . . ?
Eu01 O4 C00Z C01B -170.4(7) . . . . ?
O4 C00Z C01B C01X 20.1(16) . . . . ?
C01M C00Z C01B C01X -165.5(11) . . . . ?
O4 C00Z C01B C02H 150.1(10) . . . . ?
C01M C00Z C01B C02H -35.5(11) . . . . ?
O4 C00Z C01B C01U -103.1(11) . . . . ?
C01M C00Z C01B C01U 71.3(12) . . . . ?
C014 C00X C01C C01I 4.9(16) . . . . ?
C017 C00X C01C C01I -174.1(10) . . . . ?
C00K C00O C01D C02L 5.6(13) . . . . ?
O6 C00Q C01E C01K 19.1(15) . . . . ?
C00V C00Q C01E C01K -163.0(11) . . . . ?
O6 C00Q C01E C025 -110.0(10) . . . . ?
C00V C00Q C01E C025 67.9(10) . . . . ?
O6 C00Q C01E C013 145.1(9) . . . . ?
C00V C00Q C01E C013 -37.1(10) . . . . ?
O7 C00S C01G F008 29.1(12) . . . . ?
C016 C00S C01G F008 -149.1(9) . . . . ?
O7 C00S C01G F007 144.7(9) . . . . ?
C016 C00S C01G F007 -33.5(13) . . . . ?
O7 C00S C01G C01R -90.5(11) . . . . ?
C016 C00S C01G C01R 91.4(11) . . . . ?
C00X C01C C01I C00J -3.0(18) . . . . ?
C011 C00J C01I C01C -1.0(16) . . . . ?
C01S C00J C01I C01C 174.3(11) . . . . ?
O4 C00Z C01M C010 -5.2(19) . . . . ?
C01B C00Z C01M C010 -179.4(12) . . . . ?
O4 C00Z C01M C027 172.9(11) . . . . ?
C01B C00Z C01M C027 -1.3(13) . . . . ?
F00G C00R C01N F00U 59.4(13) . . . . ?
F00F C00R C01N F00U 179.1(9) . . . . ?
C00T C00R C01N F00U -67.9(17) . . . . ?
F00G C00R C01N F00C 175.5(11) . . . . ?
F00F C00R C01N F00C -64.9(13) . . . . ?
C00T C00R C01N F00C 48(2) . . . . ?
F00G C00R C01N C010 -62.7(17) . . . . ?
F00F C00R C01N C010 56.9(15) . . . . ?
C00T C00R C01N C010 169.9(14) . . . . ?
O1 P002 C01P C02I 0.1(12) . . . . ?
C00H P002 C01P C02I 125.9(10) . . . . ?
C00N P002 C01P C02I -123.1(10) . . . . ?
O1 P002 C01P C026 -179.8(11) . . . . ?
C00H P002 C01P C026 -54.0(13) . . . . ?
C00N P002 C01P C026 57.0(12) . . . . ?
F008 C01G C01R F00W -178.3(10) . . . . ?
F007 C01G C01R F00W 68.2(12) . . . . ?
C00S C01G C01R F00W -58.6(13) . . . . ?
F008 C01G C01R F00L -54.9(11) . . . . ?
F007 C01G C01R F00L -168.4(9) . . . . ?
C00S C01G C01R F00L 64.8(12) . . . . ?
F008 C01G C01R C02D 64.1(14) . . . . ?
F007 C01G C01R C02D -49.4(14) . . . . ?
C00S C01G C01R C02D -176.2(11) . . . . ?
C00Z C01B C01U C02K -72.3(11) . . . . ?
C01X C01B C01U C02K 163.0(10) . . . . ?
C02H C01B C01U C02K 34.5(11) . . . . ?
O2 P003 C01V C02C 24.8(10) . . . . ?
C02A P003 C01V C02C 149.0(9) . . . . ?
C021 P003 C01V C02C -99.1(9) . . . . ?
O2 P003 C01V C029 -158.9(10) . . . . ?
C02A P003 C01V C029 -34.7(12) . . . . ?
C021 P003 C01V C029 77.1(11) . . . . ?
C00O C00K C01W C024 176.7(9) . . . . ?
C016 C00K C01W C024 66.2(12) . . . . ?
C00O C00K C01W C02S -59.2(14) . . . . ?
C016 C00K C01W C02S -169.7(11) . . . . ?
C00O C00K C01W C02L 57.0(10) . . . . ?
C016 C00K C01W C02L -53.5(10) . . . . ?
Eu01 O8 C01Z C016 12.9(15) . . . . ?
Eu01 O8 C01Z C02L -173.7(7) . . . . ?
C029 C01V C02C C028 -0.9(19) . . . . ?
P003 C01V C02C C028 175.5(11) . . . . ?
F00W C01R C02D F02R -176.5(17) . . . . ?
F00L C01R C02D F02R 65.0(19) . . . . ?
C01G C01R C02D F02R -56(2) . . . . ?
F00W C01R C02D F02M -57(2) . . . . ?
F00L C01R C02D F02M -175.8(18) . . . . ?
C01G C01R C02D F02M 63(2) . . . . ?
F00W C01R C02D F019 62.2(17) . . . . ?
F00L C01R C02D F019 -56.3(17) . . . . ?
C01G C01R C02D F019 -177.3(12) . . . . ?
C02P C00N C02F C02T 4(2) . . . . ?
P002 C00N C02F C02T 177.4(13) . . . . ?
C00Z C01B C02H C027 54.9(10) . . . . ?
C01X C01B C02H C027 -178.0(10) . . . . ?
C01U C01B C02H C027 -54.0(11) . . . . ?
C00Z C01B C02H C01Y 172.0(10) . . . . ?
C01X C01B C02H C01Y -60.9(14) . . . . ?
C01U C01B C02H C01Y 63.1(13) . . . . ?
C00Z C01B C02H C02G -63.1(12) . . . . ?
C01X C01B C02H C02G 64.1(14) . . . . ?
C01U C01B C02H C02G -171.9(11) . . . . ?
C026 C01P C02I C023 -2(2) . . . . ?
P002 C01P C02I C023 177.7(12) . . . . ?
C01B C01U C02K C027 2.3(12) . . . . ?
O8 C01Z C02L C01H 21.6(17) . . . . ?
C016 C01Z C02L C01H -163.9(11) . . . . ?
O8 C01Z C02L C01D -104.3(11) . . . . ?
C016 C01Z C02L C01D 70.2(11) . . . . ?
O8 C01Z C02L C01W 151.7(10) . . . . ?
C016 C01Z C02L C01W -33.8(12) . . . . ?
C00O C01D C02L C01Z -72.0(11) . . . . ?
C00O C01D C02L C01H 161.3(10) . . . . ?
C00O C01D C02L C01W 31.0(12) . . . . ?
C024 C01W C02L C01Z -64.0(12) . . . . ?
C02S C01W C02L C01Z 168.7(11) . . . . ?
C00K C01W C02L C01Z 52.7(10) . . . . ?
C024 C01W C02L C01H 64.4(14) . . . . ?
C02S C01W C02L C01H -62.9(15) . . . . ?
C00K C01W C02L C01H -178.9(10) . . . . ?
C024 C01W C02L C01D -167.7(11) . . . . ?
C02S C01W C02L C01D 65.0(13) . . . . ?
C00K C01W C02L C01D -51.0(10) . . . . ?
C023 C01Q C02N C026 -4(3) . . . . ?
C02F C00N C02P C5 -9(2) . . . . ?
P002 C00N C02P C5 177.2(16) . . . . ?
C5 C01F C02T C02F 0(3) . . . . ?
C00N C02F C02T C01F 0(3) . . . . ?
F2 C1 C3 F4 -77(3) . . . . ?
C4 C1 C3 F4 55(3) . . . . ?
F5 C1 C3 F4 173(2) . . . . ?
F2 C1 C3 F7 56(3) . . . . ?
C4 C1 C3 F7 -173(2) . . . . ?
F5 C1 C3 F7 -54(3) . . . . ?
F2 C1 C3 F6 168(2) . . . . ?
C4 C1 C3 F6 -61(4) . . . . ?
F5 C1 C3 F6 58(2) . . . . ?
O5 C00Y C4 F3 151.4(9) . . . . ?
C00V C00Y C4 F3 -29.8(14) . . . . ?
O5 C00Y C4 F1 35.7(11) . . . . ?
C00V C00Y C4 F1 -145.5(9) . . . . ?
O5 C00Y C4 C1 -85.4(13) . . . . ?
C00V C00Y C4 C1 93.4(13) . . . . ?
C3 C1 C4 F3 -79(3) . . . . ?
F2 C1 C4 F3 55.9(18) . . . . ?
F5 C1 C4 F3 165.1(11) . . . . ?
C3 C1 C4 F1 32(3) . . . . ?
F2 C1 C4 F1 167.1(13) . . . . ?
F5 C1 C4 F1 -83.7(14) . . . . ?
C3 C1 C4 C00Y 155(2) . . . . ?
F2 C1 C4 C00Y -70.2(18) . . . . ?
F5 C1 C4 C00Y 39.0(16) . . . . ?
C00N C02P C5 C01F 9(3) . . . . ?
C02T C01F C5 C02P -5(3) . . . . ?
Eu01 O3 C010 C01M -7(2) . . . . ?
Eu01 O3 C010 C01N 171.4(8) . . . . ?
C00Z C01M C010 O3 0(2) . . . . ?
C027 C01M C010 O3 -177.2(15) . . . . ?
C00Z C01M C010 C01N -178.5(12) . . . . ?
C027 C01M C010 C01N 4(2) . . . . ?
F00U C01N C010 O3 -108.2(13) . . . . ?
F00C C01N C010 O3 134.2(12) . . . . ?
C00R C01N C010 O3 11.7(19) . . . . ?
F00U C01N C010 C01M 70.6(16) . . . . ?
F00C C01N C010 C01M -46.9(17) . . . . ?
C00R C01N C010 C01M -169.4(13) . . . . ?
C01I C00J C011 C014 3.0(15) . . . . ?
C01S C00J C011 C014 -172.0(10) . . . . ?
C13 C02O C12 C7 9(5) . . . . ?
C021 C7 C12 C02O -2(5) . . . . ?
C01K C01E C013 C01L 56.8(15) . . . . ?
C025 C01E C013 C01L -171.6(12) . . . . ?
C00Q C01E C013 C01L -65.2(13) . . . . ?
C01K C01E C013 C015 178.1(9) . . . . ?
C025 C01E C013 C015 -50.3(9) . . . . ?
C00Q C01E C013 C015 56.1(8) . . . . ?
C01K C01E C013 C01J -66.7(15) . . . . ?
C025 C01E C013 C01J 64.9(13) . . . . ?
C00Q C01E C013 C01J 171.3(12) . . . . ?
C12 C02O C13 C02E -5(5) . . . . ?
C021 C02E C13 C02O -5(5) . . . . ?
C00J C011 C014 C00X -1.1(16) . . . . ?
C01C C00X C014 C011 -3.0(15) . . . . ?
C017 C00X C014 C011 176.0(9) . . . . ?
C025 C01O C015 C00V 67.2(11) . . . . ?
C025 C01O C015 C013 -37.4(10) . . . . ?
C00Y C00V C015 C01O 99.3(12) . . . . ?
C00Q C00V C015 C01O -72.0(10) . . . . ?
C00Y C00V C015 C013 -152.5(11) . . . . ?
C00Q C00V C015 C013 36.2(11) . . . . ?
C01L C013 C015 C01O 174.9(10) . . . . ?
C01E C013 C015 C01O 54.0(9) . . . . ?
C01J C013 C015 C01O -60.8(15) . . . . ?
C01L C013 C015 C00V 64.7(13) . . . . ?
C01E C013 C015 C00V -56.2(9) . . . . ?
C01J C013 C015 C00V -171.0(13) . . . . ?
O8 C01Z C016 C00S -12.1(17) . . . . ?
C02L C01Z C016 C00S 173.8(10) . . . . ?
O8 C01Z C016 C00K 171.7(10) . . . . ?
C02L C01Z C016 C00K -2.4(12) . . . . ?
O7 C00S C016 C01Z 0.8(16) . . . . ?
C01G C00S C016 C01Z 178.6(10) . . . . ?
O7 C00S C016 C00K 175.9(10) . . . . ?
C01G C00S C016 C00K -6.2(16) . . . . ?
C00O C00K C016 C01Z -70.1(11) . . . . ?
C01W C00K C016 C01Z 36.4(11) . . . . ?
C00O C00K C016 C00S 114.0(12) . . . . ?
C01W C00K C016 C00S -139.5(11) . . . . ?
C029 C02U C020 C028 1(3) . . . . ?
C12 C7 C021 C02E -8(4) . . . . ?
C12 C7 C021 P003 -178(2) . . . . ?
C13 C02E C021 C7 11(3) . . . . ?
C13 C02E C021 P003 -179.3(17) . . . . ?
O2 P003 C021 C7 54.7(16) . . . . ?
C02A P003 C021 C7 -68.3(16) . . . . ?
C01V P003 C021 C7 179.4(15) . . . . ?
O2 P003 C021 C02E -115.1(13) . . . . ?
C02A P003 C021 C02E 121.9(13) . . . . ?
C01V P003 C021 C02E 9.6(14) . . . . ?
C02N C01Q C023 C02I 7(3) . . . . ?
C01P C02I C023 C01Q -4(3) . . . . ?
C01K C01E C025 C01O 163.4(10) . . . . ?
C00Q C01E C025 C01O -70.2(10) . . . . ?
C013 C01E C025 C01O 31.2(10) . . . . ?
C015 C01O C025 C01E 3.1(11) . . . . ?
C01Q C02N C026 C01P -3(3) . . . . ?
C02I C01P C026 C02N 6(3) . . . . ?
P002 C01P C026 C02N -174.4(16) . . . . ?
C01U C02K C027 C02H -38.8(12) . . . . ?
C01U C02K C027 C01M 69.5(12) . . . . ?
C01B C02H C027 C02K 57.8(10) . . . . ?
C01Y C02H C027 C02K -61.6(15) . . . . ?
C02G C02H C027 C02K 172.8(11) . . . . ?
C01B C02H C027 C01M -55.5(12) . . . . ?
C01Y C02H C027 C01M -174.9(13) . . . . ?
C02G C02H C027 C01M 59.5(14) . . . . ?
C010 C01M C027 C02K 104.9(18) . . . . ?
C00Z C01M C027 C02K -72.8(12) . . . . ?
C010 C01M C027 C02H -144.7(16) . . . . ?
C00Z C01M C027 C02H 37.6(14) . . . . ?
C02U C020 C028 C02C -2(3) . . . . ?
C01V C02C C028 C020 1(2) . . . . ?
C020 C02U C029 C01V -1(3) . . . . ?
C02C C01V C029 C02U 1(2) . . . . ?
P003 C01V C029 C02U -175.4(14) . . . . ?

_refine_diff_density_max         3.274
_refine_diff_density_min         -0.621
_refine_diff_density_rms         0.111



