# Electronic Supplementary Material (ESI) for Materials Horizons.
# This journal is © The Royal Society of Chemistry 2022

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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data_111111111
_database_code_depnum_ccdc_archive 'CCDC 2116501'
loop_
_audit_author_name
_audit_author_address
'zhongxu Fan'
;Xinjiang University
China
;
_audit_update_record             
;
2021-10-19 deposited with the CCDC.	2022-11-25 downloaded from the CCDC.
;
_audit_creation_date             2021-08-04
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2016/6
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'Cd Rb2 S10 Si4'
_chemical_formula_sum            'Cd Rb2 S10 Si4'
_chemical_formula_weight         716.30
_chemical_absolute_configuration ?
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Cd Cd -0.8075 1.2024 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rb Rb -0.9393 2.9676 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           33
_space_group_name_H-M_alt        'P n a 21'
_space_group_name_Hall           'P 2c -2n'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, z+1/2'
'x+1/2, -y+1/2, z'
'-x+1/2, y+1/2, z+1/2'

_cell_length_a                   18.6378(6)
_cell_length_b                   9.1309(3)
_cell_length_c                   10.6136(3)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     1806.22(10)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    5068
_cell_measurement_temperature    303.0
_cell_measurement_theta_max      27.46
_cell_measurement_theta_min      2.48
_shelx_estimated_absorpt_T_max   0.551
_shelx_estimated_absorpt_T_min   0.352
_exptl_absorpt_coefficient_mu    7.959
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.5892
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear light colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    2.634
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1352
_exptl_crystal_size_max          0.166
_exptl_crystal_size_mid          0.093
_exptl_crystal_size_min          0.085
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0407
_diffrn_reflns_av_unetI/netI     0.0629
_diffrn_reflns_Laue_measured_fraction_full 0.992
_diffrn_reflns_Laue_measured_fraction_max 0.987
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            10977
_diffrn_reflns_point_group_measured_fraction_full 0.931
_diffrn_reflns_point_group_measured_fraction_max 0.919
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.547
_diffrn_reflns_theta_min         2.185
_diffrn_ambient_temperature      303.0
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.987
_diffrn_measurement_device_type  'PHOTON III C28 detector'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.766
_reflns_Friedel_fraction_full    0.863
_reflns_Friedel_fraction_max     0.842
_reflns_number_gt                3437
_reflns_number_total             3825
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.38A (?, 2016)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.38A (?, 2016)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL (Sheldrick, 2008)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         0.486
_refine_diff_density_min         -0.630
_refine_diff_density_rms         0.135
_refine_ls_abs_structure_details 
;
 Flack x determined using 1369 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   0.016(7)
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.900
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     154
_refine_ls_number_reflns         3825
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.0331
_refine_ls_R_factor_gt           0.0265
_refine_ls_restrained_S_all      0.900
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     'w=1/[σ²(Fo²)] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0564
_refine_ls_wR_factor_ref         0.0638
_refine_special_details          ?
_olex2_refinement_description    
;
;
_atom_sites_solution_hydrogens   .
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Cd1 Cd 0.91405(3) 0.33776(6) 0.25530(5) 0.02279(13) Uani 1 1 d . . . . .
Rb1 Rb 0.82747(4) -0.14545(8) 0.50091(9) 0.03519(19) Uani 1 1 d . . . . .
Rb2 Rb 0.40181(5) 0.14277(9) 0.74593(9) 0.0415(2) Uani 1 1 d . . . . .
S1 S 0.55659(9) 0.14446(19) 0.5007(2) 0.0226(3) Uani 1 1 d . . . . .
S2 S 0.76030(9) 0.49962(19) 0.50153(19) 0.0245(4) Uani 1 1 d . . . . .
S3 S 0.87244(9) 0.2092(2) 0.45320(17) 0.0219(4) Uani 1 1 d . . . . .
S4 S 0.70607(9) 0.2051(2) 0.30970(17) 0.0234(4) Uani 1 1 d . . . . .
S5 S 0.57995(10) 0.1087(2) 0.81729(17) 0.0227(4) Uani 1 1 d . . . . .
S6 S 0.60772(10) 0.4414(2) 0.69574(17) 0.0241(4) Uani 1 1 d . . . . .
S7 S 0.64939(11) 0.7777(2) 0.55103(18) 0.0242(4) Uani 1 1 d . . . . .
S8 S 0.73048(10) 0.1561(2) 0.63719(17) 0.0217(4) Uani 1 1 d . . . . .
S9 S 0.58579(10) 0.4986(2) 0.37310(18) 0.0264(4) Uani 1 1 d . . . . .
Si1 Si 0.76621(10) 0.2698(2) 0.47119(17) 0.0177(4) Uani 1 1 d . . . . .
Si2 Si 0.59678(10) 0.2683(2) 0.34508(18) 0.0197(4) Uani 1 1 d . . . . .
S10 S 0.54258(10) 0.2103(2) 0.18375(17) 0.0269(4) Uani 1 1 d . . . . .
Si3 Si 0.61919(10) 0.2117(2) 0.65910(18) 0.0180(4) Uani 1 1 d . . . . .
Si4 Si 0.64991(11) 0.5517(2) 0.53434(17) 0.0197(4) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Cd1 Rb2 4.4210(9) 4_654 ?
Cd1 S3 2.5279(19) . ?
Cd1 S5 2.5621(19) 4_654 ?
Cd1 S7 2.5297(19) 4_644 ?
Cd1 S10 2.5511(19) 3 ?
Rb1 Rb2 5.4132(12) 3_545 ?
Rb1 Rb2 5.4544(12) 3 ?
Rb1 Rb2 5.0581(13) 2_654 ?
Rb1 S2 3.4743(18) 1_545 ?
Rb1 S3 3.383(2) . ?
Rb1 S4 3.605(2) 4_645 ?
Rb1 S5 3.437(2) 4_644 ?
Rb1 S6 3.547(2) 4_644 ?
Rb1 S7 3.434(2) 1_545 ?
Rb1 S8 3.597(2) . ?
Rb1 Si2 3.995(2) 4_645 ?
Rb1 S10 3.372(2) 4_645 ?
Rb2 S1 3.885(2) . ?
Rb2 S1 3.846(2) 2_655 ?
Rb2 S2 3.921(2) 3_455 ?
Rb2 S3 3.432(2) 3_455 ?
Rb2 S4 3.819(2) 2_655 ?
Rb2 S5 3.420(2) . ?
Rb2 S7 3.453(2) 2_665 ?
Rb2 S8 3.860(2) 3_455 ?
Rb2 S9 3.549(2) 2_665 ?
Rb2 S10 3.450(2) 2_655 ?
S1 Si2 2.137(3) . ?
S1 Si3 2.136(3) . ?
S2 Si1 2.125(3) . ?
S2 Si4 2.140(3) . ?
S3 Si1 2.065(3) . ?
S4 Si1 2.132(3) . ?
S4 Si2 2.150(3) . ?
S5 Si3 2.059(3) . ?
S6 Si3 2.144(3) . ?
S6 Si4 2.137(3) . ?
S7 Si4 2.071(3) . ?
S8 Si1 2.151(3) . ?
S8 Si3 2.148(3) . ?
S9 Si2 2.134(3) . ?
S9 Si4 2.143(3) . ?
Si2 S10 2.057(3) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
S3 Cd1 Rb2 123.32(5) . 4_654 ?
S3 Cd1 S5 104.37(6) . 4_654 ?
S3 Cd1 S7 117.91(6) . 4_644 ?
S3 Cd1 S10 117.10(6) . 3 ?
S5 Cd1 Rb2 50.48(4) 4_654 4_654 ?
S7 Cd1 Rb2 118.70(5) 4_644 4_654 ?
S7 Cd1 S5 116.74(6) 4_644 4_654 ?
S7 Cd1 S10 98.42(6) 4_644 3 ?
S10 Cd1 Rb2 51.15(5) 3 4_654 ?
S10 Cd1 S5 101.63(6) 3 4_654 ?
Rb2 Rb1 Rb2 118.51(2) 2_654 3_545 ?
Rb2 Rb1 Rb2 117.75(2) 2_654 3 ?
Rb2 Rb1 Rb2 114.32(2) 3_545 3 ?
S2 Rb1 Rb2 72.61(4) 1_545 2_654 ?
S2 Rb1 Rb2 46.27(3) 1_545 3_545 ?
S2 Rb1 Rb2 151.12(4) 1_545 3 ?
S2 Rb1 S4 65.33(5) 1_545 4_645 ?
S2 Rb1 S6 109.46(5) 1_545 4_644 ?
S2 Rb1 S8 122.15(5) 1_545 . ?
S2 Rb1 Si2 86.66(5) 1_545 4_645 ?
S3 Rb1 Rb2 144.24(4) . 3_545 ?
S3 Rb1 Rb2 97.16(4) . 2_654 ?
S3 Rb1 Rb2 37.15(3) . 3 ?
S3 Rb1 S2 169.25(6) . 1_545 ?
S3 Rb1 S4 122.78(5) . 4_645 ?
S3 Rb1 S5 114.58(5) . 4_644 ?
S3 Rb1 S6 64.21(4) . 4_644 ?
S3 Rb1 S7 117.28(5) . 1_545 ?
S3 Rb1 S8 56.77(4) . . ?
S3 Rb1 Si2 103.77(5) . 4_645 ?
S4 Rb1 Rb2 85.94(3) 4_645 3 ?
S4 Rb1 Rb2 109.99(4) 4_645 2_654 ?
S4 Rb1 Rb2 44.76(3) 4_645 3_545 ?
S4 Rb1 Si2 32.35(4) 4_645 4_645 ?
S5 Rb1 Rb2 97.12(4) 4_644 2_654 ?
S5 Rb1 Rb2 133.82(4) 4_644 3 ?
S5 Rb1 Rb2 66.17(3) 4_644 3_545 ?
S5 Rb1 S2 64.70(5) 4_644 1_545 ?
S5 Rb1 S4 110.80(5) 4_644 4_645 ?
S5 Rb1 S6 57.14(4) 4_644 4_644 ?
S5 Rb1 S8 168.55(5) 4_644 . ?
S5 Rb1 Si2 102.25(4) 4_644 4_645 ?
S6 Rb1 Rb2 99.25(3) 4_644 3 ?
S6 Rb1 Rb2 122.63(4) 4_644 3_545 ?
S6 Rb1 Rb2 78.35(4) 4_644 2_654 ?
S6 Rb1 S4 166.90(5) 4_644 4_645 ?
S6 Rb1 S8 111.54(5) 4_644 . ?
S6 Rb1 Si2 139.36(5) 4_644 4_645 ?
S7 Rb1 Rb2 42.89(4) 1_545 2_654 ?
S7 Rb1 Rb2 110.10(4) 1_545 3 ?
S7 Rb1 Rb2 90.08(4) 1_545 3_545 ?
S7 Rb1 S2 57.37(4) 1_545 1_545 ?
S7 Rb1 S4 67.30(5) 1_545 4_645 ?
S7 Rb1 S5 116.07(5) 1_545 4_644 ?
S7 Rb1 S6 121.09(5) 1_545 4_644 ?
S7 Rb1 S8 66.96(4) 1_545 . ?
S7 Rb1 Si2 99.18(5) 1_545 4_645 ?
S8 Rb1 Rb2 77.70(3) . 2_654 ?
S8 Rb1 Rb2 125.28(4) . 3_545 ?
S8 Rb1 Rb2 44.91(3) . 3 ?
S8 Rb1 S4 80.63(5) . 4_645 ?
S8 Rb1 Si2 87.75(5) . 4_645 ?
Si2 Rb1 Rb2 68.91(3) 4_645 3 ?
Si2 Rb1 Rb2 142.07(4) 4_645 2_654 ?
Si2 Rb1 Rb2 45.96(3) 4_645 3_545 ?
S10 Rb1 Rb2 156.46(4) 4_645 2_654 ?
S10 Rb1 Rb2 82.63(4) 4_645 3 ?
S10 Rb1 Rb2 37.99(4) 4_645 3_545 ?
S10 Rb1 S2 83.88(5) 4_645 1_545 ?
S10 Rb1 S3 106.38(5) 4_645 . ?
S10 Rb1 S4 56.86(4) 4_645 4_645 ?
S10 Rb1 S5 73.18(5) 4_645 4_644 ?
S10 Rb1 S6 111.61(5) 4_645 4_644 ?
S10 Rb1 S7 121.69(5) 4_645 1_545 ?
S10 Rb1 S8 115.37(5) 4_645 . ?
S10 Rb1 Si2 30.99(4) 4_645 4_645 ?
Cd1 Rb2 Rb1 130.31(2) 4_645 2_655 ?
S1 Rb2 Cd1 56.02(3) . 4_645 ?
S1 Rb2 Cd1 52.99(3) 2_655 4_645 ?
S1 Rb2 Rb1 78.31(3) 2_655 2_655 ?
S1 Rb2 Rb1 170.28(4) . 2_655 ?
S1 Rb2 S1 108.90(2) 2_655 . ?
S1 Rb2 S2 93.30(4) . 3_455 ?
S1 Rb2 S2 112.00(4) 2_655 3_455 ?
S1 Rb2 S8 134.54(5) 2_655 3_455 ?
S2 Rb2 Cd1 109.16(3) 3_455 4_645 ?
S2 Rb2 Rb1 77.72(3) 3_455 2_655 ?
S3 Rb2 Cd1 113.09(4) 3_455 4_645 ?
S3 Rb2 Rb1 110.35(4) 3_455 2_655 ?
S3 Rb2 S1 159.58(5) 3_455 2_655 ?
S3 Rb2 S1 60.69(4) 3_455 . ?
S3 Rb2 S2 54.86(4) 3_455 3_455 ?
S3 Rb2 S4 113.82(5) 3_455 2_655 ?
S3 Rb2 S7 136.22(5) 3_455 2_665 ?
S3 Rb2 S8 53.85(4) 3_455 3_455 ?
S3 Rb2 S9 89.51(5) 3_455 2_665 ?
S3 Rb2 S10 104.04(5) 3_455 2_655 ?
S4 Rb2 Cd1 83.16(3) 2_655 4_645 ?
S4 Rb2 Rb1 57.62(3) 2_655 2_655 ?
S4 Rb2 S1 54.16(4) 2_655 2_655 ?
S4 Rb2 S1 120.85(4) 2_655 . ?
S4 Rb2 S2 59.17(4) 2_655 3_455 ?
S4 Rb2 S8 90.75(4) 2_655 3_455 ?
S5 Rb2 Cd1 35.31(3) . 4_645 ?
S5 Rb2 Rb1 134.60(4) . 2_655 ?
S5 Rb2 S1 65.57(4) . 2_655 ?
S5 Rb2 S1 55.10(4) . . ?
S5 Rb2 S2 140.30(5) . 3_455 ?
S5 Rb2 S3 113.03(5) . 3_455 ?
S5 Rb2 S4 113.34(5) . 2_655 ?
S5 Rb2 S7 94.57(5) . 2_665 ?
S5 Rb2 S8 155.88(5) . 3_455 ?
S5 Rb2 S9 86.36(5) . 2_665 ?
S5 Rb2 S10 70.46(5) . 2_655 ?
S7 Rb2 Cd1 109.02(4) 2_665 4_645 ?
S7 Rb2 Rb1 42.59(3) 2_665 2_655 ?
S7 Rb2 S1 62.60(4) 2_665 2_655 ?
S7 Rb2 S1 146.35(5) 2_665 . ?
S7 Rb2 S2 120.28(5) 2_665 3_455 ?
S7 Rb2 S4 82.14(5) 2_665 2_655 ?
S7 Rb2 S8 87.23(5) 2_665 3_455 ?
S7 Rb2 S9 57.81(5) 2_665 2_665 ?
S8 Rb2 Cd1 161.55(4) 3_455 4_645 ?
S8 Rb2 Rb1 57.24(3) 3_455 2_655 ?
S8 Rb2 S1 114.33(5) 3_455 . ?
S8 Rb2 S2 53.38(4) 3_455 3_455 ?
S9 Rb2 Cd1 121.47(4) 2_665 4_645 ?
S9 Rb2 Rb1 81.20(3) 2_665 2_655 ?
S9 Rb2 S1 101.70(4) 2_665 . ?
S9 Rb2 S1 110.40(5) 2_665 2_655 ?
S9 Rb2 S2 126.96(5) 2_665 3_455 ?
S9 Rb2 S4 137.23(5) 2_665 2_655 ?
S9 Rb2 S8 74.26(4) 2_665 3_455 ?
S10 Rb2 Cd1 35.16(3) 2_655 4_645 ?
S10 Rb2 Rb1 111.14(4) 2_655 2_655 ?
S10 Rb2 S1 55.72(4) 2_655 2_655 ?
S10 Rb2 S1 69.67(4) 2_655 . ?
S10 Rb2 S2 76.45(4) 2_655 3_455 ?
S10 Rb2 S4 54.20(4) 2_655 2_655 ?
S10 Rb2 S7 117.32(5) 2_655 2_665 ?
S10 Rb2 S8 129.49(5) 2_655 3_455 ?
S10 Rb2 S9 156.24(5) 2_655 2_665 ?
Rb2 S1 Rb2 128.17(5) 2_654 . ?
Si2 S1 Rb2 141.26(9) . . ?
Si2 S1 Rb2 75.33(8) . 2_654 ?
Si3 S1 Rb2 129.73(9) . 2_654 ?
Si3 S1 Rb2 83.08(8) . . ?
Si3 S1 Si2 105.34(10) . . ?
Rb1 S2 Rb2 93.91(4) 1_565 3 ?
Si1 S2 Rb1 154.40(9) . 1_565 ?
Si1 S2 Rb2 74.82(7) . 3 ?
Si1 S2 Si4 107.08(10) . . ?
Si4 S2 Rb1 98.01(8) . 1_565 ?
Si4 S2 Rb2 127.78(9) . 3 ?
Cd1 S3 Rb1 130.14(7) . . ?
Cd1 S3 Rb2 121.37(7) . 3 ?
Rb1 S3 Rb2 106.31(5) . 3 ?
Si1 S3 Cd1 104.28(9) . . ?
Si1 S3 Rb1 90.29(8) . . ?
Si1 S3 Rb2 87.92(8) . 3 ?
Rb1 S4 Rb2 93.58(4) 4_654 2_654 ?
Si1 S4 Rb1 135.81(9) . 4_654 ?
Si1 S4 Rb2 130.55(9) . 2_654 ?
Si1 S4 Si2 106.45(10) . . ?
Si2 S4 Rb1 83.85(7) . 4_654 ?
Si2 S4 Rb2 75.86(7) . 2_654 ?
Cd1 S5 Rb1 138.96(7) 4_645 4_655 ?
Cd1 S5 Rb2 94.21(6) 4_645 . ?
Rb2 S5 Rb1 123.60(6) . 4_655 ?
Si3 S5 Cd1 102.49(9) . 4_645 ?
Si3 S5 Rb1 89.17(8) . 4_655 ?
Si3 S5 Rb2 97.04(8) . . ?
Si3 S6 Rb1 85.00(8) . 4_655 ?
Si4 S6 Rb1 135.40(10) . 4_655 ?
Si4 S6 Si3 106.20(10) . . ?
Cd1 S7 Rb1 122.69(7) 4_655 1_565 ?
Cd1 S7 Rb2 128.97(7) 4_655 2_664 ?
Rb1 S7 Rb2 94.52(5) 1_565 2_664 ?
Si4 S7 Cd1 106.96(9) . 4_655 ?
Si4 S7 Rb1 100.71(9) . 1_565 ?
Si4 S7 Rb2 97.51(8) . 2_664 ?
Rb1 S8 Rb2 93.94(4) . 3 ?
Si1 S8 Rb1 83.37(7) . . ?
Si1 S8 Rb2 76.06(7) . 3 ?
Si3 S8 Rb1 135.21(9) . . ?
Si3 S8 Rb2 130.84(9) . 3 ?
Si3 S8 Si1 105.87(10) . . ?
Si2 S9 Rb2 148.21(10) . 2_664 ?
Si2 S9 Si4 106.30(11) . . ?
Si4 S9 Rb2 93.37(8) . 2_664 ?
S2 Si1 Rb2 73.81(7) . 3 ?
S2 Si1 S4 111.62(11) . . ?
S2 Si1 S8 109.66(10) . . ?
S3 Si1 Rb2 60.51(7) . 3 ?
S3 Si1 S2 109.16(11) . . ?
S3 Si1 S4 110.83(11) . . ?
S3 Si1 S8 104.08(10) . . ?
S4 Si1 Rb2 171.29(9) . 3 ?
S4 Si1 S8 111.21(11) . . ?
S8 Si1 Rb2 71.95(7) . 3 ?
S1 Si2 Rb2 72.64(8) . 2_654 ?
S1 Si2 S4 108.96(11) . . ?
S4 Si2 Rb2 71.81(8) . 2_654 ?
S9 Si2 Rb2 170.84(9) . 2_654 ?
S9 Si2 S1 112.34(11) . . ?
S9 Si2 S4 112.33(11) . . ?
S10 Si2 Rb2 62.02(8) . 2_654 ?
S10 Si2 S1 109.56(11) . . ?
S10 Si2 S4 104.52(11) . . ?
S10 Si2 S9 108.82(12) . . ?
Cd1 S10 Rb1 155.94(8) 3_455 4_654 ?
Cd1 S10 Rb2 93.69(6) 3_455 2_654 ?
Rb1 S10 Rb2 105.03(6) 4_654 2_654 ?
Si2 S10 Cd1 104.93(9) . 3_455 ?
Si2 S10 Rb1 91.47(8) . 4_654 ?
Si2 S10 Rb2 86.20(9) . 2_654 ?
S1 Si3 Rb1 161.36(9) . 4_655 ?
S1 Si3 S6 111.69(11) . . ?
S1 Si3 S8 111.97(11) . . ?
S5 Si3 Rb1 59.69(7) . 4_655 ?
S5 Si3 S1 108.44(11) . . ?
S5 Si3 S6 105.30(11) . . ?
S5 Si3 S8 108.85(11) . . ?
S6 Si3 Rb1 62.56(7) . 4_655 ?
S6 Si3 S8 110.32(11) . . ?
S8 Si3 Rb1 86.27(8) . 4_655 ?
S2 Si4 S9 110.85(11) . . ?
S6 Si4 S2 112.30(11) . . ?
S6 Si4 S9 109.17(11) . . ?
S7 Si4 S2 103.88(11) . . ?
S7 Si4 S6 113.53(11) . . ?
S7 Si4 S9 106.91(11) . . ?

_olex2_submission_special_instructions 'No special instructions were received'
