# Electronic Supplementary Material (ESI) for Nanoscale Horizons.
# This journal is © The Royal Society of Chemistry 2022

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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#######################################################################

data_au13ag12-s
_database_code_depnum_ccdc_archive 'CCDC 2183917'
loop_
_audit_author_name
_audit_author_address
'Xi Xi Kang'
;Anhui University
China
;
_audit_update_record             
;
2022-09-21 deposited with the CCDC.	2022-09-23 downloaded from the CCDC.
;
_audit_creation_date             2022-09-16
_audit_creation_method           
;
Olex2 1.5-dev
(compiled 2022.07.25 svn.r36e0af09 for OlexSys, GUI svn.r6444)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C220 H195 Ag8.92 Au16.08 Cl2 P10 S5, 38[H2O]'
_chemical_formula_sum            'C220 H271 Ag8.92 Au16.08 Cl2 O38 P10 S5'
_chemical_formula_weight         8193.67
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag 0.1306 4.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -4.4197 7.2980 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.3331 0.5567 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   20.3734(3)
_cell_length_b                   22.9783(3)
_cell_length_c                   32.3446(4)
_cell_angle_alpha                70.7470(10)
_cell_angle_beta                 83.8450(10)
_cell_angle_gamma                67.6260(10)
_cell_volume                     13216.1(3)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    129140
_cell_measurement_temperature    150
_cell_measurement_theta_max      70.43
_cell_measurement_theta_min      3.77
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    23.065
_exptl_absorpt_correction_T_max  0.0808
_exptl_absorpt_correction_T_min  0.0013
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
STOE X-Red32, absorption correction by Gaussian integration, analogous to
P. Coppens, "The Evaluation of Absorption and Extinction in Single-Crystal
Structure Analysis", published in: F. R. Ahmed (Editor), "Crystallographic
Computing", Munksgaard, Copenhagen (1970), 255 - 270.
Afterwards scaling of reflection intensities was performed within STOE LANA.
J. Koziskova, F. Hahn, J. Richter, J. Kozisek, "Comparison of different
absorption corrections on the model structure of tetrakis(μ₂-acetato)-
diaqua-di-copper(II)", Acta Chimica Slovaca, vol. 9, no. 2, 2016, pp. 136 - 140.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            black
_exptl_crystal_colour_primary    black
_exptl_crystal_density_diffrn    2.059
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             7697
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
1 0 6 0.1976
10 -6 -15 0.1797
-4 30 -3 0.1308
-30 -23 1 0.1674
30 -1 30 0.1784
-20 -30 -21 0.2407
-16 5 30 0.2210
1 1 -6 0.2563
6 13 15 0.2896
-15 4 -8 0.2049
-4 -30 -1 0.2058
30 19 -7 0.1878
30 -24 1 0.1653
-15 -11 -6 0.1654
8 12 -15 0.1620
30 19 23 0.2610
-13 -16 30 0.1617
-21 30 8 0.1560
1 -2 -5 0.2052

_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.15
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0425
_diffrn_reflns_av_unetI/netI     0.0377
_diffrn_reflns_Laue_measured_fraction_full 0.965
_diffrn_reflns_Laue_measured_fraction_max 0.965
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       37
_diffrn_reflns_limit_l_min       -36
_diffrn_reflns_number            89666
_diffrn_reflns_point_group_measured_fraction_full 0.965
_diffrn_reflns_point_group_measured_fraction_max 0.965
_diffrn_reflns_theta_full        62.500
_diffrn_reflns_theta_max         62.499
_diffrn_reflns_theta_min         4.695
_diffrn_ambient_temperature      150.00
_diffrn_detector_area_resol_mean 5.81
_diffrn_detector_type            'DECTRIS PILATUS 300K'
_diffrn_measured_fraction_theta_full 0.965
_diffrn_measured_fraction_theta_max 0.965
_diffrn_measurement_details      '1932 frames, detector distance = 60 mm'
_diffrn_measurement_device       'Eulerian 4-circle diffractometer'
_diffrn_measurement_device_type  'STOE STADIVARI'
_diffrn_measurement_method       'rotation method, ω scans'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54186
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                34167
_reflns_number_total             40676
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'X-Area Recipe 1.33.0.0 (STOE, 2015)'
_computing_data_collection       'X-Area Pilatus3_SV 1.31.153.0 (STOE, 2018)'
_computing_data_reduction        
;
X-Area Integrate 1.74.2.0 (STOE, 2018)
X-Area LANA 1.75.3.0 (STOE, 2018)
;
_computing_molecular_graphics    'Olex2 1.5-dev (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5-dev (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT  (Sheldrick, 2015)'
_refine_diff_density_max         3.617
_refine_diff_density_min         -2.594
_refine_diff_density_rms         0.261
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.027
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     2299
_refine_ls_number_reflns         40676
_refine_ls_number_restraints     6780
_refine_ls_R_factor_all          0.0765
_refine_ls_R_factor_gt           0.0688
_refine_ls_restrained_S_all      0.971
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1556P)²+26.1934P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1975
_refine_ls_wR_factor_ref         0.2068
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
2. Shared sites
{Ag1E, Au18}
{Ag14, Au1F}
{Au1H, Ag7}
{Au16, Ag1M}
{Au1N, Ag3}
{Au1, Ag1I}
{Ag1L, Au15}
{Ag19, Au1K}
{Ag1J, Au17}
{Ag1D, Au13}
{Au, Ag1G}
3. Uiso/Uaniso restraints and constraints
P16 \\sim C1 \\sim C2 \\sim C3 \\sim C4 \\sim C5 \\sim C11 \\sim C10 \\sim C12
\\sim C6 \\sim C13 \\sim C14 \\sim C15 \\sim C9 \\sim C16 \\sim C8 \\sim C17
\\sim C18 \\sim C19 \\sim C20 \\sim C21 \\sim C22 \\sim C23 \\sim C24 \\sim C25
\\sim C26 \\sim C27 \\sim C28 \\sim C29 \\sim C30 \\sim C31 \\sim C32 \\sim C33
\\sim C34 \\sim C35 \\sim C36 \\sim C37 \\sim C38 \\sim C39 \\sim C40 \\sim C41
\\sim C42 \\sim C43 \\sim C44 \\sim C45 \\sim C46 \\sim C47 \\sim C7 \\sim C53
\\sim C54 \\sim C55 \\sim C56 \\sim C57 \\sim C58 \\sim C59 \\sim C60 \\sim C61
\\sim C62 \\sim C63 \\sim C64 \\sim C65 \\sim C66 \\sim C67 \\sim C68 \\sim C69
\\sim C70 \\sim C71 \\sim C72 \\sim C73 \\sim C74 \\sim C75 \\sim C76 \\sim C77
\\sim C78 \\sim C84 \\sim C85 \\sim C86 \\sim C87 \\sim C79 \\sim C88 \\sim C89
\\sim C90 \\sim C91 \\sim C92 \\sim C93 \\sim C94 \\sim C95 \\sim C96 \\sim C97
\\sim C98 \\sim C104 \\sim C105 \\sim C48 \\sim C106 \\sim C107 \\sim C108
\\sim C81 \\sim C109 \\sim C110 \\sim C111 \\sim C112 \\sim C113 \\sim C114
\\sim C115 \\sim C116 \\sim C117 \\sim C118 \\sim C103 \\sim C119 \\sim C120
\\sim C121 \\sim C122 \\sim C123 \\sim C124 \\sim C125 \\sim C126 \\sim C127
\\sim C128 \\sim C129 \\sim C130 \\sim C131 \\sim C132 \\sim C133 \\sim C134
\\sim C135 \\sim C136 \\sim C137 \\sim C80 \\sim C138 \\sim C139 \\sim C140
\\sim C141 \\sim C142 \\sim C143 \\sim C144 \\sim C145 \\sim C146 \\sim C147
\\sim C148 \\sim C149 \\sim C150 \\sim C83 \\sim C151 \\sim C152 \\sim C153
\\sim C82 \\sim C154 \\sim C155 \\sim C156 \\sim C162 \\sim C163 \\sim C164
\\sim C165 \\sim C166 \\sim C167 \\sim C168 \\sim C169 \\sim C170 \\sim C161
\\sim C171 \\sim C172 \\sim C173 \\sim C174 \\sim C50 \\sim C175 \\sim C176
\\sim C177 \\sim C51 \\sim C178 \\sim C179 \\sim C180 \\sim C49 \\sim C181
\\sim C182 \\sim C183 \\sim C184 \\sim C185 \\sim C52 \\sim C186 \\sim C187
\\sim C188 \\sim C189 \\sim C190 \\sim C191 \\sim C157 \\sim C192 \\sim C193
\\sim C194 \\sim C195 \\sim C196 \\sim C197 \\sim C198 \\sim C199 \\sim C200
\\sim C201 \\sim C202 \\sim C203 \\sim C204 \\sim C205 \\sim C206 \\sim C207
\\sim C99 \\sim C208 \\sim C209 \\sim C210 \\sim C211 \\sim C212 \\sim C100
\\sim C102 \\sim C101 \\sim C213 \\sim C214 \\sim C215 \\sim C216 \\sim C217
\\sim C218 \\sim C219 \\sim C220 \\sim C160 \\sim C159 \\sim C158: within 3.8A
with sigma of 0.01 and sigma for terminal atoms of 0.02 within 3.8A
S18 \\sim C137: within 3.8A with sigma of 0.01 and sigma for terminal atoms of
0.02 within 3.8A
Uanis(P16) \\sim Ueq, Uanis(C1) \\sim Ueq, Uanis(C2) \\sim Ueq, Uanis(C3) \\sim
Ueq, Uanis(C4) \\sim Ueq, Uanis(C5) \\sim Ueq, Uanis(C11) \\sim Ueq, Uanis(C10)
\\sim Ueq, Uanis(C12) \\sim Ueq, Uanis(C6) \\sim Ueq, Uanis(C13) \\sim Ueq,
Uanis(C14) \\sim Ueq, Uanis(C15) \\sim Ueq, Uanis(C9) \\sim Ueq, Uanis(C16)
\\sim Ueq, Uanis(C8) \\sim Ueq, Uanis(C17) \\sim Ueq, Uanis(C18) \\sim Ueq,
Uanis(C19) \\sim Ueq, Uanis(C20) \\sim Ueq, Uanis(C21) \\sim Ueq, Uanis(C22)
\\sim Ueq, Uanis(C23) \\sim Ueq, Uanis(C24) \\sim Ueq, Uanis(C25) \\sim Ueq,
Uanis(C26) \\sim Ueq, Uanis(C27) \\sim Ueq, Uanis(C28) \\sim Ueq, Uanis(C29)
\\sim Ueq, Uanis(C30) \\sim Ueq, Uanis(C31) \\sim Ueq, Uanis(C32) \\sim Ueq,
Uanis(C33) \\sim Ueq, Uanis(C34) \\sim Ueq, Uanis(C35) \\sim Ueq, Uanis(C36)
\\sim Ueq, Uanis(C37) \\sim Ueq, Uanis(C38) \\sim Ueq, Uanis(C39) \\sim Ueq,
Uanis(C40) \\sim Ueq, Uanis(C41) \\sim Ueq, Uanis(C42) \\sim Ueq, Uanis(C43)
\\sim Ueq, Uanis(C44) \\sim Ueq, Uanis(C45) \\sim Ueq, Uanis(C46) \\sim Ueq,
Uanis(C47) \\sim Ueq, Uanis(C7) \\sim Ueq, Uanis(C53) \\sim Ueq, Uanis(C54)
\\sim Ueq, Uanis(C55) \\sim Ueq, Uanis(C56) \\sim Ueq, Uanis(C57) \\sim Ueq,
Uanis(C58) \\sim Ueq, Uanis(C59) \\sim Ueq, Uanis(C60) \\sim Ueq, Uanis(C61)
\\sim Ueq, Uanis(C62) \\sim Ueq, Uanis(C63) \\sim Ueq, Uanis(C64) \\sim Ueq,
Uanis(C65) \\sim Ueq, Uanis(C66) \\sim Ueq, Uanis(C67) \\sim Ueq, Uanis(C68)
\\sim Ueq, Uanis(C69) \\sim Ueq, Uanis(C70) \\sim Ueq, Uanis(C71) \\sim Ueq,
Uanis(C72) \\sim Ueq, Uanis(C73) \\sim Ueq, Uanis(C74) \\sim Ueq, Uanis(C75)
\\sim Ueq, Uanis(C76) \\sim Ueq, Uanis(C77) \\sim Ueq, Uanis(C78) \\sim Ueq,
Uanis(C84) \\sim Ueq, Uanis(C85) \\sim Ueq, Uanis(C86) \\sim Ueq, Uanis(C87)
\\sim Ueq, Uanis(C79) \\sim Ueq, Uanis(C88) \\sim Ueq, Uanis(C89) \\sim Ueq,
Uanis(C90) \\sim Ueq, Uanis(C91) \\sim Ueq, Uanis(C92) \\sim Ueq, Uanis(C93)
\\sim Ueq, Uanis(C94) \\sim Ueq, Uanis(C95) \\sim Ueq, Uanis(C96) \\sim Ueq,
Uanis(C97) \\sim Ueq, Uanis(C98) \\sim Ueq, Uanis(C104) \\sim Ueq, Uanis(C105)
\\sim Ueq, Uanis(C48) \\sim Ueq, Uanis(C106) \\sim Ueq, Uanis(C107) \\sim Ueq,
Uanis(C108) \\sim Ueq, Uanis(C81) \\sim Ueq, Uanis(C109) \\sim Ueq, Uanis(C110)
\\sim Ueq, Uanis(C111) \\sim Ueq, Uanis(C112) \\sim Ueq, Uanis(C113) \\sim Ueq,
Uanis(C114) \\sim Ueq, Uanis(C115) \\sim Ueq, Uanis(C116) \\sim Ueq,
Uanis(C117) \\sim Ueq, Uanis(C118) \\sim Ueq, Uanis(C103) \\sim Ueq,
Uanis(C119) \\sim Ueq, Uanis(C120) \\sim Ueq, Uanis(C121) \\sim Ueq,
Uanis(C122) \\sim Ueq, Uanis(C123) \\sim Ueq, Uanis(C124) \\sim Ueq,
Uanis(C125) \\sim Ueq, Uanis(C126) \\sim Ueq, Uanis(C127) \\sim Ueq,
Uanis(C128) \\sim Ueq, Uanis(C129) \\sim Ueq, Uanis(C130) \\sim Ueq,
Uanis(C131) \\sim Ueq, Uanis(C132) \\sim Ueq, Uanis(C133) \\sim Ueq,
Uanis(C134) \\sim Ueq, Uanis(C135) \\sim Ueq, Uanis(C136) \\sim Ueq,
Uanis(C137) \\sim Ueq, Uanis(C80) \\sim Ueq, Uanis(C138) \\sim Ueq, Uanis(C139)
\\sim Ueq, Uanis(C140) \\sim Ueq, Uanis(C141) \\sim Ueq, Uanis(C142) \\sim Ueq,
Uanis(C143) \\sim Ueq, Uanis(C144) \\sim Ueq, Uanis(C145) \\sim Ueq,
Uanis(C146) \\sim Ueq, Uanis(C147) \\sim Ueq, Uanis(C148) \\sim Ueq,
Uanis(C149) \\sim Ueq, Uanis(C150) \\sim Ueq, Uanis(C83) \\sim Ueq, Uanis(C151)
\\sim Ueq, Uanis(C152) \\sim Ueq, Uanis(C153) \\sim Ueq, Uanis(C82) \\sim Ueq,
Uanis(C154) \\sim Ueq, Uanis(C155) \\sim Ueq, Uanis(C156) \\sim Ueq,
Uanis(C162) \\sim Ueq, Uanis(C163) \\sim Ueq, Uanis(C164) \\sim Ueq,
Uanis(C165) \\sim Ueq, Uanis(C166) \\sim Ueq, Uanis(C167) \\sim Ueq,
Uanis(C168) \\sim Ueq, Uanis(C169) \\sim Ueq, Uanis(C170) \\sim Ueq,
Uanis(C161) \\sim Ueq, Uanis(C171) \\sim Ueq, Uanis(C172) \\sim Ueq,
Uanis(C173) \\sim Ueq, Uanis(C174) \\sim Ueq, Uanis(C50) \\sim Ueq, Uanis(C175)
\\sim Ueq, Uanis(C176) \\sim Ueq, Uanis(C177) \\sim Ueq, Uanis(C51) \\sim Ueq,
Uanis(C178) \\sim Ueq, Uanis(C179) \\sim Ueq, Uanis(C180) \\sim Ueq, Uanis(C49)
\\sim Ueq, Uanis(C181) \\sim Ueq, Uanis(C182) \\sim Ueq, Uanis(C183) \\sim Ueq,
Uanis(C184) \\sim Ueq, Uanis(C185) \\sim Ueq, Uanis(C52) \\sim Ueq, Uanis(C186)
\\sim Ueq, Uanis(C187) \\sim Ueq, Uanis(C188) \\sim Ueq, Uanis(C189) \\sim Ueq,
Uanis(C190) \\sim Ueq, Uanis(C191) \\sim Ueq, Uanis(C157) \\sim Ueq,
Uanis(C192) \\sim Ueq, Uanis(C193) \\sim Ueq, Uanis(C194) \\sim Ueq,
Uanis(C195) \\sim Ueq, Uanis(C196) \\sim Ueq, Uanis(C197) \\sim Ueq,
Uanis(C198) \\sim Ueq, Uanis(C199) \\sim Ueq, Uanis(C200) \\sim Ueq,
Uanis(C201) \\sim Ueq, Uanis(C202) \\sim Ueq, Uanis(C203) \\sim Ueq,
Uanis(C204) \\sim Ueq, Uanis(C205) \\sim Ueq, Uanis(C206) \\sim Ueq,
Uanis(C207) \\sim Ueq, Uanis(C99) \\sim Ueq, Uanis(C208) \\sim Ueq, Uanis(C209)
\\sim Ueq, Uanis(C210) \\sim Ueq, Uanis(C211) \\sim Ueq, Uanis(C212) \\sim Ueq,
Uanis(C100) \\sim Ueq, Uanis(C102) \\sim Ueq, Uanis(C101) \\sim Ueq,
Uanis(C213) \\sim Ueq, Uanis(C214) \\sim Ueq, Uanis(C215) \\sim Ueq,
Uanis(C216) \\sim Ueq, Uanis(C217) \\sim Ueq, Uanis(C218) \\sim Ueq,
Uanis(C219) \\sim Ueq, Uanis(C220) \\sim Ueq, Uanis(C160) \\sim Ueq,
Uanis(C159) \\sim Ueq, Uanis(C158) \\sim Ueq: with sigma of 0.01 and sigma for
terminal atoms of 0.02
Uanis(C137) \\sim Ueq, Uanis(S18) \\sim Ueq: with sigma of 0.01 and sigma for
terminal atoms of 0.02
: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(Au18) = Uanis(Ag1E)
Uanis(Ag1E) = Uanis(Au18)
Uanis(Au1F) = Uanis(Ag14)
Uanis(Ag14) = Uanis(Au1F)
Uanis(Ag7) = Uanis(Au1H)
Uanis(Au1H) = Uanis(Ag7)
Uanis(Au16) = Uanis(Ag1M)
Uanis(Ag1M) = Uanis(Au16)
Uanis(Ag3) = Uanis(Au1N)
Uanis(Au1N) = Uanis(Ag3)
Uanis(Au1) = Uanis(Ag1I)
Uanis(Ag1I) = Uanis(Au1)
Uanis(Au15) = Uanis(Ag1L)
Uanis(Ag1L) = Uanis(Au15)
Uanis(Ag19) = Uanis(Au1K)
Uanis(Au1K) = Uanis(Ag19)
Uanis(Au17) = Uanis(Ag1J)
Uanis(Ag1J) = Uanis(Au17)
Uanis(Ag1D) = Uanis(Au13)
Uanis(Au13) = Uanis(Ag1D)
Uanis(Ag1G) = Uanis(Au)
Uanis(Au) = Uanis(Ag1G)
4. Others
 Fixed Sof: Au(0.37) Au1(0.43) Ag3(0.69) Ag7(0.7) Au13(0.42) Ag14(0.67)
 Au15(0.38) Au16(0.37) Au17(0.37) Au18(0.49) Ag19(0.69) Ag1D(0.58) Ag1E(0.51)
 Au1F(0.33) Ag1G(0.63) Au1H(0.3) Ag1I(0.57) Ag1J(0.63) Au1K(0.31) Ag1L(0.62)
 Ag1M(0.63) Au1N(0.31)
5.a Secondary CH2 refined with riding coordinates:
 C39(H39A,H39B), C76(H76A,H76B), C92(H92A,H92B), C137(H13A,H13B), C140(H14A,
 H14B), C148(H14C,H14D), C180(H18A,H18B), C184(H18C,H18D), C213(H21A,H21B),
 C215(H21C,H21D)
5.b Aromatic/amide H refined with riding coordinates:
 C4(H4), C5(H5), C6(H6), C7(H7), C8(H8), C9(H9), C11(H11), C12(H12), C13(H13),
 C15(H15), C16(H16), C17(H17), C19(H19), C20(H20), C21(H21), C22(H22), C24(H24),
  C25(H25), C26(H26), C28(H28), C30(H30), C31(H31), C32(H32), C35(H35),
 C38(H38), C41(H41), C43(H43), C44(H44), C46(H46), C48(H48), C49(H49), C50(H50),
  C51(H51), C52(H52), C53(H53), C54(H54), C55(H55), C56(H56), C57(H57),
 C58(H58), C59(H59), C60(H60), C61(H61), C62(H62), C63(H63), C64(H64), C65(H65),
  C66(H66), C68(H68), C69(H69), C70(H70), C72(H72), C73(H73), C74(H74),
 C75(H75), C77(H77), C78(H78), C80(H80), C81(H81), C82(H82), C83(H83), C84(H84),
  C86(H86), C87(H87), C88(H88), C89(H89), C90(H90), C91(H91), C93(H93),
 C94(H94), C95(H95), C96(H96), C97(H97), C99(H99), C100(H100), C101(H101),
 C102(H102), C103(H103), C105(H105), C106(H106), C108(H108), C109(H109),
 C110(H110), C111(H111), C112(H112), C113(H113), C115(H115), C116(H116),
 C117(H117), C118(H118), C119(H119), C120(H120), C121(H121), C122(H122),
 C123(H123), C124(H124), C126(H126), C127(H127), C128(H128), C129(H129),
 C130(H130), C131(H131), C132(H132), C134(H134), C135(H135), C138(H138),
 C141(H141), C142(H142), C143(H143), C144(H144), C145(H145), C146(H146),
 C147(H147), C149(H149), C150(H150), C151(H151), C153(H153), C154(H154),
 C155(H155), C157(H157), C158(H158), C159(H159), C160(H160), C161(H161),
 C162(H162), C163(H163), C164(H164), C165(H165), C166(H166), C168(H168),
 C169(H169), C170(H170), C171(H171), C172(H172), C173(H173), C174(H174),
 C175(H175), C176(H176), C177(H177), C179(H179), C181(H181), C182(H182),
 C183(H183), C185(H185), C186(H186), C187(H187), C188(H188), C189(H189),
 C190(H190), C191(H191), C192(H192), C193(H193), C194(H194), C196(H196),
 C198(H198), C199(H199), C200(H200), C201(H201), C202(H202), C203(H203),
 C204(H204), C205(H205), C206(H206), C207(H207), C208(H208), C209(H209),
 C210(H210), C211(H211), C212(H212), C214(H214), C216(H216), C217(H217),
 C218(H218), C219(H219), C220(H220)
5.c Fitted hexagon refined as free rotating group:
 C5(C6,C7,C8,C9,C10), C47(C48,C49,C50,C51,C52), C78(C79,C80,C81,C82,C83),
 C98(C99,C100,C101,C102,C103), C156(C157,C158,C159,C160,C161)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au2 Au 0.35526(2) 0.59337(2) 0.74172(2) 0.05160(12) Uani 1 1 d . U . . .
Au4 Au 0.05202(3) 0.58020(2) 0.64959(2) 0.05251(12) Uani 1 1 d . U . . .
Au5 Au 0.04569(3) 0.50972(2) 0.74300(2) 0.05270(12) Uani 1 1 d . U . . .
Au6 Au 0.45129(3) 0.53674(3) 0.68805(2) 0.05886(13) Uani 1 1 d . U . . .
Au8 Au 0.40263(3) 0.67837(3) 0.67681(2) 0.06084(13) Uani 1 1 d . U . . .
Au9 Au 0.39039(3) 0.56435(3) 0.82669(2) 0.05842(13) Uani 1 1 d . U . . .
Au10 Au 0.44341(3) 0.46591(3) 0.78065(2) 0.05903(13) Uani 1 1 d . U . . .
Au11 Au 0.06935(2) 0.62452(2) 0.71500(2) 0.04788(12) Uani 1 1 d . U . . .
Au12 Au 0.36703(3) 0.69394(3) 0.76329(2) 0.06154(13) Uani 1 1 d . U . . .
Au Au 0.15783(4) 0.63564(3) 0.64320(2) 0.05778(16) Uani 0.37 1 d . U P A .
Au1 Au 0.21254(4) 0.60847(3) 0.72840(2) 0.05828(16) Uani 0.43 1 d . U P . .
Ag3 Ag 0.29374(4) 0.51457(4) 0.80601(2) 0.05898(17) Uani 0.69 1 d . U P A 1
Ag7 Ag 0.17971(4) 0.50890(3) 0.70899(2) 0.05622(16) Uani 0.7 1 d . U P A 1
Au13 Au 0.10684(4) 0.73655(3) 0.68560(2) 0.06225(17) Uani 0.42 1 d . U P A .
Ag14 Ag 0.14338(4) 0.53171(4) 0.79250(2) 0.05891(17) Uani 0.67 1 d . U P A 1
Au15 Au 0.30966(4) 0.61862(4) 0.65703(2) 0.06174(17) Uani 0.38 1 d . U P A .
Au16 Au 0.33090(4) 0.49294(4) 0.72282(2) 0.06089(17) Uani 0.37 1 d . U P A .
Au17 Au 0.25701(4) 0.71956(4) 0.70011(2) 0.06320(17) Uani 0.37 1 d . U P A .
Au18 Au 0.09843(4) 0.67198(4) 0.77773(2) 0.06690(17) Uani 0.49 1 d . U P A .
Ag19 Ag 0.24843(4) 0.65484(4) 0.79226(2) 0.06087(17) Uani 0.69 1 d . U P A 1
Ag25 Ag 0.49298(5) 0.57888(5) 0.75454(3) 0.0637(2) Uani 1 1 d . U . . .
Au0A Au -0.03060(3) 0.73599(2) 0.72763(2) 0.05616(13) Uani 1 1 d . U . . .
Au1A Au -0.00437(3) 0.60523(2) 0.79050(2) 0.05485(12) Uani 1 1 d . U . . .
Ag1B Ag -0.06866(5) 0.63963(4) 0.70214(3) 0.05530(19) Uani 1 1 d . U . . .
S8 S 0.16119(18) 0.81943(14) 0.66049(9) 0.0611(7) Uani 1 1 d . U . . .
S10 S 0.21872(18) 0.46548(15) 0.85795(8) 0.0612(7) Uani 1 1 d . U . . .
S14 S 0.14140(19) 0.71416(16) 0.82480(10) 0.0654(7) Uani 1 1 d . U . . .
P13 P 0.42232(19) 0.54129(19) 0.89803(10) 0.0665(8) Uani 1 1 d . U . . .
P15 P 0.3787(2) 0.77910(18) 0.78092(12) 0.0720(9) Uani 1 1 d . U . . .
P2AA P 0.03689(17) 0.54381(15) 0.59369(9) 0.0571(6) Uani 1 1 d . U . . .
P17 P 0.02331(18) 0.41337(15) 0.76665(10) 0.0591(7) Uani 1 1 d . U . . .
P18 P 0.44544(19) 0.74791(19) 0.62188(10) 0.0680(8) Uani 1 1 d . U . . .
S18 S 0.28778(17) 0.41332(14) 0.71221(9) 0.0594(6) Uani 1 1 d . U . . .
S19 S 0.25277(16) 0.63187(14) 0.59080(8) 0.0562(6) Uani 1 1 d . U . . .
P0AA P 0.53282(18) 0.48666(19) 0.64336(10) 0.0666(8) Uani 1 1 d . U . . .
P1AA P -0.06803(18) 0.59093(18) 0.85386(9) 0.0632(7) Uani 1 1 d . U . . .
P20 P 0.51646(19) 0.35756(18) 0.81341(11) 0.0694(8) Uani 1 1 d . U . . .
Au1C Au 0.00521(3) 0.72183(2) 0.64063(2) 0.05227(12) Uani 1 1 d . U . . .
Cl18 Cl -0.18654(16) 0.65186(17) 0.68755(10) 0.0662(7) Uani 1 1 d . U . . .
Cl20 Cl 0.61310(18) 0.5643(2) 0.76568(11) 0.0778(9) Uani 1 1 d . U . . .
P4 P -0.04648(16) 0.80446(14) 0.57679(9) 0.0558(6) Uani 1 1 d . U . . .
P16 P -0.1169(2) 0.83158(18) 0.73569(13) 0.0765(8) Uani 1 1 d . U . . .
C1 C 0.0193(8) 0.8164(6) 0.5351(4) 0.0662(18) Uani 1 1 d . U . . .
C2 C 0.1169(8) 0.4830(7) 0.5805(4) 0.0659(19) Uani 1 1 d . U . . .
C3 C 0.3030(10) 0.8582(9) 0.7612(6) 0.092(2) Uani 1 1 d . U . . .
C4 C 0.0848(8) 0.7652(7) 0.5372(4) 0.067(2) Uani 1 1 d . U . . .
H4 H 0.095537 0.725043 0.560878 0.081 Uiso 1 1 calc R U . . .
C5 C 0.0571(4) 0.6401(4) 0.5203(2) 0.0674(19) Uani 1 1 d G U . . .
H5 H 0.098561 0.631628 0.535745 0.081 Uiso 1 1 calc R U . . .
C6 C 0.0425(4) 0.6849(4) 0.4782(2) 0.072(2) Uani 1 1 d G U . . .
H6 H 0.074017 0.707063 0.464867 0.086 Uiso 1 1 calc R U . . .
C7 C -0.0182(5) 0.6972(4) 0.4556(2) 0.074(2) Uani 1 1 d G U . . .
H7 H -0.028124 0.727861 0.426842 0.089 Uiso 1 1 calc R U . . .
C8 C -0.0643(4) 0.6648(5) 0.4751(3) 0.076(2) Uani 1 1 d G U . . .
H8 H -0.105721 0.673224 0.459693 0.091 Uiso 1 1 calc R U . . .
C9 C -0.0497(4) 0.6200(4) 0.5172(3) 0.0710(19) Uani 1 1 d G U . . .
H9 H -0.081177 0.597789 0.530571 0.085 Uiso 1 1 calc R U . . .
C10 C 0.0110(5) 0.6076(4) 0.5398(2) 0.0676(18) Uani 1 1 d G U . . .
C11 C -0.1429(8) 0.5098(7) 0.6375(5) 0.075(2) Uani 1 1 d . U . . .
H11 H -0.179665 0.523843 0.656725 0.090 Uiso 1 1 calc R U . . .
C12 C 0.1255(8) 0.4703(7) 0.5403(4) 0.0685(19) Uani 1 1 d . U . . .
H12 H 0.087804 0.493399 0.519119 0.082 Uiso 1 1 calc R U . . .
C13 C 0.0074(8) 0.8763(7) 0.5015(5) 0.072(2) Uani 1 1 d . U . . .
H13 H -0.034944 0.913581 0.500398 0.087 Uiso 1 1 calc R U . . .
C14 C -0.0960(8) 0.8866(7) 0.5816(5) 0.0708(19) Uani 1 1 d . U . . .
C15 C -0.0526(9) 0.5843(9) 0.9407(5) 0.084(2) Uani 1 1 d . U . . .
H15 H -0.077913 0.555102 0.948713 0.101 Uiso 1 1 calc R U . . .
C16 C 0.0080(10) 0.9427(8) 0.7049(6) 0.089(2) Uani 1 1 d . U . . .
H16 H 0.053806 0.937627 0.693023 0.107 Uiso 1 1 calc R U . . .
C17 C -0.0334(8) 0.4650(7) 0.5828(4) 0.0695(19) Uani 1 1 d . U . . .
H17 H 0.003841 0.449057 0.564330 0.083 Uiso 1 1 calc R U . . .
C18 C -0.1919(9) 0.8628(8) 0.6967(6) 0.086(2) Uani 1 1 d . U . . .
C19 C -0.0850(9) 0.3831(8) 0.8210(5) 0.080(2) Uani 1 1 d . U . . .
H19 H -0.049948 0.342994 0.837667 0.096 Uiso 1 1 calc R U . . .
C20 C 0.4031(9) 0.3345(8) 0.8631(5) 0.082(2) Uani 1 1 d . U . . .
H20 H 0.385932 0.381110 0.857575 0.099 Uiso 1 1 calc R U . . .
C21 C 0.1333(8) 0.7724(7) 0.5057(4) 0.068(2) Uani 1 1 d . U . . .
H21 H 0.177218 0.736336 0.508029 0.082 Uiso 1 1 calc R U . . .
C22 C 0.1273(9) 0.3619(8) 0.8312(5) 0.078(2) Uani 1 1 d . U . . .
H22 H 0.126990 0.405713 0.822776 0.094 Uiso 1 1 calc R U . . .
C23 C 0.5074(9) 0.4288(8) 0.6263(5) 0.080(2) Uani 1 1 d . U . . .
C24 C -0.1492(8) 0.7533(7) 0.5808(5) 0.075(2) Uani 1 1 d . U . . .
H24 H -0.137898 0.735487 0.611250 0.090 Uiso 1 1 calc R U . . .
C25 C 0.6034(10) 0.6128(9) 0.9030(5) 0.088(3) Uani 1 1 d . U . . .
H25 H 0.643249 0.624128 0.904242 0.106 Uiso 1 1 calc R U . . .
C26 C 0.0905(9) 0.3653(7) 0.7006(5) 0.078(2) Uani 1 1 d . U . . .
H26 H 0.124534 0.381885 0.704926 0.093 Uiso 1 1 calc R U . . .
C27 C -0.0680(9) 0.5083(8) 0.8801(5) 0.080(2) Uani 1 1 d . U . . .
C28 C 0.5150(9) 0.3640(9) 0.5811(5) 0.086(3) Uani 1 1 d . U . . .
H28 H 0.536478 0.348410 0.557264 0.103 Uiso 1 1 calc R U . . .
C29 C -0.1610(9) 0.6418(8) 0.8434(5) 0.081(2) Uani 1 1 d . U . . .
C30 C -0.1193(8) 0.4864(8) 0.7620(5) 0.077(2) Uani 1 1 d . U . . .
H30 H -0.106519 0.517372 0.738234 0.092 Uiso 1 1 calc R U . . .
C31 C -0.0886(8) 0.5306(7) 0.6314(4) 0.070(2) Uani 1 1 d . U . . .
H31 H -0.088259 0.560840 0.645458 0.085 Uiso 1 1 calc R U . . .
C32 C 0.6404(9) 0.4668(9) 0.6956(5) 0.084(2) Uani 1 1 d . U . . .
H32 H 0.606834 0.504027 0.702683 0.100 Uiso 1 1 calc R U . . .
C33 C -0.0379(9) 0.6102(8) 0.8972(5) 0.081(2) Uani 1 1 d . U . . .
C34 C 0.4010(9) 0.7779(8) 0.5689(5) 0.0774(19) Uani 1 1 d . U . . .
C35 C 0.0039(10) 0.6474(9) 0.8868(5) 0.087(2) Uani 1 1 d . U . . .
H35 H 0.017697 0.661314 0.857307 0.105 Uiso 1 1 calc R U . . .
C36 C -0.0302(8) 0.5076(7) 0.6037(4) 0.0662(19) Uani 1 1 d . U . . .
C37 C 0.6206(9) 0.4414(8) 0.6680(5) 0.079(2) Uani 1 1 d . U . . .
C38 C 0.6153(9) 0.5303(8) 0.5730(5) 0.080(2) Uani 1 1 d . U . . .
H38 H 0.654812 0.493016 0.587961 0.096 Uiso 1 1 calc R U . . .
C39 C 0.2779(8) 0.5489(7) 0.5865(4) 0.070(2) Uani 1 1 d . U . . .
H39A H 0.297553 0.515745 0.615093 0.084 Uiso 1 1 calc R U . . .
H39B H 0.234840 0.543161 0.579814 0.084 Uiso 1 1 calc R U . . .
C40 C 0.4664(9) 0.3055(8) 0.8455(5) 0.085(2) Uani 1 1 d . U . . .
C41 C 0.0263(9) 0.6650(9) 0.9169(5) 0.085(2) Uani 1 1 d . U . . .
H41 H 0.055339 0.690801 0.908614 0.101 Uiso 1 1 calc R U . . .
C42 C 0.0296(8) 0.3743(7) 0.7250(5) 0.0740(19) Uani 1 1 d . U . . .
C43 C -0.2149(9) 0.7676(7) 0.5203(5) 0.078(2) Uani 1 1 d . U . . .
H43 H -0.250206 0.759051 0.509032 0.093 Uiso 1 1 calc R U . . .
C44 C 0.3160(8) 0.7737(7) 0.5241(5) 0.076(2) Uani 1 1 d . U . . .
H44 H 0.283985 0.754672 0.520277 0.091 Uiso 1 1 calc R U . . .
C45 C -0.1103(8) 0.7876(7) 0.5523(4) 0.069(2) Uani 1 1 d . U . . .
C46 C -0.0048(9) 0.4538(8) 0.8871(5) 0.083(2) Uani 1 1 d . U . . .
H46 H 0.037516 0.460107 0.875056 0.099 Uiso 1 1 calc R U . . .
C47 C 0.1967(6) 0.4234(4) 0.9632(3) 0.090(3) Uani 1 1 d G U . . .
C48 C 0.1847(6) 0.3691(6) 0.9605(3) 0.093(2) Uani 1 1 d G U . . .
H48 H 0.148741 0.375395 0.941308 0.111 Uiso 1 1 calc R U . . .
C49 C 0.2254(7) 0.3055(5) 0.9860(4) 0.098(3) Uani 1 1 d G U . . .
H49 H 0.217245 0.268341 0.984219 0.117 Uiso 1 1 calc R U . . .
C50 C 0.2781(6) 0.2962(4) 1.0141(4) 0.105(3) Uani 1 1 d G U . . .
H50 H 0.305910 0.252754 1.031566 0.126 Uiso 1 1 calc R U . . .
C51 C 0.2901(6) 0.3506(6) 1.0168(4) 0.101(3) Uani 1 1 d G U . . .
H51 H 0.326075 0.344222 1.035999 0.121 Uiso 1 1 calc R U . . .
C52 C 0.2494(6) 0.4141(5) 0.9913(4) 0.095(2) Uani 1 1 d G U . . .
H52 H 0.257572 0.451277 0.993089 0.115 Uiso 1 1 calc R U . . .
C53 C 0.4184(10) 0.4132(9) 0.9350(5) 0.086(2) Uani 1 1 d . U . . .
H53 H 0.371185 0.433090 0.923577 0.103 Uiso 1 1 calc R U . . .
C54 C 0.4336(9) 0.3648(8) 0.6380(5) 0.085(2) Uani 1 1 d . U . . .
H54 H 0.398215 0.349775 0.654249 0.102 Uiso 1 1 calc R U . . .
C55 C 0.2458(8) 0.6832(8) 0.4262(5) 0.077(2) Uani 1 1 d . U . . .
H55 H 0.226069 0.716290 0.399288 0.092 Uiso 1 1 calc R U . . .
C56 C 0.1734(9) 0.3124(8) 0.8648(5) 0.082(2) Uani 1 1 d . U . . .
H56 H 0.204207 0.322436 0.879054 0.099 Uiso 1 1 calc R U . . .
C57 C -0.1237(10) 0.4325(9) 0.9191(5) 0.089(2) Uani 1 1 d . U . . .
H57 H -0.165760 0.424437 0.929716 0.107 Uiso 1 1 calc R U . . .
C58 C 0.5702(9) 0.7191(8) 0.5722(5) 0.082(2) Uani 1 1 d . U . . .
H58 H 0.542362 0.747265 0.546409 0.099 Uiso 1 1 calc R U . . .
C59 C 0.3011(10) 0.5774(9) 1.0034(6) 0.091(3) Uani 1 1 d . U . . .
H59 H 0.306179 0.563823 1.034410 0.110 Uiso 1 1 calc R U . . .
C60 C 0.3512(8) 0.7509(7) 0.5639(5) 0.074(2) Uani 1 1 d . U . . .
H60 H 0.342231 0.717422 0.587693 0.089 Uiso 1 1 calc R U . . .
C61 C -0.2750(10) 0.7062(9) 0.8634(6) 0.091(2) Uani 1 1 d . U . . .
H61 H -0.304069 0.727337 0.883143 0.109 Uiso 1 1 calc R U . . .
C62 C 0.4906(10) 0.2395(9) 0.8513(6) 0.090(2) Uani 1 1 d . U . . .
H62 H 0.533340 0.219951 0.837824 0.108 Uiso 1 1 calc R U . . .
C63 C 0.1739(9) 0.2517(8) 0.8766(5) 0.083(3) Uani 1 1 d . U . . .
H63 H 0.204862 0.219365 0.900075 0.100 Uiso 1 1 calc R U . . .
C64 C 0.1227(8) 0.8279(7) 0.4712(4) 0.071(2) Uani 1 1 d . U . . .
H64 H 0.157196 0.830981 0.449158 0.085 Uiso 1 1 calc R U . . .
C65 C -0.1560(8) 0.9292(7) 0.5557(5) 0.075(2) Uani 1 1 d . U . . .
H65 H -0.174840 0.914641 0.537045 0.090 Uiso 1 1 calc R U . . .
C66 C -0.2035(9) 0.7452(8) 0.5651(5) 0.078(2) Uani 1 1 d . U . . .
H66 H -0.232699 0.724801 0.584365 0.093 Uiso 1 1 calc R U . . .
C67 C -0.0663(8) 0.4287(7) 0.7856(5) 0.0713(19) Uani 1 1 d . U . . .
C68 C 0.3574(10) 0.5484(9) 0.9783(5) 0.090(2) Uani 1 1 d . U . . .
H68 H 0.399759 0.513462 0.991870 0.108 Uiso 1 1 calc R U . . .
C69 C -0.1255(10) 0.9538(8) 0.7405(6) 0.092(2) Uani 1 1 d . U . . .
H69 H -0.171408 0.959422 0.752410 0.111 Uiso 1 1 calc R U . . .
C70 C 0.4647(9) 0.3434(8) 0.6040(5) 0.082(2) Uani 1 1 d . U . . .
H70 H 0.450846 0.313262 0.596258 0.098 Uiso 1 1 calc R U . . .
C71 C 0.0824(9) 0.3487(7) 0.8101(5) 0.076(2) Uani 1 1 d . U . . .
C72 C 0.4084(9) 0.8314(8) 0.5342(5) 0.081(2) Uani 1 1 d . U . . .
H72 H 0.437855 0.852891 0.538046 0.098 Uiso 1 1 calc R U . . .
C73 C -0.2597(10) 0.6796(9) 0.7964(6) 0.091(3) Uani 1 1 d . U . . .
H73 H -0.278703 0.683668 0.769630 0.109 Uiso 1 1 calc R U . . .
C74 C 0.3280(8) 0.6388(7) 0.4878(4) 0.071(2) Uani 1 1 d . U . . .
H74 H 0.364264 0.642124 0.502078 0.085 Uiso 1 1 calc R U . . .
C75 C 0.3735(9) 0.8522(8) 0.4954(5) 0.079(2) Uani 1 1 d . U . . .
H75 H 0.380832 0.886645 0.471651 0.095 Uiso 1 1 calc R U . . .
C76 C 0.3332(8) 0.5352(7) 0.5508(4) 0.071(2) Uani 1 1 d . U . . .
H76A H 0.377733 0.537795 0.558195 0.085 Uiso 1 1 calc R U . . .
H76B H 0.344109 0.489905 0.549691 0.085 Uiso 1 1 calc R U . . .
C77 C 0.2523(8) 0.5819(7) 0.4841(4) 0.073(2) Uani 1 1 d . U . . .
H77 H 0.235513 0.546616 0.496064 0.088 Uiso 1 1 calc R U . . .
C78 C 0.0870(5) 0.9846(5) 0.5987(4) 0.087(2) Uani 1 1 d G U . . .
H78 H 0.046579 0.972620 0.606666 0.105 Uiso 1 1 calc R U . . .
C79 C 0.1428(6) 0.9486(4) 0.5776(3) 0.082(2) Uani 1 1 d G U . . .
C80 C 0.2019(5) 0.9662(5) 0.5659(3) 0.090(3) Uani 1 1 d G U . . .
H80 H 0.240058 0.941574 0.551447 0.108 Uiso 1 1 calc R U . . .
C81 C 0.2053(5) 1.0198(5) 0.5752(4) 0.092(3) Uani 1 1 d G U . . .
H81 H 0.245776 1.031877 0.567235 0.111 Uiso 1 1 calc R U . . .
C82 C 0.1496(6) 1.0559(5) 0.5963(4) 0.091(3) Uani 1 1 d G U . . .
H82 H 0.151896 1.092551 0.602739 0.109 Uiso 1 1 calc R U . . .
C83 C 0.0904(5) 1.0383(5) 0.6080(3) 0.093(3) Uani 1 1 d G U . . .
H83 H 0.052297 1.062923 0.622455 0.112 Uiso 1 1 calc R U . . .
C84 C -0.1132(11) 0.7988(9) 0.8269(6) 0.098(2) Uani 1 1 d . U . . .
H84 H -0.063136 0.778302 0.825768 0.118 Uiso 1 1 calc R U . . .
C85 C -0.0843(9) 0.8981(8) 0.7283(5) 0.0837(19) Uani 1 1 d . U . . .
C86 C -0.1615(9) 1.0163(8) 0.5842(5) 0.082(2) Uani 1 1 d . U . . .
H86 H -0.183710 1.060450 0.585153 0.098 Uiso 1 1 calc R U . . .
C87 C -0.1295(9) 0.4969(9) 0.8972(5) 0.086(2) Uani 1 1 d . U . . .
H87 H -0.174059 0.532578 0.893875 0.104 Uiso 1 1 calc R U . . .
C88 C -0.1247(8) 0.8102(7) 0.5081(4) 0.0693(18) Uani 1 1 d . U . . .
H88 H -0.097582 0.832520 0.488316 0.083 Uiso 1 1 calc R U . . .
C89 C 0.1943(11) 0.9755(9) 0.7259(6) 0.096(3) Uani 1 1 d . U . . .
H89 H 0.157209 1.016712 0.713185 0.115 Uiso 1 1 calc R U . . .
C90 C -0.1461(8) 0.4664(7) 0.6152(5) 0.071(2) Uani 1 1 d . U . . .
H90 H -0.185584 0.452905 0.618805 0.085 Uiso 1 1 calc R U . . .
C91 C 0.2238(8) 0.6310(7) 0.4436(5) 0.076(2) Uani 1 1 d . U . . .
H91 H 0.188798 0.627513 0.428315 0.091 Uiso 1 1 calc R U . . .
C92 C 0.2835(10) 0.2949(9) 0.7706(6) 0.094(2) Uani 1 1 d . U . . .
H92A H 0.290102 0.265587 0.801382 0.113 Uiso 1 1 calc R U . . .
H92B H 0.233591 0.307759 0.761854 0.113 Uiso 1 1 calc R U . . .
C93 C 0.0869(9) 0.2833(8) 0.8217(5) 0.081(2) Uani 1 1 d . U . . .
H93 H 0.059731 0.270635 0.806542 0.097 Uiso 1 1 calc R U . . .
C94 C 0.7570(9) 0.3802(9) 0.7045(5) 0.088(3) Uani 1 1 d . U . . .
H94 H 0.802950 0.357760 0.717864 0.106 Uiso 1 1 calc R U . . .
C95 C 0.5536(10) 0.3548(9) 0.9692(5) 0.090(2) Uani 1 1 d . U . . .
H95 H 0.599778 0.333128 0.982334 0.108 Uiso 1 1 calc R U . . .
C96 C 0.2975(8) 0.6866(8) 0.4487(5) 0.076(2) Uani 1 1 d . U . . .
H96 H 0.312757 0.722989 0.436955 0.091 Uiso 1 1 calc R U . . .
C97 C 0.4538(9) 0.4088(8) 0.6489(5) 0.079(2) Uani 1 1 d . U . . .
H97 H 0.430943 0.425532 0.671968 0.095 Uiso 1 1 calc R U . . .
C98 C 0.3309(6) 0.2559(6) 0.7425(3) 0.092(3) Uani 1 1 d G U . . .
C99 C 0.4014(6) 0.2180(6) 0.7553(3) 0.102(3) Uani 1 1 d G U . . .
H99 H 0.418294 0.214251 0.782643 0.122 Uiso 1 1 calc R U . . .
C100 C 0.4473(5) 0.1857(6) 0.7280(4) 0.106(3) Uani 1 1 d G U . . .
H100 H 0.495513 0.159786 0.736702 0.127 Uiso 1 1 calc R U . . .
C101 C 0.4226(6) 0.1912(6) 0.6879(4) 0.107(3) Uani 1 1 d G U . . .
H101 H 0.453959 0.169039 0.669245 0.128 Uiso 1 1 calc R U . . .
C102 C 0.3521(6) 0.2290(6) 0.6751(3) 0.103(3) Uani 1 1 d G U . . .
H102 H 0.335184 0.232758 0.647729 0.123 Uiso 1 1 calc R U . . .
C103 C 0.3062(5) 0.2614(5) 0.7024(4) 0.093(2) Uani 1 1 d G U . . .
H103 H 0.257963 0.287224 0.693670 0.111 Uiso 1 1 calc R U . . .
C104 C 0.5385(9) 0.7072(8) 0.6144(5) 0.082(2) Uani 1 1 d . U . . .
C105 C 0.6666(9) 0.3830(9) 0.6614(5) 0.087(2) Uani 1 1 d . U . . .
H105 H 0.651273 0.361005 0.646408 0.104 Uiso 1 1 calc R U . . .
C106 C 0.5099(10) 0.3196(9) 0.9727(5) 0.090(2) Uani 1 1 d . U . . .
H106 H 0.528763 0.272934 0.986380 0.108 Uiso 1 1 calc R U . . .
C107 C 0.3049(8) 0.5854(7) 0.5063(4) 0.069(2) Uani 1 1 d . U . . .
C108 C 0.5283(10) 0.4236(9) 0.9456(5) 0.086(2) Uani 1 1 d . U . . .
H108 H 0.556965 0.449221 0.942245 0.103 Uiso 1 1 calc R U . . .
C109 C 0.1365(9) 0.2333(8) 0.8591(5) 0.087(3) Uani 1 1 d . U . . .
H109 H 0.139500 0.188552 0.869370 0.104 Uiso 1 1 calc R U . . .
C110 C -0.0186(9) 0.8918(8) 0.7109(5) 0.081(2) Uani 1 1 d . U . . .
H110 H 0.009109 0.853448 0.702909 0.097 Uiso 1 1 calc R U . . .
C111 C -0.1022(9) 0.9731(7) 0.6091(5) 0.080(2) Uani 1 1 d . U . . .
H111 H -0.083795 0.987553 0.627978 0.096 Uiso 1 1 calc R U . . .
C112 C 0.2315(11) 0.6430(10) 0.9394(6) 0.097(3) Uani 1 1 d . U . . .
H112 H 0.187651 0.674976 0.925794 0.116 Uiso 1 1 calc R U . . .
C113 C 0.4451(10) 0.3469(8) 0.9584(5) 0.087(2) Uani 1 1 d . U . . .
H113 H 0.415958 0.321386 0.964032 0.104 Uiso 1 1 calc R U . . .
C114 C 0.4921(9) 0.5735(8) 0.9006(5) 0.081(2) Uani 1 1 d . U . . .
C115 C 0.0586(8) 0.8806(7) 0.4696(5) 0.075(2) Uani 1 1 d . U . . .
H115 H 0.049482 0.920640 0.445968 0.090 Uiso 1 1 calc R U . . .
C116 C 0.4561(10) 0.2015(9) 0.8754(6) 0.097(3) Uani 1 1 d . U . . .
H116 H 0.473660 0.155266 0.879567 0.116 Uiso 1 1 calc R U . . .
C117 C -0.0618(9) 0.3805(8) 0.9262(5) 0.084(2) Uani 1 1 d . U . . .
H117 H -0.060337 0.336993 0.941839 0.101 Uiso 1 1 calc R U . . .
C118 C 0.7110(9) 0.4376(9) 0.7137(5) 0.087(3) Uani 1 1 d . U . . .
H118 H 0.726048 0.456389 0.731226 0.105 Uiso 1 1 calc R U . . .
C119 C 0.0485(9) 0.3100(8) 0.6640(5) 0.080(2) Uani 1 1 d . U . . .
H119 H 0.053458 0.288336 0.642735 0.096 Uiso 1 1 calc R U . . .
C120 C -0.0296(10) 0.9979(9) 0.7155(6) 0.095(3) Uani 1 1 d . U . . .
H120 H -0.012137 1.032488 0.710336 0.114 Uiso 1 1 calc R U . . .
C121 C 0.2391(10) 0.6253(9) 0.9831(5) 0.092(3) Uani 1 1 d . U . . .
H121 H 0.201715 0.645870 0.999775 0.110 Uiso 1 1 calc R U . . .
C122 C 0.4936(10) 0.5973(9) 0.9348(5) 0.088(2) Uani 1 1 d . U . . .
H122 H 0.459139 0.597899 0.957116 0.105 Uiso 1 1 calc R U . . .
C123 C 0.4919(9) 0.5994(8) 0.5704(5) 0.078(2) Uani 1 1 d . U . . .
H123 H 0.446104 0.610381 0.582769 0.094 Uiso 1 1 calc R U . . .
C124 C 0.5354(9) 0.4077(8) 0.5919(5) 0.083(2) Uani 1 1 d . U . . .
H124 H 0.569896 0.423243 0.574867 0.100 Uiso 1 1 calc R U . . .
C125 C 0.5674(10) 0.3131(9) 0.7761(6) 0.094(2) Uani 1 1 d . U . . .
C126 C -0.0301(9) 0.6014(9) 0.9723(5) 0.088(3) Uani 1 1 d . U . . .
H126 H -0.039337 0.583811 1.002325 0.105 Uiso 1 1 calc R U . . .
C127 C 0.3611(11) 0.9293(9) 0.6399(6) 0.094(2) Uani 1 1 d . U . . .
H127 H 0.315454 0.959971 0.643196 0.113 Uiso 1 1 calc R U . . .
C128 C 0.3306(11) 0.7524(10) 0.8658(6) 0.099(2) Uani 1 1 d . U . . .
H128 H 0.299353 0.738581 0.855067 0.119 Uiso 1 1 calc R U . . .
C129 C 0.3634(9) 0.3001(8) 0.8882(5) 0.083(2) Uani 1 1 d . U . . .
H129 H 0.319541 0.321607 0.899974 0.100 Uiso 1 1 calc R U . . .
C130 C -0.1883(9) 0.9943(8) 0.5575(5) 0.085(2) Uani 1 1 d . U . . .
H130 H -0.229570 1.023813 0.539995 0.102 Uiso 1 1 calc R U . . .
C131 C 0.0069(10) 0.6454(9) 0.9591(5) 0.089(3) Uani 1 1 d . U . . .
H131 H 0.018149 0.661411 0.979961 0.106 Uiso 1 1 calc R U . . .
C132 C -0.0224(9) 0.3532(7) 0.7179(5) 0.077(2) Uani 1 1 d . U . . .
H132 H -0.065924 0.361439 0.733105 0.093 Uiso 1 1 calc R U . . .
C133 C 0.3486(10) 0.5729(9) 0.9329(5) 0.084(2) Uani 1 1 d . U . . .
C134 C -0.1900(9) 0.6459(9) 0.8052(5) 0.087(2) Uani 1 1 d . U . . .
H134 H -0.160752 0.625018 0.785345 0.105 Uiso 1 1 calc R U . . .
C135 C -0.0075(9) 0.3194(8) 0.6876(5) 0.081(2) Uani 1 1 d . U . . .
H135 H -0.041046 0.301861 0.683860 0.097 Uiso 1 1 calc R U . . .
C136 C 0.3816(11) 0.7686(9) 0.8391(6) 0.095(2) Uani 1 1 d . U . . .
C137 C 0.2957(9) 0.3572(8) 0.7685(5) 0.082(2) Uani 1 1 d . U . . .
H13A H 0.343680 0.344535 0.780538 0.099 Uiso 1 1 calc R U . . .
H13B H 0.260566 0.380473 0.786921 0.099 Uiso 1 1 calc R U . . .
C138 C 0.2843(11) 0.9114(9) 0.7783(6) 0.096(2) Uani 1 1 d . U . . .
H138 H 0.310328 0.905306 0.803084 0.116 Uiso 1 1 calc R U . . .
C139 C 0.4613(11) 0.7902(9) 0.7581(6) 0.096(2) Uani 1 1 d . U . . .
C140 C 0.1924(9) 0.5191(8) 0.8930(5) 0.083(3) Uani 1 1 d . U . . .
H14A H 0.235233 0.520948 0.903482 0.100 Uiso 1 1 calc R U . . .
H14B H 0.162402 0.564649 0.875795 0.100 Uiso 1 1 calc R U . . .
C141 C 0.6180(10) 0.2881(9) 0.8817(5) 0.089(2) Uani 1 1 d . U . . .
H141 H 0.603525 0.251704 0.886678 0.107 Uiso 1 1 calc R U . . .
C142 C 0.3720(10) 0.8660(8) 0.6370(6) 0.088(2) Uani 1 1 d . U . . .
H142 H 0.332745 0.852252 0.640329 0.106 Uiso 1 1 calc R U . . .
C143 C -0.1792(8) 0.8003(7) 0.4925(5) 0.072(2) Uani 1 1 d . U . . .
H143 H -0.190657 0.816902 0.462056 0.087 Uiso 1 1 calc R U . . .
C144 C 0.2608(10) 0.8687(8) 0.7257(6) 0.087(2) Uani 1 1 d . U . . .
H144 H 0.270485 0.833998 0.713459 0.105 Uiso 1 1 calc R U . . .
C145 C 0.4917(10) 0.8470(9) 0.6263(6) 0.093(2) Uani 1 1 d . U . . .
H145 H 0.537259 0.819243 0.620104 0.112 Uiso 1 1 calc R U . . .
C146 C 0.4240(11) 0.9429(10) 0.6375(6) 0.098(3) Uani 1 1 d . U . . .
H146 H 0.418887 0.983873 0.640964 0.117 Uiso 1 1 calc R U . . .
C147 C 0.5718(10) 0.2675(9) 0.7192(6) 0.094(2) Uani 1 1 d . U . . .
H147 H 0.548741 0.261720 0.697665 0.113 Uiso 1 1 calc R U . . .
C148 C 0.1215(12) 0.8001(9) 0.7924(7) 0.103(3) Uani 1 1 d . U . . .
H14C H 0.156637 0.801315 0.768807 0.124 Uiso 1 1 calc R U . . .
H14D H 0.074368 0.816790 0.778122 0.124 Uiso 1 1 calc R U . . .
C149 C 0.5388(9) 0.5728(8) 0.8691(5) 0.084(2) Uani 1 1 d . U . . .
H149 H 0.532229 0.561030 0.844727 0.101 Uiso 1 1 calc R U . . .
C150 C 0.6058(10) 0.4014(9) 0.8447(6) 0.089(2) Uani 1 1 d . U . . .
H150 H 0.583500 0.442230 0.822507 0.107 Uiso 1 1 calc R U . . .
C151 C 0.6937(10) 0.3338(9) 0.9016(6) 0.093(3) Uani 1 1 d . U . . .
H151 H 0.730831 0.328480 0.919563 0.111 Uiso 1 1 calc R U . . .
C152 C 0.4366(9) 0.8249(8) 0.6296(5) 0.082(2) Uani 1 1 d . U . . .
C153 C 0.3895(10) 0.2338(8) 0.8955(6) 0.088(3) Uani 1 1 d . U . . .
H153 H 0.364624 0.207670 0.913817 0.106 Uiso 1 1 calc R U . . .
C154 C 0.6419(10) 0.2881(9) 0.7777(6) 0.094(2) Uani 1 1 d . U . . .
H154 H 0.667382 0.295518 0.797194 0.113 Uiso 1 1 calc R U . . .
C155 C 0.6746(10) 0.2827(9) 0.9057(6) 0.094(3) Uani 1 1 d . U . . .
H155 H 0.700463 0.240803 0.925849 0.113 Uiso 1 1 calc R U . . .
C156 C 0.0793(8) 0.8470(8) 0.8523(4) 0.117(3) Uani 1 1 d G U . . .
C157 C 0.0067(8) 0.8815(7) 0.8448(4) 0.126(3) Uani 1 1 d G U . . .
H157 H -0.011861 0.902802 0.815694 0.151 Uiso 1 1 calc R U . . .
C158 C -0.0387(6) 0.8849(8) 0.8800(5) 0.125(3) Uani 1 1 d G U . . .
H158 H -0.088325 0.908557 0.874845 0.151 Uiso 1 1 calc R U . . .
C159 C -0.0116(8) 0.8538(8) 0.9226(4) 0.131(3) Uani 1 1 d G U . . .
H159 H -0.042598 0.856161 0.946635 0.157 Uiso 1 1 calc R U . . .
C160 C 0.0610(8) 0.8193(8) 0.9301(4) 0.125(3) Uani 1 1 d G U . . .
H160 H 0.079593 0.798010 0.959275 0.150 Uiso 1 1 calc R U . . .
C161 C 0.1065(6) 0.8159(7) 0.8950(5) 0.121(3) Uani 1 1 d G U . . .
H161 H 0.156059 0.792254 0.900126 0.145 Uiso 1 1 calc R U . . .
C162 C -0.2287(9) 0.9285(8) 0.6781(6) 0.089(2) Uani 1 1 d . U . . .
H162 H -0.212939 0.959728 0.683062 0.107 Uiso 1 1 calc R U . . .
C163 C 0.6436(10) 0.2392(9) 0.7229(6) 0.097(3) Uani 1 1 d . U . . .
H163 H 0.669768 0.210573 0.706505 0.117 Uiso 1 1 calc R U . . .
C164 C -0.2284(10) 0.8518(9) 0.7939(6) 0.096(2) Uani 1 1 d . U . . .
H164 H -0.259275 0.871207 0.769026 0.116 Uiso 1 1 calc R U . . .
C165 C -0.0937(10) 1.0021(9) 0.7340(6) 0.094(3) Uani 1 1 d . U . . .
H165 H -0.119366 1.039765 0.743187 0.113 Uiso 1 1 calc R U . . .
C166 C -0.2666(10) 0.8331(9) 0.6615(6) 0.095(3) Uani 1 1 d . U . . .
H166 H -0.278374 0.800191 0.655916 0.114 Uiso 1 1 calc R U . . .
C167 C 0.5842(10) 0.3480(9) 0.8507(5) 0.087(2) Uani 1 1 d . U . . .
C168 C 0.5298(10) 0.3053(9) 0.7459(6) 0.093(2) Uani 1 1 d . U . . .
H168 H 0.479438 0.324081 0.743485 0.111 Uiso 1 1 calc R U . . .
C169 C 0.2083(10) 0.9254(8) 0.7090(6) 0.091(3) Uani 1 1 d . U . . .
H169 H 0.180337 0.931219 0.685227 0.109 Uiso 1 1 calc R U . . .
C170 C 0.5969(10) 0.5887(9) 0.8706(5) 0.087(3) Uani 1 1 d . U . . .
H170 H 0.632614 0.583090 0.849253 0.104 Uiso 1 1 calc R U . . .
C171 C -0.2099(10) 0.8160(9) 0.6889(6) 0.090(2) Uani 1 1 d . U . . .
H171 H -0.182820 0.770475 0.702494 0.108 Uiso 1 1 calc R U . . .
C172 C 0.5167(11) 0.7401(11) 0.7520(7) 0.104(3) Uani 1 1 d . U . . .
H172 H 0.512510 0.698392 0.757645 0.125 Uiso 1 1 calc R U . . .
C173 C 0.5487(10) 0.6204(9) 0.9348(6) 0.094(2) Uani 1 1 d . U . . .
H173 H 0.549544 0.640868 0.955770 0.113 Uiso 1 1 calc R U . . .
C174 C 0.3720(11) 0.7651(10) 0.9251(6) 0.100(3) Uani 1 1 d . U . . .
H174 H 0.371593 0.760429 0.955460 0.119 Uiso 1 1 calc R U . . .
C175 C 0.6587(10) 0.3954(9) 0.8704(5) 0.091(3) Uani 1 1 d . U . . .
H175 H 0.671503 0.432321 0.867271 0.110 Uiso 1 1 calc R U . . .
C176 C -0.3062(10) 0.9012(9) 0.6422(6) 0.097(3) Uani 1 1 d . U . . .
H176 H -0.344572 0.914373 0.622653 0.117 Uiso 1 1 calc R U . . .
C177 C -0.1479(11) 0.8042(10) 0.8675(6) 0.102(3) Uani 1 1 d . U . . .
H177 H -0.118439 0.789136 0.892643 0.123 Uiso 1 1 calc R U . . .
C178 C -0.1560(10) 0.8249(9) 0.7893(6) 0.091(2) Uani 1 1 d . U . . .
C179 C 0.4230(11) 0.7810(10) 0.9007(6) 0.101(3) Uani 1 1 d . U . . .
H179 H 0.454500 0.793134 0.912815 0.121 Uiso 1 1 calc R U . . .
C180 C 0.1499(10) 0.4918(9) 0.9334(5) 0.090(2) Uani 1 1 d . U . . .
H18A H 0.132486 0.523241 0.950466 0.108 Uiso 1 1 calc R U . . .
H18B H 0.108198 0.488220 0.922802 0.108 Uiso 1 1 calc R U . . .
C181 C 0.2339(11) 0.9678(9) 0.7622(6) 0.099(3) Uani 1 1 d . U . . .
H181 H 0.223666 1.002894 0.774171 0.118 Uiso 1 1 calc R U . . .
C182 C 0.6765(11) 0.2521(9) 0.7498(6) 0.098(3) Uani 1 1 d . U . . .
H182 H 0.726933 0.235805 0.749886 0.117 Uiso 1 1 calc R U . . .
C183 C -0.2580(11) 0.8500(10) 0.8389(6) 0.103(3) Uani 1 1 d . U . . .
H183 H -0.307877 0.865222 0.843019 0.124 Uiso 1 1 calc R U . . .
C184 C 0.1206(14) 0.8445(12) 0.8131(8) 0.122(3) Uani 1 1 d . U . . .
H18C H 0.103094 0.889476 0.791448 0.147 Uiso 1 1 calc R U . . .
H18D H 0.170338 0.834681 0.820655 0.147 Uiso 1 1 calc R U . . .
C185 C 0.4618(12) 0.8558(10) 0.7469(7) 0.104(2) Uani 1 1 d . U . . .
H185 H 0.420693 0.893150 0.747813 0.125 Uiso 1 1 calc R U . . .
C186 C 0.4312(11) 0.7802(10) 0.8552(6) 0.102(2) Uani 1 1 d . U . . .
H186 H 0.469999 0.787507 0.838109 0.122 Uiso 1 1 calc R U . . .
C187 C -0.2892(10) 0.9514(9) 0.6519(6) 0.097(3) Uani 1 1 d . U . . .
H187 H -0.317644 0.997242 0.640951 0.116 Uiso 1 1 calc R U . . .
C188 C 0.3227(11) 0.7557(10) 0.9091(6) 0.100(3) Uani 1 1 d . U . . .
H188 H 0.282680 0.751056 0.925782 0.120 Uiso 1 1 calc R U . . .
C189 C -0.2140(11) 0.8271(10) 0.8723(6) 0.103(3) Uani 1 1 d . U . . .
H189 H -0.232252 0.827945 0.900457 0.123 Uiso 1 1 calc R U . . .
C190 C 0.4859(11) 0.9064(10) 0.6313(6) 0.100(2) Uani 1 1 d . U . . .
H190 H 0.525790 0.918637 0.630124 0.120 Uiso 1 1 calc R U . . .
C191 C 0.5319(11) 0.8600(11) 0.7339(7) 0.107(3) Uani 1 1 d . U . . .
H191 H 0.538394 0.900547 0.728964 0.128 Uiso 1 1 calc R U . . .
C192 C 0.2420(8) 0.3898(7) 0.5623(5) 0.075(2) Uani 1 1 d . U . . .
H192 H 0.283791 0.356751 0.556614 0.089 Uiso 1 1 calc R U . . .
C193 C 0.2357(8) 0.4029(7) 0.6013(5) 0.075(2) Uani 1 1 d . U . . .
H193 H 0.274188 0.381084 0.621907 0.090 Uiso 1 1 calc R U . . .
C194 C 0.1733(8) 0.4477(7) 0.6104(5) 0.071(2) Uani 1 1 d . U . . .
H194 H 0.168535 0.454703 0.638080 0.085 Uiso 1 1 calc R U . . .
C195 C 0.4607(9) 0.4518(8) 0.9278(5) 0.081(2) Uani 1 1 d . U . . .
C196 C 0.1874(8) 0.4248(7) 0.5310(5) 0.072(2) Uani 1 1 d . U . . .
H196 H 0.192783 0.417480 0.503358 0.087 Uiso 1 1 calc R U . . .
C197 C 0.5471(8) 0.5440(8) 0.5923(5) 0.076(2) Uani 1 1 d . U . . .
C198 C -0.0017(9) 0.3913(8) 0.9108(5) 0.080(2) Uani 1 1 d . U . . .
H198 H 0.042772 0.355337 0.916470 0.095 Uiso 1 1 calc R U . . .
C199 C -0.1583(9) 0.3990(8) 0.8309(5) 0.086(2) Uani 1 1 d . U . . .
H199 H -0.171993 0.368455 0.854498 0.104 Uiso 1 1 calc R U . . .
C200 C 0.7380(10) 0.3567(9) 0.6779(6) 0.092(2) Uani 1 1 d . U . . .
H200 H 0.772436 0.321388 0.669261 0.110 Uiso 1 1 calc R U . . .
C201 C 0.5803(9) 0.6665(8) 0.6506(6) 0.086(2) Uani 1 1 d . U . . .
H201 H 0.558751 0.657733 0.678346 0.104 Uiso 1 1 calc R U . . .
C202 C -0.0932(8) 0.4452(7) 0.5893(5) 0.076(2) Uani 1 1 d . U . . .
H202 H -0.095386 0.416161 0.574722 0.091 Uiso 1 1 calc R U . . .
C203 C 0.6235(9) 0.5714(8) 0.5324(5) 0.079(2) Uani 1 1 d . U . . .
H203 H 0.668440 0.561184 0.518880 0.095 Uiso 1 1 calc R U . . .
C204 C 0.5781(12) 0.7467(11) 0.7381(7) 0.105(3) Uani 1 1 d . U . . .
H204 H 0.616714 0.709426 0.734406 0.126 Uiso 1 1 calc R U . . .
C205 C 0.1028(9) 0.3315(8) 0.6693(5) 0.082(2) Uani 1 1 d . U . . .
H205 H 0.145017 0.323702 0.652799 0.098 Uiso 1 1 calc R U . . .
C206 C 0.5039(9) 0.6395(8) 0.5299(5) 0.079(2) Uani 1 1 d . U . . .
H206 H 0.465072 0.677478 0.514638 0.094 Uiso 1 1 calc R U . . .
C207 C 0.3269(9) 0.8235(7) 0.4901(5) 0.077(2) Uani 1 1 d . U . . .
H207 H 0.302672 0.838521 0.462859 0.093 Uiso 1 1 calc R U . . .
C208 C 0.5873(12) 0.8065(10) 0.7290(7) 0.108(3) Uani 1 1 d . U . . .
H208 H 0.631850 0.809911 0.719416 0.129 Uiso 1 1 calc R U . . .
C209 C 0.6446(9) 0.6872(8) 0.5705(6) 0.085(2) Uani 1 1 d . U . . .
H209 H 0.666067 0.693811 0.542690 0.102 Uiso 1 1 calc R U . . .
C210 C -0.2040(9) 0.6731(8) 0.8719(5) 0.086(2) Uani 1 1 d . U . . .
H210 H -0.183850 0.671465 0.897584 0.104 Uiso 1 1 calc R U . . .
C211 C 0.5675(8) 0.6270(8) 0.5114(5) 0.079(2) Uani 1 1 d . U . . .
H211 H 0.573876 0.656258 0.483956 0.095 Uiso 1 1 calc R U . . .
C212 C -0.3051(10) 0.7090(9) 0.8255(5) 0.090(3) Uani 1 1 d . U . . .
H212 H -0.354771 0.730181 0.819786 0.109 Uiso 1 1 calc R U . . .
C213 C 0.1844(9) 0.8239(7) 0.6042(5) 0.078(2) Uani 1 1 d . U . . .
H21A H 0.235041 0.818633 0.600454 0.094 Uiso 1 1 calc R U . . .
H21B H 0.179070 0.786331 0.598212 0.094 Uiso 1 1 calc R U . . .
C214 C -0.2101(9) 0.4570(8) 0.8077(5) 0.084(3) Uani 1 1 d . U . . .
H214 H -0.258505 0.467663 0.815666 0.101 Uiso 1 1 calc R U . . .
C215 C 0.1405(9) 0.8874(7) 0.5711(5) 0.082(2) Uani 1 1 d . U . . .
H21C H 0.090606 0.890272 0.572642 0.098 Uiso 1 1 calc R U . . .
H21D H 0.157516 0.886199 0.541444 0.098 Uiso 1 1 calc R U . . .
C216 C -0.0688(9) 0.9102(7) 0.6079(5) 0.076(2) Uani 1 1 d . U . . .
H216 H -0.026680 0.881973 0.624939 0.091 Uiso 1 1 calc R U . . .
C217 C 0.2850(10) 0.6163(9) 0.9137(6) 0.090(2) Uani 1 1 d . U . . .
H217 H 0.277623 0.628113 0.883044 0.108 Uiso 1 1 calc R U . . .
C218 C 0.6543(9) 0.6373(9) 0.6482(6) 0.089(3) Uani 1 1 d . U . . .
H218 H 0.682600 0.610813 0.674012 0.107 Uiso 1 1 calc R U . . .
C219 C -0.1887(9) 0.4998(8) 0.7721(5) 0.079(2) Uani 1 1 d . U . . .
H219 H -0.223634 0.539076 0.754500 0.094 Uiso 1 1 calc R U . . .
C220 C 0.6866(10) 0.6481(9) 0.6061(6) 0.091(3) Uani 1 1 d . U . . .
H220 H 0.736482 0.628131 0.603455 0.110 Uiso 1 1 calc R U . . .
Ag1D Ag 0.10684(4) 0.73655(3) 0.68560(2) 0.06225(17) Uani 0.58 1 d . U P A 1
Ag1E Ag 0.09843(4) 0.67198(4) 0.77773(2) 0.06690(17) Uani 0.51 1 d . U P A 1
Au1F Au 0.14338(4) 0.53171(4) 0.79250(2) 0.05891(17) Uani 0.33 1 d . U P A .
Ag1G Ag 0.15783(4) 0.63564(3) 0.64320(2) 0.05778(16) Uani 0.63 1 d . U P A 1
Au1H Au 0.17971(4) 0.50890(3) 0.70899(2) 0.05622(16) Uani 0.3 1 d . U P A .
Ag1I Ag 0.21254(4) 0.60847(3) 0.72840(2) 0.05828(16) Uani 0.57 1 d . U P A 1
Ag1J Ag 0.25701(4) 0.71956(4) 0.70011(2) 0.06320(17) Uani 0.63 1 d . U P A 1
Au1K Au 0.24843(4) 0.65484(4) 0.79226(2) 0.06087(17) Uani 0.31 1 d . U P A .
Ag1L Ag 0.30966(4) 0.61862(4) 0.65703(2) 0.06174(17) Uani 0.62 1 d . U P A 1
Ag1M Ag 0.33090(4) 0.49294(4) 0.72282(2) 0.06089(17) Uani 0.63 1 d . U P A 1
Au1N Au 0.29374(4) 0.51457(4) 0.80601(2) 0.05898(17) Uani 0.31 1 d . U P A .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au2 Au6 2.7125(6) . y
Au2 Au8 2.7294(6) . y
Au2 Au9 2.7130(6) . y
Au2 Au10 2.7271(7) . y
Au2 Au12 2.7214(7) . y
Au2 Au16 2.7952(8) . y
Au2 Ag25 2.7573(10) . y
Au2 Ag1J 2.7948(9) . y
Au2 Ag1L 2.7910(8) . y
Au4 Au5 2.9352(6) . y
Au4 Au11 2.7373(6) . y
Au4 Au 2.8521(8) . y
Au4 Ag1B 2.9794(9) . y
Au4 P2AA 2.319(3) . y
Au4 Au1C 2.9425(6) . y
Au4 Au1H 2.9822(9) . y
Au5 Au11 2.7038(6) . y
Au5 Ag14 2.9604(9) . y
Au5 Au1A 2.8984(6) . y
Au5 Ag1B 2.9747(10) . y
Au5 P17 2.296(3) . y
Au5 Au1H 2.8278(8) . y
Au6 Au8 2.9235(8) . y
Au6 Au10 2.9200(6) . y
Au6 Au16 2.9725(9) . y
Au6 Ag25 2.9455(10) . y
Au6 P0AA 2.302(3) . y
Au6 Ag1L 2.8487(9) . y
Au8 Au12 2.9164(7) . y
Au8 Ag25 2.9889(10) . y
Au8 P18 2.308(3) . y
Au8 Ag1J 2.8494(10) . y
Au8 Ag1L 2.9498(9) . y
Au9 Au10 2.9185(7) . y
Au9 Au12 2.8987(7) . y
Au9 Ag19 2.9178(9) . y
Au9 Ag25 2.9828(10) . y
Au9 P13 2.298(3) . y
Au9 Au1N 2.8520(9) . y
Au10 Au16 2.8649(9) . y
Au10 Ag25 2.9731(11) . y
Au10 P20 2.305(3) . y
Au10 Au1N 2.9484(9) . y
Au11 Au 2.7876(7) . y
Au11 Au0A 2.7231(6) . y
Au11 Au1A 2.7241(6) . y
Au11 Ag1B 2.7588(9) . y
Au11 Au1C 2.7196(6) . y
Au11 Ag1D 2.8002(8) . y
Au11 Au1H 2.8019(8) . y
Au12 Ag19 2.8524(9) . y
Au12 Ag25 2.9711(12) . y
Au12 P15 2.308(3) . y
Au12 Ag1J 2.9550(9) . y
Au Au1 2.8672(9) . y
Au S19 2.426(3) . y
Au Au1C 2.9760(9) . y
Au Ag1D 2.8800(9) . y
Au Au1H 2.8873(9) . y
Au Ag1L 3.0301(10) . y
Au1 Ag14 2.8720(9) . y
Au1 Au16 2.8713(10) . y
Au1 Ag1E 2.8702(9) . y
Au1 Ag1J 2.8665(10) . y
Ag14 Au1A 2.8315(9) . y
Ag14 S10 2.439(3) . y
Ag14 Ag1E 2.8786(10) . y
Ag14 Au1H 2.8860(9) . y
Ag14 Au1N 2.9976(10) . y
Au16 S18 2.437(3) . y
Au16 Au1H 3.0249(10) . y
Au16 Ag1L 2.8720(10) . y
Au16 Au1N 2.8668(9) . y
Ag19 S14 2.431(3) . y
Ag19 Ag1E 2.9975(11) . y
Ag19 Ag1J 2.8793(10) . y
Ag19 Au1N 2.8838(10) . y
Ag25 Cl20 2.390(3) . y
Au0A Au1A 2.9034(7) . y
Au0A Ag1B 2.9717(10) . y
Au0A Au1C 2.9223(6) . y
Au0A P16 2.307(4) . y
Au0A Ag1D 2.9814(9) . y
Au0A Ag1E 2.8457(9) . y
Au1A Ag1B 3.0053(9) . y
Au1A P1AA 2.302(3) . y
Au1A Ag1E 2.9583(9) . y
Ag1B Au1C 2.9721(9) . y
Ag1B Cl18 2.390(3) . y
S8 C213 1.811(15) . ?
S8 Ag1D 2.430(3) . y
S8 Ag1J 2.430(3) . y
S10 C140 1.838(15) . ?
S10 Au1N 2.438(3) . y
S14 C148 1.812(19) . ?
S14 Ag1E 2.435(3) . y
P13 C114 1.855(16) . ?
P13 C133 1.845(17) . ?
P13 C195 1.844(17) . ?
P15 C3 1.843(19) . ?
P15 C136 1.820(19) . ?
P15 C139 1.84(2) . ?
P2AA C2 1.816(14) . ?
P2AA C10 1.840(6) . ?
P2AA C36 1.805(14) . ?
P17 C42 1.818(14) . ?
P17 C67 1.802(15) . ?
P17 C71 1.803(16) . ?
P18 C34 1.820(16) . ?
P18 C104 1.797(18) . ?
P18 C152 1.808(16) . ?
S18 C137 1.834(16) . ?
S18 Au1H 2.429(3) . y
S19 C39 1.827(14) . ?
S19 Ag1L 2.420(3) . y
P0AA C23 1.848(16) . ?
P0AA C37 1.805(16) . ?
P0AA C197 1.818(15) . ?
P1AA C27 1.807(16) . ?
P1AA C29 1.805(17) . ?
P1AA C33 1.829(15) . ?
P20 C40 1.853(18) . ?
P20 C125 1.821(18) . ?
P20 C167 1.832(18) . ?
Au1C P4 2.310(3) . y
Au1C Ag1D 2.8322(8) . y
P4 C1 1.827(14) . ?
P4 C14 1.820(14) . ?
P4 C45 1.810(14) . ?
P16 C18 1.849(19) . ?
P16 C85 1.824(17) . ?
P16 C178 1.814(17) . ?
C1 C4 1.39(2) . ?
C1 C13 1.397(19) . ?
C2 C12 1.405(18) . ?
C2 C194 1.39(2) . ?
C3 C138 1.41(2) . ?
C3 C144 1.41(2) . ?
C4 H4 0.9500 . ?
C4 C21 1.357(19) . ?
C5 H5 0.9500 . ?
C5 C6 1.3900 . ?
C5 C10 1.3900 . ?
C6 H6 0.9500 . ?
C6 C7 1.3900 . ?
C7 H7 0.9500 . ?
C7 C8 1.3900 . ?
C8 H8 0.9500 . ?
C8 C9 1.3900 . ?
C9 H9 0.9500 . ?
C9 C10 1.3900 . ?
C11 H11 0.9500 . ?
C11 C31 1.34(2) . ?
C11 C90 1.43(2) . ?
C12 H12 0.9500 . ?
C12 C196 1.38(2) . ?
C13 H13 0.9500 . ?
C13 C115 1.39(2) . ?
C14 C65 1.39(2) . ?
C14 C216 1.40(2) . ?
C15 H15 0.9500 . ?
C15 C33 1.38(2) . ?
C15 C126 1.38(2) . ?
C16 H16 0.9500 . ?
C16 C110 1.42(2) . ?
C16 C120 1.34(2) . ?
C17 H17 0.9500 . ?
C17 C36 1.382(18) . ?
C17 C202 1.43(2) . ?
C18 C162 1.36(2) . ?
C18 C171 1.36(2) . ?
C19 H19 0.9500 . ?
C19 C67 1.40(2) . ?
C19 C199 1.42(2) . ?
C20 H20 0.9500 . ?
C20 C40 1.37(2) . ?
C20 C129 1.37(2) . ?
C21 H21 0.9500 . ?
C21 C64 1.350(19) . ?
C22 H22 0.9500 . ?
C22 C56 1.40(2) . ?
C22 C71 1.37(2) . ?
C23 C97 1.39(2) . ?
C23 C124 1.34(2) . ?
C24 H24 0.9500 . ?
C24 C45 1.39(2) . ?
C24 C66 1.36(2) . ?
C25 H25 0.9500 . ?
C25 C170 1.37(2) . ?
C25 C173 1.43(3) . ?
C26 H26 0.9500 . ?
C26 C42 1.38(2) . ?
C26 C205 1.42(2) . ?
C27 C46 1.39(2) . ?
C27 C87 1.40(2) . ?
C28 H28 0.9500 . ?
C28 C70 1.34(2) . ?
C28 C124 1.37(2) . ?
C29 C134 1.39(2) . ?
C29 C210 1.38(2) . ?
C30 H30 0.9500 . ?
C30 C67 1.39(2) . ?
C30 C219 1.36(2) . ?
C31 H31 0.9500 . ?
C31 C36 1.451(19) . ?
C32 H32 0.9500 . ?
C32 C37 1.38(2) . ?
C32 C118 1.43(2) . ?
C33 C35 1.37(2) . ?
C34 C60 1.42(2) . ?
C34 C72 1.41(2) . ?
C35 H35 0.9500 . ?
C35 C41 1.34(2) . ?
C37 C105 1.38(2) . ?
C38 H38 0.9500 . ?
C38 C197 1.42(2) . ?
C38 C203 1.38(2) . ?
C39 H39A 0.9900 . ?
C39 H39B 0.9900 . ?
C39 C76 1.547(18) . ?
C40 C62 1.36(2) . ?
C41 H41 0.9500 . ?
C41 C131 1.36(2) . ?
C42 C132 1.39(2) . ?
C43 H43 0.9500 . ?
C43 C66 1.38(2) . ?
C43 C143 1.31(2) . ?
C44 H44 0.9500 . ?
C44 C60 1.38(2) . ?
C44 C207 1.37(2) . ?
C45 C88 1.37(2) . ?
C46 H46 0.9500 . ?
C46 C198 1.37(2) . ?
C47 C48 1.3900 . ?
C47 C52 1.3900 . ?
C47 C180 1.537(19) . ?
C48 H48 0.9500 . ?
C48 C49 1.3900 . ?
C49 H49 0.9500 . ?
C49 C50 1.3900 . ?
C50 H50 0.9500 . ?
C50 C51 1.3900 . ?
C51 H51 0.9500 . ?
C51 C52 1.3900 . ?
C52 H52 0.9500 . ?
C53 H53 0.9500 . ?
C53 C113 1.37(2) . ?
C53 C195 1.41(2) . ?
C54 H54 0.9500 . ?
C54 C70 1.35(2) . ?
C54 C97 1.38(2) . ?
C55 H55 0.9500 . ?
C55 C91 1.37(2) . ?
C55 C96 1.38(2) . ?
C56 H56 0.9500 . ?
C56 C63 1.32(2) . ?
C57 H57 0.9500 . ?
C57 C87 1.38(2) . ?
C57 C117 1.34(2) . ?
C58 H58 0.9500 . ?
C58 C104 1.43(2) . ?
C58 C209 1.41(2) . ?
C59 H59 0.9500 . ?
C59 C68 1.41(2) . ?
C59 C121 1.37(3) . ?
C60 H60 0.9500 . ?
C61 H61 0.9500 . ?
C61 C210 1.36(2) . ?
C61 C212 1.40(2) . ?
C62 H62 0.9500 . ?
C62 C116 1.33(2) . ?
C63 H63 0.9500 . ?
C63 C109 1.25(2) . ?
C64 H64 0.9500 . ?
C64 C115 1.39(2) . ?
C65 H65 0.9500 . ?
C65 C130 1.41(2) . ?
C66 H66 0.9500 . ?
C68 H68 0.9500 . ?
C68 C133 1.39(2) . ?
C69 H69 0.9500 . ?
C69 C85 1.40(2) . ?
C69 C165 1.43(2) . ?
C70 H70 0.9500 . ?
C71 C93 1.39(2) . ?
C72 H72 0.9500 . ?
C72 C75 1.36(2) . ?
C73 H73 0.9500 . ?
C73 C134 1.34(2) . ?
C73 C212 1.40(2) . ?
C74 H74 0.9500 . ?
C74 C96 1.39(2) . ?
C74 C107 1.41(2) . ?
C75 H75 0.9500 . ?
C75 C207 1.40(2) . ?
C76 H76A 0.9900 . ?
C76 H76B 0.9900 . ?
C76 C107 1.52(2) . ?
C77 H77 0.9500 . ?
C77 C91 1.42(2) . ?
C77 C107 1.39(2) . ?
C78 H78 0.9500 . ?
C78 C79 1.3900 . ?
C78 C83 1.3900 . ?
C79 C80 1.3900 . ?
C79 C215 1.507(17) . ?
C80 H80 0.9500 . ?
C80 C81 1.3900 . ?
C81 H81 0.9500 . ?
C81 C82 1.3900 . ?
C82 H82 0.9500 . ?
C82 C83 1.3900 . ?
C83 H83 0.9500 . ?
C84 H84 0.9500 . ?
C84 C177 1.44(3) . ?
C84 C178 1.39(3) . ?
C85 C110 1.37(2) . ?
C86 H86 0.9500 . ?
C86 C111 1.37(2) . ?
C86 C130 1.38(2) . ?
C87 H87 0.9500 . ?
C88 H88 0.9500 . ?
C88 C143 1.389(19) . ?
C89 H89 0.9500 . ?
C89 C169 1.36(2) . ?
C89 C181 1.42(3) . ?
C90 H90 0.9500 . ?
C90 C202 1.33(2) . ?
C91 H91 0.9500 . ?
C92 H92A 0.9900 . ?
C92 H92B 0.9900 . ?
C92 C98 1.501(19) . ?
C92 C137 1.52(2) . ?
C93 H93 0.9500 . ?
C93 C109 1.51(2) . ?
C94 H94 0.9500 . ?
C94 C118 1.40(2) . ?
C94 C200 1.31(2) . ?
C95 H95 0.9500 . ?
C95 C106 1.39(2) . ?
C95 C108 1.42(2) . ?
C96 H96 0.9500 . ?
C97 H97 0.9500 . ?
C98 C99 1.3900 . ?
C98 C103 1.3900 . ?
C99 H99 0.9500 . ?
C99 C100 1.3900 . ?
C100 H100 0.9500 . ?
C100 C101 1.3900 . ?
C101 H101 0.9500 . ?
C101 C102 1.3900 . ?
C102 H102 0.9500 . ?
C102 C103 1.3900 . ?
C103 H103 0.9500 . ?
C104 C201 1.36(2) . ?
C105 H105 0.9500 . ?
C105 C200 1.43(2) . ?
C106 H106 0.9500 . ?
C106 C113 1.29(2) . ?
C108 H108 0.9500 . ?
C108 C195 1.38(2) . ?
C109 H109 0.9500 . ?
C110 H110 0.9500 . ?
C111 H111 0.9500 . ?
C111 C216 1.36(2) . ?
C112 H112 0.9500 . ?
C112 C121 1.34(2) . ?
C112 C217 1.37(3) . ?
C113 H113 0.9500 . ?
C114 C122 1.39(2) . ?
C114 C149 1.32(2) . ?
C115 H115 0.9500 . ?
C116 H116 0.9500 . ?
C116 C153 1.47(3) . ?
C117 H117 0.9500 . ?
C117 C198 1.35(2) . ?
C118 H118 0.9500 . ?
C119 H119 0.9500 . ?
C119 C135 1.29(2) . ?
C119 C205 1.42(2) . ?
C120 H120 0.9500 . ?
C120 C165 1.36(3) . ?
C121 H121 0.9500 . ?
C122 H122 0.9500 . ?
C122 C173 1.41(2) . ?
C123 H123 0.9500 . ?
C123 C197 1.37(2) . ?
C123 C206 1.39(2) . ?
C124 H124 0.9500 . ?
C125 C154 1.40(3) . ?
C125 C168 1.40(3) . ?
C126 H126 0.9500 . ?
C126 C131 1.42(2) . ?
C127 H127 0.9500 . ?
C127 C142 1.42(2) . ?
C127 C146 1.42(3) . ?
C128 H128 0.9500 . ?
C128 C136 1.36(3) . ?
C128 C188 1.41(3) . ?
C129 H129 0.9500 . ?
C129 C153 1.35(2) . ?
C130 H130 0.9500 . ?
C131 H131 0.9500 . ?
C132 H132 0.9500 . ?
C132 C135 1.38(2) . ?
C133 C217 1.36(2) . ?
C134 H134 0.9500 . ?
C135 H135 0.9500 . ?
C136 C186 1.33(3) . ?
C137 H13A 0.9900 . ?
C137 H13B 0.9900 . ?
C138 H138 0.9500 . ?
C138 C181 1.29(3) . ?
C139 C172 1.32(3) . ?
C139 C185 1.43(3) . ?
C140 H14A 0.9900 . ?
C140 H14B 0.9900 . ?
C140 C180 1.58(2) . ?
C141 H141 0.9500 . ?
C141 C155 1.40(2) . ?
C141 C167 1.38(2) . ?
C142 H142 0.9500 . ?
C142 C152 1.35(2) . ?
C143 H143 0.9500 . ?
C144 H144 0.9500 . ?
C144 C169 1.32(2) . ?
C145 H145 0.9500 . ?
C145 C152 1.38(2) . ?
C145 C190 1.39(3) . ?
C146 H146 0.9500 . ?
C146 C190 1.26(3) . ?
C147 H147 0.9500 . ?
C147 C163 1.36(3) . ?
C147 C168 1.42(2) . ?
C148 H14C 0.9900 . ?
C148 H14D 0.9900 . ?
C148 C184 1.39(3) . ?
C149 H149 0.9500 . ?
C149 C170 1.38(2) . ?
C150 H150 0.9500 . ?
C150 C167 1.41(2) . ?
C150 C175 1.37(2) . ?
C151 H151 0.9500 . ?
C151 C155 1.33(3) . ?
C151 C175 1.40(2) . ?
C153 H153 0.9500 . ?
C154 H154 0.9500 . ?
C154 C182 1.38(3) . ?
C155 H155 0.9500 . ?
C156 C157 1.3900 . ?
C156 C161 1.3900 . ?
C156 C184 1.45(2) . ?
C157 H157 0.9500 . ?
C157 C158 1.3900 . ?
C158 H158 0.9500 . ?
C158 C159 1.3900 . ?
C159 H159 0.9500 . ?
C159 C160 1.3900 . ?
C160 H160 0.9500 . ?
C160 C161 1.3900 . ?
C161 H161 0.9500 . ?
C162 H162 0.9500 . ?
C162 C187 1.40(3) . ?
C163 H163 0.9500 . ?
C163 C182 1.32(3) . ?
C164 H164 0.9500 . ?
C164 C178 1.38(3) . ?
C164 C183 1.51(3) . ?
C165 H165 0.9500 . ?
C166 H166 0.9500 . ?
C166 C171 1.38(3) . ?
C166 C176 1.41(3) . ?
C168 H168 0.9500 . ?
C169 H169 0.9500 . ?
C170 H170 0.9500 . ?
C171 H171 0.9500 . ?
C172 H172 0.9500 . ?
C172 C204 1.33(3) . ?
C173 H173 0.9500 . ?
C174 H174 0.9500 . ?
C174 C179 1.33(3) . ?
C174 C188 1.29(3) . ?
C175 H175 0.9500 . ?
C176 H176 0.9500 . ?
C176 C187 1.45(3) . ?
C177 H177 0.9500 . ?
C177 C189 1.26(3) . ?
C179 H179 0.9500 . ?
C179 C186 1.47(3) . ?
C180 H18A 0.9900 . ?
C180 H18B 0.9900 . ?
C181 H181 0.9500 . ?
C182 H182 0.9500 . ?
C183 H183 0.9500 . ?
C183 C189 1.31(3) . ?
C184 H18C 0.9900 . ?
C184 H18D 0.9900 . ?
C185 H185 0.9500 . ?
C185 C191 1.48(3) . ?
C186 H186 0.9500 . ?
C187 H187 0.9500 . ?
C188 H188 0.9500 . ?
C189 H189 0.9500 . ?
C190 H190 0.9500 . ?
C191 H191 0.9500 . ?
C191 C208 1.36(3) . ?
C192 H192 0.9500 . ?
C192 C193 1.37(2) . ?
C192 C196 1.39(2) . ?
C193 H193 0.9500 . ?
C193 C194 1.37(2) . ?
C194 H194 0.9500 . ?
C196 H196 0.9500 . ?
C198 H198 0.9500 . ?
C199 H199 0.9500 . ?
C199 C214 1.38(2) . ?
C200 H200 0.9500 . ?
C201 H201 0.9500 . ?
C201 C218 1.40(2) . ?
C202 H202 0.9500 . ?
C203 H203 0.9500 . ?
C203 C211 1.37(2) . ?
C204 H204 0.9500 . ?
C204 C208 1.39(3) . ?
C205 H205 0.9500 . ?
C206 H206 0.9500 . ?
C206 C211 1.34(2) . ?
C207 H207 0.9500 . ?
C208 H208 0.9500 . ?
C209 H209 0.9500 . ?
C209 C220 1.35(2) . ?
C210 H210 0.9500 . ?
C211 H211 0.9500 . ?
C212 H212 0.9500 . ?
C213 H21A 0.9900 . ?
C213 H21B 0.9900 . ?
C213 C215 1.50(2) . ?
C214 H214 0.9500 . ?
C214 C219 1.40(2) . ?
C215 H21C 0.9900 . ?
C215 H21D 0.9900 . ?
C216 H216 0.9500 . ?
C217 H217 0.9500 . ?
C218 H218 0.9500 . ?
C218 C220 1.43(2) . ?
C219 H219 0.9500 . ?
C220 H220 0.9500 . ?
Ag1D Ag1E 2.8773(9) . y
Ag1D Ag1J 3.0017(10) . y
Ag1J Ag1L 2.8963(10) . y

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Au6 Au2 Au8 64.988(19) . . y
Au6 Au2 Au9 120.26(2) . . y
Au6 Au2 Au10 64.931(18) . . y
Au6 Au2 Au12 119.79(2) . . y
Au6 Au2 Au16 65.31(2) . . y
Au6 Au2 Ag25 65.16(2) . . y
Au6 Au2 Ag1J 114.92(2) . . y
Au6 Au2 Ag1L 62.33(2) . . y
Au8 Au2 Au16 118.73(2) . . y
Au8 Au2 Ag25 66.01(2) . . y
Au8 Au2 Ag1J 62.09(2) . . y
Au8 Au2 Ag1L 64.59(2) . . y
Au9 Au2 Au8 120.33(2) . . y
Au9 Au2 Au10 64.888(18) . . y
Au9 Au2 Au12 64.471(17) . . y
Au9 Au2 Au16 114.53(2) . . y
Au9 Au2 Ag25 66.08(2) . . y
Au9 Au2 Ag1J 117.80(2) . . y
Au9 Au2 Ag1L 174.89(3) . . y
Au10 Au2 Au8 120.76(2) . . y
Au10 Au2 Au16 62.49(2) . . y
Au10 Au2 Ag25 65.65(3) . . y
Au10 Au2 Ag1J 175.07(3) . . y
Au10 Au2 Ag1L 114.45(2) . . y
Au12 Au2 Au8 64.693(18) . . y
Au12 Au2 Au10 119.86(2) . . y
Au12 Au2 Au16 174.80(3) . . y
Au12 Au2 Ag25 65.68(3) . . y
Au12 Au2 Ag1J 64.76(2) . . y
Au12 Au2 Ag1L 118.73(2) . . y
Ag25 Au2 Au16 118.98(3) . . y
Ag25 Au2 Ag1J 119.03(3) . . y
Ag25 Au2 Ag1L 118.60(3) . . y
Ag1J Au2 Au16 112.76(3) . . y
Ag1L Au2 Au16 61.88(2) . . y
Ag1L Au2 Ag1J 62.46(2) . . y
Au5 Au4 Ag1B 60.38(2) . . y
Au5 Au4 Au1C 106.849(17) . . y
Au5 Au4 Au1H 57.087(18) . . y
Au11 Au4 Au5 56.805(14) . . y
Au11 Au4 Au 59.790(18) . . y
Au11 Au4 Ag1B 57.52(2) . . y
Au11 Au4 Au1C 57.079(15) . . y
Au11 Au4 Au1H 58.481(18) . . y
Au Au4 Au5 105.78(2) . . y
Au Au4 Ag1B 110.06(2) . . y
Au Au4 Au1C 61.781(19) . . y
Au Au4 Au1H 59.27(2) . . y
Ag1B Au4 Au1H 106.80(2) . . y
P2AA Au4 Au5 123.73(8) . . y
P2AA Au4 Au11 179.39(8) . . y
P2AA Au4 Au 119.99(8) . . y
P2AA Au4 Ag1B 122.36(8) . . y
P2AA Au4 Au1C 122.32(8) . . y
P2AA Au4 Au1H 121.98(8) . . y
Au1C Au4 Ag1B 60.24(2) . . y
Au1C Au4 Au1H 107.31(2) . . y
Au4 Au5 Ag14 108.67(2) . . y
Au4 Au5 Ag1B 60.54(2) . . y
Au11 Au5 Au4 57.906(15) . . y
Au11 Au5 Ag14 59.471(19) . . y
Au11 Au5 Au1A 58.065(15) . . y
Au11 Au5 Ag1B 57.90(2) . . y
Au11 Au5 Au1H 60.818(19) . . y
Ag14 Au5 Ag1B 108.24(3) . . y
Au1A Au5 Au4 108.886(19) . . y
Au1A Au5 Ag14 57.788(19) . . y
Au1A Au5 Ag1B 61.54(2) . . y
P17 Au5 Au4 122.02(8) . . y
P17 Au5 Au11 178.91(9) . . y
P17 Au5 Ag14 121.22(8) . . y
P17 Au5 Au1A 121.40(8) . . y
P17 Au5 Ag1B 121.04(9) . . y
P17 Au5 Au1H 120.21(9) . . y
Au1H Au5 Au4 62.293(19) . . y
Au1H Au5 Ag14 59.76(2) . . y
Au1H Au5 Au1A 107.49(2) . . y
Au1H Au5 Ag1B 111.12(3) . . y
Au2 Au6 Au8 57.785(17) . . y
Au2 Au6 Au10 57.776(16) . . y
Au2 Au6 Au16 58.689(19) . . y
Au2 Au6 Ag25 58.16(2) . . y
Au2 Au6 Ag1L 60.188(19) . . y
Au8 Au6 Au16 107.46(2) . . y
Au8 Au6 Ag25 61.23(2) . . y
Au10 Au6 Au8 108.54(2) . . y
Au10 Au6 Au16 58.173(19) . . y
Au10 Au6 Ag25 60.91(2) . . y
Ag25 Au6 Au16 107.87(3) . . y
P0AA Au6 Au2 178.87(10) . . y
P0AA Au6 Au8 123.34(10) . . y
P0AA Au6 Au10 121.22(9) . . y
P0AA Au6 Au16 120.47(10) . . y
P0AA Au6 Ag25 122.05(9) . . y
P0AA Au6 Ag1L 120.23(8) . . y
Ag1L Au6 Au8 61.45(2) . . y
Ag1L Au6 Au10 107.08(2) . . y
Ag1L Au6 Au16 59.08(2) . . y
Ag1L Au6 Ag25 110.84(3) . . y
Au2 Au8 Au6 57.227(16) . . y
Au2 Au8 Au12 57.521(16) . . y
Au2 Au8 Ag25 57.44(2) . . y
Au2 Au8 Ag1J 60.08(2) . . y
Au2 Au8 Ag1L 58.718(18) . . y
Au6 Au8 Ag25 59.75(2) . . y
Au6 Au8 Ag1L 58.03(2) . . y
Au12 Au8 Au6 107.21(2) . . y
Au12 Au8 Ag25 60.40(2) . . y
Au12 Au8 Ag1L 107.91(2) . . y
P18 Au8 Au2 178.48(11) . . y
P18 Au8 Au6 121.40(10) . . y
P18 Au8 Au12 123.23(9) . . y
P18 Au8 Ag25 121.51(9) . . y
P18 Au8 Ag1J 121.39(10) . . y
P18 Au8 Ag1L 121.42(9) . . y
Ag1J Au8 Au6 107.07(2) . . y
Ag1J Au8 Au12 61.65(2) . . y
Ag1J Au8 Ag25 110.05(3) . . y
Ag1J Au8 Ag1L 59.89(2) . . y
Ag1L Au8 Ag25 106.90(3) . . y
Au2 Au9 Au10 57.791(16) . . y
Au2 Au9 Au12 57.906(16) . . y
Au2 Au9 Ag19 59.443(19) . . y
Au2 Au9 Ag25 57.67(2) . . y
Au2 Au9 Au1N 60.437(19) . . y
Au10 Au9 Ag25 60.49(2) . . y
Au12 Au9 Au10 108.299(19) . . y
Au12 Au9 Ag19 58.73(2) . . y
Au12 Au9 Ag25 60.66(2) . . y
Ag19 Au9 Au10 108.36(2) . . y
Ag19 Au9 Ag25 108.17(3) . . y
P13 Au9 Au2 178.40(9) . . y
P13 Au9 Au10 122.57(10) . . y
P13 Au9 Au12 120.92(9) . . y
P13 Au9 Ag19 121.17(10) . . y
P13 Au9 Ag25 120.94(9) . . y
P13 Au9 Au1N 121.16(9) . . y
Au1N Au9 Au10 61.44(2) . . y
Au1N Au9 Au12 107.88(2) . . y
Au1N Au9 Ag19 59.96(2) . . y
Au1N Au9 Ag25 110.27(3) . . y
Au2 Au10 Au6 57.293(16) . . y
Au2 Au10 Au9 57.322(16) . . y
Au2 Au10 Au16 59.92(2) . . y
Au2 Au10 Ag25 57.66(2) . . y
Au2 Au10 Au1N 59.046(19) . . y
Au6 Au10 Ag25 59.97(2) . . y
Au6 Au10 Au1N 107.71(2) . . y
Au9 Au10 Au6 107.38(2) . . y
Au9 Au10 Ag25 60.83(2) . . y
Au9 Au10 Au1N 58.17(2) . . y
Au16 Au10 Au6 61.832(19) . . y
Au16 Au10 Au9 106.49(2) . . y
Au16 Au10 Ag25 110.04(3) . . y
Au16 Au10 Au1N 59.07(2) . . y
P20 Au10 Au2 179.04(10) . . y
P20 Au10 Au6 122.83(9) . . y
P20 Au10 Au9 123.09(9) . . y
P20 Au10 Au16 119.20(10) . . y
P20 Au10 Ag25 123.28(10) . . y
P20 Au10 Au1N 120.29(9) . . y
Au1N Au10 Ag25 107.92(3) . . y
Au4 Au11 Au 62.151(19) . . y
Au4 Au11 Ag1B 65.65(2) . . y
Au4 Au11 Ag1D 114.14(2) . . y
Au4 Au11 Au1H 65.133(19) . . y
Au5 Au11 Au4 65.289(16) . . y
Au5 Au11 Au 114.38(2) . . y
Au5 Au11 Au0A 119.63(2) . . y
Au5 Au11 Au1A 64.549(17) . . y
Au5 Au11 Ag1B 65.98(2) . . y
Au5 Au11 Au1C 121.00(2) . . y
Au5 Au11 Ag1D 174.82(3) . . y
Au5 Au11 Au1H 61.777(19) . . y
Au Au11 Ag1D 62.05(2) . . y
Au Au11 Au1H 62.20(2) . . y
Au0A Au11 Au4 120.53(2) . . y
Au0A Au11 Au 119.57(2) . . y
Au0A Au11 Au1A 64.417(17) . . y
Au0A Au11 Ag1B 65.65(2) . . y
Au0A Au11 Ag1D 65.32(2) . . y
Au0A Au11 Au1H 174.34(2) . . y
Au1A Au11 Au4 120.68(2) . . y
Au1A Au11 Au 173.90(3) . . y
Au1A Au11 Ag1B 66.47(2) . . y
Au1A Au11 Ag1D 118.55(2) . . y
Au1A Au11 Au1H 113.35(2) . . y
Ag1B Au11 Au 119.01(2) . . y
Ag1B Au11 Ag1D 118.80(3) . . y
Ag1B Au11 Au1H 118.78(3) . . y
Au1C Au11 Au4 65.262(16) . . y
Au1C Au11 Au 65.41(2) . . y
Au1C Au11 Au0A 64.950(17) . . y
Au1C Au11 Au1A 120.53(2) . . y
Au1C Au11 Ag1B 65.70(2) . . y
Au1C Au11 Ag1D 61.721(19) . . y
Au1C Au11 Au1H 119.60(2) . . y
Ag1D Au11 Au1H 113.14(3) . . y
Au2 Au12 Au8 57.787(16) . . y
Au2 Au12 Au9 57.623(16) . . y
Au2 Au12 Ag19 60.19(2) . . y
Au2 Au12 Ag25 57.74(2) . . y
Au2 Au12 Ag1J 58.82(2) . . y
Au8 Au12 Ag25 61.01(2) . . y
Au8 Au12 Ag1J 58.06(2) . . y
Au9 Au12 Au8 108.56(2) . . y
Au9 Au12 Ag25 61.07(2) . . y
Au9 Au12 Ag1J 107.36(2) . . y
Ag19 Au12 Au8 107.17(2) . . y
Ag19 Au12 Au9 60.97(2) . . y
Ag19 Au12 Ag25 110.28(3) . . y
Ag19 Au12 Ag1J 59.41(2) . . y
P15 Au12 Au2 179.07(11) . . y
P15 Au12 Au8 121.47(10) . . y
P15 Au12 Au9 122.69(9) . . y
P15 Au12 Ag19 120.74(11) . . y
P15 Au12 Ag25 121.50(11) . . y
P15 Au12 Ag1J 121.45(10) . . y
Ag1J Au12 Ag25 107.68(3) . . y
Au4 Au Au1 110.60(3) . . y
Au4 Au Au1C 60.603(19) . . y
Au4 Au Ag1D 108.36(3) . . y
Au4 Au Au1H 62.61(2) . . y
Au4 Au Ag1L 150.28(3) . . y
Au11 Au Au4 58.059(18) . . y
Au11 Au Au1 60.75(2) . . y
Au11 Au Au1C 56.195(18) . . y
Au11 Au Ag1D 59.19(2) . . y
Au11 Au Au1H 59.14(2) . . y
Au11 Au Ag1L 119.22(3) . . y
Au1 Au Au1C 106.78(3) . . y
Au1 Au Ag1D 60.34(2) . . y
Au1 Au Au1H 60.00(2) . . y
Au1 Au Ag1L 58.47(2) . . y
S19 Au Au4 126.70(7) . . y
S19 Au Au11 169.20(8) . . y
S19 Au Au1 109.46(7) . . y
S19 Au Au1C 134.28(7) . . y
S19 Au Ag1D 121.54(7) . . y
S19 Au Au1H 112.88(7) . . y
S19 Au Ag1L 51.21(7) . . y
Au1C Au Ag1L 146.38(3) . . y
Ag1D Au Au1C 57.82(2) . . y
Ag1D Au Au1H 108.32(3) . . y
Ag1D Au Ag1L 90.34(3) . . y
Au1H Au Au1C 108.95(3) . . y
Au1H Au Ag1L 90.02(3) . . y
Au2 Au1 Au11 179.61(3) . . y
Au2 Au1 Au 121.77(3) . . y
Au2 Au1 Ag14 121.32(3) . . y
Au2 Au1 Au16 58.41(2) . . y
Au2 Au1 Ag1E 121.15(3) . . y
Au2 Au1 Ag1J 58.46(2) . . y
Au11 Au1 Au 58.25(2) . . y
Au11 Au1 Ag14 58.90(2) . . y
Au11 Au1 Au16 121.96(3) . . y
Au11 Au1 Ag1E 58.61(2) . . y
Au11 Au1 Ag1J 121.18(3) . . y
Au Au1 Ag14 108.65(3) . . y
Au Au1 Au16 93.23(3) . . y
Au Au1 Ag1E 108.18(3) . . y
Au16 Au1 Ag14 93.00(3) . . y
Ag1E Au1 Ag14 60.17(2) . . y
Ag1E Au1 Au16 149.57(3) . . y
Ag1J Au1 Au 92.98(3) . . y
Ag1J Au1 Ag14 148.73(3) . . y
Ag1J Au1 Au16 108.44(3) . . y
Ag1J Au1 Ag1E 92.17(3) . . y
Au5 Ag14 Au1N 146.18(3) . . y
Au11 Ag14 Au5 55.729(18) . . y
Au11 Ag14 Au1 60.34(2) . . y
Au11 Ag14 Au1A 57.654(19) . . y
Au11 Ag14 Ag1E 58.97(2) . . y
Au11 Ag14 Au1H 58.82(2) . . y
Au11 Ag14 Au1N 119.06(3) . . y
Au1 Ag14 Au5 106.17(3) . . y
Au1 Ag14 Ag1E 59.88(2) . . y
Au1 Ag14 Au1H 59.96(2) . . y
Au1 Ag14 Au1N 58.72(2) . . y
Au1A Ag14 Au5 60.01(2) . . y
Au1A Ag14 Au1 109.96(3) . . y
Au1A Ag14 Ag1E 62.40(2) . . y
Au1A Ag14 Au1H 107.73(3) . . y
Au1A Ag14 Au1N 150.74(3) . . y
S10 Ag14 Au5 134.75(8) . . y
S10 Ag14 Au11 169.40(8) . . y
S10 Ag14 Au1 110.44(8) . . y
S10 Ag14 Au1A 126.22(8) . . y
S10 Ag14 Ag1E 112.67(8) . . y
S10 Ag14 Au1H 122.74(8) . . y
S10 Ag14 Au1N 52.06(8) . . y
Ag1E Ag14 Au5 108.26(3) . . y
Ag1E Ag14 Au1H 107.85(3) . . y
Ag1E Ag14 Au1N 90.41(3) . . y
Au1H Ag14 Au5 57.83(2) . . y
Au1H Ag14 Au1N 90.04(3) . . y
Au2 Au16 Au6 56.005(19) . . y
Au2 Au16 Au10 57.59(2) . . y
Au2 Au16 Au1 60.54(2) . . y
Au2 Au16 Au1H 118.89(3) . . y
Au2 Au16 Ag1L 58.99(2) . . y
Au2 Au16 Au1N 59.34(2) . . y
Au6 Au16 Au1H 147.12(3) . . y
Au10 Au16 Au6 60.00(2) . . y
Au10 Au16 Au1 109.83(3) . . y
Au10 Au16 Au1H 149.76(3) . . y
Au10 Au16 Ag1L 107.95(3) . . y
Au10 Au16 Au1N 61.92(2) . . y
Au1 Au16 Au6 106.88(3) . . y
Au1 Au16 Au1H 58.35(2) . . y
Au1 Au16 Ag1L 60.28(2) . . y
S18 Au16 Au2 169.19(8) . . y
S18 Au16 Au6 134.47(8) . . y
S18 Au16 Au10 127.25(8) . . y
S18 Au16 Au1 109.59(8) . . y
S18 Au16 Au1H 51.45(7) . . y
S18 Au16 Ag1L 121.57(7) . . y
S18 Au16 Au1N 112.84(7) . . y
Ag1L Au16 Au6 58.31(2) . . y
Ag1L Au16 Au1H 90.41(3) . . y
Au1N Au16 Au6 108.48(3) . . y
Au1N Au16 Au1 60.25(2) . . y
Au1N Au16 Au1H 89.86(3) . . y
Au1N Au16 Ag1L 108.52(3) . . y
Au2 Ag19 Au9 56.633(19) . . y
Au2 Ag19 Au12 57.58(2) . . y
Au2 Ag19 Au1 60.39(2) . . y
Au2 Ag19 Ag1E 118.79(3) . . y
Au2 Ag19 Ag1J 58.97(2) . . y
Au2 Ag19 Au1N 59.11(2) . . y
Au9 Ag19 Ag1E 147.45(3) . . y
Au12 Ag19 Au9 60.30(2) . . y
Au12 Ag19 Au1 109.64(3) . . y
Au12 Ag19 Ag1E 149.26(3) . . y
Au12 Ag19 Ag1J 62.07(2) . . y
Au12 Ag19 Au1N 108.28(3) . . y
Au1 Ag19 Au9 107.27(3) . . y
Au1 Ag19 Ag1E 58.40(2) . . y
Au1 Ag19 Au1N 59.93(2) . . y
S14 Ag19 Au2 169.51(8) . . y
S14 Ag19 Au9 133.66(8) . . y
S14 Ag19 Au12 126.66(8) . . y
S14 Ag19 Au1 110.24(8) . . y
S14 Ag19 Ag1E 52.03(8) . . y
S14 Ag19 Ag1J 113.06(8) . . y
S14 Ag19 Au1N 121.87(8) . . y
Ag1J Ag19 Au9 108.89(3) . . y
Ag1J Ag19 Au1 59.68(2) . . y
Ag1J Ag19 Ag1E 89.34(3) . . y
Ag1J Ag19 Au1N 107.88(3) . . y
Au1N Ag19 Au9 58.89(2) . . y
Au1N Ag19 Ag1E 90.31(3) . . y
Au2 Ag25 Au6 56.69(2) . . y
Au2 Ag25 Au8 56.55(2) . . y
Au2 Ag25 Au9 56.24(2) . . y
Au2 Ag25 Au10 56.69(2) . . y
Au2 Ag25 Au12 56.58(2) . . y
Au6 Ag25 Au8 59.02(2) . . y
Au6 Ag25 Au9 105.05(3) . . y
Au6 Ag25 Au10 59.12(2) . . y
Au6 Ag25 Au12 105.22(3) . . y
Au9 Ag25 Au8 104.48(3) . . y
Au10 Ag25 Au8 105.43(3) . . y
Au10 Ag25 Au9 58.68(2) . . y
Au12 Ag25 Au8 58.59(2) . . y
Au12 Ag25 Au9 58.27(2) . . y
Au12 Ag25 Au10 104.98(3) . . y
Cl20 Ag25 Au2 178.95(11) . . y
Cl20 Ag25 Au6 122.61(10) . . y
Cl20 Ag25 Au8 123.99(9) . . y
Cl20 Ag25 Au9 123.86(9) . . y
Cl20 Ag25 Au10 122.35(11) . . y
Cl20 Ag25 Au12 124.45(11) . . y
Au11 Au0A Au1A 57.809(15) . . y
Au11 Au0A Ag1B 57.75(2) . . y
Au11 Au0A Au1C 57.467(15) . . y
Au11 Au0A Ag1D 58.588(18) . . y
Au11 Au0A Ag1E 60.434(19) . . y
Au1A Au0A Ag1B 61.52(2) . . y
Au1A Au0A Au1C 108.460(19) . . y
Au1A Au0A Ag1D 107.60(2) . . y
Ag1B Au0A Ag1D 106.98(2) . . y
Au1C Au0A Ag1B 60.56(2) . . y
Au1C Au0A Ag1D 57.326(18) . . y
P16 Au0A Au11 177.84(11) . . y
P16 Au0A Au1A 123.59(10) . . y
P16 Au0A Ag1B 121.04(11) . . y
P16 Au0A Au1C 120.46(10) . . y
P16 Au0A Ag1D 121.22(10) . . y
P16 Au0A Ag1E 121.53(11) . . y
Ag1E Au0A Au1A 61.93(2) . . y
Ag1E Au0A Ag1B 111.14(3) . . y
Ag1E Au0A Au1C 106.58(2) . . y
Ag1E Au0A Ag1D 59.12(2) . . y
Au5 Au1A Au0A 107.909(18) . . y
Au5 Au1A Ag1B 60.48(2) . . y
Au5 Au1A Ag1E 107.78(2) . . y
Au11 Au1A Au5 57.386(15) . . y
Au11 Au1A Ag14 60.930(19) . . y
Au11 Au1A Au0A 57.774(15) . . y
Au11 Au1A Ag1B 57.32(2) . . y
Au11 Au1A Ag1E 58.977(18) . . y
Ag14 Au1A Au5 62.20(2) . . y
Ag14 Au1A Au0A 107.65(2) . . y
Ag14 Au1A Ag1B 110.92(2) . . y
Ag14 Au1A Ag1E 59.58(2) . . y
Au0A Au1A Ag1B 60.36(2) . . y
Au0A Au1A Ag1E 58.08(2) . . y
P1AA Au1A Au5 123.40(9) . . y
P1AA Au1A Au11 178.95(10) . . y
P1AA Au1A Ag14 119.95(9) . . y
P1AA Au1A Au0A 121.19(9) . . y
P1AA Au1A Ag1B 122.24(9) . . y
P1AA Au1A Ag1E 120.78(9) . . y
Ag1E Au1A Ag1B 107.15(2) . . y
Au4 Ag1B Au1A 104.93(3) . . y
Au5 Ag1B Au4 59.07(2) . . y
Au5 Ag1B Au1A 57.98(2) . . y
Au11 Ag1B Au4 56.83(2) . . y
Au11 Ag1B Au5 56.12(2) . . y
Au11 Ag1B Au0A 56.60(2) . . y
Au11 Ag1B Au1A 56.211(19) . . y
Au11 Ag1B Au1C 56.51(2) . . y
Au0A Ag1B Au4 105.63(3) . . y
Au0A Ag1B Au5 104.16(3) . . y
Au0A Ag1B Au1A 58.12(2) . . y
Au0A Ag1B Au1C 58.90(2) . . y
Au1C Ag1B Au4 59.26(2) . . y
Au1C Ag1B Au5 105.07(3) . . y
Au1C Ag1B Au1A 104.52(3) . . y
Cl18 Ag1B Au4 120.43(8) . . y
Cl18 Ag1B Au5 123.75(8) . . y
Cl18 Ag1B Au11 177.15(8) . . y
Cl18 Ag1B Au0A 125.17(9) . . y
Cl18 Ag1B Au1A 126.46(8) . . y
Cl18 Ag1B Au1C 121.89(8) . . y
C213 S8 Ag1D 105.2(5) . . ?
C213 S8 Ag1J 101.5(5) . . ?
Ag1D S8 Ag1J 76.28(9) . . ?
C140 S10 Ag14 104.0(6) . . ?
C140 S10 Au1N 100.6(5) . . ?
Au1N S10 Ag14 75.86(8) . . ?
Ag19 S14 Ag1E 76.05(8) . . ?
C148 S14 Ag19 103.6(7) . . ?
C148 S14 Ag1E 102.6(6) . . ?
C114 P13 Au9 111.0(5) . . ?
C133 P13 Au9 114.9(5) . . ?
C133 P13 C114 108.4(7) . . ?
C195 P13 Au9 113.4(5) . . ?
C195 P13 C114 105.1(8) . . ?
C195 P13 C133 103.3(8) . . ?
C3 P15 Au12 112.9(5) . . ?
C136 P15 Au12 116.3(6) . . ?
C136 P15 C3 101.8(9) . . ?
C136 P15 C139 106.5(9) . . ?
C139 P15 Au12 109.4(6) . . ?
C139 P15 C3 109.5(9) . . ?
C2 P2AA Au4 114.2(4) . . ?
C2 P2AA C10 101.4(5) . . ?
C10 P2AA Au4 115.7(3) . . ?
C36 P2AA Au4 114.4(4) . . ?
C36 P2AA C2 106.0(6) . . ?
C36 P2AA C10 103.7(5) . . ?
C42 P17 Au5 115.2(5) . . ?
C67 P17 Au5 110.7(5) . . ?
C67 P17 C42 104.2(7) . . ?
C67 P17 C71 107.9(7) . . ?
C71 P17 Au5 114.1(5) . . ?
C71 P17 C42 104.1(7) . . ?
C34 P18 Au8 114.4(5) . . ?
C104 P18 Au8 110.7(5) . . ?
C104 P18 C34 107.4(8) . . ?
C104 P18 C152 105.7(8) . . ?
C152 P18 Au8 116.4(6) . . ?
C152 P18 C34 101.2(7) . . ?
C137 S18 Au16 100.1(5) . . ?
C137 S18 Au1H 106.0(5) . . ?
Au1H S18 Au16 76.87(9) . . ?
C39 S19 Au 102.0(4) . . ?
C39 S19 Ag1L 106.6(5) . . ?
Ag1L S19 Au 77.39(8) . . ?
C23 P0AA Au6 113.3(5) . . ?
C37 P0AA Au6 113.1(5) . . ?
C37 P0AA C23 107.4(8) . . ?
C37 P0AA C197 103.5(7) . . ?
C197 P0AA Au6 114.3(5) . . ?
C197 P0AA C23 104.5(7) . . ?
C27 P1AA Au1A 115.8(5) . . ?
C27 P1AA C33 103.9(7) . . ?
C29 P1AA Au1A 111.1(5) . . ?
C29 P1AA C27 103.7(8) . . ?
C29 P1AA C33 107.3(7) . . ?
C33 P1AA Au1A 114.2(5) . . ?
C40 P20 Au10 112.4(6) . . ?
C125 P20 Au10 115.5(6) . . ?
C125 P20 C40 103.5(8) . . ?
C125 P20 C167 103.6(9) . . ?
C167 P20 Au10 114.1(6) . . ?
C167 P20 C40 106.5(8) . . ?
Au4 Au1C Au 57.615(19) . . y
Au4 Au1C Ag1B 60.49(2) . . y
Au11 Au1C Au4 57.660(15) . . y
Au11 Au1C Au 58.399(18) . . y
Au11 Au1C Au0A 57.583(15) . . y
Au11 Au1C Ag1B 57.78(2) . . y
Au11 Au1C Ag1D 60.540(19) . . y
Au0A Au1C Au4 107.887(18) . . y
Au0A Au1C Au 107.68(2) . . y
Au0A Au1C Ag1B 60.55(2) . . y
Ag1B Au1C Au 106.93(3) . . y
P4 Au1C Au4 122.32(8) . . y
P4 Au1C Au11 178.54(8) . . y
P4 Au1C Au 120.24(8) . . y
P4 Au1C Au0A 123.22(8) . . y
P4 Au1C Ag1B 123.61(8) . . y
P4 Au1C Ag1D 118.51(8) . . y
Ag1D Au1C Au4 107.18(2) . . y
Ag1D Au1C Au 59.39(2) . . y
Ag1D Au1C Au0A 62.386(19) . . y
Ag1D Au1C Ag1B 111.03(2) . . y
C1 P4 Au1C 111.9(4) . . ?
C14 P4 Au1C 116.2(5) . . ?
C14 P4 C1 104.7(6) . . ?
C45 P4 Au1C 113.0(4) . . ?
C45 P4 C1 106.5(6) . . ?
C45 P4 C14 103.6(7) . . ?
C18 P16 Au0A 110.9(5) . . ?
C85 P16 Au0A 113.5(6) . . ?
C85 P16 C18 108.4(8) . . ?
C178 P16 Au0A 116.2(6) . . ?
C178 P16 C18 105.7(8) . . ?
C178 P16 C85 101.4(8) . . ?
C4 C1 P4 119.7(10) . . ?
C4 C1 C13 118.1(13) . . ?
C13 C1 P4 122.3(11) . . ?
C12 C2 P2AA 122.7(11) . . ?
C194 C2 P2AA 120.2(10) . . ?
C194 C2 C12 117.1(13) . . ?
C138 C3 P15 124.7(14) . . ?
C144 C3 P15 119.4(13) . . ?
C144 C3 C138 115.9(17) . . ?
C1 C4 H4 119.8 . . ?
C21 C4 C1 120.4(13) . . ?
C21 C4 H4 119.8 . . ?
C6 C5 H5 120.0 . . ?
C6 C5 C10 120.0 . . ?
C10 C5 H5 120.0 . . ?
C5 C6 H6 120.0 . . ?
C7 C6 C5 120.0 . . ?
C7 C6 H6 120.0 . . ?
C6 C7 H7 120.0 . . ?
C6 C7 C8 120.0 . . ?
C8 C7 H7 120.0 . . ?
C7 C8 H8 120.0 . . ?
C7 C8 C9 120.0 . . ?
C9 C8 H8 120.0 . . ?
C8 C9 H9 120.0 . . ?
C10 C9 C8 120.0 . . ?
C10 C9 H9 120.0 . . ?
C5 C10 P2AA 117.9(5) . . ?
C9 C10 P2AA 121.9(5) . . ?
C9 C10 C5 120.0 . . ?
C31 C11 H11 119.7 . . ?
C31 C11 C90 120.6(14) . . ?
C90 C11 H11 119.7 . . ?
C2 C12 H12 119.4 . . ?
C196 C12 C2 121.3(13) . . ?
C196 C12 H12 119.4 . . ?
C1 C13 H13 120.5 . . ?
C115 C13 C1 118.9(14) . . ?
C115 C13 H13 120.5 . . ?
C65 C14 P4 120.9(11) . . ?
C65 C14 C216 119.0(13) . . ?
C216 C14 P4 119.6(11) . . ?
C33 C15 H15 120.4 . . ?
C126 C15 H15 120.4 . . ?
C126 C15 C33 119.2(16) . . ?
C110 C16 H16 119.0 . . ?
C120 C16 H16 119.0 . . ?
C120 C16 C110 122.0(18) . . ?
C36 C17 H17 120.3 . . ?
C36 C17 C202 119.4(13) . . ?
C202 C17 H17 120.3 . . ?
C162 C18 P16 122.1(14) . . ?
C162 C18 C171 121.6(18) . . ?
C171 C18 P16 116.2(13) . . ?
C67 C19 H19 121.2 . . ?
C67 C19 C199 117.5(15) . . ?
C199 C19 H19 121.2 . . ?
C40 C20 H20 118.3 . . ?
C129 C20 H20 118.3 . . ?
C129 C20 C40 123.5(16) . . ?
C4 C21 H21 118.1 . . ?
C64 C21 C4 123.8(14) . . ?
C64 C21 H21 118.1 . . ?
C56 C22 H22 119.3 . . ?
C71 C22 H22 119.3 . . ?
C71 C22 C56 121.4(14) . . ?
C97 C23 P0AA 118.0(11) . . ?
C124 C23 P0AA 123.5(14) . . ?
C124 C23 C97 118.4(16) . . ?
C45 C24 H24 119.9 . . ?
C66 C24 H24 119.9 . . ?
C66 C24 C45 120.1(14) . . ?
C170 C25 H25 120.8 . . ?
C170 C25 C173 118.4(16) . . ?
C173 C25 H25 120.8 . . ?
C42 C26 H26 119.6 . . ?
C42 C26 C205 120.8(15) . . ?
C205 C26 H26 119.6 . . ?
C46 C27 P1AA 120.2(12) . . ?
C46 C27 C87 117.6(15) . . ?
C87 C27 P1AA 122.0(13) . . ?
C70 C28 H28 120.0 . . ?
C70 C28 C124 120.0(15) . . ?
C124 C28 H28 120.0 . . ?
C134 C29 P1AA 116.2(12) . . ?
C210 C29 P1AA 124.1(13) . . ?
C210 C29 C134 119.7(16) . . ?
C67 C30 H30 119.1 . . ?
C219 C30 H30 119.1 . . ?
C219 C30 C67 121.7(14) . . ?
C11 C31 H31 119.6 . . ?
C11 C31 C36 120.9(13) . . ?
C36 C31 H31 119.6 . . ?
C37 C32 H32 119.7 . . ?
C37 C32 C118 120.6(16) . . ?
C118 C32 H32 119.7 . . ?
C15 C33 P1AA 121.1(13) . . ?
C35 C33 P1AA 119.4(12) . . ?
C35 C33 C15 119.3(15) . . ?
C60 C34 P18 118.5(11) . . ?
C72 C34 P18 122.5(12) . . ?
C72 C34 C60 118.7(14) . . ?
C33 C35 H35 118.8 . . ?
C41 C35 C33 122.4(16) . . ?
C41 C35 H35 118.8 . . ?
C17 C36 P2AA 123.9(11) . . ?
C17 C36 C31 118.0(13) . . ?
C31 C36 P2AA 117.7(9) . . ?
C32 C37 P0AA 116.7(12) . . ?
C32 C37 C105 119.9(16) . . ?
C105 C37 P0AA 123.4(13) . . ?
C197 C38 H38 120.2 . . ?
C203 C38 H38 120.2 . . ?
C203 C38 C197 119.6(15) . . ?
S19 C39 H39A 108.9 . . ?
S19 C39 H39B 108.9 . . ?
H39A C39 H39B 107.7 . . ?
C76 C39 S19 113.3(10) . . ?
C76 C39 H39A 108.9 . . ?
C76 C39 H39B 108.9 . . ?
C20 C40 P20 119.1(13) . . ?
C62 C40 P20 121.5(14) . . ?
C62 C40 C20 119.4(17) . . ?
C35 C41 H41 120.4 . . ?
C35 C41 C131 119.2(17) . . ?
C131 C41 H41 120.4 . . ?
C26 C42 P17 116.3(11) . . ?
C26 C42 C132 120.6(14) . . ?
C132 C42 P17 123.1(12) . . ?
C66 C43 H43 118.3 . . ?
C143 C43 H43 118.3 . . ?
C143 C43 C66 123.3(15) . . ?
C60 C44 H44 119.7 . . ?
C207 C44 H44 119.7 . . ?
C207 C44 C60 120.7(15) . . ?
C24 C45 P4 116.8(11) . . ?
C88 C45 P4 123.6(11) . . ?
C88 C45 C24 119.5(13) . . ?
C27 C46 H46 119.1 . . ?
C198 C46 C27 121.9(16) . . ?
C198 C46 H46 119.1 . . ?
C48 C47 C52 120.0 . . ?
C48 C47 C180 116.5(10) . . ?
C52 C47 C180 123.5(10) . . ?
C47 C48 H48 120.0 . . ?
C49 C48 C47 120.0 . . ?
C49 C48 H48 120.0 . . ?
C48 C49 H49 120.0 . . ?
C48 C49 C50 120.0 . . ?
C50 C49 H49 120.0 . . ?
C49 C50 H50 120.0 . . ?
C51 C50 C49 120.0 . . ?
C51 C50 H50 120.0 . . ?
C50 C51 H51 120.0 . . ?
C50 C51 C52 120.0 . . ?
C52 C51 H51 120.0 . . ?
C47 C52 H52 120.0 . . ?
C51 C52 C47 120.0 . . ?
C51 C52 H52 120.0 . . ?
C113 C53 H53 119.8 . . ?
C113 C53 C195 120.4(17) . . ?
C195 C53 H53 119.8 . . ?
C70 C54 H54 120.5 . . ?
C70 C54 C97 119.0(17) . . ?
C97 C54 H54 120.5 . . ?
C91 C55 H55 120.8 . . ?
C91 C55 C96 118.3(15) . . ?
C96 C55 H55 120.8 . . ?
C22 C56 H56 120.3 . . ?
C63 C56 C22 119.4(16) . . ?
C63 C56 H56 120.3 . . ?
C87 C57 H57 118.2 . . ?
C117 C57 H57 118.2 . . ?
C117 C57 C87 123.6(17) . . ?
C104 C58 H58 121.4 . . ?
C209 C58 H58 121.4 . . ?
C209 C58 C104 117.3(15) . . ?
C68 C59 H59 120.1 . . ?
C121 C59 H59 120.1 . . ?
C121 C59 C68 119.9(16) . . ?
C34 C60 H60 120.3 . . ?
C44 C60 C34 119.4(14) . . ?
C44 C60 H60 120.3 . . ?
C210 C61 H61 119.9 . . ?
C210 C61 C212 120.1(16) . . ?
C212 C61 H61 119.9 . . ?
C40 C62 H62 119.1 . . ?
C116 C62 C40 121.8(18) . . ?
C116 C62 H62 119.1 . . ?
C56 C63 H63 117.5 . . ?
C109 C63 C56 125.0(17) . . ?
C109 C63 H63 117.5 . . ?
C21 C64 H64 121.8 . . ?
C21 C64 C115 116.5(13) . . ?
C115 C64 H64 121.8 . . ?
C14 C65 H65 120.7 . . ?
C14 C65 C130 118.7(14) . . ?
C130 C65 H65 120.7 . . ?
C24 C66 C43 118.0(15) . . ?
C24 C66 H66 121.0 . . ?
C43 C66 H66 121.0 . . ?
C19 C67 P17 122.9(12) . . ?
C30 C67 P17 117.7(11) . . ?
C30 C67 C19 119.3(14) . . ?
C59 C68 H68 121.2 . . ?
C133 C68 C59 117.6(17) . . ?
C133 C68 H68 121.2 . . ?
C85 C69 H69 122.3 . . ?
C85 C69 C165 115.4(17) . . ?
C165 C69 H69 122.3 . . ?
C28 C70 C54 121.0(17) . . ?
C28 C70 H70 119.5 . . ?
C54 C70 H70 119.5 . . ?
C22 C71 P17 120.8(11) . . ?
C22 C71 C93 117.7(15) . . ?
C93 C71 P17 121.5(12) . . ?
C34 C72 H72 119.9 . . ?
C75 C72 C34 120.2(15) . . ?
C75 C72 H72 119.9 . . ?
C134 C73 H73 119.0 . . ?
C134 C73 C212 122.0(17) . . ?
C212 C73 H73 119.0 . . ?
C96 C74 H74 120.2 . . ?
C96 C74 C107 119.7(14) . . ?
C107 C74 H74 120.2 . . ?
C72 C75 H75 119.7 . . ?
C72 C75 C207 120.5(15) . . ?
C207 C75 H75 119.7 . . ?
C39 C76 H76A 109.6 . . ?
C39 C76 H76B 109.6 . . ?
H76A C76 H76B 108.1 . . ?
C107 C76 C39 110.4(12) . . ?
C107 C76 H76A 109.6 . . ?
C107 C76 H76B 109.6 . . ?
C91 C77 H77 119.9 . . ?
C107 C77 H77 119.9 . . ?
C107 C77 C91 120.2(14) . . ?
C79 C78 H78 120.0 . . ?
C79 C78 C83 120.0 . . ?
C83 C78 H78 120.0 . . ?
C78 C79 C215 118.9(10) . . ?
C80 C79 C78 120.0 . . ?
C80 C79 C215 120.9(10) . . ?
C79 C80 H80 120.0 . . ?
C81 C80 C79 120.0 . . ?
C81 C80 H80 120.0 . . ?
C80 C81 H81 120.0 . . ?
C80 C81 C82 120.0 . . ?
C82 C81 H81 120.0 . . ?
C81 C82 H82 120.0 . . ?
C83 C82 C81 120.0 . . ?
C83 C82 H82 120.0 . . ?
C78 C83 H83 120.0 . . ?
C82 C83 C78 120.0 . . ?
C82 C83 H83 120.0 . . ?
C177 C84 H84 121.2 . . ?
C178 C84 H84 121.2 . . ?
C178 C84 C177 117.5(18) . . ?
C69 C85 P16 120.5(14) . . ?
C110 C85 P16 118.7(12) . . ?
C110 C85 C69 120.8(16) . . ?
C111 C86 H86 120.9 . . ?
C111 C86 C130 118.2(15) . . ?
C130 C86 H86 120.9 . . ?
C27 C87 H87 121.0 . . ?
C57 C87 C27 118.0(17) . . ?
C57 C87 H87 121.0 . . ?
C45 C88 H88 120.2 . . ?
C45 C88 C143 119.7(13) . . ?
C143 C88 H88 120.2 . . ?
C169 C89 H89 119.2 . . ?
C169 C89 C181 121.5(19) . . ?
C181 C89 H89 119.2 . . ?
C11 C90 H90 120.3 . . ?
C202 C90 C11 119.4(14) . . ?
C202 C90 H90 120.3 . . ?
C55 C91 C77 121.0(15) . . ?
C55 C91 H91 119.5 . . ?
C77 C91 H91 119.5 . . ?
H92A C92 H92B 107.5 . . ?
C98 C92 H92A 108.4 . . ?
C98 C92 H92B 108.4 . . ?
C98 C92 C137 115.5(15) . . ?
C137 C92 H92A 108.4 . . ?
C137 C92 H92B 108.4 . . ?
C71 C93 H93 121.3 . . ?
C71 C93 C109 117.3(15) . . ?
C109 C93 H93 121.3 . . ?
C118 C94 H94 119.3 . . ?
C200 C94 H94 119.3 . . ?
C200 C94 C118 121.5(18) . . ?
C106 C95 H95 120.5 . . ?
C106 C95 C108 119.0(17) . . ?
C108 C95 H95 120.5 . . ?
C55 C96 C74 122.4(15) . . ?
C55 C96 H96 118.8 . . ?
C74 C96 H96 118.8 . . ?
C23 C97 H97 119.8 . . ?
C54 C97 C23 120.5(14) . . ?
C54 C97 H97 119.8 . . ?
C99 C98 C92 119.3(11) . . ?
C99 C98 C103 120.0 . . ?
C103 C98 C92 120.5(11) . . ?
C98 C99 H99 120.0 . . ?
C100 C99 C98 120.0 . . ?
C100 C99 H99 120.0 . . ?
C99 C100 H100 120.0 . . ?
C99 C100 C101 120.0 . . ?
C101 C100 H100 120.0 . . ?
C100 C101 H101 120.0 . . ?
C102 C101 C100 120.0 . . ?
C102 C101 H101 120.0 . . ?
C101 C102 H102 120.0 . . ?
C103 C102 C101 120.0 . . ?
C103 C102 H102 120.0 . . ?
C98 C103 H103 120.0 . . ?
C102 C103 C98 120.0 . . ?
C102 C103 H103 120.0 . . ?
C58 C104 P18 122.2(13) . . ?
C201 C104 P18 118.2(13) . . ?
C201 C104 C58 119.5(16) . . ?
C37 C105 H105 121.0 . . ?
C37 C105 C200 118.0(16) . . ?
C200 C105 H105 121.0 . . ?
C95 C106 H106 118.3 . . ?
C113 C106 C95 123.4(18) . . ?
C113 C106 H106 118.3 . . ?
C74 C107 C76 120.9(13) . . ?
C77 C107 C74 118.3(13) . . ?
C77 C107 C76 120.7(13) . . ?
C95 C108 H108 121.4 . . ?
C195 C108 C95 117.3(17) . . ?
C195 C108 H108 121.4 . . ?
C63 C109 C93 118.9(15) . . ?
C63 C109 H109 120.5 . . ?
C93 C109 H109 120.5 . . ?
C16 C110 H110 120.1 . . ?
C85 C110 C16 119.8(15) . . ?
C85 C110 H110 120.1 . . ?
C86 C111 H111 118.9 . . ?
C216 C111 C86 122.2(16) . . ?
C216 C111 H111 118.9 . . ?
C121 C112 H112 118.9 . . ?
C121 C112 C217 122.2(19) . . ?
C217 C112 H112 118.9 . . ?
C53 C113 H113 120.2 . . ?
C106 C113 C53 119.6(18) . . ?
C106 C113 H113 120.2 . . ?
C122 C114 P13 120.1(13) . . ?
C149 C114 P13 117.2(11) . . ?
C149 C114 C122 122.6(16) . . ?
C13 C115 H115 118.9 . . ?
C64 C115 C13 122.2(13) . . ?
C64 C115 H115 118.9 . . ?
C62 C116 H116 121.2 . . ?
C62 C116 C153 117.5(17) . . ?
C153 C116 H116 121.2 . . ?
C57 C117 H117 120.6 . . ?
C57 C117 C198 118.7(16) . . ?
C198 C117 H117 120.6 . . ?
C32 C118 H118 121.3 . . ?
C94 C118 C32 117.3(16) . . ?
C94 C118 H118 121.3 . . ?
C135 C119 H119 119.5 . . ?
C135 C119 C205 121.0(15) . . ?
C205 C119 H119 119.5 . . ?
C16 C120 H120 121.4 . . ?
C16 C120 C165 117.2(18) . . ?
C165 C120 H120 121.4 . . ?
C59 C121 H121 120.1 . . ?
C112 C121 C59 119.8(18) . . ?
C112 C121 H121 120.1 . . ?
C114 C122 H122 121.6 . . ?
C114 C122 C173 116.8(17) . . ?
C173 C122 H122 121.6 . . ?
C197 C123 H123 120.4 . . ?
C197 C123 C206 119.1(15) . . ?
C206 C123 H123 120.4 . . ?
C23 C124 C28 121.0(17) . . ?
C23 C124 H124 119.5 . . ?
C28 C124 H124 119.5 . . ?
C154 C125 P20 120.5(14) . . ?
C168 C125 P20 117.8(14) . . ?
C168 C125 C154 121.7(17) . . ?
C15 C126 H126 120.6 . . ?
C15 C126 C131 118.9(15) . . ?
C131 C126 H126 120.6 . . ?
C142 C127 H127 122.8 . . ?
C142 C127 C146 114.4(18) . . ?
C146 C127 H127 122.8 . . ?
C136 C128 H128 119.0 . . ?
C136 C128 C188 122.0(19) . . ?
C188 C128 H128 119.0 . . ?
C20 C129 H129 121.6 . . ?
C153 C129 C20 116.7(17) . . ?
C153 C129 H129 121.6 . . ?
C65 C130 H130 119.3 . . ?
C86 C130 C65 121.5(16) . . ?
C86 C130 H130 119.3 . . ?
C41 C131 C126 120.3(16) . . ?
C41 C131 H131 119.9 . . ?
C126 C131 H131 119.9 . . ?
C42 C132 H132 121.8 . . ?
C135 C132 C42 116.5(15) . . ?
C135 C132 H132 121.8 . . ?
C68 C133 P13 119.8(14) . . ?
C217 C133 P13 118.8(12) . . ?
C217 C133 C68 121.2(16) . . ?
C29 C134 H134 120.2 . . ?
C73 C134 C29 119.7(16) . . ?
C73 C134 H134 120.2 . . ?
C119 C135 C132 124.8(16) . . ?
C119 C135 H135 117.6 . . ?
C132 C135 H135 117.6 . . ?
C128 C136 P15 119.9(14) . . ?
C186 C136 P15 120.3(16) . . ?
C186 C136 C128 119.7(19) . . ?
S18 C137 H13A 109.3 . . ?
S18 C137 H13B 109.3 . . ?
C92 C137 S18 111.5(12) . . ?
C92 C137 H13A 109.3 . . ?
C92 C137 H13B 109.3 . . ?
H13A C137 H13B 108.0 . . ?
C3 C138 H138 118.2 . . ?
C181 C138 C3 123.6(18) . . ?
C181 C138 H138 118.2 . . ?
C172 C139 P15 121.3(15) . . ?
C172 C139 C185 122(2) . . ?
C185 C139 P15 116.4(16) . . ?
S10 C140 H14A 109.6 . . ?
S10 C140 H14B 109.6 . . ?
H14A C140 H14B 108.1 . . ?
C180 C140 S10 110.4(11) . . ?
C180 C140 H14A 109.6 . . ?
C180 C140 H14B 109.6 . . ?
C155 C141 H141 121.1 . . ?
C167 C141 H141 121.1 . . ?
C167 C141 C155 117.7(17) . . ?
C127 C142 H142 119.2 . . ?
C152 C142 C127 121.7(17) . . ?
C152 C142 H142 119.2 . . ?
C43 C143 C88 119.2(14) . . ?
C43 C143 H143 120.4 . . ?
C88 C143 H143 120.4 . . ?
C3 C144 H144 119.1 . . ?
C169 C144 C3 121.7(17) . . ?
C169 C144 H144 119.1 . . ?
C152 C145 H145 117.4 . . ?
C152 C145 C190 125.2(19) . . ?
C190 C145 H145 117.4 . . ?
C127 C146 H146 116.6 . . ?
C190 C146 C127 127(2) . . ?
C190 C146 H146 116.6 . . ?
C163 C147 H147 118.5 . . ?
C163 C147 C168 122.9(19) . . ?
C168 C147 H147 118.5 . . ?
S14 C148 H14C 107.6 . . ?
S14 C148 H14D 107.6 . . ?
H14C C148 H14D 107.1 . . ?
C184 C148 S14 118.7(16) . . ?
C184 C148 H14C 107.6 . . ?
C184 C148 H14D 107.6 . . ?
C114 C149 H149 119.2 . . ?
C114 C149 C170 121.5(15) . . ?
C170 C149 H149 119.2 . . ?
C167 C150 H150 119.6 . . ?
C175 C150 H150 119.6 . . ?
C175 C150 C167 120.9(17) . . ?
C155 C151 H151 120.2 . . ?
C155 C151 C175 119.6(18) . . ?
C175 C151 H151 120.2 . . ?
C142 C152 P18 119.4(13) . . ?
C142 C152 C145 116.4(16) . . ?
C145 C152 P18 124.2(14) . . ?
C116 C153 H153 119.5 . . ?
C129 C153 C116 121.0(17) . . ?
C129 C153 H153 119.5 . . ?
C125 C154 H154 121.6 . . ?
C182 C154 C125 116.9(18) . . ?
C182 C154 H154 121.6 . . ?
C141 C155 H155 118.5 . . ?
C151 C155 C141 122.9(18) . . ?
C151 C155 H155 118.5 . . ?
C157 C156 C161 120.0 . . ?
C157 C156 C184 114.7(14) . . ?
C161 C156 C184 125.2(14) . . ?
C156 C157 H157 120.0 . . ?
C156 C157 C158 120.0 . . ?
C158 C157 H157 120.0 . . ?
C157 C158 H158 120.0 . . ?
C159 C158 C157 120.0 . . ?
C159 C158 H158 120.0 . . ?
C158 C159 H159 120.0 . . ?
C158 C159 C160 120.0 . . ?
C160 C159 H159 120.0 . . ?
C159 C160 H160 120.0 . . ?
C161 C160 C159 120.0 . . ?
C161 C160 H160 120.0 . . ?
C156 C161 H161 120.0 . . ?
C160 C161 C156 120.0 . . ?
C160 C161 H161 120.0 . . ?
C18 C162 H162 119.3 . . ?
C18 C162 C187 121.5(18) . . ?
C187 C162 H162 119.3 . . ?
C147 C163 H163 120.6 . . ?
C182 C163 C147 118.9(18) . . ?
C182 C163 H163 120.6 . . ?
C178 C164 H164 120.3 . . ?
C178 C164 C183 119.3(18) . . ?
C183 C164 H164 120.3 . . ?
C69 C165 H165 117.7 . . ?
C120 C165 C69 124.7(17) . . ?
C120 C165 H165 117.7 . . ?
C171 C166 H166 121.1 . . ?
C171 C166 C176 117.7(19) . . ?
C176 C166 H166 121.1 . . ?
C141 C167 P20 121.1(14) . . ?
C141 C167 C150 119.8(17) . . ?
C150 C167 P20 118.9(13) . . ?
C125 C168 C147 115.4(18) . . ?
C125 C168 H168 122.3 . . ?
C147 C168 H168 122.3 . . ?
C89 C169 H169 120.1 . . ?
C144 C169 C89 119.7(17) . . ?
C144 C169 H169 120.1 . . ?
C25 C170 C149 120.1(17) . . ?
C25 C170 H170 119.9 . . ?
C149 C170 H170 119.9 . . ?
C18 C171 C166 121.7(17) . . ?
C18 C171 H171 119.1 . . ?
C166 C171 H171 119.1 . . ?
C139 C172 H172 119.2 . . ?
C139 C172 C204 122(2) . . ?
C204 C172 H172 119.2 . . ?
C25 C173 H173 120.1 . . ?
C122 C173 C25 119.8(16) . . ?
C122 C173 H173 120.1 . . ?
C179 C174 H174 118.9 . . ?
C188 C174 H174 118.9 . . ?
C188 C174 C179 122(2) . . ?
C150 C175 C151 118.9(18) . . ?
C150 C175 H175 120.6 . . ?
C151 C175 H175 120.6 . . ?
C166 C176 H176 119.5 . . ?
C166 C176 C187 120.9(18) . . ?
C187 C176 H176 119.5 . . ?
C84 C177 H177 117.4 . . ?
C189 C177 C84 125(2) . . ?
C189 C177 H177 117.4 . . ?
C84 C178 P16 120.7(14) . . ?
C164 C178 P16 121.3(15) . . ?
C164 C178 C84 117.7(17) . . ?
C174 C179 H179 119.7 . . ?
C174 C179 C186 120.6(19) . . ?
C186 C179 H179 119.7 . . ?
C47 C180 C140 111.3(14) . . ?
C47 C180 H18A 109.4 . . ?
C47 C180 H18B 109.4 . . ?
C140 C180 H18A 109.4 . . ?
C140 C180 H18B 109.4 . . ?
H18A C180 H18B 108.0 . . ?
C89 C181 H181 121.3 . . ?
C138 C181 C89 117.4(19) . . ?
C138 C181 H181 121.3 . . ?
C154 C182 H182 118.1 . . ?
C163 C182 C154 124(2) . . ?
C163 C182 H182 118.1 . . ?
C164 C183 H183 120.5 . . ?
C189 C183 C164 119.0(19) . . ?
C189 C183 H183 120.5 . . ?
C148 C184 C156 119(2) . . ?
C148 C184 H18C 107.6 . . ?
C148 C184 H18D 107.6 . . ?
C156 C184 H18C 107.6 . . ?
C156 C184 H18D 107.6 . . ?
H18C C184 H18D 107.0 . . ?
C139 C185 H185 123.1 . . ?
C139 C185 C191 114(2) . . ?
C191 C185 H185 123.1 . . ?
C136 C186 C179 117(2) . . ?
C136 C186 H186 121.7 . . ?
C179 C186 H186 121.7 . . ?
C162 C187 C176 116.2(17) . . ?
C162 C187 H187 121.9 . . ?
C176 C187 H187 121.9 . . ?
C128 C188 H188 121.1 . . ?
C174 C188 C128 118(2) . . ?
C174 C188 H188 121.1 . . ?
C177 C189 C183 121(2) . . ?
C177 C189 H189 119.5 . . ?
C183 C189 H189 119.5 . . ?
C145 C190 H190 122.4 . . ?
C146 C190 C145 115(2) . . ?
C146 C190 H190 122.4 . . ?
C185 C191 H191 119.6 . . ?
C208 C191 C185 121(2) . . ?
C208 C191 H191 119.6 . . ?
C193 C192 H192 119.9 . . ?
C193 C192 C196 120.3(14) . . ?
C196 C192 H192 119.9 . . ?
C192 C193 H193 120.3 . . ?
C194 C193 C192 119.5(15) . . ?
C194 C193 H193 120.3 . . ?
C2 C194 H194 118.9 . . ?
C193 C194 C2 122.3(13) . . ?
C193 C194 H194 118.9 . . ?
C53 C195 P13 119.5(13) . . ?
C108 C195 P13 120.4(13) . . ?
C108 C195 C53 120.0(16) . . ?
C12 C196 C192 119.5(13) . . ?
C12 C196 H196 120.3 . . ?
C192 C196 H196 120.3 . . ?
C38 C197 P0AA 120.6(12) . . ?
C123 C197 P0AA 120.8(12) . . ?
C123 C197 C38 118.5(14) . . ?
C46 C198 H198 119.9 . . ?
C117 C198 C46 120.1(17) . . ?
C117 C198 H198 119.9 . . ?
C19 C199 H199 118.7 . . ?
C214 C199 C19 122.5(15) . . ?
C214 C199 H199 118.7 . . ?
C94 C200 C105 121.7(17) . . ?
C94 C200 H200 119.2 . . ?
C105 C200 H200 119.2 . . ?
C104 C201 H201 119.0 . . ?
C104 C201 C218 122.0(16) . . ?
C218 C201 H201 119.0 . . ?
C17 C202 H202 119.1 . . ?
C90 C202 C17 121.7(13) . . ?
C90 C202 H202 119.1 . . ?
C38 C203 H203 119.7 . . ?
C211 C203 C38 120.7(15) . . ?
C211 C203 H203 119.7 . . ?
C172 C204 H204 119.0 . . ?
C172 C204 C208 122(2) . . ?
C208 C204 H204 119.0 . . ?
C26 C205 H205 122.0 . . ?
C119 C205 C26 116.1(15) . . ?
C119 C205 H205 122.0 . . ?
C123 C206 H206 118.6 . . ?
C211 C206 C123 122.8(16) . . ?
C211 C206 H206 118.6 . . ?
C44 C207 C75 120.2(14) . . ?
C44 C207 H207 119.9 . . ?
C75 C207 H207 119.9 . . ?
C191 C208 C204 119(2) . . ?
C191 C208 H208 120.4 . . ?
C204 C208 H208 120.4 . . ?
C58 C209 H209 118.1 . . ?
C220 C209 C58 123.8(16) . . ?
C220 C209 H209 118.1 . . ?
C29 C210 H210 119.7 . . ?
C61 C210 C29 120.6(16) . . ?
C61 C210 H210 119.7 . . ?
C203 C211 H211 120.4 . . ?
C206 C211 C203 119.2(15) . . ?
C206 C211 H211 120.4 . . ?
C61 C212 H212 121.1 . . ?
C73 C212 C61 117.9(17) . . ?
C73 C212 H212 121.1 . . ?
S8 C213 H21A 108.7 . . ?
S8 C213 H21B 108.7 . . ?
H21A C213 H21B 107.6 . . ?
C215 C213 S8 114.1(12) . . ?
C215 C213 H21A 108.7 . . ?
C215 C213 H21B 108.7 . . ?
C199 C214 H214 121.2 . . ?
C199 C214 C219 117.5(15) . . ?
C219 C214 H214 121.2 . . ?
C79 C215 H21C 108.8 . . ?
C79 C215 H21D 108.8 . . ?
C213 C215 C79 113.8(12) . . ?
C213 C215 H21C 108.8 . . ?
C213 C215 H21D 108.8 . . ?
H21C C215 H21D 107.7 . . ?
C14 C216 H216 119.9 . . ?
C111 C216 C14 120.3(15) . . ?
C111 C216 H216 119.9 . . ?
C112 C217 H217 120.6 . . ?
C133 C217 C112 118.7(16) . . ?
C133 C217 H217 120.6 . . ?
C201 C218 H218 120.5 . . ?
C201 C218 C220 119.1(16) . . ?
C220 C218 H218 120.5 . . ?
C30 C219 C214 121.4(15) . . ?
C30 C219 H219 119.3 . . ?
C214 C219 H219 119.3 . . ?
C209 C220 C218 118.3(17) . . ?
C209 C220 H220 120.8 . . ?
C218 C220 H220 120.8 . . ?
Au11 Ag1D Au 58.76(2) . . y
Au11 Ag1D Au1 60.35(2) . . y
Au11 Ag1D Au0A 56.091(18) . . y
Au11 Ag1D Au1C 57.739(19) . . y
Au11 Ag1D Ag1E 59.19(2) . . y
Au11 Ag1D Ag1J 118.55(3) . . y
Au Ag1D Au1 59.61(2) . . y
Au Ag1D Au0A 108.66(3) . . y
Au Ag1D Ag1J 89.96(3) . . y
Au1 Ag1D Au0A 106.26(3) . . y
Au1 Ag1D Ag1J 58.21(2) . . y
Au0A Ag1D Ag1J 145.72(3) . . y
S8 Ag1D Au11 169.63(9) . . y
S8 Ag1D Au 114.20(8) . . y
S8 Ag1D Au1 109.91(8) . . y
S8 Ag1D Au0A 133.66(8) . . y
S8 Ag1D Au1C 127.76(7) . . y
S8 Ag1D Ag1E 120.50(7) . . y
S8 Ag1D Ag1J 51.86(8) . . y
Au1C Ag1D Au 62.79(2) . . y
Au1C Ag1D Au1 110.17(3) . . y
Au1C Ag1D Au0A 60.288(19) . . y
Au1C Ag1D Ag1E 108.17(3) . . y
Au1C Ag1D Ag1J 150.75(3) . . y
Ag1E Ag1D Au 107.64(3) . . y
Ag1E Ag1D Au1 59.71(2) . . y
Ag1E Ag1D Au0A 58.09(2) . . y
Ag1E Ag1D Ag1J 89.30(3) . . y
Au11 Ag1E Au1 60.52(2) . . y
Au11 Ag1E Ag14 59.44(2) . . y
Au11 Ag1E Ag19 119.30(3) . . y
Au11 Ag1E Au0A 57.619(19) . . y
Au11 Ag1E Au1A 56.343(18) . . y
Au11 Ag1E Ag1D 59.04(2) . . y
Au1 Ag1E Ag14 59.94(2) . . y
Au1 Ag1E Ag19 58.78(2) . . y
Au1 Ag1E Au1A 106.51(3) . . y
Au1 Ag1E Ag1D 60.34(2) . . y
Ag14 Ag1E Ag19 89.69(3) . . y
Ag14 Ag1E Au1A 58.02(2) . . y
Au0A Ag1E Au1 110.49(3) . . y
Au0A Ag1E Ag14 107.95(3) . . y
Au0A Ag1E Ag19 151.47(3) . . y
Au0A Ag1E Au1A 59.99(2) . . y
Au0A Ag1E Ag1D 62.79(2) . . y
Au1A Ag1E Ag19 145.80(3) . . y
S14 Ag1E Au11 170.22(8) . . y
S14 Ag1E Au1 110.52(8) . . y
S14 Ag1E Ag14 120.92(8) . . y
S14 Ag1E Ag19 51.93(8) . . y
S14 Ag1E Au0A 127.14(8) . . y
S14 Ag1E Au1A 133.05(8) . . y
S14 Ag1E Ag1D 114.01(8) . . y
Ag1D Ag1E Ag14 108.48(3) . . y
Ag1D Ag1E Ag19 90.74(3) . . y
Ag1D Ag1E Au1A 108.93(3) . . y
Au4 Au1H Au16 145.95(3) . . y
Au5 Au1H Au4 60.620(19) . . y
Au5 Au1H Au 107.73(3) . . y
Au5 Au1H Au1 109.66(3) . . y
Au5 Au1H Ag14 62.40(2) . . y
Au5 Au1H Au16 150.17(3) . . y
Au11 Au1H Au4 56.386(18) . . y
Au11 Au1H Au5 57.404(19) . . y
Au11 Au1H Au 58.65(2) . . y
Au11 Au1H Au1 60.46(2) . . y
Au11 Au1H Ag14 59.38(2) . . y
Au11 Au1H Au16 118.62(3) . . y
Au Au1H Au4 58.12(2) . . y
Au Au1H Au16 89.69(3) . . y
Au1 Au1H Au4 106.73(3) . . y
Au1 Au1H Au 59.65(2) . . y
Au1 Au1H Ag14 59.78(2) . . y
Au1 Au1H Au16 58.15(2) . . y
Ag14 Au1H Au4 109.41(3) . . y
Ag14 Au1H Au 107.71(3) . . y
Ag14 Au1H Au16 89.60(3) . . y
S18 Au1H Au4 133.80(7) . . y
S18 Au1H Au5 127.77(8) . . y
S18 Au1H Au11 169.32(8) . . y
S18 Au1H Au 121.38(8) . . y
S18 Au1H Au1 109.64(8) . . y
S18 Au1H Ag14 113.10(7) . . y
S18 Au1H Au16 51.68(8) . . y
Au2 Ag1J Au8 57.83(2) . . y
Au2 Ag1J Au12 56.415(19) . . y
Au2 Ag1J Au1 60.60(2) . . y
Au2 Ag1J Ag19 59.05(2) . . y
Au2 Ag1J Ag1D 119.52(3) . . y
Au2 Ag1J Ag1L 58.70(2) . . y
Au8 Ag1J Au12 60.29(2) . . y
Au8 Ag1J Au1 110.09(3) . . y
Au8 Ag1J Ag19 108.27(3) . . y
Au8 Ag1J Ag1D 149.94(3) . . y
Au8 Ag1J Ag1L 61.78(2) . . y
Au12 Ag1J Ag1D 147.21(3) . . y
Au1 Ag1J Au12 107.23(3) . . y
Au1 Ag1J Ag19 60.21(2) . . y
Au1 Ag1J Ag1D 58.92(2) . . y
Au1 Ag1J Ag1L 60.05(2) . . y
Ag19 Ag1J Au12 58.52(2) . . y
Ag19 Ag1J Ag1D 90.62(3) . . y
Ag19 Ag1J Ag1L 107.96(3) . . y
S8 Ag1J Au2 170.37(8) . . y
S8 Ag1J Au8 126.55(8) . . y
S8 Ag1J Au12 132.92(8) . . y
S8 Ag1J Au1 110.61(8) . . y
S8 Ag1J Ag19 121.49(8) . . y
S8 Ag1J Ag1D 51.86(8) . . y
S8 Ag1J Ag1L 114.34(7) . . y
Ag1L Ag1J Au12 108.31(3) . . y
Ag1L Ag1J Ag1D 90.60(3) . . y
Au2 Ag1L Au6 57.486(19) . . y
Au2 Ag1L Au8 56.694(18) . . y
Au2 Ag1L Au 118.37(3) . . y
Au2 Ag1L Au1 60.43(2) . . y
Au2 Ag1L Au16 59.13(2) . . y
Au2 Ag1L Ag1J 58.83(2) . . y
Au6 Ag1L Au8 60.52(2) . . y
Au6 Ag1L Au 150.73(3) . . y
Au6 Ag1L Au1 109.94(3) . . y
Au6 Ag1L Au16 62.61(2) . . y
Au6 Ag1L Ag1J 107.83(3) . . y
Au8 Ag1L Au 145.49(3) . . y
Au1 Ag1L Au8 106.84(3) . . y
Au1 Ag1L Au 57.94(2) . . y
Au1 Ag1L Ag1J 59.46(2) . . y
Au16 Ag1L Au8 109.47(3) . . y
Au16 Ag1L Au 89.88(3) . . y
Au16 Ag1L Au1 59.85(2) . . y
Au16 Ag1L Ag1J 107.61(3) . . y
S19 Ag1L Au2 168.78(7) . . y
S19 Ag1L Au6 128.16(8) . . y
S19 Ag1L Au8 133.94(7) . . y
S19 Ag1L Au 51.39(7) . . y
S19 Ag1L Au1 109.11(7) . . y
S19 Ag1L Au16 113.08(7) . . y
S19 Ag1L Ag1J 120.97(8) . . y
Ag1J Ag1L Au8 58.33(2) . . y
Ag1J Ag1L Au 89.09(3) . . y
Au2 Au1N Au9 57.325(19) . . y
Au2 Au1N Au10 56.538(19) . . y
Au2 Au1N Au1 60.34(2) . . y
Au2 Au1N Ag14 118.80(3) . . y
Au2 Au1N Au16 59.06(2) . . y
Au2 Au1N Ag19 58.91(2) . . y
Au9 Au1N Au10 60.39(2) . . y
Au9 Au1N Au1 109.13(3) . . y
Au9 Au1N Ag14 148.66(3) . . y
Au9 Au1N Au16 108.24(3) . . y
Au9 Au1N Ag19 61.15(2) . . y
Au10 Au1N Ag14 147.82(3) . . y
Au1 Au1N Au10 107.29(3) . . y
Au1 Au1N Ag14 58.46(2) . . y
Au1 Au1N Ag19 60.00(2) . . y
Au16 Au1N Au10 59.01(2) . . y
Au16 Au1N Au1 59.95(2) . . y
Au16 Au1N Ag14 90.51(3) . . y
Au16 Au1N Ag19 108.03(3) . . y
Ag19 Au1N Au10 108.46(3) . . y
Ag19 Au1N Ag14 89.59(3) . . y
S10 Au1N Au2 168.63(8) . . y
S10 Au1N Au9 125.70(7) . . y
S10 Au1N Au10 134.82(8) . . y
S10 Au1N Au1 110.20(8) . . y
S10 Au1N Ag14 52.08(7) . . y
S10 Au1N Au16 123.42(7) . . y
S10 Au1N Ag19 111.64(8) . . y

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Au4 P2AA C2 C12 -159.7(10) . . . . ?
Au4 P2AA C2 C194 19.3(13) . . . . ?
Au4 P2AA C10 C5 61.0(5) . . . . ?
Au4 P2AA C10 C9 -124.1(4) . . . . ?
Au4 P2AA C36 C17 -158.9(11) . . . . ?
Au4 P2AA C36 C31 28.4(12) . . . . ?
Au5 P17 C42 C26 50.1(13) . . . . ?
Au5 P17 C42 C132 -131.1(12) . . . . ?
Au5 P17 C67 C19 -144.7(11) . . . . ?
Au5 P17 C67 C30 39.7(12) . . . . ?
Au5 P17 C71 C22 10.7(15) . . . . ?
Au5 P17 C71 C93 -165.6(12) . . . . ?
Au6 P0AA C23 C97 -14.9(15) . . . . ?
Au6 P0AA C23 C124 161.7(13) . . . . ?
Au6 P0AA C37 C32 -33.3(14) . . . . ?
Au6 P0AA C37 C105 144.9(13) . . . . ?
Au6 P0AA C197 C38 146.3(11) . . . . ?
Au6 P0AA C197 C123 -37.2(14) . . . . ?
Au8 P18 C34 C60 -7.6(14) . . . . ?
Au8 P18 C34 C72 165.7(12) . . . . ?
Au8 P18 C104 C58 145.4(12) . . . . ?
Au8 P18 C104 C201 -38.3(15) . . . . ?
Au8 P18 C152 C142 -55.3(15) . . . . ?
Au8 P18 C152 C145 128.2(14) . . . . ?
Au9 P13 C114 C122 146.0(13) . . . . ?
Au9 P13 C114 C149 -33.8(16) . . . . ?
Au9 P13 C133 C68 163.9(12) . . . . ?
Au9 P13 C133 C217 -11.6(16) . . . . ?
Au9 P13 C195 C53 -63.7(14) . . . . ?
Au9 P13 C195 C108 120.8(12) . . . . ?
Au10 P20 C40 C20 -27.7(15) . . . . ?
Au10 P20 C40 C62 151.2(14) . . . . ?
Au10 P20 C125 C154 118.8(14) . . . . ?
Au10 P20 C125 C168 -60.8(16) . . . . ?
Au10 P20 C167 C141 161.3(13) . . . . ?
Au10 P20 C167 C150 -24.2(16) . . . . ?
Au12 P15 C3 C138 158.7(15) . . . . ?
Au12 P15 C3 C144 -23.1(17) . . . . ?
Au12 P15 C136 C128 -51.1(19) . . . . ?
Au12 P15 C136 C186 132.5(15) . . . . ?
Au12 P15 C139 C172 -28.5(19) . . . . ?
Au12 P15 C139 C185 151.0(14) . . . . ?
Au S19 C39 C76 173.8(10) . . . . ?
Ag14 S10 C140 C180 108.8(11) . . . . ?
Au16 S18 C137 C92 -170.5(11) . . . . ?
Ag19 S14 C148 C184 -119.0(19) . . . . ?
Au0A P16 C18 C162 -145.2(13) . . . . ?
Au0A P16 C18 C171 37.0(15) . . . . ?
Au0A P16 C85 C69 -167.1(13) . . . . ?
Au0A P16 C85 C110 12.3(16) . . . . ?
Au0A P16 C178 C84 52.8(17) . . . . ?
Au0A P16 C178 C164 -134.4(14) . . . . ?
Au1A P1AA C27 C46 48.1(14) . . . . ?
Au1A P1AA C27 C87 -137.2(12) . . . . ?
Au1A P1AA C29 C134 40.4(15) . . . . ?
Au1A P1AA C29 C210 -143.0(14) . . . . ?
Au1A P1AA C33 C15 -158.0(12) . . . . ?
Au1A P1AA C33 C35 17.6(16) . . . . ?
S8 C213 C215 C79 56.9(17) . . . . ?
S10 C140 C180 C47 64.0(15) . . . . ?
S14 C148 C184 C156 -51(3) . . . . ?
P13 C114 C122 C173 179.4(13) . . . . ?
P13 C114 C149 C170 -172.8(14) . . . . ?
P13 C133 C217 C112 -176.0(14) . . . . ?
P15 C3 C138 C181 175.5(17) . . . . ?
P15 C3 C144 C169 -176.8(15) . . . . ?
P15 C136 C186 C179 170.5(15) . . . . ?
P15 C139 C172 C204 -175.6(16) . . . . ?
P15 C139 C185 C191 172.8(14) . . . . ?
P2AA C2 C12 C196 178.6(11) . . . . ?
P2AA C2 C194 C193 -177.8(11) . . . . ?
P17 C42 C132 C135 -174.8(12) . . . . ?
P17 C71 C93 C109 -178.5(12) . . . . ?
P18 C34 C60 C44 179.0(12) . . . . ?
P18 C34 C72 C75 -179.4(13) . . . . ?
P18 C104 C201 C218 -174.4(13) . . . . ?
S19 C39 C76 C107 -58.3(15) . . . . ?
P0AA C23 C97 C54 -178.9(13) . . . . ?
P0AA C23 C124 C28 179.2(13) . . . . ?
P0AA C37 C105 C200 171.6(13) . . . . ?
P1AA C27 C46 C198 173.1(13) . . . . ?
P1AA C27 C87 C57 -176.0(13) . . . . ?
P1AA C29 C134 C73 176.1(14) . . . . ?
P1AA C29 C210 C61 -174.5(14) . . . . ?
P1AA C33 C35 C41 178.1(14) . . . . ?
P20 C40 C62 C116 177.9(15) . . . . ?
P20 C125 C154 C182 176.9(14) . . . . ?
P20 C125 C168 C147 -177.0(13) . . . . ?
Au1C P4 C1 C4 22.4(12) . . . . ?
Au1C P4 C1 C13 -155.5(10) . . . . ?
Au1C P4 C14 C65 -146.2(11) . . . . ?
Au1C P4 C14 C216 41.5(13) . . . . ?
Au1C P4 C45 C24 33.5(13) . . . . ?
Au1C P4 C45 C88 -150.7(11) . . . . ?
P4 C1 C4 C21 177.7(10) . . . . ?
P4 C1 C13 C115 -176.7(11) . . . . ?
P4 C14 C65 C130 -173.8(12) . . . . ?
P4 C14 C216 C111 174.8(12) . . . . ?
P4 C45 C88 C143 -173.9(11) . . . . ?
P16 C18 C162 C187 -174.1(14) . . . . ?
P16 C18 C171 C166 177.8(14) . . . . ?
P16 C85 C110 C16 -179.9(13) . . . . ?
C1 P4 C14 C65 89.8(13) . . . . ?
C1 P4 C14 C216 -82.5(13) . . . . ?
C1 P4 C45 C24 156.8(11) . . . . ?
C1 P4 C45 C88 -27.4(14) . . . . ?
C1 C4 C21 C64 1(2) . . . . ?
C1 C13 C115 C64 -3(2) . . . . ?
C2 P2AA C10 C5 -63.1(6) . . . . ?
C2 P2AA C10 C9 111.7(6) . . . . ?
C2 P2AA C36 C17 -32.1(14) . . . . ?
C2 P2AA C36 C31 155.2(11) . . . . ?
C2 C12 C196 C192 1(2) . . . . ?
C3 P15 C136 C128 72.1(18) . . . . ?
C3 P15 C136 C186 -104.3(18) . . . . ?
C3 P15 C139 C172 -152.7(17) . . . . ?
C3 P15 C139 C185 26.7(17) . . . . ?
C3 C138 C181 C89 2(3) . . . . ?
C3 C144 C169 C89 1(3) . . . . ?
C4 C1 C13 C115 5(2) . . . . ?
C4 C21 C64 C115 2(2) . . . . ?
C5 C6 C7 C8 0.0 . . . . ?
C6 C5 C10 P2AA 175.0(6) . . . . ?
C6 C5 C10 C9 0.0 . . . . ?
C6 C7 C8 C9 0.0 . . . . ?
C7 C8 C9 C10 0.0 . . . . ?
C8 C9 C10 P2AA -174.8(7) . . . . ?
C8 C9 C10 C5 0.0 . . . . ?
C10 P2AA C2 C12 -34.5(12) . . . . ?
C10 P2AA C2 C194 144.4(11) . . . . ?
C10 P2AA C36 C17 74.2(13) . . . . ?
C10 P2AA C36 C31 -98.4(11) . . . . ?
C10 C5 C6 C7 0.0 . . . . ?
C11 C31 C36 P2AA 174.8(11) . . . . ?
C11 C31 C36 C17 2(2) . . . . ?
C11 C90 C202 C17 -1(2) . . . . ?
C12 C2 C194 C193 1(2) . . . . ?
C13 C1 C4 C21 -4(2) . . . . ?
C14 P4 C1 C4 149.2(11) . . . . ?
C14 P4 C1 C13 -28.7(13) . . . . ?
C14 P4 C45 C24 -93.1(12) . . . . ?
C14 P4 C45 C88 82.7(13) . . . . ?
C14 C65 C130 C86 0(2) . . . . ?
C15 C33 C35 C41 -6(3) . . . . ?
C15 C126 C131 C41 -7(3) . . . . ?
C16 C120 C165 C69 -4(3) . . . . ?
C18 P16 C85 C69 69.2(16) . . . . ?
C18 P16 C85 C110 -111.4(15) . . . . ?
C18 P16 C178 C84 176.2(15) . . . . ?
C18 P16 C178 C164 -11.0(18) . . . . ?
C18 C162 C187 C176 -6(3) . . . . ?
C19 C199 C214 C219 3(3) . . . . ?
C20 C40 C62 C116 -3(3) . . . . ?
C20 C129 C153 C116 -3(3) . . . . ?
C21 C64 C115 C13 -1(2) . . . . ?
C22 C56 C63 C109 2(3) . . . . ?
C22 C71 C93 C109 5(2) . . . . ?
C23 P0AA C37 C32 -159.0(13) . . . . ?
C23 P0AA C37 C105 19.2(16) . . . . ?
C23 P0AA C197 C38 -89.4(14) . . . . ?
C23 P0AA C197 C123 87.1(14) . . . . ?
C24 C45 C88 C143 2(2) . . . . ?
C26 C42 C132 C135 4(2) . . . . ?
C27 P1AA C29 C134 -84.6(14) . . . . ?
C27 P1AA C29 C210 92.0(16) . . . . ?
C27 P1AA C33 C15 -31.0(16) . . . . ?
C27 P1AA C33 C35 144.6(14) . . . . ?
C27 C46 C198 C117 4(3) . . . . ?
C29 P1AA C27 C46 170.1(13) . . . . ?
C29 P1AA C27 C87 -15.2(15) . . . . ?
C29 P1AA C33 C15 78.4(16) . . . . ?
C29 P1AA C33 C35 -105.9(15) . . . . ?
C31 C11 C90 C202 2(2) . . . . ?
C32 C37 C105 C200 -10(2) . . . . ?
C33 P1AA C27 C46 -77.9(14) . . . . ?
C33 P1AA C27 C87 96.8(15) . . . . ?
C33 P1AA C29 C134 165.9(13) . . . . ?
C33 P1AA C29 C210 -17.5(17) . . . . ?
C33 C15 C126 C131 1(3) . . . . ?
C33 C35 C41 C131 0(3) . . . . ?
C34 P18 C104 C58 19.8(15) . . . . ?
C34 P18 C104 C201 -163.9(13) . . . . ?
C34 P18 C152 C142 69.5(15) . . . . ?
C34 P18 C152 C145 -107.1(15) . . . . ?
C34 C72 C75 C207 4(2) . . . . ?
C35 C41 C131 C126 7(3) . . . . ?
C36 P2AA C2 C12 73.4(13) . . . . ?
C36 P2AA C2 C194 -107.6(12) . . . . ?
C36 P2AA C10 C5 -173.0(6) . . . . ?
C36 P2AA C10 C9 1.9(7) . . . . ?
C36 C17 C202 C90 0(2) . . . . ?
C37 P0AA C23 C97 110.7(14) . . . . ?
C37 P0AA C23 C124 -72.7(16) . . . . ?
C37 P0AA C197 C38 22.9(14) . . . . ?
C37 P0AA C197 C123 -160.6(13) . . . . ?
C37 C32 C118 C94 -4(3) . . . . ?
C37 C105 C200 C94 11(3) . . . . ?
C38 C203 C211 C206 -3(2) . . . . ?
C39 C76 C107 C74 102.5(15) . . . . ?
C39 C76 C107 C77 -73.6(16) . . . . ?
C40 P20 C125 C154 -117.9(16) . . . . ?
C40 P20 C125 C168 62.5(16) . . . . ?
C40 P20 C167 C141 36.6(17) . . . . ?
C40 P20 C167 C150 -148.9(14) . . . . ?
C40 C20 C129 C153 0(3) . . . . ?
C40 C62 C116 C153 1(3) . . . . ?
C42 P17 C67 C19 90.9(13) . . . . ?
C42 P17 C67 C30 -84.7(12) . . . . ?
C42 P17 C71 C22 137.1(13) . . . . ?
C42 P17 C71 C93 -39.3(16) . . . . ?
C42 C26 C205 C119 2(2) . . . . ?
C42 C132 C135 C119 -4(2) . . . . ?
C45 P4 C1 C4 -101.5(11) . . . . ?
C45 P4 C1 C13 80.6(12) . . . . ?
C45 P4 C14 C65 -21.7(14) . . . . ?
C45 P4 C14 C216 166.1(12) . . . . ?
C45 C24 C66 C43 5(2) . . . . ?
C45 C88 C143 C43 -2(2) . . . . ?
C46 C27 C87 C57 -1(2) . . . . ?
C47 C48 C49 C50 0.0 . . . . ?
C48 C47 C52 C51 0.0 . . . . ?
C48 C47 C180 C140 -104.4(13) . . . . ?
C48 C49 C50 C51 0.0 . . . . ?
C49 C50 C51 C52 0.0 . . . . ?
C50 C51 C52 C47 0.0 . . . . ?
C52 C47 C48 C49 0.0 . . . . ?
C52 C47 C180 C140 74.8(15) . . . . ?
C56 C22 C71 P17 -179.9(13) . . . . ?
C56 C22 C71 C93 -3(2) . . . . ?
C56 C63 C109 C93 0(3) . . . . ?
C57 C117 C198 C46 -2(2) . . . . ?
C58 C104 C201 C218 2(3) . . . . ?
C58 C209 C220 C218 1(3) . . . . ?
C59 C68 C133 P13 175.7(14) . . . . ?
C59 C68 C133 C217 -9(3) . . . . ?
C60 C34 C72 C75 -6(2) . . . . ?
C60 C44 C207 C75 0(2) . . . . ?
C62 C116 C153 C129 2(3) . . . . ?
C65 C14 C216 C111 2(2) . . . . ?
C66 C24 C45 P4 172.7(12) . . . . ?
C66 C24 C45 C88 -3(2) . . . . ?
C66 C43 C143 C88 3(2) . . . . ?
C67 P17 C42 C26 171.5(12) . . . . ?
C67 P17 C42 C132 -9.7(15) . . . . ?
C67 P17 C71 C22 -112.7(14) . . . . ?
C67 P17 C71 C93 71.0(15) . . . . ?
C67 C19 C199 C214 -1(3) . . . . ?
C67 C30 C219 C214 2(2) . . . . ?
C68 C59 C121 C112 2(3) . . . . ?
C68 C133 C217 C112 9(3) . . . . ?
C69 C85 C110 C16 0(3) . . . . ?
C70 C28 C124 C23 2(3) . . . . ?
C70 C54 C97 C23 -2(3) . . . . ?
C71 P17 C42 C26 -75.6(13) . . . . ?
C71 P17 C42 C132 103.3(14) . . . . ?
C71 P17 C67 C19 -19.3(14) . . . . ?
C71 P17 C67 C30 165.1(11) . . . . ?
C71 C22 C56 C63 0(3) . . . . ?
C71 C93 C109 C63 -4(3) . . . . ?
C72 C34 C60 C44 6(2) . . . . ?
C72 C75 C207 C44 0(2) . . . . ?
C78 C79 C80 C81 0.0 . . . . ?
C78 C79 C215 C213 -99.5(14) . . . . ?
C79 C78 C83 C82 0.0 . . . . ?
C79 C80 C81 C82 0.0 . . . . ?
C80 C79 C215 C213 75.5(15) . . . . ?
C80 C81 C82 C83 0.0 . . . . ?
C81 C82 C83 C78 0.0 . . . . ?
C83 C78 C79 C80 0.0 . . . . ?
C83 C78 C79 C215 175.0(11) . . . . ?
C84 C177 C189 C183 -1(4) . . . . ?
C85 P16 C18 C162 -20.0(17) . . . . ?
C85 P16 C18 C171 162.3(13) . . . . ?
C85 P16 C178 C84 -70.7(16) . . . . ?
C85 P16 C178 C164 102.1(16) . . . . ?
C85 C69 C165 C120 3(3) . . . . ?
C86 C111 C216 C14 -2(3) . . . . ?
C87 C27 C46 C198 -2(2) . . . . ?
C87 C57 C117 C198 -1(3) . . . . ?
C90 C11 C31 C36 -3(2) . . . . ?
C91 C55 C96 C74 1(2) . . . . ?
C91 C77 C107 C74 1(2) . . . . ?
C91 C77 C107 C76 176.9(12) . . . . ?
C92 C98 C99 C100 -175.1(13) . . . . ?
C92 C98 C103 C102 175.1(13) . . . . ?
C95 C106 C113 C53 6(3) . . . . ?
C95 C108 C195 P13 178.3(12) . . . . ?
C95 C108 C195 C53 3(2) . . . . ?
C96 C55 C91 C77 1(2) . . . . ?
C96 C74 C107 C76 -175.4(12) . . . . ?
C96 C74 C107 C77 1(2) . . . . ?
C97 C23 C124 C28 -4(3) . . . . ?
C97 C54 C70 C28 0(3) . . . . ?
C98 C92 C137 S18 56.2(18) . . . . ?
C98 C99 C100 C101 0.0 . . . . ?
C99 C98 C103 C102 0.0 . . . . ?
C99 C100 C101 C102 0.0 . . . . ?
C100 C101 C102 C103 0.0 . . . . ?
C101 C102 C103 C98 0.0 . . . . ?
C103 C98 C99 C100 0.0 . . . . ?
C104 P18 C34 C60 115.8(13) . . . . ?
C104 P18 C34 C72 -71.0(15) . . . . ?
C104 P18 C152 C142 -178.7(14) . . . . ?
C104 P18 C152 C145 4.8(17) . . . . ?
C104 C58 C209 C220 -2(3) . . . . ?
C104 C201 C218 C220 -3(3) . . . . ?
C106 C95 C108 C195 1(2) . . . . ?
C107 C74 C96 C55 -2(2) . . . . ?
C107 C77 C91 C55 -2(2) . . . . ?
C108 C95 C106 C113 -5(3) . . . . ?
C110 C16 C120 C165 2(3) . . . . ?
C111 C86 C130 C65 0(3) . . . . ?
C113 C53 C195 P13 -177.7(13) . . . . ?
C113 C53 C195 C108 -2(2) . . . . ?
C114 P13 C133 C68 -71.3(16) . . . . ?
C114 P13 C133 C217 113.3(15) . . . . ?
C114 P13 C195 C53 174.8(12) . . . . ?
C114 P13 C195 C108 -0.7(15) . . . . ?
C114 C122 C173 C25 -6(3) . . . . ?
C114 C149 C170 C25 -7(3) . . . . ?
C117 C57 C87 C27 3(3) . . . . ?
C118 C32 C37 P0AA -174.6(13) . . . . ?
C118 C32 C37 C105 7(3) . . . . ?
C118 C94 C200 C105 -8(3) . . . . ?
C120 C16 C110 C85 0(3) . . . . ?
C121 C59 C68 C133 4(3) . . . . ?
C121 C112 C217 C133 -3(3) . . . . ?
C122 C114 C149 C170 7(3) . . . . ?
C123 C206 C211 C203 2(2) . . . . ?
C124 C23 C97 C54 4(3) . . . . ?
C124 C28 C70 C54 0(3) . . . . ?
C125 P20 C40 C20 -153.0(14) . . . . ?
C125 P20 C40 C62 25.9(17) . . . . ?
C125 P20 C167 C141 -72.3(17) . . . . ?
C125 P20 C167 C150 102.2(15) . . . . ?
C125 C154 C182 C163 -2(3) . . . . ?
C126 C15 C33 P1AA -178.6(13) . . . . ?
C126 C15 C33 C35 6(3) . . . . ?
C127 C142 C152 P18 -175.0(13) . . . . ?
C127 C142 C152 C145 2(3) . . . . ?
C127 C146 C190 C145 0(3) . . . . ?
C128 C136 C186 C179 -6(3) . . . . ?
C129 C20 C40 P20 -178.2(13) . . . . ?
C129 C20 C40 C62 3(3) . . . . ?
C130 C86 C111 C216 1(3) . . . . ?
C133 P13 C114 C122 18.8(16) . . . . ?
C133 P13 C114 C149 -161.0(14) . . . . ?
C133 P13 C195 C53 61.3(14) . . . . ?
C133 P13 C195 C108 -114.2(14) . . . . ?
C134 C29 C210 C61 2(3) . . . . ?
C134 C73 C212 C61 4(3) . . . . ?
C135 C119 C205 C26 -2(2) . . . . ?
C136 P15 C3 C138 33.3(19) . . . . ?
C136 P15 C3 C144 -148.5(15) . . . . ?
C136 P15 C139 C172 97.9(18) . . . . ?
C136 P15 C139 C185 -82.7(17) . . . . ?
C136 C128 C188 C174 -10(3) . . . . ?
C137 C92 C98 C99 74.5(17) . . . . ?
C137 C92 C98 C103 -100.6(16) . . . . ?
C138 C3 C144 C169 2(3) . . . . ?
C139 P15 C3 C138 -79.1(19) . . . . ?
C139 P15 C3 C144 99.1(16) . . . . ?
C139 P15 C136 C128 -173.2(16) . . . . ?
C139 P15 C136 C186 10(2) . . . . ?
C139 C172 C204 C208 0(3) . . . . ?
C139 C185 C191 C208 7(3) . . . . ?
C142 C127 C146 C190 3(3) . . . . ?
C143 C43 C66 C24 -5(2) . . . . ?
C144 C3 C138 C181 -3(3) . . . . ?
C146 C127 C142 C152 -4(3) . . . . ?
C147 C163 C182 C154 6(3) . . . . ?
C149 C114 C122 C173 -1(3) . . . . ?
C152 P18 C34 C60 -133.6(13) . . . . ?
C152 P18 C34 C72 39.6(16) . . . . ?
C152 P18 C104 C58 -87.6(15) . . . . ?
C152 P18 C104 C201 88.7(14) . . . . ?
C152 C145 C190 C146 -3(3) . . . . ?
C154 C125 C168 C147 3(3) . . . . ?
C155 C141 C167 P20 173.1(13) . . . . ?
C155 C141 C167 C150 -1(3) . . . . ?
C155 C151 C175 C150 -1(3) . . . . ?
C156 C157 C158 C159 0.0 . . . . ?
C157 C156 C161 C160 0.0 . . . . ?
C157 C156 C184 C148 -78(2) . . . . ?
C157 C158 C159 C160 0.0 . . . . ?
C158 C159 C160 C161 0.0 . . . . ?
C159 C160 C161 C156 0.0 . . . . ?
C161 C156 C157 C158 0.0 . . . . ?
C161 C156 C184 C148 99(2) . . . . ?
C162 C18 C171 C166 0(3) . . . . ?
C163 C147 C168 C125 1(3) . . . . ?
C164 C183 C189 C177 -3(3) . . . . ?
C165 C69 C85 P16 178.8(13) . . . . ?
C165 C69 C85 C110 -1(3) . . . . ?
C166 C176 C187 C162 5(3) . . . . ?
C167 P20 C40 C20 98.0(15) . . . . ?
C167 P20 C40 C62 -83.1(16) . . . . ?
C167 P20 C125 C154 -6.8(18) . . . . ?
C167 P20 C125 C168 173.6(15) . . . . ?
C167 C141 C155 C151 4(3) . . . . ?
C167 C150 C175 C151 3(3) . . . . ?
C168 C125 C154 C182 -4(3) . . . . ?
C168 C147 C163 C182 -6(3) . . . . ?
C169 C89 C181 C138 1(3) . . . . ?
C170 C25 C173 C122 6(3) . . . . ?
C171 C18 C162 C187 4(3) . . . . ?
C171 C166 C176 C187 -2(3) . . . . ?
C172 C139 C185 C191 -8(3) . . . . ?
C172 C204 C208 C191 -1(3) . . . . ?
C173 C25 C170 C149 0(3) . . . . ?
C174 C179 C186 C136 6(3) . . . . ?
C175 C150 C167 P20 -176.8(14) . . . . ?
C175 C150 C167 C141 -2(3) . . . . ?
C175 C151 C155 C141 -3(3) . . . . ?
C176 C166 C171 C18 -1(3) . . . . ?
C177 C84 C178 P16 170.8(14) . . . . ?
C177 C84 C178 C164 -2(3) . . . . ?
C178 P16 C18 C162 88.0(16) . . . . ?
C178 P16 C18 C171 -89.7(14) . . . . ?
C178 P16 C85 C69 -41.8(17) . . . . ?
C178 P16 C85 C110 137.6(14) . . . . ?
C178 C84 C177 C189 4(3) . . . . ?
C178 C164 C183 C189 5(3) . . . . ?
C179 C174 C188 C128 10(3) . . . . ?
C180 C47 C48 C49 179.2(12) . . . . ?
C180 C47 C52 C51 -179.2(13) . . . . ?
C181 C89 C169 C144 -2(3) . . . . ?
C183 C164 C178 P16 -174.9(14) . . . . ?
C183 C164 C178 C84 -2(3) . . . . ?
C184 C156 C157 C158 177.3(16) . . . . ?
C184 C156 C161 C160 -177.0(18) . . . . ?
C185 C139 C172 C204 5(3) . . . . ?
C185 C191 C208 C204 -3(3) . . . . ?
C188 C128 C136 P15 -168.1(15) . . . . ?
C188 C128 C136 C186 8(3) . . . . ?
C188 C174 C179 C186 -8(3) . . . . ?
C190 C145 C152 P18 178.8(15) . . . . ?
C190 C145 C152 C142 2(3) . . . . ?
C192 C193 C194 C2 -3(2) . . . . ?
C193 C192 C196 C12 -3(2) . . . . ?
C194 C2 C12 C196 0(2) . . . . ?
C195 P13 C114 C122 -91.1(15) . . . . ?
C195 P13 C114 C149 89.1(15) . . . . ?
C195 P13 C133 C68 39.9(16) . . . . ?
C195 P13 C133 C217 -135.6(14) . . . . ?
C195 C53 C113 C106 -2(3) . . . . ?
C196 C192 C193 C194 4(2) . . . . ?
C197 P0AA C23 C97 -139.9(13) . . . . ?
C197 P0AA C23 C124 36.7(17) . . . . ?
C197 P0AA C37 C32 90.9(14) . . . . ?
C197 P0AA C37 C105 -91.0(15) . . . . ?
C197 C38 C203 C211 3(2) . . . . ?
C197 C123 C206 C211 -1(2) . . . . ?
C199 C19 C67 P17 -175.9(12) . . . . ?
C199 C19 C67 C30 0(2) . . . . ?
C199 C214 C219 C30 -3(2) . . . . ?
C200 C94 C118 C32 5(3) . . . . ?
C201 C218 C220 C209 1(3) . . . . ?
C202 C17 C36 P2AA -172.8(11) . . . . ?
C202 C17 C36 C31 0(2) . . . . ?
C203 C38 C197 P0AA 174.4(12) . . . . ?
C203 C38 C197 C123 -2(2) . . . . ?
C205 C26 C42 P17 175.9(12) . . . . ?
C205 C26 C42 C132 -3(2) . . . . ?
C205 C119 C135 C132 3(3) . . . . ?
C206 C123 C197 P0AA -175.3(12) . . . . ?
C206 C123 C197 C38 1(2) . . . . ?
C207 C44 C60 C34 -2(2) . . . . ?
C209 C58 C104 P18 176.4(12) . . . . ?
C209 C58 C104 C201 0(2) . . . . ?
C210 C29 C134 C73 -1(3) . . . . ?
C210 C61 C212 C73 -3(3) . . . . ?
C212 C61 C210 C29 0(3) . . . . ?
C212 C73 C134 C29 -2(3) . . . . ?
C215 C79 C80 C81 -174.9(11) . . . . ?
C216 C14 C65 C130 -1(2) . . . . ?
C217 C112 C121 C59 -2(3) . . . . ?
C219 C30 C67 P17 175.4(12) . . . . ?
C219 C30 C67 C19 0(2) . . . . ?
Ag1D S8 C213 C215 110.4(11) . . . . ?
Ag1E S14 C148 C184 162.5(18) . . . . ?
Au1H S18 C137 C92 110.4(12) . . . . ?
Ag1J S8 C213 C215 -170.9(10) . . . . ?
Ag1L S19 C39 C76 -106.0(10) . . . . ?
Au1N S10 C140 C180 -173.2(11) . . . . ?

_smtbx_masks_special_details     
;
A solvent mask was calculated and 757 electrons were 
found in a volume of 3977Å³ in 2 voids per unit cell. 
This is consistent with the presence of 38[H2O] per Formula Unit 
which account for 760 electrons per unit cell.
;
loop_
_smtbx_masks_void_nr
_smtbx_masks_void_average_x
_smtbx_masks_void_average_y
_smtbx_masks_void_average_z
_smtbx_masks_void_volume
_smtbx_masks_void_count_electrons
_smtbx_masks_void_content
1 -0.301 0.000 -0.156 3951.0 757.4 '76 H2O'
2 0.500 0.500 0.500 26.0 0.0 ?

_smtbx_masks_void_probe_radius   1.2
_smtbx_masks_void_truncation_radius 1.2
_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_au13-dppm
_database_code_depnum_ccdc_archive 'CCDC 2163572'
loop_
_audit_author_name
_audit_author_address
'Xi Xi Kang'
;Anhui University
China
;
_audit_update_record             
;
2022-09-21 deposited with the CCDC.	2022-09-23 downloaded from the CCDC.
;
_audit_creation_date             2022-09-16
_audit_creation_method           
;
Olex2 1.5-dev
(compiled 2022.07.25 svn.r36e0af09 for OlexSys, GUI svn.r6444)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C150 H132 Au13 P12, 3(Cl), 43[H2O]'
_chemical_formula_sum            'C150 H218 Au13 Cl3 O43 P12'
_chemical_formula_weight         5747.79
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -4.4197 7.2980 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      trigonal
_space_group_IT_number           163
_space_group_name_H-M_alt        'P -3 1 c'
_space_group_name_Hall           '-P 3 2c'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'-y, -x, -z+1/2'
'-x+y, y, -z+1/2'
'x, x-y, -z+1/2'
'-x, -y, -z'
'y, -x+y, -z'
'x-y, x, -z'
'y, x, z-1/2'
'x-y, -y, z-1/2'
'-x, -x+y, z-1/2'

_cell_length_a                   19.7102(8)
_cell_length_b                   19.7102(8)
_cell_length_c                   27.4590(12)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_volume                     9238.4(9)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    18816
_cell_measurement_temperature    120
_cell_measurement_theta_max      69.94
_cell_measurement_theta_min      3.22
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    20.819
_exptl_absorpt_correction_T_max  0.2349
_exptl_absorpt_correction_T_min  0.0627
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
STOE X-Red32, absorption correction by Gaussian integration, analogous to
P. Coppens, "The Evaluation of Absorption and Extinction in Single-Crystal
Structure Analysis", published in: F. R. Ahmed (Editor), "Crystallographic
Computing", Munksgaard, Copenhagen (1970), 255 - 270.
Afterwards scaling of reflection intensities was performed within STOE LANA.
J. Koziskova, F. Hahn, J. Richter, J. Kozisek, "Comparison of different
absorption corrections on the model structure of tetrakis(μ₂-acetato)-
diaqua-di-copper(II)", Acta Chimica Slovaca, vol. 9, no. 2, 2016, pp. 136 - 140.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            black
_exptl_crystal_colour_primary    black
_exptl_crystal_density_diffrn    2.066
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             5440
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
1 -2 30 0.0665
10 -10 -3 0.0909
22 9 30 0.0552
-3 -10 -15 0.0576
-1 -1 -15 0.0593
-13 30 14 0.0815
-15 -2 -11 0.0481
15 -13 7 0.0756
2 3 1 0.0560
-15 11 0 0.0913

_exptl_crystal_size_max          0.55
_exptl_crystal_size_mid          0.31
_exptl_crystal_size_min          0.24
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0289
_diffrn_reflns_av_unetI/netI     0.0318
_diffrn_reflns_Laue_measured_fraction_full 0.994
_diffrn_reflns_Laue_measured_fraction_max 0.981
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_limit_l_min       -33
_diffrn_reflns_number            20148
_diffrn_reflns_point_group_measured_fraction_full 0.994
_diffrn_reflns_point_group_measured_fraction_max 0.981
_diffrn_reflns_theta_full        67.686
_diffrn_reflns_theta_max         69.597
_diffrn_reflns_theta_min         3.219
_diffrn_ambient_temperature      120.00
_diffrn_detector_area_resol_mean 5.81
_diffrn_detector_type            'DECTRIS PILATUS 300K'
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.981
_diffrn_measurement_details      
;
 567 frames, detector distance = 60 mm
;
_diffrn_measurement_device       'Eulerian 4-circle diffractometer'
_diffrn_measurement_device_type  'STOE STADIVARI'
_diffrn_measurement_method       'rotation method, ω scans'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54186
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                4987
_reflns_number_total             5712
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       
;
X-Area Recipe 1.33.0.0 (STOE, 2015)
;
_computing_data_collection       
;
X-Area Pilatus3_SV 1.31.153.0 (STOE, 2018)
;
_computing_data_reduction        
;
X-Area Integrate 1.74.2.0 (STOE, 2018)
X-Area LANA 1.75.3.0 (STOE, 2018)
;
_computing_molecular_graphics    'Olex2 1.5-dev (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5-dev (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         1.262
_refine_diff_density_min         -2.462
_refine_diff_density_rms         0.164
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.045
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     221
_refine_ls_number_reflns         5712
_refine_ls_number_restraints     214
_refine_ls_R_factor_all          0.0402
_refine_ls_R_factor_gt           0.0345
_refine_ls_restrained_S_all      1.028
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0570P)²+11.4688P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0897
_refine_ls_wR_factor_ref         0.0924
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
2. Rigid body (RIGU) restrains
 C18, Au1, Au3, Au2, P1, C6, C7, C8, C1, C5, P2, C9, C13, C2, C4, C19, C20,
 C10, C12, C3, C14, C21, C25, C11, C15, C17, C22, C24, C16, C23
 with sigma for 1-2 distances of 0.005 and sigma for 1-3 distances of 0.005
3.a Secondary CH2 refined with riding coordinates:
 C7(H7A,H7B)
3.b Aromatic/amide H refined with riding coordinates:
 C1(H1), C2(H2), C3(H3), C4(H4), C5(H5), C9(H9), C10(H10), C11(H11), C12(H12),
 C13(H13), C14(H14), C15(H15), C16(H16), C17(H17), C18(H18), C21(H21), C22(H22),
  C23(H23), C24(H24), C25(H25)
3.c Fitted hexagon refined as free rotating group:
 C1(C2,C3,C4,C5,C6), C8(C9,C10,C11,C12,C13), C14(C15,C16,C17,C18,C19), C20(C21,
 C22,C23,C24,C25)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.666667 0.333333 0.750000 0.01480(13) Uani 1 6 d S T P . .
Au3 Au 0.66908(2) 0.41776(2) 0.67190(2) 0.01859(9) Uani 1 1 d . . . . .
Au2 Au 0.52986(2) 0.34786(2) 0.72748(2) 0.01905(9) Uani 1 1 d . . . . .
P1 P 0.70483(10) 0.53153(10) 0.63128(6) 0.0215(3) Uani 1 1 d . . . . .
P2 P 0.86411(10) 0.58601(10) 0.68289(6) 0.0233(4) Uani 1 1 d . . . . .
C1 C 0.6870(3) 0.4613(2) 0.54233(16) 0.0316(16) Uani 1 1 d G . . . .
H1 H 0.649248 0.415633 0.558953 0.038 Uiso 1 1 calc R U . . .
C2 C 0.6986(3) 0.4584(2) 0.49262(16) 0.0413(19) Uani 1 1 d G . . . .
H2 H 0.668859 0.410774 0.475271 0.050 Uiso 1 1 calc R U . . .
C3 C 0.7538(3) 0.5253(3) 0.46831(12) 0.0375(18) Uani 1 1 d G . . . .
H3 H 0.761802 0.523298 0.434333 0.045 Uiso 1 1 calc R U . . .
C4 C 0.7974(3) 0.5950(2) 0.49370(16) 0.0337(16) Uani 1 1 d G . . . .
H4 H 0.835134 0.640682 0.477077 0.040 Uiso 1 1 calc R U . . .
C5 C 0.7858(3) 0.5979(2) 0.54341(16) 0.0336(17) Uani 1 1 d G . . . .
H5 H 0.815525 0.645542 0.560758 0.040 Uiso 1 1 calc R U . . .
C6 C 0.7305(3) 0.5310(3) 0.56772(12) 0.0268(14) Uani 1 1 d G . . . .
C7 C 0.7910(4) 0.6106(4) 0.6621(2) 0.0263(15) Uani 1 1 d . . . . .
H7A H 0.816795 0.655626 0.639453 0.032 Uiso 1 1 calc R U . . .
H7B H 0.772744 0.627889 0.690553 0.032 Uiso 1 1 calc R U . . .
C8 C 0.6333(3) 0.5645(3) 0.62885(18) 0.0272(14) Uani 1 1 d G . . . .
C9 C 0.6410(3) 0.6206(3) 0.5952(2) 0.047(2) Uani 1 1 d G . . . .
H9 H 0.685408 0.644325 0.574348 0.056 Uiso 1 1 calc R U . . .
C10 C 0.5838(4) 0.6420(4) 0.5920(2) 0.059(3) Uani 1 1 d G . . . .
H10 H 0.589085 0.680307 0.568987 0.071 Uiso 1 1 calc R U . . .
C11 C 0.5188(3) 0.6072(4) 0.6225(2) 0.056(3) Uani 1 1 d G . . . .
H11 H 0.479726 0.621834 0.620302 0.067 Uiso 1 1 calc R U . . .
C12 C 0.5111(3) 0.5511(4) 0.6561(2) 0.047(2) Uani 1 1 d G . . . .
H12 H 0.466690 0.527381 0.676978 0.056 Uiso 1 1 calc R U . . .
C13 C 0.5683(3) 0.5297(3) 0.65933(17) 0.0351(17) Uani 1 1 d G . . . .
H13 H 0.563012 0.491398 0.682339 0.042 Uiso 1 1 calc R U . . .
C14 C 0.8864(3) 0.5191(2) 0.59940(17) 0.0317(16) Uani 1 1 d G . . . .
H14 H 0.841826 0.472246 0.610216 0.038 Uiso 1 1 calc R U . . .
C15 C 0.9235(3) 0.5195(3) 0.55628(17) 0.0417(19) Uani 1 1 d G . . . .
H15 H 0.904308 0.472867 0.537619 0.050 Uiso 1 1 calc R U . . .
C16 C 0.9888(3) 0.5881(4) 0.54046(17) 0.058(3) Uani 1 1 d G . . . .
H16 H 1.014177 0.588337 0.510989 0.070 Uiso 1 1 calc R U . . .
C17 C 1.0170(3) 0.6563(3) 0.5678(2) 0.073(4) Uani 1 1 d G . . . .
H17 H 1.061566 0.703187 0.556955 0.087 Uiso 1 1 calc R U . . .
C18 C 0.9798(3) 0.6559(3) 0.6109(2) 0.053(3) Uani 1 1 d G . . . .
H18 H 0.999085 0.702567 0.629552 0.064 Uiso 1 1 calc R U . . .
C19 C 0.9146(3) 0.5873(3) 0.62671(15) 0.0262(14) Uani 1 1 d G . . . .
C20 C 0.9336(3) 0.6717(3) 0.71695(18) 0.0311(16) Uani 1 1 d G . . . .
C21 C 0.9815(4) 0.6611(3) 0.7495(2) 0.049(2) Uani 1 1 d G . . . .
H21 H 0.977737 0.611267 0.752352 0.059 Uiso 1 1 calc R U . . .
C22 C 1.0351(3) 0.7234(4) 0.7778(2) 0.070(3) Uani 1 1 d G . . . .
H22 H 1.067859 0.716203 0.800063 0.084 Uiso 1 1 calc R U . . .
C23 C 1.0407(4) 0.7963(3) 0.7736(2) 0.067(3) Uani 1 1 d G . . . .
H23 H 1.077242 0.838927 0.792998 0.080 Uiso 1 1 calc R U . . .
C24 C 0.9927(5) 0.8069(3) 0.7411(3) 0.090(4) Uani 1 1 d G . . . .
H24 H 0.996505 0.856715 0.738223 0.107 Uiso 1 1 calc R U . . .
C25 C 0.9392(4) 0.7446(3) 0.7127(2) 0.058(3) Uani 1 1 d G . . . .
H25 H 0.906382 0.751779 0.690512 0.069 Uiso 1 1 calc R U . . .
Cl1 Cl 1.000000 1.000000 0.500000 0.0622(16) Uani 1 6 d S T P . .
Cl2 Cl 0.666667 0.333333 0.38363(16) 0.0729(14) Uani 1 3 d S T P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 Au3 2.7002(3) 6_556 y
Au1 Au3 2.7002(3) 5_656 y
Au1 Au3 2.7002(3) 2_655 y
Au1 Au3 2.7002(3) 3_665 y
Au1 Au3 2.7001(3) . y
Au1 Au3 2.7002(3) 4_666 y
Au1 Au2 2.9167(3) 2_655 y
Au1 Au2 2.9167(3) 4_666 y
Au1 Au2 2.9167(3) . y
Au1 Au2 2.9167(3) 6_556 y
Au1 Au2 2.9167(3) 3_665 y
Au1 Au2 2.9167(3) 5_656 y
Au3 Au3 2.8419(5) 3_665 y
Au3 Au3 2.8419(5) 2_655 y
Au3 Au2 2.8243(4) . y
Au3 Au2 2.9965(4) 3_665 y
Au3 Au2 3.0258(4) 4_666 y
Au3 P1 2.2780(16) . y
Au2 Au2 2.7090(6) 4_666 y
Au2 P2 2.3377(17) 2_655 y
P1 C6 1.819(4) . ?
P1 C7 1.839(7) . ?
P1 C8 1.825(4) . ?
P2 C7 1.827(8) . ?
P2 C19 1.829(4) . ?
P2 C20 1.813(4) . ?
C1 H1 0.9500 . ?
C1 C2 1.3900 . ?
C1 C6 1.3900 . ?
C2 H2 0.9500 . ?
C2 C3 1.3900 . ?
C3 H3 0.9500 . ?
C3 C4 1.3900 . ?
C4 H4 0.9500 . ?
C4 C5 1.3900 . ?
C5 H5 0.9500 . ?
C5 C6 1.3900 . ?
C7 H7A 0.9900 . ?
C7 H7B 0.9900 . ?
C8 C9 1.3900 . ?
C8 C13 1.3900 . ?
C9 H9 0.9500 . ?
C9 C10 1.3900 . ?
C10 H10 0.9500 . ?
C10 C11 1.3900 . ?
C11 H11 0.9500 . ?
C11 C12 1.3900 . ?
C12 H12 0.9500 . ?
C12 C13 1.3900 . ?
C13 H13 0.9500 . ?
C14 H14 0.9500 . ?
C14 C15 1.3900 . ?
C14 C19 1.3900 . ?
C15 H15 0.9500 . ?
C15 C16 1.3900 . ?
C16 H16 0.9500 . ?
C16 C17 1.3900 . ?
C17 H17 0.9500 . ?
C17 C18 1.3900 . ?
C18 H18 0.9500 . ?
C18 C19 1.3900 . ?
C20 C21 1.3900 . ?
C20 C25 1.3900 . ?
C21 H21 0.9500 . ?
C21 C22 1.3900 . ?
C22 H22 0.9500 . ?
C22 C23 1.3900 . ?
C23 H23 0.9500 . ?
C23 C24 1.3900 . ?
C24 H24 0.9500 . ?
C24 C25 1.3900 . ?
C25 H25 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Au3 Au1 Au3 115.485(12) 6_556 3_665 y
Au3 Au1 Au3 115.485(12) . 5_656 y
Au3 Au1 Au3 117.546(11) . 4_666 y
Au3 Au1 Au3 178.247(11) 6_556 . y
Au3 Au1 Au3 63.504(10) 6_556 4_666 y
Au3 Au1 Au3 63.504(9) 3_665 . y
Au3 Au1 Au3 117.547(12) 3_665 5_656 y
Au3 Au1 Au3 117.547(12) 6_556 2_655 y
Au3 Au1 Au3 178.246(11) 2_655 5_656 y
Au3 Au1 Au3 63.504(9) 3_665 2_655 y
Au3 Au1 Au3 178.246(11) 3_665 4_666 y
Au3 Au1 Au3 63.503(10) . 2_655 y
Au3 Au1 Au3 115.485(12) 2_655 4_666 y
Au3 Au1 Au3 63.504(10) 6_556 5_656 y
Au3 Au1 Au3 63.504(10) 5_656 4_666 y
Au3 Au1 Au2 65.057(8) 2_655 6_556 y
Au3 Au1 Au2 65.057(8) . 4_666 y
Au3 Au1 Au2 60.228(7) 6_556 6_556 y
Au3 Au1 Au2 64.347(8) 4_666 6_556 y
Au3 Au1 Au2 60.228(7) 5_656 5_656 y
Au3 Au1 Au2 60.228(7) 3_665 3_665 y
Au3 Au1 Au2 121.402(7) . 6_556 y
Au3 Au1 Au2 115.107(8) 2_655 3_665 y
Au3 Au1 Au2 64.347(8) 5_656 4_666 y
Au3 Au1 Au2 121.403(7) 4_666 3_665 y
Au3 Au1 Au2 115.107(8) 4_666 5_656 y
Au3 Au1 Au2 60.228(8) . . y
Au3 Au1 Au2 113.942(8) 3_665 6_556 y
Au3 Au1 Au2 113.942(8) 5_656 . y
Au3 Au1 Au2 115.107(8) 6_556 4_666 y
Au3 Au1 Au2 115.107(8) 5_656 6_556 y
Au3 Au1 Au2 65.057(8) 6_556 2_655 y
Au3 Au1 Au2 113.942(8) 6_556 3_665 y
Au3 Au1 Au2 64.347(8) 3_665 2_655 y
Au3 Au1 Au2 64.348(8) . 3_665 y
Au3 Au1 Au2 115.107(8) . 2_655 y
Au3 Au1 Au2 65.057(8) 5_656 3_665 y
Au3 Au1 Au2 60.228(7) 2_655 2_655 y
Au3 Au1 Au2 115.108(8) 3_665 . y
Au3 Au1 Au2 121.403(7) 5_656 2_655 y
Au3 Au1 Au2 64.347(8) 2_655 . y
Au3 Au1 Au2 113.942(8) 4_666 2_655 y
Au3 Au1 Au2 65.056(8) 4_666 . y
Au3 Au1 Au2 64.347(8) 6_556 5_656 y
Au3 Au1 Au2 121.403(7) 3_665 4_666 y
Au3 Au1 Au2 65.057(8) 3_665 5_656 y
Au3 Au1 Au2 113.942(8) 2_655 4_666 y
Au3 Au1 Au2 113.943(8) . 5_656 y
Au3 Au1 Au2 60.228(7) 4_666 4_666 y
Au3 Au1 Au2 121.403(7) 2_655 5_656 y
Au3 Au1 Au2 121.402(7) 6_556 . y
Au2 Au1 Au2 115.631(3) 2_655 . y
Au2 Au1 Au2 115.631(3) 2_655 3_665 y
Au2 Au1 Au2 55.342(11) . 4_666 y
Au2 Au1 Au2 170.249(11) 5_656 . y
Au2 Au1 Au2 115.631(3) 5_656 4_666 y
Au2 Au1 Au2 73.618(11) 6_556 . y
Au2 Au1 Au2 115.631(3) 5_656 6_556 y
Au2 Au1 Au2 115.632(4) 3_665 . y
Au2 Au1 Au2 170.248(11) 2_655 4_666 y
Au2 Au1 Au2 170.248(11) 6_556 3_665 y
Au2 Au1 Au2 115.631(4) 6_556 4_666 y
Au2 Au1 Au2 73.619(11) 2_655 5_656 y
Au2 Au1 Au2 55.342(11) 5_656 3_665 y
Au2 Au1 Au2 55.342(11) 2_655 6_556 y
Au2 Au1 Au2 73.619(11) 3_665 4_666 y
Au1 Au3 Au3 58.249(5) . 2_655 y
Au1 Au3 Au3 58.249(5) . 3_665 y
Au1 Au3 Au2 63.689(8) . . y
Au1 Au3 Au2 60.931(8) . 4_666 y
Au1 Au3 Au2 61.333(7) . 3_665 y
Au3 Au3 Au3 60.0 2_655 3_665 y
Au3 Au3 Au2 113.195(8) 3_665 4_666 y
Au3 Au3 Au2 106.759(8) 2_655 4_666 y
Au3 Au3 Au2 108.579(10) 2_655 3_665 y
Au3 Au3 Au2 57.789(10) 3_665 3_665 y
Au2 Au3 Au3 113.608(10) . 3_665 y
Au2 Au3 Au3 63.854(11) . 2_655 y
Au2 Au3 Au2 115.995(13) . 3_665 y
Au2 Au3 Au2 70.951(10) 3_665 4_666 y
Au2 Au3 Au2 55.040(11) . 4_666 y
P1 Au3 Au1 153.77(5) . . y
P1 Au3 Au3 147.95(5) . 2_655 y
P1 Au3 Au3 126.92(5) . 3_665 y
P1 Au3 Au2 119.45(4) . . y
P1 Au3 Au2 98.20(5) . 3_665 y
P1 Au3 Au2 98.27(4) . 4_666 y
Au1 Au2 Au3 54.013(7) . 4_666 y
Au1 Au2 Au3 54.320(7) . 2_655 y
Au3 Au2 Au1 56.083(8) . . y
Au3 Au2 Au3 104.201(12) . 4_666 y
Au3 Au2 Au3 98.632(11) 2_655 4_666 y
Au3 Au2 Au3 58.357(12) . 2_655 y
Au2 Au2 Au1 62.329(5) 4_666 . y
Au2 Au2 Au3 66.262(11) 4_666 . y
Au2 Au2 Au3 111.205(9) 4_666 2_655 y
Au2 Au2 Au3 58.699(10) 4_666 4_666 y
P2 Au2 Au1 137.10(5) 2_655 . y
P2 Au2 Au3 115.41(4) 2_655 . y
P2 Au2 Au3 84.56(5) 2_655 2_655 y
P2 Au2 Au3 134.44(4) 2_655 4_666 y
P2 Au2 Au2 159.28(5) 2_655 4_666 y
C6 P1 Au3 114.49(17) . . ?
C6 P1 C7 107.7(3) . . ?
C6 P1 C8 103.5(2) . . ?
C7 P1 Au3 108.0(2) . . ?
C8 P1 Au3 117.03(17) . . ?
C8 P1 C7 105.4(3) . . ?
C7 P2 Au2 116.8(2) . 3_665 ?
C19 P2 Au2 113.51(18) . 3_665 ?
C19 P2 C7 103.2(3) . . ?
C20 P2 Au2 112.54(19) . 3_665 ?
C20 P2 C7 104.1(3) . . ?
C20 P2 C19 105.6(3) . . ?
C2 C1 H1 120.0 . . ?
C2 C1 C6 120.0 . . ?
C6 C1 H1 120.0 . . ?
C1 C2 H2 120.0 . . ?
C3 C2 C1 120.0 . . ?
C3 C2 H2 120.0 . . ?
C2 C3 H3 120.0 . . ?
C4 C3 C2 120.0 . . ?
C4 C3 H3 120.0 . . ?
C3 C4 H4 120.0 . . ?
C3 C4 C5 120.0 . . ?
C5 C4 H4 120.0 . . ?
C4 C5 H5 120.0 . . ?
C6 C5 C4 120.0 . . ?
C6 C5 H5 120.0 . . ?
C1 C6 P1 116.8(3) . . ?
C5 C6 P1 123.0(3) . . ?
C5 C6 C1 120.0 . . ?
P1 C7 H7A 108.3 . . ?
P1 C7 H7B 108.3 . . ?
P2 C7 P1 115.8(4) . . ?
P2 C7 H7A 108.3 . . ?
P2 C7 H7B 108.3 . . ?
H7A C7 H7B 107.4 . . ?
C9 C8 P1 120.7(3) . . ?
C9 C8 C13 120.0 . . ?
C13 C8 P1 119.2(3) . . ?
C8 C9 H9 120.0 . . ?
C8 C9 C10 120.0 . . ?
C10 C9 H9 120.0 . . ?
C9 C10 H10 120.0 . . ?
C11 C10 C9 120.0 . . ?
C11 C10 H10 120.0 . . ?
C10 C11 H11 120.0 . . ?
C12 C11 C10 120.0 . . ?
C12 C11 H11 120.0 . . ?
C11 C12 H12 120.0 . . ?
C11 C12 C13 120.0 . . ?
C13 C12 H12 120.0 . . ?
C8 C13 H13 120.0 . . ?
C12 C13 C8 120.0 . . ?
C12 C13 H13 120.0 . . ?
C15 C14 H14 120.0 . . ?
C15 C14 C19 120.0 . . ?
C19 C14 H14 120.0 . . ?
C14 C15 H15 120.0 . . ?
C16 C15 C14 120.0 . . ?
C16 C15 H15 120.0 . . ?
C15 C16 H16 120.0 . . ?
C17 C16 C15 120.0 . . ?
C17 C16 H16 120.0 . . ?
C16 C17 H17 120.0 . . ?
C18 C17 C16 120.0 . . ?
C18 C17 H17 120.0 . . ?
C17 C18 H18 120.0 . . ?
C17 C18 C19 120.0 . . ?
C19 C18 H18 120.0 . . ?
C14 C19 P2 119.3(3) . . ?
C18 C19 P2 120.7(3) . . ?
C18 C19 C14 120.0 . . ?
C21 C20 P2 116.5(3) . . ?
C21 C20 C25 120.0 . . ?
C25 C20 P2 123.5(3) . . ?
C20 C21 H21 120.0 . . ?
C20 C21 C22 120.0 . . ?
C22 C21 H21 120.0 . . ?
C21 C22 H22 120.0 . . ?
C23 C22 C21 120.0 . . ?
C23 C22 H22 120.0 . . ?
C22 C23 H23 120.0 . . ?
C22 C23 C24 120.0 . . ?
C24 C23 H23 120.0 . . ?
C23 C24 H24 120.0 . . ?
C25 C24 C23 120.0 . . ?
C25 C24 H24 120.0 . . ?
C20 C25 H25 120.0 . . ?
C24 C25 C20 120.0 . . ?
C24 C25 H25 120.0 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Au3 P1 C6 C1 37.0(3) . . . . ?
Au3 P1 C6 C5 -148.8(2) . . . . ?
Au3 P1 C7 P2 40.3(4) . . . . ?
Au3 P1 C8 C9 -163.3(3) . . . . ?
Au3 P1 C8 C13 13.2(4) . . . . ?
Au2 P2 C7 P1 -49.0(4) 3_665 . . . ?
Au2 P2 C19 C14 38.0(4) 3_665 . . . ?
Au2 P2 C19 C18 -142.9(3) 3_665 . . . ?
Au2 P2 C20 C21 33.1(4) 3_665 . . . ?
Au2 P2 C20 C25 -145.3(3) 3_665 . . . ?
P1 C8 C9 C10 176.5(4) . . . . ?
P1 C8 C13 C12 -176.6(4) . . . . ?
P2 C20 C21 C22 -178.5(4) . . . . ?
P2 C20 C25 C24 178.4(5) . . . . ?
C1 C2 C3 C4 0.0 . . . . ?
C2 C1 C6 P1 174.4(4) . . . . ?
C2 C1 C6 C5 0.0 . . . . ?
C2 C3 C4 C5 0.0 . . . . ?
C3 C4 C5 C6 0.0 . . . . ?
C4 C5 C6 P1 -174.0(4) . . . . ?
C4 C5 C6 C1 0.0 . . . . ?
C6 P1 C7 P2 -83.8(4) . . . . ?
C6 P1 C8 C9 -36.4(4) . . . . ?
C6 P1 C8 C13 140.2(3) . . . . ?
C6 C1 C2 C3 0.0 . . . . ?
C7 P1 C6 C1 157.2(3) . . . . ?
C7 P1 C6 C5 -28.6(4) . . . . ?
C7 P1 C8 C9 76.6(4) . . . . ?
C7 P1 C8 C13 -106.9(4) . . . . ?
C7 P2 C19 C14 -89.3(4) . . . . ?
C7 P2 C19 C18 89.8(4) . . . . ?
C7 P2 C20 C21 160.5(4) . . . . ?
C7 P2 C20 C25 -17.9(5) . . . . ?
C8 P1 C6 C1 -91.5(3) . . . . ?
C8 P1 C6 C5 82.7(3) . . . . ?
C8 P1 C7 P2 166.2(3) . . . . ?
C8 C9 C10 C11 0.0 . . . . ?
C9 C8 C13 C12 0.0 . . . . ?
C9 C10 C11 C12 0.0 . . . . ?
C10 C11 C12 C13 0.0 . . . . ?
C11 C12 C13 C8 0.0 . . . . ?
C13 C8 C9 C10 0.0 . . . . ?
C14 C15 C16 C17 0.0 . . . . ?
C15 C14 C19 P2 179.1(4) . . . . ?
C15 C14 C19 C18 0.0 . . . . ?
C15 C16 C17 C18 0.0 . . . . ?
C16 C17 C18 C19 0.0 . . . . ?
C17 C18 C19 P2 -179.1(4) . . . . ?
C17 C18 C19 C14 0.0 . . . . ?
C19 P2 C7 P1 76.2(4) . . . . ?
C19 P2 C20 C21 -91.2(4) . . . . ?
C19 P2 C20 C25 90.4(4) . . . . ?
C19 C14 C15 C16 0.0 . . . . ?
C20 P2 C7 P1 -173.7(3) . . . . ?
C20 P2 C19 C14 161.7(3) . . . . ?
C20 P2 C19 C18 -19.1(4) . . . . ?
C20 C21 C22 C23 0.0 . . . . ?
C21 C20 C25 C24 0.0 . . . . ?
C21 C22 C23 C24 0.0 . . . . ?
C22 C23 C24 C25 0.0 . . . . ?
C23 C24 C25 C20 0.0 . . . . ?
C25 C20 C21 C22 0.0 . . . . ?

_smtbx_masks_special_details     
;
A solvent mask was calculated and 853 electrons were 
found in a volume of 3121Å³ in 1 void per unit cell. 
This is consistent with the presence of 43[H2O] per Formula Unit 
which account for 860 electrons per unit cell.
;
loop_
_smtbx_masks_void_nr
_smtbx_masks_void_average_x
_smtbx_masks_void_average_y
_smtbx_masks_void_average_z
_smtbx_masks_void_volume
_smtbx_masks_void_count_electrons
_smtbx_masks_void_content
1 -0.887 -0.714 -0.752 3121.2 853.4 '86 H2O'

_smtbx_masks_void_probe_radius   1.2
_smtbx_masks_void_truncation_radius 1.2
_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_au13ag12-cl
_database_code_depnum_ccdc_archive 'CCDC 2163571'
loop_
_audit_author_name
_audit_author_address
'Xi Xi Kang'
;Anhui University
China
;
_audit_update_record             
;
2022-09-21 deposited with the CCDC.	2022-09-23 downloaded from the CCDC.
;
_audit_creation_date             2022-09-16
_audit_creation_method           
;
Olex2 1.5-dev
(compiled 2022.07.25 svn.r36e0af09 for OlexSys, GUI svn.r6444)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         
'C180 H150 Ag10.35 Au12.65 Cl6 P10, 2(Ag Cl), 4(Cl), 38[H2O], 1[H2O]'
_chemical_formula_sum            'C180 H228 Ag12.35 Au12.65 Cl12 O39 P10'
_chemical_formula_weight         7574.53
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag 0.1306 4.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -4.4197 7.2980 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'I 1 2/a 1'
_space_group_name_Hall           '-I 2ya'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y, -z'
'x+1/2, y+1/2, z+1/2'
'-x+1, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y, z'
'-x+1/2, -y+1/2, -z+1/2'
'x, -y+1/2, z+1/2'

_cell_length_a                   35.4973(10)
_cell_length_b                   16.6627(3)
_cell_length_c                   38.4422(12)
_cell_angle_alpha                90
_cell_angle_beta                 103.135(2)
_cell_angle_gamma                90
_cell_volume                     22142.9(10)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    21321
_cell_measurement_temperature    120
_cell_measurement_theta_max      70.01
_cell_measurement_theta_min      6.11
_shelx_estimated_absorpt_T_max   0.049
_shelx_estimated_absorpt_T_min   0.018
_exptl_absorpt_coefficient_mu    26.373
_exptl_absorpt_correction_T_max  0.1563
_exptl_absorpt_correction_T_min  0.0054
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
STOE X-Red32, absorption correction by Gaussian integration, analogous to
P. Coppens, "The Evaluation of Absorption and Extinction in Single-Crystal
Structure Analysis", published in: F. R. Ahmed (Editor), "Crystallographic
Computing", Munksgaard, Copenhagen (1970), 255 - 270.
Afterwards scaling of reflection intensities was performed within STOE LANA.
J. Koziskova, F. Hahn, J. Richter, J. Kozisek, "Comparison of different
absorption corrections on the model structure of tetrakis(μ₂-acetato)-
diaqua-di-copper(II)", Acta Chimica Slovaca, vol. 9, no. 2, 2016, pp. 136 - 140.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            black
_exptl_crystal_colour_primary    black
_exptl_crystal_density_diffrn    2.272
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             14215
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
1 0 30 0.1403
2 -1 -1 0.0768
-11 15 -1 0.0571
-30 -6 25 0.1350
30 -2 3 0.1140
-30 11 14 0.0822
-11 4 -30 0.1301
2 -10 1 0.0776
5 1 -4 0.1334
30 -17 -1 0.0612
-6 -3 1 0.1304
-3 -2 5 0.1360
-10 10 -1 0.0502

_exptl_crystal_size_max          0.75
_exptl_crystal_size_mid          0.44
_exptl_crystal_size_min          0.29
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0689
_diffrn_reflns_av_unetI/netI     0.0758
_diffrn_reflns_Laue_measured_fraction_full 0.971
_diffrn_reflns_Laue_measured_fraction_max 0.971
_diffrn_reflns_limit_h_max       36
_diffrn_reflns_limit_h_min       -40
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       40
_diffrn_reflns_limit_l_min       -44
_diffrn_reflns_number            41275
_diffrn_reflns_point_group_measured_fraction_full 0.971
_diffrn_reflns_point_group_measured_fraction_max 0.971
_diffrn_reflns_theta_full        62.500
_diffrn_reflns_theta_max         62.500
_diffrn_reflns_theta_min         6.109
_diffrn_ambient_temperature      120.00
_diffrn_detector_area_resol_mean 5.81
_diffrn_detector_type            'DECTRIS PILATUS 300K'
_diffrn_measured_fraction_theta_full 0.971
_diffrn_measured_fraction_theta_max 0.971
_diffrn_measurement_details      '999 frames, detector distance = 60 mm'
_diffrn_measurement_device       'Eulerian 4-circle diffractometer'
_diffrn_measurement_device_type  'STOE STADIVARI'
_diffrn_measurement_method       'rotation method, ω scans'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54186
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                11608
_reflns_number_total             17136
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       
;
X-Area Recipe 1.33.0.0 (STOE, 2015)
;
_computing_data_collection       
;
X-Area Pilatus3_SV 1.31.153.0 (STOE, 2018)
;
_computing_data_reduction        
;
X-Area Integrate 1.74.2.0 (STOE, 2018)
X-Area LANA 1.75.3.0 (STOE, 2018)
;
_computing_molecular_graphics    'Olex2 1.5-dev (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5-dev (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         4.226
_refine_diff_density_min         -6.592
_refine_diff_density_rms         0.445
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.992
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     861
_refine_ls_number_reflns         17136
_refine_ls_number_restraints     1128
_refine_ls_R_factor_all          0.1167
_refine_ls_R_factor_gt           0.0941
_refine_ls_restrained_S_all      0.973
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1941P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2431
_refine_ls_wR_factor_ref         0.2664
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
2. Shared sites
{Au1A, Ag1B}
3. Uiso/Uaniso restraints and constraints
C00R \\sim C00Q \\sim C00W \\sim C01B \\sim C01V \\sim C01L \\sim C00T \\sim
C59 \\sim C64 \\sim C1 \\sim C51 \\sim C2 \\sim C00V \\sim C01C \\sim C111
\\sim C027 \\sim C163 \\sim C87 \\sim C00X \\sim C63 \\sim C46 \\sim C23 \\sim
C81 \\sim C53 \\sim C00Y \\sim C019 \\sim C01H \\sim C01S \\sim C5 \\sim C024
\\sim C00Z \\sim C6 \\sim C42 \\sim C01E \\sim C023 \\sim C011 \\sim C012 \\sim
C02E \\sim C01O \\sim C01J \\sim C7 \\sim C017 \\sim C01D \\sim C60 \\sim C49
\\sim C01N \\sim C01G \\sim C02B \\sim C01F \\sim C16 \\sim C27 \\sim C3 \\sim
C02C \\sim C010 \\sim C01P \\sim C50 \\sim C28 \\sim C30 \\sim C43 \\sim C01X
\\sim C01Q \\sim C32 \\sim C4 \\sim C29 \\sim C74 \\sim C33 \\sim C44 \\sim C36
\\sim C020 \\sim C014 \\sim C24 \\sim C47 \\sim C21 \\sim C31 \\sim C55 \\sim
C96 \\sim C10 \\sim C028 \\sim C11 \\sim C14 \\sim C13 \\sim C58 \\sim C41
\\sim C12 \\sim C75 \\sim C025 \\sim C129 \\sim C9 \\sim C8 \\sim C01T: within
2A with sigma of 0.01 and sigma for terminal atoms of 0.02 within 2A
Cl3 \\sim Cl6 \\sim Cl5 \\sim Cl4: within 3.8A with sigma of 0.01 and sigma for
terminal atoms of 0.02 within 3.8A
Uanis(C00R) \\sim Ueq, Uanis(C00Q) \\sim Ueq, Uanis(C00W) \\sim Ueq,
Uanis(C01B) \\sim Ueq, Uanis(C01V) \\sim Ueq, Uanis(C01L) \\sim Ueq,
Uanis(C00T) \\sim Ueq, Uanis(C59) \\sim Ueq, Uanis(C64) \\sim Ueq, Uanis(C1)
\\sim Ueq, Uanis(C51) \\sim Ueq, Uanis(C2) \\sim Ueq, Uanis(C00V) \\sim Ueq,
Uanis(C01C) \\sim Ueq, Uanis(C111) \\sim Ueq, Uanis(C027) \\sim Ueq,
Uanis(C163) \\sim Ueq, Uanis(C87) \\sim Ueq, Uanis(C00X) \\sim Ueq, Uanis(C63)
\\sim Ueq, Uanis(C46) \\sim Ueq, Uanis(C23) \\sim Ueq, Uanis(C81) \\sim Ueq,
Uanis(C53) \\sim Ueq, Uanis(C00Y) \\sim Ueq, Uanis(C019) \\sim Ueq, Uanis(C01H)
\\sim Ueq, Uanis(C01S) \\sim Ueq, Uanis(C5) \\sim Ueq, Uanis(C024) \\sim Ueq,
Uanis(C00Z) \\sim Ueq, Uanis(C6) \\sim Ueq, Uanis(C42) \\sim Ueq, Uanis(C01E)
\\sim Ueq, Uanis(C023) \\sim Ueq, Uanis(C011) \\sim Ueq, Uanis(C012) \\sim Ueq,
Uanis(C02E) \\sim Ueq, Uanis(C01O) \\sim Ueq, Uanis(C01J) \\sim Ueq, Uanis(C7)
\\sim Ueq, Uanis(C017) \\sim Ueq, Uanis(C01D) \\sim Ueq, Uanis(C60) \\sim Ueq,
Uanis(C49) \\sim Ueq, Uanis(C01N) \\sim Ueq, Uanis(C01G) \\sim Ueq, Uanis(C02B)
\\sim Ueq, Uanis(C01F) \\sim Ueq, Uanis(C16) \\sim Ueq, Uanis(C27) \\sim Ueq,
Uanis(C3) \\sim Ueq, Uanis(C02C) \\sim Ueq, Uanis(C010) \\sim Ueq, Uanis(C01P)
\\sim Ueq, Uanis(C50) \\sim Ueq, Uanis(C28) \\sim Ueq, Uanis(C30) \\sim Ueq,
Uanis(C43) \\sim Ueq, Uanis(C01X) \\sim Ueq, Uanis(C01Q) \\sim Ueq, Uanis(C32)
\\sim Ueq, Uanis(C4) \\sim Ueq, Uanis(C29) \\sim Ueq, Uanis(C74) \\sim Ueq,
Uanis(C33) \\sim Ueq, Uanis(C44) \\sim Ueq, Uanis(C36) \\sim Ueq, Uanis(C020)
\\sim Ueq, Uanis(C014) \\sim Ueq, Uanis(C24) \\sim Ueq, Uanis(C47) \\sim Ueq,
Uanis(C21) \\sim Ueq, Uanis(C31) \\sim Ueq, Uanis(C55) \\sim Ueq, Uanis(C96)
\\sim Ueq, Uanis(C10) \\sim Ueq, Uanis(C028) \\sim Ueq, Uanis(C11) \\sim Ueq,
Uanis(C14) \\sim Ueq, Uanis(C13) \\sim Ueq, Uanis(C58) \\sim Ueq, Uanis(C41)
\\sim Ueq, Uanis(C12) \\sim Ueq, Uanis(C75) \\sim Ueq, Uanis(C025) \\sim Ueq,
Uanis(C129) \\sim Ueq, Uanis(C9) \\sim Ueq, Uanis(C8) \\sim Ueq, Uanis(C01T)
\\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(Cl5) \\sim Ueq, Uanis(Cl4) \\sim Ueq, Uanis(Cl3) \\sim Ueq, Uanis(Cl6)
\\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(Au1A) = Uanis(Ag1B)
4. Others
 Fixed Sof: Cl3(0.5) Cl4(0.5) Ag1B(0.175) Au1A(0.325) Cl5(0.5) Cl6(0.5)
5.a Aromatic/amide H refined with riding coordinates:
 C00Q(H00Q), C00W(H00W), C01B(H01B), C01V(H01V), C01L(H01L), C59(H59),
 C64(H64), C1(H1), C51(H51), C2(H2), C01C(H01C), C111(H111), C027(H027),
 C163(H163), C87(H87), C63(H63), C46(H46), C23(H23), C81(H81), C53(H53),
 C019(H019), C01H(H01H), C01S(H01S), C5(H5), C024(H024), C6(H6), C42(H42),
 C01E(H01E), C023(H023), C011(H011), C02E(H02E), C01O(H01O), C01J(H01J), C7(H7),
  C017(H017), C60(H60), C49(H49), C01N(H01N), C01G(H01G), C02B(H02B), C16(H16),
 C27(H27), C3(H3), C02C(H02C), C010(H010), C50(H50), C28(H28), C30(H30),
 C43(H43), C01X(H01X), C32(H32), C4(H4), C29(H29), C74(H74), C33(H33), C44(H44),
  C36(H36), C020(H020), C24(H24), C47(H47), C21(H21), C31(H31), C55(H55),
 C96(H96), C10(H10), C14(H14), C13(H13), C58(H58), C41(H41), C12(H12),
 C025(H025), C129(H129), C9(H9), C8(H8), C01T(H01T)
5.b Fitted hexagon refined as free rotating group:
 C00R(C00Q,C00W,C01B,C01V,C01L), C00T(C59,C64,C1,C51,C2), C00V(C01C,C111,C027,
 C163,C87), C00X(C63,C46,C23,C81,C53), C00Y(C019,C01H,C01S,C5,C024), C00Z(C6,
 C42,C01E,C023,C011), C012(C02E,C01O,C01J,C7,C017), C01D(C60,C49,C01N,C01G,
 C02B), C01F(C16,C27,C3,C02C,C010), C01P(C50,C28,C30,C43,C01X), C01Q(C32,C4,C29,
 C74,C33), C44(C36,C020,C014,C24,C47), C21(C31,C55,C96,C10,C028), C11(C14,C13,
 C58,C41,C12), C75(C025,C129,C9,C8,C01T)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au01 Au 0.62620(2) 0.15147(4) 0.45567(2) 0.0389(2) Uani 1 1 d . . . . .
Au02 Au 0.68519(2) 0.24065(4) 0.44464(2) 0.0359(2) Uani 1 1 d . . . . .
Au03 Au 0.67107(2) 0.10520(4) 0.40457(2) 0.0388(2) Uani 1 1 d . . . . .
Au04 Au 0.70265(3) 0.24851(4) 0.38055(2) 0.0442(2) Uani 1 1 d . . . . .
Au05 Au 0.62609(3) 0.32543(4) 0.46041(3) 0.0451(3) Uani 1 1 d . . . . .
Au06 Au 0.67465(3) 0.38679(5) 0.41280(3) 0.0503(3) Uani 1 1 d . . . . .
Ag08 Ag 0.67530(4) 0.22920(8) 0.51572(4) 0.0425(4) Uani 1 1 d . . . . .
Ag09 Ag 0.74840(4) 0.15184(8) 0.56457(4) 0.0422(3) Uani 1 1 d . . . . .
Ag0A Ag 0.70456(4) 0.09215(7) 0.48198(4) 0.0415(3) Uani 1 1 d . . . . .
Ag0C Ag 0.75312(5) 0.33031(8) 0.43816(4) 0.0481(4) Uani 1 1 d . . . . .
Ag0D Ag 0.70451(5) 0.37576(8) 0.48899(4) 0.0468(4) Uani 1 1 d . . . . .
P0E P 0.65531(17) -0.0008(3) 0.36548(15) 0.0440(12) Uani 1 1 d . . . . .
P0F P 0.57749(15) 0.0787(2) 0.47044(15) 0.0409(12) Uani 1 1 d . . . . .
P0G P 0.57611(17) 0.3972(3) 0.47465(17) 0.0501(14) Uani 1 1 d . . . . .
P0H P 0.71978(19) 0.2519(3) 0.32692(15) 0.0484(13) Uani 1 1 d . . . . .
Cl1 Cl 0.5622(2) 0.2590(4) 0.34293(18) 0.0663(15) Uani 1 1 d . . . . .
Cl2 Cl 0.78827(18) 0.4610(3) 0.45729(18) 0.0676(17) Uani 1 1 d . . . . .
P0K P 0.6645(2) 0.5149(3) 0.38927(19) 0.0621(17) Uani 1 1 d . . . . .
Cl3 Cl 0.6853(6) 0.2217(11) 0.5813(5) 0.080(3) Uani 0.5 1 d . U P A 2
Cl4 Cl 0.7090(6) 0.0220(12) 0.5382(5) 0.099(4) Uani 0.5 1 d . U P A 2
C00R C 0.5598(4) 0.1317(8) 0.5055(3) 0.047(3) Uani 1 1 d G U . . .
C00Q C 0.5219(3) 0.1578(8) 0.5015(3) 0.050(3) Uani 1 1 d G U . . .
H00Q H 0.503765 0.150413 0.479398 0.060 Uiso 1 1 calc R U . . .
C00W C 0.5105(3) 0.1948(8) 0.5298(4) 0.054(4) Uani 1 1 d G U . . .
H00W H 0.484529 0.212721 0.527098 0.064 Uiso 1 1 calc R U . . .
C01B C 0.5370(4) 0.2057(9) 0.5622(3) 0.058(4) Uani 1 1 d G U . . .
H01B H 0.529143 0.230990 0.581548 0.070 Uiso 1 1 calc R U . . .
C01V C 0.5749(4) 0.1795(9) 0.5662(3) 0.060(4) Uani 1 1 d G U . . .
H01V H 0.592993 0.186952 0.588300 0.072 Uiso 1 1 calc R U . . .
C01L C 0.5863(3) 0.1425(8) 0.5379(4) 0.056(4) Uani 1 1 d G U . . .
H01L H 0.612230 0.124645 0.540601 0.067 Uiso 1 1 calc R U . . .
C00T C 0.6151(5) -0.0597(12) 0.3741(6) 0.082(5) Uani 1 1 d G U . . .
C59 C 0.5766(6) -0.0397(11) 0.3601(5) 0.094(5) Uani 1 1 d G U . . .
H59 H 0.570308 0.006786 0.345671 0.113 Uiso 1 1 calc R U . . .
C64 C 0.5473(5) -0.0878(13) 0.3673(6) 0.098(5) Uani 1 1 d G U . . .
H64 H 0.520969 -0.074166 0.357801 0.117 Uiso 1 1 calc R U . . .
C1 C 0.5565(5) -0.1558(12) 0.3885(6) 0.093(5) Uani 1 1 d G U . . .
H1 H 0.536431 -0.188694 0.393411 0.112 Uiso 1 1 calc R U . . .
C51 C 0.5950(6) -0.1758(11) 0.4024(6) 0.103(6) Uani 1 1 d G U . . .
H51 H 0.601234 -0.222273 0.416891 0.123 Uiso 1 1 calc R U . . .
C2 C 0.6243(5) -0.1277(13) 0.3952(6) 0.102(5) Uani 1 1 d G U . . .
H2 H 0.650574 -0.141322 0.404762 0.122 Uiso 1 1 calc R U . . .
C00V C 0.5919(5) -0.0181(8) 0.4891(4) 0.061(4) Uani 1 1 d G U . . .
C01C C 0.5740(4) -0.0539(9) 0.5138(4) 0.063(4) Uani 1 1 d G U . . .
H01C H 0.552066 -0.029169 0.519570 0.076 Uiso 1 1 calc R U . . .
C111 C 0.5881(5) -0.1257(10) 0.5300(4) 0.077(5) Uani 1 1 d G U . . .
H111 H 0.575886 -0.150134 0.546867 0.092 Uiso 1 1 calc R U . . .
C027 C 0.6202(5) -0.1619(8) 0.5216(5) 0.082(5) Uani 1 1 d G U . . .
H027 H 0.629874 -0.210969 0.532642 0.098 Uiso 1 1 calc R U . . .
C163 C 0.6381(4) -0.1261(10) 0.4969(5) 0.081(5) Uani 1 1 d G U . . .
H163 H 0.660042 -0.150838 0.491119 0.097 Uiso 1 1 calc R U . . .
C87 C 0.6240(5) -0.0543(10) 0.4807(4) 0.072(4) Uani 1 1 d G U . . .
H87 H 0.636223 -0.029873 0.463821 0.087 Uiso 1 1 calc R U . . .
C00X C 0.5747(6) 0.5037(9) 0.4635(6) 0.076(5) Uani 1 1 d G U . . .
C63 C 0.6053(5) 0.5499(12) 0.4822(5) 0.089(5) Uani 1 1 d G U . . .
H63 H 0.627149 0.524720 0.497025 0.107 Uiso 1 1 calc R U . . .
C46 C 0.6040(5) 0.6330(12) 0.4790(5) 0.095(5) Uani 1 1 d G U . . .
H46 H 0.624894 0.664632 0.491726 0.114 Uiso 1 1 calc R U . . .
C23 C 0.5720(6) 0.6699(9) 0.4572(6) 0.094(5) Uani 1 1 d G U . . .
H23 H 0.571123 0.726725 0.455088 0.113 Uiso 1 1 calc R U . . .
C81 C 0.5414(5) 0.6237(12) 0.4386(5) 0.095(5) Uani 1 1 d G U . . .
H81 H 0.519607 0.648906 0.423748 0.113 Uiso 1 1 calc R U . . .
C53 C 0.5428(5) 0.5406(12) 0.4418(5) 0.090(5) Uani 1 1 d G U . . .
H53 H 0.521861 0.508993 0.429047 0.107 Uiso 1 1 calc R U . . .
C00Y C 0.6840(4) 0.3039(9) 0.2928(3) 0.055(4) Uani 1 1 d G U . . .
C019 C 0.6949(3) 0.3400(9) 0.2639(4) 0.057(4) Uani 1 1 d G U . . .
H019 H 0.720843 0.336168 0.261533 0.068 Uiso 1 1 calc R U . . .
C01H C 0.6677(4) 0.3816(9) 0.2386(3) 0.062(4) Uani 1 1 d G U . . .
H01H H 0.675088 0.406247 0.218923 0.075 Uiso 1 1 calc R U . . .
C01S C 0.6297(4) 0.3872(9) 0.2422(4) 0.070(4) Uani 1 1 d G U . . .
H01S H 0.611077 0.415649 0.224865 0.084 Uiso 1 1 calc R U . . .
C5 C 0.6188(3) 0.3512(10) 0.2710(4) 0.074(4) Uani 1 1 d G U . . .
H5 H 0.592822 0.354972 0.273418 0.089 Uiso 1 1 calc R U . . .
C024 C 0.6460(4) 0.3095(9) 0.2963(4) 0.065(4) Uani 1 1 d G U . . .
H024 H 0.638577 0.284892 0.316029 0.078 Uiso 1 1 calc R U . . .
C00Z C 0.7276(4) 0.1532(7) 0.3094(4) 0.054(4) Uani 1 1 d G U . . .
C6 C 0.7486(4) 0.0985(9) 0.3335(3) 0.057(4) Uani 1 1 d G U . . .
H6 H 0.756535 0.112159 0.358105 0.069 Uiso 1 1 calc R U . . .
C42 C 0.7579(4) 0.0239(8) 0.3217(4) 0.063(4) Uani 1 1 d G U . . .
H42 H 0.772249 -0.013512 0.338200 0.075 Uiso 1 1 calc R U . . .
C01E C 0.7463(5) 0.0039(7) 0.2858(4) 0.064(4) Uani 1 1 d G U . . .
H01E H 0.752636 -0.047099 0.277674 0.077 Uiso 1 1 calc R U . . .
C023 C 0.7253(5) 0.0586(9) 0.2616(3) 0.064(4) Uani 1 1 d G U . . .
H023 H 0.717308 0.044986 0.237051 0.076 Uiso 1 1 calc R U . . .
C011 C 0.7159(4) 0.1333(8) 0.2734(3) 0.058(4) Uani 1 1 d G U . . .
H011 H 0.701594 0.170658 0.256955 0.069 Uiso 1 1 calc R U . . .
C012 C 0.7656(4) 0.3033(9) 0.3281(4) 0.055(4) Uani 1 1 d G U . . .
C02E C 0.7953(5) 0.2660(7) 0.3161(4) 0.065(4) Uani 1 1 d G U . . .
H02E H 0.792289 0.212435 0.307505 0.078 Uiso 1 1 calc R U . . .
C01O C 0.8295(4) 0.3072(9) 0.3167(4) 0.069(4) Uani 1 1 d G U . . .
H01O H 0.849867 0.281732 0.308533 0.083 Uiso 1 1 calc R U . . .
C01J C 0.8340(4) 0.3856(9) 0.3293(4) 0.066(4) Uani 1 1 d G U . . .
H01J H 0.857382 0.413781 0.329693 0.080 Uiso 1 1 calc R U . . .
C7 C 0.8043(5) 0.4229(7) 0.3412(4) 0.069(4) Uani 1 1 d G U . . .
H7 H 0.807320 0.476534 0.349827 0.083 Uiso 1 1 calc R U . . .
C017 C 0.7701(4) 0.3818(9) 0.3406(4) 0.061(4) Uani 1 1 d G U . . .
H017 H 0.749741 0.407238 0.348800 0.073 Uiso 1 1 calc R U . . .
C01D C 0.5301(4) 0.3578(11) 0.4541(5) 0.072(4) Uani 1 1 d G U . . .
C60 C 0.5247(5) 0.3316(12) 0.4190(5) 0.084(5) Uani 1 1 d G U . . .
H60 H 0.545502 0.334131 0.407218 0.101 Uiso 1 1 calc R U . . .
C49 C 0.4890(6) 0.3016(12) 0.4012(4) 0.090(5) Uani 1 1 d G U . . .
H49 H 0.485376 0.283651 0.377190 0.108 Uiso 1 1 calc R U . . .
C01N C 0.4587(4) 0.2978(12) 0.4185(5) 0.081(5) Uani 1 1 d G U . . .
H01N H 0.434249 0.277344 0.406262 0.098 Uiso 1 1 calc R U . . .
C01G C 0.4640(4) 0.3241(11) 0.4536(5) 0.079(5) Uani 1 1 d G U . . .
H01G H 0.443248 0.321516 0.465362 0.094 Uiso 1 1 calc R U . . .
C02B C 0.4997(5) 0.3541(11) 0.4714(4) 0.077(5) Uani 1 1 d G U . . .
H02B H 0.503375 0.371995 0.495390 0.092 Uiso 1 1 calc R U . . .
C01F C 0.6931(4) -0.0754(9) 0.3673(4) 0.059(4) Uani 1 1 d G U . . .
C16 C 0.6878(4) -0.1403(10) 0.3440(4) 0.069(4) Uani 1 1 d G U . . .
H16 H 0.664164 -0.146133 0.326645 0.083 Uiso 1 1 calc R U . . .
C27 C 0.7171(5) -0.1966(9) 0.3459(4) 0.074(4) Uani 1 1 d G U . . .
H27 H 0.713492 -0.240934 0.329987 0.089 Uiso 1 1 calc R U . . .
C3 C 0.7517(4) -0.1881(9) 0.3713(5) 0.075(5) Uani 1 1 d G U . . .
H3 H 0.771702 -0.226564 0.372640 0.091 Uiso 1 1 calc R U . . .
C02C C 0.7570(4) -0.1232(10) 0.3946(4) 0.071(4) Uani 1 1 d G U . . .
H02C H 0.780585 -0.117393 0.411949 0.086 Uiso 1 1 calc R U . . .
C010 C 0.7277(5) -0.0669(8) 0.3926(4) 0.063(4) Uani 1 1 d G U . . .
H010 H 0.731257 -0.022590 0.408608 0.076 Uiso 1 1 calc R U . . .
C01P C 0.5791(6) 0.4078(12) 0.5225(4) 0.076(5) Uani 1 1 d G U . . .
C50 C 0.5543(5) 0.4583(11) 0.5355(5) 0.082(5) Uani 1 1 d G U . . .
H50 H 0.535374 0.488624 0.519316 0.098 Uiso 1 1 calc R U . . .
C28 C 0.5571(5) 0.4643(11) 0.5720(5) 0.088(5) Uani 1 1 d G U . . .
H28 H 0.540111 0.498812 0.580870 0.105 Uiso 1 1 calc R U . . .
C30 C 0.5848(6) 0.4199(12) 0.5957(4) 0.088(5) Uani 1 1 d G U . . .
H30 H 0.586686 0.424036 0.620652 0.106 Uiso 1 1 calc R U . . .
C43 C 0.6096(5) 0.3694(11) 0.5827(5) 0.086(5) Uani 1 1 d G U . . .
H43 H 0.628527 0.339072 0.598881 0.103 Uiso 1 1 calc R U . . .
C01X C 0.6068(5) 0.3634(11) 0.5462(5) 0.080(5) Uani 1 1 d G U . . .
H01X H 0.623791 0.328884 0.537327 0.095 Uiso 1 1 calc R U . . .
C01Q C 0.6390(5) 0.0319(11) 0.3192(4) 0.074(5) Uani 1 1 d G U . . .
C32 C 0.6474(5) -0.0070(9) 0.2899(5) 0.079(5) Uani 1 1 d G U . . .
H32 H 0.664175 -0.052171 0.293399 0.095 Uiso 1 1 calc R U . . .
C4 C 0.6314(6) 0.0203(11) 0.2556(4) 0.081(5) Uani 1 1 d G U . . .
H4 H 0.637180 -0.006333 0.235570 0.097 Uiso 1 1 calc R U . . .
C29 C 0.6069(5) 0.0864(11) 0.2505(4) 0.082(5) Uani 1 1 d G U . . .
H29 H 0.595930 0.105012 0.227042 0.098 Uiso 1 1 calc R U . . .
C74 C 0.5984(5) 0.1253(10) 0.2798(5) 0.085(5) Uani 1 1 d G U . . .
H74 H 0.581674 0.170519 0.276345 0.102 Uiso 1 1 calc R U . . .
C33 C 0.6145(6) 0.0981(11) 0.3142(4) 0.083(5) Uani 1 1 d G U . . .
H33 H 0.608668 0.124682 0.334175 0.100 Uiso 1 1 calc R U . . .
C44 C 0.4701(5) 0.0470(12) 0.3791(4) 0.090(5) Uani 1 1 d G U . . .
H44 H 0.447782 0.041216 0.360250 0.109 Uiso 1 1 calc R U . . .
C36 C 0.4739(4) 0.0017(10) 0.4101(5) 0.080(5) Uani 1 1 d G U . . .
H36 H 0.454168 -0.035111 0.412361 0.097 Uiso 1 1 calc R U . . .
C020 C 0.5066(5) 0.0102(10) 0.4377(4) 0.068(4) Uani 1 1 d G U . . .
H020 H 0.509157 -0.020766 0.458848 0.081 Uiso 1 1 calc R U . . .
C014 C 0.5354(4) 0.0641(11) 0.4344(4) 0.064(4) Uani 1 1 d G U . . .
C24 C 0.5316(5) 0.1094(10) 0.4034(5) 0.079(5) Uani 1 1 d G U . . .
H24 H 0.551376 0.146233 0.401115 0.094 Uiso 1 1 calc R U . . .
C47 C 0.4990(6) 0.1009(11) 0.3758(4) 0.091(5) Uani 1 1 d G U . . .
H47 H 0.496387 0.131890 0.354627 0.109 Uiso 1 1 calc R U . . .
C21 C 0.6832(6) 0.6725(12) 0.4121(4) 0.083(5) Uani 1 1 d G U . . .
H21 H 0.677223 0.685983 0.387409 0.100 Uiso 1 1 calc R U . . .
C31 C 0.6954(7) 0.7317(9) 0.4376(6) 0.087(5) Uani 1 1 d G U . . .
H31 H 0.697750 0.785626 0.430435 0.104 Uiso 1 1 calc R U . . .
C55 C 0.7041(7) 0.7119(12) 0.4737(5) 0.100(5) Uani 1 1 d G U . . .
H55 H 0.712482 0.752330 0.491158 0.120 Uiso 1 1 calc R U . . .
C96 C 0.7007(7) 0.6329(14) 0.4842(4) 0.103(6) Uani 1 1 d G U . . .
H96 H 0.706687 0.619391 0.508856 0.124 Uiso 1 1 calc R U . . .
C10 C 0.6885(6) 0.5737(10) 0.4586(6) 0.093(5) Uani 1 1 d G U . . .
H10 H 0.686159 0.519747 0.465830 0.112 Uiso 1 1 calc R U . . .
C028 C 0.6798(6) 0.5935(11) 0.4226(5) 0.079(5) Uani 1 1 d G U . . .
C11 C 0.6144(6) 0.534(2) 0.3708(7) 0.127(7) Uani 1 1 d G U . . .
C14 C 0.5981(8) 0.6101(16) 0.3679(7) 0.132(7) Uani 1 1 d G U . . .
H14 H 0.613644 0.655348 0.376725 0.159 Uiso 1 1 calc R U . . .
C13 C 0.5591(9) 0.6201(14) 0.3520(8) 0.135(7) Uani 1 1 d G U . . .
H13 H 0.547990 0.672215 0.350054 0.162 Uiso 1 1 calc R U . . .
C58 C 0.5364(6) 0.554(2) 0.3391(7) 0.134(7) Uani 1 1 d G U . . .
H58 H 0.509780 0.560726 0.328277 0.160 Uiso 1 1 calc R U . . .
C41 C 0.5527(8) 0.4776(16) 0.3420(7) 0.134(7) Uani 1 1 d G U . . .
H41 H 0.537224 0.432367 0.333171 0.161 Uiso 1 1 calc R U . . .
C12 C 0.5917(9) 0.4676(14) 0.3579(8) 0.129(7) Uani 1 1 d G U . . .
H12 H 0.602877 0.415498 0.359842 0.154 Uiso 1 1 calc R U . . .
C75 C 0.6908(5) 0.5389(11) 0.3557(4) 0.072(4) Uani 1 1 d G U . . .
C025 C 0.7283(5) 0.5684(10) 0.3670(3) 0.068(4) Uani 1 1 d G U . . .
H025 H 0.739500 0.573926 0.391745 0.082 Uiso 1 1 calc R U . . .
C129 C 0.7492(4) 0.5897(10) 0.3419(5) 0.072(4) Uani 1 1 d G U . . .
H129 H 0.774827 0.609817 0.349620 0.086 Uiso 1 1 calc R U . . .
C9 C 0.7328(5) 0.5816(11) 0.3057(4) 0.079(5) Uani 1 1 d G U . . .
H9 H 0.747136 0.596150 0.288583 0.095 Uiso 1 1 calc R U . . .
C8 C 0.6954(5) 0.5521(11) 0.2944(3) 0.080(5) Uani 1 1 d G U . . .
H8 H 0.684117 0.546591 0.269669 0.096 Uiso 1 1 calc R U . . .
C01T C 0.6744(4) 0.5308(11) 0.3195(5) 0.079(5) Uani 1 1 d G U . . .
H01T H 0.648788 0.510699 0.311793 0.095 Uiso 1 1 calc R U . . .
Ag1B Ag 0.750000 0.23439(8) 0.500000 0.0461(4) Uani 0.35 2 d S T P A 1
Au1A Au 0.750000 0.23439(8) 0.500000 0.0461(4) Uani 0.65 2 d S T P A .
Ag1 Ag 0.62039(5) 0.24990(8) 0.38967(4) 0.0454(4) Uani 1 1 d . . . . .
Cl5 Cl 0.6952(3) 0.0537(8) 0.5482(3) 0.058(2) Uani 0.5 1 d . U P A 1
Cl6 Cl 0.6874(4) 0.2582(7) 0.5807(4) 0.054(2) Uani 0.5 1 d . U P A 1
Cl7 Cl 0.6781(5) 0.6625(7) 0.5696(3) 0.169(6) Uani 1 1 d . . . . .
Cl8 Cl 0.8615(4) 0.6073(7) 0.3778(4) 0.161(5) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au01 Au02 2.6787(9) . ?
Au01 Au03 2.9003(10) . ?
Au01 Au05 2.9044(10) . ?
Au01 Ag08 2.8663(18) . ?
Au01 P0F 2.286(4) . ?
Au02 Au03 2.7142(10) . ?
Au02 Au04 2.6770(10) . ?
Au02 Au05 2.7099(10) . ?
Au02 Au06 2.7128(10) . ?
Au03 Au04 2.8779(10) . ?
Au03 Ag09 2.9399(18) 2_656 ?
Au03 P0E 2.304(5) . ?
Au04 Au06 2.8974(11) . ?
Au04 Ag0C 2.8581(19) . ?
Au04 P0H 2.279(5) . ?
Au05 Ag08 2.9079(18) . ?
Au05 Ag0D 2.8758(19) . ?
Au05 P0G 2.306(5) . ?
Au06 Ag0C 2.8917(19) . ?
Au06 Ag0D 2.885(2) . ?
Au06 P0K 2.315(5) . ?
Ag08 Ag09 3.115(2) . ?
Ag08 Ag0A 2.9304(18) . ?
Ag08 Ag0C 3.223(2) 2_656 ?
Ag08 Ag0D 2.9290(18) . ?
Ag08 Cl3 2.468(19) . ?
Ag08 Au1A 2.8516(13) . ?
Ag08 Cl6 2.483(14) . ?
Ag09 Ag0A 3.353(2) . ?
Ag09 Ag0A 2.8877(18) 2_656 ?
Ag09 Ag0C 2.9756(19) 2_656 ?
Ag09 Cl3 2.73(2) . ?
Ag09 Cl4 2.650(19) . ?
Ag09 Au1A 2.8497(15) . ?
Ag09 Cl5 2.468(12) . ?
Ag0A Ag0A 3.208(3) 2_656 ?
Ag0A Cl4 2.430(18) . ?
Ag0A Au1A 2.8619(17) . ?
Ag0A Cl5 2.716(11) . ?
Ag0C Ag0D 2.961(2) 2_656 ?
Ag0C Ag0D 2.9837(19) . ?
Ag0C Cl2 2.534(6) . ?
Ag0C Au1A 2.8878(16) . ?
Ag0C Cl6 2.668(12) 2_656 ?
Ag0D Ag0D 3.147(3) 2_656 ?
Ag0D Cl2 2.471(6) 2_656 ?
Ag0D Au1A 2.8328(17) . ?
P0E C00T 1.824(15) . ?
P0E C01F 1.819(12) . ?
P0E C01Q 1.824(14) . ?
P0F C00R 1.837(10) . ?
P0F C00V 1.794(12) . ?
P0F C014 1.809(14) . ?
P0G C00X 1.824(15) . ?
P0G C01D 1.771(15) . ?
P0G C01P 1.828(14) . ?
P0H C00Y 1.824(12) . ?
P0H C00Z 1.822(11) . ?
P0H C012 1.830(12) . ?
Cl1 Ag1 2.415(7) . ?
P0K C028 1.826(16) . ?
P0K C11 1.78(2) . ?
P0K C75 1.802(13) . ?
C00R C00Q 1.3900 . ?
C00R C01L 1.3900 . ?
C00Q H00Q 0.9500 . ?
C00Q C00W 1.3900 . ?
C00W H00W 0.9500 . ?
C00W C01B 1.3900 . ?
C01B H01B 0.9500 . ?
C01B C01V 1.3900 . ?
C01V H01V 0.9500 . ?
C01V C01L 1.3900 . ?
C01L H01L 0.9500 . ?
C00T C59 1.3900 . ?
C00T C2 1.3900 . ?
C59 H59 0.9500 . ?
C59 C64 1.3900 . ?
C64 H64 0.9500 . ?
C64 C1 1.3900 . ?
C1 H1 0.9500 . ?
C1 C51 1.3900 . ?
C51 H51 0.9500 . ?
C51 C2 1.3900 . ?
C2 H2 0.9500 . ?
C00V C01C 1.3900 . ?
C00V C87 1.3900 . ?
C01C H01C 0.9500 . ?
C01C C111 1.3900 . ?
C111 H111 0.9500 . ?
C111 C027 1.3900 . ?
C027 H027 0.9500 . ?
C027 C163 1.3900 . ?
C163 H163 0.9500 . ?
C163 C87 1.3900 . ?
C87 H87 0.9500 . ?
C00X C63 1.3900 . ?
C00X C53 1.3900 . ?
C63 H63 0.9500 . ?
C63 C46 1.3900 . ?
C46 H46 0.9500 . ?
C46 C23 1.3900 . ?
C23 H23 0.9500 . ?
C23 C81 1.3900 . ?
C81 H81 0.9500 . ?
C81 C53 1.3900 . ?
C53 H53 0.9500 . ?
C00Y C019 1.3900 . ?
C00Y C024 1.3900 . ?
C019 H019 0.9500 . ?
C019 C01H 1.3900 . ?
C01H H01H 0.9500 . ?
C01H C01S 1.3900 . ?
C01S H01S 0.9500 . ?
C01S C5 1.3900 . ?
C5 H5 0.9500 . ?
C5 C024 1.3900 . ?
C024 H024 0.9500 . ?
C00Z C6 1.3900 . ?
C00Z C011 1.3900 . ?
C6 H6 0.9500 . ?
C6 C42 1.3900 . ?
C42 H42 0.9500 . ?
C42 C01E 1.3900 . ?
C01E H01E 0.9500 . ?
C01E C023 1.3900 . ?
C023 H023 0.9500 . ?
C023 C011 1.3900 . ?
C011 H011 0.9500 . ?
C012 C02E 1.3900 . ?
C012 C017 1.3900 . ?
C02E H02E 0.9500 . ?
C02E C01O 1.3900 . ?
C01O H01O 0.9500 . ?
C01O C01J 1.3900 . ?
C01J H01J 0.9500 . ?
C01J C7 1.3900 . ?
C7 H7 0.9500 . ?
C7 C017 1.3900 . ?
C017 H017 0.9500 . ?
C01D C60 1.3900 . ?
C01D C02B 1.3900 . ?
C60 H60 0.9500 . ?
C60 C49 1.3900 . ?
C49 H49 0.9500 . ?
C49 C01N 1.3900 . ?
C01N H01N 0.9500 . ?
C01N C01G 1.3900 . ?
C01G H01G 0.9500 . ?
C01G C02B 1.3900 . ?
C02B H02B 0.9500 . ?
C01F C16 1.3900 . ?
C01F C010 1.3900 . ?
C16 H16 0.9500 . ?
C16 C27 1.3900 . ?
C27 H27 0.9500 . ?
C27 C3 1.3900 . ?
C3 H3 0.9500 . ?
C3 C02C 1.3900 . ?
C02C H02C 0.9500 . ?
C02C C010 1.3900 . ?
C010 H010 0.9500 . ?
C01P C50 1.3900 . ?
C01P C01X 1.3900 . ?
C50 H50 0.9500 . ?
C50 C28 1.3900 . ?
C28 H28 0.9500 . ?
C28 C30 1.3900 . ?
C30 H30 0.9500 . ?
C30 C43 1.3900 . ?
C43 H43 0.9500 . ?
C43 C01X 1.3900 . ?
C01X H01X 0.9500 . ?
C01Q C32 1.3900 . ?
C01Q C33 1.3900 . ?
C32 H32 0.9500 . ?
C32 C4 1.3900 . ?
C4 H4 0.9500 . ?
C4 C29 1.3900 . ?
C29 H29 0.9500 . ?
C29 C74 1.3900 . ?
C74 H74 0.9500 . ?
C74 C33 1.3900 . ?
C33 H33 0.9500 . ?
C44 H44 0.9500 . ?
C44 C36 1.3900 . ?
C44 C47 1.3900 . ?
C36 H36 0.9500 . ?
C36 C020 1.3900 . ?
C020 H020 0.9500 . ?
C020 C014 1.3900 . ?
C014 C24 1.3900 . ?
C24 H24 0.9500 . ?
C24 C47 1.3900 . ?
C47 H47 0.9500 . ?
C21 H21 0.9500 . ?
C21 C31 1.3900 . ?
C21 C028 1.3900 . ?
C31 H31 0.9500 . ?
C31 C55 1.3900 . ?
C55 H55 0.9500 . ?
C55 C96 1.3900 . ?
C96 H96 0.9500 . ?
C96 C10 1.3900 . ?
C10 H10 0.9500 . ?
C10 C028 1.3900 . ?
C11 C14 1.3900 . ?
C11 C12 1.3900 . ?
C14 H14 0.9500 . ?
C14 C13 1.3900 . ?
C13 H13 0.9500 . ?
C13 C58 1.3900 . ?
C58 H58 0.9500 . ?
C58 C41 1.3900 . ?
C41 H41 0.9500 . ?
C41 C12 1.3900 . ?
C12 H12 0.9500 . ?
C75 C025 1.3900 . ?
C75 C01T 1.3900 . ?
C025 H025 0.9500 . ?
C025 C129 1.3900 . ?
C129 H129 0.9500 . ?
C129 C9 1.3900 . ?
C9 H9 0.9500 . ?
C9 C8 1.3900 . ?
C8 H8 0.9500 . ?
C8 C01T 1.3900 . ?
C01T H01T 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Au02 Au01 Au03 58.06(2) . . ?
Au02 Au01 Au05 57.90(2) . . ?
Au02 Au01 Ag08 61.49(3) . . ?
Au03 Au01 Au05 108.46(3) . . ?
Ag08 Au01 Au03 109.79(4) . . ?
Ag08 Au01 Au05 60.51(4) . . ?
P0F Au01 Au02 174.77(15) . . ?
P0F Au01 Au03 126.16(12) . . ?
P0F Au01 Au05 120.10(11) . . ?
P0F Au01 Ag08 113.28(15) . . ?
Au01 Au02 Au03 65.06(3) . . ?
Au01 Au02 Au05 65.23(3) . . ?
Au01 Au02 Au06 122.46(4) . . ?
Au04 Au02 Au01 121.71(4) . . ?
Au04 Au02 Au03 64.52(3) . . ?
Au04 Au02 Au05 122.24(4) . . ?
Au04 Au02 Au06 65.03(3) . . ?
Au05 Au02 Au03 120.53(4) . . ?
Au05 Au02 Au06 66.33(3) . . ?
Au06 Au02 Au03 120.11(4) . . ?
Au01 Au03 Ag09 106.84(4) . 2_656 ?
Au02 Au03 Au01 56.88(2) . . ?
Au02 Au03 Au04 57.11(3) . . ?
Au02 Au03 Ag09 60.91(3) . 2_656 ?
Au04 Au03 Au01 108.10(3) . . ?
Au04 Au03 Ag09 59.74(4) . 2_656 ?
P0E Au03 Au01 123.80(13) . . ?
P0E Au03 Au02 173.57(14) . . ?
P0E Au03 Au04 118.77(12) . . ?
P0E Au03 Ag09 122.39(14) . 2_656 ?
Au02 Au04 Au03 58.37(3) . . ?
Au02 Au04 Au06 58.08(3) . . ?
Au02 Au04 Ag0C 62.98(4) . . ?
Au03 Au04 Au06 109.02(3) . . ?
Ag0C Au04 Au03 111.62(4) . . ?
Ag0C Au04 Au06 60.31(4) . . ?
P0H Au04 Au02 177.56(16) . . ?
P0H Au04 Au03 120.96(13) . . ?
P0H Au04 Au06 123.74(13) . . ?
P0H Au04 Ag0C 116.11(16) . . ?
Au01 Au05 Ag08 59.09(4) . . ?
Au02 Au05 Au01 56.87(2) . . ?
Au02 Au05 Ag08 60.60(3) . . ?
Au02 Au05 Ag0D 60.40(4) . . ?
Ag0D Au05 Au01 107.45(4) . . ?
Ag0D Au05 Ag08 60.85(4) . . ?
P0G Au05 Au01 122.99(13) . . ?
P0G Au05 Au02 179.22(17) . . ?
P0G Au05 Ag08 118.63(16) . . ?
P0G Au05 Ag0D 119.23(16) . . ?
Au02 Au06 Au04 56.89(3) . . ?
Au02 Au06 Ag0C 62.11(4) . . ?
Au02 Au06 Ag0D 60.24(4) . . ?
Ag0C Au06 Au04 59.17(4) . . ?
Ag0D Au06 Au04 107.52(4) . . ?
Ag0D Au06 Ag0C 62.20(5) . . ?
P0K Au06 Au02 175.92(17) . . ?
P0K Au06 Au04 127.19(17) . . ?
P0K Au06 Ag0C 119.00(17) . . ?
P0K Au06 Ag0D 116.38(19) . . ?
Au01 Ag08 Au05 60.39(4) . . ?
Au01 Ag08 Ag09 124.70(5) . . ?
Au01 Ag08 Ag0A 60.22(4) . . ?
Au01 Ag08 Ag0C 159.76(5) . 2_656 ?
Au01 Ag08 Ag0D 107.04(6) . . ?
Au02 Ag08 Au01 56.00(4) . . ?
Au02 Ag08 Au05 56.25(3) . . ?
Au02 Ag08 Ag09 109.86(5) . . ?
Au02 Ag08 Ag0A 59.52(4) . . ?
Au02 Ag08 Ag0C 103.88(5) . 2_656 ?
Au02 Ag08 Ag0D 58.35(4) . . ?
Au02 Ag08 Au1A 57.98(3) . . ?
Au05 Ag08 Ag09 161.55(5) . . ?
Au05 Ag08 Ag0A 108.70(6) . . ?
Au05 Ag08 Ag0C 112.43(5) . 2_656 ?
Au05 Ag08 Ag0D 59.03(5) . . ?
Ag09 Ag08 Ag0C 55.96(5) . 2_656 ?
Ag0A Ag08 Ag09 67.29(5) . . ?
Ag0A Ag08 Ag0C 109.66(6) . 2_656 ?
Ag0D Ag08 Ag09 104.10(6) . . ?
Ag0D Ag08 Ag0A 107.77(5) . . ?
Ag0D Ag08 Ag0C 57.29(5) . 2_656 ?
Cl3 Ag08 Au01 136.0(4) . . ?
Cl3 Ag08 Au02 165.0(4) . . ?
Cl3 Ag08 Au05 134.3(5) . . ?
Cl3 Ag08 Ag09 57.1(5) . . ?
Cl3 Ag08 Ag0A 115.4(5) . . ?
Cl3 Ag08 Ag0D 114.9(4) . . ?
Cl3 Ag08 Au1A 107.0(5) . . ?
Au1A Ag08 Au01 105.52(4) . . ?
Au1A Ag08 Au05 105.15(4) . . ?
Au1A Ag08 Ag09 56.85(4) . . ?
Au1A Ag08 Ag0A 59.32(4) . . ?
Au1A Ag08 Ag0C 56.37(4) . 2_656 ?
Au1A Ag08 Ag0D 58.67(4) . . ?
Cl6 Ag08 Au01 146.3(3) . . ?
Cl6 Ag08 Au02 157.5(3) . . ?
Cl6 Ag08 Au05 124.4(3) . . ?
Cl6 Ag08 Ag09 62.9(3) . . ?
Cl6 Ag08 Ag0A 126.8(3) . . ?
Cl6 Ag08 Ag0C 53.9(3) . 2_656 ?
Cl6 Ag08 Ag0D 101.3(3) . . ?
Cl6 Ag08 Au1A 104.5(3) . . ?
Au02 Ag09 Au03 55.66(3) 2_656 2_656 ?
Au02 Ag09 Au04 55.28(3) 2_656 2_656 ?
Au02 Ag09 Ag08 107.88(5) 2_656 . ?
Au02 Ag09 Ag0A 59.65(4) 2_656 2_656 ?
Au02 Ag09 Ag0A 104.67(5) 2_656 . ?
Au02 Ag09 Ag0C 59.32(4) 2_656 2_656 ?
Au03 Ag09 Ag08 162.35(5) 2_656 . ?
Au03 Ag09 Ag0A 120.20(5) 2_656 . ?
Au03 Ag09 Ag0C 106.65(6) 2_656 2_656 ?
Au04 Ag09 Au03 59.07(4) 2_656 2_656 ?
Au04 Ag09 Ag08 119.23(5) 2_656 . ?
Au04 Ag09 Ag0A 157.91(5) 2_656 . ?
Au04 Ag09 Ag0C 58.21(4) 2_656 2_656 ?
Ag08 Ag09 Ag0A 53.72(4) . . ?
Ag0A Ag09 Au03 60.84(4) 2_656 2_656 ?
Ag0A Ag09 Au04 107.89(6) 2_656 2_656 ?
Ag0A Ag09 Ag08 106.77(6) 2_656 . ?
Ag0A Ag09 Ag0A 61.33(6) 2_656 . ?
Ag0A Ag09 Ag0C 109.32(5) 2_656 2_656 ?
Ag0C Ag09 Ag08 63.86(5) 2_656 . ?
Ag0C Ag09 Ag0A 105.21(6) 2_656 . ?
Cl3 Ag09 Ag08 49.4(4) . . ?
Cl3 Ag09 Ag0A 96.9(4) . . ?
Cl3 Ag09 Au1A 100.3(4) . . ?
Cl4 Ag09 Ag08 79.2(4) . . ?
Cl4 Ag09 Ag0A 45.9(4) . . ?
Cl4 Ag09 Cl3 92.8(6) . . ?
Cl4 Ag09 Au1A 100.0(4) . . ?
Au1A Ag09 Au02 57.63(3) . 2_656 ?
Au1A Ag09 Au03 105.61(4) . 2_656 ?
Au1A Ag09 Au04 103.80(5) . 2_656 ?
Au1A Ag09 Ag08 56.91(4) . . ?
Au1A Ag09 Ag0A 59.84(4) . 2_656 ?
Au1A Ag09 Ag0A 54.22(4) . . ?
Au1A Ag09 Ag0C 59.39(4) . 2_656 ?
Cl5 Ag09 Au02 155.7(3) . 2_656 ?
Cl5 Ag09 Au03 123.0(3) . 2_656 ?
Cl5 Ag09 Au04 148.3(3) . 2_656 ?
Cl5 Ag09 Ag08 68.7(3) . . ?
Cl5 Ag09 Ag0A 53.0(3) . . ?
Cl5 Ag09 Ag0A 97.5(3) . 2_656 ?
Cl5 Ag09 Ag0C 130.3(3) . 2_656 ?
Cl5 Ag09 Au1A 105.2(3) . . ?
Au01 Ag0A Au03 59.33(4) . . ?
Au01 Ag0A Ag08 58.80(4) . . ?
Au01 Ag0A Ag09 115.46(5) . . ?
Au01 Ag0A Ag0A 159.80(3) . 2_656 ?
Au02 Ag0A Au01 55.28(3) . . ?
Au02 Ag0A Au03 55.61(3) . . ?
Au02 Ag0A Ag08 58.66(4) . . ?
Au02 Ag0A Ag09 103.01(5) . . ?
Au02 Ag0A Ag09 59.92(4) . 2_656 ?
Au02 Ag0A Ag0A 108.64(4) . 2_656 ?
Au03 Ag0A Ag09 157.95(5) . . ?
Au03 Ag0A Ag0A 124.78(7) . 2_656 ?
Ag08 Ag0A Au03 106.67(5) . . ?
Ag08 Ag0A Ag09 58.99(5) . . ?
Ag08 Ag0A Ag0A 103.40(6) . 2_656 ?
Ag09 Ag0A Au01 108.02(5) 2_656 . ?
Ag09 Ag0A Au03 60.45(4) 2_656 . ?
Ag09 Ag0A Ag08 108.60(5) 2_656 . ?
Ag09 Ag0A Ag09 105.98(6) 2_656 . ?
Ag09 Ag0A Ag0A 66.50(5) 2_656 2_656 ?
Ag0A Ag0A Ag09 52.16(5) 2_656 . ?
Cl4 Ag0A Au01 109.6(5) . . ?
Cl4 Ag0A Au02 145.2(5) . . ?
Cl4 Ag0A Au03 149.5(4) . . ?
Cl4 Ag0A Ag08 86.5(5) . . ?
Cl4 Ag0A Ag09 51.6(4) . . ?
Cl4 Ag0A Au1A 105.3(4) . . ?
Au1A Ag0A Au01 104.16(4) . . ?
Au1A Ag0A Au02 57.58(3) . . ?
Au1A Ag0A Au03 105.00(4) . . ?
Au1A Ag0A Ag08 58.97(4) . . ?
Au1A Ag0A Ag09 59.42(4) . 2_656 ?
Au1A Ag0A Ag09 53.88(3) . . ?
Au1A Ag0A Ag0A 55.91(3) . 2_656 ?
Cl5 Ag0A Au01 95.5(3) . . ?
Cl5 Ag0A Au02 127.3(3) . . ?
Cl5 Ag0A Au03 148.8(3) . . ?
Cl5 Ag0A Ag08 68.8(3) . . ?
Cl5 Ag0A Ag09 46.5(3) . . ?
Cl5 Ag0A Ag09 150.8(3) . 2_656 ?
Cl5 Ag0A Ag0A 85.4(3) . 2_656 ?
Cl5 Ag0A Au1A 98.7(3) . . ?
Au02 Ag0C Ag08 104.52(5) . 2_656 ?
Au02 Ag0C Ag09 58.57(4) . 2_656 ?
Au02 Ag0C Ag0D 107.73(5) . 2_656 ?
Au02 Ag0C Ag0D 57.15(4) . . ?
Au04 Ag0C Au02 55.45(4) . . ?
Au04 Ag0C Au06 60.52(4) . . ?
Au04 Ag0C Ag08 116.99(5) . 2_656 ?
Au04 Ag0C Ag09 59.53(4) . 2_656 ?
Au04 Ag0C Ag0D 161.66(6) . 2_656 ?
Au04 Ag0C Ag0D 105.93(6) . . ?
Au04 Ag0C Au1A 103.85(5) . . ?
Au06 Ag0C Au02 55.91(4) . . ?
Au06 Ag0C Ag08 159.07(5) . 2_656 ?
Au06 Ag0C Ag09 107.76(6) . 2_656 ?
Au06 Ag0C Ag0D 118.61(6) . 2_656 ?
Au06 Ag0C Ag0D 58.79(5) . . ?
Ag09 Ag0C Ag08 60.18(5) 2_656 2_656 ?
Ag09 Ag0C Ag0D 105.55(5) 2_656 . ?
Ag0D Ag0C Ag08 56.35(5) 2_656 2_656 ?
Ag0D Ag0C Ag08 105.85(6) . 2_656 ?
Ag0D Ag0C Ag09 106.87(6) 2_656 2_656 ?
Ag0D Ag0C Ag0D 63.93(6) 2_656 . ?
Cl2 Ag0C Au02 141.54(17) . . ?
Cl2 Ag0C Au04 144.61(15) . . ?
Cl2 Ag0C Au06 101.02(16) . . ?
Cl2 Ag0C Ag08 90.86(15) . 2_656 ?
Cl2 Ag0C Ag09 150.78(16) . 2_656 ?
Cl2 Ag0C Ag0D 52.76(14) . 2_656 ?
Cl2 Ag0C Ag0D 84.93(16) . . ?
Cl2 Ag0C Au1A 110.19(15) . . ?
Cl2 Ag0C Cl6 95.6(3) . 2_656 ?
Au1A Ag0C Au02 56.97(3) . . ?
Au1A Ag0C Au06 104.08(5) . . ?
Au1A Ag0C Ag08 55.30(4) . 2_656 ?
Au1A Ag0C Ag09 58.13(4) . 2_656 ?
Au1A Ag0C Ag0D 57.67(4) . . ?
Au1A Ag0C Ag0D 57.93(4) . 2_656 ?
Cl6 Ag0C Au02 121.1(3) 2_656 . ?
Cl6 Ag0C Au04 88.3(3) 2_656 . ?
Cl6 Ag0C Au06 144.7(3) 2_656 . ?
Cl6 Ag0C Ag08 48.7(3) 2_656 2_656 ?
Cl6 Ag0C Ag09 63.2(3) 2_656 2_656 ?
Cl6 Ag0C Ag0D 154.5(3) 2_656 . ?
Cl6 Ag0C Ag0D 96.2(3) 2_656 2_656 ?
Cl6 Ag0C Au1A 98.9(3) 2_656 . ?
Au02 Ag0D Au05 56.88(4) . . ?
Au02 Ag0D Au06 56.84(4) . . ?
Au02 Ag0D Ag08 59.23(4) . . ?
Au02 Ag0D Ag0C 111.72(5) . 2_656 ?
Au02 Ag0D Ag0C 59.84(4) . . ?
Au02 Ag0D Ag0D 104.89(4) . 2_656 ?
Au02 Ag0D Au1A 58.49(3) . . ?
Au05 Ag0D Au06 61.98(4) . . ?
Au05 Ag0D Ag08 60.12(4) . . ?
Au05 Ag0D Ag0C 121.76(6) . 2_656 ?
Au05 Ag0D Ag0C 109.24(6) . . ?
Au05 Ag0D Ag0D 161.43(4) . 2_656 ?
Au06 Ag0D Ag08 109.36(6) . . ?
Au06 Ag0D Ag0C 59.01(5) . . ?
Au06 Ag0D Ag0C 165.26(6) . 2_656 ?
Au06 Ag0D Ag0D 113.02(7) . 2_656 ?
Ag08 Ag0D Ag0C 108.77(5) . . ?
Ag08 Ag0D Ag0C 66.36(5) . 2_656 ?
Ag08 Ag0D Ag0D 109.21(6) . 2_656 ?
Ag0C Ag0D Ag0C 108.04(6) 2_656 . ?
Ag0C Ag0D Ag0D 58.39(6) 2_656 2_656 ?
Ag0C Ag0D Ag0D 57.68(5) . 2_656 ?
Cl2 Ag0D Au02 158.61(18) 2_656 . ?
Cl2 Ag0D Au05 113.23(16) 2_656 . ?
Cl2 Ag0D Au06 139.11(16) 2_656 . ?
Cl2 Ag0D Ag08 99.44(18) 2_656 . ?
Cl2 Ag0D Ag0C 54.73(15) 2_656 2_656 ?
Cl2 Ag0D Ag0C 136.68(17) 2_656 . ?
Cl2 Ag0D Ag0D 82.53(15) 2_656 2_656 ?
Cl2 Ag0D Au1A 113.94(15) 2_656 . ?
Au1A Ag0D Au05 106.50(5) . . ?
Au1A Ag0D Au06 105.67(5) . . ?
Au1A Ag0D Ag08 59.30(4) . . ?
Au1A Ag0D Ag0C 59.47(4) . . ?
Au1A Ag0D Ag0C 59.75(4) . 2_656 ?
Au1A Ag0D Ag0D 56.26(3) . 2_656 ?
C00T P0E Au03 112.2(7) . . ?
C00T P0E C01Q 104.4(10) . . ?
C01F P0E Au03 115.6(6) . . ?
C01F P0E C00T 103.0(9) . . ?
C01F P0E C01Q 108.1(8) . . ?
C01Q P0E Au03 112.5(6) . . ?
C00R P0F Au01 109.4(5) . . ?
C00V P0F Au01 114.4(6) . . ?
C00V P0F C00R 104.6(7) . . ?
C00V P0F C014 107.2(8) . . ?
C014 P0F Au01 114.8(5) . . ?
C014 P0F C00R 105.5(8) . . ?
C00X P0G Au05 115.5(7) . . ?
C00X P0G C01P 97.7(9) . . ?
C01D P0G Au05 112.6(6) . . ?
C01D P0G C00X 106.4(10) . . ?
C01D P0G C01P 108.8(9) . . ?
C01P P0G Au05 114.6(7) . . ?
C00Y P0H Au04 112.2(5) . . ?
C00Y P0H C012 105.3(7) . . ?
C00Z P0H Au04 114.0(5) . . ?
C00Z P0H C00Y 107.6(8) . . ?
C00Z P0H C012 102.8(7) . . ?
C012 P0H Au04 114.1(6) . . ?
Ag0D Cl2 Ag0C 72.50(14) 2_656 . ?
C028 P0K Au06 113.1(7) . . ?
C11 P0K Au06 111.8(11) . . ?
C11 P0K C028 105.2(13) . . ?
C11 P0K C75 107.9(11) . . ?
C75 P0K Au06 115.1(7) . . ?
C75 P0K C028 102.8(9) . . ?
Ag08 Cl3 Ag09 73.5(5) . . ?
Ag0A Cl4 Ag09 82.5(5) . . ?
C00Q C00R P0F 123.6(8) . . ?
C00Q C00R C01L 120.0 . . ?
C01L C00R P0F 116.4(8) . . ?
C00R C00Q H00Q 120.0 . . ?
C00R C00Q C00W 120.0 . . ?
C00W C00Q H00Q 120.0 . . ?
C00Q C00W H00W 120.0 . . ?
C01B C00W C00Q 120.0 . . ?
C01B C00W H00W 120.0 . . ?
C00W C01B H01B 120.0 . . ?
C01V C01B C00W 120.0 . . ?
C01V C01B H01B 120.0 . . ?
C01B C01V H01V 120.0 . . ?
C01L C01V C01B 120.0 . . ?
C01L C01V H01V 120.0 . . ?
C00R C01L H01L 120.0 . . ?
C01V C01L C00R 120.0 . . ?
C01V C01L H01L 120.0 . . ?
C59 C00T P0E 122.9(13) . . ?
C59 C00T C2 120.0 . . ?
C2 C00T P0E 117.1(13) . . ?
C00T C59 H59 120.0 . . ?
C00T C59 C64 120.0 . . ?
C64 C59 H59 120.0 . . ?
C59 C64 H64 120.0 . . ?
C59 C64 C1 120.0 . . ?
C1 C64 H64 120.0 . . ?
C64 C1 H1 120.0 . . ?
C51 C1 C64 120.0 . . ?
C51 C1 H1 120.0 . . ?
C1 C51 H51 120.0 . . ?
C1 C51 C2 120.0 . . ?
C2 C51 H51 120.0 . . ?
C00T C2 H2 120.0 . . ?
C51 C2 C00T 120.0 . . ?
C51 C2 H2 120.0 . . ?
C01C C00V P0F 121.7(9) . . ?
C01C C00V C87 120.0 . . ?
C87 C00V P0F 118.1(9) . . ?
C00V C01C H01C 120.0 . . ?
C111 C01C C00V 120.0 . . ?
C111 C01C H01C 120.0 . . ?
C01C C111 H111 120.0 . . ?
C027 C111 C01C 120.0 . . ?
C027 C111 H111 120.0 . . ?
C111 C027 H027 120.0 . . ?
C163 C027 C111 120.0 . . ?
C163 C027 H027 120.0 . . ?
C027 C163 H163 120.0 . . ?
C027 C163 C87 120.0 . . ?
C87 C163 H163 120.0 . . ?
C00V C87 H87 120.0 . . ?
C163 C87 C00V 120.0 . . ?
C163 C87 H87 120.0 . . ?
C63 C00X P0G 116.3(12) . . ?
C63 C00X C53 120.0 . . ?
C53 C00X P0G 123.1(12) . . ?
C00X C63 H63 120.0 . . ?
C46 C63 C00X 120.0 . . ?
C46 C63 H63 120.0 . . ?
C63 C46 H46 120.0 . . ?
C23 C46 C63 120.0 . . ?
C23 C46 H46 120.0 . . ?
C46 C23 H23 120.0 . . ?
C46 C23 C81 120.0 . . ?
C81 C23 H23 120.0 . . ?
C23 C81 H81 120.0 . . ?
C23 C81 C53 120.0 . . ?
C53 C81 H81 120.0 . . ?
C00X C53 H53 120.0 . . ?
C81 C53 C00X 120.0 . . ?
C81 C53 H53 120.0 . . ?
C019 C00Y P0H 120.4(8) . . ?
C019 C00Y C024 120.0 . . ?
C024 C00Y P0H 119.6(8) . . ?
C00Y C019 H019 120.0 . . ?
C00Y C019 C01H 120.0 . . ?
C01H C019 H019 120.0 . . ?
C019 C01H H01H 120.0 . . ?
C01S C01H C019 120.0 . . ?
C01S C01H H01H 120.0 . . ?
C01H C01S H01S 120.0 . . ?
C5 C01S C01H 120.0 . . ?
C5 C01S H01S 120.0 . . ?
C01S C5 H5 120.0 . . ?
C024 C5 C01S 120.0 . . ?
C024 C5 H5 120.0 . . ?
C00Y C024 H024 120.0 . . ?
C5 C024 C00Y 120.0 . . ?
C5 C024 H024 120.0 . . ?
C6 C00Z P0H 116.7(9) . . ?
C6 C00Z C011 120.0 . . ?
C011 C00Z P0H 123.2(8) . . ?
C00Z C6 H6 120.0 . . ?
C00Z C6 C42 120.0 . . ?
C42 C6 H6 120.0 . . ?
C6 C42 H42 120.0 . . ?
C6 C42 C01E 120.0 . . ?
C01E C42 H42 120.0 . . ?
C42 C01E H01E 120.0 . . ?
C023 C01E C42 120.0 . . ?
C023 C01E H01E 120.0 . . ?
C01E C023 H023 120.0 . . ?
C011 C023 C01E 120.0 . . ?
C011 C023 H023 120.0 . . ?
C00Z C011 H011 120.0 . . ?
C023 C011 C00Z 120.0 . . ?
C023 C011 H011 120.0 . . ?
C02E C012 P0H 121.4(8) . . ?
C02E C012 C017 120.0 . . ?
C017 C012 P0H 118.6(8) . . ?
C012 C02E H02E 120.0 . . ?
C01O C02E C012 120.0 . . ?
C01O C02E H02E 120.0 . . ?
C02E C01O H01O 120.0 . . ?
C02E C01O C01J 120.0 . . ?
C01J C01O H01O 120.0 . . ?
C01O C01J H01J 120.0 . . ?
C7 C01J C01O 120.0 . . ?
C7 C01J H01J 120.0 . . ?
C01J C7 H7 120.0 . . ?
C017 C7 C01J 120.0 . . ?
C017 C7 H7 120.0 . . ?
C012 C017 H017 120.0 . . ?
C7 C017 C012 120.0 . . ?
C7 C017 H017 120.0 . . ?
C60 C01D P0G 117.2(11) . . ?
C60 C01D C02B 120.0 . . ?
C02B C01D P0G 122.8(11) . . ?
C01D C60 H60 120.0 . . ?
C01D C60 C49 120.0 . . ?
C49 C60 H60 120.0 . . ?
C60 C49 H49 120.0 . . ?
C60 C49 C01N 120.0 . . ?
C01N C49 H49 120.0 . . ?
C49 C01N H01N 120.0 . . ?
C01G C01N C49 120.0 . . ?
C01G C01N H01N 120.0 . . ?
C01N C01G H01G 120.0 . . ?
C01N C01G C02B 120.0 . . ?
C02B C01G H01G 120.0 . . ?
C01D C02B H02B 120.0 . . ?
C01G C02B C01D 120.0 . . ?
C01G C02B H02B 120.0 . . ?
C16 C01F P0E 121.1(9) . . ?
C16 C01F C010 120.0 . . ?
C010 C01F P0E 118.9(9) . . ?
C01F C16 H16 120.0 . . ?
C27 C16 C01F 120.0 . . ?
C27 C16 H16 120.0 . . ?
C16 C27 H27 120.0 . . ?
C16 C27 C3 120.0 . . ?
C3 C27 H27 120.0 . . ?
C27 C3 H3 120.0 . . ?
C02C C3 C27 120.0 . . ?
C02C C3 H3 120.0 . . ?
C3 C02C H02C 120.0 . . ?
C3 C02C C010 120.0 . . ?
C010 C02C H02C 120.0 . . ?
C01F C010 H010 120.0 . . ?
C02C C010 C01F 120.0 . . ?
C02C C010 H010 120.0 . . ?
C50 C01P P0G 121.5(11) . . ?
C50 C01P C01X 120.0 . . ?
C01X C01P P0G 118.5(11) . . ?
C01P C50 H50 120.0 . . ?
C01P C50 C28 120.0 . . ?
C28 C50 H50 120.0 . . ?
C50 C28 H28 120.0 . . ?
C50 C28 C30 120.0 . . ?
C30 C28 H28 120.0 . . ?
C28 C30 H30 120.0 . . ?
C43 C30 C28 120.0 . . ?
C43 C30 H30 120.0 . . ?
C30 C43 H43 120.0 . . ?
C01X C43 C30 120.0 . . ?
C01X C43 H43 120.0 . . ?
C01P C01X H01X 120.0 . . ?
C43 C01X C01P 120.0 . . ?
C43 C01X H01X 120.0 . . ?
C32 C01Q P0E 124.8(10) . . ?
C32 C01Q C33 120.0 . . ?
C33 C01Q P0E 115.1(10) . . ?
C01Q C32 H32 120.0 . . ?
C01Q C32 C4 120.0 . . ?
C4 C32 H32 120.0 . . ?
C32 C4 H4 120.0 . . ?
C29 C4 C32 120.0 . . ?
C29 C4 H4 120.0 . . ?
C4 C29 H29 120.0 . . ?
C74 C29 C4 120.0 . . ?
C74 C29 H29 120.0 . . ?
C29 C74 H74 120.0 . . ?
C29 C74 C33 120.0 . . ?
C33 C74 H74 120.0 . . ?
C01Q C33 H33 120.0 . . ?
C74 C33 C01Q 120.0 . . ?
C74 C33 H33 120.0 . . ?
C36 C44 H44 120.0 . . ?
C36 C44 C47 120.0 . . ?
C47 C44 H44 120.0 . . ?
C44 C36 H36 120.0 . . ?
C44 C36 C020 120.0 . . ?
C020 C36 H36 120.0 . . ?
C36 C020 H020 120.0 . . ?
C36 C020 C014 120.0 . . ?
C014 C020 H020 120.0 . . ?
C020 C014 P0F 120.9(9) . . ?
C24 C014 P0F 119.1(9) . . ?
C24 C014 C020 120.0 . . ?
C014 C24 H24 120.0 . . ?
C014 C24 C47 120.0 . . ?
C47 C24 H24 120.0 . . ?
C44 C47 H47 120.0 . . ?
C24 C47 C44 120.0 . . ?
C24 C47 H47 120.0 . . ?
C31 C21 H21 120.0 . . ?
C31 C21 C028 120.0 . . ?
C028 C21 H21 120.0 . . ?
C21 C31 H31 120.0 . . ?
C21 C31 C55 120.0 . . ?
C55 C31 H31 120.0 . . ?
C31 C55 H55 120.0 . . ?
C96 C55 C31 120.0 . . ?
C96 C55 H55 120.0 . . ?
C55 C96 H96 120.0 . . ?
C55 C96 C10 120.0 . . ?
C10 C96 H96 120.0 . . ?
C96 C10 H10 120.0 . . ?
C96 C10 C028 120.0 . . ?
C028 C10 H10 120.0 . . ?
C21 C028 P0K 120.5(12) . . ?
C10 C028 P0K 119.5(12) . . ?
C10 C028 C21 120.0 . . ?
C14 C11 P0K 124(2) . . ?
C14 C11 C12 120.0 . . ?
C12 C11 P0K 116(2) . . ?
C11 C14 H14 120.0 . . ?
C13 C14 C11 120.0 . . ?
C13 C14 H14 120.0 . . ?
C14 C13 H13 120.0 . . ?
C14 C13 C58 120.0 . . ?
C58 C13 H13 120.0 . . ?
C13 C58 H58 120.0 . . ?
C41 C58 C13 120.0 . . ?
C41 C58 H58 120.0 . . ?
C58 C41 H41 120.0 . . ?
C12 C41 C58 120.0 . . ?
C12 C41 H41 120.0 . . ?
C11 C12 H12 120.0 . . ?
C41 C12 C11 120.0 . . ?
C41 C12 H12 120.0 . . ?
C025 C75 P0K 118.1(10) . . ?
C025 C75 C01T 120.0 . . ?
C01T C75 P0K 121.8(10) . . ?
C75 C025 H025 120.0 . . ?
C129 C025 C75 120.0 . . ?
C129 C025 H025 120.0 . . ?
C025 C129 H129 120.0 . . ?
C025 C129 C9 120.0 . . ?
C9 C129 H129 120.0 . . ?
C129 C9 H9 120.0 . . ?
C8 C9 C129 120.0 . . ?
C8 C9 H9 120.0 . . ?
C9 C8 H8 120.0 . . ?
C9 C8 C01T 120.0 . . ?
C01T C8 H8 120.0 . . ?
C75 C01T H01T 120.0 . . ?
C8 C01T C75 120.0 . . ?
C8 C01T H01T 120.0 . . ?
Au02 Au1A Au02 175.67(6) . 2_656 ?
Au02 Au1A Ag09 61.60(3) . 2_656 ?
Au02 Au1A Ag09 120.80(4) 2_656 2_656 ?
Au02 Au1A Ag0D 115.54(5) 2_656 . ?
Au02 Au1A Ag0D 60.40(4) . . ?
Au02 Au1A Ag0D 115.53(5) . 2_656 ?
Au02 Au1A Ag0D 60.40(4) 2_656 2_656 ?
Ag0D Au1A Ag09 113.25(5) . 2_656 ?
Ag0D Au1A Ag09 114.08(4) 2_656 2_656 ?
Ag0D Au1A Ag0D 67.48(7) 2_656 . ?
Au01 Ag1 Au04 102.26(5) . . ?
Au02 Ag1 Au01 55.45(4) . . ?
Au02 Ag1 Au03 56.30(4) . . ?
Au02 Ag1 Au04 55.04(4) . . ?
Au02 Ag1 Au05 56.49(4) . . ?
Au02 Ag1 Au06 56.24(4) . . ?
Au03 Ag1 Au01 58.10(3) . . ?
Au03 Ag1 Au04 57.28(3) . . ?
Au03 Ag1 Au06 103.88(6) . . ?
Au05 Ag1 Au01 58.44(4) . . ?
Au05 Ag1 Au03 104.76(5) . . ?
Au05 Ag1 Au04 104.12(6) . . ?
Au05 Ag1 Au06 59.82(4) . . ?
Au06 Ag1 Au01 104.53(6) . . ?
Au06 Ag1 Au04 57.67(4) . . ?
Cl1 Ag1 Au01 123.27(16) . . ?
Cl1 Ag1 Au02 178.01(18) . . ?
Cl1 Ag1 Au03 124.74(16) . . ?
Cl1 Ag1 Au04 126.90(17) . . ?
Cl1 Ag1 Au05 121.66(17) . . ?
Cl1 Ag1 Au06 123.92(15) . . ?
Ag09 Cl5 Ag0A 80.4(3) . . ?
Ag08 Cl6 Ag0C 77.4(3) . 2_656 ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Au01 P0F C00R C00Q 119.8(7) . . . . ?
Au01 P0F C00R C01L -62.5(8) . . . . ?
Au01 P0F C00V C01C 149.6(8) . . . . ?
Au01 P0F C00V C87 -24.9(11) . . . . ?
Au01 P0F C014 C020 169.1(9) . . . . ?
Au01 P0F C014 C24 -12.9(12) . . . . ?
Au03 P0E C00T C59 85.2(13) . . . . ?
Au03 P0E C00T C2 -95.7(11) . . . . ?
Au03 P0E C01F C16 -177.0(7) . . . . ?
Au03 P0E C01F C010 3.1(11) . . . . ?
Au03 P0E C01Q C32 142.5(10) . . . . ?
Au03 P0E C01Q C33 -41.4(11) . . . . ?
Au04 P0H C00Y C019 154.4(7) . . . . ?
Au04 P0H C00Y C024 -23.6(10) . . . . ?
Au04 P0H C00Z C6 -43.8(9) . . . . ?
Au04 P0H C00Z C011 140.6(7) . . . . ?
Au04 P0H C012 C02E 125.7(8) . . . . ?
Au04 P0H C012 C017 -55.5(10) . . . . ?
Au05 P0G C00X C63 -65.6(11) . . . . ?
Au05 P0G C00X C53 123.5(10) . . . . ?
Au05 P0G C01D C60 -40.3(11) . . . . ?
Au05 P0G C01D C02B 141.1(9) . . . . ?
Au05 P0G C01P C50 171.1(9) . . . . ?
Au05 P0G C01P C01X -9.5(12) . . . . ?
Au06 P0K C028 C21 166.7(9) . . . . ?
Au06 P0K C028 C10 -12.4(13) . . . . ?
Au06 P0K C11 C14 153.8(13) . . . . ?
Au06 P0K C11 C12 -28.3(16) . . . . ?
Au06 P0K C75 C025 -86.5(10) . . . . ?
Au06 P0K C75 C01T 95.3(10) . . . . ?
P0E C00T C59 C64 179.1(17) . . . . ?
P0E C00T C2 C51 -179.2(16) . . . . ?
P0E C01F C16 C27 -179.9(13) . . . . ?
P0E C01F C010 C02C 179.9(12) . . . . ?
P0E C01Q C32 C4 175.9(15) . . . . ?
P0E C01Q C33 C74 -176.2(13) . . . . ?
P0F C00R C00Q C00W 177.6(11) . . . . ?
P0F C00R C01L C01V -177.8(10) . . . . ?
P0F C00V C01C C111 -174.4(13) . . . . ?
P0F C00V C87 C163 174.6(13) . . . . ?
P0F C014 C24 C47 -178.0(14) . . . . ?
P0G C00X C63 C46 -171.2(14) . . . . ?
P0G C00X C53 C81 170.5(15) . . . . ?
P0G C01D C60 C49 -178.7(14) . . . . ?
P0G C01D C02B C01G 178.6(15) . . . . ?
P0G C01P C50 C28 179.3(15) . . . . ?
P0G C01P C01X C43 -179.3(15) . . . . ?
P0H C00Y C019 C01H -178.0(12) . . . . ?
P0H C00Y C024 C5 178.0(12) . . . . ?
P0H C00Z C6 C42 -175.8(11) . . . . ?
P0H C00Z C011 C023 175.5(12) . . . . ?
P0H C012 C02E C01O 178.8(12) . . . . ?
P0H C012 C017 C7 -178.9(12) . . . . ?
P0K C11 C14 C13 178(2) . . . . ?
P0K C11 C12 C41 -178(2) . . . . ?
P0K C75 C025 C129 -178.3(13) . . . . ?
P0K C75 C01T C8 178.2(14) . . . . ?
C00R P0F C00V C01C 30.0(12) . . . . ?
C00R P0F C00V C87 -144.5(9) . . . . ?
C00R P0F C014 C020 -70.4(12) . . . . ?
C00R P0F C014 C24 107.6(11) . . . . ?
C00R C00Q C00W C01B 0.0 . . . . ?
C00Q C00R C01L C01V 0.0 . . . . ?
C00Q C00W C01B C01V 0.0 . . . . ?
C00W C01B C01V C01L 0.0 . . . . ?
C01B C01V C01L C00R 0.0 . . . . ?
C01L C00R C00Q C00W 0.0 . . . . ?
C00T P0E C01F C16 60.2(12) . . . . ?
C00T P0E C01F C010 -119.7(11) . . . . ?
C00T P0E C01Q C32 -95.5(13) . . . . ?
C00T P0E C01Q C33 80.5(12) . . . . ?
C00T C59 C64 C1 0.0 . . . . ?
C59 C00T C2 C51 0.0 . . . . ?
C59 C64 C1 C51 0.0 . . . . ?
C64 C1 C51 C2 0.0 . . . . ?
C1 C51 C2 C00T 0.0 . . . . ?
C2 C00T C59 C64 0.0 . . . . ?
C00V P0F C00R C00Q -117.2(9) . . . . ?
C00V P0F C00R C01L 60.5(9) . . . . ?
C00V P0F C014 C020 40.7(13) . . . . ?
C00V P0F C014 C24 -141.3(10) . . . . ?
C00V C01C C111 C027 0.0 . . . . ?
C01C C00V C87 C163 0.0 . . . . ?
C01C C111 C027 C163 0.0 . . . . ?
C111 C027 C163 C87 0.0 . . . . ?
C027 C163 C87 C00V 0.0 . . . . ?
C87 C00V C01C C111 0.0 . . . . ?
C00X P0G C01D C60 87.2(12) . . . . ?
C00X P0G C01D C02B -91.4(13) . . . . ?
C00X P0G C01P C50 48.5(13) . . . . ?
C00X P0G C01P C01X -132.2(12) . . . . ?
C00X C63 C46 C23 0.0 . . . . ?
C63 C00X C53 C81 0.0 . . . . ?
C63 C46 C23 C81 0.0 . . . . ?
C46 C23 C81 C53 0.0 . . . . ?
C23 C81 C53 C00X 0.0 . . . . ?
C53 C00X C63 C46 0.0 . . . . ?
C00Y P0H C00Z C6 -168.8(8) . . . . ?
C00Y P0H C00Z C011 15.6(11) . . . . ?
C00Y P0H C012 C02E -110.9(10) . . . . ?
C00Y P0H C012 C017 68.0(10) . . . . ?
C00Y C019 C01H C01S 0.0 . . . . ?
C019 C00Y C024 C5 0.0 . . . . ?
C019 C01H C01S C5 0.0 . . . . ?
C01H C01S C5 C024 0.0 . . . . ?
C01S C5 C024 C00Y 0.0 . . . . ?
C024 C00Y C019 C01H 0.0 . . . . ?
C00Z P0H C00Y C019 -79.4(10) . . . . ?
C00Z P0H C00Y C024 102.5(10) . . . . ?
C00Z P0H C012 C02E 1.7(11) . . . . ?
C00Z P0H C012 C017 -179.4(9) . . . . ?
C00Z C6 C42 C01E 0.0 . . . . ?
C6 C00Z C011 C023 0.0 . . . . ?
C6 C42 C01E C023 0.0 . . . . ?
C42 C01E C023 C011 0.0 . . . . ?
C01E C023 C011 C00Z 0.0 . . . . ?
C011 C00Z C6 C42 0.0 . . . . ?
C012 P0H C00Y C019 29.8(11) . . . . ?
C012 P0H C00Y C024 -148.3(9) . . . . ?
C012 P0H C00Z C6 80.3(9) . . . . ?
C012 P0H C00Z C011 -95.3(10) . . . . ?
C012 C02E C01O C01J 0.0 . . . . ?
C02E C012 C017 C7 0.0 . . . . ?
C02E C01O C01J C7 0.0 . . . . ?
C01O C01J C7 C017 0.0 . . . . ?
C01J C7 C017 C012 0.0 . . . . ?
C017 C012 C02E C01O 0.0 . . . . ?
C01D P0G C00X C63 168.6(11) . . . . ?
C01D P0G C00X C53 -2.2(14) . . . . ?
C01D P0G C01P C50 -61.9(13) . . . . ?
C01D P0G C01P C01X 117.5(12) . . . . ?
C01D C60 C49 C01N 0.0 . . . . ?
C60 C01D C02B C01G 0.0 . . . . ?
C60 C49 C01N C01G 0.0 . . . . ?
C49 C01N C01G C02B 0.0 . . . . ?
C01N C01G C02B C01D 0.0 . . . . ?
C02B C01D C60 C49 0.0 . . . . ?
C01F P0E C00T C59 -149.9(12) . . . . ?
C01F P0E C00T C2 29.3(13) . . . . ?
C01F P0E C01Q C32 13.7(14) . . . . ?
C01F P0E C01Q C33 -170.3(10) . . . . ?
C01F C16 C27 C3 0.0 . . . . ?
C16 C01F C010 C02C 0.0 . . . . ?
C16 C27 C3 C02C 0.0 . . . . ?
C27 C3 C02C C010 0.0 . . . . ?
C3 C02C C010 C01F 0.0 . . . . ?
C010 C01F C16 C27 0.0 . . . . ?
C01P P0G C00X C63 56.4(12) . . . . ?
C01P P0G C00X C53 -114.4(12) . . . . ?
C01P P0G C01D C60 -168.4(10) . . . . ?
C01P P0G C01D C02B 12.9(14) . . . . ?
C01P C50 C28 C30 0.0 . . . . ?
C50 C01P C01X C43 0.0 . . . . ?
C50 C28 C30 C43 0.0 . . . . ?
C28 C30 C43 C01X 0.0 . . . . ?
C30 C43 C01X C01P 0.0 . . . . ?
C01X C01P C50 C28 0.0 . . . . ?
C01Q P0E C00T C59 -37.0(15) . . . . ?
C01Q P0E C00T C2 142.2(12) . . . . ?
C01Q P0E C01F C16 -49.9(12) . . . . ?
C01Q P0E C01F C010 130.2(10) . . . . ?
C01Q C32 C4 C29 0.0 . . . . ?
C32 C01Q C33 C74 0.0 . . . . ?
C32 C4 C29 C74 0.0 . . . . ?
C4 C29 C74 C33 0.0 . . . . ?
C29 C74 C33 C01Q 0.0 . . . . ?
C33 C01Q C32 C4 0.0 . . . . ?
C44 C36 C020 C014 0.0 . . . . ?
C36 C44 C47 C24 0.0 . . . . ?
C36 C020 C014 P0F 178.0(15) . . . . ?
C36 C020 C014 C24 0.0 . . . . ?
C020 C014 C24 C47 0.0 . . . . ?
C014 P0F C00R C00Q -4.2(10) . . . . ?
C014 P0F C00R C01L 173.5(8) . . . . ?
C014 P0F C00V C01C -81.8(12) . . . . ?
C014 P0F C00V C87 103.7(10) . . . . ?
C014 C24 C47 C44 0.0 . . . . ?
C47 C44 C36 C020 0.0 . . . . ?
C21 C31 C55 C96 0.0 . . . . ?
C31 C21 C028 P0K -179.1(15) . . . . ?
C31 C21 C028 C10 0.0 . . . . ?
C31 C55 C96 C10 0.0 . . . . ?
C55 C96 C10 C028 0.0 . . . . ?
C96 C10 C028 P0K 179.1(15) . . . . ?
C96 C10 C028 C21 0.0 . . . . ?
C028 P0K C11 C14 30.6(18) . . . . ?
C028 P0K C11 C12 -151.5(13) . . . . ?
C028 P0K C75 C025 37.0(12) . . . . ?
C028 P0K C75 C01T -141.3(11) . . . . ?
C028 C21 C31 C55 0.0 . . . . ?
C11 P0K C028 C21 -71.0(15) . . . . ?
C11 P0K C028 C10 109.9(14) . . . . ?
C11 P0K C75 C025 147.9(14) . . . . ?
C11 P0K C75 C01T -30.3(16) . . . . ?
C11 C14 C13 C58 0.0 . . . . ?
C14 C11 C12 C41 0.0 . . . . ?
C14 C13 C58 C41 0.0 . . . . ?
C13 C58 C41 C12 0.0 . . . . ?
C58 C41 C12 C11 0.0 . . . . ?
C12 C11 C14 C13 0.0 . . . . ?
C75 P0K C028 C21 41.9(13) . . . . ?
C75 P0K C028 C10 -137.2(12) . . . . ?
C75 P0K C11 C14 -78.7(17) . . . . ?
C75 P0K C11 C12 99.2(14) . . . . ?
C75 C025 C129 C9 0.0 . . . . ?
C025 C75 C01T C8 0.0 . . . . ?
C025 C129 C9 C8 0.0 . . . . ?
C129 C9 C8 C01T 0.0 . . . . ?
C9 C8 C01T C75 0.0 . . . . ?
C01T C75 C025 C129 0.0 . . . . ?

_smtbx_masks_special_details     
;
A solvent mask was calculated and 1560 electrons were 
found in a volume of 5938Å³ in 2 voids per unit cell. 
This is consistent with the presence of 38[H2O], 1[H2O] per Formula Unit 
which account for 1560 electrons per unit cell.
;
loop_
_smtbx_masks_void_nr
_smtbx_masks_void_average_x
_smtbx_masks_void_average_y
_smtbx_masks_void_average_z
_smtbx_masks_void_volume
_smtbx_masks_void_count_electrons
_smtbx_masks_void_content
1 -0.444 -0.787 0.250 2880.9 760.0 '76 H2O'
2 -0.070 -0.688 0.750 2880.9 760.0 '76 H2O'
3 0.250 0.106 0.500 44.4 10.5 '1 H2O'
4 0.250 0.394 0.000 44.4 22.1 '1 H2O'
5 0.750 0.606 0.000 44.4 10.5 '1 H2O'
6 0.750 0.894 0.500 44.4 22.1 '1 H2O'

_smtbx_masks_void_probe_radius   1.2
_smtbx_masks_void_truncation_radius 1.2
_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_au19ag12
_database_code_depnum_ccdc_archive 'CCDC 2163804'
loop_
_audit_author_name
_audit_author_address
'Xi Xi Kang'
;Anhui University
China
;
_audit_update_record             
;
2022-09-21 deposited with the CCDC.	2022-09-23 downloaded from the CCDC.
;
_audit_creation_date             2022-09-16
_audit_creation_method           
;
Olex2 1.5-dev
(compiled 2022.07.25 svn.r36e0af09 for OlexSys, GUI svn.r6444)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C210 H222 Ag14.34 Au16.66 Cl7 P12 S6, 32[H2O]'
_chemical_formula_sum            'C210 H286 Ag14.34 Au16.66 Cl7 O32 P12 S6'
_chemical_formula_weight         8962.84
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag 0.1306 4.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -4.4197 7.2980 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.3331 0.5567 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   21.3747(4)
_cell_length_b                   21.9612(4)
_cell_length_c                   28.8966(6)
_cell_angle_alpha                87.586(2)
_cell_angle_beta                 74.5520(10)
_cell_angle_gamma                77.0140(10)
_cell_volume                     12737.8(4)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    82334
_cell_measurement_temperature    120
_cell_measurement_theta_max      70.32
_cell_measurement_theta_min      6.07
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    28.438
_exptl_absorpt_correction_T_max  0.1530
_exptl_absorpt_correction_T_min  0.0266
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
STOE X-Red32, absorption correction by Gaussian integration, analogous to
P. Coppens, "The Evaluation of Absorption and Extinction in Single-Crystal
Structure Analysis", published in: F. R. Ahmed (Editor), "Crystallographic
Computing", Munksgaard, Copenhagen (1970), 255 - 270.
Afterwards scaling of reflection intensities was performed within STOE LANA.
J. Koziskova, F. Hahn, J. Richter, J. Kozisek, "Comparison of different
absorption corrections on the model structure of tetrakis(μ₂-acetato)-
diaqua-di-copper(II)", Acta Chimica Slovaca, vol. 9, no. 2, 2016, pp. 136 - 140.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            black
_exptl_crystal_colour_primary    black
_exptl_crystal_density_diffrn    2.337
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             8374
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
-6 -7 30 0.0639
-9 30 -28 0.0730
-15 -9 4 0.0534
25 1 30 0.0585
-6 -11 -15 0.0641
5 1 -30 0.0734
21 30 28 0.0584
-5 0 -6 0.0705
10 -6 15 0.0689
11 15 -6 0.0581
1 -17 -30 0.0645

_exptl_crystal_size_max          0.31
_exptl_crystal_size_mid          0.23
_exptl_crystal_size_min          0.12
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0351
_diffrn_reflns_av_unetI/netI     0.0517
_diffrn_reflns_Laue_measured_fraction_full 0.958
_diffrn_reflns_Laue_measured_fraction_max 0.958
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -22
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -33
_diffrn_reflns_number            77919
_diffrn_reflns_point_group_measured_fraction_full 0.958
_diffrn_reflns_point_group_measured_fraction_max 0.958
_diffrn_reflns_theta_full        62.499
_diffrn_reflns_theta_max         62.499
_diffrn_reflns_theta_min         6.073
_diffrn_ambient_temperature      120.00
_diffrn_detector_area_resol_mean 5.81
_diffrn_detector_type            'DECTRIS PILATUS 300K'
_diffrn_measured_fraction_theta_full 0.958
_diffrn_measured_fraction_theta_max 0.958
_diffrn_measurement_details      
;
 1488 frames, detector distance = 60 mm
;
_diffrn_measurement_device       'Eulerian 4-circle diffractometer'
_diffrn_measurement_device_type  STOE
_diffrn_measurement_method       'rotation method, ω scans'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                29156
_reflns_number_total             38923
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'X-Area Recipe 1.33.0.0 (STOE, 2015)'
_computing_data_collection       'X-Area Pilatus3_SV 1.31.153.0 (STOE, 2018)'
_computing_data_reduction        
;
X-Area Integrate 1.74.2.0 (STOE, 2018)
X-Area LANA 1.75.3.0 (STOE, 2018)
;
_computing_molecular_graphics    'Olex2 1.5-dev (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5-dev (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         2.077
_refine_diff_density_min         -1.983
_refine_diff_density_rms         0.168
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.923
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     2320
_refine_ls_number_reflns         38923
_refine_ls_number_restraints     2820
_refine_ls_R_factor_all          0.0540
_refine_ls_R_factor_gt           0.0415
_refine_ls_restrained_S_all      0.899
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0637P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1019
_refine_ls_wR_factor_ref         0.1063
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
2. Shared sites
{Au2, Ag0A}
{Ag1A, Au3}
{Ag2A, Au}
{Au5, Ag3A}
{Ag, Au1}
3. Uiso/Uaniso restraints and constraints
C202 \\sim C201 \\sim C200 \\sim C199 \\sim C198 \\sim C197: within 2A with
sigma of 0.001 and sigma for terminal atoms of 0.002 within 2A
: with sigma of 0.001 and sigma for terminal atoms of 0.002
Uanis(Ag0A) = Uanis(Au2)
Uanis(Au2) = Uanis(Ag0A)
Uanis(Au3) = Uanis(Ag1A)
Uanis(Ag1A) = Uanis(Au3)
Uanis(Au) = Uanis(Ag2A)
Uanis(Ag2A) = Uanis(Au)
Uanis(Ag3A) = Uanis(Au5)
Uanis(Au5) = Uanis(Ag3A)
Uanis(Au1) = Uanis(Ag)
Uanis(Ag) = Uanis(Au1)
4. Rigid body (RIGU) restrains
 All non-hydrogen atoms
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.001
5. Others
 Fixed Sof: Au(0.62) Ag3A(0.54) Au1(0.51) Au2(0.5) Au3(0.57) Au1A(0.5) C9(0.5)
 C182(0.5) H18C(0.5) H18D(0.5) C183(0.5) H18E(0.5) H18F(0.5) C184(0.5)
 H18G(0.5) H18H(0.5) C185(0.5) H18I(0.5) H18J(0.5) C186(0.5) H186(0.5)
 C187(0.5) H187(0.5) C188(0.5) H18K(0.5) H18L(0.5) C189(0.5) H189(0.5)
 C190(0.5) H19A(0.5) H19B(0.5) C211(0.5) H21C(0.5) H21D(0.5) C212(0.5)
 H21E(0.5) H21F(0.5) C213(0.5) C214(0.5) H21G(0.5) H21H(0.5) C215(0.5)
 H21I(0.5) H21J(0.5) C216(0.5) H216(0.5) C217(0.5) H217(0.5) C218(0.5)
 H218(0.5) C219(0.5) H21K(0.5) H21L(0.5) C220(0.5) H22C(0.5) H22D(0.5) Au4(0.5)
 Ag0A(0.5) Ag1A(0.43) Ag2A(0.38) Au5(0.46) Ag(0.49)
6.a Ternary CH refined with riding coordinates:
 C43(H43), C50(H50), C95(H95), C104(H104), C113(H113), C123(H123), C132(H132),
 C156(H156), C169(H169), C170(H170), C172(H172), C186(H186), C187(H187),
 C189(H189), C203(H203), C205(H205), C206(H206), C209(H209), C216(H216),
 C217(H217), C218(H218)
6.b Secondary CH2 refined with riding coordinates:
 C3(H3A,H3B), C16(H16A,H16B), C22(H22A,H22B), C37(H37A,H37B), C39(H39A,H39B),
 C46(H46A,H46B), C51(H51A,H51B), C60(H60A,H60B), C62(H62A,H62B), C64(H64A,H64B),
  C85(H85A,H85B), C90(H90A,H90B), C93(H93A,H93B), C94(H94A,H94B), C96(H96A,
 H96B), C99(H99A,H99B), C101(H10A,H10B), C103(H10C,H10D), C114(H11A,H11B),
 C129(H12A,H12B), C134(H13A,H13B), C151(H15A,H15B), C154(H15C,H15D), C157(H15E,
 H15F), C158(H15G,H15H), C160(H16C,H16D), C163(H16E,H16F), C164(H16G,H16H),
 C167(H16I,H16J), C173(H17A,H17B), C174(H17C,H17D), C181(H18A,H18B), C182(H18C,
 H18D), C183(H18E,H18F), C184(H18G,H18H), C185(H18I,H18J), C188(H18K,H18L),
 C190(H19A,H19B), C204(H20A,H20B), C207(H20C,H20D), C208(H20E,H20F), C210(H21A,
 H21B), C211(H21C,H21D), C212(H21E,H21F), C214(H21G,H21H), C215(H21I,H21J),
 C219(H21K,H21L), C220(H22C,H22D)
6.c Aromatic/amide H refined with riding coordinates:
 C4(H4), C11(H11), C12(H12), C13(H13), C14(H14), C15(H15), C17(H17), C19(H19),
 C20(H20), C21(H21), C23(H23), C25(H25), C26(H26), C27(H27), C28(H28), C29(H29),
  C30(H30), C31(H31), C33(H33), C36(H36), C38(H38), C41(H41), C42(H42),
 C44(H44), C45(H45), C47(H47), C48(H48), C49(H49), C53(H53), C54(H54), C55(H55),
  C56(H56), C57(H57), C58(H58), C59(H59), C61(H61), C63(H63), C65(H65),
 C66(H66), C67(H67), C68(H68), C69(H69), C70(H70), C71(H71), C73(H73), C74(H74),
  C75(H75), C77(H77), C78(H78), C79(H79), C80(H80), C81(H81), C82(H82),
 C83(H83), C86(H86), C87(H87), C88(H88), C91(H91), C100(H100), C102(H102),
 C105(H105), C106(H106), C107(H107), C108(H108), C110(H110), C111(H111),
 C112(H112), C115(H115), C117(H117), C118(H118), C119(H119), C120(H120),
 C121(H121), C122(H122), C124(H124), C125(H125), C126(H126), C127(H127),
 C128(H128), C130(H130), C131(H131), C133(H133), C135(H135), C136(H136),
 C138(H138), C139(H139), C140(H140), C141(H141), C143(H143), C144(H144),
 C145(H145), C146(H146), C147(H147), C148(H148), C149(H149), C152(H152),
 C153(H153), C155(H155), C159(H159), C161(H161), C162(H162), C165(H165),
 C166(H166), C168(H168), C171(H171), C175(H175), C176(H176), C177(H177),
 C179(H179), C180(H180), C191(H191), C192(H192), C193(H193), C194(H194),
 C196(H196), C197(H197), C199(H199), C200(H200), C201(H201), C202(H202)
6.d Fitted hexagon refined as free rotating group:
 C10(C11,C12,C13,C14,C15), C24(C25,C26,C27,C28,C29), C52(C53,C54,C55,C56,C57),
 C70(C71,C72,C73,C74,C75), C79(C80,C81,C82,C83,C84), C106(C107,C108,C109,C110,
 C111), C115(C116,C117,C118,C119,C120), C136(C137,C138,C139,C140,C141),
 C142(C143,C144,C145,C146,C147), C175(C176,C177,C178,C179,C180), C191(C192,C193,
 C194,C195,C196), C197(C198,C199,C200,C201,C202)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au01 Au 0.54417(2) 0.31788(2) 0.72652(2) 0.03944(9) Uani 1 1 d . . . . .
Au02 Au 0.50150(2) 0.21261(2) 0.75383(2) 0.04423(9) Uani 1 1 d . . . . .
Au03 Au 0.55679(2) 0.23732(2) 0.65378(2) 0.04288(9) Uani 1 1 d . . . . .
Au04 Au 0.77715(2) 0.33531(2) 0.76734(2) 0.04354(9) Uani 1 1 d . . . . .
Au05 Au 0.45701(2) 0.43044(2) 0.73853(2) 0.04360(9) Uani 1 1 d . . . . .
Au06 Au 0.72912(2) 0.17990(2) 0.58423(2) 0.04689(10) Uani 1 1 d . . . . .
Au07 Au 0.87775(2) 0.23492(2) 0.74130(2) 0.04819(10) Uani 1 1 d . . . . .
Au08 Au 0.96543(2) 0.25842(2) 0.61656(2) 0.04845(10) Uani 1 1 d . . . . .
Au09 Au 0.80019(2) 0.45308(2) 0.75256(2) 0.04930(10) Uani 1 1 d . . . . .
Au Au 0.66096(2) 0.32485(2) 0.74702(2) 0.03789(10) Uani 0.62 1 d . . P A .
Au0B Au 0.80705(2) 0.26420(2) 0.84132(2) 0.05059(11) Uani 1 1 d . . . . .
Au0C Au 0.48453(2) 0.51348(2) 0.63019(2) 0.05213(11) Uani 1 1 d . . . . .
Au0D Au 0.39285(2) 0.23808(2) 0.87626(2) 0.05248(11) Uani 1 1 d . . . . .
Au0E Au 0.66781(2) 0.19816(2) 0.91203(2) 0.05433(11) Uani 1 1 d . . . . .
Ag3A Ag 0.52642(2) 0.37323(2) 0.64457(2) 0.03924(11) Uani 0.54 1 d . . P A 1
Au1 Au 0.43665(2) 0.33118(3) 0.80403(2) 0.04342(11) Uani 0.51 1 d . . P A .
Au2 Au 0.87486(2) 0.35147(3) 0.68878(2) 0.04489(12) Uani 0.5 1 d . . P A .
Au3 Au 0.76014(3) 0.39925(3) 0.84852(2) 0.05197(13) Uani 0.57 1 d . . P A .
Au1A Au 0.70525(9) 0.53165(9) 0.85706(6) 0.0472(3) Uani 0.5 1 d . . P A 2
Ag0K Ag 0.42436(3) 0.31596(4) 0.70748(3) 0.04300(15) Uani 1 1 d . . . . .
Ag0L Ag 0.65825(3) 0.31231(4) 0.64838(3) 0.04637(16) Uani 1 1 d . . . . .
Ag0M Ag 0.54033(3) 0.39721(4) 0.80426(3) 0.04609(16) Uani 1 1 d . . . . .
Ag0N Ag 0.73870(3) 0.40254(4) 0.68853(3) 0.04589(16) Uani 1 1 d . . . . .
Ag0O Ag 0.78915(3) 0.26786(4) 0.68244(3) 0.04721(16) Uani 1 1 d . . . . .
Ag0P Ag 0.64595(3) 0.20757(4) 0.71524(3) 0.04696(16) Uani 1 1 d . . . . .
Ag0Q Ag 0.56625(4) 0.26231(4) 0.81261(3) 0.04703(16) Uani 1 1 d . . . . .
Ag0R Ag 0.59220(3) 0.43125(4) 0.70286(3) 0.04744(16) Uani 1 1 d . . . . .
Ag0S Ag 0.66760(3) 0.44195(4) 0.78813(3) 0.04893(17) Uani 1 1 d . . . . .
Ag0T Ag 0.89341(3) 0.34982(4) 0.78503(3) 0.04934(17) Uani 1 1 d . . . . .
Ag0U Ag 0.73958(4) 0.21757(4) 0.78054(3) 0.05280(18) Uani 1 1 d . . . . .
Ag0V Ag 0.66730(4) 0.32543(5) 0.84542(3) 0.0563(2) Uani 1 1 d . . . . .
Cl0W Cl 0.76611(11) 0.14509(12) 0.68808(9) 0.0475(5) Uani 1 1 d . . . . .
Cl0X Cl 0.68121(12) 0.44727(13) 0.62410(9) 0.0514(5) Uani 1 1 d . . . . .
Cl0Y Cl 0.65753(12) 0.14724(12) 0.81072(9) 0.0487(5) Uani 1 1 d . . . . .
P0Z P 0.54870(12) 0.17066(13) 0.59751(9) 0.0443(5) Uani 1 1 d . . . . .
S10 S 0.77243(12) 0.26180(13) 0.59978(9) 0.0462(5) Uani 1 1 d . . . . .
S11 S 0.52115(12) 0.43077(13) 0.57372(9) 0.0477(5) Uani 1 1 d . . . . .
S12 S 0.95254(12) 0.36711(13) 0.61433(10) 0.0502(6) Uani 1 1 d . . . . .
Cl13 Cl 0.56979(12) 0.45899(14) 0.86502(10) 0.0574(6) Uani 1 1 d . . . . .
S14 S 0.34640(12) 0.34507(13) 0.87575(9) 0.0498(6) Uani 1 1 d . . . . .
Cl15 Cl 0.99435(12) 0.36944(15) 0.79667(10) 0.0609(7) Uani 1 1 d . . . . .
Cl16 Cl 0.60496(14) 0.52904(13) 0.74312(11) 0.0588(6) Uani 1 1 d . . . . .
P17 P 0.47940(13) 0.11661(13) 0.77455(10) 0.0488(6) Uani 1 1 d . . . . .
P18 P 0.38857(12) 0.52692(13) 0.76059(10) 0.0462(6) Uani 1 1 d . . . . .
P19 P 0.69583(13) 0.09939(13) 0.55975(10) 0.0466(6) Uani 1 1 d . . . . .
S01A S 0.58149(12) 0.27177(14) 0.89558(9) 0.0513(6) Uani 1 1 d . . . . .
Cl1B Cl 0.31786(13) 0.32447(15) 0.69214(11) 0.0619(7) Uani 1 1 d . . . . .
P1C P 0.99145(13) 0.15271(14) 0.61021(10) 0.0504(6) Uani 1 1 d . . . . .
P1D P 0.45146(14) 0.60261(14) 0.67595(11) 0.0539(6) Uani 1 1 d . . . . .
P1E P 0.42890(14) 0.13419(15) 0.88476(11) 0.0548(6) Uani 1 1 d . . . . .
P01F P 0.95320(13) 0.14205(15) 0.72114(11) 0.0533(6) Uani 1 1 d . . . . .
P01G P 0.85044(14) 0.20522(15) 0.89836(11) 0.0560(7) Uani 1 1 d . . . . .
S01H S 0.72971(14) 0.46646(17) 0.91719(11) 0.0642(7) Uani 1 1 d . . . . .
P01I P 0.74334(16) 0.12700(15) 0.93845(11) 0.0586(7) Uani 1 1 d . . . . .
P01J P 0.81459(16) 0.55107(15) 0.72778(13) 0.0617(7) Uani 1 1 d . . . . .
P01K P 0.6951(3) 0.6198(2) 0.80851(18) 0.1014(14) Uani 1 1 d . . . . .
C1 C 0.8048(5) 0.3008(5) 0.5442(4) 0.0447(16) Uani 1 1 d . . . . .
C2 C 1.0815(5) 0.1248(5) 0.5964(4) 0.0504(19) Uani 1 1 d . . . . .
C3 C 0.8360(5) 0.3521(5) 0.5562(4) 0.0520(19) Uani 1 1 d . . . . .
H3A H 0.871167 0.333758 0.572378 0.062 Uiso 1 1 calc R U . . .
H3B H 0.801753 0.383405 0.578296 0.062 Uiso 1 1 calc R U . . .
C4 C 0.3510(5) 0.1570(6) 0.7676(4) 0.056(2) Uani 1 1 d . . . . .
H4 H 0.363088 0.195964 0.759761 0.067 Uiso 1 1 calc R U . . .
C5 C 0.3976(5) 0.1059(5) 0.7754(4) 0.052(2) Uani 1 1 d . . . . .
C6 C 0.3650(5) 0.5389(5) 0.8251(4) 0.052(2) Uani 1 1 d . . . . .
C7 C 0.2663(6) 0.3558(7) 0.8601(5) 0.064(2) Uani 1 1 d . . . . .
C8 C 0.7434(5) 0.0225(5) 0.5712(4) 0.0503(18) Uani 1 1 d . . . . .
C9 C 0.451(2) 0.420(2) 0.5533(15) 0.041(3) Uani 0.5 1 d . . P A 1
C10 C 0.3758(3) 0.6531(3) 0.6677(3) 0.055(2) Uani 1 1 d G . . . .
C11 C 0.3485(4) 0.7089(4) 0.6938(3) 0.067(3) Uani 1 1 d G . . . .
H11 H 0.370372 0.721405 0.715167 0.081 Uiso 1 1 calc R U . . .
C12 C 0.2891(4) 0.7463(3) 0.6886(3) 0.083(4) Uani 1 1 d G . . . .
H12 H 0.270382 0.784431 0.706438 0.099 Uiso 1 1 calc R U . . .
C13 C 0.2570(4) 0.7279(4) 0.6574(3) 0.078(3) Uani 1 1 d G . . . .
H13 H 0.216432 0.753529 0.653814 0.093 Uiso 1 1 calc R U . . .
C14 C 0.2844(4) 0.6721(4) 0.6313(3) 0.074(3) Uani 1 1 d G . . . .
H14 H 0.262471 0.659600 0.609919 0.089 Uiso 1 1 calc R U . . .
C15 C 0.3438(4) 0.6347(3) 0.6365(3) 0.064(3) Uani 1 1 d G . . . .
H15 H 0.362461 0.596573 0.618647 0.077 Uiso 1 1 calc R U . . .
C16 C 0.7499(5) 0.3286(5) 0.5190(4) 0.0501(18) Uani 1 1 d . . . . .
H16A H 0.730575 0.294978 0.510722 0.060 Uiso 1 1 calc R U . . .
H16B H 0.713990 0.359043 0.540773 0.060 Uiso 1 1 calc R U . . .
C17 C 0.4133(5) 0.1915(6) 0.6247(5) 0.061(3) Uani 1 1 d . . . . .
H17 H 0.416844 0.233618 0.626787 0.074 Uiso 1 1 calc R U . . .
C18 C 0.4696(5) 0.1460(6) 0.6111(4) 0.0509(19) Uani 1 1 d . . . . .
C19 C 0.3025(6) 0.4964(6) 0.7141(4) 0.057(2) Uani 1 1 d . . . . .
H19 H 0.334677 0.458111 0.706546 0.068 Uiso 1 1 calc R U . . .
C20 C 0.2692(6) 0.0945(6) 0.7832(5) 0.061(3) Uani 1 1 d . . . . .
H20 H 0.224818 0.091094 0.786104 0.073 Uiso 1 1 calc R U . . .
C21 C 0.4164(6) 0.5284(6) 0.8477(4) 0.057(2) Uani 1 1 d . . . . .
H21 H 0.461520 0.518693 0.829275 0.068 Uiso 1 1 calc R U . . .
C22 C 0.8279(6) 0.4210(6) 0.9601(5) 0.064(2) Uani 1 1 d . . . . .
H22A H 0.836910 0.381259 0.942041 0.076 Uiso 1 1 calc R U . . .
H22B H 0.790860 0.420433 0.989116 0.076 Uiso 1 1 calc R U . . .
C23 C 0.5999(5) 0.2448(5) 0.5246(4) 0.052(2) Uani 1 1 d . . . . .
H23 H 0.619347 0.257883 0.547315 0.062 Uiso 1 1 calc R U . . .
C24 C 0.9716(3) 0.1212(4) 0.5595(2) 0.053(2) Uani 1 1 d G . . . .
C25 C 1.0105(3) 0.1308(4) 0.5141(3) 0.066(3) Uani 1 1 d G . . . .
H25 H 1.045426 0.152112 0.510740 0.079 Uiso 1 1 calc R U . . .
C26 C 0.9981(4) 0.1092(4) 0.47359(19) 0.065(3) Uani 1 1 d G . . . .
H26 H 1.024668 0.115763 0.442539 0.078 Uiso 1 1 calc R U . . .
C27 C 0.9470(4) 0.0780(4) 0.4785(2) 0.066(3) Uani 1 1 d G . . . .
H27 H 0.938538 0.063209 0.450820 0.079 Uiso 1 1 calc R U . . .
C28 C 0.9081(3) 0.0683(4) 0.5239(3) 0.067(3) Uani 1 1 d G . . . .
H28 H 0.873166 0.047004 0.527301 0.080 Uiso 1 1 calc R U . . .
C29 C 0.9205(3) 0.0899(4) 0.5645(2) 0.062(3) Uani 1 1 d G . . . .
H29 H 0.893924 0.083352 0.595503 0.074 Uiso 1 1 calc R U . . .
C30 C 0.2856(6) 0.1515(6) 0.7713(5) 0.061(3) Uani 1 1 d . . . . .
H30 H 0.253254 0.186349 0.765595 0.074 Uiso 1 1 calc R U . . .
C31 C 0.2990(6) 0.5501(6) 0.8531(4) 0.060(3) Uani 1 1 d . . . . .
H31 H 0.263284 0.556034 0.838420 0.073 Uiso 1 1 calc R U . . .
C32 C 0.7070(5) 0.1016(5) 0.4945(4) 0.054(2) Uani 1 1 d . . . . .
C33 C 1.1901(5) 0.1454(6) 0.5822(4) 0.059(2) Uani 1 1 d . . . . .
H33 H 1.218127 0.174103 0.579833 0.071 Uiso 1 1 calc R U . . .
C34 C 0.3132(5) 0.5434(5) 0.7410(4) 0.0507(19) Uani 1 1 d . . . . .
C35 C 0.5589(5) 0.2034(5) 0.5376(4) 0.0467(17) Uani 1 1 d . . . . .
C36 C 0.6130(5) 0.2677(6) 0.4781(4) 0.057(2) Uani 1 1 d . . . . .
H36 H 0.640150 0.297279 0.469291 0.069 Uiso 1 1 calc R U . . .
C37 C 0.6099(5) 0.0946(5) 0.5882(4) 0.0496(19) Uani 1 1 d . . . . .
H37A H 0.608118 0.074589 0.619749 0.059 Uiso 1 1 calc R U . . .
H37B H 0.596429 0.067076 0.568148 0.059 Uiso 1 1 calc R U . . .
C38 C 0.7759(6) 0.0199(6) 0.6066(5) 0.058(2) Uani 1 1 d . . . . .
H38 H 0.773197 0.056513 0.624098 0.070 Uiso 1 1 calc R U . . .
C39 C 0.8345(6) 0.3124(6) 0.4401(4) 0.063(2) Uani 1 1 d . . . . .
H39A H 0.815266 0.278280 0.432357 0.075 Uiso 1 1 calc R U . . .
H39B H 0.852976 0.332348 0.409749 0.075 Uiso 1 1 calc R U . . .
C40 C 1.0270(6) 0.3839(7) 0.6269(5) 0.063(2) Uani 1 1 d . . . . .
C41 C 0.3456(6) 0.1167(6) 0.6299(5) 0.066(3) Uani 1 1 d . . . . .
H41 H 0.303397 0.106200 0.636154 0.080 Uiso 1 1 calc R U . . .
C42 C 0.7460(6) -0.0301(6) 0.5470(5) 0.060(2) Uani 1 1 d . . . . .
H42 H 0.721437 -0.027844 0.523729 0.071 Uiso 1 1 calc R U . . .
C43 C 0.8901(6) 0.2853(6) 0.4643(4) 0.0567(19) Uani 1 1 d . . . . .
H43 H 0.926068 0.254444 0.442215 0.068 Uiso 1 1 calc R U . . .
C44 C 0.3499(6) 0.1778(7) 0.6359(5) 0.068(3) Uani 1 1 d . . . . .
H44 H 0.310943 0.209659 0.647300 0.081 Uiso 1 1 calc R U . . .
C45 C 0.3147(6) 0.0422(6) 0.7911(5) 0.066(3) Uani 1 1 d . . . . .
H45 H 0.302669 0.003131 0.798581 0.079 Uiso 1 1 calc R U . . .
C46 C 0.9553(5) 0.1111(6) 0.6624(4) 0.054(2) Uani 1 1 d . . . . .
H46A H 0.980565 0.067096 0.659261 0.065 Uiso 1 1 calc R U . . .
H46B H 0.909096 0.110926 0.662133 0.065 Uiso 1 1 calc R U . . .
C47 C 1.1214(5) 0.1667(6) 0.5948(5) 0.061(3) Uani 1 1 d . . . . .
H47 H 1.102053 0.209672 0.602280 0.073 Uiso 1 1 calc R U . . .
C48 C 0.5864(6) 0.2471(6) 0.4452(5) 0.064(3) Uani 1 1 d . . . . .
H48 H 0.597074 0.261347 0.413165 0.077 Uiso 1 1 calc R U . . .
C49 C 0.2871(6) 0.5524(6) 0.9020(4) 0.061(3) Uani 1 1 d . . . . .
H49 H 0.242125 0.559579 0.920689 0.073 Uiso 1 1 calc R U . . .
C50 C 0.8664(5) 0.3839(6) 0.5096(4) 0.0558(18) Uani 1 1 d . . . . .
H50 H 0.885982 0.418088 0.517709 0.067 Uiso 1 1 calc R U . . .
C51 C 1.0499(6) 0.3423(7) 0.6659(5) 0.069(2) Uani 1 1 d . . . . .
H51A H 1.060711 0.297825 0.655811 0.083 Uiso 1 1 calc R U . . .
H51B H 1.013949 0.348299 0.696167 0.083 Uiso 1 1 calc R U . . .
C52 C 0.8244(4) 0.2434(4) 0.9576(2) 0.063(2) Uani 1 1 d G . . . .
C53 C 0.7602(4) 0.2800(4) 0.9721(3) 0.070(3) Uani 1 1 d G . . . .
H53 H 0.732939 0.287726 0.950375 0.084 Uiso 1 1 calc R U . . .
C54 C 0.7358(4) 0.3054(4) 1.0184(3) 0.080(3) Uani 1 1 d G . . . .
H54 H 0.691937 0.330507 1.028279 0.096 Uiso 1 1 calc R U . . .
C55 C 0.7756(5) 0.2942(5) 1.0501(2) 0.090(4) Uani 1 1 d G . . . .
H55 H 0.758996 0.311565 1.081775 0.108 Uiso 1 1 calc R U . . .
C56 C 0.8398(5) 0.2575(5) 1.0357(3) 0.087(4) Uani 1 1 d G . . . .
H56 H 0.867057 0.249842 1.057369 0.105 Uiso 1 1 calc R U . . .
C57 C 0.8642(3) 0.2321(4) 0.9894(3) 0.077(3) Uani 1 1 d G . . . .
H57 H 0.908061 0.207059 0.979465 0.092 Uiso 1 1 calc R U . . .
C58 C 1.1080(5) 0.0605(6) 0.5867(4) 0.059(2) Uani 1 1 d . . . . .
H58 H 1.080436 0.031777 0.587949 0.071 Uiso 1 1 calc R U . . .
C59 C 0.3786(5) 0.0491(5) 0.7878(5) 0.058(3) Uani 1 1 d . . . . .
H59 H 0.410501 0.014332 0.794085 0.070 Uiso 1 1 calc R U . . .
C60 C 0.4916(5) 0.0914(5) 0.8337(4) 0.050(2) Uani 1 1 d . . . . .
H60A H 0.491411 0.046430 0.837040 0.060 Uiso 1 1 calc R U . . .
H60B H 0.535991 0.096419 0.835053 0.060 Uiso 1 1 calc R U . . .
C61 C 0.2658(6) 0.5995(6) 0.7524(5) 0.061(2) Uani 1 1 d . . . . .
H61 H 0.272527 0.631431 0.770563 0.073 Uiso 1 1 calc R U . . .
C62 C 0.4318(5) 0.5908(5) 0.7407(4) 0.0462(18) Uani 1 1 d . . . . .
H62A H 0.403624 0.630064 0.757097 0.055 Uiso 1 1 calc R U . . .
H62B H 0.473718 0.581926 0.750744 0.055 Uiso 1 1 calc R U . . .
C63 C 0.2453(6) 0.5062(7) 0.6986(5) 0.071(3) Uani 1 1 d . . . . .
H63 H 0.238797 0.474822 0.679855 0.086 Uiso 1 1 calc R U . . .
C64 C 0.8597(5) 0.2528(5) 0.5107(4) 0.0533(18) Uani 1 1 d . . . . .
H64A H 0.840922 0.218592 0.502599 0.064 Uiso 1 1 calc R U . . .
H64B H 0.894764 0.234469 0.526965 0.064 Uiso 1 1 calc R U . . .
C65 C 0.1969(6) 0.5614(7) 0.7103(5) 0.067(3) Uani 1 1 d . . . . .
H65 H 0.157088 0.566871 0.700353 0.081 Uiso 1 1 calc R U . . .
C66 C 1.2178(6) 0.0823(6) 0.5731(5) 0.063(3) Uani 1 1 d . . . . .
H66 H 1.264718 0.067507 0.565352 0.076 Uiso 1 1 calc R U . . .
C67 C 0.4010(6) 0.5324(6) 0.8975(4) 0.062(3) Uani 1 1 d . . . . .
H67 H 0.436222 0.526232 0.912660 0.074 Uiso 1 1 calc R U . . .
C68 C 1.1775(6) 0.0414(6) 0.5753(5) 0.065(3) Uani 1 1 d . . . . .
H68 H 1.197419 -0.001668 0.568736 0.078 Uiso 1 1 calc R U . . .
C69 C 0.5440(7) 0.2057(7) 0.4575(5) 0.071(3) Uani 1 1 d . . . . .
H69 H 0.524323 0.193093 0.434759 0.085 Uiso 1 1 calc R U . . .
C70 C 1.1205(4) 0.2001(4) 0.7229(3) 0.078(3) Uani 1 1 d G . . . .
H70 H 1.131420 0.238073 0.729001 0.094 Uiso 1 1 calc R U . . .
C71 C 1.0545(3) 0.1977(4) 0.7286(3) 0.073(3) Uani 1 1 d G . . . .
H71 H 1.020179 0.234119 0.738696 0.087 Uiso 1 1 calc R U . . .
C72 C 1.0385(3) 0.1422(4) 0.7197(3) 0.064(2) Uani 1 1 d G . . . .
C73 C 1.0887(4) 0.0890(3) 0.7050(3) 0.070(3) Uani 1 1 d G . . . .
H73 H 1.077820 0.050988 0.698834 0.084 Uiso 1 1 calc R U . . .
C74 C 1.1548(3) 0.0913(4) 0.6992(3) 0.077(3) Uani 1 1 d G . . . .
H74 H 1.189061 0.054941 0.689139 0.093 Uiso 1 1 calc R U . . .
C75 C 1.1707(3) 0.1469(5) 0.7082(3) 0.079(3) Uani 1 1 d G . . . .
H75 H 1.215863 0.148482 0.704222 0.095 Uiso 1 1 calc R U . . .
C76 C 0.8078(6) 0.4736(6) 0.9300(5) 0.063(2) Uani 1 1 d . . . . .
C77 C 0.8173(6) -0.0905(6) 0.5900(5) 0.066(3) Uani 1 1 d . . . . .
H77 H 0.843645 -0.129583 0.595719 0.080 Uiso 1 1 calc R U . . .
C78 C 0.6685(7) 0.0765(6) 0.4712(5) 0.066(3) Uani 1 1 d . . . . .
H78 H 0.633962 0.057640 0.489133 0.079 Uiso 1 1 calc R U . . .
C79 C 0.5204(3) 0.0202(4) 0.7049(3) 0.071(3) Uani 1 1 d G . . . .
H79 H 0.474983 0.027546 0.704527 0.085 Uiso 1 1 calc R U . . .
C80 C 0.5676(4) -0.0256(4) 0.6749(3) 0.080(3) Uani 1 1 d G . . . .
H80 H 0.554443 -0.049438 0.653929 0.095 Uiso 1 1 calc R U . . .
C81 C 0.6340(4) -0.0364(4) 0.6754(3) 0.082(4) Uani 1 1 d G . . . .
H81 H 0.666242 -0.067609 0.654868 0.099 Uiso 1 1 calc R U . . .
C82 C 0.6532(3) -0.0014(4) 0.7060(3) 0.073(3) Uani 1 1 d G . . . .
H82 H 0.698582 -0.008796 0.706405 0.088 Uiso 1 1 calc R U . . .
C83 C 0.6060(4) 0.0443(4) 0.7361(3) 0.066(3) Uani 1 1 d G . . . .
H83 H 0.619123 0.068188 0.757003 0.079 Uiso 1 1 calc R U . . .
C84 C 0.5396(3) 0.0551(3) 0.7355(3) 0.057(2) Uani 1 1 d G . . . .
C85 C 0.8635(6) 0.4744(7) 0.8853(5) 0.068(2) Uani 1 1 d . . . . .
H85A H 0.850421 0.510586 0.865622 0.082 Uiso 1 1 calc R U . . .
H85B H 0.871953 0.435821 0.866007 0.082 Uiso 1 1 calc R U . . .
C86 C 0.7155(7) 0.0315(7) 0.8937(5) 0.075(3) Uani 1 1 d . . . . .
H86 H 0.702319 0.063616 0.872931 0.090 Uiso 1 1 calc R U . . .
C87 C 0.3360(6) 0.5450(6) 0.9257(5) 0.063(3) Uani 1 1 d . . . . .
H87 H 0.325782 0.548296 0.959708 0.075 Uiso 1 1 calc R U . . .
C88 C 0.9728(6) 0.2321(7) 0.8617(5) 0.072(3) Uani 1 1 d . . . . .
H88 H 0.947312 0.271379 0.855298 0.087 Uiso 1 1 calc R U . . .
C89 C 0.9323(6) 0.0795(6) 0.7609(4) 0.061(2) Uani 1 1 d . . . . .
C90 C 0.8304(6) 0.1267(6) 0.9094(5) 0.066(2) Uani 1 1 d . . . . .
H90A H 0.843163 0.104007 0.878181 0.079 Uiso 1 1 calc R U . . .
H90B H 0.858057 0.103026 0.929522 0.079 Uiso 1 1 calc R U . . .
C91 C 0.2066(6) 0.6078(6) 0.7360(5) 0.066(3) Uani 1 1 d . . . . .
H91 H 0.173913 0.645766 0.743100 0.079 Uiso 1 1 calc R U . . .
C92 C 0.9404(6) 0.1875(7) 0.8830(5) 0.066(2) Uani 1 1 d . . . . .
C93 C 1.0969(8) 0.4291(8) 0.6873(6) 0.093(3) Uani 1 1 d . . . . .
H93A H 1.060696 0.437663 0.717388 0.112 Uiso 1 1 calc R U . . .
H93B H 1.136729 0.440355 0.692708 0.112 Uiso 1 1 calc R U . . .
C94 C 0.8108(6) 0.4117(6) 0.4861(5) 0.062(2) Uani 1 1 d . . . . .
H94A H 0.776338 0.442911 0.508254 0.075 Uiso 1 1 calc R U . . .
H94B H 0.828934 0.433412 0.456515 0.075 Uiso 1 1 calc R U . . .
C95 C 0.7796(6) 0.3610(6) 0.4737(4) 0.0587(19) Uani 1 1 d . . . . .
H95 H 0.744168 0.379661 0.457302 0.070 Uiso 1 1 calc R U . . .
C96 C 0.9184(6) 0.3382(6) 0.4775(4) 0.061(2) Uani 1 1 d . . . . .
H96A H 0.954062 0.320686 0.493462 0.073 Uiso 1 1 calc R U . . .
H96B H 0.938208 0.359057 0.447977 0.073 Uiso 1 1 calc R U . . .
C97 C 0.7405(6) 0.0453(6) 0.9305(5) 0.064(2) Uani 1 1 d . . . . .
C98 C 0.8345(8) 0.5555(7) 0.6627(5) 0.076(3) Uani 1 1 d . . . . .
C99 C 0.7372(7) 0.6080(6) 0.7456(5) 0.074(3) Uani 1 1 d . . . . .
H99A H 0.705976 0.596440 0.729465 0.089 Uiso 1 1 calc R U . . .
H99B H 0.745576 0.648747 0.732720 0.089 Uiso 1 1 calc R U . . .
C100 C 0.8141(6) -0.0392(6) 0.6164(5) 0.066(3) Uani 1 1 d . . . . .
H100 H 0.836776 -0.042767 0.640896 0.080 Uiso 1 1 calc R U . . .
C101 C 0.9475(6) 0.4242(7) 0.9288(5) 0.073(2) Uani 1 1 d . . . . .
H10A H 0.989429 0.425436 0.936872 0.088 Uiso 1 1 calc R U . . .
H10B H 0.954682 0.384904 0.910604 0.088 Uiso 1 1 calc R U . . .
C102 C 0.7589(6) 0.1286(6) 0.4672(4) 0.064(3) Uani 1 1 d . . . . .
H102 H 0.785940 0.145224 0.482421 0.077 Uiso 1 1 calc R U . . .
C103 C 0.8786(7) 0.4883(7) 1.0023(5) 0.079(3) Uani 1 1 d . . . . .
H10C H 0.843031 0.489262 1.032452 0.095 Uiso 1 1 calc R U . . .
H10D H 0.919620 0.491739 1.010715 0.095 Uiso 1 1 calc R U . . .
C104 C 0.8911(6) 0.4259(7) 0.9754(5) 0.069(2) Uani 1 1 d . . . . .
H104 H 0.903314 0.390135 0.996242 0.083 Uiso 1 1 calc R U . . .
C105 C 0.4639(6) 0.0866(7) 0.6067(6) 0.081(4) Uani 1 1 d . . . . .
H105 H 0.502940 0.054220 0.597765 0.097 Uiso 1 1 calc R U . . .
C106 C 0.5087(4) 0.0843(5) 1.0177(2) 0.072(3) Uani 1 1 d G . . . .
H106 H 0.524505 0.074404 1.045509 0.086 Uiso 1 1 calc R U . . .
C107 C 0.5535(3) 0.0782(5) 0.9725(3) 0.090(5) Uani 1 1 d G . . . .
H107 H 0.599822 0.064176 0.969365 0.108 Uiso 1 1 calc R U . . .
C108 C 0.5304(3) 0.0927(5) 0.9318(2) 0.079(4) Uani 1 1 d G . . . .
H108 H 0.560948 0.088505 0.900912 0.095 Uiso 1 1 calc R U . . .
C109 C 0.4625(4) 0.1132(5) 0.9364(2) 0.065(3) Uani 1 1 d G . . . .
C110 C 0.4178(3) 0.1193(6) 0.9816(3) 0.092(5) Uani 1 1 d G . . . .
H110 H 0.371440 0.133291 0.984747 0.111 Uiso 1 1 calc R U . . .
C111 C 0.4409(4) 0.1048(6) 1.0223(2) 0.137(10) Uani 1 1 d G . . . .
H111 H 0.410312 0.108962 1.053200 0.164 Uiso 1 1 calc R U . . .
C112 C 0.8891(8) 0.5776(7) 0.6359(6) 0.090(4) Uani 1 1 d . . . . .
H112 H 0.917084 0.591880 0.651563 0.107 Uiso 1 1 calc R U . . .
C113 C 0.8584(7) 0.5426(8) 0.9720(5) 0.077(2) Uani 1 1 d . . . . .
H113 H 0.849178 0.582566 0.990541 0.093 Uiso 1 1 calc R U . . .
C114 C 0.4690(6) 0.3590(6) 0.9381(5) 0.068(2) Uani 1 1 d . . . . .
H11A H 0.444765 0.338026 0.921257 0.081 Uiso 1 1 calc R U . . .
H11B H 0.487224 0.390636 0.916500 0.081 Uiso 1 1 calc R U . . .
C115 C 0.3707(3) 0.0301(4) 0.9050(4) 0.080(4) Uani 1 1 d G . . . .
H115 H 0.414434 0.006683 0.903290 0.096 Uiso 1 1 calc R U . . .
C116 C 0.3596(3) 0.0942(4) 0.8976(3) 0.063(2) Uani 1 1 d G . . . .
C117 C 0.2956(4) 0.1284(3) 0.9001(3) 0.073(3) Uani 1 1 d G . . . .
H117 H 0.288047 0.172208 0.895016 0.088 Uiso 1 1 calc R U . . .
C118 C 0.2427(3) 0.0987(4) 0.9100(4) 0.086(4) Uani 1 1 d G . . . .
H118 H 0.198972 0.122110 0.911728 0.103 Uiso 1 1 calc R U . . .
C119 C 0.2538(4) 0.0346(4) 0.9174(4) 0.090(4) Uani 1 1 d G . . . .
H119 H 0.217627 0.014298 0.924221 0.108 Uiso 1 1 calc R U . . .
C120 C 0.3178(5) 0.0004(3) 0.9149(4) 0.097(5) Uani 1 1 d G . . . .
H120 H 0.325358 -0.043416 0.920003 0.116 Uiso 1 1 calc R U . . .
C121 C 0.6812(7) 0.0796(7) 0.4221(5) 0.075(3) Uani 1 1 d . . . . .
H121 H 0.655073 0.062214 0.406519 0.090 Uiso 1 1 calc R U . . .
C122 C 0.7839(6) -0.0870(6) 0.5560(5) 0.067(3) Uani 1 1 d . . . . .
H122 H 0.786443 -0.123424 0.538283 0.080 Uiso 1 1 calc R U . . .
C123 C 1.1125(6) 0.3606(8) 0.6737(6) 0.080(2) Uani 1 1 d . . . . .
H123 H 1.126047 0.335346 0.700480 0.095 Uiso 1 1 calc R U . . .
C124 C 0.8698(7) 0.0628(7) 0.7638(5) 0.073(3) Uani 1 1 d . . . . .
H124 H 0.841877 0.082940 0.744402 0.088 Uiso 1 1 calc R U . . .
C125 C 0.7694(8) 0.1304(7) 0.4183(5) 0.079(3) Uani 1 1 d . . . . .
H125 H 0.804290 0.148196 0.399316 0.095 Uiso 1 1 calc R U . . .
C126 C 0.7609(9) 0.0002(8) 0.9602(7) 0.094(4) Uani 1 1 d . . . . .
H126 H 0.778548 0.010219 0.985061 0.112 Uiso 1 1 calc R U . . .
C127 C 1.0415(6) 0.2226(8) 0.8489(6) 0.079(3) Uani 1 1 d . . . . .
H127 H 1.062191 0.254645 0.833290 0.095 Uiso 1 1 calc R U . . .
C128 C 0.7310(8) -0.0737(8) 0.9145(7) 0.094(4) Uani 1 1 d . . . . .
H128 H 0.730084 -0.115598 0.908257 0.113 Uiso 1 1 calc R U . . .
C129 C 0.7947(7) 0.5366(7) 0.9572(5) 0.074(2) Uani 1 1 d . . . . .
H12A H 0.757060 0.538811 0.986180 0.089 Uiso 1 1 calc R U . . .
H12B H 0.782593 0.571714 0.936260 0.089 Uiso 1 1 calc R U . . .
C130 C 0.5313(6) 0.1832(6) 0.5044(4) 0.058(2) Uani 1 1 d . . . . .
H130 H 0.503662 0.153959 0.513486 0.069 Uiso 1 1 calc R U . . .
C131 C 1.0799(7) 0.1671(8) 0.8586(6) 0.082(4) Uani 1 1 d . . . . .
H131 H 1.127110 0.159762 0.848700 0.098 Uiso 1 1 calc R U . . .
C132 C 1.0770(8) 0.4652(8) 0.6496(6) 0.092(3) Uani 1 1 d . . . . .
H132 H 1.068769 0.510390 0.658302 0.110 Uiso 1 1 calc R U . . .
C133 C 0.4019(6) 0.0724(7) 0.6152(7) 0.089(5) Uani 1 1 d . . . . .
H133 H 0.399102 0.030611 0.610439 0.107 Uiso 1 1 calc R U . . .
C134 C 1.0105(7) 0.4520(7) 0.6413(6) 0.081(3) Uani 1 1 d . . . . .
H13A H 0.973809 0.460548 0.671123 0.097 Uiso 1 1 calc R U . . .
H13B H 0.996893 0.478697 0.615579 0.097 Uiso 1 1 calc R U . . .
C135 C 1.0488(7) 0.1227(9) 0.8828(7) 0.106(6) Uani 1 1 d . . . . .
H135 H 1.074685 0.086257 0.893037 0.127 Uiso 1 1 calc R U . . .
C136 C 0.5017(4) 0.7126(4) 0.6545(4) 0.079(3) Uani 1 1 d G . . . .
H136 H 0.456873 0.735247 0.660205 0.095 Uiso 1 1 calc R U . . .
C137 C 0.5158(4) 0.6481(4) 0.6595(4) 0.071(3) Uani 1 1 d G . . . .
C138 C 0.5815(4) 0.6150(3) 0.6512(4) 0.081(3) Uani 1 1 d G . . . .
H138 H 0.591103 0.570929 0.654525 0.097 Uiso 1 1 calc R U . . .
C139 C 0.6331(3) 0.6464(5) 0.6379(4) 0.099(5) Uani 1 1 d G . . . .
H139 H 0.677921 0.623802 0.632221 0.118 Uiso 1 1 calc R U . . .
C140 C 0.6190(4) 0.7109(5) 0.6330(5) 0.108(6) Uani 1 1 d G . . . .
H140 H 0.654217 0.732397 0.623909 0.130 Uiso 1 1 calc R U . . .
C141 C 0.5533(5) 0.7440(3) 0.6413(5) 0.106(6) Uani 1 1 d G . . . .
H141 H 0.543693 0.788120 0.637900 0.128 Uiso 1 1 calc R U . . .
C142 C 0.7266(5) 0.1381(5) 1.0036(3) 0.079(3) Uani 1 1 d G . . . .
C143 C 0.6609(5) 0.1630(5) 1.0283(4) 0.098(4) Uani 1 1 d G . . . .
H143 H 0.627527 0.173115 1.011379 0.117 Uiso 1 1 calc R U . . .
C144 C 0.6441(5) 0.1731(6) 1.0776(4) 0.115(5) Uani 1 1 d G . . . .
H144 H 0.599262 0.190038 1.094515 0.138 Uiso 1 1 calc R U . . .
C145 C 0.6930(7) 0.1583(6) 1.1024(3) 0.127(5) Uani 1 1 d G . . . .
H145 H 0.681553 0.165122 1.136103 0.153 Uiso 1 1 calc R U . . .
C146 C 0.7587(6) 0.1334(6) 1.0777(4) 0.119(5) Uani 1 1 d G . . . .
H146 H 0.792108 0.123284 1.094555 0.143 Uiso 1 1 calc R U . . .
C147 C 0.7755(5) 0.1233(5) 1.0283(4) 0.101(4) Uani 1 1 d G . . . .
H147 H 0.820374 0.106361 1.011418 0.122 Uiso 1 1 calc R U . . .
C148 C 0.7285(8) 0.1059(7) 0.3956(6) 0.082(3) Uani 1 1 d . . . . .
H148 H 0.735178 0.108339 0.361757 0.098 Uiso 1 1 calc R U . . .
C149 C 0.8896(8) -0.0099(8) 0.8246(6) 0.089(4) Uani 1 1 d . . . . .
H149 H 0.875594 -0.041665 0.845496 0.106 Uiso 1 1 calc R U . . .
C150 C 0.5250(8) 0.3118(8) 0.9497(5) 0.081(3) Uani 1 1 d . . . . .
C151 C 0.1364(9) 0.4391(10) 0.8734(7) 0.111(4) Uani 1 1 d . . . . .
H15A H 0.143346 0.473258 0.891414 0.133 Uiso 1 1 calc R U . . .
H15B H 0.089863 0.450504 0.870965 0.133 Uiso 1 1 calc R U . . .
C152 C 0.9787(7) 0.1295(8) 0.8929(7) 0.092(5) Uani 1 1 d . . . . .
H152 H 0.958223 0.096116 0.905936 0.111 Uiso 1 1 calc R U . . .
C153 C 0.9686(7) 0.0523(8) 0.7919(5) 0.085(4) Uani 1 1 d . . . . .
H153 H 1.009072 0.063996 0.791005 0.102 Uiso 1 1 calc R U . . .
C154 C 0.9140(7) 0.5429(8) 0.9261(5) 0.084(3) Uani 1 1 d . . . . .
H15C H 0.954476 0.548799 0.934142 0.100 Uiso 1 1 calc R U . . .
H15D H 0.899983 0.577691 0.905552 0.100 Uiso 1 1 calc R U . . .
C155 C 0.7930(9) 0.5390(8) 0.6390(6) 0.097(5) Uani 1 1 d . . . . .
H155 H 0.753440 0.527471 0.657220 0.116 Uiso 1 1 calc R U . . .
C156 C 0.9289(6) 0.4791(7) 0.8990(5) 0.073(2) Uani 1 1 d . . . . .
H156 H 0.965623 0.478312 0.869031 0.087 Uiso 1 1 calc R U . . .
C157 C 0.4684(11) 0.3106(11) 1.0492(9) 0.135(4) Uani 1 1 d . . . . .
H15E H 0.434100 0.328125 1.078667 0.162 Uiso 1 1 calc R U . . .
H15F H 0.500342 0.276602 1.059695 0.162 Uiso 1 1 calc R U . . .
C158 C 1.0835(6) 0.3724(8) 0.5807(5) 0.082(3) Uani 1 1 d . . . . .
H15G H 1.070565 0.400642 0.555510 0.098 Uiso 1 1 calc R U . . .
H15H H 1.091127 0.328831 0.569251 0.098 Uiso 1 1 calc R U . . .
C159 C 0.7094(8) -0.0285(7) 0.8870(6) 0.083(3) Uani 1 1 d . . . . .
H159 H 0.689888 -0.037280 0.862817 0.100 Uiso 1 1 calc R U . . .
C160 C 1.1317(8) 0.4522(9) 0.6008(7) 0.100(3) Uani 1 1 d . . . . .
H16C H 1.115135 0.476275 0.575081 0.120 Uiso 1 1 calc R U . . .
H16D H 1.171926 0.465555 0.603272 0.120 Uiso 1 1 calc R U . . .
C161 C 0.9475(8) 0.0076(8) 0.8250(6) 0.092(4) Uani 1 1 d . . . . .
H161 H 0.972368 -0.010133 0.846930 0.111 Uiso 1 1 calc R U . . .
C162 C 0.8518(8) 0.0180(8) 0.7945(6) 0.090(4) Uani 1 1 d . . . . .
H162 H 0.811897 0.005286 0.795297 0.107 Uiso 1 1 calc R U . . .
C163 C 0.1806(10) 0.3803(11) 0.7974(8) 0.121(4) Uani 1 1 d . . . . .
H16E H 0.219920 0.373997 0.769239 0.145 Uiso 1 1 calc R U . . .
H16F H 0.140347 0.389049 0.785268 0.145 Uiso 1 1 calc R U . . .
C164 C 0.4873(9) 0.2560(9) 0.9784(6) 0.110(4) Uani 1 1 d . . . . .
H16G H 0.469950 0.236615 0.955596 0.132 Uiso 1 1 calc R U . . .
H16H H 0.521074 0.223095 0.988235 0.132 Uiso 1 1 calc R U . . .
C165 C 0.8067(10) 0.5384(8) 0.5887(6) 0.098(4) Uani 1 1 d . . . . .
H165 H 0.778811 0.524484 0.572733 0.118 Uiso 1 1 calc R U . . .
C166 C 0.8631(10) 0.5591(8) 0.5630(7) 0.103(4) Uani 1 1 d . . . . .
H166 H 0.874144 0.559567 0.528945 0.123 Uiso 1 1 calc R U . . .
C167 C 0.1307(7) 0.3353(10) 0.8768(7) 0.107(4) Uani 1 1 d . . . . .
H16I H 0.085124 0.346750 0.872535 0.129 Uiso 1 1 calc R U . . .
H16J H 0.133800 0.298283 0.897470 0.129 Uiso 1 1 calc R U . . .
C168 C 0.9023(10) 0.5785(10) 0.5869(7) 0.115(6) Uani 1 1 d . . . . .
H168 H 0.939978 0.593254 0.568923 0.138 Uiso 1 1 calc R U . . .
C169 C 0.1438(7) 0.3862(10) 0.8992(7) 0.102(3) Uani 1 1 d . . . . .
H169 H 0.111125 0.394510 0.931513 0.123 Uiso 1 1 calc R U . . .
C170 C 0.1800(8) 0.4357(10) 0.8259(7) 0.104(3) Uani 1 1 d . . . . .
H170 H 0.172989 0.475771 0.808255 0.125 Uiso 1 1 calc R U . . .
C171 C 0.7560(11) -0.0601(9) 0.9539(8) 0.119(6) Uani 1 1 d . . . . .
H171 H 0.768704 -0.092082 0.974928 0.142 Uiso 1 1 calc R U . . .
C172 C 0.1826(7) 0.3193(9) 0.8266(7) 0.103(4) Uani 1 1 d . . . . .
H172 H 0.175318 0.284085 0.809234 0.124 Uiso 1 1 calc R U . . .
C173 C 0.2504(7) 0.3032(9) 0.8409(7) 0.103(4) Uani 1 1 d . . . . .
H17A H 0.248537 0.269983 0.865169 0.123 Uiso 1 1 calc R U . . .
H17B H 0.286643 0.286337 0.812227 0.123 Uiso 1 1 calc R U . . .
C174 C 0.2598(8) 0.4096(10) 0.8285(8) 0.125(4) Uani 1 1 d . . . . .
H17C H 0.288690 0.397484 0.795860 0.150 Uiso 1 1 calc R U . . .
H17D H 0.275003 0.443681 0.840654 0.150 Uiso 1 1 calc R U . . .
C175 C 0.9808(6) 0.6198(5) 0.7687(5) 0.139(8) Uani 1 1 d G . . . .
H175 H 1.015605 0.633396 0.777096 0.167 Uiso 1 1 calc R U . . .
C176 C 0.9362(7) 0.6614(4) 0.7488(6) 0.175(12) Uani 1 1 d G . . . .
H176 H 0.940545 0.703410 0.743505 0.210 Uiso 1 1 calc R U . . .
C177 C 0.8853(6) 0.6415(4) 0.7366(6) 0.157(10) Uani 1 1 d G . . . .
H177 H 0.854809 0.669922 0.722932 0.188 Uiso 1 1 calc R U . . .
C178 C 0.8789(5) 0.5800(4) 0.7443(4) 0.081(3) Uani 1 1 d G . . . .
C179 C 0.9235(5) 0.5384(4) 0.7643(4) 0.072(3) Uani 1 1 d G . . . .
H179 H 0.919190 0.496406 0.769540 0.087 Uiso 1 1 calc R U . . .
C180 C 0.9745(5) 0.5583(5) 0.7765(4) 0.090(4) Uani 1 1 d G . . . .
H180 H 1.004927 0.529893 0.790113 0.108 Uiso 1 1 calc R U . . .
C181 C 0.2147(7) 0.3749(10) 0.9062(6) 0.103(4) Uani 1 1 d . . . . .
H18A H 0.221078 0.413702 0.918761 0.123 Uiso 1 1 calc R U . . .
H18B H 0.219990 0.341854 0.930080 0.123 Uiso 1 1 calc R U . . .
C182 C 0.3192(13) 0.3974(13) 0.5619(10) 0.052(3) Uani 0.5 1 d . . P A 1
H18C H 0.284772 0.391278 0.546504 0.062 Uiso 0.5 1 calc R U P A 1
H18D H 0.300442 0.397553 0.597122 0.062 Uiso 0.5 1 calc R U P A 1
C183 C 0.4753(10) 0.4169(11) 0.4973(7) 0.044(3) Uani 0.5 1 d . . P A 1
H18E H 0.488340 0.456398 0.485537 0.052 Uiso 0.5 1 calc R U P A 1
H18F H 0.515122 0.382355 0.487148 0.052 Uiso 0.5 1 calc R U P A 1
C184 C 0.3607(12) 0.4577(12) 0.4902(9) 0.048(3) Uani 0.5 1 d . . P A 1
H18G H 0.324830 0.449517 0.477258 0.057 Uiso 0.5 1 calc R U P A 1
H18H H 0.370669 0.498115 0.477789 0.057 Uiso 0.5 1 calc R U P A 1
C185 C 0.4016(12) 0.3428(12) 0.4912(9) 0.053(3) Uani 0.5 1 d . . P A 1
H18I H 0.364192 0.337956 0.478622 0.064 Uiso 0.5 1 calc R U P A 1
H18J H 0.439850 0.307482 0.478820 0.064 Uiso 0.5 1 calc R U P A 1
C186 C 0.3379(11) 0.4602(11) 0.5468(8) 0.046(3) Uani 0.5 1 d . . P A 1
H186 H 0.297627 0.494861 0.557661 0.056 Uiso 0.5 1 calc R U P A 1
C187 C 0.4214(11) 0.4066(12) 0.4749(8) 0.047(3) Uani 0.5 1 d . . P A 1
H187 H 0.438348 0.406181 0.439074 0.057 Uiso 0.5 1 calc R U P A 1
C188 C 0.4341(9) 0.3554(10) 0.5690(8) 0.046(3) Uani 0.5 1 d . . P A 1
H18K H 0.474736 0.321759 0.558721 0.055 Uiso 0.5 1 calc R U P A 1
H18L H 0.418263 0.354805 0.604458 0.055 Uiso 0.5 1 calc R U P A 1
C189 C 0.3807(10) 0.3433(12) 0.5470(9) 0.050(3) Uani 0.5 1 d . . P A 1
H189 H 0.368700 0.302911 0.558773 0.060 Uiso 0.5 1 calc R U P A 1
C190 C 0.3918(10) 0.4699(11) 0.5686(7) 0.047(3) Uani 0.5 1 d . . P A 1
H19A H 0.403068 0.510667 0.558622 0.056 Uiso 0.5 1 calc R U P A 1
H19B H 0.375504 0.470610 0.604076 0.056 Uiso 0.5 1 calc R U P A 1
C191 C 0.5318(7) 0.7273(5) 0.7707(4) 0.122(6) Uani 1 1 d G . . . .
H191 H 0.522664 0.758312 0.747978 0.146 Uiso 1 1 calc R U . . .
C192 C 0.4796(5) 0.7093(6) 0.8043(5) 0.128(7) Uani 1 1 d G . . . .
H192 H 0.434899 0.728097 0.804697 0.153 Uiso 1 1 calc R U . . .
C193 C 0.4930(5) 0.6639(5) 0.8375(4) 0.105(4) Uani 1 1 d G . . . .
H193 H 0.457333 0.651642 0.860543 0.126 Uiso 1 1 calc R U . . .
C194 C 0.5584(6) 0.6364(4) 0.8370(3) 0.088(3) Uani 1 1 d G . . . .
H194 H 0.567531 0.605401 0.859671 0.106 Uiso 1 1 calc R U . . .
C195 C 0.6106(4) 0.6544(5) 0.8033(4) 0.104(4) Uani 1 1 d G . . . .
C196 C 0.5972(6) 0.6998(6) 0.7701(4) 0.121(6) Uani 1 1 d G . . . .
H196 H 0.632863 0.712070 0.747106 0.145 Uiso 1 1 calc R U . . .
C197 C 0.6997(10) 0.7377(17) 0.8269(8) 0.223(6) Uiso 1 1 d G U . . .
H197 H 0.661631 0.749886 0.814800 0.268 Uiso 1 1 calc R U . . .
C198 C 0.7265(15) 0.6747(14) 0.8318(8) 0.223(6) Uiso 1 1 d G U . . .
C199 C 0.7822(15) 0.6569(9) 0.8495(9) 0.223(6) Uiso 1 1 d G U . . .
H199 H 0.800509 0.613802 0.852846 0.268 Uiso 1 1 calc R U . . .
C200 C 0.8111(10) 0.7020(17) 0.8624(8) 0.223(6) Uiso 1 1 d G U . . .
H200 H 0.849214 0.689811 0.874461 0.268 Uiso 1 1 calc R U . . .
C201 C 0.7844(14) 0.7650(14) 0.8575(8) 0.223(6) Uiso 1 1 d G U . . .
H201 H 0.804128 0.795858 0.866247 0.268 Uiso 1 1 calc R U . . .
C202 C 0.7286(15) 0.7828(10) 0.8398(9) 0.223(6) Uiso 1 1 d G U . . .
H202 H 0.710337 0.825897 0.836416 0.268 Uiso 1 1 calc R U . . .
C203 C 0.4217(9) 0.3908(10) 0.9833(6) 0.104(3) Uani 1 1 d . . . . .
H203 H 0.389649 0.427387 0.974900 0.125 Uiso 1 1 calc R U . . .
C204 C 0.5542(9) 0.3367(10) 0.9814(7) 0.116(4) Uani 1 1 d . . . . .
H20A H 0.570312 0.373758 0.966757 0.139 Uiso 1 1 calc R U . . .
H20B H 0.593117 0.305044 0.985886 0.139 Uiso 1 1 calc R U . . .
C205 C 0.4326(9) 0.2781(10) 1.0209(7) 0.110(4) Uani 1 1 d . . . . .
H205 H 0.412260 0.244339 1.038832 0.132 Uiso 1 1 calc R U . . .
C206 C 0.5023(11) 0.3563(11) 1.0329(8) 0.120(4) Uani 1 1 d . . . . .
H206 H 0.521055 0.372481 1.056940 0.145 Uiso 1 1 calc R U . . .
C207 C 0.4480(10) 0.4075(10) 1.0141(7) 0.124(4) Uani 1 1 d . . . . .
H20C H 0.411488 0.424954 1.042507 0.148 Uiso 1 1 calc R U . . .
H20D H 0.469365 0.442104 1.000156 0.148 Uiso 1 1 calc R U . . .
C208 C 0.3808(9) 0.3362(10) 1.0099(7) 0.121(4) Uani 1 1 d . . . . .
H20E H 0.347962 0.353463 1.040143 0.145 Uiso 1 1 calc R U . . .
H20F H 0.356537 0.323490 0.988501 0.145 Uiso 1 1 calc R U . . .
C209 C 1.1485(7) 0.3840(9) 0.5889(6) 0.088(3) Uani 1 1 d . . . . .
H209 H 1.185199 0.374794 0.558643 0.106 Uiso 1 1 calc R U . . .
C210 C 1.1683(7) 0.3458(9) 0.6288(6) 0.093(3) Uani 1 1 d . . . . .
H21A H 1.209075 0.355540 0.633874 0.112 Uiso 1 1 calc R U . . .
H21B H 1.177862 0.300778 0.620547 0.112 Uiso 1 1 calc R U . . .
C211 C 0.3853(15) 0.418(2) 0.5996(14) 0.103(6) Uani 0.5 1 d . . P A 2
H21C H 0.372966 0.455117 0.621129 0.124 Uiso 0.5 1 calc R U P A 2
H21D H 0.396645 0.380137 0.618231 0.124 Uiso 0.5 1 calc R U P A 2
C212 C 0.379(2) 0.432(2) 0.4813(17) 0.109(6) Uani 0.5 1 d . . P A 2
H21E H 0.344594 0.430382 0.464923 0.131 Uiso 0.5 1 calc R U P A 2
H21F H 0.416315 0.444805 0.457154 0.131 Uiso 0.5 1 calc R U P A 2
C213 C 0.446(3) 0.423(4) 0.555(3) 0.085(6) Uani 0.5 1 d . . P A 2
C214 C 0.4625(17) 0.384(2) 0.5169(15) 0.104(6) Uani 0.5 1 d . . P A 2
H21G H 0.486825 0.343088 0.525766 0.124 Uiso 0.5 1 calc R U P A 2
H21H H 0.494456 0.400530 0.490893 0.124 Uiso 0.5 1 calc R U P A 2
C215 C 0.4108(15) 0.4936(18) 0.5403(14) 0.096(6) Uani 0.5 1 d . . P A 2
H21I H 0.392227 0.522114 0.568661 0.115 Uiso 0.5 1 calc R U P A 2
H21J H 0.443460 0.511840 0.515976 0.115 Uiso 0.5 1 calc R U P A 2
C216 C 0.3516(15) 0.4813(19) 0.5180(16) 0.094(6) Uani 0.5 1 d . . P A 2
H216 H 0.331647 0.520601 0.503576 0.112 Uiso 0.5 1 calc R U P A 2
C217 C 0.404(2) 0.370(2) 0.4942(18) 0.105(6) Uani 0.5 1 d . . P A 2
H217 H 0.416808 0.336617 0.468971 0.126 Uiso 0.5 1 calc R U P A 2
C218 C 0.321(2) 0.414(2) 0.5759(18) 0.101(6) Uani 0.5 1 d . . P A 2
H218 H 0.283998 0.404459 0.602329 0.122 Uiso 0.5 1 calc R U P A 2
C219 C 0.3019(17) 0.4648(19) 0.5590(15) 0.106(6) Uani 0.5 1 d . . P A 2
H21K H 0.289614 0.497508 0.584400 0.127 Uiso 0.5 1 calc R U P A 2
H21L H 0.261402 0.463822 0.548883 0.127 Uiso 0.5 1 calc R U P A 2
C220 C 0.353(2) 0.358(2) 0.5478(17) 0.114(7) Uani 0.5 1 d . . P A 2
H22C H 0.318480 0.338479 0.542249 0.137 Uiso 0.5 1 calc R U P A 2
H22D H 0.379318 0.328994 0.566116 0.137 Uiso 0.5 1 calc R U P A 2
Au4 Au 0.72046(12) 0.54739(12) 0.85775(10) 0.0882(7) Uani 0.5 1 d . . P A 1
Ag0A Ag 0.87486(2) 0.35147(3) 0.68878(2) 0.04489(12) Uani 0.5 1 d . . P A 1
Ag1A Ag 0.76014(3) 0.39925(3) 0.84852(2) 0.05197(13) Uani 0.43 1 d . . P A 1
Ag2A Ag 0.66096(2) 0.32485(2) 0.74702(2) 0.03789(10) Uani 0.38 1 d . . P A 1
Au5 Au 0.52642(2) 0.37323(2) 0.64457(2) 0.03924(11) Uani 0.46 1 d . . P A .
Ag Ag 0.43665(2) 0.33118(3) 0.80403(2) 0.04342(11) Uani 0.49 1 d . . P A 1


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au01 Au02 2.6851(6) . y
Au01 Au05 2.7129(6) . y
Au01 Au5 2.6940(6) . y
Au01 Ag 2.7194(6) . y
Au02 Au03 2.8957(6) . y
Au02 Ag0Q 2.8426(8) . y
Au02 P17 2.284(3) . y
Au02 Ag 2.9036(7) . y
Au03 Ag0P 2.8911(8) . y
Au03 P0Z 2.298(3) . y
Au03 Au5 2.9248(7) . y
Au04 Au07 2.6828(6) . y
Au04 Au0B 2.7233(6) . y
Au04 Au2 2.7167(6) . y
Au04 Ag1A 2.6835(7) . y
Au05 Ag0M 2.9004(8) . y
Au05 Ag0R 2.8014(8) . y
Au05 P18 2.293(3) . y
Au05 Ag 2.8572(7) . y
Au06 Ag0L 3.3416(9) . y
Au06 S10 2.309(2) . y
Au06 P19 2.252(3) . y
Au07 Au0B 2.9059(7) . y
Au07 Au2 2.9171(7) . y
Au07 Ag0O 2.8281(8) . y
Au07 P01F 2.285(3) . y
Au08 Au2 2.9508(7) . y
Au08 S12 2.341(3) . y
Au08 P1C 2.266(3) . y
Au09 Au2 2.8466(7) . y
Au09 Ag0N 2.9167(8) . y
Au09 Ag0S 2.8083(8) . y
Au09 P01J 2.300(3) . y
Au0B Ag0U 2.8944(9) . y
Au0B P01G 2.313(3) . y
Au0B Ag1A 2.9068(8) . y
Au0C S11 2.346(3) . y
Au0C P1D 2.276(3) . y
Au0C Au5 3.0515(7) . y
Au0D S14 2.337(3) . y
Au0D P1E 2.264(3) . y
Au0D Ag 2.9787(7) . y
Au0E Ag0V 3.3258(10) . y
Au0E S01A 2.303(3) . y
Au0E P01I 2.248(3) . y
Au2 Ag0N 2.8761(9) . y
Au2 Ag0O 2.9121(9) . y
Au2 Ag0T 2.9098(9) . y
Au2 S12 2.407(3) . y
Au1A Ag0S 3.2235(16) . y
Au1A S01H 2.298(4) . y
Au1A P01K 2.348(5) . y
Ag0K Cl1B 2.398(3) . y
Ag0K Au5 2.9279(8) . y
Ag0K Ag 2.9110(9) . y
Ag0L S10 2.500(3) . y
Ag0L Ag2A 2.8921(8) . y
Ag0L Au5 2.8637(9) . y
Ag0M Ag0Q 2.9008(11) . y
Ag0M Cl13 2.548(3) . y
Ag0M Ag2A 2.8315(9) . y
Ag0N Cl0X 2.542(3) . y
Ag0N Ag2A 2.8397(8) . y
Ag0O Cl0W 2.838(3) . y
Ag0O S10 2.521(3) . y
Ag0P Cl0W 2.555(2) . y
Ag0P Ag2A 2.8823(9) . y
Ag0Q Cl0Y 2.817(3) . y
Ag0Q S01A 2.527(3) . y
Ag0Q Ag 2.9110(9) . y
Ag0R Cl0X 2.617(3) . y
Ag0R Cl16 2.585(3) . y
Ag0R Ag2A 2.9073(9) . y
Ag0S Cl13 2.587(3) . y
Ag0S Cl16 2.590(3) . y
Ag0S Ag2A 2.9253(9) . y
Ag0T Cl15 2.402(2) . y
Ag0T Ag1A 2.9415(9) . y
Ag0U Ag0V 2.9494(13) . y
Ag0U Cl0Y 2.552(2) . y
Ag0U Ag2A 2.8651(9) . y
Ag0V S01A 2.503(3) . y
Ag0V Ag1A 2.8508(10) . y
Ag0V Ag2A 2.8833(9) . y
P0Z C18 1.829(10) . ?
P0Z C35 1.825(11) . ?
P0Z C37 1.856(11) . ?
S10 C1 1.831(10) . ?
S11 C9 1.81(5) . ?
S11 C213 1.87(7) . ?
S11 Au5 2.375(3) . y
S12 C40 1.839(10) . ?
S14 C7 1.849(11) . ?
S14 Ag 2.402(3) . y
P17 C5 1.810(10) . ?
P17 C60 1.842(11) . ?
P17 C84 1.824(6) . ?
P18 C6 1.811(11) . ?
P18 C34 1.804(10) . ?
P18 C62 1.840(10) . ?
P19 C8 1.832(11) . ?
P19 C32 1.837(12) . ?
P19 C37 1.826(10) . ?
S01A C150 1.820(15) . ?
P1C C2 1.822(10) . ?
P1C C24 1.831(6) . ?
P1C C46 1.814(11) . ?
P1D C10 1.810(6) . ?
P1D C62 1.825(11) . ?
P1D C137 1.830(7) . ?
P1E C60 1.830(11) . ?
P1E C109 1.822(6) . ?
P1E C116 1.835(6) . ?
P01F C46 1.840(12) . ?
P01F C72 1.814(6) . ?
P01F C89 1.810(13) . ?
P01G C52 1.829(7) . ?
P01G C90 1.863(13) . ?
P01G C92 1.807(12) . ?
S01H C76 1.843(12) . ?
S01H Au4 2.432(4) . y
S01H Ag1A 2.380(3) . y
P01I C90 1.825(13) . ?
P01I C97 1.834(13) . ?
P01I C142 1.836(8) . ?
P01J C98 1.817(15) . ?
P01J C99 1.799(14) . ?
P01J C178 1.814(7) . ?
P01K C99 1.801(15) . ?
P01K C195 1.838(9) . ?
P01K C198 1.740(19) . ?
P01K Au4 2.164(5) . y
C1 C3 1.526(14) . ?
C1 C16 1.540(13) . ?
C1 C64 1.534(15) . ?
C2 C47 1.380(16) . ?
C2 C58 1.408(17) . ?
C3 H3A 0.9900 . ?
C3 H3B 0.9900 . ?
C3 C50 1.543(15) . ?
C4 H4 0.9500 . ?
C4 C5 1.377(16) . ?
C4 C30 1.407(15) . ?
C5 C59 1.400(15) . ?
C6 C21 1.394(16) . ?
C6 C31 1.399(16) . ?
C7 C173 1.444(19) . ?
C7 C174 1.47(2) . ?
C7 C181 1.491(19) . ?
C8 C38 1.373(16) . ?
C8 C42 1.361(16) . ?
C9 C183 1.56(4) . ?
C9 C188 1.56(5) . ?
C9 C190 1.46(5) . ?
C10 C11 1.3900 . ?
C10 C15 1.3900 . ?
C11 H11 0.9500 . ?
C11 C12 1.3900 . ?
C12 H12 0.9500 . ?
C12 C13 1.3900 . ?
C13 H13 0.9500 . ?
C13 C14 1.3900 . ?
C14 H14 0.9500 . ?
C14 C15 1.3900 . ?
C15 H15 0.9500 . ?
C16 H16A 0.9900 . ?
C16 H16B 0.9900 . ?
C16 C95 1.516(15) . ?
C17 H17 0.9500 . ?
C17 C18 1.357(16) . ?
C17 C44 1.404(15) . ?
C18 C105 1.351(17) . ?
C19 H19 0.9500 . ?
C19 C34 1.412(16) . ?
C19 C63 1.381(16) . ?
C20 H20 0.9500 . ?
C20 C30 1.379(17) . ?
C20 C45 1.384(18) . ?
C21 H21 0.9500 . ?
C21 C67 1.390(16) . ?
C22 H22A 0.9900 . ?
C22 H22B 0.9900 . ?
C22 C76 1.472(19) . ?
C22 C104 1.556(15) . ?
C23 H23 0.9500 . ?
C23 C35 1.374(15) . ?
C23 C36 1.393(16) . ?
C24 C25 1.3900 . ?
C24 C29 1.3900 . ?
C25 H25 0.9500 . ?
C25 C26 1.3900 . ?
C26 H26 0.9500 . ?
C26 C27 1.3900 . ?
C27 H27 0.9500 . ?
C27 C28 1.3900 . ?
C28 H28 0.9500 . ?
C28 C29 1.3900 . ?
C29 H29 0.9500 . ?
C30 H30 0.9500 . ?
C31 H31 0.9500 . ?
C31 C49 1.369(16) . ?
C32 C78 1.402(16) . ?
C32 C102 1.413(17) . ?
C33 H33 0.9500 . ?
C33 C47 1.390(15) . ?
C33 C66 1.385(17) . ?
C34 C61 1.395(16) . ?
C35 C130 1.386(14) . ?
C36 H36 0.9500 . ?
C36 C48 1.366(17) . ?
C37 H37A 0.9900 . ?
C37 H37B 0.9900 . ?
C38 H38 0.9500 . ?
C38 C100 1.432(17) . ?
C39 H39A 0.9900 . ?
C39 H39B 0.9900 . ?
C39 C43 1.531(16) . ?
C39 C95 1.541(17) . ?
C40 C51 1.533(18) . ?
C40 C134 1.508(19) . ?
C40 C158 1.529(17) . ?
C41 H41 0.9500 . ?
C41 C44 1.388(18) . ?
C41 C133 1.346(19) . ?
C42 H42 0.9500 . ?
C42 C122 1.383(18) . ?
C43 H43 1.0000 . ?
C43 C64 1.547(15) . ?
C43 C96 1.530(16) . ?
C44 H44 0.9500 . ?
C45 H45 0.9500 . ?
C45 C59 1.385(15) . ?
C46 H46A 0.9900 . ?
C46 H46B 0.9900 . ?
C47 H47 0.9500 . ?
C48 H48 0.9500 . ?
C48 C69 1.395(18) . ?
C49 H49 0.9500 . ?
C49 C87 1.374(17) . ?
C50 H50 1.0000 . ?
C50 C94 1.522(16) . ?
C50 C96 1.460(17) . ?
C51 H51A 0.9900 . ?
C51 H51B 0.9900 . ?
C51 C123 1.554(14) . ?
C52 C53 1.3900 . ?
C52 C57 1.3900 . ?
C53 H53 0.9500 . ?
C53 C54 1.3900 . ?
C54 H54 0.9500 . ?
C54 C55 1.3900 . ?
C55 H55 0.9500 . ?
C55 C56 1.3900 . ?
C56 H56 0.9500 . ?
C56 C57 1.3900 . ?
C57 H57 0.9500 . ?
C58 H58 0.9500 . ?
C58 C68 1.400(15) . ?
C59 H59 0.9500 . ?
C60 H60A 0.9900 . ?
C60 H60B 0.9900 . ?
C61 H61 0.9500 . ?
C61 C91 1.439(16) . ?
C62 H62A 0.9900 . ?
C62 H62B 0.9900 . ?
C63 H63 0.9500 . ?
C63 C65 1.392(18) . ?
C64 H64A 0.9900 . ?
C64 H64B 0.9900 . ?
C65 H65 0.9500 . ?
C65 C91 1.369(18) . ?
C66 H66 0.9500 . ?
C66 C68 1.366(17) . ?
C67 H67 0.9500 . ?
C67 C87 1.383(17) . ?
C68 H68 0.9500 . ?
C69 H69 0.9500 . ?
C69 C130 1.400(18) . ?
C70 H70 0.9500 . ?
C70 C71 1.3900 . ?
C70 C75 1.3900 . ?
C71 H71 0.9500 . ?
C71 C72 1.3900 . ?
C72 C73 1.3900 . ?
C73 H73 0.9500 . ?
C73 C74 1.3900 . ?
C74 H74 0.9500 . ?
C74 C75 1.3900 . ?
C75 H75 0.9500 . ?
C76 C85 1.507(17) . ?
C76 C129 1.554(18) . ?
C77 H77 0.9500 . ?
C77 C100 1.365(18) . ?
C77 C122 1.352(19) . ?
C78 H78 0.9500 . ?
C78 C121 1.373(18) . ?
C79 H79 0.9500 . ?
C79 C80 1.3900 . ?
C79 C84 1.3900 . ?
C80 H80 0.9500 . ?
C80 C81 1.3900 . ?
C81 H81 0.9500 . ?
C81 C82 1.3900 . ?
C82 H82 0.9500 . ?
C82 C83 1.3900 . ?
C83 H83 0.9500 . ?
C83 C84 1.3900 . ?
C85 H85A 0.9900 . ?
C85 H85B 0.9900 . ?
C85 C156 1.575(17) . ?
C86 H86 0.9500 . ?
C86 C97 1.382(19) . ?
C86 C159 1.38(2) . ?
C87 H87 0.9500 . ?
C88 H88 0.9500 . ?
C88 C92 1.359(19) . ?
C88 C127 1.385(17) . ?
C89 C124 1.445(18) . ?
C89 C153 1.370(19) . ?
C90 H90A 0.9900 . ?
C90 H90B 0.9900 . ?
C91 H91 0.9500 . ?
C92 C152 1.41(2) . ?
C93 H93A 0.9900 . ?
C93 H93B 0.9900 . ?
C93 C123 1.51(2) . ?
C93 C132 1.42(2) . ?
C94 H94A 0.9900 . ?
C94 H94B 0.9900 . ?
C94 C95 1.521(16) . ?
C95 H95 1.0000 . ?
C96 H96A 0.9900 . ?
C96 H96B 0.9900 . ?
C97 C126 1.36(2) . ?
C98 C112 1.39(2) . ?
C98 C155 1.37(2) . ?
C99 H99A 0.9900 . ?
C99 H99B 0.9900 . ?
C100 H100 0.9500 . ?
C101 H10A 0.9900 . ?
C101 H10B 0.9900 . ?
C101 C104 1.545(18) . ?
C101 C156 1.50(2) . ?
C102 H102 0.9500 . ?
C102 C125 1.372(18) . ?
C103 H10C 0.9900 . ?
C103 H10D 0.9900 . ?
C103 C104 1.536(18) . ?
C103 C113 1.50(2) . ?
C104 H104 1.0000 . ?
C105 H105 0.9500 . ?
C105 C133 1.387(16) . ?
C106 H106 0.9500 . ?
C106 C107 1.3900 . ?
C106 C111 1.3900 . ?
C107 H107 0.9500 . ?
C107 C108 1.3900 . ?
C108 H108 0.9500 . ?
C108 C109 1.3900 . ?
C109 C110 1.3900 . ?
C110 H110 0.9500 . ?
C110 C111 1.3900 . ?
C111 H111 0.9500 . ?
C112 H112 0.9500 . ?
C112 C168 1.37(2) . ?
C113 H113 1.0000 . ?
C113 C129 1.567(18) . ?
C113 C154 1.527(19) . ?
C114 H11A 0.9900 . ?
C114 H11B 0.9900 . ?
C114 C150 1.498(18) . ?
C114 C203 1.51(2) . ?
C115 H115 0.9500 . ?
C115 C116 1.3900 . ?
C115 C120 1.3900 . ?
C116 C117 1.3900 . ?
C117 H117 0.9500 . ?
C117 C118 1.3900 . ?
C118 H118 0.9500 . ?
C118 C119 1.3900 . ?
C119 H119 0.9500 . ?
C119 C120 1.3900 . ?
C120 H120 0.9500 . ?
C121 H121 0.9500 . ?
C121 C148 1.33(2) . ?
C122 H122 0.9500 . ?
C123 H123 1.0000 . ?
C123 C210 1.50(2) . ?
C124 H124 0.9500 . ?
C124 C162 1.35(2) . ?
C125 H125 0.9500 . ?
C125 C148 1.43(2) . ?
C126 H126 0.9500 . ?
C126 C171 1.38(2) . ?
C127 H127 0.9500 . ?
C127 C131 1.37(2) . ?
C128 H128 0.9500 . ?
C128 C159 1.32(2) . ?
C128 C171 1.45(2) . ?
C129 H12A 0.9900 . ?
C129 H12B 0.9900 . ?
C130 H130 0.9500 . ?
C131 H131 0.9500 . ?
C131 C135 1.37(2) . ?
C132 H132 1.0000 . ?
C132 C134 1.592(17) . ?
C132 C160 1.56(2) . ?
C133 H133 0.9500 . ?
C134 H13A 0.9900 . ?
C134 H13B 0.9900 . ?
C135 H135 0.9500 . ?
C135 C152 1.422(19) . ?
C136 H136 0.9500 . ?
C136 C137 1.3900 . ?
C136 C141 1.3900 . ?
C137 C138 1.3900 . ?
C138 H138 0.9500 . ?
C138 C139 1.3900 . ?
C139 H139 0.9500 . ?
C139 C140 1.3900 . ?
C140 H140 0.9500 . ?
C140 C141 1.3900 . ?
C141 H141 0.9500 . ?
C142 C143 1.3900 . ?
C142 C147 1.3900 . ?
C143 H143 0.9500 . ?
C143 C144 1.3900 . ?
C144 H144 0.9500 . ?
C144 C145 1.3900 . ?
C145 H145 0.9500 . ?
C145 C146 1.3900 . ?
C146 H146 0.9500 . ?
C146 C147 1.3900 . ?
C147 H147 0.9500 . ?
C148 H148 0.9500 . ?
C149 H149 0.9500 . ?
C149 C161 1.38(2) . ?
C149 C162 1.38(2) . ?
C150 C164 1.68(2) . ?
C150 C204 1.42(2) . ?
C151 H15A 0.9900 . ?
C151 H15B 0.9900 . ?
C151 C169 1.35(3) . ?
C151 C170 1.43(3) . ?
C152 H152 0.9500 . ?
C153 H153 0.9500 . ?
C153 C161 1.40(2) . ?
C154 H15C 0.9900 . ?
C154 H15D 0.9900 . ?
C154 C156 1.562(19) . ?
C155 H155 0.9500 . ?
C155 C165 1.40(2) . ?
C156 H156 1.0000 . ?
C157 H15E 0.9900 . ?
C157 H15F 0.9900 . ?
C157 C205 1.55(3) . ?
C157 C206 1.36(3) . ?
C158 H15G 0.9900 . ?
C158 H15H 0.9900 . ?
C158 C209 1.547(16) . ?
C159 H159 0.9500 . ?
C160 H16C 0.9900 . ?
C160 H16D 0.9900 . ?
C160 C209 1.49(2) . ?
C161 H161 0.9500 . ?
C162 H162 0.9500 . ?
C163 H16E 0.9900 . ?
C163 H16F 0.9900 . ?
C163 C170 1.49(3) . ?
C163 C172 1.55(3) . ?
C164 H16G 0.9900 . ?
C164 H16H 0.9900 . ?
C164 C205 1.46(2) . ?
C165 H165 0.9500 . ?
C165 C166 1.40(2) . ?
C166 H166 0.9500 . ?
C166 C168 1.36(3) . ?
C167 H16I 0.9900 . ?
C167 H16J 0.9900 . ?
C167 C169 1.43(2) . ?
C167 C172 1.57(2) . ?
C168 H168 0.9500 . ?
C169 H169 1.0000 . ?
C169 C181 1.546(18) . ?
C170 H170 1.0000 . ?
C170 C174 1.69(2) . ?
C171 H171 0.9500 . ?
C172 H172 1.0000 . ?
C172 C173 1.573(19) . ?
C173 H17A 0.9900 . ?
C173 H17B 0.9900 . ?
C174 H17C 0.9900 . ?
C174 H17D 0.9900 . ?
C175 H175 0.9500 . ?
C175 C176 1.3900 . ?
C175 C180 1.3900 . ?
C176 H176 0.9500 . ?
C176 C177 1.3900 . ?
C177 H177 0.9500 . ?
C177 C178 1.3900 . ?
C178 C179 1.3900 . ?
C179 H179 0.9500 . ?
C179 C180 1.3900 . ?
C180 H180 0.9500 . ?
C181 H18A 0.9900 . ?
C181 H18B 0.9900 . ?
C182 H18C 0.9900 . ?
C182 H18D 0.9900 . ?
C182 C186 1.54(3) . ?
C182 C189 1.54(3) . ?
C183 H18E 0.9900 . ?
C183 H18F 0.9900 . ?
C183 C187 1.53(2) . ?
C184 H18G 0.9900 . ?
C184 H18H 0.9900 . ?
C184 C186 1.58(3) . ?
C184 C187 1.49(3) . ?
C185 H18I 0.9900 . ?
C185 H18J 0.9900 . ?
C185 C187 1.57(3) . ?
C185 C189 1.55(4) . ?
C186 H186 1.0000 . ?
C186 C190 1.51(3) . ?
C187 H187 1.0000 . ?
C188 H18K 0.9900 . ?
C188 H18L 0.9900 . ?
C188 C189 1.52(3) . ?
C189 H189 1.0000 . ?
C190 H19A 0.9900 . ?
C190 H19B 0.9900 . ?
C191 H191 0.9500 . ?
C191 C192 1.3900 . ?
C191 C196 1.3900 . ?
C192 H192 0.9500 . ?
C192 C193 1.3900 . ?
C193 H193 0.9500 . ?
C193 C194 1.3900 . ?
C194 H194 0.9500 . ?
C194 C195 1.3900 . ?
C195 C196 1.3900 . ?
C196 H196 0.9500 . ?
C197 H197 0.9500 . ?
C197 C198 1.3900 . ?
C197 C202 1.3900 . ?
C198 C199 1.3900 . ?
C199 H199 0.9500 . ?
C199 C200 1.3900 . ?
C200 H200 0.9500 . ?
C200 C201 1.3900 . ?
C201 H201 0.9500 . ?
C201 C202 1.3900 . ?
C202 H202 0.9500 . ?
C203 H203 1.0000 . ?
C203 C207 1.28(2) . ?
C203 C208 1.68(3) . ?
C204 H20A 0.9900 . ?
C204 H20B 0.9900 . ?
C204 C206 1.61(3) . ?
C205 H205 1.0000 . ?
C205 C208 1.57(3) . ?
C206 H206 1.0000 . ?
C206 C207 1.61(3) . ?
C207 H20C 0.9900 . ?
C207 H20D 0.9900 . ?
C208 H20E 0.9900 . ?
C208 H20F 0.9900 . ?
C209 H209 1.0000 . ?
C209 C210 1.49(2) . ?
C210 H21A 0.9900 . ?
C210 H21B 0.9900 . ?
C211 H21C 0.9900 . ?
C211 H21D 0.9900 . ?
C211 C213 1.58(8) . ?
C211 C218 1.70(5) . ?
C212 H21E 0.9900 . ?
C212 H21F 0.9900 . ?
C212 C216 1.46(5) . ?
C212 C217 1.41(6) . ?
C213 C214 1.36(8) . ?
C213 C215 1.66(9) . ?
C214 H21G 0.9900 . ?
C214 H21H 0.9900 . ?
C214 C217 1.65(4) . ?
C215 H21I 0.9900 . ?
C215 H21J 0.9900 . ?
C215 C216 1.64(4) . ?
C216 H216 1.0000 . ?
C216 C219 1.46(5) . ?
C217 H217 1.0000 . ?
C217 C220 1.69(6) . ?
C218 H218 1.0000 . ?
C218 C219 1.23(6) . ?
C218 C220 1.42(6) . ?
C219 H21K 0.9900 . ?
C219 H21L 0.9900 . ?
C220 H22C 0.9900 . ?
C220 H22D 0.9900 . ?
Au4 Ag1A 3.176(3) . y

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Au02 Au01 Au05 120.602(18) . . y
Au02 Au01 Au5 120.013(19) . . y
Au02 Au01 Ag 64.992(17) . . y
Au05 Au01 Ag 63.468(17) . . y
Au5 Au01 Au05 65.067(17) . . y
Au5 Au01 Ag 117.84(2) . . y
Au01 Au02 Au03 58.272(14) . . y
Au01 Au02 Ag0Q 61.524(19) . . y
Au01 Au02 Ag 58.074(15) . . y
Au03 Au02 Ag 108.416(19) . . y
Ag0Q Au02 Au03 110.25(2) . . y
Ag0Q Au02 Ag 60.86(2) . . y
P17 Au02 Au01 172.58(7) . . y
P17 Au02 Au03 119.22(8) . . y
P17 Au02 Ag0Q 115.80(7) . . y
P17 Au02 Ag 127.67(7) . . y
Au01 Au03 Au02 56.991(14) . . y
Au01 Au03 Ag0P 60.529(19) . . y
Au01 Au03 Au5 56.839(15) . . y
Au02 Au03 Au5 106.334(19) . . y
Ag0P Au03 Au02 61.724(19) . . y
Ag0P Au03 Au5 107.18(2) . . y
P0Z Au03 Au01 170.44(6) . . y
P0Z Au03 Au02 117.32(7) . . y
P0Z Au03 Ag0P 125.25(7) . . y
P0Z Au03 Au5 122.60(7) . . y
Au07 Au04 Au0B 65.025(17) . . y
Au07 Au04 Au2 65.398(18) . . y
Au07 Au04 Ag1A 120.28(2) . . y
Au2 Au04 Au0B 120.64(2) . . y
Ag1A Au04 Au0B 65.039(19) . . y
Ag1A Au04 Au2 118.97(2) . . y
Au01 Au05 Ag0M 61.469(19) . . y
Au01 Au05 Ag0R 63.19(2) . . y
Au01 Au05 Ag 58.376(16) . . y
Ag0R Au05 Ag0M 62.80(2) . . y
Ag0R Au05 Ag 111.95(2) . . y
P18 Au05 Au01 170.17(7) . . y
P18 Au05 Ag0M 108.78(7) . . y
P18 Au05 Ag0R 114.61(7) . . y
P18 Au05 Ag 116.93(7) . . y
Ag Au05 Ag0M 60.71(2) . . y
S10 Au06 Ag0L 48.38(6) . . y
P19 Au06 Ag0L 137.28(7) . . y
P19 Au06 S10 172.77(10) . . y
Au04 Au07 Au0B 58.160(16) . . y
Au04 Au07 Au2 57.860(16) . . y
Au04 Au07 Ag0O 62.03(2) . . y
Au0B Au07 Au2 108.51(2) . . y
Ag0O Au07 Au0B 110.21(2) . . y
Ag0O Au07 Au2 60.89(2) . . y
P01F Au07 Au04 172.66(7) . . y
P01F Au07 Au0B 119.74(8) . . y
P01F Au07 Au2 127.47(8) . . y
P01F Au07 Ag0O 114.87(7) . . y
S12 Au08 Au2 52.59(7) . . y
P1C Au08 Au2 135.33(7) . . y
P1C Au08 S12 171.78(10) . . y
Au04 Au09 Au2 58.207(16) . . y
Au04 Au09 Ag0N 60.820(19) . . y
Au04 Au09 Ag0S 62.33(2) . . y
Au2 Au09 Ag0N 59.86(2) . . y
Ag0S Au09 Au2 110.41(2) . . y
Ag0S Au09 Ag0N 61.71(2) . . y
P01J Au09 Au04 169.97(9) . . y
P01J Au09 Au2 116.58(9) . . y
P01J Au09 Ag0N 109.28(8) . . y
P01J Au09 Ag0S 115.65(9) . . y
Au04 Au0B Au07 56.815(15) . . y
Au04 Au0B Ag0U 61.05(2) . . y
Au04 Au0B Ag1A 56.819(17) . . y
Au07 Au0B Ag1A 106.38(2) . . y
Ag0U Au0B Au07 61.66(2) . . y
Ag0U Au0B Ag1A 107.47(2) . . y
P01G Au0B Au04 170.47(8) . . y
P01G Au0B Au07 116.91(8) . . y
P01G Au0B Ag0U 123.99(8) . . y
P01G Au0B Ag1A 123.52(8) . . y
S11 Au0C Au5 50.16(6) . . y
P1D Au0C S11 171.95(10) . . y
P1D Au0C Au5 137.62(8) . . y
S14 Au0D Ag 52.03(6) . . y
P1E Au0D S14 173.45(10) . . y
P1E Au0D Ag 134.52(8) . . y
S01A Au0E Ag0V 48.75(7) . . y
P01I Au0E Ag0V 136.81(8) . . y
P01I Au0E S01A 172.18(10) . . y
Au04 Au2 Au09 58.845(17) . . y
Au04 Au2 Ag0N 61.56(2) . . y
Au04 Au2 Ag0O 60.54(2) . . y
Au04 Au2 Ag0T 58.492(19) . . y
Au09 Au2 Ag0N 61.28(2) . . y
Au09 Au2 Ag0O 109.39(2) . . y
Au09 Au2 Ag0T 61.94(2) . . y
Ag0N Au2 Ag0O 60.30(2) . . y
Ag0N Au2 Ag0T 111.86(3) . . y
Ag0T Au2 Ag0O 110.08(3) . . y
S12 Au2 Au04 173.79(6) . . y
S12 Au2 Au09 121.55(7) . . y
S12 Au2 Ag0N 112.73(7) . . y
S12 Au2 Ag0O 115.09(6) . . y
S12 Au2 Ag0T 127.61(6) . . y
S01H Au1A Ag0S 103.33(10) . . y
S01H Au1A P01K 160.87(17) . . y
P01K Au1A Ag0S 95.53(14) . . y
Au01 Ag0K Au5 56.366(17) . . y
Au01 Ag0K Ag 57.150(17) . . y
Cl1B Ag0K Au01 174.76(8) . . y
Cl1B Ag0K Au5 121.51(8) . . y
Cl1B Ag0K Ag 121.41(8) . . y
Ag Ag0K Au5 105.12(2) . . y
Au01 Ag0L Ag2A 57.470(18) . . y
Au01 Ag0L Au5 56.463(18) . . y
S10 Ag0L Au01 153.19(7) . . y
S10 Ag0L Ag2A 108.96(6) . . y
S10 Ag0L Au5 144.97(6) . . y
Au5 Ag0L Ag2A 105.74(3) . . y
Au01 Ag0M Au05 56.049(17) . . y
Au01 Ag0M Ag0Q 58.71(2) . . y
Au05 Ag0M Ag0Q 107.15(3) . . y
Cl13 Ag0M Au01 165.03(7) . . y
Cl13 Ag0M Au05 133.76(8) . . y
Cl13 Ag0M Ag0Q 117.41(8) . . y
Cl13 Ag0M Ag2A 107.41(6) . . y
Ag2A Ag0M Au01 57.678(18) . . y
Ag2A Ag0M Au05 104.06(3) . . y
Ag2A Ag0M Ag0Q 61.38(2) . . y
Au04 Ag0N Au2 56.481(19) . . y
Cl0X Ag0N Au04 165.55(6) . . y
Cl0X Ag0N Au2 134.19(6) . . y
Cl0X Ag0N Ag2A 107.76(6) . . y
Ag2A Ag0N Au04 57.834(18) . . y
Ag2A Ag0N Au2 106.95(3) . . y
Au04 Ag0O Ag0N 59.77(2) . . y
Au07 Ag0O Au04 56.475(18) . . y
Au07 Ag0O Ag0N 108.74(3) . . y
Au07 Ag0O Cl0W 90.79(5) . . y
Cl0W Ag0O Au04 120.36(6) . . y
Cl0W Ag0O Ag0N 150.18(5) . . y
S10 Ag0O Au04 151.72(7) . . y
S10 Ag0O Au07 146.50(7) . . y
S10 Ag0O Ag0N 92.06(7) . . y
S10 Ag0O Cl0W 82.41(8) . . y
Au01 Ag0P Au03 56.806(18) . . y
Au01 Ag0P Ag0L 58.54(2) . . y
Au01 Ag0P Ag2A 57.556(18) . . y
Au03 Ag0P Ag0L 61.16(2) . . y
Cl0W Ag0P Au01 154.23(7) . . y
Cl0W Ag0P Au03 124.35(6) . . y
Cl0W Ag0P Ag0L 98.07(6) . . y
Cl0W Ag0P Ag2A 102.71(6) . . y
Ag2A Ag0P Au03 106.74(3) . . y
Ag2A Ag0P Ag0L 59.41(2) . . y
Au01 Ag0Q Au02 56.498(17) . . y
Au01 Ag0Q Ag0M 60.16(2) . . y
Au01 Ag0Q Ag 56.520(19) . . y
Au02 Ag0Q Ag0M 109.14(3) . . y
Au02 Ag0Q Ag 60.605(19) . . y
Ag0M Ag0Q Ag 60.09(2) . . y
Cl0Y Ag0Q Au01 120.86(6) . . y
Cl0Y Ag0Q Au02 91.58(5) . . y
Cl0Y Ag0Q Ag0M 149.48(5) . . y
Cl0Y Ag0Q Ag 149.19(5) . . y
S01A Ag0Q Au01 150.30(8) . . y
S01A Ag0Q Au02 147.39(7) . . y
S01A Ag0Q Ag0M 90.24(7) . . y
S01A Ag0Q Cl0Y 82.97(8) . . y
S01A Ag0Q Ag 112.72(7) . . y
Au01 Ag0R Ag2A 56.678(18) . . y
Au05 Ag0R Au01 56.910(17) . . y
Au05 Ag0R Ag2A 104.65(3) . . y
Cl0X Ag0R Au01 124.76(7) . . y
Cl0X Ag0R Au05 142.22(6) . . y
Cl0X Ag0R Ag2A 103.80(6) . . y
Cl16 Ag0R Au01 141.03(7) . . y
Cl16 Ag0R Au05 103.99(7) . . y
Cl16 Ag0R Cl0X 91.68(9) . . y
Cl16 Ag0R Ag2A 105.58(7) . . y
Au04 Ag0S Ag2A 56.849(19) . . y
Au09 Ag0S Au04 57.589(19) . . y
Au09 Ag0S Ag2A 105.64(3) . . y
Cl13 Ag0S Au04 125.57(8) . . y
Cl13 Ag0S Au09 142.17(6) . . y
Cl13 Ag0S Cl16 92.53(10) . . y
Cl13 Ag0S Ag2A 103.69(6) . . y
Cl16 Ag0S Au04 139.35(7) . . y
Cl16 Ag0S Au09 102.36(7) . . y
Cl16 Ag0S Ag2A 104.93(6) . . y
Au04 Ag0T Au2 57.246(18) . . y
Au04 Ag0T Ag1A 56.103(19) . . y
Au2 Ag0T Ag1A 105.32(3) . . y
Cl15 Ag0T Au04 175.60(9) . . y
Cl15 Ag0T Au2 119.86(8) . . y
Cl15 Ag0T Ag1A 124.12(8) . . y
Au04 Ag0U Au0B 56.518(19) . . y
Au04 Ag0U Ag0V 58.35(2) . . y
Au04 Ag0U Ag2A 57.65(2) . . y
Au0B Ag0U Ag0V 60.87(2) . . y
Cl0Y Ag0U Au04 153.92(7) . . y
Cl0Y Ag0U Au0B 123.22(6) . . y
Cl0Y Ag0U Ag0V 97.49(7) . . y
Cl0Y Ag0U Ag2A 103.20(6) . . y
Ag2A Ag0U Au0B 106.55(3) . . y
Ag2A Ag0U Ag0V 59.44(2) . . y
Au04 Ag0V Ag1A 56.360(19) . . y
Au04 Ag0V Ag2A 57.718(19) . . y
S01A Ag0V Au04 154.75(8) . . y
S01A Ag0V Ag1A 144.34(7) . . y
S01A Ag0V Ag2A 108.91(6) . . y
Ag1A Ag0V Ag2A 106.25(3) . . y
Ag0P Cl0W Ag0O 80.50(7) . . ?
Ag0N Cl0X Ag0R 70.25(7) . . ?
Ag0U Cl0Y Ag0Q 80.86(8) . . ?
C18 P0Z Au03 114.6(4) . . ?
C18 P0Z C37 101.9(5) . . ?
C35 P0Z Au03 113.4(3) . . ?
C35 P0Z C18 105.3(5) . . ?
C35 P0Z C37 104.1(5) . . ?
C37 P0Z Au03 116.0(3) . . ?
Au06 S10 Ag0L 87.95(8) . . ?
Au06 S10 Ag0O 116.87(11) . . ?
Ag0L S10 Ag0O 77.66(7) . . ?
C1 S10 Au06 110.8(3) . . ?
C1 S10 Ag0L 116.1(3) . . ?
C1 S10 Ag0O 130.9(3) . . ?
Au0C S11 Au5 80.52(8) . . ?
C9 S11 Au0C 109.0(15) . . ?
C9 S11 Au5 110.1(13) . . ?
C213 S11 Au0C 106(3) . . ?
C213 S11 Au5 109(2) . . ?
Au08 S12 Au2 76.84(8) . . ?
C40 S12 Au08 106.6(5) . . ?
C40 S12 Au2 109.4(4) . . ?
Ag0M Cl13 Ag0S 71.82(7) . . ?
Au0D S14 Ag 77.88(8) . . ?
C7 S14 Au0D 108.7(5) . . ?
C7 S14 Ag 110.0(4) . . ?
Ag0R Cl16 Ag0S 79.96(9) . . ?
C5 P17 Au02 117.3(4) . . ?
C5 P17 C60 105.5(5) . . ?
C5 P17 C84 106.8(5) . . ?
C60 P17 Au02 113.3(4) . . ?
C84 P17 Au02 111.3(3) . . ?
C84 P17 C60 101.2(5) . . ?
C6 P18 Au05 111.4(4) . . ?
C6 P18 C62 101.0(5) . . ?
C34 P18 Au05 115.6(4) . . ?
C34 P18 C6 107.6(5) . . ?
C34 P18 C62 108.0(5) . . ?
C62 P18 Au05 112.3(3) . . ?
C8 P19 Au06 113.8(3) . . ?
C8 P19 C32 105.5(5) . . ?
C32 P19 Au06 110.2(4) . . ?
C37 P19 Au06 115.8(4) . . ?
C37 P19 C8 102.8(5) . . ?
C37 P19 C32 108.0(5) . . ?
Au0E S01A Ag0Q 114.71(11) . . ?
Au0E S01A Ag0V 87.47(8) . . ?
Ag0V S01A Ag0Q 78.06(8) . . ?
C150 S01A Au0E 112.1(5) . . ?
C150 S01A Ag0Q 131.0(5) . . ?
C150 S01A Ag0V 118.2(6) . . ?
C2 P1C Au08 109.5(4) . . ?
C2 P1C C24 102.2(4) . . ?
C24 P1C Au08 114.6(3) . . ?
C46 P1C Au08 116.4(4) . . ?
C46 P1C C2 107.4(5) . . ?
C46 P1C C24 105.7(4) . . ?
C10 P1D Au0C 113.3(3) . . ?
C10 P1D C62 103.2(4) . . ?
C10 P1D C137 106.5(4) . . ?
C62 P1D Au0C 115.1(3) . . ?
C62 P1D C137 108.9(5) . . ?
C137 P1D Au0C 109.5(3) . . ?
C60 P1E Au0D 117.0(4) . . ?
C60 P1E C116 105.6(5) . . ?
C109 P1E Au0D 114.8(4) . . ?
C109 P1E C60 105.2(5) . . ?
C109 P1E C116 101.6(4) . . ?
C116 P1E Au0D 111.1(3) . . ?
C46 P01F Au07 112.5(4) . . ?
C72 P01F Au07 116.2(3) . . ?
C72 P01F C46 106.6(4) . . ?
C89 P01F Au07 113.0(4) . . ?
C89 P01F C46 102.2(6) . . ?
C89 P01F C72 105.3(5) . . ?
C52 P01G Au0B 113.7(3) . . ?
C52 P01G C90 105.0(5) . . ?
C90 P01G Au0B 115.8(4) . . ?
C92 P01G Au0B 113.2(5) . . ?
C92 P01G C52 104.9(5) . . ?
C92 P01G C90 103.1(6) . . ?
C76 S01H Au1A 112.0(5) . . ?
C76 S01H Au4 100.2(5) . . ?
C76 S01H Ag1A 106.7(4) . . ?
Ag1A S01H Au4 82.59(12) . . ?
C90 P01I Au0E 115.8(4) . . ?
C90 P01I C97 102.0(6) . . ?
C90 P01I C142 109.9(6) . . ?
C97 P01I Au0E 115.1(4) . . ?
C97 P01I C142 104.8(5) . . ?
C142 P01I Au0E 108.5(4) . . ?
C98 P01J Au09 110.9(4) . . ?
C99 P01J Au09 110.7(5) . . ?
C99 P01J C98 102.0(7) . . ?
C99 P01J C178 109.1(6) . . ?
C178 P01J Au09 118.0(4) . . ?
C178 P01J C98 104.8(6) . . ?
C99 P01K Au1A 116.6(5) . . ?
C99 P01K C195 98.9(6) . . ?
C99 P01K Au4 118.4(5) . . ?
C195 P01K Au1A 115.8(5) . . ?
C195 P01K Au4 125.6(5) . . ?
C198 P01K Au1A 106.6(12) . . ?
C198 P01K C99 108.4(9) . . ?
C198 P01K C195 110.3(13) . . ?
C198 P01K Au4 94.7(12) . . ?
C3 C1 S10 108.5(7) . . ?
C3 C1 C16 110.3(9) . . ?
C3 C1 C64 108.0(8) . . ?
C16 C1 S10 111.9(7) . . ?
C64 C1 S10 108.2(7) . . ?
C64 C1 C16 109.7(9) . . ?
C47 C2 P1C 119.8(9) . . ?
C47 C2 C58 122.1(10) . . ?
C58 C2 P1C 118.1(8) . . ?
C1 C3 H3A 109.7 . . ?
C1 C3 H3B 109.7 . . ?
C1 C3 C50 109.6(9) . . ?
H3A C3 H3B 108.2 . . ?
C50 C3 H3A 109.7 . . ?
C50 C3 H3B 109.7 . . ?
C5 C4 H4 120.0 . . ?
C5 C4 C30 120.0(11) . . ?
C30 C4 H4 120.0 . . ?
C4 C5 P17 118.4(8) . . ?
C4 C5 C59 119.2(10) . . ?
C59 C5 P17 122.1(9) . . ?
C21 C6 P18 116.9(9) . . ?
C21 C6 C31 119.3(11) . . ?
C31 C6 P18 123.3(8) . . ?
C173 C7 S14 119.1(10) . . ?
C173 C7 C174 110.7(15) . . ?
C173 C7 C181 106.9(13) . . ?
C174 C7 S14 108.6(10) . . ?
C174 C7 C181 106.0(16) . . ?
C181 C7 S14 104.5(9) . . ?
C38 C8 P19 116.7(9) . . ?
C42 C8 P19 122.5(9) . . ?
C42 C8 C38 120.8(11) . . ?
C183 C9 S11 106(2) . . ?
C183 C9 C188 106(3) . . ?
C188 C9 S11 111(3) . . ?
C190 C9 S11 114(3) . . ?
C190 C9 C183 110(3) . . ?
C190 C9 C188 110(3) . . ?
C11 C10 P1D 120.3(4) . . ?
C11 C10 C15 120.0 . . ?
C15 C10 P1D 119.7(4) . . ?
C10 C11 H11 120.0 . . ?
C10 C11 C12 120.0 . . ?
C12 C11 H11 120.0 . . ?
C11 C12 H12 120.0 . . ?
C13 C12 C11 120.0 . . ?
C13 C12 H12 120.0 . . ?
C12 C13 H13 120.0 . . ?
C12 C13 C14 120.0 . . ?
C14 C13 H13 120.0 . . ?
C13 C14 H14 120.0 . . ?
C13 C14 C15 120.0 . . ?
C15 C14 H14 120.0 . . ?
C10 C15 H15 120.0 . . ?
C14 C15 C10 120.0 . . ?
C14 C15 H15 120.0 . . ?
C1 C16 H16A 109.8 . . ?
C1 C16 H16B 109.8 . . ?
H16A C16 H16B 108.2 . . ?
C95 C16 C1 109.4(8) . . ?
C95 C16 H16A 109.8 . . ?
C95 C16 H16B 109.8 . . ?
C18 C17 H17 119.2 . . ?
C18 C17 C44 121.5(12) . . ?
C44 C17 H17 119.2 . . ?
C17 C18 P0Z 116.8(9) . . ?
C105 C18 P0Z 124.4(9) . . ?
C105 C18 C17 118.7(10) . . ?
C34 C19 H19 120.1 . . ?
C63 C19 H19 120.1 . . ?
C63 C19 C34 119.8(12) . . ?
C30 C20 H20 118.6 . . ?
C30 C20 C45 122.8(11) . . ?
C45 C20 H20 118.6 . . ?
C6 C21 H21 120.3 . . ?
C67 C21 C6 119.3(11) . . ?
C67 C21 H21 120.3 . . ?
H22A C22 H22B 107.9 . . ?
C76 C22 H22A 109.3 . . ?
C76 C22 H22B 109.3 . . ?
C76 C22 C104 111.7(11) . . ?
C104 C22 H22A 109.3 . . ?
C104 C22 H22B 109.3 . . ?
C35 C23 H23 119.9 . . ?
C35 C23 C36 120.1(10) . . ?
C36 C23 H23 119.9 . . ?
C25 C24 P1C 116.2(4) . . ?
C25 C24 C29 120.0 . . ?
C29 C24 P1C 123.8(4) . . ?
C24 C25 H25 120.0 . . ?
C24 C25 C26 120.0 . . ?
C26 C25 H25 120.0 . . ?
C25 C26 H26 120.0 . . ?
C27 C26 C25 120.0 . . ?
C27 C26 H26 120.0 . . ?
C26 C27 H27 120.0 . . ?
C28 C27 C26 120.0 . . ?
C28 C27 H27 120.0 . . ?
C27 C28 H28 120.0 . . ?
C27 C28 C29 120.0 . . ?
C29 C28 H28 120.0 . . ?
C24 C29 H29 120.0 . . ?
C28 C29 C24 120.0 . . ?
C28 C29 H29 120.0 . . ?
C4 C30 H30 120.6 . . ?
C20 C30 C4 118.8(12) . . ?
C20 C30 H30 120.6 . . ?
C6 C31 H31 120.7 . . ?
C49 C31 C6 118.5(11) . . ?
C49 C31 H31 120.7 . . ?
C78 C32 P19 123.5(10) . . ?
C78 C32 C102 119.7(12) . . ?
C102 C32 P19 116.7(9) . . ?
C47 C33 H33 120.1 . . ?
C66 C33 H33 120.1 . . ?
C66 C33 C47 119.8(11) . . ?
C19 C34 P18 117.4(9) . . ?
C61 C34 P18 122.4(9) . . ?
C61 C34 C19 120.2(10) . . ?
C23 C35 P0Z 118.1(8) . . ?
C23 C35 C130 120.4(11) . . ?
C130 C35 P0Z 121.3(9) . . ?
C23 C36 H36 120.3 . . ?
C48 C36 C23 119.5(12) . . ?
C48 C36 H36 120.3 . . ?
P0Z C37 H37A 108.5 . . ?
P0Z C37 H37B 108.5 . . ?
P19 C37 P0Z 114.9(6) . . ?
P19 C37 H37A 108.5 . . ?
P19 C37 H37B 108.5 . . ?
H37A C37 H37B 107.5 . . ?
C8 C38 H38 120.8 . . ?
C8 C38 C100 118.4(11) . . ?
C100 C38 H38 120.8 . . ?
H39A C39 H39B 108.1 . . ?
C43 C39 H39A 109.6 . . ?
C43 C39 H39B 109.6 . . ?
C43 C39 C95 110.2(10) . . ?
C95 C39 H39A 109.6 . . ?
C95 C39 H39B 109.6 . . ?
C51 C40 S12 112.8(8) . . ?
C134 C40 S12 107.1(9) . . ?
C134 C40 C51 111.0(11) . . ?
C134 C40 C158 109.3(12) . . ?
C158 C40 S12 108.2(9) . . ?
C158 C40 C51 108.2(12) . . ?
C44 C41 H41 120.4 . . ?
C133 C41 H41 120.4 . . ?
C133 C41 C44 119.3(11) . . ?
C8 C42 H42 119.7 . . ?
C8 C42 C122 120.6(12) . . ?
C122 C42 H42 119.7 . . ?
C39 C43 H43 110.0 . . ?
C39 C43 C64 108.1(9) . . ?
C64 C43 H43 110.0 . . ?
C96 C43 C39 109.6(10) . . ?
C96 C43 H43 110.0 . . ?
C96 C43 C64 109.1(10) . . ?
C17 C44 H44 120.8 . . ?
C41 C44 C17 118.4(12) . . ?
C41 C44 H44 120.8 . . ?
C20 C45 H45 121.4 . . ?
C20 C45 C59 117.2(11) . . ?
C59 C45 H45 121.4 . . ?
P1C C46 P01F 116.2(6) . . ?
P1C C46 H46A 108.2 . . ?
P1C C46 H46B 108.2 . . ?
P01F C46 H46A 108.2 . . ?
P01F C46 H46B 108.2 . . ?
H46A C46 H46B 107.4 . . ?
C2 C47 C33 119.4(12) . . ?
C2 C47 H47 120.3 . . ?
C33 C47 H47 120.3 . . ?
C36 C48 H48 119.2 . . ?
C36 C48 C69 121.6(12) . . ?
C69 C48 H48 119.2 . . ?
C31 C49 H49 118.0 . . ?
C31 C49 C87 124.1(12) . . ?
C87 C49 H49 118.0 . . ?
C3 C50 H50 109.4 . . ?
C94 C50 C3 108.0(9) . . ?
C94 C50 H50 109.4 . . ?
C96 C50 C3 109.9(10) . . ?
C96 C50 H50 109.4 . . ?
C96 C50 C94 110.7(11) . . ?
C40 C51 H51A 110.0 . . ?
C40 C51 H51B 110.0 . . ?
C40 C51 C123 108.5(11) . . ?
H51A C51 H51B 108.4 . . ?
C123 C51 H51A 110.0 . . ?
C123 C51 H51B 110.0 . . ?
C53 C52 P01G 117.7(5) . . ?
C53 C52 C57 120.0 . . ?
C57 C52 P01G 122.0(5) . . ?
C52 C53 H53 120.0 . . ?
C54 C53 C52 120.0 . . ?
C54 C53 H53 120.0 . . ?
C53 C54 H54 120.0 . . ?
C53 C54 C55 120.0 . . ?
C55 C54 H54 120.0 . . ?
C54 C55 H55 120.0 . . ?
C56 C55 C54 120.0 . . ?
C56 C55 H55 120.0 . . ?
C55 C56 H56 120.0 . . ?
C55 C56 C57 120.0 . . ?
C57 C56 H56 120.0 . . ?
C52 C57 H57 120.0 . . ?
C56 C57 C52 120.0 . . ?
C56 C57 H57 120.0 . . ?
C2 C58 H58 121.9 . . ?
C68 C58 C2 116.1(11) . . ?
C68 C58 H58 121.9 . . ?
C5 C59 H59 119.0 . . ?
C45 C59 C5 122.0(11) . . ?
C45 C59 H59 119.0 . . ?
P17 C60 H60A 108.6 . . ?
P17 C60 H60B 108.6 . . ?
P1E C60 P17 114.6(6) . . ?
P1E C60 H60A 108.6 . . ?
P1E C60 H60B 108.6 . . ?
H60A C60 H60B 107.6 . . ?
C34 C61 H61 120.9 . . ?
C34 C61 C91 118.3(12) . . ?
C91 C61 H61 120.9 . . ?
P18 C62 H62A 108.7 . . ?
P18 C62 H62B 108.7 . . ?
P1D C62 P18 114.1(5) . . ?
P1D C62 H62A 108.7 . . ?
P1D C62 H62B 108.7 . . ?
H62A C62 H62B 107.6 . . ?
C19 C63 H63 119.6 . . ?
C19 C63 C65 120.9(12) . . ?
C65 C63 H63 119.6 . . ?
C1 C64 C43 109.3(9) . . ?
C1 C64 H64A 109.8 . . ?
C1 C64 H64B 109.8 . . ?
C43 C64 H64A 109.8 . . ?
C43 C64 H64B 109.8 . . ?
H64A C64 H64B 108.3 . . ?
C63 C65 H65 119.9 . . ?
C91 C65 C63 120.1(11) . . ?
C91 C65 H65 119.9 . . ?
C33 C66 H66 120.0 . . ?
C68 C66 C33 120.0(11) . . ?
C68 C66 H66 120.0 . . ?
C21 C67 H67 118.9 . . ?
C87 C67 C21 122.2(11) . . ?
C87 C67 H67 118.9 . . ?
C58 C68 H68 118.8 . . ?
C66 C68 C58 122.5(12) . . ?
C66 C68 H68 118.8 . . ?
C48 C69 H69 120.9 . . ?
C48 C69 C130 118.2(12) . . ?
C130 C69 H69 120.9 . . ?
C71 C70 H70 120.0 . . ?
C71 C70 C75 120.0 . . ?
C75 C70 H70 120.0 . . ?
C70 C71 H71 120.0 . . ?
C72 C71 C70 120.0 . . ?
C72 C71 H71 120.0 . . ?
C71 C72 P01F 119.3(5) . . ?
C71 C72 C73 120.0 . . ?
C73 C72 P01F 120.4(5) . . ?
C72 C73 H73 120.0 . . ?
C74 C73 C72 120.0 . . ?
C74 C73 H73 120.0 . . ?
C73 C74 H74 120.0 . . ?
C73 C74 C75 120.0 . . ?
C75 C74 H74 120.0 . . ?
C70 C75 H75 120.0 . . ?
C74 C75 C70 120.0 . . ?
C74 C75 H75 120.0 . . ?
C22 C76 S01H 108.4(9) . . ?
C22 C76 C85 109.7(11) . . ?
C22 C76 C129 110.2(11) . . ?
C85 C76 S01H 113.3(9) . . ?
C85 C76 C129 106.9(11) . . ?
C129 C76 S01H 108.3(9) . . ?
C100 C77 H77 119.1 . . ?
C122 C77 H77 119.1 . . ?
C122 C77 C100 121.7(13) . . ?
C32 C78 H78 120.3 . . ?
C121 C78 C32 119.4(13) . . ?
C121 C78 H78 120.3 . . ?
C80 C79 H79 120.0 . . ?
C80 C79 C84 120.0 . . ?
C84 C79 H79 120.0 . . ?
C79 C80 H80 120.0 . . ?
C79 C80 C81 120.0 . . ?
C81 C80 H80 120.0 . . ?
C80 C81 H81 120.0 . . ?
C82 C81 C80 120.0 . . ?
C82 C81 H81 120.0 . . ?
C81 C82 H82 120.0 . . ?
C83 C82 C81 120.0 . . ?
C83 C82 H82 120.0 . . ?
C82 C83 H83 120.0 . . ?
C82 C83 C84 120.0 . . ?
C84 C83 H83 120.0 . . ?
C79 C84 P17 121.3(4) . . ?
C83 C84 P17 118.7(4) . . ?
C83 C84 C79 120.0 . . ?
C76 C85 H85A 109.6 . . ?
C76 C85 H85B 109.6 . . ?
C76 C85 C156 110.4(11) . . ?
H85A C85 H85B 108.1 . . ?
C156 C85 H85A 109.6 . . ?
C156 C85 H85B 109.6 . . ?
C97 C86 H86 119.7 . . ?
C159 C86 H86 119.7 . . ?
C159 C86 C97 120.5(15) . . ?
C49 C87 C67 116.5(12) . . ?
C49 C87 H87 121.8 . . ?
C67 C87 H87 121.8 . . ?
C92 C88 H88 118.7 . . ?
C92 C88 C127 122.5(14) . . ?
C127 C88 H88 118.7 . . ?
C124 C89 P01F 117.4(10) . . ?
C153 C89 P01F 123.6(11) . . ?
C153 C89 C124 118.6(13) . . ?
P01G C90 H90A 108.4 . . ?
P01G C90 H90B 108.4 . . ?
P01I C90 P01G 115.4(7) . . ?
P01I C90 H90A 108.4 . . ?
P01I C90 H90B 108.4 . . ?
H90A C90 H90B 107.5 . . ?
C61 C91 H91 119.7 . . ?
C65 C91 C61 120.6(12) . . ?
C65 C91 H91 119.7 . . ?
C88 C92 P01G 118.7(11) . . ?
C88 C92 C152 118.3(12) . . ?
C152 C92 P01G 122.9(11) . . ?
H93A C93 H93B 108.3 . . ?
C123 C93 H93A 109.9 . . ?
C123 C93 H93B 109.9 . . ?
C132 C93 H93A 109.9 . . ?
C132 C93 H93B 109.9 . . ?
C132 C93 C123 109.0(14) . . ?
C50 C94 H94A 109.5 . . ?
C50 C94 H94B 109.5 . . ?
H94A C94 H94B 108.1 . . ?
C95 C94 C50 110.7(10) . . ?
C95 C94 H94A 109.5 . . ?
C95 C94 H94B 109.5 . . ?
C16 C95 C39 108.6(10) . . ?
C16 C95 C94 109.9(10) . . ?
C16 C95 H95 109.9 . . ?
C39 C95 H95 109.9 . . ?
C94 C95 C39 108.5(10) . . ?
C94 C95 H95 109.9 . . ?
C43 C96 H96A 109.5 . . ?
C43 C96 H96B 109.5 . . ?
C50 C96 C43 110.8(9) . . ?
C50 C96 H96A 109.5 . . ?
C50 C96 H96B 109.5 . . ?
H96A C96 H96B 108.1 . . ?
C86 C97 P01I 117.6(11) . . ?
C126 C97 P01I 121.4(12) . . ?
C126 C97 C86 121.1(14) . . ?
C112 C98 P01J 122.4(13) . . ?
C155 C98 P01J 119.2(12) . . ?
C155 C98 C112 118.3(16) . . ?
P01J C99 P01K 119.2(8) . . ?
P01J C99 H99A 107.5 . . ?
P01J C99 H99B 107.5 . . ?
P01K C99 H99A 107.5 . . ?
P01K C99 H99B 107.5 . . ?
H99A C99 H99B 107.0 . . ?
C38 C100 H100 120.6 . . ?
C77 C100 C38 118.8(12) . . ?
C77 C100 H100 120.6 . . ?
H10A C101 H10B 108.3 . . ?
C104 C101 H10A 109.8 . . ?
C104 C101 H10B 109.8 . . ?
C156 C101 H10A 109.8 . . ?
C156 C101 H10B 109.8 . . ?
C156 C101 C104 109.3(12) . . ?
C32 C102 H102 120.7 . . ?
C125 C102 C32 118.5(13) . . ?
C125 C102 H102 120.7 . . ?
H10C C103 H10D 108.0 . . ?
C104 C103 H10C 109.4 . . ?
C104 C103 H10D 109.4 . . ?
C113 C103 H10C 109.4 . . ?
C113 C103 H10D 109.4 . . ?
C113 C103 C104 111.1(12) . . ?
C22 C104 H104 110.3 . . ?
C101 C104 C22 106.8(10) . . ?
C101 C104 H104 110.3 . . ?
C103 C104 C22 110.0(11) . . ?
C103 C104 C101 109.2(12) . . ?
C103 C104 H104 110.3 . . ?
C18 C105 H105 119.6 . . ?
C18 C105 C133 120.8(13) . . ?
C133 C105 H105 119.6 . . ?
C107 C106 H106 120.0 . . ?
C107 C106 C111 120.0 . . ?
C111 C106 H106 120.0 . . ?
C106 C107 H107 120.0 . . ?
C108 C107 C106 120.0 . . ?
C108 C107 H107 120.0 . . ?
C107 C108 H108 120.0 . . ?
C107 C108 C109 120.0 . . ?
C109 C108 H108 120.0 . . ?
C108 C109 P1E 122.4(5) . . ?
C110 C109 P1E 117.6(5) . . ?
C110 C109 C108 120.0 . . ?
C109 C110 H110 120.0 . . ?
C109 C110 C111 120.0 . . ?
C111 C110 H110 120.0 . . ?
C106 C111 H111 120.0 . . ?
C110 C111 C106 120.0 . . ?
C110 C111 H111 120.0 . . ?
C98 C112 H112 120.1 . . ?
C168 C112 C98 119.7(18) . . ?
C168 C112 H112 120.1 . . ?
C103 C113 H113 109.7 . . ?
C103 C113 C129 109.9(12) . . ?
C103 C113 C154 109.9(13) . . ?
C129 C113 H113 109.7 . . ?
C154 C113 H113 109.7 . . ?
C154 C113 C129 107.8(12) . . ?
H11A C114 H11B 108.1 . . ?
C150 C114 H11A 109.5 . . ?
C150 C114 H11B 109.5 . . ?
C150 C114 C203 110.6(13) . . ?
C203 C114 H11A 109.5 . . ?
C203 C114 H11B 109.5 . . ?
C116 C115 H115 120.0 . . ?
C116 C115 C120 120.0 . . ?
C120 C115 H115 120.0 . . ?
C115 C116 P1E 120.5(5) . . ?
C115 C116 C117 120.0 . . ?
C117 C116 P1E 119.5(5) . . ?
C116 C117 H117 120.0 . . ?
C118 C117 C116 120.0 . . ?
C118 C117 H117 120.0 . . ?
C117 C118 H118 120.0 . . ?
C117 C118 C119 120.0 . . ?
C119 C118 H118 120.0 . . ?
C118 C119 H119 120.0 . . ?
C118 C119 C120 120.0 . . ?
C120 C119 H119 120.0 . . ?
C115 C120 H120 120.0 . . ?
C119 C120 C115 120.0 . . ?
C119 C120 H120 120.0 . . ?
C78 C121 H121 118.8 . . ?
C148 C121 C78 122.4(14) . . ?
C148 C121 H121 118.8 . . ?
C42 C122 H122 120.2 . . ?
C77 C122 C42 119.6(13) . . ?
C77 C122 H122 120.2 . . ?
C51 C123 H123 108.8 . . ?
C93 C123 C51 110.1(12) . . ?
C93 C123 H123 108.8 . . ?
C210 C123 C51 109.2(12) . . ?
C210 C123 C93 111.1(14) . . ?
C210 C123 H123 108.8 . . ?
C89 C124 H124 120.7 . . ?
C162 C124 C89 118.6(14) . . ?
C162 C124 H124 120.7 . . ?
C102 C125 H125 119.7 . . ?
C102 C125 C148 120.6(14) . . ?
C148 C125 H125 119.7 . . ?
C97 C126 H126 120.2 . . ?
C97 C126 C171 119.5(17) . . ?
C171 C126 H126 120.2 . . ?
C88 C127 H127 119.8 . . ?
C131 C127 C88 120.5(15) . . ?
C131 C127 H127 119.8 . . ?
C159 C128 H128 119.6 . . ?
C159 C128 C171 120.8(17) . . ?
C171 C128 H128 119.6 . . ?
C76 C129 C113 110.1(12) . . ?
C76 C129 H12A 109.6 . . ?
C76 C129 H12B 109.6 . . ?
C113 C129 H12A 109.6 . . ?
C113 C129 H12B 109.6 . . ?
H12A C129 H12B 108.2 . . ?
C35 C130 C69 120.1(11) . . ?
C35 C130 H130 119.9 . . ?
C69 C130 H130 119.9 . . ?
C127 C131 H131 120.7 . . ?
C135 C131 C127 118.5(14) . . ?
C135 C131 H131 120.7 . . ?
C93 C132 H132 108.3 . . ?
C93 C132 C134 112.2(13) . . ?
C93 C132 C160 112.1(16) . . ?
C134 C132 H132 108.3 . . ?
C160 C132 H132 108.3 . . ?
C160 C132 C134 107.5(13) . . ?
C41 C133 C105 121.1(14) . . ?
C41 C133 H133 119.4 . . ?
C105 C133 H133 119.4 . . ?
C40 C134 C132 105.4(12) . . ?
C40 C134 H13A 110.7 . . ?
C40 C134 H13B 110.7 . . ?
C132 C134 H13A 110.7 . . ?
C132 C134 H13B 110.7 . . ?
H13A C134 H13B 108.8 . . ?
C131 C135 H135 119.1 . . ?
C131 C135 C152 121.7(16) . . ?
C152 C135 H135 119.1 . . ?
C137 C136 H136 120.0 . . ?
C137 C136 C141 120.0 . . ?
C141 C136 H136 120.0 . . ?
C136 C137 P1D 123.2(5) . . ?
C138 C137 P1D 116.8(5) . . ?
C138 C137 C136 120.0 . . ?
C137 C138 H138 120.0 . . ?
C137 C138 C139 120.0 . . ?
C139 C138 H138 120.0 . . ?
C138 C139 H139 120.0 . . ?
C138 C139 C140 120.0 . . ?
C140 C139 H139 120.0 . . ?
C139 C140 H140 120.0 . . ?
C141 C140 C139 120.0 . . ?
C141 C140 H140 120.0 . . ?
C136 C141 H141 120.0 . . ?
C140 C141 C136 120.0 . . ?
C140 C141 H141 120.0 . . ?
C143 C142 P01I 116.4(6) . . ?
C143 C142 C147 120.0 . . ?
C147 C142 P01I 123.6(6) . . ?
C142 C143 H143 120.0 . . ?
C142 C143 C144 120.0 . . ?
C144 C143 H143 120.0 . . ?
C143 C144 H144 120.0 . . ?
C145 C144 C143 120.0 . . ?
C145 C144 H144 120.0 . . ?
C144 C145 H145 120.0 . . ?
C146 C145 C144 120.0 . . ?
C146 C145 H145 120.0 . . ?
C145 C146 H146 120.0 . . ?
C145 C146 C147 120.0 . . ?
C147 C146 H146 120.0 . . ?
C142 C147 H147 120.0 . . ?
C146 C147 C142 120.0 . . ?
C146 C147 H147 120.0 . . ?
C121 C148 C125 119.4(14) . . ?
C121 C148 H148 120.3 . . ?
C125 C148 H148 120.3 . . ?
C161 C149 H149 119.5 . . ?
C162 C149 H149 119.5 . . ?
C162 C149 C161 121.0(15) . . ?
C114 C150 S01A 111.1(10) . . ?
C114 C150 C164 103.4(12) . . ?
C164 C150 S01A 103.5(11) . . ?
C204 C150 S01A 116.8(12) . . ?
C204 C150 C114 112.2(14) . . ?
C204 C150 C164 108.7(16) . . ?
H15A C151 H15B 107.4 . . ?
C169 C151 H15A 108.3 . . ?
C169 C151 H15B 108.3 . . ?
C169 C151 C170 115.8(19) . . ?
C170 C151 H15A 108.3 . . ?
C170 C151 H15B 108.3 . . ?
C92 C152 C135 117.9(15) . . ?
C92 C152 H152 121.0 . . ?
C135 C152 H152 121.0 . . ?
C89 C153 H153 119.2 . . ?
C89 C153 C161 121.7(15) . . ?
C161 C153 H153 119.2 . . ?
C113 C154 H15C 110.0 . . ?
C113 C154 H15D 110.0 . . ?
C113 C154 C156 108.4(12) . . ?
H15C C154 H15D 108.4 . . ?
C156 C154 H15C 110.0 . . ?
C156 C154 H15D 110.0 . . ?
C98 C155 H155 118.8 . . ?
C98 C155 C165 122.4(16) . . ?
C165 C155 H155 118.8 . . ?
C85 C156 H156 109.4 . . ?
C101 C156 C85 108.6(12) . . ?
C101 C156 C154 112.9(12) . . ?
C101 C156 H156 109.4 . . ?
C154 C156 C85 107.1(12) . . ?
C154 C156 H156 109.4 . . ?
H15E C157 H15F 106.1 . . ?
C205 C157 H15E 105.6 . . ?
C205 C157 H15F 105.6 . . ?
C206 C157 H15E 105.6 . . ?
C206 C157 H15F 105.6 . . ?
C206 C157 C205 127(2) . . ?
C40 C158 H15G 109.4 . . ?
C40 C158 H15H 109.4 . . ?
C40 C158 C209 111.1(12) . . ?
H15G C158 H15H 108.0 . . ?
C209 C158 H15G 109.4 . . ?
C209 C158 H15H 109.4 . . ?
C86 C159 H159 120.2 . . ?
C128 C159 C86 119.5(16) . . ?
C128 C159 H159 120.2 . . ?
C132 C160 H16C 109.8 . . ?
C132 C160 H16D 109.8 . . ?
H16C C160 H16D 108.3 . . ?
C209 C160 C132 109.2(14) . . ?
C209 C160 H16C 109.8 . . ?
C209 C160 H16D 109.8 . . ?
C149 C161 C153 118.0(15) . . ?
C149 C161 H161 121.0 . . ?
C153 C161 H161 121.0 . . ?
C124 C162 C149 122.0(16) . . ?
C124 C162 H162 119.0 . . ?
C149 C162 H162 119.0 . . ?
H16E C163 H16F 107.7 . . ?
C170 C163 H16E 108.9 . . ?
C170 C163 H16F 108.9 . . ?
C170 C163 C172 113.3(18) . . ?
C172 C163 H16E 108.9 . . ?
C172 C163 H16F 108.9 . . ?
C150 C164 H16G 108.6 . . ?
C150 C164 H16H 108.6 . . ?
H16G C164 H16H 107.6 . . ?
C205 C164 C150 114.7(16) . . ?
C205 C164 H16G 108.6 . . ?
C205 C164 H16H 108.6 . . ?
C155 C165 H165 121.3 . . ?
C166 C165 C155 117.4(18) . . ?
C166 C165 H165 121.3 . . ?
C165 C166 H166 120.0 . . ?
C168 C166 C165 120.0(19) . . ?
C168 C166 H166 120.0 . . ?
H16I C167 H16J 108.2 . . ?
C169 C167 H16I 109.7 . . ?
C169 C167 H16J 109.7 . . ?
C169 C167 C172 109.9(15) . . ?
C172 C167 H16I 109.7 . . ?
C172 C167 H16J 109.7 . . ?
C112 C168 H168 119.0 . . ?
C166 C168 C112 122.1(18) . . ?
C166 C168 H168 119.0 . . ?
C151 C169 C167 111.7(18) . . ?
C151 C169 H169 108.2 . . ?
C151 C169 C181 105.7(17) . . ?
C167 C169 H169 108.2 . . ?
C167 C169 C181 114.6(16) . . ?
C181 C169 H169 108.2 . . ?
C151 C170 C163 113.2(19) . . ?
C151 C170 H170 113.0 . . ?
C151 C170 C174 109.4(16) . . ?
C163 C170 H170 113.0 . . ?
C163 C170 C174 93.9(15) . . ?
C174 C170 H170 113.0 . . ?
C126 C171 C128 118.4(17) . . ?
C126 C171 H171 120.8 . . ?
C128 C171 H171 120.8 . . ?
C163 C172 C167 107.6(16) . . ?
C163 C172 H172 113.0 . . ?
C163 C172 C173 107.6(15) . . ?
C167 C172 H172 113.0 . . ?
C167 C172 C173 101.7(15) . . ?
C173 C172 H172 113.0 . . ?
C7 C173 C172 114.1(14) . . ?
C7 C173 H17A 108.7 . . ?
C7 C173 H17B 108.7 . . ?
C172 C173 H17A 108.7 . . ?
C172 C173 H17B 108.7 . . ?
H17A C173 H17B 107.6 . . ?
C7 C174 C170 111.3(14) . . ?
C7 C174 H17C 109.4 . . ?
C7 C174 H17D 109.4 . . ?
C170 C174 H17C 109.4 . . ?
C170 C174 H17D 109.4 . . ?
H17C C174 H17D 108.0 . . ?
C176 C175 H175 120.0 . . ?
C176 C175 C180 120.0 . . ?
C180 C175 H175 120.0 . . ?
C175 C176 H176 120.0 . . ?
C175 C176 C177 120.0 . . ?
C177 C176 H176 120.0 . . ?
C176 C177 H177 120.0 . . ?
C178 C177 C176 120.0 . . ?
C178 C177 H177 120.0 . . ?
C177 C178 P01J 121.9(6) . . ?
C177 C178 C179 120.0 . . ?
C179 C178 P01J 118.1(6) . . ?
C178 C179 H179 120.0 . . ?
C180 C179 C178 120.0 . . ?
C180 C179 H179 120.0 . . ?
C175 C180 H180 120.0 . . ?
C179 C180 C175 120.0 . . ?
C179 C180 H180 120.0 . . ?
C7 C181 C169 111.2(13) . . ?
C7 C181 H18A 109.4 . . ?
C7 C181 H18B 109.4 . . ?
C169 C181 H18A 109.4 . . ?
C169 C181 H18B 109.4 . . ?
H18A C181 H18B 108.0 . . ?
H18C C182 H18D 108.1 . . ?
C186 C182 H18C 109.6 . . ?
C186 C182 H18D 109.6 . . ?
C186 C182 C189 110(2) . . ?
C189 C182 H18C 109.6 . . ?
C189 C182 H18D 109.6 . . ?
C9 C183 H18E 109.2 . . ?
C9 C183 H18F 109.2 . . ?
H18E C183 H18F 107.9 . . ?
C187 C183 C9 112(2) . . ?
C187 C183 H18E 109.2 . . ?
C187 C183 H18F 109.2 . . ?
H18G C184 H18H 108.4 . . ?
C186 C184 H18G 110.0 . . ?
C186 C184 H18H 110.0 . . ?
C187 C184 H18G 110.0 . . ?
C187 C184 H18H 110.0 . . ?
C187 C184 C186 108.3(19) . . ?
H18I C185 H18J 108.5 . . ?
C187 C185 H18I 110.2 . . ?
C187 C185 H18J 110.2 . . ?
C189 C185 H18I 110.2 . . ?
C189 C185 H18J 110.2 . . ?
C189 C185 C187 107.7(18) . . ?
C182 C186 C184 105.7(19) . . ?
C182 C186 H186 109.3 . . ?
C184 C186 H186 109.3 . . ?
C190 C186 C182 110.7(19) . . ?
C190 C186 C184 112.4(18) . . ?
C190 C186 H186 109.3 . . ?
C183 C187 C185 110.6(19) . . ?
C183 C187 H187 109.3 . . ?
C184 C187 C183 110.1(18) . . ?
C184 C187 C185 108.1(19) . . ?
C184 C187 H187 109.3 . . ?
C185 C187 H187 109.3 . . ?
C9 C188 H18K 109.5 . . ?
C9 C188 H18L 109.5 . . ?
H18K C188 H18L 108.1 . . ?
C189 C188 C9 111(2) . . ?
C189 C188 H18K 109.5 . . ?
C189 C188 H18L 109.5 . . ?
C182 C189 C185 105(2) . . ?
C182 C189 H189 109.9 . . ?
C185 C189 H189 109.9 . . ?
C188 C189 C182 109(2) . . ?
C188 C189 C185 113.1(17) . . ?
C188 C189 H189 109.9 . . ?
C9 C190 C186 110(3) . . ?
C9 C190 H19A 109.6 . . ?
C9 C190 H19B 109.6 . . ?
C186 C190 H19A 109.6 . . ?
C186 C190 H19B 109.6 . . ?
H19A C190 H19B 108.1 . . ?
C192 C191 H191 120.0 . . ?
C192 C191 C196 120.0 . . ?
C196 C191 H191 120.0 . . ?
C191 C192 H192 120.0 . . ?
C191 C192 C193 120.0 . . ?
C193 C192 H192 120.0 . . ?
C192 C193 H193 120.0 . . ?
C194 C193 C192 120.0 . . ?
C194 C193 H193 120.0 . . ?
C193 C194 H194 120.0 . . ?
C195 C194 C193 120.0 . . ?
C195 C194 H194 120.0 . . ?
C194 C195 P01K 116.7(7) . . ?
C194 C195 C196 120.0 . . ?
C196 C195 P01K 123.2(7) . . ?
C191 C196 H196 120.0 . . ?
C195 C196 C191 120.0 . . ?
C195 C196 H196 120.0 . . ?
C198 C197 H197 120.0 . . ?
C198 C197 C202 120.0 . . ?
C202 C197 H197 120.0 . . ?
C197 C198 P01K 118(2) . . ?
C197 C198 C199 120.0 . . ?
C199 C198 P01K 121(2) . . ?
C198 C199 H199 120.0 . . ?
C200 C199 C198 120.0 . . ?
C200 C199 H199 120.0 . . ?
C199 C200 H200 120.0 . . ?
C199 C200 C201 120.0 . . ?
C201 C200 H200 120.0 . . ?
C200 C201 H201 120.0 . . ?
C202 C201 C200 120.0 . . ?
C202 C201 H201 120.0 . . ?
C197 C202 H202 120.0 . . ?
C201 C202 C197 120.0 . . ?
C201 C202 H202 120.0 . . ?
C114 C203 H203 109.8 . . ?
C114 C203 C208 104.5(15) . . ?
C207 C203 C114 116.4(17) . . ?
C207 C203 H203 109.8 . . ?
C207 C203 C208 106(2) . . ?
C208 C203 H203 109.8 . . ?
C150 C204 H20A 109.2 . . ?
C150 C204 H20B 109.2 . . ?
C150 C204 C206 112.0(17) . . ?
H20A C204 H20B 107.9 . . ?
C206 C204 H20A 109.2 . . ?
C206 C204 H20B 109.2 . . ?
C157 C205 H205 114.3 . . ?
C157 C205 C208 100.0(18) . . ?
C164 C205 C157 100.2(18) . . ?
C164 C205 H205 114.3 . . ?
C164 C205 C208 112.1(16) . . ?
C208 C205 H205 114.3 . . ?
C157 C206 C204 110.5(19) . . ?
C157 C206 H206 115.0 . . ?
C157 C206 C207 102(2) . . ?
C204 C206 H206 115.0 . . ?
C204 C206 C207 97.3(16) . . ?
C207 C206 H206 115.0 . . ?
C203 C207 C206 119.0(19) . . ?
C203 C207 H20C 107.6 . . ?
C203 C207 H20D 107.6 . . ?
C206 C207 H20C 107.6 . . ?
C206 C207 H20D 107.6 . . ?
H20C C207 H20D 107.0 . . ?
C203 C208 H20E 109.9 . . ?
C203 C208 H20F 109.9 . . ?
C205 C208 C203 108.8(15) . . ?
C205 C208 H20E 109.9 . . ?
C205 C208 H20F 109.9 . . ?
H20E C208 H20F 108.3 . . ?
C158 C209 H209 109.9 . . ?
C160 C209 C158 103.4(13) . . ?
C160 C209 H209 109.9 . . ?
C160 C209 C210 111.4(16) . . ?
C210 C209 C158 112.1(12) . . ?
C210 C209 H209 109.9 . . ?
C123 C210 H21A 109.9 . . ?
C123 C210 H21B 109.9 . . ?
C209 C210 C123 108.8(14) . . ?
C209 C210 H21A 109.9 . . ?
C209 C210 H21B 109.9 . . ?
H21A C210 H21B 108.3 . . ?
H21C C211 H21D 108.7 . . ?
C213 C211 H21C 110.6 . . ?
C213 C211 H21D 110.6 . . ?
C213 C211 C218 106(4) . . ?
C218 C211 H21C 110.6 . . ?
C218 C211 H21D 110.6 . . ?
H21E C212 H21F 106.9 . . ?
C216 C212 H21E 107.3 . . ?
C216 C212 H21F 107.3 . . ?
C217 C212 H21E 107.3 . . ?
C217 C212 H21F 107.3 . . ?
C217 C212 C216 120(4) . . ?
C211 C213 S11 113(5) . . ?
C211 C213 C215 95(5) . . ?
C214 C213 S11 111(5) . . ?
C214 C213 C211 120(6) . . ?
C214 C213 C215 109(6) . . ?
C215 C213 S11 107(5) . . ?
C213 C214 H21G 107.4 . . ?
C213 C214 H21H 107.4 . . ?
C213 C214 C217 120(4) . . ?
H21G C214 H21H 106.9 . . ?
C217 C214 H21G 107.4 . . ?
C217 C214 H21H 107.4 . . ?
C213 C215 H21I 111.0 . . ?
C213 C215 H21J 111.0 . . ?
H21I C215 H21J 109.0 . . ?
C216 C215 C213 104(4) . . ?
C216 C215 H21I 111.0 . . ?
C216 C215 H21J 111.0 . . ?
C212 C216 C215 109(3) . . ?
C212 C216 H216 109.7 . . ?
C215 C216 H216 109.7 . . ?
C219 C216 C212 113(4) . . ?
C219 C216 C215 105(3) . . ?
C219 C216 H216 109.7 . . ?
C212 C217 C214 98(4) . . ?
C212 C217 H217 117.8 . . ?
C212 C217 C220 107(4) . . ?
C214 C217 H217 117.8 . . ?
C214 C217 C220 95(3) . . ?
C220 C217 H217 117.8 . . ?
C211 C218 H218 108.4 . . ?
C219 C218 C211 109(4) . . ?
C219 C218 H218 108.4 . . ?
C219 C218 C220 124(5) . . ?
C220 C218 C211 97(3) . . ?
C220 C218 H218 108.4 . . ?
C216 C219 H21K 109.0 . . ?
C216 C219 H21L 109.0 . . ?
C218 C219 C216 113(4) . . ?
C218 C219 H21K 109.0 . . ?
C218 C219 H21L 109.0 . . ?
H21K C219 H21L 107.8 . . ?
C217 C220 H22C 108.7 . . ?
C217 C220 H22D 108.7 . . ?
C218 C220 C217 114(4) . . ?
C218 C220 H22C 108.7 . . ?
C218 C220 H22D 108.7 . . ?
H22C C220 H22D 107.6 . . ?
S01H Au4 Ag1A 48.01(9) . . y
P01K Au4 S01H 170.7(2) . . y
P01K Au4 Ag1A 132.72(18) . . y
Au04 Ag1A Au0B 58.142(18) . . y
Au04 Ag1A Ag0S 61.02(2) . . y
Au04 Ag1A Ag0T 58.415(19) . . y
Au04 Ag1A Ag0V 61.46(2) . . y
Au0B Ag1A Ag0S 110.61(2) . . y
Au0B Ag1A Ag0T 62.82(2) . . y
Ag0T Ag1A Ag0S 108.25(3) . . y
Ag0V Ag1A Au0B 61.88(2) . . y
Ag0V Ag1A Ag0S 62.00(2) . . y
Ag0V Ag1A Ag0T 112.81(3) . . y
S01H Ag1A Au04 170.63(8) . . y
S01H Ag1A Au0B 129.18(9) . . y
S01H Ag1A Ag0S 109.62(8) . . y
S01H Ag1A Ag0T 128.65(7) . . y
S01H Ag1A Ag0V 115.07(8) . . y
Au01 Ag2A Au04 178.44(2) . . y
Au01 Ag2A Ag0M 61.923(18) . . y
Au01 Ag2A Ag0N 117.37(2) . . y
Au01 Ag2A Ag0P 60.331(19) . . y
Au01 Ag2A Ag0U 120.50(2) . . y
Au04 Ag2A Ag0M 117.17(2) . . y
Au04 Ag2A Ag0N 61.546(19) . . y
Au04 Ag2A Ag0P 121.14(2) . . y
Au04 Ag2A Ag0U 61.031(19) . . y
Ag0M Ag2A Ag0N 110.87(3) . . y
Ag0M Ag2A Ag0P 112.77(2) . . y
Ag0M Ag2A Ag0U 123.98(3) . . y
Ag0N Ag2A Ag0P 124.24(3) . . y
Ag0N Ag2A Ag0U 113.09(2) . . y
Ag0U Ag2A Ag0P 66.23(2) . . y
Au01 Au5 Au03 57.811(16) . . y
Au01 Au5 Au05 57.781(16) . . y
Au01 Au5 Ag0K 58.823(18) . . y
Au01 Au5 Ag0L 61.16(2) . . y
Au03 Au5 Ag0K 62.019(19) . . y
Au05 Au5 Au03 109.05(2) . . y
Au05 Au5 Ag0K 61.587(19) . . y
Ag0L Au5 Au03 61.81(2) . . y
Ag0L Au5 Au05 107.28(2) . . y
Ag0L Au5 Ag0K 112.53(3) . . y
S11 Au5 Au01 171.91(6) . . y
S11 Au5 Au03 127.40(7) . . y
S11 Au5 Au05 120.38(7) . . y
S11 Au5 Ag0K 128.32(6) . . y
S11 Au5 Ag0L 114.47(6) . . y
Au01 Ag Au02 56.934(15) . . y
Au01 Ag Au05 58.156(16) . . y
Au01 Ag Ag0K 58.784(18) . . y
Au01 Ag Ag0M 61.275(19) . . y
Au02 Ag Ag0K 61.75(2) . . y
Au02 Ag Ag0M 107.23(2) . . y
Au05 Ag Au02 108.96(2) . . y
Au05 Ag Ag0K 62.38(2) . . y
Au05 Ag Ag0M 60.38(2) . . y
Ag0M Ag Ag0K 111.87(3) . . y
S14 Ag Au01 175.95(6) . . y
S14 Ag Au02 124.86(7) . . y
S14 Ag Au05 121.97(7) . . y
S14 Ag Ag0K 125.17(6) . . y
S14 Ag Ag0M 114.96(7) . . y

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Au02 P17 C5 C4 -5.4(11) . . . . ?
Au02 P17 C5 C59 -179.7(9) . . . . ?
Au02 P17 C60 P1E 71.3(6) . . . . ?
Au02 P17 C84 C79 -114.9(5) . . . . ?
Au02 P17 C84 C83 63.8(5) . . . . ?
Au03 P0Z C18 C17 47.3(10) . . . . ?
Au03 P0Z C18 C105 -135.1(11) . . . . ?
Au03 P0Z C35 C23 31.3(9) . . . . ?
Au03 P0Z C35 C130 -154.6(8) . . . . ?
Au03 P0Z C37 P19 -68.9(6) . . . . ?
Au05 P18 C6 C21 52.3(10) . . . . ?
Au05 P18 C6 C31 -119.5(10) . . . . ?
Au05 P18 C34 C19 -0.1(10) . . . . ?
Au05 P18 C34 C61 178.6(8) . . . . ?
Au05 P18 C62 P1D 71.0(6) . . . . ?
Au06 S10 C1 C3 -177.0(6) . . . . ?
Au06 S10 C1 C16 61.0(8) . . . . ?
Au06 S10 C1 C64 -60.0(7) . . . . ?
Au06 P19 C8 C38 22.1(10) . . . . ?
Au06 P19 C8 C42 -159.2(8) . . . . ?
Au06 P19 C32 C78 -152.9(9) . . . . ?
Au06 P19 C32 C102 29.1(10) . . . . ?
Au06 P19 C37 P0Z 40.3(7) . . . . ?
Au07 P01F C46 P1C 70.9(6) . . . . ?
Au07 P01F C72 C71 -2.6(5) . . . . ?
Au07 P01F C72 C73 -176.0(4) . . . . ?
Au07 P01F C89 C124 60.7(11) . . . . ?
Au07 P01F C89 C153 -112.1(12) . . . . ?
Au08 S12 C40 C51 -39.6(11) . . . . ?
Au08 S12 C40 C134 -162.1(8) . . . . ?
Au08 S12 C40 C158 80.1(10) . . . . ?
Au08 P1C C2 C47 4.4(11) . . . . ?
Au08 P1C C2 C58 -174.4(8) . . . . ?
Au08 P1C C24 C25 69.9(4) . . . . ?
Au08 P1C C24 C29 -109.1(5) . . . . ?
Au08 P1C C46 P01F -40.7(7) . . . . ?
Au09 P01J C98 C112 -128.5(13) . . . . ?
Au09 P01J C98 C155 54.2(15) . . . . ?
Au09 P01J C99 P01K 60.3(9) . . . . ?
Au09 P01J C178 C177 -171.2(6) . . . . ?
Au09 P01J C178 C179 10.2(9) . . . . ?
Au0B P01G C52 C53 35.4(5) . . . . ?
Au0B P01G C52 C57 -150.5(4) . . . . ?
Au0B P01G C90 P01I -68.6(8) . . . . ?
Au0B P01G C92 C88 38.5(13) . . . . ?
Au0B P01G C92 C152 -142.5(12) . . . . ?
Au0C S11 C9 C183 131(2) . . . . ?
Au0C S11 C9 C188 -114(2) . . . . ?
Au0C S11 C9 C190 10(3) . . . . ?
Au0C S11 C213 C211 -52(5) . . . . ?
Au0C S11 C213 C214 169(5) . . . . ?
Au0C S11 C213 C215 51(4) . . . . ?
Au0C P1D C10 C11 178.8(4) . . . . ?
Au0C P1D C10 C15 1.2(6) . . . . ?
Au0C P1D C62 P18 -38.6(6) . . . . ?
Au0C P1D C137 C136 137.8(5) . . . . ?
Au0C P1D C137 C138 -41.3(6) . . . . ?
Au0D S14 C7 C173 -13.1(14) . . . . ?
Au0D S14 C7 C174 -141.0(13) . . . . ?
Au0D S14 C7 C181 106.2(11) . . . . ?
Au0D P1E C60 P17 -38.7(7) . . . . ?
Au0D P1E C109 C108 -105.9(6) . . . . ?
Au0D P1E C109 C110 73.1(6) . . . . ?
Au0D P1E C116 C115 -178.8(4) . . . . ?
Au0D P1E C116 C117 0.9(6) . . . . ?
Au0E S01A C150 C114 -179.5(9) . . . . ?
Au0E S01A C150 C164 -69.2(11) . . . . ?
Au0E S01A C150 C204 50.1(16) . . . . ?
Au0E P01I C90 P01G 42.1(8) . . . . ?
Au0E P01I C97 C86 26.2(12) . . . . ?
Au0E P01I C97 C126 -152.5(12) . . . . ?
Au0E P01I C142 C143 28.4(6) . . . . ?
Au0E P01I C142 C147 -151.4(5) . . . . ?
Au2 S12 C40 C51 41.9(11) . . . . ?
Au2 S12 C40 C134 -80.6(10) . . . . ?
Au2 S12 C40 C158 161.7(9) . . . . ?
Au1A S01H C76 C22 -167.0(8) . . . . ?
Au1A S01H C76 C85 -44.9(11) . . . . ?
Au1A S01H C76 C129 73.5(10) . . . . ?
Au1A P01K C99 P01J -33.4(10) . . . . ?
Au1A P01K C195 C194 15.8(8) . . . . ?
Au1A P01K C195 C196 -169.0(5) . . . . ?
Au1A P01K C198 C197 -149.4(9) . . . . ?
Au1A P01K C198 C199 38.4(13) . . . . ?
Ag0L S10 C1 C3 84.8(7) . . . . ?
Ag0L S10 C1 C16 -37.2(9) . . . . ?
Ag0L S10 C1 C64 -158.2(6) . . . . ?
Ag0O S10 C1 C3 -11.4(9) . . . . ?
Ag0O S10 C1 C16 -133.4(6) . . . . ?
Ag0O S10 C1 C64 105.6(7) . . . . ?
Ag0Q S01A C150 C114 -17.8(16) . . . . ?
Ag0Q S01A C150 C164 92.5(11) . . . . ?
Ag0Q S01A C150 C204 -148.1(13) . . . . ?
Ag0V S01A C150 C114 81.1(12) . . . . ?
Ag0V S01A C150 C164 -168.6(9) . . . . ?
Ag0V S01A C150 C204 -49.2(16) . . . . ?
P0Z C18 C105 C133 -176.4(13) . . . . ?
P0Z C35 C130 C69 -175.2(10) . . . . ?
S10 C1 C3 C50 177.6(7) . . . . ?
S10 C1 C16 C95 179.2(8) . . . . ?
S10 C1 C64 C43 -177.5(7) . . . . ?
S11 C9 C183 C187 179(2) . . . . ?
S11 C9 C188 C189 -174(2) . . . . ?
S11 C9 C190 C186 175.2(19) . . . . ?
S11 C213 C214 C217 -180(3) . . . . ?
S11 C213 C215 C216 173(3) . . . . ?
S12 C40 C51 C123 -179.7(10) . . . . ?
S12 C40 C134 C132 -177.6(10) . . . . ?
S12 C40 C158 C209 -178.5(11) . . . . ?
S14 C7 C173 C172 -177.0(13) . . . . ?
S14 C7 C174 C170 -163.1(13) . . . . ?
S14 C7 C181 C169 179.8(14) . . . . ?
P17 C5 C59 C45 176.2(10) . . . . ?
P18 C6 C21 C67 -175.2(9) . . . . ?
P18 C6 C31 C49 173.6(10) . . . . ?
P18 C34 C61 C91 -178.7(9) . . . . ?
P19 C8 C38 C100 -179.6(9) . . . . ?
P19 C8 C42 C122 178.4(9) . . . . ?
P19 C32 C78 C121 -179.0(10) . . . . ?
P19 C32 C102 C125 179.1(10) . . . . ?
S01A C150 C164 C205 -172.7(15) . . . . ?
S01A C150 C204 C206 -166.7(14) . . . . ?
P1C C2 C47 C33 -177.2(9) . . . . ?
P1C C2 C58 C68 178.6(9) . . . . ?
P1C C24 C25 C26 -179.0(6) . . . . ?
P1C C24 C29 C28 178.9(6) . . . . ?
P1D C10 C11 C12 -177.7(6) . . . . ?
P1D C10 C15 C14 177.7(6) . . . . ?
P1D C137 C138 C139 179.2(8) . . . . ?
P1E C109 C110 C111 -179.0(8) . . . . ?
P1E C116 C117 C118 -179.7(7) . . . . ?
P01F C72 C73 C74 173.4(6) . . . . ?
P01F C89 C124 C162 -177.6(13) . . . . ?
P01F C89 C153 C161 174.6(13) . . . . ?
P01G C52 C53 C54 174.2(7) . . . . ?
P01G C52 C57 C56 -174.0(7) . . . . ?
P01G C92 C152 C135 -175.0(14) . . . . ?
S01H C76 C85 C156 -178.8(10) . . . . ?
S01H C76 C129 C113 176.0(10) . . . . ?
P01I C97 C126 C171 177.9(15) . . . . ?
P01I C142 C143 C144 -179.8(8) . . . . ?
P01I C142 C147 C146 179.8(8) . . . . ?
P01J C98 C112 C168 178.6(14) . . . . ?
P01J C98 C155 C165 -176.9(14) . . . . ?
P01J C178 C179 C180 178.6(9) . . . . ?
P01K C195 C196 C191 -175.1(9) . . . . ?
P01K C198 C199 C200 172.0(16) . . . . ?
C1 C3 C50 C94 59.8(12) . . . . ?
C1 C3 C50 C96 -61.1(12) . . . . ?
C1 C16 C95 C39 60.4(12) . . . . ?
C1 C16 C95 C94 -58.1(13) . . . . ?
C2 P1C C24 C25 -48.4(6) . . . . ?
C2 P1C C24 C29 132.6(6) . . . . ?
C2 P1C C46 P01F 82.3(7) . . . . ?
C2 C58 C68 C66 -0.5(19) . . . . ?
C3 C1 C16 C95 58.3(12) . . . . ?
C3 C1 C64 C43 -60.2(11) . . . . ?
C3 C50 C94 C95 -60.6(13) . . . . ?
C3 C50 C96 C43 60.1(12) . . . . ?
C4 C5 C59 C45 2(2) . . . . ?
C5 P17 C60 P1E -58.4(7) . . . . ?
C5 P17 C84 C79 14.3(7) . . . . ?
C5 P17 C84 C83 -166.9(6) . . . . ?
C5 C4 C30 C20 0.7(19) . . . . ?
C6 P18 C34 C19 -125.3(9) . . . . ?
C6 P18 C34 C61 53.4(11) . . . . ?
C6 P18 C62 P1D -170.2(6) . . . . ?
C6 C21 C67 C87 2(2) . . . . ?
C6 C31 C49 C87 1(2) . . . . ?
C8 P19 C32 C78 83.9(11) . . . . ?
C8 P19 C32 C102 -94.1(10) . . . . ?
C8 P19 C37 P0Z 165.1(6) . . . . ?
C8 C38 C100 C77 0.7(19) . . . . ?
C8 C42 C122 C77 2(2) . . . . ?
C9 C183 C187 C184 58(3) . . . . ?
C9 C183 C187 C185 -61(3) . . . . ?
C9 C188 C189 C182 -57(3) . . . . ?
C9 C188 C189 C185 60(3) . . . . ?
C10 P1D C62 P18 85.3(6) . . . . ?
C10 P1D C137 C136 15.0(7) . . . . ?
C10 P1D C137 C138 -164.2(5) . . . . ?
C10 C11 C12 C13 0.0 . . . . ?
C11 C10 C15 C14 0.0 . . . . ?
C11 C12 C13 C14 0.0 . . . . ?
C12 C13 C14 C15 0.0 . . . . ?
C13 C14 C15 C10 0.0 . . . . ?
C15 C10 C11 C12 0.0 . . . . ?
C16 C1 C3 C50 -59.4(12) . . . . ?
C16 C1 C64 C43 60.1(11) . . . . ?
C17 C18 C105 C133 1(2) . . . . ?
C18 P0Z C35 C23 157.4(9) . . . . ?
C18 P0Z C35 C130 -28.4(10) . . . . ?
C18 P0Z C37 P19 165.9(6) . . . . ?
C18 C17 C44 C41 -4(2) . . . . ?
C18 C105 C133 C41 -3(3) . . . . ?
C19 C34 C61 C91 0.0(17) . . . . ?
C19 C63 C65 C91 2(2) . . . . ?
C20 C45 C59 C5 -2(2) . . . . ?
C21 C6 C31 C49 2.0(18) . . . . ?
C21 C67 C87 C49 1(2) . . . . ?
C22 C76 C85 C156 -57.5(15) . . . . ?
C22 C76 C129 C113 57.6(15) . . . . ?
C23 C35 C130 C69 -1.2(18) . . . . ?
C23 C36 C48 C69 3(2) . . . . ?
C24 P1C C2 C47 126.3(9) . . . . ?
C24 P1C C2 C58 -52.5(10) . . . . ?
C24 P1C C46 P01F -169.1(5) . . . . ?
C24 C25 C26 C27 0.0 . . . . ?
C25 C24 C29 C28 0.0 . . . . ?
C25 C26 C27 C28 0.0 . . . . ?
C26 C27 C28 C29 0.0 . . . . ?
C27 C28 C29 C24 0.0 . . . . ?
C29 C24 C25 C26 0.0 . . . . ?
C30 C4 C5 P17 -175.7(9) . . . . ?
C30 C4 C5 C59 -1.1(19) . . . . ?
C30 C20 C45 C59 2(2) . . . . ?
C31 C6 C21 C67 -3.1(18) . . . . ?
C31 C49 C87 C67 -2(2) . . . . ?
C32 P19 C8 C38 143.0(9) . . . . ?
C32 P19 C8 C42 -38.3(11) . . . . ?
C32 P19 C37 P0Z -83.7(7) . . . . ?
C32 C78 C121 C148 0(2) . . . . ?
C32 C102 C125 C148 0(2) . . . . ?
C33 C66 C68 C58 0(2) . . . . ?
C34 P18 C6 C21 179.9(9) . . . . ?
C34 P18 C6 C31 8.1(12) . . . . ?
C34 P18 C62 P1D -57.5(7) . . . . ?
C34 C19 C63 C65 -2(2) . . . . ?
C34 C61 C91 C65 0.6(19) . . . . ?
C35 P0Z C18 C17 -78.1(10) . . . . ?
C35 P0Z C18 C105 99.5(13) . . . . ?
C35 P0Z C37 P19 56.5(6) . . . . ?
C35 C23 C36 C48 -2.0(17) . . . . ?
C36 C23 C35 P0Z 175.4(8) . . . . ?
C36 C23 C35 C130 1.2(17) . . . . ?
C36 C48 C69 C130 -3(2) . . . . ?
C37 P0Z C18 C17 173.4(9) . . . . ?
C37 P0Z C18 C105 -9.0(13) . . . . ?
C37 P0Z C35 C23 -95.7(9) . . . . ?
C37 P0Z C35 C130 78.5(10) . . . . ?
C37 P19 C8 C38 -104.0(9) . . . . ?
C37 P19 C8 C42 74.7(10) . . . . ?
C37 P19 C32 C78 -25.5(12) . . . . ?
C37 P19 C32 C102 156.5(9) . . . . ?
C38 C8 C42 C122 -3.0(18) . . . . ?
C39 C43 C64 C1 -60.0(12) . . . . ?
C39 C43 C96 C50 58.6(13) . . . . ?
C40 C51 C123 C93 57.6(16) . . . . ?
C40 C51 C123 C210 -64.7(17) . . . . ?
C40 C158 C209 C160 -64.8(17) . . . . ?
C40 C158 C209 C210 55(2) . . . . ?
C42 C8 C38 C100 1.7(18) . . . . ?
C43 C39 C95 C16 -61.8(12) . . . . ?
C43 C39 C95 C94 57.7(12) . . . . ?
C44 C17 C18 P0Z 179.9(10) . . . . ?
C44 C17 C18 C105 2(2) . . . . ?
C44 C41 C133 C105 1(3) . . . . ?
C45 C20 C30 C4 -1(2) . . . . ?
C46 P1C C2 C47 -122.7(10) . . . . ?
C46 P1C C2 C58 58.5(10) . . . . ?
C46 P1C C24 C25 -160.6(5) . . . . ?
C46 P1C C24 C29 20.4(7) . . . . ?
C46 P01F C72 C71 123.6(6) . . . . ?
C46 P01F C72 C73 -49.9(7) . . . . ?
C46 P01F C89 C124 -60.4(11) . . . . ?
C46 P01F C89 C153 126.9(13) . . . . ?
C47 C2 C58 C68 -0.2(18) . . . . ?
C47 C33 C66 C68 2(2) . . . . ?
C48 C69 C130 C35 2(2) . . . . ?
C50 C94 C95 C16 60.7(13) . . . . ?
C50 C94 C95 C39 -57.9(13) . . . . ?
C51 C40 C134 C132 58.8(14) . . . . ?
C51 C40 C158 C209 -55.9(16) . . . . ?
C51 C123 C210 C209 62.0(18) . . . . ?
C52 P01G C90 P01I 57.6(8) . . . . ?
C52 P01G C92 C88 -85.9(12) . . . . ?
C52 P01G C92 C152 93.0(14) . . . . ?
C52 C53 C54 C55 0.0 . . . . ?
C53 C52 C57 C56 0.0 . . . . ?
C53 C54 C55 C56 0.0 . . . . ?
C54 C55 C56 C57 0.0 . . . . ?
C55 C56 C57 C52 0.0 . . . . ?
C57 C52 C53 C54 0.0 . . . . ?
C58 C2 C47 C33 1.6(19) . . . . ?
C60 P17 C5 C4 121.9(10) . . . . ?
C60 P17 C5 C59 -52.5(12) . . . . ?
C60 P17 C84 C79 124.5(6) . . . . ?
C60 P17 C84 C83 -56.8(6) . . . . ?
C60 P1E C109 C108 24.1(8) . . . . ?
C60 P1E C109 C110 -156.9(6) . . . . ?
C60 P1E C116 C115 53.4(6) . . . . ?
C60 P1E C116 C117 -126.9(6) . . . . ?
C62 P18 C6 C21 -67.1(10) . . . . ?
C62 P18 C6 C31 121.1(11) . . . . ?
C62 P18 C34 C19 126.6(9) . . . . ?
C62 P18 C34 C61 -54.7(11) . . . . ?
C62 P1D C10 C11 53.8(6) . . . . ?
C62 P1D C10 C15 -123.9(5) . . . . ?
C62 P1D C137 C136 -95.6(7) . . . . ?
C62 P1D C137 C138 85.2(6) . . . . ?
C63 C19 C34 P18 179.2(10) . . . . ?
C63 C19 C34 C61 0.5(18) . . . . ?
C63 C65 C91 C61 -2(2) . . . . ?
C64 C1 C3 C50 60.5(11) . . . . ?
C64 C1 C16 C95 -60.6(12) . . . . ?
C64 C43 C96 C50 -59.5(13) . . . . ?
C66 C33 C47 C2 -2.3(19) . . . . ?
C70 C71 C72 P01F -173.5(6) . . . . ?
C70 C71 C72 C73 0.0 . . . . ?
C71 C70 C75 C74 0.0 . . . . ?
C71 C72 C73 C74 0.0 . . . . ?
C72 P01F C46 P1C -57.4(7) . . . . ?
C72 P01F C89 C124 -171.6(10) . . . . ?
C72 P01F C89 C153 15.7(14) . . . . ?
C72 C73 C74 C75 0.0 . . . . ?
C73 C74 C75 C70 0.0 . . . . ?
C75 C70 C71 C72 0.0 . . . . ?
C76 C22 C104 C101 -61.0(15) . . . . ?
C76 C22 C104 C103 57.4(15) . . . . ?
C76 C85 C156 C101 59.0(15) . . . . ?
C76 C85 C156 C154 -63.2(16) . . . . ?
C78 C32 C102 C125 1.0(19) . . . . ?
C78 C121 C148 C125 2(2) . . . . ?
C79 C80 C81 C82 0.0 . . . . ?
C80 C79 C84 P17 178.7(7) . . . . ?
C80 C79 C84 C83 0.0 . . . . ?
C80 C81 C82 C83 0.0 . . . . ?
C81 C82 C83 C84 0.0 . . . . ?
C82 C83 C84 P17 -178.7(7) . . . . ?
C82 C83 C84 C79 0.0 . . . . ?
C84 P17 C5 C4 -131.0(10) . . . . ?
C84 P17 C5 C59 54.6(12) . . . . ?
C84 P17 C60 P1E -169.5(5) . . . . ?
C84 C79 C80 C81 0.0 . . . . ?
C85 C76 C129 C113 -61.6(15) . . . . ?
C86 C97 C126 C171 -1(3) . . . . ?
C88 C92 C152 C135 4(2) . . . . ?
C88 C127 C131 C135 -3(3) . . . . ?
C89 P01F C46 P1C -167.6(6) . . . . ?
C89 P01F C72 C71 -128.4(6) . . . . ?
C89 P01F C72 C73 58.1(6) . . . . ?
C89 C124 C162 C149 3(3) . . . . ?
C89 C153 C161 C149 2(3) . . . . ?
C90 P01G C52 C53 -92.2(6) . . . . ?
C90 P01G C52 C57 81.9(6) . . . . ?
C90 P01G C92 C88 164.4(11) . . . . ?
C90 P01G C92 C152 -16.6(15) . . . . ?
C90 P01I C97 C86 -100.0(11) . . . . ?
C90 P01I C97 C126 81.3(14) . . . . ?
C90 P01I C142 C143 156.0(6) . . . . ?
C90 P01I C142 C147 -23.8(8) . . . . ?
C92 P01G C52 C53 159.6(6) . . . . ?
C92 P01G C52 C57 -26.4(7) . . . . ?
C92 P01G C90 P01I 167.2(7) . . . . ?
C92 C88 C127 C131 -2(2) . . . . ?
C93 C123 C210 C209 -59.7(16) . . . . ?
C93 C132 C134 C40 -62.1(19) . . . . ?
C93 C132 C160 C209 56.3(16) . . . . ?
C94 C50 C96 C43 -59.2(13) . . . . ?
C95 C39 C43 C64 61.0(13) . . . . ?
C95 C39 C43 C96 -57.7(12) . . . . ?
C96 C43 C64 C1 59.1(12) . . . . ?
C96 C50 C94 C95 59.8(13) . . . . ?
C97 P01I C90 P01G 167.8(7) . . . . ?
C97 P01I C142 C143 -95.0(7) . . . . ?
C97 P01I C142 C147 85.1(8) . . . . ?
C97 C86 C159 C128 -4(2) . . . . ?
C97 C126 C171 C128 2(3) . . . . ?
C98 P01J C99 P01K 178.3(8) . . . . ?
C98 P01J C178 C177 64.9(8) . . . . ?
C98 P01J C178 C179 -113.7(8) . . . . ?
C98 C112 C168 C166 1(3) . . . . ?
C98 C155 C165 C166 -4(3) . . . . ?
C99 P01J C98 C112 113.6(14) . . . . ?
C99 P01J C98 C155 -63.7(15) . . . . ?
C99 P01J C178 C177 -43.7(9) . . . . ?
C99 P01J C178 C179 137.7(8) . . . . ?
C99 P01K C195 C194 141.1(7) . . . . ?
C99 P01K C195 C196 -43.7(8) . . . . ?
C99 P01K C198 C197 84.3(13) . . . . ?
C99 P01K C198 C199 -87.8(14) . . . . ?
C100 C77 C122 C42 1(2) . . . . ?
C102 C32 C78 C121 -1.0(19) . . . . ?
C102 C125 C148 C121 -2(2) . . . . ?
C103 C113 C129 C76 -57.2(15) . . . . ?
C103 C113 C154 C156 57.3(16) . . . . ?
C104 C22 C76 S01H -176.1(8) . . . . ?
C104 C22 C76 C85 59.7(14) . . . . ?
C104 C22 C76 C129 -57.8(14) . . . . ?
C104 C101 C156 C85 -61.4(14) . . . . ?
C104 C101 C156 C154 57.2(14) . . . . ?
C104 C103 C113 C129 57.5(15) . . . . ?
C104 C103 C113 C154 -61.1(15) . . . . ?
C106 C107 C108 C109 0.0 . . . . ?
C107 C106 C111 C110 0.0 . . . . ?
C107 C108 C109 P1E 179.0(8) . . . . ?
C107 C108 C109 C110 0.0 . . . . ?
C108 C109 C110 C111 0.0 . . . . ?
C109 P1E C60 P17 -167.5(6) . . . . ?
C109 P1E C116 C115 -56.2(6) . . . . ?
C109 P1E C116 C117 123.5(6) . . . . ?
C109 C110 C111 C106 0.0 . . . . ?
C111 C106 C107 C108 0.0 . . . . ?
C112 C98 C155 C165 6(3) . . . . ?
C113 C103 C104 C22 -56.8(15) . . . . ?
C113 C103 C104 C101 60.2(15) . . . . ?
C113 C154 C156 C85 62.3(16) . . . . ?
C113 C154 C156 C101 -57.2(16) . . . . ?
C114 C150 C164 C205 -57(2) . . . . ?
C114 C150 C204 C206 63(2) . . . . ?
C114 C203 C207 C206 -54(3) . . . . ?
C114 C203 C208 C205 60(2) . . . . ?
C115 C116 C117 C118 0.0 . . . . ?
C116 P1E C60 P17 85.5(6) . . . . ?
C116 P1E C109 C108 134.1(7) . . . . ?
C116 P1E C109 C110 -47.0(7) . . . . ?
C116 C115 C120 C119 0.0 . . . . ?
C116 C117 C118 C119 0.0 . . . . ?
C117 C118 C119 C120 0.0 . . . . ?
C118 C119 C120 C115 0.0 . . . . ?
C120 C115 C116 P1E 179.7(7) . . . . ?
C120 C115 C116 C117 0.0 . . . . ?
C122 C77 C100 C38 -2(2) . . . . ?
C123 C93 C132 C134 63.0(19) . . . . ?
C123 C93 C132 C160 -58.1(16) . . . . ?
C124 C89 C153 C161 2(2) . . . . ?
C127 C88 C92 P01G 179.8(11) . . . . ?
C127 C88 C92 C152 1(2) . . . . ?
C127 C131 C135 C152 8(3) . . . . ?
C129 C76 C85 C156 62.1(15) . . . . ?
C129 C113 C154 C156 -62.5(17) . . . . ?
C131 C135 C152 C92 -8(3) . . . . ?
C132 C93 C123 C51 -60.3(17) . . . . ?
C132 C93 C123 C210 60.8(16) . . . . ?
C132 C160 C209 C158 65.8(16) . . . . ?
C132 C160 C209 C210 -54.8(15) . . . . ?
C133 C41 C44 C17 2(2) . . . . ?
C134 C40 C51 C123 -59.4(15) . . . . ?
C134 C40 C158 C209 65.1(17) . . . . ?
C134 C132 C160 C209 -67.5(18) . . . . ?
C136 C137 C138 C139 0.0 . . . . ?
C137 P1D C10 C11 -60.7(6) . . . . ?
C137 P1D C10 C15 121.6(6) . . . . ?
C137 P1D C62 P18 -161.9(5) . . . . ?
C137 C136 C141 C140 0.0 . . . . ?
C137 C138 C139 C140 0.0 . . . . ?
C138 C139 C140 C141 0.0 . . . . ?
C139 C140 C141 C136 0.0 . . . . ?
C141 C136 C137 P1D -179.2(8) . . . . ?
C141 C136 C137 C138 0.0 . . . . ?
C142 P01I C90 P01G -81.4(8) . . . . ?
C142 P01I C97 C86 145.4(11) . . . . ?
C142 P01I C97 C126 -33.4(15) . . . . ?
C142 C143 C144 C145 0.0 . . . . ?
C143 C142 C147 C146 0.0 . . . . ?
C143 C144 C145 C146 0.0 . . . . ?
C144 C145 C146 C147 0.0 . . . . ?
C145 C146 C147 C142 0.0 . . . . ?
C147 C142 C143 C144 0.0 . . . . ?
C150 C114 C203 C207 44(3) . . . . ?
C150 C114 C203 C208 -72.9(17) . . . . ?
C150 C164 C205 C157 -54(2) . . . . ?
C150 C164 C205 C208 51(3) . . . . ?
C150 C204 C206 C157 45(3) . . . . ?
C150 C204 C206 C207 -60(2) . . . . ?
C151 C169 C181 C7 -70(2) . . . . ?
C151 C170 C174 C7 45(2) . . . . ?
C153 C89 C124 C162 -4(2) . . . . ?
C154 C113 C129 C76 62.6(16) . . . . ?
C155 C98 C112 C168 -4(3) . . . . ?
C155 C165 C166 C168 0(3) . . . . ?
C156 C101 C104 C22 61.8(14) . . . . ?
C156 C101 C104 C103 -57.2(14) . . . . ?
C157 C205 C208 C203 53.5(19) . . . . ?
C157 C206 C207 C203 -55(3) . . . . ?
C158 C40 C51 C123 60.5(15) . . . . ?
C158 C40 C134 C132 -60.5(15) . . . . ?
C158 C209 C210 C123 -57(2) . . . . ?
C159 C86 C97 P01I -177.4(11) . . . . ?
C159 C86 C97 C126 1(2) . . . . ?
C159 C128 C171 C126 -4(3) . . . . ?
C160 C132 C134 C40 61.6(17) . . . . ?
C160 C209 C210 C123 57.8(15) . . . . ?
C161 C149 C162 C124 1(3) . . . . ?
C162 C149 C161 C153 -3(3) . . . . ?
C163 C170 C174 C7 -71(2) . . . . ?
C163 C172 C173 C7 46(2) . . . . ?
C164 C150 C204 C206 -50(2) . . . . ?
C164 C205 C208 C203 -52(2) . . . . ?
C165 C166 C168 C112 1(3) . . . . ?
C167 C169 C181 C7 53(2) . . . . ?
C167 C172 C173 C7 -67(2) . . . . ?
C169 C151 C170 C163 50(2) . . . . ?
C169 C151 C170 C174 -53(2) . . . . ?
C169 C167 C172 C163 -54.0(19) . . . . ?
C169 C167 C172 C173 59(2) . . . . ?
C170 C151 C169 C167 -61(2) . . . . ?
C170 C151 C169 C181 64(2) . . . . ?
C170 C163 C172 C167 44.9(19) . . . . ?
C170 C163 C172 C173 -64(2) . . . . ?
C171 C128 C159 C86 5(3) . . . . ?
C172 C163 C170 C151 -43(2) . . . . ?
C172 C163 C170 C174 70.2(18) . . . . ?
C172 C167 C169 C151 63(2) . . . . ?
C172 C167 C169 C181 -57(2) . . . . ?
C173 C7 C174 C170 64(2) . . . . ?
C173 C7 C181 C169 -53(2) . . . . ?
C174 C7 C173 C172 -50(2) . . . . ?
C174 C7 C181 C169 65(2) . . . . ?
C175 C176 C177 C178 0.0 . . . . ?
C176 C175 C180 C179 0.0 . . . . ?
C176 C177 C178 P01J -178.6(9) . . . . ?
C176 C177 C178 C179 0.0 . . . . ?
C177 C178 C179 C180 0.0 . . . . ?
C178 P01J C98 C112 -0.1(15) . . . . ?
C178 P01J C98 C155 -177.4(14) . . . . ?
C178 P01J C99 P01K -71.1(9) . . . . ?
C178 C179 C180 C175 0.0 . . . . ?
C180 C175 C176 C177 0.0 . . . . ?
C181 C7 C173 C172 65(2) . . . . ?
C181 C7 C174 C170 -51.3(19) . . . . ?
C182 C186 C190 C9 59(3) . . . . ?
C183 C9 C188 C189 -59(3) . . . . ?
C183 C9 C190 C186 57(3) . . . . ?
C184 C186 C190 C9 -58(3) . . . . ?
C186 C182 C189 C185 -65(2) . . . . ?
C186 C182 C189 C188 56(3) . . . . ?
C186 C184 C187 C183 -56(2) . . . . ?
C186 C184 C187 C185 65(2) . . . . ?
C187 C184 C186 C182 -64(2) . . . . ?
C187 C184 C186 C190 57(3) . . . . ?
C187 C185 C189 C182 63(2) . . . . ?
C187 C185 C189 C188 -56(3) . . . . ?
C188 C9 C183 C187 61(3) . . . . ?
C188 C9 C190 C186 -59(3) . . . . ?
C189 C182 C186 C184 64(2) . . . . ?
C189 C182 C186 C190 -58(3) . . . . ?
C189 C185 C187 C183 55(2) . . . . ?
C189 C185 C187 C184 -65(2) . . . . ?
C190 C9 C183 C187 -58(4) . . . . ?
C190 C9 C188 C189 60(3) . . . . ?
C191 C192 C193 C194 0.0 . . . . ?
C192 C191 C196 C195 0.0 . . . . ?
C192 C193 C194 C195 0.0 . . . . ?
C193 C194 C195 P01K 175.4(8) . . . . ?
C193 C194 C195 C196 0.0 . . . . ?
C194 C195 C196 C191 0.0 . . . . ?
C195 P01K C99 P01J -158.1(8) . . . . ?
C195 P01K C198 C197 -22.9(13) . . . . ?
C195 P01K C198 C199 164.9(10) . . . . ?
C196 C191 C192 C193 0.0 . . . . ?
C197 C198 C199 C200 0.0 . . . . ?
C198 P01K C99 P01J 86.9(16) . . . . ?
C198 P01K C195 C194 -105.4(11) . . . . ?
C198 P01K C195 C196 69.8(11) . . . . ?
C198 C197 C202 C201 0.0 . . . . ?
C198 C199 C200 C201 0.0 . . . . ?
C199 C200 C201 C202 0.0 . . . . ?
C200 C201 C202 C197 0.0 . . . . ?
C202 C197 C198 P01K -172.3(16) . . . . ?
C202 C197 C198 C199 0.0 . . . . ?
C203 C114 C150 S01A 178.7(12) . . . . ?
C203 C114 C150 C164 68.3(16) . . . . ?
C203 C114 C150 C204 -49(2) . . . . ?
C204 C150 C164 C205 63(2) . . . . ?
C204 C206 C207 C203 58(3) . . . . ?
C205 C157 C206 C204 -49(3) . . . . ?
C205 C157 C206 C207 53(2) . . . . ?
C206 C157 C205 C164 55(3) . . . . ?
C206 C157 C205 C208 -60(2) . . . . ?
C207 C203 C208 C205 -64(2) . . . . ?
C208 C203 C207 C206 62(2) . . . . ?
C211 C213 C214 C217 45(9) . . . . ?
C211 C213 C215 C216 -72(5) . . . . ?
C211 C218 C219 C216 66(5) . . . . ?
C211 C218 C220 C217 -83(4) . . . . ?
C212 C216 C219 C218 51(5) . . . . ?
C212 C217 C220 C218 -27(5) . . . . ?
C213 C211 C218 C219 -70(6) . . . . ?
C213 C211 C218 C220 60(5) . . . . ?
C213 C214 C217 C212 61(7) . . . . ?
C213 C214 C217 C220 -46(6) . . . . ?
C213 C215 C216 C212 -52(5) . . . . ?
C213 C215 C216 C219 70(5) . . . . ?
C214 C213 C215 C216 53(6) . . . . ?
C214 C217 C220 C218 73(4) . . . . ?
C215 C213 C214 C217 -62(7) . . . . ?
C215 C216 C219 C218 -68(5) . . . . ?
C216 C212 C217 C214 -61(5) . . . . ?
C216 C212 C217 C220 37(5) . . . . ?
C217 C212 C216 C215 67(5) . . . . ?
C217 C212 C216 C219 -50(6) . . . . ?
C218 C211 C213 S11 178(4) . . . . ?
C218 C211 C213 C214 -47(7) . . . . ?
C218 C211 C213 C215 68(5) . . . . ?
C219 C218 C220 C217 37(6) . . . . ?
C220 C218 C219 C216 -48(6) . . . . ?
Au4 S01H C76 C22 -171.1(8) . . . . ?
Au4 S01H C76 C85 -49.1(10) . . . . ?
Au4 S01H C76 C129 69.3(9) . . . . ?
Au4 P01K C99 P01J -19.3(11) . . . . ?
Au4 P01K C195 C194 6.4(9) . . . . ?
Au4 P01K C195 C196 -178.3(5) . . . . ?
Au4 P01K C198 C197 -153.7(10) . . . . ?
Au4 P01K C198 C199 34.1(12) . . . . ?
Ag1A S01H C76 C22 -85.9(9) . . . . ?
Ag1A S01H C76 C85 36.2(11) . . . . ?
Ag1A S01H C76 C129 154.6(8) . . . . ?
Au5 S11 C9 C183 -143(2) . . . . ?
Au5 S11 C9 C188 -28(3) . . . . ?
Au5 S11 C9 C190 97(3) . . . . ?
Au5 S11 C213 C211 34(6) . . . . ?
Au5 S11 C213 C214 -105(5) . . . . ?
Au5 S11 C213 C215 136(3) . . . . ?
Ag S14 C7 C173 70.5(14) . . . . ?
Ag S14 C7 C174 -57.5(14) . . . . ?
Ag S14 C7 C181 -170.3(11) . . . . ?

_smtbx_masks_special_details     
;
A solvent mask was calculated and 647 electrons were 
found in a volume of 3179Å³ in 2 voids per unit cell. 
This is consistent with the presence of 32[H2O] per Formula Unit 
which account for 640 electrons per unit cell.
;
loop_
_smtbx_masks_void_nr
_smtbx_masks_void_average_x
_smtbx_masks_void_average_y
_smtbx_masks_void_average_z
_smtbx_masks_void_volume
_smtbx_masks_void_count_electrons
_smtbx_masks_void_content
1 -0.218 0.000 -0.774 3139.4 646.9 '64 H2O'
2 0.000 0.500 0.500 40.1 0.0 ?

_smtbx_masks_void_probe_radius   1.2
_smtbx_masks_void_truncation_radius 1.2
_olex2_submission_special_instructions 'No special instructions were received'
