# Electronic Supplementary Material (ESI) for New Journal of Chemistry.
# This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2022

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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data_1a
_database_code_depnum_ccdc_archive 'CCDC 2166955'
loop_
_audit_author_name
_audit_author_address
'Qiao-Hua Wei'
;College of Chemistry, Fuzhou University
China
;
_audit_update_record             
;
2022-08-26 deposited with the CCDC.	2022-08-29 downloaded from the CCDC.
;
_audit_creation_date             2022-08-26
_audit_creation_method           
;
Olex2 1.5
(compiled 2021.11.18 svn.ra9532c28 for OlexSys, GUI svn.r6429)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C70 H58 Ag Cl O4 P4 Pt, C H2 Cl2'
_chemical_formula_sum            'C71 H60 Ag Cl3 O4 P4 Pt'
_chemical_formula_weight         1510.38
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           61
_space_group_name_H-M_alt        'P b c a'
_space_group_name_Hall           '-P 2ac 2ab'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z-1/2'
'-x-1/2, y-1/2, z'

_cell_length_a                   27.5216(5)
_cell_length_b                   16.1867(2)
_cell_length_c                   28.0818(5)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     12510.0(4)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    13785
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      27.11
_cell_measurement_theta_min      2.52
_shelx_estimated_absorpt_T_max   0.805
_shelx_estimated_absorpt_T_min   0.602
_exptl_absorpt_coefficient_mu    2.828
_exptl_absorpt_correction_T_max  0.8511
_exptl_absorpt_correction_T_min  0.6794
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS 2016/2'
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'light yellow'
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.604
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       prism
_exptl_crystal_F_000             6032
_exptl_crystal_preparation       ?
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.08
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0367
_diffrn_reflns_av_unetI/netI     0.0222
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       35
_diffrn_reflns_limit_h_min       -32
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       36
_diffrn_reflns_limit_l_min       -35
_diffrn_reflns_number            100054
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.109
_diffrn_reflns_theta_min         2.517
_diffrn_ambient_temperature      100
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                12265
_reflns_number_total             13783
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.38A (Bruker, 2018)'
_computing_data_collection       'SAINT V8.38A (Bruker, 2018)'
_computing_data_reduction        'SAINT V8.38A (Bruker, 2018)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT  (Sheldrick, 2015)'
_refine_diff_density_max         1.032
_refine_diff_density_min         -0.798
_refine_diff_density_rms         0.080
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.052
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     851
_refine_ls_number_reflns         13783
_refine_ls_number_restraints     36
_refine_ls_R_factor_all          0.0280
_refine_ls_R_factor_gt           0.0214
_refine_ls_restrained_S_all      1.051
_refine_ls_shift/su_max          0.006
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0111P)²+23.3932P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0454
_refine_ls_wR_factor_ref         0.0491
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Uiso/Uaniso restraints and constraints
Uanis(C14A) \\sim Ueq, Uanis(C16A) \\sim Ueq: with sigma of 0.005 and sigma for
terminal atoms of 0.01
Uanis(C13A) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
3. Rigid body (RIGU) restrains
 C13, C13A, C18, C18A, C14A, C14
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
4. Others
 Sof(O3A)=Sof(O4A)=Sof(C14A)=Sof(H14A)=Sof(C15A)=Sof(H15A)=Sof(C16A)=Sof(C17A)=
 Sof(H17A)=Sof(C18A)=Sof(H18A)=Sof(C19A)=Sof(C20A)=Sof(H20D)=Sof(H20E)=
 Sof(H20F)=Sof(C13A)=1-FVAR(1)
 Sof(O3)=Sof(O4)=Sof(C13)=Sof(C14)=Sof(H14)=Sof(C15)=Sof(H15)=Sof(C16)=
 Sof(C17)=Sof(H17)=Sof(C18)=Sof(H18)=Sof(C19)=Sof(C20)=Sof(H20A)=Sof(H20B)=
 Sof(H20C)=FVAR(1)
5.a Secondary CH2 refined with riding coordinates:
 C33(H33A,H33B), C58(H58A,H58B), C71(H71A,H71B)
5.b Aromatic/amide H refined with riding coordinates:
 C4(H4), C5(H5), C7(H7), C8(H8), C14(H14), C14A(H14A), C15(H15), C15A(H15A),
 C17(H17), C17A(H17A), C18(H18), C18A(H18A), C22(H22), C23(H23), C24(H24),
 C25(H25), C26(H26), C28(H28), C29(H29), C30(H30), C31(H31), C32(H32), C34(H34),
  C35(H35), C36(H36), C37(H37), C38(H38), C41(H41), C42(H42), C43(H43),
 C44(H44), C45(H45), C47(H47), C48(H48), C49(H49), C50(H50), C51(H51), C53(H53),
  C54(H54), C55(H55), C56(H56), C57(H57), C60(H60), C61(H61), C62(H62),
 C63(H63), C64(H64), C66(H66), C67(H67), C68(H68), C69(H69), C70(H70)
5.c Idealised Me refined as rotating group:
 C10(H10A,H10B,H10C), C20(H20A,H20B,H20C), C20A(H20D,H20E,H20F)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.41036(2) 0.89869(2) 0.41092(2) 0.01039(3) Uani 1 1 d . . . . .
Ag2 Ag 0.33569(2) 0.75916(2) 0.39174(2) 0.01473(4) Uani 1 1 d . . . . .
Cl1 Cl 0.29362(2) 0.62378(4) 0.41575(2) 0.02201(13) Uani 1 1 d . . . . .
P1 P 0.34856(2) 0.98396(3) 0.43519(2) 0.01177(11) Uani 1 1 d . . . . .
P2 P 0.27218(2) 0.86516(4) 0.39984(2) 0.01380(12) Uani 1 1 d . . . . .
P3 P 0.39821(2) 0.69955(4) 0.33823(2) 0.01310(12) Uani 1 1 d . . . . .
P4 P 0.47085(2) 0.81472(3) 0.38097(2) 0.01142(11) Uani 1 1 d . . . . .
O1 O 0.51306(7) 0.73865(13) 0.72357(7) 0.0318(5) Uani 1 1 d . . . . .
O2 O 0.55716(8) 0.85496(13) 0.71849(7) 0.0330(5) Uani 1 1 d . . . . .
O3 O 0.32832(14) 0.8511(2) 0.08410(15) 0.0242(10) Uani 0.617(5) 1 d . . P A 1
O3A O 0.3629(2) 0.8873(4) 0.0757(3) 0.0279(17) Uani 0.383(5) 1 d . . P A 2
O4 O 0.39626(13) 0.9256(2) 0.07255(10) 0.0279(10) Uani 0.617(5) 1 d . . P A 1
O4A O 0.2961(2) 0.8188(3) 0.09861(17) 0.0261(15) Uani 0.383(5) 1 d . . P A 2
C1 C 0.43591(8) 0.88807(14) 0.47719(8) 0.0143(5) Uani 1 1 d . . . . .
C2 C 0.45164(9) 0.88095(14) 0.51740(8) 0.0158(5) Uani 1 1 d . . . . .
C3 C 0.46884(9) 0.86368(14) 0.56437(8) 0.0145(5) Uani 1 1 d . . . . .
C4 C 0.50095(9) 0.91746(15) 0.58805(8) 0.0165(5) Uani 1 1 d . . . . .
H4 H 0.510494 0.967573 0.573124 0.020 Uiso 1 1 calc R U . . .
C5 C 0.51876(9) 0.89839(15) 0.63265(9) 0.0187(5) Uani 1 1 d . . . . .
H5 H 0.540421 0.935297 0.648186 0.022 Uiso 1 1 calc R U . . .
C6 C 0.50503(9) 0.82501(15) 0.65498(8) 0.0181(5) Uani 1 1 d . . . . .
C7 C 0.47268(9) 0.77142(15) 0.63232(9) 0.0193(5) Uani 1 1 d . . . . .
H7 H 0.462971 0.721771 0.647641 0.023 Uiso 1 1 calc R U . . .
C8 C 0.45467(9) 0.79048(15) 0.58748(9) 0.0183(5) Uani 1 1 d . . . . .
H8 H 0.432606 0.753814 0.572306 0.022 Uiso 1 1 calc R U . . .
C9 C 0.52456(9) 0.80028(17) 0.70224(9) 0.0220(5) Uani 1 1 d . . . . .
C10 C 0.58012(12) 0.8351(2) 0.76337(11) 0.0410(8) Uani 1 1 d . . . . .
H10A H 0.558247 0.849639 0.789600 0.061 Uiso 1 1 calc R U . . .
H10B H 0.610446 0.866367 0.766415 0.061 Uiso 1 1 calc R U . . .
H10C H 0.587216 0.775793 0.764505 0.061 Uiso 1 1 calc R U . . .
C11 C 0.38847(9) 0.91752(14) 0.34350(8) 0.0148(5) Uani 1 1 d . . . . .
C12 C 0.37697(9) 0.92639(15) 0.30224(9) 0.0182(5) Uani 1 1 d . . . . .
C13 C 0.3711(6) 0.9291(13) 0.2523(7) 0.021(3) Uani 0.617(5) 1 d . . P A 1
C14 C 0.4100(3) 0.9490(5) 0.2220(3) 0.0213(15) Uani 0.617(5) 1 d . . P A 1
H14 H 0.439332 0.969021 0.235659 0.026 Uiso 0.617(5) 1 calc R U P A 1
C14A C 0.3998(5) 0.9309(9) 0.2177(6) 0.021(3) Uani 0.383(5) 1 d . U P A 2
H14A H 0.431482 0.948119 0.226835 0.025 Uiso 0.383(5) 1 calc R U P A 2
C15 C 0.4075(2) 0.9406(4) 0.1726(2) 0.0215(12) Uani 0.617(5) 1 d . . P A 1
H15 H 0.434630 0.954925 0.153338 0.026 Uiso 0.617(5) 1 calc R U P A 1
C15A C 0.3880(4) 0.9168(6) 0.1699(3) 0.021(2) Uani 0.383(5) 1 d . . P A 2
H15A H 0.411750 0.926109 0.145887 0.025 Uiso 0.383(5) 1 calc R U P A 2
C16 C 0.3650(3) 0.9112(3) 0.15147(19) 0.0175(11) Uani 0.617(5) 1 d . . P A 1
C16A C 0.3429(4) 0.8898(6) 0.1573(4) 0.0174(18) Uani 0.383(5) 1 d . U P A 2
C17 C 0.3254(3) 0.8933(4) 0.1796(2) 0.0226(13) Uani 0.617(5) 1 d . . P A 1
H17 H 0.296068 0.874961 0.165232 0.027 Uiso 0.617(5) 1 calc R U P A 1
C17A C 0.3068(4) 0.8838(6) 0.1915(4) 0.021(2) Uani 0.383(5) 1 d . . P A 2
H17A H 0.274960 0.868289 0.182106 0.025 Uiso 0.383(5) 1 calc R U P A 2
C18 C 0.3280(4) 0.9019(9) 0.2295(4) 0.0241(19) Uani 0.617(5) 1 d . . P A 1
H18 H 0.300242 0.889171 0.248214 0.029 Uiso 0.617(5) 1 calc R U P A 1
C18A C 0.3159(6) 0.8995(15) 0.2388(7) 0.020(3) Uani 0.383(5) 1 d . . P A 2
H18A H 0.290911 0.897461 0.262035 0.024 Uiso 0.383(5) 1 calc R U P A 2
C19 C 0.3657(2) 0.8989(3) 0.0990(2) 0.0214(11) Uani 0.617(5) 1 d . . P A 1
C19A C 0.3309(3) 0.8616(5) 0.1081(4) 0.0231(19) Uani 0.383(5) 1 d . . P A 2
C20 C 0.3267(2) 0.8374(3) 0.03289(18) 0.0294(12) Uani 0.617(5) 1 d . . P A 1
H20A H 0.300101 0.799265 0.025328 0.044 Uiso 0.617(5) 1 calc R U P A 1
H20B H 0.357552 0.813576 0.022271 0.044 Uiso 0.617(5) 1 calc R U P A 1
H20C H 0.321215 0.890134 0.016609 0.044 Uiso 0.617(5) 1 calc R U P A 1
C20A C 0.3522(4) 0.8620(6) 0.0267(3) 0.032(2) Uani 0.383(5) 1 d . . P A 2
H20D H 0.350081 0.801610 0.025089 0.048 Uiso 0.383(5) 1 calc R U P A 2
H20E H 0.378207 0.881212 0.005530 0.048 Uiso 0.383(5) 1 calc R U P A 2
H20F H 0.321246 0.886199 0.016620 0.048 Uiso 0.383(5) 1 calc R U P A 2
C21 C 0.36696(9) 1.09149(14) 0.43266(9) 0.0154(5) Uani 1 1 d . . . . .
C22 C 0.39889(9) 1.11810(15) 0.46802(9) 0.0206(5) Uani 1 1 d . . . . .
H22 H 0.408591 1.081175 0.492536 0.025 Uiso 1 1 calc R U . . .
C23 C 0.41654(10) 1.19846(16) 0.46749(10) 0.0258(6) Uani 1 1 d . . . . .
H23 H 0.437895 1.216915 0.491844 0.031 Uiso 1 1 calc R U . . .
C24 C 0.40287(10) 1.25132(16) 0.43135(11) 0.0288(6) Uani 1 1 d . . . . .
H24 H 0.415290 1.306073 0.430756 0.035 Uiso 1 1 calc R U . . .
C25 C 0.37141(11) 1.22574(16) 0.39608(11) 0.0296(6) Uani 1 1 d . . . . .
H25 H 0.362188 1.262842 0.371475 0.036 Uiso 1 1 calc R U . . .
C26 C 0.35311(10) 1.14525(15) 0.39654(10) 0.0220(5) Uani 1 1 d . . . . .
H26 H 0.331373 1.127402 0.372359 0.026 Uiso 1 1 calc R U . . .
C27 C 0.32442(9) 0.97313(14) 0.49512(8) 0.0141(5) Uani 1 1 d . . . . .
C28 C 0.32923(9) 0.90008(15) 0.52082(8) 0.0165(5) Uani 1 1 d . . . . .
H28 H 0.347263 0.855266 0.507974 0.020 Uiso 1 1 calc R U . . .
C29 C 0.30761(9) 0.89290(16) 0.56529(9) 0.0208(5) Uani 1 1 d . . . . .
H29 H 0.310819 0.843041 0.582857 0.025 Uiso 1 1 calc R U . . .
C30 C 0.28131(10) 0.95832(17) 0.58418(9) 0.0222(5) Uani 1 1 d . . . . .
H30 H 0.266829 0.953274 0.614750 0.027 Uiso 1 1 calc R U . . .
C31 C 0.27614(9) 1.03092(16) 0.55859(9) 0.0214(5) Uani 1 1 d . . . . .
H31 H 0.258216 1.075688 0.571632 0.026 Uiso 1 1 calc R U . . .
C32 C 0.29713(9) 1.03816(15) 0.51395(9) 0.0180(5) Uani 1 1 d . . . . .
H32 H 0.292952 1.087488 0.496087 0.022 Uiso 1 1 calc R U . . .
C33 C 0.29432(8) 0.97265(14) 0.39852(8) 0.0140(4) Uani 1 1 d . . . . .
H33A H 0.301901 0.988541 0.365297 0.017 Uiso 1 1 calc R U . . .
H33B H 0.268584 1.010055 0.410427 0.017 Uiso 1 1 calc R U . . .
C34 C 0.23132(10) 0.79161(17) 0.32006(10) 0.0274(6) Uani 1 1 d . . . . .
H34 H 0.252425 0.746990 0.327483 0.033 Uiso 1 1 calc R U . . .
C35 C 0.20053(12) 0.78592(19) 0.28110(11) 0.0355(7) Uani 1 1 d . . . . .
H35 H 0.200677 0.737537 0.261950 0.043 Uiso 1 1 calc R U . . .
C36 C 0.16959(11) 0.85053(19) 0.27006(10) 0.0316(7) Uani 1 1 d . . . . .
H36 H 0.148895 0.847067 0.243054 0.038 Uiso 1 1 calc R U . . .
C37 C 0.16899(11) 0.92030(18) 0.29864(11) 0.0319(7) Uani 1 1 d . . . . .
H37 H 0.147289 0.964244 0.291532 0.038 Uiso 1 1 calc R U . . .
C38 C 0.19980(10) 0.92651(17) 0.33752(10) 0.0264(6) Uani 1 1 d . . . . .
H38 H 0.199273 0.974705 0.356821 0.032 Uiso 1 1 calc R U . . .
C39 C 0.23154(9) 0.86212(15) 0.34833(9) 0.0169(5) Uani 1 1 d . . . . .
C40 C 0.23077(9) 0.85757(14) 0.45057(8) 0.0158(5) Uani 1 1 d . . . . .
C41 C 0.22835(10) 0.78246(15) 0.47446(9) 0.0216(5) Uani 1 1 d . . . . .
H41 H 0.248573 0.737984 0.464741 0.026 Uiso 1 1 calc R U . . .
C42 C 0.19647(10) 0.77191(16) 0.51259(10) 0.0259(6) Uani 1 1 d . . . . .
H42 H 0.195176 0.720449 0.528806 0.031 Uiso 1 1 calc R U . . .
C43 C 0.16687(10) 0.83596(16) 0.52680(9) 0.0227(5) Uani 1 1 d . . . . .
H43 H 0.145186 0.828738 0.552791 0.027 Uiso 1 1 calc R U . . .
C44 C 0.16880(10) 0.91077(17) 0.50311(10) 0.0249(6) Uani 1 1 d . . . . .
H44 H 0.148311 0.954861 0.512890 0.030 Uiso 1 1 calc R U . . .
C45 C 0.20057(10) 0.92202(16) 0.46500(9) 0.0222(5) Uani 1 1 d . . . . .
H45 H 0.201645 0.973571 0.448866 0.027 Uiso 1 1 calc R U . . .
C46 C 0.36887(9) 0.68443(14) 0.28052(8) 0.0158(5) Uani 1 1 d . . . . .
C47 C 0.32425(9) 0.64345(15) 0.28225(9) 0.0205(5) Uani 1 1 d . . . . .
H47 H 0.311029 0.627503 0.312113 0.025 Uiso 1 1 calc R U . . .
C48 C 0.29914(10) 0.62589(17) 0.24070(10) 0.0258(6) Uani 1 1 d . . . . .
H48 H 0.268877 0.597748 0.241966 0.031 Uiso 1 1 calc R U . . .
C49 C 0.31852(10) 0.64971(17) 0.19729(9) 0.0247(6) Uani 1 1 d . . . . .
H49 H 0.301271 0.638272 0.168738 0.030 Uiso 1 1 calc R U . . .
C50 C 0.36274(10) 0.68995(17) 0.19519(9) 0.0247(6) Uani 1 1 d . . . . .
H50 H 0.375866 0.705732 0.165252 0.030 Uiso 1 1 calc R U . . .
C51 C 0.38810(10) 0.70743(15) 0.23693(9) 0.0200(5) Uani 1 1 d . . . . .
H51 H 0.418516 0.735058 0.235484 0.024 Uiso 1 1 calc R U . . .
C52 C 0.42259(9) 0.59593(14) 0.34865(9) 0.0154(5) Uani 1 1 d . . . . .
C53 C 0.44899(10) 0.55430(15) 0.31346(9) 0.0208(5) Uani 1 1 d . . . . .
H53 H 0.456339 0.581237 0.284275 0.025 Uiso 1 1 calc R U . . .
C54 C 0.46448(10) 0.47373(16) 0.32108(10) 0.0254(6) Uani 1 1 d . . . . .
H54 H 0.482207 0.445456 0.297069 0.030 Uiso 1 1 calc R U . . .
C55 C 0.45402(11) 0.43459(16) 0.36382(10) 0.0285(6) Uani 1 1 d . . . . .
H55 H 0.464643 0.379499 0.369080 0.034 Uiso 1 1 calc R U . . .
C56 C 0.42818(11) 0.47559(16) 0.39872(10) 0.0259(6) Uani 1 1 d . . . . .
H56 H 0.421328 0.448659 0.428014 0.031 Uiso 1 1 calc R U . . .
C57 C 0.41217(9) 0.55581(15) 0.39131(9) 0.0191(5) Uani 1 1 d . . . . .
H57 H 0.394100 0.583396 0.415350 0.023 Uiso 1 1 calc R U . . .
C58 C 0.45209(8) 0.76338(14) 0.32585(8) 0.0137(4) Uani 1 1 d . . . . .
H58A H 0.478818 0.728223 0.313774 0.016 Uiso 1 1 calc R U . . .
H58B H 0.444299 0.805146 0.301257 0.016 Uiso 1 1 calc R U . . .
C59 C 0.52497(8) 0.87320(14) 0.36608(8) 0.0136(4) Uani 1 1 d . . . . .
C60 C 0.53562(9) 0.89787(15) 0.31967(9) 0.0186(5) Uani 1 1 d . . . . .
H60 H 0.516020 0.879572 0.293898 0.022 Uiso 1 1 calc R U . . .
C61 C 0.57526(10) 0.94960(16) 0.31135(9) 0.0232(5) Uani 1 1 d . . . . .
H61 H 0.582446 0.966898 0.279803 0.028 Uiso 1 1 calc R U . . .
C62 C 0.60410(10) 0.97584(16) 0.34854(10) 0.0236(6) Uani 1 1 d . . . . .
H62 H 0.631079 1.010946 0.342565 0.028 Uiso 1 1 calc R U . . .
C63 C 0.59367(9) 0.95091(16) 0.39473(10) 0.0223(5) Uani 1 1 d . . . . .
H63 H 0.613612 0.968657 0.420380 0.027 Uiso 1 1 calc R U . . .
C64 C 0.55417(9) 0.90017(15) 0.40333(9) 0.0196(5) Uani 1 1 d . . . . .
H64 H 0.546948 0.883607 0.435008 0.024 Uiso 1 1 calc R U . . .
C65 C 0.49334(9) 0.72855(14) 0.41680(8) 0.0143(5) Uani 1 1 d . . . . .
C66 C 0.53394(9) 0.68502(15) 0.40032(9) 0.0190(5) Uani 1 1 d . . . . .
H66 H 0.550564 0.703155 0.372579 0.023 Uiso 1 1 calc R U . . .
C67 C 0.54994(10) 0.61531(16) 0.42454(10) 0.0232(5) Uani 1 1 d . . . . .
H67 H 0.576799 0.584652 0.412750 0.028 Uiso 1 1 calc R U . . .
C68 C 0.52674(10) 0.59060(15) 0.46578(10) 0.0255(6) Uani 1 1 d . . . . .
H68 H 0.538128 0.543507 0.482609 0.031 Uiso 1 1 calc R U . . .
C69 C 0.48702(11) 0.63401(15) 0.48275(9) 0.0244(6) Uani 1 1 d . . . . .
H69 H 0.471413 0.617094 0.511308 0.029 Uiso 1 1 calc R U . . .
C70 C 0.46994(10) 0.70269(15) 0.45779(9) 0.0195(5) Uani 1 1 d . . . . .
H70 H 0.442202 0.731741 0.468962 0.023 Uiso 1 1 calc R U . . .
Cl2 Cl 0.66280(3) 0.79125(5) 0.36201(3) 0.0450(2) Uani 1 1 d . . . . .
Cl3 Cl 0.68166(3) 0.61866(5) 0.33799(3) 0.04294(19) Uani 1 1 d . . . . .
C71 C 0.70719(11) 0.71375(19) 0.35625(11) 0.0336(7) Uani 1 1 d . . . . .
H71A H 0.723835 0.706111 0.387187 0.040 Uiso 1 1 calc R U . . .
H71B H 0.731776 0.731478 0.332630 0.040 Uiso 1 1 calc R U . . .
C13A C 0.3639(9) 0.919(2) 0.2509(10) 0.013(3) Uani 0.383(5) 1 d . U P A 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 Ag2 3.10066(19) . ?
Pt1 P1 2.2941(6) . ?
Pt1 P4 2.3080(6) . ?
Pt1 C1 1.997(2) . ?
Pt1 C11 2.010(2) . ?
Ag2 Cl1 2.5686(6) . ?
Ag2 P2 2.4599(6) . ?
Ag2 P3 2.4798(6) . ?
P1 C21 1.814(2) . ?
P1 C27 1.818(2) . ?
P1 C33 1.823(2) . ?
P2 C33 1.844(2) . ?
P2 C39 1.829(2) . ?
P2 C40 1.828(2) . ?
P3 C46 1.827(2) . ?
P3 C52 1.830(2) . ?
P3 C58 1.840(2) . ?
P4 C58 1.831(2) . ?
P4 C59 1.814(2) . ?
P4 C65 1.828(2) . ?
O1 C9 1.206(3) . ?
O2 C9 1.340(3) . ?
O2 C10 1.446(3) . ?
O3 C19 1.354(7) . ?
O3 C20 1.455(6) . ?
O3A C19A 1.333(12) . ?
O3A C20A 1.467(11) . ?
O4 C19 1.203(7) . ?
O4A C19A 1.211(11) . ?
C1 C2 1.215(3) . ?
C2 C3 1.429(3) . ?
C3 C4 1.408(3) . ?
C3 C8 1.406(3) . ?
C4 H4 0.9500 . ?
C4 C5 1.380(3) . ?
C5 H5 0.9500 . ?
C5 C6 1.395(3) . ?
C6 C7 1.396(4) . ?
C6 C9 1.487(3) . ?
C7 H7 0.9500 . ?
C7 C8 1.388(3) . ?
C8 H8 0.9500 . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C11 C12 1.210(3) . ?
C12 C13 1.41(2) . ?
C12 C13A 1.49(3) . ?
C13 C14 1.407(18) . ?
C13 C18 1.419(14) . ?
C14 H14 0.9500 . ?
C14 C15 1.396(11) . ?
C14A H14A 0.9500 . ?
C14A C15A 1.401(19) . ?
C14A C13A 1.37(3) . ?
C15 H15 0.9500 . ?
C15 C16 1.394(8) . ?
C15A H15A 0.9500 . ?
C15A C16A 1.363(13) . ?
C16 C17 1.377(8) . ?
C16 C19 1.486(8) . ?
C16A C17A 1.384(12) . ?
C16A C19A 1.493(14) . ?
C17 H17 0.9500 . ?
C17 C18 1.410(14) . ?
C17A H17A 0.9500 . ?
C17A C18A 1.37(2) . ?
C18 H18 0.9500 . ?
C18A H18A 0.9500 . ?
C18A C13A 1.40(2) . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C20A H20D 0.9800 . ?
C20A H20E 0.9800 . ?
C20A H20F 0.9800 . ?
C21 C22 1.394(3) . ?
C21 C26 1.390(3) . ?
C22 H22 0.9500 . ?
C22 C23 1.389(3) . ?
C23 H23 0.9500 . ?
C23 C24 1.380(4) . ?
C24 H24 0.9500 . ?
C24 C25 1.379(4) . ?
C25 H25 0.9500 . ?
C25 C26 1.397(4) . ?
C26 H26 0.9500 . ?
C27 C28 1.392(3) . ?
C27 C32 1.397(3) . ?
C28 H28 0.9500 . ?
C28 C29 1.388(3) . ?
C29 H29 0.9500 . ?
C29 C30 1.388(4) . ?
C30 H30 0.9500 . ?
C30 C31 1.385(4) . ?
C31 H31 0.9500 . ?
C31 C32 1.385(3) . ?
C32 H32 0.9500 . ?
C33 H33A 0.9900 . ?
C33 H33B 0.9900 . ?
C34 H34 0.9500 . ?
C34 C35 1.387(4) . ?
C34 C39 1.390(3) . ?
C35 H35 0.9500 . ?
C35 C36 1.384(4) . ?
C36 H36 0.9500 . ?
C36 C37 1.386(4) . ?
C37 H37 0.9500 . ?
C37 C38 1.386(4) . ?
C38 H38 0.9500 . ?
C38 C39 1.393(4) . ?
C40 C41 1.390(3) . ?
C40 C45 1.394(3) . ?
C41 H41 0.9500 . ?
C41 C42 1.395(4) . ?
C42 H42 0.9500 . ?
C42 C43 1.378(4) . ?
C43 H43 0.9500 . ?
C43 C44 1.383(4) . ?
C44 H44 0.9500 . ?
C44 C45 1.394(4) . ?
C45 H45 0.9500 . ?
C46 C47 1.397(3) . ?
C46 C51 1.384(3) . ?
C47 H47 0.9500 . ?
C47 C48 1.386(4) . ?
C48 H48 0.9500 . ?
C48 C49 1.385(4) . ?
C49 H49 0.9500 . ?
C49 C50 1.382(4) . ?
C50 H50 0.9500 . ?
C50 C51 1.393(4) . ?
C51 H51 0.9500 . ?
C52 C53 1.400(3) . ?
C52 C57 1.392(3) . ?
C53 H53 0.9500 . ?
C53 C54 1.389(4) . ?
C54 H54 0.9500 . ?
C54 C55 1.387(4) . ?
C55 H55 0.9500 . ?
C55 C56 1.381(4) . ?
C56 H56 0.9500 . ?
C56 C57 1.387(3) . ?
C57 H57 0.9500 . ?
C58 H58A 0.9900 . ?
C58 H58B 0.9900 . ?
C59 C60 1.394(3) . ?
C59 C64 1.390(3) . ?
C60 H60 0.9500 . ?
C60 C61 1.395(3) . ?
C61 H61 0.9500 . ?
C61 C62 1.379(4) . ?
C62 H62 0.9500 . ?
C62 C63 1.388(4) . ?
C63 H63 0.9500 . ?
C63 C64 1.384(3) . ?
C64 H64 0.9500 . ?
C65 C66 1.400(3) . ?
C65 C70 1.384(3) . ?
C66 H66 0.9500 . ?
C66 C67 1.389(3) . ?
C67 H67 0.9500 . ?
C67 C68 1.382(4) . ?
C68 H68 0.9500 . ?
C68 C69 1.384(4) . ?
C69 H69 0.9500 . ?
C69 C70 1.396(3) . ?
C70 H70 0.9500 . ?
Cl2 C71 1.758(3) . ?
Cl3 C71 1.768(3) . ?
C71 H71A 0.9900 . ?
C71 H71B 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Pt1 Ag2 89.911(15) . . ?
P1 Pt1 P4 175.90(2) . . ?
P4 Pt1 Ag2 89.186(15) . . ?
C1 Pt1 Ag2 109.43(7) . . ?
C1 Pt1 P1 92.07(7) . . ?
C1 Pt1 P4 92.00(7) . . ?
C1 Pt1 C11 175.15(9) . . ?
C11 Pt1 Ag2 75.42(7) . . ?
C11 Pt1 P1 88.07(7) . . ?
C11 Pt1 P4 87.84(7) . . ?
Cl1 Ag2 Pt1 150.996(16) . . ?
P2 Ag2 Pt1 86.954(15) . . ?
P2 Ag2 Cl1 104.50(2) . . ?
P2 Ag2 P3 145.14(2) . . ?
P3 Ag2 Pt1 85.921(15) . . ?
P3 Ag2 Cl1 98.04(2) . . ?
C21 P1 Pt1 111.02(8) . . ?
C21 P1 C27 103.34(11) . . ?
C21 P1 C33 107.64(11) . . ?
C27 P1 Pt1 119.20(8) . . ?
C27 P1 C33 102.36(11) . . ?
C33 P1 Pt1 112.27(8) . . ?
C33 P2 Ag2 114.92(8) . . ?
C39 P2 Ag2 110.03(8) . . ?
C39 P2 C33 102.21(11) . . ?
C40 P2 Ag2 117.92(8) . . ?
C40 P2 C33 106.57(11) . . ?
C40 P2 C39 103.49(11) . . ?
C46 P3 Ag2 106.44(8) . . ?
C46 P3 C52 100.44(11) . . ?
C46 P3 C58 105.29(11) . . ?
C52 P3 Ag2 120.94(8) . . ?
C52 P3 C58 104.44(11) . . ?
C58 P3 Ag2 117.06(7) . . ?
C58 P4 Pt1 111.83(8) . . ?
C59 P4 Pt1 111.65(7) . . ?
C59 P4 C58 105.88(11) . . ?
C59 P4 C65 104.31(11) . . ?
C65 P4 Pt1 119.54(8) . . ?
C65 P4 C58 102.39(10) . . ?
C9 O2 C10 116.3(2) . . ?
C19 O3 C20 114.6(5) . . ?
C19A O3A C20A 114.8(9) . . ?
C2 C1 Pt1 179.4(2) . . ?
C1 C2 C3 174.0(3) . . ?
C4 C3 C2 121.5(2) . . ?
C8 C3 C2 119.9(2) . . ?
C8 C3 C4 118.5(2) . . ?
C3 C4 H4 119.6 . . ?
C5 C4 C3 120.9(2) . . ?
C5 C4 H4 119.6 . . ?
C4 C5 H5 119.9 . . ?
C4 C5 C6 120.1(2) . . ?
C6 C5 H5 119.9 . . ?
C5 C6 C7 119.8(2) . . ?
C5 C6 C9 122.2(2) . . ?
C7 C6 C9 118.0(2) . . ?
C6 C7 H7 119.9 . . ?
C8 C7 C6 120.2(2) . . ?
C8 C7 H7 119.9 . . ?
C3 C8 H8 119.8 . . ?
C7 C8 C3 120.5(2) . . ?
C7 C8 H8 119.8 . . ?
O1 C9 O2 123.6(2) . . ?
O1 C9 C6 124.8(2) . . ?
O2 C9 C6 111.6(2) . . ?
O2 C10 H10A 109.5 . . ?
O2 C10 H10B 109.5 . . ?
O2 C10 H10C 109.5 . . ?
H10A C10 H10B 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
C12 C11 Pt1 177.0(2) . . ?
C11 C12 C13 170.0(9) . . ?
C11 C12 C13A 168.4(14) . . ?
C12 C13 C18 122.4(13) . . ?
C14 C13 C12 121.5(12) . . ?
C14 C13 C18 115.7(14) . . ?
C13 C14 H14 118.6 . . ?
C15 C14 C13 122.8(10) . . ?
C15 C14 H14 118.6 . . ?
C15A C14A H14A 121.3 . . ?
C13A C14A H14A 121.3 . . ?
C13A C14A C15A 117.5(14) . . ?
C14 C15 H15 120.1 . . ?
C16 C15 C14 119.8(6) . . ?
C16 C15 H15 120.1 . . ?
C14A C15A H15A 119.6 . . ?
C16A C15A C14A 120.7(9) . . ?
C16A C15A H15A 119.6 . . ?
C15 C16 C19 117.2(6) . . ?
C17 C16 C15 119.5(5) . . ?
C17 C16 C19 123.3(7) . . ?
C15A C16A C17A 119.8(8) . . ?
C15A C16A C19A 122.6(11) . . ?
C17A C16A C19A 117.6(10) . . ?
C16 C17 H17 119.7 . . ?
C16 C17 C18 120.6(7) . . ?
C18 C17 H17 119.7 . . ?
C16A C17A H17A 119.1 . . ?
C18A C17A C16A 121.7(10) . . ?
C18A C17A H17A 119.1 . . ?
C13 C18 H18 119.2 . . ?
C17 C18 C13 121.5(10) . . ?
C17 C18 H18 119.2 . . ?
C17A C18A H18A 121.6 . . ?
C17A C18A C13A 116.7(15) . . ?
C13A C18A H18A 121.6 . . ?
O3 C19 C16 112.0(6) . . ?
O4 C19 O3 123.0(6) . . ?
O4 C19 C16 125.0(6) . . ?
O3A C19A C16A 112.9(10) . . ?
O4A C19A O3A 123.5(10) . . ?
O4A C19A C16A 123.6(9) . . ?
O3 C20 H20A 109.5 . . ?
O3 C20 H20B 109.5 . . ?
O3 C20 H20C 109.5 . . ?
H20A C20 H20B 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
O3A C20A H20D 109.5 . . ?
O3A C20A H20E 109.5 . . ?
O3A C20A H20F 109.5 . . ?
H20D C20A H20E 109.5 . . ?
H20D C20A H20F 109.5 . . ?
H20E C20A H20F 109.5 . . ?
C22 C21 P1 116.40(18) . . ?
C26 C21 P1 123.55(19) . . ?
C26 C21 C22 120.0(2) . . ?
C21 C22 H22 119.9 . . ?
C23 C22 C21 120.2(2) . . ?
C23 C22 H22 119.9 . . ?
C22 C23 H23 120.2 . . ?
C24 C23 C22 119.6(3) . . ?
C24 C23 H23 120.2 . . ?
C23 C24 H24 119.6 . . ?
C25 C24 C23 120.9(2) . . ?
C25 C24 H24 119.6 . . ?
C24 C25 H25 120.0 . . ?
C24 C25 C26 120.0(3) . . ?
C26 C25 H25 120.0 . . ?
C21 C26 C25 119.5(3) . . ?
C21 C26 H26 120.3 . . ?
C25 C26 H26 120.3 . . ?
C28 C27 P1 121.82(18) . . ?
C28 C27 C32 119.7(2) . . ?
C32 C27 P1 118.30(18) . . ?
C27 C28 H28 120.1 . . ?
C29 C28 C27 119.8(2) . . ?
C29 C28 H28 120.1 . . ?
C28 C29 H29 119.9 . . ?
C30 C29 C28 120.2(2) . . ?
C30 C29 H29 119.9 . . ?
C29 C30 H30 119.9 . . ?
C31 C30 C29 120.2(2) . . ?
C31 C30 H30 119.9 . . ?
C30 C31 H31 120.1 . . ?
C30 C31 C32 119.9(2) . . ?
C32 C31 H31 120.1 . . ?
C27 C32 H32 119.9 . . ?
C31 C32 C27 120.2(2) . . ?
C31 C32 H32 119.9 . . ?
P1 C33 P2 110.74(12) . . ?
P1 C33 H33A 109.5 . . ?
P1 C33 H33B 109.5 . . ?
P2 C33 H33A 109.5 . . ?
P2 C33 H33B 109.5 . . ?
H33A C33 H33B 108.1 . . ?
C35 C34 H34 119.7 . . ?
C35 C34 C39 120.5(3) . . ?
C39 C34 H34 119.7 . . ?
C34 C35 H35 119.9 . . ?
C36 C35 C34 120.2(3) . . ?
C36 C35 H35 119.9 . . ?
C35 C36 H36 120.2 . . ?
C35 C36 C37 119.6(3) . . ?
C37 C36 H36 120.2 . . ?
C36 C37 H37 119.7 . . ?
C36 C37 C38 120.5(3) . . ?
C38 C37 H37 119.7 . . ?
C37 C38 H38 120.0 . . ?
C37 C38 C39 120.1(2) . . ?
C39 C38 H38 120.0 . . ?
C34 C39 P2 118.45(19) . . ?
C34 C39 C38 119.1(2) . . ?
C38 C39 P2 122.38(19) . . ?
C41 C40 P2 117.68(18) . . ?
C41 C40 C45 119.1(2) . . ?
C45 C40 P2 123.21(19) . . ?
C40 C41 H41 119.7 . . ?
C40 C41 C42 120.5(2) . . ?
C42 C41 H41 119.7 . . ?
C41 C42 H42 119.9 . . ?
C43 C42 C41 120.1(2) . . ?
C43 C42 H42 119.9 . . ?
C42 C43 H43 120.1 . . ?
C42 C43 C44 119.8(2) . . ?
C44 C43 H43 120.1 . . ?
C43 C44 H44 119.7 . . ?
C43 C44 C45 120.5(2) . . ?
C45 C44 H44 119.7 . . ?
C40 C45 C44 120.0(2) . . ?
C40 C45 H45 120.0 . . ?
C44 C45 H45 120.0 . . ?
C47 C46 P3 114.91(18) . . ?
C51 C46 P3 125.41(19) . . ?
C51 C46 C47 119.6(2) . . ?
C46 C47 H47 119.8 . . ?
C48 C47 C46 120.4(2) . . ?
C48 C47 H47 119.8 . . ?
C47 C48 H48 120.3 . . ?
C49 C48 C47 119.5(3) . . ?
C49 C48 H48 120.3 . . ?
C48 C49 H49 119.7 . . ?
C50 C49 C48 120.5(2) . . ?
C50 C49 H49 119.7 . . ?
C49 C50 H50 120.0 . . ?
C49 C50 C51 120.1(2) . . ?
C51 C50 H50 120.0 . . ?
C46 C51 C50 119.9(2) . . ?
C46 C51 H51 120.1 . . ?
C50 C51 H51 120.1 . . ?
C53 C52 P3 121.24(19) . . ?
C57 C52 P3 119.32(18) . . ?
C57 C52 C53 119.3(2) . . ?
C52 C53 H53 119.9 . . ?
C54 C53 C52 120.2(2) . . ?
C54 C53 H53 119.9 . . ?
C53 C54 H54 120.0 . . ?
C55 C54 C53 119.9(2) . . ?
C55 C54 H54 120.0 . . ?
C54 C55 H55 120.0 . . ?
C56 C55 C54 120.1(2) . . ?
C56 C55 H55 120.0 . . ?
C55 C56 H56 119.8 . . ?
C55 C56 C57 120.5(2) . . ?
C57 C56 H56 119.8 . . ?
C52 C57 H57 120.0 . . ?
C56 C57 C52 120.0(2) . . ?
C56 C57 H57 120.0 . . ?
P3 C58 H58A 109.9 . . ?
P3 C58 H58B 109.9 . . ?
P4 C58 P3 108.81(12) . . ?
P4 C58 H58A 109.9 . . ?
P4 C58 H58B 109.9 . . ?
H58A C58 H58B 108.3 . . ?
C60 C59 P4 122.53(18) . . ?
C64 C59 P4 117.73(18) . . ?
C64 C59 C60 119.5(2) . . ?
C59 C60 H60 120.2 . . ?
C59 C60 C61 119.5(2) . . ?
C61 C60 H60 120.2 . . ?
C60 C61 H61 119.7 . . ?
C62 C61 C60 120.5(2) . . ?
C62 C61 H61 119.7 . . ?
C61 C62 H62 120.0 . . ?
C61 C62 C63 119.9(2) . . ?
C63 C62 H62 120.0 . . ?
C62 C63 H63 120.1 . . ?
C64 C63 C62 119.9(2) . . ?
C64 C63 H63 120.1 . . ?
C59 C64 H64 119.7 . . ?
C63 C64 C59 120.6(2) . . ?
C63 C64 H64 119.7 . . ?
C66 C65 P4 118.20(18) . . ?
C70 C65 P4 122.08(19) . . ?
C70 C65 C66 119.6(2) . . ?
C65 C66 H66 120.0 . . ?
C67 C66 C65 120.0(2) . . ?
C67 C66 H66 120.0 . . ?
C66 C67 H67 120.0 . . ?
C68 C67 C66 119.9(2) . . ?
C68 C67 H67 120.0 . . ?
C67 C68 H68 119.8 . . ?
C67 C68 C69 120.4(2) . . ?
C69 C68 H68 119.8 . . ?
C68 C69 H69 120.1 . . ?
C68 C69 C70 119.8(2) . . ?
C70 C69 H69 120.1 . . ?
C65 C70 C69 120.1(2) . . ?
C65 C70 H70 119.9 . . ?
C69 C70 H70 119.9 . . ?
Cl2 C71 Cl3 111.82(17) . . ?
Cl2 C71 H71A 109.3 . . ?
Cl2 C71 H71B 109.3 . . ?
Cl3 C71 H71A 109.3 . . ?
Cl3 C71 H71B 109.3 . . ?
H71A C71 H71B 107.9 . . ?
C14A C13A C12 118.1(17) . . ?
C14A C13A C18A 123(2) . . ?
C18A C13A C12 119(2) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Pt1 P1 C21 C22 -74.1(2) . . . . ?
Pt1 P1 C21 C26 102.3(2) . . . . ?
Pt1 P1 C27 C28 -22.5(2) . . . . ?
Pt1 P1 C27 C32 162.52(16) . . . . ?
Pt1 P1 C33 P2 58.60(13) . . . . ?
Pt1 P4 C58 P3 -60.00(12) . . . . ?
Pt1 P4 C59 C60 -99.2(2) . . . . ?
Pt1 P4 C59 C64 74.93(19) . . . . ?
Pt1 P4 C65 C66 -172.30(15) . . . . ?
Pt1 P4 C65 C70 11.4(2) . . . . ?
Ag2 P2 C33 P1 -44.12(14) . . . . ?
Ag2 P2 C39 C34 18.0(2) . . . . ?
Ag2 P2 C39 C38 -164.2(2) . . . . ?
Ag2 P2 C40 C41 -16.9(2) . . . . ?
Ag2 P2 C40 C45 165.61(18) . . . . ?
Ag2 P3 C46 C47 -49.45(19) . . . . ?
Ag2 P3 C46 C51 132.9(2) . . . . ?
Ag2 P3 C52 C53 165.14(17) . . . . ?
Ag2 P3 C52 C57 -10.9(2) . . . . ?
Ag2 P3 C58 P4 40.63(14) . . . . ?
P1 C21 C22 C23 177.1(2) . . . . ?
P1 C21 C26 C25 -176.2(2) . . . . ?
P1 C27 C28 C29 -176.00(19) . . . . ?
P1 C27 C32 C31 176.95(19) . . . . ?
P2 C40 C41 C42 -178.2(2) . . . . ?
P2 C40 C45 C44 177.9(2) . . . . ?
P3 C46 C47 C48 -177.9(2) . . . . ?
P3 C46 C51 C50 177.9(2) . . . . ?
P3 C52 C53 C54 -175.9(2) . . . . ?
P3 C52 C57 C56 176.6(2) . . . . ?
P4 C59 C60 C61 173.68(19) . . . . ?
P4 C59 C64 C63 -174.5(2) . . . . ?
P4 C65 C66 C67 -175.08(19) . . . . ?
P4 C65 C70 C69 176.79(19) . . . . ?
C2 C3 C4 C5 -177.4(2) . . . . ?
C2 C3 C8 C7 177.4(2) . . . . ?
C3 C4 C5 C6 0.0(4) . . . . ?
C4 C3 C8 C7 -1.0(4) . . . . ?
C4 C5 C6 C7 -0.9(4) . . . . ?
C4 C5 C6 C9 177.8(2) . . . . ?
C5 C6 C7 C8 0.8(4) . . . . ?
C5 C6 C9 O1 178.2(3) . . . . ?
C5 C6 C9 O2 -2.3(3) . . . . ?
C6 C7 C8 C3 0.2(4) . . . . ?
C7 C6 C9 O1 -3.2(4) . . . . ?
C7 C6 C9 O2 176.4(2) . . . . ?
C8 C3 C4 C5 1.0(4) . . . . ?
C9 C6 C7 C8 -177.9(2) . . . . ?
C10 O2 C9 O1 2.2(4) . . . . ?
C10 O2 C9 C6 -177.4(2) . . . . ?
C11 C12 C13 C14 -45(6) . . . . ?
C11 C12 C13 C18 127(4) . . . . ?
C11 C12 C13A C14A -96(5) . . . . ?
C11 C12 C13A C18A 84(6) . . . . ?
C12 C13 C14 C15 170.4(12) . . . . ?
C12 C13 C18 C17 -170.2(15) . . . . ?
C13 C14 C15 C16 -0.2(15) . . . . ?
C14 C13 C18 C17 2(2) . . . . ?
C14 C15 C16 C17 2.1(9) . . . . ?
C14 C15 C16 C19 -176.4(6) . . . . ?
C14A C15A C16A C17A 6.2(15) . . . . ?
C14A C15A C16A C19A -170.3(10) . . . . ?
C15 C16 C17 C18 -2.1(11) . . . . ?
C15 C16 C19 O3 163.9(4) . . . . ?
C15 C16 C19 O4 -13.8(7) . . . . ?
C15A C14A C13A C12 174.8(18) . . . . ?
C15A C14A C13A C18A -5(4) . . . . ?
C15A C16A C17A C18A -4.0(19) . . . . ?
C15A C16A C19A O3A -18.3(11) . . . . ?
C15A C16A C19A O4A 160.7(8) . . . . ?
C16 C17 C18 C13 0.0(18) . . . . ?
C16A C17A C18A C13A -2(3) . . . . ?
C17 C16 C19 O3 -14.6(7) . . . . ?
C17 C16 C19 O4 167.7(5) . . . . ?
C17A C16A C19A O3A 165.1(8) . . . . ?
C17A C16A C19A O4A -15.9(12) . . . . ?
C17A C18A C13A C12 -173(2) . . . . ?
C17A C18A C13A C14A 7(4) . . . . ?
C18 C13 C14 C15 -2(2) . . . . ?
C19 C16 C17 C18 176.4(8) . . . . ?
C19A C16A C17A C18A 172.7(14) . . . . ?
C20 O3 C19 O4 -2.8(7) . . . . ?
C20 O3 C19 C16 179.4(4) . . . . ?
C20A O3A C19A O4A 1.8(11) . . . . ?
C20A O3A C19A C16A -179.2(7) . . . . ?
C21 P1 C27 C28 -146.2(2) . . . . ?
C21 P1 C27 C32 38.8(2) . . . . ?
C21 P1 C33 P2 -178.93(12) . . . . ?
C21 C22 C23 C24 -1.0(4) . . . . ?
C22 C21 C26 C25 0.0(4) . . . . ?
C22 C23 C24 C25 0.8(4) . . . . ?
C23 C24 C25 C26 -0.3(4) . . . . ?
C24 C25 C26 C21 -0.1(4) . . . . ?
C26 C21 C22 C23 0.6(4) . . . . ?
C27 P1 C21 C22 54.8(2) . . . . ?
C27 P1 C21 C26 -128.8(2) . . . . ?
C27 P1 C33 P2 -70.41(14) . . . . ?
C27 C28 C29 C30 -0.1(4) . . . . ?
C28 C27 C32 C31 1.9(4) . . . . ?
C28 C29 C30 C31 0.6(4) . . . . ?
C29 C30 C31 C32 0.2(4) . . . . ?
C30 C31 C32 C27 -1.4(4) . . . . ?
C32 C27 C28 C29 -1.1(4) . . . . ?
C33 P1 C21 C22 162.68(19) . . . . ?
C33 P1 C21 C26 -21.0(2) . . . . ?
C33 P1 C27 C28 102.0(2) . . . . ?
C33 P1 C27 C32 -72.9(2) . . . . ?
C33 P2 C39 C34 140.6(2) . . . . ?
C33 P2 C39 C38 -41.7(2) . . . . ?
C33 P2 C40 C41 -147.8(2) . . . . ?
C33 P2 C40 C45 34.7(2) . . . . ?
C34 C35 C36 C37 -1.1(5) . . . . ?
C35 C34 C39 P2 178.9(2) . . . . ?
C35 C34 C39 C38 1.1(4) . . . . ?
C35 C36 C37 C38 1.3(5) . . . . ?
C36 C37 C38 C39 -0.4(5) . . . . ?
C37 C38 C39 P2 -178.6(2) . . . . ?
C37 C38 C39 C34 -0.9(4) . . . . ?
C39 P2 C33 P1 -163.27(12) . . . . ?
C39 P2 C40 C41 104.8(2) . . . . ?
C39 P2 C40 C45 -72.7(2) . . . . ?
C39 C34 C35 C36 -0.1(5) . . . . ?
C40 P2 C33 P1 88.48(14) . . . . ?
C40 P2 C39 C34 -108.8(2) . . . . ?
C40 P2 C39 C38 68.9(2) . . . . ?
C40 C41 C42 C43 0.3(4) . . . . ?
C41 C40 C45 C44 0.4(4) . . . . ?
C41 C42 C43 C44 0.1(4) . . . . ?
C42 C43 C44 C45 -0.1(4) . . . . ?
C43 C44 C45 C40 -0.1(4) . . . . ?
C45 C40 C41 C42 -0.5(4) . . . . ?
C46 P3 C52 C53 48.7(2) . . . . ?
C46 P3 C52 C57 -127.4(2) . . . . ?
C46 P3 C58 P4 158.60(11) . . . . ?
C46 C47 C48 C49 -0.3(4) . . . . ?
C47 C46 C51 C50 0.3(4) . . . . ?
C47 C48 C49 C50 0.6(4) . . . . ?
C48 C49 C50 C51 -0.4(4) . . . . ?
C49 C50 C51 C46 -0.1(4) . . . . ?
C51 C46 C47 C48 -0.1(4) . . . . ?
C52 P3 C46 C47 77.4(2) . . . . ?
C52 P3 C46 C51 -100.3(2) . . . . ?
C52 P3 C58 P4 -96.07(13) . . . . ?
C52 C53 C54 C55 -0.4(4) . . . . ?
C53 C52 C57 C56 0.4(4) . . . . ?
C53 C54 C55 C56 0.1(4) . . . . ?
C54 C55 C56 C57 0.5(4) . . . . ?
C55 C56 C57 C52 -0.7(4) . . . . ?
C57 C52 C53 C54 0.2(4) . . . . ?
C58 P3 C46 C47 -174.37(18) . . . . ?
C58 P3 C46 C51 8.0(2) . . . . ?
C58 P3 C52 C53 -60.3(2) . . . . ?
C58 P3 C52 C57 123.7(2) . . . . ?
C58 P4 C59 C60 22.7(2) . . . . ?
C58 P4 C59 C64 -163.13(19) . . . . ?
C58 P4 C65 C66 63.5(2) . . . . ?
C58 P4 C65 C70 -112.8(2) . . . . ?
C59 P4 C58 P3 178.18(11) . . . . ?
C59 P4 C65 C66 -46.7(2) . . . . ?
C59 P4 C65 C70 137.0(2) . . . . ?
C59 C60 C61 C62 0.5(4) . . . . ?
C60 C59 C64 C63 -0.2(4) . . . . ?
C60 C61 C62 C63 -0.2(4) . . . . ?
C61 C62 C63 C64 -0.4(4) . . . . ?
C62 C63 C64 C59 0.6(4) . . . . ?
C64 C59 C60 C61 -0.4(4) . . . . ?
C65 P4 C58 P3 69.18(14) . . . . ?
C65 P4 C59 C60 130.4(2) . . . . ?
C65 P4 C59 C64 -55.5(2) . . . . ?
C65 C66 C67 C68 -2.2(4) . . . . ?
C66 C65 C70 C69 0.5(4) . . . . ?
C66 C67 C68 C69 1.2(4) . . . . ?
C67 C68 C69 C70 0.7(4) . . . . ?
C68 C69 C70 C65 -1.5(4) . . . . ?
C70 C65 C66 C67 1.3(4) . . . . ?
C13A C14A C15A C16A -2(2) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1b
_database_code_depnum_ccdc_archive 'CCDC 2166956'
loop_
_audit_author_name
_audit_author_address
'Qiao-Hua Wei'
;College of Chemistry, Fuzhou University
China
;
_audit_update_record             
;
2022-08-26 deposited with the CCDC.	2022-08-29 downloaded from the CCDC.
;
_audit_creation_date             2022-08-26
_audit_creation_method           
;
Olex2 1.5
(compiled 2021.11.18 svn.ra9532c28 for OlexSys, GUI svn.r6429)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C70 H58 Ag Cl O4 P4 Pt, 2(C H4 O)'
_chemical_formula_sum            'C72 H66 Ag Cl O6 P4 Pt'
_chemical_formula_weight         1489.53
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   13.0729(11)
_cell_length_b                   15.4714(13)
_cell_length_c                   17.6099(14)
_cell_angle_alpha                101.452(3)
_cell_angle_beta                 91.844(3)
_cell_angle_gamma                113.429(3)
_cell_volume                     3178.4(5)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    9711
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      25.06
_cell_measurement_theta_min      2.38
_shelx_estimated_absorpt_T_max   0.813
_shelx_estimated_absorpt_T_min   0.614
_exptl_absorpt_coefficient_mu    2.702
_exptl_absorpt_correction_T_max  0.7452
_exptl_absorpt_correction_T_min  0.5559
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS 2016/2'
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            yellow
_exptl_crystal_colour_modifier   ?
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.556
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       plate
_exptl_crystal_F_000             1496
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.16
_exptl_crystal_size_min          0.08
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0353
_diffrn_reflns_av_unetI/netI     0.0261
_diffrn_reflns_Laue_measured_fraction_full 0.995
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            52969
_diffrn_reflns_point_group_measured_fraction_full 0.995
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_theta_full        25.079
_diffrn_reflns_theta_max         25.079
_diffrn_reflns_theta_min         2.177
_diffrn_ambient_temperature      100.02
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           1.4
_diffrn_source_power             0.07
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                10627
_reflns_number_total             11244
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.38A (Bruker, 2018)'
_computing_data_collection       'SAINT V8.38A (Bruker, 2018)'
_computing_data_reduction        'SAINT V8.38A (Bruker, 2018)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_refine_diff_density_max         0.829
_refine_diff_density_min         -0.570
_refine_diff_density_rms         0.066
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.052
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     781
_refine_ls_number_reflns         11244
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0220
_refine_ls_R_factor_gt           0.0194
_refine_ls_restrained_S_all      1.052
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0085P)²+3.7730P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0430
_refine_ls_wR_factor_ref         0.0444
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups, All C(H,H,H,H,H,H) groups, All O(H) groups
2. Others
 Sof(O5)=Sof(H5A)=Sof(H71D)=Sof(H71E)=Sof(H71F)=1-FVAR(1)
 Sof(O5A)=Sof(H5AA)=Sof(H71A)=Sof(H71B)=Sof(H71C)=FVAR(1)
3.a Secondary CH2 refined with riding coordinates:
 C33(H33A,H33B), C58(H58A,H58B)
3.b Me refined with riding coordinates:
 C10(H10A,H10B,H10C), C20(H20A,H20B,H20C)
3.c Aromatic/amide H refined with riding coordinates:
 C4(H4), C5(H5), C7(H7), C8(H8), C14(H14), C15(H15), C17(H17), C18(H18),
 C22(H22), C23(H23), C24(H24), C25(H25), C26(H26), C28(H28), C29(H29), C30(H30),
  C31(H31), C32(H32), C35(H35), C36(H36), C37(H37), C38(H38), C39(H39),
 C41(H41), C42(H42), C43(H43), C44(H44), C45(H45), C46(H46), C47(H47), C48(H48),
  C49(H49), C50(H50), C53(H53), C54(H54), C55(H55), C56(H56), C57(H57),
 C59(H59), C60(H60), C61(H61), C62(H62), C63(H63), C65(H65), C66(H66), C67(H67),
  C68(H68), C69(H69)
3.d Idealised Me refined as rotating group:
 C71(H71A,H71B,H71C), C71(H71D,H71E,H71F), C72(H72A,H72B,H72C)
3.e Idealised tetrahedral OH refined as rotating group:
 O5(H5A), O5A(H5AA), O6(H6)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.87234(2) 0.36125(2) 0.80466(2) 0.01219(3) Uani 1 1 d . . . . .
Ag2 Ag 0.78389(2) 0.16575(2) 0.68904(2) 0.01387(4) Uani 1 1 d . . . . .
Cl1 Cl 0.79183(5) 0.03732(5) 0.75743(4) 0.02505(14) Uani 1 1 d . . . . .
P1 P 0.68931(5) 0.33049(4) 0.82574(4) 0.01312(12) Uani 1 1 d . . . . .
P2 P 0.59010(5) 0.15564(4) 0.68421(4) 0.01332(13) Uani 1 1 d . . . . .
P3 P 0.94260(5) 0.23539(4) 0.61555(4) 0.01323(12) Uani 1 1 d . . . . .
P4 P 1.04817(5) 0.38648(4) 0.77032(4) 0.01315(13) Uani 1 1 d . . . . .
O1 O 0.62596(18) 0.64039(14) 0.44433(11) 0.0320(5) Uani 1 1 d . . . . .
O2 O 0.6146(2) 0.51530(17) 0.35079(12) 0.0478(6) Uani 1 1 d . . . . .
O3 O 1.10576(17) 0.22476(13) 1.27333(11) 0.0293(5) Uani 1 1 d . . . . .
O4 O 0.97178(16) 0.07761(14) 1.21862(11) 0.0278(4) Uani 1 1 d . . . . .
C1 C 0.9108(2) 0.33335(17) 0.90521(15) 0.0178(5) Uani 1 1 d . . . . .
C2 C 0.9377(2) 0.31746(19) 0.96581(15) 0.0211(6) Uani 1 1 d . . . . .
C3 C 0.9606(2) 0.28207(19) 1.03104(15) 0.0209(6) Uani 1 1 d . . . . .
C4 C 1.0227(2) 0.34356(19) 1.10148(15) 0.0235(6) Uani 1 1 d . . . . .
H4 H 1.050228 0.411665 1.107562 0.028 Uiso 1 1 calc R U . . .
C5 C 1.0446(2) 0.30667(19) 1.16245(15) 0.0233(6) Uani 1 1 d . . . . .
H5 H 1.088265 0.349375 1.209547 0.028 Uiso 1 1 calc R U . . .
C6 C 1.0025(2) 0.20680(19) 1.15478(15) 0.0212(6) Uani 1 1 d . . . . .
C7 C 0.9383(2) 0.1450(2) 1.08548(16) 0.0253(6) Uani 1 1 d . . . . .
H7 H 0.907992 0.076976 1.080458 0.030 Uiso 1 1 calc R U . . .
C8 C 0.9182(2) 0.18185(19) 1.02379(16) 0.0248(6) Uani 1 1 d . . . . .
H8 H 0.875439 0.138990 0.976453 0.030 Uiso 1 1 calc R U . . .
C9 C 1.0227(2) 0.1620(2) 1.21750(15) 0.0225(6) Uani 1 1 d . . . . .
C10 C 1.1280(3) 0.1831(2) 1.33566(18) 0.0384(8) Uani 1 1 d . . . . .
H10A H 1.189281 0.233057 1.373981 0.058 Uiso 1 1 calc R U . . .
H10B H 1.060198 0.157939 1.361217 0.058 Uiso 1 1 calc R U . . .
H10C H 1.149461 0.130249 1.313788 0.058 Uiso 1 1 calc R U . . .
C11 C 0.8384(2) 0.40543(17) 0.71128(15) 0.0167(5) Uani 1 1 d . . . . .
C12 C 0.8123(2) 0.43694(17) 0.65957(15) 0.0178(5) Uani 1 1 d . . . . .
C13 C 0.7699(2) 0.46927(18) 0.59938(15) 0.0186(5) Uani 1 1 d . . . . .
C14 C 0.7215(2) 0.53578(19) 0.61875(16) 0.0219(6) Uani 1 1 d . . . . .
H14 H 0.718814 0.561185 0.672034 0.026 Uiso 1 1 calc R U . . .
C15 C 0.6774(2) 0.56481(19) 0.56069(16) 0.0233(6) Uani 1 1 d . . . . .
H15 H 0.646042 0.610809 0.574395 0.028 Uiso 1 1 calc R U . . .
C16 C 0.6791(2) 0.52662(18) 0.48254(15) 0.0197(5) Uani 1 1 d . . . . .
C17 C 0.7244(2) 0.45873(19) 0.46278(16) 0.0221(6) Uani 1 1 d . . . . .
H17 H 0.723471 0.431086 0.409381 0.027 Uiso 1 1 calc R U . . .
C18 C 0.7709(2) 0.43120(18) 0.52042(15) 0.0203(5) Uani 1 1 d . . . . .
H18 H 0.803718 0.386306 0.506348 0.024 Uiso 1 1 calc R U . . .
C19 C 0.6359(2) 0.5576(2) 0.41846(17) 0.0263(6) Uani 1 1 d . . . . .
C20 C 0.5874(3) 0.6773(3) 0.3849(2) 0.0451(9) Uani 1 1 d . . . . .
H20A H 0.582635 0.738082 0.409293 0.068 Uiso 1 1 calc R U . . .
H20B H 0.640370 0.688903 0.346112 0.068 Uiso 1 1 calc R U . . .
H20C H 0.513023 0.629760 0.359328 0.068 Uiso 1 1 calc R U . . .
C21 C 0.6721(2) 0.44101(17) 0.86515(15) 0.0185(5) Uani 1 1 d . . . . .
C22 C 0.7292(3) 0.4936(2) 0.93903(17) 0.0292(6) Uani 1 1 d . . . . .
H22 H 0.773342 0.470411 0.966018 0.035 Uiso 1 1 calc R U . . .
C23 C 0.7220(3) 0.5790(2) 0.97322(19) 0.0412(8) Uani 1 1 d . . . . .
H23 H 0.761197 0.614453 1.023532 0.049 Uiso 1 1 calc R U . . .
C24 C 0.6579(3) 0.6127(2) 0.9342(2) 0.0468(9) Uani 1 1 d . . . . .
H24 H 0.652386 0.671163 0.958003 0.056 Uiso 1 1 calc R U . . .
C25 C 0.6013(3) 0.5619(2) 0.8604(2) 0.0457(9) Uani 1 1 d . . . . .
H25 H 0.557294 0.585442 0.833719 0.055 Uiso 1 1 calc R U . . .
C26 C 0.6093(3) 0.4763(2) 0.82571(18) 0.0316(7) Uani 1 1 d . . . . .
H26 H 0.571637 0.441851 0.774830 0.038 Uiso 1 1 calc R U . . .
C27 C 0.6245(2) 0.25182(17) 0.89022(14) 0.0153(5) Uani 1 1 d . . . . .
C28 C 0.5368(2) 0.26012(19) 0.92960(15) 0.0209(6) Uani 1 1 d . . . . .
H28 H 0.513606 0.310025 0.925262 0.025 Uiso 1 1 calc R U . . .
C29 C 0.4834(2) 0.19561(19) 0.97510(16) 0.0244(6) Uani 1 1 d . . . . .
H29 H 0.423452 0.201241 1.001621 0.029 Uiso 1 1 calc R U . . .
C30 C 0.5173(2) 0.12307(19) 0.98198(16) 0.0240(6) Uani 1 1 d . . . . .
H30 H 0.480726 0.079026 1.013217 0.029 Uiso 1 1 calc R U . . .
C31 C 0.6045(2) 0.11486(18) 0.94332(15) 0.0214(6) Uani 1 1 d . . . . .
H31 H 0.627633 0.065039 0.948211 0.026 Uiso 1 1 calc R U . . .
C32 C 0.6586(2) 0.17852(17) 0.89751(14) 0.0171(5) Uani 1 1 d . . . . .
H32 H 0.718522 0.172433 0.871179 0.021 Uiso 1 1 calc R U . . .
C33 C 0.5920(2) 0.27337(17) 0.73494(14) 0.0149(5) Uani 1 1 d . . . . .
H33A H 0.613237 0.317981 0.699230 0.018 Uiso 1 1 calc R U . . .
H33B H 0.515241 0.263395 0.747070 0.018 Uiso 1 1 calc R U . . .
C34 C 0.4820(2) 0.06716(17) 0.72598(14) 0.0151(5) Uani 1 1 d . . . . .
C35 C 0.5055(2) -0.00520(18) 0.74772(14) 0.0189(5) Uani 1 1 d . . . . .
H35 H 0.574874 -0.009270 0.738728 0.023 Uiso 1 1 calc R U . . .
C36 C 0.4275(2) -0.07168(19) 0.78263(15) 0.0238(6) Uani 1 1 d . . . . .
H36 H 0.443646 -0.121227 0.797298 0.029 Uiso 1 1 calc R U . . .
C37 C 0.3266(2) -0.06589(19) 0.79607(15) 0.0251(6) Uani 1 1 d . . . . .
H37 H 0.274165 -0.110737 0.820825 0.030 Uiso 1 1 calc R U . . .
C38 C 0.3016(2) 0.00514(19) 0.77354(16) 0.0241(6) Uani 1 1 d . . . . .
H38 H 0.231619 0.008249 0.781894 0.029 Uiso 1 1 calc R U . . .
C39 C 0.3795(2) 0.07182(18) 0.73865(15) 0.0211(6) Uani 1 1 d . . . . .
H39 H 0.362649 0.120740 0.723398 0.025 Uiso 1 1 calc R U . . .
C40 C 0.5259(2) 0.14073(18) 0.58600(14) 0.0162(5) Uani 1 1 d . . . . .
C41 C 0.4268(2) 0.06224(18) 0.55029(14) 0.0176(5) Uani 1 1 d . . . . .
H41 H 0.388606 0.013785 0.577557 0.021 Uiso 1 1 calc R U . . .
C42 C 0.3836(2) 0.05461(18) 0.47484(15) 0.0191(5) Uani 1 1 d . . . . .
H42 H 0.316257 0.000530 0.450892 0.023 Uiso 1 1 calc R U . . .
C43 C 0.4371(2) 0.12463(19) 0.43417(15) 0.0228(6) Uani 1 1 d . . . . .
H43 H 0.405945 0.119997 0.383278 0.027 Uiso 1 1 calc R U . . .
C44 C 0.5369(2) 0.2015(2) 0.46880(16) 0.0308(7) Uani 1 1 d . . . . .
H44 H 0.575074 0.249601 0.441199 0.037 Uiso 1 1 calc R U . . .
C45 C 0.5816(2) 0.2089(2) 0.54345(16) 0.0267(6) Uani 1 1 d . . . . .
H45 H 0.651163 0.261112 0.565937 0.032 Uiso 1 1 calc R U . . .
C46 C 0.8103(2) 0.18644(18) 0.47498(15) 0.0211(6) Uani 1 1 d . . . . .
H46 H 0.757856 0.138842 0.497564 0.025 Uiso 1 1 calc R U . . .
C47 C 0.7842(2) 0.1899(2) 0.39867(16) 0.0285(6) Uani 1 1 d . . . . .
H47 H 0.714695 0.144544 0.369449 0.034 Uiso 1 1 calc R U . . .
C48 C 0.8593(2) 0.2592(2) 0.36548(16) 0.0270(6) Uani 1 1 d . . . . .
H48 H 0.842259 0.260906 0.313107 0.032 Uiso 1 1 calc R U . . .
C49 C 0.9597(2) 0.32617(19) 0.40880(16) 0.0244(6) Uani 1 1 d . . . . .
H49 H 1.010646 0.375019 0.386530 0.029 Uiso 1 1 calc R U . . .
C50 C 0.9862(2) 0.32221(18) 0.48456(15) 0.0197(5) Uani 1 1 d . . . . .
H50 H 1.055572 0.368012 0.513657 0.024 Uiso 1 1 calc R U . . .
C51 C 0.9116(2) 0.25143(17) 0.51854(14) 0.0154(5) Uani 1 1 d . . . . .
C52 C 1.0284(2) 0.16654(17) 0.59790(14) 0.0150(5) Uani 1 1 d . . . . .
C53 C 1.1022(2) 0.1790(2) 0.54184(16) 0.0272(6) Uani 1 1 d . . . . .
H53 H 1.110247 0.225656 0.511960 0.033 Uiso 1 1 calc R U . . .
C54 C 1.1640(3) 0.1238(2) 0.52933(18) 0.0333(7) Uani 1 1 d . . . . .
H54 H 1.213077 0.131558 0.490147 0.040 Uiso 1 1 calc R U . . .
C55 C 1.1543(2) 0.0570(2) 0.57398(17) 0.0274(6) Uani 1 1 d . . . . .
H55 H 1.196446 0.018967 0.565220 0.033 Uiso 1 1 calc R U . . .
C56 C 1.0836(2) 0.04603(19) 0.63093(17) 0.0257(6) Uani 1 1 d . . . . .
H56 H 1.078815 0.001883 0.662657 0.031 Uiso 1 1 calc R U . . .
C57 C 1.0191(2) 0.09943(18) 0.64210(16) 0.0209(6) Uani 1 1 d . . . . .
H57 H 0.968428 0.089936 0.680232 0.025 Uiso 1 1 calc R U . . .
C58 C 1.0446(2) 0.35872(17) 0.66409(14) 0.0149(5) Uani 1 1 d . . . . .
H58A H 1.120480 0.366500 0.651158 0.018 Uiso 1 1 calc R U . . .
H58B H 1.025720 0.406075 0.643105 0.018 Uiso 1 1 calc R U . . .
C59 C 1.2070(3) 0.5641(2) 0.74990(17) 0.0365(8) Uani 1 1 d . . . . .
H59 H 1.195333 0.534404 0.695812 0.044 Uiso 1 1 calc R U . . .
C60 C 1.2844(3) 0.6591(2) 0.77691(18) 0.0412(9) Uani 1 1 d . . . . .
H60 H 1.325082 0.694545 0.741322 0.049 Uiso 1 1 calc R U . . .
C61 C 1.3023(2) 0.70228(19) 0.85553(16) 0.0258(6) Uani 1 1 d . . . . .
H61 H 1.356178 0.767113 0.874230 0.031 Uiso 1 1 calc R U . . .
C62 C 1.2420(2) 0.65113(19) 0.90675(16) 0.0252(6) Uani 1 1 d . . . . .
H62 H 1.253920 0.680938 0.960820 0.030 Uiso 1 1 calc R U . . .
C63 C 1.1644(2) 0.55668(18) 0.87982(15) 0.0216(6) Uani 1 1 d . . . . .
H63 H 1.122727 0.521938 0.915462 0.026 Uiso 1 1 calc R U . . .
C64 C 1.1467(2) 0.51214(17) 0.80109(14) 0.0155(5) Uani 1 1 d . . . . .
C65 C 1.2384(2) 0.35438(19) 0.80279(16) 0.0229(6) Uani 1 1 d . . . . .
H65 H 1.278591 0.412861 0.787041 0.028 Uiso 1 1 calc R U . . .
C66 C 1.2949(2) 0.3025(2) 0.82540(16) 0.0281(6) Uani 1 1 d . . . . .
H66 H 1.374052 0.326164 0.825544 0.034 Uiso 1 1 calc R U . . .
C67 C 1.2373(2) 0.2168(2) 0.84769(16) 0.0273(6) Uani 1 1 d . . . . .
H67 H 1.276713 0.181980 0.863335 0.033 Uiso 1 1 calc R U . . .
C68 C 1.1222(2) 0.18216(19) 0.84710(16) 0.0260(6) Uani 1 1 d . . . . .
H68 H 1.082196 0.122637 0.861415 0.031 Uiso 1 1 calc R U . . .
C69 C 1.0644(2) 0.23374(18) 0.82574(15) 0.0199(5) Uani 1 1 d . . . . .
H69 H 0.985453 0.210005 0.826428 0.024 Uiso 1 1 calc R U . . .
C70 C 1.1220(2) 0.32012(17) 0.80331(14) 0.0165(5) Uani 1 1 d . . . . .
O5 O 0.4222(5) 0.2206(4) 0.1790(3) 0.0598(19) Uani 0.499(6) 1 d . . P A 2
H5A H 0.365029 0.171077 0.156639 0.090 Uiso 0.499(6) 1 calc R U P A 2
O5A O 0.4744(4) 0.3014(3) 0.3288(2) 0.0429(15) Uani 0.501(6) 1 d . . P A 1
H5AA H 0.513986 0.359346 0.328394 0.064 Uiso 0.501(6) 1 calc R U P A 1
O6 O 0.2785(3) 0.0553(2) 0.09660(18) 0.0674(8) Uani 1 1 d . . . . .
H6 H 0.259095 0.028515 0.134004 0.101 Uiso 1 1 calc R U . . .
C71 C 0.4043(4) 0.2541(3) 0.2565(3) 0.0778(14) Uani 1 1 d . . . . .
H71A H 0.450941 0.253697 0.214137 0.117 Uiso 0.501(6) 1 calc R U P A 1
H71B H 0.357867 0.288516 0.247699 0.117 Uiso 0.501(6) 1 calc R U P A 1
H71C H 0.355621 0.187304 0.257927 0.117 Uiso 0.501(6) 1 calc R U P A 1
H71D H 0.338350 0.269247 0.255107 0.117 Uiso 0.499(6) 1 calc R U P A 2
H71E H 0.470463 0.312393 0.282325 0.117 Uiso 0.499(6) 1 calc R U P A 2
H71F H 0.391661 0.203608 0.285618 0.117 Uiso 0.499(6) 1 calc R U P A 2
C72 C 0.1994(4) 0.0882(3) 0.0756(3) 0.0652(12) Uani 1 1 d . . . . .
H72A H 0.209103 0.101748 0.023608 0.098 Uiso 1 1 calc R U . . .
H72B H 0.209725 0.147525 0.113582 0.098 Uiso 1 1 calc R U . . .
H72C H 0.123724 0.038500 0.074764 0.098 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 Ag2 3.0418(3) . ?
Pt1 P1 2.3046(7) . ?
Pt1 P4 2.2960(7) . ?
Pt1 C1 1.998(3) . ?
Pt1 C11 2.002(3) . ?
Ag2 Cl1 2.5526(6) . ?
Ag2 P2 2.4730(7) . ?
Ag2 P3 2.4676(7) . ?
P1 C21 1.817(2) . ?
P1 C27 1.811(2) . ?
P1 C33 1.836(2) . ?
P2 C33 1.853(2) . ?
P2 C34 1.827(2) . ?
P2 C40 1.828(2) . ?
P3 C51 1.830(2) . ?
P3 C52 1.825(2) . ?
P3 C58 1.845(2) . ?
P4 C58 1.829(2) . ?
P4 C64 1.810(2) . ?
P4 C70 1.819(3) . ?
O1 C19 1.330(3) . ?
O1 C20 1.451(3) . ?
O2 C19 1.204(4) . ?
O3 C9 1.342(3) . ?
O3 C10 1.454(3) . ?
O4 C9 1.211(3) . ?
C1 C2 1.213(4) . ?
C2 C3 1.438(4) . ?
C3 C4 1.398(4) . ?
C3 C8 1.400(4) . ?
C4 H4 0.9500 . ?
C4 C5 1.383(4) . ?
C5 H5 0.9500 . ?
C5 C6 1.394(4) . ?
C6 C7 1.393(4) . ?
C6 C9 1.484(4) . ?
C7 H7 0.9500 . ?
C7 C8 1.386(4) . ?
C8 H8 0.9500 . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C11 C12 1.214(4) . ?
C12 C13 1.440(3) . ?
C13 C14 1.403(4) . ?
C13 C18 1.401(4) . ?
C14 H14 0.9500 . ?
C14 C15 1.389(4) . ?
C15 H15 0.9500 . ?
C15 C16 1.390(4) . ?
C16 C17 1.393(4) . ?
C16 C19 1.487(4) . ?
C17 H17 0.9500 . ?
C17 C18 1.385(4) . ?
C18 H18 0.9500 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C21 C22 1.395(4) . ?
C21 C26 1.388(4) . ?
C22 H22 0.9500 . ?
C22 C23 1.379(4) . ?
C23 H23 0.9500 . ?
C23 C24 1.379(5) . ?
C24 H24 0.9500 . ?
C24 C25 1.387(5) . ?
C25 H25 0.9500 . ?
C25 C26 1.389(4) . ?
C26 H26 0.9500 . ?
C27 C28 1.394(4) . ?
C27 C32 1.399(3) . ?
C28 H28 0.9500 . ?
C28 C29 1.387(4) . ?
C29 H29 0.9500 . ?
C29 C30 1.384(4) . ?
C30 H30 0.9500 . ?
C30 C31 1.382(4) . ?
C31 H31 0.9500 . ?
C31 C32 1.385(3) . ?
C32 H32 0.9500 . ?
C33 H33A 0.9900 . ?
C33 H33B 0.9900 . ?
C34 C35 1.389(3) . ?
C34 C39 1.394(4) . ?
C35 H35 0.9500 . ?
C35 C36 1.390(3) . ?
C36 H36 0.9500 . ?
C36 C37 1.382(4) . ?
C37 H37 0.9500 . ?
C37 C38 1.386(4) . ?
C38 H38 0.9500 . ?
C38 C39 1.391(4) . ?
C39 H39 0.9500 . ?
C40 C41 1.393(3) . ?
C40 C45 1.393(4) . ?
C41 H41 0.9500 . ?
C41 C42 1.391(4) . ?
C42 H42 0.9500 . ?
C42 C43 1.384(4) . ?
C43 H43 0.9500 . ?
C43 C44 1.384(4) . ?
C44 H44 0.9500 . ?
C44 C45 1.386(4) . ?
C45 H45 0.9500 . ?
C46 H46 0.9500 . ?
C46 C47 1.392(4) . ?
C46 C51 1.387(3) . ?
C47 H47 0.9500 . ?
C47 C48 1.380(4) . ?
C48 H48 0.9500 . ?
C48 C49 1.385(4) . ?
C49 H49 0.9500 . ?
C49 C50 1.387(4) . ?
C50 H50 0.9500 . ?
C50 C51 1.398(3) . ?
C52 C53 1.390(4) . ?
C52 C57 1.388(3) . ?
C53 H53 0.9500 . ?
C53 C54 1.385(4) . ?
C54 H54 0.9500 . ?
C54 C55 1.387(4) . ?
C55 H55 0.9500 . ?
C55 C56 1.375(4) . ?
C56 H56 0.9500 . ?
C56 C57 1.389(4) . ?
C57 H57 0.9500 . ?
C58 H58A 0.9900 . ?
C58 H58B 0.9900 . ?
C59 H59 0.9500 . ?
C59 C60 1.386(4) . ?
C59 C64 1.382(4) . ?
C60 H60 0.9500 . ?
C60 C61 1.380(4) . ?
C61 H61 0.9500 . ?
C61 C62 1.376(4) . ?
C62 H62 0.9500 . ?
C62 C63 1.380(4) . ?
C63 H63 0.9500 . ?
C63 C64 1.387(3) . ?
C65 H65 0.9500 . ?
C65 C66 1.389(4) . ?
C65 C70 1.400(4) . ?
C66 H66 0.9500 . ?
C66 C67 1.382(4) . ?
C67 H67 0.9500 . ?
C67 C68 1.382(4) . ?
C68 H68 0.9500 . ?
C68 C69 1.388(4) . ?
C69 H69 0.9500 . ?
C69 C70 1.392(3) . ?
O5 H5A 0.8400 . ?
O5 C71 1.423(7) . ?
O5A H5AA 0.8400 . ?
O5A C71 1.420(6) . ?
O6 H6 0.8400 . ?
O6 C72 1.390(4) . ?
C71 H71A 0.9800 . ?
C71 H71B 0.9800 . ?
C71 H71C 0.9800 . ?
C71 H71D 0.9800 . ?
C71 H71E 0.9800 . ?
C71 H71F 0.9800 . ?
C72 H72A 0.9800 . ?
C72 H72B 0.9800 . ?
C72 H72C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Pt1 Ag2 88.025(16) . . ?
P4 Pt1 Ag2 87.872(16) . . ?
P4 Pt1 P1 174.16(2) . . ?
C1 Pt1 Ag2 104.16(7) . . ?
C1 Pt1 P1 94.06(7) . . ?
C1 Pt1 P4 90.98(7) . . ?
C1 Pt1 C11 173.10(10) . . ?
C11 Pt1 Ag2 82.71(7) . . ?
C11 Pt1 P1 85.47(7) . . ?
C11 Pt1 P4 89.89(7) . . ?
Cl1 Ag2 Pt1 109.726(19) . . ?
P2 Ag2 Pt1 91.321(16) . . ?
P2 Ag2 Cl1 107.97(2) . . ?
P3 Ag2 Pt1 87.814(16) . . ?
P3 Ag2 Cl1 115.72(2) . . ?
P3 Ag2 P2 133.78(2) . . ?
C21 P1 Pt1 111.89(8) . . ?
C21 P1 C33 105.09(12) . . ?
C27 P1 Pt1 118.70(8) . . ?
C27 P1 C21 104.55(11) . . ?
C27 P1 C33 103.21(11) . . ?
C33 P1 Pt1 112.16(8) . . ?
C33 P2 Ag2 109.69(8) . . ?
C34 P2 Ag2 120.88(8) . . ?
C34 P2 C33 103.98(11) . . ?
C34 P2 C40 104.77(11) . . ?
C40 P2 Ag2 113.81(8) . . ?
C40 P2 C33 101.64(11) . . ?
C51 P3 Ag2 118.20(8) . . ?
C51 P3 C58 101.29(11) . . ?
C52 P3 Ag2 114.12(8) . . ?
C52 P3 C51 103.12(11) . . ?
C52 P3 C58 103.87(11) . . ?
C58 P3 Ag2 114.35(8) . . ?
C58 P4 Pt1 110.75(8) . . ?
C64 P4 Pt1 112.50(8) . . ?
C64 P4 C58 104.09(11) . . ?
C64 P4 C70 104.30(11) . . ?
C70 P4 Pt1 119.57(8) . . ?
C70 P4 C58 104.22(11) . . ?
C19 O1 C20 115.3(2) . . ?
C9 O3 C10 114.2(2) . . ?
C2 C1 Pt1 177.9(2) . . ?
C1 C2 C3 170.5(3) . . ?
C4 C3 C2 122.7(2) . . ?
C4 C3 C8 118.8(2) . . ?
C8 C3 C2 118.5(2) . . ?
C3 C4 H4 119.5 . . ?
C5 C4 C3 121.0(2) . . ?
C5 C4 H4 119.5 . . ?
C4 C5 H5 120.0 . . ?
C4 C5 C6 120.0(2) . . ?
C6 C5 H5 120.0 . . ?
C5 C6 C9 123.1(2) . . ?
C7 C6 C5 119.4(2) . . ?
C7 C6 C9 117.6(2) . . ?
C6 C7 H7 119.7 . . ?
C8 C7 C6 120.7(2) . . ?
C8 C7 H7 119.7 . . ?
C3 C8 H8 119.9 . . ?
C7 C8 C3 120.2(2) . . ?
C7 C8 H8 119.9 . . ?
O3 C9 C6 112.8(2) . . ?
O4 C9 O3 122.8(2) . . ?
O4 C9 C6 124.4(2) . . ?
O3 C10 H10A 109.5 . . ?
O3 C10 H10B 109.5 . . ?
O3 C10 H10C 109.5 . . ?
H10A C10 H10B 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
C12 C11 Pt1 173.3(2) . . ?
C11 C12 C13 174.3(3) . . ?
C14 C13 C12 120.5(2) . . ?
C18 C13 C12 120.6(2) . . ?
C18 C13 C14 118.8(2) . . ?
C13 C14 H14 119.7 . . ?
C15 C14 C13 120.6(3) . . ?
C15 C14 H14 119.7 . . ?
C14 C15 H15 120.0 . . ?
C14 C15 C16 120.1(3) . . ?
C16 C15 H15 120.0 . . ?
C15 C16 C17 119.7(2) . . ?
C15 C16 C19 122.0(2) . . ?
C17 C16 C19 118.3(2) . . ?
C16 C17 H17 119.8 . . ?
C18 C17 C16 120.5(3) . . ?
C18 C17 H17 119.8 . . ?
C13 C18 H18 119.8 . . ?
C17 C18 C13 120.3(2) . . ?
C17 C18 H18 119.8 . . ?
O1 C19 C16 111.8(2) . . ?
O2 C19 O1 123.1(3) . . ?
O2 C19 C16 125.1(3) . . ?
O1 C20 H20A 109.5 . . ?
O1 C20 H20B 109.5 . . ?
O1 C20 H20C 109.5 . . ?
H20A C20 H20B 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C22 C21 P1 116.5(2) . . ?
C26 C21 P1 124.2(2) . . ?
C26 C21 C22 119.3(2) . . ?
C21 C22 H22 119.7 . . ?
C23 C22 C21 120.6(3) . . ?
C23 C22 H22 119.7 . . ?
C22 C23 H23 120.1 . . ?
C24 C23 C22 119.8(3) . . ?
C24 C23 H23 120.1 . . ?
C23 C24 H24 119.8 . . ?
C23 C24 C25 120.5(3) . . ?
C25 C24 H24 119.8 . . ?
C24 C25 H25 120.2 . . ?
C24 C25 C26 119.7(3) . . ?
C26 C25 H25 120.2 . . ?
C21 C26 C25 120.2(3) . . ?
C21 C26 H26 119.9 . . ?
C25 C26 H26 119.9 . . ?
C28 C27 P1 120.73(19) . . ?
C28 C27 C32 119.5(2) . . ?
C32 C27 P1 119.73(19) . . ?
C27 C28 H28 119.9 . . ?
C29 C28 C27 120.1(2) . . ?
C29 C28 H28 119.9 . . ?
C28 C29 H29 119.9 . . ?
C30 C29 C28 120.2(3) . . ?
C30 C29 H29 119.9 . . ?
C29 C30 H30 120.1 . . ?
C31 C30 C29 119.9(2) . . ?
C31 C30 H30 120.1 . . ?
C30 C31 H31 119.7 . . ?
C30 C31 C32 120.7(2) . . ?
C32 C31 H31 119.7 . . ?
C27 C32 H32 120.2 . . ?
C31 C32 C27 119.7(2) . . ?
C31 C32 H32 120.2 . . ?
P1 C33 P2 113.69(12) . . ?
P1 C33 H33A 108.8 . . ?
P1 C33 H33B 108.8 . . ?
P2 C33 H33A 108.8 . . ?
P2 C33 H33B 108.8 . . ?
H33A C33 H33B 107.7 . . ?
C35 C34 P2 118.14(19) . . ?
C35 C34 C39 119.5(2) . . ?
C39 C34 P2 122.33(19) . . ?
C34 C35 H35 120.0 . . ?
C34 C35 C36 120.1(2) . . ?
C36 C35 H35 120.0 . . ?
C35 C36 H36 119.9 . . ?
C37 C36 C35 120.2(3) . . ?
C37 C36 H36 119.9 . . ?
C36 C37 H37 119.9 . . ?
C36 C37 C38 120.2(2) . . ?
C38 C37 H37 119.9 . . ?
C37 C38 H38 120.1 . . ?
C37 C38 C39 119.7(3) . . ?
C39 C38 H38 120.1 . . ?
C34 C39 H39 119.9 . . ?
C38 C39 C34 120.3(2) . . ?
C38 C39 H39 119.9 . . ?
C41 C40 P2 123.24(19) . . ?
C41 C40 C45 118.4(2) . . ?
C45 C40 P2 118.30(19) . . ?
C40 C41 H41 119.9 . . ?
C42 C41 C40 120.2(2) . . ?
C42 C41 H41 119.9 . . ?
C41 C42 H42 119.5 . . ?
C43 C42 C41 121.0(2) . . ?
C43 C42 H42 119.5 . . ?
C42 C43 H43 120.5 . . ?
C42 C43 C44 119.0(2) . . ?
C44 C43 H43 120.5 . . ?
C43 C44 H44 119.8 . . ?
C43 C44 C45 120.5(3) . . ?
C45 C44 H44 119.8 . . ?
C40 C45 H45 119.5 . . ?
C44 C45 C40 120.9(2) . . ?
C44 C45 H45 119.5 . . ?
C47 C46 H46 119.5 . . ?
C51 C46 H46 119.5 . . ?
C51 C46 C47 121.0(2) . . ?
C46 C47 H47 120.0 . . ?
C48 C47 C46 120.0(3) . . ?
C48 C47 H47 120.0 . . ?
C47 C48 H48 120.1 . . ?
C47 C48 C49 119.8(2) . . ?
C49 C48 H48 120.1 . . ?
C48 C49 H49 119.9 . . ?
C48 C49 C50 120.2(2) . . ?
C50 C49 H49 119.9 . . ?
C49 C50 H50 119.7 . . ?
C49 C50 C51 120.6(2) . . ?
C51 C50 H50 119.7 . . ?
C46 C51 P3 117.70(18) . . ?
C46 C51 C50 118.3(2) . . ?
C50 C51 P3 123.88(19) . . ?
C53 C52 P3 122.27(19) . . ?
C57 C52 P3 118.58(19) . . ?
C57 C52 C53 119.2(2) . . ?
C52 C53 H53 119.8 . . ?
C54 C53 C52 120.3(3) . . ?
C54 C53 H53 119.8 . . ?
C53 C54 H54 120.0 . . ?
C53 C54 C55 120.0(3) . . ?
C55 C54 H54 120.0 . . ?
C54 C55 H55 120.0 . . ?
C56 C55 C54 120.0(3) . . ?
C56 C55 H55 120.0 . . ?
C55 C56 H56 120.0 . . ?
C55 C56 C57 120.0(2) . . ?
C57 C56 H56 120.0 . . ?
C52 C57 C56 120.4(2) . . ?
C52 C57 H57 119.8 . . ?
C56 C57 H57 119.8 . . ?
P3 C58 H58A 108.8 . . ?
P3 C58 H58B 108.8 . . ?
P4 C58 P3 113.65(12) . . ?
P4 C58 H58A 108.8 . . ?
P4 C58 H58B 108.8 . . ?
H58A C58 H58B 107.7 . . ?
C60 C59 H59 119.8 . . ?
C64 C59 H59 119.8 . . ?
C64 C59 C60 120.5(3) . . ?
C59 C60 H60 120.0 . . ?
C61 C60 C59 120.0(3) . . ?
C61 C60 H60 120.0 . . ?
C60 C61 H61 120.1 . . ?
C62 C61 C60 119.8(2) . . ?
C62 C61 H61 120.1 . . ?
C61 C62 H62 119.9 . . ?
C61 C62 C63 120.2(2) . . ?
C63 C62 H62 119.9 . . ?
C62 C63 H63 119.8 . . ?
C62 C63 C64 120.5(2) . . ?
C64 C63 H63 119.8 . . ?
C59 C64 P4 122.74(19) . . ?
C59 C64 C63 119.0(2) . . ?
C63 C64 P4 118.20(18) . . ?
C66 C65 H65 120.2 . . ?
C66 C65 C70 119.7(3) . . ?
C70 C65 H65 120.2 . . ?
C65 C66 H66 119.6 . . ?
C67 C66 C65 120.7(3) . . ?
C67 C66 H66 119.6 . . ?
C66 C67 H67 120.2 . . ?
C66 C67 C68 119.6(3) . . ?
C68 C67 H67 120.2 . . ?
C67 C68 H68 119.8 . . ?
C67 C68 C69 120.4(3) . . ?
C69 C68 H68 119.8 . . ?
C68 C69 H69 119.9 . . ?
C68 C69 C70 120.2(3) . . ?
C70 C69 H69 119.9 . . ?
C65 C70 P4 119.29(19) . . ?
C69 C70 P4 121.37(19) . . ?
C69 C70 C65 119.3(2) . . ?
C71 O5 H5A 109.5 . . ?
C71 O5A H5AA 109.5 . . ?
C72 O6 H6 109.5 . . ?
O5 C71 H71D 109.5 . . ?
O5 C71 H71E 109.5 . . ?
O5 C71 H71F 109.5 . . ?
O5A C71 H71A 109.5 . . ?
O5A C71 H71B 109.5 . . ?
O5A C71 H71C 109.5 . . ?
H71A C71 H71B 109.5 . . ?
H71A C71 H71C 109.5 . . ?
H71B C71 H71C 109.5 . . ?
H71D C71 H71E 109.5 . . ?
H71D C71 H71F 109.5 . . ?
H71E C71 H71F 109.5 . . ?
O6 C72 H72A 109.5 . . ?
O6 C72 H72B 109.5 . . ?
O6 C72 H72C 109.5 . . ?
H72A C72 H72B 109.5 . . ?
H72A C72 H72C 109.5 . . ?
H72B C72 H72C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Pt1 P1 C21 C22 -64.4(2) . . . . ?
Pt1 P1 C21 C26 113.8(2) . . . . ?
Pt1 P1 C27 C28 154.06(17) . . . . ?
Pt1 P1 C27 C32 -29.3(2) . . . . ?
Pt1 P1 C33 P2 60.03(14) . . . . ?
Pt1 P4 C58 P3 -55.22(14) . . . . ?
Pt1 P4 C64 C59 -124.8(2) . . . . ?
Pt1 P4 C64 C63 57.3(2) . . . . ?
Pt1 P4 C70 C65 -161.32(17) . . . . ?
Pt1 P4 C70 C69 21.6(2) . . . . ?
Ag2 P2 C33 P1 -41.22(14) . . . . ?
Ag2 P2 C34 C35 -11.4(2) . . . . ?
Ag2 P2 C34 C39 166.70(18) . . . . ?
Ag2 P2 C40 C41 121.2(2) . . . . ?
Ag2 P2 C40 C45 -55.7(2) . . . . ?
Ag2 P3 C51 C46 -30.8(2) . . . . ?
Ag2 P3 C51 C50 152.31(19) . . . . ?
Ag2 P3 C52 C53 163.17(19) . . . . ?
Ag2 P3 C52 C57 -16.7(2) . . . . ?
Ag2 P3 C58 P4 25.65(16) . . . . ?
P1 C21 C22 C23 179.3(2) . . . . ?
P1 C21 C26 C25 -179.7(3) . . . . ?
P1 C27 C28 C29 176.1(2) . . . . ?
P1 C27 C32 C31 -176.28(19) . . . . ?
P2 C34 C35 C36 177.40(19) . . . . ?
P2 C34 C39 C38 -177.37(19) . . . . ?
P2 C40 C41 C42 -178.89(19) . . . . ?
P2 C40 C45 C44 -179.9(2) . . . . ?
P3 C52 C53 C54 -178.7(2) . . . . ?
P3 C52 C57 C56 -179.5(2) . . . . ?
C2 C3 C4 C5 -178.9(3) . . . . ?
C2 C3 C8 C7 -179.8(3) . . . . ?
C3 C4 C5 C6 -1.4(4) . . . . ?
C4 C3 C8 C7 -0.4(4) . . . . ?
C4 C5 C6 C7 -0.2(4) . . . . ?
C4 C5 C6 C9 179.8(3) . . . . ?
C5 C6 C7 C8 1.5(4) . . . . ?
C5 C6 C9 O3 -15.0(4) . . . . ?
C5 C6 C9 O4 166.0(3) . . . . ?
C6 C7 C8 C3 -1.2(4) . . . . ?
C7 C6 C9 O3 165.0(2) . . . . ?
C7 C6 C9 O4 -14.0(4) . . . . ?
C8 C3 C4 C5 1.7(4) . . . . ?
C9 C6 C7 C8 -178.5(3) . . . . ?
C10 O3 C9 O4 -0.8(4) . . . . ?
C10 O3 C9 C6 -179.9(2) . . . . ?
C12 C13 C14 C15 -178.0(2) . . . . ?
C12 C13 C18 C17 176.5(2) . . . . ?
C13 C14 C15 C16 1.2(4) . . . . ?
C14 C13 C18 C17 -0.3(4) . . . . ?
C14 C15 C16 C17 0.4(4) . . . . ?
C14 C15 C16 C19 -178.2(2) . . . . ?
C15 C16 C17 C18 -2.0(4) . . . . ?
C15 C16 C19 O1 16.9(4) . . . . ?
C15 C16 C19 O2 -164.7(3) . . . . ?
C16 C17 C18 C13 1.9(4) . . . . ?
C17 C16 C19 O1 -161.7(2) . . . . ?
C17 C16 C19 O2 16.6(4) . . . . ?
C18 C13 C14 C15 -1.3(4) . . . . ?
C19 C16 C17 C18 176.7(2) . . . . ?
C20 O1 C19 O2 -0.1(4) . . . . ?
C20 O1 C19 C16 178.3(2) . . . . ?
C21 P1 C27 C28 28.5(2) . . . . ?
C21 P1 C27 C32 -154.9(2) . . . . ?
C21 P1 C33 P2 -178.18(12) . . . . ?
C21 C22 C23 C24 0.1(5) . . . . ?
C22 C21 C26 C25 -1.5(4) . . . . ?
C22 C23 C24 C25 -0.6(5) . . . . ?
C23 C24 C25 C26 0.1(6) . . . . ?
C24 C25 C26 C21 1.0(5) . . . . ?
C26 C21 C22 C23 1.0(4) . . . . ?
C27 P1 C21 C22 65.3(2) . . . . ?
C27 P1 C21 C26 -116.4(2) . . . . ?
C27 P1 C33 P2 -68.88(15) . . . . ?
C27 C28 C29 C30 0.4(4) . . . . ?
C28 C27 C32 C31 0.4(4) . . . . ?
C28 C29 C30 C31 -0.1(4) . . . . ?
C29 C30 C31 C32 -0.1(4) . . . . ?
C30 C31 C32 C27 -0.1(4) . . . . ?
C32 C27 C28 C29 -0.5(4) . . . . ?
C33 P1 C21 C22 173.7(2) . . . . ?
C33 P1 C21 C26 -8.1(3) . . . . ?
C33 P1 C27 C28 -81.2(2) . . . . ?
C33 P1 C27 C32 95.4(2) . . . . ?
C33 P2 C34 C35 -134.96(19) . . . . ?
C33 P2 C34 C39 43.1(2) . . . . ?
C33 P2 C40 C41 -121.0(2) . . . . ?
C33 P2 C40 C45 62.1(2) . . . . ?
C34 P2 C33 P1 89.39(14) . . . . ?
C34 P2 C40 C41 -13.0(2) . . . . ?
C34 P2 C40 C45 170.1(2) . . . . ?
C34 C35 C36 C37 -0.2(4) . . . . ?
C35 C34 C39 C38 0.7(4) . . . . ?
C35 C36 C37 C38 1.2(4) . . . . ?
C36 C37 C38 C39 -1.2(4) . . . . ?
C37 C38 C39 C34 0.3(4) . . . . ?
C39 C34 C35 C36 -0.7(4) . . . . ?
C40 P2 C33 P1 -161.98(13) . . . . ?
C40 P2 C34 C35 118.7(2) . . . . ?
C40 P2 C34 C39 -63.2(2) . . . . ?
C40 C41 C42 C43 -0.5(4) . . . . ?
C41 C40 C45 C44 3.1(4) . . . . ?
C41 C42 C43 C44 1.9(4) . . . . ?
C42 C43 C44 C45 -0.9(4) . . . . ?
C43 C44 C45 C40 -1.7(5) . . . . ?
C45 C40 C41 C42 -2.0(4) . . . . ?
C46 C47 C48 C49 -1.1(5) . . . . ?
C47 C46 C51 P3 -175.5(2) . . . . ?
C47 C46 C51 C50 1.5(4) . . . . ?
C47 C48 C49 C50 1.7(4) . . . . ?
C48 C49 C50 C51 -0.7(4) . . . . ?
C49 C50 C51 P3 175.9(2) . . . . ?
C49 C50 C51 C46 -0.9(4) . . . . ?
C51 P3 C52 C53 33.7(2) . . . . ?
C51 P3 C52 C57 -146.2(2) . . . . ?
C51 P3 C58 P4 153.92(13) . . . . ?
C51 C46 C47 C48 -0.5(4) . . . . ?
C52 P3 C51 C46 96.1(2) . . . . ?
C52 P3 C51 C50 -80.7(2) . . . . ?
C52 P3 C58 P4 -99.36(14) . . . . ?
C52 C53 C54 C55 -1.4(5) . . . . ?
C53 C52 C57 C56 0.6(4) . . . . ?
C53 C54 C55 C56 -0.3(5) . . . . ?
C54 C55 C56 C57 2.1(4) . . . . ?
C55 C56 C57 C52 -2.2(4) . . . . ?
C57 C52 C53 C54 1.2(4) . . . . ?
C58 P3 C51 C46 -156.6(2) . . . . ?
C58 P3 C51 C50 26.6(2) . . . . ?
C58 P3 C52 C53 -71.7(2) . . . . ?
C58 P3 C52 C57 108.4(2) . . . . ?
C58 P4 C64 C59 -4.8(3) . . . . ?
C58 P4 C64 C63 177.2(2) . . . . ?
C58 P4 C70 C65 74.3(2) . . . . ?
C58 P4 C70 C69 -102.7(2) . . . . ?
C59 C60 C61 C62 -0.9(5) . . . . ?
C60 C59 C64 P4 -177.7(3) . . . . ?
C60 C59 C64 C63 0.3(5) . . . . ?
C60 C61 C62 C63 0.5(5) . . . . ?
C61 C62 C63 C64 0.4(4) . . . . ?
C62 C63 C64 P4 177.3(2) . . . . ?
C62 C63 C64 C59 -0.8(4) . . . . ?
C64 P4 C58 P3 -176.35(13) . . . . ?
C64 P4 C70 C65 -34.5(2) . . . . ?
C64 P4 C70 C69 148.4(2) . . . . ?
C64 C59 C60 C61 0.5(6) . . . . ?
C65 C66 C67 C68 0.3(4) . . . . ?
C66 C65 C70 P4 -177.9(2) . . . . ?
C66 C65 C70 C69 -0.7(4) . . . . ?
C66 C67 C68 C69 -1.2(4) . . . . ?
C67 C68 C69 C70 1.2(4) . . . . ?
C68 C69 C70 P4 176.9(2) . . . . ?
C68 C69 C70 C65 -0.2(4) . . . . ?
C70 P4 C58 P3 74.60(15) . . . . ?
C70 P4 C64 C59 104.2(3) . . . . ?
C70 P4 C64 C63 -73.8(2) . . . . ?
C70 C65 C66 C67 0.6(4) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
