# Electronic Supplementary Material (ESI) for Nanoscale.
# This journal is © The Royal Society of Chemistry 2023

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_Au6_SbP3_2_PF6_2
_database_code_depnum_ccdc_archive 'CCDC 2176488'
loop_
_audit_author_name
_audit_author_address
'Maxime Siegler'
;Johns Hopkins University
United States of America
;
_audit_update_record             
;
2022-06-02 deposited with the CCDC.	2023-03-27 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C108 H84 Au6 P6 Sb2, 2(F6 P), 1.831(C H2 Cl2)'
_chemical_formula_sum            'C109.83 H87.66 Au6 Cl3.66 F12 P8 Sb2'
_chemical_formula_weight         3438.16

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   14.2806(3)
_cell_length_b                   18.2744(6)
_cell_length_c                   22.8464(6)
_cell_angle_alpha                80.353(3)
_cell_angle_beta                 75.399(2)
_cell_angle_gamma                80.671(2)
_cell_volume                     5643.0(3)
_cell_formula_units_Z            2
_cell_measurement_temperature    110(2)
_cell_measurement_reflns_used    17945
_cell_measurement_theta_min      1.9210
_cell_measurement_theta_max      25.2110

_exptl_crystal_description       plate
_exptl_crystal_colour            orange
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    2.023
_exptl_crystal_F_000             3226
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.210
_exptl_crystal_size_mid          0.120
_exptl_crystal_size_min          0.026
_exptl_absorpt_coefficient_mu    8.504
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   analytical
_exptl_absorpt_correction_T_min  0.281
_exptl_absorpt_correction_T_max  0.805
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.41.93a (Rigaku Oxford Diffraction, 2020)
Analytical numeric absorption correction using a multifaceted crystal
model based on expressions derived by R.C. Clark & J.S. Reid.
(Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_oxdiff_exptl_absorpt_empirical_full_min 0.449
_oxdiff_exptl_absorpt_empirical_full_max 3.364
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
- Detector area scaling
- B-factor correction
;

_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      110(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'SuperNova (Mo) X-ray Source'
_diffrn_radiation_monochromator  mirror
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_standards_number         .
_diffrn_standards_interval_time  .
_diffrn_reflns_number            74920
_diffrn_reflns_av_unetI/netI     0.0464
_diffrn_reflns_av_R_equivalents  0.0482
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_theta_min         1.739
_diffrn_reflns_theta_max         25.000
_diffrn_reflns_theta_full        25.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             19846
_reflns_number_gt                15987
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'CrysAlisPro 1.171.39.29c (Rigaku OD, 2017)'
_computing_cell_refinement       'CrysAlisPro 1.171.39.29c (Rigaku OD, 2017)'
_computing_data_reduction        'CrysAlisPro 1.171.39.29c (Rigaku OD, 2017)'
_computing_structure_solution    'SHELXS-2018/3 (Sheldrick, 2018)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    'SHELXTL v6.10 (Sheldrick, 2008)'
_computing_publication_material  'SHELXTL v6.10 (Sheldrick, 2008)'
_refine_special_details          SQUEEZE
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0513P)²+24.8589P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         19846
_refine_ls_number_parameters     1721
_refine_ls_number_restraints     1689
_refine_ls_R_factor_all          0.0536
_refine_ls_R_factor_gt           0.0379
_refine_ls_wR_factor_ref         0.1000
_refine_ls_wR_factor_gt          0.0912
_refine_ls_goodness_of_fit_ref   1.021
_refine_ls_restrained_S_all      0.994
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au -0.03283(2) -0.11429(2) 0.47086(2) 0.02312(8) Uani 1 1 d . . . . .
Au2 Au 0.07397(2) 0.00532(2) 0.45098(2) 0.01857(8) Uani 1 1 d . . . . .
Au3 Au 0.09398(2) -0.11214(2) 0.54122(2) 0.02174(8) Uani 1 1 d . . . . .
Sb1 Sb 0.23345(3) 0.00529(3) 0.51546(2) 0.01984(12) Uani 1 1 d . . . . .
P1 P -0.12867(15) -0.17521(13) 0.43302(9) 0.0246(5) Uani 1 1 d . . . . .
C1 C -0.1610(6) -0.1340(5) 0.3615(4) 0.030(2) Uani 1 1 d . . . . .
C2 C -0.1227(6) -0.0698(6) 0.3292(4) 0.040(2) Uani 1 1 d . . . . .
H2 H -0.075146 -0.050476 0.342787 0.048 Uiso 1 1 calc R U . . .
C3 C -0.1531(7) -0.0334(7) 0.2774(4) 0.050(3) Uani 1 1 d . . . . .
H3 H -0.127118 0.010665 0.255771 0.060 Uiso 1 1 calc R U . . .
C4 C -0.2222(7) -0.0626(7) 0.2578(4) 0.049(3) Uani 1 1 d . . . . .
H4 H -0.243148 -0.038415 0.222332 0.059 Uiso 1 1 calc R U . . .
C5 C -0.2604(6) -0.1261(6) 0.2891(4) 0.042(3) Uani 1 1 d . . . . .
H5 H -0.307491 -0.145560 0.275223 0.051 Uiso 1 1 calc R U . . .
C6 C -0.2307(6) -0.1614(5) 0.3406(4) 0.034(2) Uani 1 1 d . . . . .
H6 H -0.257807 -0.205060 0.362221 0.041 Uiso 1 1 calc R U . . .
C7 C -0.2500(6) -0.1765(5) 0.4839(4) 0.0255(18) Uani 1 1 d . . . . .
C8 C -0.3001(5) -0.1099(5) 0.5033(3) 0.0238(18) Uani 1 1 d . . . . .
C9 C -0.3959(6) -0.1092(5) 0.5382(4) 0.030(2) Uani 1 1 d . . . . .
H9 H -0.431535 -0.063991 0.551317 0.036 Uiso 1 1 calc R U . . .
C10 C -0.4387(6) -0.1747(5) 0.5536(4) 0.035(2) Uani 1 1 d . . . . .
H10 H -0.503904 -0.174063 0.577013 0.043 Uiso 1 1 calc R U . . .
C11 C -0.3880(7) -0.2403(5) 0.5353(4) 0.035(2) Uani 1 1 d . . . . .
H11 H -0.417523 -0.285132 0.546925 0.042 Uiso 1 1 calc R U . . .
C12 C -0.2937(6) -0.2414(5) 0.5000(4) 0.034(2) Uani 1 1 d . . . . .
H12 H -0.258921 -0.286882 0.486814 0.041 Uiso 1 1 calc R U . . .
C13 C -0.0727(6) -0.2701(5) 0.4235(4) 0.036(2) Uani 1 1 d . . . . .
C14 C -0.0547(8) -0.3179(6) 0.4746(5) 0.050(3) Uani 1 1 d . . . . .
H14 H -0.082306 -0.304013 0.514219 0.060 Uiso 1 1 calc R U . . .
C15 C 0.0029(9) -0.3852(6) 0.4681(6) 0.060(3) Uani 1 1 d . . . . .
H15 H 0.015051 -0.417559 0.503217 0.072 Uiso 1 1 calc R U . . .
C16 C 0.0429(9) -0.4060(7) 0.4116(7) 0.072(4) Uani 1 1 d . . . . .
H16 H 0.081048 -0.453368 0.407609 0.087 Uiso 1 1 calc R U . . .
C17 C 0.0275(9) -0.3571(8) 0.3590(6) 0.076(4) Uani 1 1 d . . . . .
H17 H 0.057464 -0.370007 0.319351 0.091 Uiso 1 1 calc R U . . .
C18 C -0.0317(8) -0.2903(7) 0.3664(5) 0.057(3) Uani 1 1 d . . . . .
H18 H -0.044380 -0.257717 0.331534 0.068 Uiso 1 1 calc R U . . .
P2 P 0.20092(14) 0.01902(12) 0.36675(9) 0.0218(4) Uani 1 1 d D . . . .
C19 C 0.1894(5) -0.0062(5) 0.2954(3) 0.0255(18) Uani 1 1 d . . . . .
C20 C 0.2374(7) 0.0258(6) 0.2390(4) 0.038(2) Uani 1 1 d . . . . .
H20 H 0.276102 0.064421 0.236304 0.046 Uiso 1 1 calc R U . . .
C21 C 0.2293(8) 0.0021(7) 0.1867(4) 0.051(3) Uani 1 1 d . . . . .
H21 H 0.263061 0.024284 0.148168 0.062 Uiso 1 1 calc R U . . .
C22 C 0.1732(7) -0.0530(6) 0.1895(4) 0.043(2) Uani 1 1 d . . . . .
H22 H 0.167420 -0.068601 0.153044 0.051 Uiso 1 1 calc R U . . .
C23 C 0.1249(7) -0.0861(6) 0.2460(4) 0.049(3) Uani 1 1 d . . . . .
H23 H 0.086190 -0.124725 0.248771 0.059 Uiso 1 1 calc R U . . .
C24 C 0.1342(7) -0.0617(6) 0.2982(4) 0.042(2) Uani 1 1 d . . . . .
H24 H 0.101245 -0.084083 0.336893 0.051 Uiso 1 1 calc R U . . .
C25 C 0.2288(12) 0.1149(6) 0.3499(5) 0.028(2) Uani 0.64(2) 1 d D U P A 1
C26 C 0.3232(11) 0.1358(8) 0.3365(5) 0.031(3) Uani 0.64(2) 1 d D U P A 1
H26 H 0.378024 0.098197 0.332763 0.037 Uiso 0.64(2) 1 calc R U P A 1
C27 C 0.3373(11) 0.2090(8) 0.3288(6) 0.034(3) Uani 0.64(2) 1 d D U P A 1
H27 H 0.401527 0.222229 0.319712 0.040 Uiso 0.64(2) 1 calc R U P A 1
C28 C 0.2579(13) 0.2642(8) 0.3341(5) 0.033(3) Uani 0.64(2) 1 d D U P A 1
H28 H 0.267862 0.315264 0.328824 0.040 Uiso 0.64(2) 1 calc R U P A 1
C29 C 0.1658(12) 0.2456(8) 0.3469(5) 0.032(3) Uani 0.64(2) 1 d D U P A 1
H29 H 0.111537 0.283581 0.350473 0.038 Uiso 0.64(2) 1 calc R U P A 1
C30 C 0.1512(10) 0.1705(8) 0.3549(6) 0.026(2) Uani 0.64(2) 1 d D U P A 1
H30 H 0.086686 0.157683 0.363979 0.031 Uiso 0.64(2) 1 calc R U P A 1
C25' C 0.2360(19) 0.1128(8) 0.3478(9) 0.029(3) Uani 0.36(2) 1 d D U P A 2
C26' C 0.3331(18) 0.1230(13) 0.3187(8) 0.031(3) Uani 0.36(2) 1 d D U P A 2
H26' H 0.379056 0.081630 0.306078 0.037 Uiso 0.36(2) 1 calc R U P A 2
C27' C 0.3606(17) 0.1928(14) 0.3086(9) 0.032(3) Uani 0.36(2) 1 d D U P A 2
H27' H 0.426215 0.199484 0.288931 0.038 Uiso 0.36(2) 1 calc R U P A 2
C28' C 0.296(2) 0.2537(14) 0.3263(10) 0.033(3) Uani 0.36(2) 1 d D U P A 2
H28' H 0.316584 0.301949 0.318865 0.040 Uiso 0.36(2) 1 calc R U P A 2
C29' C 0.202(2) 0.2447(13) 0.3543(10) 0.033(3) Uani 0.36(2) 1 d D U P A 2
H29' H 0.157250 0.286609 0.366615 0.040 Uiso 0.36(2) 1 calc R U P A 2
C30' C 0.1719(19) 0.1736(13) 0.3653(11) 0.030(3) Uani 0.36(2) 1 d D U P A 2
H30' H 0.106116 0.167556 0.384993 0.036 Uiso 0.36(2) 1 calc R U P A 2
C31 C 0.3111(5) -0.0392(5) 0.3834(3) 0.0230(18) Uani 1 1 d . . . . .
C32 C 0.3764(6) -0.0766(5) 0.3375(4) 0.031(2) Uani 1 1 d . . . . .
H32 H 0.364566 -0.069840 0.297767 0.038 Uiso 1 1 calc R U . . .
C33 C 0.4576(6) -0.1230(6) 0.3496(4) 0.038(2) Uani 1 1 d . . . . .
H33 H 0.501686 -0.147363 0.318059 0.046 Uiso 1 1 calc R U . . .
C34 C 0.4752(6) -0.1340(5) 0.4074(4) 0.036(2) Uani 1 1 d . . . . .
H34 H 0.529710 -0.167355 0.416258 0.044 Uiso 1 1 calc R U . . .
C35 C 0.4117(5) -0.0956(5) 0.4525(4) 0.0272(19) Uani 1 1 d . . . . .
H35 H 0.424843 -0.102217 0.491927 0.033 Uiso 1 1 calc R U . . .
C36 C 0.3302(5) -0.0482(5) 0.4417(4) 0.0230(18) Uani 1 1 d . . . . .
P3 P 0.18854(14) -0.17271(12) 0.60673(9) 0.0218(4) Uani 1 1 d . . . . .
C37 C 0.3013(5) -0.0517(5) 0.5879(3) 0.0233(18) Uani 1 1 d . . . . .
C38 C 0.3665(5) -0.0143(5) 0.6055(4) 0.0260(18) Uani 1 1 d . . . . .
H38 H 0.385423 0.031213 0.582074 0.031 Uiso 1 1 calc R U . . .
C39 C 0.4038(6) -0.0430(5) 0.6568(4) 0.032(2) Uani 1 1 d . . . . .
H39 H 0.447991 -0.017181 0.667952 0.039 Uiso 1 1 calc R U . . .
C40 C 0.3764(6) -0.1084(5) 0.6911(4) 0.031(2) Uani 1 1 d . . . . .
H40 H 0.401421 -0.127922 0.726154 0.038 Uiso 1 1 calc R U . . .
C41 C 0.3124(6) -0.1460(5) 0.6748(4) 0.030(2) Uani 1 1 d . . . . .
H41 H 0.293188 -0.190898 0.699220 0.036 Uiso 1 1 calc R U . . .
C42 C 0.2755(5) -0.1194(4) 0.6235(3) 0.0213(17) Uani 1 1 d . . . . .
C43 C 0.2557(6) -0.2592(5) 0.5806(3) 0.0249(18) Uani 1 1 d . . . . .
C44 C 0.2153(7) -0.2940(5) 0.5451(4) 0.041(2) Uani 1 1 d . . . . .
H44 H 0.155324 -0.272349 0.534969 0.049 Uiso 1 1 calc R U . . .
C45 C 0.2625(8) -0.3599(6) 0.5245(5) 0.049(3) Uani 1 1 d . . . . .
H45 H 0.234437 -0.383469 0.500182 0.059 Uiso 1 1 calc R U . . .
C46 C 0.3481(7) -0.3920(6) 0.5382(5) 0.047(3) Uani 1 1 d . . . . .
H46 H 0.380693 -0.436719 0.522581 0.057 Uiso 1 1 calc R U . . .
C47 C 0.3872(7) -0.3593(6) 0.5748(5) 0.048(3) Uani 1 1 d . . . . .
H47 H 0.446245 -0.382387 0.585562 0.058 Uiso 1 1 calc R U . . .
C48 C 0.3421(6) -0.2940(5) 0.5960(5) 0.040(2) Uani 1 1 d . . . . .
H48 H 0.369840 -0.272000 0.621409 0.048 Uiso 1 1 calc R U . . .
C49 C 0.1118(6) -0.1958(5) 0.6825(4) 0.030(2) Uani 1 1 d . . . . .
C50 C 0.0466(7) -0.1387(6) 0.7075(4) 0.040(2) Uani 1 1 d . . . . .
H50 H 0.040659 -0.090763 0.684113 0.048 Uiso 1 1 calc R U . . .
C51 C -0.0102(7) -0.1500(7) 0.7660(4) 0.053(3) Uani 1 1 d . . . . .
H51 H -0.055292 -0.110368 0.782823 0.063 Uiso 1 1 calc R U . . .
C52 C -0.0006(7) -0.2203(8) 0.8001(5) 0.058(3) Uani 1 1 d . . . . .
H52 H -0.037702 -0.228763 0.840876 0.069 Uiso 1 1 calc R U . . .
C53 C 0.0618(8) -0.2766(7) 0.7749(5) 0.062(4) Uani 1 1 d . . . . .
H53 H 0.066428 -0.324760 0.798095 0.074 Uiso 1 1 calc R U . . .
C54 C 0.1198(7) -0.2660(6) 0.7158(4) 0.046(3) Uani 1 1 d . . . . .
H54 H 0.163620 -0.306069 0.698863 0.055 Uiso 1 1 calc R U . . .
Au4 Au 0.09516(2) 0.59775(2) -0.06116(2) 0.02758(9) Uani 1 1 d . . . . .
Au5 Au -0.02211(2) 0.52863(2) -0.10419(2) 0.02891(9) Uani 1 1 d . . . . .
Au6 Au -0.07664(2) 0.55073(2) 0.01648(2) 0.02365(8) Uani 1 1 d . . . . .
Sb2 Sb -0.23383(4) 0.48394(3) -0.01337(2) 0.02637(13) Uani 1 1 d . . . . .
P4 P 0.20255(15) 0.68488(13) -0.08388(9) 0.0282(5) Uani 1 1 d D . . . .
C55 C 0.2908(9) 0.6748(8) -0.1553(4) 0.0345(19) Uani 0.64(3) 1 d D U P B 1
C56 C 0.3704(9) 0.7161(7) -0.1712(6) 0.037(3) Uani 0.64(3) 1 d D U P B 1
H56 H 0.376414 0.751360 -0.146561 0.044 Uiso 0.64(3) 1 calc R U P B 1
C57 C 0.4396(9) 0.7036(9) -0.2241(6) 0.041(3) Uani 0.64(3) 1 d D U P B 1
H57 H 0.494201 0.730781 -0.235866 0.049 Uiso 0.64(3) 1 calc R U P B 1
C58 C 0.4315(10) 0.6518(10) -0.2607(6) 0.038(3) Uani 0.64(3) 1 d D U P B 1
H58 H 0.480052 0.644050 -0.296928 0.045 Uiso 0.64(3) 1 calc R U P B 1
C59 C 0.3543(11) 0.6130(9) -0.2442(6) 0.039(3) Uani 0.64(3) 1 d D U P B 1
H59 H 0.347980 0.577723 -0.268679 0.047 Uiso 0.64(3) 1 calc R U P B 1
C60 C 0.2840(10) 0.6250(8) -0.1912(6) 0.038(3) Uani 0.64(3) 1 d D U P B 1
H60 H 0.229720 0.597481 -0.179786 0.046 Uiso 0.64(3) 1 calc R U P B 1
C55' C 0.2858(14) 0.6695(13) -0.1564(5) 0.0345(19) Uani 0.36(3) 1 d D U P B 2
C56' C 0.3726(17) 0.7015(13) -0.1843(10) 0.039(3) Uani 0.36(3) 1 d D U P B 2
H56' H 0.389839 0.738209 -0.165370 0.047 Uiso 0.36(3) 1 calc R U P B 2
C57' C 0.4330(14) 0.6814(14) -0.2378(11) 0.039(3) Uani 0.36(3) 1 d D U P B 2
H57' H 0.490628 0.704431 -0.254812 0.046 Uiso 0.36(3) 1 calc R U P B 2
C58' C 0.4112(18) 0.6278(15) -0.2674(9) 0.039(4) Uani 0.36(3) 1 d D U P B 2
H58' H 0.452736 0.613762 -0.304382 0.047 Uiso 0.36(3) 1 calc R U P B 2
C59' C 0.3286(19) 0.5969(12) -0.2414(10) 0.039(3) Uani 0.36(3) 1 d D U P B 2
H59' H 0.311420 0.560149 -0.260329 0.047 Uiso 0.36(3) 1 calc R U P B 2
C60' C 0.2681(16) 0.6176(13) -0.1873(10) 0.037(3) Uani 0.36(3) 1 d D U P B 2
H60' H 0.210742 0.594048 -0.170818 0.044 Uiso 0.36(3) 1 calc R U P B 2
C61 C 0.1353(9) 0.7786(6) -0.0865(6) 0.0396(19) Uani 0.767(18) 1 d D U P B 1
C62 C 0.1647(9) 0.8414(7) -0.1262(5) 0.041(2) Uani 0.767(18) 1 d D U P B 1
H62 H 0.225643 0.837640 -0.155031 0.050 Uiso 0.767(18) 1 calc R U P B 1
C63 C 0.1062(10) 0.9085(7) -0.1241(5) 0.046(3) Uani 0.767(18) 1 d D U P B 1
H63 H 0.127456 0.950840 -0.151645 0.055 Uiso 0.767(18) 1 calc R U P B 1
C64 C 0.0195(11) 0.9160(8) -0.0840(7) 0.051(3) Uani 0.767(18) 1 d D U P B 1
H64 H -0.019718 0.963272 -0.083584 0.061 Uiso 0.767(18) 1 calc R U P B 1
C65 C -0.0129(10) 0.8554(8) -0.0436(7) 0.054(3) Uani 0.767(18) 1 d D U P B 1
H65 H -0.074094 0.860527 -0.015154 0.065 Uiso 0.767(18) 1 calc R U P B 1
C66 C 0.0456(10) 0.7863(8) -0.0450(6) 0.049(3) Uani 0.767(18) 1 d D U P B 1
H66 H 0.023909 0.744155 -0.017424 0.059 Uiso 0.767(18) 1 calc R U P B 1
C61' C 0.141(2) 0.7798(10) -0.0943(13) 0.0396(19) Uani 0.233(18) 1 d D U P B 2
C62' C 0.193(2) 0.8315(17) -0.1363(10) 0.042(3) Uani 0.233(18) 1 d D U P B 2
H62' H 0.255736 0.816309 -0.160233 0.050 Uiso 0.233(18) 1 calc R U P B 2
C63' C 0.152(2) 0.9045(17) -0.1428(12) 0.046(4) Uani 0.233(18) 1 d D U P B 2
H63' H 0.187168 0.940275 -0.171499 0.055 Uiso 0.233(18) 1 calc R U P B 2
C64' C 0.063(3) 0.9264(19) -0.1091(17) 0.048(3) Uani 0.233(18) 1 d D U P B 2
H64' H 0.037026 0.977583 -0.114763 0.057 Uiso 0.233(18) 1 calc R U P B 2
C65' C 0.009(2) 0.878(2) -0.0669(17) 0.050(3) Uani 0.233(18) 1 d D U P B 2
H65' H -0.053727 0.893985 -0.043537 0.060 Uiso 0.233(18) 1 calc R U P B 2
C66' C 0.050(2) 0.8026(19) -0.0598(16) 0.047(3) Uani 0.233(18) 1 d D U P B 2
H66' H 0.014379 0.767106 -0.031107 0.057 Uiso 0.233(18) 1 calc R U P B 2
C67 C 0.2788(5) 0.6824(5) -0.0296(3) 0.0239(18) Uani 1 1 d . . . . .
C68 C 0.3200(6) 0.7446(5) -0.0287(4) 0.033(2) Uani 1 1 d . . . . .
H68 H 0.305388 0.789350 -0.054380 0.039 Uiso 1 1 calc R U . . .
C69 C 0.3829(7) 0.7436(5) 0.0092(4) 0.038(2) Uani 1 1 d . . . . .
H69 H 0.409071 0.787791 0.010457 0.046 Uiso 1 1 calc R U . . .
C70 C 0.4068(7) 0.6781(5) 0.0446(4) 0.038(2) Uani 1 1 d . . . . .
H70 H 0.451237 0.676418 0.069712 0.046 Uiso 1 1 calc R U . . .
C71 C -0.3663(6) 0.3856(5) -0.0439(4) 0.030(2) Uani 1 1 d . . . . .
H71 H -0.382617 0.430338 -0.069089 0.036 Uiso 1 1 calc R U . . .
C72 C -0.3028(6) 0.3853(5) -0.0075(4) 0.0260(18) Uani 1 1 d . . . . .
P5 P -0.11581(16) 0.51483(13) -0.16835(9) 0.0269(5) Uani 1 1 d D . . . .
C73 C -0.057(2) 0.5382(12) -0.2477(6) 0.036(3) Uani 0.45(3) 1 d D U P C 1
C74 C 0.047(2) 0.5333(10) -0.2603(9) 0.040(3) Uani 0.45(3) 1 d D U P C 1
H74 H 0.079833 0.520974 -0.227861 0.048 Uiso 0.45(3) 1 calc R U P C 1
C75 C 0.0996(18) 0.5465(12) -0.3200(10) 0.042(3) Uani 0.45(3) 1 d D U P C 1
H75 H 0.168689 0.543133 -0.328177 0.050 Uiso 0.45(3) 1 calc R U P C 1
C76 C 0.0539(19) 0.5643(12) -0.3676(10) 0.042(3) Uani 0.45(3) 1 d D U P C 1
H76 H 0.091048 0.573263 -0.408382 0.050 Uiso 0.45(3) 1 calc R U P C 1
C77 C -0.0452(19) 0.5692(15) -0.3561(10) 0.039(3) Uani 0.45(3) 1 d D U P C 1
H77 H -0.077253 0.581537 -0.388798 0.047 Uiso 0.45(3) 1 calc R U P C 1
C78 C -0.100(2) 0.5560(16) -0.2963(11) 0.039(3) Uani 0.45(3) 1 d D U P C 1
H78 H -0.168477 0.559570 -0.289072 0.046 Uiso 0.45(3) 1 calc R U P C 1
C73' C -0.0642(19) 0.5414(10) -0.2484(5) 0.036(3) Uani 0.55(3) 1 d D U P C 2
C74' C 0.0347(18) 0.5552(10) -0.2644(8) 0.041(3) Uani 0.55(3) 1 d D U P C 2
H74' H 0.069790 0.551472 -0.233548 0.049 Uiso 0.55(3) 1 calc R U P C 2
C75' C 0.0797(15) 0.5741(11) -0.3251(8) 0.042(3) Uani 0.55(3) 1 d D U P C 2
H75' H 0.145915 0.583248 -0.335831 0.050 Uiso 0.55(3) 1 calc R U P C 2
C76' C 0.0291(16) 0.5796(10) -0.3700(8) 0.041(3) Uani 0.55(3) 1 d D U P C 2
H76' H 0.060404 0.592558 -0.411536 0.049 Uiso 0.55(3) 1 calc R U P C 2
C77' C -0.0659(15) 0.5663(12) -0.3546(9) 0.039(3) Uani 0.55(3) 1 d D U P C 2
H77' H -0.100454 0.570239 -0.385755 0.047 Uiso 0.55(3) 1 calc R U P C 2
C78' C -0.1128(17) 0.5472(13) -0.2939(9) 0.038(3) Uani 0.55(3) 1 d D U P C 2
H78' H -0.178998 0.538013 -0.283976 0.046 Uiso 0.55(3) 1 calc R U P C 2
C79 C -0.1486(6) 0.4217(5) -0.1632(4) 0.031(2) Uani 1 1 d . . . . .
C80 C -0.1026(6) 0.3612(5) -0.1299(4) 0.037(2) Uani 1 1 d . . . . .
H80 H -0.054747 0.369225 -0.110214 0.044 Uiso 1 1 calc R U . . .
C81 C -0.1268(8) 0.2900(6) -0.1258(5) 0.055(3) Uani 1 1 d . . . . .
H81 H -0.096719 0.249300 -0.102368 0.066 Uiso 1 1 calc R U . . .
C82 C -0.1939(8) 0.2782(7) -0.1553(5) 0.059(3) Uani 1 1 d . . . . .
H82 H -0.209275 0.229005 -0.152959 0.071 Uiso 1 1 calc R U . . .
C83 C -0.2392(8) 0.3362(7) -0.1881(5) 0.057(3) Uani 1 1 d . . . . .
H83 H -0.285182 0.326755 -0.208693 0.069 Uiso 1 1 calc R U . . .
C84 C -0.2191(7) 0.4093(6) -0.1918(4) 0.045(2) Uani 1 1 d . . . . .
H84 H -0.252684 0.449735 -0.213403 0.054 Uiso 1 1 calc R U . . .
C85 C -0.2327(6) 0.5716(5) -0.1453(4) 0.032(2) Uani 1 1 d . . . . .
C86 C -0.2629(7) 0.6325(5) -0.1844(4) 0.037(2) Uani 1 1 d . . . . .
H86 H -0.223093 0.643744 -0.224081 0.045 Uiso 1 1 calc R U . . .
C87 C -0.3499(8) 0.6766(6) -0.1664(4) 0.050(3) Uani 1 1 d . . . . .
H87 H -0.369614 0.717634 -0.194045 0.060 Uiso 1 1 calc R U . . .
C88 C -0.4083(7) 0.6625(6) -0.1094(4) 0.047(3) Uani 1 1 d . . . . .
H88 H -0.469370 0.692193 -0.098000 0.057 Uiso 1 1 calc R U . . .
C89 C -0.3773(6) 0.6045(5) -0.0686(4) 0.034(2) Uani 1 1 d . . . . .
H89 H -0.416154 0.596367 -0.028267 0.041 Uiso 1 1 calc R U . . .
C90 C -0.2917(6) 0.5585(5) -0.0851(4) 0.0294(19) Uani 1 1 d . . . . .
P6 P -0.20595(15) 0.63269(13) 0.05788(10) 0.0278(5) Uani 1 1 d D . . . .
C91 C -0.3336(5) 0.5276(5) 0.0650(4) 0.0252(18) Uani 1 1 d . . . . .
C92 C -0.4183(6) 0.4934(5) 0.0928(4) 0.031(2) Uani 1 1 d . . . . .
H92 H -0.433621 0.455238 0.074534 0.037 Uiso 1 1 calc R U . . .
C93 C -0.4797(6) 0.5145(5) 0.1462(4) 0.034(2) Uani 1 1 d . . . . .
H93 H -0.535719 0.489997 0.164680 0.041 Uiso 1 1 calc R U . . .
C94 C -0.4598(6) 0.5712(6) 0.1727(4) 0.038(2) Uani 1 1 d . . . . .
H94 H -0.501966 0.585558 0.209406 0.045 Uiso 1 1 calc R U . . .
C95 C -0.3791(6) 0.6064(6) 0.1458(4) 0.037(2) Uani 1 1 d . . . . .
H95 H -0.366761 0.646430 0.163294 0.045 Uiso 1 1 calc R U . . .
C96 C -0.3139(6) 0.5842(5) 0.0924(4) 0.029(2) Uani 1 1 d . . . . .
C97 C -0.2498(9) 0.7096(7) 0.0047(6) 0.033(2) Uani 0.76(3) 1 d D U P D 1
C98 C -0.2015(8) 0.7186(7) -0.0567(6) 0.038(2) Uani 0.76(3) 1 d D U P D 1
H98 H -0.142775 0.687351 -0.070665 0.046 Uiso 0.76(3) 1 calc R U P D 1
C99 C -0.2395(8) 0.7732(8) -0.0974(6) 0.039(3) Uani 0.76(3) 1 d D U P D 1
H99 H -0.206116 0.778995 -0.139133 0.047 Uiso 0.76(3) 1 calc R U P D 1
C100 C -0.3240(8) 0.8189(8) -0.0785(7) 0.040(3) Uani 0.76(3) 1 d D U P D 1
H100 H -0.348818 0.856011 -0.107119 0.048 Uiso 0.76(3) 1 calc R U P D 1
C101 C -0.3728(9) 0.8111(7) -0.0182(7) 0.041(3) Uani 0.76(3) 1 d D U P D 1
H101 H -0.431391 0.843025 -0.005301 0.049 Uiso 0.76(3) 1 calc R U P D 1
C102 C -0.3377(10) 0.7576(8) 0.0235(7) 0.037(2) Uani 0.76(3) 1 d D U P D 1
H102 H -0.372101 0.752687 0.065113 0.044 Uiso 0.76(3) 1 calc R U P D 1
C97C C -0.253(2) 0.7107(16) 0.0071(13) 0.035(3) Uani 0.24(3) 1 d D U P D 2
C98C C -0.2007(19) 0.7338(14) -0.0511(13) 0.038(3) Uani 0.24(3) 1 d D U P D 2
H98C H -0.140559 0.706277 -0.068478 0.045 Uiso 0.24(3) 1 calc R U P D 2
C99C C -0.238(2) 0.7977(17) -0.0836(14) 0.041(4) Uani 0.24(3) 1 d D U P D 2
H99C H -0.203865 0.814627 -0.123640 0.049 Uiso 0.24(3) 1 calc R U P D 2
C10C C -0.325(2) 0.8367(18) -0.0579(19) 0.042(4) Uani 0.24(3) 1 d D U P D 2
H10C H -0.349804 0.880533 -0.080820 0.050 Uiso 0.24(3) 1 calc R U P D 2
C11C C -0.377(2) 0.814(2) -0.0001(18) 0.039(3) Uani 0.24(3) 1 d D U P D 2
H11C H -0.437345 0.842732 0.016436 0.047 Uiso 0.24(3) 1 calc R U P D 2
C12C C -0.342(3) 0.751(2) 0.0336(16) 0.037(3) Uani 0.24(3) 1 d D U P D 2
H12C H -0.377472 0.734768 0.073630 0.044 Uiso 0.24(3) 1 calc R U P D 2
C103 C -0.1799(14) 0.6812(15) 0.1142(9) 0.042(3) Uani 0.52(3) 1 d D U P D 1
C104 C -0.1689(12) 0.7566(15) 0.1023(10) 0.044(3) Uani 0.52(3) 1 d D U P D 1
H104 H -0.181664 0.785574 0.065948 0.053 Uiso 0.52(3) 1 calc R U P D 1
C105 C -0.1391(12) 0.7893(14) 0.1436(12) 0.047(3) Uani 0.52(3) 1 d D U P D 1
H105 H -0.131386 0.840966 0.135714 0.056 Uiso 0.52(3) 1 calc R U P D 1
C106 C -0.1208(13) 0.7474(16) 0.1960(11) 0.047(4) Uani 0.52(3) 1 d D U P D 1
H106 H -0.100504 0.771053 0.223901 0.056 Uiso 0.52(3) 1 calc R U P D 1
C107 C -0.1305(14) 0.6731(16) 0.2098(10) 0.047(3) Uani 0.52(3) 1 d D U P D 1
H107 H -0.117320 0.645109 0.246487 0.056 Uiso 0.52(3) 1 calc R U P D 1
C108 C -0.1608(16) 0.6392(15) 0.1679(11) 0.044(3) Uani 0.52(3) 1 d D U P D 1
H108 H -0.168339 0.587467 0.176163 0.053 Uiso 0.52(3) 1 calc R U P D 1
C13C C -0.1820(15) 0.6703(16) 0.1208(10) 0.042(3) Uani 0.48(3) 1 d D U P D 2
C14C C -0.1725(12) 0.7448(16) 0.1186(10) 0.044(3) Uani 0.48(3) 1 d D U P D 2
H14C H -0.183077 0.779161 0.084071 0.053 Uiso 0.48(3) 1 calc R U P D 2
C15C C -0.1478(12) 0.7700(15) 0.1656(12) 0.047(3) Uani 0.48(3) 1 d D U P D 2
H15C H -0.141260 0.821214 0.164042 0.057 Uiso 0.48(3) 1 calc R U P D 2
C16C C -0.1331(14) 0.7188(17) 0.2147(11) 0.045(4) Uani 0.48(3) 1 d D U P D 2
H16C H -0.116129 0.736007 0.247151 0.055 Uiso 0.48(3) 1 calc R U P D 2
C17C C -0.1415(16) 0.6442(17) 0.2195(11) 0.045(3) Uani 0.48(3) 1 d D U P D 2
H17C H -0.130595 0.610801 0.254455 0.055 Uiso 0.48(3) 1 calc R U P D 2
C18C C -0.1667(17) 0.6182(15) 0.1716(12) 0.041(3) Uani 0.48(3) 1 d D U P D 2
H18C H -0.173108 0.566853 0.173372 0.050 Uiso 0.48(3) 1 calc R U P D 2
P7 P 0.3447(3) 0.4859(2) 0.3590(2) 0.0566(11) Uani 0.853(6) 1 d D U P E 1
F1 F 0.2842(10) 0.5518(7) 0.3270(5) 0.128(4) Uani 0.853(6) 1 d D U P E 1
F2 F 0.3445(9) 0.5322(6) 0.4107(4) 0.099(3) Uani 0.853(6) 1 d D U P E 1
F3 F 0.3979(6) 0.4154(5) 0.3882(4) 0.085(3) Uani 0.853(6) 1 d D U P E 1
F4 F 0.3468(6) 0.4436(5) 0.3021(4) 0.081(3) Uani 0.853(6) 1 d D U P E 1
F5 F 0.2440(6) 0.4571(7) 0.3961(5) 0.103(3) Uani 0.853(6) 1 d D U P E 1
F6 F 0.4457(8) 0.5097(6) 0.3235(4) 0.106(3) Uani 0.853(6) 1 d D U P E 1
P7' P 0.3304(17) 0.4702(14) 0.3990(12) 0.082(4) Uani 0.147(6) 1 d D U P E 2
F1' F 0.272(3) 0.494(3) 0.3483(18) 0.093(6) Uani 0.147(6) 1 d D U P E 2
F2' F 0.280(3) 0.5416(19) 0.428(2) 0.093(7) Uani 0.147(6) 1 d D U P E 2
F3' F 0.384(3) 0.443(2) 0.4496(15) 0.087(7) Uani 0.147(6) 1 d D U P E 2
F4' F 0.377(3) 0.399(2) 0.364(2) 0.075(7) Uani 0.147(6) 1 d D U P E 2
F5' F 0.242(2) 0.426(2) 0.438(2) 0.109(9) Uani 0.147(6) 1 d D U P E 2
F6' F 0.421(3) 0.508(2) 0.3633(19) 0.083(6) Uani 0.147(6) 1 d D U P E 2
P8 P 0.5465(4) 0.0669(3) 0.16024(19) 0.0580(12) Uani 0.795(8) 1 d D U P F 1
F7 F 0.5568(9) 0.1112(7) 0.0962(4) 0.095(3) Uani 0.795(8) 1 d D U P F 1
F8 F 0.4871(8) 0.1391(6) 0.1918(4) 0.081(3) Uani 0.795(8) 1 d D U P F 1
F9 F 0.5309(8) 0.0181(6) 0.2235(4) 0.073(3) Uani 0.795(8) 1 d D U P F 1
F10 F 0.6090(8) -0.0038(6) 0.1287(5) 0.093(3) Uani 0.795(8) 1 d D U P F 1
F11 F 0.4500(7) 0.0436(6) 0.1516(5) 0.079(3) Uani 0.795(8) 1 d D U P F 1
F12 F 0.6436(7) 0.0885(6) 0.1645(4) 0.077(3) Uani 0.795(8) 1 d D U P F 1
P8' P 0.5146(16) 0.0879(12) 0.1513(10) 0.091(4) Uani 0.205(8) 1 d D U P F 2
F7' F 0.543(3) 0.131(2) 0.0870(13) 0.088(7) Uani 0.205(8) 1 d D U P F 2
F8' F 0.4007(18) 0.123(2) 0.1598(16) 0.103(7) Uani 0.205(8) 1 d D U P F 2
F9' F 0.482(2) 0.0418(18) 0.2140(12) 0.074(6) Uani 0.205(8) 1 d D U P F 2
F10' F 0.6292(18) 0.056(2) 0.1515(17) 0.079(5) Uani 0.205(8) 1 d D U P F 2
F11' F 0.506(3) 0.0240(17) 0.1174(15) 0.093(6) Uani 0.205(8) 1 d D U P F 2
F12' F 0.537(2) 0.1574(16) 0.1727(15) 0.072(6) Uani 0.205(8) 1 d D U P F 2
C1S C 0.5171(12) 0.1321(10) 0.8361(8) 0.110(6) Uani 0.939(8) 1 d D . P . .
H1S1 H 0.492173 0.089677 0.865767 0.132 Uiso 0.939(8) 1 calc R U P . .
H1S2 H 0.562735 0.110953 0.800878 0.132 Uiso 0.939(8) 1 calc R U P . .
Cl1 Cl 0.5801(3) 0.1763(3) 0.8689(2) 0.0998(18) Uani 0.939(8) 1 d D . P . .
Cl2 Cl 0.4205(3) 0.1852(3) 0.8110(2) 0.120(2) Uani 0.939(8) 1 d D . P . .
C2S C 0.7241(16) 0.2795(11) 0.6373(9) 0.153(11) Uani 0.892(8) 1 d D . P . .
H2S1 H 0.678939 0.298169 0.609985 0.184 Uiso 0.892(8) 1 calc R U P . .
H2S2 H 0.754439 0.323060 0.640938 0.184 Uiso 0.892(8) 1 calc R U P . .
Cl3 Cl 0.8112(3) 0.2221(2) 0.60123(17) 0.0787(14) Uani 0.892(8) 1 d D . P . .
Cl4 Cl 0.6550(4) 0.2536(3) 0.7064(2) 0.114(2) Uani 0.892(8) 1 d D . P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 P1 2.296(2) . ?
Au1 Au3 2.7160(4) . ?
Au1 Au2 2.7764(4) . ?
Au1 Au2 2.7898(4) 2_556 ?
Au1 Sb1 3.1906(6) 2_556 ?
Au2 P2 2.2978(19) . ?
Au2 Au2 2.6682(5) 2_556 ?
Au2 Au3 2.7485(4) . ?
Au2 Au3 2.8245(4) 2_556 ?
Au2 Sb1 3.0079(6) . ?
Au3 P3 2.295(2) . ?
Au3 Sb1 3.0479(6) . ?
Sb1 C36 2.156(8) . ?
Sb1 C37 2.160(8) . ?
Sb1 C8 2.202(8) 2_556 ?
P1 C13 1.811(9) . ?
P1 C1 1.818(8) . ?
P1 C7 1.829(8) . ?
C1 C2 1.391(13) . ?
C1 C6 1.397(12) . ?
C2 C3 1.390(13) . ?
C2 H2 0.9500 . ?
C3 C4 1.390(14) . ?
C3 H3 0.9500 . ?
C4 C5 1.373(14) . ?
C4 H4 0.9500 . ?
C5 C6 1.374(13) . ?
C5 H5 0.9500 . ?
C6 H6 0.9500 . ?
C7 C12 1.381(12) . ?
C7 C8 1.389(11) . ?
C8 C9 1.398(11) . ?
C9 C10 1.384(12) . ?
C9 H9 0.9500 . ?
C10 C11 1.366(13) . ?
C10 H10 0.9500 . ?
C11 C12 1.383(12) . ?
C11 H11 0.9500 . ?
C12 H12 0.9500 . ?
C13 C18 1.374(13) . ?
C13 C14 1.389(14) . ?
C14 C15 1.372(14) . ?
C14 H14 0.9500 . ?
C15 C16 1.363(16) . ?
C15 H15 0.9500 . ?
C16 C17 1.415(18) . ?
C16 H16 0.9500 . ?
C17 C18 1.376(16) . ?
C17 H17 0.9500 . ?
C18 H18 0.9500 . ?
P2 C25' 1.815(11) . ?
P2 C25 1.817(10) . ?
P2 C19 1.818(8) . ?
P2 C31 1.838(8) . ?
C19 C24 1.367(12) . ?
C19 C20 1.380(11) . ?
C20 C21 1.373(13) . ?
C20 H20 0.9500 . ?
C21 C22 1.370(14) . ?
C21 H21 0.9500 . ?
C22 C23 1.391(13) . ?
C22 H22 0.9500 . ?
C23 C24 1.383(13) . ?
C23 H23 0.9500 . ?
C24 H24 0.9500 . ?
C25 C30 1.372(15) . ?
C25 C26 1.406(13) . ?
C26 C27 1.361(16) . ?
C26 H26 0.9500 . ?
C27 C28 1.385(18) . ?
C27 H27 0.9500 . ?
C28 C29 1.360(17) . ?
C28 H28 0.9500 . ?
C29 C30 1.397(15) . ?
C29 H29 0.9500 . ?
C30 H30 0.9500 . ?
C25' C30' 1.366(18) . ?
C25' C26' 1.407(17) . ?
C26' C27' 1.360(19) . ?
C26' H26' 0.9500 . ?
C27' C28' 1.37(2) . ?
C27' H27' 0.9500 . ?
C28' C29' 1.35(2) . ?
C28' H28' 0.9500 . ?
C29' C30' 1.400(19) . ?
C29' H29' 0.9500 . ?
C30' H30' 0.9500 . ?
C31 C36 1.404(11) . ?
C31 C32 1.405(11) . ?
C32 C33 1.380(12) . ?
C32 H32 0.9500 . ?
C33 C34 1.381(13) . ?
C33 H33 0.9500 . ?
C34 C35 1.393(12) . ?
C34 H34 0.9500 . ?
C35 C36 1.383(11) . ?
C35 H35 0.9500 . ?
P3 C43 1.819(8) . ?
P3 C49 1.823(8) . ?
P3 C42 1.842(8) . ?
C37 C38 1.408(11) . ?
C37 C42 1.411(11) . ?
C38 C39 1.397(11) . ?
C38 H38 0.9500 . ?
C39 C40 1.371(12) . ?
C39 H39 0.9500 . ?
C40 C41 1.381(12) . ?
C40 H40 0.9500 . ?
C41 C42 1.387(11) . ?
C41 H41 0.9500 . ?
C43 C44 1.387(12) . ?
C43 C48 1.392(12) . ?
C44 C45 1.377(13) . ?
C44 H44 0.9500 . ?
C45 C46 1.354(14) . ?
C45 H45 0.9500 . ?
C46 C47 1.371(14) . ?
C46 H46 0.9500 . ?
C47 C48 1.365(13) . ?
C47 H47 0.9500 . ?
C48 H48 0.9500 . ?
C49 C50 1.378(13) . ?
C49 C54 1.381(13) . ?
C50 C51 1.379(13) . ?
C50 H50 0.9500 . ?
C51 C52 1.393(16) . ?
C51 H51 0.9500 . ?
C52 C53 1.351(16) . ?
C52 H52 0.9500 . ?
C53 C54 1.395(13) . ?
C53 H53 0.9500 . ?
C54 H54 0.9500 . ?
Au4 P4 2.296(2) . ?
Au4 Au5 2.7017(5) . ?
Au4 Au6 2.7644(5) 2_565 ?
Au4 Au6 2.8076(4) . ?
Au4 Sb2 2.9899(6) 2_565 ?
Au5 P5 2.286(2) . ?
Au5 Au6 2.7494(4) . ?
Au5 Au6 2.8099(5) 2_565 ?
Au5 Sb2 3.3442(6) . ?
Au6 P6 2.290(2) . ?
Au6 Au6 2.6678(6) 2_565 ?
Au6 Sb2 2.9889(6) . ?
Sb2 C72 2.159(8) . ?
Sb2 C91 2.168(8) . ?
Sb2 C90 2.190(8) . ?
P4 C55 1.808(9) . ?
P4 C55' 1.815(11) . ?
P4 C61' 1.819(13) . ?
P4 C61 1.822(10) . ?
P4 C67 1.837(8) . ?
C55 C60 1.352(15) . ?
C55 C56 1.405(14) . ?
C56 C57 1.380(16) . ?
C56 H56 0.9500 . ?
C57 C58 1.401(19) . ?
C57 H57 0.9500 . ?
C58 C59 1.347(19) . ?
C58 H58 0.9500 . ?
C59 C60 1.389(15) . ?
C59 H59 0.9500 . ?
C60 H60 0.9500 . ?
C55' C60' 1.362(18) . ?
C55' C56' 1.412(18) . ?
C56' C57' 1.37(2) . ?
C56' H56' 0.9500 . ?
C57' C58' 1.39(2) . ?
C57' H57' 0.9500 . ?
C58' C59' 1.35(2) . ?
C58' H58' 0.9500 . ?
C59' C60' 1.388(19) . ?
C59' H59' 0.9500 . ?
C60' H60' 0.9500 . ?
C61 C66 1.390(14) . ?
C61 C62 1.390(13) . ?
C62 C63 1.368(16) . ?
C62 H62 0.9500 . ?
C63 C64 1.344(18) . ?
C63 H63 0.9500 . ?
C64 C65 1.380(19) . ?
C64 H64 0.9500 . ?
C65 C66 1.397(17) . ?
C65 H65 0.9500 . ?
C66 H66 0.9500 . ?
C61' C66' 1.38(2) . ?
C61' C62' 1.388(19) . ?
C62' C63' 1.37(2) . ?
C62' H62' 0.9500 . ?
C63' C64' 1.35(2) . ?
C63' H63' 0.9500 . ?
C64' C65' 1.37(3) . ?
C64' H64' 0.9500 . ?
C65' C66' 1.40(2) . ?
C65' H65' 0.9500 . ?
C66' H66' 0.9500 . ?
C67 C68 1.367(12) . ?
C67 C72 1.422(11) 2_565 ?
C68 C69 1.391(12) . ?
C68 H68 0.9500 . ?
C69 C70 1.375(13) . ?
C69 H69 0.9500 . ?
C70 C71 1.385(12) 2_565 ?
C70 H70 0.9500 . ?
C71 C72 1.376(11) . ?
C71 H71 0.9500 . ?
P5 C73' 1.806(10) . ?
P5 C73 1.807(11) . ?
P5 C79 1.815(9) . ?
P5 C85 1.821(9) . ?
C73 C78 1.367(17) . ?
C73 C74 1.427(17) . ?
C74 C75 1.384(17) . ?
C74 H74 0.9500 . ?
C75 C76 1.375(19) . ?
C75 H75 0.9500 . ?
C76 C77 1.363(19) . ?
C76 H76 0.9500 . ?
C77 C78 1.393(17) . ?
C77 H77 0.9500 . ?
C78 H78 0.9500 . ?
C73' C78' 1.370(16) . ?
C73' C74' 1.420(16) . ?
C74' C75' 1.385(16) . ?
C74' H74' 0.9500 . ?
C75' C76' 1.378(18) . ?
C75' H75' 0.9500 . ?
C76' C77' 1.364(17) . ?
C76' H76' 0.9500 . ?
C77' C78' 1.394(16) . ?
C77' H77' 0.9500 . ?
C78' H78' 0.9500 . ?
C79 C84 1.395(13) . ?
C79 C80 1.401(12) . ?
C80 C81 1.382(14) . ?
C80 H80 0.9500 . ?
C81 C82 1.364(16) . ?
C81 H81 0.9500 . ?
C82 C83 1.364(17) . ?
C82 H82 0.9500 . ?
C83 C84 1.394(14) . ?
C83 H83 0.9500 . ?
C84 H84 0.9500 . ?
C85 C86 1.388(12) . ?
C85 C90 1.425(12) . ?
C86 C87 1.375(13) . ?
C86 H86 0.9500 . ?
C87 C88 1.366(13) . ?
C87 H87 0.9500 . ?
C88 C89 1.383(13) . ?
C88 H88 0.9500 . ?
C89 C90 1.373(12) . ?
C89 H89 0.9500 . ?
P6 C13C 1.820(11) . ?
P6 C103 1.820(11) . ?
P6 C97C 1.830(12) . ?
P6 C97 1.835(9) . ?
P6 C96 1.838(8) . ?
C91 C96 1.393(12) . ?
C91 C92 1.407(11) . ?
C92 C93 1.383(12) . ?
C92 H92 0.9500 . ?
C93 C94 1.382(13) . ?
C93 H93 0.9500 . ?
C94 C95 1.368(13) . ?
C94 H94 0.9500 . ?
C95 C96 1.410(12) . ?
C95 H95 0.9500 . ?
C97 C98 1.394(13) . ?
C97 C102 1.424(13) . ?
C98 C99 1.385(14) . ?
C98 H98 0.9500 . ?
C99 C100 1.368(15) . ?
C99 H99 0.9500 . ?
C100 C101 1.373(15) . ?
C100 H100 0.9500 . ?
C101 C102 1.374(15) . ?
C101 H101 0.9500 . ?
C102 H102 0.9500 . ?
C97C C98C 1.383(18) . ?
C97C C12C 1.416(19) . ?
C98C C99C 1.38(2) . ?
C98C H98C 0.9500 . ?
C99C C10C 1.37(2) . ?
C99C H99C 0.9500 . ?
C10C C11C 1.37(2) . ?
C10C H10C 0.9500 . ?
C11C C12C 1.38(2) . ?
C11C H11C 0.9500 . ?
C12C H12C 0.9500 . ?
C103 C104 1.385(18) . ?
C103 C108 1.399(18) . ?
C104 C105 1.379(18) . ?
C104 H104 0.9500 . ?
C105 C106 1.37(2) . ?
C105 H105 0.9500 . ?
C106 C107 1.36(2) . ?
C106 H106 0.9500 . ?
C107 C108 1.408(18) . ?
C107 H107 0.9500 . ?
C108 H108 0.9500 . ?
C13C C14C 1.381(18) . ?
C13C C18C 1.410(18) . ?
C14C C15C 1.378(18) . ?
C14C H14C 0.9500 . ?
C15C C16C 1.37(2) . ?
C15C H15C 0.9500 . ?
C16C C17C 1.37(2) . ?
C16C H16C 0.9500 . ?
C17C C18C 1.408(19) . ?
C17C H17C 0.9500 . ?
C18C H18C 0.9500 . ?
P7 F3 1.528(9) . ?
P7 F1 1.554(11) . ?
P7 F6 1.557(10) . ?
P7 F2 1.562(9) . ?
P7 F5 1.595(11) . ?
P7 F4 1.611(9) . ?
P7' F3' 1.518(19) . ?
P7' F6' 1.55(2) . ?
P7' F2' 1.549(19) . ?
P7' F1' 1.56(2) . ?
P7' F5' 1.60(2) . ?
P7' F4' 1.604(19) . ?
P8 F12 1.531(10) . ?
P8 F7 1.534(9) . ?
P8 F9 1.550(9) . ?
P8 F11 1.572(9) . ?
P8 F10 1.614(11) . ?
P8 F8 1.621(10) . ?
P8' F7' 1.538(18) . ?
P8' F9' 1.539(18) . ?
P8' F11' 1.542(18) . ?
P8' F12' 1.542(19) . ?
P8' F8' 1.624(19) . ?
P8' F10' 1.65(2) . ?
C1S Cl1 1.674(14) . ?
C1S Cl2 1.718(15) . ?
C1S H1S1 0.9900 . ?
C1S H1S2 0.9900 . ?
C2S Cl3 1.636(16) . ?
C2S Cl4 1.676(15) . ?
C2S H2S1 0.9900 . ?
C2S H2S2 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Au1 Au3 151.91(6) . . ?
P1 Au1 Au2 146.17(6) . . ?
Au3 Au1 Au2 60.044(11) . . ?
P1 Au1 Au2 133.41(5) . 2_556 ?
Au3 Au1 Au2 61.711(11) . 2_556 ?
Au2 Au1 Au2 57.286(11) . 2_556 ?
P1 Au1 Sb1 76.76(5) . 2_556 ?
Au3 Au1 Sb1 121.442(16) . 2_556 ?
Au2 Au1 Sb1 91.742(14) . 2_556 ?
Au2 Au1 Sb1 59.947(13) 2_556 2_556 ?
P2 Au2 Au2 177.93(6) . 2_556 ?
P2 Au2 Au3 118.61(5) . . ?
Au2 Au2 Au3 62.837(13) 2_556 . ?
P2 Au2 Au1 120.31(6) . . ?
Au2 Au2 Au1 61.609(13) 2_556 . ?
Au3 Au2 Au1 58.888(11) . . ?
P2 Au2 Au1 116.97(6) . 2_556 ?
Au2 Au2 Au1 61.106(13) 2_556 2_556 ?
Au3 Au2 Au1 94.452(13) . 2_556 ?
Au1 Au2 Au1 122.715(11) . 2_556 ?
P2 Au2 Au3 118.56(5) . 2_556 ?
Au2 Au2 Au3 59.972(12) 2_556 2_556 ?
Au3 Au2 Au3 122.809(11) . 2_556 ?
Au1 Au2 Au3 93.075(12) . 2_556 ?
Au1 Au2 Au3 57.860(11) 2_556 2_556 ?
P2 Au2 Sb1 81.54(5) . . ?
Au2 Au2 Sb1 98.097(16) 2_556 . ?
Au3 Au2 Sb1 63.754(13) . . ?
Au1 Au2 Sb1 122.243(15) . . ?
Au1 Au2 Sb1 66.657(13) 2_556 . ?
Au3 Au2 Sb1 124.289(16) 2_556 . ?
P3 Au3 Au1 150.65(5) . . ?
P3 Au3 Au2 145.76(5) . . ?
Au1 Au3 Au2 61.068(11) . . ?
P3 Au3 Au2 136.00(5) . 2_556 ?
Au1 Au3 Au2 60.429(11) . 2_556 ?
Au2 Au3 Au2 57.190(11) . 2_556 ?
P3 Au3 Sb1 83.89(5) . . ?
Au1 Au3 Sb1 122.927(15) . . ?
Au2 Au3 Sb1 62.266(13) . . ?
Au2 Au3 Sb1 93.861(15) 2_556 . ?
C36 Sb1 C37 97.8(3) . . ?
C36 Sb1 C8 97.0(3) . 2_556 ?
C37 Sb1 C8 98.9(3) . 2_556 ?
C36 Sb1 Au2 86.5(2) . . ?
C37 Sb1 Au2 144.9(2) . . ?
C8 Sb1 Au2 115.2(2) 2_556 . ?
C36 Sb1 Au3 92.2(2) . . ?
C37 Sb1 Au3 90.9(2) . . ?
C8 Sb1 Au3 165.5(2) 2_556 . ?
Au2 Sb1 Au3 53.979(12) . . ?
C36 Sb1 Au1 134.5(2) . 2_556 ?
C37 Sb1 Au1 127.1(2) . 2_556 ?
C8 Sb1 Au1 84.2(2) 2_556 2_556 ?
Au2 Sb1 Au1 53.397(11) . 2_556 ?
Au3 Sb1 Au1 81.298(14) . 2_556 ?
C13 P1 C1 106.8(4) . . ?
C13 P1 C7 109.8(4) . . ?
C1 P1 C7 100.3(4) . . ?
C13 P1 Au1 110.5(3) . . ?
C1 P1 Au1 118.3(3) . . ?
C7 P1 Au1 110.5(3) . . ?
C2 C1 C6 118.4(8) . . ?
C2 C1 P1 120.0(7) . . ?
C6 C1 P1 121.3(7) . . ?
C3 C2 C1 121.0(9) . . ?
C3 C2 H2 119.5 . . ?
C1 C2 H2 119.5 . . ?
C4 C3 C2 118.9(10) . . ?
C4 C3 H3 120.5 . . ?
C2 C3 H3 120.5 . . ?
C5 C4 C3 120.8(9) . . ?
C5 C4 H4 119.6 . . ?
C3 C4 H4 119.6 . . ?
C4 C5 C6 120.0(9) . . ?
C4 C5 H5 120.0 . . ?
C6 C5 H5 120.0 . . ?
C5 C6 C1 120.9(9) . . ?
C5 C6 H6 119.6 . . ?
C1 C6 H6 119.6 . . ?
C12 C7 C8 120.4(7) . . ?
C12 C7 P1 120.9(7) . . ?
C8 C7 P1 118.6(6) . . ?
C7 C8 C9 119.0(8) . . ?
C7 C8 Sb1 122.9(6) . 2_556 ?
C9 C8 Sb1 118.1(6) . 2_556 ?
C10 C9 C8 119.8(8) . . ?
C10 C9 H9 120.1 . . ?
C8 C9 H9 120.1 . . ?
C11 C10 C9 120.7(8) . . ?
C11 C10 H10 119.7 . . ?
C9 C10 H10 119.7 . . ?
C10 C11 C12 120.0(8) . . ?
C10 C11 H11 120.0 . . ?
C12 C11 H11 120.0 . . ?
C7 C12 C11 120.1(9) . . ?
C7 C12 H12 120.0 . . ?
C11 C12 H12 120.0 . . ?
C18 C13 C14 119.5(9) . . ?
C18 C13 P1 120.9(8) . . ?
C14 C13 P1 118.4(7) . . ?
C15 C14 C13 120.2(10) . . ?
C15 C14 H14 119.9 . . ?
C13 C14 H14 119.9 . . ?
C16 C15 C14 120.6(11) . . ?
C16 C15 H15 119.7 . . ?
C14 C15 H15 119.7 . . ?
C15 C16 C17 120.0(11) . . ?
C15 C16 H16 120.0 . . ?
C17 C16 H16 120.0 . . ?
C18 C17 C16 118.6(11) . . ?
C18 C17 H17 120.7 . . ?
C16 C17 H17 120.7 . . ?
C13 C18 C17 121.1(12) . . ?
C13 C18 H18 119.5 . . ?
C17 C18 H18 119.5 . . ?
C25' P2 C19 105.3(7) . . ?
C25 P2 C19 106.1(5) . . ?
C25' P2 C31 103.6(9) . . ?
C25 P2 C31 106.4(6) . . ?
C19 P2 C31 105.2(4) . . ?
C25' P2 Au2 113.8(7) . . ?
C25 P2 Au2 110.8(4) . . ?
C19 P2 Au2 118.5(3) . . ?
C31 P2 Au2 109.0(2) . . ?
C24 C19 C20 118.8(8) . . ?
C24 C19 P2 118.2(6) . . ?
C20 C19 P2 122.9(7) . . ?
C21 C20 C19 120.3(9) . . ?
C21 C20 H20 119.8 . . ?
C19 C20 H20 119.8 . . ?
C22 C21 C20 120.9(9) . . ?
C22 C21 H21 119.6 . . ?
C20 C21 H21 119.6 . . ?
C21 C22 C23 119.5(9) . . ?
C21 C22 H22 120.3 . . ?
C23 C22 H22 120.3 . . ?
C24 C23 C22 118.8(9) . . ?
C24 C23 H23 120.6 . . ?
C22 C23 H23 120.6 . . ?
C19 C24 C23 121.7(8) . . ?
C19 C24 H24 119.1 . . ?
C23 C24 H24 119.1 . . ?
C30 C25 C26 118.2(10) . . ?
C30 C25 P2 117.0(10) . . ?
C26 C25 P2 124.7(11) . . ?
C27 C26 C25 120.9(12) . . ?
C27 C26 H26 119.5 . . ?
C25 C26 H26 119.5 . . ?
C26 C27 C28 120.0(12) . . ?
C26 C27 H27 120.0 . . ?
C28 C27 H27 120.0 . . ?
C29 C28 C27 120.3(12) . . ?
C29 C28 H28 119.9 . . ?
C27 C28 H28 119.9 . . ?
C28 C29 C30 119.9(13) . . ?
C28 C29 H29 120.1 . . ?
C30 C29 H29 120.1 . . ?
C25 C30 C29 120.8(11) . . ?
C25 C30 H30 119.6 . . ?
C29 C30 H30 119.6 . . ?
C30' C25' C26' 118.7(15) . . ?
C30' C25' P2 121.5(16) . . ?
C26' C25' P2 119.7(17) . . ?
C27' C26' C25' 119.4(17) . . ?
C27' C26' H26' 120.3 . . ?
C25' C26' H26' 120.3 . . ?
C26' C27' C28' 121.7(17) . . ?
C26' C27' H27' 119.2 . . ?
C28' C27' H27' 119.2 . . ?
C29' C28' C27' 119.6(18) . . ?
C29' C28' H28' 120.2 . . ?
C27' C28' H28' 120.2 . . ?
C28' C29' C30' 120.1(19) . . ?
C28' C29' H29' 120.0 . . ?
C30' C29' H29' 120.0 . . ?
C25' C30' C29' 120.6(17) . . ?
C25' C30' H30' 119.7 . . ?
C29' C30' H30' 119.7 . . ?
C36 C31 C32 119.3(7) . . ?
C36 C31 P2 121.0(6) . . ?
C32 C31 P2 119.7(6) . . ?
C33 C32 C31 120.7(8) . . ?
C33 C32 H32 119.6 . . ?
C31 C32 H32 119.6 . . ?
C32 C33 C34 120.3(8) . . ?
C32 C33 H33 119.9 . . ?
C34 C33 H33 119.9 . . ?
C33 C34 C35 119.0(8) . . ?
C33 C34 H34 120.5 . . ?
C35 C34 H34 120.5 . . ?
C36 C35 C34 122.1(8) . . ?
C36 C35 H35 119.0 . . ?
C34 C35 H35 119.0 . . ?
C35 C36 C31 118.5(7) . . ?
C35 C36 Sb1 119.2(6) . . ?
C31 C36 Sb1 122.2(6) . . ?
C43 P3 C49 108.2(4) . . ?
C43 P3 C42 108.0(4) . . ?
C49 P3 C42 101.6(4) . . ?
C43 P3 Au3 111.1(3) . . ?
C49 P3 Au3 110.0(3) . . ?
C42 P3 Au3 117.3(3) . . ?
C38 C37 C42 117.7(7) . . ?
C38 C37 Sb1 117.7(6) . . ?
C42 C37 Sb1 124.1(6) . . ?
C39 C38 C37 121.2(8) . . ?
C39 C38 H38 119.4 . . ?
C37 C38 H38 119.4 . . ?
C40 C39 C38 119.8(8) . . ?
C40 C39 H39 120.1 . . ?
C38 C39 H39 120.1 . . ?
C39 C40 C41 120.0(8) . . ?
C39 C40 H40 120.0 . . ?
C41 C40 H40 120.0 . . ?
C40 C41 C42 121.4(8) . . ?
C40 C41 H41 119.3 . . ?
C42 C41 H41 119.3 . . ?
C41 C42 C37 119.8(7) . . ?
C41 C42 P3 117.9(6) . . ?
C37 C42 P3 122.2(6) . . ?
C44 C43 C48 118.2(8) . . ?
C44 C43 P3 117.2(7) . . ?
C48 C43 P3 124.5(7) . . ?
C45 C44 C43 119.7(9) . . ?
C45 C44 H44 120.1 . . ?
C43 C44 H44 120.1 . . ?
C46 C45 C44 121.4(10) . . ?
C46 C45 H45 119.3 . . ?
C44 C45 H45 119.3 . . ?
C45 C46 C47 119.4(10) . . ?
C45 C46 H46 120.3 . . ?
C47 C46 H46 120.3 . . ?
C48 C47 C46 120.5(9) . . ?
C48 C47 H47 119.7 . . ?
C46 C47 H47 119.7 . . ?
C47 C48 C43 120.6(9) . . ?
C47 C48 H48 119.7 . . ?
C43 C48 H48 119.7 . . ?
C50 C49 C54 119.9(8) . . ?
C50 C49 P3 117.2(7) . . ?
C54 C49 P3 122.9(7) . . ?
C49 C50 C51 121.1(10) . . ?
C49 C50 H50 119.4 . . ?
C51 C50 H50 119.4 . . ?
C50 C51 C52 119.0(10) . . ?
C50 C51 H51 120.5 . . ?
C52 C51 H51 120.5 . . ?
C53 C52 C51 119.7(10) . . ?
C53 C52 H52 120.1 . . ?
C51 C52 H52 120.1 . . ?
C52 C53 C54 121.9(11) . . ?
C52 C53 H53 119.1 . . ?
C54 C53 H53 119.1 . . ?
C49 C54 C53 118.4(10) . . ?
C49 C54 H54 120.8 . . ?
C53 C54 H54 120.8 . . ?
P4 Au4 Au5 145.79(5) . . ?
P4 Au4 Au6 142.89(6) . 2_565 ?
Au5 Au4 Au6 61.856(12) . 2_565 ?
P4 Au4 Au6 146.00(6) . . ?
Au5 Au4 Au6 59.838(11) . . ?
Au6 Au4 Au6 57.206(13) 2_565 . ?
P4 Au4 Sb2 82.47(6) . 2_565 ?
Au5 Au4 Sb2 123.254(18) . 2_565 ?
Au6 Au4 Sb2 62.440(14) 2_565 2_565 ?
Au6 Au4 Sb2 97.490(15) . 2_565 ?
P5 Au5 Au4 156.09(6) . . ?
P5 Au5 Au6 129.70(5) . . ?
Au4 Au5 Au6 61.994(12) . . ?
P5 Au5 Au6 142.97(6) . 2_565 ?
Au4 Au5 Au6 60.170(12) . 2_565 ?
Au6 Au5 Au6 57.343(13) . 2_565 ?
P5 Au5 Sb2 74.51(5) . . ?
Au4 Au5 Sb2 119.613(16) . . ?
Au6 Au5 Sb2 57.762(13) . . ?
Au6 Au5 Sb2 89.792(14) 2_565 . ?
P6 Au6 Au6 172.33(6) . 2_565 ?
P6 Au6 Au5 125.17(6) . . ?
Au6 Au6 Au5 62.468(14) 2_565 . ?
P6 Au6 Au4 113.99(6) . 2_565 ?
Au6 Au6 Au4 62.211(14) 2_565 2_565 ?
Au5 Au6 Au4 95.138(15) . 2_565 ?
P6 Au6 Au4 122.78(6) . . ?
Au6 Au6 Au4 60.583(13) 2_565 . ?
Au5 Au6 Au4 58.168(11) . . ?
Au4 Au6 Au4 122.795(13) 2_565 . ?
P6 Au6 Au5 112.16(6) . 2_565 ?
Au6 Au6 Au5 60.190(13) 2_565 2_565 ?
Au5 Au6 Au5 122.658(13) . 2_565 ?
Au4 Au6 Au5 57.977(12) 2_565 2_565 ?
Au4 Au6 Au5 92.852(13) . 2_565 ?
P6 Au6 Sb2 82.36(6) . . ?
Au6 Au6 Sb2 100.70(2) 2_565 . ?
Au5 Au6 Sb2 71.154(14) . . ?
Au4 Au6 Sb2 62.477(14) 2_565 . ?
Au4 Au6 Sb2 129.150(16) . . ?
Au5 Au6 Sb2 119.493(17) 2_565 . ?
C72 Sb2 C91 96.4(3) . . ?
C72 Sb2 C90 101.4(3) . . ?
C91 Sb2 C90 98.4(3) . . ?
C72 Sb2 Au6 147.4(2) . . ?
C91 Sb2 Au6 88.0(2) . . ?
C90 Sb2 Au6 109.9(2) . . ?
C72 Sb2 Au4 92.4(2) . 2_565 ?
C91 Sb2 Au4 92.6(2) . 2_565 ?
C90 Sb2 Au4 161.2(2) . 2_565 ?
Au6 Sb2 Au4 55.081(13) . 2_565 ?
C72 Sb2 Au5 128.3(2) . . ?
C91 Sb2 Au5 134.6(2) . . ?
C90 Sb2 Au5 81.7(2) . . ?
Au6 Sb2 Au5 51.085(11) . . ?
Au4 Sb2 Au5 79.745(15) 2_565 . ?
C55' P4 C61' 106.5(10) . . ?
C55 P4 C61 110.3(5) . . ?
C55 P4 C67 103.3(5) . . ?
C55' P4 C67 106.3(8) . . ?
C61' P4 C67 107.3(12) . . ?
C61 P4 C67 104.7(5) . . ?
C55 P4 Au4 111.9(6) . . ?
C55' P4 Au4 107.6(11) . . ?
C61' P4 Au4 111.8(12) . . ?
C61 P4 Au4 109.6(4) . . ?
C67 P4 Au4 116.7(3) . . ?
C60 C55 C56 120.1(10) . . ?
C60 C55 P4 120.8(11) . . ?
C56 C55 P4 118.9(11) . . ?
C57 C56 C55 117.4(12) . . ?
C57 C56 H56 121.3 . . ?
C55 C56 H56 121.3 . . ?
C56 C57 C58 121.8(12) . . ?
C56 C57 H57 119.1 . . ?
C58 C57 H57 119.1 . . ?
C59 C58 C57 119.4(12) . . ?
C59 C58 H58 120.3 . . ?
C57 C58 H58 120.3 . . ?
C58 C59 C60 119.6(14) . . ?
C58 C59 H59 120.2 . . ?
C60 C59 H59 120.2 . . ?
C55 C60 C59 121.8(13) . . ?
C55 C60 H60 119.1 . . ?
C59 C60 H60 119.1 . . ?
C60' C55' C56' 114.0(15) . . ?
C60' C55' P4 117.8(19) . . ?
C56' C55' P4 128(2) . . ?
C57' C56' C55' 122.4(19) . . ?
C57' C56' H56' 118.8 . . ?
C55' C56' H56' 118.8 . . ?
C56' C57' C58' 121(2) . . ?
C56' C57' H57' 119.4 . . ?
C58' C57' H57' 119.4 . . ?
C59' C58' C57' 117.1(19) . . ?
C59' C58' H58' 121.5 . . ?
C57' C58' H58' 121.5 . . ?
C58' C59' C60' 121(2) . . ?
C58' C59' H59' 119.4 . . ?
C60' C59' H59' 119.4 . . ?
C55' C60' C59' 124.1(19) . . ?
C55' C60' H60' 117.9 . . ?
C59' C60' H60' 117.9 . . ?
C66 C61 C62 118.1(10) . . ?
C66 C61 P4 115.7(9) . . ?
C62 C61 P4 126.2(9) . . ?
C63 C62 C61 120.4(11) . . ?
C63 C62 H62 119.8 . . ?
C61 C62 H62 119.8 . . ?
C64 C63 C62 121.6(13) . . ?
C64 C63 H63 119.2 . . ?
C62 C63 H63 119.2 . . ?
C63 C64 C65 120.3(13) . . ?
C63 C64 H64 119.9 . . ?
C65 C64 H64 119.9 . . ?
C64 C65 C66 119.1(13) . . ?
C64 C65 H65 120.5 . . ?
C66 C65 H65 120.5 . . ?
C61 C66 C65 120.6(12) . . ?
C61 C66 H66 119.7 . . ?
C65 C66 H66 119.7 . . ?
C66' C61' C62' 119.9(18) . . ?
C66' C61' P4 123(2) . . ?
C62' C61' P4 117(2) . . ?
C63' C62' C61' 119.0(19) . . ?
C63' C62' H62' 120.5 . . ?
C61' C62' H62' 120.5 . . ?
C64' C63' C62' 121(2) . . ?
C64' C63' H63' 119.6 . . ?
C62' C63' H63' 119.6 . . ?
C63' C64' C65' 123(2) . . ?
C63' C64' H64' 118.7 . . ?
C65' C64' H64' 118.7 . . ?
C64' C65' C66' 117(2) . . ?
C64' C65' H65' 121.4 . . ?
C66' C65' H65' 121.4 . . ?
C61' C66' C65' 120(2) . . ?
C61' C66' H66' 119.8 . . ?
C65' C66' H66' 119.8 . . ?
C68 C67 C72 119.6(7) . 2_565 ?
C68 C67 P4 119.5(6) . . ?
C72 C67 P4 120.7(6) 2_565 . ?
C67 C68 C69 121.3(8) . . ?
C67 C68 H68 119.4 . . ?
C69 C68 H68 119.4 . . ?
C70 C69 C68 119.3(9) . . ?
C70 C69 H69 120.4 . . ?
C68 C69 H69 120.4 . . ?
C69 C70 C71 120.1(8) . 2_565 ?
C69 C70 H70 119.9 . . ?
C71 C70 H70 119.9 2_565 . ?
C72 C71 C70 121.4(8) . 2_565 ?
C72 C71 H71 119.3 . . ?
C70 C71 H71 119.3 2_565 . ?
C71 C72 C67 118.4(8) . 2_565 ?
C71 C72 Sb2 119.5(6) . . ?
C67 C72 Sb2 121.9(6) 2_565 . ?
C73' P5 C79 105.2(7) . . ?
C73 P5 C79 104.7(8) . . ?
C73' P5 C85 109.6(8) . . ?
C73 P5 C85 113.2(10) . . ?
C79 P5 C85 103.7(4) . . ?
C73' P5 Au5 114.9(9) . . ?
C73 P5 Au5 112.2(11) . . ?
C79 P5 Au5 116.0(3) . . ?
C85 P5 Au5 106.9(3) . . ?
C78 C73 C74 117.4(14) . . ?
C78 C73 P5 127.5(19) . . ?
C74 C73 P5 115.1(18) . . ?
C75 C74 C73 119.6(15) . . ?
C75 C74 H74 120.2 . . ?
C73 C74 H74 120.2 . . ?
C76 C75 C74 121.3(16) . . ?
C76 C75 H75 119.4 . . ?
C74 C75 H75 119.4 . . ?
C77 C76 C75 119.5(16) . . ?
C77 C76 H76 120.2 . . ?
C75 C76 H76 120.2 . . ?
C76 C77 C78 120.1(17) . . ?
C76 C77 H77 119.9 . . ?
C78 C77 H77 119.9 . . ?
C73 C78 C77 122.1(16) . . ?
C73 C78 H78 119.0 . . ?
C77 C78 H78 119.0 . . ?
C78' C73' C74' 118.7(12) . . ?
C78' C73' P5 124.7(16) . . ?
C74' C73' P5 116.5(15) . . ?
C75' C74' C73' 119.7(14) . . ?
C75' C74' H74' 120.2 . . ?
C73' C74' H74' 120.2 . . ?
C76' C75' C74' 120.4(14) . . ?
C76' C75' H75' 119.8 . . ?
C74' C75' H75' 119.8 . . ?
C77' C76' C75' 119.9(14) . . ?
C77' C76' H76' 120.0 . . ?
C75' C76' H76' 120.0 . . ?
C76' C77' C78' 120.8(15) . . ?
C76' C77' H77' 119.6 . . ?
C78' C77' H77' 119.6 . . ?
C73' C78' C77' 120.4(14) . . ?
C73' C78' H78' 119.8 . . ?
C77' C78' H78' 119.8 . . ?
C84 C79 C80 119.4(9) . . ?
C84 C79 P5 121.0(7) . . ?
C80 C79 P5 119.6(7) . . ?
C81 C80 C79 120.2(9) . . ?
C81 C80 H80 119.9 . . ?
C79 C80 H80 119.9 . . ?
C82 C81 C80 119.9(11) . . ?
C82 C81 H81 120.1 . . ?
C80 C81 H81 120.1 . . ?
C83 C82 C81 120.8(11) . . ?
C83 C82 H82 119.6 . . ?
C81 C82 H82 119.6 . . ?
C82 C83 C84 121.0(11) . . ?
C82 C83 H83 119.5 . . ?
C84 C83 H83 119.5 . . ?
C83 C84 C79 118.7(10) . . ?
C83 C84 H84 120.7 . . ?
C79 C84 H84 120.7 . . ?
C86 C85 C90 118.2(8) . . ?
C86 C85 P5 120.8(7) . . ?
C90 C85 P5 120.9(7) . . ?
C87 C86 C85 120.8(9) . . ?
C87 C86 H86 119.6 . . ?
C85 C86 H86 119.6 . . ?
C88 C87 C86 121.1(9) . . ?
C88 C87 H87 119.4 . . ?
C86 C87 H87 119.4 . . ?
C87 C88 C89 119.2(9) . . ?
C87 C88 H88 120.4 . . ?
C89 C88 H88 120.4 . . ?
C90 C89 C88 121.4(8) . . ?
C90 C89 H89 119.3 . . ?
C88 C89 H89 119.3 . . ?
C89 C90 C85 119.2(8) . . ?
C89 C90 Sb2 118.5(6) . . ?
C85 C90 Sb2 120.8(6) . . ?
C13C P6 C97C 108.3(16) . . ?
C103 P6 C97 103.0(10) . . ?
C13C P6 C96 104.5(8) . . ?
C103 P6 C96 109.6(8) . . ?
C97C P6 C96 102.6(11) . . ?
C97 P6 C96 103.4(5) . . ?
C13C P6 Au6 111.3(7) . . ?
C103 P6 Au6 113.1(7) . . ?
C97C P6 Au6 118.4(10) . . ?
C97 P6 Au6 116.5(4) . . ?
C96 P6 Au6 110.6(3) . . ?
C96 C91 C92 118.1(8) . . ?
C96 C91 Sb2 122.9(6) . . ?
C92 C91 Sb2 118.9(7) . . ?
C93 C92 C91 121.2(9) . . ?
C93 C92 H92 119.4 . . ?
C91 C92 H92 119.4 . . ?
C94 C93 C92 120.3(8) . . ?
C94 C93 H93 119.9 . . ?
C92 C93 H93 119.9 . . ?
C95 C94 C93 119.6(8) . . ?
C95 C94 H94 120.2 . . ?
C93 C94 H94 120.2 . . ?
C94 C95 C96 121.1(9) . . ?
C94 C95 H95 119.5 . . ?
C96 C95 H95 119.5 . . ?
C91 C96 C95 119.8(8) . . ?
C91 C96 P6 120.5(6) . . ?
C95 C96 P6 119.7(7) . . ?
C98 C97 C102 118.1(10) . . ?
C98 C97 P6 120.3(9) . . ?
C102 C97 P6 121.4(9) . . ?
C99 C98 C97 119.8(10) . . ?
C99 C98 H98 120.1 . . ?
C97 C98 H98 120.1 . . ?
C100 C99 C98 121.3(11) . . ?
C100 C99 H99 119.3 . . ?
C98 C99 H99 119.3 . . ?
C99 C100 C101 119.9(11) . . ?
C99 C100 H100 120.1 . . ?
C101 C100 H100 120.1 . . ?
C100 C101 C102 120.6(11) . . ?
C100 C101 H101 119.7 . . ?
C102 C101 H101 119.7 . . ?
C101 C102 C97 120.2(11) . . ?
C101 C102 H102 119.9 . . ?
C97 C102 H102 119.9 . . ?
C98C C97C C12C 121.4(17) . . ?
C98C C97C P6 123.2(19) . . ?
C12C C97C P6 115(2) . . ?
C99C C98C C97C 118.6(17) . . ?
C99C C98C H98C 120.7 . . ?
C97C C98C H98C 120.7 . . ?
C10C C99C C98C 120(2) . . ?
C10C C99C H99C 120.0 . . ?
C98C C99C H99C 120.0 . . ?
C99C C10C C11C 122(2) . . ?
C99C C10C H10C 118.9 . . ?
C11C C10C H10C 118.9 . . ?
C10C C11C C12C 120(2) . . ?
C10C C11C H11C 120.2 . . ?
C12C C11C H11C 120.2 . . ?
C11C C12C C97C 118(2) . . ?
C11C C12C H12C 120.9 . . ?
C97C C12C H12C 120.9 . . ?
C104 C103 C108 119.7(13) . . ?
C104 C103 P6 121.6(17) . . ?
C108 C103 P6 118.4(17) . . ?
C105 C104 C103 119.6(16) . . ?
C105 C104 H104 120.2 . . ?
C103 C104 H104 120.2 . . ?
C106 C105 C104 120.0(17) . . ?
C106 C105 H105 120.0 . . ?
C104 C105 H105 120.0 . . ?
C107 C106 C105 122.7(16) . . ?
C107 C106 H106 118.7 . . ?
C105 C106 H106 118.7 . . ?
C106 C107 C108 117.7(17) . . ?
C106 C107 H107 121.1 . . ?
C108 C107 H107 121.1 . . ?
C103 C108 C107 120.3(17) . . ?
C103 C108 H108 119.8 . . ?
C107 C108 H108 119.8 . . ?
C14C C13C C18C 120.5(14) . . ?
C14C C13C P6 122.9(18) . . ?
C18C C13C P6 116.5(17) . . ?
C15C C14C C13C 121.0(17) . . ?
C15C C14C H14C 119.5 . . ?
C13C C14C H14C 119.5 . . ?
C16C C15C C14C 117.9(18) . . ?
C16C C15C H15C 121.0 . . ?
C14C C15C H15C 121.0 . . ?
C15C C16C C17C 123.7(16) . . ?
C15C C16C H16C 118.1 . . ?
C17C C16C H16C 118.1 . . ?
C16C C17C C18C 118.6(18) . . ?
C16C C17C H17C 120.7 . . ?
C18C C17C H17C 120.7 . . ?
C17C C18C C13C 118.3(17) . . ?
C17C C18C H18C 120.9 . . ?
C13C C18C H18C 120.9 . . ?
F3 P7 F1 173.6(7) . . ?
F3 P7 F6 88.5(6) . . ?
F1 P7 F6 95.1(7) . . ?
F3 P7 F2 93.2(6) . . ?
F1 P7 F2 92.0(6) . . ?
F6 P7 F2 89.8(6) . . ?
F3 P7 F5 88.5(6) . . ?
F1 P7 F5 87.8(7) . . ?
F6 P7 F5 176.9(7) . . ?
F2 P7 F5 91.2(6) . . ?
F3 P7 F4 89.9(5) . . ?
F1 P7 F4 85.1(6) . . ?
F6 P7 F4 87.4(5) . . ?
F2 P7 F4 175.8(6) . . ?
F5 P7 F4 91.8(5) . . ?
F3' P7' F6' 87.6(18) . . ?
F3' P7' F2' 92.9(19) . . ?
F6' P7' F2' 92.6(19) . . ?
F3' P7' F1' 176(2) . . ?
F6' P7' F1' 96(2) . . ?
F2' P7' F1' 89.1(18) . . ?
F3' P7' F5' 89.2(19) . . ?
F6' P7' F5' 176(2) . . ?
F2' P7' F5' 90.0(19) . . ?
F1' P7' F5' 87.2(18) . . ?
F3' P7' F4' 92.6(18) . . ?
F6' P7' F4' 88.0(18) . . ?
F2' P7' F4' 175(2) . . ?
F1' P7' F4' 85.4(18) . . ?
F5' P7' F4' 89.7(18) . . ?
F12 P8 F7 90.4(6) . . ?
F12 P8 F9 93.7(5) . . ?
F7 P8 F9 175.3(7) . . ?
F12 P8 F11 176.3(7) . . ?
F7 P8 F11 87.0(6) . . ?
F9 P8 F11 88.8(5) . . ?
F12 P8 F10 87.1(6) . . ?
F7 P8 F10 87.9(6) . . ?
F9 P8 F10 90.2(6) . . ?
F11 P8 F10 90.2(6) . . ?
F12 P8 F8 91.0(6) . . ?
F7 P8 F8 91.8(7) . . ?
F9 P8 F8 90.2(6) . . ?
F11 P8 F8 91.7(7) . . ?
F10 P8 F8 178.0(7) . . ?
F7' P8' F9' 176(2) . . ?
F7' P8' F11' 84.8(17) . . ?
F9' P8' F11' 92.1(16) . . ?
F7' P8' F12' 84.5(16) . . ?
F9' P8' F12' 98.8(17) . . ?
F11' P8' F12' 168.4(19) . . ?
F7' P8' F8' 92.7(17) . . ?
F9' P8' F8' 85.6(16) . . ?
F11' P8' F8' 94.6(18) . . ?
F12' P8' F8' 90.2(17) . . ?
F7' P8' F10' 92.1(17) . . ?
F9' P8' F10' 89.9(17) . . ?
F11' P8' F10' 91.9(18) . . ?
F12' P8' F10' 84.1(17) . . ?
F8' P8' F10' 172(2) . . ?
Cl1 C1S Cl2 116.3(10) . . ?
Cl1 C1S H1S1 108.2 . . ?
Cl2 C1S H1S1 108.2 . . ?
Cl1 C1S H1S2 108.2 . . ?
Cl2 C1S H1S2 108.2 . . ?
H1S1 C1S H1S2 107.4 . . ?
Cl3 C2S Cl4 122.4(12) . . ?
Cl3 C2S H2S1 106.7 . . ?
Cl4 C2S H2S1 106.7 . . ?
Cl3 C2S H2S2 106.7 . . ?
Cl4 C2S H2S2 106.7 . . ?
H2S1 C2S H2S2 106.6 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C13 P1 C1 C2 -121.2(8) . . . . ?
C7 P1 C1 C2 124.3(7) . . . . ?
Au1 P1 C1 C2 4.1(8) . . . . ?
C13 P1 C1 C6 64.6(8) . . . . ?
C7 P1 C1 C6 -49.8(8) . . . . ?
Au1 P1 C1 C6 -170.1(6) . . . . ?
C6 C1 C2 C3 0.2(14) . . . . ?
P1 C1 C2 C3 -174.2(8) . . . . ?
C1 C2 C3 C4 -0.6(15) . . . . ?
C2 C3 C4 C5 0.4(16) . . . . ?
C3 C4 C5 C6 0.1(16) . . . . ?
C4 C5 C6 C1 -0.5(14) . . . . ?
C2 C1 C6 C5 0.3(13) . . . . ?
P1 C1 C6 C5 174.6(7) . . . . ?
C13 P1 C7 C12 -11.9(8) . . . . ?
C1 P1 C7 C12 100.2(7) . . . . ?
Au1 P1 C7 C12 -134.1(6) . . . . ?
C13 P1 C7 C8 171.9(6) . . . . ?
C1 P1 C7 C8 -75.9(7) . . . . ?
Au1 P1 C7 C8 49.8(7) . . . . ?
C12 C7 C8 C9 -1.2(12) . . . . ?
P1 C7 C8 C9 174.9(6) . . . . ?
C12 C7 C8 Sb1 176.2(6) . . . 2_556 ?
P1 C7 C8 Sb1 -7.6(9) . . . 2_556 ?
C7 C8 C9 C10 0.9(12) . . . . ?
Sb1 C8 C9 C10 -176.7(6) 2_556 . . . ?
C8 C9 C10 C11 0.5(13) . . . . ?
C9 C10 C11 C12 -1.4(14) . . . . ?
C8 C7 C12 C11 0.3(13) . . . . ?
P1 C7 C12 C11 -175.8(7) . . . . ?
C10 C11 C12 C7 1.1(13) . . . . ?
C1 P1 C13 C18 22.3(9) . . . . ?
C7 P1 C13 C18 130.2(8) . . . . ?
Au1 P1 C13 C18 -107.6(8) . . . . ?
C1 P1 C13 C14 -170.2(8) . . . . ?
C7 P1 C13 C14 -62.3(9) . . . . ?
Au1 P1 C13 C14 59.8(8) . . . . ?
C18 C13 C14 C15 -0.6(16) . . . . ?
P1 C13 C14 C15 -168.2(9) . . . . ?
C13 C14 C15 C16 -0.2(18) . . . . ?
C14 C15 C16 C17 2(2) . . . . ?
C15 C16 C17 C18 -3(2) . . . . ?
C14 C13 C18 C17 -0.4(17) . . . . ?
P1 C13 C18 C17 166.9(10) . . . . ?
C16 C17 C18 C13 2(2) . . . . ?
C25' P2 C19 C24 -158.8(11) . . . . ?
C25 P2 C19 C24 -155.4(9) . . . . ?
C31 P2 C19 C24 92.1(8) . . . . ?
Au2 P2 C19 C24 -30.1(8) . . . . ?
C25' P2 C19 C20 24.1(12) . . . . ?
C25 P2 C19 C20 27.5(10) . . . . ?
C31 P2 C19 C20 -85.0(8) . . . . ?
Au2 P2 C19 C20 152.8(7) . . . . ?
C24 C19 C20 C21 0.0(14) . . . . ?
P2 C19 C20 C21 177.1(8) . . . . ?
C19 C20 C21 C22 0.5(16) . . . . ?
C20 C21 C22 C23 -0.8(16) . . . . ?
C21 C22 C23 C24 0.6(16) . . . . ?
C20 C19 C24 C23 -0.3(15) . . . . ?
P2 C19 C24 C23 -177.5(8) . . . . ?
C22 C23 C24 C19 0.0(16) . . . . ?
C19 P2 C25 C30 88.4(7) . . . . ?
C31 P2 C25 C30 -159.9(6) . . . . ?
Au2 P2 C25 C30 -41.5(7) . . . . ?
C19 P2 C25 C26 -96.5(8) . . . . ?
C31 P2 C25 C26 15.2(8) . . . . ?
Au2 P2 C25 C26 133.6(7) . . . . ?
C30 C25 C26 C27 -0.01(15) . . . . ?
P2 C25 C26 C27 -175.1(8) . . . . ?
C25 C26 C27 C28 0.05(15) . . . . ?
C26 C27 C28 C29 -0.1(3) . . . . ?
C27 C28 C29 C30 0.2(4) . . . . ?
C26 C25 C30 C29 0.1(3) . . . . ?
P2 C25 C30 C29 175.5(8) . . . . ?
C28 C29 C30 C25 -0.1(5) . . . . ?
C19 P2 C25' C30' 107.2(11) . . . . ?
C31 P2 C25' C30' -142.5(12) . . . . ?
Au2 P2 C25' C30' -24.2(14) . . . . ?
C19 P2 C25' C26' -77.7(12) . . . . ?
C31 P2 C25' C26' 32.6(13) . . . . ?
Au2 P2 C25' C26' 150.8(10) . . . . ?
C30' C25' C26' C27' 0.00(15) . . . . ?
P2 C25' C26' C27' -175.2(15) . . . . ?
C25' C26' C27' C28' 0.01(15) . . . . ?
C26' C27' C28' C29' 0.0(3) . . . . ?
C27' C28' C29' C30' 0.0(5) . . . . ?
C26' C25' C30' C29' 0.0(3) . . . . ?
P2 C25' C30' C29' 175.1(15) . . . . ?
C28' C29' C30' C25' 0.0(5) . . . . ?
C25' P2 C31 C36 85.1(9) . . . . ?
C25 P2 C31 C36 83.1(8) . . . . ?
C19 P2 C31 C36 -164.6(7) . . . . ?
Au2 P2 C31 C36 -36.4(7) . . . . ?
C25' P2 C31 C32 -96.2(9) . . . . ?
C25 P2 C31 C32 -98.2(8) . . . . ?
C19 P2 C31 C32 14.1(8) . . . . ?
Au2 P2 C31 C32 142.3(6) . . . . ?
C36 C31 C32 C33 1.3(13) . . . . ?
P2 C31 C32 C33 -177.4(7) . . . . ?
C31 C32 C33 C34 0.8(14) . . . . ?
C32 C33 C34 C35 -2.3(14) . . . . ?
C33 C34 C35 C36 1.8(13) . . . . ?
C34 C35 C36 C31 0.4(12) . . . . ?
C34 C35 C36 Sb1 177.6(6) . . . . ?
C32 C31 C36 C35 -1.9(12) . . . . ?
P2 C31 C36 C35 176.9(6) . . . . ?
C32 C31 C36 Sb1 -179.1(6) . . . . ?
P2 C31 C36 Sb1 -0.4(9) . . . . ?
C42 C37 C38 C39 -0.5(12) . . . . ?
Sb1 C37 C38 C39 171.8(6) . . . . ?
C37 C38 C39 C40 -0.4(13) . . . . ?
C38 C39 C40 C41 0.2(13) . . . . ?
C39 C40 C41 C42 0.8(13) . . . . ?
C40 C41 C42 C37 -1.7(12) . . . . ?
C40 C41 C42 P3 -178.7(7) . . . . ?
C38 C37 C42 C41 1.5(11) . . . . ?
Sb1 C37 C42 C41 -170.2(6) . . . . ?
C38 C37 C42 P3 178.4(6) . . . . ?
Sb1 C37 C42 P3 6.6(10) . . . . ?
C43 P3 C42 C41 -71.6(7) . . . . ?
C49 P3 C42 C41 42.0(7) . . . . ?
Au3 P3 C42 C41 161.9(5) . . . . ?
C43 P3 C42 C37 111.5(7) . . . . ?
C49 P3 C42 C37 -134.9(7) . . . . ?
Au3 P3 C42 C37 -15.0(7) . . . . ?
C49 P3 C43 C44 93.9(7) . . . . ?
C42 P3 C43 C44 -156.9(7) . . . . ?
Au3 P3 C43 C44 -27.0(7) . . . . ?
C49 P3 C43 C48 -83.2(8) . . . . ?
C42 P3 C43 C48 26.0(8) . . . . ?
Au3 P3 C43 C48 155.9(7) . . . . ?
C48 C43 C44 C45 -2.0(14) . . . . ?
P3 C43 C44 C45 -179.4(8) . . . . ?
C43 C44 C45 C46 0.0(16) . . . . ?
C44 C45 C46 C47 2.0(17) . . . . ?
C45 C46 C47 C48 -1.9(16) . . . . ?
C46 C47 C48 C43 -0.2(15) . . . . ?
C44 C43 C48 C47 2.1(14) . . . . ?
P3 C43 C48 C47 179.3(7) . . . . ?
C43 P3 C49 C50 -172.8(7) . . . . ?
C42 P3 C49 C50 73.7(8) . . . . ?
Au3 P3 C49 C50 -51.2(8) . . . . ?
C43 P3 C49 C54 10.0(9) . . . . ?
C42 P3 C49 C54 -103.5(8) . . . . ?
Au3 P3 C49 C54 131.6(7) . . . . ?
C54 C49 C50 C51 1.1(15) . . . . ?
P3 C49 C50 C51 -176.1(8) . . . . ?
C49 C50 C51 C52 0.4(15) . . . . ?
C50 C51 C52 C53 -1.9(17) . . . . ?
C51 C52 C53 C54 1.9(18) . . . . ?
C50 C49 C54 C53 -1.1(15) . . . . ?
P3 C49 C54 C53 176.0(8) . . . . ?
C52 C53 C54 C49 -0.4(17) . . . . ?
C61 P4 C55 C60 -116.7(6) . . . . ?
C67 P4 C55 C60 131.9(5) . . . . ?
Au4 P4 C55 C60 5.5(5) . . . . ?
C61 P4 C55 C56 67.4(6) . . . . ?
C67 P4 C55 C56 -44.0(5) . . . . ?
Au4 P4 C55 C56 -170.4(3) . . . . ?
C60 C55 C56 C57 0.00(11) . . . . ?
P4 C55 C56 C57 176.0(5) . . . . ?
C55 C56 C57 C58 0.00(10) . . . . ?
C56 C57 C58 C59 0.0(2) . . . . ?
C57 C58 C59 C60 0.0(3) . . . . ?
C56 C55 C60 C59 0.0(2) . . . . ?
P4 C55 C60 C59 -175.9(5) . . . . ?
C58 C59 C60 C55 0.0(3) . . . . ?
C61' P4 C55' C60' -114.2(14) . . . . ?
C67 P4 C55' C60' 131.6(5) . . . . ?
Au4 P4 C55' C60' 5.9(5) . . . . ?
C61' P4 C55' C56' 70.4(14) . . . . ?
C67 P4 C55' C56' -43.8(7) . . . . ?
Au4 P4 C55' C56' -169.5(5) . . . . ?
C60' C55' C56' C57' 0.0(4) . . . . ?
P4 C55' C56' C57' 175.5(6) . . . . ?
C55' C56' C57' C58' 0.0(5) . . . . ?
C56' C57' C58' C59' 0.0(5) . . . . ?
C57' C58' C59' C60' 0.0(5) . . . . ?
C56' C55' C60' C59' 0.0(5) . . . . ?
P4 C55' C60' C59' -176.0(5) . . . . ?
C58' C59' C60' C55' 0.0(5) . . . . ?
C55 P4 C61 C66 158.7(8) . . . . ?
C67 P4 C61 C66 -90.8(6) . . . . ?
Au4 P4 C61 C66 35.1(6) . . . . ?
C55 P4 C61 C62 -20.1(11) . . . . ?
C67 P4 C61 C62 90.4(8) . . . . ?
Au4 P4 C61 C62 -143.7(6) . . . . ?
C66 C61 C62 C63 0.04(15) . . . . ?
P4 C61 C62 C63 178.8(10) . . . . ?
C61 C62 C63 C64 -0.02(16) . . . . ?
C62 C63 C64 C65 0.1(3) . . . . ?
C63 C64 C65 C66 -0.1(4) . . . . ?
C62 C61 C66 C65 -0.1(3) . . . . ?
P4 C61 C66 C65 -179.0(9) . . . . ?
C64 C65 C66 C61 0.2(4) . . . . ?
C55' P4 C61' C66' 154.3(18) . . . . ?
C67 P4 C61' C66' -92.2(18) . . . . ?
Au4 P4 C61' C66' 37.0(19) . . . . ?
C55' P4 C61' C62' -30(2) . . . . ?
C67 P4 C61' C62' 83.4(18) . . . . ?
Au4 P4 C61' C62' -147.3(15) . . . . ?
C66' C61' C62' C63' 0.01(15) . . . . ?
P4 C61' C62' C63' -176(3) . . . . ?
C61' C62' C63' C64' 0.00(16) . . . . ?
C62' C63' C64' C65' 0.0(4) . . . . ?
C63' C64' C65' C66' 0.0(5) . . . . ?
C62' C61' C66' C65' 0.0(3) . . . . ?
P4 C61' C66' C65' 175(3) . . . . ?
C64' C65' C66' C61' 0.0(4) . . . . ?
C55 P4 C67 C68 77.7(8) . . . . ?
C55' P4 C67 C68 81.0(11) . . . . ?
C61' P4 C67 C68 -32.7(12) . . . . ?
C61 P4 C67 C68 -37.8(8) . . . . ?
Au4 P4 C67 C68 -159.0(6) . . . . ?
C55 P4 C67 C72 -96.4(8) . . . 2_565 ?
C55' P4 C67 C72 -93.2(10) . . . 2_565 ?
C61' P4 C67 C72 153.2(11) . . . 2_565 ?
C61 P4 C67 C72 148.1(7) . . . 2_565 ?
Au4 P4 C67 C72 26.8(7) . . . 2_565 ?
C72 C67 C68 C69 -1.9(13) 2_565 . . . ?
P4 C67 C68 C69 -176.1(7) . . . . ?
C67 C68 C69 C70 2.4(14) . . . . ?
C68 C69 C70 C71 -1.9(14) . . . 2_565 ?
C70 C71 C72 C67 0.4(13) 2_565 . . 2_565 ?
C70 C71 C72 Sb2 175.5(7) 2_565 . . . ?
C79 P5 C73 C78 72.7(11) . . . . ?
C85 P5 C73 C78 -39.5(13) . . . . ?
Au5 P5 C73 C78 -160.6(10) . . . . ?
C79 P5 C73 C74 -103.7(12) . . . . ?
C85 P5 C73 C74 144.0(11) . . . . ?
Au5 P5 C73 C74 23.0(14) . . . . ?
C78 C73 C74 C75 0.04(14) . . . . ?
P5 C73 C74 C75 176.9(14) . . . . ?
C73 C74 C75 C76 0.01(15) . . . . ?
C74 C75 C76 C77 0.0(3) . . . . ?
C75 C76 C77 C78 0.0(4) . . . . ?
C74 C73 C78 C77 -0.1(3) . . . . ?
P5 C73 C78 C77 -176.5(16) . . . . ?
C76 C77 C78 C73 0.1(4) . . . . ?
C79 P5 C73' C78' 60.2(10) . . . . ?
C85 P5 C73' C78' -50.6(10) . . . . ?
Au5 P5 C73' C78' -170.9(8) . . . . ?
C79 P5 C73' C74' -118.0(10) . . . . ?
C85 P5 C73' C74' 131.1(10) . . . . ?
Au5 P5 C73' C74' 10.8(12) . . . . ?
C78' C73' C74' C75' 0.07(15) . . . . ?
P5 C73' C74' C75' 178.4(12) . . . . ?
C73' C74' C75' C76' 0.03(15) . . . . ?
C74' C75' C76' C77' 0.0(3) . . . . ?
C75' C76' C77' C78' 0.0(4) . . . . ?
C74' C73' C78' C77' -0.2(3) . . . . ?
P5 C73' C78' C77' -178.4(13) . . . . ?
C76' C77' C78' C73' 0.1(4) . . . . ?
C73' P5 C79 C84 -63.3(12) . . . . ?
C73 P5 C79 C84 -67.2(13) . . . . ?
C85 P5 C79 C84 51.7(8) . . . . ?
Au5 P5 C79 C84 168.5(6) . . . . ?
C73' P5 C79 C80 116.8(11) . . . . ?
C73 P5 C79 C80 113.0(13) . . . . ?
C85 P5 C79 C80 -128.2(7) . . . . ?
Au5 P5 C79 C80 -11.4(8) . . . . ?
C84 C79 C80 C81 0.2(13) . . . . ?
P5 C79 C80 C81 -179.9(7) . . . . ?
C79 C80 C81 C82 1.5(15) . . . . ?
C80 C81 C82 C83 -1.3(17) . . . . ?
C81 C82 C83 C84 -0.7(17) . . . . ?
C82 C83 C84 C79 2.5(15) . . . . ?
C80 C79 C84 C83 -2.2(14) . . . . ?
P5 C79 C84 C83 177.9(7) . . . . ?
C73' P5 C85 C86 -9.3(11) . . . . ?
C73 P5 C85 C86 -8.3(13) . . . . ?
C79 P5 C85 C86 -121.2(8) . . . . ?
Au5 P5 C85 C86 115.8(7) . . . . ?
C73' P5 C85 C90 176.0(10) . . . . ?
C73 P5 C85 C90 177.0(11) . . . . ?
C79 P5 C85 C90 64.1(8) . . . . ?
Au5 P5 C85 C90 -58.9(7) . . . . ?
C90 C85 C86 C87 -3.2(14) . . . . ?
P5 C85 C86 C87 -178.1(8) . . . . ?
C85 C86 C87 C88 0.8(16) . . . . ?
C86 C87 C88 C89 2.5(17) . . . . ?
C87 C88 C89 C90 -3.4(16) . . . . ?
C88 C89 C90 C85 1.1(14) . . . . ?
C88 C89 C90 Sb2 167.5(8) . . . . ?
C86 C85 C90 C89 2.2(13) . . . . ?
P5 C85 C90 C89 177.1(7) . . . . ?
C86 C85 C90 Sb2 -163.9(7) . . . . ?
P5 C85 C90 Sb2 11.0(10) . . . . ?
C96 C91 C92 C93 -1.0(12) . . . . ?
Sb2 C91 C92 C93 174.0(6) . . . . ?
C91 C92 C93 C94 1.5(13) . . . . ?
C92 C93 C94 C95 0.1(13) . . . . ?
C93 C94 C95 C96 -2.1(14) . . . . ?
C92 C91 C96 C95 -1.0(12) . . . . ?
Sb2 C91 C96 C95 -175.7(6) . . . . ?
C92 C91 C96 P6 -178.7(6) . . . . ?
Sb2 C91 C96 P6 6.5(10) . . . . ?
C94 C95 C96 C91 2.6(13) . . . . ?
C94 C95 C96 P6 -179.7(7) . . . . ?
C13C P6 C96 C91 -157.2(11) . . . . ?
C103 P6 C96 C91 -162.7(11) . . . . ?
C97C P6 C96 C91 89.9(14) . . . . ?
C97 P6 C96 C91 88.1(8) . . . . ?
Au6 P6 C96 C91 -37.3(7) . . . . ?
C13C P6 C96 C95 25.0(12) . . . . ?
C103 P6 C96 C95 19.6(12) . . . . ?
C97C P6 C96 C95 -87.9(14) . . . . ?
C97 P6 C96 C95 -89.7(8) . . . . ?
Au6 P6 C96 C95 144.9(6) . . . . ?
C103 P6 C97 C98 120.6(10) . . . . ?
C96 P6 C97 C98 -125.3(7) . . . . ?
Au6 P6 C97 C98 -3.8(9) . . . . ?
C103 P6 C97 C102 -64.5(9) . . . . ?
C96 P6 C97 C102 49.6(7) . . . . ?
Au6 P6 C97 C102 171.1(5) . . . . ?
C102 C97 C98 C99 0.01(14) . . . . ?
P6 C97 C98 C99 175.1(9) . . . . ?
C97 C98 C99 C100 -0.02(15) . . . . ?
C98 C99 C100 C101 0.1(3) . . . . ?
C99 C100 C101 C102 -0.1(4) . . . . ?
C100 C101 C102 C97 0.1(4) . . . . ?
C98 C97 C102 C101 0.0(3) . . . . ?
P6 C97 C102 C101 -175.1(9) . . . . ?
C13C P6 C97C C98C 111(2) . . . . ?
C96 P6 C97C C98C -139(2) . . . . ?
Au6 P6 C97C C98C -16(3) . . . . ?
C13C P6 C97C C12C -62.7(17) . . . . ?
C96 P6 C97C C12C 47.4(16) . . . . ?
Au6 P6 C97C C12C 169.4(13) . . . . ?
C12C C97C C98C C99C 0.00(15) . . . . ?
P6 C97C C98C C99C -174(3) . . . . ?
C97C C98C C99C C10C 0.00(15) . . . . ?
C98C C99C C10C C11C 0.0(3) . . . . ?
C99C C10C C11C C12C 0.0(5) . . . . ?
C10C C11C C12C C97C 0.0(4) . . . . ?
C98C C97C C12C C11C 0.0(3) . . . . ?
P6 C97C C12C C11C 174(3) . . . . ?
C97 P6 C103 C104 -17.8(12) . . . . ?
C96 P6 C103 C104 -127.3(9) . . . . ?
Au6 P6 C103 C104 108.8(10) . . . . ?
C97 P6 C103 C108 169.0(8) . . . . ?
C96 P6 C103 C108 59.4(9) . . . . ?
Au6 P6 C103 C108 -64.4(10) . . . . ?
C108 C103 C104 C105 -0.03(15) . . . . ?
P6 C103 C104 C105 -173.2(14) . . . . ?
C103 C104 C105 C106 -0.04(15) . . . . ?
C104 C105 C106 C107 0.1(4) . . . . ?
C105 C106 C107 C108 -0.1(5) . . . . ?
C104 C103 C108 C107 0.0(3) . . . . ?
P6 C103 C108 C107 173.4(13) . . . . ?
C106 C107 C108 C103 0.0(4) . . . . ?
C97C P6 C13C C14C -18.1(16) . . . . ?
C96 P6 C13C C14C -126.8(10) . . . . ?
Au6 P6 C13C C14C 113.8(11) . . . . ?
C97C P6 C13C C18C 166.2(12) . . . . ?
C96 P6 C13C C18C 57.5(9) . . . . ?
Au6 P6 C13C C18C -61.9(9) . . . . ?
C18C C13C C14C C15C -0.01(15) . . . . ?
P6 C13C C14C C15C -175.5(15) . . . . ?
C13C C14C C15C C16C -0.01(15) . . . . ?
C14C C15C C16C C17C 0.0(4) . . . . ?
C15C C16C C17C C18C 0.0(5) . . . . ?
C16C C17C C18C C13C 0.0(4) . . . . ?
C14C C13C C18C C17C 0.0(3) . . . . ?
P6 C13C C18C C17C 175.8(14) . . . . ?

_refine_diff_density_max         2.569
_refine_diff_density_min         -1.614
_refine_diff_density_rms         0.189




