# Electronic Supplementary Material (ESI) for Inorganic Chemistry Frontiers.
# This journal is © the Partner Organisations 2022

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_3
_database_code_depnum_ccdc_archive 'CCDC 2132950'
loop_
_audit_author_name
_audit_author_address
'Wenxiu Bao'
;Fujian Institute of Research on the Structure of Matter, Chinese Academy of Science
China
;
_audit_update_record             
;
2022-01-07 deposited with the CCDC.	2022-03-01 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C12 H8 Cl5 K N2 O4 Pb3'
_chemical_formula_weight         1082.12

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
K K 0.2009 0.2494 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pb Pb -3.3944 10.1111 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_H-M   'C m c 2 1 '

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, z+1/2'
'x, -y, z+1/2'
'-x, y, z'
'x+1/2, y+1/2, z'
'-x+1/2, -y+1/2, z+1/2'
'x+1/2, -y+1/2, z+1/2'
'-x+1/2, y+1/2, z'

_cell_length_a                   29.3437(10)
_cell_length_b                   8.9592(3)
_cell_length_c                   8.0146(3)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_volume                     2107.01(13)
_cell_formula_units_Z            4
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    10088
_cell_measurement_theta_min      2.0720
_cell_measurement_theta_max      35.8010

_exptl_crystal_description       tabular
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.3000
_exptl_crystal_size_mid          0.2000
_exptl_crystal_size_min          0.1000
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    3.411
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1904
_exptl_absorpt_coefficient_mu    24.765
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.07246
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  
'dtrek-CrysAlisPro-abstract goniometer imported rigaku-d*trek images'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            8482
_diffrn_reflns_av_R_equivalents  0.0300
_diffrn_reflns_av_sigmaI/netI    0.0229
_diffrn_reflns_limit_h_min       -38
_diffrn_reflns_limit_h_max       38
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_theta_min         2.38
_diffrn_reflns_theta_max         27.48
_reflns_number_total             2413
_reflns_number_gt                2345
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0492P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   -0.016(9)
_refine_ls_number_reflns         2413
_refine_ls_number_parameters     127
_refine_ls_number_restraints     7
_refine_ls_R_factor_all          0.0275
_refine_ls_R_factor_gt           0.0266
_refine_ls_wR_factor_ref         0.0675
_refine_ls_wR_factor_gt          0.0671
_refine_ls_goodness_of_fit_ref   1.059
_refine_ls_restrained_S_all      1.057
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pb1 Pb 0.5000 0.87047(4) 0.53666(5) 0.02410(10) Uani 1 2 d S . .
Pb2 Pb 0.377434(9) 0.06425(3) 0.37463(5) 0.02851(9) Uani 1 1 d U . .
K1 K 0.5000 0.4293(2) 0.6887(3) 0.0279(5) Uani 1 2 d S . .
Cl1 Cl 0.43807(7) -0.13244(19) 0.1845(3) 0.0319(4) Uani 1 1 d . . .
Cl2 Cl 0.31162(8) -0.0287(3) 0.1523(3) 0.0397(5) Uani 1 1 d . . .
Cl3 Cl 0.5000 0.7631(3) 0.8433(4) 0.0471(8) Uani 1 2 d S . .
O1 O 0.4032(2) 0.8109(6) 0.5688(7) 0.0314(12) Uani 1 1 d . . .
O2 O 0.45134(19) 0.6335(5) 0.4952(7) 0.0279(13) Uani 1 1 d . . .
N1 N 0.3477(2) 0.3361(7) 0.3887(9) 0.0308(14) Uani 1 1 d . . .
C1 C 0.3806(2) 0.4339(8) 0.4323(13) 0.0260(18) Uani 1 1 d . . .
H1 H 0.4104 0.3995 0.4414 0.031 Uiso 1 1 calc R . .
C2 C 0.3720(3) 0.5829(8) 0.4642(11) 0.0260(17) Uani 1 1 d . . .
C3 C 0.3276(3) 0.6326(8) 0.4505(13) 0.037(2) Uani 1 1 d . . .
H2 H 0.3207 0.7319 0.4728 0.045 Uiso 1 1 calc R . .
C4 C 0.2936(3) 0.5345(10) 0.4037(15) 0.049(3) Uani 1 1 d . . .
H3 H 0.2637 0.5666 0.3903 0.059 Uiso 1 1 calc R . .
C5 C 0.3055(3) 0.3888(9) 0.3777(16) 0.042(2) Uani 1 1 d . . .
H4 H 0.2824 0.3220 0.3504 0.051 Uiso 1 1 calc R . .
C6 C 0.4120(2) 0.6827(7) 0.5125(9) 0.0214(13) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pb1 O2 2.580(5) . ?
Pb1 O2 2.580(5) 4_655 ?
Pb1 Cl3 2.639(3) . ?
Pb1 K1 3.872(2) 2_664 ?
Pb1 K1 4.136(2) . ?
Pb2 N1 2.590(6) . ?
Pb2 Cl2 2.757(2) . ?
Pb2 Cl1 2.9314(19) . ?
Pb2 Cl2 2.964(2) 3 ?
K1 O2 2.792(5) 4_655 ?
K1 O2 2.792(5) . ?
K1 O2 2.897(6) 3_565 ?
K1 O2 2.897(6) 2_665 ?
K1 Cl1 3.221(2) 3 ?
K1 Cl1 3.221(2) 2_655 ?
K1 Cl3 3.238(4) . ?
K1 Cl3 3.260(4) 2_664 ?
K1 Pb1 3.872(2) 2_665 ?
K1 K1 4.2030(12) 2_665 ?
K1 K1 4.2030(12) 2_664 ?
Cl1 K1 3.221(2) 2_654 ?
Cl2 Pb2 2.964(2) 3_554 ?
Cl3 K1 3.260(4) 2_665 ?
O1 C6 1.261(8) . ?
O2 C6 1.243(9) . ?
O2 K1 2.897(6) 2_664 ?
N1 C5 1.329(11) . ?
N1 C1 1.351(9) . ?
C1 C2 1.382(9) . ?
C1 H1 0.9300 . ?
C2 C3 1.380(12) . ?
C2 C6 1.525(10) . ?
C3 C4 1.382(12) . ?
C3 H2 0.9300 . ?
C4 C5 1.367(13) . ?
C4 H3 0.9300 . ?
C5 H4 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O2 Pb1 O2 67.2(2) . 4_655 ?
O2 Pb1 Cl3 79.64(14) . . ?
O2 Pb1 Cl3 79.64(14) 4_655 . ?
O2 Pb1 K1 48.43(13) . 2_664 ?
O2 Pb1 K1 48.43(13) 4_655 2_664 ?
Cl3 Pb1 K1 114.71(7) . 2_664 ?
O2 Pb1 K1 41.55(12) . . ?
O2 Pb1 K1 41.55(12) 4_655 . ?
Cl3 Pb1 K1 51.50(7) . . ?
K1 Pb1 K1 63.214(16) 2_664 . ?
N1 Pb2 Cl2 94.36(16) . . ?
N1 Pb2 Cl1 142.44(17) . . ?
Cl2 Pb2 Cl1 84.70(6) . . ?
N1 Pb2 Cl2 81.29(16) . 3 ?
Cl2 Pb2 Cl2 89.79(6) . 3 ?
Cl1 Pb2 Cl2 136.15(6) . 3 ?
O2 K1 O2 61.5(2) 4_655 . ?
O2 K1 O2 148.27(15) 4_655 3_565 ?
O2 K1 O2 110.26(18) . 3_565 ?
O2 K1 O2 110.26(18) 4_655 2_665 ?
O2 K1 O2 148.27(15) . 2_665 ?
O2 K1 O2 59.1(2) 3_565 2_665 ?
O2 K1 Cl1 145.49(15) 4_655 3 ?
O2 K1 Cl1 104.29(12) . 3 ?
O2 K1 Cl1 64.55(11) 3_565 3 ?
O2 K1 Cl1 97.27(12) 2_665 3 ?
O2 K1 Cl1 104.29(12) 4_655 2_655 ?
O2 K1 Cl1 145.49(15) . 2_655 ?
O2 K1 Cl1 97.27(12) 3_565 2_655 ?
O2 K1 Cl1 64.55(11) 2_665 2_655 ?
Cl1 K1 Cl1 68.69(8) 3 2_655 ?
O2 K1 Cl3 66.86(12) 4_655 . ?
O2 K1 Cl3 66.86(12) . . ?
O2 K1 Cl3 81.64(12) 3_565 . ?
O2 K1 Cl3 81.64(12) 2_665 . ?
Cl1 K1 Cl3 140.05(7) 3 . ?
Cl1 K1 Cl3 140.05(7) 2_655 . ?
O2 K1 Cl3 82.82(14) 4_655 2_664 ?
O2 K1 Cl3 82.82(14) . 2_664 ?
O2 K1 Cl3 128.12(12) 3_565 2_664 ?
O2 K1 Cl3 128.12(12) 2_665 2_664 ?
Cl1 K1 Cl3 63.56(7) 3 2_664 ?
Cl1 K1 Cl3 63.56(7) 2_655 2_664 ?
Cl3 K1 Cl3 144.42(11) . 2_664 ?
O2 K1 Pb1 148.74(12) 4_655 2_665 ?
O2 K1 Pb1 148.74(12) . 2_665 ?
O2 K1 Pb1 41.79(10) 3_565 2_665 ?
O2 K1 Pb1 41.79(10) 2_665 2_665 ?
Cl1 K1 Pb1 55.59(5) 3 2_665 ?
Cl1 K1 Pb1 55.59(5) 2_655 2_665 ?
Cl3 K1 Pb1 111.40(9) . 2_665 ?
Cl3 K1 Pb1 104.18(7) 2_664 2_665 ?
O2 K1 Pb1 37.80(11) 4_655 . ?
O2 K1 Pb1 37.80(11) . . ?
O2 K1 Pb1 115.81(11) 3_565 . ?
O2 K1 Pb1 115.81(11) 2_665 . ?
Cl1 K1 Pb1 141.81(5) 3 . ?
Cl1 K1 Pb1 141.81(5) 2_655 . ?
Cl3 K1 Pb1 39.64(5) . . ?
Cl3 K1 Pb1 104.78(8) 2_664 . ?
Pb1 K1 Pb1 151.04(7) 2_665 . ?
O2 K1 K1 109.38(14) 4_655 2_665 ?
O2 K1 K1 109.38(14) . 2_665 ?
O2 K1 K1 41.41(10) 3_565 2_665 ?
O2 K1 K1 41.41(10) 2_665 2_665 ?
Cl1 K1 K1 105.00(7) 3 2_665 ?
Cl1 K1 K1 105.00(7) 2_655 2_665 ?
Cl3 K1 K1 49.93(8) . 2_665 ?
Cl3 K1 K1 165.64(10) 2_664 2_665 ?
Pb1 K1 K1 61.47(4) 2_665 2_665 ?
Pb1 K1 K1 89.58(7) . 2_665 ?
O2 K1 K1 43.34(13) 4_655 2_664 ?
O2 K1 K1 43.34(13) . 2_664 ?
O2 K1 K1 150.13(11) 3_565 2_664 ?
O2 K1 K1 150.13(11) 2_665 2_664 ?
Cl1 K1 K1 103.83(7) 3 2_664 ?
Cl1 K1 K1 103.83(7) 2_655 2_664 ?
Cl3 K1 K1 94.96(9) . 2_664 ?
Cl3 K1 K1 49.46(6) 2_664 2_664 ?
Pb1 K1 K1 153.64(8) 2_665 2_664 ?
Pb1 K1 K1 55.32(6) . 2_664 ?
K1 K1 K1 144.89(10) 2_665 2_664 ?
Pb2 Cl1 K1 146.44(9) . 2_654 ?
Pb2 Cl2 Pb2 93.52(6) . 3_554 ?
Pb1 Cl3 K1 88.86(9) . . ?
Pb1 Cl3 K1 169.46(12) . 2_665 ?
K1 Cl3 K1 80.60(7) . 2_665 ?
C6 O2 Pb1 102.0(4) . . ?
C6 O2 K1 130.2(5) . . ?
Pb1 O2 K1 100.65(18) . . ?
C6 O2 K1 128.4(5) . 2_664 ?
Pb1 O2 K1 89.78(17) . 2_664 ?
K1 O2 K1 95.26(16) . 2_664 ?
C5 N1 C1 117.0(7) . . ?
C5 N1 Pb2 130.2(5) . . ?
C1 N1 Pb2 112.3(5) . . ?
N1 C1 C2 122.9(7) . . ?
N1 C1 H1 118.6 . . ?
C2 C1 H1 118.6 . . ?
C3 C2 C1 118.0(7) . . ?
C3 C2 C6 123.8(7) . . ?
C1 C2 C6 118.2(7) . . ?
C2 C3 C4 119.8(7) . . ?
C2 C3 H2 120.1 . . ?
C4 C3 H2 120.1 . . ?
C5 C4 C3 117.7(8) . . ?
C5 C4 H3 121.1 . . ?
C3 C4 H3 121.1 . . ?
N1 C5 C4 124.5(7) . . ?
N1 C5 H4 117.8 . . ?
C4 C5 H4 117.8 . . ?
O2 C6 O1 123.6(6) . . ?
O2 C6 C2 118.6(6) . . ?
O1 C6 C2 117.8(6) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O2 Pb1 K1 O2 113.1(4) . . . 4_655 ?
Cl3 Pb1 K1 O2 -123.4(2) . . . 4_655 ?
K1 Pb1 K1 O2 56.6(2) 2_664 . . 4_655 ?
O2 Pb1 K1 O2 -113.1(4) 4_655 . . . ?
Cl3 Pb1 K1 O2 123.4(2) . . . . ?
K1 Pb1 K1 O2 -56.6(2) 2_664 . . . ?
O2 Pb1 K1 O2 -90.2(2) . . . 3_565 ?
O2 Pb1 K1 O2 156.6(2) 4_655 . . 3_565 ?
Cl3 Pb1 K1 O2 33.20(13) . . . 3_565 ?
K1 Pb1 K1 O2 -146.80(13) 2_664 . . 3_565 ?
O2 Pb1 K1 O2 -156.6(2) . . . 2_665 ?
O2 Pb1 K1 O2 90.2(2) 4_655 . . 2_665 ?
Cl3 Pb1 K1 O2 -33.20(13) . . . 2_665 ?
K1 Pb1 K1 O2 146.80(13) 2_664 . . 2_665 ?
O2 Pb1 K1 Cl1 -9.3(2) . . . 3 ?
O2 Pb1 K1 Cl1 -122.4(3) 4_655 . . 3 ?
Cl3 Pb1 K1 Cl1 114.16(12) . . . 3 ?
K1 Pb1 K1 Cl1 -65.84(12) 2_664 . . 3 ?
O2 Pb1 K1 Cl1 122.4(3) . . . 2_655 ?
O2 Pb1 K1 Cl1 9.3(2) 4_655 . . 2_655 ?
Cl3 Pb1 K1 Cl1 -114.16(12) . . . 2_655 ?
K1 Pb1 K1 Cl1 65.84(12) 2_664 . . 2_655 ?
O2 Pb1 K1 Cl3 -123.4(2) . . . . ?
O2 Pb1 K1 Cl3 123.4(2) 4_655 . . . ?
K1 Pb1 K1 Cl3 180.0 2_664 . . . ?
O2 Pb1 K1 Cl3 56.6(2) . . . 2_664 ?
O2 Pb1 K1 Cl3 -56.6(2) 4_655 . . 2_664 ?
Cl3 Pb1 K1 Cl3 180.0 . . . 2_664 ?
K1 Pb1 K1 Cl3 0.0 2_664 . . 2_664 ?
O2 Pb1 K1 Pb1 -123.4(2) . . . 2_665 ?
O2 Pb1 K1 Pb1 123.4(2) 4_655 . . 2_665 ?
Cl3 Pb1 K1 Pb1 0.0 . . . 2_665 ?
K1 Pb1 K1 Pb1 180.0 2_664 . . 2_665 ?
O2 Pb1 K1 K1 -123.4(2) . . . 2_665 ?
O2 Pb1 K1 K1 123.4(2) 4_655 . . 2_665 ?
Cl3 Pb1 K1 K1 0.0 . . . 2_665 ?
K1 Pb1 K1 K1 180.0 2_664 . . 2_665 ?
O2 Pb1 K1 K1 56.6(2) . . . 2_664 ?
O2 Pb1 K1 K1 -56.6(2) 4_655 . . 2_664 ?
Cl3 Pb1 K1 K1 180.0 . . . 2_664 ?
N1 Pb2 Cl1 K1 155.1(3) . . . 2_654 ?
Cl2 Pb2 Cl1 K1 -114.65(15) . . . 2_654 ?
Cl2 Pb2 Cl1 K1 -30.50(19) 3 . . 2_654 ?
N1 Pb2 Cl2 Pb2 110.53(17) . . . 3_554 ?
Cl1 Pb2 Cl2 Pb2 -31.78(5) . . . 3_554 ?
Cl2 Pb2 Cl2 Pb2 -168.22(9) 3 . . 3_554 ?
O2 Pb1 Cl3 K1 34.24(12) . . . . ?
O2 Pb1 Cl3 K1 -34.24(12) 4_655 . . . ?
K1 Pb1 Cl3 K1 0.0 2_664 . . . ?
O2 Pb1 Cl3 K1 34.24(12) . . . 2_665 ?
O2 Pb1 Cl3 K1 -34.24(12) 4_655 . . 2_665 ?
K1 Pb1 Cl3 K1 0.000(3) 2_664 . . 2_665 ?
K1 Pb1 Cl3 K1 0.000(3) . . . 2_665 ?
O2 K1 Cl3 Pb1 33.80(13) 4_655 . . . ?
O2 K1 Cl3 Pb1 -33.80(13) . . . . ?
O2 K1 Cl3 Pb1 -150.12(11) 3_565 . . . ?
O2 K1 Cl3 Pb1 150.12(11) 2_665 . . . ?
Cl1 K1 Cl3 Pb1 -118.52(13) 3 . . . ?
Cl1 K1 Cl3 Pb1 118.52(13) 2_655 . . . ?
Cl3 K1 Cl3 Pb1 0.0 2_664 . . . ?
Pb1 K1 Cl3 Pb1 180.0 2_665 . . . ?
K1 K1 Cl3 Pb1 180.0 2_665 . . . ?
K1 K1 Cl3 Pb1 0.0 2_664 . . . ?
O2 K1 Cl3 K1 -146.20(13) 4_655 . . 2_665 ?
O2 K1 Cl3 K1 146.20(13) . . . 2_665 ?
O2 K1 Cl3 K1 29.88(11) 3_565 . . 2_665 ?
O2 K1 Cl3 K1 -29.88(11) 2_665 . . 2_665 ?
Cl1 K1 Cl3 K1 61.48(13) 3 . . 2_665 ?
Cl1 K1 Cl3 K1 -61.48(13) 2_655 . . 2_665 ?
Cl3 K1 Cl3 K1 180.0 2_664 . . 2_665 ?
Pb1 K1 Cl3 K1 0.0 2_665 . . 2_665 ?
Pb1 K1 Cl3 K1 180.0 . . . 2_665 ?
K1 K1 Cl3 K1 180.0 2_664 . . 2_665 ?
O2 Pb1 O2 C6 176.8(4) 4_655 . . . ?
Cl3 Pb1 O2 C6 93.7(4) . . . . ?
K1 Pb1 O2 C6 -129.4(5) 2_664 . . . ?
K1 Pb1 O2 C6 135.3(5) . . . . ?
O2 Pb1 O2 K1 41.4(2) 4_655 . . . ?
Cl3 Pb1 O2 K1 -41.60(14) . . . . ?
K1 Pb1 O2 K1 95.31(18) 2_664 . . . ?
O2 Pb1 O2 K1 -53.89(17) 4_655 . . 2_664 ?
Cl3 Pb1 O2 K1 -136.91(13) . . . 2_664 ?
K1 Pb1 O2 K1 -95.31(18) . . . 2_664 ?
O2 K1 O2 C6 -155.7(5) 4_655 . . . ?
O2 K1 O2 C6 -9.5(6) 3_565 . . . ?
O2 K1 O2 C6 -73.1(5) 2_665 . . . ?
Cl1 K1 O2 C6 58.2(6) 3 . . . ?
Cl1 K1 O2 C6 131.3(5) 2_655 . . . ?
Cl3 K1 O2 C6 -80.5(6) . . . . ?
Cl3 K1 O2 C6 118.6(6) 2_664 . . . ?
Pb1 K1 O2 C6 13.0(7) 2_665 . . . ?
Pb1 K1 O2 C6 -115.9(6) . . . . ?
K1 K1 O2 C6 -53.6(6) 2_665 . . . ?
K1 K1 O2 C6 153.4(6) 2_664 . . . ?
O2 K1 O2 Pb1 -39.9(2) 4_655 . . . ?
O2 K1 O2 Pb1 106.34(19) 3_565 . . . ?
O2 K1 O2 Pb1 42.8(3) 2_665 . . . ?
Cl1 K1 O2 Pb1 174.09(14) 3 . . . ?
Cl1 K1 O2 Pb1 -112.85(19) 2_655 . . . ?
Cl3 K1 O2 Pb1 35.38(12) . . . . ?
Cl3 K1 O2 Pb1 -125.58(17) 2_664 . . . ?
Pb1 K1 O2 Pb1 128.86(19) 2_665 . . . ?
K1 K1 O2 Pb1 62.20(18) 2_665 . . . ?
K1 K1 O2 Pb1 -90.8(2) 2_664 . . . ?
O2 K1 O2 K1 50.88(16) 4_655 . . 2_664 ?
O2 K1 O2 K1 -162.89(14) 3_565 . . 2_664 ?
O2 K1 O2 K1 133.5(3) 2_665 . . 2_664 ?
Cl1 K1 O2 K1 -95.14(13) 3 . . 2_664 ?
Cl1 K1 O2 K1 -22.1(3) 2_655 . . 2_664 ?
Cl3 K1 O2 K1 126.15(15) . . . 2_664 ?
Cl3 K1 O2 K1 -34.81(10) 2_664 . . 2_664 ?
Pb1 K1 O2 K1 -140.4(2) 2_665 . . 2_664 ?
Pb1 K1 O2 K1 90.8(2) . . . 2_664 ?
K1 K1 O2 K1 152.97(10) 2_665 . . 2_664 ?
Cl2 Pb2 N1 C5 33.1(10) . . . . ?
Cl1 Pb2 N1 C5 120.0(9) . . . . ?
Cl2 Pb2 N1 C5 -56.1(9) 3 . . . ?
Cl2 Pb2 N1 C1 -155.0(6) . . . . ?
Cl1 Pb2 N1 C1 -68.0(7) . . . . ?
Cl2 Pb2 N1 C1 115.9(6) 3 . . . ?
C5 N1 C1 C2 -0.3(15) . . . . ?
Pb2 N1 C1 C2 -173.4(7) . . . . ?
N1 C1 C2 C3 0.0(14) . . . . ?
N1 C1 C2 C6 180.0(8) . . . . ?
C1 C2 C3 C4 -1.0(15) . . . . ?
C6 C2 C3 C4 179.1(9) . . . . ?
C2 C3 C4 C5 2.1(17) . . . . ?
C1 N1 C5 C4 1.5(17) . . . . ?
Pb2 N1 C5 C4 173.2(8) . . . . ?
C3 C4 C5 N1 -2.4(19) . . . . ?
Pb1 O2 C6 O1 -12.0(8) . . . . ?
K1 O2 C6 O1 103.3(7) . . . . ?
K1 O2 C6 O1 -111.4(7) 2_664 . . . ?
Pb1 O2 C6 C2 168.4(6) . . . . ?
K1 O2 C6 C2 -76.3(8) . . . . ?
K1 O2 C6 C2 69.0(8) 2_664 . . . ?
C3 C2 C6 O2 -168.5(8) . . . . ?
C1 C2 C6 O2 11.6(11) . . . . ?
C3 C2 C6 O1 11.9(12) . . . . ?
C1 C2 C6 O1 -168.1(7) . . . . ?

_diffrn_measured_fraction_theta_max 0.995
_diffrn_reflns_theta_full        27.48
_diffrn_measured_fraction_theta_full 0.995
_refine_diff_density_max         1.662
_refine_diff_density_min         -1.086
_refine_diff_density_rms         0.211
