# Electronic Supplementary Material (ESI) for Inorganic Chemistry Frontiers.
# This journal is © the Partner Organisations 2022

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_skd120
_database_code_depnum_ccdc_archive 'CCDC 2033177'
loop_
_audit_author_name
_audit_author_address
'Samar Das'
;University of Hyderabad
India
;
_audit_update_record             
;
2022-02-23 deposited with the CCDC.	2022-05-26 downloaded from the CCDC.
;
_audit_creation_date             2021-12-05
_audit_creation_method           
;
Olex2 1.3-ac4
(compiled 2018.12.18 svn.r3554 for Rigaku Oxford Diffraction, GUI svn.r1)
;
_shelx_SHELXL_version_number     2018/1
_chemical_name_common            ?
_chemical_name_systematic        
;
 ?
;
_chemical_formula_moiety         '0.5(Bi4 Co4 H8 Na12 O156 W40), 6(O)'
_chemical_formula_sum            'Bi2 H4 Co2 Na6 O84 W20'
_chemical_formula_weight         5698.79
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Bi Bi -4.1077 10.2566 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Na Na 0.0362 0.0249 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           12
_space_group_name_H-M_alt        'C 1 2/m 1'
_space_group_name_Hall           '-C 2y'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'

_cell_length_a                   17.7208(7)
_cell_length_b                   18.7141(7)
_cell_length_c                   14.1533(6)
_cell_angle_alpha                90
_cell_angle_beta                 112.7410(10)
_cell_angle_gamma                90
_cell_volume                     4328.8(3)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    9839
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      26.33
_cell_measurement_theta_min      2.49
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    31.004
_exptl_absorpt_correction_T_max  0.7454
_exptl_absorpt_correction_T_min  0.1275
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear pink'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   ?
_exptl_crystal_colour_primary    pink
_exptl_crystal_density_diffrn    4.372
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             4884
_exptl_crystal_size_max          0.38
_exptl_crystal_size_mid          0.32
_exptl_crystal_size_min          0.28
_exptl_special_details           
;
 ?
;
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0933
_diffrn_reflns_av_unetI/netI     0.0214
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            149781
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        24.999
_diffrn_reflns_theta_max         24.999
_diffrn_reflns_theta_min         2.375
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                3728
_reflns_number_total             3944
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'olex2.solve (Bourhis et al., 2015)'
_refine_diff_density_max         3.344
_refine_diff_density_min         -2.612
_refine_diff_density_rms         0.375
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.175
_refine_ls_hydrogen_treatment    refall
_refine_ls_matrix_type           full
_refine_ls_number_parameters     288
_refine_ls_number_reflns         3944
_refine_ls_number_restraints     2
_refine_ls_R_factor_all          0.0455
_refine_ls_R_factor_gt           0.0421
_refine_ls_restrained_S_all      1.183
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0304P)²+553.3894P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1012
_refine_ls_wR_factor_ref         0.1029
_refine_special_details          ?
_olex2_refinement_description    
;
1. Restrained distances
 H20-O20
 1 with sigma of 0.02
 O20-H20
 0.8 with sigma of 0.02
2. Uiso/Uaniso restraints and constraints
Uanis(O15) = Uanis(O16) = Uanis(Na1) = Uanis(W6B)
3. Others
 Fixed Sof: W6A(0.42879) Na1(0.2) Na2(0.55) Na3(0.5) Na4(0.25) W6B(0.0711)
;
_atom_sites_solution_hydrogens   difmap
_atom_sites_solution_primary     iterative
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Bi1 Bi 0.34009(4) 0.500000 0.37141(6) 0.01288(18) Uani 1 2 d S T P . .
W4 W 0.52182(5) 0.500000 0.33242(6) 0.0158(2) Uani 1 2 d S T P . .
W5 W 0.30345(4) 0.68826(3) 0.30669(5) 0.02187(17) Uani 1 1 d . . . . .
W2 W 0.16632(4) 0.59946(4) 0.11705(5) 0.02372(17) Uani 1 1 d . . . . .
W1 W 0.16102(4) 0.59789(4) 0.35168(5) 0.02278(17) Uani 1 1 d . . . . .
W3 W 0.38105(4) 0.58870(4) 0.13820(5) 0.02497(18) Uani 1 1 d . . . . .
W6A W 0.500000 0.65792(6) 0.500000 0.0266(3) Uani 0.8576 2 d S T P . .
Co1 Co 0.2373(9) 0.500000 0.5926(13) 0.0491(18) Uani 1 2 d S T P . .
O15 O 0.2512(6) 0.4221(6) 0.2835(8) 0.0215(17) Uani 1 1 d . . . . .
O18 O 0.3795(6) 0.6458(6) 0.4251(9) 0.025(3) Uani 1 1 d . . . . .
O11 O 0.3709(6) 0.6542(6) 0.2345(8) 0.021(2) Uani 1 1 d . . . . .
O2 O 0.1265(9) 0.500000 0.3199(12) 0.025(4) Uani 1 2 d S T P . .
O3 O 0.1042(6) 0.6145(6) 0.1988(10) 0.027(3) Uani 1 1 d . . . . .
O7 O 0.1387(9) 0.500000 0.1037(13) 0.029(4) Uani 1 2 d S T P . .
O17 O 0.5117(7) 0.5705(6) 0.4109(8) 0.025(3) Uani 1 1 d . . . . .
O13 O 0.4917(7) 0.5721(7) 0.2141(8) 0.026(3) Uani 1 1 d . . . . .
O12 O 0.3735(10) 0.500000 0.0639(12) 0.031(4) Uani 1 2 d S T P . .
O14 O 0.3870(9) 0.500000 0.2533(10) 0.016(3) Uani 1 2 d S T P . .
O5 O 0.2185(7) 0.6900(6) 0.3585(11) 0.035(3) Uani 1 1 d . . . . .
O8 O 0.2611(7) 0.5789(7) 0.0913(9) 0.031(3) Uani 1 1 d . . . . .
O9 O 0.2175(7) 0.6916(7) 0.1685(10) 0.034(3) Uani 1 1 d . . . . .
O4 O 0.2363(8) 0.5727(7) 0.4734(9) 0.034(3) Uani 1 1 d . . . . .
O6 O 0.0991(8) 0.6271(7) -0.0012(10) 0.037(3) Uani 1 1 d . . . . .
O16 O 0.6269(9) 0.500000 0.3561(12) 0.0215(17) Uani 1 2 d S T P . .
O20 O 0.4870(8) 0.7201(8) 0.5915(13) 0.049(4) Uani 1 1 d D . . . .
O10 O 0.3882(9) 0.6459(9) 0.0469(10) 0.046(4) Uani 1 1 d . . . . .
O1 O 0.0822(8) 0.6322(8) 0.3787(12) 0.043(3) Uani 1 1 d . . . . .
O19 O 0.3304(8) 0.7768(7) 0.3214(11) 0.038(3) Uani 1 1 d . . . . .
Na1 Na -0.0296(12) 0.500000 0.1401(17) 0.0215(17) Uani 0.4 2 d S T P . .
Na2 Na 0.1556(10) 0.8248(9) 0.3765(13) 0.053(4) Uani 0.55 1 d . . . . .
Na3 Na 0.5362(14) 0.7826(13) 0.802(2) 0.096(9) Uani 0.5 1 d . . . . .
Na4 Na 0.394(2) 0.500000 -0.121(3) 0.106(16) Uani 0.5 2 d S T P . .
O25 O 0.0884(17) 0.7934(15) 0.131(2) 0.114(9) Uani 1 1 d . . . . .
O23 O -0.202(2) 0.500000 0.114(3) 0.18(3) Uani 1 2 d S T P . .
W6B W 0.2350(13) 0.500000 0.5925(19) 0.0215(17) Uani 0.1422 2 d S T P . .
O21 O 0.2546(19) 0.4181(15) 0.708(3) 0.147(13) Uani 1 1 d . . . . .
O22 O 0.116(3) 0.500000 0.553(4) 0.17(2) Uani 1 2 d S T P . .
O24 O 0.500000 0.856(3) 0.500000 0.29(5) Uani 1 2 d S T P . .
H20 H 0.435(9) 0.73(2) 0.58(3) 0.17(19) Uiso 1 1 d D . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Bi1 O15 2.154(10) . ?
Bi1 O15 2.154(10) 6_565 ?
Bi1 O14 2.136(15) . ?
W4 O17 1.778(10) . ?
W4 O17 1.778(10) 6_565 ?
W4 O13 2.055(11) 6_565 ?
W4 O13 2.055(11) . ?
W4 O14 2.212(15) . ?
W4 O16 1.760(15) . ?
W5 O15 2.235(11) 6_565 ?
W5 O18 1.874(12) . ?
W5 O11 1.956(11) . ?
W5 O5 1.912(13) . ?
W5 O9 1.961(12) . ?
W5 O19 1.715(13) . ?
W2 O15 2.288(10) 6_565 ?
W2 O3 1.900(12) . ?
W2 O7 1.915(4) . ?
W2 O8 1.890(12) . ?
W2 O9 1.954(13) . ?
W2 O6 1.716(12) . ?
W1 O15 2.194(11) 6_565 ?
W1 O2 1.929(5) . ?
W1 O3 2.027(12) . ?
W1 O5 1.986(13) . ?
W1 O4 1.787(12) . ?
W1 O1 1.709(12) . ?
W3 O11 1.892(11) . ?
W3 O13 1.862(11) . ?
W3 O12 1.941(8) . ?
W3 O14 2.299(10) . ?
W3 O8 1.976(11) . ?
W3 O10 1.720(12) . ?
W6A O18 1.995(11) 2_656 ?
W6A O18 1.995(11) . ?
W6A O17 2.124(10) . ?
W6A O17 2.124(10) 2_656 ?
W6A O20 1.821(16) . ?
W6A O20 1.821(16) 2_656 ?
Co1 O4 2.161(18) . ?
Co1 O4 2.161(18) 6_565 ?
Co1 O16 2.23(2) 5_666 ?
Co1 O21 2.17(4) 6_565 ?
Co1 O21 2.17(4) . ?
Co1 O22 1.99(5) . ?
O2 Na1 2.95(3) . ?
O12 Na4 2.78(3) . ?
O5 Na2 2.809(19) . ?
O4 Na2 2.95(2) 7_566 ?
O4 W6B 2.17(3) . ?
O20 Na2 2.86(2) 7_566 ?
O20 Na3 3.00(3) . ?
Na1 Na3 4.16(2) 4_546 ?
Na1 Na3 4.16(2) 7_566 ?
Na1 O23 2.93(4) . ?
Na2 Na3 3.92(3) 7_566 ?
Na2 O21 2.91(4) 4_556 ?
Na4 Na4 3.98(7) 5_665 ?
W6B O21 2.17(4) . ?
W6B O21 2.17(4) 6_565 ?
W6B O22 1.95(5) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O15 Bi1 O15 85.2(6) 6_565 . ?
O14 Bi1 O15 88.1(4) . 6_565 ?
O14 Bi1 O15 88.1(4) . . ?
O17 W4 O17 95.8(8) 6_565 . ?
O17 W4 O13 160.0(5) 6_565 . ?
O17 W4 O13 160.0(5) . 6_565 ?
O17 W4 O13 88.0(5) 6_565 6_565 ?
O17 W4 O13 88.0(5) . . ?
O17 W4 O14 88.1(4) . . ?
O17 W4 O14 88.1(4) 6_565 . ?
O13 W4 O13 82.1(7) . 6_565 ?
O13 W4 O14 72.4(4) . . ?
O13 W4 O14 72.4(4) 6_565 . ?
O16 W4 O17 103.6(5) . 6_565 ?
O16 W4 O17 103.6(5) . . ?
O16 W4 O13 94.4(5) . 6_565 ?
O16 W4 O13 94.4(5) . . ?
O16 W4 O14 162.3(6) . . ?
O18 W5 O15 81.6(4) . 6_565 ?
O18 W5 O11 87.4(5) . . ?
O18 W5 O5 93.7(5) . . ?
O18 W5 O9 156.7(5) . . ?
O11 W5 O15 85.7(4) . 6_565 ?
O11 W5 O9 83.4(5) . . ?
O5 W5 O15 74.3(5) . 6_565 ?
O5 W5 O11 159.5(5) . . ?
O5 W5 O9 87.6(6) . . ?
O9 W5 O15 76.4(5) . 6_565 ?
O19 W5 O15 172.3(5) . 6_565 ?
O19 W5 O18 103.3(6) . . ?
O19 W5 O11 100.4(6) . . ?
O19 W5 O5 99.3(6) . . ?
O19 W5 O9 99.4(6) . . ?
O3 W2 O15 72.8(4) . 6_565 ?
O3 W2 O7 91.0(6) . . ?
O3 W2 O9 86.4(5) . . ?
O7 W2 O15 88.4(5) . 6_565 ?
O7 W2 O9 163.5(6) . . ?
O8 W2 O15 83.3(4) . 6_565 ?
O8 W2 O3 156.0(5) . . ?
O8 W2 O7 89.8(7) . . ?
O8 W2 O9 86.1(6) . . ?
O9 W2 O15 75.3(5) . 6_565 ?
O6 W2 O15 171.6(6) . 6_565 ?
O6 W2 O3 101.7(6) . . ?
O6 W2 O7 98.1(7) . . ?
O6 W2 O8 101.9(6) . . ?
O6 W2 O9 98.3(6) . . ?
O2 W1 O15 87.4(6) . 6_565 ?
O2 W1 O3 85.1(6) . . ?
O2 W1 O5 161.1(6) . . ?
O3 W1 O15 72.6(4) . 6_565 ?
O5 W1 O15 73.9(5) . 6_565 ?
O5 W1 O3 87.3(5) . . ?
O4 W1 O15 88.9(5) . 6_565 ?
O4 W1 O2 91.4(6) . . ?
O4 W1 O3 161.3(5) . . ?
O4 W1 O5 90.3(6) . . ?
O1 W1 O15 163.6(6) . 6_565 ?
O1 W1 O2 101.3(7) . . ?
O1 W1 O3 94.0(6) . . ?
O1 W1 O5 96.4(6) . . ?
O1 W1 O4 104.7(7) . . ?
O11 W3 O12 159.7(5) . . ?
O11 W3 O14 87.1(4) . . ?
O11 W3 O8 85.0(5) . . ?
O13 W3 O11 93.7(5) . . ?
O13 W3 O12 90.4(6) . . ?
O13 W3 O14 73.8(5) . . ?
O13 W3 O8 159.3(5) . . ?
O12 W3 O14 75.0(5) . . ?
O12 W3 O8 84.2(6) . . ?
O8 W3 O14 85.4(5) . . ?
O10 W3 O11 101.1(6) . . ?
O10 W3 O13 99.8(6) . . ?
O10 W3 O12 97.7(7) . . ?
O10 W3 O14 170.0(6) . . ?
O10 W3 O8 100.8(6) . . ?
O18 W6A O18 167.0(7) . 2_656 ?
O18 W6A O17 84.1(5) . 2_656 ?
O18 W6A O17 84.1(5) 2_656 . ?
O18 W6A O17 85.8(5) 2_656 2_656 ?
O18 W6A O17 85.8(5) . . ?
O17 W6A O17 79.3(7) . 2_656 ?
O20 W6A O18 95.6(6) 2_656 . ?
O20 W6A O18 92.7(5) 2_656 2_656 ?
O20 W6A O18 95.6(6) . 2_656 ?
O20 W6A O18 92.7(5) . . ?
O20 W6A O17 169.4(6) 2_656 2_656 ?
O20 W6A O17 90.1(6) 2_656 . ?
O20 W6A O17 169.4(7) . . ?
O20 W6A O17 90.1(6) . 2_656 ?
O20 W6A O20 100.5(11) 2_656 . ?
O4 Co1 O4 78.0(9) . 6_565 ?
O4 Co1 O16 86.4(7) 6_565 5_666 ?
O4 Co1 O16 86.4(7) . 5_666 ?
O4 Co1 O21 95.6(10) 6_565 . ?
O4 Co1 O21 95.6(10) . 6_565 ?
O4 Co1 O21 170.5(13) 6_565 6_565 ?
O4 Co1 O21 170.5(13) . . ?
O21 Co1 O16 86.2(10) 6_565 5_666 ?
O21 Co1 O16 86.2(10) . 5_666 ?
O21 Co1 O21 89.8(19) 6_565 . ?
O22 Co1 O4 95.4(14) . 6_565 ?
O22 Co1 O4 95.4(14) . . ?
O22 Co1 O16 177.7(19) . 5_666 ?
O22 Co1 O21 92.1(15) . . ?
O22 Co1 O21 92.1(15) . 6_565 ?
Bi1 O15 W5 111.8(4) . 6_565 ?
Bi1 O15 W2 139.2(6) . 6_565 ?
Bi1 O15 W1 110.8(5) . 6_565 ?
W5 O15 W2 93.3(4) 6_565 6_565 ?
W1 O15 W5 96.3(4) 6_565 6_565 ?
W1 O15 W2 97.0(4) 6_565 6_565 ?
W5 O18 W6A 132.8(6) . . ?
W3 O11 W5 146.5(6) . . ?
W1 O2 W1 143.6(8) . 6_565 ?
W1 O2 Na1 108.0(4) 6_565 . ?
W1 O2 Na1 108.0(4) . . ?
W2 O3 W1 117.5(5) . . ?
W2 O7 W2 152.7(9) 6_565 . ?
W4 O17 W6A 177.5(7) . . ?
W3 O13 W4 117.6(6) . . ?
W3 O12 W3 117.5(8) 6_565 . ?
W3 O12 Na4 120.2(4) 6_565 . ?
W3 O12 Na4 120.2(4) . . ?
Bi1 O14 W4 105.9(6) . . ?
Bi1 O14 W3 129.0(4) . . ?
Bi1 O14 W3 129.0(4) . 6_565 ?
W4 O14 W3 96.0(5) . 6_565 ?
W4 O14 W3 96.0(5) . . ?
W3 O14 W3 92.4(5) . 6_565 ?
W5 O5 W1 115.6(6) . . ?
W5 O5 Na2 116.7(7) . . ?
W1 O5 Na2 124.7(6) . . ?
W2 O8 W3 146.8(7) . . ?
W2 O9 W5 114.4(6) . . ?
W1 O4 Co1 134.2(8) . . ?
W1 O4 Na2 123.8(7) . 7_566 ?
W1 O4 W6B 133.3(8) . . ?
Co1 O4 Na2 92.3(6) . 7_566 ?
Co1 O4 W6B 1.0(10) . . ?
W6B O4 Na2 92.7(7) . 7_566 ?
W4 O16 Co1 172.6(10) . 5_666 ?
W6A O20 Na2 106.7(7) . 7_566 ?
W6A O20 Na3 152.5(8) . . ?
Na2 O20 Na3 83.8(8) 7_566 . ?
O2 Na1 Na3 85.4(4) . 7_566 ?
O2 Na1 Na3 85.4(4) . 4_546 ?
Na3 Na1 Na3 156.0(11) 7_566 4_546 ?
O23 Na1 O2 134.0(11) . . ?
O23 Na1 Na3 85.3(5) . 4_546 ?
O23 Na1 Na3 85.3(5) . 7_566 ?
O5 Na2 O4 118.6(7) . 7_566 ?
O5 Na2 O20 99.0(7) . 7_566 ?
O5 Na2 Na3 75.9(5) . 7_566 ?
O5 Na2 O21 101.7(8) . 4_556 ?
O4 Na2 Na3 163.3(7) 7_566 7_566 ?
O20 Na2 O4 116.4(7) 7_566 7_566 ?
O20 Na2 Na3 49.7(6) 7_566 7_566 ?
O20 Na2 O21 153.9(9) 7_566 4_556 ?
O21 Na2 O4 66.4(8) 4_556 7_566 ?
O21 Na2 Na3 121.2(10) 4_556 7_566 ?
O20 Na3 Na1 123.7(10) . 7_566 ?
O20 Na3 Na2 46.6(5) . 7_566 ?
Na2 Na3 Na1 123.0(6) 7_566 7_566 ?
O12 Na4 Na4 67.2(10) . 5_665 ?
O4 W6B O4 77.5(11) . 6_565 ?
O4 W6B O16 85.1(10) . 5_666 ?
O4 W6B O16 85.1(10) 6_565 5_666 ?
O21 W6B O4 168.6(16) 6_565 6_565 ?
O21 W6B O4 95.4(10) . 6_565 ?
O21 W6B O4 95.4(10) 6_565 . ?
O21 W6B O4 168.6(16) . . ?
O21 W6B O16 85.4(11) 6_565 5_666 ?
O21 W6B O16 85.4(11) . 5_666 ?
O21 W6B O21 90(2) 6_565 . ?
O22 W6B O4 96.2(15) . . ?
O22 W6B O4 96.2(15) . 6_565 ?
O22 W6B O16 178(2) . 5_666 ?
O22 W6B O21 93.4(17) . . ?
O22 W6B O21 93.4(17) . 6_565 ?
Co1 O21 Na2 93.2(15) . 4_546 ?
W6B O21 Co1 1.1(10) . . ?
W6B O21 Na2 94.0(16) . 4_546 ?
W6B O22 Co1 0.3(13) . . ?

_olex2_submission_special_instructions 'No special instructions were received'
