# Electronic Supplementary Material (ESI) for Inorganic Chemistry Frontiers.
# This journal is © the Partner Organisations 2022

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1922GG61_0m_a
_database_code_depnum_ccdc_archive 'CCDC 2153928'
loop_
_audit_author_name
_audit_author_address
'E. Carolina Sanudo'
;Universitat de Barcelona
Spain
;
_audit_update_record             
;
2022-02-22 deposited with the CCDC.	2022-06-23 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C84 H54 Eu2 N6 O7, (H2 O)'
_chemical_formula_sum            'C84 H56 Eu2 N6 O8'
_chemical_formula_weight         1581.25

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   10.589(6)
_cell_length_b                   18.019(9)
_cell_length_c                   18.633(10)
_cell_angle_alpha                67.421(12)
_cell_angle_beta                 74.502(17)
_cell_angle_gamma                87.982(10)
_cell_volume                     3154(3)
_cell_formula_units_Z            2
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    2952
_cell_measurement_theta_min      2.47
_cell_measurement_theta_max      21.27

_exptl_crystal_description       plate
_exptl_crystal_colour            orange
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.663
_exptl_crystal_F_000             1580
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.109
_exptl_crystal_size_mid          0.100
_exptl_crystal_size_min          0.050
_exptl_absorpt_coefficient_mu    2.040
_shelx_estimated_absorpt_T_min   0.808
_shelx_estimated_absorpt_T_max   0.905
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_correction_T_min  0.6643
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_process_details   'APEX3 SADABS'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            25067
_diffrn_reflns_av_unetI/netI     0.1421
_diffrn_reflns_av_R_equivalents  0.0730
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_theta_min         2.002
_diffrn_reflns_theta_max         27.509
_diffrn_reflns_theta_full        25.000
_diffrn_measured_fraction_theta_max 0.855
_diffrn_measured_fraction_theta_full 0.899
_diffrn_reflns_Laue_measured_fraction_max 0.855
_diffrn_reflns_Laue_measured_fraction_full 0.899
_diffrn_reflns_point_group_measured_fraction_max 0.855
_diffrn_reflns_point_group_measured_fraction_full 0.899
_reflns_number_total             12423
_reflns_number_gt                5676
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXT Bruker APEX3'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1333P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     'SHELXL-2014/7 (Sheldrick 2014'
_refine_ls_extinction_coef       0.0023(5)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         12423
_refine_ls_number_parameters     866
_refine_ls_number_restraints     768
_refine_ls_R_factor_all          0.1641
_refine_ls_R_factor_gt           0.0719
_refine_ls_wR_factor_ref         0.2564
_refine_ls_wR_factor_gt          0.1844
_refine_ls_goodness_of_fit_ref   0.962
_refine_ls_restrained_S_all      0.959
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.50405(6) 0.37047(3) 0.65668(4) 0.0457(3) Uani 1 1 d . . . . .
Eu2 Eu 0.83075(6) 0.29190(3) 0.70888(5) 0.0627(3) Uani 1 1 d . . . . .
N1 N 0.3895(9) 0.3801(5) 0.7891(6) 0.044(2) Uani 1 1 d . U . . .
N2 N 0.3621(9) 0.2468(4) 0.7607(6) 0.041(2) Uani 1 1 d . U . . .
N3 N 0.7033(9) 0.3015(5) 0.8455(7) 0.050(3) Uani 1 1 d . U . . .
N4 N 0.6777(9) 0.1693(5) 0.8160(7) 0.051(3) Uani 1 1 d . U . . .
N5 N 0.9628(10) 0.2096(5) 0.8062(8) 0.065(3) Uani 1 1 d . U . . .
N6 N 0.9399(10) 0.1772(6) 0.6778(8) 0.063(3) Uani 1 1 d . U . . .
O1 O 0.4227(8) 0.4933(4) 0.6325(5) 0.048(2) Uani 1 1 d . U . . .
O2 O 0.3779(8) 0.3290(4) 0.5969(5) 0.052(2) Uani 1 1 d . U . . .
O3 O 0.6938(8) 0.4016(4) 0.6887(5) 0.056(2) Uani 1 1 d . U . . .
O4 O 0.6516(7) 0.2661(4) 0.6626(5) 0.046(2) Uani 1 1 d . U . . .
O5 O 0.9762(9) 0.3765(5) 0.7220(7) 0.086(3) Uani 1 1 d . U . . .
O6 O 0.9358(9) 0.3356(5) 0.5726(7) 0.093(4) Uani 1 1 d . U . . .
O7 O 0.6369(8) 0.4449(4) 0.5174(5) 0.057(3) Uani 1 1 d . . . . .
C1 C 0.3629(11) 0.3047(6) 0.8576(8) 0.042(3) Uani 1 1 d . U . . .
C2 C 0.3605(12) 0.2962(6) 0.9342(8) 0.047(3) Uani 1 1 d . U . . .
H2 H 0.3745 0.3432 0.9433 0.057 Uiso 1 1 calc R U . . .
C3 C 0.3385(12) 0.2212(6) 1.0000(8) 0.047(3) Uani 1 1 d . U . . .
H3A H 0.3357 0.2175 1.0527 0.056 Uiso 1 1 calc R U . . .
C4 C 0.3210(11) 0.1525(6) 0.9853(8) 0.047(3) Uani 1 1 d . U . . .
H4 H 0.3075 0.1008 1.0281 0.057 Uiso 1 1 calc R U . . .
C5 C 0.3232(11) 0.1599(6) 0.9072(7) 0.044(3) Uani 1 1 d . U . . .
H5 H 0.3080 0.1128 0.8984 0.053 Uiso 1 1 calc R U . . .
C6 C 0.3475(10) 0.2351(5) 0.8416(7) 0.041(3) Uani 1 1 d . U . . .
C7 C 0.3514(12) 0.4436(6) 0.8040(8) 0.045(3) Uani 1 1 d . U . . .
H7 H 0.3049 0.4340 0.8583 0.055 Uiso 1 1 calc R U . . .
C8 C 0.3712(12) 0.5261(6) 0.7481(8) 0.044(3) Uani 1 1 d . U . . .
C9 C 0.4003(12) 0.5457(6) 0.6669(8) 0.048(3) Uani 1 1 d . U . . .
C10 C 0.4059(13) 0.6300(6) 0.6139(8) 0.059(3) Uani 1 1 d . U . . .
H10A H 0.4282 0.6444 0.5571 0.071 Uiso 1 1 calc R U . . .
C11 C 0.3807(13) 0.6877(6) 0.6431(8) 0.057(3) Uani 1 1 d . U . . .
H11 H 0.3837 0.7421 0.6066 0.068 Uiso 1 1 calc R U . . .
C12 C 0.3504(13) 0.6702(6) 0.7246(8) 0.050(3) Uani 1 1 d . U . . .
C13 C 0.3454(13) 0.5885(6) 0.7794(8) 0.052(3) Uani 1 1 d . U . . .
C14 C 0.3180(15) 0.5758(7) 0.8597(9) 0.068(3) Uani 1 1 d . U . . .
H14A H 0.3191 0.5224 0.8973 0.082 Uiso 1 1 calc R U . . .
C15 C 0.2881(16) 0.6375(7) 0.8901(9) 0.073(3) Uani 1 1 d . U . . .
H15A H 0.2613 0.6255 0.9465 0.088 Uiso 1 1 calc R U . . .
C16 C 0.2999(15) 0.7160(7) 0.8335(9) 0.068(3) Uani 1 1 d . U . . .
H16 H 0.2896 0.7590 0.8517 0.082 Uiso 1 1 calc R U . . .
C17 C 0.3260(14) 0.7337(6) 0.7523(8) 0.059(3) Uani 1 1 d . U . . .
H17 H 0.3276 0.7877 0.7152 0.071 Uiso 1 1 calc R U . . .
C18 C 0.3097(11) 0.1897(6) 0.7467(8) 0.050(3) Uani 1 1 d . U . . .
H18 H 0.2622 0.1452 0.7928 0.060 Uiso 1 1 calc R U . . .
C19 C 0.3169(11) 0.1880(6) 0.6712(8) 0.044(3) Uani 1 1 d . U . . .
C20 C 0.3395(12) 0.2581(6) 0.5970(8) 0.048(3) Uani 1 1 d . U . . .
C21 C 0.3217(12) 0.2566(7) 0.5254(8) 0.052(3) Uani 1 1 d . U . . .
H21 H 0.3295 0.3051 0.4792 0.062 Uiso 1 1 calc R U . . .
C22 C 0.2939(11) 0.1867(6) 0.5233(8) 0.047(3) Uani 1 1 d . U . . .
H22 H 0.2819 0.1870 0.4745 0.056 Uiso 1 1 calc R U . . .
C23 C 0.2887(11) 0.1130(6) 0.6644(8) 0.045(3) Uani 1 1 d . U . . .
C24 C 0.2765(11) 0.0375(6) 0.7291(8) 0.049(3) Uani 1 1 d . U . . .
H24A H 0.2820 0.0353 0.7799 0.058 Uiso 1 1 calc R U . . .
C25 C 0.2570(11) -0.0329(6) 0.7200(8) 0.051(3) Uani 1 1 d . U . . .
H25A H 0.2521 -0.0828 0.7644 0.061 Uiso 1 1 calc R U . . .
C26 C 0.2438(12) -0.0335(6) 0.6456(7) 0.046(3) Uani 1 1 d . U . . .
H26A H 0.2281 -0.0824 0.6402 0.056 Uiso 1 1 calc R U . . .
C27 C 0.2546(11) 0.0393(6) 0.5828(7) 0.048(3) Uani 1 1 d . U . . .
H27 H 0.2440 0.0407 0.5332 0.057 Uiso 1 1 calc R U . . .
C28 C 0.2808(11) 0.1118(6) 0.5887(7) 0.046(3) Uani 1 1 d . U . . .
C29 C 0.6644(11) 0.1577(5) 0.8996(8) 0.045(3) Uani 1 1 d . U . . .
C30 C 0.6810(11) 0.2271(5) 0.9135(8) 0.046(3) Uani 1 1 d . U . . .
C31 C 0.6792(13) 0.2196(6) 0.9887(9) 0.058(3) Uani 1 1 d . U . . .
H31 H 0.6905 0.2664 0.9989 0.070 Uiso 1 1 calc R U . . .
C32 C 0.6612(13) 0.1449(6) 1.0505(9) 0.056(3) Uani 1 1 d . U . . .
H32 H 0.6588 0.1404 1.1033 0.067 Uiso 1 1 calc R U . . .
C33 C 0.6467(12) 0.0762(6) 1.0364(8) 0.051(3) Uani 1 1 d . U . . .
H33 H 0.6356 0.0247 1.0793 0.061 Uiso 1 1 calc R U . . .
C34 C 0.6482(12) 0.0822(6) 0.9624(8) 0.050(3) Uani 1 1 d . U . . .
H34 H 0.6382 0.0350 0.9527 0.060 Uiso 1 1 calc R U . . .
C35 C 0.6664(12) 0.3677(6) 0.8569(9) 0.057(3) Uani 1 1 d . U . . .
H35A H 0.6229 0.3617 0.9107 0.069 Uiso 1 1 calc R U . . .
C36 C 0.6855(13) 0.4470(6) 0.7968(10) 0.063(3) Uani 1 1 d . U . . .
C37 C 0.7031(12) 0.4622(6) 0.7131(9) 0.058(3) Uani 1 1 d . U . . .
C38 C 0.7218(12) 0.5430(6) 0.6533(10) 0.064(3) Uani 1 1 d . U . . .
H38 H 0.7368 0.5523 0.5978 0.077 Uiso 1 1 calc R U . . .
C39 C 0.7179(14) 0.6059(7) 0.6765(10) 0.071(3) Uani 1 1 d . U . . .
H39 H 0.7291 0.6591 0.6364 0.085 Uiso 1 1 calc R U . . .
C40 C 0.6983(17) 0.5955(7) 0.7565(11) 0.083(2) Uani 1 1 d . U . . .
C41 C 0.6781(17) 0.5156(7) 0.8195(11) 0.083(2) Uani 1 1 d . U . . .
C42 C 0.6565(16) 0.5083(7) 0.8988(11) 0.083(2) Uani 1 1 d . U . . .
H42 H 0.6479 0.4559 0.9402 0.100 Uiso 1 1 calc R U . . .
C43 C 0.6469(16) 0.5758(7) 0.9203(11) 0.084(2) Uani 1 1 d . U . . .
H43A H 0.6260 0.5703 0.9750 0.100 Uiso 1 1 calc R U . . .
C44 C 0.6703(16) 0.6522(7) 0.8553(11) 0.083(2) Uani 1 1 d . U . . .
H44 H 0.6697 0.6988 0.8674 0.100 Uiso 1 1 calc R U . . .
C45 C 0.6926(16) 0.6621(7) 0.7796(11) 0.083(2) Uani 1 1 d . U . . .
H45 H 0.7053 0.7151 0.7391 0.100 Uiso 1 1 calc R U . . .
C46 C 0.6228(11) 0.1153(6) 0.8012(8) 0.051(3) Uani 1 1 d . U . . .
H46 H 0.5751 0.0696 0.8458 0.061 Uiso 1 1 calc R U . . .
C47 C 0.6305(11) 0.1211(6) 0.7212(8) 0.050(3) Uani 1 1 d . U . . .
C48 C 0.6415(11) 0.1964(6) 0.6546(8) 0.049(3) Uani 1 1 d . U . . .
C49 C 0.6366(12) 0.1968(6) 0.5763(8) 0.055(3) Uani 1 1 d . U . . .
H49A H 0.6427 0.2470 0.5323 0.066 Uiso 1 1 calc R U . . .
C50 C 0.6237(11) 0.1286(6) 0.5650(8) 0.049(3) Uani 1 1 d . U . . .
H50 H 0.6232 0.1320 0.5129 0.059 Uiso 1 1 calc R U . . .
C51 C 0.6106(11) 0.0508(6) 0.6291(8) 0.053(3) Uani 1 1 d . U . . .
C52 C 0.6183(11) 0.0478(6) 0.7069(8) 0.052(3) Uani 1 1 d . U . . .
C53 C 0.6132(11) -0.0317(5) 0.7680(8) 0.049(3) Uani 1 1 d . U . . .
H53 H 0.6195 -0.0367 0.8196 0.059 Uiso 1 1 calc R U . . .
C54 C 0.6001(11) -0.0983(6) 0.7553(8) 0.054(3) Uani 1 1 d . U . . .
H54 H 0.5971 -0.1494 0.7976 0.065 Uiso 1 1 calc R U . . .
C55 C 0.5903(12) -0.0938(6) 0.6770(8) 0.054(3) Uani 1 1 d . U . . .
H55A H 0.5792 -0.1418 0.6687 0.065 Uiso 1 1 calc R U . . .
C56 C 0.5972(11) -0.0197(6) 0.6154(8) 0.052(3) Uani 1 1 d . U . . .
H56 H 0.5929 -0.0161 0.5639 0.062 Uiso 1 1 calc R U . . .
C57 C 0.9491(8) 0.1108(4) 0.7513(5) 0.069(3) Uani 1 1 d G U . . .
C58 C 0.9670(8) 0.1269(3) 0.8153(6) 0.061(3) Uani 1 1 d G U . . .
C59 C 0.9718(8) 0.0637(5) 0.8866(5) 0.067(4) Uani 1 1 d G U . . .
H59 H 0.9841 0.0747 0.9303 0.081 Uiso 1 1 calc R U . . .
C60 C 0.9588(8) -0.0155(4) 0.8938(5) 0.069(4) Uani 1 1 d G U . . .
H60 H 0.9621 -0.0587 0.9425 0.083 Uiso 1 1 calc R U . . .
C61 C 0.9410(8) -0.0316(3) 0.8298(6) 0.075(4) Uani 1 1 d G U . . .
H61 H 0.9321 -0.0858 0.8347 0.090 Uiso 1 1 calc R U . . .
C62 C 0.9361(8) 0.0315(5) 0.7585(5) 0.070(4) Uani 1 1 d G U . . .
H62 H 0.9239 0.0206 0.7148 0.084 Uiso 1 1 calc R U . . .
C63 C 1.0046(13) 0.2322(7) 0.8537(10) 0.063(3) Uani 1 1 d . U . . .
H63 H 1.0387 0.1918 0.8927 0.076 Uiso 1 1 calc R U . . .
C64 C 1.0059(14) 0.3116(8) 0.8549(9) 0.067(3) Uani 1 1 d . U . . .
C65 C 0.9972(16) 0.3780(9) 0.7863(11) 0.071(3) Uani 1 1 d . U . . .
C66 C 1.0191(16) 0.4609(10) 0.7847(11) 0.082(4) Uani 1 1 d . U . . .
H66 H 1.0231 0.5075 0.7373 0.098 Uiso 1 1 calc R U . . .
C67 C 1.0315(17) 0.4670(10) 0.8448(11) 0.087(4) Uani 1 1 d . U . . .
H67 H 1.0339 0.5198 0.8443 0.105 Uiso 1 1 calc R U . . .
C68 C 1.0436(11) 0.3997(5) 0.9196(6) 0.087(3) Uani 1 1 d G U . . .
C69 C 1.0197(11) 0.3227(6) 0.9235(5) 0.074(3) Uani 1 1 d G U . . .
C70 C 1.0113(10) 0.2561(5) 0.9948(7) 0.078(3) Uani 1 1 d G U . . .
H70 H 0.9950 0.2035 0.9975 0.093 Uiso 1 1 calc R U . . .
C71 C 1.0268(11) 0.2666(6) 1.0622(5) 0.094(4) Uani 1 1 d G U . . .
H71 H 1.0210 0.2211 1.1109 0.112 Uiso 1 1 calc R U . . .
C72 C 1.0507(11) 0.3436(7) 1.0583(6) 0.100(4) Uani 1 1 d G U . . .
H72 H 1.0612 0.3508 1.1043 0.120 Uiso 1 1 calc R U . . .
C73 C 1.0590(11) 0.4102(5) 0.9870(7) 0.099(4) Uani 1 1 d G U . . .
H73 H 1.0754 0.4628 0.9843 0.118 Uiso 1 1 calc R U . . .
C74 C 0.9787(14) 0.1709(8) 0.6081(10) 0.070(4) Uani 1 1 d . U . . .
H74A H 1.0183 0.1223 0.6100 0.084 Uiso 1 1 calc R U . . .
C75 C 0.9723(11) 0.2274(6) 0.5237(5) 0.0836(16) Uani 1 1 d G U . . .
C76 C 0.9435(11) 0.3061(7) 0.5132(6) 0.0839(16) Uani 1 1 d G U . . .
C77 C 0.9274(11) 0.3595(5) 0.4397(7) 0.0844(16) Uani 1 1 d G U . . .
H77 H 0.9077 0.4133 0.4326 0.101 Uiso 1 1 calc R U . . .
C78 C 0.9402(10) 0.3341(6) 0.3766(5) 0.0844(16) Uani 1 1 d G U . . .
H78 H 0.9292 0.3706 0.3264 0.101 Uiso 1 1 calc R U . . .
C79 C 0.9690(11) 0.2554(7) 0.3871(6) 0.0841(15) Uani 1 1 d G U . . .
C80 C 0.9851(11) 0.2021(5) 0.4606(7) 0.0837(15) Uani 1 1 d G U . . .
C81 C 1.0220(16) 0.1240(10) 0.4636(11) 0.0839(16) Uani 1 1 d . U . . .
H81 H 1.0304 0.0841 0.5130 0.101 Uiso 1 1 calc R U . . .
C82 C 1.0446(16) 0.1063(10) 0.3986(10) 0.0840(16) Uani 1 1 d . U . . .
H82 H 1.0723 0.0545 0.4026 0.101 Uiso 1 1 calc R U . . .
C83 C 1.0295(16) 0.1606(10) 0.3247(10) 0.0840(16) Uani 1 1 d . U . . .
H83 H 1.0462 0.1467 0.2789 0.101 Uiso 1 1 calc R U . . .
C84 C 0.9894(16) 0.2352(10) 0.3212(10) 0.0841(16) Uani 1 1 d . U . . .
H84 H 0.9755 0.2732 0.2725 0.101 Uiso 1 1 calc R U . . .
O1S O 1.1529(14) 0.4499(8) 0.5375(7) 0.163(8) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O2 2.256(9) . ?
Eu1 O1 2.270(7) . ?
Eu1 O3 2.384(9) . ?
Eu1 O4 2.391(7) . ?
Eu1 O7 2.455(8) . ?
Eu1 N1 2.510(10) . ?
Eu1 N2 2.519(8) . ?
Eu1 Eu2 3.913(2) . ?
Eu2 O6 2.307(11) . ?
Eu2 O5 2.326(11) . ?
Eu2 O3 2.382(7) . ?
Eu2 O4 2.409(9) . ?
Eu2 N6 2.518(11) . ?
Eu2 N5 2.566(13) . ?
Eu2 N4 2.574(9) . ?
Eu2 N3 2.611(11) . ?
Eu2 C48 3.265(14) . ?
N1 C7 1.304(13) . ?
N1 C1 1.433(13) . ?
N2 C18 1.324(15) . ?
N2 C6 1.406(15) . ?
N3 C35 1.320(14) . ?
N3 C30 1.419(13) . ?
N4 C46 1.302(15) . ?
N4 C29 1.456(17) . ?
N5 C63 1.283(18) . ?
N5 C58 1.435(11) . ?
N6 C74 1.299(18) . ?
N6 C57 1.457(13) . ?
O1 C9 1.313(13) . ?
O2 C20 1.353(13) . ?
O3 C37 1.349(15) . ?
O4 C48 1.331(13) . ?
O5 C65 1.285(19) . ?
O6 C76 1.383(14) . ?
C1 C2 1.369(17) . ?
C1 C6 1.420(15) . ?
C2 C3 1.408(15) . ?
C2 H2 0.9500 . ?
C3 C4 1.394(15) . ?
C3 H3A 0.9500 . ?
C4 C5 1.402(18) . ?
C4 H4 0.9500 . ?
C5 C6 1.408(14) . ?
C5 H5 0.9500 . ?
C7 C8 1.434(13) . ?
C7 H7 0.9500 . ?
C8 C9 1.363(17) . ?
C8 C13 1.442(16) . ?
C9 C10 1.452(13) . ?
C10 C11 1.336(16) . ?
C10 H10A 0.9500 . ?
C11 C12 1.375(18) . ?
C11 H11 0.9500 . ?
C12 C17 1.415(16) . ?
C12 C13 1.426(14) . ?
C13 C14 1.373(19) . ?
C14 C15 1.420(18) . ?
C14 H14A 0.9500 . ?
C15 C16 1.387(16) . ?
C15 H15A 0.9500 . ?
C16 C17 1.371(19) . ?
C16 H16 0.9500 . ?
C17 H17 0.9500 . ?
C18 C19 1.401(18) . ?
C18 H18 0.9500 . ?
C19 C20 1.438(16) . ?
C19 C23 1.453(15) . ?
C20 C21 1.408(19) . ?
C21 C22 1.319(16) . ?
C21 H21 0.9500 . ?
C22 C28 1.410(15) . ?
C22 H22 0.9500 . ?
C23 C24 1.411(16) . ?
C23 C28 1.443(18) . ?
C24 C25 1.371(16) . ?
C24 H24A 0.9500 . ?
C25 C26 1.435(18) . ?
C25 H25A 0.9500 . ?
C26 C27 1.365(15) . ?
C26 H26A 0.9500 . ?
C27 C28 1.396(15) . ?
C27 H27 0.9500 . ?
C29 C34 1.391(14) . ?
C29 C30 1.396(15) . ?
C30 C31 1.351(18) . ?
C31 C32 1.373(16) . ?
C31 H31 0.9500 . ?
C32 C33 1.382(16) . ?
C32 H32 0.9500 . ?
C33 C34 1.337(18) . ?
C33 H33 0.9500 . ?
C34 H34 0.9500 . ?
C35 C36 1.416(15) . ?
C35 H35A 0.9500 . ?
C36 C37 1.44(2) . ?
C36 C41 1.445(19) . ?
C37 C38 1.434(15) . ?
C38 C39 1.356(18) . ?
C38 H38 0.9500 . ?
C39 C40 1.39(2) . ?
C39 H39 0.9500 . ?
C40 C45 1.42(2) . ?
C40 C41 1.444(19) . ?
C41 C42 1.39(2) . ?
C42 C43 1.411(19) . ?
C42 H42 0.9500 . ?
C43 C44 1.416(18) . ?
C43 H43A 0.9500 . ?
C44 C45 1.31(2) . ?
C44 H44 0.9500 . ?
C45 H45 0.9500 . ?
C46 C47 1.434(19) . ?
C46 H46 0.9500 . ?
C47 C48 1.426(15) . ?
C47 C52 1.460(16) . ?
C48 C49 1.471(19) . ?
C49 C50 1.341(16) . ?
C49 H49A 0.9500 . ?
C50 C51 1.432(15) . ?
C50 H50 0.9500 . ?
C51 C56 1.409(16) . ?
C51 C52 1.453(19) . ?
C52 C53 1.440(14) . ?
C53 C54 1.327(16) . ?
C53 H53 0.9500 . ?
C54 C55 1.462(19) . ?
C54 H54 0.9500 . ?
C55 C56 1.375(16) . ?
C55 H55A 0.9500 . ?
C56 H56 0.9500 . ?
C57 C58 1.3900 . ?
C57 C62 1.3900 . ?
C58 C59 1.3900 . ?
C59 C60 1.3900 . ?
C59 H59 0.9500 . ?
C60 C61 1.3900 . ?
C60 H60 0.9500 . ?
C61 C62 1.3900 . ?
C61 H61 0.9500 . ?
C62 H62 0.9500 . ?
C63 C64 1.441(18) . ?
C63 H63 0.9500 . ?
C64 C65 1.40(2) . ?
C64 C69 1.411(17) . ?
C65 C66 1.51(2) . ?
C66 C67 1.21(2) . ?
C66 H66 0.9500 . ?
C67 C68 1.488(19) . ?
C67 H67 0.9500 . ?
C68 C69 1.3900 . ?
C68 C73 1.3900 . ?
C69 C70 1.3900 . ?
C70 C71 1.3900 . ?
C70 H70 0.9500 . ?
C71 C72 1.3900 . ?
C71 H71 0.9500 . ?
C72 C73 1.3900 . ?
C72 H72 0.9500 . ?
C73 H73 0.9500 . ?
C74 C75 1.529(17) . ?
C74 H74A 0.9500 . ?
C75 C76 1.3900 . ?
C75 C80 1.3900 . ?
C76 C77 1.3900 . ?
C77 C78 1.3900 . ?
C77 H77 0.9500 . ?
C78 C79 1.3900 . ?
C78 H78 0.9500 . ?
C79 C84 1.372(17) . ?
C79 C80 1.3900 . ?
C80 C81 1.431(17) . ?
C81 C82 1.33(2) . ?
C81 H81 0.9500 . ?
C82 C83 1.40(2) . ?
C82 H82 0.9500 . ?
C83 C84 1.38(2) . ?
C83 H83 0.9500 . ?
C84 H84 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O2 Eu1 O1 95.4(3) . . ?
O2 Eu1 O3 160.5(3) . . ?
O1 Eu1 O3 96.2(3) . . ?
O2 Eu1 O4 95.2(3) . . ?
O1 Eu1 O4 162.4(3) . . ?
O3 Eu1 O4 70.0(3) . . ?
O2 Eu1 O7 83.9(3) . . ?
O1 Eu1 O7 79.8(2) . . ?
O3 Eu1 O7 82.8(3) . . ?
O4 Eu1 O7 87.5(2) . . ?
O2 Eu1 N1 116.6(3) . . ?
O1 Eu1 N1 71.0(3) . . ?
O3 Eu1 N1 82.1(3) . . ?
O4 Eu1 N1 116.1(3) . . ?
O7 Eu1 N1 145.2(3) . . ?
O2 Eu1 N2 71.4(3) . . ?
O1 Eu1 N2 119.3(3) . . ?
O3 Eu1 N2 115.6(3) . . ?
O4 Eu1 N2 77.5(2) . . ?
O7 Eu1 N2 149.5(3) . . ?
N1 Eu1 N2 64.7(3) . . ?
O2 Eu1 Eu2 130.40(19) . . ?
O1 Eu1 Eu2 130.8(2) . . ?
O3 Eu1 Eu2 34.79(17) . . ?
O4 Eu1 Eu2 35.5(2) . . ?
O7 Eu1 Eu2 87.5(2) . . ?
N1 Eu1 Eu2 97.4(2) . . ?
N2 Eu1 Eu2 94.9(2) . . ?
O6 Eu2 O5 89.9(4) . . ?
O6 Eu2 O3 92.4(3) . . ?
O5 Eu2 O3 85.5(3) . . ?
O6 Eu2 O4 81.0(3) . . ?
O5 Eu2 O4 153.1(3) . . ?
O3 Eu2 O4 69.8(3) . . ?
O6 Eu2 N6 70.2(4) . . ?
O5 Eu2 N6 112.7(4) . . ?
O3 Eu2 N6 154.0(4) . . ?
O4 Eu2 N6 88.1(3) . . ?
O6 Eu2 N5 116.6(4) . . ?
O5 Eu2 N5 69.5(3) . . ?
O3 Eu2 N5 140.6(4) . . ?
O4 Eu2 N5 137.1(3) . . ?
N6 Eu2 N5 65.3(4) . . ?
O6 Eu2 N4 136.3(4) . . ?
O5 Eu2 N4 130.7(4) . . ?
O3 Eu2 N4 104.6(3) . . ?
O4 Eu2 N4 68.3(3) . . ?
N6 Eu2 N4 78.1(3) . . ?
N5 Eu2 N4 73.4(3) . . ?
O6 Eu2 N3 158.0(3) . . ?
O5 Eu2 N3 78.5(4) . . ?
O3 Eu2 N3 68.4(3) . . ?
O4 Eu2 N3 101.0(3) . . ?
N6 Eu2 N3 131.4(3) . . ?
N5 Eu2 N3 76.9(3) . . ?
N4 Eu2 N3 62.2(3) . . ?
O6 Eu2 C48 80.1(4) . . ?
O5 Eu2 C48 169.2(4) . . ?
O3 Eu2 C48 90.7(3) . . ?
O4 Eu2 C48 20.9(2) . . ?
N6 Eu2 C48 67.9(3) . . ?
N5 Eu2 C48 118.8(3) . . ?
N4 Eu2 C48 60.1(3) . . ?
N3 Eu2 C48 109.5(3) . . ?
O6 Eu2 Eu1 89.5(3) . . ?
O5 Eu2 Eu1 120.2(2) . . ?
O3 Eu2 Eu1 34.8(2) . . ?
O4 Eu2 Eu1 35.23(15) . . ?
N6 Eu2 Eu1 122.9(3) . . ?
N5 Eu2 Eu1 153.0(2) . . ?
N4 Eu2 Eu1 83.1(2) . . ?
N3 Eu2 Eu1 80.6(2) . . ?
C48 Eu2 Eu1 56.04(19) . . ?
C7 N1 C1 116.0(10) . . ?
C7 N1 Eu1 129.2(7) . . ?
C1 N1 Eu1 114.8(7) . . ?
C18 N2 C6 117.8(9) . . ?
C18 N2 Eu1 126.7(8) . . ?
C6 N2 Eu1 115.3(7) . . ?
C35 N3 C30 118.9(12) . . ?
C35 N3 Eu2 126.6(8) . . ?
C30 N3 Eu2 114.4(7) . . ?
C46 N4 C29 119.2(9) . . ?
C46 N4 Eu2 125.4(9) . . ?
C29 N4 Eu2 115.1(7) . . ?
C63 N5 C58 119.6(12) . . ?
C63 N5 Eu2 126.2(8) . . ?
C58 N5 Eu2 113.3(9) . . ?
C74 N6 C57 120.8(11) . . ?
C74 N6 Eu2 128.0(10) . . ?
C57 N6 Eu2 111.1(8) . . ?
C9 O1 Eu1 138.1(8) . . ?
C20 O2 Eu1 137.0(8) . . ?
C37 O3 Eu2 124.0(8) . . ?
C37 O3 Eu1 123.4(7) . . ?
Eu2 O3 Eu1 110.4(3) . . ?
C48 O4 Eu1 131.4(8) . . ?
C48 O4 Eu2 118.7(7) . . ?
Eu1 O4 Eu2 109.2(3) . . ?
C65 O5 Eu2 129.5(10) . . ?
C76 O6 Eu2 135.1(7) . . ?
C2 C1 C6 119.5(10) . . ?
C2 C1 N1 124.2(11) . . ?
C6 C1 N1 116.1(11) . . ?
C1 C2 C3 123.2(11) . . ?
C1 C2 H2 118.4 . . ?
C3 C2 H2 118.4 . . ?
C4 C3 C2 117.7(13) . . ?
C4 C3 H3A 121.1 . . ?
C2 C3 H3A 121.1 . . ?
C3 C4 C5 120.0(10) . . ?
C3 C4 H4 120.0 . . ?
C5 C4 H4 120.0 . . ?
C4 C5 C6 121.8(11) . . ?
C4 C5 H5 119.1 . . ?
C6 C5 H5 119.1 . . ?
N2 C6 C5 125.2(10) . . ?
N2 C6 C1 117.1(9) . . ?
C5 C6 C1 117.7(12) . . ?
N1 C7 C8 127.7(12) . . ?
N1 C7 H7 116.2 . . ?
C8 C7 H7 116.2 . . ?
C9 C8 C7 121.1(11) . . ?
C9 C8 C13 119.8(9) . . ?
C7 C8 C13 118.7(11) . . ?
O1 C9 C8 124.6(9) . . ?
O1 C9 C10 117.0(11) . . ?
C8 C9 C10 118.4(11) . . ?
C11 C10 C9 121.7(13) . . ?
C11 C10 H10A 119.2 . . ?
C9 C10 H10A 119.2 . . ?
C10 C11 C12 121.5(10) . . ?
C10 C11 H11 119.2 . . ?
C12 C11 H11 119.2 . . ?
C11 C12 C17 119.3(10) . . ?
C11 C12 C13 119.2(11) . . ?
C17 C12 C13 121.4(12) . . ?
C14 C13 C12 116.1(11) . . ?
C14 C13 C8 124.7(10) . . ?
C12 C13 C8 119.3(12) . . ?
C13 C14 C15 124.1(12) . . ?
C13 C14 H14A 118.0 . . ?
C15 C14 H14A 118.0 . . ?
C16 C15 C14 116.9(14) . . ?
C16 C15 H15A 121.6 . . ?
C14 C15 H15A 121.6 . . ?
C17 C16 C15 122.3(13) . . ?
C17 C16 H16 118.8 . . ?
C15 C16 H16 118.8 . . ?
C16 C17 C12 118.9(11) . . ?
C16 C17 H17 120.6 . . ?
C12 C17 H17 120.6 . . ?
N2 C18 C19 126.9(10) . . ?
N2 C18 H18 116.5 . . ?
C19 C18 H18 116.5 . . ?
C18 C19 C20 124.6(11) . . ?
C18 C19 C23 120.6(10) . . ?
C20 C19 C23 114.6(12) . . ?
O2 C20 C21 118.8(10) . . ?
O2 C20 C19 118.0(12) . . ?
C21 C20 C19 123.2(11) . . ?
C22 C21 C20 119.1(11) . . ?
C22 C21 H21 120.5 . . ?
C20 C21 H21 120.5 . . ?
C21 C22 C28 124.3(14) . . ?
C21 C22 H22 117.8 . . ?
C28 C22 H22 117.8 . . ?
C24 C23 C28 116.4(11) . . ?
C24 C23 C19 122.3(13) . . ?
C28 C23 C19 121.2(11) . . ?
C25 C24 C23 121.4(13) . . ?
C25 C24 H24A 119.3 . . ?
C23 C24 H24A 119.3 . . ?
C24 C25 C26 121.9(11) . . ?
C24 C25 H25A 119.0 . . ?
C26 C25 H25A 119.0 . . ?
C27 C26 C25 117.2(11) . . ?
C27 C26 H26A 121.4 . . ?
C25 C26 H26A 121.4 . . ?
C26 C27 C28 122.3(13) . . ?
C26 C27 H27 118.8 . . ?
C28 C27 H27 118.8 . . ?
C27 C28 C22 122.1(13) . . ?
C27 C28 C23 120.7(11) . . ?
C22 C28 C23 117.1(11) . . ?
C34 C29 C30 120.1(13) . . ?
C34 C29 N4 123.4(11) . . ?
C30 C29 N4 116.3(10) . . ?
C31 C30 C29 119.0(11) . . ?
C31 C30 N3 124.3(11) . . ?
C29 C30 N3 116.7(12) . . ?
C30 C31 C32 120.4(13) . . ?
C30 C31 H31 119.8 . . ?
C32 C31 H31 119.8 . . ?
C31 C32 C33 120.6(14) . . ?
C31 C32 H32 119.7 . . ?
C33 C32 H32 119.7 . . ?
C34 C33 C32 120.0(12) . . ?
C34 C33 H33 120.0 . . ?
C32 C33 H33 120.0 . . ?
C33 C34 C29 119.9(12) . . ?
C33 C34 H34 120.0 . . ?
C29 C34 H34 120.0 . . ?
N3 C35 C36 126.4(14) . . ?
N3 C35 H35A 116.8 . . ?
C36 C35 H35A 116.8 . . ?
C35 C36 C37 121.9(12) . . ?
C35 C36 C41 120.1(15) . . ?
C37 C36 C41 117.9(11) . . ?
O3 C37 C38 117.5(14) . . ?
O3 C37 C36 121.4(10) . . ?
C38 C37 C36 121.0(13) . . ?
C39 C38 C37 119.5(15) . . ?
C39 C38 H38 120.3 . . ?
C37 C38 H38 120.3 . . ?
C38 C39 C40 122.5(13) . . ?
C38 C39 H39 118.7 . . ?
C40 C39 H39 118.7 . . ?
C39 C40 C45 121.6(13) . . ?
C39 C40 C41 120.4(14) . . ?
C45 C40 C41 117.9(17) . . ?
C42 C41 C36 123.1(13) . . ?
C42 C41 C40 118.3(14) . . ?
C36 C41 C40 118.6(16) . . ?
C41 C42 C43 122.4(14) . . ?
C41 C42 H42 118.8 . . ?
C43 C42 H42 118.8 . . ?
C42 C43 C44 116.0(17) . . ?
C42 C43 H43A 122.0 . . ?
C44 C43 H43A 122.0 . . ?
C45 C44 C43 123.7(15) . . ?
C45 C44 H44 118.2 . . ?
C43 C44 H44 118.2 . . ?
C44 C45 C40 121.5(14) . . ?
C44 C45 H45 119.3 . . ?
C40 C45 H45 119.3 . . ?
N4 C46 C47 123.4(10) . . ?
N4 C46 H46 118.3 . . ?
C47 C46 H46 118.3 . . ?
C48 C47 C46 122.7(11) . . ?
C48 C47 C52 117.6(13) . . ?
C46 C47 C52 119.6(10) . . ?
O4 C48 C47 121.5(13) . . ?
O4 C48 C49 119.5(10) . . ?
C47 C48 C49 119.0(11) . . ?
O4 C48 Eu2 40.3(6) . . ?
C47 C48 Eu2 96.1(9) . . ?
C49 C48 Eu2 133.9(7) . . ?
C50 C49 C48 122.3(11) . . ?
C50 C49 H49A 118.9 . . ?
C48 C49 H49A 118.9 . . ?
C49 C50 C51 121.9(14) . . ?
C49 C50 H50 119.1 . . ?
C51 C50 H50 119.1 . . ?
C56 C51 C50 120.6(13) . . ?
C56 C51 C52 121.8(11) . . ?
C50 C51 C52 117.5(11) . . ?
C53 C52 C51 115.6(11) . . ?
C53 C52 C47 122.8(13) . . ?
C51 C52 C47 121.6(10) . . ?
C54 C53 C52 122.7(14) . . ?
C54 C53 H53 118.6 . . ?
C52 C53 H53 118.6 . . ?
C53 C54 C55 120.8(11) . . ?
C53 C54 H54 119.6 . . ?
C55 C54 H54 119.6 . . ?
C56 C55 C54 119.5(12) . . ?
C56 C55 H55A 120.3 . . ?
C54 C55 H55A 120.3 . . ?
C55 C56 C51 119.6(14) . . ?
C55 C56 H56 120.2 . . ?
C51 C56 H56 120.2 . . ?
C58 C57 C62 120.0 . . ?
C58 C57 N6 119.7(8) . . ?
C62 C57 N6 120.2(8) . . ?
C59 C58 C57 120.0 . . ?
C59 C58 N5 123.6(8) . . ?
C57 C58 N5 115.9(9) . . ?
C58 C59 C60 120.0 . . ?
C58 C59 H59 120.0 . . ?
C60 C59 H59 120.0 . . ?
C59 C60 C61 120.0 . . ?
C59 C60 H60 120.0 . . ?
C61 C60 H60 120.0 . . ?
C62 C61 C60 120.0 . . ?
C62 C61 H61 120.0 . . ?
C60 C61 H61 120.0 . . ?
C61 C62 C57 120.0 . . ?
C61 C62 H62 120.0 . . ?
C57 C62 H62 120.0 . . ?
N5 C63 C64 127.6(14) . . ?
N5 C63 H63 116.2 . . ?
C64 C63 H63 116.2 . . ?
C65 C64 C69 120.3(13) . . ?
C65 C64 C63 119.1(15) . . ?
C69 C64 C63 120.5(13) . . ?
O5 C65 C64 126.9(15) . . ?
O5 C65 C66 115.4(15) . . ?
C64 C65 C66 117.7(16) . . ?
C67 C66 C65 118.9(18) . . ?
C67 C66 H66 120.5 . . ?
C65 C66 H66 120.5 . . ?
C66 C67 C68 126.3(17) . . ?
C66 C67 H67 116.9 . . ?
C68 C67 H67 116.9 . . ?
C69 C68 C73 120.0 . . ?
C69 C68 C67 115.4(11) . . ?
C73 C68 C67 124.0(10) . . ?
C68 C69 C70 120.0 . . ?
C68 C69 C64 120.2(9) . . ?
C70 C69 C64 119.8(9) . . ?
C71 C70 C69 120.0 . . ?
C71 C70 H70 120.0 . . ?
C69 C70 H70 120.0 . . ?
C70 C71 C72 120.0 . . ?
C70 C71 H71 120.0 . . ?
C72 C71 H71 120.0 . . ?
C73 C72 C71 120.0 . . ?
C73 C72 H72 120.0 . . ?
C71 C72 H72 120.0 . . ?
C72 C73 C68 120.0 . . ?
C72 C73 H73 120.0 . . ?
C68 C73 H73 120.0 . . ?
N6 C74 C75 131.9(13) . . ?
N6 C74 H74A 114.1 . . ?
C75 C74 H74A 114.1 . . ?
C76 C75 C80 120.0 . . ?
C76 C75 C74 116.7(9) . . ?
C80 C75 C74 123.1(9) . . ?
O6 C76 C77 117.5(9) . . ?
O6 C76 C75 122.4(9) . . ?
C77 C76 C75 120.0 . . ?
C78 C77 C76 120.0 . . ?
C78 C77 H77 120.0 . . ?
C76 C77 H77 120.0 . . ?
C77 C78 C79 120.0 . . ?
C77 C78 H78 120.0 . . ?
C79 C78 H78 120.0 . . ?
C84 C79 C80 122.3(11) . . ?
C84 C79 C78 117.6(11) . . ?
C80 C79 C78 120.0 . . ?
C79 C80 C75 120.0 . . ?
C79 C80 C81 115.5(11) . . ?
C75 C80 C81 124.4(11) . . ?
C82 C81 C80 121.2(16) . . ?
C82 C81 H81 119.4 . . ?
C80 C81 H81 119.4 . . ?
C81 C82 C83 122.8(17) . . ?
C81 C82 H82 118.6 . . ?
C83 C82 H82 118.6 . . ?
C84 C83 C82 116.9(17) . . ?
C84 C83 H83 121.5 . . ?
C82 C83 H83 121.5 . . ?
C79 C84 C83 121.1(16) . . ?
C79 C84 H84 119.4 . . ?
C83 C84 H84 119.4 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C7 N1 C1 C2 -31.9(17) . . . . ?
Eu1 N1 C1 C2 148.1(10) . . . . ?
C7 N1 C1 C6 152.7(11) . . . . ?
Eu1 N1 C1 C6 -27.3(13) . . . . ?
C6 C1 C2 C3 -2.4(19) . . . . ?
N1 C1 C2 C3 -177.8(11) . . . . ?
C1 C2 C3 C4 1.3(19) . . . . ?
C2 C3 C4 C5 -1.2(18) . . . . ?
C3 C4 C5 C6 2.2(18) . . . . ?
C18 N2 C6 C5 22.8(16) . . . . ?
Eu1 N2 C6 C5 -152.1(9) . . . . ?
C18 N2 C6 C1 -159.4(10) . . . . ?
Eu1 N2 C6 C1 25.7(12) . . . . ?
C4 C5 C6 N2 174.5(10) . . . . ?
C4 C5 C6 C1 -3.3(17) . . . . ?
C2 C1 C6 N2 -174.6(11) . . . . ?
N1 C1 C6 N2 1.1(15) . . . . ?
C2 C1 C6 C5 3.3(17) . . . . ?
N1 C1 C6 C5 179.0(10) . . . . ?
C1 N1 C7 C8 176.6(13) . . . . ?
Eu1 N1 C7 C8 -3(2) . . . . ?
N1 C7 C8 C9 20(2) . . . . ?
N1 C7 C8 C13 -167.4(12) . . . . ?
Eu1 O1 C9 C8 -29.3(19) . . . . ?
Eu1 O1 C9 C10 151.3(9) . . . . ?
C7 C8 C9 O1 -6(2) . . . . ?
C13 C8 C9 O1 -178.6(12) . . . . ?
C7 C8 C9 C10 173.8(12) . . . . ?
C13 C8 C9 C10 0.8(19) . . . . ?
O1 C9 C10 C11 177.9(12) . . . . ?
C8 C9 C10 C11 -2(2) . . . . ?
C9 C10 C11 C12 1(2) . . . . ?
C10 C11 C12 C17 179.2(14) . . . . ?
C10 C11 C12 C13 0(2) . . . . ?
C11 C12 C13 C14 178.3(13) . . . . ?
C17 C12 C13 C14 -1(2) . . . . ?
C11 C12 C13 C8 0(2) . . . . ?
C17 C12 C13 C8 -179.9(12) . . . . ?
C9 C8 C13 C14 -178.6(13) . . . . ?
C7 C8 C13 C14 8(2) . . . . ?
C9 C8 C13 C12 0.1(19) . . . . ?
C7 C8 C13 C12 -173.0(12) . . . . ?
C12 C13 C14 C15 4(2) . . . . ?
C8 C13 C14 C15 -177.7(14) . . . . ?
C13 C14 C15 C16 -6(2) . . . . ?
C14 C15 C16 C17 6(2) . . . . ?
C15 C16 C17 C12 -4(2) . . . . ?
C11 C12 C17 C16 -178.0(14) . . . . ?
C13 C12 C17 C16 1(2) . . . . ?
C6 N2 C18 C19 -177.5(11) . . . . ?
Eu1 N2 C18 C19 -3.3(16) . . . . ?
N2 C18 C19 C20 -23.8(19) . . . . ?
N2 C18 C19 C23 162.2(11) . . . . ?
Eu1 O2 C20 C21 -146.1(10) . . . . ?
Eu1 O2 C20 C19 34.9(16) . . . . ?
C18 C19 C20 O2 11.4(18) . . . . ?
C23 C19 C20 O2 -174.2(10) . . . . ?
C18 C19 C20 C21 -167.5(12) . . . . ?
C23 C19 C20 C21 6.8(17) . . . . ?
O2 C20 C21 C22 175.0(10) . . . . ?
C19 C20 C21 C22 -6.1(19) . . . . ?
C20 C21 C22 C28 -0.2(19) . . . . ?
C18 C19 C23 C24 -11.7(17) . . . . ?
C20 C19 C23 C24 173.7(11) . . . . ?
C18 C19 C23 C28 172.8(11) . . . . ?
C20 C19 C23 C28 -1.8(16) . . . . ?
C28 C23 C24 C25 -0.6(17) . . . . ?
C19 C23 C24 C25 -176.4(10) . . . . ?
C23 C24 C25 C26 -2.0(18) . . . . ?
C24 C25 C26 C27 1.6(18) . . . . ?
C25 C26 C27 C28 1.6(18) . . . . ?
C26 C27 C28 C22 179.0(11) . . . . ?
C26 C27 C28 C23 -4.3(18) . . . . ?
C21 C22 C28 C27 -178.3(11) . . . . ?
C21 C22 C28 C23 4.9(18) . . . . ?
C24 C23 C28 C27 3.7(17) . . . . ?
C19 C23 C28 C27 179.5(11) . . . . ?
C24 C23 C28 C22 -179.5(10) . . . . ?
C19 C23 C28 C22 -3.7(17) . . . . ?
C46 N4 C29 C34 28.5(17) . . . . ?
Eu2 N4 C29 C34 -145.8(10) . . . . ?
C46 N4 C29 C30 -157.3(11) . . . . ?
Eu2 N4 C29 C30 28.4(13) . . . . ?
C34 C29 C30 C31 -0.9(19) . . . . ?
N4 C29 C30 C31 -175.3(11) . . . . ?
C34 C29 C30 N3 177.0(11) . . . . ?
N4 C29 C30 N3 2.6(16) . . . . ?
C35 N3 C30 C31 -30.2(18) . . . . ?
Eu2 N3 C30 C31 146.0(11) . . . . ?
C35 N3 C30 C29 152.1(11) . . . . ?
Eu2 N3 C30 C29 -31.8(13) . . . . ?
C29 C30 C31 C32 0(2) . . . . ?
N3 C30 C31 C32 -177.8(12) . . . . ?
C30 C31 C32 C33 1(2) . . . . ?
C31 C32 C33 C34 -1(2) . . . . ?
C32 C33 C34 C29 0(2) . . . . ?
C30 C29 C34 C33 0.9(19) . . . . ?
N4 C29 C34 C33 174.9(11) . . . . ?
C30 N3 C35 C36 177.5(13) . . . . ?
Eu2 N3 C35 C36 1.8(19) . . . . ?
N3 C35 C36 C37 24(2) . . . . ?
N3 C35 C36 C41 -160.8(13) . . . . ?
Eu2 O3 C37 C38 124.5(10) . . . . ?
Eu1 O3 C37 C38 -74.3(13) . . . . ?
Eu2 O3 C37 C36 -59.9(15) . . . . ?
Eu1 O3 C37 C36 101.3(13) . . . . ?
C35 C36 C37 O3 4(2) . . . . ?
C41 C36 C37 O3 -171.3(12) . . . . ?
C35 C36 C37 C38 179.8(12) . . . . ?
C41 C36 C37 C38 4(2) . . . . ?
O3 C37 C38 C39 173.2(12) . . . . ?
C36 C37 C38 C39 -2(2) . . . . ?
C37 C38 C39 C40 1(2) . . . . ?
C38 C39 C40 C45 -179.0(15) . . . . ?
C38 C39 C40 C41 -1(3) . . . . ?
C35 C36 C41 C42 2(2) . . . . ?
C37 C36 C41 C42 177.6(15) . . . . ?
C35 C36 C41 C40 179.9(14) . . . . ?
C37 C36 C41 C40 -4(2) . . . . ?
C39 C40 C41 C42 -178.9(16) . . . . ?
C45 C40 C41 C42 -1(3) . . . . ?
C39 C40 C41 C36 3(3) . . . . ?
C45 C40 C41 C36 -179.1(14) . . . . ?
C36 C41 C42 C43 -178.7(15) . . . . ?
C40 C41 C42 C43 3(3) . . . . ?
C41 C42 C43 C44 -5(3) . . . . ?
C42 C43 C44 C45 4(3) . . . . ?
C43 C44 C45 C40 -2(3) . . . . ?
C39 C40 C45 C44 178.0(17) . . . . ?
C41 C40 C45 C44 0(3) . . . . ?
C29 N4 C46 C47 -179.9(10) . . . . ?
Eu2 N4 C46 C47 -6.2(16) . . . . ?
N4 C46 C47 C48 -30.1(19) . . . . ?
N4 C46 C47 C52 153.9(11) . . . . ?
Eu1 O4 C48 C47 -112.1(12) . . . . ?
Eu2 O4 C48 C47 58.0(12) . . . . ?
Eu1 O4 C48 C49 65.5(13) . . . . ?
Eu2 O4 C48 C49 -124.4(10) . . . . ?
Eu1 O4 C48 Eu2 -170.1(12) . . . . ?
C46 C47 C48 O4 3.2(18) . . . . ?
C52 C47 C48 O4 179.3(10) . . . . ?
C46 C47 C48 C49 -174.4(11) . . . . ?
C52 C47 C48 C49 1.6(17) . . . . ?
C46 C47 C48 Eu2 36.7(12) . . . . ?
C52 C47 C48 Eu2 -147.2(9) . . . . ?
O4 C48 C49 C50 -178.6(10) . . . . ?
C47 C48 C49 C50 -0.9(18) . . . . ?
Eu2 C48 C49 C50 133.6(10) . . . . ?
C48 C49 C50 C51 1.6(19) . . . . ?
C49 C50 C51 C56 180.0(11) . . . . ?
C49 C50 C51 C52 -3.0(18) . . . . ?
C56 C51 C52 C53 0.9(17) . . . . ?
C50 C51 C52 C53 -176.1(10) . . . . ?
C56 C51 C52 C47 -179.2(11) . . . . ?
C50 C51 C52 C47 3.8(17) . . . . ?
C48 C47 C52 C53 176.8(11) . . . . ?
C46 C47 C52 C53 -7.1(18) . . . . ?
C48 C47 C52 C51 -3.2(17) . . . . ?
C46 C47 C52 C51 173.0(11) . . . . ?
C51 C52 C53 C54 -1.1(17) . . . . ?
C47 C52 C53 C54 178.9(11) . . . . ?
C52 C53 C54 C55 0.1(18) . . . . ?
C53 C54 C55 C56 1.2(18) . . . . ?
C54 C55 C56 C51 -1.4(18) . . . . ?
C50 C51 C56 C55 177.3(11) . . . . ?
C52 C51 C56 C55 0.4(18) . . . . ?
C74 N6 C57 C58 150.3(11) . . . . ?
Eu2 N6 C57 C58 -33.2(8) . . . . ?
C74 N6 C57 C62 -31.6(14) . . . . ?
Eu2 N6 C57 C62 144.8(5) . . . . ?
C62 C57 C58 C59 0.0 . . . . ?
N6 C57 C58 C59 178.0(8) . . . . ?
C62 C57 C58 N5 -172.4(8) . . . . ?
N6 C57 C58 N5 5.6(9) . . . . ?
C63 N5 C58 C59 22.2(14) . . . . ?
Eu2 N5 C58 C59 -147.4(5) . . . . ?
C63 N5 C58 C57 -165.7(10) . . . . ?
Eu2 N5 C58 C57 24.7(8) . . . . ?
C57 C58 C59 C60 0.0 . . . . ?
N5 C58 C59 C60 171.8(9) . . . . ?
C58 C59 C60 C61 0.0 . . . . ?
C59 C60 C61 C62 0.0 . . . . ?
C60 C61 C62 C57 0.0 . . . . ?
C58 C57 C62 C61 0.0 . . . . ?
N6 C57 C62 C61 -178.0(8) . . . . ?
C58 N5 C63 C64 -178.7(12) . . . . ?
Eu2 N5 C63 C64 -11(2) . . . . ?
N5 C63 C64 C65 -20(2) . . . . ?
N5 C63 C64 C69 162.0(14) . . . . ?
Eu2 O5 C65 C64 42(2) . . . . ?
Eu2 O5 C65 C66 -140.7(11) . . . . ?
C69 C64 C65 O5 -175.3(15) . . . . ?
C63 C64 C65 O5 7(3) . . . . ?
C69 C64 C65 C66 7(2) . . . . ?
C63 C64 C65 C66 -171.0(13) . . . . ?
O5 C65 C66 C67 175.6(17) . . . . ?
C64 C65 C66 C67 -7(2) . . . . ?
C65 C66 C67 C68 8(3) . . . . ?
C66 C67 C68 C69 -9(2) . . . . ?
C66 C67 C68 C73 179.3(16) . . . . ?
C73 C68 C69 C70 0.0 . . . . ?
C67 C68 C69 C70 -171.5(12) . . . . ?
C73 C68 C69 C64 -179.0(12) . . . . ?
C67 C68 C69 C64 9.4(13) . . . . ?
C65 C64 C69 C68 -9.2(18) . . . . ?
C63 C64 C69 C68 168.9(10) . . . . ?
C65 C64 C69 C70 171.7(11) . . . . ?
C63 C64 C69 C70 -10.1(17) . . . . ?
C68 C69 C70 C71 0.0 . . . . ?
C64 C69 C70 C71 179.0(12) . . . . ?
C69 C70 C71 C72 0.0 . . . . ?
C70 C71 C72 C73 0.0 . . . . ?
C71 C72 C73 C68 0.0 . . . . ?
C69 C68 C73 C72 0.0 . . . . ?
C67 C68 C73 C72 170.8(13) . . . . ?
C57 N6 C74 C75 175.4(12) . . . . ?
Eu2 N6 C74 C75 0(2) . . . . ?
N6 C74 C75 C76 14.1(19) . . . . ?
N6 C74 C75 C80 -161.5(13) . . . . ?
Eu2 O6 C76 C77 133.8(8) . . . . ?
Eu2 O6 C76 C75 -49.3(14) . . . . ?
C80 C75 C76 O6 -176.9(11) . . . . ?
C74 C75 C76 O6 7.3(11) . . . . ?
C80 C75 C76 C77 0.0 . . . . ?
C74 C75 C76 C77 -175.7(10) . . . . ?
O6 C76 C77 C78 177.1(11) . . . . ?
C75 C76 C77 C78 0.0 . . . . ?
C76 C77 C78 C79 0.0 . . . . ?
C77 C78 C79 C84 -175.7(12) . . . . ?
C77 C78 C79 C80 0.0 . . . . ?
C84 C79 C80 C75 175.5(13) . . . . ?
C78 C79 C80 C75 0.0 . . . . ?
C84 C79 C80 C81 -1.1(14) . . . . ?
C78 C79 C80 C81 -176.5(11) . . . . ?
C76 C75 C80 C79 0.0 . . . . ?
C74 C75 C80 C79 175.5(11) . . . . ?
C76 C75 C80 C81 176.2(12) . . . . ?
C74 C75 C80 C81 -8.3(14) . . . . ?
C79 C80 C81 C82 3(2) . . . . ?
C75 C80 C81 C82 -173.4(13) . . . . ?
C80 C81 C82 C83 -2(3) . . . . ?
C81 C82 C83 C84 0(3) . . . . ?
C80 C79 C84 C83 -1(2) . . . . ?
C78 C79 C84 C83 174.3(12) . . . . ?
C82 C83 C84 C79 2(2) . . . . ?

_refine_diff_density_max         1.196
_refine_diff_density_min         -1.808
_refine_diff_density_rms         0.188

