# Electronic Supplementary Material (ESI) for Inorganic Chemistry Frontiers.
# This journal is © the Partner Organisations 2023

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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data_1
_database_code_depnum_ccdc_archive 'CCDC 2221344'
loop_
_audit_author_name
_audit_author_address
'Tian Han'
;Xian Jiaotong University
China
;
_audit_update_record             
;
2022-11-22 deposited with the CCDC.	2023-02-06 downloaded from the CCDC.
;
_audit_creation_date             2022-11-04
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         '2(C36 H44 Dy0.5 N2 Si), C24 H48 K O6'
_chemical_formula_sum            'C96 H136 Dy K N4 O6 Si2'
_chemical_formula_weight         1699.86
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
K K 0.2009 0.2494 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      tetragonal
_space_group_IT_number           86
_space_group_name_H-M_alt        'P 42/n'
_space_group_name_Hall           '-P 4bc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-y, x+1/2, z+1/2'
'-x+1/2, -y+1/2, z'
'y+1/2, -x, z+1/2'
'-x, -y, -z'
'y, -x-1/2, -z-1/2'
'x-1/2, y-1/2, -z'
'-y-1/2, x, -z-1/2'

_cell_length_a                   27.6854(7)
_cell_length_b                   27.6854(7)
_cell_length_c                   23.5921(5)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     18082.9(10)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    9939
_cell_measurement_temperature    100.46
_cell_measurement_theta_max      27.47
_cell_measurement_theta_min      2.33
_shelx_estimated_absorpt_T_max   0.770
_shelx_estimated_absorpt_T_min   0.714
_exptl_absorpt_coefficient_mu    0.953
_exptl_absorpt_correction_T_max  0.0289
_exptl_absorpt_correction_T_min  0.0098
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1379 before and 0.0789 after correction.
The Ratio of minimum to maximum transmission is 0.3391.
The λ/2 correction factor is Not present.
;
_exptl_crystal_colour            'clear light yellow'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.249
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             7208
_exptl_crystal_size_max          0.38
_exptl_crystal_size_mid          0.35
_exptl_crystal_size_min          0.29
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0588
_diffrn_reflns_av_unetI/netI     0.0495
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.994
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -35
_diffrn_reflns_limit_k_max       35
_diffrn_reflns_limit_k_min       -35
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            86911
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.994
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.472
_diffrn_reflns_theta_min         2.253
_diffrn_ambient_temperature      100.46
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                16170
_reflns_number_total             20591
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.38A (Bruker, 2018)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.38A (Bruker, 2018)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'XS  (Sheldrick, 2008)'
_refine_diff_density_max         1.547
_refine_diff_density_min         -0.791
_refine_diff_density_rms         0.077
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.056
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1008
_refine_ls_number_reflns         20591
_refine_ls_number_restraints     61
_refine_ls_R_factor_all          0.0675
_refine_ls_R_factor_gt           0.0489
_refine_ls_restrained_S_all      1.079
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0397P)²+26.2318P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1063
_refine_ls_wR_factor_ref         0.1159
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 C90-C89
 1.52 with sigma of 0.01
3. Uiso/Uaniso restraints and constraints
O5 \\sim C89 \\sim C90 \\sim C91 \\sim C92: within 2A with sigma of 0.01 and
sigma for terminal atoms of 0.02
O1 \\sim C73 \\sim C74 \\sim C75 \\sim C76: within 2A with sigma of 0.01 and
sigma for terminal atoms of 0.02
4.a Ternary CH refined with riding coordinates:
 C2(H2), C11(H11), C27(H27), C34(H34), C38(H38), C46(H46), C62(H62), C70(H70)
4.b Secondary CH2 refined with riding coordinates:
 C73(H73A,H73B), C74(H74A,H74B), C75(H75A,H75B), C76(H76A,H76B), C77(H77A,
 H77B), C78(H78A,H78B), C79(H79A,H79B), C80(H80A,H80B), C81(H81A,H81B),
 C82(H82A,H82B), C83(H83A,H83B), C84(H84A,H84B), C85(H85A,H85B), C86(H86A,H86B),
  C87(H87A,H87B), C88(H88A,H88B), C89(H89A,H89B), C90(H90A,H90B), C91(H91A,
 H91B), C92(H92A,H92B), C93(H93A,H93B), C94(H94A,H94B), C95(H95A,H95B),
 C96(H96A,H96B)
4.c Aromatic/amide H refined with riding coordinates:
 C5(H5), C6(H6), C7(H7), C14(H14), C15(H15), C16(H16), C17(H17), C18(H18),
 C20(H20), C21(H21), C22(H22), C23(H23), C24(H24), C29(H29), C30(H30), C31(H31),
  C41(H41), C42(H42), C43(H43), C50(H50), C51(H51), C52(H52), C53(H53),
 C54(H54), C56(H56), C57(H57), C58(H58), C59(H59), C60(H60), C65(H65), C66(H66),
  C67(H67)
4.d Idealised Me refined as rotating group:
 C1(H1A,H1B,H1C), C3(H3A,H3B,H3C), C10(H10A,H10B,H10C), C12(H12A,H12B,H12C),
 C25(H25A,H25B,H25C), C26(H26A,H26B,H26C), C35(H35A,H35B,H35C), C36(H36A,H36B,
 H36C), C37(H37A,H37B,H37C), C39(H39A,H39B,H39C), C47(H47A,H47B,H47C), C48(H48A,
 H48B,H48C), C61(H61A,H61B,H61C), C63(H63A,H63B,H63C), C71(H71A,H71B,H71C),
 C72(H72A,H72B,H72C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.750000 -0.250000 0.45359(2) 0.02483(6) Uani 1 2 d S T P . .
Si1 Si 0.82617(3) -0.18402(3) 0.49894(3) 0.02498(18) Uani 1 1 d . . . . .
N1 N 0.82545(10) -0.24598(10) 0.49346(11) 0.0267(6) Uani 1 1 d . . . . .
N2 N 0.77409(9) -0.17143(9) 0.46143(10) 0.0258(5) Uani 1 1 d . . . . .
C1 C 0.84646(14) -0.33907(14) 0.35823(15) 0.0400(8) Uani 1 1 d . . . . .
H1A H 0.875516 -0.358312 0.350928 0.060 Uiso 1 1 calc GR . . . .
H1B H 0.830074 -0.332214 0.322299 0.060 Uiso 1 1 calc GR . . . .
H1C H 0.824676 -0.357131 0.383178 0.060 Uiso 1 1 calc GR . . . .
C2 C 0.86075(13) -0.29139(13) 0.38684(14) 0.0336(7) Uani 1 1 d . . . . .
H2 H 0.830685 -0.271920 0.392274 0.040 Uiso 1 1 calc R . . . .
C3 C 0.89471(14) -0.26257(14) 0.34757(15) 0.0407(8) Uani 1 1 d . . . . .
H3A H 0.901622 -0.231034 0.364609 0.061 Uiso 1 1 calc GR . . . .
H3B H 0.879138 -0.257920 0.310667 0.061 Uiso 1 1 calc GR . . . .
H3C H 0.924961 -0.280439 0.342472 0.061 Uiso 1 1 calc GR . . . .
C4 C 0.88298(12) -0.30013(12) 0.44518(14) 0.0307(7) Uani 1 1 d . . . . .
C5 C 0.92323(13) -0.33003(13) 0.44743(15) 0.0359(8) Uani 1 1 d . . . . .
H5 H 0.935565 -0.343163 0.413157 0.043 Uiso 1 1 calc R . . . .
C6 C 0.94586(13) -0.34124(13) 0.49780(15) 0.0362(8) Uani 1 1 d . . . . .
H6 H 0.973293 -0.361839 0.498407 0.043 Uiso 1 1 calc R . . . .
C7 C 0.92764(13) -0.32176(13) 0.54756(15) 0.0351(8) Uani 1 1 d . . . . .
H7 H 0.942809 -0.329473 0.582533 0.042 Uiso 1 1 calc R . . . .
C8 C 0.88752(12) -0.29105(12) 0.54760(14) 0.0294(7) Uani 1 1 d . . . . .
C9 C 0.86482(12) -0.27832(12) 0.49592(13) 0.0271(7) Uani 1 1 d . . . . .
C10 C 0.85232(15) -0.31335(15) 0.64249(16) 0.0445(9) Uani 1 1 d . . . . .
H10A H 0.829011 -0.333556 0.622120 0.067 Uiso 1 1 calc GR . . . .
H10B H 0.836993 -0.299832 0.676410 0.067 Uiso 1 1 calc GR . . . .
H10C H 0.880184 -0.332999 0.653660 0.067 Uiso 1 1 calc GR . . . .
C11 C 0.86917(13) -0.27217(13) 0.60385(14) 0.0345(8) Uani 1 1 d . . . . .
H11 H 0.840487 -0.251295 0.595851 0.041 Uiso 1 1 calc R . . . .
C12 C 0.90661(16) -0.24099(15) 0.63379(18) 0.0496(10) Uani 1 1 d . . . . .
H12A H 0.933775 -0.261219 0.645861 0.074 Uiso 1 1 calc GR . . . .
H12B H 0.891901 -0.225686 0.667028 0.074 Uiso 1 1 calc GR . . . .
H12C H 0.918255 -0.215998 0.607735 0.074 Uiso 1 1 calc GR . . . .
C13 C 0.82172(12) -0.16105(12) 0.57481(13) 0.0291(7) Uani 1 1 d . . . . .
C14 C 0.78394(13) -0.17688(12) 0.60998(13) 0.0325(7) Uani 1 1 d . . . . .
H14 H 0.760418 -0.198252 0.594796 0.039 Uiso 1 1 calc R . . . .
C15 C 0.77972(14) -0.16240(14) 0.66615(15) 0.0397(8) Uani 1 1 d . . . . .
H15 H 0.754044 -0.174259 0.688954 0.048 Uiso 1 1 calc R . . . .
C16 C 0.81349(15) -0.13030(14) 0.68885(15) 0.0438(9) Uani 1 1 d . . . . .
H16 H 0.810687 -0.119754 0.727029 0.053 Uiso 1 1 calc R . . . .
C17 C 0.85098(14) -0.11402(13) 0.65534(15) 0.0394(8) Uani 1 1 d . . . . .
H17 H 0.874223 -0.092388 0.670610 0.047 Uiso 1 1 calc R . . . .
C18 C 0.85489(13) -0.12918(12) 0.59918(14) 0.0335(7) Uani 1 1 d . . . . .
H18 H 0.880898 -0.117488 0.576791 0.040 Uiso 1 1 calc R . . . .
C19 C 0.88115(12) -0.15199(12) 0.46891(13) 0.0285(7) Uani 1 1 d . . . . .
C20 C 0.92498(13) -0.17440(13) 0.45510(14) 0.0348(7) Uani 1 1 d . . . . .
H20 H 0.928983 -0.207867 0.462656 0.042 Uiso 1 1 calc R . . . .
C21 C 0.96282(14) -0.14863(14) 0.43052(16) 0.0412(9) Uani 1 1 d . . . . .
H21 H 0.992085 -0.164684 0.421178 0.049 Uiso 1 1 calc R . . . .
C22 C 0.95794(14) -0.09981(14) 0.41968(16) 0.0432(9) Uani 1 1 d . . . . .
H22 H 0.983671 -0.082500 0.402436 0.052 Uiso 1 1 calc R . . . .
C23 C 0.91571(14) -0.07617(13) 0.43387(15) 0.0380(8) Uani 1 1 d . . . . .
H23 H 0.912422 -0.042528 0.426966 0.046 Uiso 1 1 calc R . . . .
C24 C 0.87793(13) -0.10213(12) 0.45845(14) 0.0326(7) Uani 1 1 d . . . . .
H24 H 0.849103 -0.085560 0.468419 0.039 Uiso 1 1 calc R . . . .
C25 C 0.84915(14) -0.13761(14) 0.30855(15) 0.0382(8) Uani 1 1 d . . . . .
H25A H 0.833884 -0.119372 0.277790 0.057 Uiso 1 1 calc GR . . . .
H25B H 0.867521 -0.164652 0.292615 0.057 Uiso 1 1 calc GR . . . .
H25C H 0.871008 -0.116356 0.329664 0.057 Uiso 1 1 calc GR . . . .
C26 C 0.77566(14) -0.19086(13) 0.31638(15) 0.0398(8) Uani 1 1 d . . . . .
H26A H 0.751675 -0.203975 0.342776 0.060 Uiso 1 1 calc GR . . . .
H26B H 0.794097 -0.217425 0.299487 0.060 Uiso 1 1 calc GR . . . .
H26C H 0.759187 -0.172725 0.286395 0.060 Uiso 1 1 calc GR . . . .
C27 C 0.81018(13) -0.15706(12) 0.34852(13) 0.0315(7) Uani 1 1 d . . . . .
H27 H 0.826872 -0.176890 0.378038 0.038 Uiso 1 1 calc R . . . .
C28 C 0.78185(12) -0.11793(12) 0.37930(13) 0.0289(7) Uani 1 1 d . . . . .
C29 C 0.77230(13) -0.07439(13) 0.35276(14) 0.0356(8) Uani 1 1 d . . . . .
H29 H 0.783645 -0.069224 0.315244 0.043 Uiso 1 1 calc R . . . .
C30 C 0.74640(14) -0.03797(13) 0.37988(15) 0.0373(8) Uani 1 1 d . . . . .
H30 H 0.740395 -0.008106 0.361345 0.045 Uiso 1 1 calc R . . . .
C31 C 0.72963(12) -0.04601(12) 0.43404(14) 0.0327(7) Uani 1 1 d . . . . .
H31 H 0.712036 -0.021185 0.452648 0.039 Uiso 1 1 calc R . . . .
C32 C 0.73770(12) -0.08958(12) 0.46248(13) 0.0284(7) Uani 1 1 d . . . . .
C33 C 0.76443(11) -0.12658(11) 0.43552(13) 0.0257(6) Uani 1 1 d . . . . .
C34 C 0.71709(12) -0.09546(12) 0.52201(14) 0.0313(7) Uani 1 1 d . . . . .
H34 H 0.722741 -0.129541 0.534368 0.038 Uiso 1 1 calc R . . . .
C35 C 0.74246(14) -0.06175(14) 0.56453(15) 0.0397(8) Uani 1 1 d . . . . .
H35A H 0.777315 -0.067874 0.563829 0.060 Uiso 1 1 calc GR . . . .
H35B H 0.729959 -0.067865 0.602727 0.060 Uiso 1 1 calc GR . . . .
H35C H 0.736243 -0.028053 0.554102 0.060 Uiso 1 1 calc GR . . . .
C36 C 0.66243(13) -0.08596(14) 0.52312(17) 0.0408(8) Uani 1 1 d . . . . .
H36A H 0.656190 -0.052093 0.513515 0.061 Uiso 1 1 calc GR . . . .
H36B H 0.649819 -0.092798 0.561094 0.061 Uiso 1 1 calc GR . . . .
H36C H 0.646400 -0.106941 0.495445 0.061 Uiso 1 1 calc GR . . . .
Dy2 Dy 0.750000 0.250000 0.50722(2) 0.02439(6) Uani 1 2 d S T P . .
Si2 Si 0.81203(3) 0.17099(3) 0.46204(3) 0.02531(18) Uani 1 1 d . . . . .
N3 N 0.74996(10) 0.17747(10) 0.46277(10) 0.0269(6) Uani 1 1 d . . . . .
N4 N 0.82719(10) 0.21985(10) 0.50342(10) 0.0251(6) Uani 1 1 d . . . . .
C37 C 0.66202(15) 0.15155(14) 0.60101(16) 0.0461(9) Uani 1 1 d . . . . .
H37A H 0.643998 0.175536 0.578961 0.069 Uiso 1 1 calc GR . . . .
H37B H 0.670783 0.165330 0.637867 0.069 Uiso 1 1 calc GR . . . .
H37C H 0.641879 0.122858 0.606776 0.069 Uiso 1 1 calc GR . . . .
C38 C 0.70821(14) 0.13730(13) 0.56869(14) 0.0363(8) Uani 1 1 d . . . . .
H38 H 0.728298 0.167067 0.564144 0.044 Uiso 1 1 calc R . . . .
C39 C 0.73793(14) 0.10052(15) 0.60358(16) 0.0444(9) Uani 1 1 d . . . . .
H39A H 0.719290 0.070678 0.608140 0.067 Uiso 1 1 calc GR . . . .
H39B H 0.745132 0.114166 0.640961 0.067 Uiso 1 1 calc GR . . . .
H39C H 0.768206 0.093399 0.583740 0.067 Uiso 1 1 calc GR . . . .
C40 C 0.69632(12) 0.11855(12) 0.50974(15) 0.0317(7) Uani 1 1 d . . . . .
C41 C 0.66566(13) 0.07853(13) 0.50585(16) 0.0364(8) Uani 1 1 d . . . . .
H41 H 0.653623 0.064236 0.539624 0.044 Uiso 1 1 calc R . . . .
C42 C 0.65242(13) 0.05924(13) 0.45398(17) 0.0399(8) Uani 1 1 d . . . . .
H42 H 0.632021 0.031701 0.452043 0.048 Uiso 1 1 calc R . . . .
C43 C 0.66942(12) 0.08079(13) 0.40514(16) 0.0369(8) Uani 1 1 d . . . . .
H43 H 0.659896 0.068014 0.369476 0.044 Uiso 1 1 calc R . . . .
C44 C 0.69996(12) 0.12050(12) 0.40644(15) 0.0316(7) Uani 1 1 d . . . . .
C45 C 0.71606(11) 0.13965(11) 0.45939(13) 0.0262(6) Uani 1 1 d . . . . .
C46 C 0.71633(13) 0.14301(13) 0.35085(14) 0.0346(8) Uani 1 1 d . . . . .
H46 H 0.736736 0.171779 0.359952 0.041 Uiso 1 1 calc R . . . .
C47 C 0.67284(14) 0.16032(14) 0.31603(15) 0.0404(8) Uani 1 1 d . . . . .
H47A H 0.652596 0.132580 0.305990 0.061 Uiso 1 1 calc GR . . . .
H47B H 0.684262 0.176155 0.281378 0.061 Uiso 1 1 calc GR . . . .
H47C H 0.653902 0.183301 0.338490 0.061 Uiso 1 1 calc GR . . . .
C48 C 0.74691(14) 0.10791(15) 0.31532(16) 0.0448(9) Uani 1 1 d . . . . .
H48A H 0.774034 0.096110 0.338132 0.067 Uiso 1 1 calc GR . . . .
H48B H 0.759303 0.124704 0.281771 0.067 Uiso 1 1 calc GR . . . .
H48C H 0.726879 0.080545 0.303409 0.067 Uiso 1 1 calc GR . . . .
C49 C 0.83671(12) 0.17384(12) 0.38664(13) 0.0280(7) Uani 1 1 d . . . . .
C50 C 0.82200(13) 0.21063(13) 0.34963(14) 0.0331(7) Uani 1 1 d . . . . .
H50 H 0.800733 0.234972 0.363144 0.040 Uiso 1 1 calc R . . . .
C51 C 0.83767(14) 0.21247(14) 0.29376(15) 0.0395(8) Uani 1 1 d . . . . .
H51 H 0.826775 0.237585 0.269488 0.047 Uiso 1 1 calc R . . . .
C52 C 0.86922(14) 0.17764(15) 0.27339(15) 0.0430(9) Uani 1 1 d . . . . .
H52 H 0.879987 0.178779 0.235176 0.052 Uiso 1 1 calc R . . . .
C53 C 0.88490(13) 0.14126(14) 0.30907(15) 0.0376(8) Uani 1 1 d . . . . .
H53 H 0.906844 0.117543 0.295499 0.045 Uiso 1 1 calc R . . . .
C54 C 0.86861(12) 0.13932(13) 0.36480(14) 0.0331(7) Uani 1 1 d . . . . .
H54 H 0.879417 0.113883 0.388671 0.040 Uiso 1 1 calc R . . . .
C55 C 0.83447(12) 0.11077(12) 0.48840(14) 0.0286(7) Uani 1 1 d . . . . .
C56 C 0.81099(13) 0.06754(13) 0.47408(15) 0.0357(8) Uani 1 1 d . . . . .
H56 H 0.782710 0.068785 0.451317 0.043 Uiso 1 1 calc R . . . .
C57 C 0.82814(14) 0.02262(13) 0.49244(16) 0.0398(8) Uani 1 1 d . . . . .
H57 H 0.811532 -0.006111 0.482193 0.048 Uiso 1 1 calc R . . . .
C58 C 0.86940(14) 0.02015(13) 0.52561(15) 0.0382(8) Uani 1 1 d . . . . .
H58 H 0.880801 -0.010205 0.538784 0.046 Uiso 1 1 calc R . . . .
C59 C 0.89378(14) 0.06183(13) 0.53938(15) 0.0377(8) Uani 1 1 d . . . . .
H59 H 0.922211 0.060157 0.561836 0.045 Uiso 1 1 calc R . . . .
C60 C 0.87702(12) 0.10641(12) 0.52060(13) 0.0309(7) Uani 1 1 d . . . . .
H60 H 0.894808 0.134699 0.529762 0.037 Uiso 1 1 calc R . . . .
C61 C 0.94068(15) 0.24354(15) 0.40144(17) 0.0467(9) Uani 1 1 d . . . . .
H61A H 0.974235 0.250083 0.412220 0.070 Uiso 1 1 calc GR . . . .
H61B H 0.935397 0.253790 0.362167 0.070 Uiso 1 1 calc GR . . . .
H61C H 0.934210 0.208857 0.404818 0.070 Uiso 1 1 calc GR . . . .
C62 C 0.90655(13) 0.27154(13) 0.44076(14) 0.0338(7) Uani 1 1 d . . . . .
H62 H 0.872683 0.266053 0.427528 0.041 Uiso 1 1 calc R . . . .
C63 C 0.91732(14) 0.32593(14) 0.43682(17) 0.0436(9) Uani 1 1 d . . . . .
H63A H 0.894602 0.343745 0.460849 0.065 Uiso 1 1 calc GR . . . .
H63B H 0.913820 0.336599 0.397426 0.065 Uiso 1 1 calc GR . . . .
H63C H 0.950415 0.332103 0.449670 0.065 Uiso 1 1 calc GR . . . .
C64 C 0.91041(13) 0.25387(12) 0.50180(13) 0.0303(7) Uani 1 1 d . . . . .
C65 C 0.95355(13) 0.26271(13) 0.53066(16) 0.0380(8) Uani 1 1 d . . . . .
H65 H 0.979297 0.278162 0.511176 0.046 Uiso 1 1 calc R . . . .
C66 C 0.95990(13) 0.24972(14) 0.58643(17) 0.0421(9) Uani 1 1 d . . . . .
H66 H 0.989394 0.256538 0.605385 0.051 Uiso 1 1 calc R . . . .
C67 C 0.92259(13) 0.22655(13) 0.61451(15) 0.0378(8) Uani 1 1 d . . . . .
H67 H 0.926586 0.217923 0.653200 0.045 Uiso 1 1 calc R . . . .
C68 C 0.87945(12) 0.21564(12) 0.58734(14) 0.0303(7) Uani 1 1 d . . . . .
C69 C 0.87223(11) 0.22969(11) 0.52962(13) 0.0268(6) Uani 1 1 d . . . . .
C70 C 0.83966(13) 0.18909(13) 0.61917(14) 0.0325(7) Uani 1 1 d . . . . .
H70 H 0.819572 0.171589 0.590549 0.039 Uiso 1 1 calc R . . . .
C71 C 0.80690(14) 0.22529(14) 0.64947(17) 0.0438(9) Uani 1 1 d . . . . .
H71A H 0.825142 0.241512 0.679555 0.066 Uiso 1 1 calc GR . . . .
H71B H 0.779302 0.208226 0.666070 0.066 Uiso 1 1 calc GR . . . .
H71C H 0.795267 0.249331 0.622212 0.066 Uiso 1 1 calc GR . . . .
C72 C 0.85843(14) 0.15175(13) 0.66157(14) 0.0387(8) Uani 1 1 d . . . . .
H72A H 0.880016 0.129110 0.642127 0.058 Uiso 1 1 calc GR . . . .
H72B H 0.831135 0.134014 0.677874 0.058 Uiso 1 1 calc GR . . . .
H72C H 0.876182 0.168214 0.691879 0.058 Uiso 1 1 calc GR . . . .
K1 K 0.99531(3) -0.02195(3) 0.75197(3) 0.03902(17) Uani 1 1 d . . . . .
O1 O 0.98305(10) -0.11145(10) 0.79386(13) 0.0495(7) Uani 1 1 d . U . . .
O2 O 1.00139(12) -0.00391(11) 0.86308(12) 0.0579(9) Uani 1 1 d . . . . .
O3 O 1.09209(10) -0.02552(11) 0.75124(13) 0.0527(7) Uani 1 1 d . . . . .
O4 O 1.00583(10) 0.07504(10) 0.74517(12) 0.0491(7) Uani 1 1 d . . . . .
O5 O 0.9951(2) -0.06714(13) 0.65310(14) 0.1120(16) Uani 1 1 d . U . . .
O6 O 0.89896(11) -0.00432(12) 0.74093(13) 0.0568(8) Uani 1 1 d . . . . .
C73 C 1.00823(19) -0.1549(2) 0.8067(3) 0.0805(16) Uani 1 1 d . U . . .
H73A H 1.010571 -0.159890 0.848115 0.097 Uiso 1 1 calc R . . . .
H73B H 1.041161 -0.154520 0.790294 0.097 Uiso 1 1 calc R . . . .
C74 C 0.9767(2) -0.19445(18) 0.7786(2) 0.0827(16) Uani 1 1 d . U . . .
H74A H 0.987382 -0.200917 0.739295 0.099 Uiso 1 1 calc R . . . .
H74B H 0.977909 -0.224901 0.800571 0.099 Uiso 1 1 calc R . . . .
C75 C 0.9271(2) -0.17320(18) 0.7795(2) 0.0720(14) Uani 1 1 d . U . . .
H75A H 0.912647 -0.173800 0.741157 0.086 Uiso 1 1 calc R . . . .
H75B H 0.905942 -0.191429 0.805693 0.086 Uiso 1 1 calc R . . . .
C76 C 0.93340(17) -0.12316(17) 0.7992(2) 0.0580(11) Uani 1 1 d . U . . .
H76A H 0.913593 -0.100908 0.776029 0.070 Uiso 1 1 calc R . . . .
H76B H 0.923118 -0.120206 0.839283 0.070 Uiso 1 1 calc R . . . .
C77 C 1.00907(19) -0.03797(18) 0.90760(18) 0.0613(13) Uani 1 1 d . . . . .
H77A H 1.037797 -0.029036 0.930290 0.074 Uiso 1 1 calc R . . . .
H77B H 1.013917 -0.070799 0.891975 0.074 Uiso 1 1 calc R . . . .
C78 C 0.96389(18) -0.03606(17) 0.9435(2) 0.0582(12) Uani 1 1 d . . . . .
H78A H 0.971803 -0.039118 0.984286 0.070 Uiso 1 1 calc R . . . .
H78B H 0.941137 -0.062106 0.932849 0.070 Uiso 1 1 calc R . . . .
C79 C 0.94243(17) 0.01398(17) 0.93034(19) 0.0569(11) Uani 1 1 d . . . . .
H79A H 0.910092 0.011023 0.912768 0.068 Uiso 1 1 calc R . . . .
H79B H 0.939775 0.033771 0.965154 0.068 Uiso 1 1 calc R . . . .
C80 C 0.97847(17) 0.03580(16) 0.88918(18) 0.0539(11) Uani 1 1 d . . . . .
H80A H 0.961762 0.055980 0.860618 0.065 Uiso 1 1 calc R . . . .
H80B H 1.002301 0.056038 0.909532 0.065 Uiso 1 1 calc R . . . .
C81 C 1.11081(17) -0.04326(19) 0.8036(2) 0.0618(12) Uani 1 1 d . . . . .
H81A H 1.095038 -0.074146 0.813785 0.074 Uiso 1 1 calc R . . . .
H81B H 1.104887 -0.019668 0.834346 0.074 Uiso 1 1 calc R . . . .
C82 C 1.16362(17) -0.05056(19) 0.7954(2) 0.0626(12) Uani 1 1 d . . . . .
H82A H 1.170634 -0.082626 0.778750 0.075 Uiso 1 1 calc R . . . .
H82B H 1.181485 -0.047098 0.831528 0.075 Uiso 1 1 calc R . . . .
C83 C 1.17575(17) -0.01020(18) 0.7546(2) 0.0589(12) Uani 1 1 d . . . . .
H83A H 1.178879 0.021137 0.774433 0.071 Uiso 1 1 calc R . . . .
H83B H 1.205974 -0.017017 0.733598 0.071 Uiso 1 1 calc R . . . .
C84 C 1.13261(17) -0.01062(16) 0.7157(2) 0.0563(11) Uani 1 1 d . . . . .
H84A H 1.126863 0.021908 0.699598 0.068 Uiso 1 1 calc R . . . .
H84B H 1.137500 -0.033734 0.684174 0.068 Uiso 1 1 calc R . . . .
C85 C 1.04808(14) 0.09212(15) 0.77478(18) 0.0449(9) Uani 1 1 d . . . . .
H85A H 1.077102 0.089318 0.750482 0.054 Uiso 1 1 calc R . . . .
H85B H 1.053410 0.073210 0.809840 0.054 Uiso 1 1 calc R . . . .
C86 C 1.03803(15) 0.14401(16) 0.78865(18) 0.0503(10) Uani 1 1 d . . . . .
H86A H 1.068298 0.162905 0.791483 0.060 Uiso 1 1 calc R . . . .
H86B H 1.019764 0.147090 0.824540 0.060 Uiso 1 1 calc R . . . .
C87 C 1.00775(17) 0.16008(16) 0.73800(19) 0.0532(10) Uani 1 1 d . . . . .
H87A H 0.987443 0.188391 0.747472 0.064 Uiso 1 1 calc R . . . .
H87B H 1.028280 0.167919 0.704898 0.064 Uiso 1 1 calc R . . . .
C88 C 0.97721(15) 0.11543(15) 0.72723(18) 0.0484(10) Uani 1 1 d . . . . .
H88A H 0.946774 0.117013 0.749177 0.058 Uiso 1 1 calc R . . . .
H88B H 0.969185 0.112668 0.686470 0.058 Uiso 1 1 calc R . . . .
C89 C 1.0116(4) -0.0361(2) 0.6091(2) 0.124(2) Uani 1 1 d D U . . .
H89A H 0.994929 -0.004526 0.610903 0.149 Uiso 1 1 calc R . . . .
H89B H 1.046823 -0.030663 0.612377 0.149 Uiso 1 1 calc R . . . .
C90 C 1.0007(3) -0.0598(2) 0.5581(2) 0.103(2) Uani 1 1 d D U . . .
H90A H 1.025718 -0.052719 0.529303 0.124 Uiso 1 1 calc R . . . .
H90B H 0.969081 -0.048784 0.543448 0.124 Uiso 1 1 calc R . . . .
C91 C 0.99926(18) -0.11159(19) 0.56995(19) 0.0616(12) Uani 1 1 d . U . . .
H91A H 1.030082 -0.127275 0.559272 0.074 Uiso 1 1 calc R . . . .
H91B H 0.972512 -0.127346 0.549119 0.074 Uiso 1 1 calc R . . . .
C92 C 0.99118(16) -0.11423(15) 0.63304(17) 0.0491(10) Uani 1 1 d . U . . .
H92A H 0.958761 -0.127509 0.641425 0.059 Uiso 1 1 calc R . . . .
H92B H 1.015770 -0.135184 0.651034 0.059 Uiso 1 1 calc R . . . .
C93 C 0.8619(2) 0.0064(2) 0.7812(2) 0.0842(18) Uani 1 1 d . . . . .
H93A H 0.874744 0.027884 0.811188 0.101 Uiso 1 1 calc R . . . .
H93B H 0.850442 -0.023796 0.799306 0.101 Uiso 1 1 calc R . . . .
C94 C 0.8212(2) 0.0306(2) 0.7509(2) 0.0712(14) Uani 1 1 d . . . . .
H94A H 0.822394 0.066025 0.756191 0.085 Uiso 1 1 calc R . . . .
H94B H 0.789633 0.018386 0.764366 0.085 Uiso 1 1 calc R . . . .
C95 C 0.82959(16) 0.01715(16) 0.6894(2) 0.0545(11) Uani 1 1 d . . . . .
H95A H 0.814132 -0.014056 0.679850 0.065 Uiso 1 1 calc R . . . .
H95B H 0.817311 0.042473 0.663463 0.065 Uiso 1 1 calc R . . . .
C96 C 0.88397(16) 0.01356(16) 0.68683(19) 0.0516(10) Uani 1 1 d . . . . .
H96A H 0.894032 -0.008821 0.656315 0.062 Uiso 1 1 calc R . . . .
H96B H 0.898408 0.045667 0.679451 0.062 Uiso 1 1 calc R . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 Si1 2.9881(9) 3_645 ?
Dy1 Si1 2.9880(9) . ?
Dy1 N1 2.293(3) 3_645 ?
Dy1 N1 2.294(3) . ?
Dy1 N2 2.283(3) . ?
Dy1 N2 2.283(3) 3_645 ?
Si1 N1 1.720(3) . ?
Si1 N2 1.727(3) . ?
Si1 C13 1.904(3) . ?
Si1 C19 1.899(3) . ?
N1 C9 1.412(4) . ?
N2 C33 1.409(4) . ?
C1 H1A 0.9800 . ?
C1 H1B 0.9800 . ?
C1 H1C 0.9800 . ?
C1 C2 1.534(5) . ?
C2 H2 1.0000 . ?
C2 C3 1.543(5) . ?
C2 C4 1.527(5) . ?
C3 H3A 0.9800 . ?
C3 H3B 0.9800 . ?
C3 H3C 0.9800 . ?
C4 C5 1.389(5) . ?
C4 C9 1.432(4) . ?
C5 H5 0.9500 . ?
C5 C6 1.379(5) . ?
C6 H6 0.9500 . ?
C6 C7 1.387(5) . ?
C7 H7 0.9500 . ?
C7 C8 1.399(5) . ?
C8 C9 1.416(4) . ?
C8 C11 1.514(5) . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C10 C11 1.533(5) . ?
C11 H11 1.0000 . ?
C11 C12 1.523(5) . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
C13 C14 1.405(5) . ?
C13 C18 1.397(5) . ?
C14 H14 0.9500 . ?
C14 C15 1.389(5) . ?
C15 H15 0.9500 . ?
C15 C16 1.397(6) . ?
C16 H16 0.9500 . ?
C16 C17 1.380(6) . ?
C17 H17 0.9500 . ?
C17 C18 1.394(5) . ?
C18 H18 0.9500 . ?
C19 C20 1.401(5) . ?
C19 C24 1.405(5) . ?
C20 H20 0.9500 . ?
C20 C21 1.394(5) . ?
C21 H21 0.9500 . ?
C21 C22 1.382(5) . ?
C22 H22 0.9500 . ?
C22 C23 1.381(5) . ?
C23 H23 0.9500 . ?
C23 C24 1.395(5) . ?
C24 H24 0.9500 . ?
C25 H25A 0.9800 . ?
C25 H25B 0.9800 . ?
C25 H25C 0.9800 . ?
C25 C27 1.531(5) . ?
C26 H26A 0.9800 . ?
C26 H26B 0.9800 . ?
C26 H26C 0.9800 . ?
C26 C27 1.538(5) . ?
C27 H27 1.0000 . ?
C27 C28 1.522(5) . ?
C28 C29 1.384(5) . ?
C28 C33 1.432(4) . ?
C29 H29 0.9500 . ?
C29 C30 1.393(5) . ?
C30 H30 0.9500 . ?
C30 C31 1.378(5) . ?
C31 H31 0.9500 . ?
C31 C32 1.398(5) . ?
C32 C33 1.415(4) . ?
C32 C34 1.525(4) . ?
C34 H34 1.0000 . ?
C34 C35 1.540(5) . ?
C34 C36 1.536(5) . ?
C35 H35A 0.9800 . ?
C35 H35B 0.9800 . ?
C35 H35C 0.9800 . ?
C36 H36A 0.9800 . ?
C36 H36B 0.9800 . ?
C36 H36C 0.9800 . ?
Dy2 Si2 2.9782(9) 3_655 ?
Dy2 Si2 2.9782(9) . ?
Dy2 N3 2.265(3) 3_655 ?
Dy2 N3 2.265(3) . ?
Dy2 N4 2.296(3) 3_655 ?
Dy2 N4 2.296(3) . ?
Si2 N3 1.728(3) . ?
Si2 N4 1.720(3) . ?
Si2 C49 1.907(3) . ?
Si2 C55 1.885(3) . ?
N3 C45 1.408(4) . ?
N4 C69 1.418(4) . ?
C37 H37A 0.9800 . ?
C37 H37B 0.9800 . ?
C37 H37C 0.9800 . ?
C37 C38 1.540(5) . ?
C38 H38 1.0000 . ?
C38 C39 1.547(5) . ?
C38 C40 1.520(5) . ?
C39 H39A 0.9800 . ?
C39 H39B 0.9800 . ?
C39 H39C 0.9800 . ?
C40 C41 1.399(5) . ?
C40 C45 1.432(5) . ?
C41 H41 0.9500 . ?
C41 C42 1.385(5) . ?
C42 H42 0.9500 . ?
C42 C43 1.380(5) . ?
C43 H43 0.9500 . ?
C43 C44 1.387(5) . ?
C44 C45 1.428(4) . ?
C44 C46 1.521(5) . ?
C46 H46 1.0000 . ?
C46 C47 1.534(5) . ?
C46 C48 1.537(5) . ?
C47 H47A 0.9800 . ?
C47 H47B 0.9800 . ?
C47 H47C 0.9800 . ?
C48 H48A 0.9800 . ?
C48 H48B 0.9800 . ?
C48 H48C 0.9800 . ?
C49 C50 1.402(5) . ?
C49 C54 1.400(5) . ?
C50 H50 0.9500 . ?
C50 C51 1.388(5) . ?
C51 H51 0.9500 . ?
C51 C52 1.387(5) . ?
C52 H52 0.9500 . ?
C52 C53 1.383(5) . ?
C53 H53 0.9500 . ?
C53 C54 1.391(5) . ?
C54 H54 0.9500 . ?
C55 C56 1.403(5) . ?
C55 C60 1.407(5) . ?
C56 H56 0.9500 . ?
C56 C57 1.400(5) . ?
C57 H57 0.9500 . ?
C57 C58 1.387(5) . ?
C58 H58 0.9500 . ?
C58 C59 1.376(5) . ?
C59 H59 0.9500 . ?
C59 C60 1.391(5) . ?
C60 H60 0.9500 . ?
C61 H61A 0.9800 . ?
C61 H61B 0.9800 . ?
C61 H61C 0.9800 . ?
C61 C62 1.534(5) . ?
C62 H62 1.0000 . ?
C62 C63 1.538(5) . ?
C62 C64 1.525(4) . ?
C63 H63A 0.9800 . ?
C63 H63B 0.9800 . ?
C63 H63C 0.9800 . ?
C64 C65 1.396(5) . ?
C64 C69 1.413(5) . ?
C65 H65 0.9500 . ?
C65 C66 1.375(5) . ?
C66 H66 0.9500 . ?
C66 C67 1.385(5) . ?
C67 H67 0.9500 . ?
C67 C68 1.389(5) . ?
C68 C69 1.430(4) . ?
C68 C70 1.522(5) . ?
C70 H70 1.0000 . ?
C70 C71 1.529(5) . ?
C70 C72 1.529(5) . ?
C71 H71A 0.9800 . ?
C71 H71B 0.9800 . ?
C71 H71C 0.9800 . ?
C72 H72A 0.9800 . ?
C72 H72B 0.9800 . ?
C72 H72C 0.9800 . ?
K1 O1 2.689(3) . ?
K1 O2 2.674(3) . ?
K1 O3 2.681(3) . ?
K1 O4 2.706(3) . ?
K1 O5 2.647(4) . ?
K1 O6 2.724(3) . ?
O1 C73 1.422(6) . ?
O1 C76 1.418(5) . ?
O2 C77 1.427(5) . ?
O2 C80 1.411(5) . ?
O3 C81 1.426(5) . ?
O3 C84 1.460(5) . ?
O4 C85 1.442(5) . ?
O4 C88 1.434(5) . ?
O5 C89 1.424(6) . ?
O5 C92 1.391(5) . ?
O6 C93 1.429(6) . ?
O6 C96 1.431(5) . ?
C73 H73A 0.9900 . ?
C73 H73B 0.9900 . ?
C73 C74 1.549(8) . ?
C74 H74A 0.9900 . ?
C74 H74B 0.9900 . ?
C74 C75 1.493(8) . ?
C75 H75A 0.9900 . ?
C75 H75B 0.9900 . ?
C75 C76 1.472(7) . ?
C76 H76A 0.9900 . ?
C76 H76B 0.9900 . ?
C77 H77A 0.9900 . ?
C77 H77B 0.9900 . ?
C77 C78 1.512(6) . ?
C78 H78A 0.9900 . ?
C78 H78B 0.9900 . ?
C78 C79 1.539(6) . ?
C79 H79A 0.9900 . ?
C79 H79B 0.9900 . ?
C79 C80 1.518(6) . ?
C80 H80A 0.9900 . ?
C80 H80B 0.9900 . ?
C81 H81A 0.9900 . ?
C81 H81B 0.9900 . ?
C81 C82 1.489(6) . ?
C82 H82A 0.9900 . ?
C82 H82B 0.9900 . ?
C82 C83 1.513(7) . ?
C83 H83A 0.9900 . ?
C83 H83B 0.9900 . ?
C83 C84 1.506(7) . ?
C84 H84A 0.9900 . ?
C84 H84B 0.9900 . ?
C85 H85A 0.9900 . ?
C85 H85B 0.9900 . ?
C85 C86 1.499(6) . ?
C86 H86A 0.9900 . ?
C86 H86B 0.9900 . ?
C86 C87 1.526(6) . ?
C87 H87A 0.9900 . ?
C87 H87B 0.9900 . ?
C87 C88 1.519(6) . ?
C88 H88A 0.9900 . ?
C88 H88B 0.9900 . ?
C89 H89A 0.9900 . ?
C89 H89B 0.9900 . ?
C89 C90 1.402(7) . ?
C90 H90A 0.9900 . ?
C90 H90B 0.9900 . ?
C90 C91 1.461(8) . ?
C91 H91A 0.9900 . ?
C91 H91B 0.9900 . ?
C91 C92 1.507(6) . ?
C92 H92A 0.9900 . ?
C92 H92B 0.9900 . ?
C93 H93A 0.9900 . ?
C93 H93B 0.9900 . ?
C93 C94 1.494(7) . ?
C94 H94A 0.9900 . ?
C94 H94B 0.9900 . ?
C94 C95 1.516(7) . ?
C95 H95A 0.9900 . ?
C95 H95B 0.9900 . ?
C95 C96 1.510(6) . ?
C96 H96A 0.9900 . ?
C96 H96B 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Si1 Dy1 Si1 138.04(3) . 3_645 ?
N1 Dy1 Si1 121.71(7) . 3_645 ?
N1 Dy1 Si1 34.99(7) . . ?
N1 Dy1 Si1 34.99(7) 3_645 3_645 ?
N1 Dy1 Si1 121.71(7) 3_645 . ?
N1 Dy1 N1 131.58(13) 3_645 . ?
N2 Dy1 Si1 35.14(7) . . ?
N2 Dy1 Si1 35.14(7) 3_645 3_645 ?
N2 Dy1 Si1 139.44(7) 3_645 . ?
N2 Dy1 Si1 139.44(7) . 3_645 ?
N2 Dy1 N1 69.79(9) . . ?
N2 Dy1 N1 106.21(9) 3_645 . ?
N2 Dy1 N1 69.78(9) 3_645 3_645 ?
N2 Dy1 N1 106.21(9) . 3_645 ?
N2 Dy1 N2 170.71(12) 3_645 . ?
N1 Si1 Dy1 49.86(9) . . ?
N1 Si1 N2 98.80(13) . . ?
N1 Si1 C13 113.77(14) . . ?
N1 Si1 C19 116.56(14) . . ?
N2 Si1 Dy1 49.52(9) . . ?
N2 Si1 C13 111.11(14) . . ?
N2 Si1 C19 112.56(14) . . ?
C13 Si1 Dy1 119.68(11) . . ?
C19 Si1 Dy1 135.87(10) . . ?
C19 Si1 C13 104.28(14) . . ?
Si1 N1 Dy1 95.15(12) . . ?
C9 N1 Dy1 133.6(2) . . ?
C9 N1 Si1 128.3(2) . . ?
Si1 N2 Dy1 95.34(12) . . ?
C33 N2 Dy1 138.5(2) . . ?
C33 N2 Si1 123.9(2) . . ?
H1A C1 H1B 109.5 . . ?
H1A C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
C2 C1 H1A 109.5 . . ?
C2 C1 H1B 109.5 . . ?
C2 C1 H1C 109.5 . . ?
C1 C2 H2 107.8 . . ?
C1 C2 C3 109.7(3) . . ?
C3 C2 H2 107.8 . . ?
C4 C2 C1 111.4(3) . . ?
C4 C2 H2 107.8 . . ?
C4 C2 C3 112.2(3) . . ?
C2 C3 H3A 109.5 . . ?
C2 C3 H3B 109.5 . . ?
C2 C3 H3C 109.5 . . ?
H3A C3 H3B 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
C5 C4 C2 116.9(3) . . ?
C5 C4 C9 120.1(3) . . ?
C9 C4 C2 123.0(3) . . ?
C4 C5 H5 119.0 . . ?
C6 C5 C4 122.1(3) . . ?
C6 C5 H5 119.0 . . ?
C5 C6 H6 120.8 . . ?
C5 C6 C7 118.5(3) . . ?
C7 C6 H6 120.8 . . ?
C6 C7 H7 119.1 . . ?
C6 C7 C8 121.7(3) . . ?
C8 C7 H7 119.1 . . ?
C7 C8 C9 120.2(3) . . ?
C7 C8 C11 118.5(3) . . ?
C9 C8 C11 121.3(3) . . ?
N1 C9 C4 120.3(3) . . ?
N1 C9 C8 122.4(3) . . ?
C8 C9 C4 117.3(3) . . ?
H10A C10 H10B 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
C11 C10 H10A 109.5 . . ?
C11 C10 H10B 109.5 . . ?
C11 C10 H10C 109.5 . . ?
C8 C11 C10 111.5(3) . . ?
C8 C11 H11 107.5 . . ?
C8 C11 C12 111.9(3) . . ?
C10 C11 H11 107.5 . . ?
C12 C11 C10 110.7(3) . . ?
C12 C11 H11 107.5 . . ?
C11 C12 H12A 109.5 . . ?
C11 C12 H12B 109.5 . . ?
C11 C12 H12C 109.5 . . ?
H12A C12 H12B 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
C14 C13 Si1 119.9(2) . . ?
C18 C13 Si1 123.7(3) . . ?
C18 C13 C14 116.3(3) . . ?
C13 C14 H14 118.8 . . ?
C15 C14 C13 122.4(3) . . ?
C15 C14 H14 118.8 . . ?
C14 C15 H15 120.2 . . ?
C14 C15 C16 119.5(3) . . ?
C16 C15 H15 120.2 . . ?
C15 C16 H16 120.3 . . ?
C17 C16 C15 119.4(3) . . ?
C17 C16 H16 120.3 . . ?
C16 C17 H17 119.9 . . ?
C16 C17 C18 120.3(3) . . ?
C18 C17 H17 119.9 . . ?
C13 C18 H18 119.0 . . ?
C17 C18 C13 122.0(3) . . ?
C17 C18 H18 119.0 . . ?
C20 C19 Si1 125.0(3) . . ?
C20 C19 C24 116.7(3) . . ?
C24 C19 Si1 118.3(3) . . ?
C19 C20 H20 119.3 . . ?
C21 C20 C19 121.4(3) . . ?
C21 C20 H20 119.3 . . ?
C20 C21 H21 119.9 . . ?
C22 C21 C20 120.3(4) . . ?
C22 C21 H21 119.9 . . ?
C21 C22 H22 120.0 . . ?
C23 C22 C21 120.1(3) . . ?
C23 C22 H22 120.0 . . ?
C22 C23 H23 120.3 . . ?
C22 C23 C24 119.4(3) . . ?
C24 C23 H23 120.3 . . ?
C19 C24 H24 119.0 . . ?
C23 C24 C19 122.1(3) . . ?
C23 C24 H24 119.0 . . ?
H25A C25 H25B 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
C27 C25 H25A 109.5 . . ?
C27 C25 H25B 109.5 . . ?
C27 C25 H25C 109.5 . . ?
H26A C26 H26B 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
C27 C26 H26A 109.5 . . ?
C27 C26 H26B 109.5 . . ?
C27 C26 H26C 109.5 . . ?
C25 C27 C26 110.4(3) . . ?
C25 C27 H27 107.2 . . ?
C26 C27 H27 107.2 . . ?
C28 C27 C25 114.0(3) . . ?
C28 C27 C26 110.4(3) . . ?
C28 C27 H27 107.2 . . ?
C29 C28 C27 120.2(3) . . ?
C29 C28 C33 120.0(3) . . ?
C33 C28 C27 119.8(3) . . ?
C28 C29 H29 119.3 . . ?
C28 C29 C30 121.4(3) . . ?
C30 C29 H29 119.3 . . ?
C29 C30 H30 120.6 . . ?
C31 C30 C29 118.9(3) . . ?
C31 C30 H30 120.6 . . ?
C30 C31 H31 119.0 . . ?
C30 C31 C32 122.0(3) . . ?
C32 C31 H31 119.0 . . ?
C31 C32 C33 119.5(3) . . ?
C31 C32 C34 118.3(3) . . ?
C33 C32 C34 122.2(3) . . ?
N2 C33 C28 119.0(3) . . ?
N2 C33 C32 122.8(3) . . ?
C32 C33 C28 118.1(3) . . ?
C32 C34 H34 108.1 . . ?
C32 C34 C35 111.4(3) . . ?
C32 C34 C36 111.5(3) . . ?
C35 C34 H34 108.1 . . ?
C36 C34 H34 108.1 . . ?
C36 C34 C35 109.5(3) . . ?
C34 C35 H35A 109.5 . . ?
C34 C35 H35B 109.5 . . ?
C34 C35 H35C 109.5 . . ?
H35A C35 H35B 109.5 . . ?
H35A C35 H35C 109.5 . . ?
H35B C35 H35C 109.5 . . ?
C34 C36 H36A 109.5 . . ?
C34 C36 H36B 109.5 . . ?
C34 C36 H36C 109.5 . . ?
H36A C36 H36B 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
Si2 Dy2 Si2 138.06(3) 3_655 . ?
N3 Dy2 Si2 119.02(7) 3_655 . ?
N3 Dy2 Si2 119.02(7) . 3_655 ?
N3 Dy2 Si2 35.27(7) 3_655 3_655 ?
N3 Dy2 Si2 35.27(7) . . ?
N3 Dy2 N3 124.85(13) . 3_655 ?
N3 Dy2 N4 107.68(9) . 3_655 ?
N3 Dy2 N4 70.12(9) 3_655 3_655 ?
N3 Dy2 N4 107.68(9) 3_655 . ?
N3 Dy2 N4 70.13(9) . . ?
N4 Dy2 Si2 35.14(7) 3_655 3_655 ?
N4 Dy2 Si2 35.14(7) . . ?
N4 Dy2 Si2 142.16(7) 3_655 . ?
N4 Dy2 Si2 142.16(7) . 3_655 ?
N4 Dy2 N4 175.52(12) 3_655 . ?
N3 Si2 Dy2 49.21(9) . . ?
N3 Si2 C49 111.18(13) . . ?
N3 Si2 C55 114.60(14) . . ?
N4 Si2 Dy2 50.21(9) . . ?
N4 Si2 N3 98.95(13) . . ?
N4 Si2 C49 114.17(14) . . ?
N4 Si2 C55 115.34(14) . . ?
C49 Si2 Dy2 120.67(11) . . ?
C55 Si2 Dy2 136.19(10) . . ?
C55 Si2 C49 103.07(15) . . ?
Si2 N3 Dy2 95.52(12) . . ?
C45 N3 Dy2 133.3(2) . . ?
C45 N3 Si2 125.8(2) . . ?
Si2 N4 Dy2 94.64(12) . . ?
C69 N4 Dy2 137.0(2) . . ?
C69 N4 Si2 127.8(2) . . ?
H37A C37 H37B 109.5 . . ?
H37A C37 H37C 109.5 . . ?
H37B C37 H37C 109.5 . . ?
C38 C37 H37A 109.5 . . ?
C38 C37 H37B 109.5 . . ?
C38 C37 H37C 109.5 . . ?
C37 C38 H38 107.7 . . ?
C37 C38 C39 110.3(3) . . ?
C39 C38 H38 107.7 . . ?
C40 C38 C37 111.1(3) . . ?
C40 C38 H38 107.7 . . ?
C40 C38 C39 112.2(3) . . ?
C38 C39 H39A 109.5 . . ?
C38 C39 H39B 109.5 . . ?
C38 C39 H39C 109.5 . . ?
H39A C39 H39B 109.5 . . ?
H39A C39 H39C 109.5 . . ?
H39B C39 H39C 109.5 . . ?
C41 C40 C38 117.5(3) . . ?
C41 C40 C45 120.0(3) . . ?
C45 C40 C38 122.5(3) . . ?
C40 C41 H41 119.2 . . ?
C42 C41 C40 121.6(3) . . ?
C42 C41 H41 119.2 . . ?
C41 C42 H42 120.6 . . ?
C43 C42 C41 118.7(3) . . ?
C43 C42 H42 120.6 . . ?
C42 C43 H43 118.9 . . ?
C42 C43 C44 122.1(3) . . ?
C44 C43 H43 118.9 . . ?
C43 C44 C45 120.3(3) . . ?
C43 C44 C46 119.1(3) . . ?
C45 C44 C46 120.6(3) . . ?
N3 C45 C40 120.7(3) . . ?
N3 C45 C44 122.2(3) . . ?
C44 C45 C40 117.1(3) . . ?
C44 C46 H46 108.0 . . ?
C44 C46 C47 110.8(3) . . ?
C44 C46 C48 112.0(3) . . ?
C47 C46 H46 108.0 . . ?
C47 C46 C48 109.7(3) . . ?
C48 C46 H46 108.0 . . ?
C46 C47 H47A 109.5 . . ?
C46 C47 H47B 109.5 . . ?
C46 C47 H47C 109.5 . . ?
H47A C47 H47B 109.5 . . ?
H47A C47 H47C 109.5 . . ?
H47B C47 H47C 109.5 . . ?
C46 C48 H48A 109.5 . . ?
C46 C48 H48B 109.5 . . ?
C46 C48 H48C 109.5 . . ?
H48A C48 H48B 109.5 . . ?
H48A C48 H48C 109.5 . . ?
H48B C48 H48C 109.5 . . ?
C50 C49 Si2 120.5(2) . . ?
C54 C49 Si2 122.8(2) . . ?
C54 C49 C50 116.7(3) . . ?
C49 C50 H50 119.1 . . ?
C51 C50 C49 121.8(3) . . ?
C51 C50 H50 119.1 . . ?
C50 C51 H51 120.0 . . ?
C52 C51 C50 120.0(3) . . ?
C52 C51 H51 120.0 . . ?
C51 C52 H52 120.2 . . ?
C53 C52 C51 119.6(3) . . ?
C53 C52 H52 120.2 . . ?
C52 C53 H53 119.9 . . ?
C52 C53 C54 120.1(3) . . ?
C54 C53 H53 119.9 . . ?
C49 C54 H54 119.1 . . ?
C53 C54 C49 121.8(3) . . ?
C53 C54 H54 119.1 . . ?
C56 C55 Si2 121.5(3) . . ?
C56 C55 C60 116.4(3) . . ?
C60 C55 Si2 122.0(3) . . ?
C55 C56 H56 119.1 . . ?
C57 C56 C55 121.7(3) . . ?
C57 C56 H56 119.1 . . ?
C56 C57 H57 120.1 . . ?
C58 C57 C56 119.9(3) . . ?
C58 C57 H57 120.1 . . ?
C57 C58 H58 120.1 . . ?
C59 C58 C57 119.7(3) . . ?
C59 C58 H58 120.1 . . ?
C58 C59 H59 119.8 . . ?
C58 C59 C60 120.4(3) . . ?
C60 C59 H59 119.8 . . ?
C55 C60 H60 119.1 . . ?
C59 C60 C55 121.8(3) . . ?
C59 C60 H60 119.1 . . ?
H61A C61 H61B 109.5 . . ?
H61A C61 H61C 109.5 . . ?
H61B C61 H61C 109.5 . . ?
C62 C61 H61A 109.5 . . ?
C62 C61 H61B 109.5 . . ?
C62 C61 H61C 109.5 . . ?
C61 C62 H62 108.2 . . ?
C61 C62 C63 109.8(3) . . ?
C63 C62 H62 108.2 . . ?
C64 C62 C61 111.5(3) . . ?
C64 C62 H62 108.2 . . ?
C64 C62 C63 111.0(3) . . ?
C62 C63 H63A 109.5 . . ?
C62 C63 H63B 109.5 . . ?
C62 C63 H63C 109.5 . . ?
H63A C63 H63B 109.5 . . ?
H63A C63 H63C 109.5 . . ?
H63B C63 H63C 109.5 . . ?
C65 C64 C62 117.7(3) . . ?
C65 C64 C69 119.8(3) . . ?
C69 C64 C62 122.6(3) . . ?
C64 C65 H65 119.0 . . ?
C66 C65 C64 122.0(3) . . ?
C66 C65 H65 119.0 . . ?
C65 C66 H66 120.5 . . ?
C65 C66 C67 118.9(3) . . ?
C67 C66 H66 120.5 . . ?
C66 C67 H67 119.3 . . ?
C66 C67 C68 121.4(3) . . ?
C68 C67 H67 119.3 . . ?
C67 C68 C69 120.0(3) . . ?
C67 C68 C70 120.0(3) . . ?
C69 C68 C70 120.0(3) . . ?
N4 C69 C68 119.1(3) . . ?
C64 C69 N4 123.1(3) . . ?
C64 C69 C68 117.8(3) . . ?
C68 C70 H70 107.7 . . ?
C68 C70 C71 110.1(3) . . ?
C68 C70 C72 113.8(3) . . ?
C71 C70 H70 107.7 . . ?
C71 C70 C72 109.8(3) . . ?
C72 C70 H70 107.7 . . ?
C70 C71 H71A 109.5 . . ?
C70 C71 H71B 109.5 . . ?
C70 C71 H71C 109.5 . . ?
H71A C71 H71B 109.5 . . ?
H71A C71 H71C 109.5 . . ?
H71B C71 H71C 109.5 . . ?
C70 C72 H72A 109.5 . . ?
C70 C72 H72B 109.5 . . ?
C70 C72 H72C 109.5 . . ?
H72A C72 H72B 109.5 . . ?
H72A C72 H72C 109.5 . . ?
H72B C72 H72C 109.5 . . ?
O1 K1 O4 161.77(9) . . ?
O1 K1 O6 94.39(9) . . ?
O2 K1 O1 79.61(10) . . ?
O2 K1 O3 87.15(10) . . ?
O2 K1 O4 82.30(9) . . ?
O2 K1 O6 97.00(10) . . ?
O3 K1 O1 95.42(9) . . ?
O3 K1 O4 85.91(9) . . ?
O3 K1 O6 169.89(10) . . ?
O4 K1 O6 85.52(9) . . ?
O5 K1 O1 83.57(10) . . ?
O5 K1 O2 162.25(11) . . ?
O5 K1 O3 88.82(15) . . ?
O5 K1 O4 114.65(10) . . ?
O5 K1 O6 89.88(15) . . ?
C73 O1 K1 142.7(3) . . ?
C76 O1 K1 111.5(2) . . ?
C76 O1 C73 105.2(3) . . ?
C77 O2 K1 127.4(3) . . ?
C80 O2 K1 123.0(3) . . ?
C80 O2 C77 105.1(3) . . ?
C81 O3 K1 111.7(2) . . ?
C81 O3 C84 108.4(3) . . ?
C84 O3 K1 139.5(3) . . ?
C85 O4 K1 112.6(2) . . ?
C88 O4 K1 137.0(2) . . ?
C88 O4 C85 109.6(3) . . ?
C89 O5 K1 110.9(3) . . ?
C92 O5 K1 138.0(3) . . ?
C92 O5 C89 110.0(4) . . ?
C93 O6 K1 132.5(3) . . ?
C93 O6 C96 108.3(3) . . ?
C96 O6 K1 115.6(2) . . ?
O1 C73 H73A 111.1 . . ?
O1 C73 H73B 111.1 . . ?
O1 C73 C74 103.3(4) . . ?
H73A C73 H73B 109.1 . . ?
C74 C73 H73A 111.1 . . ?
C74 C73 H73B 111.1 . . ?
C73 C74 H74A 111.1 . . ?
C73 C74 H74B 111.1 . . ?
H74A C74 H74B 109.0 . . ?
C75 C74 C73 103.5(4) . . ?
C75 C74 H74A 111.1 . . ?
C75 C74 H74B 111.1 . . ?
C74 C75 H75A 110.6 . . ?
C74 C75 H75B 110.6 . . ?
H75A C75 H75B 108.8 . . ?
C76 C75 C74 105.5(5) . . ?
C76 C75 H75A 110.6 . . ?
C76 C75 H75B 110.6 . . ?
O1 C76 C75 107.5(4) . . ?
O1 C76 H76A 110.2 . . ?
O1 C76 H76B 110.2 . . ?
C75 C76 H76A 110.2 . . ?
C75 C76 H76B 110.2 . . ?
H76A C76 H76B 108.5 . . ?
O2 C77 H77A 110.7 . . ?
O2 C77 H77B 110.7 . . ?
O2 C77 C78 105.4(4) . . ?
H77A C77 H77B 108.8 . . ?
C78 C77 H77A 110.7 . . ?
C78 C77 H77B 110.7 . . ?
C77 C78 H78A 111.0 . . ?
C77 C78 H78B 111.0 . . ?
C77 C78 C79 103.7(4) . . ?
H78A C78 H78B 109.0 . . ?
C79 C78 H78A 111.0 . . ?
C79 C78 H78B 111.0 . . ?
C78 C79 H79A 111.1 . . ?
C78 C79 H79B 111.1 . . ?
H79A C79 H79B 109.0 . . ?
C80 C79 C78 103.5(4) . . ?
C80 C79 H79A 111.1 . . ?
C80 C79 H79B 111.1 . . ?
O2 C80 C79 105.4(4) . . ?
O2 C80 H80A 110.7 . . ?
O2 C80 H80B 110.7 . . ?
C79 C80 H80A 110.7 . . ?
C79 C80 H80B 110.7 . . ?
H80A C80 H80B 108.8 . . ?
O3 C81 H81A 110.3 . . ?
O3 C81 H81B 110.3 . . ?
O3 C81 C82 106.9(4) . . ?
H81A C81 H81B 108.6 . . ?
C82 C81 H81A 110.3 . . ?
C82 C81 H81B 110.3 . . ?
C81 C82 H82A 111.5 . . ?
C81 C82 H82B 111.5 . . ?
C81 C82 C83 101.5(4) . . ?
H82A C82 H82B 109.3 . . ?
C83 C82 H82A 111.5 . . ?
C83 C82 H82B 111.5 . . ?
C82 C83 H83A 111.4 . . ?
C82 C83 H83B 111.4 . . ?
H83A C83 H83B 109.3 . . ?
C84 C83 C82 101.9(4) . . ?
C84 C83 H83A 111.4 . . ?
C84 C83 H83B 111.4 . . ?
O3 C84 C83 105.2(4) . . ?
O3 C84 H84A 110.7 . . ?
O3 C84 H84B 110.7 . . ?
C83 C84 H84A 110.7 . . ?
C83 C84 H84B 110.7 . . ?
H84A C84 H84B 108.8 . . ?
O4 C85 H85A 110.6 . . ?
O4 C85 H85B 110.6 . . ?
O4 C85 C86 105.6(3) . . ?
H85A C85 H85B 108.7 . . ?
C86 C85 H85A 110.6 . . ?
C86 C85 H85B 110.6 . . ?
C85 C86 H86A 111.3 . . ?
C85 C86 H86B 111.3 . . ?
C85 C86 C87 102.1(3) . . ?
H86A C86 H86B 109.2 . . ?
C87 C86 H86A 111.3 . . ?
C87 C86 H86B 111.3 . . ?
C86 C87 H87A 111.5 . . ?
C86 C87 H87B 111.5 . . ?
H87A C87 H87B 109.3 . . ?
C88 C87 C86 101.5(4) . . ?
C88 C87 H87A 111.5 . . ?
C88 C87 H87B 111.5 . . ?
O4 C88 C87 106.1(3) . . ?
O4 C88 H88A 110.5 . . ?
O4 C88 H88B 110.5 . . ?
C87 C88 H88A 110.5 . . ?
C87 C88 H88B 110.5 . . ?
H88A C88 H88B 108.7 . . ?
O5 C89 H89A 110.6 . . ?
O5 C89 H89B 110.6 . . ?
H89A C89 H89B 108.7 . . ?
C90 C89 O5 105.9(5) . . ?
C90 C89 H89A 110.6 . . ?
C90 C89 H89B 110.6 . . ?
C89 C90 H90A 110.2 . . ?
C89 C90 H90B 110.2 . . ?
C89 C90 C91 107.5(5) . . ?
H90A C90 H90B 108.5 . . ?
C91 C90 H90A 110.2 . . ?
C91 C90 H90B 110.2 . . ?
C90 C91 H91A 111.0 . . ?
C90 C91 H91B 111.0 . . ?
C90 C91 C92 103.9(4) . . ?
H91A C91 H91B 109.0 . . ?
C92 C91 H91A 111.0 . . ?
C92 C91 H91B 111.0 . . ?
O5 C92 C91 106.2(4) . . ?
O5 C92 H92A 110.5 . . ?
O5 C92 H92B 110.5 . . ?
C91 C92 H92A 110.5 . . ?
C91 C92 H92B 110.5 . . ?
H92A C92 H92B 108.7 . . ?
O6 C93 H93A 110.0 . . ?
O6 C93 H93B 110.0 . . ?
O6 C93 C94 108.4(4) . . ?
H93A C93 H93B 108.4 . . ?
C94 C93 H93A 110.0 . . ?
C94 C93 H93B 110.0 . . ?
C93 C94 H94A 111.1 . . ?
C93 C94 H94B 111.1 . . ?
C93 C94 C95 103.5(4) . . ?
H94A C94 H94B 109.0 . . ?
C95 C94 H94A 111.1 . . ?
C95 C94 H94B 111.1 . . ?
C94 C95 H95A 111.4 . . ?
C94 C95 H95B 111.4 . . ?
H95A C95 H95B 109.3 . . ?
C96 C95 C94 101.9(4) . . ?
C96 C95 H95A 111.4 . . ?
C96 C95 H95B 111.4 . . ?
O6 C96 C95 106.1(4) . . ?
O6 C96 H96A 110.5 . . ?
O6 C96 H96B 110.5 . . ?
C95 C96 H96A 110.5 . . ?
C95 C96 H96B 110.5 . . ?
H96A C96 H96B 108.7 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Dy1 Si1 N1 C9 162.5(3) . . . . ?
Dy1 Si1 N2 C33 -165.8(3) . . . . ?
Dy1 Si1 C19 C20 -74.2(3) . . . . ?
Dy1 Si1 C19 C24 104.4(3) . . . . ?
Dy1 N1 C9 C4 51.3(4) . . . . ?
Dy1 N1 C9 C8 -127.9(3) . . . . ?
Dy1 N2 C33 C28 -71.9(4) . . . . ?
Dy1 N2 C33 C32 107.5(3) . . . . ?
Si1 N1 C9 C4 -104.2(3) . . . . ?
Si1 N1 C9 C8 76.6(4) . . . . ?
Si1 N2 C33 C28 86.5(3) . . . . ?
Si1 N2 C33 C32 -94.1(3) . . . . ?
Si1 C13 C14 C15 178.1(3) . . . . ?
Si1 C13 C18 C17 -178.5(3) . . . . ?
Si1 C19 C20 C21 176.7(3) . . . . ?
Si1 C19 C24 C23 -176.8(3) . . . . ?
N1 Si1 N2 Dy1 8.19(13) . . . . ?
N1 Si1 N2 C33 -157.6(2) . . . . ?
N1 Si1 C19 C20 -15.6(3) . . . . ?
N1 Si1 C19 C24 163.1(2) . . . . ?
N2 Si1 N1 Dy1 -8.15(12) . . . . ?
N2 Si1 N1 C9 154.3(3) . . . . ?
N2 Si1 C19 C20 -128.7(3) . . . . ?
N2 Si1 C19 C24 50.0(3) . . . . ?
C1 C2 C4 C5 56.9(4) . . . . ?
C1 C2 C4 C9 -124.4(3) . . . . ?
C2 C4 C5 C6 -178.8(3) . . . . ?
C2 C4 C9 N1 -1.8(5) . . . . ?
C2 C4 C9 C8 177.4(3) . . . . ?
C3 C2 C4 C5 -66.6(4) . . . . ?
C3 C2 C4 C9 112.1(4) . . . . ?
C4 C5 C6 C7 -0.2(6) . . . . ?
C5 C4 C9 N1 176.8(3) . . . . ?
C5 C4 C9 C8 -4.0(5) . . . . ?
C5 C6 C7 C8 -0.5(5) . . . . ?
C6 C7 C8 C9 -1.1(5) . . . . ?
C6 C7 C8 C11 178.7(3) . . . . ?
C7 C8 C9 N1 -177.4(3) . . . . ?
C7 C8 C9 C4 3.3(5) . . . . ?
C7 C8 C11 C10 -61.9(4) . . . . ?
C7 C8 C11 C12 62.7(4) . . . . ?
C9 C4 C5 C6 2.5(5) . . . . ?
C9 C8 C11 C10 117.9(4) . . . . ?
C9 C8 C11 C12 -117.5(4) . . . . ?
C11 C8 C9 N1 2.8(5) . . . . ?
C11 C8 C9 C4 -176.5(3) . . . . ?
C13 Si1 N1 Dy1 109.66(14) . . . . ?
C13 Si1 N1 C9 -87.9(3) . . . . ?
C13 Si1 N2 Dy1 -111.61(13) . . . . ?
C13 Si1 N2 C33 82.6(3) . . . . ?
C13 Si1 C19 C20 110.7(3) . . . . ?
C13 Si1 C19 C24 -70.6(3) . . . . ?
C13 C14 C15 C16 1.2(5) . . . . ?
C14 C13 C18 C17 0.3(5) . . . . ?
C14 C15 C16 C17 -1.0(6) . . . . ?
C15 C16 C17 C18 0.5(6) . . . . ?
C16 C17 C18 C13 -0.2(6) . . . . ?
C18 C13 C14 C15 -0.8(5) . . . . ?
C19 Si1 N1 Dy1 -128.91(13) . . . . ?
C19 Si1 N1 C9 33.6(3) . . . . ?
C19 Si1 N2 Dy1 131.85(12) . . . . ?
C19 Si1 N2 C33 -34.0(3) . . . . ?
C19 C20 C21 C22 0.6(6) . . . . ?
C20 C19 C24 C23 2.0(5) . . . . ?
C20 C21 C22 C23 0.9(6) . . . . ?
C21 C22 C23 C24 -0.9(6) . . . . ?
C22 C23 C24 C19 -0.6(5) . . . . ?
C24 C19 C20 C21 -2.0(5) . . . . ?
C25 C27 C28 C29 34.0(4) . . . . ?
C25 C27 C28 C33 -147.0(3) . . . . ?
C26 C27 C28 C29 -90.9(4) . . . . ?
C26 C27 C28 C33 88.1(4) . . . . ?
C27 C28 C29 C30 179.9(3) . . . . ?
C27 C28 C33 N2 0.2(4) . . . . ?
C27 C28 C33 C32 -179.2(3) . . . . ?
C28 C29 C30 C31 -0.7(6) . . . . ?
C29 C28 C33 N2 179.2(3) . . . . ?
C29 C28 C33 C32 -0.2(5) . . . . ?
C29 C30 C31 C32 -0.2(5) . . . . ?
C30 C31 C32 C33 0.9(5) . . . . ?
C30 C31 C32 C34 -179.1(3) . . . . ?
C31 C32 C33 N2 179.9(3) . . . . ?
C31 C32 C33 C28 -0.7(5) . . . . ?
C31 C32 C34 C35 -67.8(4) . . . . ?
C31 C32 C34 C36 55.0(4) . . . . ?
C33 C28 C29 C30 0.9(5) . . . . ?
C33 C32 C34 C35 112.3(3) . . . . ?
C33 C32 C34 C36 -125.0(3) . . . . ?
C34 C32 C33 N2 -0.1(5) . . . . ?
C34 C32 C33 C28 179.3(3) . . . . ?
Dy2 Si2 N3 C45 -156.7(3) . . . . ?
Dy2 Si2 N4 C69 172.7(3) . . . . ?
Dy2 Si2 C55 C56 96.7(3) . . . . ?
Dy2 Si2 C55 C60 -87.1(3) . . . . ?
Dy2 N3 C45 C40 -53.5(4) . . . . ?
Dy2 N3 C45 C44 126.7(3) . . . . ?
Dy2 N4 C69 C64 -104.5(3) . . . . ?
Dy2 N4 C69 C68 74.1(4) . . . . ?
Si2 N3 C45 C40 93.8(3) . . . . ?
Si2 N3 C45 C44 -85.9(4) . . . . ?
Si2 N4 C69 C64 86.2(4) . . . . ?
Si2 N4 C69 C68 -95.2(3) . . . . ?
Si2 C49 C50 C51 -177.1(3) . . . . ?
Si2 C49 C54 C53 177.9(3) . . . . ?
Si2 C55 C56 C57 178.5(3) . . . . ?
Si2 C55 C60 C59 -179.2(3) . . . . ?
N3 Si2 N4 Dy2 -7.41(12) . . . . ?
N3 Si2 N4 C69 165.3(3) . . . . ?
N3 Si2 C55 C56 40.8(3) . . . . ?
N3 Si2 C55 C60 -143.0(3) . . . . ?
N4 Si2 N3 Dy2 7.52(12) . . . . ?
N4 Si2 N3 C45 -149.2(3) . . . . ?
N4 Si2 C55 C56 154.7(3) . . . . ?
N4 Si2 C55 C60 -29.0(3) . . . . ?
C37 C38 C40 C41 -58.3(4) . . . . ?
C37 C38 C40 C45 123.1(3) . . . . ?
C38 C40 C41 C42 179.3(3) . . . . ?
C38 C40 C45 N3 3.7(5) . . . . ?
C38 C40 C45 C44 -176.5(3) . . . . ?
C39 C38 C40 C41 65.7(4) . . . . ?
C39 C38 C40 C45 -112.9(4) . . . . ?
C40 C41 C42 C43 -1.1(6) . . . . ?
C41 C40 C45 N3 -174.9(3) . . . . ?
C41 C40 C45 C44 4.8(5) . . . . ?
C41 C42 C43 C44 1.2(5) . . . . ?
C42 C43 C44 C45 1.9(5) . . . . ?
C42 C43 C44 C46 -178.6(3) . . . . ?
C43 C44 C45 N3 175.0(3) . . . . ?
C43 C44 C45 C40 -4.8(5) . . . . ?
C43 C44 C46 C47 59.4(4) . . . . ?
C43 C44 C46 C48 -63.6(4) . . . . ?
C45 C40 C41 C42 -2.0(5) . . . . ?
C45 C44 C46 C47 -121.1(3) . . . . ?
C45 C44 C46 C48 115.9(3) . . . . ?
C46 C44 C45 N3 -4.5(5) . . . . ?
C46 C44 C45 C40 175.7(3) . . . . ?
C49 Si2 N3 Dy2 -112.84(13) . . . . ?
C49 Si2 N3 C45 90.4(3) . . . . ?
C49 Si2 N4 Dy2 110.72(13) . . . . ?
C49 Si2 N4 C69 -76.6(3) . . . . ?
C49 Si2 C55 C56 -80.2(3) . . . . ?
C49 Si2 C55 C60 96.1(3) . . . . ?
C49 C50 C51 C52 -0.8(6) . . . . ?
C50 C49 C54 C53 -0.1(5) . . . . ?
C50 C51 C52 C53 -0.1(6) . . . . ?
C51 C52 C53 C54 0.8(6) . . . . ?
C52 C53 C54 C49 -0.7(5) . . . . ?
C54 C49 C50 C51 0.9(5) . . . . ?
C55 Si2 N3 Dy2 130.79(13) . . . . ?
C55 Si2 N3 C45 -26.0(3) . . . . ?
C55 Si2 N4 Dy2 -130.15(13) . . . . ?
C55 Si2 N4 C69 42.6(3) . . . . ?
C55 C56 C57 C58 -0.1(6) . . . . ?
C56 C55 C60 C59 -2.8(5) . . . . ?
C56 C57 C58 C59 -1.2(6) . . . . ?
C57 C58 C59 C60 0.5(6) . . . . ?
C58 C59 C60 C55 1.6(5) . . . . ?
C60 C55 C56 C57 2.0(5) . . . . ?
C61 C62 C64 C65 67.7(4) . . . . ?
C61 C62 C64 C69 -112.9(4) . . . . ?
C62 C64 C65 C66 177.6(3) . . . . ?
C62 C64 C69 N4 -0.1(5) . . . . ?
C62 C64 C69 C68 -178.7(3) . . . . ?
C63 C62 C64 C65 -55.0(4) . . . . ?
C63 C62 C64 C69 124.4(3) . . . . ?
C64 C65 C66 C67 1.0(6) . . . . ?
C65 C64 C69 N4 179.3(3) . . . . ?
C65 C64 C69 C68 0.8(5) . . . . ?
C65 C66 C67 C68 0.9(6) . . . . ?
C66 C67 C68 C69 -1.9(5) . . . . ?
C66 C67 C68 C70 178.6(3) . . . . ?
C67 C68 C69 N4 -177.6(3) . . . . ?
C67 C68 C69 C64 1.1(5) . . . . ?
C67 C68 C70 C71 88.6(4) . . . . ?
C67 C68 C70 C72 -35.1(4) . . . . ?
C69 C64 C65 C66 -1.8(5) . . . . ?
C69 C68 C70 C71 -90.9(4) . . . . ?
C69 C68 C70 C72 145.4(3) . . . . ?
C70 C68 C69 N4 1.9(4) . . . . ?
C70 C68 C69 C64 -179.5(3) . . . . ?
K1 O1 C73 C74 -130.4(4) . . . . ?
K1 O1 C76 C75 137.7(3) . . . . ?
K1 O2 C77 C78 -116.6(3) . . . . ?
K1 O2 C80 C79 117.0(3) . . . . ?
K1 O3 C81 C82 171.8(3) . . . . ?
K1 O3 C84 C83 160.2(3) . . . . ?
K1 O4 C85 C86 -156.3(2) . . . . ?
K1 O4 C88 C87 178.2(3) . . . . ?
K1 O5 C89 C90 -168.2(6) . . . . ?
K1 O5 C92 C91 -174.5(4) . . . . ?
K1 O6 C93 C94 158.7(3) . . . . ?
K1 O6 C96 C95 176.1(3) . . . . ?
O1 C73 C74 C75 -28.1(5) . . . . ?
O2 C77 C78 C79 -22.7(5) . . . . ?
O3 C81 C82 C83 33.3(5) . . . . ?
O4 C85 C86 C87 -33.4(4) . . . . ?
O5 C89 C90 C91 -26.2(9) . . . . ?
O6 C93 C94 C95 19.3(6) . . . . ?
C73 O1 C76 C75 -35.4(5) . . . . ?
C73 C74 C75 C76 7.4(5) . . . . ?
C74 C75 C76 O1 16.2(5) . . . . ?
C76 O1 C73 C74 38.9(5) . . . . ?
C77 O2 C80 C79 -40.8(5) . . . . ?
C77 C78 C79 C80 -1.3(5) . . . . ?
C78 C79 C80 O2 25.1(5) . . . . ?
C80 O2 C77 C78 40.0(5) . . . . ?
C81 O3 C84 C83 -12.2(5) . . . . ?
C81 C82 C83 C84 -39.5(5) . . . . ?
C82 C83 C84 O3 32.2(5) . . . . ?
C84 O3 C81 C82 -13.5(5) . . . . ?
C85 O4 C88 C87 9.6(4) . . . . ?
C85 C86 C87 C88 38.0(4) . . . . ?
C86 C87 C88 O4 -29.8(4) . . . . ?
C88 O4 C85 C86 15.2(4) . . . . ?
C89 O5 C92 C91 -8.1(7) . . . . ?
C89 C90 C91 C92 20.9(8) . . . . ?
C90 C91 C92 O5 -7.7(6) . . . . ?
C92 O5 C89 C90 21.5(9) . . . . ?
C93 O6 C96 C95 -22.7(5) . . . . ?
C93 C94 C95 C96 -31.5(5) . . . . ?
C94 C95 C96 O6 33.7(5) . . . . ?
C96 O6 C93 C94 1.9(6) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'

# start Validation Reply Form
_vrf_PLAT910_1                   
;
PROBLEM:  PLAT910_ALERT_3_B Missing # of FCF Reflection(s) Below Theta(Min).         11 Note      
RESPONSE: The unit cell is reasonable large and these low angle reflections are 
probably missing due to the beamstop.
;
# end Validation Reply Form 
