# Electronic Supplementary Material (ESI) for Organic Chemistry Frontiers.
# This journal is © the Partner Organisations 2023

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
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data_211230zhq_0ma
_database_code_depnum_ccdc_archive 'CCDC 2157919'
loop_
_audit_author_name
_audit_author_address
'Hanqi Zhou'
;Hangzhou Normal University
China
;
_audit_update_record             
;
2022-03-11 deposited with the CCDC.	2022-12-01 downloaded from the CCDC.
;
_audit_creation_date             2021-12-31
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6408)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C26 H28 Cl N O Si'
_chemical_formula_sum            'C26 H28 Cl N O Si'
_chemical_formula_weight         434.03
_chemical_absolute_configuration ad
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           19
_space_group_name_H-M_alt        'P 21 21 21'
_space_group_name_Hall           'P 2ac 2ab'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'

_cell_length_a                   6.7825(10)
_cell_length_b                   14.777(2)
_cell_length_c                   23.648(4)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     2370.1(6)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    2954
_cell_measurement_temperature    296.15
_cell_measurement_theta_max      21.19
_cell_measurement_theta_min      2.21
_shelx_estimated_absorpt_T_max   0.977
_shelx_estimated_absorpt_T_min   0.956
_exptl_absorpt_coefficient_mu    0.229
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.6582
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2014/5 (Bruker,2014/5) was used for absorption correction.
wR2(int) was 0.0726 before and 0.0462 after correction.
The Ratio of minimum to maximum transmission is 0.8828.
The λ/2 correction factor is 0.00150.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            ?
_exptl_crystal_colour_lustre     .
_exptl_crystal_density_diffrn    1.216
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             920
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.1
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0575
_diffrn_reflns_av_unetI/netI     0.0660
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.986
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            14333
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.981
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.570
_diffrn_reflns_theta_min         1.625
_diffrn_ambient_temperature      296.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.986
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           30.0
_diffrn_source_power             1.5
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.742
_reflns_Friedel_fraction_full    0.998
_reflns_Friedel_fraction_max     0.976
_reflns_number_gt                3616
_reflns_number_total             5375
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT v8.34A (Bruker, 2013)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT v8.34A (Bruker, 2013)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         0.711
_refine_diff_density_min         -0.250
_refine_diff_density_rms         0.062
_refine_ls_abs_structure_details 
;
 Flack x determined using 1134 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   0.05(6)
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.032
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     273
_refine_ls_number_reflns         5375
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0990
_refine_ls_R_factor_gt           0.0602
_refine_ls_restrained_S_all      1.032
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1006P)²+0.0907P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1540
_refine_ls_wR_factor_ref         0.1835
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups, All Si(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Ternary CH refined with riding coordinates:
 Si1(H1), C8(H8)
2.b Secondary CH2 refined with riding coordinates:
 C7(H7A,H7B), C2(H2A,H2B), C3(H3A,H3B)
2.c Aromatic/amide H refined with riding coordinates:
 C14(H14), C11(H11), C12(H12), C16(H16), C20(H20), C10(H10), C17(H17),
 C22(H22), C26(H26), C19(H19), C23(H23), C24(H24), C18(H18), C25(H25)
2.d Idealised Me refined as rotating group:
 C4(H4A,H4B,H4C), C1(H1A,H1B,H1C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Si1 Si 0.3484(2) 0.47667(9) 0.56427(5) 0.0479(4) Uani 1 1 d . . . . .
H1 H 0.208014 0.481483 0.573587 0.057 Uiso 1 1 calc R U . . .
Cl1 Cl 0.6376(3) 0.58410(12) 0.80130(5) 0.0756(5) Uani 1 1 d . . . . .
O1 O 0.8085(5) 0.6859(3) 0.57968(16) 0.0561(9) Uani 1 1 d . . . . .
N1 N 0.6378(7) 0.8101(3) 0.60666(15) 0.0485(9) Uani 1 1 d . . . . .
C5 C 0.6498(7) 0.7217(3) 0.59242(16) 0.0392(10) Uani 1 1 d . . . . .
C9 C 0.3861(7) 0.6459(3) 0.65286(17) 0.0390(10) Uani 1 1 d . . . . .
C6 C 0.4616(6) 0.6661(3) 0.59423(17) 0.0376(10) Uani 1 1 d . . . . .
C14 C 0.5260(7) 0.6290(3) 0.69582(18) 0.0419(10) Uani 1 1 d . . . . .
H14 H 0.660009 0.634144 0.688193 0.050 Uiso 1 1 calc R U . . .
C8 C 0.4496(7) 0.5913(3) 0.55014(18) 0.0452(11) Uani 1 1 d . . . . .
H8 H 0.561979 0.590828 0.524099 0.054 Uiso 1 1 calc R U . . .
C21 C 0.3793(9) 0.4047(3) 0.4997(2) 0.0564(13) Uani 1 1 d . . . . .
C7 C 0.3226(8) 0.6749(3) 0.54456(18) 0.0485(12) Uani 1 1 d . . . . .
H7A H 0.356378 0.718064 0.515207 0.058 Uiso 1 1 calc R U . . .
H7B H 0.182498 0.668694 0.551816 0.058 Uiso 1 1 calc R U . . .
C13 C 0.4626(8) 0.6047(3) 0.74927(19) 0.0481(12) Uani 1 1 d . . . . .
C11 C 0.1893(7) 0.6377(4) 0.6667(2) 0.0517(12) Uani 1 1 d . . . . .
H11 H 0.094102 0.648720 0.639296 0.062 Uiso 1 1 calc R U . . .
C2 C 0.4533(8) 0.8574(3) 0.6190(2) 0.0546(13) Uani 1 1 d . . . . .
H2A H 0.468905 0.892095 0.653575 0.066 Uiso 1 1 calc R U . . .
H2B H 0.349827 0.813225 0.625274 0.066 Uiso 1 1 calc R U . . .
C15 C 0.4841(8) 0.4255(3) 0.62540(19) 0.0503(12) Uani 1 1 d . . . . .
C12 C 0.2692(9) 0.5977(4) 0.7618(2) 0.0616(14) Uani 1 1 d . . . . .
H12 H 0.229729 0.582096 0.798207 0.074 Uiso 1 1 calc R U . . .
C3 C 0.8209(9) 0.8639(4) 0.6103(2) 0.0619(14) Uani 1 1 d . . . . .
H3A H 0.795405 0.924307 0.596027 0.074 Uiso 1 1 calc R U . . .
H3B H 0.920248 0.836428 0.586284 0.074 Uiso 1 1 calc R U . . .
C16 C 0.3890(11) 0.3675(4) 0.6630(2) 0.0698(17) Uani 1 1 d . . . . .
H16 H 0.257048 0.352952 0.657265 0.084 Uiso 1 1 calc R U . . .
C20 C 0.6802(9) 0.4428(4) 0.6354(2) 0.0652(15) Uani 1 1 d . . . . .
H20 H 0.747432 0.480734 0.610650 0.078 Uiso 1 1 calc R U . . .
C10 C 0.1312(9) 0.6136(4) 0.7206(2) 0.0674(15) Uani 1 1 d . . . . .
H10 H -0.002234 0.608145 0.729001 0.081 Uiso 1 1 calc R U . . .
C4 C 0.9006(10) 0.8708(5) 0.6700(2) 0.0743(18) Uani 1 1 d . . . . .
H4A H 1.016603 0.908012 0.670074 0.111 Uiso 1 1 calc R U . . .
H4B H 0.933274 0.811452 0.683594 0.111 Uiso 1 1 calc R U . . .
H4C H 0.802439 0.897281 0.694088 0.111 Uiso 1 1 calc R U . . .
C17 C 0.4899(16) 0.3307(4) 0.7093(3) 0.092(3) Uani 1 1 d . . . . .
H17 H 0.424306 0.293447 0.734793 0.111 Uiso 1 1 calc R U . . .
C22 C 0.2212(12) 0.3661(5) 0.4720(3) 0.089(2) Uani 1 1 d . . . . .
H22 H 0.093639 0.375609 0.485143 0.107 Uiso 1 1 calc R U . . .
C26 C 0.5647(12) 0.3889(5) 0.4773(3) 0.085(2) Uani 1 1 d . . . . .
H26 H 0.673835 0.414004 0.495169 0.102 Uiso 1 1 calc R U . . .
C19 C 0.7810(12) 0.4065(5) 0.6802(3) 0.085(2) Uani 1 1 d . . . . .
H19 H 0.913466 0.420162 0.685683 0.102 Uiso 1 1 calc R U . . .
C23 C 0.2548(15) 0.3111(6) 0.4228(4) 0.104(3) Uani 1 1 d . . . . .
H23 H 0.148909 0.283409 0.404752 0.124 Uiso 1 1 calc R U . . .
C1 C 0.3917(10) 0.9205(4) 0.5717(3) 0.0811(19) Uani 1 1 d . . . . .
H1A H 0.385210 0.887373 0.536830 0.122 Uiso 1 1 calc R U . . .
H1B H 0.486438 0.968467 0.568198 0.122 Uiso 1 1 calc R U . . .
H1C H 0.264534 0.945666 0.580072 0.122 Uiso 1 1 calc R U . . .
C24 C 0.4386(18) 0.2996(6) 0.4026(3) 0.107(3) Uani 1 1 d . . . . .
H24 H 0.457136 0.265470 0.369958 0.128 Uiso 1 1 calc R U . . .
C18 C 0.6856(16) 0.3501(5) 0.7168(3) 0.098(3) Uani 1 1 d . . . . .
H18 H 0.753806 0.324657 0.747028 0.118 Uiso 1 1 calc R U . . .
C25 C 0.5941(13) 0.3358(6) 0.4282(3) 0.098(2) Uani 1 1 d . . . . .
H25 H 0.720366 0.326355 0.414048 0.118 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Si1 H1 0.9800 . ?
Si1 C8 1.858(5) . ?
Si1 C21 1.873(5) . ?
Si1 C15 1.873(5) . ?
Cl1 C13 1.736(5) . ?
O1 C5 1.237(6) . ?
N1 C5 1.352(6) . ?
N1 C2 1.463(7) . ?
N1 C3 1.477(7) . ?
C5 C6 1.519(6) . ?
C9 C6 1.508(6) . ?
C9 C14 1.412(6) . ?
C9 C11 1.380(6) . ?
C6 C8 1.522(6) . ?
C6 C7 1.512(6) . ?
C14 H14 0.9300 . ?
C14 C13 1.382(6) . ?
C8 H8 0.9800 . ?
C8 C7 1.512(7) . ?
C21 C22 1.379(8) . ?
C21 C26 1.384(9) . ?
C7 H7A 0.9700 . ?
C7 H7B 0.9700 . ?
C13 C12 1.349(7) . ?
C11 H11 0.9300 . ?
C11 C10 1.380(7) . ?
C2 H2A 0.9700 . ?
C2 H2B 0.9700 . ?
C2 C1 1.515(8) . ?
C15 C16 1.394(7) . ?
C15 C20 1.374(8) . ?
C12 H12 0.9300 . ?
C12 C10 1.372(8) . ?
C3 H3A 0.9700 . ?
C3 H3B 0.9700 . ?
C3 C4 1.515(8) . ?
C16 H16 0.9300 . ?
C16 C17 1.401(10) . ?
C20 H20 0.9300 . ?
C20 C19 1.371(9) . ?
C10 H10 0.9300 . ?
C4 H4A 0.9600 . ?
C4 H4B 0.9600 . ?
C4 H4C 0.9600 . ?
C17 H17 0.9300 . ?
C17 C18 1.370(12) . ?
C22 H22 0.9300 . ?
C22 C23 1.439(11) . ?
C26 H26 0.9300 . ?
C26 C25 1.416(9) . ?
C19 H19 0.9300 . ?
C19 C18 1.364(11) . ?
C23 H23 0.9300 . ?
C23 C24 1.345(12) . ?
C1 H1A 0.9600 . ?
C1 H1B 0.9600 . ?
C1 H1C 0.9600 . ?
C24 H24 0.9300 . ?
C24 C25 1.329(11) . ?
C18 H18 0.9300 . ?
C25 H25 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C8 Si1 H1 109.5 . . ?
C8 Si1 C21 109.2(2) . . ?
C8 Si1 C15 109.0(2) . . ?
C21 Si1 H1 109.5 . . ?
C21 Si1 C15 110.2(2) . . ?
C15 Si1 H1 109.5 . . ?
C5 N1 C2 124.3(4) . . ?
C5 N1 C3 118.9(4) . . ?
C2 N1 C3 116.8(4) . . ?
O1 C5 N1 121.8(4) . . ?
O1 C5 C6 120.5(4) . . ?
N1 C5 C6 117.7(4) . . ?
C14 C9 C6 117.9(4) . . ?
C11 C9 C6 124.4(4) . . ?
C11 C9 C14 117.6(4) . . ?
C5 C6 C8 114.7(4) . . ?
C9 C6 C5 114.8(4) . . ?
C9 C6 C8 117.9(4) . . ?
C9 C6 C7 121.3(4) . . ?
C7 C6 C5 117.1(4) . . ?
C7 C6 C8 59.8(3) . . ?
C9 C14 H14 120.2 . . ?
C13 C14 C9 119.7(4) . . ?
C13 C14 H14 120.2 . . ?
Si1 C8 H8 113.2 . . ?
C6 C8 Si1 124.0(3) . . ?
C6 C8 H8 113.2 . . ?
C7 C8 Si1 123.4(4) . . ?
C7 C8 C6 59.8(3) . . ?
C7 C8 H8 113.2 . . ?
C22 C21 Si1 122.3(5) . . ?
C22 C21 C26 117.0(6) . . ?
C26 C21 Si1 120.6(4) . . ?
C6 C7 C8 60.4(3) . . ?
C6 C7 H7A 117.7 . . ?
C6 C7 H7B 117.7 . . ?
C8 C7 H7A 117.7 . . ?
C8 C7 H7B 117.7 . . ?
H7A C7 H7B 114.8 . . ?
C14 C13 Cl1 118.7(4) . . ?
C12 C13 Cl1 119.7(4) . . ?
C12 C13 C14 121.6(5) . . ?
C9 C11 H11 119.4 . . ?
C9 C11 C10 121.2(5) . . ?
C10 C11 H11 119.4 . . ?
N1 C2 H2A 109.1 . . ?
N1 C2 H2B 109.1 . . ?
N1 C2 C1 112.5(5) . . ?
H2A C2 H2B 107.8 . . ?
C1 C2 H2A 109.1 . . ?
C1 C2 H2B 109.1 . . ?
C16 C15 Si1 120.9(5) . . ?
C20 C15 Si1 122.2(4) . . ?
C20 C15 C16 116.9(6) . . ?
C13 C12 H12 120.2 . . ?
C13 C12 C10 119.6(5) . . ?
C10 C12 H12 120.2 . . ?
N1 C3 H3A 109.0 . . ?
N1 C3 H3B 109.0 . . ?
N1 C3 C4 113.0(5) . . ?
H3A C3 H3B 107.8 . . ?
C4 C3 H3A 109.0 . . ?
C4 C3 H3B 109.0 . . ?
C15 C16 H16 119.6 . . ?
C15 C16 C17 120.7(7) . . ?
C17 C16 H16 119.6 . . ?
C15 C20 H20 118.6 . . ?
C19 C20 C15 122.9(6) . . ?
C19 C20 H20 118.6 . . ?
C11 C10 H10 119.8 . . ?
C12 C10 C11 120.3(5) . . ?
C12 C10 H10 119.8 . . ?
C3 C4 H4A 109.5 . . ?
C3 C4 H4B 109.5 . . ?
C3 C4 H4C 109.5 . . ?
H4A C4 H4B 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
C16 C17 H17 120.2 . . ?
C18 C17 C16 119.6(7) . . ?
C18 C17 H17 120.2 . . ?
C21 C22 H22 120.2 . . ?
C21 C22 C23 119.6(8) . . ?
C23 C22 H22 120.2 . . ?
C21 C26 H26 118.8 . . ?
C21 C26 C25 122.4(7) . . ?
C25 C26 H26 118.8 . . ?
C20 C19 H19 120.2 . . ?
C18 C19 C20 119.5(8) . . ?
C18 C19 H19 120.2 . . ?
C22 C23 H23 119.8 . . ?
C24 C23 C22 120.4(7) . . ?
C24 C23 H23 119.8 . . ?
C2 C1 H1A 109.5 . . ?
C2 C1 H1B 109.5 . . ?
C2 C1 H1C 109.5 . . ?
H1A C1 H1B 109.5 . . ?
H1A C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
C23 C24 H24 119.2 . . ?
C25 C24 C23 121.5(7) . . ?
C25 C24 H24 119.2 . . ?
C17 C18 H18 119.9 . . ?
C19 C18 C17 120.3(6) . . ?
C19 C18 H18 119.9 . . ?
C26 C25 H25 120.5 . . ?
C24 C25 C26 119.0(8) . . ?
C24 C25 H25 120.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Si1 C8 C7 C6 113.0(4) . . . . ?
Si1 C21 C22 C23 -179.7(6) . . . . ?
Si1 C21 C26 C25 -179.3(6) . . . . ?
Si1 C15 C16 C17 -178.7(5) . . . . ?
Si1 C15 C20 C19 179.4(5) . . . . ?
Cl1 C13 C12 C10 -179.7(4) . . . . ?
O1 C5 C6 C9 106.5(5) . . . . ?
O1 C5 C6 C8 -34.7(6) . . . . ?
O1 C5 C6 C7 -102.0(5) . . . . ?
N1 C5 C6 C9 -71.7(5) . . . . ?
N1 C5 C6 C8 147.1(4) . . . . ?
N1 C5 C6 C7 79.8(5) . . . . ?
C5 N1 C2 C1 -106.1(5) . . . . ?
C5 N1 C3 C4 -96.2(6) . . . . ?
C5 C6 C8 Si1 139.7(4) . . . . ?
C5 C6 C8 C7 -108.2(4) . . . . ?
C5 C6 C7 C8 104.2(5) . . . . ?
C9 C6 C8 Si1 -0.2(6) . . . . ?
C9 C6 C8 C7 111.9(5) . . . . ?
C9 C6 C7 C8 -106.2(5) . . . . ?
C9 C14 C13 Cl1 179.9(4) . . . . ?
C9 C14 C13 C12 -0.8(8) . . . . ?
C9 C11 C10 C12 0.4(9) . . . . ?
C6 C9 C14 C13 -176.1(4) . . . . ?
C6 C9 C11 C10 176.0(5) . . . . ?
C14 C9 C6 C5 -36.5(6) . . . . ?
C14 C9 C6 C8 103.4(5) . . . . ?
C14 C9 C6 C7 173.3(4) . . . . ?
C14 C9 C11 C10 -0.3(8) . . . . ?
C14 C13 C12 C10 0.9(9) . . . . ?
C8 Si1 C21 C22 -120.3(5) . . . . ?
C8 Si1 C21 C26 59.0(6) . . . . ?
C8 Si1 C15 C16 146.9(4) . . . . ?
C8 Si1 C15 C20 -33.3(5) . . . . ?
C21 Si1 C8 C6 -176.0(4) . . . . ?
C21 Si1 C8 C7 110.4(4) . . . . ?
C21 Si1 C15 C16 -93.2(4) . . . . ?
C21 Si1 C15 C20 86.6(5) . . . . ?
C21 C22 C23 C24 -2.1(13) . . . . ?
C21 C26 C25 C24 -0.1(12) . . . . ?
C7 C6 C8 Si1 -112.1(4) . . . . ?
C13 C12 C10 C11 -0.7(9) . . . . ?
C11 C9 C6 C5 147.3(5) . . . . ?
C11 C9 C6 C8 -72.8(6) . . . . ?
C11 C9 C6 C7 -3.0(7) . . . . ?
C11 C9 C14 C13 0.4(7) . . . . ?
C2 N1 C5 O1 176.4(4) . . . . ?
C2 N1 C5 C6 -5.4(6) . . . . ?
C2 N1 C3 C4 83.8(6) . . . . ?
C15 Si1 C8 C6 -55.5(4) . . . . ?
C15 Si1 C8 C7 -129.1(4) . . . . ?
C15 Si1 C21 C22 120.0(5) . . . . ?
C15 Si1 C21 C26 -60.7(6) . . . . ?
C15 C16 C17 C18 -1.8(10) . . . . ?
C15 C20 C19 C18 0.5(10) . . . . ?
C3 N1 C5 O1 -3.6(6) . . . . ?
C3 N1 C5 C6 174.6(4) . . . . ?
C3 N1 C2 C1 73.9(6) . . . . ?
C16 C15 C20 C19 -0.8(8) . . . . ?
C16 C17 C18 C19 1.5(10) . . . . ?
C20 C15 C16 C17 1.4(8) . . . . ?
C20 C19 C18 C17 -0.8(10) . . . . ?
C22 C21 C26 C25 0.1(10) . . . . ?
C22 C23 C24 C25 2.1(15) . . . . ?
C26 C21 C22 C23 1.0(10) . . . . ?
C23 C24 C25 C26 -1.0(14) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
