# Electronic Supplementary Material (ESI) for Organic Chemistry Frontiers.
# This journal is © the Partner Organisations 2023

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
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# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
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data_221009qcg
_database_code_depnum_ccdc_archive 'CCDC 2215587'
loop_
_audit_author_name
_audit_author_address
'Chenggang Qian'
;University of Science and Technology of China
China
;
_audit_update_record             
;
2022-10-27 deposited with the CCDC.	2022-12-05 downloaded from the CCDC.
;
_audit_creation_date             2022-10-09
_audit_creation_method           
;
Olex2 1.5
(compiled 2022.04.07 svn.rca3783a0 for OlexSys, GUI svn.r6498)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C32 H21 N O2'
_chemical_formula_sum            'C32 H21 N O2'
_chemical_formula_weight         451.50
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0137 0.0067 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0241 0.0134 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0389 0.0241 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'C 1 2/c 1'
_space_group_name_Hall           '-C 2yc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   30.6180(6)
_cell_length_b                   14.6059(3)
_cell_length_c                   20.4158(5)
_cell_angle_alpha                90
_cell_angle_beta                 92.2370(10)
_cell_angle_gamma                90
_cell_volume                     9123.1(3)
_cell_formula_units_Z            16
_cell_measurement_reflns_used    4363
_cell_measurement_temperature    213.00
_cell_measurement_theta_max      42.524
_cell_measurement_theta_min      2.514
_shelx_estimated_absorpt_T_max   0.980
_shelx_estimated_absorpt_T_min   0.972
_exptl_absorpt_coefficient_mu    0.410
_exptl_absorpt_correction_T_max  0.7508
_exptl_absorpt_correction_T_min  0.5912
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.0965 before and 0.0701 after correction.
The Ratio of minimum to maximum transmission is 0.7874.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.315
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             3776
_exptl_crystal_size_max          0.07
_exptl_crystal_size_mid          0.07
_exptl_crystal_size_min          0.05
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.1352
_diffrn_reflns_av_unetI/netI     0.1167
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       37
_diffrn_reflns_limit_h_min       -36
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            42094
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        53.594
_diffrn_reflns_theta_max         54.987
_diffrn_reflns_theta_min         2.513
_diffrn_ambient_temperature      213.00
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker D8 Venture'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           GaK\a
_diffrn_radiation_wavelength     1.34139
_diffrn_source                   ?
_diffrn_source_current           2.86
_diffrn_source_power             0.1995708
_diffrn_source_voltage           69.78
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                3756
_reflns_number_total             8685
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT v8.37A (Bruker, 2015)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT v8.37A (Bruker, 2015)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT  (Sheldrick, 2015)'
_refine_diff_density_max         0.203
_refine_diff_density_min         -0.268
_refine_diff_density_rms         0.060
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.001
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     633
_refine_ls_number_reflns         8685
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.2010
_refine_ls_R_factor_gt           0.0763
_refine_ls_restrained_S_all      1.001
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0931P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1542
_refine_ls_wR_factor_ref         0.2144
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Secondary CH2 refined with riding coordinates:
 C9(H9A,H9B), C41(H41A,H41B)
2.b Aromatic/amide H refined with riding coordinates:
 C5(H5), C6(H6), C7(H7), C8(H8), C16(H16), C17(H17), C18(H18), C20(H20),
 C21(H21), C23(H23), C24(H24), C25(H25), C27(H27), C28(H28), C30(H30), C31(H31),
  C37(H37), C38(H38), C39(H39), C40(H40), C48(H48), C49(H49), C50(H50),
 C52(H52), C53(H53), C55(H55), C56(H56), C57(H57), C59(H59), C60(H60), C62(H62),
  C63(H63)
2.c Idealised Me refined as rotating group:
 C32(H32A,H32B,H32C), C64(H64A,H64B,H64C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
O1 O 0.33004(8) 0.77883(18) 0.60409(13) 0.0559(8) Uani 1 1 d . . . . .
O2 O 0.28930(8) 0.89781(18) 0.40400(13) 0.0541(7) Uani 1 1 d . . . . .
N1 N 0.32136(9) 0.8379(2) 0.49903(14) 0.0418(8) Uani 1 1 d . . . . .
C1 C 0.30753(12) 0.8162(3) 0.5620(2) 0.0443(10) Uani 1 1 d . . . . .
C2 C 0.28682(12) 0.8749(2) 0.4609(2) 0.0410(9) Uani 1 1 d . . . . .
C3 C 0.24871(11) 0.8801(2) 0.50323(18) 0.0396(9) Uani 1 1 d . . . . .
C4 C 0.26126(11) 0.8465(2) 0.56431(18) 0.0382(9) Uani 1 1 d . . . . .
C5 C 0.23299(13) 0.8446(3) 0.6144(2) 0.0504(10) Uani 1 1 d . . . . .
H5 H 0.241711 0.821993 0.656012 0.060 Uiso 1 1 calc R U . . .
C6 C 0.19072(13) 0.8773(3) 0.6017(2) 0.0557(11) Uani 1 1 d . . . . .
H6 H 0.170505 0.876783 0.635151 0.067 Uiso 1 1 calc R U . . .
C7 C 0.17817(13) 0.9105(3) 0.5401(2) 0.0523(11) Uani 1 1 d . . . . .
H7 H 0.149574 0.932625 0.532674 0.063 Uiso 1 1 calc R U . . .
C8 C 0.20704(12) 0.9119(2) 0.4891(2) 0.0463(10) Uani 1 1 d . . . . .
H8 H 0.198535 0.933417 0.447165 0.056 Uiso 1 1 calc R U . . .
C9 C 0.36405(11) 0.8122(3) 0.47361(18) 0.0441(10) Uani 1 1 d . . . . .
H9A H 0.364500 0.828991 0.427157 0.053 Uiso 1 1 calc R U . . .
H9B H 0.367469 0.745650 0.476692 0.053 Uiso 1 1 calc R U . . .
C10 C 0.40237(11) 0.8576(2) 0.50988(17) 0.0399(9) Uani 1 1 d . . . . .
C11 C 0.42990(11) 0.8065(3) 0.54927(18) 0.0432(10) Uani 1 1 d . . . . .
C12 C 0.46393(11) 0.8498(3) 0.58965(18) 0.0464(10) Uani 1 1 d . . . . .
C13 C 0.46987(11) 0.9467(3) 0.58427(19) 0.0470(10) Uani 1 1 d . . . . .
C14 C 0.44336(12) 0.9981(3) 0.53890(19) 0.0433(10) Uani 1 1 d . . . . .
C15 C 0.40912(11) 0.9557(2) 0.50158(18) 0.0416(10) Uani 1 1 d . . . . .
C16 C 0.38460(12) 1.0075(3) 0.4565(2) 0.0499(11) Uani 1 1 d . . . . .
H16 H 0.362175 0.979659 0.430849 0.060 Uiso 1 1 calc R U . . .
C17 C 0.39297(14) 1.0999(3) 0.4492(2) 0.0637(13) Uani 1 1 d . . . . .
H17 H 0.376381 1.133924 0.418086 0.076 Uiso 1 1 calc R U . . .
C18 C 0.42505(14) 1.1427(3) 0.4866(2) 0.0633(12) Uani 1 1 d . . . . .
H18 H 0.429707 1.205938 0.481622 0.076 Uiso 1 1 calc R U . . .
C19 C 0.45078(12) 1.0933(3) 0.5318(2) 0.0513(11) Uani 1 1 d . . . . .
C20 C 0.48416(14) 1.1357(3) 0.5716(2) 0.0663(13) Uani 1 1 d . . . . .
H20 H 0.489026 1.198947 0.567487 0.080 Uiso 1 1 calc R U . . .
C21 C 0.50891(14) 1.0873(3) 0.6151(2) 0.0693(14) Uani 1 1 d . . . . .
H21 H 0.530601 1.117406 0.640880 0.083 Uiso 1 1 calc R U . . .
C22 C 0.50290(13) 0.9908(3) 0.6230(2) 0.0564(12) Uani 1 1 d . . . . .
C23 C 0.52828(14) 0.9399(4) 0.6684(2) 0.0743(14) Uani 1 1 d . . . . .
H23 H 0.549546 0.969178 0.695471 0.089 Uiso 1 1 calc R U . . .
C24 C 0.52204(14) 0.8469(4) 0.6734(2) 0.0719(14) Uani 1 1 d . . . . .
H24 H 0.539211 0.813154 0.704028 0.086 Uiso 1 1 calc R U . . .
C25 C 0.49090(13) 0.8021(3) 0.6342(2) 0.0600(12) Uani 1 1 d . . . . .
H25 H 0.487936 0.738268 0.637708 0.072 Uiso 1 1 calc R U . . .
C26 C 0.42806(11) 0.7033(3) 0.5504(2) 0.0451(10) Uani 1 1 d . . . . .
C27 C 0.44377(12) 0.6557(3) 0.4979(2) 0.0493(10) Uani 1 1 d . . . . .
H27 H 0.453699 0.688111 0.461556 0.059 Uiso 1 1 calc R U . . .
C28 C 0.44512(12) 0.5609(3) 0.4978(2) 0.0558(11) Uani 1 1 d . . . . .
H28 H 0.456021 0.530150 0.461462 0.067 Uiso 1 1 calc R U . . .
C29 C 0.43077(12) 0.5104(3) 0.5502(2) 0.0527(11) Uani 1 1 d . . . . .
C30 C 0.41473(13) 0.5584(3) 0.6022(2) 0.0632(13) Uani 1 1 d . . . . .
H30 H 0.404523 0.525796 0.638275 0.076 Uiso 1 1 calc R U . . .
C31 C 0.41317(13) 0.6531(3) 0.6031(2) 0.0566(11) Uani 1 1 d . . . . .
H31 H 0.402026 0.683649 0.639350 0.068 Uiso 1 1 calc R U . . .
C32 C 0.43312(13) 0.4071(3) 0.5499(3) 0.0753(15) Uani 1 1 d . . . . .
H32A H 0.412239 0.383077 0.517332 0.113 Uiso 1 1 calc R U . . .
H32B H 0.426263 0.383851 0.592838 0.113 Uiso 1 1 calc R U . . .
H32C H 0.462359 0.387906 0.539406 0.113 Uiso 1 1 calc R U . . .
O3 O 0.34456(9) 0.70473(19) 0.07475(14) 0.0604(8) Uani 1 1 d . . . . .
O4 O 0.20475(9) 0.62805(19) 0.12302(13) 0.0589(8) Uani 1 1 d . . . . .
N2 N 0.27758(10) 0.6658(2) 0.11580(15) 0.0437(8) Uani 1 1 d . . . . .
C33 C 0.30729(13) 0.6764(2) 0.0667(2) 0.0468(10) Uani 1 1 d . . . . .
C34 C 0.23659(14) 0.6386(3) 0.0900(2) 0.0480(10) Uani 1 1 d . . . . .
C35 C 0.24174(13) 0.6266(2) 0.01860(19) 0.0447(10) Uani 1 1 d . . . . .
C36 C 0.28431(13) 0.6478(2) 0.00438(19) 0.0450(10) Uani 1 1 d . . . . .
C37 C 0.29926(14) 0.6421(3) -0.0580(2) 0.0552(11) Uani 1 1 d . . . . .
H37 H 0.328081 0.658056 -0.067441 0.066 Uiso 1 1 calc R U . . .
C38 C 0.26976(17) 0.6117(3) -0.1063(2) 0.0657(13) Uani 1 1 d . . . . .
H38 H 0.278975 0.605572 -0.149498 0.079 Uiso 1 1 calc R U . . .
C39 C 0.22682(16) 0.5900(3) -0.0926(2) 0.0622(12) Uani 1 1 d . . . . .
H39 H 0.207612 0.569679 -0.126599 0.075 Uiso 1 1 calc R U . . .
C40 C 0.21195(14) 0.5979(2) -0.0297(2) 0.0522(11) Uani 1 1 d . . . . .
H40 H 0.182856 0.584403 -0.020204 0.063 Uiso 1 1 calc R U . . .
C41 C 0.28608(12) 0.6911(3) 0.18461(17) 0.0455(10) Uani 1 1 d . . . . .
H41A H 0.260072 0.677117 0.209270 0.055 Uiso 1 1 calc R U . . .
H41B H 0.290953 0.757361 0.187206 0.055 Uiso 1 1 calc R U . . .
C44 C 0.39847(12) 0.6471(3) 0.26853(18) 0.0447(10) Uani 1 1 d . . . . .
C42 C 0.32523(12) 0.6424(3) 0.21689(17) 0.0416(9) Uani 1 1 d . . . . .
C47 C 0.32381(12) 0.5444(3) 0.22457(18) 0.0428(10) Uani 1 1 d . . . . .
C43 C 0.36069(11) 0.6929(3) 0.23815(17) 0.0410(9) Uani 1 1 d . . . . .
C45 C 0.39785(12) 0.5509(3) 0.27577(18) 0.0483(10) Uani 1 1 d . . . . .
C58 C 0.36204(11) 0.7951(3) 0.23310(19) 0.0432(10) Uani 1 1 d . . . . .
C46 C 0.36079(13) 0.4991(3) 0.25432(18) 0.0461(10) Uani 1 1 d . . . . .
C48 C 0.28811(13) 0.4910(3) 0.20438(19) 0.0490(11) Uani 1 1 d . . . . .
H48 H 0.263113 0.519813 0.185836 0.059 Uiso 1 1 calc R U . . .
C49 C 0.28841(14) 0.3967(3) 0.21085(19) 0.0567(12) Uani 1 1 d . . . . .
H49 H 0.264144 0.362271 0.195575 0.068 Uiso 1 1 calc R U . . .
C50 C 0.32403(15) 0.3531(3) 0.2395(2) 0.0618(12) Uani 1 1 d . . . . .
H50 H 0.323946 0.288991 0.243507 0.074 Uiso 1 1 calc R U . . .
C51 C 0.36016(14) 0.4025(3) 0.2626(2) 0.0559(11) Uani 1 1 d . . . . .
C52 C 0.39757(16) 0.3592(3) 0.2930(2) 0.0757(15) Uani 1 1 d . . . . .
H52 H 0.397546 0.295358 0.299042 0.091 Uiso 1 1 calc R U . . .
C53 C 0.43301(16) 0.4084(3) 0.3131(3) 0.0818(16) Uani 1 1 d . . . . .
H53 H 0.457108 0.377815 0.332917 0.098 Uiso 1 1 calc R U . . .
C54 C 0.43494(13) 0.5054(3) 0.3053(2) 0.0602(12) Uani 1 1 d . . . . .
C55 C 0.47159(14) 0.5572(4) 0.3252(2) 0.0692(13) Uani 1 1 d . . . . .
H55 H 0.496450 0.527505 0.343402 0.083 Uiso 1 1 calc R U . . .
C56 C 0.47170(13) 0.6510(4) 0.3184(2) 0.0641(13) Uani 1 1 d . . . . .
H56 H 0.496342 0.684927 0.332823 0.077 Uiso 1 1 calc R U . . .
C57 C 0.43583(12) 0.6954(3) 0.29063(19) 0.0559(11) Uani 1 1 d . . . . .
H57 H 0.436405 0.759442 0.286379 0.067 Uiso 1 1 calc R U . . .
C59 C 0.34063(12) 0.8482(3) 0.27781(18) 0.0448(10) Uani 1 1 d . . . . .
H59 H 0.324553 0.819493 0.310275 0.054 Uiso 1 1 calc R U . . .
C60 C 0.34235(12) 0.9424(3) 0.27578(19) 0.0482(10) Uani 1 1 d . . . . .
H60 H 0.327219 0.976778 0.306544 0.058 Uiso 1 1 calc R U . . .
C61 C 0.36580(13) 0.9869(3) 0.2296(2) 0.0489(10) Uani 1 1 d . . . . .
C62 C 0.38704(14) 0.9337(3) 0.1849(2) 0.0611(12) Uani 1 1 d . . . . .
H62 H 0.403106 0.962781 0.152574 0.073 Uiso 1 1 calc R U . . .
C63 C 0.38553(13) 0.8397(3) 0.1861(2) 0.0575(11) Uani 1 1 d . . . . .
H63 H 0.400456 0.805636 0.154950 0.069 Uiso 1 1 calc R U . . .
C64 C 0.36785(15) 1.0903(3) 0.2278(2) 0.0746(14) Uani 1 1 d . . . . .
H64A H 0.340830 1.114138 0.208109 0.112 Uiso 1 1 calc R U . . .
H64B H 0.392195 1.109360 0.202008 0.112 Uiso 1 1 calc R U . . .
H64C H 0.371821 1.113696 0.272075 0.112 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
O1 C1 1.210(4) . ?
O2 C2 1.214(4) . ?
N1 C1 1.405(5) . ?
N1 C2 1.398(4) . ?
N1 C9 1.473(4) . ?
C1 C4 1.486(5) . ?
C2 C3 1.481(5) . ?
C3 C4 1.381(5) . ?
C3 C8 1.378(5) . ?
C4 C5 1.366(5) . ?
C5 H5 0.9400 . ?
C5 C6 1.394(5) . ?
C6 H6 0.9400 . ?
C6 C7 1.388(5) . ?
C7 H7 0.9400 . ?
C7 C8 1.391(5) . ?
C8 H8 0.9400 . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 C10 1.515(5) . ?
C10 C11 1.365(5) . ?
C10 C15 1.458(5) . ?
C11 C12 1.449(5) . ?
C11 C26 1.508(5) . ?
C12 C13 1.431(5) . ?
C12 C25 1.391(5) . ?
C13 C14 1.422(5) . ?
C13 C22 1.415(5) . ?
C14 C15 1.415(5) . ?
C14 C19 1.417(5) . ?
C15 C16 1.389(5) . ?
C16 H16 0.9400 . ?
C16 C17 1.382(5) . ?
C17 H17 0.9400 . ?
C17 C18 1.371(6) . ?
C18 H18 0.9400 . ?
C18 C19 1.393(6) . ?
C19 C20 1.423(5) . ?
C20 H20 0.9400 . ?
C20 C21 1.346(6) . ?
C21 H21 0.9400 . ?
C21 C22 1.431(6) . ?
C22 C23 1.400(6) . ?
C23 H23 0.9400 . ?
C23 C24 1.376(6) . ?
C24 H24 0.9400 . ?
C24 C25 1.386(5) . ?
C25 H25 0.9400 . ?
C26 C27 1.380(5) . ?
C26 C31 1.393(5) . ?
C27 H27 0.9400 . ?
C27 C28 1.386(5) . ?
C28 H28 0.9400 . ?
C28 C29 1.385(5) . ?
C29 C30 1.379(6) . ?
C29 C32 1.511(5) . ?
C30 H30 0.9400 . ?
C30 C31 1.384(6) . ?
C31 H31 0.9400 . ?
C32 H32A 0.9700 . ?
C32 H32B 0.9700 . ?
C32 H32C 0.9700 . ?
O3 C33 1.219(4) . ?
O4 C34 1.217(4) . ?
N2 C33 1.389(5) . ?
N2 C34 1.399(5) . ?
N2 C41 1.466(4) . ?
C33 C36 1.489(5) . ?
C34 C35 1.483(5) . ?
C35 C36 1.382(5) . ?
C35 C40 1.381(5) . ?
C36 C37 1.373(5) . ?
C37 H37 0.9400 . ?
C37 C38 1.384(6) . ?
C38 H38 0.9400 . ?
C38 C39 1.391(6) . ?
C39 H39 0.9400 . ?
C39 C40 1.385(6) . ?
C40 H40 0.9400 . ?
C41 H41A 0.9800 . ?
C41 H41B 0.9800 . ?
C41 C42 1.522(5) . ?
C44 C43 1.454(5) . ?
C44 C45 1.414(5) . ?
C44 C57 1.403(5) . ?
C42 C47 1.441(5) . ?
C42 C43 1.369(5) . ?
C47 C46 1.427(5) . ?
C47 C48 1.392(5) . ?
C43 C58 1.496(5) . ?
C45 C46 1.419(5) . ?
C45 C54 1.429(5) . ?
C58 C59 1.383(5) . ?
C58 C63 1.384(5) . ?
C46 C51 1.420(5) . ?
C48 H48 0.9400 . ?
C48 C49 1.384(5) . ?
C49 H49 0.9400 . ?
C49 C50 1.374(5) . ?
C50 H50 0.9400 . ?
C50 C51 1.388(5) . ?
C51 C52 1.429(5) . ?
C52 H52 0.9400 . ?
C52 C53 1.353(6) . ?
C53 H53 0.9400 . ?
C53 C54 1.427(6) . ?
C54 C55 1.400(6) . ?
C55 H55 0.9400 . ?
C55 C56 1.378(6) . ?
C56 H56 0.9400 . ?
C56 C57 1.378(5) . ?
C57 H57 0.9400 . ?
C59 H59 0.9400 . ?
C59 C60 1.377(5) . ?
C60 H60 0.9400 . ?
C60 C61 1.371(5) . ?
C61 C62 1.380(5) . ?
C61 C64 1.512(5) . ?
C62 H62 0.9400 . ?
C62 C63 1.374(5) . ?
C63 H63 0.9400 . ?
C64 H64A 0.9700 . ?
C64 H64B 0.9700 . ?
C64 H64C 0.9700 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 N1 C9 124.6(3) . . ?
C2 N1 C1 110.4(3) . . ?
C2 N1 C9 124.4(3) . . ?
O1 C1 N1 124.6(4) . . ?
O1 C1 C4 129.0(4) . . ?
N1 C1 C4 106.5(3) . . ?
O2 C2 N1 124.4(3) . . ?
O2 C2 C3 128.7(4) . . ?
N1 C2 C3 106.9(3) . . ?
C4 C3 C2 108.1(3) . . ?
C8 C3 C2 129.8(4) . . ?
C8 C3 C4 122.1(4) . . ?
C3 C4 C1 108.0(3) . . ?
C5 C4 C1 130.6(4) . . ?
C5 C4 C3 121.4(3) . . ?
C4 C5 H5 121.2 . . ?
C4 C5 C6 117.6(4) . . ?
C6 C5 H5 121.2 . . ?
C5 C6 H6 119.6 . . ?
C7 C6 C5 120.7(4) . . ?
C7 C6 H6 119.6 . . ?
C6 C7 H7 119.3 . . ?
C6 C7 C8 121.4(4) . . ?
C8 C7 H7 119.3 . . ?
C3 C8 C7 116.7(4) . . ?
C3 C8 H8 121.7 . . ?
C7 C8 H8 121.7 . . ?
N1 C9 H9A 108.9 . . ?
N1 C9 H9B 108.9 . . ?
N1 C9 C10 113.4(3) . . ?
H9A C9 H9B 107.7 . . ?
C10 C9 H9A 108.9 . . ?
C10 C9 H9B 108.9 . . ?
C11 C10 C9 119.8(3) . . ?
C11 C10 C15 121.3(3) . . ?
C15 C10 C9 118.9(3) . . ?
C10 C11 C12 120.7(3) . . ?
C10 C11 C26 122.2(3) . . ?
C12 C11 C26 117.0(3) . . ?
C13 C12 C11 118.6(3) . . ?
C25 C12 C11 123.3(4) . . ?
C25 C12 C13 118.1(4) . . ?
C14 C13 C12 120.1(3) . . ?
C22 C13 C12 119.9(4) . . ?
C22 C13 C14 120.0(4) . . ?
C15 C14 C13 120.8(4) . . ?
C15 C14 C19 119.6(4) . . ?
C19 C14 C13 119.7(4) . . ?
C14 C15 C10 118.2(3) . . ?
C16 C15 C10 122.5(3) . . ?
C16 C15 C14 119.2(3) . . ?
C15 C16 H16 119.8 . . ?
C17 C16 C15 120.4(4) . . ?
C17 C16 H16 119.8 . . ?
C16 C17 H17 119.4 . . ?
C18 C17 C16 121.1(4) . . ?
C18 C17 H17 119.4 . . ?
C17 C18 H18 119.8 . . ?
C17 C18 C19 120.5(4) . . ?
C19 C18 H18 119.8 . . ?
C14 C19 C20 118.9(4) . . ?
C18 C19 C14 119.2(4) . . ?
C18 C19 C20 121.9(4) . . ?
C19 C20 H20 119.3 . . ?
C21 C20 C19 121.4(4) . . ?
C21 C20 H20 119.3 . . ?
C20 C21 H21 119.3 . . ?
C20 C21 C22 121.3(4) . . ?
C22 C21 H21 119.3 . . ?
C13 C22 C21 118.6(4) . . ?
C23 C22 C13 119.6(4) . . ?
C23 C22 C21 121.8(4) . . ?
C22 C23 H23 120.1 . . ?
C24 C23 C22 119.9(4) . . ?
C24 C23 H23 120.1 . . ?
C23 C24 H24 119.4 . . ?
C23 C24 C25 121.2(4) . . ?
C25 C24 H24 119.4 . . ?
C12 C25 H25 119.4 . . ?
C24 C25 C12 121.3(4) . . ?
C24 C25 H25 119.4 . . ?
C27 C26 C11 118.5(4) . . ?
C27 C26 C31 118.0(4) . . ?
C31 C26 C11 123.5(4) . . ?
C26 C27 H27 119.5 . . ?
C26 C27 C28 121.0(4) . . ?
C28 C27 H27 119.5 . . ?
C27 C28 H28 119.3 . . ?
C29 C28 C27 121.4(4) . . ?
C29 C28 H28 119.3 . . ?
C28 C29 C32 120.8(4) . . ?
C30 C29 C28 117.2(4) . . ?
C30 C29 C32 122.0(4) . . ?
C29 C30 H30 119.0 . . ?
C29 C30 C31 122.1(4) . . ?
C31 C30 H30 119.0 . . ?
C26 C31 H31 119.9 . . ?
C30 C31 C26 120.3(4) . . ?
C30 C31 H31 119.9 . . ?
C29 C32 H32A 109.5 . . ?
C29 C32 H32B 109.5 . . ?
C29 C32 H32C 109.5 . . ?
H32A C32 H32B 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
C33 N2 C34 111.3(3) . . ?
C33 N2 C41 124.6(3) . . ?
C34 N2 C41 123.7(3) . . ?
O3 C33 N2 125.2(4) . . ?
O3 C33 C36 128.3(4) . . ?
N2 C33 C36 106.5(3) . . ?
O4 C34 N2 123.6(4) . . ?
O4 C34 C35 130.4(4) . . ?
N2 C34 C35 106.0(3) . . ?
C36 C35 C34 108.5(3) . . ?
C40 C35 C34 130.2(4) . . ?
C40 C35 C36 121.3(4) . . ?
C35 C36 C33 107.6(3) . . ?
C37 C36 C33 130.2(4) . . ?
C37 C36 C35 122.2(4) . . ?
C36 C37 H37 121.7 . . ?
C36 C37 C38 116.7(4) . . ?
C38 C37 H37 121.7 . . ?
C37 C38 H38 119.2 . . ?
C37 C38 C39 121.7(4) . . ?
C39 C38 H38 119.2 . . ?
C38 C39 H39 119.5 . . ?
C40 C39 C38 121.0(4) . . ?
C40 C39 H39 119.5 . . ?
C35 C40 C39 117.1(4) . . ?
C35 C40 H40 121.4 . . ?
C39 C40 H40 121.4 . . ?
N2 C41 H41A 108.8 . . ?
N2 C41 H41B 108.8 . . ?
N2 C41 C42 113.8(3) . . ?
H41A C41 H41B 107.7 . . ?
C42 C41 H41A 108.8 . . ?
C42 C41 H41B 108.8 . . ?
C45 C44 C43 119.2(3) . . ?
C57 C44 C43 122.1(4) . . ?
C57 C44 C45 118.7(4) . . ?
C47 C42 C41 119.0(3) . . ?
C43 C42 C41 119.2(3) . . ?
C43 C42 C47 121.8(3) . . ?
C46 C47 C42 118.7(3) . . ?
C48 C47 C42 123.4(3) . . ?
C48 C47 C46 117.8(4) . . ?
C44 C43 C58 117.7(3) . . ?
C42 C43 C44 119.7(3) . . ?
C42 C43 C58 122.6(3) . . ?
C44 C45 C46 120.8(3) . . ?
C44 C45 C54 119.5(4) . . ?
C46 C45 C54 119.6(4) . . ?
C59 C58 C43 120.0(3) . . ?
C59 C58 C63 117.7(4) . . ?
C63 C58 C43 122.3(4) . . ?
C45 C46 C47 119.7(4) . . ?
C45 C46 C51 120.5(4) . . ?
C51 C46 C47 119.8(4) . . ?
C47 C48 H48 119.1 . . ?
C49 C48 C47 121.8(4) . . ?
C49 C48 H48 119.1 . . ?
C48 C49 H49 119.9 . . ?
C50 C49 C48 120.3(4) . . ?
C50 C49 H49 119.9 . . ?
C49 C50 H50 119.6 . . ?
C49 C50 C51 120.9(4) . . ?
C51 C50 H50 119.6 . . ?
C46 C51 C52 118.5(4) . . ?
C50 C51 C46 119.3(4) . . ?
C50 C51 C52 122.1(4) . . ?
C51 C52 H52 119.5 . . ?
C53 C52 C51 121.1(4) . . ?
C53 C52 H52 119.5 . . ?
C52 C53 H53 119.0 . . ?
C52 C53 C54 122.0(4) . . ?
C54 C53 H53 119.0 . . ?
C53 C54 C45 118.3(4) . . ?
C55 C54 C45 119.1(4) . . ?
C55 C54 C53 122.7(4) . . ?
C54 C55 H55 119.5 . . ?
C56 C55 C54 120.9(4) . . ?
C56 C55 H55 119.5 . . ?
C55 C56 H56 119.9 . . ?
C55 C56 C57 120.3(4) . . ?
C57 C56 H56 119.9 . . ?
C44 C57 H57 119.2 . . ?
C56 C57 C44 121.5(4) . . ?
C56 C57 H57 119.2 . . ?
C58 C59 H59 119.3 . . ?
C60 C59 C58 121.4(4) . . ?
C60 C59 H59 119.3 . . ?
C59 C60 H60 119.5 . . ?
C61 C60 C59 121.0(4) . . ?
C61 C60 H60 119.5 . . ?
C60 C61 C62 117.5(4) . . ?
C60 C61 C64 120.8(4) . . ?
C62 C61 C64 121.7(4) . . ?
C61 C62 H62 118.9 . . ?
C63 C62 C61 122.3(4) . . ?
C63 C62 H62 118.9 . . ?
C58 C63 H63 120.0 . . ?
C62 C63 C58 120.1(4) . . ?
C62 C63 H63 120.0 . . ?
C61 C64 H64A 109.5 . . ?
C61 C64 H64B 109.5 . . ?
C61 C64 H64C 109.5 . . ?
H64A C64 H64B 109.5 . . ?
H64A C64 H64C 109.5 . . ?
H64B C64 H64C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O1 C1 C4 C3 -176.0(4) . . . . ?
O1 C1 C4 C5 3.7(7) . . . . ?
O2 C2 C3 C4 -179.9(4) . . . . ?
O2 C2 C3 C8 -0.3(6) . . . . ?
N1 C1 C4 C3 2.9(4) . . . . ?
N1 C1 C4 C5 -177.4(4) . . . . ?
N1 C2 C3 C4 -0.1(4) . . . . ?
N1 C2 C3 C8 179.5(3) . . . . ?
N1 C9 C10 C11 109.8(4) . . . . ?
N1 C9 C10 C15 -70.4(4) . . . . ?
C1 N1 C2 O2 -178.2(3) . . . . ?
C1 N1 C2 C3 2.0(4) . . . . ?
C1 N1 C9 C10 -65.0(4) . . . . ?
C1 C4 C5 C6 -179.3(4) . . . . ?
C2 N1 C1 O1 176.0(3) . . . . ?
C2 N1 C1 C4 -3.0(4) . . . . ?
C2 N1 C9 C10 124.9(4) . . . . ?
C2 C3 C4 C1 -1.7(4) . . . . ?
C2 C3 C4 C5 178.5(3) . . . . ?
C2 C3 C8 C7 -178.1(3) . . . . ?
C3 C4 C5 C6 0.4(5) . . . . ?
C4 C3 C8 C7 1.4(5) . . . . ?
C4 C5 C6 C7 -0.1(6) . . . . ?
C5 C6 C7 C8 0.4(6) . . . . ?
C6 C7 C8 C3 -1.1(5) . . . . ?
C8 C3 C4 C1 178.6(3) . . . . ?
C8 C3 C4 C5 -1.1(5) . . . . ?
C9 N1 C1 O1 4.7(6) . . . . ?
C9 N1 C1 C4 -174.3(3) . . . . ?
C9 N1 C2 O2 -6.9(6) . . . . ?
C9 N1 C2 C3 173.3(3) . . . . ?
C9 C10 C11 C12 -173.5(3) . . . . ?
C9 C10 C11 C26 9.7(5) . . . . ?
C9 C10 C15 C14 176.1(3) . . . . ?
C9 C10 C15 C16 -6.9(5) . . . . ?
C10 C11 C12 C13 -3.9(5) . . . . ?
C10 C11 C12 C25 175.2(4) . . . . ?
C10 C11 C26 C27 73.5(5) . . . . ?
C10 C11 C26 C31 -109.5(4) . . . . ?
C10 C15 C16 C17 -178.3(4) . . . . ?
C11 C10 C15 C14 -4.2(5) . . . . ?
C11 C10 C15 C16 172.8(4) . . . . ?
C11 C12 C13 C14 -1.5(5) . . . . ?
C11 C12 C13 C22 -179.9(3) . . . . ?
C11 C12 C25 C24 -177.7(4) . . . . ?
C11 C26 C27 C28 176.4(3) . . . . ?
C11 C26 C31 C30 -176.3(4) . . . . ?
C12 C11 C26 C27 -103.3(4) . . . . ?
C12 C11 C26 C31 73.6(5) . . . . ?
C12 C13 C14 C15 4.0(5) . . . . ?
C12 C13 C14 C19 -177.2(3) . . . . ?
C12 C13 C22 C21 178.2(4) . . . . ?
C12 C13 C22 C23 -2.8(6) . . . . ?
C13 C12 C25 C24 1.4(6) . . . . ?
C13 C14 C15 C10 -1.3(5) . . . . ?
C13 C14 C15 C16 -178.4(3) . . . . ?
C13 C14 C19 C18 179.1(4) . . . . ?
C13 C14 C19 C20 -1.4(5) . . . . ?
C13 C22 C23 C24 2.3(6) . . . . ?
C14 C13 C22 C21 -0.3(6) . . . . ?
C14 C13 C22 C23 178.8(4) . . . . ?
C14 C15 C16 C17 -1.3(6) . . . . ?
C14 C19 C20 C21 0.7(6) . . . . ?
C15 C10 C11 C12 6.8(5) . . . . ?
C15 C10 C11 C26 -170.0(3) . . . . ?
C15 C14 C19 C18 -2.1(5) . . . . ?
C15 C14 C19 C20 177.4(3) . . . . ?
C15 C16 C17 C18 -0.9(6) . . . . ?
C16 C17 C18 C19 1.6(7) . . . . ?
C17 C18 C19 C14 -0.1(6) . . . . ?
C17 C18 C19 C20 -179.6(4) . . . . ?
C18 C19 C20 C21 -179.9(4) . . . . ?
C19 C14 C15 C10 179.9(3) . . . . ?
C19 C14 C15 C16 2.8(5) . . . . ?
C19 C20 C21 C22 0.3(7) . . . . ?
C20 C21 C22 C13 -0.5(6) . . . . ?
C20 C21 C22 C23 -179.6(4) . . . . ?
C21 C22 C23 C24 -178.6(4) . . . . ?
C22 C13 C14 C15 -177.6(3) . . . . ?
C22 C13 C14 C19 1.3(5) . . . . ?
C22 C23 C24 C25 0.0(7) . . . . ?
C23 C24 C25 C12 -1.9(7) . . . . ?
C25 C12 C13 C14 179.3(4) . . . . ?
C25 C12 C13 C22 0.9(5) . . . . ?
C26 C11 C12 C13 173.0(3) . . . . ?
C26 C11 C12 C25 -7.8(5) . . . . ?
C26 C27 C28 C29 0.1(6) . . . . ?
C27 C26 C31 C30 0.6(6) . . . . ?
C27 C28 C29 C30 0.5(6) . . . . ?
C27 C28 C29 C32 -179.0(4) . . . . ?
C28 C29 C30 C31 -0.6(6) . . . . ?
C29 C30 C31 C26 0.0(6) . . . . ?
C31 C26 C27 C28 -0.7(6) . . . . ?
C32 C29 C30 C31 179.0(4) . . . . ?
O3 C33 C36 C35 -176.0(4) . . . . ?
O3 C33 C36 C37 3.2(7) . . . . ?
O4 C34 C35 C36 179.5(4) . . . . ?
O4 C34 C35 C40 -1.7(7) . . . . ?
N2 C33 C36 C35 3.3(4) . . . . ?
N2 C33 C36 C37 -177.5(4) . . . . ?
N2 C34 C35 C36 -0.9(4) . . . . ?
N2 C34 C35 C40 177.9(4) . . . . ?
N2 C41 C42 C47 -64.2(4) . . . . ?
N2 C41 C42 C43 116.1(4) . . . . ?
C33 N2 C34 O4 -177.3(4) . . . . ?
C33 N2 C34 C35 3.1(4) . . . . ?
C33 N2 C41 C42 -58.7(5) . . . . ?
C33 C36 C37 C38 179.3(4) . . . . ?
C34 N2 C33 O3 175.4(4) . . . . ?
C34 N2 C33 C36 -4.0(4) . . . . ?
C34 N2 C41 C42 129.7(4) . . . . ?
C34 C35 C36 C33 -1.4(4) . . . . ?
C34 C35 C36 C37 179.3(3) . . . . ?
C34 C35 C40 C39 -177.7(4) . . . . ?
C35 C36 C37 C38 -1.6(6) . . . . ?
C36 C35 C40 C39 1.0(5) . . . . ?
C36 C37 C38 C39 1.4(6) . . . . ?
C37 C38 C39 C40 -0.1(6) . . . . ?
C38 C39 C40 C35 -1.1(6) . . . . ?
C40 C35 C36 C33 179.7(3) . . . . ?
C40 C35 C36 C37 0.4(6) . . . . ?
C41 N2 C33 O3 2.9(6) . . . . ?
C41 N2 C33 C36 -176.4(3) . . . . ?
C41 N2 C34 O4 -4.7(6) . . . . ?
C41 N2 C34 C35 175.7(3) . . . . ?
C41 C42 C47 C46 179.4(3) . . . . ?
C41 C42 C47 C48 -0.5(5) . . . . ?
C41 C42 C43 C44 -179.4(3) . . . . ?
C41 C42 C43 C58 2.2(5) . . . . ?
C44 C43 C58 C59 -100.1(4) . . . . ?
C44 C43 C58 C63 77.5(5) . . . . ?
C44 C45 C46 C47 0.5(6) . . . . ?
C44 C45 C46 C51 -179.1(4) . . . . ?
C44 C45 C54 C53 178.7(4) . . . . ?
C44 C45 C54 C55 -1.4(6) . . . . ?
C42 C47 C46 C45 0.2(5) . . . . ?
C42 C47 C46 C51 179.8(3) . . . . ?
C42 C47 C48 C49 178.1(4) . . . . ?
C42 C43 C58 C59 78.3(5) . . . . ?
C42 C43 C58 C63 -104.1(4) . . . . ?
C47 C42 C43 C44 0.9(5) . . . . ?
C47 C42 C43 C58 -177.4(3) . . . . ?
C47 C46 C51 C50 2.3(6) . . . . ?
C47 C46 C51 C52 -179.6(4) . . . . ?
C47 C48 C49 C50 1.9(6) . . . . ?
C43 C44 C45 C46 -0.6(5) . . . . ?
C43 C44 C45 C54 179.7(3) . . . . ?
C43 C44 C57 C56 -179.0(4) . . . . ?
C43 C42 C47 C46 -0.9(5) . . . . ?
C43 C42 C47 C48 179.1(4) . . . . ?
C43 C58 C59 C60 178.0(3) . . . . ?
C43 C58 C63 C62 -177.7(4) . . . . ?
C45 C44 C43 C42 -0.2(5) . . . . ?
C45 C44 C43 C58 178.3(3) . . . . ?
C45 C44 C57 C56 0.6(6) . . . . ?
C45 C46 C51 C50 -178.1(4) . . . . ?
C45 C46 C51 C52 0.0(6) . . . . ?
C45 C54 C55 C56 1.9(6) . . . . ?
C58 C59 C60 C61 -0.6(6) . . . . ?
C46 C47 C48 C49 -1.8(6) . . . . ?
C46 C45 C54 C53 -1.0(6) . . . . ?
C46 C45 C54 C55 178.9(4) . . . . ?
C46 C51 C52 C53 -0.4(7) . . . . ?
C48 C47 C46 C45 -179.9(3) . . . . ?
C48 C47 C46 C51 -0.2(5) . . . . ?
C48 C49 C50 C51 0.2(6) . . . . ?
C49 C50 C51 C46 -2.3(6) . . . . ?
C49 C50 C51 C52 179.7(4) . . . . ?
C50 C51 C52 C53 177.7(5) . . . . ?
C51 C52 C53 C54 0.0(8) . . . . ?
C52 C53 C54 C45 0.7(7) . . . . ?
C52 C53 C54 C55 -179.2(5) . . . . ?
C53 C54 C55 C56 -178.2(4) . . . . ?
C54 C45 C46 C47 -179.7(3) . . . . ?
C54 C45 C46 C51 0.7(6) . . . . ?
C54 C55 C56 C57 -1.3(7) . . . . ?
C55 C56 C57 C44 0.0(6) . . . . ?
C57 C44 C43 C42 179.4(4) . . . . ?
C57 C44 C43 C58 -2.2(5) . . . . ?
C57 C44 C45 C46 179.9(4) . . . . ?
C57 C44 C45 C54 0.1(5) . . . . ?
C59 C58 C63 C62 0.0(6) . . . . ?
C59 C60 C61 C62 0.8(6) . . . . ?
C59 C60 C61 C64 -179.6(4) . . . . ?
C60 C61 C62 C63 -0.5(6) . . . . ?
C61 C62 C63 C58 0.1(6) . . . . ?
C63 C58 C59 C60 0.2(5) . . . . ?
C64 C61 C62 C63 179.9(4) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
