# Electronic Supplementary Material (ESI) for Organic Chemistry Frontiers.
# This journal is © the Partner Organisations 2023

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_pccn
_database_code_depnum_ccdc_archive 'CCDC 2106357'
loop_
_audit_author_name
_audit_author_address
'Hu Cai'
;Nanchang University
China
;
_audit_update_record             
;
2021-08-30 deposited with the CCDC.	2023-05-02 downloaded from the CCDC.
;
_audit_creation_date             2021-08-29
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C24 H25 N O'
_chemical_formula_sum            'C24 H25 N O'
_chemical_formula_weight         343.45
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           56
_space_group_name_H-M_alt        'P c c n'
_space_group_name_Hall           '-P 2ab 2ac'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y+1/2, z'
'x+1/2, -y, -z+1/2'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, y-1/2, -z'
'-x-1/2, y, z-1/2'
'x, -y-1/2, z-1/2'

_cell_length_a                   18.0253(8)
_cell_length_b                   30.0603(13)
_cell_length_c                   6.9438(3)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     3762.5(3)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    7796
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      30.1170
_cell_measurement_theta_min      2.3190
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    0.073
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_type   none
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            ?
_exptl_crystal_density_diffrn    1.213
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1472
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.23
_exptl_crystal_size_min          0.2
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0251
_diffrn_reflns_av_unetI/netI     0.0245
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.836
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_k_max       40
_diffrn_reflns_limit_k_min       -37
_diffrn_reflns_limit_l_max       8
_diffrn_reflns_limit_l_min       -8
_diffrn_reflns_number            20956
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.836
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         30.805
_diffrn_reflns_theta_min         2.260
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.836
_diffrn_measurement_device_type  'multiwire proportional'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                3318
_reflns_number_total             4921
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'olex2.solve (Bourhis et al., 2015)'
_refine_diff_density_max         0.133
_refine_diff_density_min         -0.167
_refine_diff_density_rms         0.035
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.035
_refine_ls_hydrogen_treatment    refall
_refine_ls_matrix_type           full
_refine_ls_number_parameters     335
_refine_ls_number_reflns         4921
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0698
_refine_ls_R_factor_gt           0.0439
_refine_ls_restrained_S_all      1.035
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0680P)²+0.2860P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1184
_refine_ls_wR_factor_ref         0.1318
_refine_special_details          ?
_olex2_refinement_description    
;
;
_atom_sites_solution_hydrogens   difmap
_atom_sites_solution_primary     iterative
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.47011(5) 0.12556(3) 0.65700(14) 0.0365(2) Uani 1 1 d . . . . .
C2 C 0.52015(6) 0.15259(4) 0.51910(16) 0.0425(3) Uani 1 1 d . . . . .
C3 C 0.41813(6) 0.09542(4) 0.54256(15) 0.0385(2) Uani 1 1 d . . . . .
N4 N 0.51986(5) 0.09765(4) 0.77472(14) 0.0467(2) Uani 1 1 d . . . . .
C5 C 0.61189(6) 0.14959(4) 0.23935(15) 0.0438(3) Uani 1 1 d . . . . .
C6 C 0.42575(6) 0.15833(4) 0.78546(14) 0.0388(2) Uani 1 1 d . . . . .
C7 C 0.56620(8) 0.12402(4) 0.38347(19) 0.0514(3) Uani 1 1 d . . . . .
O8 O 0.65533(5) 0.08086(4) 0.12950(14) 0.0658(3) Uani 1 1 d . . . . .
C9 C 0.65614(6) 0.12614(5) 0.10865(17) 0.0508(3) Uani 1 1 d . . . . .
C10 C 0.46400(8) 0.18943(4) 0.89616(17) 0.0513(3) Uani 1 1 d . . . . .
C11 C 0.37727(7) 0.11287(5) 0.38938(17) 0.0496(3) Uani 1 1 d . . . . .
C12 C 0.61240(7) 0.19573(5) 0.22674(18) 0.0519(3) Uani 1 1 d . . . . .
C13 C 0.32829(8) 0.08660(6) 0.2855(2) 0.0661(4) Uani 1 1 d . . . . .
C14 C 0.40937(7) 0.05077(4) 0.5892(2) 0.0533(3) Uani 1 1 d . . . . .
C15 C 0.34919(7) 0.15758(5) 0.80273(19) 0.0531(3) Uani 1 1 d . . . . .
C16 C 0.48078(9) 0.06458(5) 0.8888(2) 0.0619(4) Uani 1 1 d . . . . .
C17 C 0.42716(9) 0.21860(5) 1.01669(19) 0.0630(4) Uani 1 1 d . . . . .
C18 C 0.69733(8) 0.14837(7) -0.0302(2) 0.0695(4) Uani 1 1 d . . . . .
C19 C 0.69580(9) 0.19404(7) -0.0395(2) 0.0766(5) Uani 1 1 d . . . . .
C20 C 0.65414(8) 0.21797(6) 0.0890(2) 0.0670(4) Uani 1 1 d . . . . .
C21 C 0.35973(10) 0.02493(6) 0.4827(3) 0.0774(5) Uani 1 1 d . . . . .
C22 C 0.35054(9) 0.21731(5) 1.0308(2) 0.0665(4) Uani 1 1 d . . . . .
C23 C 0.45248(10) 0.02980(5) 0.7514(3) 0.0741(5) Uani 1 1 d . . . . .
C24 C 0.31939(9) 0.04272(6) 0.3338(3) 0.0788(5) Uani 1 1 d . . . . .
C25 C 0.31211(9) 0.18695(5) 0.9237(2) 0.0670(4) Uani 1 1 d . . . . .
C26 C 0.69261(14) 0.05508(9) -0.0115(4) 0.0945(6) Uani 1 1 d . . . . .
H2A H 0.4869(7) 0.1747(4) 0.4465(18) 0.047(3) Uiso 1 1 d . . . . .
H2B H 0.5545(8) 0.1700(4) 0.5985(19) 0.053(3) Uiso 1 1 d . . . . .
H15 H 0.3210(8) 0.1356(5) 0.724(2) 0.058(4) Uiso 1 1 d . . . . .
H12 H 0.5811(8) 0.2129(5) 0.318(2) 0.061(4) Uiso 1 1 d . . . . .
H10 H 0.5172(9) 0.1911(5) 0.891(2) 0.063(4) Uiso 1 1 d . . . . .
H11 H 0.3823(8) 0.1451(5) 0.357(2) 0.065(4) Uiso 1 1 d . . . . .
H17 H 0.4551(9) 0.2397(6) 1.093(2) 0.082(5) Uiso 1 1 d . . . . .
H22 H 0.3261(9) 0.2386(6) 1.113(3) 0.085(5) Uiso 1 1 d . . . . .
H16A H 0.4377(10) 0.0772(5) 0.961(2) 0.082(5) Uiso 1 1 d . . . . .
H7A H 0.5986(10) 0.1032(6) 0.457(3) 0.086(5) Uiso 1 1 d . . . . .
H7B H 0.5332(10) 0.1041(6) 0.310(2) 0.081(5) Uiso 1 1 d . . . . .
H4 H 0.5461(9) 0.1163(5) 0.853(2) 0.066(4) Uiso 1 1 d . . . . .
H13 H 0.2998(10) 0.0998(6) 0.177(3) 0.091(5) Uiso 1 1 d . . . . .
H25 H 0.2586(12) 0.1853(6) 0.937(3) 0.096(6) Uiso 1 1 d . . . . .
H24 H 0.2842(11) 0.0236(6) 0.267(3) 0.098(6) Uiso 1 1 d . . . . .
H26A H 0.7452(14) 0.0632(7) -0.015(3) 0.112(7) Uiso 1 1 d . . . . .
H19 H 0.7256(11) 0.2090(6) -0.137(3) 0.102(6) Uiso 1 1 d . . . . .
H16B H 0.5181(9) 0.0523(6) 0.986(2) 0.080(5) Uiso 1 1 d . . . . .
H23A H 0.4203(12) 0.0079(7) 0.817(3) 0.112(6) Uiso 1 1 d . . . . .
H20 H 0.6548(9) 0.2514(7) 0.084(3) 0.085(5) Uiso 1 1 d . . . . .
H21 H 0.3546(12) -0.0071(7) 0.515(3) 0.107(7) Uiso 1 1 d . . . . .
H18 H 0.7258(10) 0.1317(5) -0.111(3) 0.083(5) Uiso 1 1 d . . . . .
H23B H 0.4978(11) 0.0128(6) 0.696(3) 0.096(6) Uiso 1 1 d . . . . .
H26B H 0.6690(12) 0.0594(7) -0.137(4) 0.116(8) Uiso 1 1 d . . . . .
H26C H 0.6842(14) 0.0234(9) 0.023(4) 0.137(9) Uiso 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C2 1.5463(14) . ?
C1 C3 1.5265(14) . ?
C1 N4 1.4752(13) . ?
C1 C6 1.5509(14) . ?
C2 C7 1.5211(16) . ?
C2 H2A 1.026(13) . ?
C2 H2B 0.980(14) . ?
C3 C11 1.3961(16) . ?
C3 C14 1.3896(17) . ?
N4 C16 1.4530(17) . ?
N4 H4 0.912(16) . ?
C5 C7 1.5068(15) . ?
C5 C9 1.3988(17) . ?
C5 C12 1.3897(18) . ?
C6 C10 1.3930(16) . ?
C6 C15 1.3854(16) . ?
C7 H7A 0.997(19) . ?
C7 H7B 0.986(18) . ?
O8 C9 1.3689(17) . ?
O8 C26 1.4181(19) . ?
C9 C18 1.3886(19) . ?
C10 C17 1.3822(18) . ?
C10 H10 0.962(15) . ?
C11 C13 1.3868(19) . ?
C11 H11 0.999(16) . ?
C12 C20 1.3888(18) . ?
C12 H12 0.995(15) . ?
C13 C24 1.371(3) . ?
C13 H13 0.994(18) . ?
C14 C21 1.397(2) . ?
C14 C23 1.506(2) . ?
C15 C25 1.3900(19) . ?
C15 H15 0.995(15) . ?
C16 C23 1.505(2) . ?
C16 H16A 0.999(18) . ?
C16 H16B 1.021(17) . ?
C17 C22 1.385(2) . ?
C17 H17 0.969(17) . ?
C18 C19 1.375(3) . ?
C18 H18 0.912(18) . ?
C19 C20 1.370(2) . ?
C19 H19 0.97(2) . ?
C20 H20 1.006(19) . ?
C21 C24 1.372(3) . ?
C21 H21 0.99(2) . ?
C22 C25 1.366(2) . ?
C22 H22 0.965(18) . ?
C23 H23A 0.99(2) . ?
C23 H23B 1.036(19) . ?
C24 H24 0.976(19) . ?
C25 H25 0.97(2) . ?
C26 H26A 0.98(2) . ?
C26 H26B 0.98(2) . ?
C26 H26C 0.99(3) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 C1 C6 108.84(8) . . ?
C3 C1 C2 110.34(8) . . ?
C3 C1 C6 111.10(8) . . ?
N4 C1 C2 106.70(8) . . ?
N4 C1 C3 108.91(9) . . ?
N4 C1 C6 110.85(8) . . ?
C1 C2 H2A 107.7(7) . . ?
C1 C2 H2B 107.5(8) . . ?
C7 C2 C1 113.89(9) . . ?
C7 C2 H2A 112.3(7) . . ?
C7 C2 H2B 107.7(8) . . ?
H2A C2 H2B 107.5(10) . . ?
C11 C3 C1 119.82(10) . . ?
C14 C3 C1 121.45(10) . . ?
C14 C3 C11 118.72(11) . . ?
C1 N4 H4 107.1(10) . . ?
C16 N4 C1 113.35(9) . . ?
C16 N4 H4 110.5(9) . . ?
C9 C5 C7 119.05(11) . . ?
C12 C5 C7 123.68(11) . . ?
C12 C5 C9 117.27(11) . . ?
C10 C6 C1 119.24(10) . . ?
C15 C6 C1 123.57(10) . . ?
C15 C6 C10 117.14(11) . . ?
C2 C7 H7A 110.8(10) . . ?
C2 C7 H7B 109.6(10) . . ?
C5 C7 C2 114.93(10) . . ?
C5 C7 H7A 110.0(10) . . ?
C5 C7 H7B 107.1(10) . . ?
H7A C7 H7B 103.9(14) . . ?
C9 O8 C26 117.73(14) . . ?
O8 C9 C5 115.23(10) . . ?
O8 C9 C18 123.89(13) . . ?
C18 C9 C5 120.87(14) . . ?
C6 C10 H10 120.5(9) . . ?
C17 C10 C6 121.47(13) . . ?
C17 C10 H10 118.0(9) . . ?
C3 C11 H11 119.3(9) . . ?
C13 C11 C3 121.20(13) . . ?
C13 C11 H11 119.5(9) . . ?
C5 C12 H12 118.2(8) . . ?
C20 C12 C5 121.84(14) . . ?
C20 C12 H12 119.9(8) . . ?
C11 C13 H13 119.6(11) . . ?
C24 C13 C11 119.70(15) . . ?
C24 C13 H13 120.7(11) . . ?
C3 C14 C21 119.11(14) . . ?
C3 C14 C23 121.31(12) . . ?
C21 C14 C23 119.58(13) . . ?
C6 C15 C25 121.40(13) . . ?
C6 C15 H15 118.2(8) . . ?
C25 C15 H15 120.4(8) . . ?
N4 C16 C23 107.11(12) . . ?
N4 C16 H16A 112.9(9) . . ?
N4 C16 H16B 106.7(9) . . ?
C23 C16 H16A 108.7(10) . . ?
C23 C16 H16B 112.9(10) . . ?
H16A C16 H16B 108.6(13) . . ?
C10 C17 C22 120.27(13) . . ?
C10 C17 H17 119.9(10) . . ?
C22 C17 H17 119.8(10) . . ?
C9 C18 H18 117.8(11) . . ?
C19 C18 C9 120.15(15) . . ?
C19 C18 H18 122.1(10) . . ?
C18 C19 H19 118.9(11) . . ?
C20 C19 C18 120.34(13) . . ?
C20 C19 H19 120.8(11) . . ?
C12 C20 H20 120.6(10) . . ?
C19 C20 C12 119.51(16) . . ?
C19 C20 H20 119.9(10) . . ?
C14 C21 H21 118.8(13) . . ?
C24 C21 C14 121.45(16) . . ?
C24 C21 H21 119.8(13) . . ?
C17 C22 H22 118.6(10) . . ?
C25 C22 C17 119.08(13) . . ?
C25 C22 H22 122.3(10) . . ?
C14 C23 C16 110.98(12) . . ?
C14 C23 H23A 108.8(12) . . ?
C14 C23 H23B 109.7(10) . . ?
C16 C23 H23A 111.5(13) . . ?
C16 C23 H23B 108.0(11) . . ?
H23A C23 H23B 107.8(15) . . ?
C13 C24 C21 119.82(14) . . ?
C13 C24 H24 121.7(11) . . ?
C21 C24 H24 118.4(11) . . ?
C15 C25 H25 120.2(11) . . ?
C22 C25 C15 120.63(14) . . ?
C22 C25 H25 119.1(11) . . ?
O8 C26 H26A 109.9(13) . . ?
O8 C26 H26B 109.8(13) . . ?
O8 C26 H26C 106.4(15) . . ?
H26A C26 H26B 111.4(18) . . ?
H26A C26 H26C 113(2) . . ?
H26B C26 H26C 106(2) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1 C2 C7 C5 176.39(10) . . . . ?
C1 C3 C11 C13 -178.47(11) . . . . ?
C1 C3 C14 C21 178.45(12) . . . . ?
C1 C3 C14 C23 -1.76(18) . . . . ?
C1 N4 C16 C23 71.47(14) . . . . ?
C1 C6 C10 C17 -178.33(11) . . . . ?
C1 C6 C15 C25 178.32(12) . . . . ?
C2 C1 C3 C11 -48.93(12) . . . . ?
C2 C1 C3 C14 132.14(11) . . . . ?
C2 C1 N4 C16 -169.96(10) . . . . ?
C2 C1 C6 C10 -56.35(13) . . . . ?
C2 C1 C6 C15 126.10(11) . . . . ?
C3 C1 C2 C7 -57.29(13) . . . . ?
C3 C1 N4 C16 -50.86(12) . . . . ?
C3 C1 C6 C10 -178.05(10) . . . . ?
C3 C1 C6 C15 4.40(14) . . . . ?
C3 C11 C13 C24 0.2(2) . . . . ?
C3 C14 C21 C24 -0.2(2) . . . . ?
C3 C14 C23 C16 20.3(2) . . . . ?
N4 C1 C2 C7 60.88(13) . . . . ?
N4 C1 C3 C11 -165.74(9) . . . . ?
N4 C1 C3 C14 15.34(13) . . . . ?
N4 C1 C6 C10 60.71(13) . . . . ?
N4 C1 C6 C15 -116.84(12) . . . . ?
N4 C16 C23 C14 -52.04(17) . . . . ?
C5 C9 C18 C19 0.8(2) . . . . ?
C5 C12 C20 C19 0.4(2) . . . . ?
C6 C1 C2 C7 -179.45(10) . . . . ?
C6 C1 C3 C11 71.89(12) . . . . ?
C6 C1 C3 C14 -107.04(11) . . . . ?
C6 C1 N4 C16 71.67(13) . . . . ?
C6 C10 C17 C22 0.4(2) . . . . ?
C6 C15 C25 C22 -0.6(2) . . . . ?
C7 C5 C9 O8 -2.09(16) . . . . ?
C7 C5 C9 C18 178.03(12) . . . . ?
C7 C5 C12 C20 -178.61(12) . . . . ?
O8 C9 C18 C19 -179.07(13) . . . . ?
C9 C5 C7 C2 179.93(11) . . . . ?
C9 C5 C12 C20 0.83(17) . . . . ?
C9 C18 C19 C20 0.5(2) . . . . ?
C10 C6 C15 C25 0.72(19) . . . . ?
C10 C17 C22 C25 -0.2(2) . . . . ?
C11 C3 C14 C21 -0.49(18) . . . . ?
C11 C3 C14 C23 179.30(13) . . . . ?
C11 C13 C24 C21 -0.9(2) . . . . ?
C12 C5 C7 C2 -0.64(18) . . . . ?
C12 C5 C9 O8 178.44(10) . . . . ?
C12 C5 C9 C18 -1.43(17) . . . . ?
C14 C3 C11 C13 0.49(17) . . . . ?
C14 C21 C24 C13 0.9(3) . . . . ?
C15 C6 C10 C17 -0.62(18) . . . . ?
C17 C22 C25 C15 0.3(2) . . . . ?
C18 C19 C20 C12 -1.1(2) . . . . ?
C21 C14 C23 C16 -159.91(14) . . . . ?
C23 C14 C21 C24 180.00(16) . . . . ?
C26 O8 C9 C5 173.29(15) . . . . ?
C26 O8 C9 C18 -6.8(2) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
