# Electronic Supplementary Material (ESI) for RSC Advances.
# This journal is © The Royal Society of Chemistry 2022

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_shi_4946_ilgu_autored
_database_code_depnum_ccdc_archive 'CCDC 2151141'
loop_
_audit_author_name
_audit_author_address
'Katerina Terebilenko'
;Taras Shevchenko National University of Kyiv
Ukraine
;
_audit_update_record             
;
2022-02-09 deposited with the CCDC.	2022-03-17 downloaded from the CCDC.
;
_audit_creation_date             2021-04-06
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6272)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'Eu K2 O8 P W'
_chemical_formula_sum            'Eu K2 O8 P W'
_chemical_formula_weight         572.98
_chemical_melting_point          ?
_chemical_oxdiff_formula         Eu1K2O8P1W1
_chemical_oxdiff_usercomment     zovg48
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
K K 0.2009 0.2494 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           73
_space_group_name_H-M_alt        'I b c a'
_space_group_name_Hall           '-I 2b 2c'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'
'x+1/2, y+1/2, z+1/2'
'-x+1, -y+1/2, z+1'
'-x+1/2, y+1, -z+1'
'x+1, -y+1, -z+1/2'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z-1/2'
'-x-1/2, y-1/2, z'
'-x+1/2, -y+1/2, -z+1/2'
'x, y+1/2, -z'
'x+1/2, -y, z'
'-x, y, z+1/2'

_cell_length_a                   6.9856(4)
_cell_length_b                   12.2954(5)
_cell_length_c                   19.7434(9)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     1695.79(15)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    3033
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      29.4020
_cell_measurement_theta_min      2.0550
_shelx_estimated_absorpt_T_max   0.667
_shelx_estimated_absorpt_T_min   0.073
_exptl_absorpt_coefficient_mu    22.064
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.10323
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.41.104a (Rigaku Oxford Diffraction, 2021)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear light colourless'
_exptl_crystal_density_diffrn    4.489
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       plate
_exptl_crystal_F_000             2032
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.02
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0528
_diffrn_reflns_av_unetI/netI     0.0374
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.887
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            5948
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.887
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         29.458
_diffrn_reflns_theta_min         2.063
_diffrn_ambient_temperature      293(2)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 16.1593
_diffrn_detector_type            Eos
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.887
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω    -18.00   9.00   1.00   10.00    --  -15.44 -77.00-158.00   27
  2  ω     13.00  39.00   1.00   10.00    --  -15.44  77.00 -32.00   26
  3  ω    -39.00  42.00   1.00   10.00    --   17.94 -77.00-158.00   81
  4  ω     -8.00  17.00   1.00   10.00    --   17.94  77.00 -32.00   25
  5  ω    -38.00  -7.00   1.00   10.00    --  -15.44 -77.00 120.00   31
  6  ω    -83.00 -56.00   1.00   10.00    --  -15.44-178.00  30.00   27
  7  ω     10.00  39.00   1.00   10.00    --   17.94  77.00-150.00   29
  8  ω    -20.00  53.00   1.00   10.00    --   17.94 -99.00   0.00   73
  9  ω     -8.00  39.00   1.00   10.00    --   17.94  77.00  90.00   47
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'Xcalibur, Eos'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      0.0066814000
_diffrn_orient_matrix_UB_12      -0.0188478000
_diffrn_orient_matrix_UB_13      -0.0338636000
_diffrn_orient_matrix_UB_21      0.0837138000
_diffrn_orient_matrix_UB_22      0.0317341000
_diffrn_orient_matrix_UB_23      -0.0048247000
_diffrn_orient_matrix_UB_31      0.0571504000
_diffrn_orient_matrix_UB_32      -0.0443132000
_diffrn_orient_matrix_UB_33      0.0109676000
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'fine-focus sealed X-ray tube'
_diffrn_source_type              'Enhance (Mo) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                870
_reflns_number_total             1049
_reflns_odcompleteness_completeness 100.00
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     26.32
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.41.104a (Rigaku OD, 2021)'
_computing_data_collection       'CrysAlisPro 1.171.41.104a (Rigaku OD, 2021)'
_computing_data_reduction        'CrysAlisPro 1.171.41.104a (Rigaku OD, 2021)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         2.899
_refine_diff_density_min         -1.773
_refine_diff_density_rms         0.412
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.084
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     61
_refine_ls_number_reflns         1049
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0413
_refine_ls_R_factor_gt           0.0326
_refine_ls_restrained_S_all      1.084
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0419P)²+23.6831P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0799
_refine_ls_wR_factor_ref         0.0870
_refine_special_details          ?
_olex2_refinement_description    
;
;
_atom_sites_solution_hydrogens   .
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
W1 W 0.500000 0.250000 0.66743(2) 0.01542(17) Uani 1 2 d S T P . .
Eu1 Eu 0.250000 0.32626(4) 0.500000 0.01028(17) Uani 1 2 d S T P . .
K1 K 0.4677(3) 0.42182(18) 0.84361(11) 0.0277(5) Uani 1 1 d . . . . .
P6 P 0.750000 0.4284(2) 0.500000 0.0097(6) Uani 1 2 d S T P . .
O2 O 0.5796(8) 0.3497(4) 0.4915(3) 0.0173(12) Uani 1 1 d . . . . .
O1 O 0.7285(7) 0.5022(4) 0.5610(3) 0.0151(12) Uani 1 1 d . . . . .
O3 O 0.2951(9) 0.2815(5) 0.6168(3) 0.0224(13) Uani 1 1 d . . . . .
O4 O 0.5591(10) 0.3632(5) 0.7181(3) 0.0314(15) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
W1 Eu1 3.8543(4) . ?
W1 Eu1 3.8543(4) 6_554 ?
W1 K1 4.047(2) 3_646 ?
W1 K1 4.076(2) . ?
W1 K1 4.076(2) 6_554 ?
W1 K1 3.897(2) 13_556 ?
W1 K1 4.047(2) 8_456 ?
W1 K1 3.897(2) 10_657 ?
W1 O3 1.788(6) . ?
W1 O3 1.788(6) 6_554 ?
W1 O4 1.763(6) 6_554 ?
W1 O4 1.763(6) . ?
Eu1 K1 3.847(2) 16_654 ?
Eu1 K1 3.847(2) 10_557 ?
Eu1 P6 3.132(2) 6_554 ?
Eu1 P6 3.016(2) 9_666 ?
Eu1 O2 2.475(5) 6_554 ?
Eu1 O2 2.327(6) 7_545 ?
Eu1 O2 2.475(6) 4_456 ?
Eu1 O2 2.327(6) . ?
Eu1 O1 2.433(6) 15_465 ?
Eu1 O1 2.433(6) 9_666 ?
Eu1 O3 2.392(6) 7_545 ?
Eu1 O3 2.392(6) . ?
K1 K1 3.987(2) 15_565 ?
K1 P6 3.443(2) 10_557 ?
K1 O2 3.069(6) 16_655 ?
K1 O1 2.705(6) 10_557 ?
K1 O1 2.782(6) 8_456 ?
K1 O3 3.198(7) 13_556 ?
K1 O3 2.970(7) 10_657 ?
K1 O4 3.186(7) 10_557 ?
K1 O4 2.659(6) . ?
K1 O4 2.980(7) 8_456 ?
P6 O2 1.543(6) 7_645 ?
P6 O2 1.543(6) . ?
P6 O1 1.515(5) 7_645 ?
P6 O1 1.515(5) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Eu1 W1 Eu1 61.898(9) . 6_554 ?
Eu1 W1 K1 72.78(3) 6_554 10_657 ?
Eu1 W1 K1 101.54(3) . 10_657 ?
Eu1 W1 K1 152.02(3) 6_554 . ?
Eu1 W1 K1 102.80(3) . 3_646 ?
Eu1 W1 K1 71.70(3) . 8_456 ?
Eu1 W1 K1 72.78(3) . 13_556 ?
Eu1 W1 K1 125.50(3) . . ?
Eu1 W1 K1 152.02(3) . 6_554 ?
Eu1 W1 K1 125.50(3) 6_554 6_554 ?
Eu1 W1 K1 101.54(3) 6_554 13_556 ?
Eu1 W1 K1 71.70(3) 6_554 3_646 ?
Eu1 W1 K1 102.80(3) 6_554 8_456 ?
K1 W1 K1 79.23(5) 13_556 6_554 ?
K1 W1 K1 60.21(3) 10_657 8_456 ?
K1 W1 K1 106.40(4) 10_657 6_554 ?
K1 W1 K1 60.21(3) 13_556 3_646 ?
K1 W1 K1 79.23(5) 10_657 . ?
K1 W1 K1 124.46(3) 3_646 . ?
K1 W1 K1 62.83(6) . 6_554 ?
K1 W1 K1 119.39(3) 10_657 3_646 ?
K1 W1 K1 173.59(6) 13_556 10_657 ?
K1 W1 K1 119.39(3) 13_556 8_456 ?
K1 W1 K1 173.82(6) 3_646 8_456 ?
K1 W1 K1 61.71(5) 8_456 . ?
K1 W1 K1 61.72(5) 3_646 6_554 ?
K1 W1 K1 124.46(3) 8_456 6_554 ?
K1 W1 K1 106.40(4) 13_556 . ?
O3 W1 Eu1 86.3(2) 6_554 . ?
O3 W1 Eu1 26.54(19) 6_554 6_554 ?
O3 W1 Eu1 86.34(19) . 6_554 ?
O3 W1 Eu1 26.54(19) . . ?
O3 W1 K1 54.2(2) 6_554 10_657 ?
O3 W1 K1 103.3(2) . 3_646 ?
O3 W1 K1 54.2(2) . 13_556 ?
O3 W1 K1 73.1(2) . 8_456 ?
O3 W1 K1 129.30(19) . 6_554 ?
O3 W1 K1 121.5(2) 6_554 13_556 ?
O3 W1 K1 103.3(2) 6_554 8_456 ?
O3 W1 K1 121.5(2) . 10_657 ?
O3 W1 K1 108.7(2) . . ?
O3 W1 K1 108.7(2) 6_554 6_554 ?
O3 W1 K1 73.1(2) 6_554 3_646 ?
O3 W1 K1 129.30(19) 6_554 . ?
O3 W1 O3 112.0(4) . 6_554 ?
O4 W1 Eu1 124.9(2) 6_554 . ?
O4 W1 Eu1 124.9(2) . 6_554 ?
O4 W1 Eu1 113.6(2) 6_554 6_554 ?
O4 W1 Eu1 113.6(2) . . ?
O4 W1 K1 131.0(2) . 13_556 ?
O4 W1 K1 53.7(2) 6_554 13_556 ?
O4 W1 K1 143.6(2) . 3_646 ?
O4 W1 K1 42.0(2) 6_554 3_646 ?
O4 W1 K1 28.3(2) 6_554 6_554 ?
O4 W1 K1 131.0(2) 6_554 10_657 ?
O4 W1 K1 143.6(2) 6_554 8_456 ?
O4 W1 K1 53.7(2) . 10_657 ?
O4 W1 K1 28.3(2) . . ?
O4 W1 K1 84.9(2) . 6_554 ?
O4 W1 K1 42.0(2) . 8_456 ?
O4 W1 K1 84.9(2) 6_554 . ?
O4 W1 O3 107.5(3) . 6_554 ?
O4 W1 O3 109.5(3) . . ?
O4 W1 O3 109.5(3) 6_554 6_554 ?
O4 W1 O3 107.5(3) 6_554 . ?
O4 W1 O4 110.9(4) 6_554 . ?
K1 Eu1 K1 144.44(6) 10_557 16_654 ?
P6 Eu1 K1 72.22(3) 9_666 16_654 ?
P6 Eu1 K1 107.78(3) 6_554 16_654 ?
P6 Eu1 K1 107.78(3) 6_554 10_557 ?
P6 Eu1 K1 72.22(3) 9_666 10_557 ?
P6 Eu1 P6 180.0 9_666 6_554 ?
O2 Eu1 K1 88.06(13) 6_554 16_654 ?
O2 Eu1 K1 124.59(13) 4_456 16_654 ?
O2 Eu1 K1 121.82(14) 7_545 16_654 ?
O2 Eu1 K1 88.06(13) 4_456 10_557 ?
O2 Eu1 K1 52.92(14) . 16_654 ?
O2 Eu1 K1 52.92(14) 7_545 10_557 ?
O2 Eu1 K1 124.59(14) 6_554 10_557 ?
O2 Eu1 K1 121.82(14) . 10_557 ?
O2 Eu1 P6 82.87(13) . 9_666 ?
O2 Eu1 P6 82.87(13) 7_545 9_666 ?
O2 Eu1 P6 150.95(13) 6_554 9_666 ?
O2 Eu1 P6 97.13(13) . 6_554 ?
O2 Eu1 P6 97.13(13) 7_545 6_554 ?
O2 Eu1 P6 150.95(13) 4_456 9_666 ?
O2 Eu1 P6 29.05(13) 4_456 6_554 ?
O2 Eu1 P6 29.05(13) 6_554 6_554 ?
O2 Eu1 O2 68.1(2) 7_545 4_456 ?
O2 Eu1 O2 126.10(15) 7_545 6_554 ?
O2 Eu1 O2 126.10(15) . 4_456 ?
O2 Eu1 O2 68.1(2) . 6_554 ?
O2 Eu1 O2 165.7(3) . 7_545 ?
O2 Eu1 O2 58.1(3) 4_456 6_554 ?
O2 Eu1 O1 78.22(17) 7_545 15_465 ?
O2 Eu1 O1 89.38(18) 7_545 9_666 ?
O2 Eu1 O1 78.22(18) . 9_666 ?
O2 Eu1 O1 89.38(18) . 15_465 ?
O2 Eu1 O3 95.1(2) 7_545 . ?
O2 Eu1 O3 95.1(2) . 7_545 ?
O2 Eu1 O3 88.1(2) 7_545 7_545 ?
O2 Eu1 O3 88.1(2) . . ?
O1 Eu1 K1 46.09(13) 15_465 10_557 ?
O1 Eu1 K1 46.09(13) 9_666 16_654 ?
O1 Eu1 K1 99.44(13) 15_465 16_654 ?
O1 Eu1 K1 99.44(13) 9_666 10_557 ?
O1 Eu1 P6 150.08(13) 9_666 6_554 ?
O1 Eu1 P6 150.08(13) 15_465 6_554 ?
O1 Eu1 P6 29.92(13) 15_465 9_666 ?
O1 Eu1 P6 29.92(13) 9_666 9_666 ?
O1 Eu1 O2 145.18(18) 9_666 4_456 ?
O1 Eu1 O2 145.18(18) 15_465 6_554 ?
O1 Eu1 O2 133.99(18) 9_666 6_554 ?
O1 Eu1 O2 133.99(18) 15_465 4_456 ?
O1 Eu1 O1 59.8(3) 15_465 9_666 ?
O3 Eu1 K1 140.94(15) . 16_654 ?
O3 Eu1 K1 140.94(15) 7_545 10_557 ?
O3 Eu1 K1 50.52(15) 7_545 16_654 ?
O3 Eu1 K1 50.52(15) . 10_557 ?
O3 Eu1 P6 103.31(15) . 9_666 ?
O3 Eu1 P6 103.31(15) 7_545 9_666 ?
O3 Eu1 P6 76.69(15) 7_545 6_554 ?
O3 Eu1 P6 76.69(15) . 6_554 ?
O3 Eu1 O2 78.5(2) . 6_554 ?
O3 Eu1 O2 78.3(2) . 4_456 ?
O3 Eu1 O2 78.3(2) 7_545 6_554 ?
O3 Eu1 O2 78.5(2) 7_545 4_456 ?
O3 Eu1 O1 132.0(2) . 9_666 ?
O3 Eu1 O1 74.4(2) . 15_465 ?
O3 Eu1 O1 132.0(2) 7_545 15_465 ?
O3 Eu1 O1 74.4(2) 7_545 9_666 ?
O3 Eu1 O3 153.4(3) 7_545 . ?
W1 K1 K1 174.83(7) 13_556 15_565 ?
Eu1 K1 W1 108.00(5) 10_657 13_556 ?
Eu1 K1 K1 72.43(3) 10_657 15_565 ?
P6 K1 W1 72.10(5) 10_557 13_556 ?
P6 K1 Eu1 60.92(4) 10_557 10_657 ?
P6 K1 K1 112.06(5) 10_557 15_565 ?
O2 K1 W1 78.83(11) 16_655 13_556 ?
O2 K1 Eu1 37.21(11) 16_655 10_657 ?
O2 K1 K1 103.51(11) 16_655 15_565 ?
O2 K1 P6 26.63(11) 16_655 10_557 ?
O2 K1 O3 58.68(16) 16_655 13_556 ?
O2 K1 O4 101.64(17) 16_655 10_557 ?
O1 K1 W1 73.69(12) 10_557 13_556 ?
O1 K1 W1 140.26(13) 8_456 13_556 ?
O1 K1 Eu1 39.06(12) 8_456 10_657 ?
O1 K1 Eu1 82.50(12) 10_557 10_657 ?
O1 K1 K1 111.40(13) 10_557 15_565 ?
O1 K1 K1 42.64(12) 8_456 15_565 ?
O1 K1 P6 25.04(12) 10_557 10_557 ?
O1 K1 P6 70.98(12) 8_456 10_557 ?
O1 K1 O2 51.43(15) 10_557 16_655 ?
O1 K1 O2 61.54(16) 8_456 16_655 ?
O1 K1 O1 79.07(14) 10_557 8_456 ?
O1 K1 O3 60.83(16) 8_456 10_657 ?
O1 K1 O3 118.23(17) 8_456 13_556 ?
O1 K1 O3 76.17(16) 10_557 13_556 ?
O1 K1 O3 120.33(18) 10_557 10_657 ?
O1 K1 O4 80.71(18) 8_456 8_456 ?
O1 K1 O4 95.32(18) 10_557 8_456 ?
O1 K1 O4 78.20(17) 10_557 10_557 ?
O1 K1 O4 157.16(18) 8_456 10_557 ?
O3 K1 W1 110.21(14) 10_657 13_556 ?
O3 K1 W1 26.95(11) 13_556 13_556 ?
O3 K1 Eu1 38.44(12) 10_657 10_657 ?
O3 K1 Eu1 81.93(12) 13_556 10_657 ?
O3 K1 K1 66.76(13) 10_657 15_565 ?
O3 K1 K1 151.62(13) 13_556 15_565 ?
O3 K1 P6 62.99(12) 13_556 10_557 ?
O3 K1 P6 96.78(13) 10_657 10_557 ?
O3 K1 O2 70.43(16) 10_657 16_655 ?
O3 K1 O3 85.63(19) 10_657 13_556 ?
O3 K1 O4 117.3(2) 10_657 8_456 ?
O3 K1 O4 131.22(19) 10_657 10_557 ?
O4 K1 W1 90.13(16) . 13_556 ?
O4 K1 W1 129.63(15) 8_456 13_556 ?
O4 K1 W1 26.46(11) 10_557 13_556 ?
O4 K1 Eu1 122.82(17) . 10_657 ?
O4 K1 Eu1 134.18(13) 10_557 10_657 ?
O4 K1 Eu1 119.28(14) 8_456 10_657 ?
O4 K1 K1 52.01(14) 8_456 15_565 ?
O4 K1 K1 85.43(15) . 15_565 ?
O4 K1 K1 153.38(13) 10_557 15_565 ?
O4 K1 P6 116.12(14) 8_456 10_557 ?
O4 K1 P6 87.28(13) 10_557 10_557 ?
O4 K1 P6 161.52(17) . 10_557 ?
O4 K1 O2 146.54(19) . 16_655 ?
O4 K1 O2 131.92(17) 8_456 16_655 ?
O4 K1 O1 153.7(2) . 10_557 ?
O4 K1 O1 124.4(2) . 8_456 ?
O4 K1 O3 53.28(16) 10_557 13_556 ?
O4 K1 O3 84.4(2) . 10_657 ?
O4 K1 O3 156.37(18) 8_456 13_556 ?
O4 K1 O3 98.83(19) . 13_556 ?
O4 K1 O4 103.7(2) 8_456 10_557 ?
O4 K1 O4 78.31(14) . 10_557 ?
O4 K1 O4 78.9(2) . 8_456 ?
Eu1 P6 Eu1 180.0 9_666 6_554 ?
Eu1 P6 K1 88.64(6) 6_554 10_657 ?
Eu1 P6 K1 88.64(6) 6_554 16_654 ?
Eu1 P6 K1 91.36(6) 9_666 10_657 ?
Eu1 P6 K1 91.36(6) 9_666 16_654 ?
K1 P6 K1 177.29(11) 16_654 10_657 ?
O2 P6 Eu1 51.2(2) 7_645 6_554 ?
O2 P6 Eu1 128.8(2) 7_645 9_666 ?
O2 P6 Eu1 128.8(2) . 9_666 ?
O2 P6 Eu1 51.2(2) . 6_554 ?
O2 P6 K1 115.0(2) 7_645 16_654 ?
O2 P6 K1 115.0(2) . 10_657 ?
O2 P6 K1 63.1(2) 7_645 10_657 ?
O2 P6 K1 63.1(2) . 16_654 ?
O2 P6 O2 102.3(4) 7_645 . ?
O1 P6 Eu1 126.8(2) . 6_554 ?
O1 P6 Eu1 53.2(2) 7_645 9_666 ?
O1 P6 Eu1 126.8(2) 7_645 6_554 ?
O1 P6 Eu1 53.2(2) . 9_666 ?
O1 P6 K1 133.1(2) . 16_654 ?
O1 P6 K1 49.1(2) 7_645 16_654 ?
O1 P6 K1 133.1(2) 7_645 10_657 ?
O1 P6 K1 49.1(2) . 10_657 ?
O1 P6 O2 112.7(3) 7_645 7_645 ?
O1 P6 O2 112.7(3) . . ?
O1 P6 O2 111.4(3) 7_645 . ?
O1 P6 O2 111.4(3) . 7_645 ?
O1 P6 O1 106.4(5) 7_645 . ?
Eu1 O2 Eu1 111.3(2) . 6_554 ?
Eu1 O2 K1 111.63(19) 6_554 16_654 ?
Eu1 O2 K1 89.87(18) . 16_654 ?
P6 O2 Eu1 99.8(3) . 6_554 ?
P6 O2 Eu1 146.4(3) . . ?
P6 O2 K1 90.3(2) . 16_654 ?
Eu1 O1 K1 94.85(17) 9_666 8_456 ?
Eu1 O1 K1 128.6(2) 9_666 10_657 ?
K1 O1 K1 93.20(18) 10_657 8_456 ?
P6 O1 Eu1 96.9(3) . 9_666 ?
P6 O1 K1 143.5(3) . 8_456 ?
P6 O1 K1 105.9(3) . 10_657 ?
W1 O3 Eu1 134.0(3) . . ?
W1 O3 K1 126.5(3) . 10_557 ?
W1 O3 K1 98.9(2) . 13_556 ?
Eu1 O3 K1 91.04(19) . 10_557 ?
Eu1 O3 K1 109.9(2) . 13_556 ?
K1 O3 K1 87.00(17) 10_557 13_556 ?
W1 O4 K1 99.9(3) . 10_657 ?
W1 O4 K1 114.7(3) . 8_456 ?
W1 O4 K1 133.4(3) . . ?
K1 O4 K1 80.50(17) 8_456 10_657 ?
K1 O4 K1 95.1(2) . 8_456 ?
K1 O4 K1 120.7(2) . 10_657 ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Eu1 W1 O3 Eu1 -21.8(4) 6_554 . . . ?
Eu1 W1 O3 K1 -138.3(7) . . . 10_557 ?
Eu1 W1 O3 K1 -160.1(3) 6_554 . . 10_557 ?
Eu1 W1 O3 K1 128.9(5) . . . 13_556 ?
Eu1 W1 O3 K1 107.06(15) 6_554 . . 13_556 ?
Eu1 W1 O4 K1 121.6(4) . . . . ?
Eu1 W1 O4 K1 -15.9(3) 6_554 . . 10_657 ?
Eu1 W1 O4 K1 -3.1(3) . . . 8_456 ?
Eu1 W1 O4 K1 68.2(3) 6_554 . . 8_456 ?
Eu1 W1 O4 K1 -87.1(2) . . . 10_657 ?
Eu1 W1 O4 K1 -167.1(3) 6_554 . . . ?
Eu1 P6 O2 Eu1 157.8(7) 6_554 . . . ?
Eu1 P6 O2 Eu1 180.0 9_666 . . 6_554 ?
Eu1 P6 O2 Eu1 -22.2(7) 9_666 . . . ?
Eu1 P6 O2 K1 68.0(2) 9_666 . . 16_654 ?
Eu1 P6 O2 K1 -112.0(2) 6_554 . . 16_654 ?
Eu1 P6 O1 Eu1 180.000(1) 6_554 . . 9_666 ?
Eu1 P6 O1 K1 -133.4(3) 9_666 . . 10_657 ?
Eu1 P6 O1 K1 46.6(3) 6_554 . . 10_657 ?
Eu1 P6 O1 K1 -72.2(6) 6_554 . . 8_456 ?
Eu1 P6 O1 K1 107.8(6) 9_666 . . 8_456 ?
K1 W1 O3 Eu1 -92.1(4) 3_646 . . . ?
K1 W1 O3 Eu1 -156.2(3) 6_554 . . . ?
K1 W1 O3 Eu1 45.4(5) 10_657 . . . ?
K1 W1 O3 Eu1 134.0(4) . . . . ?
K1 W1 O3 Eu1 82.7(4) 8_456 . . . ?
K1 W1 O3 Eu1 -128.9(5) 13_556 . . . ?
K1 W1 O3 K1 129.7(3) 3_646 . . 10_557 ?
K1 W1 O3 K1 92.8(3) 13_556 . . 10_557 ?
K1 W1 O3 K1 -27.3(3) 6_554 . . 13_556 ?
K1 W1 O3 K1 -92.9(3) 10_657 . . 10_557 ?
K1 W1 O3 K1 36.85(18) 3_646 . . 13_556 ?
K1 W1 O3 K1 -148.4(2) 8_456 . . 13_556 ?
K1 W1 O3 K1 -4.2(4) . . . 10_557 ?
K1 W1 O3 K1 -97.09(16) . . . 13_556 ?
K1 W1 O3 K1 174.28(6) 10_657 . . 13_556 ?
K1 W1 O3 K1 65.5(4) 6_554 . . 10_557 ?
K1 W1 O3 K1 -55.5(3) 8_456 . . 10_557 ?
K1 W1 O4 K1 151.3(6) . . . 10_657 ?
K1 W1 O4 K1 -59.6(6) 3_646 . . . ?
K1 W1 O4 K1 34.4(6) 13_556 . . . ?
K1 W1 O4 K1 124.7(6) 8_456 . . . ?
K1 W1 O4 K1 114.64(18) 6_554 . . 10_657 ?
K1 W1 O4 K1 -90.3(3) 13_556 . . 8_456 ?
K1 W1 O4 K1 -84.0(3) 8_456 . . 10_657 ?
K1 W1 O4 K1 -151.3(6) 10_657 . . . ?
K1 W1 O4 K1 -124.7(6) . . . 8_456 ?
K1 W1 O4 K1 -161.3(3) 6_554 . . 8_456 ?
K1 W1 O4 K1 -174.35(6) 13_556 . . 10_657 ?
K1 W1 O4 K1 84.0(3) 10_657 . . 8_456 ?
K1 W1 O4 K1 91.7(3) 3_646 . . 10_657 ?
K1 W1 O4 K1 175.68(7) 3_646 . . 8_456 ?
K1 W1 O4 K1 -36.6(4) 6_554 . . . ?
K1 P6 O2 Eu1 91.9(6) 10_657 . . . ?
K1 P6 O2 Eu1 112.0(2) 16_654 . . 6_554 ?
K1 P6 O2 Eu1 -90.2(6) 16_654 . . . ?
K1 P6 O2 Eu1 -65.8(2) 10_657 . . 6_554 ?
K1 P6 O2 K1 -177.84(9) 10_657 . . 16_654 ?
K1 P6 O1 Eu1 -48.8(3) 16_654 . . 9_666 ?
K1 P6 O1 Eu1 133.4(3) 10_657 . . 9_666 ?
K1 P6 O1 K1 -118.8(6) 10_657 . . 8_456 ?
K1 P6 O1 K1 59.0(6) 16_654 . . 8_456 ?
K1 P6 O1 K1 177.84(10) 16_654 . . 10_657 ?
O2 P6 O2 Eu1 157.8(7) 7_645 . . . ?
O2 P6 O2 Eu1 -0.001(0) 7_645 . . 6_554 ?
O2 P6 O2 K1 -112.0(2) 7_645 . . 16_654 ?
O2 P6 O1 Eu1 123.2(3) 7_645 . . 9_666 ?
O2 P6 O1 Eu1 -122.4(3) . . . 9_666 ?
O2 P6 O1 K1 104.2(3) . . . 10_657 ?
O2 P6 O1 K1 -10.2(3) 7_645 . . 10_657 ?
O2 P6 O1 K1 -129.0(5) 7_645 . . 8_456 ?
O2 P6 O1 K1 -14.6(6) . . . 8_456 ?
O1 P6 O2 Eu1 -81.6(6) 7_645 . . . ?
O1 P6 O2 Eu1 -119.8(3) . . . 6_554 ?
O1 P6 O2 Eu1 38.0(7) . . . . ?
O1 P6 O2 Eu1 120.6(3) 7_645 . . 6_554 ?
O1 P6 O2 K1 128.2(3) . . . 16_654 ?
O1 P6 O2 K1 8.6(3) 7_645 . . 16_654 ?
O1 P6 O1 Eu1 0.001(1) 7_645 . . 9_666 ?
O1 P6 O1 K1 107.8(6) 7_645 . . 8_456 ?
O1 P6 O1 K1 -133.4(3) 7_645 . . 10_657 ?
O3 W1 O3 Eu1 -15.1(3) 6_554 . . . ?
O3 W1 O3 K1 113.8(2) 6_554 . . 13_556 ?
O3 W1 O3 K1 -153.4(4) 6_554 . . 10_557 ?
O3 W1 O4 K1 90.6(3) 6_554 . . 8_456 ?
O3 W1 O4 K1 93.4(5) . . . . ?
O3 W1 O4 K1 -31.3(4) . . . 8_456 ?
O3 W1 O4 K1 6.6(3) 6_554 . . 10_657 ?
O3 W1 O4 K1 -115.3(3) . . . 10_657 ?
O3 W1 O4 K1 -144.7(4) 6_554 . . . ?
O4 W1 O3 Eu1 104.0(4) . . . . ?
O4 W1 O3 Eu1 -135.5(4) 6_554 . . . ?
O4 W1 O3 K1 86.3(4) 6_554 . . 10_557 ?
O4 W1 O3 K1 -6.6(3) 6_554 . . 13_556 ?
O4 W1 O3 K1 -34.2(4) . . . 10_557 ?
O4 W1 O3 K1 -127.1(3) . . . 13_556 ?
O4 W1 O4 K1 -25.0(3) 6_554 . . . ?
O4 W1 O4 K1 126.3(3) 6_554 . . 10_657 ?
O4 W1 O4 K1 -149.7(4) 6_554 . . 8_456 ?


_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 7.779
_oxdiff_exptl_absorpt_empirical_full_min 0.545
