# Electronic Supplementary Material (ESI) for RSC Advances.
# This journal is © The Royal Society of Chemistry 2022

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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data_mo_ag202_a_1_3_0m
_database_code_depnum_ccdc_archive 'CCDC 2195992'
loop_
_audit_author_name
_audit_author_address
'Guenther Thiele'
;FU Berlin
Germany
;
_audit_update_record             
;
2022-08-10 deposited with the CCDC.	2022-10-14 downloaded from the CCDC.
;
_audit_creation_date             2022-08-08
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6272)
;
_shelx_SHELXL_version_number     2017/1
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'Fe4 K6 S8'
_chemical_formula_sum            'Fe4 K6 S8'
_chemical_formula_weight         714.48
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Fe Fe 0.3463 0.8444 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
K K 0.2009 0.2494 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           62
_space_group_name_H-M_alt        'P n m a'
_space_group_name_Hall           '-P 2ac 2n'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z'
'x+1/2, -y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z'
'-x-1/2, y-1/2, z-1/2'

_cell_length_a                   7.1219(4)
_cell_length_b                   10.9301(6)
_cell_length_c                   11.4840(7)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     893.95(9)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    4889
_cell_measurement_temperature    100
_cell_measurement_theta_max      30.35
_cell_measurement_theta_min      3.37
_shelx_estimated_absorpt_T_max   0.627
_shelx_estimated_absorpt_T_min   0.489
_exptl_absorpt_coefficient_mu    5.485
_exptl_absorpt_correction_T_max  0.7461
_exptl_absorpt_correction_T_min  0.5885
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.0857 before and 0.0607 after correction.
The Ratio of minimum to maximum transmission is 0.7888.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'metallic dark green'
_exptl_crystal_colour_lustre     metallic
_exptl_crystal_colour_modifier   dark
_exptl_crystal_colour_primary    green
_exptl_crystal_density_diffrn    2.654
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             692
_exptl_crystal_size_max          0.152
_exptl_crystal_size_mid          0.097
_exptl_crystal_size_min          0.094
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0896
_diffrn_reflns_av_unetI/netI     0.0371
_diffrn_reflns_Laue_measured_fraction_full 0.993
_diffrn_reflns_Laue_measured_fraction_max 0.987
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            19979
_diffrn_reflns_point_group_measured_fraction_full 0.993
_diffrn_reflns_point_group_measured_fraction_max 0.987
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         30.825
_diffrn_reflns_theta_min         2.573
_diffrn_ambient_temperature      100
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.987
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           1.0
_diffrn_source_power             0.05
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                1228
_reflns_number_total             1450
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.38A (Bruker, 2018)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.38A (Bruker, 2018)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL  (Sheldrick, 2008)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_refine_diff_density_max         0.866
_refine_diff_density_min         -0.938
_refine_diff_density_rms         0.195
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.141
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     46
_refine_ls_number_reflns         1450
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0555
_refine_ls_R_factor_gt           0.0428
_refine_ls_restrained_S_all      1.141
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+6.5705P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0691
_refine_ls_wR_factor_ref         0.0724
_refine_special_details          ?
_olex2_refinement_description    
;
;
_atom_sites_solution_hydrogens   .
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Fe1 Fe 0.44846(7) 0.62301(5) 0.53179(5) 0.00591(12) Uani 1 1 d . . . . .
K3 K -0.08255(16) 0.750000 0.26902(10) 0.0077(2) Uani 1 2 d S T P . .
K5 K 0.93785(11) 0.92474(7) 0.63828(7) 0.01007(16) Uani 1 1 d . . . . .
S4 S 0.59570(18) 0.750000 0.65972(12) 0.0072(2) Uani 1 2 d S T P . .
S2 S 0.21031(17) 0.750000 0.46726(12) 0.0072(2) Uani 1 2 d S T P . .
S6 S 0.34447(13) 0.44420(8) 0.61295(8) 0.00725(17) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Fe1 Fe1 2.7760(10) 7_575 ?
Fe1 Fe1 2.8814(10) 5_666 ?
Fe1 K3 3.7294(12) 6_656 ?
Fe1 K5 3.8254(10) 4_466 ?
Fe1 K5 3.7305(10) 7_575 ?
Fe1 K5 3.8720(10) 7_475 ?
Fe1 S4 2.2770(12) . ?
Fe1 S2 2.3135(11) . ?
Fe1 S6 2.2884(10) . ?
Fe1 S6 2.3404(11) 5_666 ?
K3 K3 3.5876(3) 6_656 ?
K3 K3 3.5876(3) 6_556 ?
K3 K5 3.8514(9) 5_676 ?
K3 K5 3.8514(9) 3_646 ?
K3 S2 3.0886(18) 6_556 ?
K3 S2 3.0876(17) . ?
K3 S6 3.1341(12) 5_566 ?
K3 S6 3.2547(13) 2_564 ?
K3 S6 3.1341(12) 3_556 ?
K3 S6 3.2547(13) 8_665 ?
K5 K5 3.8199(16) 7_575 ?
K5 K5 3.6848(16) 5_776 ?
K5 S4 3.2082(14) 6_657 ?
K5 S4 3.1059(13) . ?
K5 S2 3.3571(14) 1_655 ?
K5 S6 3.2439(12) 7_675 ?
K5 S6 3.5231(13) 3_656 ?
K5 S6 3.2643(13) 4_566 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Fe1 Fe1 Fe1 158.94(2) 7_575 5_666 ?
Fe1 Fe1 K3 68.151(10) 7_575 6_656 ?
Fe1 Fe1 K3 97.34(3) 5_666 6_656 ?
Fe1 Fe1 K5 98.043(15) 7_575 7_575 ?
Fe1 Fe1 K5 73.41(2) 5_666 7_575 ?
Fe1 Fe1 K5 97.39(3) 5_666 4_466 ?
Fe1 Fe1 K5 97.842(14) 7_575 4_466 ?
Fe1 Fe1 K5 97.748(14) 7_575 7_475 ?
Fe1 Fe1 K5 101.16(3) 5_666 7_475 ?
K3 Fe1 K5 165.25(2) 6_656 4_466 ?
K3 Fe1 K5 106.69(2) 6_656 7_475 ?
K3 Fe1 K5 114.27(3) 6_656 7_575 ?
K5 Fe1 K5 71.013(17) 7_575 4_466 ?
K5 Fe1 K5 69.526(17) 4_466 7_475 ?
K5 Fe1 K5 139.03(3) 7_575 7_475 ?
S4 Fe1 Fe1 52.44(2) . 7_575 ?
S4 Fe1 Fe1 127.96(4) . 5_666 ?
S4 Fe1 K3 113.46(3) . 6_656 ?
S4 Fe1 K5 56.18(3) . 7_575 ?
S4 Fe1 K5 108.11(4) . 7_475 ?
S4 Fe1 K5 56.85(3) . 4_466 ?
S4 Fe1 S2 100.29(4) . . ?
S4 Fe1 S6 114.01(4) . . ?
S4 Fe1 S6 111.06(5) . 5_666 ?
S2 Fe1 Fe1 53.13(2) . 7_575 ?
S2 Fe1 Fe1 131.72(4) . 5_666 ?
S2 Fe1 K3 55.71(4) . 6_656 ?
S2 Fe1 K5 112.62(4) . 4_466 ?
S2 Fe1 K5 150.92(3) . 7_575 ?
S2 Fe1 K5 59.57(3) . 7_475 ?
S2 Fe1 S6 115.01(5) . 5_666 ?
S6 Fe1 Fe1 108.29(3) 5_666 7_575 ?
S6 Fe1 Fe1 52.31(3) . 5_666 ?
S6 Fe1 Fe1 50.70(3) 5_666 5_666 ?
S6 Fe1 Fe1 148.65(3) . 7_575 ?
S6 Fe1 K3 132.53(3) . 6_656 ?
S6 Fe1 K3 59.75(3) 5_666 6_656 ?
S6 Fe1 K5 56.79(3) . 7_475 ?
S6 Fe1 K5 92.83(3) . 7_575 ?
S6 Fe1 K5 140.70(3) 5_666 7_475 ?
S6 Fe1 K5 132.30(3) 5_666 4_466 ?
S6 Fe1 K5 66.43(3) 5_666 7_575 ?
S6 Fe1 K5 58.24(3) . 4_466 ?
S6 Fe1 S2 113.93(4) . . ?
S6 Fe1 S6 103.01(3) . 5_666 ?
Fe1 K3 Fe1 43.70(2) 6_556 4_465 ?
Fe1 K3 K5 125.71(3) 4_465 3_646 ?
Fe1 K3 K5 84.067(18) 6_556 3_646 ?
Fe1 K3 K5 84.067(18) 4_465 5_676 ?
Fe1 K3 K5 125.71(3) 6_556 5_676 ?
K3 K3 Fe1 86.90(4) 6_556 4_465 ?
K3 K3 Fe1 80.12(4) 6_656 4_465 ?
K3 K3 Fe1 80.12(4) 6_656 6_556 ?
K3 K3 Fe1 86.90(4) 6_556 6_556 ?
K3 K3 K3 166.01(7) 6_556 6_656 ?
K3 K3 K5 76.59(2) 6_656 5_676 ?
K3 K3 K5 107.41(2) 6_556 5_676 ?
K3 K3 K5 107.41(2) 6_556 3_646 ?
K3 K3 K5 76.59(2) 6_656 3_646 ?
K5 K3 K5 134.75(4) 5_676 3_646 ?
S2 K3 Fe1 130.01(4) . 6_556 ?
S2 K3 Fe1 38.23(2) 6_556 6_556 ?
S2 K3 Fe1 38.23(2) 6_556 4_465 ?
S2 K3 Fe1 130.01(4) . 4_465 ?
S2 K3 K3 139.49(6) . 6_556 ?
S2 K3 K3 54.48(4) 6_556 6_556 ?
S2 K3 K3 111.54(6) 6_556 6_656 ?
S2 K3 K3 54.50(4) . 6_656 ?
S2 K3 K5 67.38(2) . 5_676 ?
S2 K3 K5 111.75(2) 6_556 5_676 ?
S2 K3 K5 67.38(2) . 3_646 ?
S2 K3 K5 111.75(2) 6_556 3_646 ?
S2 K3 S2 166.04(6) . 6_556 ?
S2 K3 S6 94.77(4) . 5_566 ?
S2 K3 S6 94.77(4) . 3_556 ?
S2 K3 S6 95.49(4) 6_556 5_566 ?
S2 K3 S6 93.10(4) . 2_564 ?
S2 K3 S6 95.49(4) 6_556 3_556 ?
S2 K3 S6 76.41(3) 6_556 2_564 ?
S2 K3 S6 93.10(4) . 8_665 ?
S2 K3 S6 76.41(3) 6_556 8_665 ?
S6 K3 Fe1 100.59(3) 3_556 4_465 ?
S6 K3 Fe1 72.65(3) 8_665 6_556 ?
S6 K3 Fe1 133.47(4) 5_566 4_465 ?
S6 K3 Fe1 100.59(3) 5_566 6_556 ?
S6 K3 Fe1 38.40(2) 8_665 4_465 ?
S6 K3 Fe1 38.40(2) 2_564 6_556 ?
S6 K3 Fe1 72.65(3) 2_564 4_465 ?
S6 K3 Fe1 133.47(4) 3_556 6_556 ?
S6 K3 K3 57.45(3) 5_566 6_556 ?
S6 K3 K3 130.05(3) 3_556 6_656 ?
S6 K3 K3 54.26(3) 8_665 6_656 ?
S6 K3 K3 130.05(3) 5_566 6_656 ?
S6 K3 K3 116.75(4) 2_564 6_556 ?
S6 K3 K3 54.26(3) 2_564 6_656 ?
S6 K3 K3 57.45(3) 3_556 6_556 ?
S6 K3 K3 116.75(4) 8_665 6_556 ?
S6 K3 K5 54.17(2) 5_566 3_646 ?
S6 K3 K5 127.94(4) 8_665 3_646 ?
S6 K3 K5 131.67(4) 3_556 3_646 ?
S6 K3 K5 54.17(2) 3_556 5_676 ?
S6 K3 K5 131.67(4) 5_566 5_676 ?
S6 K3 K5 53.90(2) 8_665 5_676 ?
S6 K3 K5 127.94(4) 2_564 5_676 ?
S6 K3 K5 53.90(2) 2_564 3_646 ?
S6 K3 S6 96.11(3) 5_566 2_564 ?
S6 K3 S6 96.11(3) 3_556 8_665 ?
S6 K3 S6 171.87(4) 3_556 2_564 ?
S6 K3 S6 81.41(4) 2_564 8_665 ?
S6 K3 S6 171.87(4) 5_566 8_665 ?
S6 K3 S6 85.26(4) 5_566 3_556 ?
Fe1 K5 Fe1 106.01(2) 4_566 7_675 ?
Fe1 K5 Fe1 139.03(3) 7_575 7_675 ?
Fe1 K5 Fe1 108.91(2) 7_575 4_566 ?
Fe1 K5 K3 81.19(2) 4_566 5_676 ?
Fe1 K5 K3 118.02(3) 7_575 5_676 ?
Fe1 K5 K5 81.958(15) 7_575 7_575 ?
K3 K5 Fe1 87.73(2) 5_676 7_675 ?
K5 K5 Fe1 64.04(2) 5_776 7_675 ?
K5 K5 Fe1 82.253(14) 7_575 7_675 ?
K5 K5 Fe1 155.49(4) 5_776 4_566 ?
K5 K5 Fe1 82.158(14) 7_575 4_566 ?
K5 K5 Fe1 90.25(3) 5_776 7_575 ?
K5 K5 K3 76.22(3) 5_776 5_676 ?
K5 K5 K3 157.38(2) 7_575 5_676 ?
K5 K5 K5 116.52(3) 5_776 7_575 ?
S4 K5 Fe1 118.76(3) 6_657 7_575 ?
S4 K5 Fe1 79.57(3) 6_657 7_675 ?
S4 K5 Fe1 81.55(3) . 4_566 ?
S4 K5 Fe1 37.52(2) . 7_575 ?
S4 K5 Fe1 132.77(3) . 7_675 ?
S4 K5 Fe1 36.46(2) 6_657 4_566 ?
S4 K5 K3 104.83(3) 6_657 5_676 ?
S4 K5 K3 139.08(4) . 5_676 ?
S4 K5 K5 143.60(5) 6_657 5_776 ?
S4 K5 K5 53.46(2) 6_657 7_575 ?
S4 K5 K5 52.05(2) . 7_575 ?
S4 K5 K5 122.10(4) . 5_776 ?
S4 K5 S4 81.46(3) . 6_657 ?
S4 K5 S2 83.21(3) 6_657 1_655 ?
S4 K5 S2 98.63(3) . 1_655 ?
S4 K5 S6 92.33(3) . 4_566 ?
S4 K5 S6 90.85(3) 6_657 7_675 ?
S4 K5 S6 69.77(3) . 3_656 ?
S4 K5 S6 145.90(3) 6_657 3_656 ?
S4 K5 S6 168.26(4) . 7_675 ?
S4 K5 S6 72.53(3) 6_657 4_566 ?
S2 K5 Fe1 119.37(3) 1_655 4_566 ?
S2 K5 Fe1 36.46(2) 1_655 7_675 ?
S2 K5 Fe1 105.58(3) 1_655 7_575 ?
S2 K5 K3 122.15(3) 1_655 5_676 ?
S2 K5 K5 55.325(19) 1_655 7_575 ?
S2 K5 K5 67.10(3) 1_655 5_776 ?
S2 K5 S6 83.40(3) 1_655 3_656 ?
S6 K5 Fe1 99.09(3) 4_566 7_575 ?
S6 K5 Fe1 150.05(3) 7_675 7_575 ?
S6 K5 Fe1 37.509(19) 3_656 7_575 ?
S6 K5 Fe1 146.16(3) 3_656 4_566 ?
S6 K5 Fe1 97.55(3) 7_675 4_566 ?
S6 K5 Fe1 36.17(2) 7_675 7_675 ?
S6 K5 Fe1 121.80(3) 4_566 7_675 ?
S6 K5 Fe1 106.59(3) 3_656 7_675 ?
S6 K5 Fe1 36.59(2) 4_566 4_566 ?
S6 K5 K3 51.56(3) 7_675 5_676 ?
S6 K5 K3 53.67(3) 4_566 5_676 ?
S6 K5 K3 108.86(3) 3_656 5_676 ?
S6 K5 K5 53.44(3) 3_656 5_776 ?
S6 K5 K5 116.03(2) 4_566 7_575 ?
S6 K5 K5 93.46(2) 3_656 7_575 ?
S6 K5 K5 116.21(2) 7_675 7_575 ?
S6 K5 K5 60.73(3) 7_675 5_776 ?
S6 K5 K5 127.40(4) 4_566 5_776 ?
S6 K5 S2 151.57(4) 4_566 1_655 ?
S6 K5 S2 71.50(3) 7_675 1_655 ?
S6 K5 S6 125.02(3) 4_566 3_656 ?
S6 K5 S6 93.82(3) 7_675 4_566 ?
S6 K5 S6 114.17(3) 7_675 3_656 ?
Fe1 S4 Fe1 75.12(5) 7_575 . ?
Fe1 S4 K5 86.29(3) . 7_575 ?
Fe1 S4 K5 86.69(3) . 4_466 ?
Fe1 S4 K5 131.92(5) . 6_557 ?
Fe1 S4 K5 86.29(3) 7_575 . ?
Fe1 S4 K5 133.24(6) 7_575 7_575 ?
Fe1 S4 K5 133.24(6) . . ?
Fe1 S4 K5 86.69(3) 7_575 6_557 ?
Fe1 S4 K5 131.92(5) 7_575 4_466 ?
K5 S4 K5 134.29(5) 7_575 6_557 ?
K5 S4 K5 134.29(5) . 4_466 ?
K5 S4 K5 75.90(4) . 7_575 ?
K5 S4 K5 88.06(3) . 6_557 ?
K5 S4 K5 73.07(4) 6_557 4_466 ?
K5 S4 K5 88.06(3) 7_575 4_466 ?
Fe1 S2 Fe1 73.73(5) . 7_575 ?
Fe1 S2 K3 86.06(4) . 6_656 ?
Fe1 S2 K3 137.00(4) 7_575 . ?
Fe1 S2 K3 137.00(4) . . ?
Fe1 S2 K3 86.06(4) 7_575 6_656 ?
Fe1 S2 K5 83.97(3) . 7_475 ?
Fe1 S2 K5 125.29(5) . 1_455 ?
Fe1 S2 K5 83.97(3) 7_575 1_455 ?
Fe1 S2 K5 125.29(5) 7_575 7_475 ?
K3 S2 K3 71.03(3) . 6_656 ?
K3 S2 K5 142.19(3) 6_656 1_455 ?
K3 S2 K5 92.34(4) . 7_475 ?
K3 S2 K5 142.19(3) 6_656 7_475 ?
K3 S2 K5 92.34(4) . 1_455 ?
K5 S2 K5 69.35(4) 7_475 1_455 ?
Fe1 S6 Fe1 76.99(3) . 5_666 ?
Fe1 S6 K3 81.84(3) 5_666 2_565 ?
Fe1 S6 K3 161.30(4) . 5_566 ?
Fe1 S6 K3 127.78(4) . 2_565 ?
Fe1 S6 K3 118.01(4) 5_666 5_566 ?
Fe1 S6 K5 87.04(3) . 7_475 ?
Fe1 S6 K5 85.17(3) . 4_466 ?
Fe1 S6 K5 139.89(4) 5_666 7_475 ?
Fe1 S6 K5 129.12(4) 5_666 4_466 ?
Fe1 S6 K5 84.42(3) . 3_646 ?
Fe1 S6 K5 76.06(3) 5_666 3_646 ?
K3 S6 K3 68.296(19) 5_566 2_565 ?
K3 S6 K5 74.27(3) 5_566 7_475 ?
K3 S6 K5 88.49(3) 5_566 3_646 ?
K3 S6 K5 92.29(3) 5_566 4_466 ?
K3 S6 K5 135.15(3) 2_565 3_646 ?
K3 S6 K5 72.43(3) 2_565 4_466 ?
K5 S6 K3 134.72(4) 7_475 2_565 ?
K5 S6 K5 149.26(3) 4_466 3_646 ?
K5 S6 K5 84.81(3) 7_475 4_466 ?
K5 S6 K5 65.83(3) 7_475 3_646 ?

_olex2_submission_special_instructions 'No special instructions were received'
_chemical_properties_physical    Air-sensitive,Moisture-sensitive
_exptl_crystal_preparation       'Magnetic properties,dielectric, impedance'
