# Electronic Supplementary Material (ESI) for Chemical Science.
# This journal is © The Royal Society of Chemistry 2022

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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data_cu_1030_4_0m
_database_code_depnum_ccdc_archive 'CCDC 2070932'
loop_
_audit_author_name
_audit_author_address
'Bing Sun'
;Lanzhou University
China
;
_audit_update_record             
;
2021-03-17 deposited with the CCDC.	2022-08-12 downloaded from the CCDC.
;
_audit_creation_date             2019-10-30
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C44 H46 N2 O2'
_chemical_formula_sum            'C44 H46 N2 O2'
_chemical_formula_weight         634.83
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   17.3779(9)
_cell_length_b                   5.2454(3)
_cell_length_c                   19.4069(10)
_cell_angle_alpha                90
_cell_angle_beta                 108.694(3)
_cell_angle_gamma                90
_cell_volume                     1675.69(16)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    3992
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      74.602
_cell_measurement_theta_min      4.811
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    0.590
_exptl_absorpt_correction_T_max  0.0872
_exptl_absorpt_correction_T_min  0.0100
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
'SADABS-2016/2 (Bruker,2016/2) was used for absorption correction. wR2(int) was 0.1653 before and 0.0694 after correction. The Ratio of minimum to maximum transmission is 0.1147. The λ/2 correction factor is Not present.'
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.258
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             680
_exptl_crystal_size_max          ?
_exptl_crystal_size_mid          ?
_exptl_crystal_size_min          ?
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0509
_diffrn_reflns_av_unetI/netI     0.0388
_diffrn_reflns_Laue_measured_fraction_full 0.977
_diffrn_reflns_Laue_measured_fraction_max 0.979
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_k_min       -6
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            16415
_diffrn_reflns_point_group_measured_fraction_full 0.977
_diffrn_reflns_point_group_measured_fraction_max 0.979
_diffrn_reflns_theta_full        67.679
_diffrn_reflns_theta_max         72.122
_diffrn_reflns_theta_min         4.811
_diffrn_ambient_temperature      150.0
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.977
_diffrn_measured_fraction_theta_max 0.979
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_source                   ?
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                2159
_reflns_number_total             3233
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT v8.37A (Bruker, 2015)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT v8.37A (Bruker, 2015)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         0.303
_refine_diff_density_min         -0.194
_refine_diff_density_rms         0.064
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.050
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     285
_refine_ls_number_reflns         3233
_refine_ls_number_restraints     90
_refine_ls_R_factor_all          0.1080
_refine_ls_R_factor_gt           0.0837
_refine_ls_restrained_S_all      1.044
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1356P)²+0.3743P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2201
_refine_ls_wR_factor_ref         0.2462
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups, All C(H,H,H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Uiso/Uaniso restraints and constraints
Uanis(C22) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
3. Rigid body (RIGU) restrains
 C20, C15, C17, C16, C19, C18, C22, C21, C18A, C17A, C19A, C20A, C16A, C21A,
 C22A
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
4. Others
 Sof(H15C)=Sof(H15D)=Sof(C18A)=Sof(H18C)=Sof(H18D)=Sof(C17A)=Sof(H17C)=
 Sof(H17D)=Sof(C19A)=Sof(H19C)=Sof(H19D)=Sof(C20A)=Sof(H20D)=Sof(H20E)=
 Sof(H20F)=Sof(C16A)=Sof(H16A)=Sof(C21A)=Sof(H21C)=Sof(H21D)=Sof(C22A)=
 Sof(H22D)=Sof(H22E)=Sof(H22F)=1-FVAR(1)
 Sof(C20)=Sof(H20A)=Sof(H20B)=Sof(H20C)=Sof(H15A)=Sof(H15B)=Sof(C17)=Sof(H17A)=
 Sof(H17B)=Sof(C16)=Sof(H16)=Sof(C19)=Sof(H19A)=Sof(H19B)=Sof(C18)=Sof(H18A)=
 Sof(H18B)=Sof(C22)=Sof(H22A)=Sof(H22B)=Sof(H22C)=Sof(C21)=Sof(H21A)=Sof(H21B)=
 FVAR(1)
5.a Ternary CH refined with riding coordinates:
 C16(H16), C16A(H16A)
5.b Secondary CH2 refined with riding coordinates:
 C15(H15A,H15B), C15(H15C,H15D), C17(H17A,H17B), C19(H19A,H19B), C18(H18A,
 H18B), C21(H21A,H21B), C18A(H18C,H18D), C17A(H17C,H17D), C19A(H19C,H19D),
 C21A(H21C,H21D)
5.c Aromatic/amide H refined with riding coordinates:
 C11(H11), C10(H10), C14(H14), C8(H8), C9(H9), C13(H13)
5.d Idealised Me refined as rotating group:
 C20(H20A,H20B,H20C), C22(H22A,H22B,H22C), C20A(H20D,H20E,H20F), C22A(H22D,
 H22E,H22F)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
O1 O 0.71848(12) 0.2226(4) 0.58036(10) 0.0727(6) Uani 1 1 d . . . . .
N1 N 0.49541(13) 0.8341(4) 0.37603(10) 0.0583(5) Uani 1 1 d . . . . .
C20 C 0.8676(6) -0.159(2) 0.9187(4) 0.135(3) Uani 0.671(8) 1 d . U P A 1
H20A H 0.857284 -0.339028 0.905587 0.202 Uiso 0.671(8) 1 calc GR . P A 1
H20B H 0.842980 -0.114706 0.956040 0.202 Uiso 0.671(8) 1 calc GR . P A 1
H20C H 0.926364 -0.129265 0.937755 0.202 Uiso 0.671(8) 1 calc GR . P A 1
C12 C 0.52847(15) 0.9256(5) 0.52590(12) 0.0564(6) Uani 1 1 d . . . . .
C7 C 0.64880(15) 0.3326(5) 0.45515(13) 0.0604(6) Uani 1 1 d . . . . .
C1 C 0.66545(15) 0.3815(5) 0.53117(13) 0.0610(6) Uani 1 1 d . . . . .
C5 C 0.45730(15) 1.0203(5) 0.39840(12) 0.0571(6) Uani 1 1 d . . . . .
C11 C 0.57663(16) 0.4337(5) 0.32817(13) 0.0609(6) Uani 1 1 d . . . . .
H11 H 0.539203 0.536577 0.292611 0.073 Uiso 1 1 calc R . . . .
C6 C 0.59181(15) 0.4877(5) 0.40254(13) 0.0586(6) Uani 1 1 d . . . . .
C10 C 0.61448(16) 0.2374(6) 0.30625(14) 0.0641(7) Uani 1 1 d . . . . .
H10 H 0.603690 0.205624 0.255833 0.077 Uiso 1 1 calc R . . . .
C14 C 0.60054(15) 0.8186(5) 0.65301(13) 0.0606(6) Uani 1 1 d . . . . .
H14 H 0.611413 0.847316 0.703573 0.073 Uiso 1 1 calc R . . . .
C3 C 0.56891(14) 0.7292(5) 0.50261(12) 0.0564(6) Uani 1 1 d . . . . .
C2 C 0.62669(15) 0.5743(5) 0.55528(13) 0.0578(6) Uani 1 1 d . . . . .
C4 C 0.55036(15) 0.6891(5) 0.42680(12) 0.0575(6) Uani 1 1 d . . . . .
C8 C 0.68644(17) 0.1290(5) 0.43056(14) 0.0658(7) Uani 1 1 d . . . . .
H8 H 0.724158 0.023501 0.465036 0.079 Uiso 1 1 calc R . . . .
C9 C 0.66949(17) 0.0815(5) 0.35804(15) 0.0663(7) Uani 1 1 d . . . . .
H9 H 0.694956 -0.057347 0.342514 0.080 Uiso 1 1 calc R . . . .
C13 C 0.63949(15) 0.6292(5) 0.63143(13) 0.0597(6) Uani 1 1 d . . . . .
H13 H 0.676809 0.527267 0.667351 0.072 Uiso 1 1 calc R . . . .
C15 C 0.8006(2) 0.3052(9) 0.6043(2) 0.0999(12) Uani 1 1 d . U . . .
H15A H 0.805988 0.471962 0.629298 0.120 Uiso 0.671(8) 1 calc R . P A 1
H15B H 0.821879 0.320654 0.562873 0.120 Uiso 0.671(8) 1 calc R . P A 1
H15C H 0.799956 0.474423 0.626697 0.120 Uiso 0.329(8) 1 calc R . P A 2
H15D H 0.814434 0.336986 0.559373 0.120 Uiso 0.329(8) 1 calc R . P A 2
C17 C 0.8256(4) 0.1385(12) 0.7285(4) 0.0829(16) Uani 0.671(8) 1 d . U P A 1
H17A H 0.845728 0.309569 0.747328 0.100 Uiso 0.671(8) 1 calc R . P A 1
H17B H 0.765696 0.141759 0.715994 0.100 Uiso 0.671(8) 1 calc R . P A 1
C16 C 0.8457(5) 0.0967(18) 0.6570(4) 0.089(2) Uani 0.671(8) 1 d . U P A 1
H16 H 0.823716 -0.072800 0.636220 0.107 Uiso 0.671(8) 1 calc R . P A 1
C19 C 0.8329(7) -0.003(2) 0.8555(6) 0.109(3) Uani 0.671(8) 1 d . U P A 1
H19A H 0.845425 0.176794 0.869982 0.131 Uiso 0.671(8) 1 calc R . P A 1
H19B H 0.773128 -0.022550 0.840622 0.131 Uiso 0.671(8) 1 calc R . P A 1
C18 C 0.8585(5) -0.052(2) 0.7901(4) 0.106(2) Uani 0.671(8) 1 d . U P A 1
H18A H 0.840384 -0.224734 0.771451 0.127 Uiso 0.671(8) 1 calc R . P A 1
H18B H 0.918571 -0.049210 0.805148 0.127 Uiso 0.671(8) 1 calc R . P A 1
C22 C 0.9505(11) 0.001(4) 0.5976(10) 0.182(7) Uani 0.671(8) 1 d . U P A 1
H22A H 0.923633 -0.165002 0.584403 0.273 Uiso 0.671(8) 1 calc GR . P A 1
H22B H 1.009117 -0.019765 0.607678 0.273 Uiso 0.671(8) 1 calc GR . P A 1
H22C H 0.929085 0.120428 0.557212 0.273 Uiso 0.671(8) 1 calc GR . P A 1
C21 C 0.9340(4) 0.1047(17) 0.6661(4) 0.121(2) Uani 0.671(8) 1 d . U P A 1
H21A H 0.964167 0.001219 0.708923 0.145 Uiso 0.671(8) 1 calc R . P A 1
H21B H 0.953718 0.282608 0.675017 0.145 Uiso 0.671(8) 1 calc R . P A 1
C18A C 0.8559(12) 0.107(4) 0.7729(11) 0.110(4) Uani 0.329(8) 1 d . U P A 2
H18C H 0.821659 0.261519 0.765830 0.132 Uiso 0.329(8) 1 calc R . P A 2
H18D H 0.913118 0.160158 0.795573 0.132 Uiso 0.329(8) 1 calc R . P A 2
C17A C 0.8468(8) -0.007(3) 0.7010(8) 0.101(4) Uani 0.329(8) 1 d . U P A 2
H17C H 0.789769 -0.060956 0.678023 0.121 Uiso 0.329(8) 1 calc R . P A 2
H17D H 0.881710 -0.159849 0.707564 0.121 Uiso 0.329(8) 1 calc R . P A 2
C19A C 0.8316(19) -0.080(6) 0.8276(14) 0.131(8) Uani 0.329(8) 1 d . U P A 2
H19C H 0.771904 -0.102368 0.812999 0.157 Uiso 0.329(8) 1 calc R . P A 2
H19D H 0.857175 -0.249796 0.829000 0.157 Uiso 0.329(8) 1 calc R . P A 2
C20A C 0.8642(16) 0.054(5) 0.9027(12) 0.163(10) Uani 0.329(8) 1 d . U P A 2
H20D H 0.922032 0.014519 0.925012 0.245 Uiso 0.329(8) 1 calc GR . P A 2
H20E H 0.834067 -0.006815 0.934402 0.245 Uiso 0.329(8) 1 calc GR . P A 2
H20F H 0.857170 0.238585 0.896127 0.245 Uiso 0.329(8) 1 calc GR . P A 2
C16A C 0.8694(11) 0.176(4) 0.6522(12) 0.104(5) Uani 0.329(8) 1 d . U P A 2
H16A H 0.915638 0.290866 0.677767 0.125 Uiso 0.329(8) 1 calc R . P A 2
C21A C 0.8878(10) -0.014(3) 0.5904(10) 0.124(5) Uani 0.329(8) 1 d . U P A 2
H21C H 0.844805 -0.145840 0.576945 0.149 Uiso 0.329(8) 1 calc R . P A 2
H21D H 0.881869 0.089389 0.546307 0.149 Uiso 0.329(8) 1 calc R . P A 2
C22A C 0.9609(16) -0.135(7) 0.6081(16) 0.152(10) Uani 0.329(8) 1 d . U P A 2
H22D H 1.003608 -0.011570 0.609355 0.228 Uiso 0.329(8) 1 calc GR . P A 2
H22E H 0.959057 -0.266528 0.571604 0.228 Uiso 0.329(8) 1 calc GR . P A 2
H22F H 0.972734 -0.215372 0.655992 0.228 Uiso 0.329(8) 1 calc GR . P A 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
O1 C1 1.375(3) . ?
O1 C15 1.420(4) . ?
N1 C5 1.328(3) . ?
N1 C4 1.363(3) . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C20 C19 1.436(13) . ?
C12 C12 1.401(5) 3_676 ?
C12 C5 1.438(3) 3_676 ?
C12 C3 1.401(4) . ?
C7 C1 1.433(3) . ?
C7 C6 1.427(4) . ?
C7 C8 1.413(4) . ?
C1 C2 1.377(4) . ?
C5 C14 1.441(4) 3_676 ?
C11 H11 0.9500 . ?
C11 C6 1.410(3) . ?
C11 C10 1.362(4) . ?
C6 C4 1.440(4) . ?
C10 H10 0.9500 . ?
C10 C9 1.406(4) . ?
C14 H14 0.9500 . ?
C14 C13 1.343(4) . ?
C3 C2 1.433(3) . ?
C3 C4 1.417(3) . ?
C2 C13 1.451(3) . ?
C8 H8 0.9500 . ?
C8 C9 1.365(4) . ?
C9 H9 0.9500 . ?
C13 H13 0.9500 . ?
C15 H15A 0.9900 . ?
C15 H15B 0.9900 . ?
C15 H15C 0.9900 . ?
C15 H15D 0.9900 . ?
C15 C16 1.530(10) . ?
C15 C16A 1.43(2) . ?
C17 H17A 0.9900 . ?
C17 H17B 0.9900 . ?
C17 C16 1.551(11) . ?
C17 C18 1.521(10) . ?
C16 H16 1.0000 . ?
C16 C21 1.488(11) . ?
C19 H19A 0.9900 . ?
C19 H19B 0.9900 . ?
C19 C18 1.495(13) . ?
C18 H18A 0.9900 . ?
C18 H18B 0.9900 . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C22 C21 1.548(17) . ?
C21 H21A 0.9900 . ?
C21 H21B 0.9900 . ?
C18A H18C 0.9900 . ?
C18A H18D 0.9900 . ?
C18A C17A 1.48(2) . ?
C18A C19A 1.60(3) . ?
C17A H17C 0.9900 . ?
C17A H17D 0.9900 . ?
C17A C16A 1.48(2) . ?
C19A H19C 0.9900 . ?
C19A H19D 0.9900 . ?
C19A C20A 1.55(3) . ?
C20A H20D 0.9800 . ?
C20A H20E 0.9800 . ?
C20A H20F 0.9800 . ?
C16A H16A 1.0000 . ?
C16A C21A 1.67(3) . ?
C21A H21C 0.9900 . ?
C21A H21D 0.9900 . ?
C21A C22A 1.36(3) . ?
C22A H22D 0.9800 . ?
C22A H22E 0.9800 . ?
C22A H22F 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 O1 C15 115.0(2) . . ?
C5 N1 C4 118.8(2) . . ?
H20A C20 H20B 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C19 C20 H20A 109.5 . . ?
C19 C20 H20B 109.5 . . ?
C19 C20 H20C 109.5 . . ?
C12 C12 C5 118.3(3) 3_676 3_676 ?
C12 C12 C3 119.4(3) 3_676 . ?
C3 C12 C5 122.3(2) . 3_676 ?
C6 C7 C1 119.9(2) . . ?
C8 C7 C1 121.4(2) . . ?
C8 C7 C6 118.7(2) . . ?
O1 C1 C7 118.4(2) . . ?
O1 C1 C2 120.1(2) . . ?
C2 C1 C7 121.5(2) . . ?
N1 C5 C12 122.6(2) . 3_676 ?
N1 C5 C14 121.0(2) . 3_676 ?
C12 C5 C14 116.4(2) 3_676 3_676 ?
C6 C11 H11 119.3 . . ?
C10 C11 H11 119.3 . . ?
C10 C11 C6 121.4(2) . . ?
C7 C6 C4 119.3(2) . . ?
C11 C6 C7 118.5(2) . . ?
C11 C6 C4 122.2(2) . . ?
C11 C10 H10 119.9 . . ?
C11 C10 C9 120.2(2) . . ?
C9 C10 H10 119.9 . . ?
C5 C14 H14 119.1 3_676 . ?
C13 C14 C5 121.8(2) . 3_676 ?
C13 C14 H14 119.1 . . ?
C12 C3 C2 119.7(2) . . ?
C12 C3 C4 118.2(2) . . ?
C4 C3 C2 122.0(2) . . ?
C1 C2 C3 118.7(2) . . ?
C1 C2 C13 124.0(2) . . ?
C3 C2 C13 117.2(2) . . ?
N1 C4 C6 118.7(2) . . ?
N1 C4 C3 122.8(2) . . ?
C3 C4 C6 118.5(2) . . ?
C7 C8 H8 119.5 . . ?
C9 C8 C7 121.1(3) . . ?
C9 C8 H8 119.5 . . ?
C10 C9 H9 119.9 . . ?
C8 C9 C10 120.2(3) . . ?
C8 C9 H9 119.9 . . ?
C14 C13 C2 122.4(2) . . ?
C14 C13 H13 118.8 . . ?
C2 C13 H13 118.8 . . ?
O1 C15 H15A 110.9 . . ?
O1 C15 H15B 110.9 . . ?
O1 C15 H15C 105.4 . . ?
O1 C15 H15D 105.4 . . ?
O1 C15 C16 104.3(4) . . ?
O1 C15 C16A 127.7(7) . . ?
H15A C15 H15B 108.9 . . ?
H15C C15 H15D 106.0 . . ?
C16 C15 H15A 110.9 . . ?
C16 C15 H15B 110.9 . . ?
C16A C15 H15C 105.4 . . ?
C16A C15 H15D 105.4 . . ?
H17A C17 H17B 107.1 . . ?
C16 C17 H17A 107.7 . . ?
C16 C17 H17B 107.7 . . ?
C18 C17 H17A 107.7 . . ?
C18 C17 H17B 107.7 . . ?
C18 C17 C16 118.3(7) . . ?
C15 C16 C17 106.4(6) . . ?
C15 C16 H16 108.6 . . ?
C17 C16 H16 108.6 . . ?
C21 C16 C15 110.3(7) . . ?
C21 C16 C17 114.1(6) . . ?
C21 C16 H16 108.6 . . ?
C20 C19 H19A 107.8 . . ?
C20 C19 H19B 107.8 . . ?
C20 C19 C18 118.1(10) . . ?
H19A C19 H19B 107.1 . . ?
C18 C19 H19A 107.8 . . ?
C18 C19 H19B 107.8 . . ?
C17 C18 H18A 108.6 . . ?
C17 C18 H18B 108.6 . . ?
C19 C18 C17 114.6(8) . . ?
C19 C18 H18A 108.6 . . ?
C19 C18 H18B 108.6 . . ?
H18A C18 H18B 107.6 . . ?
H22A C22 H22B 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C21 C22 H22A 109.5 . . ?
C21 C22 H22B 109.5 . . ?
C21 C22 H22C 109.5 . . ?
C16 C21 C22 110.8(10) . . ?
C16 C21 H21A 109.5 . . ?
C16 C21 H21B 109.5 . . ?
C22 C21 H21A 109.5 . . ?
C22 C21 H21B 109.5 . . ?
H21A C21 H21B 108.1 . . ?
H18C C18A H18D 107.6 . . ?
C17A C18A H18C 108.7 . . ?
C17A C18A H18D 108.7 . . ?
C17A C18A C19A 114.2(19) . . ?
C19A C18A H18C 108.7 . . ?
C19A C18A H18D 108.7 . . ?
C18A C17A H17C 109.2 . . ?
C18A C17A H17D 109.2 . . ?
C18A C17A C16A 111.9(18) . . ?
H17C C17A H17D 107.9 . . ?
C16A C17A H17C 109.2 . . ?
C16A C17A H17D 109.2 . . ?
C18A C19A H19C 110.9 . . ?
C18A C19A H19D 110.9 . . ?
H19C C19A H19D 108.9 . . ?
C20A C19A C18A 104(2) . . ?
C20A C19A H19C 110.9 . . ?
C20A C19A H19D 110.9 . . ?
C19A C20A H20D 109.5 . . ?
C19A C20A H20E 109.5 . . ?
C19A C20A H20F 109.5 . . ?
H20D C20A H20E 109.5 . . ?
H20D C20A H20F 109.5 . . ?
H20E C20A H20F 109.5 . . ?
C15 C16A C17A 112.6(13) . . ?
C15 C16A H16A 114.1 . . ?
C15 C16A C21A 97.4(14) . . ?
C17A C16A H16A 114.1 . . ?
C17A C16A C21A 103.0(16) . . ?
C21A C16A H16A 114.1 . . ?
C16A C21A H21C 107.7 . . ?
C16A C21A H21D 107.7 . . ?
H21C C21A H21D 107.1 . . ?
C22A C21A C16A 118.4(18) . . ?
C22A C21A H21C 107.7 . . ?
C22A C21A H21D 107.7 . . ?
C21A C22A H22D 109.5 . . ?
C21A C22A H22E 109.5 . . ?
C21A C22A H22F 109.5 . . ?
H22D C22A H22E 109.5 . . ?
H22D C22A H22F 109.5 . . ?
H22E C22A H22F 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O1 C1 C2 C3 -177.1(2) . . . . ?
O1 C1 C2 C13 1.7(4) . . . . ?
O1 C15 C16 C17 -76.0(6) . . . . ?
O1 C15 C16 C21 159.7(6) . . . . ?
O1 C15 C16A C17A -24(2) . . . . ?
O1 C15 C16A C21A 83.3(13) . . . . ?
C20 C19 C18 C17 -174.0(9) . . . . ?
C12 C12 C3 C2 -179.4(3) 3_676 . . . ?
C12 C12 C3 C4 0.1(4) 3_676 . . . ?
C12 C3 C2 C1 179.7(2) . . . . ?
C12 C3 C2 C13 0.8(3) . . . . ?
C12 C3 C4 N1 0.4(4) . . . . ?
C12 C3 C4 C6 179.9(2) . . . . ?
C7 C1 C2 C3 -0.4(4) . . . . ?
C7 C1 C2 C13 178.4(2) . . . . ?
C7 C6 C4 N1 -179.3(2) . . . . ?
C7 C6 C4 C3 1.1(3) . . . . ?
C7 C8 C9 C10 0.7(4) . . . . ?
C1 O1 C15 C16 -179.5(4) . . . . ?
C1 O1 C15 C16A -176.9(13) . . . . ?
C1 C7 C6 C11 -179.8(2) . . . . ?
C1 C7 C6 C4 -1.3(4) . . . . ?
C1 C7 C8 C9 179.1(2) . . . . ?
C1 C2 C13 C14 -179.9(2) . . . . ?
C5 N1 C4 C6 -179.8(2) . . . . ?
C5 N1 C4 C3 -0.3(4) . . . . ?
C5 C12 C3 C2 0.1(4) 3_676 . . . ?
C5 C12 C3 C4 179.5(2) 3_676 . . . ?
C5 C14 C13 C2 0.4(4) 3_676 . . . ?
C11 C6 C4 N1 -0.8(4) . . . . ?
C11 C6 C4 C3 179.6(2) . . . . ?
C11 C10 C9 C8 -1.2(4) . . . . ?
C6 C7 C1 O1 177.7(2) . . . . ?
C6 C7 C1 C2 0.9(4) . . . . ?
C6 C7 C8 C9 0.5(4) . . . . ?
C6 C11 C10 C9 0.6(4) . . . . ?
C10 C11 C6 C7 0.6(4) . . . . ?
C10 C11 C6 C4 -177.9(2) . . . . ?
C3 C2 C13 C14 -1.1(4) . . . . ?
C2 C3 C4 N1 179.8(2) . . . . ?
C2 C3 C4 C6 -0.6(4) . . . . ?
C4 N1 C5 C12 -0.2(4) . . . 3_676 ?
C4 N1 C5 C14 179.2(2) . . . 3_676 ?
C4 C3 C2 C1 0.3(4) . . . . ?
C4 C3 C2 C13 -178.7(2) . . . . ?
C8 C7 C1 O1 -0.9(4) . . . . ?
C8 C7 C1 C2 -177.7(2) . . . . ?
C8 C7 C6 C11 -1.1(4) . . . . ?
C8 C7 C6 C4 177.4(2) . . . . ?
C15 O1 C1 C7 92.9(3) . . . . ?
C15 O1 C1 C2 -90.2(3) . . . . ?
C15 C16 C21 C22 -73.5(11) . . . . ?
C15 C16A C21A C22A 165(2) . . . . ?
C17 C16 C21 C22 166.8(10) . . . . ?
C16 C17 C18 C19 -177.3(8) . . . . ?
C18 C17 C16 C15 176.6(6) . . . . ?
C18 C17 C16 C21 -61.5(10) . . . . ?
C18A C17A C16A C15 -96.3(17) . . . . ?
C18A C17A C16A C21A 159.9(14) . . . . ?
C17A C18A C19A C20A 167.5(17) . . . . ?
C17A C16A C21A C22A -80(3) . . . . ?
C19A C18A C17A C16A 179.4(18) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
