# Electronic Supplementary Material (ESI) for Chemical Science.
# This journal is © The Royal Society of Chemistry 2022

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_OTRhPMe3
_database_code_depnum_ccdc_archive 'CCDC 2155445'
loop_
_audit_author_name
_audit_author_address
'Jose Goicoechea'
;University of Oxford
United Kingdom
;
_audit_update_record             
;
2022-02-28 deposited with the CCDC.	2022-06-09 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/1
_shelx_SHELXL_version_number     2018/1
_chemical_name_systematic        
;
 Ge9{Si(SiMe3)}3Rh(PMe3)
;
_contact_author_fax              '+44 1865 272690'
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C30 H90 Ge9 P Rh Si12'
_chemical_formula_sum            'C30 H90 Ge9 P Rh Si12'
_chemical_formula_weight         1575.28

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge -1.0885 0.8855 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh 0.0927 3.6045 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.2541 0.3302 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   14.44110(10)
_cell_length_b                   25.5519(2)
_cell_length_c                   18.90460(10)
_cell_angle_alpha                90
_cell_angle_beta                 101.7710(10)
_cell_angle_gamma                90
_cell_volume                     6829.06(8)
_cell_formula_units_Z            4
_cell_measurement_temperature    150(2)
_cell_measurement_reflns_used    57481
_cell_measurement_theta_min      2.9440
_cell_measurement_theta_max      76.5900

_exptl_crystal_description       plate
_exptl_crystal_colour            black
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    .
_exptl_crystal_density_diffrn    1.532
_exptl_crystal_F_000             3144
_exptl_transmission_factor_min   .
_exptl_transmission_factor_max   .
_exptl_crystal_size_max          0.220
_exptl_crystal_size_mid          0.180
_exptl_crystal_size_min          0.060
_exptl_absorpt_coefficient_mu    8.686
_shelx_estimated_absorpt_T_min   0.251
_shelx_estimated_absorpt_T_max   0.624
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.19791
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.41.81a (Rigaku Oxford Diffraction, 2020)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   .

_diffrn_ambient_temperature      150(2)
_diffrn_radiation_wavelength     1.54184
_diffrn_radiation_type           CuK\a
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'SuperNova (Cu) X-ray Source'
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at home/near, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_detector                 'CCD plate'
_diffrn_detector_type            Atlas
_diffrn_detector_area_resol_mean 10.5035
_diffrn_reflns_number            132946
_diffrn_reflns_av_unetI/netI     0.0219
_diffrn_reflns_av_R_equivalents  0.0521
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_k_min       -32
_diffrn_reflns_limit_k_max       30
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_theta_min         2.948
_diffrn_reflns_theta_max         76.788
_diffrn_reflns_theta_full        67.684
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.994
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.994
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             14310
_reflns_number_gt                12542
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'CrysAlisPro 1.171.41.81a (Rigaku OD, 2020)'
_computing_cell_refinement       'CrysAlisPro 1.171.41.81a (Rigaku OD, 2020)'
_computing_data_reduction        'CrysAlisPro 1.171.41.81a (Rigaku OD, 2020)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2018/1 (Sheldrick, 2018)'
_computing_molecular_graphics    .
_computing_publication_material  .
_refine_special_details          .

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0442P)²+15.4871P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     .
_atom_sites_solution_secondary   .
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         14310
_refine_ls_number_parameters     569
_refine_ls_number_restraints     27
_refine_ls_R_factor_all          0.0456
_refine_ls_R_factor_gt           0.0393
_refine_ls_wR_factor_ref         0.1020
_refine_ls_wR_factor_gt          0.0975
_refine_ls_goodness_of_fit_ref   1.019
_refine_ls_restrained_S_all      1.027
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.32769(3) 0.36604(2) 0.53661(2) 0.04031(13) Uani 0.6152(8) 1 d . . P A
1
Ge1 Ge 0.2695(4) 0.4391(3) 0.6928(3) 0.0320(6) Uani 0.6152(8) 1 d . . P A 1
Ge2 Ge 0.2009(6) 0.3453(3) 0.7241(6) 0.0348(8) Uani 0.6152(8) 1 d . . P A 1
Ge3 Ge 0.18561(17) 0.39021(12) 0.57742(15) 0.0338(5) Uani 0.6152(8) 1 d . . P A
1
Ge4 Ge 0.40922(5) 0.42645(3) 0.62794(4) 0.03907(17) Uani 0.6152(8) 1 d . . P A
1
Ge5 Ge 0.3656(6) 0.3825(3) 0.7958(4) 0.0363(7) Uani 0.6152(8) 1 d . . P A 1
Ge6 Ge 0.3600(5) 0.2933(2) 0.7433(4) 0.0326(7) Uani 0.6152(8) 1 d . . P A 1
Ge7 Ge 0.2557(5) 0.30600(18) 0.6162(4) 0.0295(6) Uani 0.6152(8) 1 d . . P A 1
Ge8 Ge 0.4844(5) 0.36054(19) 0.7209(3) 0.0311(6) Uani 0.6152(8) 1 d . . P A 1
Ge9 Ge 0.43259(5) 0.30310(3) 0.60438(4) 0.03884(17) Uani 0.6152(8) 1 d . . P A
1
Rh1A Rh 0.33110(5) 0.43058(3) 0.57244(4) 0.0418(2) Uani 0.3848(8) 1 d . . P A 2
Ge1A Ge 0.4847(8) 0.3502(3) 0.7153(6) 0.0310(9) Uani 0.3848(8) 1 d . . P A 2
Ge2A Ge 0.3645(10) 0.3911(5) 0.7929(6) 0.0386(14) Uani 0.3848(8) 1 d . . P A 2
Ge3A Ge 0.43941(7) 0.45184(4) 0.68115(6) 0.0367(3) Uani 0.3848(8) 1 d . . P A 2
Ge4A Ge 0.40639(8) 0.34496(5) 0.58852(6) 0.0387(3) Uani 0.3848(8) 1 d . . P A 2
Ge5A Ge 0.3575(9) 0.2834(4) 0.7438(7) 0.0317(10) Uani 0.3848(8) 1 d . . P A 2
Ge6A Ge 0.2094(10) 0.3468(6) 0.7330(9) 0.0365(16) Uani 0.3848(8) 1 d . . P A 2
Ge7A Ge 0.2578(7) 0.4341(4) 0.6814(5) 0.0343(11) Uani 0.3848(8) 1 d . . P A 2
Ge8A Ge 0.2609(8) 0.2955(3) 0.6157(6) 0.0287(9) Uani 0.3848(8) 1 d . . P A 2
Ge9A Ge 0.1793(4) 0.3891(2) 0.5787(3) 0.0640(16) Uani 0.3848(8) 1 d . . P A 2
P1 P 0.35249(11) 0.42268(9) 0.44782(8) 0.0909(6) Uani 1 1 d . . . . .
C1 C 0.0800(7) 0.5533(3) 0.5547(4) 0.142(4) Uani 1 1 d . . . . .
H1A H 0.091455 0.517928 0.538449 0.213 Uiso 1 1 calc R U . . .
H1B H 0.021305 0.553739 0.573029 0.213 Uiso 1 1 calc R U . . .
H1C H 0.074494 0.577710 0.513981 0.213 Uiso 1 1 calc R U . . .
C2 C 0.1578(4) 0.64104(19) 0.6582(4) 0.0788(17) Uani 1 1 d . . . . .
H2A H 0.210336 0.652042 0.696710 0.118 Uiso 1 1 calc R U . . .
H2B H 0.152089 0.665235 0.617271 0.118 Uiso 1 1 calc R U . . .
H2C H 0.098900 0.641265 0.676319 0.118 Uiso 1 1 calc R U . . .
C3 C 0.2926(6) 0.5761(2) 0.5925(4) 0.097(2) Uani 1 1 d . . . . .
H3A H 0.306828 0.541204 0.576098 0.146 Uiso 1 1 calc R U . . .
H3B H 0.284812 0.600676 0.551845 0.146 Uiso 1 1 calc R U . . .
H3C H 0.344756 0.587845 0.630870 0.146 Uiso 1 1 calc R U . . .
C4 C 0.4134(6) 0.5704(5) 0.7975(5) 0.180(6) Uani 1 1 d . . . . .
H4A H 0.398415 0.594530 0.756531 0.269 Uiso 1 1 calc R U . . .
H4B H 0.455668 0.587681 0.837891 0.269 Uiso 1 1 calc R U . . .
H4C H 0.444549 0.539189 0.783233 0.269 Uiso 1 1 calc R U . . .
C5 C 0.3338(7) 0.5055(3) 0.9030(3) 0.126(4) Uani 1 1 d . . . . .
H5A H 0.275766 0.494999 0.918428 0.189 Uiso 1 1 calc R U . . .
H5B H 0.365177 0.474515 0.888445 0.189 Uiso 1 1 calc R U . . .
H5C H 0.376296 0.523007 0.943102 0.189 Uiso 1 1 calc R U . . .
C6 C 0.2482(7) 0.6096(2) 0.8600(4) 0.113(3) Uani 1 1 d . . . . .
H6A H 0.189808 0.598957 0.874796 0.170 Uiso 1 1 calc R U . . .
H6B H 0.292157 0.624502 0.901500 0.170 Uiso 1 1 calc R U . . .
H6C H 0.233518 0.635947 0.821625 0.170 Uiso 1 1 calc R U . . .
C7 C -0.0167(4) 0.5600(2) 0.7550(5) 0.101(3) Uani 1 1 d . . . . .
H7A H 0.019867 0.583284 0.791545 0.152 Uiso 1 1 calc R U . . .
H7B H -0.026748 0.577134 0.707587 0.152 Uiso 1 1 calc R U . . .
H7C H -0.077945 0.552463 0.767346 0.152 Uiso 1 1 calc R U . . .
C8 C -0.0188(4) 0.4532(3) 0.6826(6) 0.148(5) Uani 1 1 d . . . . .
H8A H -0.026242 0.469525 0.634854 0.222 Uiso 1 1 calc R U . . .
H8B H 0.014658 0.419862 0.682759 0.222 Uiso 1 1 calc R U . . .
H8C H -0.081347 0.446982 0.693643 0.222 Uiso 1 1 calc R U . . .
C9 C 0.0643(7) 0.4666(3) 0.8425(6) 0.163(5) Uani 1 1 d . . . . .
H9A H 0.100671 0.490032 0.878972 0.244 Uiso 1 1 calc R U . . .
H9B H 0.001823 0.460407 0.853646 0.244 Uiso 1 1 calc R U . . .
H9C H 0.097827 0.433288 0.842762 0.244 Uiso 1 1 calc R U . . .
C10 C 0.3765(8) 0.1521(5) 0.5502(7) 0.233(7) Uani 1 1 d . U . . .
H10A H 0.353631 0.157873 0.498328 0.350 Uiso 1 1 calc R U . . .
H10B H 0.419670 0.180457 0.570226 0.350 Uiso 1 1 calc R U . . .
H10C H 0.410056 0.118581 0.557769 0.350 Uiso 1 1 calc R U . . .
C11 C 0.3155(5) 0.1403(2) 0.6927(3) 0.092(2) Uani 1 1 d . U . . .
H11A H 0.259641 0.139948 0.714692 0.138 Uiso 1 1 calc R U . . .
H11B H 0.348442 0.106646 0.701508 0.138 Uiso 1 1 calc R U . . .
H11C H 0.358056 0.168522 0.713965 0.138 Uiso 1 1 calc R U . . .
C12 C 0.2094(10) 0.0906(3) 0.5597(6) 0.221(7) Uani 1 1 d . U . . .
H12A H 0.154050 0.087559 0.582074 0.331 Uiso 1 1 calc R U . . .
H12B H 0.188523 0.092990 0.507149 0.331 Uiso 1 1 calc R U . . .
H12C H 0.249644 0.059636 0.571850 0.331 Uiso 1 1 calc R U . . .
C13 C 0.0628(4) 0.2069(2) 0.7074(2) 0.0638(13) Uani 1 1 d . . . . .
H13A H 0.100300 0.236034 0.731952 0.096 Uiso 1 1 calc R U . . .
H13B H 0.002692 0.204733 0.723671 0.096 Uiso 1 1 calc R U . . .
H13C H 0.097906 0.174124 0.718897 0.096 Uiso 1 1 calc R U . . .
C14 C -0.0326(4) 0.1622(2) 0.5610(3) 0.0812(18) Uani 1 1 d . . . . .
H14A H 0.003419 0.129645 0.571613 0.122 Uiso 1 1 calc R U . . .
H14B H -0.091745 0.159511 0.578507 0.122 Uiso 1 1 calc R U . . .
H14C H -0.046867 0.168203 0.508678 0.122 Uiso 1 1 calc R U . . .
C15 C -0.0323(3) 0.2795(2) 0.5854(3) 0.0673(14) Uani 1 1 d . . . . .
H15A H 0.004072 0.309334 0.609069 0.101 Uiso 1 1 calc R U . . .
H15B H -0.046555 0.285015 0.532973 0.101 Uiso 1 1 calc R U . . .
H15C H -0.091433 0.276323 0.602802 0.101 Uiso 1 1 calc R U . . .
C16 C 0.0638(5) 0.2917(3) 0.4142(3) 0.104(3) Uani 1 1 d . . . . .
H16A H 0.004804 0.283483 0.429821 0.155 Uiso 1 1 calc R U . . .
H16B H 0.090468 0.324207 0.437478 0.155 Uiso 1 1 calc R U . . .
H16C H 0.050924 0.296178 0.361627 0.155 Uiso 1 1 calc R U . . .
C17 C 0.2609(4) 0.2538(2) 0.4102(2) 0.0686(14) Uani 1 1 d . . . . .
H17A H 0.306597 0.225412 0.423746 0.103 Uiso 1 1 calc R U . . .
H17B H 0.247595 0.258351 0.357657 0.103 Uiso 1 1 calc R U . . .
H17C H 0.287139 0.286380 0.433507 0.103 Uiso 1 1 calc R U . . .
C18 C 0.0980(4) 0.1768(3) 0.3938(3) 0.0807(18) Uani 1 1 d . . . . .
H18A H 0.142514 0.147740 0.406950 0.121 Uiso 1 1 calc R U . . .
H18B H 0.038450 0.168575 0.408530 0.121 Uiso 1 1 calc R U . . .
H18C H 0.086028 0.182074 0.341331 0.121 Uiso 1 1 calc R U . . .
C19 C 0.5909(4) 0.21657(19) 0.8329(3) 0.0734(15) Uani 1 1 d . . . . .
H19A H 0.632217 0.205869 0.800308 0.110 Uiso 1 1 calc R U . . .
H19B H 0.592021 0.189749 0.870122 0.110 Uiso 1 1 calc R U . . .
H19C H 0.526091 0.220758 0.805273 0.110 Uiso 1 1 calc R U . . .
C20 C 0.5537(5) 0.2992(3) 0.9381(3) 0.0840(19) Uani 1 1 d . . . . .
H20A H 0.575094 0.332556 0.961508 0.126 Uiso 1 1 calc R U . . .
H20B H 0.489007 0.303168 0.910094 0.126 Uiso 1 1 calc R U . . .
H20C H 0.554938 0.272158 0.974944 0.126 Uiso 1 1 calc R U . . .
C21 C 0.7544(4) 0.2693(2) 0.9327(3) 0.0819(18) Uani 1 1 d . . . . .
H21A H 0.797627 0.259124 0.901297 0.123 Uiso 1 1 calc R U . . .
H21B H 0.776930 0.301739 0.958146 0.123 Uiso 1 1 calc R U . . .
H21C H 0.752035 0.241482 0.967915 0.123 Uiso 1 1 calc R U . . .
C22 C 0.6022(5) 0.4510(3) 0.8954(4) 0.096(2) Uani 1 1 d . . . . .
H22A H 0.594559 0.425420 0.932368 0.144 Uiso 1 1 calc R U . . .
H22B H 0.624950 0.484186 0.918648 0.144 Uiso 1 1 calc R U . . .
H22C H 0.541209 0.456654 0.862474 0.144 Uiso 1 1 calc R U . . .
C23 C 0.7025(7) 0.4750(2) 0.7741(3) 0.111(3) Uani 1 1 d . . . . .
H23A H 0.748315 0.462297 0.746341 0.166 Uiso 1 1 calc R U . . .
H23B H 0.641229 0.480610 0.741500 0.166 Uiso 1 1 calc R U . . .
H23C H 0.724970 0.508141 0.797674 0.166 Uiso 1 1 calc R U . . .
C24 C 0.8051(4) 0.4197(3) 0.9088(4) 0.105(3) Uani 1 1 d . . . . .
H24A H 0.799164 0.393857 0.945945 0.158 Uiso 1 1 calc R U . . .
H24B H 0.853823 0.408280 0.882942 0.158 Uiso 1 1 calc R U . . .
H24C H 0.822870 0.453643 0.931699 0.158 Uiso 1 1 calc R U . . .
C25 C 0.7233(5) 0.3674(2) 0.6323(3) 0.0774(16) Uani 1 1 d . . . . .
H25A H 0.740859 0.402519 0.651265 0.116 Uiso 1 1 calc R U . . .
H25B H 0.764872 0.356921 0.599822 0.116 Uiso 1 1 calc R U . . .
H25C H 0.657513 0.367687 0.605644 0.116 Uiso 1 1 calc R U . . .
C26 C 0.8621(4) 0.3184(4) 0.7577(4) 0.121(3) Uani 1 1 d . . . . .
H26A H 0.880252 0.352847 0.778846 0.182 Uiso 1 1 calc R U . . .
H26B H 0.869547 0.292117 0.796261 0.182 Uiso 1 1 calc R U . . .
H26C H 0.902626 0.309287 0.723855 0.182 Uiso 1 1 calc R U . . .
C27 C 0.7014(5) 0.2550(2) 0.6688(4) 0.091(2) Uani 1 1 d . . . . .
H27A H 0.707054 0.228922 0.707395 0.137 Uiso 1 1 calc R U . . .
H27B H 0.635846 0.256214 0.641803 0.137 Uiso 1 1 calc R U . . .
H27C H 0.743205 0.245448 0.635981 0.137 Uiso 1 1 calc R U . . .
C28 C 0.2512(7) 0.4126(5) 0.3745(5) 0.149(4) Uani 1 1 d . . . . .
H28A H 0.193515 0.423916 0.389851 0.223 Uiso 1 1 calc R U . . .
H28B H 0.259343 0.433117 0.332374 0.223 Uiso 1 1 calc R U . . .
H28C H 0.246152 0.375417 0.361729 0.223 Uiso 1 1 calc R U . . .
C29 C 0.3588(11) 0.4912(4) 0.4422(5) 0.195(6) Uani 1 1 d . . . . .
H29A H 0.305888 0.506881 0.459815 0.292 Uiso 1 1 calc R U . . .
H29B H 0.418663 0.503395 0.471788 0.292 Uiso 1 1 calc R U . . .
H29C H 0.355425 0.501464 0.391770 0.292 Uiso 1 1 calc R U . . .
C30 C 0.4504(7) 0.4014(5) 0.4148(7) 0.201(7) Uani 1 1 d . . . . .
H30A H 0.452970 0.363111 0.415826 0.301 Uiso 1 1 calc R U . . .
H30B H 0.445045 0.413667 0.364977 0.301 Uiso 1 1 calc R U . . .
H30C H 0.508283 0.415598 0.444995 0.301 Uiso 1 1 calc R U . . .
Si1 Si 0.19833(7) 0.51569(4) 0.72577(6) 0.0414(2) Uani 1 1 d . . . . .
Si2 Si 0.18073(10) 0.57361(5) 0.62801(8) 0.0587(3) Uani 1 1 d . . . . .
Si3 Si 0.30399(12) 0.55115(7) 0.82552(8) 0.0716(4) Uani 1 1 d . . . . .
Si4 Si 0.05006(11) 0.49738(5) 0.75185(12) 0.0827(6) Uani 1 1 d . . . . .
Si5 Si 0.18075(7) 0.22431(4) 0.56554(5) 0.0347(2) Uani 1 1 d . . . . .
Si6 Si 0.27834(14) 0.15099(7) 0.59450(9) 0.0822(5) Uani 1 1 d . U . . .
Si7 Si 0.03888(8) 0.21802(5) 0.60699(6) 0.0465(3) Uani 1 1 d . . . . .
Si8 Si 0.14951(8) 0.23753(5) 0.44021(5) 0.0454(2) Uani 1 1 d . . . . .
Si9 Si 0.64014(7) 0.34487(4) 0.78940(5) 0.03444(19) Uani 1 1 d . . . . .
Si10 Si 0.63342(8) 0.28001(5) 0.87665(6) 0.0496(3) Uani 1 1 d . . . . .
Si11 Si 0.68927(9) 0.42600(5) 0.84359(6) 0.0496(3) Uani 1 1 d . . . . .
Si12 Si 0.73572(8) 0.32015(5) 0.70863(7) 0.0503(3) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 P1 2.2992(14) . ?
Rh1 Ge9 2.3939(9) . ?
Rh1 Ge3 2.415(2) . ?
Rh1 Ge4 2.4333(9) . ?
Rh1 Ge7 2.517(7) . ?
Ge1 Si1 2.354(7) . ?
Ge1 Ge4 2.586(6) . ?
Ge1 Ge5 2.589(10) . ?
Ge1 Ge3 2.590(6) . ?
Ge1 Ge2 2.703(11) . ?
Ge2 Ge7 2.540(11) . ?
Ge2 Ge6 2.614(11) . ?
Ge2 Ge5 2.661(13) . ?
Ge3 Ge7 2.427(6) . ?
Ge4 Ge8 2.516(6) . ?
Ge5 Ge6 2.480(9) . ?
Ge5 Ge8 2.501(10) . ?
Ge6 Ge8 2.581(9) . ?
Ge6 Ge7 2.583(10) . ?
Ge7 Si5 2.454(6) . ?
Ge7 Ge9 2.610(7) . ?
Ge8 Si9 2.389(6) . ?
Ge8 Ge9 2.626(5) . ?
Rh1A Ge3A 2.3776(14) . ?
Rh1A Ge4A 2.4345(15) . ?
Rh1A P1 2.4461(17) . ?
Rh1A Ge9A 2.460(5) . ?
Rh1A Ge7A 2.502(10) . ?
Ge1A Si9 2.395(11) . ?
Ge1A Ge4A 2.437(11) . ?
Ge1A Ge5A 2.641(16) . ?
Ge1A Ge2A 2.702(16) . ?
Ge1A Ge3A 2.723(9) . ?
Ge2A Ge6A 2.56(2) . ?
Ge2A Ge7A 2.588(16) . ?
Ge2A Ge5A 2.899(15) . ?
Ge3A Ge7A 2.663(10) . ?
Ge4A Ge8A 2.592(12) . ?
Ge5A Ge8A 2.556(17) . ?
Ge5A Ge6A 2.657(18) . ?
Ge6A Ge7A 2.586(17) . ?
Ge6A Ge8A 2.804(18) . ?
Ge7A Ge9A 2.340(11) . ?
Ge7A Si1 2.467(11) . ?
Ge8A Si5 2.258(10) . ?
Ge8A Ge9A 2.694(10) . ?
P1 C30 1.745(8) . ?
P1 C29 1.757(11) . ?
P1 C28 1.816(9) . ?
C1 Si2 1.866(7) . ?
C1 H1A 0.9800 . ?
C1 H1B 0.9800 . ?
C1 H1C 0.9800 . ?
C2 Si2 1.866(5) . ?
C2 H2A 0.9800 . ?
C2 H2B 0.9800 . ?
C2 H2C 0.9800 . ?
C3 Si2 1.873(7) . ?
C3 H3A 0.9800 . ?
C3 H3B 0.9800 . ?
C3 H3C 0.9800 . ?
C4 Si3 1.832(9) . ?
C4 H4A 0.9800 . ?
C4 H4B 0.9800 . ?
C4 H4C 0.9800 . ?
C5 Si3 1.852(7) . ?
C5 H5A 0.9800 . ?
C5 H5B 0.9800 . ?
C5 H5C 0.9800 . ?
C6 Si3 1.876(7) . ?
C6 H6A 0.9800 . ?
C6 H6B 0.9800 . ?
C6 H6C 0.9800 . ?
C7 Si4 1.876(5) . ?
C7 H7A 0.9800 . ?
C7 H7B 0.9800 . ?
C7 H7C 0.9800 . ?
C8 Si4 1.856(8) . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C9 Si4 1.858(9) . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
C10 Si6 1.788(9) . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C11 Si6 1.844(6) . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C12 Si6 1.882(10) . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
C13 Si7 1.880(4) . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C13 H13C 0.9800 . ?
C14 Si7 1.868(5) . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C15 Si7 1.876(6) . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 Si8 1.856(6) . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 Si8 1.858(5) . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C18 Si8 1.862(5) . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C19 Si10 1.866(6) . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C20 Si10 1.860(6) . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C21 Si10 1.869(5) . ?
C21 H21A 0.9800 . ?
C21 H21B 0.9800 . ?
C21 H21C 0.9800 . ?
C22 Si11 1.857(6) . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C23 Si11 1.854(6) . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C24 Si11 1.871(6) . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C25 Si12 1.862(6) . ?
C25 H25A 0.9800 . ?
C25 H25B 0.9800 . ?
C25 H25C 0.9800 . ?
C26 Si12 1.872(6) . ?
C26 H26A 0.9800 . ?
C26 H26B 0.9800 . ?
C26 H26C 0.9800 . ?
C27 Si12 1.852(6) . ?
C27 H27A 0.9800 . ?
C27 H27B 0.9800 . ?
C27 H27C 0.9800 . ?
C28 H28A 0.9800 . ?
C28 H28B 0.9800 . ?
C28 H28C 0.9800 . ?
C29 H29A 0.9800 . ?
C29 H29B 0.9800 . ?
C29 H29C 0.9800 . ?
C30 H30A 0.9800 . ?
C30 H30B 0.9800 . ?
C30 H30C 0.9800 . ?
Si1 Si4 2.3404(16) . ?
Si1 Si2 2.3407(17) . ?
Si1 Si3 2.3519(19) . ?
Si5 Si6 2.3410(16) . ?
Si5 Si7 2.3435(14) . ?
Si5 Si8 2.3442(14) . ?
Si9 Si12 2.3444(14) . ?
Si9 Si10 2.3541(15) . ?
Si9 Si11 2.3567(15) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Rh1 Ge9 129.63(5) . . ?
P1 Rh1 Ge3 109.95(9) . . ?
Ge9 Rh1 Ge3 119.14(8) . . ?
P1 Rh1 Ge4 89.64(6) . . ?
Ge9 Rh1 Ge4 83.38(3) . . ?
Ge3 Rh1 Ge4 86.03(7) . . ?
P1 Rh1 Ge7 164.78(16) . . ?
Ge9 Rh1 Ge7 64.16(14) . . ?
Ge3 Rh1 Ge7 58.90(14) . . ?
Ge4 Rh1 Ge7 99.30(15) . . ?
Si1 Ge1 Ge4 130.9(3) . . ?
Si1 Ge1 Ge5 117.5(3) . . ?
Ge4 Ge1 Ge5 86.4(3) . . ?
Si1 Ge1 Ge3 118.0(3) . . ?
Ge4 Ge1 Ge3 79.43(17) . . ?
Ge5 Ge1 Ge3 116.8(3) . . ?
Si1 Ge1 Ge2 118.7(3) . . ?
Ge4 Ge1 Ge2 110.5(3) . . ?
Ge5 Ge1 Ge2 60.3(3) . . ?
Ge3 Ge1 Ge2 68.2(3) . . ?
Ge7 Ge2 Ge6 60.1(3) . . ?
Ge7 Ge2 Ge5 99.1(4) . . ?
Ge6 Ge2 Ge5 56.1(3) . . ?
Ge7 Ge2 Ge1 89.2(3) . . ?
Ge6 Ge2 Ge1 97.4(4) . . ?
Ge5 Ge2 Ge1 57.7(3) . . ?
Rh1 Ge3 Ge7 62.65(19) . . ?
Rh1 Ge3 Ge1 96.33(16) . . ?
Ge7 Ge3 Ge1 94.5(2) . . ?
Rh1 Ge4 Ge8 98.54(11) . . ?
Rh1 Ge4 Ge1 95.98(12) . . ?
Ge8 Ge4 Ge1 91.1(2) . . ?
Ge6 Ge5 Ge8 62.4(3) . . ?
Ge6 Ge5 Ge1 104.1(3) . . ?
Ge8 Ge5 Ge1 91.3(3) . . ?
Ge6 Ge5 Ge2 61.0(3) . . ?
Ge8 Ge5 Ge2 106.0(3) . . ?
Ge1 Ge5 Ge2 62.0(3) . . ?
Ge5 Ge6 Ge8 59.2(3) . . ?
Ge5 Ge6 Ge7 102.9(3) . . ?
Ge8 Ge6 Ge7 93.3(3) . . ?
Ge5 Ge6 Ge2 62.9(3) . . ?
Ge8 Ge6 Ge2 105.1(3) . . ?
Ge7 Ge6 Ge2 58.5(3) . . ?
Ge3 Ge7 Si5 120.8(3) . . ?
Ge3 Ge7 Rh1 58.44(14) . . ?
Si5 Ge7 Rh1 119.2(3) . . ?
Ge3 Ge7 Ge2 73.3(3) . . ?
Si5 Ge7 Ge2 117.7(4) . . ?
Rh1 Ge7 Ge2 118.3(3) . . ?
Ge3 Ge7 Ge6 121.4(3) . . ?
Si5 Ge7 Ge6 112.6(2) . . ?
Rh1 Ge7 Ge6 113.5(3) . . ?
Ge2 Ge7 Ge6 61.4(3) . . ?
Ge3 Ge7 Ge9 110.8(3) . . ?
Si5 Ge7 Ge9 107.7(2) . . ?
Rh1 Ge7 Ge9 55.63(15) . . ?
Ge2 Ge7 Ge9 123.4(4) . . ?
Ge6 Ge7 Ge9 71.4(3) . . ?
Si9 Ge8 Ge5 114.2(3) . . ?
Si9 Ge8 Ge4 135.7(3) . . ?
Ge5 Ge8 Ge4 89.9(3) . . ?
Si9 Ge8 Ge6 114.2(3) . . ?
Ge5 Ge8 Ge6 58.4(3) . . ?
Ge4 Ge8 Ge6 110.1(3) . . ?
Si9 Ge8 Ge9 115.9(2) . . ?
Ge5 Ge8 Ge9 119.3(3) . . ?
Ge4 Ge8 Ge9 77.25(18) . . ?
Ge6 Ge8 Ge9 71.2(2) . . ?
Rh1 Ge9 Ge7 60.21(14) . . ?
Rh1 Ge9 Ge8 96.57(13) . . ?
Ge7 Ge9 Ge8 91.6(2) . . ?
Ge3A Rh1A Ge4A 84.21(4) . . ?
Ge3A Rh1A P1 131.40(6) . . ?
Ge4A Rh1A P1 84.55(6) . . ?
Ge3A Rh1A Ge9A 119.50(15) . . ?
Ge4A Rh1A Ge9A 89.21(15) . . ?
P1 Rh1A Ge9A 107.44(15) . . ?
Ge3A Rh1A Ge7A 66.1(2) . . ?
Ge4A Rh1A Ge7A 100.5(3) . . ?
P1 Rh1A Ge7A 162.5(2) . . ?
Ge9A Rh1A Ge7A 56.3(2) . . ?
Si9 Ge1A Ge4A 139.8(5) . . ?
Si9 Ge1A Ge5A 116.8(5) . . ?
Ge4A Ge1A Ge5A 87.9(4) . . ?
Si9 Ge1A Ge2A 109.5(5) . . ?
Ge4A Ge1A Ge2A 109.6(5) . . ?
Ge5A Ge1A Ge2A 65.7(5) . . ?
Si9 Ge1A Ge3A 110.1(3) . . ?
Ge4A Ge1A Ge3A 77.2(3) . . ?
Ge5A Ge1A Ge3A 121.4(5) . . ?
Ge2A Ge1A Ge3A 67.1(3) . . ?
Ge6A Ge2A Ge7A 60.3(5) . . ?
Ge6A Ge2A Ge1A 100.9(5) . . ?
Ge7A Ge2A Ge1A 93.6(5) . . ?
Ge6A Ge2A Ge5A 57.9(5) . . ?
Ge7A Ge2A Ge5A 99.5(5) . . ?
Ge1A Ge2A Ge5A 56.1(4) . . ?
Rh1A Ge3A Ge7A 59.2(2) . . ?
Rh1A Ge3A Ge1A 94.1(2) . . ?
Ge7A Ge3A Ge1A 91.5(4) . . ?
Rh1A Ge4A Ge1A 100.31(19) . . ?
Rh1A Ge4A Ge8A 95.94(18) . . ?
Ge1A Ge4A Ge8A 93.7(4) . . ?
Ge8A Ge5A Ge1A 89.8(5) . . ?
Ge8A Ge5A Ge6A 65.0(5) . . ?
Ge1A Ge5A Ge6A 99.9(5) . . ?
Ge8A Ge5A Ge2A 99.5(4) . . ?
Ge1A Ge5A Ge2A 58.1(4) . . ?
Ge6A Ge5A Ge2A 54.6(5) . . ?
Ge2A Ge6A Ge7A 60.4(5) . . ?
Ge2A Ge6A Ge5A 67.5(5) . . ?
Ge7A Ge6A Ge5A 106.2(6) . . ?
Ge2A Ge6A Ge8A 102.0(6) . . ?
Ge7A Ge6A Ge8A 88.3(5) . . ?
Ge5A Ge6A Ge8A 55.7(4) . . ?
Ge9A Ge7A Si1 123.6(5) . . ?
Ge9A Ge7A Rh1A 61.0(3) . . ?
Si1 Ge7A Rh1A 123.0(4) . . ?
Ge9A Ge7A Ge6A 76.5(5) . . ?
Si1 Ge7A Ge6A 117.5(5) . . ?
Rh1A Ge7A Ge6A 118.2(5) . . ?
Ge9A Ge7A Ge2A 125.1(5) . . ?
Si1 Ge7A Ge2A 105.8(4) . . ?
Rh1A Ge7A Ge2A 112.0(5) . . ?
Ge6A Ge7A Ge2A 59.3(5) . . ?
Ge9A Ge7A Ge3A 113.1(4) . . ?
Si1 Ge7A Ge3A 105.5(3) . . ?
Rh1A Ge7A Ge3A 54.7(2) . . ?
Ge6A Ge7A Ge3A 119.3(5) . . ?
Ge2A Ge7A Ge3A 69.6(4) . . ?
Si5 Ge8A Ge5A 115.8(4) . . ?
Si5 Ge8A Ge4A 132.6(5) . . ?
Ge5A Ge8A Ge4A 86.5(4) . . ?
Si5 Ge8A Ge9A 116.5(5) . . ?
Ge5A Ge8A Ge9A 118.6(4) . . ?
Ge4A Ge8A Ge9A 81.1(3) . . ?
Si5 Ge8A Ge6A 120.9(6) . . ?
Ge5A Ge8A Ge6A 59.2(5) . . ?
Ge4A Ge8A Ge6A 106.6(4) . . ?
Ge9A Ge8A Ge6A 67.5(4) . . ?
Ge7A Ge9A Rh1A 62.8(3) . . ?
Ge7A Ge9A Ge8A 96.2(4) . . ?
Rh1A Ge9A Ge8A 92.8(3) . . ?
C30 P1 C29 103.4(6) . . ?
C30 P1 C28 105.5(6) . . ?
C29 P1 C28 98.0(6) . . ?
C30 P1 Rh1 108.9(3) . . ?
C29 P1 Rh1 133.6(3) . . ?
C28 P1 Rh1 104.3(3) . . ?
C30 P1 Rh1A 129.9(4) . . ?
C29 P1 Rh1A 89.7(3) . . ?
C28 P1 Rh1A 120.4(3) . . ?
Si2 C1 H1A 109.5 . . ?
Si2 C1 H1B 109.5 . . ?
H1A C1 H1B 109.5 . . ?
Si2 C1 H1C 109.5 . . ?
H1A C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
Si2 C2 H2A 109.5 . . ?
Si2 C2 H2B 109.5 . . ?
H2A C2 H2B 109.5 . . ?
Si2 C2 H2C 109.5 . . ?
H2A C2 H2C 109.5 . . ?
H2B C2 H2C 109.5 . . ?
Si2 C3 H3A 109.5 . . ?
Si2 C3 H3B 109.5 . . ?
H3A C3 H3B 109.5 . . ?
Si2 C3 H3C 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
Si3 C4 H4A 109.5 . . ?
Si3 C4 H4B 109.5 . . ?
H4A C4 H4B 109.5 . . ?
Si3 C4 H4C 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
Si3 C5 H5A 109.5 . . ?
Si3 C5 H5B 109.5 . . ?
H5A C5 H5B 109.5 . . ?
Si3 C5 H5C 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
Si3 C6 H6A 109.5 . . ?
Si3 C6 H6B 109.5 . . ?
H6A C6 H6B 109.5 . . ?
Si3 C6 H6C 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
Si4 C7 H7A 109.5 . . ?
Si4 C7 H7B 109.5 . . ?
H7A C7 H7B 109.5 . . ?
Si4 C7 H7C 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
Si4 C8 H8A 109.5 . . ?
Si4 C8 H8B 109.5 . . ?
H8A C8 H8B 109.5 . . ?
Si4 C8 H8C 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
Si4 C9 H9A 109.5 . . ?
Si4 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
Si4 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
Si6 C10 H10A 109.5 . . ?
Si6 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
Si6 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
Si6 C11 H11A 109.5 . . ?
Si6 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
Si6 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
Si6 C12 H12A 109.5 . . ?
Si6 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
Si6 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
Si7 C13 H13A 109.5 . . ?
Si7 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
Si7 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
Si7 C14 H14A 109.5 . . ?
Si7 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
Si7 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
Si7 C15 H15A 109.5 . . ?
Si7 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
Si7 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
Si8 C16 H16A 109.5 . . ?
Si8 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
Si8 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
Si8 C17 H17A 109.5 . . ?
Si8 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
Si8 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
Si8 C18 H18A 109.5 . . ?
Si8 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
Si8 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
Si10 C19 H19A 109.5 . . ?
Si10 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
Si10 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
Si10 C20 H20A 109.5 . . ?
Si10 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
Si10 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
Si10 C21 H21A 109.5 . . ?
Si10 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
Si10 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
Si11 C22 H22A 109.5 . . ?
Si11 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
Si11 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
Si11 C23 H23A 109.5 . . ?
Si11 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
Si11 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
Si11 C24 H24A 109.5 . . ?
Si11 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
Si11 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
Si12 C25 H25A 109.5 . . ?
Si12 C25 H25B 109.5 . . ?
H25A C25 H25B 109.5 . . ?
Si12 C25 H25C 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
Si12 C26 H26A 109.5 . . ?
Si12 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
Si12 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
Si12 C27 H27A 109.5 . . ?
Si12 C27 H27B 109.5 . . ?
H27A C27 H27B 109.5 . . ?
Si12 C27 H27C 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
P1 C28 H28A 109.5 . . ?
P1 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
P1 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
P1 C29 H29A 109.5 . . ?
P1 C29 H29B 109.5 . . ?
H29A C29 H29B 109.5 . . ?
P1 C29 H29C 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
P1 C30 H30A 109.5 . . ?
P1 C30 H30B 109.5 . . ?
H30A C30 H30B 109.5 . . ?
P1 C30 H30C 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
Si4 Si1 Si2 109.64(8) . . ?
Si4 Si1 Si3 112.32(8) . . ?
Si2 Si1 Si3 109.74(7) . . ?
Si4 Si1 Ge1 110.93(15) . . ?
Si2 Si1 Ge1 107.46(15) . . ?
Si3 Si1 Ge1 106.60(14) . . ?
Si4 Si1 Ge7A 107.4(2) . . ?
Si2 Si1 Ge7A 104.8(2) . . ?
Si3 Si1 Ge7A 112.6(2) . . ?
C2 Si2 C1 108.9(4) . . ?
C2 Si2 C3 107.3(3) . . ?
C1 Si2 C3 110.0(4) . . ?
C2 Si2 Si1 109.9(2) . . ?
C1 Si2 Si1 110.7(3) . . ?
C3 Si2 Si1 110.0(2) . . ?
C4 Si3 C5 108.8(5) . . ?
C4 Si3 C6 110.1(5) . . ?
C5 Si3 C6 105.9(3) . . ?
C4 Si3 Si1 109.2(3) . . ?
C5 Si3 Si1 113.6(3) . . ?
C6 Si3 Si1 109.3(3) . . ?
C8 Si4 C9 109.6(5) . . ?
C8 Si4 C7 109.6(4) . . ?
C9 Si4 C7 107.0(4) . . ?
C8 Si4 Si1 110.8(2) . . ?
C9 Si4 Si1 110.2(3) . . ?
C7 Si4 Si1 109.5(2) . . ?
Ge8A Si5 Si6 108.3(3) . . ?
Ge8A Si5 Si7 108.8(3) . . ?
Si6 Si5 Si7 113.12(7) . . ?
Ge8A Si5 Si8 106.5(3) . . ?
Si6 Si5 Si8 109.53(6) . . ?
Si7 Si5 Si8 110.29(6) . . ?
Si6 Si5 Ge7 113.13(16) . . ?
Si7 Si5 Ge7 105.89(17) . . ?
Si8 Si5 Ge7 104.50(18) . . ?
C10 Si6 C11 112.2(5) . . ?
C10 Si6 C12 105.3(7) . . ?
C11 Si6 C12 104.7(4) . . ?
C10 Si6 Si5 112.0(3) . . ?
C11 Si6 Si5 113.1(2) . . ?
C12 Si6 Si5 108.9(3) . . ?
C14 Si7 C15 108.2(3) . . ?
C14 Si7 C13 109.0(2) . . ?
C15 Si7 C13 109.0(2) . . ?
C14 Si7 Si5 109.5(2) . . ?
C15 Si7 Si5 110.30(16) . . ?
C13 Si7 Si5 110.78(18) . . ?
C16 Si8 C17 108.9(3) . . ?
C16 Si8 C18 108.5(3) . . ?
C17 Si8 C18 109.3(2) . . ?
C16 Si8 Si5 110.84(16) . . ?
C17 Si8 Si5 109.91(17) . . ?
C18 Si8 Si5 109.43(19) . . ?
Si12 Si9 Si10 112.37(6) . . ?
Si12 Si9 Si11 110.80(6) . . ?
Si10 Si9 Si11 111.50(6) . . ?
Si12 Si9 Ge8 107.86(16) . . ?
Si10 Si9 Ge8 109.19(17) . . ?
Si11 Si9 Ge8 104.76(11) . . ?
Si12 Si9 Ge1A 103.9(3) . . ?
Si10 Si9 Ge1A 106.4(3) . . ?
Si11 Si9 Ge1A 111.54(18) . . ?
C20 Si10 C19 108.5(3) . . ?
C20 Si10 C21 108.1(3) . . ?
C19 Si10 C21 108.0(3) . . ?
C20 Si10 Si9 111.74(18) . . ?
C19 Si10 Si9 110.98(19) . . ?
C21 Si10 Si9 109.4(2) . . ?
C23 Si11 C22 108.7(4) . . ?
C23 Si11 C24 108.5(4) . . ?
C22 Si11 C24 107.0(3) . . ?
C23 Si11 Si9 110.6(2) . . ?
C22 Si11 Si9 110.8(2) . . ?
C24 Si11 Si9 111.1(2) . . ?
C27 Si12 C25 107.0(3) . . ?
C27 Si12 C26 109.5(4) . . ?
C25 Si12 C26 109.3(4) . . ?
C27 Si12 Si9 111.3(2) . . ?
C25 Si12 Si9 110.69(19) . . ?
C26 Si12 Si9 109.1(2) . . ?


_refine_diff_density_max         3.251
_refine_diff_density_min         -1.383
_refine_diff_density_rms         0.085



####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_OT502
_database_code_depnum_ccdc_archive 'CCDC 2155448'
loop_
_audit_author_name
_audit_author_address
'Jose Goicoechea'
;University of Oxford
United Kingdom
;
_audit_update_record             
;
2022-02-28 deposited with the CCDC.	2022-06-09 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/1
_shelx_SHELXL_version_number     2018/1
_chemical_name_systematic        
;
 [Ge9{Si(SiMe3)}3RhH(PPh3)][B{C6H3(CF3)2}4]*1.5hex
;
_contact_author_fax              '+44 1865 272690'
_chemical_name_common            .
_chemical_melting_point          .
_chemical_formula_moiety         
'C45 H97 Ge9 P Rh Si12, C32 H12 B F24, 1.5(C6 H14)'
_chemical_formula_sum            'C86 H130 B F24 Ge9 P Rh Si12'
_chemical_formula_weight         2754.97

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0090 0.0039 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.2541 0.3302 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge -1.0885 0.8855 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh 0.0927 3.6045 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   15.0839(2)
_cell_length_b                   19.3502(3)
_cell_length_c                   21.6497(4)
_cell_angle_alpha                106.3130(10)
_cell_angle_beta                 96.7570(10)
_cell_angle_gamma                92.7710(10)
_cell_volume                     6000.51(17)
_cell_formula_units_Z            2
_cell_measurement_temperature    150(2)
_cell_measurement_reflns_used    47612
_cell_measurement_theta_min      3.5990
_cell_measurement_theta_max      76.1460

_exptl_crystal_description       block
_exptl_crystal_colour            red
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    .
_exptl_crystal_density_diffrn    1.525
_exptl_crystal_F_000             2766
_exptl_transmission_factor_min   .
_exptl_transmission_factor_max   .
_exptl_crystal_size_max          0.240
_exptl_crystal_size_mid          0.180
_exptl_crystal_size_min          0.100
_exptl_absorpt_coefficient_mu    5.511
_shelx_estimated_absorpt_T_min   0.351
_shelx_estimated_absorpt_T_max   0.609
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.50882
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.41.81a (Rigaku Oxford Diffraction, 2020)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   .

_diffrn_ambient_temperature      150(2)
_diffrn_radiation_wavelength     1.54184
_diffrn_radiation_type           CuK\a
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'SuperNova (Cu) X-ray Source'
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at home/near, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_detector                 'CCD plate'
_diffrn_detector_type            Atlas
_diffrn_detector_area_resol_mean 10.4102
_diffrn_reflns_number            89656
_diffrn_reflns_av_unetI/netI     0.0331
_diffrn_reflns_av_R_equivalents  0.0439
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_theta_min         3.412
_diffrn_reflns_theta_max         76.187
_diffrn_reflns_theta_full        67.684
_diffrn_measured_fraction_theta_max 0.985
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.985
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.985
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             24711
_reflns_number_gt                21619
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'CrysAlisPro 1.171.41.81a (Rigaku OD, 2020)'
_computing_cell_refinement       'CrysAlisPro 1.171.41.81a (Rigaku OD, 2020)'
_computing_data_reduction        'CrysAlisPro 1.171.41.81a (Rigaku OD, 2020)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2018/1 (Sheldrick, 2018)'
_computing_molecular_graphics    .
_computing_publication_material  .
_refine_special_details          .

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0518P)²+2.0187P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     .
_atom_sites_solution_secondary   .
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         24711
_refine_ls_number_parameters     1332
_refine_ls_number_restraints     81
_refine_ls_R_factor_all          0.0402
_refine_ls_R_factor_gt           0.0344
_refine_ls_wR_factor_ref         0.0936
_refine_ls_wR_factor_gt          0.0894
_refine_ls_goodness_of_fit_ref   1.022
_refine_ls_restrained_S_all      1.201
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ge1 Ge 1.13916(6) 0.33582(5) 0.35596(4) 0.03495(10) Uani 0.9581(5) 1 d D . P A
1
Ge2 Ge 1.05428(6) 0.45037(4) 0.37679(4) 0.03525(11) Uani 0.9581(5) 1 d D . P A
1
Ge3 Ge 1.10167(2) 0.35810(2) 0.24869(2) 0.03201(7) Uani 0.9581(5) 1 d D . P A 1
Ge4 Ge 1.02241(2) 0.23709(2) 0.29577(2) 0.03101(7) Uani 0.9581(5) 1 d D . P A 1
Ge5 Ge 1.01698(6) 0.34967(3) 0.43369(3) 0.03881(12) Uani 0.9581(5) 1 d D . P A
1
Ge6 Ge 0.88349(7) 0.40213(5) 0.37436(5) 0.03584(9) Uani 0.9581(5) 1 d D . P A 1
Ge7 Ge 0.94612(3) 0.40070(3) 0.26585(3) 0.03003(10) Uani 0.9581(5) 1 d D . P A
1
Ge8 Ge 0.88877(3) 0.26333(3) 0.35079(2) 0.03300(10) Uani 0.9581(5) 1 d D . P A
1
Ge9 Ge 0.84156(3) 0.28478(2) 0.24321(2) 0.03167(9) Uani 0.9581(5) 1 d D . P A 1
Rh1 Rh 0.97988(2) 0.26803(2) 0.19889(2) 0.02739(5) Uani 0.9581(5) 1 d D . P A 1
Ge1A Ge 0.9303(10) 0.3962(8) 0.2624(9) 0.03003(10) Uani 0.0419(5) 1 d D . P A 2
Ge2A Ge 0.8804(15) 0.4053(11) 0.3731(11) 0.03584(9) Uani 0.0419(5) 1 d D . P A
2
Ge3A Ge 0.8507(7) 0.2674(6) 0.2448(6) 0.03167(9) Uani 0.0419(5) 1 d D . P A 2
Ge4A Ge 1.0555(4) 0.3229(4) 0.2551(3) 0.03201(7) Uani 0.0419(5) 1 d D . P A 2
Ge5A Ge 1.0466(15) 0.4519(9) 0.3695(11) 0.03525(11) Uani 0.0419(5) 1 d D . P A
2
Ge6A Ge 1.0211(14) 0.3628(10) 0.4395(7) 0.03881(12) Uani 0.0419(5) 1 d D . P A
2
Ge7A Ge 0.9031(9) 0.2698(8) 0.3601(5) 0.03300(10) Uani 0.0419(5) 1 d D . P A 2
Ge8A Ge 1.1391(12) 0.3367(11) 0.3620(10) 0.03495(10) Uani 0.0419(5) 1 d D . P A
2
Ge9A Ge 1.0514(4) 0.2138(4) 0.3328(3) 0.03101(7) Uani 0.0419(5) 1 d D . P A 2
Rh1A Rh 0.9672(3) 0.2173(2) 0.2382(2) 0.0358(11) Uani 0.0419(5) 1 d D . P A 2
P1 P 0.99907(4) 0.15891(3) 0.12451(3) 0.02993(12) Uani 1 1 d D . . . .
Si1 Si 1.29317(4) 0.33084(4) 0.39256(4) 0.03288(14) Uani 1 1 d . . . . .
Si2 Si 1.36715(5) 0.42116(4) 0.35794(5) 0.04408(18) Uani 1 1 d . . . . .
Si3 Si 1.32236(6) 0.21392(4) 0.33472(5) 0.0499(2) Uani 1 1 d . . . . .
Si4 Si 1.31238(6) 0.35612(6) 0.50567(4) 0.0549(2) Uani 1 1 d . . . . .
C1 C 1.4902(3) 0.4243(3) 0.3828(4) 0.108(2) Uani 1 1 d . . . . .
H1A H 1.512067 0.378068 0.360949 0.163 Uiso 1 1 calc R U . . .
H1B H 1.502449 0.433195 0.429945 0.163 Uiso 1 1 calc R U . . .
H1C H 1.520743 0.463299 0.370498 0.163 Uiso 1 1 calc R U . . .
C2 C 1.3484(4) 0.4040(3) 0.2683(2) 0.0868(15) Uani 1 1 d . . . . .
H2A H 1.387465 0.438542 0.256120 0.130 Uiso 1 1 calc R U . . .
H2B H 1.285640 0.409881 0.254436 0.130 Uiso 1 1 calc R U . . .
H2C H 1.362067 0.354703 0.247096 0.130 Uiso 1 1 calc R U . . .
C3 C 1.3266(4) 0.5109(2) 0.3962(3) 0.0867(16) Uani 1 1 d . . . . .
H3A H 1.361088 0.548753 0.384898 0.130 Uiso 1 1 calc R U . . .
H3B H 1.334502 0.520403 0.443504 0.130 Uiso 1 1 calc R U . . .
H3C H 1.263007 0.510621 0.380254 0.130 Uiso 1 1 calc R U . . .
C4 C 1.4415(3) 0.2025(3) 0.3575(4) 0.149(4) Uani 1 1 d . . . . .
H4A H 1.451890 0.204030 0.403449 0.223 Uiso 1 1 calc R U . . .
H4B H 1.479146 0.241516 0.350456 0.223 Uiso 1 1 calc R U . . .
H4C H 1.456634 0.155820 0.330744 0.223 Uiso 1 1 calc R U . . .
C5 C 1.2518(3) 0.1435(2) 0.3531(3) 0.0754(13) Uani 1 1 d . . . . .
H5A H 1.263614 0.095749 0.326382 0.113 Uiso 1 1 calc R U . . .
H5B H 1.188463 0.151041 0.343575 0.113 Uiso 1 1 calc R U . . .
H5C H 1.265854 0.146348 0.399179 0.113 Uiso 1 1 calc R U . . .
C6 C 1.2933(5) 0.2045(2) 0.2458(2) 0.0981(18) Uani 1 1 d . . . . .
H6A H 1.339871 0.231293 0.231612 0.147 Uiso 1 1 calc R U . . .
H6B H 1.235554 0.224041 0.238349 0.147 Uiso 1 1 calc R U . . .
H6C H 1.289352 0.153352 0.220996 0.147 Uiso 1 1 calc R U . . .
C7 C 1.4341(3) 0.3542(5) 0.5331(2) 0.123(3) Uani 1 1 d . . . . .
H7A H 1.445489 0.370787 0.580662 0.185 Uiso 1 1 calc R U . . .
H7B H 1.469317 0.386124 0.515359 0.185 Uiso 1 1 calc R U . . .
H7C H 1.451336 0.304755 0.517658 0.185 Uiso 1 1 calc R U . . .
C8 C 1.2458(4) 0.2873(3) 0.5299(3) 0.0933(16) Uani 1 1 d . . . . .
H8A H 1.258919 0.238848 0.505552 0.140 Uiso 1 1 calc R U . . .
H8B H 1.181838 0.292765 0.520482 0.140 Uiso 1 1 calc R U . . .
H8C H 1.261594 0.293886 0.576568 0.140 Uiso 1 1 calc R U . . .
C9 C 1.2741(5) 0.4483(3) 0.5419(2) 0.1019(19) Uani 1 1 d . . . . .
H9A H 1.211284 0.449263 0.524566 0.153 Uiso 1 1 calc R U . . .
H9B H 1.311162 0.484759 0.530670 0.153 Uiso 1 1 calc R U . . .
H9C H 1.279877 0.458710 0.589233 0.153 Uiso 1 1 calc R U . . .
Si5 Si 0.91345(5) 0.48292(4) 0.20376(3) 0.03260(14) Uani 1 1 d . . . . .
Si6 Si 0.96277(5) 0.43501(4) 0.10234(4) 0.03580(15) Uani 1 1 d . . . . .
Si7 Si 0.75773(6) 0.48962(6) 0.18847(5) 0.0567(2) Uani 1 1 d . . . . .
Si8 Si 0.99589(7) 0.59192(4) 0.26357(5) 0.0544(2) Uani 1 1 d . . . . .
Si9 Si 0.81305(5) 0.18504(4) 0.39907(4) 0.03292(14) Uani 1 1 d . . . . .
C10 C 0.9290(3) 0.33566(16) 0.07199(16) 0.0503(7) Uani 1 1 d . . . . .
H10A H 0.958456 0.311550 0.102024 0.076 Uiso 1 1 calc R U . . .
H10B H 0.863851 0.327376 0.069200 0.076 Uiso 1 1 calc R U . . .
H10C H 0.947010 0.316051 0.028859 0.076 Uiso 1 1 calc R U . . .
C11 C 0.9075(2) 0.48262(18) 0.04591(16) 0.0509(7) Uani 1 1 d . . . . .
H11A H 0.926567 0.534395 0.062091 0.076 Uiso 1 1 calc R U . . .
H11B H 0.842282 0.475446 0.043565 0.076 Uiso 1 1 calc R U . . .
H11C H 0.924682 0.462954 0.002522 0.076 Uiso 1 1 calc R U . . .
C12 C 1.0876(2) 0.4480(2) 0.10593(18) 0.0530(8) Uani 1 1 d . . . . .
H12A H 1.104559 0.424870 0.063080 0.080 Uiso 1 1 calc R U . . .
H12B H 1.116810 0.426227 0.137860 0.080 Uiso 1 1 calc R U . . .
H12C H 1.106575 0.499820 0.118721 0.080 Uiso 1 1 calc R U . . .
C13 C 0.7056(3) 0.4104(3) 0.1193(3) 0.0849(15) Uani 1 1 d . . . . .
H13A H 0.715007 0.365586 0.130851 0.127 Uiso 1 1 calc R U . . .
H13B H 0.733445 0.409550 0.080460 0.127 Uiso 1 1 calc R U . . .
H13C H 0.641226 0.414829 0.110601 0.127 Uiso 1 1 calc R U . . .
C14 C 0.7103(3) 0.4862(4) 0.2638(3) 0.110(2) Uani 1 1 d . . . . .
H14A H 0.644944 0.486602 0.256422 0.166 Uiso 1 1 calc R U . . .
H14B H 0.735350 0.528360 0.299833 0.166 Uiso 1 1 calc R U . . .
H14C H 0.725628 0.441936 0.274503 0.166 Uiso 1 1 calc R U . . .
C15 C 0.7320(3) 0.5759(3) 0.1688(2) 0.0736(12) Uani 1 1 d . . . . .
H15A H 0.667128 0.576052 0.158059 0.110 Uiso 1 1 calc R U . . .
H15B H 0.761565 0.579249 0.131703 0.110 Uiso 1 1 calc R U . . .
H15C H 0.754054 0.617199 0.206558 0.110 Uiso 1 1 calc R U . . .
C16 C 1.1186(3) 0.5804(2) 0.27921(19) 0.0602(9) Uani 1 1 d . . . . .
H16A H 1.151239 0.627459 0.301624 0.090 Uiso 1 1 calc R U . . .
H16B H 1.141027 0.559811 0.237794 0.090 Uiso 1 1 calc R U . . .
H16C H 1.127630 0.547752 0.306384 0.090 Uiso 1 1 calc R U . . .
C17 C 0.9504(4) 0.6284(3) 0.3415(2) 0.0961(19) Uani 1 1 d . . . . .
H17A H 0.979792 0.676618 0.364151 0.144 Uiso 1 1 calc R U . . .
H17B H 0.961613 0.596203 0.368851 0.144 Uiso 1 1 calc R U . . .
H17C H 0.885690 0.631503 0.332551 0.144 Uiso 1 1 calc R U . . .
C18 C 0.9843(4) 0.6557(2) 0.2125(3) 0.0915(18) Uani 1 1 d . . . . .
H18A H 0.921085 0.664447 0.204463 0.137 Uiso 1 1 calc R U . . .
H18B H 1.006170 0.634500 0.171052 0.137 Uiso 1 1 calc R U . . .
H18C H 1.019486 0.701571 0.235454 0.137 Uiso 1 1 calc R U . . .
Si10 Si 0.91904(6) 0.12229(5) 0.44622(5) 0.04662(19) Uani 1 1 d . . . . .
Si11 Si 0.71394(6) 0.10731(5) 0.31203(5) 0.04640(18) Uani 1 1 d . . . . .
Si12 Si 0.73810(6) 0.26396(5) 0.47508(4) 0.04841(19) Uani 1 1 d . . . . .
C19 C 0.9908(4) 0.0737(4) 0.3871(3) 0.125(3) Uani 1 1 d . . . . .
H19A H 1.029441 0.108876 0.375361 0.187 Uiso 1 1 calc R U . . .
H19B H 0.952848 0.043538 0.348011 0.187 Uiso 1 1 calc R U . . .
H19C H 1.027911 0.043154 0.406640 0.187 Uiso 1 1 calc R U . . .
C20 C 0.8563(3) 0.0529(2) 0.4729(2) 0.0718(11) Uani 1 1 d . . . . .
H20A H 0.821499 0.017917 0.434886 0.108 Uiso 1 1 calc R U . . .
H20B H 0.815648 0.076429 0.502890 0.108 Uiso 1 1 calc R U . . .
H20C H 0.898702 0.027731 0.494834 0.108 Uiso 1 1 calc R U . . .
C21 C 0.9902(4) 0.1840(3) 0.5174(3) 0.126(3) Uani 1 1 d . . . . .
H21A H 1.031835 0.156315 0.537071 0.190 Uiso 1 1 calc R U . . .
H21B H 0.952364 0.208310 0.549321 0.190 Uiso 1 1 calc R U . . .
H21C H 1.024220 0.220191 0.503649 0.190 Uiso 1 1 calc R U . . .
C22 C 0.6469(3) 0.1593(2) 0.2655(2) 0.0636(10) Uani 1 1 d . . . . .
H22A H 0.686049 0.180926 0.241623 0.095 Uiso 1 1 calc R U . . .
H22B H 0.620025 0.197662 0.295721 0.095 Uiso 1 1 calc R U . . .
H22C H 0.599437 0.126809 0.234832 0.095 Uiso 1 1 calc R U . . .
C23 C 0.6349(3) 0.0525(3) 0.3440(3) 0.0886(17) Uani 1 1 d . . . . .
H23A H 0.596336 0.084549 0.370272 0.133 Uiso 1 1 calc R U . . .
H23B H 0.669188 0.027225 0.370915 0.133 Uiso 1 1 calc R U . . .
H23C H 0.597794 0.017123 0.307553 0.133 Uiso 1 1 calc R U . . .
C24 C 0.7807(4) 0.0453(3) 0.2570(3) 0.103(2) Uani 1 1 d . . . . .
H24A H 0.740113 0.010938 0.221911 0.154 Uiso 1 1 calc R U . . .
H24B H 0.816977 0.018763 0.281672 0.154 Uiso 1 1 calc R U . . .
H24C H 0.820097 0.073451 0.238421 0.154 Uiso 1 1 calc R U . . .
C25 C 0.6707(2) 0.3215(2) 0.4349(2) 0.0576(9) Uani 1 1 d . . . . .
H25A H 0.633670 0.349740 0.465436 0.086 Uiso 1 1 calc R U . . .
H25B H 0.632035 0.290683 0.396566 0.086 Uiso 1 1 calc R U . . .
H25C H 0.711017 0.354321 0.421735 0.086 Uiso 1 1 calc R U . . .
C26 C 0.6590(4) 0.2090(4) 0.5074(3) 0.111(2) Uani 1 1 d . . . . .
H26A H 0.692911 0.177455 0.527946 0.166 Uiso 1 1 calc R U . . .
H26B H 0.615116 0.179439 0.471586 0.166 Uiso 1 1 calc R U . . .
H26C H 0.627792 0.241425 0.539563 0.166 Uiso 1 1 calc R U . . .
C27 C 0.8183(4) 0.3239(4) 0.5420(2) 0.118(3) Uani 1 1 d . . . . .
H27A H 0.857067 0.353718 0.524559 0.177 Uiso 1 1 calc R U . . .
H27B H 0.854990 0.294575 0.563398 0.177 Uiso 1 1 calc R U . . .
H27C H 0.785266 0.355234 0.573674 0.177 Uiso 1 1 calc R U . . .
C28 C 0.91229(17) 0.14660(13) 0.05527(13) 0.0327(5) Uani 1 1 d . . . . .
C29 C 0.82379(18) 0.15649(15) 0.06667(14) 0.0387(6) Uani 1 1 d . . . . .
H29 H 0.809413 0.166019 0.109669 0.046 Uiso 1 1 calc R U . . .
C30 C 0.75701(19) 0.15253(16) 0.01591(16) 0.0436(6) Uani 1 1 d . . . . .
H30 H 0.696955 0.158791 0.024045 0.052 Uiso 1 1 calc R U . . .
C31 C 0.7777(2) 0.13947(18) -0.04660(16) 0.0499(7) Uani 1 1 d . . . . .
H31 H 0.732041 0.137444 -0.081426 0.060 Uiso 1 1 calc R U . . .
C32 C 0.8652(2) 0.1293(2) -0.05843(16) 0.0528(8) Uani 1 1 d . . . . .
H32 H 0.879260 0.120256 -0.101491 0.063 Uiso 1 1 calc R U . . .
C33 C 0.9323(2) 0.13228(16) -0.00816(14) 0.0416(6) Uani 1 1 d . . . . .
H33 H 0.991897 0.124573 -0.016802 0.050 Uiso 1 1 calc R U . . .
C34 C 0.99139(18) 0.07463(14) 0.14645(13) 0.0348(5) Uani 1 1 d . . . . .
C35 C 0.9181(2) 0.02393(15) 0.12289(17) 0.0439(6) Uani 1 1 d . . . . .
H35 H 0.870522 0.031668 0.093359 0.053 Uiso 1 1 calc R U . . .
C36 C 0.9150(3) -0.03869(18) 0.1430(2) 0.0574(9) Uani 1 1 d . . . . .
H36 H 0.864562 -0.073270 0.127654 0.069 Uiso 1 1 calc R U . . .
C37 C 0.9843(3) -0.05039(18) 0.1849(2) 0.0591(9) Uani 1 1 d . . . . .
H37 H 0.981471 -0.093182 0.198150 0.071 Uiso 1 1 calc R U . . .
C38 C 1.0579(3) -0.00093(17) 0.20797(17) 0.0519(8) Uani 1 1 d . . . . .
H38 H 1.105563 -0.009554 0.236941 0.062 Uiso 1 1 calc R U . . .
C39 C 1.0620(2) 0.06185(15) 0.18856(15) 0.0432(6) Uani 1 1 d . . . . .
H39 H 1.112839 0.095972 0.203972 0.052 Uiso 1 1 calc R U . . .
C40 C 1.10593(17) 0.15625(15) 0.09265(13) 0.0357(5) Uani 1 1 d . . . . .
C41 C 1.1567(2) 0.21980(17) 0.09751(15) 0.0431(6) Uani 1 1 d . . . . .
H41 H 1.134093 0.265165 0.114997 0.052 Uiso 1 1 calc R U . . .
C42 C 1.2410(2) 0.2170(2) 0.07667(17) 0.0538(8) Uani 1 1 d . . . . .
H42 H 1.275746 0.260634 0.080403 0.065 Uiso 1 1 calc R U . . .
C43 C 1.2737(2) 0.1521(2) 0.05096(17) 0.0545(8) Uani 1 1 d . . . . .
H43 H 1.331573 0.150634 0.037647 0.065 Uiso 1 1 calc R U . . .
C44 C 1.2225(2) 0.0882(2) 0.04428(19) 0.0571(8) Uani 1 1 d . . . . .
H44 H 1.244974 0.043126 0.025572 0.068 Uiso 1 1 calc R U . . .
C45 C 1.1390(2) 0.08996(18) 0.06474(17) 0.0473(7) Uani 1 1 d . . . . .
H45 H 1.104103 0.046098 0.059852 0.057 Uiso 1 1 calc R U . . .
B101 B 0.44443(19) 0.22948(15) 0.89122(14) 0.0302(5) Uani 1 1 d . . . . .
C101 C 0.33936(18) 0.22135(13) 0.85759(13) 0.0325(5) Uani 1 1 d . . . . .
C102 C 0.31636(19) 0.19251(14) 0.79015(14) 0.0362(5) Uani 1 1 d . . . . .
H102 H 0.362519 0.177776 0.764219 0.043 Uiso 1 1 calc R U . . .
C103 C 0.22831(19) 0.18474(15) 0.75993(14) 0.0376(6) Uani 1 1 d . . . . .
C104 C 0.15843(18) 0.20317(15) 0.79623(15) 0.0376(6) Uani 1 1 d . . . . .
H104 H 0.098216 0.197773 0.775755 0.045 Uiso 1 1 calc R U . . .
C105 C 0.17895(18) 0.22953(14) 0.86284(14) 0.0347(5) Uani 1 1 d . . . . .
C106 C 0.26764(17) 0.23861(13) 0.89292(13) 0.0329(5) Uani 1 1 d . . . . .
H106 H 0.279565 0.257127 0.938889 0.039 Uiso 1 1 calc R U . . .
C107 C 0.2084(2) 0.1578(2) 0.68723(17) 0.0541(8) Uani 1 1 d . . . . .
C108 C 0.1067(2) 0.25025(17) 0.90473(16) 0.0438(6) Uani 1 1 d . . . . .
C109 C 0.51101(17) 0.27540(13) 0.85972(13) 0.0321(5) Uani 1 1 d . . . . .
C110 C 0.60286(18) 0.28440(14) 0.88253(14) 0.0356(5) Uani 1 1 d . . . . .
H110 H 0.624071 0.264832 0.916592 0.043 Uiso 1 1 calc R U . . .
C111 C 0.66398(19) 0.32088(15) 0.85715(15) 0.0402(6) Uani 1 1 d . . . . .
C112 C 0.6358(2) 0.35173(16) 0.80867(16) 0.0457(7) Uani 1 1 d . . . . .
H112 H 0.677617 0.376089 0.790738 0.055 Uiso 1 1 calc R U . . .
C113 C 0.5456(2) 0.34618(17) 0.78710(17) 0.0471(7) Uani 1 1 d . . . . .
C114 C 0.4842(2) 0.30856(15) 0.81185(15) 0.0396(6) Uani 1 1 d . . . . .
H114 H 0.422315 0.305401 0.795664 0.047 Uiso 1 1 calc R U . . .
C115 C 0.7616(2) 0.3248(2) 0.8818(2) 0.0564(9) Uani 1 1 d . . . . .
C116 C 0.5128(3) 0.3818(3) 0.7366(3) 0.0778(14) Uani 1 1 d . . . . .
C117 C 0.45302(16) 0.27462(13) 0.96861(13) 0.0320(5) Uani 1 1 d . . . . .
C118 C 0.42514(19) 0.34515(14) 0.98460(15) 0.0383(6) Uani 1 1 d . . . . .
H118 H 0.404145 0.364797 0.950547 0.046 Uiso 1 1 calc R U . . .
C119 C 0.4273(2) 0.38660(15) 1.04809(16) 0.0426(6) Uani 1 1 d . . . . .
C120 C 0.46008(19) 0.36140(15) 1.09973(15) 0.0406(6) Uani 1 1 d . . . . .
H120 H 0.461382 0.390049 1.143422 0.049 Uiso 1 1 calc R U . . .
C121 C 0.49071(17) 0.29326(15) 1.08542(14) 0.0353(5) Uani 1 1 d . . . . .
C122 C 0.48610(16) 0.25041(13) 1.02091(13) 0.0322(5) Uani 1 1 d . . . . .
H122 H 0.506190 0.203303 1.012599 0.039 Uiso 1 1 calc R U . . .
C123 C 0.3962(3) 0.46183(19) 1.0628(2) 0.0618(10) Uani 1 1 d . . . . .
C124 C 0.5285(2) 0.26390(17) 1.13910(15) 0.0447(6) Uani 1 1 d . . . . .
C125 C 0.47323(16) 0.14624(13) 0.88063(12) 0.0297(5) Uani 1 1 d . . . . .
C126 C 0.42572(17) 0.09896(14) 0.90564(13) 0.0327(5) Uani 1 1 d . . . . .
H126 H 0.377249 0.115737 0.928491 0.039 Uiso 1 1 calc R U . . .
C127 C 0.44682(18) 0.02820(13) 0.89828(13) 0.0335(5) Uani 1 1 d . . . . .
C128 C 0.51605(18) 0.00117(13) 0.86457(14) 0.0352(5) Uani 1 1 d . . . . .
H128 H 0.531457 -0.046834 0.860204 0.042 Uiso 1 1 calc R U . . .
C129 C 0.56225(18) 0.04633(14) 0.83736(13) 0.0343(5) Uani 1 1 d . . . . .
C130 C 0.54126(17) 0.11724(13) 0.84519(13) 0.0320(5) Uani 1 1 d . . . . .
H130 H 0.574095 0.146809 0.825904 0.038 Uiso 1 1 calc R U . . .
C131 C 0.3938(2) -0.01803(15) 0.92824(16) 0.0426(6) Uani 1 1 d . . . . .
C132 C 0.6353(2) 0.01724(16) 0.79875(17) 0.0460(7) Uani 1 1 d . . . . .
F101 F 0.10931(15) 0.21695(15) 0.95131(12) 0.0699(6) Uani 1 1 d . . . . .
F102 F 0.02416(12) 0.23366(11) 0.87187(11) 0.0548(5) Uani 1 1 d . . . . .
F103 F 0.11303(15) 0.32106(12) 0.93472(12) 0.0664(6) Uani 1 1 d . . . . .
F104 F 0.1268(6) 0.1333(12) 0.6651(5) 0.133(6) Uani 0.59(3) 1 d . . P B 1
F105 F 0.2282(16) 0.2089(6) 0.6604(4) 0.116(5) Uani 0.59(3) 1 d . . P B 1
F106 F 0.2592(9) 0.1080(6) 0.6624(5) 0.097(4) Uani 0.59(3) 1 d . . P B 1
F4A F 0.1437(14) 0.1046(9) 0.6697(8) 0.116(6) Uani 0.41(3) 1 d . . P B 2
F5A F 0.1705(18) 0.2055(10) 0.6634(6) 0.104(6) Uani 0.41(3) 1 d . . P B 2
F6A F 0.2727(9) 0.1358(17) 0.6570(7) 0.121(8) Uani 0.41(3) 1 d . . P B 2
F107 F 0.7976(6) 0.2647(6) 0.8537(5) 0.098(3) Uani 0.64(3) 1 d . . P C 1
F108 F 0.8091(8) 0.3795(6) 0.8753(7) 0.095(4) Uani 0.64(3) 1 d . . P C 1
F109 F 0.7785(5) 0.3296(5) 0.9450(4) 0.080(2) Uani 0.64(3) 1 d . . P C 1
F7A F 0.7923(11) 0.2659(10) 0.8776(18) 0.127(9) Uani 0.36(3) 1 d . . P C 2
F8A F 0.8123(13) 0.353(2) 0.8469(19) 0.124(9) Uani 0.36(3) 1 d . . P C 2
F9A F 0.7801(13) 0.364(3) 0.9391(13) 0.180(14) Uani 0.36(3) 1 d . . P C 2
F110 F 0.4331(2) 0.35588(19) 0.70489(15) 0.0994(11) Uani 1 1 d . . . . .
F111 F 0.5681(2) 0.3820(3) 0.6951(2) 0.1391(18) Uani 1 1 d . . . . .
F112 F 0.5019(2) 0.45289(17) 0.7640(2) 0.1202(14) Uani 1 1 d . . . . .
F113 F 0.3498(3) 0.47446(17) 1.01284(16) 0.1408(19) Uani 1 1 d . . . . .
F114 F 0.3472(2) 0.47530(13) 1.11092(16) 0.0920(9) Uani 1 1 d . . . . .
F115 F 0.4641(2) 0.51250(12) 1.08144(19) 0.1048(11) Uani 1 1 d . . . . .
F116 F 0.47834(15) 0.20588(13) 1.14198(12) 0.0657(6) Uani 1 1 d . . . . .
F117 F 0.5377(2) 0.31166(14) 1.19744(10) 0.0803(8) Uani 1 1 d . . . . .
F118 F 0.60944(13) 0.24060(11) 1.13099(10) 0.0553(5) Uani 1 1 d . . . . .
F119 F 0.4212(2) -0.08405(11) 0.91867(15) 0.0850(9) Uani 1 1 d . . . . .
F120 F 0.30648(15) -0.02375(15) 0.90644(13) 0.0787(8) Uani 1 1 d . . . . .
F121 F 0.39888(13) 0.00943(11) 0.99223(10) 0.0521(4) Uani 1 1 d . . . . .
F122 F 0.68618(18) -0.02378(14) 0.82622(15) 0.0830(8) Uani 1 1 d . . . . .
F123 F 0.69304(13) 0.06831(11) 0.79250(11) 0.0577(5) Uani 1 1 d . . . . .
F124 F 0.60346(18) -0.02300(15) 0.73912(13) 0.0893(9) Uani 1 1 d . . . . .
C1S C 0.4901(9) 0.1481(11) 0.6385(12) 0.394(17) Uani 1 1 d D . . . .
H1S1 H 0.446412 0.183543 0.650960 0.590 Uiso 1 1 calc R U . . .
H1S2 H 0.488178 0.133359 0.591154 0.590 Uiso 1 1 calc R U . . .
H1S3 H 0.475552 0.105657 0.652868 0.590 Uiso 1 1 calc R U . . .
C2S C 0.5791(11) 0.1800(6) 0.6688(7) 0.320(14) Uani 1 1 d D . . . .
H2S1 H 0.580930 0.195524 0.716598 0.384 Uiso 1 1 calc R U . . .
H2S2 H 0.593576 0.223268 0.654790 0.384 Uiso 1 1 calc R U . . .
C3S C 0.6465(9) 0.1274(6) 0.6507(6) 0.207(7) Uani 1 1 d D . . . .
H3S1 H 0.642183 0.109744 0.602795 0.248 Uiso 1 1 calc R U . . .
H3S2 H 0.634089 0.085493 0.666994 0.248 Uiso 1 1 calc R U . . .
C4S C 0.7416(10) 0.1623(7) 0.6794(6) 0.306(15) Uani 1 1 d D . . . .
H4S1 H 0.757438 0.199650 0.658343 0.367 Uiso 1 1 calc R U . . .
H4S2 H 0.743762 0.186135 0.726472 0.367 Uiso 1 1 calc R U . . .
C5S C 0.8049(9) 0.1088(7) 0.6694(6) 0.227(7) Uani 1 1 d D . . . .
H5S1 H 0.795197 0.080580 0.622996 0.273 Uiso 1 1 calc R U . . .
H5S2 H 0.792086 0.075225 0.694937 0.273 Uiso 1 1 calc R U . . .
C6S C 0.9014(9) 0.1366(6) 0.6873(5) 0.240(8) Uani 1 1 d D . . . .
H6S1 H 0.938806 0.095827 0.678693 0.359 Uiso 1 1 calc R U . . .
H6S2 H 0.915839 0.168704 0.661432 0.359 Uiso 1 1 calc R U . . .
H6S3 H 0.912719 0.163334 0.733584 0.359 Uiso 1 1 calc R U . . .
C3T C 0.4727(11) 0.0252(16) 0.4844(16) 0.438(13) Uani 1 1 d D U . . .
H3T1 H 0.501868 0.075039 0.498904 0.526 Uiso 1 1 calc R U . . .
H3T2 H 0.466462 0.007412 0.436420 0.526 Uiso 1 1 calc R U . . .
C1T C 0.3212(11) 0.0721(11) 0.4828(11) 0.410(13) Uani 1 1 d D U . . .
H1T1 H 0.262730 0.070337 0.498113 0.616 Uiso 1 1 calc R U . . .
H1T2 H 0.349294 0.121740 0.498525 0.616 Uiso 1 1 calc R U . . .
H1T3 H 0.313031 0.056393 0.435185 0.616 Uiso 1 1 calc R U . . .
C2T C 0.3807(10) 0.0225(12) 0.5084(13) 0.383(11) Uani 1 1 d D U . . .
H2T1 H 0.352198 -0.027627 0.493031 0.460 Uiso 1 1 calc R U . . .
H2T2 H 0.388545 0.037871 0.556517 0.460 Uiso 1 1 calc R U . . .
H1 H 0.9571(6) 0.2943(4) 0.1555(3) 0.575 Uiso 0.9581(5) 1 d D U P A 1
H2 H 0.9322(8) 0.1542(5) 0.2375(4) 0.575 Uiso 0.0419(5) 1 d D U P A 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ge1 Si1 2.3803(10) . ?
Ge1 Ge3 2.4850(9) . ?
Ge1 Ge4 2.4870(8) . ?
Ge1 Ge2 2.5698(8) . ?
Ge1 Ge5 2.6124(9) . ?
Ge2 Ge7 2.6427(7) . ?
Ge2 Ge5 2.6526(8) . ?
Ge2 Ge6 2.6868(9) . ?
Ge3 Rh1 2.3965(3) . ?
Ge3 Ge7 2.5578(6) . ?
Ge4 Rh1 2.3653(4) . ?
Ge4 Ge8 2.4626(6) . ?
Ge5 Ge8 2.6342(7) . ?
Ge5 Ge6 2.6564(8) . ?
Ge6 Ge8 2.5963(8) . ?
Ge6 Ge7 2.6269(9) . ?
Ge7 Si5 2.3877(9) . ?
Ge7 Ge9 2.5724(6) . ?
Ge7 Rh1 2.6759(7) . ?
Ge8 Si9 2.3864(9) . ?
Ge8 Ge9 2.5070(6) . ?
Ge9 Rh1 2.3959(5) . ?
Rh1 P1 2.3225(6) . ?
Rh1 H1 1.211(8) . ?
Ge1A Si5 2.377(16) . ?
Ge1A Ge4A 2.410(15) . ?
Ge1A Ge2A 2.558(18) . ?
Ge1A Ge3A 2.621(15) . ?
Ge1A Ge5A 2.659(17) . ?
Ge2A Ge7A 2.601(17) . ?
Ge2A Ge5A 2.640(18) . ?
Ge2A Ge6A 2.714(18) . ?
Ge3A Rh1A 2.048(10) . ?
Ge3A Ge7A 2.515(14) . ?
Ge4A Rh1A 2.298(8) . ?
Ge4A Ge8A 2.439(17) . ?
Ge5A Ge6A 2.637(18) . ?
Ge5A Ge8A 2.662(18) . ?
Ge6A Ge8A 2.560(18) . ?
Ge6A Ge7A 2.568(16) . ?
Ge7A Si9 2.465(15) . ?
Ge7A Ge9A 2.591(13) . ?
Ge7A Rh1A 2.850(11) . ?
Ge8A Si1 2.357(18) . ?
Ge8A Ge9A 2.543(17) . ?
Ge9A Rh1A 2.300(7) . ?
Rh1A P1 2.517(5) . ?
Rh1A H2 1.302(8) . ?
P1 C28 1.823(3) . ?
P1 C40 1.824(3) . ?
P1 C34 1.824(3) . ?
Si1 Si4 2.3380(12) . ?
Si1 Si3 2.3484(10) . ?
Si1 Si2 2.3676(11) . ?
Si2 C2 1.859(5) . ?
Si2 C1 1.864(4) . ?
Si2 C3 1.868(4) . ?
Si3 C4 1.847(4) . ?
Si3 C5 1.848(4) . ?
Si3 C6 1.879(5) . ?
Si4 C8 1.856(5) . ?
Si4 C7 1.867(4) . ?
Si4 C9 1.884(5) . ?
C1 H1A 0.9800 . ?
C1 H1B 0.9800 . ?
C1 H1C 0.9800 . ?
C2 H2A 0.9800 . ?
C2 H2B 0.9800 . ?
C2 H2C 0.9800 . ?
C3 H3A 0.9800 . ?
C3 H3B 0.9800 . ?
C3 H3C 0.9800 . ?
C4 H4A 0.9800 . ?
C4 H4B 0.9800 . ?
C4 H4C 0.9800 . ?
C5 H5A 0.9800 . ?
C5 H5B 0.9800 . ?
C5 H5C 0.9800 . ?
C6 H6A 0.9800 . ?
C6 H6B 0.9800 . ?
C6 H6C 0.9800 . ?
C7 H7A 0.9800 . ?
C7 H7B 0.9800 . ?
C7 H7C 0.9800 . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
Si5 Si8 2.3463(11) . ?
Si5 Si7 2.3482(11) . ?
Si5 Si6 2.3541(11) . ?
Si6 C10 1.872(3) . ?
Si6 C11 1.872(3) . ?
Si6 C12 1.877(3) . ?
Si7 C14 1.872(5) . ?
Si7 C13 1.877(5) . ?
Si7 C15 1.881(4) . ?
Si8 C17 1.862(5) . ?
Si8 C18 1.875(4) . ?
Si8 C16 1.878(4) . ?
Si9 Si12 2.3476(11) . ?
Si9 Si10 2.3606(10) . ?
Si9 Si11 2.3613(11) . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C13 H13C 0.9800 . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
Si10 C21 1.846(5) . ?
Si10 C19 1.855(5) . ?
Si10 C20 1.864(4) . ?
Si11 C24 1.863(5) . ?
Si11 C22 1.865(4) . ?
Si11 C23 1.873(4) . ?
Si12 C27 1.848(5) . ?
Si12 C25 1.863(4) . ?
Si12 C26 1.881(5) . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C21 H21A 0.9800 . ?
C21 H21B 0.9800 . ?
C21 H21C 0.9800 . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C25 H25A 0.9800 . ?
C25 H25B 0.9800 . ?
C25 H25C 0.9800 . ?
C26 H26A 0.9800 . ?
C26 H26B 0.9800 . ?
C26 H26C 0.9800 . ?
C27 H27A 0.9800 . ?
C27 H27B 0.9800 . ?
C27 H27C 0.9800 . ?
C28 C33 1.395(4) . ?
C28 C29 1.398(4) . ?
C29 C30 1.383(4) . ?
C29 H29 0.9500 . ?
C30 C31 1.381(5) . ?
C30 H30 0.9500 . ?
C31 C32 1.388(5) . ?
C31 H31 0.9500 . ?
C32 C33 1.382(4) . ?
C32 H32 0.9500 . ?
C33 H33 0.9500 . ?
C34 C35 1.388(4) . ?
C34 C39 1.396(4) . ?
C35 C36 1.399(5) . ?
C35 H35 0.9500 . ?
C36 C37 1.372(6) . ?
C36 H36 0.9500 . ?
C37 C38 1.377(5) . ?
C37 H37 0.9500 . ?
C38 C39 1.394(4) . ?
C38 H38 0.9500 . ?
C39 H39 0.9500 . ?
C40 C41 1.388(4) . ?
C40 C45 1.399(4) . ?
C41 C42 1.397(4) . ?
C41 H41 0.9500 . ?
C42 C43 1.366(5) . ?
C42 H42 0.9500 . ?
C43 C44 1.387(5) . ?
C43 H43 0.9500 . ?
C44 C45 1.382(4) . ?
C44 H44 0.9500 . ?
C45 H45 0.9500 . ?
B101 C109 1.636(4) . ?
B101 C117 1.644(4) . ?
B101 C101 1.645(4) . ?
B101 C125 1.649(3) . ?
C101 C106 1.398(4) . ?
C101 C102 1.403(4) . ?
C102 C103 1.391(4) . ?
C102 H102 0.9500 . ?
C103 C104 1.389(4) . ?
C103 C107 1.501(4) . ?
C104 C105 1.379(4) . ?
C104 H104 0.9500 . ?
C105 C106 1.397(4) . ?
C105 C108 1.497(4) . ?
C106 H106 0.9500 . ?
C107 F6A 1.258(13) . ?
C107 F104 1.283(9) . ?
C107 F106 1.297(10) . ?
C107 F5A 1.303(12) . ?
C107 F105 1.320(9) . ?
C107 F4A 1.323(13) . ?
C108 F103 1.335(4) . ?
C108 F102 1.335(4) . ?
C108 F101 1.338(4) . ?
C109 C114 1.396(4) . ?
C109 C110 1.401(4) . ?
C110 C111 1.387(4) . ?
C110 H110 0.9500 . ?
C111 C112 1.382(4) . ?
C111 C115 1.497(4) . ?
C112 C113 1.375(5) . ?
C112 H112 0.9500 . ?
C113 C114 1.395(4) . ?
C113 C116 1.497(5) . ?
C114 H114 0.9500 . ?
C115 F7A 1.235(17) . ?
C115 F9A 1.25(2) . ?
C115 F108 1.299(10) . ?
C115 F107 1.326(9) . ?
C115 F8A 1.34(2) . ?
C115 F109 1.337(9) . ?
C116 F111 1.296(6) . ?
C116 F110 1.313(5) . ?
C116 F112 1.364(7) . ?
C117 C122 1.392(4) . ?
C117 C118 1.408(4) . ?
C118 C119 1.379(4) . ?
C118 H118 0.9500 . ?
C119 C120 1.390(5) . ?
C119 C123 1.510(4) . ?
C120 C121 1.382(4) . ?
C120 H120 0.9500 . ?
C121 C122 1.401(4) . ?
C121 C124 1.498(4) . ?
C122 H122 0.9500 . ?
C123 F113 1.307(5) . ?
C123 F114 1.322(5) . ?
C123 F115 1.325(5) . ?
C124 F117 1.326(4) . ?
C124 F118 1.336(4) . ?
C124 F116 1.343(4) . ?
C125 C126 1.396(4) . ?
C125 C130 1.399(4) . ?
C126 C127 1.390(4) . ?
C126 H126 0.9500 . ?
C127 C128 1.384(4) . ?
C127 C131 1.496(4) . ?
C128 C129 1.387(4) . ?
C128 H128 0.9500 . ?
C129 C130 1.391(4) . ?
C129 C132 1.498(4) . ?
C130 H130 0.9500 . ?
C131 F121 1.329(4) . ?
C131 F119 1.329(3) . ?
C131 F120 1.334(4) . ?
C132 F124 1.326(4) . ?
C132 F123 1.331(4) . ?
C132 F122 1.337(4) . ?
C1S C2S 1.449(15) . ?
C1S H1S1 0.9800 . ?
C1S H1S2 0.9800 . ?
C1S H1S3 0.9800 . ?
C2S C3S 1.480(12) . ?
C2S H2S1 0.9900 . ?
C2S H2S2 0.9900 . ?
C3S C4S 1.536(14) . ?
C3S H3S1 0.9900 . ?
C3S H3S2 0.9900 . ?
C4S C5S 1.431(13) . ?
C4S H4S1 0.9900 . ?
C4S H4S2 0.9900 . ?
C5S C6S 1.493(12) . ?
C5S H5S1 0.9900 . ?
C5S H5S2 0.9900 . ?
C6S H6S1 0.9800 . ?
C6S H6S2 0.9800 . ?
C6S H6S3 0.9800 . ?
C3T C2T 1.542(15) . ?
C3T C3T 1.548(17) 2_656 ?
C3T H3T1 0.9900 . ?
C3T H3T2 0.9900 . ?
C1T C2T 1.518(13) . ?
C1T H1T1 0.9800 . ?
C1T H1T2 0.9800 . ?
C1T H1T3 0.9800 . ?
C2T H2T1 0.9900 . ?
C2T H2T2 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Si1 Ge1 Ge3 117.36(4) . . ?
Si1 Ge1 Ge4 130.22(4) . . ?
Ge3 Ge1 Ge4 75.70(2) . . ?
Si1 Ge1 Ge2 125.71(4) . . ?
Ge3 Ge1 Ge2 73.72(3) . . ?
Ge4 Ge1 Ge2 104.00(3) . . ?
Si1 Ge1 Ge5 122.21(4) . . ?
Ge3 Ge1 Ge5 118.78(3) . . ?
Ge4 Ge1 Ge5 77.01(3) . . ?
Ge2 Ge1 Ge5 61.57(2) . . ?
Ge1 Ge2 Ge7 92.81(3) . . ?
Ge1 Ge2 Ge5 60.01(2) . . ?
Ge7 Ge2 Ge5 100.30(3) . . ?
Ge1 Ge2 Ge6 104.29(3) . . ?
Ge7 Ge2 Ge6 59.05(2) . . ?
Ge5 Ge2 Ge6 59.67(2) . . ?
Rh1 Ge3 Ge1 101.64(2) . . ?
Rh1 Ge3 Ge7 65.288(15) . . ?
Ge1 Ge3 Ge7 96.94(3) . . ?
Rh1 Ge4 Ge8 101.248(17) . . ?
Rh1 Ge4 Ge1 102.48(2) . . ?
Ge8 Ge4 Ge1 105.61(3) . . ?
Ge1 Ge5 Ge8 97.44(3) . . ?
Ge1 Ge5 Ge2 58.42(2) . . ?
Ge8 Ge5 Ge2 103.76(3) . . ?
Ge1 Ge5 Ge6 103.96(3) . . ?
Ge8 Ge5 Ge6 58.78(2) . . ?
Ge2 Ge5 Ge6 60.81(2) . . ?
Ge8 Ge6 Ge7 91.91(3) . . ?
Ge8 Ge6 Ge5 60.19(2) . . ?
Ge7 Ge6 Ge5 100.61(3) . . ?
Ge8 Ge6 Ge2 103.85(3) . . ?
Ge7 Ge6 Ge2 59.64(2) . . ?
Ge5 Ge6 Ge2 59.53(2) . . ?
Si5 Ge7 Ge3 108.76(3) . . ?
Si5 Ge7 Ge9 118.92(3) . . ?
Ge3 Ge7 Ge9 105.50(2) . . ?
Si5 Ge7 Ge6 125.33(4) . . ?
Ge3 Ge7 Ge6 119.37(3) . . ?
Ge9 Ge7 Ge6 72.41(3) . . ?
Si5 Ge7 Ge2 117.56(3) . . ?
Ge3 Ge7 Ge2 71.33(3) . . ?
Ge9 Ge7 Ge2 120.69(3) . . ?
Ge6 Ge7 Ge2 61.31(2) . . ?
Si5 Ge7 Rh1 116.11(3) . . ?
Ge3 Ge7 Rh1 54.446(15) . . ?
Ge9 Ge7 Rh1 54.281(16) . . ?
Ge6 Ge7 Rh1 112.34(3) . . ?
Ge2 Ge7 Rh1 112.28(3) . . ?
Si9 Ge8 Ge4 125.64(3) . . ?
Si9 Ge8 Ge9 127.20(3) . . ?
Ge4 Ge8 Ge9 77.561(18) . . ?
Si9 Ge8 Ge6 127.77(3) . . ?
Ge4 Ge8 Ge6 104.09(3) . . ?
Ge9 Ge8 Ge6 73.98(3) . . ?
Si9 Ge8 Ge5 111.99(3) . . ?
Ge4 Ge8 Ge5 77.02(2) . . ?
Ge9 Ge8 Ge5 119.79(3) . . ?
Ge6 Ge8 Ge5 61.04(2) . . ?
Rh1 Ge9 Ge8 99.127(17) . . ?
Rh1 Ge9 Ge7 65.063(19) . . ?
Ge8 Ge9 Ge7 95.30(2) . . ?
P1 Rh1 Ge4 98.696(19) . . ?
P1 Rh1 Ge9 119.772(19) . . ?
Ge4 Rh1 Ge9 81.655(13) . . ?
P1 Rh1 Ge3 122.400(18) . . ?
Ge4 Rh1 Ge3 79.683(12) . . ?
Ge9 Rh1 Ge3 116.890(14) . . ?
P1 Rh1 Ge7 169.72(2) . . ?
Ge4 Rh1 Ge7 91.541(17) . . ?
Ge9 Rh1 Ge7 60.656(15) . . ?
Ge3 Rh1 Ge7 60.266(13) . . ?
P1 Rh1 H1 91.2(3) . . ?
Ge4 Rh1 H1 170.0(3) . . ?
Ge9 Rh1 H1 94.1(4) . . ?
Ge3 Rh1 H1 94.4(4) . . ?
Ge7 Rh1 H1 78.5(3) . . ?
Si5 Ge1A Ge4A 121.4(8) . . ?
Si5 Ge1A Ge2A 126.3(8) . . ?
Ge4A Ge1A Ge2A 106.0(6) . . ?
Si5 Ge1A Ge3A 132.7(7) . . ?
Ge4A Ge1A Ge3A 78.4(5) . . ?
Ge2A Ge1A Ge3A 77.3(7) . . ?
Si5 Ge1A Ge5A 109.3(7) . . ?
Ge4A Ge1A Ge5A 72.5(6) . . ?
Ge2A Ge1A Ge5A 60.8(5) . . ?
Ge3A Ge1A Ge5A 117.8(7) . . ?
Ge1A Ge2A Ge7A 91.5(7) . . ?
Ge1A Ge2A Ge5A 61.5(5) . . ?
Ge7A Ge2A Ge5A 99.0(6) . . ?
Ge1A Ge2A Ge6A 103.9(7) . . ?
Ge7A Ge2A Ge6A 57.7(5) . . ?
Ge5A Ge2A Ge6A 59.0(5) . . ?
Rh1A Ge3A Ge7A 76.5(4) . . ?
Rh1A Ge3A Ge1A 93.9(5) . . ?
Ge7A Ge3A Ge1A 92.0(6) . . ?
Rh1A Ge4A Ge1A 93.7(4) . . ?
Rh1A Ge4A Ge8A 101.9(5) . . ?
Ge1A Ge4A Ge8A 111.4(7) . . ?
Ge6A Ge5A Ge2A 61.9(6) . . ?
Ge6A Ge5A Ge1A 103.2(6) . . ?
Ge2A Ge5A Ge1A 57.7(5) . . ?
Ge6A Ge5A Ge8A 57.8(5) . . ?
Ge2A Ge5A Ge8A 104.6(7) . . ?
Ge1A Ge5A Ge8A 97.6(7) . . ?
Ge8A Ge6A Ge7A 93.1(6) . . ?
Ge8A Ge6A Ge5A 61.6(5) . . ?
Ge7A Ge6A Ge5A 100.0(6) . . ?
Ge8A Ge6A Ge2A 105.3(7) . . ?
Ge7A Ge6A Ge2A 58.9(5) . . ?
Ge5A Ge6A Ge2A 59.1(5) . . ?
Si9 Ge7A Ge3A 113.6(5) . . ?
Si9 Ge7A Ge6A 120.3(6) . . ?
Ge3A Ge7A Ge6A 125.4(7) . . ?
Si9 Ge7A Ge9A 108.1(6) . . ?
Ge3A Ge7A Ge9A 93.9(4) . . ?
Ge6A Ge7A Ge9A 77.8(6) . . ?
Si9 Ge7A Ge2A 127.1(7) . . ?
Ge3A Ge7A Ge2A 78.4(7) . . ?
Ge6A Ge7A Ge2A 63.4(5) . . ?
Ge9A Ge7A Ge2A 122.8(6) . . ?
Si9 Ge7A Rh1A 118.6(5) . . ?
Ge3A Ge7A Rh1A 44.3(3) . . ?
Ge6A Ge7A Rh1A 109.6(6) . . ?
Ge9A Ge7A Rh1A 49.7(2) . . ?
Ge2A Ge7A Rh1A 105.5(6) . . ?
Si1 Ge8A Ge4A 130.1(10) . . ?
Si1 Ge8A Ge9A 112.2(8) . . ?
Ge4A Ge8A Ge9A 75.5(5) . . ?
Si1 Ge8A Ge6A 125.5(9) . . ?
Ge4A Ge8A Ge6A 104.4(7) . . ?
Ge9A Ge8A Ge6A 78.8(7) . . ?
Si1 Ge8A Ge5A 129.5(9) . . ?
Ge4A Ge8A Ge5A 72.0(7) . . ?
Ge9A Ge8A Ge5A 117.7(7) . . ?
Ge6A Ge8A Ge5A 60.6(5) . . ?
Rh1A Ge9A Ge8A 98.8(5) . . ?
Rh1A Ge9A Ge7A 71.0(3) . . ?
Ge8A Ge9A Ge7A 92.9(6) . . ?
Ge3A Rh1A Ge4A 94.0(4) . . ?
Ge3A Rh1A Ge9A 118.2(4) . . ?
Ge4A Rh1A Ge9A 83.1(3) . . ?
Ge3A Rh1A P1 115.4(4) . . ?
Ge4A Rh1A P1 96.5(2) . . ?
Ge9A Rh1A P1 126.3(3) . . ?
Ge3A Rh1A Ge7A 59.1(4) . . ?
Ge4A Rh1A Ge7A 91.9(4) . . ?
Ge9A Rh1A Ge7A 59.3(3) . . ?
P1 Rh1A Ge7A 170.5(3) . . ?
Ge3A Rh1A H2 96.0(6) . . ?
Ge4A Rh1A H2 166.8(6) . . ?
Ge9A Rh1A H2 84.5(5) . . ?
P1 Rh1A H2 87.1(4) . . ?
Ge7A Rh1A H2 85.8(5) . . ?
C28 P1 C40 106.38(12) . . ?
C28 P1 C34 105.31(12) . . ?
C40 P1 C34 102.36(12) . . ?
C28 P1 Rh1 106.66(8) . . ?
C40 P1 Rh1 114.37(9) . . ?
C34 P1 Rh1 120.68(9) . . ?
C28 P1 Rh1A 120.51(13) . . ?
C40 P1 Rh1A 128.70(14) . . ?
C34 P1 Rh1A 85.17(13) . . ?
Si4 Si1 Si3 115.69(5) . . ?
Si4 Si1 Ge8A 105.6(5) . . ?
Si3 Si1 Ge8A 104.6(5) . . ?
Si4 Si1 Si2 112.33(5) . . ?
Si3 Si1 Si2 112.16(4) . . ?
Ge8A Si1 Si2 105.3(5) . . ?
Si4 Si1 Ge1 108.59(4) . . ?
Si3 Si1 Ge1 103.19(4) . . ?
Si2 Si1 Ge1 103.65(4) . . ?
C2 Si2 C1 107.4(3) . . ?
C2 Si2 C3 108.2(3) . . ?
C1 Si2 C3 109.4(3) . . ?
C2 Si2 Si1 112.92(15) . . ?
C1 Si2 Si1 109.27(17) . . ?
C3 Si2 Si1 109.64(15) . . ?
C4 Si3 C5 109.1(3) . . ?
C4 Si3 C6 112.9(4) . . ?
C5 Si3 C6 107.2(3) . . ?
C4 Si3 Si1 108.13(16) . . ?
C5 Si3 Si1 111.98(15) . . ?
C6 Si3 Si1 107.59(15) . . ?
C8 Si4 C7 109.9(3) . . ?
C8 Si4 C9 109.6(3) . . ?
C7 Si4 C9 110.6(3) . . ?
C8 Si4 Si1 110.24(19) . . ?
C7 Si4 Si1 107.59(17) . . ?
C9 Si4 Si1 108.79(17) . . ?
Si2 C1 H1A 109.5 . . ?
Si2 C1 H1B 109.5 . . ?
H1A C1 H1B 109.5 . . ?
Si2 C1 H1C 109.5 . . ?
H1A C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
Si2 C2 H2A 109.5 . . ?
Si2 C2 H2B 109.5 . . ?
H2A C2 H2B 109.5 . . ?
Si2 C2 H2C 109.5 . . ?
H2A C2 H2C 109.5 . . ?
H2B C2 H2C 109.5 . . ?
Si2 C3 H3A 109.5 . . ?
Si2 C3 H3B 109.5 . . ?
H3A C3 H3B 109.5 . . ?
Si2 C3 H3C 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
Si3 C4 H4A 109.5 . . ?
Si3 C4 H4B 109.5 . . ?
H4A C4 H4B 109.5 . . ?
Si3 C4 H4C 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
Si3 C5 H5A 109.5 . . ?
Si3 C5 H5B 109.5 . . ?
H5A C5 H5B 109.5 . . ?
Si3 C5 H5C 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
Si3 C6 H6A 109.5 . . ?
Si3 C6 H6B 109.5 . . ?
H6A C6 H6B 109.5 . . ?
Si3 C6 H6C 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
Si4 C7 H7A 109.5 . . ?
Si4 C7 H7B 109.5 . . ?
H7A C7 H7B 109.5 . . ?
Si4 C7 H7C 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
Si4 C8 H8A 109.5 . . ?
Si4 C8 H8B 109.5 . . ?
H8A C8 H8B 109.5 . . ?
Si4 C8 H8C 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
Si4 C9 H9A 109.5 . . ?
Si4 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
Si4 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
Si8 Si5 Si7 114.55(5) . . ?
Si8 Si5 Si6 111.76(5) . . ?
Si7 Si5 Si6 109.38(4) . . ?
Si8 Si5 Ge1A 109.6(4) . . ?
Si7 Si5 Ge1A 103.1(4) . . ?
Si6 Si5 Ge1A 107.9(4) . . ?
Si8 Si5 Ge7 104.96(4) . . ?
Si7 Si5 Ge7 108.71(4) . . ?
Si6 Si5 Ge7 107.09(4) . . ?
C10 Si6 C11 110.48(16) . . ?
C10 Si6 C12 107.82(17) . . ?
C11 Si6 C12 109.30(16) . . ?
C10 Si6 Si5 109.37(12) . . ?
C11 Si6 Si5 106.88(12) . . ?
C12 Si6 Si5 113.01(12) . . ?
C14 Si7 C13 108.8(3) . . ?
C14 Si7 C15 110.0(2) . . ?
C13 Si7 C15 109.4(2) . . ?
C14 Si7 Si5 109.78(16) . . ?
C13 Si7 Si5 109.09(15) . . ?
C15 Si7 Si5 109.82(15) . . ?
C17 Si8 C18 110.9(3) . . ?
C17 Si8 C16 110.6(2) . . ?
C18 Si8 C16 107.0(2) . . ?
C17 Si8 Si5 109.3(2) . . ?
C18 Si8 Si5 107.09(15) . . ?
C16 Si8 Si5 111.89(12) . . ?
Si12 Si9 Si10 113.58(4) . . ?
Si12 Si9 Si11 112.68(4) . . ?
Si10 Si9 Si11 112.54(4) . . ?
Si12 Si9 Ge8 103.53(4) . . ?
Si10 Si9 Ge8 109.30(4) . . ?
Si11 Si9 Ge8 104.33(4) . . ?
Si12 Si9 Ge7A 102.0(3) . . ?
Si10 Si9 Ge7A 104.8(3) . . ?
Si11 Si9 Ge7A 110.4(3) . . ?
Si6 C10 H10A 109.5 . . ?
Si6 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
Si6 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
Si6 C11 H11A 109.5 . . ?
Si6 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
Si6 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
Si6 C12 H12A 109.5 . . ?
Si6 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
Si6 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
Si7 C13 H13A 109.5 . . ?
Si7 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
Si7 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
Si7 C14 H14A 109.5 . . ?
Si7 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
Si7 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
Si7 C15 H15A 109.5 . . ?
Si7 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
Si7 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
Si8 C16 H16A 109.5 . . ?
Si8 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
Si8 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
Si8 C17 H17A 109.5 . . ?
Si8 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
Si8 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
Si8 C18 H18A 109.5 . . ?
Si8 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
Si8 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C21 Si10 C19 109.6(4) . . ?
C21 Si10 C20 109.0(3) . . ?
C19 Si10 C20 107.2(3) . . ?
C21 Si10 Si9 111.18(16) . . ?
C19 Si10 Si9 112.04(16) . . ?
C20 Si10 Si9 107.76(14) . . ?
C24 Si11 C22 109.5(3) . . ?
C24 Si11 C23 109.1(3) . . ?
C22 Si11 C23 108.5(2) . . ?
C24 Si11 Si9 108.65(17) . . ?
C22 Si11 Si9 111.30(13) . . ?
C23 Si11 Si9 109.80(17) . . ?
C27 Si12 C25 108.2(3) . . ?
C27 Si12 C26 110.6(3) . . ?
C25 Si12 C26 108.0(2) . . ?
C27 Si12 Si9 111.14(16) . . ?
C25 Si12 Si9 109.98(13) . . ?
C26 Si12 Si9 108.78(19) . . ?
Si10 C19 H19A 109.5 . . ?
Si10 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
Si10 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
Si10 C20 H20A 109.5 . . ?
Si10 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
Si10 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
Si10 C21 H21A 109.5 . . ?
Si10 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
Si10 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
Si11 C22 H22A 109.5 . . ?
Si11 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
Si11 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
Si11 C23 H23A 109.5 . . ?
Si11 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
Si11 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
Si11 C24 H24A 109.5 . . ?
Si11 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
Si11 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
Si12 C25 H25A 109.5 . . ?
Si12 C25 H25B 109.5 . . ?
H25A C25 H25B 109.5 . . ?
Si12 C25 H25C 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
Si12 C26 H26A 109.5 . . ?
Si12 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
Si12 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
Si12 C27 H27A 109.5 . . ?
Si12 C27 H27B 109.5 . . ?
H27A C27 H27B 109.5 . . ?
Si12 C27 H27C 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
C33 C28 C29 119.0(3) . . ?
C33 C28 P1 122.0(2) . . ?
C29 C28 P1 118.8(2) . . ?
C30 C29 C28 120.6(3) . . ?
C30 C29 H29 119.7 . . ?
C28 C29 H29 119.7 . . ?
C31 C30 C29 120.0(3) . . ?
C31 C30 H30 120.0 . . ?
C29 C30 H30 120.0 . . ?
C30 C31 C32 119.9(3) . . ?
C30 C31 H31 120.1 . . ?
C32 C31 H31 120.1 . . ?
C33 C32 C31 120.6(3) . . ?
C33 C32 H32 119.7 . . ?
C31 C32 H32 119.7 . . ?
C32 C33 C28 119.9(3) . . ?
C32 C33 H33 120.0 . . ?
C28 C33 H33 120.0 . . ?
C35 C34 C39 119.8(3) . . ?
C35 C34 P1 122.1(2) . . ?
C39 C34 P1 118.1(2) . . ?
C34 C35 C36 119.4(3) . . ?
C34 C35 H35 120.3 . . ?
C36 C35 H35 120.3 . . ?
C37 C36 C35 120.3(3) . . ?
C37 C36 H36 119.8 . . ?
C35 C36 H36 119.8 . . ?
C36 C37 C38 120.9(3) . . ?
C36 C37 H37 119.6 . . ?
C38 C37 H37 119.6 . . ?
C37 C38 C39 119.6(3) . . ?
C37 C38 H38 120.2 . . ?
C39 C38 H38 120.2 . . ?
C38 C39 C34 120.0(3) . . ?
C38 C39 H39 120.0 . . ?
C34 C39 H39 120.0 . . ?
C41 C40 C45 119.2(3) . . ?
C41 C40 P1 120.5(2) . . ?
C45 C40 P1 120.3(2) . . ?
C40 C41 C42 120.0(3) . . ?
C40 C41 H41 120.0 . . ?
C42 C41 H41 120.0 . . ?
C43 C42 C41 120.5(3) . . ?
C43 C42 H42 119.8 . . ?
C41 C42 H42 119.8 . . ?
C42 C43 C44 120.0(3) . . ?
C42 C43 H43 120.0 . . ?
C44 C43 H43 120.0 . . ?
C45 C44 C43 120.3(3) . . ?
C45 C44 H44 119.9 . . ?
C43 C44 H44 119.9 . . ?
C44 C45 C40 120.1(3) . . ?
C44 C45 H45 120.0 . . ?
C40 C45 H45 120.0 . . ?
C109 B101 C117 105.6(2) . . ?
C109 B101 C101 112.9(2) . . ?
C117 B101 C101 109.9(2) . . ?
C109 B101 C125 111.0(2) . . ?
C117 B101 C125 111.9(2) . . ?
C101 B101 C125 105.7(2) . . ?
C106 C101 C102 115.7(2) . . ?
C106 C101 B101 123.7(2) . . ?
C102 C101 B101 120.6(2) . . ?
C103 C102 C101 122.3(3) . . ?
C103 C102 H102 118.9 . . ?
C101 C102 H102 118.9 . . ?
C104 C103 C102 120.7(3) . . ?
C104 C103 C107 119.4(3) . . ?
C102 C103 C107 119.9(3) . . ?
C105 C104 C103 118.1(3) . . ?
C105 C104 H104 120.9 . . ?
C103 C104 H104 120.9 . . ?
C104 C105 C106 121.0(3) . . ?
C104 C105 C108 120.7(3) . . ?
C106 C105 C108 118.3(3) . . ?
C105 C106 C101 122.1(3) . . ?
C105 C106 H106 118.9 . . ?
C101 C106 H106 118.9 . . ?
F104 C107 F106 107.7(9) . . ?
F6A C107 F5A 109.3(10) . . ?
F104 C107 F105 107.3(8) . . ?
F106 C107 F105 102.5(8) . . ?
F6A C107 F4A 107.3(13) . . ?
F5A C107 F4A 100.7(10) . . ?
F6A C107 C103 116.8(7) . . ?
F104 C107 C103 114.8(6) . . ?
F106 C107 C103 112.4(6) . . ?
F5A C107 C103 111.3(6) . . ?
F105 C107 C103 111.3(5) . . ?
F4A C107 C103 110.2(8) . . ?
F103 C108 F102 106.3(2) . . ?
F103 C108 F101 106.6(3) . . ?
F102 C108 F101 105.7(3) . . ?
F103 C108 C105 112.2(2) . . ?
F102 C108 C105 113.4(3) . . ?
F101 C108 C105 112.1(2) . . ?
C114 C109 C110 115.6(2) . . ?
C114 C109 B101 125.5(2) . . ?
C110 C109 B101 118.8(2) . . ?
C111 C110 C109 122.3(3) . . ?
C111 C110 H110 118.8 . . ?
C109 C110 H110 118.8 . . ?
C112 C111 C110 120.8(3) . . ?
C112 C111 C115 120.2(3) . . ?
C110 C111 C115 119.0(3) . . ?
C113 C112 C111 118.2(3) . . ?
C113 C112 H112 120.9 . . ?
C111 C112 H112 120.9 . . ?
C112 C113 C114 121.1(3) . . ?
C112 C113 C116 119.3(3) . . ?
C114 C113 C116 119.6(3) . . ?
C113 C114 C109 121.9(3) . . ?
C113 C114 H114 119.1 . . ?
C109 C114 H114 119.1 . . ?
F7A C115 F9A 109.0(18) . . ?
F108 C115 F107 108.6(8) . . ?
F7A C115 F8A 102.3(14) . . ?
F9A C115 F8A 105.9(14) . . ?
F108 C115 F109 104.8(7) . . ?
F107 C115 F109 102.9(6) . . ?
F7A C115 C111 115.1(9) . . ?
F9A C115 C111 112.0(11) . . ?
F108 C115 C111 114.5(6) . . ?
F107 C115 C111 111.4(5) . . ?
F8A C115 C111 111.7(10) . . ?
F109 C115 C111 113.8(5) . . ?
F111 C116 F110 109.0(5) . . ?
F111 C116 F112 104.6(4) . . ?
F110 C116 F112 103.0(4) . . ?
F111 C116 C113 113.6(4) . . ?
F110 C116 C113 114.4(3) . . ?
F112 C116 C113 111.3(4) . . ?
C122 C117 C118 115.8(2) . . ?
C122 C117 B101 126.5(2) . . ?
C118 C117 B101 117.7(2) . . ?
C119 C118 C117 122.1(3) . . ?
C119 C118 H118 118.9 . . ?
C117 C118 H118 118.9 . . ?
C118 C119 C120 121.3(3) . . ?
C118 C119 C123 120.2(3) . . ?
C120 C119 C123 118.5(3) . . ?
C121 C120 C119 117.8(3) . . ?
C121 C120 H120 121.1 . . ?
C119 C120 H120 121.1 . . ?
C120 C121 C122 120.8(3) . . ?
C120 C121 C124 120.1(3) . . ?
C122 C121 C124 119.1(2) . . ?
C117 C122 C121 122.1(2) . . ?
C117 C122 H122 118.9 . . ?
C121 C122 H122 118.9 . . ?
F113 C123 F114 107.8(4) . . ?
F113 C123 F115 105.4(4) . . ?
F114 C123 F115 105.4(3) . . ?
F113 C123 C119 113.3(3) . . ?
F114 C123 C119 112.1(3) . . ?
F115 C123 C119 112.2(3) . . ?
F117 C124 F118 106.1(3) . . ?
F117 C124 F116 107.3(3) . . ?
F118 C124 F116 104.5(3) . . ?
F117 C124 C121 113.6(3) . . ?
F118 C124 C121 112.3(3) . . ?
F116 C124 C121 112.4(3) . . ?
C126 C125 C130 115.9(2) . . ?
C126 C125 B101 119.7(2) . . ?
C130 C125 B101 124.3(2) . . ?
C127 C126 C125 122.3(2) . . ?
C127 C126 H126 118.8 . . ?
C125 C126 H126 118.8 . . ?
C128 C127 C126 120.8(2) . . ?
C128 C127 C131 120.5(2) . . ?
C126 C127 C131 118.7(2) . . ?
C127 C128 C129 117.9(2) . . ?
C127 C128 H128 121.0 . . ?
C129 C128 H128 121.0 . . ?
C128 C129 C130 121.1(2) . . ?
C128 C129 C132 118.7(2) . . ?
C130 C129 C132 120.2(3) . . ?
C129 C130 C125 121.9(2) . . ?
C129 C130 H130 119.0 . . ?
C125 C130 H130 119.0 . . ?
F121 C131 F119 105.7(3) . . ?
F121 C131 F120 104.6(3) . . ?
F119 C131 F120 108.7(3) . . ?
F121 C131 C127 112.5(2) . . ?
F119 C131 C127 113.0(3) . . ?
F120 C131 C127 111.8(3) . . ?
F124 C132 F123 106.6(3) . . ?
F124 C132 F122 106.9(3) . . ?
F123 C132 F122 104.5(3) . . ?
F124 C132 C129 112.1(3) . . ?
F123 C132 C129 113.7(2) . . ?
F122 C132 C129 112.4(3) . . ?
C2S C1S H1S1 109.5 . . ?
C2S C1S H1S2 109.5 . . ?
H1S1 C1S H1S2 109.5 . . ?
C2S C1S H1S3 109.5 . . ?
H1S1 C1S H1S3 109.5 . . ?
H1S2 C1S H1S3 109.5 . . ?
C1S C2S C3S 110.6(12) . . ?
C1S C2S H2S1 109.5 . . ?
C3S C2S H2S1 109.5 . . ?
C1S C2S H2S2 109.5 . . ?
C3S C2S H2S2 109.5 . . ?
H2S1 C2S H2S2 108.1 . . ?
C2S C3S C4S 110.9(11) . . ?
C2S C3S H3S1 109.5 . . ?
C4S C3S H3S1 109.5 . . ?
C2S C3S H3S2 109.5 . . ?
C4S C3S H3S2 109.5 . . ?
H3S1 C3S H3S2 108.1 . . ?
C5S C4S C3S 110.4(11) . . ?
C5S C4S H4S1 109.6 . . ?
C3S C4S H4S1 109.6 . . ?
C5S C4S H4S2 109.6 . . ?
C3S C4S H4S2 109.6 . . ?
H4S1 C4S H4S2 108.1 . . ?
C4S C5S C6S 116.0(11) . . ?
C4S C5S H5S1 108.3 . . ?
C6S C5S H5S1 108.3 . . ?
C4S C5S H5S2 108.3 . . ?
C6S C5S H5S2 108.3 . . ?
H5S1 C5S H5S2 107.4 . . ?
C5S C6S H6S1 109.5 . . ?
C5S C6S H6S2 109.5 . . ?
H6S1 C6S H6S2 109.5 . . ?
C5S C6S H6S3 109.5 . . ?
H6S1 C6S H6S3 109.5 . . ?
H6S2 C6S H6S3 109.5 . . ?
C2T C3T C3T 104.4(14) . 2_656 ?
C2T C3T H3T1 110.9 . . ?
C3T C3T H3T1 110.9 2_656 . ?
C2T C3T H3T2 110.9 . . ?
C3T C3T H3T2 110.9 2_656 . ?
H3T1 C3T H3T2 108.9 . . ?
C2T C1T H1T1 109.5 . . ?
C2T C1T H1T2 109.5 . . ?
H1T1 C1T H1T2 109.5 . . ?
C2T C1T H1T3 109.5 . . ?
H1T1 C1T H1T3 109.5 . . ?
H1T2 C1T H1T3 109.5 . . ?
C1T C2T C3T 109.6(11) . . ?
C1T C2T H2T1 109.7 . . ?
C3T C2T H2T1 109.7 . . ?
C1T C2T H2T2 109.7 . . ?
C3T C2T H2T2 109.7 . . ?
H2T1 C2T H2T2 108.2 . . ?

_refine_diff_density_max         0.827
_refine_diff_density_min         -0.568
_refine_diff_density_rms         0.076



####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_OT345_recryst
_database_code_depnum_ccdc_archive 'CCDC 2155446'
loop_
_audit_author_name
_audit_author_address
'Jose Goicoechea'
;University of Oxford
United Kingdom
;
_audit_update_record             
;
2022-02-28 deposited with the CCDC.	2022-06-09 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/1
_shelx_SHELXL_version_number     2018/1
_chemical_name_systematic        
;
 Ge9{Si(SiMe3)}3Rh(Me2IMe)*hex
;
_contact_author_fax              '+44 1865 272690'
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C34 H93 Ge9 N2 Rh Si12, C6 H14'
_chemical_formula_sum            'C40 H107 Ge9 N2 Rh Si12'
_chemical_formula_weight         1709.57

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge -1.0885 0.8855 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh 0.0927 3.6045 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.2541 0.3302 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   16.3622(3)
_cell_length_b                   19.8996(3)
_cell_length_c                   25.9438(4)
_cell_angle_alpha                68.5600(10)
_cell_angle_beta                 79.8560(10)
_cell_angle_gamma                82.1130(10)
_cell_volume                     7715.4(2)
_cell_formula_units_Z            4
_cell_measurement_temperature    150(2)
_cell_measurement_reflns_used    60376
_cell_measurement_theta_min      1.8360
_cell_measurement_theta_max      77.1850

_exptl_crystal_description       block
_exptl_crystal_colour            black
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    .
_exptl_crystal_density_diffrn    1.472
_exptl_crystal_F_000             3448
_exptl_transmission_factor_min   .
_exptl_transmission_factor_max   .
_exptl_crystal_size_max          0.220
_exptl_crystal_size_mid          0.123
_exptl_crystal_size_min          0.060
_exptl_absorpt_coefficient_mu    7.552
_shelx_estimated_absorpt_T_min   0.287
_shelx_estimated_absorpt_T_max   0.660
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.54997
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.40.67a (Rigaku Oxford Diffraction, 2019)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   .

_diffrn_ambient_temperature      150(2)
_diffrn_radiation_wavelength     1.54184
_diffrn_radiation_type           CuK\a
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'SuperNova (Cu) X-ray Source'
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at home/near, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_detector                 'CCD plate'
_diffrn_detector_type            Atlas
_diffrn_detector_area_resol_mean 10.5035
_diffrn_reflns_number            141405
_diffrn_reflns_av_unetI/netI     0.0294
_diffrn_reflns_av_R_equivalents  0.0488
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_l_min       -32
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_theta_min         1.847
_diffrn_reflns_theta_max         77.250
_diffrn_reflns_theta_full        67.684
_diffrn_measured_fraction_theta_max 0.988
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.988
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.988
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             32320
_reflns_number_gt                27830
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'CrysAlisPro 1.171.40.67a (Rigaku OD, 2019)'
_computing_cell_refinement       'CrysAlisPro 1.171.40.67a (Rigaku OD, 2019)'
_computing_data_reduction        'CrysAlisPro 1.171.40.67a (Rigaku OD, 2019)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2018/1 (Sheldrick, 2018)'
_computing_molecular_graphics    .
_computing_publication_material  .
_refine_special_details          .

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1167P)²+1.0887P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     .
_atom_sites_solution_secondary   .
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         32320
_refine_ls_number_parameters     1332
_refine_ls_number_restraints     315
_refine_ls_R_factor_all          0.0593
_refine_ls_R_factor_gt           0.0544
_refine_ls_wR_factor_ref         0.1728
_refine_ls_wR_factor_gt          0.1641
_refine_ls_goodness_of_fit_ref   1.048
_refine_ls_restrained_S_all      1.049
_refine_ls_shift/su_max          0.007
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ge1 Ge 0.55832(3) 0.91995(2) 0.84794(2) 0.05142(10) Uani 1 1 d . . . . .
Ge2 Ge 0.60110(3) 0.84527(3) 0.94827(2) 0.05520(11) Uani 1 1 d . . . . .
Ge3 Ge 0.58179(3) 0.79297(2) 0.85231(2) 0.05116(10) Uani 1 1 d . . . . .
Ge4 Ge 0.68199(3) 0.93433(2) 0.76828(2) 0.05026(10) Uani 1 1 d . . . . .
Ge5 Ge 0.65745(3) 0.97226(2) 0.88667(2) 0.05514(11) Uani 1 1 d . . . . .
Ge6 Ge 0.76010(3) 0.86049(3) 0.93439(2) 0.05526(11) Uani 1 1 d . . . . .
Ge8 Ge 0.78893(3) 0.94230(2) 0.82696(2) 0.05164(10) Uani 1 1 d . . . . .
Ge7 Ge 0.70695(3) 0.76366(2) 0.90381(2) 0.04922(10) Uani 1 1 d . . . . .
Ge9 Ge 0.82997(3) 0.81625(2) 0.83312(2) 0.05230(10) Uani 1 1 d . . . . .
Rh1 Rh 0.71325(2) 0.80497(2) 0.79322(2) 0.04822(8) Uani 1 1 d . . . . .
C28 C 0.7257(2) 0.81198(19) 0.71198(15) 0.0508(7) Uani 1 1 d . . . . .
N1 N 0.7981(2) 0.80554(18) 0.67772(14) 0.0556(7) Uani 1 1 d . . . . .
N2 N 0.6657(2) 0.81872(17) 0.67996(12) 0.0516(6) Uani 1 1 d . . . . .
C29 C 0.7825(3) 0.8077(2) 0.62624(16) 0.0563(8) Uani 1 1 d . . . . .
C30 C 0.6993(3) 0.8156(2) 0.62740(15) 0.0550(8) Uani 1 1 d . . . . .
C31 C 0.8818(3) 0.7994(3) 0.6925(2) 0.0770(13) Uani 1 1 d . . . . .
H31A H 0.899073 0.847846 0.684355 0.115 Uiso 1 1 calc R U . . .
H31B H 0.920825 0.774806 0.670553 0.115 Uiso 1 1 calc R U . . .
H31C H 0.881446 0.771340 0.732393 0.115 Uiso 1 1 calc R U . . .
C32 C 0.8502(3) 0.8014(3) 0.5812(2) 0.0703(11) Uani 1 1 d . . . . .
H32A H 0.825717 0.797596 0.550562 0.105 Uiso 1 1 calc R U . . .
H32B H 0.887455 0.758121 0.596165 0.105 Uiso 1 1 calc R U . . .
H32C H 0.881846 0.844425 0.567083 0.105 Uiso 1 1 calc R U . . .
C33 C 0.6462(3) 0.8190(3) 0.58538(18) 0.0663(10) Uani 1 1 d . . . . .
H33A H 0.681545 0.819930 0.550495 0.100 Uiso 1 1 calc R U . . .
H33B H 0.608087 0.862933 0.578304 0.100 Uiso 1 1 calc R U . . .
H33C H 0.613937 0.776336 0.599671 0.100 Uiso 1 1 calc R U . . .
C34 C 0.5770(2) 0.8287(2) 0.69788(17) 0.0584(8) Uani 1 1 d . . . . .
H34A H 0.559557 0.786147 0.730060 0.088 Uiso 1 1 calc R U . . .
H34B H 0.546081 0.834720 0.667159 0.088 Uiso 1 1 calc R U . . .
H34C H 0.565491 0.871872 0.708488 0.088 Uiso 1 1 calc R U . . .
Si1 Si 0.72926(7) 0.63953(5) 0.96009(4) 0.0515(2) Uani 1 1 d . . . . .
Si2 Si 0.86861(8) 0.61595(7) 0.97627(6) 0.0681(3) Uani 1 1 d . . . . .
C1 C 0.8832(4) 0.5241(4) 1.0312(3) 0.110(3) Uani 1 1 d . . . . .
H1A H 0.940678 0.515462 1.039485 0.165 Uiso 1 1 calc R U . . .
H1B H 0.871604 0.486925 1.017581 0.165 Uiso 1 1 calc R U . . .
H1C H 0.844843 0.521827 1.065301 0.165 Uiso 1 1 calc R U . . .
C2 C 0.9026(5) 0.6841(5) 0.9999(4) 0.119(3) Uani 1 1 d . . . . .
H2A H 0.960340 0.670988 1.007450 0.179 Uiso 1 1 calc R U . . .
H2B H 0.866581 0.685312 1.034022 0.179 Uiso 1 1 calc R U . . .
H2C H 0.898712 0.731991 0.970560 0.179 Uiso 1 1 calc R U . . .
C3 C 0.9383(3) 0.6166(3) 0.9106(2) 0.0851(15) Uani 1 1 d . . . . .
H3A H 0.929025 0.663228 0.880745 0.128 Uiso 1 1 calc R U . . .
H3B H 0.925720 0.577472 0.899475 0.128 Uiso 1 1 calc R U . . .
H3C H 0.996548 0.609467 0.917133 0.128 Uiso 1 1 calc R U . . .
Si3 Si 0.70701(8) 0.56703(6) 0.91081(6) 0.0653(3) Uani 1 1 d . . . . .
C4 C 0.7533(5) 0.4721(3) 0.9439(3) 0.0972(19) Uani 1 1 d . . . . .
H4A H 0.730232 0.453241 0.983473 0.146 Uiso 1 1 calc R U . . .
H4B H 0.813944 0.472184 0.940414 0.146 Uiso 1 1 calc R U . . .
H4C H 0.740027 0.441239 0.924899 0.146 Uiso 1 1 calc R U . . .
C5 C 0.7567(4) 0.6037(3) 0.8364(2) 0.0841(14) Uani 1 1 d . . . . .
H5A H 0.743736 0.574747 0.815800 0.126 Uiso 1 1 calc R U . . .
H5B H 0.817225 0.601458 0.835098 0.126 Uiso 1 1 calc R U . . .
H5C H 0.735248 0.654143 0.819212 0.126 Uiso 1 1 calc R U . . .
C6 C 0.5935(4) 0.5625(4) 0.9116(4) 0.100(2) Uani 1 1 d . . . . .
H6A H 0.567567 0.611468 0.894861 0.151 Uiso 1 1 calc R U . . .
H6B H 0.567102 0.540927 0.950274 0.151 Uiso 1 1 calc R U . . .
H6C H 0.586258 0.532714 0.890114 0.151 Uiso 1 1 calc R U . . .
Si4 Si 0.63580(9) 0.61891(7) 1.04283(5) 0.0679(3) Uani 1 1 d . . . . .
C7 C 0.6434(5) 0.5197(4) 1.0857(3) 0.116(3) Uani 1 1 d . . . . .
H7A H 0.691923 0.508012 1.105673 0.174 Uiso 1 1 calc R U . . .
H7B H 0.649321 0.491450 1.061049 0.174 Uiso 1 1 calc R U . . .
H7C H 0.592782 0.507900 1.112722 0.174 Uiso 1 1 calc R U . . .
C8 C 0.6611(5) 0.6713(4) 1.0833(2) 0.0950(18) Uani 1 1 d . . . . .
H8A H 0.617586 0.667474 1.115234 0.143 Uiso 1 1 calc R U . . .
H8B H 0.664184 0.722296 1.059246 0.143 Uiso 1 1 calc R U . . .
H8C H 0.714813 0.651970 1.096729 0.143 Uiso 1 1 calc R U . . .
C9 C 0.5266(3) 0.6468(4) 1.0261(3) 0.0887(15) Uani 1 1 d . . . . .
H9A H 0.487526 0.634182 1.060870 0.133 Uiso 1 1 calc R U . . .
H9B H 0.514474 0.621477 1.002558 0.133 Uiso 1 1 calc R U . . .
H9C H 0.520680 0.699169 1.006153 0.133 Uiso 1 1 calc R U . . .
Si5 Si 0.89087(6) 1.02897(6) 0.79775(5) 0.0528(2) Uani 1 1 d . . . . .
Si6 Si 0.96898(8) 1.00616(7) 0.87050(6) 0.0638(3) Uani 1 1 d . . . . .
C10 C 1.0230(4) 0.9136(3) 0.8886(3) 0.0861(15) Uani 1 1 d . . . . .
H10A H 1.059941 0.909229 0.855731 0.129 Uiso 1 1 calc R U . . .
H10B H 0.981579 0.877748 0.900816 0.129 Uiso 1 1 calc R U . . .
H10C H 1.055797 0.905153 0.918886 0.129 Uiso 1 1 calc R U . . .
C11 C 0.9016(4) 1.0157(4) 0.9341(2) 0.0849(14) Uani 1 1 d . . . . .
H11A H 0.856030 0.983995 0.945029 0.127 Uiso 1 1 calc R U . . .
H11B H 0.878622 1.066115 0.925829 0.127 Uiso 1 1 calc R U . . .
H11C H 0.935040 1.002115 0.964799 0.127 Uiso 1 1 calc R U . . .
C12 C 1.0501(4) 1.0733(4) 0.8471(3) 0.0885(16) Uani 1 1 d . . . . .
H12A H 1.082588 1.064594 0.877621 0.133 Uiso 1 1 calc R U . . .
H12B H 1.022842 1.122526 0.836991 0.133 Uiso 1 1 calc R U . . .
H12C H 1.087203 1.067853 0.814629 0.133 Uiso 1 1 calc R U . . .
Si7 Si 0.97331(8) 1.00732(8) 0.72084(5) 0.0704(3) Uani 1 1 d . . . . .
C13 C 1.0297(3) 0.9152(3) 0.7419(2) 0.0808(13) Uani 1 1 d . . . . .
H13A H 0.990724 0.879253 0.765497 0.121 Uiso 1 1 calc R U . . .
H13B H 1.074428 0.914255 0.762927 0.121 Uiso 1 1 calc R U . . .
H13C H 1.053685 0.903682 0.708473 0.121 Uiso 1 1 calc R U . . .
C14 C 1.0545(5) 1.0755(4) 0.6875(3) 0.114(2) Uani 1 1 d . . . . .
H14A H 1.087291 1.074998 0.715821 0.170 Uiso 1 1 calc R U . . .
H14B H 1.026850 1.123982 0.671617 0.170 Uiso 1 1 calc R U . . .
H14C H 1.091422 1.062816 0.657734 0.170 Uiso 1 1 calc R U . . .
C15 C 0.9055(5) 1.0135(5) 0.6682(3) 0.114(3) Uani 1 1 d . . . . .
H15A H 0.939191 1.000883 0.637331 0.172 Uiso 1 1 calc R U . . .
H15B H 0.879713 1.062960 0.653689 0.172 Uiso 1 1 calc R U . . .
H15C H 0.861868 0.979736 0.685870 0.172 Uiso 1 1 calc R U . . .
Si8 Si 0.82203(8) 1.14541(6) 0.77151(6) 0.0647(3) Uani 1 1 d . . . . .
C16 C 0.7643(5) 1.1602(4) 0.7120(4) 0.113(3) Uani 1 1 d . . . . .
H16A H 0.731781 1.118739 0.720360 0.170 Uiso 1 1 calc R U . . .
H16B H 0.804014 1.165304 0.678026 0.170 Uiso 1 1 calc R U . . .
H16C H 0.726761 1.204365 0.706312 0.170 Uiso 1 1 calc R U . . .
C17 C 0.8973(4) 1.2160(3) 0.7487(4) 0.102(2) Uani 1 1 d . . . . .
H17A H 0.867253 1.264102 0.736970 0.152 Uiso 1 1 calc R U . . .
H17B H 0.937380 1.210680 0.717346 0.152 Uiso 1 1 calc R U . . .
H17C H 0.927024 1.210567 0.779876 0.152 Uiso 1 1 calc R U . . .
C18 C 0.7488(4) 1.1569(3) 0.8319(3) 0.099(2) Uani 1 1 d . . . . .
H18A H 0.708255 1.120244 0.844849 0.149 Uiso 1 1 calc R U . . .
H18B H 0.780119 1.151212 0.862372 0.149 Uiso 1 1 calc R U . . .
H18C H 0.719492 1.205311 0.820358 0.149 Uiso 1 1 calc R U . . .
Si9 Si 0.42546(6) 0.98783(6) 0.84538(4) 0.0524(2) Uani 1 1 d . . . . .
Si10 Si 0.44227(11) 1.11060(8) 0.82293(8) 0.0759(4) Uani 0.885(3) 1 d D U P A 1
C19 C 0.5314(6) 1.1361(5) 0.7636(4) 0.123(3) Uani 0.885(3) 1 d D . P A 1
H19A H 0.518875 1.125952 0.731724 0.185 Uiso 0.885(3) 1 calc R U P A 1
H19B H 0.538691 1.187850 0.752346 0.185 Uiso 0.885(3) 1 calc R U P A 1
H19C H 0.582747 1.107783 0.776050 0.185 Uiso 0.885(3) 1 calc R U P A 1
C20 C 0.4687(8) 1.1308(5) 0.8821(5) 0.119(4) Uani 0.885(3) 1 d D . P A 1
H20A H 0.519955 1.101960 0.894317 0.179 Uiso 0.885(3) 1 calc R U P A 1
H20B H 0.477003 1.182380 0.870156 0.179 Uiso 0.885(3) 1 calc R U P A 1
H20C H 0.423130 1.118572 0.913235 0.179 Uiso 0.885(3) 1 calc R U P A 1
C21 C 0.3447(6) 1.1653(4) 0.7994(6) 0.145(5) Uani 0.885(3) 1 d D . P A 1
H21A H 0.330947 1.154425 0.768165 0.217 Uiso 0.885(3) 1 calc R U P A 1
H21B H 0.298962 1.153103 0.830456 0.217 Uiso 0.885(3) 1 calc R U P A 1
H21C H 0.352834 1.216911 0.787377 0.217 Uiso 0.885(3) 1 calc R U P A 1
Si11 Si 0.36939(8) 0.96835(8) 0.77636(5) 0.0594(3) Uani 0.885(3) 1 d D U P A 1
C22 C 0.4322(5) 1.0122(5) 0.7076(2) 0.0901(19) Uani 0.885(3) 1 d D . P A 1
H22A H 0.490362 0.992407 0.708828 0.135 Uiso 0.885(3) 1 calc R U P A 1
H22B H 0.410246 1.002751 0.678290 0.135 Uiso 0.885(3) 1 calc R U P A 1
H22C H 0.429094 1.064569 0.699336 0.135 Uiso 0.885(3) 1 calc R U P A 1
C23 C 0.2587(4) 1.0078(5) 0.7721(4) 0.094(2) Uani 0.885(3) 1 d D . P A 1
H23A H 0.224382 0.985410 0.807955 0.142 Uiso 0.885(3) 1 calc R U P A 1
H23B H 0.256352 1.060155 0.763575 0.142 Uiso 0.885(3) 1 calc R U P A 1
H23C H 0.237503 0.998336 0.742529 0.142 Uiso 0.885(3) 1 calc R U P A 1
C24 C 0.3716(8) 0.8687(4) 0.7891(4) 0.0801(14) Uani 0.885(3) 1 d D . P A 1
H24A H 0.338719 0.844853 0.825263 0.120 Uiso 0.885(3) 1 calc R U P A 1
H24B H 0.347907 0.862040 0.759334 0.120 Uiso 0.885(3) 1 calc R U P A 1
H24C H 0.429252 0.847450 0.789458 0.120 Uiso 0.885(3) 1 calc R U P A 1
Si12 Si 0.34460(10) 0.93838(11) 0.93358(6) 0.0758(4) Uani 0.885(3) 1 d D U P A
1
C25 C 0.3881(6) 0.9453(8) 0.9918(3) 0.114(3) Uani 0.885(3) 1 d D . P A 1
H25A H 0.444774 0.921886 0.992729 0.171 Uiso 0.885(3) 1 calc R U P A 1
H25B H 0.389337 0.996486 0.986649 0.171 Uiso 0.885(3) 1 calc R U P A 1
H25C H 0.353281 0.921333 1.027025 0.171 Uiso 0.885(3) 1 calc R U P A 1
C26 C 0.2379(5) 0.9822(9) 0.9311(4) 0.171(6) Uani 0.885(3) 1 d D . P A 1
H26A H 0.215280 0.978172 0.899877 0.257 Uiso 0.885(3) 1 calc R U P A 1
H26B H 0.202842 0.958257 0.966220 0.257 Uiso 0.885(3) 1 calc R U P A 1
H26C H 0.238899 1.033409 0.925844 0.257 Uiso 0.885(3) 1 calc R U P A 1
C27 C 0.3416(8) 0.8364(6) 0.9492(4) 0.152(4) Uani 0.885(3) 1 d D . P A 1
H27A H 0.318719 0.829384 0.919276 0.228 Uiso 0.885(3) 1 calc R U P A 1
H27B H 0.398159 0.812857 0.951500 0.228 Uiso 0.885(3) 1 calc R U P A 1
H27C H 0.306346 0.815163 0.984891 0.228 Uiso 0.885(3) 1 calc R U P A 1
Si1A Si 0.4484(6) 1.0879(4) 0.7532(3) 0.060(3) Uani 0.115(3) 1 d D . P A 2
C19A C 0.463(4) 1.050(3) 0.6948(16) 0.0901(19) Uani 0.115(3) 1 d D U P A 2
H1A1 H 0.436797 1.004004 0.708279 0.135 Uiso 0.115(3) 1 calc R U P A 2
H1A2 H 0.435993 1.084517 0.663321 0.135 Uiso 0.115(3) 1 calc R U P A 2
H1A3 H 0.522088 1.042172 0.682692 0.135 Uiso 0.115(3) 1 calc R U P A 2
C20A C 0.497(3) 1.1747(18) 0.727(2) 0.18(4) Uani 0.115(3) 1 d D U P A 2
H1A4 H 0.556576 1.166599 0.714630 0.266 Uiso 0.115(3) 1 calc R U P A 2
H1A5 H 0.470245 1.209014 0.695791 0.266 Uiso 0.115(3) 1 calc R U P A 2
H1A6 H 0.490572 1.194482 0.757264 0.266 Uiso 0.115(3) 1 calc R U P A 2
C21A C 0.3351(16) 1.102(4) 0.777(4) 1.2(8) Uani 0.115(3) 1 d D U P A 2
H1A7 H 0.309799 1.055860 0.790957 1.745 Uiso 0.115(3) 1 calc R U P A 2
H1A8 H 0.328154 1.121826 0.807461 1.745 Uiso 0.115(3) 1 calc R U P A 2
H1A9 H 0.307827 1.136359 0.745987 1.745 Uiso 0.115(3) 1 calc R U P A 2
Si2A Si 0.3259(6) 0.9208(5) 0.8313(4) 0.062(3) Uani 0.115(3) 1 d D . P A 2
C22A C 0.372(5) 0.860(2) 0.792(2) 0.0801(14) Uani 0.115(3) 1 d D U P A 2
H2A1 H 0.417099 0.828110 0.810012 0.120 Uiso 0.115(3) 1 calc R U P A 2
H2A2 H 0.328917 0.831660 0.790114 0.120 Uiso 0.115(3) 1 calc R U P A 2
H2A3 H 0.394014 0.889942 0.753391 0.120 Uiso 0.115(3) 1 calc R U P A 2
C23A C 0.240(3) 0.982(4) 0.795(2) 0.094(2) Uani 0.115(3) 1 d D U P A 2
H2A4 H 0.214609 1.014098 0.814999 0.142 Uiso 0.115(3) 1 calc R U P A 2
H2A5 H 0.262433 1.010741 0.756508 0.142 Uiso 0.115(3) 1 calc R U P A 2
H2A6 H 0.197336 0.952460 0.793231 0.142 Uiso 0.115(3) 1 calc R U P A 2
C24A C 0.279(3) 0.863(2) 0.9031(9) 0.11(2) Uani 0.115(3) 1 d D U P A 2
H2A7 H 0.254459 0.894502 0.924535 0.168 Uiso 0.115(3) 1 calc R U P A 2
H2A8 H 0.235604 0.836326 0.899748 0.168 Uiso 0.115(3) 1 calc R U P A 2
H2A9 H 0.322445 0.829268 0.922350 0.168 Uiso 0.115(3) 1 calc R U P A 2
Si3A Si 0.3819(6) 1.0326(5) 0.9131(3) 0.057(2) Uani 0.115(3) 1 d D . P A 2
C25A C 0.443(5) 1.108(3) 0.903(4) 0.119(4) Uani 0.115(3) 1 d D U P A 2
H3A1 H 0.502418 1.092054 0.900270 0.179 Uiso 0.115(3) 1 calc R U P A 2
H3A2 H 0.431889 1.148013 0.868544 0.179 Uiso 0.115(3) 1 calc R U P A 2
H3A3 H 0.427288 1.124852 0.934844 0.179 Uiso 0.115(3) 1 calc R U P A 2
C26A C 0.2698(14) 1.062(4) 0.918(3) 0.171(6) Uani 0.115(3) 1 d D U P A 2
H3A4 H 0.237753 1.021218 0.923672 0.257 Uiso 0.115(3) 1 calc R U P A 2
H3A5 H 0.253793 1.078524 0.950176 0.257 Uiso 0.115(3) 1 calc R U P A 2
H3A6 H 0.258394 1.101685 0.883876 0.257 Uiso 0.115(3) 1 calc R U P A 2
C27A C 0.405(4) 0.960(5) 0.983(2) 0.114(3) Uani 0.115(3) 1 d D U P A 2
H3A7 H 0.374078 0.917610 0.990621 0.171 Uiso 0.115(3) 1 calc R U P A 2
H3A8 H 0.465035 0.944912 0.980698 0.171 Uiso 0.115(3) 1 calc R U P A 2
H3A9 H 0.388506 0.979430 1.013085 0.171 Uiso 0.115(3) 1 calc R U P A 2
Ge21 Ge 0.45182(3) 0.58473(2) 0.65138(2) 0.04991(10) Uani 1 1 d . . . . .
Ge22 Ge 0.35498(3) 0.53434(2) 0.60949(2) 0.05391(11) Uani 1 1 d . . . . .
Ge23 Ge 0.32405(3) 0.57365(2) 0.72772(2) 0.04975(10) Uani 1 1 d . . . . .
Ge24 Ge 0.43045(3) 0.71248(2) 0.64506(2) 0.05020(10) Uani 1 1 d . . . . .
Ge25 Ge 0.41514(3) 0.66101(2) 0.54941(2) 0.05443(11) Uani 1 1 d . . . . .
Ge26 Ge 0.25583(3) 0.64808(3) 0.55938(2) 0.05541(11) Uani 1 1 d . . . . .
Ge27 Ge 0.22122(3) 0.56591(2) 0.66601(2) 0.05203(10) Uani 1 1 d . . . . .
Ge28 Ge 0.30647(3) 0.74331(2) 0.59187(2) 0.04852(10) Uani 1 1 d . . . . .
Ge29 Ge 0.18215(3) 0.69134(2) 0.66174(2) 0.05200(10) Uani 1 1 d . . . . .
Rh2 Rh 0.29759(2) 0.70348(2) 0.70241(2) 0.04773(8) Uani 1 1 d . . . . .
C228 C 0.2863(2) 0.69498(19) 0.78423(16) 0.0520(7) Uani 1 1 d . . . . .
N201 N 0.2160(2) 0.70727(19) 0.81705(14) 0.0580(7) Uani 1 1 d . . . . .
N202 N 0.3468(2) 0.67980(17) 0.81763(13) 0.0518(6) Uani 1 1 d . . . . .
C229 C 0.2324(3) 0.6997(2) 0.86992(17) 0.0612(9) Uani 1 1 d . . . . .
C230 C 0.3145(3) 0.6833(2) 0.87013(16) 0.0576(8) Uani 1 1 d . . . . .
C231 C 0.1330(3) 0.7270(3) 0.7994(2) 0.0795(14) Uani 1 1 d . . . . .
H23G H 0.092466 0.732997 0.830430 0.119 Uiso 1 1 calc R U . . .
H23H H 0.133676 0.772633 0.767469 0.119 Uiso 1 1 calc R U . . .
H23I H 0.117327 0.688734 0.788643 0.119 Uiso 1 1 calc R U . . .
C233 C 0.3684(3) 0.6707(3) 0.91401(18) 0.0695(11) Uani 1 1 d . . . . .
H23J H 0.426310 0.659798 0.899768 0.104 Uiso 1 1 calc R U . . .
H23K H 0.364452 0.714291 0.923829 0.104 Uiso 1 1 calc R U . . .
H23L H 0.349919 0.629859 0.947270 0.104 Uiso 1 1 calc R U . . .
C232 C 0.1654(4) 0.7098(4) 0.9147(2) 0.0831(14) Uani 1 1 d . . . . .
H23M H 0.111491 0.721545 0.900601 0.125 Uiso 1 1 calc R U . . .
H23N H 0.163271 0.665007 0.947423 0.125 Uiso 1 1 calc R U . . .
H23O H 0.177587 0.749401 0.925399 0.125 Uiso 1 1 calc R U . . .
C234 C 0.4346(2) 0.6629(3) 0.80165(17) 0.0611(9) Uani 1 1 d . . . . .
H23P H 0.465016 0.654094 0.833137 0.092 Uiso 1 1 calc R U . . .
H23Q H 0.441416 0.619485 0.791404 0.092 Uiso 1 1 calc R U . . .
H23R H 0.456585 0.703686 0.769637 0.092 Uiso 1 1 calc R U . . .
Si21 Si 0.11522(6) 0.48318(6) 0.69347(5) 0.0558(2) Uani 1 1 d . . . . .
Si22 Si 0.02815(9) 0.51728(9) 0.76345(7) 0.0814(4) Uani 1 1 d . . . . .
C201 C -0.0482(4) 0.4480(4) 0.8031(3) 0.107(2) Uani 1 1 d . . . . .
H20D H -0.081919 0.442817 0.777246 0.160 Uiso 1 1 calc R U . . .
H20E H -0.018128 0.401435 0.821130 0.160 Uiso 1 1 calc R U . . .
H20F H -0.084654 0.463599 0.831606 0.160 Uiso 1 1 calc R U . . .
C202 C -0.0326(4) 0.6071(4) 0.7332(4) 0.113(3) Uani 1 1 d . . . . .
H20G H -0.067411 0.603583 0.707322 0.170 Uiso 1 1 calc R U . . .
H20H H -0.068124 0.619644 0.763513 0.170 Uiso 1 1 calc R U . . .
H20I H 0.006110 0.644620 0.713158 0.170 Uiso 1 1 calc R U . . .
C203 C 0.0929(5) 0.5278(5) 0.8123(3) 0.116(3) Uani 1 1 d . . . . .
H20J H 0.132702 0.564096 0.791260 0.174 Uiso 1 1 calc R U . . .
H20K H 0.056650 0.543455 0.840821 0.174 Uiso 1 1 calc R U . . .
H20L H 0.123176 0.481290 0.830344 0.174 Uiso 1 1 calc R U . . .
Si23 Si 0.17555(8) 0.36501(6) 0.73150(6) 0.0650(3) Uani 1 1 d . . . . .
C204 C 0.0973(4) 0.2969(3) 0.7466(3) 0.098(2) Uani 1 1 d . . . . .
H20M H 0.049789 0.305824 0.772756 0.148 Uiso 1 1 calc R U . . .
H20N H 0.077966 0.301358 0.711737 0.148 Uiso 1 1 calc R U . . .
H20O H 0.123341 0.247898 0.763226 0.148 Uiso 1 1 calc R U . . .
C205 C 0.2104(4) 0.3550(3) 0.7991(2) 0.0859(14) Uani 1 1 d . . . . .
H20P H 0.162502 0.364924 0.824554 0.129 Uiso 1 1 calc R U . . .
H20Q H 0.234729 0.305439 0.816077 0.129 Uiso 1 1 calc R U . . .
H20R H 0.252218 0.389265 0.792052 0.129 Uiso 1 1 calc R U . . .
C206 C 0.2650(4) 0.3465(3) 0.6817(3) 0.0842(14) Uani 1 1 d . . . . .
H20S H 0.245365 0.352034 0.646689 0.126 Uiso 1 1 calc R U . . .
H20T H 0.307085 0.380735 0.674119 0.126 Uiso 1 1 calc R U . . .
H20U H 0.289595 0.296909 0.698144 0.126 Uiso 1 1 calc R U . . .
Si24 Si 0.05109(9) 0.50147(8) 0.61510(7) 0.0757(3) Uani 1 1 d . . . . .
C207 C -0.0323(4) 0.4375(5) 0.6348(4) 0.109(2) Uani 1 1 d . . . . .
H21D H -0.007670 0.387552 0.648859 0.164 Uiso 1 1 calc R U . . .
H21E H -0.074155 0.446760 0.663973 0.164 Uiso 1 1 calc R U . . .
H21F H -0.058754 0.444698 0.601900 0.164 Uiso 1 1 calc R U . . .
C208 C 0.1280(4) 0.4850(4) 0.5580(3) 0.0958(18) Uani 1 1 d . . . . .
H21G H 0.154371 0.435564 0.571617 0.144 Uiso 1 1 calc R U . . .
H21H H 0.099462 0.490964 0.526227 0.144 Uiso 1 1 calc R U . . .
H21I H 0.170689 0.519669 0.546122 0.144 Uiso 1 1 calc R U . . .
C209 C 0.0017(6) 0.5950(5) 0.5888(4) 0.128(3) Uani 1 1 d . . . . .
H21J H -0.038851 0.604084 0.618659 0.193 Uiso 1 1 calc R U . . .
H21K H 0.044553 0.629592 0.576898 0.193 Uiso 1 1 calc R U . . .
H21L H -0.026675 0.600887 0.557004 0.193 Uiso 1 1 calc R U . . .
Si25 Si 0.28264(6) 0.86725(5) 0.53548(4) 0.04867(19) Uani 1 1 d . . . . .
Si26 Si 0.14165(7) 0.89273(7) 0.52368(5) 0.0608(2) Uani 1 1 d . . . . .
C210 C 0.1033(4) 0.8271(4) 0.4994(3) 0.0906(17) Uani 1 1 d . . . . .
H21M H 0.136969 0.826951 0.464283 0.136 Uiso 1 1 calc R U . . .
H21N H 0.107653 0.778495 0.527782 0.136 Uiso 1 1 calc R U . . .
H21O H 0.044923 0.841219 0.493493 0.136 Uiso 1 1 calc R U . . .
C211 C 0.1262(4) 0.9867(3) 0.4711(2) 0.0838(15) Uani 1 1 d . . . . .
H21P H 0.146339 1.021562 0.483633 0.126 Uiso 1 1 calc R U . . .
H21Q H 0.157471 0.988652 0.434782 0.126 Uiso 1 1 calc R U . . .
H21R H 0.066877 0.998709 0.467607 0.126 Uiso 1 1 calc R U . . .
C212 C 0.0768(3) 0.8925(3) 0.5909(2) 0.0808(14) Uani 1 1 d . . . . .
H21S H 0.096700 0.926999 0.603872 0.121 Uiso 1 1 calc R U . . .
H21T H 0.018466 0.906559 0.584821 0.121 Uiso 1 1 calc R U . . .
H21U H 0.081195 0.843835 0.619109 0.121 Uiso 1 1 calc R U . . .
Si27 Si 0.31154(8) 0.93750(6) 0.58455(5) 0.0596(2) Uani 1 1 d . . . . .
C213 C 0.2682(5) 1.0334(3) 0.5546(3) 0.0907(17) Uani 1 1 d . . . . .
H13E H 0.291876 1.054068 0.515178 0.136 Uiso 1 1 calc R U . . .
H13F H 0.207464 1.034897 0.557449 0.136 Uiso 1 1 calc R U . . .
H13G H 0.282408 1.061627 0.575318 0.136 Uiso 1 1 calc R U . . .
C214 C 0.4278(4) 0.9377(4) 0.5805(3) 0.0858(14) Uani 1 1 d . . . . .
H14D H 0.452661 0.957103 0.541312 0.129 Uiso 1 1 calc R U . . .
H14E H 0.439514 0.967911 0.600478 0.129 Uiso 1 1 calc R U . . .
H14F H 0.451706 0.888031 0.597772 0.129 Uiso 1 1 calc R U . . .
C215 C 0.2649(4) 0.9004(3) 0.6594(2) 0.0739(12) Uani 1 1 d . . . . .
H15D H 0.286790 0.849989 0.676000 0.111 Uiso 1 1 calc R U . . .
H15E H 0.279129 0.929225 0.679636 0.111 Uiso 1 1 calc R U . . .
H15F H 0.204185 0.902495 0.661767 0.111 Uiso 1 1 calc R U . . .
Si28 Si 0.36879(8) 0.88870(7) 0.44951(5) 0.0625(3) Uani 1 1 d . . . . .
C216 C 0.3383(5) 0.8359(4) 0.4110(3) 0.0979(19) Uani 1 1 d . . . . .
H16D H 0.279745 0.849124 0.405447 0.147 Uiso 1 1 calc R U . . .
H16E H 0.373247 0.846594 0.374585 0.147 Uiso 1 1 calc R U . . .
H16F H 0.345877 0.784052 0.432601 0.147 Uiso 1 1 calc R U . . .
C217 C 0.4807(3) 0.8637(3) 0.4603(3) 0.0884(16) Uani 1 1 d . . . . .
H17D H 0.496528 0.891720 0.480629 0.133 Uiso 1 1 calc R U . . .
H17E H 0.488331 0.811887 0.481913 0.133 Uiso 1 1 calc R U . . .
H17F H 0.515701 0.874430 0.423897 0.133 Uiso 1 1 calc R U . . .
C218 C 0.3594(4) 0.9879(3) 0.4064(2) 0.0887(17) Uani 1 1 d . . . . .
H18E H 0.375486 1.015809 0.426752 0.133 Uiso 1 1 calc R U . . .
H18D H 0.396134 0.996674 0.370816 0.133 Uiso 1 1 calc R U . . .
H18F H 0.301646 1.002815 0.399228 0.133 Uiso 1 1 calc R U . . .
Si29 Si 0.57860(6) 0.50788(5) 0.66184(4) 0.0505(2) Uani 1 1 d . . . . .
Si30 Si 0.68238(8) 0.56994(8) 0.67363(6) 0.0636(3) Uani 0.881(3) 1 d D U P B 1
C219 C 0.7357(5) 0.6261(5) 0.6045(4) 0.097(2) Uani 0.881(3) 1 d D . P B 1
H19D H 0.759088 0.595165 0.582719 0.146 Uiso 0.881(3) 1 calc R U P B 1
H19E H 0.695366 0.663237 0.584270 0.146 Uiso 0.881(3) 1 calc R U P B 1
H19F H 0.780501 0.649549 0.610244 0.146 Uiso 0.881(3) 1 calc R U P B 1
C220 C 0.7615(4) 0.5029(6) 0.7140(4) 0.091(2) Uani 0.881(3) 1 d D . P B 1
H201 H 0.785594 0.469837 0.694086 0.137 Uiso 0.881(3) 1 calc R U P B 1
H202 H 0.805664 0.528781 0.717702 0.137 Uiso 0.881(3) 1 calc R U P B 1
H203 H 0.734409 0.475124 0.751205 0.137 Uiso 0.881(3) 1 calc R U P B 1
C221 C 0.6390(5) 0.6309(3) 0.7134(4) 0.0667(18) Uani 0.881(3) 1 d D . P B 1
H22P H 0.610623 0.602599 0.749986 0.100 Uiso 0.881(3) 1 calc R U P B 1
H22Q H 0.684375 0.654316 0.718551 0.100 Uiso 0.881(3) 1 calc R U P B 1
H22R H 0.599240 0.668003 0.692576 0.100 Uiso 0.881(3) 1 calc R U P B 1
Si31 Si 0.54748(8) 0.41146(7) 0.74678(6) 0.0624(3) Uani 0.881(3) 1 d D U P B 1
C222 C 0.4473(5) 0.3733(5) 0.7493(5) 0.080(2) Uani 0.881(3) 1 d D . P B 1
H22S H 0.451738 0.355754 0.718165 0.119 Uiso 0.881(3) 1 calc R U P B 1
H22T H 0.436533 0.333092 0.784772 0.119 Uiso 0.881(3) 1 calc R U P B 1
H22U H 0.401433 0.411189 0.746418 0.119 Uiso 0.881(3) 1 calc R U P B 1
C223 C 0.6320(4) 0.3359(4) 0.7555(3) 0.0920(19) Uani 0.881(3) 1 d D . P B 1
H23S H 0.638066 0.318435 0.724189 0.138 Uiso 0.881(3) 1 calc R U P B 1
H23T H 0.684636 0.353601 0.756309 0.138 Uiso 0.881(3) 1 calc R U P B 1
H23U H 0.617527 0.296172 0.790656 0.138 Uiso 0.881(3) 1 calc R U P B 1
C224 C 0.5366(5) 0.4441(4) 0.8065(3) 0.0874(17) Uani 0.881(3) 1 d D . P B 1
H24G H 0.492486 0.483634 0.802132 0.131 Uiso 0.881(3) 1 calc R U P B 1
H24H H 0.522239 0.404241 0.841515 0.131 Uiso 0.881(3) 1 calc R U P B 1
H24I H 0.589349 0.461670 0.807168 0.131 Uiso 0.881(3) 1 calc R U P B 1
Si32 Si 0.62229(9) 0.46320(9) 0.58893(6) 0.0687(4) Uani 0.881(3) 1 d D U P B 1
C225 C 0.5545(5) 0.3913(5) 0.5950(4) 0.094(2) Uani 0.881(3) 1 d D . P B 1
H25G H 0.556648 0.352226 0.631243 0.141 Uiso 0.881(3) 1 calc R U P B 1
H25H H 0.496970 0.412209 0.591889 0.141 Uiso 0.881(3) 1 calc R U P B 1
H25I H 0.574433 0.371812 0.564929 0.141 Uiso 0.881(3) 1 calc R U P B 1
C226 C 0.7327(4) 0.4199(4) 0.5945(3) 0.092(2) Uani 0.881(3) 1 d D . P B 1
H26J H 0.734166 0.380502 0.630677 0.137 Uiso 0.881(3) 1 calc R U P B 1
H26K H 0.751179 0.400446 0.564317 0.137 Uiso 0.881(3) 1 calc R U P B 1
H26L H 0.769737 0.456312 0.591406 0.137 Uiso 0.881(3) 1 calc R U P B 1
C227 C 0.6192(5) 0.5385(5) 0.5198(3) 0.094(2) Uani 0.881(3) 1 d D . P B 1
H27M H 0.654796 0.575731 0.517195 0.141 Uiso 0.881(3) 1 calc R U P B 1
H27N H 0.639254 0.519404 0.489625 0.141 Uiso 0.881(3) 1 calc R U P B 1
H27O H 0.561791 0.559801 0.516585 0.141 Uiso 0.881(3) 1 calc R U P B 1
Si1B Si 0.6351(5) 0.5306(4) 0.7250(3) 0.0478(19) Uani 0.119(3) 1 d D . P B 2
C19B C 0.628(5) 0.6302(10) 0.709(3) 0.0667(18) Uani 0.119(3) 1 d D U P B 2
H1B1 H 0.659911 0.653657 0.672858 0.100 Uiso 0.119(3) 1 calc R U P B 2
H1B2 H 0.569433 0.649303 0.708876 0.100 Uiso 0.119(3) 1 calc R U P B 2
H1B3 H 0.650488 0.639968 0.738291 0.100 Uiso 0.119(3) 1 calc R U P B 2
C20B C 0.7465(15) 0.493(4) 0.730(2) 0.091(2) Uani 0.119(3) 1 d D U P B 2
H1B4 H 0.780341 0.514945 0.693534 0.137 Uiso 0.119(3) 1 calc R U P B 2
H1B5 H 0.767106 0.505376 0.758366 0.137 Uiso 0.119(3) 1 calc R U P B 2
H1B6 H 0.750067 0.440766 0.739802 0.137 Uiso 0.119(3) 1 calc R U P B 2
C21B C 0.574(2) 0.4883(19) 0.7945(9) 0.075(11) Uani 0.119(3) 1 d D U P B 2
H1B7 H 0.576524 0.435779 0.803627 0.112 Uiso 0.119(3) 1 calc R U P B 2
H1B8 H 0.596479 0.498760 0.823009 0.112 Uiso 0.119(3) 1 calc R U P B 2
H1B9 H 0.515425 0.508095 0.793593 0.112 Uiso 0.119(3) 1 calc R U P B 2
Si2B Si 0.5499(7) 0.3908(4) 0.6837(5) 0.073(3) Uani 0.119(3) 1 d D . P B 2
C22B C 0.453(2) 0.383(4) 0.7360(18) 0.11(4) Uani 0.119(3) 1 d D U P B 2
H2B1 H 0.464044 0.395785 0.767093 0.168 Uiso 0.119(3) 1 calc R U P B 2
H2B2 H 0.407941 0.415760 0.718050 0.168 Uiso 0.119(3) 1 calc R U P B 2
H2B3 H 0.437263 0.332967 0.750282 0.168 Uiso 0.119(3) 1 calc R U P B 2
C23B C 0.633(3) 0.324(2) 0.720(2) 0.12(3) Uani 0.119(3) 1 d D U P B 2
H2B4 H 0.645149 0.337391 0.750388 0.180 Uiso 0.119(3) 1 calc R U P B 2
H2B5 H 0.613856 0.275634 0.734473 0.180 Uiso 0.119(3) 1 calc R U P B 2
H2B6 H 0.683736 0.325810 0.692831 0.180 Uiso 0.119(3) 1 calc R U P B 2
C24B C 0.527(3) 0.366(3) 0.6255(18) 0.094(2) Uani 0.119(3) 1 d D U P B 2
H2B7 H 0.483986 0.400622 0.606575 0.141 Uiso 0.119(3) 1 calc R U P B 2
H2B8 H 0.578144 0.367362 0.598746 0.141 Uiso 0.119(3) 1 calc R U P B 2
H2B9 H 0.508264 0.317185 0.640388 0.141 Uiso 0.119(3) 1 calc R U P B 2
Si3B Si 0.6625(7) 0.5489(7) 0.5694(3) 0.087(4) Uani 0.119(3) 1 d D . P B 2
C25B C 0.646(6) 0.576(3) 0.4945(15) 0.32(10) Uani 0.119(3) 1 d D U P B 2
H3B1 H 0.613147 0.541345 0.490538 0.474 Uiso 0.119(3) 1 calc R U P B 2
H3B2 H 0.616350 0.624558 0.482750 0.474 Uiso 0.119(3) 1 calc R U P B 2
H3B3 H 0.700168 0.577459 0.471001 0.474 Uiso 0.119(3) 1 calc R U P B 2
C26B C 0.723(3) 0.4562(18) 0.589(2) 0.092(2) Uani 0.119(3) 1 d D U P B 2
H3B4 H 0.732454 0.440136 0.627823 0.137 Uiso 0.119(3) 1 calc R U P B 2
H3B5 H 0.690419 0.421462 0.583960 0.137 Uiso 0.119(3) 1 calc R U P B 2
H3B6 H 0.776272 0.459413 0.564485 0.137 Uiso 0.119(3) 1 calc R U P B 2
C27B C 0.726(4) 0.615(3) 0.578(4) 0.28(7) Uani 0.119(3) 1 d D U P B 2
H3B7 H 0.733804 0.600727 0.616928 0.418 Uiso 0.119(3) 1 calc R U P B 2
H3B8 H 0.779761 0.616647 0.554348 0.418 Uiso 0.119(3) 1 calc R U P B 2
H3B9 H 0.695943 0.663746 0.566097 0.418 Uiso 0.119(3) 1 calc R U P B 2
C1T C 0.8987(11) 0.8170(7) 1.0718(6) 0.197(5) Uani 1 1 d . U . C 1
H1T1 H 0.871023 0.855703 1.042984 0.296 Uiso 1 1 calc R U . C 1
H1T2 H 0.876603 0.770769 1.078398 0.296 Uiso 1 1 calc R U . C 1
H1T3 H 0.888282 0.827562 1.106583 0.296 Uiso 1 1 calc R U . C 1
C2T C 0.9940(12) 0.8121(7) 1.0521(5) 0.201(5) Uani 1 1 d . U . C 1
H2T1 H 1.003878 0.802598 1.016546 0.241 Uiso 1 1 calc R U . C 1
H2T2 H 1.015552 0.859367 1.044719 0.241 Uiso 1 1 calc R U . C 1
C3T C 1.1864(9) 0.7022(8) 1.1111(5) 0.188(4) Uani 1 1 d . U . C 1
H3T1 H 1.166162 0.653203 1.124810 0.225 Uiso 1 1 calc R U . C 1
H3T2 H 1.175802 0.719904 1.142851 0.225 Uiso 1 1 calc R U . C 1
C4T C 1.0353(9) 0.7612(5) 1.0888(4) 0.167(3) Uani 1 1 d . U . C 1
H4T1 H 1.010436 0.714836 1.098268 0.201 Uiso 1 1 calc R U . C 1
H4T2 H 1.028223 0.772885 1.123366 0.201 Uiso 1 1 calc R U . C 1
C5T C 1.1363(10) 0.7502(8) 1.0677(5) 0.206(5) Uani 1 1 d . U . C 1
H5T1 H 1.143241 0.730404 1.037091 0.248 Uiso 1 1 calc R U . C 1
H5T2 H 1.158936 0.798303 1.051883 0.248 Uiso 1 1 calc R U . C 1
C6T C 1.2795(9) 0.6953(7) 1.0940(6) 0.197(5) Uani 1 1 d . U . C 1
H6T1 H 1.306098 0.662311 1.125960 0.295 Uiso 1 1 calc R U . C 1
H6T2 H 1.291483 0.676114 1.063383 0.295 Uiso 1 1 calc R U . C 1
H6T3 H 1.301157 0.743047 1.081486 0.295 Uiso 1 1 calc R U . C 1
C1S C 1.0239(15) 0.7242(9) 0.4346(6) 0.398(12) Uani 1 1 d D U . D 1
H1S1 H 1.064771 0.699583 0.413611 0.596 Uiso 1 1 calc R U . D 1
H1S2 H 1.035348 0.775159 0.422461 0.596 Uiso 1 1 calc R U . D 1
H1S3 H 1.027731 0.700869 0.474625 0.596 Uiso 1 1 calc R U . D 1
C2S C 0.9391(14) 0.7197(9) 0.4242(8) 0.328(9) Uani 1 1 d D U . D 1
H2S1 H 0.932551 0.667404 0.434733 0.394 Uiso 1 1 calc R U . D 1
H2S2 H 0.940089 0.740917 0.383115 0.394 Uiso 1 1 calc R U . D 1
C3S C 0.8598(15) 0.7506(11) 0.4486(7) 0.378(11) Uani 1 1 d D U . D 1
H3S1 H 0.868081 0.797622 0.451164 0.453 Uiso 1 1 calc R U . D 1
H3S2 H 0.840596 0.717116 0.486501 0.453 Uiso 1 1 calc R U . D 1
C4S C 0.7971(16) 0.7607(17) 0.4096(9) 0.390(11) Uani 1 1 d D U . D 1
H4S1 H 0.802489 0.808849 0.379852 0.468 Uiso 1 1 calc R U . D 1
H4S2 H 0.812116 0.723913 0.391503 0.468 Uiso 1 1 calc R U . D 1
C5S C 0.7094(17) 0.7557(19) 0.4346(9) 0.424(13) Uani 1 1 d D U . D 1
H5S1 H 0.700208 0.705258 0.459405 0.508 Uiso 1 1 calc R U . D 1
H5S2 H 0.694771 0.787329 0.457256 0.508 Uiso 1 1 calc R U . D 1
C6S C 0.6568(17) 0.7780(14) 0.3903(11) 0.466(16) Uani 1 1 d D U . D 1
H6S1 H 0.598175 0.774674 0.406968 0.699 Uiso 1 1 calc R U . D 1
H6S2 H 0.665653 0.828138 0.366075 0.699 Uiso 1 1 calc R U . D 1
H6S3 H 0.671077 0.746267 0.368218 0.699 Uiso 1 1 calc R U . D 1


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ge1 Si9 2.3947(10) . ?
Ge1 Ge3 2.4666(6) . ?
Ge1 Ge5 2.5548(6) . ?
Ge1 Ge4 2.5886(6) . ?
Ge1 Ge2 2.6463(6) . ?
Ge2 Ge6 2.6069(7) . ?
Ge2 Ge7 2.6195(6) . ?
Ge2 Ge5 2.6379(7) . ?
Ge3 Rh1 2.3971(5) . ?
Ge3 Ge7 2.5270(6) . ?
Ge4 Rh1 2.4176(5) . ?
Ge4 Ge8 2.5681(6) . ?
Ge5 Ge8 2.5559(6) . ?
Ge5 Ge6 2.6448(6) . ?
Ge6 Ge7 2.6306(6) . ?
Ge6 Ge8 2.6593(6) . ?
Ge8 Si5 2.3917(11) . ?
Ge8 Ge9 2.4599(6) . ?
Ge7 Si1 2.3812(10) . ?
Ge7 Ge9 2.5269(6) . ?
Ge7 Rh1 2.6669(5) . ?
Ge9 Rh1 2.3985(5) . ?
Rh1 C28 2.036(4) . ?
C28 N2 1.357(5) . ?
C28 N1 1.371(5) . ?
N1 C29 1.387(5) . ?
N1 C31 1.463(6) . ?
N2 C30 1.398(5) . ?
N2 C34 1.454(5) . ?
C29 C30 1.345(6) . ?
C29 C32 1.491(5) . ?
C30 C33 1.487(6) . ?
C31 H31A 0.9800 . ?
C31 H31B 0.9800 . ?
C31 H31C 0.9800 . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32 H32C 0.9800 . ?
C33 H33A 0.9800 . ?
C33 H33B 0.9800 . ?
C33 H33C 0.9800 . ?
C34 H34A 0.9800 . ?
C34 H34B 0.9800 . ?
C34 H34C 0.9800 . ?
Si1 Si4 2.3424(15) . ?
Si1 Si2 2.3440(16) . ?
Si1 Si3 2.3463(16) . ?
Si2 C2 1.860(7) . ?
Si2 C3 1.873(6) . ?
Si2 C1 1.878(7) . ?
C1 H1A 0.9800 . ?
C1 H1B 0.9800 . ?
C1 H1C 0.9800 . ?
C2 H2A 0.9800 . ?
C2 H2B 0.9800 . ?
C2 H2C 0.9800 . ?
C3 H3A 0.9800 . ?
C3 H3B 0.9800 . ?
C3 H3C 0.9800 . ?
Si3 C6 1.868(6) . ?
Si3 C5 1.872(6) . ?
Si3 C4 1.879(6) . ?
C4 H4A 0.9800 . ?
C4 H4B 0.9800 . ?
C4 H4C 0.9800 . ?
C5 H5A 0.9800 . ?
C5 H5B 0.9800 . ?
C5 H5C 0.9800 . ?
C6 H6A 0.9800 . ?
C6 H6B 0.9800 . ?
C6 H6C 0.9800 . ?
Si4 C8 1.852(7) . ?
Si4 C9 1.875(6) . ?
Si4 C7 1.878(6) . ?
C7 H7A 0.9800 . ?
C7 H7B 0.9800 . ?
C7 H7C 0.9800 . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
Si5 Si6 2.3379(15) . ?
Si5 Si8 2.3455(15) . ?
Si5 Si7 2.3467(17) . ?
Si6 C10 1.860(6) . ?
Si6 C11 1.873(6) . ?
Si6 C12 1.878(6) . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
Si7 C15 1.868(7) . ?
Si7 C13 1.869(6) . ?
Si7 C14 1.894(7) . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C13 H13C 0.9800 . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
Si8 C17 1.858(6) . ?
Si8 C16 1.862(6) . ?
Si8 C18 1.863(7) . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
Si9 Si3A 2.217(6) . ?
Si9 Si11 2.3200(16) . ?
Si9 Si10 2.3390(19) . ?
Si9 Si12 2.3664(18) . ?
Si9 Si2A 2.394(7) . ?
Si9 Si1A 2.497(7) . ?
Si10 C20 1.855(10) . ?
Si10 C21 1.867(7) . ?
Si10 C19 1.896(10) . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C21 H21A 0.9800 . ?
C21 H21B 0.9800 . ?
C21 H21C 0.9800 . ?
Si11 C22 1.862(6) . ?
Si11 C23 1.878(6) . ?
Si11 C24 1.883(8) . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
Si12 C25 1.833(12) . ?
Si12 C26 1.841(7) . ?
Si12 C27 1.924(11) . ?
C25 H25A 0.9800 . ?
C25 H25B 0.9800 . ?
C25 H25C 0.9800 . ?
C26 H26A 0.9800 . ?
C26 H26B 0.9800 . ?
C26 H26C 0.9800 . ?
C27 H27A 0.9800 . ?
C27 H27B 0.9800 . ?
C27 H27C 0.9800 . ?
Si1A C20A 1.848(14) . ?
Si1A C21A 1.867(13) . ?
Si1A C19A 1.889(14) . ?
C19A H1A1 0.9800 . ?
C19A H1A2 0.9800 . ?
C19A H1A3 0.9800 . ?
C20A H1A4 0.9800 . ?
C20A H1A5 0.9800 . ?
C20A H1A6 0.9800 . ?
C21A H1A7 0.9800 . ?
C21A H1A8 0.9800 . ?
C21A H1A9 0.9800 . ?
Si2A C22A 1.860(12) . ?
Si2A C23A 1.877(11) . ?
Si2A C24A 1.882(11) . ?
C22A H2A1 0.9800 . ?
C22A H2A2 0.9800 . ?
C22A H2A3 0.9800 . ?
C23A H2A4 0.9800 . ?
C23A H2A5 0.9800 . ?
C23A H2A6 0.9800 . ?
C24A H2A7 0.9800 . ?
C24A H2A8 0.9800 . ?
C24A H2A9 0.9800 . ?
Si3A C25A 1.834(15) . ?
Si3A C26A 1.843(12) . ?
Si3A C27A 1.925(15) . ?
C25A H3A1 0.9800 . ?
C25A H3A2 0.9800 . ?
C25A H3A3 0.9800 . ?
C26A H3A4 0.9800 . ?
C26A H3A5 0.9800 . ?
C26A H3A6 0.9800 . ?
C27A H3A7 0.9800 . ?
C27A H3A8 0.9800 . ?
C27A H3A9 0.9800 . ?
Ge21 Si29 2.3958(10) . ?
Ge21 Ge24 2.4665(6) . ?
Ge21 Ge22 2.5567(6) . ?
Ge21 Ge23 2.5866(6) . ?
Ge21 Ge25 2.6526(6) . ?
Ge22 Ge27 2.5496(6) . ?
Ge22 Ge25 2.6497(6) . ?
Ge22 Ge26 2.6512(6) . ?
Ge23 Rh2 2.4178(5) . ?
Ge23 Ge27 2.5724(6) . ?
Ge24 Rh2 2.3966(5) . ?
Ge24 Ge28 2.5341(6) . ?
Ge25 Ge26 2.6125(7) . ?
Ge25 Ge28 2.6242(6) . ?
Ge26 Ge28 2.6140(6) . ?
Ge26 Ge27 2.6539(6) . ?
Ge27 Si21 2.3910(11) . ?
Ge27 Ge29 2.4569(6) . ?
Ge28 Si25 2.3823(10) . ?
Ge28 Ge29 2.5299(6) . ?
Ge28 Rh2 2.6638(5) . ?
Ge29 Rh2 2.3984(5) . ?
Rh2 C228 2.044(4) . ?
C228 N201 1.356(5) . ?
C228 N202 1.361(5) . ?
N201 C229 1.394(5) . ?
N201 C231 1.466(6) . ?
N202 C230 1.395(5) . ?
N202 C234 1.451(5) . ?
C229 C230 1.339(6) . ?
C229 C232 1.501(6) . ?
C230 C233 1.491(6) . ?
C231 H23G 0.9800 . ?
C231 H23H 0.9800 . ?
C231 H23I 0.9800 . ?
C233 H23J 0.9800 . ?
C233 H23K 0.9800 . ?
C233 H23L 0.9800 . ?
C232 H23M 0.9800 . ?
C232 H23N 0.9800 . ?
C232 H23O 0.9800 . ?
C234 H23P 0.9800 . ?
C234 H23Q 0.9800 . ?
C234 H23R 0.9800 . ?
Si21 Si24 2.3395(18) . ?
Si21 Si23 2.3426(16) . ?
Si21 Si22 2.3476(18) . ?
Si22 C203 1.870(8) . ?
Si22 C201 1.871(6) . ?
Si22 C202 1.886(7) . ?
C201 H20D 0.9800 . ?
C201 H20E 0.9800 . ?
C201 H20F 0.9800 . ?
C202 H20G 0.9800 . ?
C202 H20H 0.9800 . ?
C202 H20I 0.9800 . ?
C203 H20J 0.9800 . ?
C203 H20K 0.9800 . ?
C203 H20L 0.9800 . ?
Si23 C206 1.866(6) . ?
Si23 C205 1.872(6) . ?
Si23 C204 1.883(6) . ?
C204 H20M 0.9800 . ?
C204 H20N 0.9800 . ?
C204 H20O 0.9800 . ?
C205 H20P 0.9800 . ?
C205 H20Q 0.9800 . ?
C205 H20R 0.9800 . ?
C206 H20S 0.9800 . ?
C206 H20T 0.9800 . ?
C206 H20U 0.9800 . ?
Si24 C209 1.854(8) . ?
Si24 C208 1.863(7) . ?
Si24 C207 1.870(7) . ?
C207 H21D 0.9800 . ?
C207 H21E 0.9800 . ?
C207 H21F 0.9800 . ?
C208 H21G 0.9800 . ?
C208 H21H 0.9800 . ?
C208 H21I 0.9800 . ?
C209 H21J 0.9800 . ?
C209 H21K 0.9800 . ?
C209 H21L 0.9800 . ?
Si25 Si26 2.3424(14) . ?
Si25 Si27 2.3436(15) . ?
Si25 Si28 2.3465(14) . ?
Si26 C210 1.860(6) . ?
Si26 C212 1.874(5) . ?
Si26 C211 1.883(6) . ?
C210 H21M 0.9800 . ?
C210 H21N 0.9800 . ?
C210 H21O 0.9800 . ?
C211 H21P 0.9800 . ?
C211 H21Q 0.9800 . ?
C211 H21R 0.9800 . ?
C212 H21S 0.9800 . ?
C212 H21T 0.9800 . ?
C212 H21U 0.9800 . ?
Si27 C215 1.866(5) . ?
Si27 C213 1.868(5) . ?
Si27 C214 1.888(6) . ?
C213 H13E 0.9800 . ?
C213 H13F 0.9800 . ?
C213 H13G 0.9800 . ?
C214 H14D 0.9800 . ?
C214 H14E 0.9800 . ?
C214 H14F 0.9800 . ?
C215 H15D 0.9800 . ?
C215 H15E 0.9800 . ?
C215 H15F 0.9800 . ?
Si28 C216 1.854(7) . ?
Si28 C217 1.872(6) . ?
Si28 C218 1.879(5) . ?
C216 H16D 0.9800 . ?
C216 H16E 0.9800 . ?
C216 H16F 0.9800 . ?
C217 H17D 0.9800 . ?
C217 H17E 0.9800 . ?
C217 H17F 0.9800 . ?
C218 H18E 0.9800 . ?
C218 H18D 0.9800 . ?
C218 H18F 0.9800 . ?
Si29 Si1B 2.221(6) . ?
Si29 Si2B 2.282(8) . ?
Si29 Si32 2.3362(16) . ?
Si29 Si30 2.3531(16) . ?
Si29 Si31 2.3619(16) . ?
Si29 Si3B 2.454(8) . ?
Si30 C221 1.860(7) . ?
Si30 C219 1.865(8) . ?
Si30 C220 1.880(6) . ?
C219 H19D 0.9800 . ?
C219 H19E 0.9800 . ?
C219 H19F 0.9800 . ?
C220 H201 0.9800 . ?
C220 H202 0.9800 . ?
C220 H203 0.9800 . ?
C221 H22P 0.9800 . ?
C221 H22Q 0.9800 . ?
C221 H22R 0.9800 . ?
Si31 C224 1.859(7) . ?
Si31 C223 1.875(6) . ?
Si31 C222 1.880(8) . ?
C222 H22S 0.9800 . ?
C222 H22T 0.9800 . ?
C222 H22U 0.9800 . ?
C223 H23S 0.9800 . ?
C223 H23T 0.9800 . ?
C223 H23U 0.9800 . ?
C224 H24G 0.9800 . ?
C224 H24H 0.9800 . ?
C224 H24I 0.9800 . ?
Si32 C227 1.873(8) . ?
Si32 C225 1.874(8) . ?
Si32 C226 1.898(6) . ?
C225 H25G 0.9800 . ?
C225 H25H 0.9800 . ?
C225 H25I 0.9800 . ?
C226 H26J 0.9800 . ?
C226 H26K 0.9800 . ?
C226 H26L 0.9800 . ?
C227 H27M 0.9800 . ?
C227 H27N 0.9800 . ?
C227 H27O 0.9800 . ?
Si1B C21B 1.859(11) . ?
Si1B C19B 1.864(13) . ?
Si1B C20B 1.877(11) . ?
C19B H1B1 0.9800 . ?
C19B H1B2 0.9800 . ?
C19B H1B3 0.9800 . ?
C20B H1B4 0.9800 . ?
C20B H1B5 0.9800 . ?
C20B H1B6 0.9800 . ?
C21B H1B7 0.9800 . ?
C21B H1B8 0.9800 . ?
C21B H1B9 0.9800 . ?
Si2B C24B 1.856(12) . ?
Si2B C23B 1.876(11) . ?
Si2B C22B 1.879(12) . ?
C22B H2B1 0.9800 . ?
C22B H2B2 0.9800 . ?
C22B H2B3 0.9800 . ?
C23B H2B4 0.9800 . ?
C23B H2B5 0.9800 . ?
C23B H2B6 0.9800 . ?
C24B H2B7 0.9800 . ?
C24B H2B8 0.9800 . ?
C24B H2B9 0.9800 . ?
Si3B C25B 1.875(13) . ?
Si3B C27B 1.877(13) . ?
Si3B C26B 1.903(12) . ?
C25B H3B1 0.9800 . ?
C25B H3B2 0.9800 . ?
C25B H3B3 0.9800 . ?
C26B H3B4 0.9800 . ?
C26B H3B5 0.9800 . ?
C26B H3B6 0.9800 . ?
C27B H3B7 0.9800 . ?
C27B H3B8 0.9800 . ?
C27B H3B9 0.9800 . ?
C1T C2T 1.55(2) . ?
C1T H1T1 0.9800 . ?
C1T H1T2 0.9800 . ?
C1T H1T3 0.9800 . ?
C2T C4T 1.313(17) . ?
C2T H2T1 0.9900 . ?
C2T H2T2 0.9900 . ?
C3T C5T 1.48(2) . ?
C3T C6T 1.511(17) . ?
C3T H3T1 0.9900 . ?
C3T H3T2 0.9900 . ?
C4T C5T 1.658(18) . ?
C4T H4T1 0.9900 . ?
C4T H4T2 0.9900 . ?
C5T H5T1 0.9900 . ?
C5T H5T2 0.9900 . ?
C6T H6T1 0.9800 . ?
C6T H6T2 0.9800 . ?
C6T H6T3 0.9800 . ?
C1S C2S 1.480(16) . ?
C1S H1S1 0.9800 . ?
C1S H1S2 0.9800 . ?
C1S H1S3 0.9800 . ?
C2S C3S 1.498(16) . ?
C2S H2S1 0.9900 . ?
C2S H2S2 0.9900 . ?
C3S C4S 1.508(16) . ?
C3S H3S1 0.9900 . ?
C3S H3S2 0.9900 . ?
C4S C5S 1.467(17) . ?
C4S H4S1 0.9900 . ?
C4S H4S2 0.9900 . ?
C5S C6S 1.458(17) . ?
C5S H5S1 0.9900 . ?
C5S H5S2 0.9900 . ?
C6S H6S1 0.9800 . ?
C6S H6S2 0.9800 . ?
C6S H6S3 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Si9 Ge1 Ge3 124.69(3) . . ?
Si9 Ge1 Ge5 110.36(3) . . ?
Ge3 Ge1 Ge5 120.37(2) . . ?
Si9 Ge1 Ge4 128.34(3) . . ?
Ge3 Ge1 Ge4 81.407(18) . . ?
Ge5 Ge1 Ge4 81.804(19) . . ?
Si9 Ge1 Ge2 116.35(3) . . ?
Ge3 Ge1 Ge2 74.700(18) . . ?
Ge5 Ge1 Ge2 60.922(18) . . ?
Ge4 Ge1 Ge2 113.26(2) . . ?
Ge6 Ge2 Ge7 60.441(17) . . ?
Ge6 Ge2 Ge5 60.563(18) . . ?
Ge7 Ge2 Ge5 98.83(2) . . ?
Ge6 Ge2 Ge1 103.11(2) . . ?
Ge7 Ge2 Ge1 88.734(18) . . ?
Ge5 Ge2 Ge1 57.825(17) . . ?
Rh1 Ge3 Ge1 96.614(19) . . ?
Rh1 Ge3 Ge7 65.523(15) . . ?
Ge1 Ge3 Ge7 95.01(2) . . ?
Rh1 Ge4 Ge8 91.787(18) . . ?
Rh1 Ge4 Ge1 92.959(18) . . ?
Ge8 Ge4 Ge1 94.30(2) . . ?
Ge1 Ge5 Ge8 95.41(2) . . ?
Ge1 Ge5 Ge2 61.253(17) . . ?
Ge8 Ge5 Ge2 104.45(2) . . ?
Ge1 Ge5 Ge6 104.60(2) . . ?
Ge8 Ge5 Ge6 61.476(17) . . ?
Ge2 Ge5 Ge6 59.138(17) . . ?
Ge2 Ge6 Ge7 60.016(17) . . ?
Ge2 Ge6 Ge5 60.299(17) . . ?
Ge7 Ge6 Ge5 98.371(19) . . ?
Ge2 Ge6 Ge8 102.45(2) . . ?
Ge7 Ge6 Ge8 88.381(18) . . ?
Ge5 Ge6 Ge8 57.616(17) . . ?
Si5 Ge8 Ge9 120.54(3) . . ?
Si5 Ge8 Ge5 114.69(3) . . ?
Ge9 Ge8 Ge5 120.18(2) . . ?
Si5 Ge8 Ge4 126.09(3) . . ?
Ge9 Ge8 Ge4 83.413(19) . . ?
Ge5 Ge8 Ge4 82.182(19) . . ?
Si5 Ge8 Ge6 119.19(3) . . ?
Ge9 Ge8 Ge6 73.208(18) . . ?
Ge5 Ge8 Ge6 60.909(17) . . ?
Ge4 Ge8 Ge6 113.71(2) . . ?
Si1 Ge7 Ge9 115.01(3) . . ?
Si1 Ge7 Ge3 114.67(3) . . ?
Ge9 Ge7 Ge3 107.39(2) . . ?
Si1 Ge7 Ge2 117.05(3) . . ?
Ge9 Ge7 Ge2 120.72(2) . . ?
Ge3 Ge7 Ge2 74.198(18) . . ?
Si1 Ge7 Ge6 117.53(3) . . ?
Ge9 Ge7 Ge6 72.660(18) . . ?
Ge3 Ge7 Ge6 121.28(2) . . ?
Ge2 Ge7 Ge6 59.543(17) . . ?
Si1 Ge7 Rh1 121.36(3) . . ?
Ge9 Ge7 Rh1 54.926(14) . . ?
Ge3 Ge7 Rh1 54.891(14) . . ?
Ge2 Ge7 Rh1 113.504(18) . . ?
Ge6 Ge7 Rh1 112.502(19) . . ?
Rh1 Ge9 Ge8 94.977(18) . . ?
Rh1 Ge9 Ge7 65.505(16) . . ?
Ge8 Ge9 Ge7 95.36(2) . . ?
C28 Rh1 Ge3 122.69(11) . . ?
C28 Rh1 Ge9 120.92(11) . . ?
Ge3 Rh1 Ge9 116.273(18) . . ?
C28 Rh1 Ge4 91.96(10) . . ?
Ge3 Rh1 Ge4 86.468(17) . . ?
Ge9 Rh1 Ge4 88.021(17) . . ?
C28 Rh1 Ge7 166.83(10) . . ?
Ge3 Rh1 Ge7 59.586(15) . . ?
Ge9 Rh1 Ge7 59.569(15) . . ?
Ge4 Rh1 Ge7 101.190(16) . . ?
N2 C28 N1 103.2(3) . . ?
N2 C28 Rh1 129.1(3) . . ?
N1 C28 Rh1 127.5(3) . . ?
C28 N1 C29 111.7(3) . . ?
C28 N1 C31 124.6(3) . . ?
C29 N1 C31 123.7(3) . . ?
C28 N2 C30 112.0(3) . . ?
C28 N2 C34 124.1(3) . . ?
C30 N2 C34 123.9(3) . . ?
C30 C29 N1 106.9(3) . . ?
C30 C29 C32 130.3(4) . . ?
N1 C29 C32 122.8(4) . . ?
C29 C30 N2 106.2(3) . . ?
C29 C30 C33 131.5(4) . . ?
N2 C30 C33 122.3(4) . . ?
N1 C31 H31A 109.5 . . ?
N1 C31 H31B 109.5 . . ?
H31A C31 H31B 109.5 . . ?
N1 C31 H31C 109.5 . . ?
H31A C31 H31C 109.5 . . ?
H31B C31 H31C 109.5 . . ?
C29 C32 H32A 109.5 . . ?
C29 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
C29 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
C30 C33 H33A 109.5 . . ?
C30 C33 H33B 109.5 . . ?
H33A C33 H33B 109.5 . . ?
C30 C33 H33C 109.5 . . ?
H33A C33 H33C 109.5 . . ?
H33B C33 H33C 109.5 . . ?
N2 C34 H34A 109.5 . . ?
N2 C34 H34B 109.5 . . ?
H34A C34 H34B 109.5 . . ?
N2 C34 H34C 109.5 . . ?
H34A C34 H34C 109.5 . . ?
H34B C34 H34C 109.5 . . ?
Si4 Si1 Si2 112.54(6) . . ?
Si4 Si1 Si3 111.41(7) . . ?
Si2 Si1 Si3 107.57(6) . . ?
Si4 Si1 Ge7 107.48(5) . . ?
Si2 Si1 Ge7 108.73(6) . . ?
Si3 Si1 Ge7 109.05(5) . . ?
C2 Si2 C3 107.8(4) . . ?
C2 Si2 C1 108.5(4) . . ?
C3 Si2 C1 108.3(3) . . ?
C2 Si2 Si1 112.5(2) . . ?
C3 Si2 Si1 110.01(19) . . ?
C1 Si2 Si1 109.6(2) . . ?
Si2 C1 H1A 109.5 . . ?
Si2 C1 H1B 109.5 . . ?
H1A C1 H1B 109.5 . . ?
Si2 C1 H1C 109.5 . . ?
H1A C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
Si2 C2 H2A 109.5 . . ?
Si2 C2 H2B 109.5 . . ?
H2A C2 H2B 109.5 . . ?
Si2 C2 H2C 109.5 . . ?
H2A C2 H2C 109.5 . . ?
H2B C2 H2C 109.5 . . ?
Si2 C3 H3A 109.5 . . ?
Si2 C3 H3B 109.5 . . ?
H3A C3 H3B 109.5 . . ?
Si2 C3 H3C 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
C6 Si3 C5 108.5(3) . . ?
C6 Si3 C4 107.7(3) . . ?
C5 Si3 C4 108.7(3) . . ?
C6 Si3 Si1 111.4(2) . . ?
C5 Si3 Si1 110.5(2) . . ?
C4 Si3 Si1 109.9(2) . . ?
Si3 C4 H4A 109.5 . . ?
Si3 C4 H4B 109.5 . . ?
H4A C4 H4B 109.5 . . ?
Si3 C4 H4C 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
Si3 C5 H5A 109.5 . . ?
Si3 C5 H5B 109.5 . . ?
H5A C5 H5B 109.5 . . ?
Si3 C5 H5C 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
Si3 C6 H6A 109.5 . . ?
Si3 C6 H6B 109.5 . . ?
H6A C6 H6B 109.5 . . ?
Si3 C6 H6C 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
C8 Si4 C9 109.4(3) . . ?
C8 Si4 C7 109.6(4) . . ?
C9 Si4 C7 108.6(4) . . ?
C8 Si4 Si1 110.0(2) . . ?
C9 Si4 Si1 110.0(2) . . ?
C7 Si4 Si1 109.2(2) . . ?
Si4 C7 H7A 109.5 . . ?
Si4 C7 H7B 109.5 . . ?
H7A C7 H7B 109.5 . . ?
Si4 C7 H7C 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
Si4 C8 H8A 109.5 . . ?
Si4 C8 H8B 109.5 . . ?
H8A C8 H8B 109.5 . . ?
Si4 C8 H8C 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
Si4 C9 H9A 109.5 . . ?
Si4 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
Si4 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
Si6 Si5 Si8 112.70(6) . . ?
Si6 Si5 Si7 111.07(6) . . ?
Si8 Si5 Si7 111.45(7) . . ?
Si6 Si5 Ge8 108.95(5) . . ?
Si8 Si5 Ge8 108.47(5) . . ?
Si7 Si5 Ge8 103.76(6) . . ?
C10 Si6 C11 109.4(3) . . ?
C10 Si6 C12 108.2(3) . . ?
C11 Si6 C12 108.4(3) . . ?
C10 Si6 Si5 110.54(19) . . ?
C11 Si6 Si5 111.24(19) . . ?
C12 Si6 Si5 108.9(2) . . ?
Si6 C10 H10A 109.5 . . ?
Si6 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
Si6 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
Si6 C11 H11A 109.5 . . ?
Si6 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
Si6 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
Si6 C12 H12A 109.5 . . ?
Si6 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
Si6 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
C15 Si7 C13 108.2(3) . . ?
C15 Si7 C14 109.4(4) . . ?
C13 Si7 C14 107.4(3) . . ?
C15 Si7 Si5 109.4(2) . . ?
C13 Si7 Si5 111.48(18) . . ?
C14 Si7 Si5 110.8(3) . . ?
Si7 C13 H13A 109.5 . . ?
Si7 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
Si7 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
Si7 C14 H14A 109.5 . . ?
Si7 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
Si7 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
Si7 C15 H15A 109.5 . . ?
Si7 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
Si7 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C17 Si8 C16 107.9(4) . . ?
C17 Si8 C18 107.7(4) . . ?
C16 Si8 C18 110.1(4) . . ?
C17 Si8 Si5 111.0(2) . . ?
C16 Si8 Si5 109.9(2) . . ?
C18 Si8 Si5 110.07(19) . . ?
Si8 C16 H16A 109.5 . . ?
Si8 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
Si8 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
Si8 C17 H17A 109.5 . . ?
Si8 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
Si8 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
Si8 C18 H18A 109.5 . . ?
Si8 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
Si8 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
Si11 Si9 Si10 111.49(7) . . ?
Si11 Si9 Si12 110.70(7) . . ?
Si10 Si9 Si12 112.09(8) . . ?
Si3A Si9 Si2A 114.1(3) . . ?
Si3A Si9 Ge1 117.1(2) . . ?
Si11 Si9 Ge1 104.13(5) . . ?
Si10 Si9 Ge1 110.22(6) . . ?
Si12 Si9 Ge1 107.84(6) . . ?
Si2A Si9 Ge1 109.1(3) . . ?
Si3A Si9 Si1A 110.4(3) . . ?
Si2A Si9 Si1A 103.0(3) . . ?
Ge1 Si9 Si1A 101.5(2) . . ?
C20 Si10 C21 109.8(5) . . ?
C20 Si10 C19 107.9(5) . . ?
C21 Si10 C19 109.5(5) . . ?
C20 Si10 Si9 112.8(3) . . ?
C21 Si10 Si9 109.2(3) . . ?
C19 Si10 Si9 107.6(3) . . ?
Si10 C19 H19A 109.5 . . ?
Si10 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
Si10 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
Si10 C20 H20A 109.5 . . ?
Si10 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
Si10 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
Si10 C21 H21A 109.5 . . ?
Si10 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
Si10 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C22 Si11 C23 108.1(4) . . ?
C22 Si11 C24 108.5(4) . . ?
C23 Si11 C24 108.0(4) . . ?
C22 Si11 Si9 108.9(2) . . ?
C23 Si11 Si9 112.2(3) . . ?
C24 Si11 Si9 111.1(3) . . ?
Si11 C22 H22A 109.5 . . ?
Si11 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
Si11 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
Si11 C23 H23A 109.5 . . ?
Si11 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
Si11 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
Si11 C24 H24A 109.5 . . ?
Si11 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
Si11 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C25 Si12 C26 110.1(5) . . ?
C25 Si12 C27 105.8(6) . . ?
C26 Si12 C27 109.4(7) . . ?
C25 Si12 Si9 114.0(4) . . ?
C26 Si12 Si9 109.4(3) . . ?
C27 Si12 Si9 108.0(3) . . ?
Si12 C25 H25A 109.5 . . ?
Si12 C25 H25B 109.5 . . ?
H25A C25 H25B 109.5 . . ?
Si12 C25 H25C 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
Si12 C26 H26A 109.5 . . ?
Si12 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
Si12 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
Si12 C27 H27A 109.5 . . ?
Si12 C27 H27B 109.5 . . ?
H27A C27 H27B 109.5 . . ?
Si12 C27 H27C 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
C20A Si1A C21A 110.1(10) . . ?
C20A Si1A C19A 108.9(9) . . ?
C21A Si1A C19A 109.9(10) . . ?
C20A Si1A Si9 135.3(16) . . ?
C21A Si1A Si9 77(3) . . ?
C19A Si1A Si9 109.7(16) . . ?
Si1A C19A H1A1 109.5 . . ?
Si1A C19A H1A2 109.5 . . ?
H1A1 C19A H1A2 109.5 . . ?
Si1A C19A H1A3 109.5 . . ?
H1A1 C19A H1A3 109.5 . . ?
H1A2 C19A H1A3 109.5 . . ?
Si1A C20A H1A4 109.5 . . ?
Si1A C20A H1A5 109.5 . . ?
H1A4 C20A H1A5 109.5 . . ?
Si1A C20A H1A6 109.5 . . ?
H1A4 C20A H1A6 109.5 . . ?
H1A5 C20A H1A6 109.5 . . ?
Si1A C21A H1A7 109.5 . . ?
Si1A C21A H1A8 109.5 . . ?
H1A7 C21A H1A8 109.5 . . ?
Si1A C21A H1A9 109.5 . . ?
H1A7 C21A H1A9 109.5 . . ?
H1A8 C21A H1A9 109.5 . . ?
C22A Si2A C23A 108.2(9) . . ?
C22A Si2A C24A 108.7(10) . . ?
C23A Si2A C24A 108.1(8) . . ?
C22A Si2A Si9 114(3) . . ?
C23A Si2A Si9 112(3) . . ?
C24A Si2A Si9 106.1(15) . . ?
Si2A C22A H2A1 109.5 . . ?
Si2A C22A H2A2 109.5 . . ?
H2A1 C22A H2A2 109.5 . . ?
Si2A C22A H2A3 109.5 . . ?
H2A1 C22A H2A3 109.5 . . ?
H2A2 C22A H2A3 109.5 . . ?
Si2A C23A H2A4 109.5 . . ?
Si2A C23A H2A5 109.5 . . ?
H2A4 C23A H2A5 109.5 . . ?
Si2A C23A H2A6 109.5 . . ?
H2A4 C23A H2A6 109.5 . . ?
H2A5 C23A H2A6 109.5 . . ?
Si2A C24A H2A7 109.5 . . ?
Si2A C24A H2A8 109.5 . . ?
H2A7 C24A H2A8 109.5 . . ?
Si2A C24A H2A9 109.5 . . ?
H2A7 C24A H2A9 109.5 . . ?
H2A8 C24A H2A9 109.5 . . ?
C25A Si3A C26A 110.1(9) . . ?
C25A Si3A C27A 105.7(10) . . ?
C26A Si3A C27A 109.2(11) . . ?
C25A Si3A Si9 110(3) . . ?
C26A Si3A Si9 113(2) . . ?
C27A Si3A Si9 109(3) . . ?
Si3A C25A H3A1 109.5 . . ?
Si3A C25A H3A2 109.5 . . ?
H3A1 C25A H3A2 109.5 . . ?
Si3A C25A H3A3 109.5 . . ?
H3A1 C25A H3A3 109.5 . . ?
H3A2 C25A H3A3 109.5 . . ?
Si3A C26A H3A4 109.5 . . ?
Si3A C26A H3A5 109.5 . . ?
H3A4 C26A H3A5 109.5 . . ?
Si3A C26A H3A6 109.5 . . ?
H3A4 C26A H3A6 109.5 . . ?
H3A5 C26A H3A6 109.5 . . ?
Si3A C27A H3A7 109.5 . . ?
Si3A C27A H3A8 109.5 . . ?
H3A7 C27A H3A8 109.5 . . ?
Si3A C27A H3A9 109.5 . . ?
H3A7 C27A H3A9 109.5 . . ?
H3A8 C27A H3A9 109.5 . . ?
Si29 Ge21 Ge24 127.45(3) . . ?
Si29 Ge21 Ge22 108.73(3) . . ?
Ge24 Ge21 Ge22 120.06(2) . . ?
Si29 Ge21 Ge23 125.42(3) . . ?
Ge24 Ge21 Ge23 81.713(18) . . ?
Ge22 Ge21 Ge23 81.948(19) . . ?
Si29 Ge21 Ge25 119.12(3) . . ?
Ge24 Ge21 Ge25 73.560(18) . . ?
Ge22 Ge21 Ge25 61.114(17) . . ?
Ge23 Ge21 Ge25 112.80(2) . . ?
Ge27 Ge22 Ge21 95.561(19) . . ?
Ge27 Ge22 Ge25 104.40(2) . . ?
Ge21 Ge22 Ge25 61.229(17) . . ?
Ge27 Ge22 Ge26 61.330(17) . . ?
Ge21 Ge22 Ge26 104.49(2) . . ?
Ge25 Ge22 Ge26 59.057(17) . . ?
Rh2 Ge23 Ge27 93.355(18) . . ?
Rh2 Ge23 Ge21 92.942(18) . . ?
Ge27 Ge23 Ge21 94.28(2) . . ?
Rh2 Ge24 Ge21 96.563(18) . . ?
Rh2 Ge24 Ge28 65.332(15) . . ?
Ge21 Ge24 Ge28 95.348(19) . . ?
Ge26 Ge25 Ge28 59.888(17) . . ?
Ge26 Ge25 Ge22 60.500(17) . . ?
Ge28 Ge25 Ge22 98.502(19) . . ?
Ge26 Ge25 Ge21 102.91(2) . . ?
Ge28 Ge25 Ge21 88.961(18) . . ?
Ge22 Ge25 Ge21 57.657(16) . . ?
Ge25 Ge26 Ge28 60.278(17) . . ?
Ge25 Ge26 Ge22 60.443(17) . . ?
Ge28 Ge26 Ge22 98.722(19) . . ?
Ge25 Ge26 Ge27 102.55(2) . . ?
Ge28 Ge26 Ge27 88.650(18) . . ?
Ge22 Ge26 Ge27 57.449(16) . . ?
Si21 Ge27 Ge29 119.12(3) . . ?
Si21 Ge27 Ge22 116.39(3) . . ?
Ge29 Ge27 Ge22 120.62(2) . . ?
Si21 Ge27 Ge23 126.39(3) . . ?
Ge29 Ge27 Ge23 81.485(19) . . ?
Ge22 Ge27 Ge23 82.364(19) . . ?
Si21 Ge27 Ge26 119.82(3) . . ?
Ge29 Ge27 Ge26 74.099(19) . . ?
Ge22 Ge27 Ge26 61.222(18) . . ?
Ge23 Ge27 Ge26 113.24(2) . . ?
Si25 Ge28 Ge29 114.05(3) . . ?
Si25 Ge28 Ge24 116.03(3) . . ?
Ge29 Ge28 Ge24 107.07(2) . . ?
Si25 Ge28 Ge26 116.43(3) . . ?
Ge29 Ge28 Ge26 73.634(18) . . ?
Ge24 Ge28 Ge26 120.97(2) . . ?
Si25 Ge28 Ge25 117.96(3) . . ?
Ge29 Ge28 Ge25 121.02(2) . . ?
Ge24 Ge28 Ge25 72.987(18) . . ?
Ge26 Ge28 Ge25 59.834(17) . . ?
Si25 Ge28 Rh2 120.82(3) . . ?
Ge29 Ge28 Rh2 54.931(14) . . ?
Ge24 Ge28 Rh2 54.844(14) . . ?
Ge26 Ge28 Rh2 113.768(18) . . ?
Ge25 Ge28 Rh2 113.174(18) . . ?
Rh2 Ge29 Ge27 96.835(19) . . ?
Rh2 Ge29 Ge28 65.373(15) . . ?
Ge27 Ge29 Ge28 95.13(2) . . ?
C228 Rh2 Ge24 121.40(11) . . ?
C228 Rh2 Ge29 121.96(11) . . ?
Ge24 Rh2 Ge29 116.282(18) . . ?
C228 Rh2 Ge23 91.14(10) . . ?
Ge24 Rh2 Ge23 86.764(17) . . ?
Ge29 Rh2 Ge23 85.964(17) . . ?
C228 Rh2 Ge28 168.34(10) . . ?
Ge24 Rh2 Ge28 59.824(15) . . ?
Ge29 Rh2 Ge28 59.696(15) . . ?
Ge23 Rh2 Ge28 100.519(16) . . ?
N201 C228 N202 103.7(3) . . ?
N201 C228 Rh2 127.3(3) . . ?
N202 C228 Rh2 128.9(3) . . ?
C228 N201 C229 111.5(4) . . ?
C228 N201 C231 124.7(4) . . ?
C229 N201 C231 123.7(4) . . ?
C228 N202 C230 111.5(3) . . ?
C228 N202 C234 125.4(3) . . ?
C230 N202 C234 123.1(3) . . ?
C230 C229 N201 106.7(4) . . ?
C230 C229 C232 130.7(4) . . ?
N201 C229 C232 122.6(4) . . ?
C229 C230 N202 106.5(4) . . ?
C229 C230 C233 131.5(4) . . ?
N202 C230 C233 122.0(4) . . ?
N201 C231 H23G 109.5 . . ?
N201 C231 H23H 109.5 . . ?
H23G C231 H23H 109.5 . . ?
N201 C231 H23I 109.5 . . ?
H23G C231 H23I 109.5 . . ?
H23H C231 H23I 109.5 . . ?
C230 C233 H23J 109.5 . . ?
C230 C233 H23K 109.5 . . ?
H23J C233 H23K 109.5 . . ?
C230 C233 H23L 109.5 . . ?
H23J C233 H23L 109.5 . . ?
H23K C233 H23L 109.5 . . ?
C229 C232 H23M 109.5 . . ?
C229 C232 H23N 109.5 . . ?
H23M C232 H23N 109.5 . . ?
C229 C232 H23O 109.5 . . ?
H23M C232 H23O 109.5 . . ?
H23N C232 H23O 109.5 . . ?
N202 C234 H23P 109.5 . . ?
N202 C234 H23Q 109.5 . . ?
H23P C234 H23Q 109.5 . . ?
N202 C234 H23R 109.5 . . ?
H23P C234 H23R 109.5 . . ?
H23Q C234 H23R 109.5 . . ?
Si24 Si21 Si23 113.29(7) . . ?
Si24 Si21 Si22 113.69(7) . . ?
Si23 Si21 Si22 110.28(7) . . ?
Si24 Si21 Ge27 108.02(6) . . ?
Si23 Si21 Ge27 108.91(5) . . ?
Si22 Si21 Ge27 101.91(6) . . ?
C203 Si22 C201 109.9(4) . . ?
C203 Si22 C202 107.2(4) . . ?
C201 Si22 C202 107.9(3) . . ?
C203 Si22 Si21 109.5(2) . . ?
C201 Si22 Si21 110.6(3) . . ?
C202 Si22 Si21 111.6(3) . . ?
Si22 C201 H20D 109.5 . . ?
Si22 C201 H20E 109.5 . . ?
H20D C201 H20E 109.5 . . ?
Si22 C201 H20F 109.5 . . ?
H20D C201 H20F 109.5 . . ?
H20E C201 H20F 109.5 . . ?
Si22 C202 H20G 109.5 . . ?
Si22 C202 H20H 109.5 . . ?
H20G C202 H20H 109.5 . . ?
Si22 C202 H20I 109.5 . . ?
H20G C202 H20I 109.5 . . ?
H20H C202 H20I 109.5 . . ?
Si22 C203 H20J 109.5 . . ?
Si22 C203 H20K 109.5 . . ?
H20J C203 H20K 109.5 . . ?
Si22 C203 H20L 109.5 . . ?
H20J C203 H20L 109.5 . . ?
H20K C203 H20L 109.5 . . ?
C206 Si23 C205 110.9(3) . . ?
C206 Si23 C204 108.4(3) . . ?
C205 Si23 C204 108.1(3) . . ?
C206 Si23 Si21 110.38(19) . . ?
C205 Si23 Si21 108.3(2) . . ?
C204 Si23 Si21 110.7(2) . . ?
Si23 C204 H20M 109.5 . . ?
Si23 C204 H20N 109.5 . . ?
H20M C204 H20N 109.5 . . ?
Si23 C204 H20O 109.5 . . ?
H20M C204 H20O 109.5 . . ?
H20N C204 H20O 109.5 . . ?
Si23 C205 H20P 109.5 . . ?
Si23 C205 H20Q 109.5 . . ?
H20P C205 H20Q 109.5 . . ?
Si23 C205 H20R 109.5 . . ?
H20P C205 H20R 109.5 . . ?
H20Q C205 H20R 109.5 . . ?
Si23 C206 H20S 109.5 . . ?
Si23 C206 H20T 109.5 . . ?
H20S C206 H20T 109.5 . . ?
Si23 C206 H20U 109.5 . . ?
H20S C206 H20U 109.5 . . ?
H20T C206 H20U 109.5 . . ?
C209 Si24 C208 109.0(4) . . ?
C209 Si24 C207 107.9(4) . . ?
C208 Si24 C207 108.7(4) . . ?
C209 Si24 Si21 110.9(3) . . ?
C208 Si24 Si21 110.9(2) . . ?
C207 Si24 Si21 109.4(3) . . ?
Si24 C207 H21D 109.5 . . ?
Si24 C207 H21E 109.5 . . ?
H21D C207 H21E 109.5 . . ?
Si24 C207 H21F 109.5 . . ?
H21D C207 H21F 109.5 . . ?
H21E C207 H21F 109.5 . . ?
Si24 C208 H21G 109.5 . . ?
Si24 C208 H21H 109.5 . . ?
H21G C208 H21H 109.5 . . ?
Si24 C208 H21I 109.5 . . ?
H21G C208 H21I 109.5 . . ?
H21H C208 H21I 109.5 . . ?
Si24 C209 H21J 109.5 . . ?
Si24 C209 H21K 109.5 . . ?
H21J C209 H21K 109.5 . . ?
Si24 C209 H21L 109.5 . . ?
H21J C209 H21L 109.5 . . ?
H21K C209 H21L 109.5 . . ?
Si26 Si25 Si27 107.44(6) . . ?
Si26 Si25 Si28 111.57(6) . . ?
Si27 Si25 Si28 112.33(6) . . ?
Si26 Si25 Ge28 109.45(5) . . ?
Si27 Si25 Ge28 107.48(5) . . ?
Si28 Si25 Ge28 108.48(5) . . ?
C210 Si26 C212 109.1(3) . . ?
C210 Si26 C211 109.0(3) . . ?
C212 Si26 C211 106.8(3) . . ?
C210 Si26 Si25 112.5(2) . . ?
C212 Si26 Si25 110.17(17) . . ?
C211 Si26 Si25 109.10(19) . . ?
Si26 C210 H21M 109.5 . . ?
Si26 C210 H21N 109.5 . . ?
H21M C210 H21N 109.5 . . ?
Si26 C210 H21O 109.5 . . ?
H21M C210 H21O 109.5 . . ?
H21N C210 H21O 109.5 . . ?
Si26 C211 H21P 109.5 . . ?
Si26 C211 H21Q 109.5 . . ?
H21P C211 H21Q 109.5 . . ?
Si26 C211 H21R 109.5 . . ?
H21P C211 H21R 109.5 . . ?
H21Q C211 H21R 109.5 . . ?
Si26 C212 H21S 109.5 . . ?
Si26 C212 H21T 109.5 . . ?
H21S C212 H21T 109.5 . . ?
Si26 C212 H21U 109.5 . . ?
H21S C212 H21U 109.5 . . ?
H21T C212 H21U 109.5 . . ?
C215 Si27 C213 108.0(3) . . ?
C215 Si27 C214 109.1(3) . . ?
C213 Si27 C214 107.9(3) . . ?
C215 Si27 Si25 110.38(18) . . ?
C213 Si27 Si25 111.4(2) . . ?
C214 Si27 Si25 109.9(2) . . ?
Si27 C213 H13E 109.5 . . ?
Si27 C213 H13F 109.5 . . ?
H13E C213 H13F 109.5 . . ?
Si27 C213 H13G 109.5 . . ?
H13E C213 H13G 109.5 . . ?
H13F C213 H13G 109.5 . . ?
Si27 C214 H14D 109.5 . . ?
Si27 C214 H14E 109.5 . . ?
H14D C214 H14E 109.5 . . ?
Si27 C214 H14F 109.5 . . ?
H14D C214 H14F 109.5 . . ?
H14E C214 H14F 109.5 . . ?
Si27 C215 H15D 109.5 . . ?
Si27 C215 H15E 109.5 . . ?
H15D C215 H15E 109.5 . . ?
Si27 C215 H15F 109.5 . . ?
H15D C215 H15F 109.5 . . ?
H15E C215 H15F 109.5 . . ?
C216 Si28 C217 109.7(4) . . ?
C216 Si28 C218 109.4(3) . . ?
C217 Si28 C218 107.1(3) . . ?
C216 Si28 Si25 110.1(2) . . ?
C217 Si28 Si25 110.7(2) . . ?
C218 Si28 Si25 109.76(19) . . ?
Si28 C216 H16D 109.5 . . ?
Si28 C216 H16E 109.5 . . ?
H16D C216 H16E 109.5 . . ?
Si28 C216 H16F 109.5 . . ?
H16D C216 H16F 109.5 . . ?
H16E C216 H16F 109.5 . . ?
Si28 C217 H17D 109.5 . . ?
Si28 C217 H17E 109.5 . . ?
H17D C217 H17E 109.5 . . ?
Si28 C217 H17F 109.5 . . ?
H17D C217 H17F 109.5 . . ?
H17E C217 H17F 109.5 . . ?
Si28 C218 H18E 109.5 . . ?
Si28 C218 H18D 109.5 . . ?
H18E C218 H18D 109.5 . . ?
Si28 C218 H18F 109.5 . . ?
H18E C218 H18F 109.5 . . ?
H18D C218 H18F 109.5 . . ?
Si1B Si29 Si2B 116.1(3) . . ?
Si32 Si29 Si30 111.66(7) . . ?
Si32 Si29 Si31 110.09(7) . . ?
Si30 Si29 Si31 107.61(7) . . ?
Si1B Si29 Ge21 105.0(2) . . ?
Si2B Si29 Ge21 109.4(3) . . ?
Si32 Si29 Ge21 113.57(6) . . ?
Si30 Si29 Ge21 109.23(5) . . ?
Si31 Si29 Ge21 104.27(5) . . ?
Si1B Si29 Si3B 111.6(3) . . ?
Si2B Si29 Si3B 109.3(3) . . ?
Ge21 Si29 Si3B 104.8(3) . . ?
C221 Si30 C219 107.9(4) . . ?
C221 Si30 C220 107.4(3) . . ?
C219 Si30 C220 109.1(4) . . ?
C221 Si30 Si29 112.1(3) . . ?
C219 Si30 Si29 110.7(3) . . ?
C220 Si30 Si29 109.6(4) . . ?
Si30 C219 H19D 109.5 . . ?
Si30 C219 H19E 109.5 . . ?
H19D C219 H19E 109.5 . . ?
Si30 C219 H19F 109.5 . . ?
H19D C219 H19F 109.5 . . ?
H19E C219 H19F 109.5 . . ?
Si30 C220 H201 109.5 . . ?
Si30 C220 H202 109.5 . . ?
H201 C220 H202 109.5 . . ?
Si30 C220 H203 109.5 . . ?
H201 C220 H203 109.5 . . ?
H202 C220 H203 109.5 . . ?
Si30 C221 H22P 109.5 . . ?
Si30 C221 H22Q 109.5 . . ?
H22P C221 H22Q 109.5 . . ?
Si30 C221 H22R 109.5 . . ?
H22P C221 H22R 109.5 . . ?
H22Q C221 H22R 109.5 . . ?
C224 Si31 C223 109.1(4) . . ?
C224 Si31 C222 108.2(4) . . ?
C223 Si31 C222 107.6(3) . . ?
C224 Si31 Si29 109.8(2) . . ?
C223 Si31 Si29 110.7(3) . . ?
C222 Si31 Si29 111.4(3) . . ?
Si31 C222 H22S 109.5 . . ?
Si31 C222 H22T 109.5 . . ?
H22S C222 H22T 109.5 . . ?
Si31 C222 H22U 109.5 . . ?
H22S C222 H22U 109.5 . . ?
H22T C222 H22U 109.5 . . ?
Si31 C223 H23S 109.5 . . ?
Si31 C223 H23T 109.5 . . ?
H23S C223 H23T 109.5 . . ?
Si31 C223 H23U 109.5 . . ?
H23S C223 H23U 109.5 . . ?
H23T C223 H23U 109.5 . . ?
Si31 C224 H24G 109.5 . . ?
Si31 C224 H24H 109.5 . . ?
H24G C224 H24H 109.5 . . ?
Si31 C224 H24I 109.5 . . ?
H24G C224 H24I 109.5 . . ?
H24H C224 H24I 109.5 . . ?
C227 Si32 C225 110.2(4) . . ?
C227 Si32 C226 109.6(4) . . ?
C225 Si32 C226 107.6(4) . . ?
C227 Si32 Si29 110.2(2) . . ?
C225 Si32 Si29 110.1(2) . . ?
C226 Si32 Si29 109.0(2) . . ?
Si32 C225 H25G 109.5 . . ?
Si32 C225 H25H 109.5 . . ?
H25G C225 H25H 109.5 . . ?
Si32 C225 H25I 109.5 . . ?
H25G C225 H25I 109.5 . . ?
H25H C225 H25I 109.5 . . ?
Si32 C226 H26J 109.5 . . ?
Si32 C226 H26K 109.5 . . ?
H26J C226 H26K 109.5 . . ?
Si32 C226 H26L 109.5 . . ?
H26J C226 H26L 109.5 . . ?
H26K C226 H26L 109.5 . . ?
Si32 C227 H27M 109.5 . . ?
Si32 C227 H27N 109.5 . . ?
H27M C227 H27N 109.5 . . ?
Si32 C227 H27O 109.5 . . ?
H27M C227 H27O 109.5 . . ?
H27N C227 H27O 109.5 . . ?
C21B Si1B C19B 108.0(9) . . ?
C21B Si1B C20B 107.8(8) . . ?
C19B Si1B C20B 109.3(9) . . ?
C21B Si1B Si29 108.0(13) . . ?
C19B Si1B Si29 110(3) . . ?
C20B Si1B Si29 114(3) . . ?
Si1B C19B H1B1 109.5 . . ?
Si1B C19B H1B2 109.5 . . ?
H1B1 C19B H1B2 109.5 . . ?
Si1B C19B H1B3 109.5 . . ?
H1B1 C19B H1B3 109.5 . . ?
H1B2 C19B H1B3 109.5 . . ?
Si1B C20B H1B4 109.5 . . ?
Si1B C20B H1B5 109.5 . . ?
H1B4 C20B H1B5 109.5 . . ?
Si1B C20B H1B6 109.5 . . ?
H1B4 C20B H1B6 109.5 . . ?
H1B5 C20B H1B6 109.5 . . ?
Si1B C21B H1B7 109.5 . . ?
Si1B C21B H1B8 109.5 . . ?
H1B7 C21B H1B8 109.5 . . ?
Si1B C21B H1B9 109.5 . . ?
H1B7 C21B H1B9 109.5 . . ?
H1B8 C21B H1B9 109.5 . . ?
C24B Si2B C23B 109.2(8) . . ?
C24B Si2B C22B 108.4(9) . . ?
C23B Si2B C22B 107.6(8) . . ?
C24B Si2B Si29 116(2) . . ?
C23B Si2B Si29 112.0(18) . . ?
C22B Si2B Si29 103(2) . . ?
Si2B C22B H2B1 109.5 . . ?
Si2B C22B H2B2 109.5 . . ?
H2B1 C22B H2B2 109.5 . . ?
Si2B C22B H2B3 109.5 . . ?
H2B1 C22B H2B3 109.5 . . ?
H2B2 C22B H2B3 109.5 . . ?
Si2B C23B H2B4 109.5 . . ?
Si2B C23B H2B5 109.5 . . ?
H2B4 C23B H2B5 109.5 . . ?
Si2B C23B H2B6 109.5 . . ?
H2B4 C23B H2B6 109.5 . . ?
H2B5 C23B H2B6 109.5 . . ?
Si2B C24B H2B7 109.5 . . ?
Si2B C24B H2B8 109.5 . . ?
H2B7 C24B H2B8 109.5 . . ?
Si2B C24B H2B9 109.5 . . ?
H2B7 C24B H2B9 109.5 . . ?
H2B8 C24B H2B9 109.5 . . ?
C25B Si3B C27B 110.0(9) . . ?
C25B Si3B C26B 107.2(9) . . ?
C27B Si3B C26B 109.2(9) . . ?
C25B Si3B Si29 138(3) . . ?
C27B Si3B Si29 101(3) . . ?
C26B Si3B Si29 88.5(17) . . ?
Si3B C25B H3B1 109.5 . . ?
Si3B C25B H3B2 109.5 . . ?
H3B1 C25B H3B2 109.5 . . ?
Si3B C25B H3B3 109.5 . . ?
H3B1 C25B H3B3 109.5 . . ?
H3B2 C25B H3B3 109.5 . . ?
Si3B C26B H3B4 109.5 . . ?
Si3B C26B H3B5 109.5 . . ?
H3B4 C26B H3B5 109.5 . . ?
Si3B C26B H3B6 109.5 . . ?
H3B4 C26B H3B6 109.5 . . ?
H3B5 C26B H3B6 109.5 . . ?
Si3B C27B H3B7 109.5 . . ?
Si3B C27B H3B8 109.5 . . ?
H3B7 C27B H3B8 109.5 . . ?
Si3B C27B H3B9 109.5 . . ?
H3B7 C27B H3B9 109.5 . . ?
H3B8 C27B H3B9 109.5 . . ?
C2T C1T H1T1 109.5 . . ?
C2T C1T H1T2 109.5 . . ?
H1T1 C1T H1T2 109.5 . . ?
C2T C1T H1T3 109.5 . . ?
H1T1 C1T H1T3 109.5 . . ?
H1T2 C1T H1T3 109.5 . . ?
C4T C2T C1T 112.9(12) . . ?
C4T C2T H2T1 109.0 . . ?
C1T C2T H2T1 109.0 . . ?
C4T C2T H2T2 109.0 . . ?
C1T C2T H2T2 109.0 . . ?
H2T1 C2T H2T2 107.8 . . ?
C5T C3T C6T 116.7(11) . . ?
C5T C3T H3T1 108.1 . . ?
C6T C3T H3T1 108.1 . . ?
C5T C3T H3T2 108.1 . . ?
C6T C3T H3T2 108.1 . . ?
H3T1 C3T H3T2 107.3 . . ?
C2T C4T C5T 114.6(11) . . ?
C2T C4T H4T1 108.6 . . ?
C5T C4T H4T1 108.6 . . ?
C2T C4T H4T2 108.6 . . ?
C5T C4T H4T2 108.6 . . ?
H4T1 C4T H4T2 107.6 . . ?
C3T C5T C4T 115.6(9) . . ?
C3T C5T H5T1 108.4 . . ?
C4T C5T H5T1 108.4 . . ?
C3T C5T H5T2 108.4 . . ?
C4T C5T H5T2 108.4 . . ?
H5T1 C5T H5T2 107.4 . . ?
C3T C6T H6T1 109.5 . . ?
C3T C6T H6T2 109.5 . . ?
H6T1 C6T H6T2 109.5 . . ?
C3T C6T H6T3 109.5 . . ?
H6T1 C6T H6T3 109.5 . . ?
H6T2 C6T H6T3 109.5 . . ?
C2S C1S H1S1 109.5 . . ?
C2S C1S H1S2 109.5 . . ?
H1S1 C1S H1S2 109.5 . . ?
C2S C1S H1S3 109.5 . . ?
H1S1 C1S H1S3 109.5 . . ?
H1S2 C1S H1S3 109.5 . . ?
C1S C2S C3S 125.8(13) . . ?
C1S C2S H2S1 105.9 . . ?
C3S C2S H2S1 105.9 . . ?
C1S C2S H2S2 105.9 . . ?
C3S C2S H2S2 105.9 . . ?
H2S1 C2S H2S2 106.2 . . ?
C2S C3S C4S 106.1(13) . . ?
C2S C3S H3S1 110.5 . . ?
C4S C3S H3S1 110.5 . . ?
C2S C3S H3S2 110.5 . . ?
C4S C3S H3S2 110.5 . . ?
H3S1 C3S H3S2 108.7 . . ?
C5S C4S C3S 116.8(17) . . ?
C5S C4S H4S1 108.1 . . ?
C3S C4S H4S1 108.1 . . ?
C5S C4S H4S2 108.1 . . ?
C3S C4S H4S2 108.1 . . ?
H4S1 C4S H4S2 107.3 . . ?
C6S C5S C4S 109.5(18) . . ?
C6S C5S H5S1 109.8 . . ?
C4S C5S H5S1 109.8 . . ?
C6S C5S H5S2 109.8 . . ?
C4S C5S H5S2 109.8 . . ?
H5S1 C5S H5S2 108.2 . . ?
C5S C6S H6S1 109.5 . . ?
C5S C6S H6S2 109.5 . . ?
H6S1 C6S H6S2 109.5 . . ?
C5S C6S H6S3 109.5 . . ?
H6S1 C6S H6S3 109.5 . . ?
H6S2 C6S H6S3 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N2 C28 N1 C29 -0.5(4) . . . . ?
Rh1 C28 N1 C29 175.3(3) . . . . ?
N2 C28 N1 C31 177.7(4) . . . . ?
Rh1 C28 N1 C31 -6.5(6) . . . . ?
N1 C28 N2 C30 0.8(4) . . . . ?
Rh1 C28 N2 C30 -174.9(3) . . . . ?
N1 C28 N2 C34 -178.7(3) . . . . ?
Rh1 C28 N2 C34 5.6(5) . . . . ?
C28 N1 C29 C30 0.0(4) . . . . ?
C31 N1 C29 C30 -178.3(4) . . . . ?
C28 N1 C29 C32 -179.6(4) . . . . ?
C31 N1 C29 C32 2.2(6) . . . . ?
N1 C29 C30 N2 0.5(4) . . . . ?
C32 C29 C30 N2 -180.0(4) . . . . ?
N1 C29 C30 C33 -177.9(4) . . . . ?
C32 C29 C30 C33 1.7(8) . . . . ?
C28 N2 C30 C29 -0.9(4) . . . . ?
C34 N2 C30 C29 178.6(4) . . . . ?
C28 N2 C30 C33 177.7(4) . . . . ?
C34 N2 C30 C33 -2.8(6) . . . . ?
N202 C228 N201 C229 -0.2(4) . . . . ?
Rh2 C228 N201 C229 -177.0(3) . . . . ?
N202 C228 N201 C231 179.1(4) . . . . ?
Rh2 C228 N201 C231 2.2(6) . . . . ?
N201 C228 N202 C230 -0.5(4) . . . . ?
Rh2 C228 N202 C230 176.3(3) . . . . ?
N201 C228 N202 C234 -179.7(4) . . . . ?
Rh2 C228 N202 C234 -2.9(6) . . . . ?
C228 N201 C229 C230 0.8(5) . . . . ?
C231 N201 C229 C230 -178.4(4) . . . . ?
C228 N201 C229 C232 -179.5(4) . . . . ?
C231 N201 C229 C232 1.2(7) . . . . ?
N201 C229 C230 N202 -1.1(5) . . . . ?
C232 C229 C230 N202 179.3(5) . . . . ?
N201 C229 C230 C233 178.3(4) . . . . ?
C232 C229 C230 C233 -1.3(9) . . . . ?
C228 N202 C230 C229 1.1(4) . . . . ?
C234 N202 C230 C229 -179.7(4) . . . . ?
C228 N202 C230 C233 -178.4(4) . . . . ?
C234 N202 C230 C233 0.8(6) . . . . ?
C1T C2T C4T C5T 175.8(10) . . . . ?
C6T C3T C5T C4T -175.8(10) . . . . ?
C2T C4T C5T C3T 170.2(12) . . . . ?
C1S C2S C3S C4S 157(2) . . . . ?
C2S C3S C4S C5S 151(3) . . . . ?
C3S C4S C5S C6S 171(2) . . . . ?

_refine_diff_density_max         1.543
_refine_diff_density_min         -0.549
_refine_diff_density_rms         0.148



####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_OT490
_database_code_depnum_ccdc_archive 'CCDC 2155449'
loop_
_audit_author_name
_audit_author_address
'Jose Goicoechea'
;University of Oxford
United Kingdom
;
_audit_update_record             
;
2022-02-28 deposited with the CCDC.	2022-06-09 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/1
_shelx_SHELXL_version_number     2018/1
_chemical_name_systematic        
;
 [Ge9{Si(SiMe3)}3RhH(H)2W(Cp)2][B{C6H3(CF3)2}4]*Et2O
;
_contact_author_fax              '+44 1865 272690'
_chemical_name_common            .
_chemical_melting_point          .
_chemical_formula_moiety         
'C37 H94 Ge9 Rh Si12 W, C32 H12 B F24, C4 H10 O'
_chemical_formula_sum            'C73 H116 B F24 Ge9 O Rh Si12 W'
_chemical_formula_weight         2753.61

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0090 0.0039 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.2541 0.3302 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge -1.0885 0.8855 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh 0.0927 3.6045 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -5.4734 5.5774 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   17.9023(5)
_cell_length_b                   13.8042(5)
_cell_length_c                   44.4206(12)
_cell_angle_alpha                90
_cell_angle_beta                 96.969(3)
_cell_angle_gamma                90
_cell_volume                     10896.4(6)
_cell_formula_units_Z            4
_cell_measurement_temperature    150(2)
_cell_measurement_reflns_used    18711
_cell_measurement_theta_min      3.7350
_cell_measurement_theta_max      76.2770

_exptl_crystal_description       needle
_exptl_crystal_colour            'dark red'
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    .
_exptl_crystal_density_diffrn    1.679
_exptl_crystal_F_000             5432
_exptl_transmission_factor_min   .
_exptl_transmission_factor_max   .
_exptl_crystal_size_max          0.140
_exptl_crystal_size_mid          0.060
_exptl_crystal_size_min          0.040
_exptl_absorpt_coefficient_mu    7.778
_shelx_estimated_absorpt_T_min   0.409
_shelx_estimated_absorpt_T_max   0.746
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.53652
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.41.81a (Rigaku Oxford Diffraction, 2020)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   .

_diffrn_ambient_temperature      150(2)
_diffrn_radiation_wavelength     1.54184
_diffrn_radiation_type           CuK\a
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'SuperNova (Cu) X-ray Source'
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at home/near, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_detector                 'CCD plate'
_diffrn_detector_type            Atlas
_diffrn_detector_area_resol_mean 10.5035
_diffrn_reflns_number            101192
_diffrn_reflns_av_unetI/netI     0.0838
_diffrn_reflns_av_R_equivalents  0.1242
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -52
_diffrn_reflns_limit_l_max       52
_diffrn_reflns_theta_min         3.778
_diffrn_reflns_theta_max         66.489
_diffrn_reflns_theta_full        66.489
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             19207
_reflns_number_gt                13688
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'CrysAlisPro 1.171.41.81a (Rigaku OD, 2020)'
_computing_cell_refinement       'CrysAlisPro 1.171.41.81a (Rigaku OD, 2020)'
_computing_data_reduction        'CrysAlisPro 1.171.41.81a (Rigaku OD, 2020)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2018/1 (Sheldrick, 2018)'
_computing_molecular_graphics    .
_computing_publication_material  .
_refine_special_details          .

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0908P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     .
_atom_sites_solution_secondary   .
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         19207
_refine_ls_number_parameters     1312
_refine_ls_number_restraints     367
_refine_ls_R_factor_all          0.0910
_refine_ls_R_factor_gt           0.0647
_refine_ls_wR_factor_ref         0.1838
_refine_ls_wR_factor_gt          0.1656
_refine_ls_goodness_of_fit_ref   1.058
_refine_ls_restrained_S_all      1.144
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.19228(4) 0.54115(5) 0.12315(2) 0.0357(2) Uani 0.7964(18) 1 d D . P A 1
Ge1 Ge 0.36899(7) 0.65985(16) 0.12281(5) 0.0351(3) Uani 0.7964(18) 1 d D . P A
1
Ge2 Ge 0.34658(13) 0.7396(2) 0.17389(8) 0.0373(4) Uani 0.7964(18) 1 d D . P A 1
Ge3 Ge 0.23238(10) 0.70597(17) 0.11892(6) 0.0354(4) Uani 0.7964(18) 1 d D . P A
1
Ge4 Ge 0.32180(6) 0.49879(9) 0.12639(3) 0.0388(3) Uani 0.7964(18) 1 d D . P A 1
Ge5 Ge 0.43631(12) 0.5851(3) 0.17330(8) 0.0406(4) Uani 0.7964(18) 1 d D . P A 1
Ge6 Ge 0.3297(2) 0.5899(2) 0.21094(5) 0.0385(4) Uani 0.7964(18) 1 d D . P A 1
Ge7 Ge 0.21581(14) 0.65212(17) 0.17274(6) 0.0330(4) Uani 0.7964(18) 1 d D . P A
1
Ge8 Ge 0.34723(15) 0.4384(2) 0.17856(5) 0.0377(4) Uani 0.7964(18) 1 d D . P A 1
Ge9 Ge 0.20847(6) 0.46703(9) 0.17250(3) 0.0386(3) Uani 0.7964(18) 1 d D . P A 1
W1 W 0.11846(10) 0.45342(14) 0.07104(4) 0.0440(3) Uani 0.7964(18) 1 d D . P A 1
C28 C 0.2247(6) 0.4025(10) 0.0492(3) 0.060(3) Uani 0.7964(18) 1 d D U P A 1
H28 H 0.261601 0.360398 0.059294 0.072 Uiso 0.7964(18) 1 calc R U P A 1
C29 C 0.2234(6) 0.5034(9) 0.0507(3) 0.052(2) Uani 0.7964(18) 1 d D U P A 1
H29 H 0.259930 0.542479 0.062337 0.062 Uiso 0.7964(18) 1 calc R U P A 1
C30 C 0.1594(6) 0.5386(10) 0.0322(3) 0.057(2) Uani 0.7964(18) 1 d D U P A 1
H30 H 0.145084 0.604519 0.029409 0.069 Uiso 0.7964(18) 1 calc R U P A 1
C31 C 0.1213(6) 0.4584(11) 0.0189(3) 0.067(3) Uani 0.7964(18) 1 d D U P A 1
H31 H 0.076734 0.459821 0.004856 0.080 Uiso 0.7964(18) 1 calc R U P A 1
C32 C 0.1603(6) 0.3763(10) 0.0298(3) 0.066(3) Uani 0.7964(18) 1 d D U P A 1
H32 H 0.145422 0.311585 0.024837 0.079 Uiso 0.7964(18) 1 calc R U P A 1
C33 C 0.0407(9) 0.3316(12) 0.0802(4) 0.090(4) Uani 0.7964(18) 1 d D U P A 1
H33 H 0.056517 0.266238 0.078807 0.108 Uiso 0.7964(18) 1 calc R U P A 1
C34 C 0.0050(7) 0.3897(15) 0.0565(4) 0.095(4) Uani 0.7964(18) 1 d D U P A 1
H34 H -0.008880 0.369429 0.036170 0.114 Uiso 0.7964(18) 1 calc R U P A 1
C35 C -0.0065(7) 0.4812(14) 0.0679(3) 0.086(4) Uani 0.7964(18) 1 d D U P A 1
H35 H -0.027956 0.535219 0.056743 0.103 Uiso 0.7964(18) 1 calc R U P A 1
C36 C 0.0190(7) 0.4792(11) 0.0985(3) 0.062(3) Uani 0.7964(18) 1 d D U P A 1
H36 H 0.016274 0.532579 0.111825 0.075 Uiso 0.7964(18) 1 calc R U P A 1
C37 C 0.0481(8) 0.3925(10) 0.1071(3) 0.065(3) Uani 0.7964(18) 1 d D U P A 1
H37 H 0.069518 0.374404 0.126905 0.078 Uiso 0.7964(18) 1 calc R U P A 1
Rh1A Rh 0.25115(15) 0.5388(2) 0.10416(6) 0.0397(8) Uani 0.2036(18) 1 d D . P A
2
Ge1A Ge 0.3869(4) 0.6618(7) 0.1230(2) 0.0351(3) Uani 0.2036(18) 1 d D . P A 2
Ge2A Ge 0.3599(7) 0.7391(9) 0.1727(3) 0.0373(4) Uani 0.2036(18) 1 d D . P A 2
Ge3A Ge 0.2469(6) 0.7117(8) 0.1166(3) 0.0354(4) Uani 0.2036(18) 1 d D . P A 2
Ge4A Ge 0.3688(2) 0.4634(3) 0.11938(9) 0.0337(10) Uani 0.2036(18) 1 d D . P A 2
Ge5A Ge 0.4487(6) 0.5838(12) 0.1738(4) 0.0406(4) Uani 0.2036(18) 1 d D . P A 2
Ge6A Ge 0.3304(9) 0.5825(11) 0.2056(3) 0.0385(4) Uani 0.2036(18) 1 d D . P A 2
Ge7A Ge 0.2236(6) 0.6676(8) 0.1697(3) 0.0330(4) Uani 0.2036(18) 1 d D . P A 2
Ge8A Ge 0.3565(7) 0.4357(10) 0.1740(3) 0.0377(4) Uani 0.2036(18) 1 d D . P A 2
Ge9A Ge 0.2322(3) 0.4987(4) 0.15554(13) 0.0490(13) Uani 0.2036(18) 1 d D . P A
2
W1A W 0.1337(4) 0.4608(6) 0.06625(17) 0.057(2) Uani 0.2036(18) 1 d D . P A 2
C28A C 0.2170(14) 0.400(2) 0.0330(7) 0.060(3) Uani 0.2036(18) 1 d D U P A 2
H28A H 0.257463 0.357447 0.039236 0.072 Uiso 0.2036(18) 1 calc R U P A 2
C29A C 0.2185(13) 0.501(2) 0.0334(6) 0.052(2) Uani 0.2036(18) 1 d D U P A 2
H29A H 0.261101 0.539865 0.040316 0.062 Uiso 0.2036(18) 1 calc R U P A 2
C30A C 0.1461(17) 0.537(2) 0.0219(5) 0.057(2) Uani 0.2036(18) 1 d D U P A 2
H30A H 0.131568 0.603104 0.020053 0.069 Uiso 0.2036(18) 1 calc R U P A 2
C31A C 0.1004(16) 0.457(3) 0.0139(4) 0.067(3) Uani 0.2036(18) 1 d D U P A 2
H31A H 0.049404 0.458368 0.005051 0.080 Uiso 0.2036(18) 1 calc R U P A 2
C32A C 0.1433(18) 0.375(2) 0.0213(6) 0.066(3) Uani 0.2036(18) 1 d D U P A 2
H32A H 0.125219 0.310198 0.018763 0.079 Uiso 0.2036(18) 1 calc R U P A 2
C33A C 0.070(2) 0.338(2) 0.0854(7) 0.090(4) Uani 0.2036(18) 1 d D U P A 2
H33A H 0.082746 0.272327 0.082671 0.108 Uiso 0.2036(18) 1 calc R U P A 2
C34A C 0.0195(14) 0.395(3) 0.0654(7) 0.095(4) Uani 0.2036(18) 1 d D U P A 2
H34A H -0.007715 0.373471 0.046885 0.114 Uiso 0.2036(18) 1 calc R U P A 2
C35A C 0.0173(13) 0.487(3) 0.0777(7) 0.086(4) Uani 0.2036(18) 1 d D U P A 2
H35A H -0.010302 0.541442 0.068949 0.103 Uiso 0.2036(18) 1 calc R U P A 2
C36A C 0.0632(16) 0.485(3) 0.1051(6) 0.062(3) Uani 0.2036(18) 1 d D U P A 2
H36A H 0.070091 0.539209 0.118513 0.075 Uiso 0.2036(18) 1 calc R U P A 2
C37A C 0.0966(18) 0.400(2) 0.1107(5) 0.065(3) Uani 0.2036(18) 1 d D U P A 2
H37A H 0.131182 0.383403 0.127850 0.078 Uiso 0.2036(18) 1 calc R U P A 2
Si1 Si 0.45505(9) 0.72263(15) 0.08951(4) 0.0333(4) Uani 1 1 d . . . . .
Si2 Si 0.50377(12) 0.58988(19) 0.06526(5) 0.0467(5) Uani 1 1 d . . . . .
Si3 Si 0.37963(12) 0.82810(18) 0.05720(5) 0.0451(5) Uani 1 1 d . . . . .
Si4 Si 0.55287(11) 0.80943(18) 0.11847(5) 0.0427(5) Uani 1 1 d . . . . .
C1 C 0.4289(6) 0.5252(9) 0.0394(3) 0.076(3) Uani 1 1 d . . . . .
H1A H 0.408474 0.568910 0.023111 0.114 Uiso 1 1 calc R U . . .
H1B H 0.388475 0.504726 0.051048 0.114 Uiso 1 1 calc R U . . .
H1C H 0.450815 0.468152 0.030712 0.114 Uiso 1 1 calc R U . . .
C2 C 0.5757(6) 0.6359(10) 0.0419(3) 0.074(3) Uani 1 1 d . . . . .
H2A H 0.611989 0.676569 0.054415 0.111 Uiso 1 1 calc R U . . .
H2B H 0.550967 0.674241 0.024945 0.111 Uiso 1 1 calc R U . . .
H2C H 0.602037 0.581046 0.033906 0.111 Uiso 1 1 calc R U . . .
C3 C 0.5486(8) 0.5028(10) 0.0947(3) 0.086(4) Uani 1 1 d . . . . .
H3A H 0.538570 0.436160 0.087658 0.129 Uiso 1 1 calc R U . . .
H3B H 0.527500 0.512872 0.113763 0.129 Uiso 1 1 calc R U . . .
H3C H 0.603043 0.513872 0.097846 0.129 Uiso 1 1 calc R U . . .
C4 C 0.2954(5) 0.7674(8) 0.0368(2) 0.059(2) Uani 1 1 d . . . . .
H4A H 0.261601 0.747372 0.051418 0.089 Uiso 1 1 calc R U . . .
H4B H 0.311278 0.710282 0.026096 0.089 Uiso 1 1 calc R U . . .
H4C H 0.269084 0.812520 0.022135 0.089 Uiso 1 1 calc R U . . .
C5 C 0.4378(6) 0.8740(10) 0.0273(3) 0.077(3) Uani 1 1 d . . . . .
H5A H 0.406723 0.916163 0.013072 0.116 Uiso 1 1 calc R U . . .
H5B H 0.455753 0.818951 0.016234 0.116 Uiso 1 1 calc R U . . .
H5C H 0.480938 0.910720 0.037039 0.116 Uiso 1 1 calc R U . . .
C6 C 0.3489(7) 0.9297(8) 0.0798(3) 0.077(3) Uani 1 1 d . . . . .
H6A H 0.313348 0.970425 0.066957 0.115 Uiso 1 1 calc R U . . .
H6B H 0.392734 0.968400 0.087839 0.115 Uiso 1 1 calc R U . . .
H6C H 0.324323 0.904053 0.096704 0.115 Uiso 1 1 calc R U . . .
C7 C 0.5156(6) 0.9011(9) 0.1432(3) 0.074(3) Uani 1 1 d . . . . .
H7A H 0.480213 0.870132 0.155432 0.110 Uiso 1 1 calc R U . . .
H7B H 0.489584 0.952129 0.130699 0.110 Uiso 1 1 calc R U . . .
H7C H 0.557290 0.929553 0.156706 0.110 Uiso 1 1 calc R U . . .
C8 C 0.6104(5) 0.8723(9) 0.0923(2) 0.065(3) Uani 1 1 d . . . . .
H8A H 0.652490 0.905837 0.104116 0.098 Uiso 1 1 calc R U . . .
H8B H 0.579099 0.919612 0.080092 0.098 Uiso 1 1 calc R U . . .
H8C H 0.630042 0.824754 0.078886 0.098 Uiso 1 1 calc R U . . .
C9 C 0.6148(5) 0.7260(9) 0.1424(3) 0.073(3) Uani 1 1 d . . . . .
H9A H 0.633190 0.675428 0.129683 0.109 Uiso 1 1 calc R U . . .
H9B H 0.586552 0.696229 0.157536 0.109 Uiso 1 1 calc R U . . .
H9C H 0.657648 0.762158 0.152691 0.109 Uiso 1 1 calc R U . . .
Si5 Si 0.11956(10) 0.73335(15) 0.19480(4) 0.0345(4) Uani 1 1 d . . . . .
Si6 Si 0.04040(13) 0.6133(2) 0.21144(5) 0.0482(5) Uani 1 1 d D . . . .
Si7 Si 0.05246(14) 0.8306(2) 0.15712(5) 0.0503(5) Uani 1 1 d D . . . .
Si8 Si 0.17205(13) 0.82660(19) 0.23619(5) 0.0475(5) Uani 1 1 d D . . . .
C10 C -0.0117(5) 0.5499(9) 0.1783(2) 0.070(3) Uani 1 1 d D . . . .
H10A H 0.024203 0.517123 0.166754 0.105 Uiso 1 1 calc R U . . .
H10B H -0.040731 0.597273 0.165237 0.105 Uiso 1 1 calc R U . . .
H10C H -0.045929 0.502073 0.185437 0.105 Uiso 1 1 calc R U . . .
C11 C -0.0294(6) 0.6740(9) 0.2336(3) 0.078(3) Uani 1 1 d D . . . .
H11A H -0.049192 0.732197 0.222749 0.117 Uiso 1 1 calc R U . . .
H11B H -0.004526 0.692214 0.253643 0.117 Uiso 1 1 calc R U . . .
H11C H -0.070841 0.629295 0.235845 0.117 Uiso 1 1 calc R U . . .
C12 C 0.0949(7) 0.5236(8) 0.2367(2) 0.074(3) Uani 1 1 d D . . . .
H12A H 0.070100 0.460269 0.234445 0.111 Uiso 1 1 calc R U . . .
H12B H 0.097111 0.545051 0.257835 0.111 Uiso 1 1 calc R U . . .
H12C H 0.146034 0.518362 0.231139 0.111 Uiso 1 1 calc R U . . .
C13 C 0.0305(5) 0.7680(8) 0.1198(2) 0.062(3) Uani 1 1 d D . . . .
H13A H -0.001404 0.711517 0.122184 0.093 Uiso 1 1 calc R U . . .
H13B H 0.077438 0.746828 0.112521 0.093 Uiso 1 1 calc R U . . .
H13C H 0.004014 0.812781 0.105044 0.093 Uiso 1 1 calc R U . . .
C14 C 0.1087(7) 0.9435(7) 0.1514(2) 0.071(3) Uani 1 1 d D . . . .
H14A H 0.160097 0.925363 0.148188 0.106 Uiso 1 1 calc R U . . .
H14B H 0.110288 0.984872 0.169394 0.106 Uiso 1 1 calc R U . . .
H14C H 0.085000 0.978912 0.133630 0.106 Uiso 1 1 calc R U . . .
C15 C -0.0395(6) 0.8656(10) 0.1696(2) 0.076(3) Uani 1 1 d D . . . .
H15A H -0.071022 0.896712 0.152807 0.114 Uiso 1 1 calc R U . . .
H15B H -0.030832 0.910830 0.186713 0.114 Uiso 1 1 calc R U . . .
H15C H -0.064985 0.807572 0.176010 0.114 Uiso 1 1 calc R U . . .
C16 C 0.2119(7) 0.7484(9) 0.2686(2) 0.077(3) Uani 1 1 d D . . . .
H16A H 0.226858 0.789024 0.286420 0.116 Uiso 1 1 calc R U . . .
H16B H 0.255966 0.713641 0.263073 0.116 Uiso 1 1 calc R U . . .
H16C H 0.173774 0.701707 0.273304 0.116 Uiso 1 1 calc R U . . .
C17 C 0.2480(7) 0.9102(10) 0.2257(3) 0.091(4) Uani 1 1 d D . . . .
H17A H 0.229405 0.945790 0.207200 0.137 Uiso 1 1 calc R U . . .
H17B H 0.292275 0.872135 0.222169 0.137 Uiso 1 1 calc R U . . .
H17C H 0.261664 0.956170 0.242258 0.137 Uiso 1 1 calc R U . . .
C18 C 0.0969(6) 0.9051(11) 0.2490(3) 0.100(5) Uani 1 1 d D . . . .
H18A H 0.050744 0.867092 0.249269 0.149 Uiso 1 1 calc R U . . .
H18B H 0.087066 0.959680 0.234954 0.149 Uiso 1 1 calc R U . . .
H18C H 0.113469 0.929596 0.269395 0.149 Uiso 1 1 calc R U . . .
Si9 Si 0.39675(12) 0.28522(17) 0.19550(5) 0.0433(5) Uani 1 1 d . . . . .
Si10 Si 0.5269(5) 0.2765(7) 0.1843(2) 0.057(2) Uani 0.382(7) 1 d D . P A 1
Si11 Si 0.4009(4) 0.2971(6) 0.24905(14) 0.058(2) Uani 0.382(7) 1 d D . P A 1
Si12 Si 0.3212(5) 0.1758(5) 0.1725(2) 0.062(2) Uani 0.382(7) 1 d D . P A 1
C19 C 0.568(3) 0.168(2) 0.2057(9) 0.14(3) Uani 0.382(7) 1 d D . P A 1
H19A H 0.569416 0.179678 0.227545 0.206 Uiso 0.382(7) 1 calc R U P A 1
H19B H 0.536004 0.111114 0.200118 0.206 Uiso 0.382(7) 1 calc R U P A 1
H19C H 0.618606 0.155932 0.200689 0.206 Uiso 0.382(7) 1 calc R U P A 1
C20 C 0.5850(13) 0.3866(17) 0.1949(10) 0.101(14) Uani 0.382(7) 1 d D . P A 1
H20A H 0.587253 0.397852 0.216744 0.151 Uiso 0.382(7) 1 calc R U P A 1
H20B H 0.636066 0.376714 0.189576 0.151 Uiso 0.382(7) 1 calc R U P A 1
H20C H 0.562267 0.442810 0.183855 0.151 Uiso 0.382(7) 1 calc R U P A 1
C21 C 0.523(2) 0.255(3) 0.1428(4) 0.095(12) Uani 0.382(7) 1 d D . P A 1
H21A H 0.492532 0.197798 0.137197 0.143 Uiso 0.382(7) 1 calc R U P A 1
H21B H 0.500236 0.311829 0.131855 0.143 Uiso 0.382(7) 1 calc R U P A 1
H21C H 0.574035 0.245733 0.137577 0.143 Uiso 0.382(7) 1 calc R U P A 1
C22 C 0.415(2) 0.1700(19) 0.2635(13) 0.094(19) Uani 0.382(7) 1 d D . P A 1
H22A H 0.374924 0.128472 0.253793 0.140 Uiso 0.382(7) 1 calc R U P A 1
H22B H 0.463950 0.145826 0.258848 0.140 Uiso 0.382(7) 1 calc R U P A 1
H22C H 0.414201 0.169299 0.285547 0.140 Uiso 0.382(7) 1 calc R U P A 1
C23 C 0.3049(16) 0.340(3) 0.2564(9) 0.13(2) Uani 0.382(7) 1 d D U P A 1
H23A H 0.266491 0.296314 0.246352 0.202 Uiso 0.382(7) 1 calc R U P A 1
H23B H 0.301937 0.340097 0.278280 0.202 Uiso 0.382(7) 1 calc R U P A 1
H23C H 0.296369 0.405664 0.248380 0.202 Uiso 0.382(7) 1 calc R U P A 1
C24 C 0.4761(15) 0.375(2) 0.2672(7) 0.105(14) Uani 0.382(7) 1 d D . P A 1
H24A H 0.468388 0.441592 0.259540 0.158 Uiso 0.382(7) 1 calc R U P A 1
H24B H 0.475118 0.374769 0.289186 0.158 Uiso 0.382(7) 1 calc R U P A 1
H24C H 0.524867 0.351296 0.262487 0.158 Uiso 0.382(7) 1 calc R U P A 1
C25 C 0.368(2) 0.0560(17) 0.1785(9) 0.068(6) Uani 0.382(7) 1 d D . P A 1
H25A H 0.415323 0.056474 0.169392 0.102 Uiso 0.382(7) 1 calc R U P A 1
H25B H 0.378735 0.042986 0.200255 0.102 Uiso 0.382(7) 1 calc R U P A 1
H25C H 0.334943 0.005363 0.168884 0.102 Uiso 0.382(7) 1 calc R U P A 1
C26 C 0.299(2) 0.203(2) 0.1313(5) 0.13(2) Uani 0.382(7) 1 d D U P A 1
H26A H 0.345780 0.201641 0.121766 0.201 Uiso 0.382(7) 1 calc R U P A 1
H26B H 0.264283 0.154032 0.121800 0.201 Uiso 0.382(7) 1 calc R U P A 1
H26C H 0.276123 0.267134 0.128714 0.201 Uiso 0.382(7) 1 calc R U P A 1
C27 C 0.2312(13) 0.179(2) 0.1893(10) 0.13(2) Uani 0.382(7) 1 d D U P A 1
H27A H 0.207851 0.242981 0.185807 0.197 Uiso 0.382(7) 1 calc R U P A 1
H27B H 0.197206 0.129237 0.179775 0.197 Uiso 0.382(7) 1 calc R U P A 1
H27C H 0.240997 0.166860 0.211145 0.197 Uiso 0.382(7) 1 calc R U P A 1
Si0A Si 0.5241(3) 0.2825(5) 0.2014(2) 0.079(2) Uani 0.618(7) 1 d D . P A 2
Si1A Si 0.3410(3) 0.2513(4) 0.23984(10) 0.0662(16) Uani 0.618(7) 1 d D . P A 2
Si2A Si 0.3438(3) 0.1761(3) 0.15525(12) 0.0516(11) Uani 0.618(7) 1 d D . P A 2
C19A C 0.5589(15) 0.1540(14) 0.2061(7) 0.090(12) Uani 0.618(7) 1 d D U P A 2
H19D H 0.538584 0.124069 0.223335 0.135 Uiso 0.618(7) 1 calc R U P A 2
H19E H 0.542298 0.117225 0.187583 0.135 Uiso 0.618(7) 1 calc R U P A 2
H19F H 0.614028 0.153856 0.209664 0.135 Uiso 0.618(7) 1 calc R U P A 2
C20A C 0.5571(12) 0.354(2) 0.2365(5) 0.134(12) Uani 0.618(7) 1 d D . P A 2
H20D H 0.537256 0.324558 0.253947 0.202 Uiso 0.618(7) 1 calc R U P A 2
H20E H 0.612231 0.353500 0.239796 0.202 Uiso 0.618(7) 1 calc R U P A 2
H20F H 0.539089 0.420737 0.233935 0.202 Uiso 0.618(7) 1 calc R U P A 2
C21A C 0.5625(12) 0.340(2) 0.1686(6) 0.143(16) Uani 0.618(7) 1 d D . P A 2
H21D H 0.545717 0.303150 0.150139 0.215 Uiso 0.618(7) 1 calc R U P A 2
H21E H 0.544488 0.406598 0.166334 0.215 Uiso 0.618(7) 1 calc R U P A 2
H21F H 0.617630 0.339361 0.172194 0.215 Uiso 0.618(7) 1 calc R U P A 2
C22A C 0.3888(17) 0.1435(19) 0.2593(9) 0.095(10) Uani 0.618(7) 1 d D . P A 2
H22D H 0.382384 0.087254 0.245776 0.143 Uiso 0.618(7) 1 calc R U P A 2
H22E H 0.442533 0.157267 0.264389 0.143 Uiso 0.618(7) 1 calc R U P A 2
H22F H 0.366422 0.129672 0.277911 0.143 Uiso 0.618(7) 1 calc R U P A 2
C23A C 0.2382(8) 0.2214(17) 0.2298(5) 0.087(7) Uani 0.618(7) 1 d D . P A 2
H23D H 0.233089 0.165917 0.215960 0.130 Uiso 0.618(7) 1 calc R U P A 2
H23E H 0.216071 0.205394 0.248311 0.130 Uiso 0.618(7) 1 calc R U P A 2
H23F H 0.212010 0.277468 0.219941 0.130 Uiso 0.618(7) 1 calc R U P A 2
C24A C 0.354(2) 0.3555(17) 0.2659(5) 0.131(15) Uani 0.618(7) 1 d D . P A 2
H24D H 0.329521 0.412655 0.256140 0.197 Uiso 0.618(7) 1 calc R U P A 2
H24E H 0.331957 0.340743 0.284501 0.197 Uiso 0.618(7) 1 calc R U P A 2
H24F H 0.408068 0.368338 0.270978 0.197 Uiso 0.618(7) 1 calc R U P A 2
C25A C 0.3498(12) 0.0494(10) 0.1695(5) 0.068(6) Uani 0.618(7) 1 d D . P A 2
H25D H 0.321696 0.043632 0.187023 0.102 Uiso 0.618(7) 1 calc R U P A 2
H25E H 0.328292 0.005459 0.153431 0.102 Uiso 0.618(7) 1 calc R U P A 2
H25F H 0.402646 0.032452 0.175581 0.102 Uiso 0.618(7) 1 calc R U P A 2
C26A C 0.3968(12) 0.1892(14) 0.1219(4) 0.083(6) Uani 0.618(7) 1 d D . P A 2
H26D H 0.393139 0.256257 0.114666 0.124 Uiso 0.618(7) 1 calc R U P A 2
H26E H 0.449764 0.172600 0.127873 0.124 Uiso 0.618(7) 1 calc R U P A 2
H26F H 0.375409 0.145607 0.105722 0.124 Uiso 0.618(7) 1 calc R U P A 2
C27A C 0.2438(9) 0.2069(17) 0.1414(5) 0.091(7) Uani 0.618(7) 1 d D . P A 2
H27D H 0.240993 0.273753 0.133877 0.136 Uiso 0.618(7) 1 calc R U P A 2
H27E H 0.225003 0.162771 0.124878 0.136 Uiso 0.618(7) 1 calc R U P A 2
H27F H 0.212983 0.200320 0.158034 0.136 Uiso 0.618(7) 1 calc R U P A 2
B1 B 0.1592(4) 0.9304(6) -0.06536(16) 0.0266(15) Uani 1 1 d . . . . .
C101 C 0.2257(4) 0.8508(5) -0.05667(14) 0.0310(14) Uani 1 1 d . . . . .
C102 C 0.2091(4) 0.7533(6) -0.05330(16) 0.0371(15) Uiso 1 1 d . . . . .
H102 H 0.157845 0.734635 -0.053873 0.045 Uiso 1 1 calc R U . . .
C103 C 0.2641(4) 0.6821(6) -0.04912(18) 0.0432(18) Uani 1 1 d . . . . .
C104 C 0.3393(4) 0.7054(7) -0.04916(19) 0.049(2) Uani 1 1 d . . . . .
H104 H 0.377316 0.657203 -0.046059 0.059 Uiso 1 1 calc R U . . .
C105 C 0.3569(4) 0.7997(7) -0.05377(19) 0.048(2) Uani 1 1 d . . . . .
C106 C 0.3014(4) 0.8723(6) -0.05705(17) 0.0373(16) Uani 1 1 d . . . . .
H106 H 0.316075 0.937648 -0.059581 0.045 Uiso 1 1 calc R U . . .
C107 C 0.2450(6) 0.5779(7) -0.0454(3) 0.064(3) Uani 1 1 d . . . . .
C108 C 0.4367(5) 0.8281(10) -0.0568(3) 0.070(3) Uani 1 1 d . . . . .
C109 C 0.0839(3) 0.9106(5) -0.04843(15) 0.0283(13) Uani 1 1 d . . . . .
C110 C 0.0142(4) 0.9511(5) -0.05954(15) 0.0326(14) Uani 1 1 d . . . . .
H110 H 0.010586 0.987628 -0.077789 0.039 Uiso 1 1 calc R U . . .
C111 C -0.0495(4) 0.9404(6) -0.04518(16) 0.0350(16) Uani 1 1 d . . . . .
C112 C -0.0470(4) 0.8886(6) -0.01814(17) 0.0391(17) Uani 1 1 d . . . . .
H112 H -0.090709 0.880976 -0.008174 0.047 Uiso 1 1 calc R U . . .
C113 C 0.0205(4) 0.8491(6) -0.00643(15) 0.0344(15) Uani 1 1 d . . . . .
C114 C 0.0849(4) 0.8591(5) -0.02102(15) 0.0311(14) Uani 1 1 d . . . . .
H114 H 0.130673 0.830476 -0.012208 0.037 Uiso 1 1 calc R U . . .
C115 C -0.1237(4) 0.9808(7) -0.05912(18) 0.047(2) Uani 1 1 d . . . . .
C116 C 0.0239(5) 0.7880(6) 0.02171(18) 0.0444(18) Uani 1 1 d . . . . .
C117 C 0.1878(3) 1.0398(5) -0.05611(16) 0.0314(14) Uani 1 1 d . . . . .
C118 C 0.2310(4) 1.0599(6) -0.02804(17) 0.0372(16) Uani 1 1 d . . . . .
H118 H 0.243782 1.007832 -0.014379 0.045 Uiso 1 1 calc R U . . .
C119 C 0.2554(4) 1.1519(6) -0.01963(18) 0.0397(17) Uani 1 1 d . . . . .
C120 C 0.2375(4) 1.2294(6) -0.0386(2) 0.0441(18) Uani 1 1 d . . . . .
H120 H 0.253332 1.292935 -0.032577 0.053 Uiso 1 1 calc R U . . .
C121 C 0.1952(4) 1.2133(6) -0.0674(2) 0.0461(19) Uani 1 1 d . . . . .
C122 C 0.1698(4) 1.1200(6) -0.07522(19) 0.0413(17) Uani 1 1 d . . . . .
H122 H 0.139283 1.110284 -0.094014 0.050 Uiso 1 1 calc R U . . .
C123 C 0.3024(6) 1.1671(7) 0.0099(2) 0.057(2) Uani 1 1 d . . . . .
C124 C 0.1804(6) 1.2967(8) -0.0891(3) 0.070(3) Uani 1 1 d . . . . .
C125 C 0.1408(4) 0.9197(6) -0.10254(15) 0.0332(15) Uani 1 1 d . . . . .
C126 C 0.1932(4) 0.9560(7) -0.12076(18) 0.0450(19) Uani 1 1 d . . . . .
H126 H 0.236264 0.989259 -0.111302 0.054 Uiso 1 1 calc R U . . .
C127 C 0.1845(5) 0.9451(8) -0.15213(19) 0.053(2) Uani 1 1 d . . . . .
C128 C 0.1218(4) 0.8984(6) -0.16682(17) 0.0423(17) Uani 1 1 d . . . . .
H128 H 0.114876 0.892818 -0.188292 0.051 Uiso 1 1 calc R U . . .
C129 C 0.0702(4) 0.8607(6) -0.14985(18) 0.0426(18) Uani 1 1 d . . . . .
C130 C 0.0804(4) 0.8697(6) -0.11793(16) 0.0368(16) Uani 1 1 d . . . . .
H130 H 0.044718 0.840469 -0.106579 0.044 Uiso 1 1 calc R U . . .
C131 C 0.0025(6) 0.8093(10) -0.1655(2) 0.067(3) Uani 1 1 d . . . . .
F101 F 0.1756(4) 0.5605(5) -0.0443(3) 0.112(3) Uani 1 1 d . . . . .
F102 F 0.2816(4) 0.5385(6) -0.0195(2) 0.099(2) Uani 1 1 d . . . . .
F103 F 0.2697(6) 0.5208(6) -0.0657(3) 0.123(3) Uani 1 1 d . . . . .
F104 F 0.4475(4) 0.8378(11) -0.0852(2) 0.165(6) Uani 1 1 d . . . . .
F105 F 0.4572(3) 0.9112(5) -0.04416(18) 0.0784(19) Uani 1 1 d . . . . .
F106 F 0.4858(3) 0.7638(6) -0.0452(3) 0.138(5) Uani 1 1 d . . . . .
F107 F -0.1159(3) 1.0546(5) -0.07810(13) 0.0687(16) Uani 1 1 d . . . . .
F108 F -0.1642(3) 0.9138(5) -0.07557(14) 0.0753(19) Uani 1 1 d . . . . .
F109 F -0.1666(2) 1.0122(4) -0.03873(11) 0.0537(12) Uani 1 1 d . . . . .
F110 F 0.0029(4) 0.6960(4) 0.01459(13) 0.0696(16) Uani 1 1 d . . . . .
F111 F 0.0918(3) 0.7806(4) 0.03702(12) 0.0608(14) Uani 1 1 d . . . . .
F112 F -0.0229(4) 0.8171(5) 0.04072(13) 0.0766(19) Uani 1 1 d . . . . .
F113 F 0.2584(6) 1.1678(8) 0.03258(15) 0.115(3) Uani 1 1 d . . . . .
F114 F 0.3520(7) 1.1034(8) 0.0163(3) 0.179(7) Uani 1 1 d . . . . .
F115 F 0.3340(4) 1.2535(5) 0.01242(14) 0.082(2) Uani 1 1 d . . . . .
F116 F 0.1308(4) 1.3557(6) -0.0811(2) 0.098(2) Uani 1 1 d . . . . .
F117 F 0.1545(4) 1.2674(5) -0.11748(16) 0.087(2) Uani 1 1 d . . . . .
F118 F 0.2434(4) 1.3441(5) -0.09219(17) 0.084(2) Uani 1 1 d . . . . .
F119 F -0.0538(3) 0.8040(5) -0.14955(14) 0.0754(18) Uani 1 1 d . . . . .
F120 F 0.0163(4) 0.7258(7) -0.1753(3) 0.135(4) Uani 1 1 d . . . . .
F121 F -0.0274(4) 0.8586(8) -0.19067(15) 0.104(3) Uani 1 1 d . . . . .
F122 F 0.2300(6) 0.9738(9) -0.19855(15) 0.151(5) Uani 1 1 d . . . . .
F123 F 0.3106(5) 0.9506(11) -0.1611(3) 0.158(5) Uani 1 1 d . . . . .
F124 F 0.2554(7) 1.0780(8) -0.1641(2) 0.134(4) Uani 1 1 d . . . . .
O1S O 0.2191(11) 0.9303(12) 0.3298(3) 0.155(6) Uani 1 1 d . . . . .
C2S C 0.2363(11) 1.0803(15) 0.3093(4) 0.139(8) Uani 1 1 d . . . . .
H2S1 H 0.249169 1.146688 0.315826 0.209 Uiso 1 1 calc R U . . .
H2S2 H 0.273795 1.056014 0.296858 0.209 Uiso 1 1 calc R U . . .
H2S3 H 0.186467 1.079694 0.297419 0.209 Uiso 1 1 calc R U . . .
C1S C 0.2353(12) 1.0156(19) 0.3372(5) 0.141(9) Uani 1 1 d . . . . .
H1S1 H 0.285438 1.017174 0.349376 0.169 Uiso 1 1 calc R U . . .
H1S2 H 0.198036 1.040875 0.349938 0.169 Uiso 1 1 calc R U . . .
C4S C 0.2542(15) 0.822(2) 0.3644(5) 0.216(17) Uani 1 1 d D . . . .
H4S1 H 0.255002 0.779470 0.382053 0.324 Uiso 1 1 calc R U . . .
H4S2 H 0.255319 0.782597 0.346055 0.324 Uiso 1 1 calc R U . . .
H4S3 H 0.298347 0.864600 0.366927 0.324 Uiso 1 1 calc R U . . .
C3S C 0.183(2) 0.883(3) 0.3613(8) 0.32(3) Uani 1 1 d D . . . .
H3S1 H 0.180153 0.929424 0.377996 0.381 Uiso 1 1 calc R U . . .
H3S2 H 0.136084 0.845437 0.356618 0.381 Uiso 1 1 calc R U . . .
C132 C 0.2415(7) 0.9880(12) -0.1698(2) 0.080(4) Uani 1 1 d . . . . .
H1 H 0.131(6) 0.5751(16) 0.0836(13) 0.096 Uiso 1 1 d D U . B 1
H2 H 0.187(5) 0.415(3) 0.1010(16) 0.096 Uiso 1 1 d D U . C 1
H3 H 0.1270(11) 0.6142(17) 0.1153(6) 0.096 Uiso 1 1 d D U . D 1


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 Ge4 2.3786(13) . ?
Rh1 Ge3 2.400(2) . ?
Rh1 Ge9 2.4049(14) . ?
Rh1 Ge7 2.674(3) . ?
Rh1 W1 2.7978(17) . ?
Rh1 H1 2.01(2) . ?
Rh1 H2 2.00(2) . ?
Rh1 H3 1.55(2) . ?
Ge1 Ge4 2.391(2) . ?
Ge1 Si1 2.422(2) . ?
Ge1 Ge3 2.513(2) . ?
Ge1 Ge2 2.596(3) . ?
Ge1 Ge5 2.625(3) . ?
Ge2 Ge7 2.629(3) . ?
Ge2 Ge5 2.672(3) . ?
Ge2 Ge6 2.682(3) . ?
Ge3 Ge7 2.555(3) . ?
Ge4 Ge8 2.453(3) . ?
Ge5 Ge8 2.605(3) . ?
Ge5 Ge6 2.687(3) . ?
Ge6 Ge8 2.579(3) . ?
Ge6 Ge7 2.633(3) . ?
Ge7 Si5 2.366(3) . ?
Ge7 Ge9 2.558(3) . ?
Ge8 Si9 2.379(4) . ?
Ge8 Ge9 2.498(3) . ?
W1 C34 2.236(11) . ?
W1 C33 2.252(14) . ?
W1 C35 2.258(11) . ?
W1 C30 2.281(12) . ?
W1 C29 2.288(11) . ?
W1 C36 2.305(11) . ?
W1 C37 2.312(12) . ?
W1 C32 2.320(11) . ?
W1 C31 2.325(12) . ?
W1 C28 2.345(11) . ?
W1 H1 1.78(2) . ?
W1 H2 1.78(2) . ?
C28 C29 1.395(18) . ?
C28 C32 1.402(15) . ?
C28 H28 0.9500 . ?
C29 C30 1.412(16) . ?
C29 H29 0.9500 . ?
C30 C31 1.395(17) . ?
C30 H30 0.9500 . ?
C31 C32 1.388(19) . ?
C31 H31 0.9500 . ?
C32 H32 0.9500 . ?
C33 C34 1.41(2) . ?
C33 C37 1.45(2) . ?
C33 H33 0.9500 . ?
C34 C35 1.38(2) . ?
C34 H34 0.9500 . ?
C35 C36 1.381(19) . ?
C35 H35 0.9500 . ?
C36 C37 1.34(2) . ?
C36 H36 0.9500 . ?
C37 H37 0.9500 . ?
Rh1A Ge4A 2.373(5) . ?
Rh1A Ge9A 2.412(7) . ?
Rh1A Ge3A 2.452(11) . ?
Rh1A W1A 2.749(7) . ?
Rh1A Ge1A 2.999(8) . ?
Ge1A Si1 2.202(9) . ?
Ge1A Ge2A 2.549(13) . ?
Ge1A Ge3A 2.581(11) . ?
Ge1A Ge5A 2.621(13) . ?
Ge1A Ge4A 2.759(10) . ?
Ge2A Ge7A 2.621(13) . ?
Ge2A Ge5A 2.665(14) . ?
Ge2A Ge6A 2.699(14) . ?
Ge3A Ge7A 2.517(12) . ?
Ge4A Ge8A 2.490(12) . ?
Ge5A Ge8A 2.630(14) . ?
Ge5A Ge6A 2.686(14) . ?
Ge6A Ge8A 2.543(13) . ?
Ge6A Ge7A 2.616(13) . ?
Ge7A Ge9A 2.425(12) . ?
Ge7A Si5 2.458(11) . ?
Ge8A Si9 2.363(12) . ?
Ge8A Ge9A 2.435(12) . ?
W1A C34A 2.234(18) . ?
W1A C35A 2.235(18) . ?
W1A C30A 2.267(18) . ?
W1A C33A 2.27(2) . ?
W1A C36A 2.285(18) . ?
W1A C29A 2.298(17) . ?
W1A C37A 2.315(18) . ?
W1A C31A 2.330(17) . ?
W1A C32A 2.348(17) . ?
W1A C28A 2.376(18) . ?
C28A C29A 1.39(2) . ?
C28A C32A 1.40(2) . ?
C28A H28A 0.9500 . ?
C29A C30A 1.42(2) . ?
C29A H29A 0.9500 . ?
C30A C31A 1.40(2) . ?
C30A H30A 0.9500 . ?
C31A C32A 1.39(3) . ?
C31A H31A 0.9500 . ?
C32A H32A 0.9500 . ?
C33A C34A 1.42(3) . ?
C33A C37A 1.45(3) . ?
C33A H33A 0.9500 . ?
C34A C35A 1.39(3) . ?
C34A H34A 0.9500 . ?
C35A C36A 1.39(3) . ?
C35A H35A 0.9500 . ?
C36A C37A 1.33(3) . ?
C36A H36A 0.9500 . ?
C37A H37A 0.9500 . ?
Si1 Si2 2.347(3) . ?
Si1 Si3 2.352(3) . ?
Si1 Si4 2.369(3) . ?
Si2 C2 1.862(10) . ?
Si2 C1 1.880(9) . ?
Si2 C3 1.882(12) . ?
Si3 C6 1.848(10) . ?
Si3 C4 1.861(9) . ?
Si3 C5 1.894(11) . ?
Si4 C9 1.844(10) . ?
Si4 C7 1.854(11) . ?
Si4 C8 1.860(10) . ?
C1 H1A 0.9800 . ?
C1 H1B 0.9800 . ?
C1 H1C 0.9800 . ?
C2 H2A 0.9800 . ?
C2 H2B 0.9800 . ?
C2 H2C 0.9800 . ?
C3 H3A 0.9800 . ?
C3 H3B 0.9800 . ?
C3 H3C 0.9800 . ?
C4 H4A 0.9800 . ?
C4 H4B 0.9800 . ?
C4 H4C 0.9800 . ?
C5 H5A 0.9800 . ?
C5 H5B 0.9800 . ?
C5 H5C 0.9800 . ?
C6 H6A 0.9800 . ?
C6 H6B 0.9800 . ?
C6 H6C 0.9800 . ?
C7 H7A 0.9800 . ?
C7 H7B 0.9800 . ?
C7 H7C 0.9800 . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
Si5 Si8 2.346(3) . ?
Si5 Si6 2.357(3) . ?
Si5 Si7 2.358(3) . ?
Si6 C10 1.863(9) . ?
Si6 C12 1.865(10) . ?
Si6 C11 1.878(10) . ?
Si7 C15 1.864(10) . ?
Si7 C13 1.870(9) . ?
Si7 C14 1.890(10) . ?
Si8 C18 1.869(10) . ?
Si8 C16 1.870(10) . ?
Si8 C17 1.884(10) . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C13 H13C 0.9800 . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
Si9 Si12 2.195(7) . ?
Si9 Si0A 2.263(6) . ?
Si9 Si1A 2.361(5) . ?
Si9 Si11 2.376(7) . ?
Si9 Si2A 2.440(5) . ?
Si9 Si10 2.445(8) . ?
Si10 C21 1.856(17) . ?
Si10 C20 1.870(18) . ?
Si10 C19 1.875(18) . ?
Si11 C24 1.833(18) . ?
Si11 C22 1.876(16) . ?
Si11 C23 1.883(18) . ?
Si12 C27 1.855(17) . ?
Si12 C25 1.859(16) . ?
Si12 C26 1.863(18) . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C21 H21A 0.9800 . ?
C21 H21B 0.9800 . ?
C21 H21C 0.9800 . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C25 H25A 0.9800 . ?
C25 H25B 0.9800 . ?
C25 H25C 0.9800 . ?
C26 H26A 0.9800 . ?
C26 H26B 0.9800 . ?
C26 H26C 0.9800 . ?
C27 H27A 0.9800 . ?
C27 H27B 0.9800 . ?
C27 H27C 0.9800 . ?
Si0A C21A 1.859(17) . ?
Si0A C20A 1.876(17) . ?
Si0A C19A 1.884(14) . ?
Si1A C24A 1.844(17) . ?
Si1A C22A 1.875(16) . ?
Si1A C23A 1.885(15) . ?
Si2A C25A 1.858(14) . ?
Si2A C26A 1.861(15) . ?
Si2A C27A 1.870(15) . ?
C19A H19D 0.9800 . ?
C19A H19E 0.9800 . ?
C19A H19F 0.9800 . ?
C20A H20D 0.9800 . ?
C20A H20E 0.9800 . ?
C20A H20F 0.9800 . ?
C21A H21D 0.9800 . ?
C21A H21E 0.9800 . ?
C21A H21F 0.9800 . ?
C22A H22D 0.9800 . ?
C22A H22E 0.9800 . ?
C22A H22F 0.9800 . ?
C23A H23D 0.9800 . ?
C23A H23E 0.9800 . ?
C23A H23F 0.9800 . ?
C24A H24D 0.9800 . ?
C24A H24E 0.9800 . ?
C24A H24F 0.9800 . ?
C25A H25D 0.9800 . ?
C25A H25E 0.9800 . ?
C25A H25F 0.9800 . ?
C26A H26D 0.9800 . ?
C26A H26E 0.9800 . ?
C26A H26F 0.9800 . ?
C27A H27D 0.9800 . ?
C27A H27E 0.9800 . ?
C27A H27F 0.9800 . ?
B1 C117 1.631(10) . ?
B1 C101 1.631(10) . ?
B1 C109 1.645(9) . ?
B1 C125 1.651(9) . ?
C101 C102 1.391(11) . ?
C101 C106 1.390(10) . ?
C102 C103 1.388(11) . ?
C102 H102 0.9500 . ?
C103 C104 1.385(12) . ?
C103 C107 1.492(14) . ?
C104 C105 1.361(14) . ?
C104 H104 0.9500 . ?
C105 C106 1.406(12) . ?
C105 C108 1.502(12) . ?
C106 H106 0.9500 . ?
C107 F101 1.271(13) . ?
C107 F103 1.314(14) . ?
C107 F102 1.365(14) . ?
C108 F104 1.306(15) . ?
C108 F106 1.310(15) . ?
C108 F105 1.311(14) . ?
C109 C110 1.402(10) . ?
C109 C114 1.408(10) . ?
C110 C111 1.380(10) . ?
C110 H110 0.9500 . ?
C111 C112 1.394(12) . ?
C111 C115 1.502(10) . ?
C112 C113 1.371(11) . ?
C112 H112 0.9500 . ?
C113 C114 1.397(10) . ?
C113 C116 1.503(11) . ?
C114 H114 0.9500 . ?
C115 F109 1.329(9) . ?
C115 F108 1.336(10) . ?
C115 F107 1.340(12) . ?
C116 F112 1.322(10) . ?
C116 F111 1.323(10) . ?
C116 F110 1.352(10) . ?
C117 C122 1.409(11) . ?
C117 C118 1.413(10) . ?
C118 C119 1.380(11) . ?
C118 H118 0.9500 . ?
C119 C120 1.376(13) . ?
C119 C123 1.487(12) . ?
C120 C121 1.424(12) . ?
C120 H120 0.9500 . ?
C121 C122 1.395(12) . ?
C121 C124 1.501(15) . ?
C122 H122 0.9500 . ?
C123 F114 1.259(14) . ?
C123 F115 1.318(12) . ?
C123 F113 1.350(13) . ?
C124 F116 1.286(14) . ?
C124 F118 1.326(13) . ?
C124 F117 1.353(14) . ?
C125 C130 1.391(10) . ?
C125 C126 1.404(11) . ?
C126 C127 1.391(12) . ?
C126 H126 0.9500 . ?
C127 C128 1.388(12) . ?
C127 C132 1.484(14) . ?
C128 C129 1.365(12) . ?
C128 H128 0.9500 . ?
C129 C130 1.413(11) . ?
C129 C131 1.499(12) . ?
C130 H130 0.9500 . ?
C131 F120 1.268(15) . ?
C131 F119 1.302(12) . ?
C131 F121 1.363(14) . ?
F122 C132 1.282(12) . ?
F123 C132 1.354(18) . ?
F124 C132 1.286(17) . ?
O1S C1S 1.25(3) . ?
O1S C3S 1.74(4) . ?
C2S C1S 1.53(3) . ?
C2S H2S1 0.9800 . ?
C2S H2S2 0.9800 . ?
C2S H2S3 0.9800 . ?
C1S H1S1 0.9900 . ?
C1S H1S2 0.9900 . ?
C4S C3S 1.514(19) . ?
C4S H4S1 0.9800 . ?
C4S H4S2 0.9800 . ?
C4S H4S3 0.9800 . ?
C3S H3S1 0.9900 . ?
C3S H3S2 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ge4 Rh1 Ge3 86.51(6) . . ?
Ge4 Rh1 Ge9 80.30(4) . . ?
Ge3 Rh1 Ge9 118.07(7) . . ?
Ge4 Rh1 Ge7 92.07(6) . . ?
Ge3 Rh1 Ge7 60.18(7) . . ?
Ge9 Rh1 Ge7 60.21(5) . . ?
Ge4 Rh1 W1 107.63(5) . . ?
Ge3 Rh1 W1 117.47(8) . . ?
Ge9 Rh1 W1 124.23(6) . . ?
Ge7 Rh1 W1 160.18(7) . . ?
Ge4 Rh1 H1 122(4) . . ?
Ge3 Rh1 H1 81.1(15) . . ?
Ge9 Rh1 H1 153(3) . . ?
Ge7 Rh1 H1 127.0(14) . . ?
W1 Rh1 H1 39.2(6) . . ?
Ge4 Rh1 H2 78(3) . . ?
Ge3 Rh1 H2 142(3) . . ?
Ge9 Rh1 H2 94(2) . . ?
Ge7 Rh1 H2 153.9(18) . . ?
W1 Rh1 H2 39.4(6) . . ?
H1 Rh1 H2 77.7(12) . . ?
Ge4 Rh1 H3 151.1(9) . . ?
Ge3 Rh1 H3 65.8(8) . . ?
Ge9 Rh1 H3 119.0(11) . . ?
Ge7 Rh1 H3 81.4(9) . . ?
W1 Rh1 H3 80.2(8) . . ?
H1 Rh1 H3 49(3) . . ?
H2 Rh1 H3 118.1(15) . . ?
Ge4 Ge1 Si1 129.02(11) . . ?
Ge4 Ge1 Ge3 83.76(7) . . ?
Si1 Ge1 Ge3 123.59(11) . . ?
Ge4 Ge1 Ge2 104.05(9) . . ?
Si1 Ge1 Ge2 124.00(10) . . ?
Ge3 Ge1 Ge2 72.56(9) . . ?
Ge4 Ge1 Ge5 72.95(10) . . ?
Si1 Ge1 Ge5 113.73(9) . . ?
Ge3 Ge1 Ge5 120.03(10) . . ?
Ge2 Ge1 Ge5 61.56(9) . . ?
Ge1 Ge2 Ge7 91.15(10) . . ?
Ge1 Ge2 Ge5 59.75(9) . . ?
Ge7 Ge2 Ge5 99.68(11) . . ?
Ge1 Ge2 Ge6 104.51(11) . . ?
Ge7 Ge2 Ge6 59.43(9) . . ?
Ge5 Ge2 Ge6 60.25(9) . . ?
Rh1 Ge3 Ge1 92.99(9) . . ?
Rh1 Ge3 Ge7 65.24(8) . . ?
Ge1 Ge3 Ge7 94.84(10) . . ?
Rh1 Ge4 Ge1 96.73(6) . . ?
Rh1 Ge4 Ge8 102.04(7) . . ?
Ge1 Ge4 Ge8 110.63(10) . . ?
Ge8 Ge5 Ge1 99.19(11) . . ?
Ge8 Ge5 Ge2 104.14(10) . . ?
Ge1 Ge5 Ge2 58.69(9) . . ?
Ge8 Ge5 Ge6 58.30(9) . . ?
Ge1 Ge5 Ge6 103.57(9) . . ?
Ge2 Ge5 Ge6 60.06(9) . . ?
Ge8 Ge6 Ge7 92.43(11) . . ?
Ge8 Ge6 Ge2 104.60(10) . . ?
Ge7 Ge6 Ge2 59.29(8) . . ?
Ge8 Ge6 Ge5 59.26(9) . . ?
Ge7 Ge6 Ge5 99.20(10) . . ?
Ge2 Ge6 Ge5 59.70(9) . . ?
Si5 Ge7 Ge3 115.01(12) . . ?
Si5 Ge7 Ge9 115.81(9) . . ?
Ge3 Ge7 Ge9 107.37(11) . . ?
Si5 Ge7 Ge6 115.69(13) . . ?
Ge3 Ge7 Ge6 121.96(11) . . ?
Ge9 Ge7 Ge6 73.27(10) . . ?
Si5 Ge7 Ge2 117.77(13) . . ?
Ge3 Ge7 Ge2 71.36(9) . . ?
Ge9 Ge7 Ge2 120.26(12) . . ?
Ge6 Ge7 Ge2 61.29(9) . . ?
Si5 Ge7 Rh1 124.25(12) . . ?
Ge3 Ge7 Rh1 54.58(8) . . ?
Ge9 Ge7 Rh1 54.67(6) . . ?
Ge6 Ge7 Rh1 112.10(10) . . ?
Ge2 Ge7 Rh1 109.26(10) . . ?
Si9 Ge8 Ge4 128.33(12) . . ?
Si9 Ge8 Ge9 120.15(14) . . ?
Ge4 Ge8 Ge9 77.07(9) . . ?
Si9 Ge8 Ge6 127.61(14) . . ?
Ge4 Ge8 Ge6 103.31(11) . . ?
Ge9 Ge8 Ge6 75.21(10) . . ?
Si9 Ge8 Ge5 120.69(14) . . ?
Ge4 Ge8 Ge5 72.34(10) . . ?
Ge9 Ge8 Ge5 118.62(12) . . ?
Ge6 Ge8 Ge5 62.44(10) . . ?
Rh1 Ge9 Ge8 100.01(7) . . ?
Rh1 Ge9 Ge7 65.12(7) . . ?
Ge8 Ge9 Ge7 96.18(10) . . ?
C34 W1 C33 36.7(6) . . ?
C34 W1 C35 35.9(6) . . ?
C33 W1 C35 60.5(7) . . ?
C34 W1 C30 110.4(5) . . ?
C33 W1 C30 141.6(6) . . ?
C35 W1 C30 105.8(5) . . ?
C34 W1 C29 140.0(5) . . ?
C33 W1 C29 148.4(5) . . ?
C35 W1 C29 141.2(6) . . ?
C30 W1 C29 36.0(4) . . ?
C34 W1 C36 58.7(5) . . ?
C33 W1 C36 59.0(5) . . ?
C35 W1 C36 35.2(5) . . ?
C30 W1 C36 131.3(5) . . ?
C29 W1 C36 152.4(5) . . ?
C34 W1 C37 60.3(5) . . ?
C33 W1 C37 37.1(5) . . ?
C35 W1 C37 59.1(6) . . ?
C30 W1 C37 164.4(5) . . ?
C29 W1 C37 157.7(5) . . ?
C36 W1 C37 33.8(5) . . ?
C34 W1 C32 87.7(5) . . ?
C33 W1 C32 93.7(5) . . ?
C35 W1 C32 116.2(5) . . ?
C30 W1 C32 58.4(5) . . ?
C29 W1 C32 57.8(4) . . ?
C36 W1 C32 146.4(4) . . ?
C37 W1 C32 129.4(5) . . ?
C34 W1 C31 81.5(5) . . ?
C33 W1 C31 106.9(6) . . ?
C35 W1 C31 94.3(5) . . ?
C30 W1 C31 35.2(4) . . ?
C29 W1 C31 58.6(4) . . ?
C36 W1 C31 129.4(4) . . ?
C37 W1 C31 141.3(4) . . ?
C32 W1 C31 34.8(5) . . ?
C34 W1 C28 121.2(5) . . ?
C33 W1 C28 113.7(5) . . ?
C35 W1 C28 150.8(5) . . ?
C30 W1 C28 59.4(5) . . ?
C29 W1 C28 35.0(4) . . ?
C36 W1 C28 169.3(5) . . ?
C37 W1 C28 135.6(5) . . ?
C32 W1 C28 35.0(4) . . ?
C31 W1 C28 58.7(4) . . ?
C34 W1 Rh1 136.9(4) . . ?
C33 W1 Rh1 114.5(5) . . ?
C35 W1 Rh1 110.0(4) . . ?
C30 W1 Rh1 103.9(3) . . ?
C29 W1 Rh1 82.4(3) . . ?
C36 W1 Rh1 79.2(3) . . ?
C37 W1 Rh1 80.0(3) . . ?
C32 W1 Rh1 133.4(3) . . ?
C31 W1 Rh1 138.3(3) . . ?
C28 W1 Rh1 98.4(3) . . ?
C34 W1 H1 123(3) . . ?
C33 W1 H1 135(4) . . ?
C35 W1 H1 87(4) . . ?
C30 W1 H1 73(3) . . ?
C29 W1 H1 76(4) . . ?
C36 W1 H1 77(4) . . ?
C37 W1 H1 101(4) . . ?
C32 W1 H1 130(4) . . ?
C31 W1 H1 105(3) . . ?
C28 W1 H1 109(4) . . ?
Rh1 W1 H1 45.7(7) . . ?
C34 W1 H2 128(4) . . ?
C33 W1 H2 92(4) . . ?
C35 W1 H2 133(4) . . ?
C30 W1 H2 118(4) . . ?
C29 W1 H2 82(4) . . ?
C36 W1 H2 99(4) . . ?
C37 W1 H2 76(4) . . ?
C32 W1 H2 101(3) . . ?
C31 W1 H2 131(4) . . ?
C28 W1 H2 72(4) . . ?
Rh1 W1 H2 45.4(7) . . ?
H1 W1 H2 89.9(15) . . ?
C29 C28 C32 105.7(11) . . ?
C29 C28 W1 70.3(6) . . ?
C32 C28 W1 71.5(6) . . ?
C29 C28 H28 127.2 . . ?
C32 C28 H28 127.2 . . ?
W1 C28 H28 122.8 . . ?
C28 C29 C30 109.4(10) . . ?
C28 C29 W1 74.7(7) . . ?
C30 C29 W1 71.7(6) . . ?
C28 C29 H29 125.3 . . ?
C30 C29 H29 125.3 . . ?
W1 C29 H29 120.0 . . ?
C31 C30 C29 107.2(11) . . ?
C31 C30 W1 74.1(7) . . ?
C29 C30 W1 72.3(7) . . ?
C31 C30 H30 126.4 . . ?
C29 C30 H30 126.4 . . ?
W1 C30 H30 119.1 . . ?
C32 C31 C30 107.4(9) . . ?
C32 C31 W1 72.4(7) . . ?
C30 C31 W1 70.6(7) . . ?
C32 C31 H31 126.3 . . ?
C30 C31 H31 126.3 . . ?
W1 C31 H31 122.4 . . ?
C31 C32 C28 110.2(11) . . ?
C31 C32 W1 72.8(7) . . ?
C28 C32 W1 73.5(7) . . ?
C31 C32 H32 124.9 . . ?
C28 C32 H32 124.9 . . ?
W1 C32 H32 120.5 . . ?
C34 C33 C37 105.8(14) . . ?
C34 C33 W1 71.1(8) . . ?
C37 C33 W1 73.7(8) . . ?
C34 C33 H33 127.1 . . ?
C37 C33 H33 127.1 . . ?
W1 C33 H33 120.1 . . ?
C35 C34 C33 108.7(13) . . ?
C35 C34 W1 72.9(7) . . ?
C33 C34 W1 72.3(7) . . ?
C35 C34 H34 125.7 . . ?
C33 C34 H34 125.7 . . ?
W1 C34 H34 120.9 . . ?
C36 C35 C34 107.2(15) . . ?
C36 C35 W1 74.3(7) . . ?
C34 C35 W1 71.2(7) . . ?
C36 C35 H35 126.4 . . ?
C34 C35 H35 126.4 . . ?
W1 C35 H35 120.0 . . ?
C37 C36 C35 111.6(14) . . ?
C37 C36 W1 73.4(7) . . ?
C35 C36 W1 70.5(7) . . ?
C37 C36 H36 124.2 . . ?
C35 C36 H36 124.2 . . ?
W1 C36 H36 123.4 . . ?
C36 C37 C33 106.8(13) . . ?
C36 C37 W1 72.8(7) . . ?
C33 C37 W1 69.2(8) . . ?
C36 C37 H37 126.6 . . ?
C33 C37 H37 126.6 . . ?
W1 C37 H37 123.1 . . ?
Ge4A Rh1A Ge9A 81.44(17) . . ?
Ge4A Rh1A Ge3A 114.4(3) . . ?
Ge9A Rh1A Ge3A 89.9(3) . . ?
Ge4A Rh1A W1A 126.1(2) . . ?
Ge9A Rh1A W1A 107.7(2) . . ?
Ge3A Rh1A W1A 118.5(3) . . ?
Ge4A Rh1A Ge1A 60.5(2) . . ?
Ge9A Rh1A Ge1A 93.9(2) . . ?
Ge3A Rh1A Ge1A 55.4(3) . . ?
W1A Rh1A Ge1A 157.9(3) . . ?
Si1 Ge1A Ge2A 127.1(5) . . ?
Si1 Ge1A Ge3A 115.7(5) . . ?
Ge2A Ge1A Ge3A 72.5(5) . . ?
Si1 Ge1A Ge5A 121.9(5) . . ?
Ge2A Ge1A Ge5A 62.0(4) . . ?
Ge3A Ge1A Ge5A 120.4(5) . . ?
Si1 Ge1A Ge4A 114.2(4) . . ?
Ge2A Ge1A Ge4A 115.6(4) . . ?
Ge3A Ge1A Ge4A 98.8(4) . . ?
Ge5A Ge1A Ge4A 71.2(4) . . ?
Si1 Ge1A Rh1A 121.6(4) . . ?
Ge2A Ge1A Rh1A 104.2(4) . . ?
Ge3A Ge1A Rh1A 51.5(3) . . ?
Ge5A Ge1A Rh1A 104.6(4) . . ?
Ge4A Ge1A Rh1A 48.46(17) . . ?
Ge1A Ge2A Ge7A 94.1(5) . . ?
Ge1A Ge2A Ge5A 60.3(4) . . ?
Ge7A Ge2A Ge5A 104.4(5) . . ?
Ge1A Ge2A Ge6A 101.8(5) . . ?
Ge7A Ge2A Ge6A 58.9(4) . . ?
Ge5A Ge2A Ge6A 60.1(4) . . ?
Rh1A Ge3A Ge7A 89.4(4) . . ?
Rh1A Ge3A Ge1A 73.1(3) . . ?
Ge7A Ge3A Ge1A 95.9(5) . . ?
Rh1A Ge4A Ge8A 99.5(3) . . ?
Rh1A Ge4A Ge1A 71.1(2) . . ?
Ge8A Ge4A Ge1A 96.9(4) . . ?
Ge1A Ge5A Ge8A 97.0(5) . . ?
Ge1A Ge5A Ge2A 57.7(4) . . ?
Ge8A Ge5A Ge2A 104.6(5) . . ?
Ge1A Ge5A Ge6A 100.3(5) . . ?
Ge8A Ge5A Ge6A 57.2(4) . . ?
Ge2A Ge5A Ge6A 60.6(4) . . ?
Ge8A Ge6A Ge7A 100.9(5) . . ?
Ge8A Ge6A Ge5A 60.3(4) . . ?
Ge7A Ge6A Ge5A 103.9(5) . . ?
Ge8A Ge6A Ge2A 106.1(5) . . ?
Ge7A Ge6A Ge2A 59.1(4) . . ?
Ge5A Ge6A Ge2A 59.3(4) . . ?
Ge9A Ge7A Si5 123.2(4) . . ?
Ge9A Ge7A Ge3A 88.1(5) . . ?
Si5 Ge7A Ge3A 123.8(5) . . ?
Ge9A Ge7A Ge2A 106.7(5) . . ?
Si5 Ge7A Ge2A 126.2(6) . . ?
Ge3A Ge7A Ge2A 72.4(5) . . ?
Ge9A Ge7A Ge6A 70.2(4) . . ?
Si5 Ge7A Ge6A 115.3(5) . . ?
Ge3A Ge7A Ge6A 119.2(5) . . ?
Ge2A Ge7A Ge6A 62.0(4) . . ?
Si9 Ge8A Ge9A 132.2(6) . . ?
Si9 Ge8A Ge4A 118.1(5) . . ?
Ge9A Ge8A Ge4A 78.7(4) . . ?
Si9 Ge8A Ge6A 123.0(6) . . ?
Ge9A Ge8A Ge6A 71.3(5) . . ?
Ge4A Ge8A Ge6A 117.4(5) . . ?
Si9 Ge8A Ge5A 121.6(6) . . ?
Ge9A Ge8A Ge5A 105.7(5) . . ?
Ge4A Ge8A Ge5A 75.4(5) . . ?
Ge6A Ge8A Ge5A 62.5(4) . . ?
Rh1A Ge9A Ge7A 92.6(3) . . ?
Rh1A Ge9A Ge8A 99.9(3) . . ?
Ge7A Ge9A Ge8A 109.9(4) . . ?
C34A W1A C35A 36.3(8) . . ?
C34A W1A C30A 111.1(10) . . ?
C35A W1A C30A 108.2(10) . . ?
C34A W1A C33A 36.7(8) . . ?
C35A W1A C33A 60.6(10) . . ?
C30A W1A C33A 141.2(10) . . ?
C34A W1A C36A 59.0(9) . . ?
C35A W1A C36A 35.7(7) . . ?
C30A W1A C36A 135.1(11) . . ?
C33A W1A C36A 58.5(9) . . ?
C34A W1A C29A 139.6(9) . . ?
C35A W1A C29A 144.1(11) . . ?
C30A W1A C29A 36.3(6) . . ?
C33A W1A C29A 145.3(11) . . ?
C36A W1A C29A 155.7(11) . . ?
C34A W1A C37A 60.7(9) . . ?
C35A W1A C37A 59.6(9) . . ?
C30A W1A C37A 167.7(11) . . ?
C33A W1A C37A 36.9(7) . . ?
C36A W1A C37A 33.6(7) . . ?
C29A W1A C37A 155.4(10) . . ?
C34A W1A C31A 81.4(9) . . ?
C35A W1A C31A 95.6(9) . . ?
C30A W1A C31A 35.3(6) . . ?
C33A W1A C31A 106.0(10) . . ?
C36A W1A C31A 131.3(10) . . ?
C29A W1A C31A 58.7(8) . . ?
C37A W1A C31A 141.1(9) . . ?
C34A W1A C32A 86.6(9) . . ?
C35A W1A C32A 116.3(10) . . ?
C30A W1A C32A 58.0(8) . . ?
C33A W1A C32A 91.9(9) . . ?
C36A W1A C32A 145.3(9) . . ?
C29A W1A C32A 57.4(8) . . ?
C37A W1A C32A 127.0(10) . . ?
C31A W1A C32A 34.4(6) . . ?
C34A W1A C28A 119.2(10) . . ?
C35A W1A C28A 150.7(10) . . ?
C30A W1A C28A 59.2(8) . . ?
C33A W1A C28A 110.8(10) . . ?
C36A W1A C28A 165.7(11) . . ?
C29A W1A C28A 34.7(6) . . ?
C37A W1A C28A 132.1(11) . . ?
C31A W1A C28A 58.3(8) . . ?
C32A W1A C28A 34.5(6) . . ?
C34A W1A Rh1A 143.2(8) . . ?
C35A W1A Rh1A 117.5(9) . . ?
C30A W1A Rh1A 101.6(8) . . ?
C33A W1A Rh1A 116.6(9) . . ?
C36A W1A Rh1A 86.0(8) . . ?
C29A W1A Rh1A 77.2(7) . . ?
C37A W1A Rh1A 84.1(7) . . ?
C31A W1A Rh1A 134.8(7) . . ?
C32A W1A Rh1A 126.2(7) . . ?
C28A W1A Rh1A 91.6(7) . . ?
C29A C28A C32A 105.8(19) . . ?
C29A C28A W1A 69.6(10) . . ?
C32A C28A W1A 71.7(9) . . ?
C29A C28A H28A 127.1 . . ?
C32A C28A H28A 127.1 . . ?
W1A C28A H28A 123.3 . . ?
C28A C29A C30A 109.0(18) . . ?
C28A C29A W1A 75.7(10) . . ?
C30A C29A W1A 70.7(9) . . ?
C28A C29A H29A 125.5 . . ?
C30A C29A H29A 125.5 . . ?
W1A C29A H29A 119.9 . . ?
C31A C30A C29A 107.3(19) . . ?
C31A C30A W1A 74.8(10) . . ?
C29A C30A W1A 73.0(11) . . ?
C31A C30A H30A 126.4 . . ?
C29A C30A H30A 126.4 . . ?
W1A C30A H30A 117.9 . . ?
C32A C31A C30A 107.3(19) . . ?
C32A C31A W1A 73.5(10) . . ?
C30A C31A W1A 69.9(10) . . ?
C32A C31A H31A 126.3 . . ?
C30A C31A H31A 126.3 . . ?
W1A C31A H31A 122.0 . . ?
C31A C32A C28A 110.6(19) . . ?
C31A C32A W1A 72.1(10) . . ?
C28A C32A W1A 73.8(10) . . ?
C31A C32A H32A 124.7 . . ?
C28A C32A H32A 124.7 . . ?
W1A C32A H32A 121.0 . . ?
C34A C33A C37A 107(2) . . ?
C34A C33A W1A 70.4(11) . . ?
C37A C33A W1A 73.3(11) . . ?
C34A C33A H33A 126.7 . . ?
C37A C33A H33A 126.7 . . ?
W1A C33A H33A 121.4 . . ?
C35A C34A C33A 108(2) . . ?
C35A C34A W1A 71.9(11) . . ?
C33A C34A W1A 72.9(11) . . ?
C35A C34A H34A 126.0 . . ?
C33A C34A H34A 126.0 . . ?
W1A C34A H34A 120.9 . . ?
C36A C35A C34A 107(2) . . ?
C36A C35A W1A 74.1(11) . . ?
C34A C35A W1A 71.8(10) . . ?
C36A C35A H35A 126.7 . . ?
C34A C35A H35A 126.7 . . ?
W1A C35A H35A 119.3 . . ?
C37A C36A C35A 113(2) . . ?
C37A C36A W1A 74.5(11) . . ?
C35A C36A W1A 70.2(10) . . ?
C37A C36A H36A 123.6 . . ?
C35A C36A H36A 123.6 . . ?
W1A C36A H36A 123.2 . . ?
C36A C37A C33A 106(2) . . ?
C36A C37A W1A 72.0(11) . . ?
C33A C37A W1A 69.8(10) . . ?
C36A C37A H37A 126.9 . . ?
C33A C37A H37A 126.9 . . ?
W1A C37A H37A 123.0 . . ?
Ge1A Si1 Si2 106.2(3) . . ?
Ge1A Si1 Si3 108.9(3) . . ?
Si2 Si1 Si3 114.90(12) . . ?
Ge1A Si1 Si4 105.1(3) . . ?
Si2 Si1 Si4 110.66(10) . . ?
Si3 Si1 Si4 110.49(12) . . ?
Si2 Si1 Ge1 107.48(11) . . ?
Si3 Si1 Ge1 103.51(10) . . ?
Si4 Si1 Ge1 109.42(10) . . ?
C2 Si2 C1 108.2(6) . . ?
C2 Si2 C3 109.9(6) . . ?
C1 Si2 C3 109.4(7) . . ?
C2 Si2 Si1 108.1(4) . . ?
C1 Si2 Si1 112.0(4) . . ?
C3 Si2 Si1 109.4(4) . . ?
C6 Si3 C4 109.2(5) . . ?
C6 Si3 C5 110.7(7) . . ?
C4 Si3 C5 106.9(5) . . ?
C6 Si3 Si1 108.9(3) . . ?
C4 Si3 Si1 112.9(3) . . ?
C5 Si3 Si1 108.2(4) . . ?
C9 Si4 C7 108.6(6) . . ?
C9 Si4 C8 108.2(5) . . ?
C7 Si4 C8 108.6(6) . . ?
C9 Si4 Si1 110.5(4) . . ?
C7 Si4 Si1 111.8(3) . . ?
C8 Si4 Si1 109.0(3) . . ?
Si2 C1 H1A 109.5 . . ?
Si2 C1 H1B 109.5 . . ?
H1A C1 H1B 109.5 . . ?
Si2 C1 H1C 109.5 . . ?
H1A C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
Si2 C2 H2A 109.5 . . ?
Si2 C2 H2B 109.5 . . ?
H2A C2 H2B 109.5 . . ?
Si2 C2 H2C 109.5 . . ?
H2A C2 H2C 109.5 . . ?
H2B C2 H2C 109.5 . . ?
Si2 C3 H3A 109.5 . . ?
Si2 C3 H3B 109.5 . . ?
H3A C3 H3B 109.5 . . ?
Si2 C3 H3C 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
Si3 C4 H4A 109.5 . . ?
Si3 C4 H4B 109.5 . . ?
H4A C4 H4B 109.5 . . ?
Si3 C4 H4C 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
Si3 C5 H5A 109.5 . . ?
Si3 C5 H5B 109.5 . . ?
H5A C5 H5B 109.5 . . ?
Si3 C5 H5C 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
Si3 C6 H6A 109.5 . . ?
Si3 C6 H6B 109.5 . . ?
H6A C6 H6B 109.5 . . ?
Si3 C6 H6C 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
Si4 C7 H7A 109.5 . . ?
Si4 C7 H7B 109.5 . . ?
H7A C7 H7B 109.5 . . ?
Si4 C7 H7C 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
Si4 C8 H8A 109.5 . . ?
Si4 C8 H8B 109.5 . . ?
H8A C8 H8B 109.5 . . ?
Si4 C8 H8C 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
Si4 C9 H9A 109.5 . . ?
Si4 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
Si4 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
Si8 Si5 Si6 109.81(11) . . ?
Si8 Si5 Si7 111.42(12) . . ?
Si6 Si5 Si7 110.43(12) . . ?
Si8 Si5 Ge7 110.00(11) . . ?
Si6 Si5 Ge7 107.01(11) . . ?
Si7 Si5 Ge7 108.05(11) . . ?
Si8 Si5 Ge7A 107.7(3) . . ?
Si6 Si5 Ge7A 113.6(3) . . ?
Si7 Si5 Ge7A 103.7(3) . . ?
C10 Si6 C12 109.8(6) . . ?
C10 Si6 C11 108.8(5) . . ?
C12 Si6 C11 108.3(6) . . ?
C10 Si6 Si5 110.2(4) . . ?
C12 Si6 Si5 111.4(4) . . ?
C11 Si6 Si5 108.3(4) . . ?
C15 Si7 C13 106.7(5) . . ?
C15 Si7 C14 109.3(6) . . ?
C13 Si7 C14 108.7(5) . . ?
C15 Si7 Si5 109.1(4) . . ?
C13 Si7 Si5 113.6(4) . . ?
C14 Si7 Si5 109.3(4) . . ?
C18 Si8 C16 108.8(6) . . ?
C18 Si8 C17 106.7(7) . . ?
C16 Si8 C17 108.9(6) . . ?
C18 Si8 Si5 108.8(4) . . ?
C16 Si8 Si5 111.5(4) . . ?
C17 Si8 Si5 112.0(4) . . ?
Si6 C10 H10A 109.5 . . ?
Si6 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
Si6 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
Si6 C11 H11A 109.5 . . ?
Si6 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
Si6 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
Si6 C12 H12A 109.5 . . ?
Si6 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
Si6 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
Si7 C13 H13A 109.5 . . ?
Si7 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
Si7 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
Si7 C14 H14A 109.5 . . ?
Si7 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
Si7 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
Si7 C15 H15A 109.5 . . ?
Si7 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
Si7 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
Si8 C16 H16A 109.5 . . ?
Si8 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
Si8 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
Si8 C17 H17A 109.5 . . ?
Si8 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
Si8 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
Si8 C18 H18A 109.5 . . ?
Si8 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
Si8 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
Si0A Si9 Si1A 115.0(3) . . ?
Si0A Si9 Ge8A 108.4(4) . . ?
Si1A Si9 Ge8A 111.9(3) . . ?
Si12 Si9 Si11 117.1(4) . . ?
Si12 Si9 Ge8 106.2(2) . . ?
Si11 Si9 Ge8 102.7(2) . . ?
Si0A Si9 Si2A 111.8(3) . . ?
Si1A Si9 Si2A 108.8(2) . . ?
Ge8A Si9 Si2A 100.0(4) . . ?
Si12 Si9 Si10 114.9(4) . . ?
Si11 Si9 Si10 107.0(3) . . ?
Ge8 Si9 Si10 107.9(3) . . ?
C21 Si10 C20 109.2(15) . . ?
C21 Si10 C19 110.2(15) . . ?
C20 Si10 C19 110.6(16) . . ?
C21 Si10 Si9 106.7(13) . . ?
C20 Si10 Si9 115.1(10) . . ?
C19 Si10 Si9 104.9(18) . . ?
C24 Si11 C22 109.8(15) . . ?
C24 Si11 C23 112.1(16) . . ?
C22 Si11 C23 108.9(16) . . ?
C24 Si11 Si9 114.4(12) . . ?
C22 Si11 Si9 105.4(19) . . ?
C23 Si11 Si9 106.1(13) . . ?
C27 Si12 C25 111.4(15) . . ?
C27 Si12 C26 107.4(14) . . ?
C25 Si12 C26 110.8(14) . . ?
C27 Si12 Si9 108.2(12) . . ?
C25 Si12 Si9 107.7(13) . . ?
C26 Si12 Si9 111.3(12) . . ?
Si10 C19 H19A 109.5 . . ?
Si10 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
Si10 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
Si10 C20 H20A 109.5 . . ?
Si10 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
Si10 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
Si10 C21 H21A 109.5 . . ?
Si10 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
Si10 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
Si11 C22 H22A 109.5 . . ?
Si11 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
Si11 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
Si11 C23 H23A 109.5 . . ?
Si11 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
Si11 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
Si11 C24 H24A 109.5 . . ?
Si11 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
Si11 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
Si12 C25 H25A 109.5 . . ?
Si12 C25 H25B 109.5 . . ?
H25A C25 H25B 109.5 . . ?
Si12 C25 H25C 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
Si12 C26 H26A 109.5 . . ?
Si12 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
Si12 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
Si12 C27 H27A 109.5 . . ?
Si12 C27 H27B 109.5 . . ?
H27A C27 H27B 109.5 . . ?
Si12 C27 H27C 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
C21A Si0A C20A 108.5(12) . . ?
C21A Si0A C19A 109.6(13) . . ?
C20A Si0A C19A 109.7(11) . . ?
C21A Si0A Si9 111.4(7) . . ?
C20A Si0A Si9 107.4(8) . . ?
C19A Si0A Si9 110.1(10) . . ?
C24A Si1A C22A 108.2(13) . . ?
C24A Si1A C23A 111.5(12) . . ?
C22A Si1A C23A 108.3(11) . . ?
C24A Si1A Si9 109.5(11) . . ?
C22A Si1A Si9 109.1(14) . . ?
C23A Si1A Si9 110.2(7) . . ?
C25A Si2A C26A 110.4(10) . . ?
C25A Si2A C27A 109.9(10) . . ?
C26A Si2A C27A 106.0(10) . . ?
C25A Si2A Si9 109.3(7) . . ?
C26A Si2A Si9 109.4(7) . . ?
C27A Si2A Si9 111.9(7) . . ?
Si0A C19A H19D 109.5 . . ?
Si0A C19A H19E 109.5 . . ?
H19D C19A H19E 109.5 . . ?
Si0A C19A H19F 109.5 . . ?
H19D C19A H19F 109.5 . . ?
H19E C19A H19F 109.5 . . ?
Si0A C20A H20D 109.5 . . ?
Si0A C20A H20E 109.5 . . ?
H20D C20A H20E 109.5 . . ?
Si0A C20A H20F 109.5 . . ?
H20D C20A H20F 109.5 . . ?
H20E C20A H20F 109.5 . . ?
Si0A C21A H21D 109.5 . . ?
Si0A C21A H21E 109.5 . . ?
H21D C21A H21E 109.5 . . ?
Si0A C21A H21F 109.5 . . ?
H21D C21A H21F 109.5 . . ?
H21E C21A H21F 109.5 . . ?
Si1A C22A H22D 109.5 . . ?
Si1A C22A H22E 109.5 . . ?
H22D C22A H22E 109.5 . . ?
Si1A C22A H22F 109.5 . . ?
H22D C22A H22F 109.5 . . ?
H22E C22A H22F 109.5 . . ?
Si1A C23A H23D 109.5 . . ?
Si1A C23A H23E 109.5 . . ?
H23D C23A H23E 109.5 . . ?
Si1A C23A H23F 109.5 . . ?
H23D C23A H23F 109.5 . . ?
H23E C23A H23F 109.5 . . ?
Si1A C24A H24D 109.5 . . ?
Si1A C24A H24E 109.5 . . ?
H24D C24A H24E 109.5 . . ?
Si1A C24A H24F 109.5 . . ?
H24D C24A H24F 109.5 . . ?
H24E C24A H24F 109.5 . . ?
Si2A C25A H25D 109.5 . . ?
Si2A C25A H25E 109.5 . . ?
H25D C25A H25E 109.5 . . ?
Si2A C25A H25F 109.5 . . ?
H25D C25A H25F 109.5 . . ?
H25E C25A H25F 109.5 . . ?
Si2A C26A H26D 109.5 . . ?
Si2A C26A H26E 109.5 . . ?
H26D C26A H26E 109.5 . . ?
Si2A C26A H26F 109.5 . . ?
H26D C26A H26F 109.5 . . ?
H26E C26A H26F 109.5 . . ?
Si2A C27A H27D 109.5 . . ?
Si2A C27A H27E 109.5 . . ?
H27D C27A H27E 109.5 . . ?
Si2A C27A H27F 109.5 . . ?
H27D C27A H27F 109.5 . . ?
H27E C27A H27F 109.5 . . ?
C117 B1 C101 111.5(5) . . ?
C117 B1 C109 106.8(5) . . ?
C101 B1 C109 113.3(6) . . ?
C117 B1 C125 110.7(6) . . ?
C101 B1 C125 103.2(5) . . ?
C109 B1 C125 111.5(5) . . ?
C102 C101 C106 115.5(7) . . ?
C102 C101 B1 121.2(6) . . ?
C106 C101 B1 122.6(7) . . ?
C103 C102 C101 122.8(7) . . ?
C103 C102 H102 118.6 . . ?
C101 C102 H102 118.6 . . ?
C104 C103 C102 120.6(8) . . ?
C104 C103 C107 117.4(8) . . ?
C102 C103 C107 122.0(8) . . ?
C105 C104 C103 117.8(8) . . ?
C105 C104 H104 121.1 . . ?
C103 C104 H104 121.1 . . ?
C104 C105 C106 121.5(7) . . ?
C104 C105 C108 120.2(9) . . ?
C106 C105 C108 118.2(9) . . ?
C101 C106 C105 121.7(8) . . ?
C101 C106 H106 119.2 . . ?
C105 C106 H106 119.2 . . ?
F101 C107 F103 108.9(10) . . ?
F101 C107 F102 105.4(11) . . ?
F103 C107 F102 99.8(9) . . ?
F101 C107 C103 115.1(8) . . ?
F103 C107 C103 113.7(11) . . ?
F102 C107 C103 112.6(8) . . ?
F104 C108 F106 106.2(10) . . ?
F104 C108 F105 104.9(12) . . ?
F106 C108 F105 106.5(9) . . ?
F104 C108 C105 111.6(9) . . ?
F106 C108 C105 112.8(11) . . ?
F105 C108 C105 114.1(8) . . ?
C110 C109 C114 115.1(6) . . ?
C110 C109 B1 121.1(6) . . ?
C114 C109 B1 123.6(6) . . ?
C111 C110 C109 123.0(7) . . ?
C111 C110 H110 118.5 . . ?
C109 C110 H110 118.5 . . ?
C110 C111 C112 120.8(7) . . ?
C110 C111 C115 120.5(7) . . ?
C112 C111 C115 118.6(6) . . ?
C113 C112 C111 117.8(6) . . ?
C113 C112 H112 121.1 . . ?
C111 C112 H112 121.1 . . ?
C112 C113 C114 121.6(7) . . ?
C112 C113 C116 118.9(7) . . ?
C114 C113 C116 119.3(7) . . ?
C113 C114 C109 121.7(6) . . ?
C113 C114 H114 119.1 . . ?
C109 C114 H114 119.1 . . ?
F109 C115 F108 106.2(6) . . ?
F109 C115 F107 107.1(8) . . ?
F108 C115 F107 105.8(7) . . ?
F109 C115 C111 113.3(6) . . ?
F108 C115 C111 111.3(8) . . ?
F107 C115 C111 112.7(7) . . ?
F112 C116 F111 108.0(7) . . ?
F112 C116 F110 104.8(7) . . ?
F111 C116 F110 105.0(7) . . ?
F112 C116 C113 113.3(7) . . ?
F111 C116 C113 114.4(7) . . ?
F110 C116 C113 110.5(6) . . ?
C122 C117 C118 116.0(7) . . ?
C122 C117 B1 122.3(6) . . ?
C118 C117 B1 121.7(6) . . ?
C119 C118 C117 122.7(7) . . ?
C119 C118 H118 118.6 . . ?
C117 C118 H118 118.6 . . ?
C120 C119 C118 120.5(7) . . ?
C120 C119 C123 119.7(8) . . ?
C118 C119 C123 119.8(8) . . ?
C119 C120 C121 119.2(7) . . ?
C119 C120 H120 120.4 . . ?
C121 C120 H120 120.4 . . ?
C122 C121 C120 119.3(8) . . ?
C122 C121 C124 121.5(8) . . ?
C120 C121 C124 119.2(8) . . ?
C121 C122 C117 122.2(7) . . ?
C121 C122 H122 118.9 . . ?
C117 C122 H122 118.9 . . ?
F114 C123 F115 109.2(10) . . ?
F114 C123 F113 107.3(11) . . ?
F115 C123 F113 102.4(8) . . ?
F114 C123 C119 114.0(8) . . ?
F115 C123 C119 113.2(9) . . ?
F113 C123 C119 109.9(8) . . ?
F116 C124 F118 109.9(10) . . ?
F116 C124 F117 106.0(9) . . ?
F118 C124 F117 104.4(10) . . ?
F116 C124 C121 112.5(11) . . ?
F118 C124 C121 111.0(8) . . ?
F117 C124 C121 112.4(9) . . ?
C130 C125 C126 115.3(7) . . ?
C130 C125 B1 125.8(6) . . ?
C126 C125 B1 118.6(6) . . ?
C127 C126 C125 122.5(7) . . ?
C127 C126 H126 118.7 . . ?
C125 C126 H126 118.7 . . ?
C128 C127 C126 120.4(8) . . ?
C128 C127 C132 120.3(8) . . ?
C126 C127 C132 119.2(8) . . ?
C129 C128 C127 118.8(7) . . ?
C129 C128 H128 120.6 . . ?
C127 C128 H128 120.6 . . ?
C128 C129 C130 120.5(7) . . ?
C128 C129 C131 119.2(7) . . ?
C130 C129 C131 120.3(7) . . ?
C125 C130 C129 122.4(7) . . ?
C125 C130 H130 118.8 . . ?
C129 C130 H130 118.8 . . ?
F120 C131 F119 109.4(11) . . ?
F120 C131 F121 104.1(10) . . ?
F119 C131 F121 102.8(9) . . ?
F120 C131 C129 114.2(9) . . ?
F119 C131 C129 114.2(8) . . ?
F121 C131 C129 111.1(10) . . ?
C1S O1S C3S 104.1(18) . . ?
C1S C2S H2S1 109.5 . . ?
C1S C2S H2S2 109.5 . . ?
H2S1 C2S H2S2 109.5 . . ?
C1S C2S H2S3 109.5 . . ?
H2S1 C2S H2S3 109.5 . . ?
H2S2 C2S H2S3 109.5 . . ?
O1S C1S C2S 111.4(17) . . ?
O1S C1S H1S1 109.3 . . ?
C2S C1S H1S1 109.3 . . ?
O1S C1S H1S2 109.3 . . ?
C2S C1S H1S2 109.3 . . ?
H1S1 C1S H1S2 108.0 . . ?
C3S C4S H4S1 109.5 . . ?
C3S C4S H4S2 109.5 . . ?
H4S1 C4S H4S2 109.5 . . ?
C3S C4S H4S3 109.5 . . ?
H4S1 C4S H4S3 109.5 . . ?
H4S2 C4S H4S3 109.5 . . ?
C4S C3S O1S 84(3) . . ?
C4S C3S H3S1 114.7 . . ?
O1S C3S H3S1 114.7 . . ?
C4S C3S H3S2 114.7 . . ?
O1S C3S H3S2 114.7 . . ?
H3S1 C3S H3S2 111.7 . . ?
F122 C132 F124 110.4(13) . . ?
F122 C132 F123 104.8(12) . . ?
F124 C132 F123 99.5(10) . . ?
F122 C132 C127 115.4(9) . . ?
F124 C132 C127 114.1(10) . . ?
F123 C132 C127 111.0(12) . . ?

_refine_diff_density_max         2.530
_refine_diff_density_min         -1.110
_refine_diff_density_rms         0.148



####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_OT445
_database_code_depnum_ccdc_archive 'CCDC 2155447'
loop_
_audit_author_name
_audit_author_address
'Jose Goicoechea'
;University of Oxford
United Kingdom
;
_audit_update_record             
;
2022-02-28 deposited with the CCDC.	2022-06-09 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/1
_shelx_SHELXL_version_number     2018/1
_chemical_name_systematic        
;
 Ge9{Si(SiMe3)}3RhH2W(Cp)2
;
_contact_author_fax              '+44 1865 272690'
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C37 H93 Ge9 Rh Si12 W'
_chemical_formula_sum            'C37 H93 Ge9 Rh Si12 W'
_chemical_formula_weight         1815.26

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.2541 0.3302 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge -1.0885 0.8855 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh 0.0927 3.6045 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -5.4734 5.5774 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   14.27830(10)
_cell_length_b                   25.64300(10)
_cell_length_c                   19.84610(10)
_cell_angle_alpha                90
_cell_angle_beta                 101.5750(10)
_cell_angle_gamma                90
_cell_volume                     7118.64(7)
_cell_formula_units_Z            4
_cell_measurement_temperature    150(2)
_cell_measurement_reflns_used    123473
_cell_measurement_theta_min      3.8540
_cell_measurement_theta_max      76.4680

_exptl_crystal_description       block
_exptl_crystal_colour            black
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    .
_exptl_crystal_density_diffrn    1.694
_exptl_crystal_F_000             3560
_exptl_transmission_factor_min   .
_exptl_transmission_factor_max   .
_exptl_crystal_size_max          0.180
_exptl_crystal_size_mid          0.140
_exptl_crystal_size_min          0.100
_exptl_absorpt_coefficient_mu    11.032
_shelx_estimated_absorpt_T_min   0.241
_shelx_estimated_absorpt_T_max   0.405
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.65893
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.41.81a (Rigaku Oxford Diffraction, 2020)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   .

_diffrn_ambient_temperature      150(2)
_diffrn_radiation_wavelength     1.54184
_diffrn_radiation_type           CuK\a
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'SuperNova (Cu) X-ray Source'
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at home/near, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_detector                 'CCD plate'
_diffrn_detector_type            Atlas
_diffrn_detector_area_resol_mean 10.5035
_diffrn_reflns_number            196412
_diffrn_reflns_av_unetI/netI     0.0172
_diffrn_reflns_av_R_equivalents  0.0545
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_k_min       -32
_diffrn_reflns_limit_k_max       29
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_theta_min         3.599
_diffrn_reflns_theta_max         76.490
_diffrn_reflns_theta_full        67.684
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             14900
_reflns_number_gt                14470
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'CrysAlisPro 1.171.41.81a (Rigaku OD, 2020)'
_computing_cell_refinement       'CrysAlisPro 1.171.41.81a (Rigaku OD, 2020)'
_computing_data_reduction        'CrysAlisPro 1.171.41.81a (Rigaku OD, 2020)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2018/1 (Sheldrick, 2018)'
_computing_molecular_graphics    .
_computing_publication_material  .
_refine_special_details          .
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0332P)²+7.5677P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     .
_atom_sites_solution_secondary   .
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         14900
_refine_ls_number_parameters     668
_refine_ls_number_restraints     157
_refine_ls_R_factor_all          0.0252
_refine_ls_R_factor_gt           0.0244
_refine_ls_wR_factor_ref         0.0629
_refine_ls_wR_factor_gt          0.0623
_refine_ls_goodness_of_fit_ref   1.054
_refine_ls_restrained_S_all      1.117
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
W1 W 0.14956(3) 0.57978(2) 0.56040(2) 0.03417(8) Uani 0.8491(8) 1 d D . P A 1
Rh1 Rh 0.16275(2) 0.62554(2) 0.43167(2) 0.02081(6) Uani 0.8491(8) 1 d D . P A 1
Ge1 Ge 0.00371(8) 0.65361(3) 0.26206(6) 0.02219(14) Uani 0.8491(8) 1 d D . P A
1
Ge2 Ge 0.13242(9) 0.72208(3) 0.24507(6) 0.02140(13) Uani 0.8491(8) 1 d D . P A
1
Ge3 Ge 0.05547(3) 0.69286(2) 0.37617(2) 0.02442(8) Uani 0.8491(8) 1 d D . P A 1
Ge4 Ge 0.08231(3) 0.57481(2) 0.33360(2) 0.02225(8) Uani 0.8491(8) 1 d D . P A 1
Ge5 Ge 0.12762(12) 0.62595(6) 0.19229(7) 0.02273(15) Uani 0.8491(8) 1 d D . P A
1
Ge6 Ge 0.28970(9) 0.66769(3) 0.25831(7) 0.02192(14) Uani 0.8491(8) 1 d D . P A
1
Ge7 Ge 0.22978(9) 0.70331(4) 0.36774(7) 0.01907(14) Uani 0.8491(8) 1 d D . P A
1
Ge8 Ge 0.23381(10) 0.57206(4) 0.28804(6) 0.02233(14) Uani 0.8491(8) 1 d D . P A
1
Ge9 Ge 0.31233(10) 0.61635(4) 0.39423(8) 0.02215(15) Uani 0.8491(8) 1 d D . P A
1
W1A W 0.13535(16) 0.56600(8) 0.54862(11) 0.0204(3) Uani 0.1509(8) 1 d D . P A 2
Rh1A Rh 0.16591(8) 0.58359(5) 0.41143(6) 0.0238(4) Uani 0.1509(8) 1 d D . P A 2
Ge1A Ge 0.0069(5) 0.6446(2) 0.2596(4) 0.02219(14) Uani 0.1509(8) 1 d D . P A 2
Ge2A Ge 0.1334(6) 0.7134(2) 0.2482(4) 0.02140(13) Uani 0.1509(8) 1 d D . P A 2
Ge3A Ge 0.08350(17) 0.66727(11) 0.38594(10) 0.0262(5) Uani 0.1509(8) 1 d D . P
A 2
Ge4A Ge 0.05727(15) 0.55612(10) 0.30819(13) 0.0238(4) Uani 0.1509(8) 1 d D . P
A 2
Ge5A Ge 0.1306(7) 0.6204(4) 0.1866(5) 0.02273(15) Uani 0.1509(8) 1 d D . P A 2
Ge6A Ge 0.2913(6) 0.6588(3) 0.2569(4) 0.02192(14) Uani 0.1509(8) 1 d D . P A 2
Ge7A Ge 0.2357(6) 0.6957(3) 0.3703(4) 0.01907(14) Uani 0.1509(8) 1 d D . P A 2
Ge8A Ge 0.2329(6) 0.5661(3) 0.2806(4) 0.02233(14) Uani 0.1509(8) 1 d D . P A 2
Ge9A Ge 0.3141(6) 0.6084(3) 0.3928(5) 0.02215(15) Uani 0.1509(8) 1 d D . P A 2
C1 C -0.2055(3) 0.74997(14) 0.3173(2) 0.0574(9) Uani 1 1 d . . . . .
H1A H -0.246982 0.758947 0.349331 0.086 Uiso 1 1 calc R U . . .
H1B H -0.207181 0.778128 0.283654 0.086 Uiso 1 1 calc R U . . .
H1C H -0.139799 0.745273 0.342824 0.086 Uiso 1 1 calc R U . . .
C2 C -0.2449(3) 0.63642(14) 0.33793(18) 0.0518(8) Uani 1 1 d . . . . .
H2A H -0.178402 0.629358 0.360067 0.078 Uiso 1 1 calc R U . . .
H2B H -0.274193 0.604517 0.316008 0.078 Uiso 1 1 calc R U . . .
H2C H -0.280418 0.648152 0.372592 0.078 Uiso 1 1 calc R U . . .
C3 C -0.3742(2) 0.69919(19) 0.2234(2) 0.0630(10) Uani 1 1 d . . . . .
H3A H -0.416114 0.704901 0.256294 0.094 Uiso 1 1 calc R U . . .
H3B H -0.396115 0.668507 0.195209 0.094 Uiso 1 1 calc R U . . .
H3C H -0.376136 0.729864 0.193742 0.094 Uiso 1 1 calc R U . . .
C4 C -0.1921(4) 0.53165(13) 0.20527(19) 0.0662(12) Uani 1 1 d . . . . .
H4A H -0.206753 0.497953 0.182268 0.099 Uiso 1 1 calc R U . . .
H4B H -0.238756 0.538884 0.234186 0.099 Uiso 1 1 calc R U . . .
H4C H -0.127732 0.530567 0.233981 0.099 Uiso 1 1 calc R U . . .
C5 C -0.1169(3) 0.56662(17) 0.0806(2) 0.0686(12) Uani 1 1 d . . . . .
H5A H -0.050341 0.570254 0.104959 0.103 Uiso 1 1 calc R U . . .
H5B H -0.128730 0.589937 0.040699 0.103 Uiso 1 1 calc R U . . .
H5C H -0.128735 0.530482 0.065208 0.103 Uiso 1 1 calc R U . . .
C6 C -0.3233(3) 0.58550(17) 0.0882(3) 0.0710(12) Uani 1 1 d . . . . .
H6A H -0.328185 0.611685 0.051670 0.107 Uiso 1 1 calc R U . . .
H6B H -0.367443 0.594445 0.118395 0.107 Uiso 1 1 calc R U . . .
H6C H -0.339974 0.551132 0.067629 0.107 Uiso 1 1 calc R U . . .
C7 C -0.2683(3) 0.7347(2) 0.0528(3) 0.105(2) Uani 1 1 d . . . . .
H7A H -0.268643 0.764387 0.021605 0.158 Uiso 1 1 calc R U . . .
H7B H -0.317659 0.739792 0.080095 0.158 Uiso 1 1 calc R U . . .
H7C H -0.281347 0.702547 0.025912 0.158 Uiso 1 1 calc R U . . .
C8 C -0.1219(3) 0.79405(12) 0.1566(3) 0.0640(11) Uani 1 1 d . . . . .
H8A H -0.116054 0.821125 0.122799 0.096 Uiso 1 1 calc R U . . .
H8B H -0.061831 0.791498 0.190429 0.096 Uiso 1 1 calc R U . . .
H8C H -0.173960 0.803078 0.179960 0.096 Uiso 1 1 calc R U . . .
C9 C -0.0559(3) 0.71619(14) 0.05883(18) 0.0518(8) Uani 1 1 d . . . . .
H9A H -0.065678 0.681076 0.039185 0.078 Uiso 1 1 calc R U . . .
H9B H 0.008003 0.718498 0.088129 0.078 Uiso 1 1 calc R U . . .
H9C H -0.061585 0.741843 0.021631 0.078 Uiso 1 1 calc R U . . .
C10 C 0.2319(3) 0.75024(15) 0.57313(17) 0.0502(8) Uani 1 1 d . . . . .
H10A H 0.247158 0.738129 0.620920 0.075 Uiso 1 1 calc R U . . .
H10B H 0.194920 0.723384 0.544214 0.075 Uiso 1 1 calc R U . . .
H10C H 0.194168 0.782381 0.570397 0.075 Uiso 1 1 calc R U . . .
C11 C 0.4298(3) 0.70766(18) 0.56554(18) 0.0637(11) Uani 1 1 d . . . . .
H11A H 0.439102 0.700774 0.615007 0.095 Uiso 1 1 calc R U . . .
H11B H 0.491324 0.716578 0.553766 0.095 Uiso 1 1 calc R U . . .
H11C H 0.403665 0.676484 0.539937 0.095 Uiso 1 1 calc R U . . .
C12 C 0.4002(3) 0.82298(16) 0.58822(16) 0.0601(10) Uani 1 1 d . . . . .
H12A H 0.354489 0.851909 0.579649 0.090 Uiso 1 1 calc R U . . .
H12B H 0.457863 0.832222 0.571190 0.090 Uiso 1 1 calc R U . . .
H12C H 0.417181 0.816061 0.637734 0.090 Uiso 1 1 calc R U . . .
C13 C 0.5239(2) 0.72434(14) 0.39477(18) 0.0465(7) Uani 1 1 d . . . . .
H13A H 0.489295 0.696596 0.366159 0.070 Uiso 1 1 calc R U . . .
H13B H 0.533635 0.714248 0.443309 0.070 Uiso 1 1 calc R U . . .
H13C H 0.586092 0.729829 0.382105 0.070 Uiso 1 1 calc R U . . .
C14 C 0.5275(3) 0.83968(15) 0.42940(18) 0.0532(9) Uani 1 1 d . . . . .
H14A H 0.586498 0.843618 0.411791 0.080 Uiso 1 1 calc R U . . .
H14B H 0.543379 0.830803 0.478399 0.080 Uiso 1 1 calc R U . . .
H14C H 0.491580 0.872488 0.423293 0.080 Uiso 1 1 calc R U . . .
C15 C 0.4271(2) 0.80293(14) 0.28656(15) 0.0457(7) Uani 1 1 d . . . . .
H15A H 0.487293 0.804537 0.270071 0.069 Uiso 1 1 calc R U . . .
H15B H 0.394953 0.836843 0.279635 0.069 Uiso 1 1 calc R U . . .
H15C H 0.385737 0.776114 0.260897 0.069 Uiso 1 1 calc R U . . .
C16 C 0.1076(5) 0.8465(3) 0.4390(5) 0.179(5) Uani 1 1 d . . . . .
H16A H 0.073903 0.880054 0.434676 0.269 Uiso 1 1 calc R U . . .
H16B H 0.127822 0.837591 0.487712 0.269 Uiso 1 1 calc R U . . .
H16C H 0.064745 0.819387 0.415577 0.269 Uiso 1 1 calc R U . . .
C17 C 0.1766(4) 0.86461(15) 0.30651(18) 0.0728(14) Uani 1 1 d . . . . .
H17A H 0.132058 0.837501 0.285003 0.109 Uiso 1 1 calc R U . . .
H17B H 0.233166 0.864614 0.285575 0.109 Uiso 1 1 calc R U . . .
H17C H 0.145157 0.898717 0.299571 0.109 Uiso 1 1 calc R U . . .
C18 C 0.2810(6) 0.91050(18) 0.4365(4) 0.149(4) Uani 1 1 d . . . . .
H18A H 0.336537 0.915326 0.415115 0.224 Uiso 1 1 calc R U . . .
H18B H 0.302623 0.905912 0.486266 0.224 Uiso 1 1 calc R U . . .
H18C H 0.239530 0.941219 0.427725 0.224 Uiso 1 1 calc R U . . .
C19 C 0.0748(4) 0.4385(4) 0.2038(3) 0.159(4) Uani 1 1 d . . . . .
H19A H 0.061862 0.467815 0.232374 0.238 Uiso 1 1 calc R U . . .
H19B H 0.089434 0.407321 0.232461 0.238 Uiso 1 1 calc R U . . .
H19C H 0.018375 0.431979 0.167624 0.238 Uiso 1 1 calc R U . . .
C20 C 0.2262(4) 0.39486(14) 0.1287(2) 0.0736(14) Uani 1 1 d . . . . .
H20A H 0.251064 0.370850 0.166466 0.110 Uiso 1 1 calc R U . . .
H20B H 0.277769 0.404537 0.105102 0.110 Uiso 1 1 calc R U . . .
H20C H 0.174737 0.377783 0.096050 0.110 Uiso 1 1 calc R U . . .
C21 C 0.1371(4) 0.49926(17) 0.0895(2) 0.0833(17) Uani 1 1 d . . . . .
H21A H 0.085252 0.482477 0.056796 0.125 Uiso 1 1 calc R U . . .
H21B H 0.190328 0.506812 0.066598 0.125 Uiso 1 1 calc R U . . .
H21C H 0.113737 0.531853 0.105953 0.125 Uiso 1 1 calc R U . . .
C22 C 0.2303(3) 0.43624(14) 0.38971(19) 0.0496(8) Uani 1 1 d . . . . .
H22A H 0.248730 0.416751 0.432816 0.074 Uiso 1 1 calc R U . . .
H22B H 0.177718 0.418142 0.359366 0.074 Uiso 1 1 calc R U . . .
H22C H 0.209585 0.471368 0.399578 0.074 Uiso 1 1 calc R U . . .
C23 C 0.3683(3) 0.37317(12) 0.32357(19) 0.0495(8) Uani 1 1 d . . . . .
H23A H 0.379858 0.351362 0.364963 0.074 Uiso 1 1 calc R U . . .
H23B H 0.426395 0.374536 0.304376 0.074 Uiso 1 1 calc R U . . .
H23C H 0.315946 0.358279 0.289455 0.074 Uiso 1 1 calc R U . . .
C24 C 0.4384(2) 0.46998(16) 0.40871(19) 0.0555(9) Uani 1 1 d . . . . .
H24A H 0.422473 0.505714 0.419874 0.083 Uiso 1 1 calc R U . . .
H24B H 0.495145 0.470408 0.387967 0.083 Uiso 1 1 calc R U . . .
H24C H 0.451370 0.448997 0.450822 0.083 Uiso 1 1 calc R U . . .
C25 C 0.5155(2) 0.45252(14) 0.2145(2) 0.0492(8) Uani 1 1 d . . . . .
H25A H 0.571912 0.459833 0.194945 0.074 Uiso 1 1 calc R U . . .
H25B H 0.479757 0.423376 0.189676 0.074 Uiso 1 1 calc R U . . .
H25C H 0.535695 0.443357 0.263184 0.074 Uiso 1 1 calc R U . . .
C26 C 0.4059(3) 0.5292(2) 0.1127(3) 0.0840(16) Uani 1 1 d . . . . .
H26A H 0.361086 0.558596 0.106284 0.126 Uiso 1 1 calc R U . . .
H26B H 0.376150 0.499170 0.086235 0.126 Uiso 1 1 calc R U . . .
H26C H 0.464042 0.539083 0.096633 0.126 Uiso 1 1 calc R U . . .
C27 C 0.5061(3) 0.56495(18) 0.2572(3) 0.0883(18) Uani 1 1 d . . . . .
H27A H 0.520247 0.555320 0.305930 0.132 Uiso 1 1 calc R U . . .
H27B H 0.468277 0.597104 0.251038 0.132 Uiso 1 1 calc R U . . .
H27C H 0.566116 0.570525 0.241339 0.132 Uiso 1 1 calc R U . . .
C28 C 0.0652(3) 0.6273(2) 0.62092(19) 0.0682(13) Uani 1 1 d D . . . .
H28 H 0.098668 0.648945 0.656590 0.082 Uiso 1 1 calc R U . A 1
C29 C 0.0400(3) 0.5746(2) 0.6272(2) 0.0747(15) Uani 1 1 d D . . . .
H29 H 0.052743 0.554810 0.668463 0.090 Uiso 1 1 calc R U . A 1
C30 C -0.0072(3) 0.55606(18) 0.5626(2) 0.0660(12) Uani 1 1 d D . . . .
H30 H -0.030625 0.521743 0.551980 0.079 Uiso 1 1 calc R U . A 1
C31 C -0.0128(2) 0.59884(16) 0.51615(17) 0.0500(8) Uani 1 1 d D . . . .
H31 H -0.041862 0.598141 0.468704 0.060 Uiso 1 1 calc R U . A 1
C32 C 0.0314(2) 0.64175(15) 0.55180(17) 0.0489(8) Uani 1 1 d D . . . .
H32 H 0.037739 0.675249 0.532774 0.059 Uiso 1 1 calc R U . A 1
C33 C 0.240(2) 0.5383(8) 0.6520(9) 0.0561(19) Uani 0.521(9) 1 d D U P A 1
H33 H 0.217570 0.532026 0.693041 0.067 Uiso 0.521(9) 1 calc R U P A 1
C34 C 0.2279(7) 0.5051(3) 0.5930(6) 0.065(2) Uani 0.521(9) 1 d D U P A 1
H34 H 0.193584 0.473082 0.587084 0.078 Uiso 0.521(9) 1 calc R U P A 1
C35 C 0.276(4) 0.5287(14) 0.5448(15) 0.0478(10) Uani 0.521(9) 1 d D U P A 1
H35 H 0.279835 0.515442 0.500713 0.057 Uiso 0.521(9) 1 calc R U P A 1
C36 C 0.3172(7) 0.5745(4) 0.5740(4) 0.0449(19) Uani 0.521(9) 1 d D U P A 1
H36 H 0.356028 0.597389 0.553662 0.054 Uiso 0.521(9) 1 calc R U P A 1
C37 C 0.2922(5) 0.5818(3) 0.6381(3) 0.0517(19) Uani 0.521(9) 1 d D U P A 1
H37 H 0.307855 0.611282 0.667130 0.062 Uiso 0.521(9) 1 calc R U P A 1
C33A C 0.2031(6) 0.5062(3) 0.6239(3) 0.045(2) Uani 0.479(9) 1 d D U P A 2
H33A H 0.163930 0.486731 0.648104 0.054 Uiso 0.479(9) 1 calc R U P A 2
C34A C 0.2169(6) 0.4948(3) 0.5575(4) 0.0451(18) Uani 0.479(9) 1 d D U P A 2
H34A H 0.187380 0.467463 0.528571 0.054 Uiso 0.479(9) 1 calc R U P A 2
C35A C 0.284(4) 0.5320(15) 0.5417(16) 0.0478(10) Uani 0.479(9) 1 d D U P A 2
H35A H 0.308840 0.533314 0.500895 0.057 Uiso 0.479(9) 1 calc R U P A 2
C36A C 0.3047(7) 0.5660(5) 0.5976(6) 0.056(2) Uani 0.479(9) 1 d D U P A 2
H36A H 0.346218 0.595211 0.600399 0.068 Uiso 0.479(9) 1 calc R U P A 2
C37A C 0.256(2) 0.5506(9) 0.6492(10) 0.0561(19) Uani 0.479(9) 1 d D U P A 2
H37A H 0.257593 0.567087 0.692361 0.067 Uiso 0.479(9) 1 calc R U P A 2
Si1 Si -0.15240(4) 0.66415(2) 0.19336(3) 0.02209(12) Uani 1 1 d . . . . .
Si2 Si -0.24825(5) 0.68826(3) 0.27158(4) 0.03256(15) Uani 1 1 d . . . . .
Si3 Si -0.19806(5) 0.58404(3) 0.13943(3) 0.02847(14) Uani 1 1 d . . . . .
Si4 Si -0.14840(5) 0.72987(3) 0.11158(4) 0.03795(17) Uani 1 1 d . . . . .
Si5 Si 0.31119(4) 0.77731(2) 0.42313(3) 0.02158(12) Uani 1 1 d . . . . .
Si6 Si 0.34473(5) 0.76320(3) 0.54247(3) 0.02949(14) Uani 1 1 d . . . . .
Si7 Si 0.45268(5) 0.78621(3) 0.38089(4) 0.03134(14) Uani 1 1 d . . . . .
Si8 Si 0.21294(6) 0.85142(3) 0.39943(4) 0.03879(17) Uani 1 1 d . . . . .
Si9 Si 0.29798(4) 0.49323(2) 0.24740(4) 0.02675(13) Uani 1 1 d . . . . .
Si10 Si 0.17872(6) 0.45476(4) 0.16382(5) 0.0449(2) Uani 1 1 d . . . . .
Si11 Si 0.33532(5) 0.44096(3) 0.34643(4) 0.03404(15) Uani 1 1 d . . . . .
Si12 Si 0.43738(5) 0.51166(3) 0.20624(5) 0.03928(17) Uani 1 1 d . . . . .
H1 H 0.124(3) 0.5602(19) 0.470(2) 0.077(14) Uiso 1 1 d . . . . .
H2 H 0.199(3) 0.6372(19) 0.536(2) 0.079(14) Uiso 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
W1 C28 2.227(3) . ?
W1 C34 2.247(7) . ?
W1 C29 2.249(3) . ?
W1 C33 2.27(3) . ?
W1 C37 2.295(6) . ?
W1 C32 2.299(3) . ?
W1 C35 2.30(5) . ?
W1 C30 2.328(4) . ?
W1 C36 2.358(10) . ?
W1 C31 2.359(3) . ?
W1 Rh1 2.8517(5) . ?
W1 H1 1.82(5) . ?
W1 H2 1.74(5) . ?
Rh1 Ge9 2.4094(15) . ?
Rh1 Ge3 2.4214(5) . ?
Rh1 Ge4 2.4293(6) . ?
Rh1 Ge7 2.6439(12) . ?
Rh1 H1 1.97(5) . ?
Rh1 H2 2.05(5) . ?
Ge1 Si1 2.3834(13) . ?
Ge1 Ge3 2.4528(11) . ?
Ge1 Ge5 2.5560(16) . ?
Ge1 Ge4 2.5921(10) . ?
Ge1 Ge2 2.6120(14) . ?
Ge2 Ge7 2.5948(15) . ?
Ge2 Ge6 2.6116(15) . ?
Ge2 Ge5 2.6738(14) . ?
Ge3 Ge7 2.5419(14) . ?
Ge4 Ge8 2.5073(13) . ?
Ge5 Ge8 2.5814(18) . ?
Ge5 Ge6 2.6460(18) . ?
Ge6 Ge7 2.6511(16) . ?
Ge6 Ge8 2.6811(15) . ?
Ge7 Si5 2.3764(14) . ?
Ge7 Ge9 2.5278(12) . ?
Ge8 Si9 2.4233(11) . ?
Ge8 Ge9 2.4576(15) . ?
W1A C30 2.123(4) . ?
W1A C34A 2.153(8) . ?
W1A C33A 2.221(7) . ?
W1A C31 2.247(4) . ?
W1A C29 2.277(4) . ?
W1A C35A 2.32(6) . ?
W1A C37A 2.39(3) . ?
W1A C36A 2.419(10) . ?
W1A C32 2.453(4) . ?
W1A C28 2.472(4) . ?
W1A Rh1A 2.878(3) . ?
W1A H1 1.54(5) . ?
W1A H2 2.07(5) . ?
Rh1A Ge9A 2.309(9) . ?
Rh1A Ge4A 2.414(3) . ?
Rh1A Ge3A 2.451(3) . ?
Rh1A Ge8A 2.976(8) . ?
Rh1A H1 1.54(5) . ?
Ge1A Si1 2.440(7) . ?
Ge1A Ge4A 2.514(7) . ?
Ge1A Ge2A 2.566(10) . ?
Ge1A Ge5A 2.576(11) . ?
Ge1A Ge3A 2.592(8) . ?
Ge2A Ge7A 2.607(10) . ?
Ge2A Ge6A 2.630(10) . ?
Ge2A Ge5A 2.676(10) . ?
Ge3A Ge7A 2.370(9) . ?
Ge4A Ge8A 2.684(9) . ?
Ge5A Ge8A 2.542(11) . ?
Ge5A Ge6A 2.626(11) . ?
Ge6A Ge8A 2.593(10) . ?
Ge6A Ge7A 2.705(10) . ?
Ge7A Si5 2.488(8) . ?
Ge7A Ge9A 2.502(9) . ?
Ge8A Si9 2.244(7) . ?
Ge8A Ge9A 2.539(10) . ?
C1 Si2 1.865(4) . ?
C1 H1A 0.9800 . ?
C1 H1B 0.9800 . ?
C1 H1C 0.9800 . ?
C2 Si2 1.865(3) . ?
C2 H2A 0.9800 . ?
C2 H2B 0.9800 . ?
C2 H2C 0.9800 . ?
C3 Si2 1.881(3) . ?
C3 H3A 0.9800 . ?
C3 H3B 0.9800 . ?
C3 H3C 0.9800 . ?
C4 Si3 1.864(3) . ?
C4 H4A 0.9800 . ?
C4 H4B 0.9800 . ?
C4 H4C 0.9800 . ?
C5 Si3 1.857(4) . ?
C5 H5A 0.9800 . ?
C5 H5B 0.9800 . ?
C5 H5C 0.9800 . ?
C6 Si3 1.872(4) . ?
C6 H6A 0.9800 . ?
C6 H6B 0.9800 . ?
C6 H6C 0.9800 . ?
C7 Si4 1.872(4) . ?
C7 H7A 0.9800 . ?
C7 H7B 0.9800 . ?
C7 H7C 0.9800 . ?
C8 Si4 1.874(4) . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C9 Si4 1.876(4) . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
C10 Si6 1.863(3) . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C11 Si6 1.868(4) . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C12 Si6 1.874(3) . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
C13 Si7 1.875(3) . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C13 H13C 0.9800 . ?
C14 Si7 1.880(3) . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C15 Si7 1.884(3) . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 Si8 1.835(5) . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 Si8 1.844(4) . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C18 Si8 1.869(5) . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C19 Si10 1.865(5) . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C20 Si10 1.870(4) . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C21 Si10 1.866(5) . ?
C21 H21A 0.9800 . ?
C21 H21B 0.9800 . ?
C21 H21C 0.9800 . ?
C22 Si11 1.876(3) . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C23 Si11 1.880(3) . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C24 Si11 1.875(3) . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C25 Si12 1.870(3) . ?
C25 H25A 0.9800 . ?
C25 H25B 0.9800 . ?
C25 H25C 0.9800 . ?
C26 Si12 1.875(5) . ?
C26 H26A 0.9800 . ?
C26 H26B 0.9800 . ?
C26 H26C 0.9800 . ?
C27 Si12 1.858(4) . ?
C27 H27A 0.9800 . ?
C27 H27B 0.9800 . ?
C27 H27C 0.9800 . ?
C28 C32 1.410(5) . ?
C28 C29 1.410(7) . ?
C28 H28 0.9500 . ?
C29 C30 1.406(7) . ?
C29 H29 0.9500 . ?
C30 C31 1.425(5) . ?
C30 H30 0.9500 . ?
C31 C32 1.389(6) . ?
C31 H31 0.9500 . ?
C32 H32 0.9500 . ?
C33 C37 1.396(12) . ?
C33 C34 1.431(13) . ?
C33 H33 0.9500 . ?
C34 C35 1.422(12) . ?
C34 H34 0.9500 . ?
C35 C36 1.387(11) . ?
C35 H35 0.9500 . ?
C36 C37 1.401(9) . ?
C36 H36 0.9500 . ?
C37 H37 0.9500 . ?
C33A C37A 1.400(14) . ?
C33A C34A 1.401(8) . ?
C33A H33A 0.9500 . ?
C34A C35A 1.427(12) . ?
C34A H34A 0.9500 . ?
C35A C36A 1.396(12) . ?
C35A H35A 0.9500 . ?
C36A C37A 1.409(14) . ?
C36A H36A 0.9500 . ?
C37A H37A 0.9500 . ?
Si1 Si3 2.3475(9) . ?
Si1 Si4 2.3482(9) . ?
Si1 Si2 2.3491(9) . ?
Si5 Si6 2.3484(9) . ?
Si5 Si7 2.3484(9) . ?
Si5 Si8 2.3528(9) . ?
Si9 Si10 2.3432(10) . ?
Si9 Si12 2.3464(10) . ?
Si9 Si11 2.3500(11) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C28 W1 C34 127.1(3) . . ?
C28 W1 C29 36.72(17) . . ?
C34 W1 C29 98.3(3) . . ?
C28 W1 C33 96.2(5) . . ?
C34 W1 C33 36.9(4) . . ?
C29 W1 C33 81.6(5) . . ?
C28 W1 C37 97.4(2) . . ?
C34 W1 C37 60.2(3) . . ?
C29 W1 C37 103.5(2) . . ?
C33 W1 C37 35.6(4) . . ?
C28 W1 C32 36.25(12) . . ?
C34 W1 C32 157.8(3) . . ?
C29 W1 C32 59.82(13) . . ?
C33 W1 C32 132.4(5) . . ?
C37 W1 C32 125.0(2) . . ?
C28 W1 C35 155.2(9) . . ?
C34 W1 C35 36.4(6) . . ?
C29 W1 C35 134.7(7) . . ?
C33 W1 C35 60.3(10) . . ?
C37 W1 C35 59.2(8) . . ?
C32 W1 C35 165.3(7) . . ?
C28 W1 C30 60.44(18) . . ?
C34 W1 C30 101.3(3) . . ?
C29 W1 C30 35.73(17) . . ?
C33 W1 C30 105.0(5) . . ?
C37 W1 C30 136.1(2) . . ?
C32 W1 C30 59.21(14) . . ?
C35 W1 C30 129.6(3) . . ?
C28 W1 C36 128.0(3) . . ?
C34 W1 C36 58.9(3) . . ?
C29 W1 C36 137.7(2) . . ?
C33 W1 C36 58.6(5) . . ?
C37 W1 C36 35.0(2) . . ?
C32 W1 C36 139.5(3) . . ?
C35 W1 C36 34.6(4) . . ?
C30 W1 C36 160.1(3) . . ?
C28 W1 C31 59.34(14) . . ?
C34 W1 C31 132.7(3) . . ?
C29 W1 C31 58.91(13) . . ?
C33 W1 C31 139.0(5) . . ?
C37 W1 C31 156.7(2) . . ?
C32 W1 C31 34.67(14) . . ?
C35 W1 C31 143.8(7) . . ?
C30 W1 C31 35.38(12) . . ?
C36 W1 C31 162.4(2) . . ?
C28 W1 Rh1 113.48(11) . . ?
C34 W1 Rh1 119.4(3) . . ?
C29 W1 Rh1 136.99(10) . . ?
C33 W1 Rh1 141.2(5) . . ?
C37 W1 Rh1 112.5(2) . . ?
C32 W1 Rh1 80.13(8) . . ?
C35 W1 Rh1 85.4(8) . . ?
C30 W1 Rh1 111.15(10) . . ?
C36 W1 Rh1 83.0(2) . . ?
C31 W1 Rh1 79.50(8) . . ?
C28 W1 H1 130.9(15) . . ?
C34 W1 H1 92.3(15) . . ?
C29 W1 H1 122.3(15) . . ?
C33 W1 H1 128.8(16) . . ?
C37 W1 H1 130.0(15) . . ?
C32 W1 H1 96.6(15) . . ?
C35 W1 H1 73.9(17) . . ?
C30 W1 H1 86.6(15) . . ?
C36 W1 H1 95.6(15) . . ?
C31 W1 H1 72.6(15) . . ?
Rh1 W1 H1 43.2(15) . . ?
C28 W1 H2 88.8(16) . . ?
C34 W1 H2 126.6(16) . . ?
C29 W1 H2 125.5(16) . . ?
C33 W1 H2 114.8(16) . . ?
C37 W1 H2 79.3(16) . . ?
C32 W1 H2 74.1(16) . . ?
C35 W1 H2 94.2(17) . . ?
C30 W1 H2 132.0(16) . . ?
C36 W1 H2 67.9(16) . . ?
C31 W1 H2 98.2(16) . . ?
Rh1 W1 H2 45.6(16) . . ?
H1 W1 H2 89(2) . . ?
Ge9 Rh1 Ge3 116.64(3) . . ?
Ge9 Rh1 Ge4 90.37(3) . . ?
Ge3 Rh1 Ge4 82.130(13) . . ?
Ge9 Rh1 Ge7 59.82(3) . . ?
Ge3 Rh1 Ge7 60.05(3) . . ?
Ge4 Rh1 Ge7 100.25(3) . . ?
Ge9 Rh1 W1 117.26(4) . . ?
Ge3 Rh1 W1 123.463(14) . . ?
Ge4 Rh1 W1 113.069(14) . . ?
Ge7 Rh1 W1 146.68(3) . . ?
Ge9 Rh1 H1 112.0(14) . . ?
Ge3 Rh1 H1 125.5(14) . . ?
Ge4 Rh1 H1 74.3(14) . . ?
Ge7 Rh1 H1 170.6(14) . . ?
W1 Rh1 H1 39.4(14) . . ?
Ge9 Rh1 H2 105.5(13) . . ?
Ge3 Rh1 H2 111.3(13) . . ?
Ge4 Rh1 H2 150.2(14) . . ?
Ge7 Rh1 H2 109.5(14) . . ?
W1 Rh1 H2 37.2(14) . . ?
H1 Rh1 H2 76.4(19) . . ?
Si1 Ge1 Ge3 123.75(4) . . ?
Si1 Ge1 Ge5 113.02(6) . . ?
Ge3 Ge1 Ge5 120.06(6) . . ?
Si1 Ge1 Ge4 130.86(5) . . ?
Ge3 Ge1 Ge4 78.29(4) . . ?
Ge5 Ge1 Ge4 79.03(4) . . ?
Si1 Ge1 Ge2 116.83(5) . . ?
Ge3 Ge1 Ge2 75.75(4) . . ?
Ge5 Ge1 Ge2 62.30(5) . . ?
Ge4 Ge1 Ge2 110.87(5) . . ?
Ge7 Ge2 Ge6 61.22(4) . . ?
Ge7 Ge2 Ge1 90.72(5) . . ?
Ge6 Ge2 Ge1 103.95(4) . . ?
Ge7 Ge2 Ge5 99.40(5) . . ?
Ge6 Ge2 Ge5 60.07(4) . . ?
Ge1 Ge2 Ge5 57.82(4) . . ?
Rh1 Ge3 Ge1 99.98(3) . . ?
Rh1 Ge3 Ge7 64.32(2) . . ?
Ge1 Ge3 Ge7 95.75(4) . . ?
Rh1 Ge4 Ge8 90.03(3) . . ?
Rh1 Ge4 Ge1 96.00(3) . . ?
Ge8 Ge4 Ge1 97.73(4) . . ?
Ge1 Ge5 Ge8 96.78(6) . . ?
Ge1 Ge5 Ge6 104.55(5) . . ?
Ge8 Ge5 Ge6 61.70(5) . . ?
Ge1 Ge5 Ge2 59.88(4) . . ?
Ge8 Ge5 Ge2 103.89(5) . . ?
Ge6 Ge5 Ge2 58.80(4) . . ?
Ge2 Ge6 Ge5 61.13(4) . . ?
Ge2 Ge6 Ge7 59.08(4) . . ?
Ge5 Ge6 Ge7 98.69(6) . . ?
Ge2 Ge6 Ge8 102.87(5) . . ?
Ge5 Ge6 Ge8 57.97(5) . . ?
Ge7 Ge6 Ge8 88.60(5) . . ?
Si5 Ge7 Ge9 116.35(6) . . ?
Si5 Ge7 Ge3 116.64(5) . . ?
Ge9 Ge7 Ge3 108.37(6) . . ?
Si5 Ge7 Ge2 113.96(4) . . ?
Ge9 Ge7 Ge2 119.89(6) . . ?
Ge3 Ge7 Ge2 74.57(4) . . ?
Si5 Ge7 Rh1 124.82(6) . . ?
Ge9 Ge7 Rh1 55.48(4) . . ?
Ge3 Ge7 Rh1 55.63(3) . . ?
Ge2 Ge7 Rh1 114.38(5) . . ?
Si5 Ge7 Ge6 116.47(6) . . ?
Ge9 Ge7 Ge6 69.68(5) . . ?
Ge3 Ge7 Ge6 119.92(6) . . ?
Ge2 Ge7 Ge6 59.70(4) . . ?
Rh1 Ge7 Ge6 109.91(4) . . ?
Si9 Ge8 Ge9 122.21(6) . . ?
Si9 Ge8 Ge4 123.69(5) . . ?
Ge9 Ge8 Ge4 87.47(5) . . ?
Si9 Ge8 Ge5 114.02(5) . . ?
Ge9 Ge8 Ge5 118.90(5) . . ?
Ge4 Ge8 Ge5 80.13(5) . . ?
Si9 Ge8 Ge6 122.73(6) . . ?
Ge9 Ge8 Ge6 70.20(5) . . ?
Ge4 Ge8 Ge6 111.72(5) . . ?
Ge5 Ge8 Ge6 60.34(5) . . ?
Rh1 Ge9 Ge8 91.69(6) . . ?
Rh1 Ge9 Ge7 64.70(4) . . ?
Ge8 Ge9 Ge7 96.66(6) . . ?
C30 W1A C34A 113.8(3) . . ?
C30 W1A C33A 97.4(3) . . ?
C34A W1A C33A 37.3(2) . . ?
C30 W1A C31 37.91(14) . . ?
C34A W1A C31 143.5(3) . . ?
C33A W1A C31 135.2(2) . . ?
C30 W1A C29 37.05(18) . . ?
C34A W1A C29 114.4(2) . . ?
C33A W1A C29 81.2(2) . . ?
C31 W1A C29 60.15(14) . . ?
C30 W1A C35A 150.8(6) . . ?
C34A W1A C35A 37.0(6) . . ?
C33A W1A C35A 60.1(9) . . ?
C31 W1A C35A 160.3(9) . . ?
C29 W1A C35A 139.1(9) . . ?
C30 W1A C37A 114.7(4) . . ?
C34A W1A C37A 60.4(6) . . ?
C33A W1A C37A 35.1(4) . . ?
C31 W1A C37A 141.1(6) . . ?
C29 W1A C37A 82.7(5) . . ?
C35A W1A C37A 58.4(10) . . ?
C30 W1A C36A 148.7(3) . . ?
C34A W1A C36A 59.1(4) . . ?
C33A W1A C36A 57.6(3) . . ?
C31 W1A C36A 157.4(3) . . ?
C29 W1A C36A 114.3(3) . . ?
C35A W1A C36A 34.2(5) . . ?
C37A W1A C36A 34.1(4) . . ?
C30 W1A C32 59.41(16) . . ?
C34A W1A C32 171.5(2) . . ?
C33A W1A C32 135.5(2) . . ?
C31 W1A C32 34.02(14) . . ?
C29 W1A C32 57.15(14) . . ?
C35A W1A C32 149.7(5) . . ?
C37A W1A C32 116.5(6) . . ?
C36A W1A C32 123.5(3) . . ?
C30 W1A C28 59.33(19) . . ?
C34A W1A C28 140.1(2) . . ?
C33A W1A C28 102.8(2) . . ?
C31 W1A C28 57.35(15) . . ?
C29 W1A C28 34.23(16) . . ?
C35A W1A C28 139.0(5) . . ?
C37A W1A C28 85.8(6) . . ?
C36A W1A C28 104.8(3) . . ?
C32 W1A C28 33.26(12) . . ?
C30 W1A Rh1A 118.26(15) . . ?
C34A W1A Rh1A 91.63(19) . . ?
C33A W1A Rh1A 128.0(2) . . ?
C31 W1A Rh1A 89.00(11) . . ?
C29 W1A Rh1A 149.03(14) . . ?
C35A W1A Rh1A 71.9(9) . . ?
C37A W1A Rh1A 126.6(5) . . ?
C36A W1A Rh1A 92.9(3) . . ?
C32 W1A Rh1A 96.18(11) . . ?
C28 W1A Rh1A 127.28(13) . . ?
C30 W1A H1 102.0(18) . . ?
C34A W1A H1 87.1(18) . . ?
C33A W1A H1 123.9(18) . . ?
C31 W1A H1 80.9(18) . . ?
C29 W1A H1 138.0(18) . . ?
C35A W1A H1 80(2) . . ?
C37A W1A H1 138.0(19) . . ?
C36A W1A H1 107.6(18) . . ?
C32 W1A H1 99.1(18) . . ?
C28 W1A H1 132.4(18) . . ?
Rh1A W1A H1 20.7(18) . . ?
C30 W1A H2 125.0(13) . . ?
C34A W1A H2 121.0(14) . . ?
C33A W1A H2 123.1(14) . . ?
C31 W1A H2 92.5(13) . . ?
C29 W1A H2 109.4(13) . . ?
C35A W1A H2 84.2(15) . . ?
C37A W1A H2 89.3(14) . . ?
C36A W1A H2 67.9(14) . . ?
C32 W1A H2 65.6(13) . . ?
C28 W1A H2 75.4(13) . . ?
Rh1A W1A H2 66.2(13) . . ?
H1 W1A H2 86(2) . . ?
Ge9A Rh1A Ge4A 113.4(2) . . ?
Ge9A Rh1A Ge3A 98.2(2) . . ?
Ge4A Rh1A Ge3A 83.12(8) . . ?
Ge9A Rh1A W1A 120.8(2) . . ?
Ge4A Rh1A W1A 124.32(7) . . ?
Ge3A Rh1A W1A 100.07(7) . . ?
Ge9A Rh1A Ge8A 55.7(3) . . ?
Ge4A Rh1A Ge8A 58.64(17) . . ?
Ge3A Rh1A Ge8A 100.19(17) . . ?
W1A Rh1A Ge8A 159.74(17) . . ?
Ge9A Rh1A H1 137.8(18) . . ?
Ge4A Rh1A H1 104.3(18) . . ?
Ge3A Rh1A H1 104.6(18) . . ?
W1A Rh1A H1 20.7(18) . . ?
Ge8A Rh1A H1 147.9(18) . . ?
Si1 Ge1A Ge4A 123.8(3) . . ?
Si1 Ge1A Ge2A 114.1(3) . . ?
Ge4A Ge1A Ge2A 120.1(3) . . ?
Si1 Ge1A Ge5A 114.6(4) . . ?
Ge4A Ge1A Ge5A 79.8(3) . . ?
Ge2A Ge1A Ge5A 62.7(3) . . ?
Si1 Ge1A Ge3A 130.0(3) . . ?
Ge4A Ge1A Ge3A 78.4(2) . . ?
Ge2A Ge1A Ge3A 76.3(3) . . ?
Ge5A Ge1A Ge3A 113.2(3) . . ?
Ge1A Ge2A Ge7A 94.1(3) . . ?
Ge1A Ge2A Ge6A 103.8(3) . . ?
Ge7A Ge2A Ge6A 62.2(3) . . ?
Ge1A Ge2A Ge5A 58.8(3) . . ?
Ge7A Ge2A Ge5A 103.0(3) . . ?
Ge6A Ge2A Ge5A 59.3(3) . . ?
Ge7A Ge3A Rh1A 83.19(18) . . ?
Ge7A Ge3A Ge1A 99.4(3) . . ?
Rh1A Ge3A Ge1A 95.48(16) . . ?
Rh1A Ge4A Ge1A 98.5(2) . . ?
Rh1A Ge4A Ge8A 71.21(17) . . ?
Ge1A Ge4A Ge8A 92.5(3) . . ?
Ge8A Ge5A Ge1A 94.4(4) . . ?
Ge8A Ge5A Ge6A 60.2(3) . . ?
Ge1A Ge5A Ge6A 103.6(3) . . ?
Ge8A Ge5A Ge2A 101.5(4) . . ?
Ge1A Ge5A Ge2A 58.5(3) . . ?
Ge6A Ge5A Ge2A 59.5(3) . . ?
Ge8A Ge6A Ge5A 58.3(3) . . ?
Ge8A Ge6A Ge2A 101.4(3) . . ?
Ge5A Ge6A Ge2A 61.2(3) . . ?
Ge8A Ge6A Ge7A 90.6(3) . . ?
Ge5A Ge6A Ge7A 101.7(4) . . ?
Ge2A Ge6A Ge7A 58.5(3) . . ?
Ge3A Ge7A Si5 122.3(3) . . ?
Ge3A Ge7A Ge9A 95.2(3) . . ?
Si5 Ge7A Ge9A 122.5(4) . . ?
Ge3A Ge7A Ge2A 79.5(3) . . ?
Si5 Ge7A Ge2A 111.1(3) . . ?
Ge9A Ge7A Ge2A 117.9(4) . . ?
Ge3A Ge7A Ge6A 115.5(4) . . ?
Si5 Ge7A Ge6A 118.0(4) . . ?
Ge9A Ge7A Ge6A 68.9(3) . . ?
Ge2A Ge7A Ge6A 59.3(3) . . ?
Si9 Ge8A Ge9A 118.0(4) . . ?
Si9 Ge8A Ge5A 116.8(3) . . ?
Ge9A Ge8A Ge5A 120.3(4) . . ?
Si9 Ge8A Ge6A 122.9(4) . . ?
Ge9A Ge8A Ge6A 70.2(3) . . ?
Ge5A Ge8A Ge6A 61.5(3) . . ?
Si9 Ge8A Ge4A 116.1(3) . . ?
Ge9A Ge8A Ge4A 98.2(3) . . ?
Ge5A Ge8A Ge4A 77.3(3) . . ?
Ge6A Ge8A Ge4A 118.2(3) . . ?
Si9 Ge8A Rh1A 127.3(3) . . ?
Ge9A Ge8A Rh1A 48.7(2) . . ?
Ge5A Ge8A Rh1A 108.7(3) . . ?
Ge6A Ge8A Rh1A 101.1(3) . . ?
Ge4A Ge8A Rh1A 50.16(15) . . ?
Rh1A Ge9A Ge7A 83.3(3) . . ?
Rh1A Ge9A Ge8A 75.6(3) . . ?
Ge7A Ge9A Ge8A 96.7(4) . . ?
Si2 C1 H1A 109.5 . . ?
Si2 C1 H1B 109.5 . . ?
H1A C1 H1B 109.5 . . ?
Si2 C1 H1C 109.5 . . ?
H1A C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
Si2 C2 H2A 109.5 . . ?
Si2 C2 H2B 109.5 . . ?
H2A C2 H2B 109.5 . . ?
Si2 C2 H2C 109.5 . . ?
H2A C2 H2C 109.5 . . ?
H2B C2 H2C 109.5 . . ?
Si2 C3 H3A 109.5 . . ?
Si2 C3 H3B 109.5 . . ?
H3A C3 H3B 109.5 . . ?
Si2 C3 H3C 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
Si3 C4 H4A 109.5 . . ?
Si3 C4 H4B 109.5 . . ?
H4A C4 H4B 109.5 . . ?
Si3 C4 H4C 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
Si3 C5 H5A 109.5 . . ?
Si3 C5 H5B 109.5 . . ?
H5A C5 H5B 109.5 . . ?
Si3 C5 H5C 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
Si3 C6 H6A 109.5 . . ?
Si3 C6 H6B 109.5 . . ?
H6A C6 H6B 109.5 . . ?
Si3 C6 H6C 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
Si4 C7 H7A 109.5 . . ?
Si4 C7 H7B 109.5 . . ?
H7A C7 H7B 109.5 . . ?
Si4 C7 H7C 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
Si4 C8 H8A 109.5 . . ?
Si4 C8 H8B 109.5 . . ?
H8A C8 H8B 109.5 . . ?
Si4 C8 H8C 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
Si4 C9 H9A 109.5 . . ?
Si4 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
Si4 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
Si6 C10 H10A 109.5 . . ?
Si6 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
Si6 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
Si6 C11 H11A 109.5 . . ?
Si6 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
Si6 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
Si6 C12 H12A 109.5 . . ?
Si6 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
Si6 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
Si7 C13 H13A 109.5 . . ?
Si7 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
Si7 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
Si7 C14 H14A 109.5 . . ?
Si7 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
Si7 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
Si7 C15 H15A 109.5 . . ?
Si7 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
Si7 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
Si8 C16 H16A 109.5 . . ?
Si8 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
Si8 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
Si8 C17 H17A 109.5 . . ?
Si8 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
Si8 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
Si8 C18 H18A 109.5 . . ?
Si8 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
Si8 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
Si10 C19 H19A 109.5 . . ?
Si10 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
Si10 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
Si10 C20 H20A 109.5 . . ?
Si10 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
Si10 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
Si10 C21 H21A 109.5 . . ?
Si10 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
Si10 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
Si11 C22 H22A 109.5 . . ?
Si11 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
Si11 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
Si11 C23 H23A 109.5 . . ?
Si11 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
Si11 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
Si11 C24 H24A 109.5 . . ?
Si11 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
Si11 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
Si12 C25 H25A 109.5 . . ?
Si12 C25 H25B 109.5 . . ?
H25A C25 H25B 109.5 . . ?
Si12 C25 H25C 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
Si12 C26 H26A 109.5 . . ?
Si12 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
Si12 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
Si12 C27 H27A 109.5 . . ?
Si12 C27 H27B 109.5 . . ?
H27A C27 H27B 109.5 . . ?
Si12 C27 H27C 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
C32 C28 C29 107.1(4) . . ?
C32 C28 W1 74.67(19) . . ?
C29 C28 W1 72.5(2) . . ?
C32 C28 W1A 72.7(2) . . ?
C29 C28 W1A 65.3(2) . . ?
C32 C28 H28 126.4 . . ?
C29 C28 H28 126.4 . . ?
W1 C28 H28 118.4 . . ?
C30 C29 C28 109.1(3) . . ?
C30 C29 W1 75.21(18) . . ?
C28 C29 W1 70.81(19) . . ?
C30 C29 W1A 65.51(18) . . ?
C28 C29 W1A 80.4(2) . . ?
C30 C29 H29 125.4 . . ?
C28 C29 H29 125.4 . . ?
W1 C29 H29 120.3 . . ?
C29 C30 C31 106.5(4) . . ?
C29 C30 W1A 77.4(2) . . ?
C31 C30 W1A 75.76(19) . . ?
C29 C30 W1 69.1(2) . . ?
C31 C30 W1 73.51(19) . . ?
C29 C30 H30 126.8 . . ?
C31 C30 H30 126.8 . . ?
W1 C30 H30 122.4 . . ?
C32 C31 C30 108.6(3) . . ?
C32 C31 W1A 81.14(19) . . ?
C30 C31 W1A 66.32(19) . . ?
C32 C31 W1 70.30(17) . . ?
C30 C31 W1 71.10(19) . . ?
C32 C31 H31 125.7 . . ?
C30 C31 H31 125.7 . . ?
W1 C31 H31 124.5 . . ?
C31 C32 C28 108.6(4) . . ?
C31 C32 W1 75.03(19) . . ?
C28 C32 W1 69.08(19) . . ?
C31 C32 W1A 64.84(18) . . ?
C28 C32 W1A 74.1(2) . . ?
C31 C32 H32 125.7 . . ?
C28 C32 H32 125.7 . . ?
W1 C32 H32 121.8 . . ?
C37 C33 C34 107.4(9) . . ?
C37 C33 W1 73.1(11) . . ?
C34 C33 W1 70.6(10) . . ?
C37 C33 H33 126.3 . . ?
C34 C33 H33 126.3 . . ?
W1 C33 H33 121.8 . . ?
C35 C34 C33 107.4(8) . . ?
C35 C34 W1 74(2) . . ?
C33 C34 W1 72.5(13) . . ?
C35 C34 H34 126.3 . . ?
C33 C34 H34 126.3 . . ?
W1 C34 H34 119.1 . . ?
C36 C35 C34 107.6(9) . . ?
C36 C35 W1 75(2) . . ?
C34 C35 W1 69.6(18) . . ?
C36 C35 H35 126.2 . . ?
C34 C35 H35 126.2 . . ?
W1 C35 H35 121.1 . . ?
C35 C36 C37 109.1(8) . . ?
C35 C36 W1 71(2) . . ?
C37 C36 W1 70.0(5) . . ?
C35 C36 H36 125.4 . . ?
C37 C36 H36 125.4 . . ?
W1 C36 H36 125.6 . . ?
C33 C37 C36 108.4(9) . . ?
C33 C37 W1 71.4(13) . . ?
C36 C37 W1 75.0(5) . . ?
C33 C37 H37 125.8 . . ?
C36 C37 H37 125.8 . . ?
W1 C37 H37 119.7 . . ?
C37A C33A C34A 110.0(9) . . ?
C37A C33A W1A 79.0(14) . . ?
C34A C33A W1A 68.7(5) . . ?
C37A C33A H33A 125.0 . . ?
C34A C33A H33A 125.0 . . ?
W1A C33A H33A 118.8 . . ?
C33A C34A C35A 107.1(9) . . ?
C33A C34A W1A 74.0(5) . . ?
C35A C34A W1A 78(3) . . ?
C33A C34A H34A 126.5 . . ?
C35A C34A H34A 126.5 . . ?
W1A C34A H34A 114.2 . . ?
C36A C35A C34A 106.8(10) . . ?
C36A C35A W1A 77(2) . . ?
C34A C35A W1A 65(2) . . ?
C36A C35A H35A 126.6 . . ?
C34A C35A H35A 126.6 . . ?
W1A C35A H35A 122.9 . . ?
C35A C36A C37A 110.1(10) . . ?
C35A C36A W1A 69(3) . . ?
C37A C36A W1A 71.8(14) . . ?
C35A C36A H36A 124.9 . . ?
C37A C36A H36A 124.9 . . ?
W1A C36A H36A 125.8 . . ?
C33A C37A C36A 105.9(10) . . ?
C33A C37A W1A 65.9(11) . . ?
C36A C37A W1A 74.1(12) . . ?
C33A C37A H37A 127.0 . . ?
C36A C37A H37A 127.0 . . ?
W1A C37A H37A 124.5 . . ?
Si3 Si1 Si4 110.85(4) . . ?
Si3 Si1 Si2 112.72(4) . . ?
Si4 Si1 Si2 111.47(4) . . ?
Si3 Si1 Ge1 107.69(3) . . ?
Si4 Si1 Ge1 109.09(4) . . ?
Si2 Si1 Ge1 104.70(4) . . ?
Si3 Si1 Ge1A 102.11(15) . . ?
Si4 Si1 Ge1A 111.75(18) . . ?
Si2 Si1 Ge1A 107.55(18) . . ?
C1 Si2 C2 107.58(19) . . ?
C1 Si2 C3 107.88(19) . . ?
C2 Si2 C3 110.56(19) . . ?
C1 Si2 Si1 111.55(12) . . ?
C2 Si2 Si1 110.08(12) . . ?
C3 Si2 Si1 109.16(13) . . ?
C5 Si3 C4 108.7(2) . . ?
C5 Si3 C6 108.2(2) . . ?
C4 Si3 C6 107.4(2) . . ?
C5 Si3 Si1 110.23(12) . . ?
C4 Si3 Si1 109.98(12) . . ?
C6 Si3 Si1 112.20(14) . . ?
C7 Si4 C8 108.1(3) . . ?
C7 Si4 C9 108.8(3) . . ?
C8 Si4 C9 109.42(17) . . ?
C7 Si4 Si1 109.42(14) . . ?
C8 Si4 Si1 109.37(14) . . ?
C9 Si4 Si1 111.65(11) . . ?
Si6 Si5 Si7 111.04(3) . . ?
Si6 Si5 Si8 108.59(4) . . ?
Si7 Si5 Si8 111.80(4) . . ?
Si6 Si5 Ge7 108.98(4) . . ?
Si7 Si5 Ge7 106.77(4) . . ?
Si8 Si5 Ge7 109.62(4) . . ?
Si6 Si5 Ge7A 106.17(19) . . ?
Si7 Si5 Ge7A 105.2(2) . . ?
Si8 Si5 Ge7A 113.88(17) . . ?
C10 Si6 C11 110.3(2) . . ?
C10 Si6 C12 107.26(17) . . ?
C11 Si6 C12 108.3(2) . . ?
C10 Si6 Si5 110.01(11) . . ?
C11 Si6 Si5 110.83(11) . . ?
C12 Si6 Si5 110.09(12) . . ?
C13 Si7 C14 107.83(17) . . ?
C13 Si7 C15 109.26(16) . . ?
C14 Si7 C15 108.66(15) . . ?
C13 Si7 Si5 110.21(10) . . ?
C14 Si7 Si5 109.22(12) . . ?
C15 Si7 Si5 111.57(11) . . ?
C16 Si8 C17 110.5(4) . . ?
C16 Si8 C18 107.0(5) . . ?
C17 Si8 C18 105.4(3) . . ?
C16 Si8 Si5 111.51(18) . . ?
C17 Si8 Si5 112.64(12) . . ?
C18 Si8 Si5 109.50(19) . . ?
Ge8A Si9 Si10 105.9(2) . . ?
Ge8A Si9 Si12 111.4(2) . . ?
Si10 Si9 Si12 112.64(4) . . ?
Ge8A Si9 Si11 105.5(2) . . ?
Si10 Si9 Si11 111.26(4) . . ?
Si12 Si9 Si11 109.89(4) . . ?
Si10 Si9 Ge8 108.49(4) . . ?
Si12 Si9 Ge8 110.59(4) . . ?
Si11 Si9 Ge8 103.59(5) . . ?
C19 Si10 C21 108.6(3) . . ?
C19 Si10 C20 110.8(3) . . ?
C21 Si10 C20 106.82(18) . . ?
C19 Si10 Si9 108.66(15) . . ?
C21 Si10 Si9 111.94(15) . . ?
C20 Si10 Si9 110.08(16) . . ?
C24 Si11 C22 108.51(18) . . ?
C24 Si11 C23 108.93(17) . . ?
C22 Si11 C23 108.25(16) . . ?
C24 Si11 Si9 109.94(14) . . ?
C22 Si11 Si9 110.59(12) . . ?
C23 Si11 Si9 110.57(12) . . ?
C27 Si12 C25 107.9(2) . . ?
C27 Si12 C26 110.9(3) . . ?
C25 Si12 C26 107.6(2) . . ?
C27 Si12 Si9 110.56(15) . . ?
C25 Si12 Si9 109.80(12) . . ?
C26 Si12 Si9 109.97(15) . . ?

_refine_diff_density_max         0.971
_refine_diff_density_min         -0.776
_refine_diff_density_rms         0.086


