# Electronic Supplementary Material (ESI) for Chemical Science.
# This journal is © The Royal Society of Chemistry 2023

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 2214247'
loop_
_audit_author_name
_audit_author_address
'Xinda Huang'
;Nanjing University
China
;
_audit_update_record             
;
2022-10-20 deposited with the CCDC.	2023-01-27 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        '[Dy(NO3)3(depma2)1.5].(depma2)0.5.CH3OH'
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         
'C57 H63 Dy N3 O18 P3, (C19 H21 O3 P), (C H4 O)'
_chemical_formula_sum            'C77 H88 Dy N3 O22 P4'
_chemical_formula_weight         1693.88

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   12.0582(4)
_cell_length_b                   13.8579(5)
_cell_length_c                   23.2328(8)
_cell_angle_alpha                90.6460(10)
_cell_angle_beta                 97.9700(10)
_cell_angle_gamma                86.0330(10)
_cell_volume                     3835.5(2)
_cell_formula_units_Z            2
_cell_measurement_temperature    193(2)
_cell_measurement_reflns_used    9965
_cell_measurement_theta_min      2.2605
_cell_measurement_theta_max      26.6295

_exptl_crystal_description       rod
_exptl_crystal_colour            colorless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.467
_exptl_crystal_F_000             1746
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.400
_exptl_crystal_size_mid          0.100
_exptl_crystal_size_min          0.080
_exptl_absorpt_coefficient_mu    1.134
_shelx_estimated_absorpt_T_min   0.660
_shelx_estimated_absorpt_T_max   0.915
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.873
_exptl_absorpt_correction_T_max  0.915
_exptl_absorpt_process_details   'SADABS 2016/2'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      193(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker D8 Venture'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            16030
_diffrn_reflns_av_unetI/netI     0.0742
_diffrn_reflns_av_R_equivalents  0.0467
_diffrn_reflns_limit_h_min       ?
_diffrn_reflns_limit_h_max       ?
_diffrn_reflns_limit_k_min       ?
_diffrn_reflns_limit_k_max       ?
_diffrn_reflns_limit_l_min       ?
_diffrn_reflns_limit_l_max       ?
_diffrn_reflns_theta_min         2.179
_diffrn_reflns_theta_max         26.636
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measured_fraction_theta_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.994
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.994
_diffrn_reflns_point_group_measured_fraction_full 0.997
_reflns_number_total             16030
_reflns_number_gt                13018
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker APEX3'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXT 2014/4 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0521P)²+6.5602P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         16030
_refine_ls_number_parameters     1014
_refine_ls_number_restraints     1075
_refine_ls_R_factor_all          0.0697
_refine_ls_R_factor_gt           0.0504
_refine_ls_wR_factor_ref         0.1222
_refine_ls_wR_factor_gt          0.1148
_refine_ls_goodness_of_fit_ref   1.040
_refine_ls_restrained_S_all      1.073
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.29041(2) 0.81606(2) 0.74575(2) 0.02569(7) Uani 1 1 d . . . . .
P1 P 0.24049(10) 0.63859(8) 0.85976(5) 0.0298(2) Uani 1 1 d . U . . .
P2 P 0.08611(10) 0.97896(9) 0.81572(4) 0.0318(3) Uani 1 1 d . U . . .
P3 P 0.43559(10) 1.01589(8) 0.68978(5) 0.0299(2) Uani 1 1 d . U . . .
P4 P 0.18778(17) 0.43117(12) 0.34520(8) 0.0677(5) Uani 1 1 d . U . . .
C1 C 0.3268(4) 0.6538(3) 0.92882(17) 0.0277(8) Uani 1 1 d . U . . .
H1A H 0.374642 0.707810 0.924540 0.033 Uiso 1 1 calc R U . . .
H1B H 0.276146 0.674953 0.957308 0.033 Uiso 1 1 calc R U . . .
C2 C 0.4046(3) 0.5677(3) 0.95617(16) 0.0239(7) Uani 1 1 d . U . . .
C3 C 0.3393(3) 0.4839(3) 0.97208(16) 0.0259(7) Uani 1 1 d . U . . .
C4 C 0.2246(4) 0.4908(3) 0.97498(18) 0.0319(8) Uani 1 1 d . U . . .
H4 H 0.182617 0.550519 0.966036 0.038 Uiso 1 1 calc R U . . .
C5 C 0.1703(4) 0.4120(4) 0.9907(2) 0.0393(9) Uani 1 1 d . U . . .
H5 H 0.091663 0.417649 0.991686 0.047 Uiso 1 1 calc R U . . .
C6 C 0.2310(4) 0.3255(4) 1.0048(2) 0.0427(10) Uani 1 1 d . U . . .
H6 H 0.194256 0.271409 1.015602 0.051 Uiso 1 1 calc R U . . .
C7 C 0.3453(4) 0.3176(3) 1.0033(2) 0.0362(9) Uani 1 1 d . U . . .
H7 H 0.387134 0.258352 1.013812 0.043 Uiso 1 1 calc R U . . .
C8 C 0.3998(4) 0.3960(3) 0.98637(17) 0.0276(8) Uani 1 1 d . U . . .
C9 C 0.5248(4) 0.3898(3) 0.98475(17) 0.0265(8) Uani 1 1 d . U . . .
H9 H 0.549865 0.319904 0.981468 0.032 Uiso 1 1 calc R U . . .
C10 C 0.5459(4) 0.4394(3) 0.93060(17) 0.0276(8) Uani 1 1 d . U . . .
C11 C 0.6221(4) 0.3998(4) 0.89583(19) 0.0364(9) Uani 1 1 d . U . . .
H11 H 0.658507 0.337730 0.904716 0.044 Uiso 1 1 calc R U . . .
C12 C 0.6456(4) 0.4501(4) 0.8482(2) 0.0451(10) Uani 1 1 d . U . . .
H12 H 0.697918 0.422599 0.824614 0.054 Uiso 1 1 calc R U . . .
C13 C 0.5929(4) 0.5400(4) 0.8353(2) 0.0446(10) Uani 1 1 d . U . . .
H13 H 0.610153 0.575207 0.803217 0.053 Uiso 1 1 calc R U . . .
C14 C 0.5146(4) 0.5797(4) 0.86905(18) 0.0357(9) Uani 1 1 d . U . . .
H14 H 0.478470 0.641780 0.859812 0.043 Uiso 1 1 calc R U . . .
C15 C 0.4888(3) 0.5292(3) 0.91609(16) 0.0267(7) Uani 1 1 d . U . . .
C16 C 0.2914(13) 0.4943(10) 0.7904(4) 0.0504(16) Uani 0.529(10) 1 d D U P A 1
H16A H 0.230618 0.496498 0.757001 0.061 Uiso 0.529(10) 1 calc R U P A 1
H16B H 0.348792 0.537522 0.781525 0.061 Uiso 0.529(10) 1 calc R U P A 1
C17 C 0.3412(11) 0.3974(8) 0.7970(5) 0.066(3) Uani 0.529(10) 1 d D U P A 1
H17A H 0.413424 0.397629 0.822154 0.100 Uiso 0.529(10) 1 calc R U P A 1
H17B H 0.353023 0.371172 0.758765 0.100 Uiso 0.529(10) 1 calc R U P A 1
H17C H 0.291140 0.357085 0.814433 0.100 Uiso 0.529(10) 1 calc R U P A 1
C16' C 0.2766(12) 0.4879(14) 0.7885(4) 0.0508(17) Uani 0.471(10) 1 d D U P A 2
H16C H 0.334029 0.526357 0.774855 0.061 Uiso 0.471(10) 1 calc R U P A 2
H16D H 0.310837 0.421615 0.796791 0.061 Uiso 0.471(10) 1 calc R U P A 2
C17' C 0.1841(11) 0.4834(10) 0.7432(4) 0.063(3) Uani 0.471(10) 1 d D U P A 2
H17D H 0.129693 0.440910 0.755054 0.094 Uiso 0.471(10) 1 calc R U P A 2
H17E H 0.211112 0.457743 0.707780 0.094 Uiso 0.471(10) 1 calc R U P A 2
H17F H 0.148046 0.548416 0.735610 0.094 Uiso 0.471(10) 1 calc R U P A 2
C18 C 0.0221(4) 0.6452(5) 0.8312(2) 0.0527(12) Uani 1 1 d D U . . .
H18A H 0.004474 0.703311 0.806375 0.063 Uiso 1 1 calc R U . . .
H18B H 0.041219 0.589955 0.806211 0.063 Uiso 1 1 calc R U . . .
C19 C -0.0737(5) 0.6257(7) 0.8579(3) 0.098(2) Uani 1 1 d D U . . .
H19A H -0.064498 0.559624 0.873284 0.147 Uiso 1 1 calc R U . . .
H19B H -0.141189 0.632396 0.829004 0.147 Uiso 1 1 calc R U . . .
H19C H -0.081339 0.671636 0.889721 0.147 Uiso 1 1 calc R U . . .
C20 C 0.0149(4) 0.9303(3) 0.87111(17) 0.0287(9) Uani 1 1 d . U . . .
H20A H -0.065308 0.929187 0.854756 0.034 Uiso 1 1 calc R U . . .
H20B H 0.044067 0.862056 0.877072 0.034 Uiso 1 1 calc R U . . .
C21 C 0.0194(3) 0.9775(3) 0.93182(16) 0.0243(8) Uani 1 1 d . U . . .
C22 C 0.1393(3) 0.9748(3) 0.96383(16) 0.0244(8) Uani 1 1 d . U . . .
C23 C 0.2303(3) 0.9206(3) 0.94629(17) 0.0290(9) Uani 1 1 d . U . . .
H23 H 0.219440 0.880291 0.912934 0.035 Uiso 1 1 calc R U . . .
C24 C 0.3373(4) 0.9252(3) 0.97734(19) 0.0347(10) Uani 1 1 d . U . . .
H24 H 0.399199 0.889275 0.964373 0.042 Uiso 1 1 calc R U . . .
C25 C 0.3539(4) 0.9806(4) 1.0261(2) 0.0367(10) Uani 1 1 d . U . . .
H25 H 0.426998 0.982593 1.047311 0.044 Uiso 1 1 calc R U . . .
C26 C 0.2635(4) 1.0346(3) 1.04493(18) 0.0322(9) Uani 1 1 d . U . . .
H26 H 0.275318 1.074158 1.078591 0.039 Uiso 1 1 calc R U . . .
C27 C 0.1571(3) 1.0305(3) 1.01465(17) 0.0259(8) Uani 1 1 d . U . . .
C28 C 0.0573(3) 1.0878(3) 1.03335(17) 0.0252(8) Uani 1 1 d . U . . .
H28 H 0.086636 1.139432 1.060544 0.030 Uiso 1 1 calc R U . . .
C29 C -0.0089(3) 1.1369(3) 0.98113(17) 0.0250(8) Uani 1 1 d . U . . .
C30 C -0.0486(4) 1.2330(3) 0.98299(19) 0.0310(9) Uani 1 1 d . U . . .
H30 H -0.033882 1.268998 1.017936 0.037 Uiso 1 1 calc R U . . .
C31 C -0.1094(4) 1.2768(3) 0.9342(2) 0.0385(10) Uani 1 1 d . U . . .
H31 H -0.135469 1.342963 0.935201 0.046 Uiso 1 1 calc R U . . .
C32 C -0.1319(4) 1.2227(4) 0.8839(2) 0.0399(11) Uani 1 1 d . U . . .
H32 H -0.174790 1.251727 0.850410 0.048 Uiso 1 1 calc R U . . .
C33 C -0.0924(4) 1.1270(3) 0.88215(18) 0.0322(9) Uani 1 1 d . U . . .
H33 H -0.109533 1.090732 0.847515 0.039 Uiso 1 1 calc R U . . .
C34 C -0.0286(3) 1.0833(3) 0.92973(17) 0.0254(8) Uani 1 1 d . U . . .
C35 C -0.0120(5) 1.0592(4) 0.7163(2) 0.0528(13) Uani 1 1 d D U . . .
H35A H 0.053023 1.034982 0.697251 0.063 Uiso 1 1 calc R U . . .
H35B H -0.003603 1.128210 0.726336 0.063 Uiso 1 1 calc R U . . .
C36 C -0.1150(6) 1.0493(5) 0.6774(3) 0.084(2) Uani 1 1 d D U . . .
H36A H -0.123280 0.980745 0.668190 0.126 Uiso 1 1 calc R U . . .
H36B H -0.112857 1.085194 0.641544 0.126 Uiso 1 1 calc R U . . .
H36C H -0.178778 1.075116 0.696170 0.126 Uiso 1 1 calc R U . . .
C37 C 0.2525(4) 1.0909(4) 0.8435(3) 0.0600(15) Uani 1 1 d D U . . .
H37A H 0.295629 1.031509 0.859605 0.072 Uiso 1 1 calc R U . . .
H37B H 0.276405 1.104491 0.805507 0.072 Uiso 1 1 calc R U . . .
C38 C 0.2753(7) 1.1703(6) 0.8823(4) 0.112(3) Uani 1 1 d D U . . .
H38A H 0.231117 1.228575 0.866753 0.168 Uiso 1 1 calc R U . . .
H38B H 0.355374 1.181429 0.886340 0.168 Uiso 1 1 calc R U . . .
H38C H 0.254925 1.155268 0.920475 0.168 Uiso 1 1 calc R U . . .
C39 C 0.4997(3) 0.9530(3) 0.63344(16) 0.0270(8) Uani 1 1 d . U . . .
H39A H 0.581015 0.944054 0.647634 0.032 Uiso 1 1 calc R U . . .
H39B H 0.470912 0.887700 0.630491 0.032 Uiso 1 1 calc R U . . .
C40 C 0.4886(3) 0.9926(3) 0.57077(17) 0.0252(7) Uani 1 1 d . U . . .
C41 C 0.3674(3) 1.0077(3) 0.54223(17) 0.0250(7) Uani 1 1 d . U . . .
C42 C 0.2774(3) 0.9698(3) 0.56404(18) 0.0291(8) Uani 1 1 d . U . . .
H42 H 0.290352 0.931653 0.598341 0.035 Uiso 1 1 calc R U . . .
C43 C 0.1690(4) 0.9878(4) 0.5356(2) 0.0367(9) Uani 1 1 d . U . . .
H43 H 0.107863 0.962983 0.551002 0.044 Uiso 1 1 calc R U . . .
C44 C 0.1494(4) 1.0411(4) 0.4854(2) 0.0375(9) Uani 1 1 d . U . . .
H44 H 0.074723 1.054314 0.466765 0.045 Uiso 1 1 calc R U . . .
C45 C 0.2386(4) 1.0758(3) 0.46193(19) 0.0324(9) Uani 1 1 d . U . . .
H45 H 0.225156 1.111878 0.426841 0.039 Uiso 1 1 calc R U . . .
C46 C 0.3477(3) 1.0577(3) 0.48974(17) 0.0262(7) Uani 1 1 d . U . . .
C47 C 0.4472(3) 1.0922(3) 0.46469(17) 0.0265(8) Uani 1 1 d . U . . .
H47 H 0.418363 1.145076 0.436452 0.032 Uiso 1 1 calc R U . . .
C48 C 0.5249(3) 1.1357(3) 0.51294(17) 0.0269(7) Uani 1 1 d . U . . .
C49 C 0.5775(4) 1.2194(3) 0.5045(2) 0.0336(9) Uani 1 1 d . U . . .
H49 H 0.563951 1.251044 0.467910 0.040 Uiso 1 1 calc R U . . .
C50 C 0.6495(4) 1.2566(4) 0.5495(2) 0.0406(9) Uani 1 1 d . U . . .
H50 H 0.686863 1.313089 0.543550 0.049 Uiso 1 1 calc R U . . .
C51 C 0.6672(4) 1.2116(4) 0.6033(2) 0.0415(10) Uani 1 1 d . U . . .
H51 H 0.714501 1.238461 0.634681 0.050 Uiso 1 1 calc R U . . .
C52 C 0.6160(4) 1.1278(3) 0.61124(19) 0.0338(9) Uani 1 1 d . U . . .
H52 H 0.629868 1.096684 0.648023 0.041 Uiso 1 1 calc R U . . .
C53 C 0.5446(3) 1.0877(3) 0.56657(17) 0.0262(7) Uani 1 1 d . U . . .
C54 C 0.2650(5) 1.1468(4) 0.6563(2) 0.0567(13) Uani 1 1 d D U . . .
H54A H 0.220147 1.091530 0.662497 0.068 Uiso 1 1 calc R U . . .
H54B H 0.246835 1.166721 0.615088 0.068 Uiso 1 1 calc R U . . .
C55 C 0.2367(6) 1.2276(5) 0.6942(3) 0.080(2) Uani 1 1 d D U . . .
H55A H 0.238778 1.203972 0.733969 0.120 Uiso 1 1 calc R U . . .
H55B H 0.161260 1.256055 0.680149 0.120 Uiso 1 1 calc R U . . .
H55C H 0.291198 1.276825 0.693838 0.120 Uiso 1 1 calc R U . . .
C56 C 0.5295(6) 1.0894(6) 0.7871(2) 0.0762(16) Uani 1 1 d D U . . .
H56A H 0.462377 1.135386 0.780482 0.091 Uiso 1 1 calc R U . . .
H56B H 0.517173 1.042857 0.817199 0.091 Uiso 1 1 calc R U . . .
C57 C 0.6227(8) 1.1401(8) 0.8073(4) 0.143(3) Uani 1 1 d D U . . .
H57A H 0.689841 1.095321 0.812794 0.214 Uiso 1 1 calc R U . . .
H57B H 0.612046 1.170994 0.844518 0.214 Uiso 1 1 calc R U . . .
H57C H 0.631953 1.189755 0.779000 0.214 Uiso 1 1 calc R U . . .
C58 C 0.0654(5) 0.4160(4) 0.3810(2) 0.0508(13) Uani 1 1 d . U . . .
H58A H -0.001251 0.438444 0.353377 0.061 Uiso 1 1 calc R U . . .
H58B H 0.060857 0.345591 0.386061 0.061 Uiso 1 1 calc R U . . .
C59 C 0.0521(4) 0.4644(3) 0.4403(2) 0.0396(10) Uani 1 1 d . U . . .
C60 C 0.0511(4) 0.5749(3) 0.4377(2) 0.0410(10) Uani 1 1 d . U . . .
C61 C 0.0408(5) 0.6279(4) 0.3871(3) 0.0519(13) Uani 1 1 d . U . . .
H61 H 0.033324 0.595390 0.350665 0.062 Uiso 1 1 calc R U . . .
C62 C 0.0413(5) 0.7268(4) 0.3885(3) 0.0621(15) Uani 1 1 d . U . . .
H62 H 0.035000 0.761890 0.353208 0.075 Uiso 1 1 calc R U . . .
C63 C 0.0510(5) 0.7757(4) 0.4408(3) 0.0598(14) Uani 1 1 d . U . . .
H63 H 0.050572 0.844271 0.441530 0.072 Uiso 1 1 calc R U . . .
C64 C 0.0612(5) 0.7247(4) 0.4918(3) 0.0514(13) Uani 1 1 d . U . . .
H64 H 0.068497 0.758075 0.527931 0.062 Uiso 1 1 calc R U . . .
C65 C 0.0608(4) 0.6241(3) 0.4908(2) 0.0405(10) Uani 1 1 d . U . . .
C66 C 0.0702(4) 0.5662(3) 0.5457(2) 0.0404(11) Uani 1 1 d . U . . .
H66 H 0.102702 0.607486 0.578518 0.048 Uiso 1 1 calc R U . . .
C67 C 0.1520(4) 0.4804(4) 0.5409(2) 0.0428(11) Uani 1 1 d . U . . .
C68 C 0.2368(5) 0.4545(5) 0.5861(3) 0.0611(14) Uani 1 1 d . U . . .
H68 H 0.245661 0.491985 0.620741 0.073 Uiso 1 1 calc R U . . .
C69 C 0.3087(5) 0.3728(5) 0.5801(3) 0.0748(17) Uani 1 1 d . U . . .
H69 H 0.367527 0.355173 0.610425 0.090 Uiso 1 1 calc R U . . .
C70 C 0.2947(5) 0.3181(5) 0.5306(3) 0.0729(17) Uani 1 1 d . U . . .
H70 H 0.342131 0.261127 0.527373 0.087 Uiso 1 1 calc R U . . .
C71 C 0.2124(5) 0.3450(4) 0.4854(3) 0.0575(14) Uani 1 1 d . U . . .
H71 H 0.203340 0.306035 0.451333 0.069 Uiso 1 1 calc R U . . .
C72 C 0.1422(4) 0.4284(3) 0.4888(2) 0.0415(10) Uani 1 1 d . U . . .
C73 C 0.3833(7) 0.4899(17) 0.3805(7) 0.089(3) Uani 0.514(11) 1 d D U P B .
H73A H 0.424235 0.522139 0.414438 0.107 Uiso 0.514(11) 1 calc R U P . .
H73B H 0.412037 0.421159 0.381519 0.107 Uiso 0.514(11) 1 calc R U P . .
C74 C 0.4121(12) 0.5324(11) 0.3289(6) 0.089(4) Uani 0.514(11) 1 d D U P . .
H74A H 0.380062 0.496524 0.294679 0.134 Uiso 0.514(11) 1 calc R U P . .
H74B H 0.493974 0.529791 0.330744 0.134 Uiso 0.514(11) 1 calc R U P . .
H74C H 0.381985 0.599978 0.325977 0.134 Uiso 0.514(11) 1 calc R U P . .
C73' C 0.3863(7) 0.5002(19) 0.4000(6) 0.091(3) Uani 0.486(11) 1 d D U P B 2
H73C H 0.422361 0.450308 0.376569 0.109 Uiso 0.486(11) 1 calc R U P B 2
H73D H 0.403498 0.564018 0.386061 0.109 Uiso 0.486(11) 1 calc R U P B 2
C74' C 0.4382(10) 0.4896(11) 0.4594(6) 0.085(4) Uani 0.486(11) 1 d D U P B 2
H74D H 0.411020 0.543368 0.482598 0.128 Uiso 0.486(11) 1 calc R U P B 2
H74E H 0.519861 0.489811 0.461111 0.128 Uiso 0.486(11) 1 calc R U P B 2
H74F H 0.419122 0.428309 0.474863 0.128 Uiso 0.486(11) 1 calc R U P B 2
C75 C 0.2941(7) 0.2822(5) 0.2966(3) 0.088(2) Uani 1 1 d D U . . .
H75A H 0.287861 0.329385 0.264447 0.105 Uiso 1 1 calc R U . . .
H75B H 0.374758 0.263364 0.308233 0.105 Uiso 1 1 calc R U . . .
C76 C 0.2373(6) 0.1985(5) 0.2765(3) 0.086(2) Uani 1 1 d D U . . .
H76A H 0.245651 0.150541 0.307763 0.129 Uiso 1 1 calc R U . . .
H76B H 0.269716 0.170693 0.243094 0.129 Uiso 1 1 calc R U . . .
H76C H 0.157397 0.216812 0.264850 0.129 Uiso 1 1 calc R U . . .
C77 C 0.0116(13) 0.6581(11) 0.2173(6) 0.193(4) Uani 1 1 d . U . . .
H77A H -0.019057 0.725204 0.219348 0.290 Uiso 1 1 calc R U . . .
H77B H -0.027138 0.616981 0.240938 0.290 Uiso 1 1 calc R U . . .
H77C H 0.000725 0.635925 0.176814 0.290 Uiso 1 1 calc R U . . .
N1 N 0.0812(4) 0.8178(3) 0.66879(16) 0.0382(9) Uani 1 1 d . . . . .
N2 N 0.3628(4) 0.6876(3) 0.65867(19) 0.0518(11) Uani 1 1 d . U . . .
N3 N 0.5000(3) 0.8294(3) 0.82088(18) 0.0450(10) Uani 1 1 d . . . . .
O1 O 0.2686(3) 0.7032(2) 0.81453(13) 0.0372(7) Uani 1 1 d . U . . .
O2 O 0.2454(3) 0.5304(2) 0.84191(13) 0.0418(7) Uani 1 1 d D U . . .
O3 O 0.1183(3) 0.6611(2) 0.87523(13) 0.0373(7) Uani 1 1 d D U . . .
O4 O 0.1719(3) 0.9093(3) 0.79633(13) 0.0413(8) Uani 1 1 d . U . . .
O5 O -0.0162(3) 1.0041(3) 0.76816(13) 0.0431(8) Uani 1 1 d D U . . .
O6 O 0.1338(3) 1.0760(3) 0.83568(15) 0.0463(8) Uani 1 1 d D U . . .
O7 O 0.3554(3) 0.9591(2) 0.71587(12) 0.0329(7) Uani 1 1 d . U . . .
O8 O 0.3831(3) 1.1178(2) 0.66918(15) 0.0466(8) Uani 1 1 d D U . . .
O9 O 0.5414(3) 1.0377(3) 0.73388(14) 0.0518(9) Uani 1 1 d D U . . .
O10 O 0.1494(3) 0.8819(3) 0.66850(14) 0.0416(8) Uani 1 1 d . . . . .
O11 O 0.1099(4) 0.7522(3) 0.70564(19) 0.0701(13) Uani 1 1 d . . . . .
O12 O -0.0061(3) 0.8193(3) 0.63539(18) 0.0630(11) Uani 1 1 d . . . . .
O13 O 0.3600(4) 0.7758(2) 0.65532(14) 0.0507(10) Uani 1 1 d . U . . .
O14 O 0.3346(5) 0.6556(3) 0.7045(2) 0.0810(15) Uani 1 1 d . U . . .
O15 O 0.3929(5) 0.6349(3) 0.6211(2) 0.0929(18) Uani 1 1 d . U . . .
O16 O 0.4100(3) 0.8695(3) 0.83472(14) 0.0460(9) Uani 1 1 d . . . . .
O17 O 0.4917(3) 0.7816(3) 0.77426(15) 0.0477(9) Uani 1 1 d . . . . .
O18 O 0.5904(4) 0.8366(4) 0.8510(2) 0.0815(15) Uani 1 1 d . . . . .
O19 O 0.1596(5) 0.4729(4) 0.2868(2) 0.0921(17) Uani 1 1 d . U . . .
O20 O 0.2663(4) 0.4932(4) 0.3881(2) 0.0891(14) Uani 1 1 d D U . . .
O21 O 0.2484(5) 0.3276(3) 0.3455(2) 0.0892(15) Uani 1 1 d D U . . .
O22 O 0.1314(9) 0.6524(8) 0.2393(5) 0.194(4) Uani 1 1 d . U . . .
H22 H 0.148562 0.601000 0.258226 0.291 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O4 2.295(3) . ?
Dy1 O1 2.302(3) . ?
Dy1 O7 2.328(3) . ?
Dy1 O13 2.414(3) . ?
Dy1 O10 2.433(3) . ?
Dy1 O17 2.441(3) . ?
Dy1 O14 2.464(4) . ?
Dy1 O11 2.464(4) . ?
Dy1 O16 2.487(3) . ?
P1 O1 1.478(3) . ?
P1 O2 1.550(3) . ?
P1 O3 1.574(3) . ?
P1 C1 1.806(4) . ?
P2 O4 1.479(3) . ?
P2 O6 1.541(4) . ?
P2 O5 1.561(3) . ?
P2 C20 1.804(4) . ?
P3 O7 1.483(3) . ?
P3 O8 1.559(4) . ?
P3 O9 1.566(4) . ?
P3 C39 1.798(4) . ?
P4 O19 1.468(5) . ?
P4 O21 1.564(5) . ?
P4 O20 1.569(6) . ?
P4 C58 1.817(5) . ?
C1 C2 1.551(5) . ?
C1 H1A 0.9900 . ?
C1 H1B 0.9900 . ?
C2 C3 1.525(6) . ?
C2 C15 1.536(5) . ?
C2 C9 1.638(6) 2_667 ?
C3 C4 1.390(6) . ?
C3 C8 1.394(6) . ?
C4 C5 1.388(6) . ?
C4 H4 0.9500 . ?
C5 C6 1.379(7) . ?
C5 H5 0.9500 . ?
C6 C7 1.380(7) . ?
C6 H6 0.9500 . ?
C7 C8 1.396(6) . ?
C7 H7 0.9500 . ?
C8 C9 1.509(6) . ?
C9 C10 1.501(5) . ?
C9 H9 1.0000 . ?
C10 C11 1.387(6) . ?
C10 C15 1.400(6) . ?
C11 C12 1.385(7) . ?
C11 H11 0.9500 . ?
C12 C13 1.376(7) . ?
C12 H12 0.9500 . ?
C13 C14 1.390(6) . ?
C13 H13 0.9500 . ?
C14 C15 1.387(6) . ?
C14 H14 0.9500 . ?
C16 C17 1.434(8) . ?
C16 O2 1.456(7) . ?
C16 H16A 0.9900 . ?
C16 H16B 0.9900 . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C16' C17' 1.428(8) . ?
C16' O2 1.453(7) . ?
C16' H16C 0.9900 . ?
C16' H16D 0.9900 . ?
C17' H17D 0.9800 . ?
C17' H17E 0.9800 . ?
C17' H17F 0.9800 . ?
C18 C19 1.428(6) . ?
C18 O3 1.463(5) . ?
C18 H18A 0.9900 . ?
C18 H18B 0.9900 . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C20 C21 1.544(5) . ?
C20 H20A 0.9900 . ?
C20 H20B 0.9900 . ?
C21 C22 1.529(6) . ?
C21 C34 1.538(6) . ?
C21 C28 1.633(5) 2_577 ?
C22 C23 1.392(5) . ?
C22 C27 1.403(6) . ?
C23 C24 1.393(6) . ?
C23 H23 0.9500 . ?
C24 C25 1.361(7) . ?
C24 H24 0.9500 . ?
C25 C26 1.397(6) . ?
C25 H25 0.9500 . ?
C26 C27 1.380(6) . ?
C26 H26 0.9500 . ?
C27 C28 1.507(5) . ?
C28 C29 1.499(6) . ?
C28 H28 1.0000 . ?
C29 C30 1.386(6) . ?
C29 C34 1.400(6) . ?
C30 C31 1.383(6) . ?
C30 H30 0.9500 . ?
C31 C32 1.386(7) . ?
C31 H31 0.9500 . ?
C32 C33 1.379(6) . ?
C32 H32 0.9500 . ?
C33 C34 1.377(6) . ?
C33 H33 0.9500 . ?
C35 O5 1.443(5) . ?
C35 C36 1.444(6) . ?
C35 H35A 0.9900 . ?
C35 H35B 0.9900 . ?
C36 H36A 0.9800 . ?
C36 H36B 0.9800 . ?
C36 H36C 0.9800 . ?
C37 C38 1.432(6) . ?
C37 O6 1.447(5) . ?
C37 H37A 0.9900 . ?
C37 H37B 0.9900 . ?
C38 H38A 0.9800 . ?
C38 H38B 0.9800 . ?
C38 H38C 0.9800 . ?
C39 C40 1.547(5) . ?
C39 H39A 0.9900 . ?
C39 H39B 0.9900 . ?
C40 C41 1.521(5) . ?
C40 C53 1.531(6) . ?
C40 C47 1.640(5) 2_676 ?
C41 C46 1.393(6) . ?
C41 C42 1.395(6) . ?
C42 C43 1.388(6) . ?
C42 H42 0.9500 . ?
C43 C44 1.370(7) . ?
C43 H43 0.9500 . ?
C44 C45 1.389(6) . ?
C44 H44 0.9500 . ?
C45 C46 1.390(6) . ?
C45 H45 0.9500 . ?
C46 C47 1.512(5) . ?
C47 C48 1.506(6) . ?
C47 H47 1.0000 . ?
C48 C49 1.388(6) . ?
C48 C53 1.402(6) . ?
C49 C50 1.382(7) . ?
C49 H49 0.9500 . ?
C50 C51 1.387(7) . ?
C50 H50 0.9500 . ?
C51 C52 1.378(7) . ?
C51 H51 0.9500 . ?
C52 C53 1.390(6) . ?
C52 H52 0.9500 . ?
C54 O8 1.444(5) . ?
C54 C55 1.469(6) . ?
C54 H54A 0.9900 . ?
C54 H54B 0.9900 . ?
C55 H55A 0.9800 . ?
C55 H55B 0.9800 . ?
C55 H55C 0.9800 . ?
C56 C57 1.391(7) . ?
C56 O9 1.441(5) . ?
C56 H56A 0.9900 . ?
C56 H56B 0.9900 . ?
C57 H57A 0.9800 . ?
C57 H57B 0.9800 . ?
C57 H57C 0.9800 . ?
C58 C59 1.549(7) . ?
C58 H58A 0.9900 . ?
C58 H58B 0.9900 . ?
C59 C72 1.516(7) . ?
C59 C60 1.532(6) . ?
C59 C66 1.639(6) 2_566 ?
C60 C61 1.380(7) . ?
C60 C65 1.397(7) . ?
C61 C62 1.370(8) . ?
C61 H61 0.9500 . ?
C62 C63 1.379(9) . ?
C62 H62 0.9500 . ?
C63 C64 1.373(8) . ?
C63 H63 0.9500 . ?
C64 C65 1.394(7) . ?
C64 H64 0.9500 . ?
C65 C66 1.501(7) . ?
C66 C67 1.504(7) . ?
C66 H66 1.0000 . ?
C67 C68 1.393(8) . ?
C67 C72 1.397(7) . ?
C68 C69 1.395(9) . ?
C68 H68 0.9500 . ?
C69 C70 1.368(10) . ?
C69 H69 0.9500 . ?
C70 C71 1.377(9) . ?
C70 H70 0.9500 . ?
C71 C72 1.394(7) . ?
C71 H71 0.9500 . ?
C73 C74 1.438(8) . ?
C73 O20 1.443(7) . ?
C73 H73A 0.9900 . ?
C73 H73B 0.9900 . ?
C74 H74A 0.9800 . ?
C74 H74B 0.9800 . ?
C74 H74C 0.9800 . ?
C73' C74' 1.438(8) . ?
C73' O20 1.445(7) . ?
C73' H73C 0.9900 . ?
C73' H73D 0.9900 . ?
C74' H74D 0.9800 . ?
C74' H74E 0.9800 . ?
C74' H74F 0.9800 . ?
C75 C76 1.429(7) . ?
C75 O21 1.449(5) . ?
C75 H75A 0.9900 . ?
C75 H75B 0.9900 . ?
C76 H76A 0.9800 . ?
C76 H76B 0.9800 . ?
C76 H76C 0.9800 . ?
C77 O22 1.461(16) . ?
C77 H77A 0.9800 . ?
C77 H77B 0.9800 . ?
C77 H77C 0.9800 . ?
N1 O12 1.217(5) . ?
N1 O10 1.252(5) . ?
N1 O11 1.253(5) . ?
N2 O15 1.211(5) . ?
N2 O13 1.224(5) . ?
N2 O14 1.256(5) . ?
N3 O18 1.220(6) . ?
N3 O17 1.259(5) . ?
N3 O16 1.265(5) . ?
O22 H22 0.8400 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O4 Dy1 O1 82.14(12) . . ?
O4 Dy1 O7 87.66(11) . . ?
O1 Dy1 O7 153.17(11) . . ?
O4 Dy1 O13 149.48(12) . . ?
O1 Dy1 O13 123.64(11) . . ?
O7 Dy1 O13 75.08(10) . . ?
O4 Dy1 O10 77.67(11) . . ?
O1 Dy1 O10 127.58(11) . . ?
O7 Dy1 O10 73.43(11) . . ?
O13 Dy1 O10 73.40(13) . . ?
O4 Dy1 O17 126.22(12) . . ?
O1 Dy1 O17 85.72(12) . . ?
O7 Dy1 O17 80.43(12) . . ?
O13 Dy1 O17 76.14(13) . . ?
O10 Dy1 O17 143.90(11) . . ?
O4 Dy1 O14 146.64(14) . . ?
O1 Dy1 O14 73.01(12) . . ?
O7 Dy1 O14 124.04(11) . . ?
O13 Dy1 O14 50.83(12) . . ?
O10 Dy1 O14 100.05(16) . . ?
O17 Dy1 O14 74.44(16) . . ?
O4 Dy1 O11 80.22(15) . . ?
O1 Dy1 O11 78.13(12) . . ?
O7 Dy1 O11 124.53(11) . . ?
O13 Dy1 O11 88.99(16) . . ?
O10 Dy1 O11 51.12(12) . . ?
O17 Dy1 O11 146.89(14) . . ?
O14 Dy1 O11 73.26(18) . . ?
O4 Dy1 O16 74.61(11) . . ?
O1 Dy1 O16 76.10(12) . . ?
O7 Dy1 O16 77.29(11) . . ?
O13 Dy1 O16 123.90(13) . . ?
O10 Dy1 O16 140.09(12) . . ?
O17 Dy1 O16 51.63(11) . . ?
O14 Dy1 O16 118.82(16) . . ?
O11 Dy1 O16 145.98(14) . . ?
O1 P1 O2 113.25(18) . . ?
O1 P1 O3 113.08(18) . . ?
O2 P1 O3 104.97(19) . . ?
O1 P1 C1 112.3(2) . . ?
O2 P1 C1 109.88(18) . . ?
O3 P1 C1 102.61(18) . . ?
O4 P2 O6 112.6(2) . . ?
O4 P2 O5 113.93(18) . . ?
O6 P2 O5 106.2(2) . . ?
O4 P2 C20 112.8(2) . . ?
O6 P2 C20 110.53(19) . . ?
O5 P2 C20 99.92(19) . . ?
O7 P3 O8 112.22(19) . . ?
O7 P3 O9 112.85(19) . . ?
O8 P3 O9 104.2(2) . . ?
O7 P3 C39 114.01(19) . . ?
O8 P3 C39 111.48(19) . . ?
O9 P3 C39 101.12(19) . . ?
O19 P4 O21 113.3(3) . . ?
O19 P4 O20 113.8(3) . . ?
O21 P4 O20 105.9(3) . . ?
O19 P4 C58 113.2(3) . . ?
O21 P4 C58 104.4(3) . . ?
O20 P4 C58 105.5(3) . . ?
C2 C1 P1 119.8(3) . . ?
C2 C1 H1A 107.4 . . ?
P1 C1 H1A 107.4 . . ?
C2 C1 H1B 107.4 . . ?
P1 C1 H1B 107.4 . . ?
H1A C1 H1B 106.9 . . ?
C3 C2 C15 108.4(3) . . ?
C3 C2 C1 112.5(3) . . ?
C15 C2 C1 112.3(3) . . ?
C3 C2 C9 109.3(3) . 2_667 ?
C15 C2 C9 108.2(3) . 2_667 ?
C1 C2 C9 105.9(3) . 2_667 ?
C4 C3 C8 118.5(4) . . ?
C4 C3 C2 124.1(4) . . ?
C8 C3 C2 117.4(4) . . ?
C5 C4 C3 121.3(4) . . ?
C5 C4 H4 119.4 . . ?
C3 C4 H4 119.4 . . ?
C6 C5 C4 119.7(4) . . ?
C6 C5 H5 120.1 . . ?
C4 C5 H5 120.1 . . ?
C5 C6 C7 119.9(4) . . ?
C5 C6 H6 120.0 . . ?
C7 C6 H6 120.0 . . ?
C6 C7 C8 120.6(4) . . ?
C6 C7 H7 119.7 . . ?
C8 C7 H7 119.7 . . ?
C3 C8 C7 120.0(4) . . ?
C3 C8 C9 118.2(4) . . ?
C7 C8 C9 121.7(4) . . ?
C10 C9 C8 108.1(3) . . ?
C10 C9 C2 112.9(3) . 2_667 ?
C8 C9 C2 112.7(3) . 2_667 ?
C10 C9 H9 107.6 . . ?
C8 C9 H9 107.6 . . ?
C2 C9 H9 107.6 2_667 . ?
C11 C10 C15 119.7(4) . . ?
C11 C10 C9 121.7(4) . . ?
C15 C10 C9 118.6(3) . . ?
C12 C11 C10 120.5(4) . . ?
C12 C11 H11 119.7 . . ?
C10 C11 H11 119.7 . . ?
C13 C12 C11 119.8(4) . . ?
C13 C12 H12 120.1 . . ?
C11 C12 H12 120.1 . . ?
C12 C13 C14 120.3(4) . . ?
C12 C13 H13 119.8 . . ?
C14 C13 H13 119.8 . . ?
C15 C14 C13 120.4(4) . . ?
C15 C14 H14 119.8 . . ?
C13 C14 H14 119.8 . . ?
C14 C15 C10 119.2(4) . . ?
C14 C15 C2 124.0(4) . . ?
C10 C15 C2 116.7(3) . . ?
C17 C16 O2 113.2(9) . . ?
C17 C16 H16A 108.9 . . ?
O2 C16 H16A 108.9 . . ?
C17 C16 H16B 108.9 . . ?
O2 C16 H16B 108.9 . . ?
H16A C16 H16B 107.8 . . ?
C16 C17 H17A 109.5 . . ?
C16 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C16 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C17' C16' O2 113.4(9) . . ?
C17' C16' H16C 108.9 . . ?
O2 C16' H16C 108.9 . . ?
C17' C16' H16D 108.9 . . ?
O2 C16' H16D 108.9 . . ?
H16C C16' H16D 107.7 . . ?
C16' C17' H17D 109.5 . . ?
C16' C17' H17E 109.5 . . ?
H17D C17' H17E 109.5 . . ?
C16' C17' H17F 109.5 . . ?
H17D C17' H17F 109.5 . . ?
H17E C17' H17F 109.5 . . ?
C19 C18 O3 110.8(5) . . ?
C19 C18 H18A 109.5 . . ?
O3 C18 H18A 109.5 . . ?
C19 C18 H18B 109.5 . . ?
O3 C18 H18B 109.5 . . ?
H18A C18 H18B 108.1 . . ?
C18 C19 H19A 109.5 . . ?
C18 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
C18 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C21 C20 P2 121.3(3) . . ?
C21 C20 H20A 107.0 . . ?
P2 C20 H20A 107.0 . . ?
C21 C20 H20B 107.0 . . ?
P2 C20 H20B 107.0 . . ?
H20A C20 H20B 106.8 . . ?
C22 C21 C34 107.9(3) . . ?
C22 C21 C20 111.8(3) . . ?
C34 C21 C20 113.0(3) . . ?
C22 C21 C28 109.9(3) . 2_577 ?
C34 C21 C28 109.6(3) . 2_577 ?
C20 C21 C28 104.7(3) . 2_577 ?
C23 C22 C27 118.5(4) . . ?
C23 C22 C21 124.6(4) . . ?
C27 C22 C21 116.9(3) . . ?
C22 C23 C24 120.4(4) . . ?
C22 C23 H23 119.8 . . ?
C24 C23 H23 119.8 . . ?
C25 C24 C23 120.5(4) . . ?
C25 C24 H24 119.7 . . ?
C23 C24 H24 119.7 . . ?
C24 C25 C26 120.0(4) . . ?
C24 C25 H25 120.0 . . ?
C26 C25 H25 120.0 . . ?
C27 C26 C25 120.0(4) . . ?
C27 C26 H26 120.0 . . ?
C25 C26 H26 120.0 . . ?
C26 C27 C22 120.5(4) . . ?
C26 C27 C28 121.7(4) . . ?
C22 C27 C28 117.8(4) . . ?
C29 C28 C27 108.8(3) . . ?
C29 C28 C21 112.5(3) . 2_577 ?
C27 C28 C21 112.9(3) . 2_577 ?
C29 C28 H28 107.5 . . ?
C27 C28 H28 107.5 . . ?
C21 C28 H28 107.5 2_577 . ?
C30 C29 C34 120.5(4) . . ?
C30 C29 C28 121.4(4) . . ?
C34 C29 C28 118.1(4) . . ?
C31 C30 C29 120.3(4) . . ?
C31 C30 H30 119.8 . . ?
C29 C30 H30 119.8 . . ?
C30 C31 C32 119.1(4) . . ?
C30 C31 H31 120.5 . . ?
C32 C31 H31 120.5 . . ?
C33 C32 C31 120.5(4) . . ?
C33 C32 H32 119.7 . . ?
C31 C32 H32 119.7 . . ?
C34 C33 C32 121.1(4) . . ?
C34 C33 H33 119.4 . . ?
C32 C33 H33 119.4 . . ?
C33 C34 C29 118.4(4) . . ?
C33 C34 C21 124.9(4) . . ?
C29 C34 C21 116.7(3) . . ?
O5 C35 C36 108.4(4) . . ?
O5 C35 H35A 110.0 . . ?
C36 C35 H35A 110.0 . . ?
O5 C35 H35B 110.0 . . ?
C36 C35 H35B 110.0 . . ?
H35A C35 H35B 108.4 . . ?
C35 C36 H36A 109.5 . . ?
C35 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
C35 C36 H36C 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
C38 C37 O6 109.9(5) . . ?
C38 C37 H37A 109.7 . . ?
O6 C37 H37A 109.7 . . ?
C38 C37 H37B 109.7 . . ?
O6 C37 H37B 109.7 . . ?
H37A C37 H37B 108.2 . . ?
C37 C38 H38A 109.5 . . ?
C37 C38 H38B 109.5 . . ?
H38A C38 H38B 109.5 . . ?
C37 C38 H38C 109.5 . . ?
H38A C38 H38C 109.5 . . ?
H38B C38 H38C 109.5 . . ?
C40 C39 P3 122.3(3) . . ?
C40 C39 H39A 106.7 . . ?
P3 C39 H39A 106.7 . . ?
C40 C39 H39B 106.7 . . ?
P3 C39 H39B 106.7 . . ?
H39A C39 H39B 106.6 . . ?
C41 C40 C53 107.9(3) . . ?
C41 C40 C39 113.0(3) . . ?
C53 C40 C39 113.5(3) . . ?
C41 C40 C47 108.8(3) . 2_676 ?
C53 C40 C47 109.3(3) . 2_676 ?
C39 C40 C47 104.1(3) . 2_676 ?
C46 C41 C42 119.1(4) . . ?
C46 C41 C40 117.2(3) . . ?
C42 C41 C40 123.6(4) . . ?
C43 C42 C41 119.9(4) . . ?
C43 C42 H42 120.0 . . ?
C41 C42 H42 120.0 . . ?
C44 C43 C42 120.7(4) . . ?
C44 C43 H43 119.7 . . ?
C42 C43 H43 119.7 . . ?
C43 C44 C45 119.9(4) . . ?
C43 C44 H44 120.0 . . ?
C45 C44 H44 120.0 . . ?
C44 C45 C46 120.0(4) . . ?
C44 C45 H45 120.0 . . ?
C46 C45 H45 120.0 . . ?
C45 C46 C41 120.1(4) . . ?
C45 C46 C47 121.5(4) . . ?
C41 C46 C47 118.3(4) . . ?
C48 C47 C46 108.7(3) . . ?
C48 C47 C40 112.4(3) . 2_676 ?
C46 C47 C40 113.0(3) . 2_676 ?
C48 C47 H47 107.5 . . ?
C46 C47 H47 107.5 . . ?
C40 C47 H47 107.5 2_676 . ?
C49 C48 C53 120.8(4) . . ?
C49 C48 C47 121.4(4) . . ?
C53 C48 C47 117.9(4) . . ?
C50 C49 C48 119.9(4) . . ?
C50 C49 H49 120.1 . . ?
C48 C49 H49 120.1 . . ?
C49 C50 C51 120.0(5) . . ?
C49 C50 H50 120.0 . . ?
C51 C50 H50 120.0 . . ?
C52 C51 C50 119.9(5) . . ?
C52 C51 H51 120.1 . . ?
C50 C51 H51 120.1 . . ?
C51 C52 C53 121.5(4) . . ?
C51 C52 H52 119.3 . . ?
C53 C52 H52 119.3 . . ?
C52 C53 C48 118.0(4) . . ?
C52 C53 C40 124.8(4) . . ?
C48 C53 C40 117.1(4) . . ?
O8 C54 C55 109.6(5) . . ?
O8 C54 H54A 109.8 . . ?
C55 C54 H54A 109.8 . . ?
O8 C54 H54B 109.8 . . ?
C55 C54 H54B 109.8 . . ?
H54A C54 H54B 108.2 . . ?
C54 C55 H55A 109.5 . . ?
C54 C55 H55B 109.5 . . ?
H55A C55 H55B 109.5 . . ?
C54 C55 H55C 109.5 . . ?
H55A C55 H55C 109.5 . . ?
H55B C55 H55C 109.5 . . ?
C57 C56 O9 112.8(6) . . ?
C57 C56 H56A 109.0 . . ?
O9 C56 H56A 109.0 . . ?
C57 C56 H56B 109.0 . . ?
O9 C56 H56B 109.0 . . ?
H56A C56 H56B 107.8 . . ?
C56 C57 H57A 109.5 . . ?
C56 C57 H57B 109.5 . . ?
H57A C57 H57B 109.5 . . ?
C56 C57 H57C 109.5 . . ?
H57A C57 H57C 109.5 . . ?
H57B C57 H57C 109.5 . . ?
C59 C58 P4 121.5(4) . . ?
C59 C58 H58A 107.0 . . ?
P4 C58 H58A 107.0 . . ?
C59 C58 H58B 107.0 . . ?
P4 C58 H58B 107.0 . . ?
H58A C58 H58B 106.7 . . ?
C72 C59 C60 108.5(4) . . ?
C72 C59 C58 113.0(4) . . ?
C60 C59 C58 112.5(4) . . ?
C72 C59 C66 109.2(4) . 2_566 ?
C60 C59 C66 109.2(4) . 2_566 ?
C58 C59 C66 104.4(4) . 2_566 ?
C61 C60 C65 118.7(5) . . ?
C61 C60 C59 124.6(5) . . ?
C65 C60 C59 116.7(4) . . ?
C62 C61 C60 121.0(6) . . ?
C62 C61 H61 119.5 . . ?
C60 C61 H61 119.5 . . ?
C61 C62 C63 120.6(6) . . ?
C61 C62 H62 119.7 . . ?
C63 C62 H62 119.7 . . ?
C64 C63 C62 119.6(5) . . ?
C64 C63 H63 120.2 . . ?
C62 C63 H63 120.2 . . ?
C63 C64 C65 120.3(5) . . ?
C63 C64 H64 119.9 . . ?
C65 C64 H64 119.9 . . ?
C64 C65 C60 119.9(5) . . ?
C64 C65 C66 121.6(5) . . ?
C60 C65 C66 118.5(4) . . ?
C65 C66 C67 108.1(4) . . ?
C65 C66 C59 112.3(4) . 2_566 ?
C67 C66 C59 112.8(4) . 2_566 ?
C65 C66 H66 107.8 . . ?
C67 C66 H66 107.8 . . ?
C59 C66 H66 107.8 2_566 . ?
C68 C67 C72 120.6(5) . . ?
C68 C67 C66 121.5(5) . . ?
C72 C67 C66 117.9(5) . . ?
C67 C68 C69 119.3(6) . . ?
C67 C68 H68 120.4 . . ?
C69 C68 H68 120.4 . . ?
C70 C69 C68 120.3(6) . . ?
C70 C69 H69 119.9 . . ?
C68 C69 H69 119.9 . . ?
C69 C70 C71 120.4(6) . . ?
C69 C70 H70 119.8 . . ?
C71 C70 H70 119.8 . . ?
C70 C71 C72 121.0(6) . . ?
C70 C71 H71 119.5 . . ?
C72 C71 H71 119.5 . . ?
C71 C72 C67 118.3(5) . . ?
C71 C72 C59 124.1(5) . . ?
C67 C72 C59 117.6(4) . . ?
C74 C73 O20 118.0(10) . . ?
C74 C73 H73A 107.8 . . ?
O20 C73 H73A 107.8 . . ?
C74 C73 H73B 107.8 . . ?
O20 C73 H73B 107.8 . . ?
H73A C73 H73B 107.1 . . ?
C73 C74 H74A 109.5 . . ?
C73 C74 H74B 109.5 . . ?
H74A C74 H74B 109.5 . . ?
C73 C74 H74C 109.5 . . ?
H74A C74 H74C 109.5 . . ?
H74B C74 H74C 109.5 . . ?
C74' C73' O20 117.5(10) . . ?
C74' C73' H73C 107.9 . . ?
O20 C73' H73C 107.9 . . ?
C74' C73' H73D 107.9 . . ?
O20 C73' H73D 107.9 . . ?
H73C C73' H73D 107.2 . . ?
C73' C74' H74D 109.5 . . ?
C73' C74' H74E 109.5 . . ?
H74D C74' H74E 109.5 . . ?
C73' C74' H74F 109.5 . . ?
H74D C74' H74F 109.5 . . ?
H74E C74' H74F 109.5 . . ?
C76 C75 O21 112.1(5) . . ?
C76 C75 H75A 109.2 . . ?
O21 C75 H75A 109.2 . . ?
C76 C75 H75B 109.2 . . ?
O21 C75 H75B 109.2 . . ?
H75A C75 H75B 107.9 . . ?
C75 C76 H76A 109.5 . . ?
C75 C76 H76B 109.5 . . ?
H76A C76 H76B 109.5 . . ?
C75 C76 H76C 109.5 . . ?
H76A C76 H76C 109.5 . . ?
H76B C76 H76C 109.5 . . ?
O22 C77 H77A 109.5 . . ?
O22 C77 H77B 109.5 . . ?
H77A C77 H77B 109.5 . . ?
O22 C77 H77C 109.5 . . ?
H77A C77 H77C 109.5 . . ?
H77B C77 H77C 109.5 . . ?
O12 N1 O10 122.2(4) . . ?
O12 N1 O11 122.8(5) . . ?
O10 N1 O11 115.1(4) . . ?
O15 N2 O13 122.4(4) . . ?
O15 N2 O14 122.4(5) . . ?
O13 N2 O14 115.2(4) . . ?
O18 N3 O17 121.5(5) . . ?
O18 N3 O16 122.0(5) . . ?
O17 N3 O16 116.5(4) . . ?
P1 O1 Dy1 172.3(2) . . ?
C16' O2 P1 128.0(9) . . ?
C16 O2 P1 123.3(7) . . ?
C18 O3 P1 119.2(3) . . ?
P2 O4 Dy1 166.9(2) . . ?
C35 O5 P2 124.9(3) . . ?
C37 O6 P2 123.0(3) . . ?
P3 O7 Dy1 153.55(18) . . ?
C54 O8 P3 126.5(3) . . ?
C56 O9 P3 120.6(4) . . ?
N1 O10 Dy1 97.7(3) . . ?
N1 O11 Dy1 96.1(3) . . ?
N2 O13 Dy1 98.7(2) . . ?
N2 O14 Dy1 95.3(3) . . ?
N3 O16 Dy1 94.7(3) . . ?
N3 O17 Dy1 97.1(3) . . ?
C73 O20 C73' 18.8(11) . . ?
C73 O20 P4 117.1(9) . . ?
C73' O20 P4 134.3(9) . . ?
C75 O21 P4 125.2(5) . . ?
C77 O22 H22 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O1 P1 C1 C2 -118.2(3) . . . . ?
O2 P1 C1 C2 8.8(4) . . . . ?
O3 P1 C1 C2 120.0(3) . . . . ?
P1 C1 C2 C3 -64.5(4) . . . . ?
P1 C1 C2 C15 58.1(4) . . . . ?
P1 C1 C2 C9 176.1(3) . . . 2_667 ?
C15 C2 C3 C4 -139.1(4) . . . . ?
C1 C2 C3 C4 -14.3(5) . . . . ?
C9 C2 C3 C4 103.1(4) 2_667 . . . ?
C15 C2 C3 C8 43.1(5) . . . . ?
C1 C2 C3 C8 167.9(3) . . . . ?
C9 C2 C3 C8 -74.7(4) 2_667 . . . ?
C8 C3 C4 C5 -1.1(6) . . . . ?
C2 C3 C4 C5 -178.9(4) . . . . ?
C3 C4 C5 C6 1.2(7) . . . . ?
C4 C5 C6 C7 0.0(8) . . . . ?
C5 C6 C7 C8 -1.3(7) . . . . ?
C4 C3 C8 C7 -0.2(6) . . . . ?
C2 C3 C8 C7 177.8(4) . . . . ?
C4 C3 C8 C9 -178.3(4) . . . . ?
C2 C3 C8 C9 -0.4(5) . . . . ?
C6 C7 C8 C3 1.4(7) . . . . ?
C6 C7 C8 C9 179.5(4) . . . . ?
C3 C8 C9 C10 -43.6(5) . . . . ?
C7 C8 C9 C10 138.3(4) . . . . ?
C3 C8 C9 C2 81.9(4) . . . 2_667 ?
C7 C8 C9 C2 -96.2(5) . . . 2_667 ?
C8 C9 C10 C11 -136.6(4) . . . . ?
C2 C9 C10 C11 97.9(5) 2_667 . . . ?
C8 C9 C10 C15 45.0(5) . . . . ?
C2 C9 C10 C15 -80.4(5) 2_667 . . . ?
C15 C10 C11 C12 2.7(7) . . . . ?
C9 C10 C11 C12 -175.7(4) . . . . ?
C10 C11 C12 C13 0.0(8) . . . . ?
C11 C12 C13 C14 -1.4(8) . . . . ?
C12 C13 C14 C15 0.1(8) . . . . ?
C13 C14 C15 C10 2.5(7) . . . . ?
C13 C14 C15 C2 179.2(4) . . . . ?
C11 C10 C15 C14 -3.9(7) . . . . ?
C9 C10 C15 C14 174.5(4) . . . . ?
C11 C10 C15 C2 179.2(4) . . . . ?
C9 C10 C15 C2 -2.4(6) . . . . ?
C3 C2 C15 C14 141.7(4) . . . . ?
C1 C2 C15 C14 16.7(6) . . . . ?
C9 C2 C15 C14 -99.8(5) 2_667 . . . ?
C3 C2 C15 C10 -41.6(5) . . . . ?
C1 C2 C15 C10 -166.5(4) . . . . ?
C9 C2 C15 C10 76.9(4) 2_667 . . . ?
O4 P2 C20 C21 119.6(3) . . . . ?
O6 P2 C20 C21 -7.4(4) . . . . ?
O5 P2 C20 C21 -119.0(3) . . . . ?
P2 C20 C21 C22 -62.3(4) . . . . ?
P2 C20 C21 C34 59.7(4) . . . . ?
P2 C20 C21 C28 178.9(3) . . . 2_577 ?
C34 C21 C22 C23 -136.7(4) . . . . ?
C20 C21 C22 C23 -11.9(5) . . . . ?
C28 C21 C22 C23 103.9(4) 2_577 . . . ?
C34 C21 C22 C27 43.9(4) . . . . ?
C20 C21 C22 C27 168.8(4) . . . . ?
C28 C21 C22 C27 -75.5(4) 2_577 . . . ?
C27 C22 C23 C24 -2.7(6) . . . . ?
C21 C22 C23 C24 178.0(4) . . . . ?
C22 C23 C24 C25 1.7(7) . . . . ?
C23 C24 C25 C26 -0.9(7) . . . . ?
C24 C25 C26 C27 1.1(7) . . . . ?
C25 C26 C27 C22 -2.1(7) . . . . ?
C25 C26 C27 C28 -179.8(4) . . . . ?
C23 C22 C27 C26 2.9(6) . . . . ?
C21 C22 C27 C26 -177.7(4) . . . . ?
C23 C22 C27 C28 -179.3(4) . . . . ?
C21 C22 C27 C28 0.1(5) . . . . ?
C26 C27 C28 C29 133.3(4) . . . . ?
C22 C27 C28 C29 -44.5(5) . . . . ?
C26 C27 C28 C21 -101.1(5) . . . 2_577 ?
C22 C27 C28 C21 81.2(4) . . . 2_577 ?
C27 C28 C29 C30 -135.0(4) . . . . ?
C21 C28 C29 C30 99.1(4) 2_577 . . . ?
C27 C28 C29 C34 44.2(5) . . . . ?
C21 C28 C29 C34 -81.7(4) 2_577 . . . ?
C34 C29 C30 C31 0.8(6) . . . . ?
C28 C29 C30 C31 180.0(4) . . . . ?
C29 C30 C31 C32 1.2(7) . . . . ?
C30 C31 C32 C33 -1.2(7) . . . . ?
C31 C32 C33 C34 -1.0(7) . . . . ?
C32 C33 C34 C29 2.9(7) . . . . ?
C32 C33 C34 C21 -179.7(4) . . . . ?
C30 C29 C34 C33 -2.9(6) . . . . ?
C28 C29 C34 C33 178.0(4) . . . . ?
C30 C29 C34 C21 179.6(4) . . . . ?
C28 C29 C34 C21 0.4(5) . . . . ?
C22 C21 C34 C33 138.4(4) . . . . ?
C20 C21 C34 C33 14.2(6) . . . . ?
C28 C21 C34 C33 -102.1(4) 2_577 . . . ?
C22 C21 C34 C29 -44.3(4) . . . . ?
C20 C21 C34 C29 -168.4(3) . . . . ?
C28 C21 C34 C29 75.3(4) 2_577 . . . ?
O7 P3 C39 C40 121.1(3) . . . . ?
O8 P3 C39 C40 -7.2(4) . . . . ?
O9 P3 C39 C40 -117.5(4) . . . . ?
P3 C39 C40 C41 -58.4(5) . . . . ?
P3 C39 C40 C53 64.9(4) . . . . ?
P3 C39 C40 C47 -176.3(3) . . . 2_676 ?
C53 C40 C41 C46 43.4(4) . . . . ?
C39 C40 C41 C46 169.8(3) . . . . ?
C47 C40 C41 C46 -75.1(4) 2_676 . . . ?
C53 C40 C41 C42 -140.4(4) . . . . ?
C39 C40 C41 C42 -14.0(5) . . . . ?
C47 C40 C41 C42 101.1(4) 2_676 . . . ?
C46 C41 C42 C43 -4.5(6) . . . . ?
C40 C41 C42 C43 179.4(4) . . . . ?
C41 C42 C43 C44 1.3(7) . . . . ?
C42 C43 C44 C45 1.5(7) . . . . ?
C43 C44 C45 C46 -1.0(7) . . . . ?
C44 C45 C46 C41 -2.2(6) . . . . ?
C44 C45 C46 C47 178.5(4) . . . . ?
C42 C41 C46 C45 4.9(6) . . . . ?
C40 C41 C46 C45 -178.7(4) . . . . ?
C42 C41 C46 C47 -175.8(4) . . . . ?
C40 C41 C46 C47 0.6(5) . . . . ?
C45 C46 C47 C48 135.4(4) . . . . ?
C41 C46 C47 C48 -43.8(5) . . . . ?
C45 C46 C47 C40 -99.0(5) . . . 2_676 ?
C41 C46 C47 C40 81.7(4) . . . 2_676 ?
C46 C47 C48 C49 -139.4(4) . . . . ?
C40 C47 C48 C49 94.7(4) 2_676 . . . ?
C46 C47 C48 C53 41.9(5) . . . . ?
C40 C47 C48 C53 -84.0(4) 2_676 . . . ?
C53 C48 C49 C50 -0.5(6) . . . . ?
C47 C48 C49 C50 -179.2(4) . . . . ?
C48 C49 C50 C51 -1.5(7) . . . . ?
C49 C50 C51 C52 2.3(7) . . . . ?
C50 C51 C52 C53 -1.3(7) . . . . ?
C51 C52 C53 C48 -0.6(6) . . . . ?
C51 C52 C53 C40 177.1(4) . . . . ?
C49 C48 C53 C52 1.5(6) . . . . ?
C47 C48 C53 C52 -179.8(3) . . . . ?
C49 C48 C53 C40 -176.4(4) . . . . ?
C47 C48 C53 C40 2.3(5) . . . . ?
C41 C40 C53 C52 137.2(4) . . . . ?
C39 C40 C53 C52 11.2(5) . . . . ?
C47 C40 C53 C52 -104.6(4) 2_676 . . . ?
C41 C40 C53 C48 -45.1(4) . . . . ?
C39 C40 C53 C48 -171.1(3) . . . . ?
C47 C40 C53 C48 73.1(4) 2_676 . . . ?
O19 P4 C58 C59 -122.1(5) . . . . ?
O21 P4 C58 C59 114.3(5) . . . . ?
O20 P4 C58 C59 3.0(5) . . . . ?
P4 C58 C59 C72 -63.1(6) . . . . ?
P4 C58 C59 C60 60.1(6) . . . . ?
P4 C58 C59 C66 178.4(4) . . . 2_566 ?
C72 C59 C60 C61 137.8(5) . . . . ?
C58 C59 C60 C61 12.0(7) . . . . ?
C66 C59 C60 C61 -103.3(5) 2_566 . . . ?
C72 C59 C60 C65 -42.5(5) . . . . ?
C58 C59 C60 C65 -168.3(4) . . . . ?
C66 C59 C60 C65 76.4(5) 2_566 . . . ?
C65 C60 C61 C62 0.7(8) . . . . ?
C59 C60 C61 C62 -179.6(5) . . . . ?
C60 C61 C62 C63 -0.7(9) . . . . ?
C61 C62 C63 C64 0.6(10) . . . . ?
C62 C63 C64 C65 -0.5(9) . . . . ?
C63 C64 C65 C60 0.6(8) . . . . ?
C63 C64 C65 C66 -179.2(5) . . . . ?
C61 C60 C65 C64 -0.6(7) . . . . ?
C59 C60 C65 C64 179.6(4) . . . . ?
C61 C60 C65 C66 179.1(4) . . . . ?
C59 C60 C65 C66 -0.6(6) . . . . ?
C64 C65 C66 C67 -136.0(5) . . . . ?
C60 C65 C66 C67 44.3(6) . . . . ?
C64 C65 C66 C59 98.9(5) . . . 2_566 ?
C60 C65 C66 C59 -80.8(5) . . . 2_566 ?
C65 C66 C67 C68 133.4(5) . . . . ?
C59 C66 C67 C68 -101.9(6) 2_566 . . . ?
C65 C66 C67 C72 -45.1(6) . . . . ?
C59 C66 C67 C72 79.7(6) 2_566 . . . ?
C72 C67 C68 C69 -3.3(9) . . . . ?
C66 C67 C68 C69 178.4(6) . . . . ?
C67 C68 C69 C70 -1.0(11) . . . . ?
C68 C69 C70 C71 2.5(11) . . . . ?
C69 C70 C71 C72 0.4(10) . . . . ?
C70 C71 C72 C67 -4.6(9) . . . . ?
C70 C71 C72 C59 178.1(5) . . . . ?
C68 C67 C72 C71 6.0(8) . . . . ?
C66 C67 C72 C71 -175.6(5) . . . . ?
C68 C67 C72 C59 -176.5(5) . . . . ?
C66 C67 C72 C59 1.9(7) . . . . ?
C60 C59 C72 C71 -140.8(5) . . . . ?
C58 C59 C72 C71 -15.3(7) . . . . ?
C66 C59 C72 C71 100.3(6) 2_566 . . . ?
C60 C59 C72 C67 41.9(6) . . . . ?
C58 C59 C72 C67 167.3(4) . . . . ?
C66 C59 C72 C67 -77.0(5) 2_566 . . . ?
C17' C16' O2 P1 -88.8(15) . . . . ?
C17 C16 O2 P1 149.2(9) . . . . ?
O1 P1 O2 C16' 2.0(8) . . . . ?
O3 P1 O2 C16' 125.8(7) . . . . ?
C1 P1 O2 C16' -124.5(7) . . . . ?
O1 P1 O2 C16 9.9(8) . . . . ?
O3 P1 O2 C16 133.8(8) . . . . ?
C1 P1 O2 C16 -116.5(8) . . . . ?
C19 C18 O3 P1 153.2(5) . . . . ?
O1 P1 O3 C18 66.0(4) . . . . ?
O2 P1 O3 C18 -58.0(4) . . . . ?
C1 P1 O3 C18 -172.8(4) . . . . ?
O6 P2 O4 Dy1 -92.5(11) . . . . ?
O5 P2 O4 Dy1 28.6(12) . . . . ?
C20 P2 O4 Dy1 141.6(10) . . . . ?
C36 C35 O5 P2 167.6(5) . . . . ?
O4 P2 O5 C35 -69.1(4) . . . . ?
O6 P2 O5 C35 55.4(4) . . . . ?
C20 P2 O5 C35 170.3(4) . . . . ?
C38 C37 O6 P2 -157.5(5) . . . . ?
O4 P2 O6 C37 -9.6(4) . . . . ?
O5 P2 O6 C37 -134.9(4) . . . . ?
C20 P2 O6 C37 117.6(4) . . . . ?
O8 P3 O7 Dy1 160.2(4) . . . . ?
O9 P3 O7 Dy1 -82.4(4) . . . . ?
C39 P3 O7 Dy1 32.3(5) . . . . ?
C55 C54 O8 P3 120.7(5) . . . . ?
O7 P3 O8 C54 -21.0(4) . . . . ?
O9 P3 O8 C54 -143.4(4) . . . . ?
C39 P3 O8 C54 108.3(4) . . . . ?
C57 C56 O9 P3 -152.4(7) . . . . ?
O7 P3 O9 C56 -58.3(5) . . . . ?
O8 P3 O9 C56 63.7(5) . . . . ?
C39 P3 O9 C56 179.5(5) . . . . ?
O12 N1 O10 Dy1 -179.0(4) . . . . ?
O11 N1 O10 Dy1 0.6(5) . . . . ?
O12 N1 O11 Dy1 179.0(4) . . . . ?
O10 N1 O11 Dy1 -0.5(4) . . . . ?
O15 N2 O13 Dy1 179.4(6) . . . . ?
O14 N2 O13 Dy1 -2.1(6) . . . . ?
O15 N2 O14 Dy1 -179.5(6) . . . . ?
O13 N2 O14 Dy1 2.0(6) . . . . ?
O18 N3 O16 Dy1 177.6(5) . . . . ?
O17 N3 O16 Dy1 -2.4(5) . . . . ?
O18 N3 O17 Dy1 -177.5(5) . . . . ?
O16 N3 O17 Dy1 2.5(5) . . . . ?
C74 C73 O20 C73' -134(6) . . . . ?
C74 C73 O20 P4 68(2) . . . . ?
C74' C73' O20 C73 -154(7) . . . . ?
C74' C73' O20 P4 -126.9(14) . . . . ?
O19 P4 O20 C73 -75.3(9) . . . . ?
O21 P4 O20 C73 49.8(9) . . . . ?
C58 P4 O20 C73 160.0(9) . . . . ?
O19 P4 O20 C73' -84.8(13) . . . . ?
O21 P4 O20 C73' 40.3(13) . . . . ?
C58 P4 O20 C73' 150.5(12) . . . . ?
C76 C75 O21 P4 -115.4(7) . . . . ?
O19 P4 O21 C75 11.9(7) . . . . ?
O20 P4 O21 C75 -113.5(6) . . . . ?
C58 P4 O21 C75 135.4(6) . . . . ?

_refine_diff_density_max         0.955
_refine_diff_density_min         -0.965
_refine_diff_density_rms         0.112


_exptl_crystal_recrystallization_method 
'Re-crystallisation from solvent: methanol dichloromethane'
_chemical_properties_physical    
Heat-sensitive,Light-sensitive,Photo-sensitive
_exptl_crystal_preparation       Luminescent,mechanical
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_2
_database_code_depnum_ccdc_archive 'CCDC 2214250'
loop_
_audit_author_name
_audit_author_address
'Xinda Huang'
;Nanjing University
China
;
_audit_update_record             
;
2022-10-20 deposited with the CCDC.	2023-01-27 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        '[Dy(NO3)3(depma2)1.5].(depma2)0.5'
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C57 H63 Dy N3 O18 P3, (C19 H21 O3 P)'
_chemical_formula_sum            'C76 H84 Dy N3 O21 P4'
_chemical_formula_weight         1661.84

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   12.0168(18)
_cell_length_b                   13.485(2)
_cell_length_c                   23.445(3)
_cell_angle_alpha                90.470(6)
_cell_angle_beta                 97.255(4)
_cell_angle_gamma                93.184(6)
_cell_volume                     3762.6(10)
_cell_formula_units_Z            2
_cell_measurement_temperature    193(2)
_cell_measurement_reflns_used    9989
_cell_measurement_theta_min      2.2185
_cell_measurement_theta_max      27.065

_exptl_crystal_description       rod
_exptl_crystal_colour            colorless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.467
_exptl_crystal_F_000             1710
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.400
_exptl_crystal_size_mid          0.120
_exptl_crystal_size_min          0.100
_exptl_absorpt_coefficient_mu    1.154
_shelx_estimated_absorpt_T_min   0.655
_shelx_estimated_absorpt_T_max   0.893
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.630
_exptl_absorpt_correction_T_max  0.893
_exptl_absorpt_process_details   'SADABS 2016/2'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      193(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker D8 Venture'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            34654
_diffrn_reflns_av_unetI/netI     0.0932
_diffrn_reflns_av_R_equivalents  0.0624
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_theta_min         2.218
_diffrn_reflns_theta_max         27.214
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.987
_diffrn_measured_fraction_theta_full 0.993
_diffrn_reflns_Laue_measured_fraction_max 0.987
_diffrn_reflns_Laue_measured_fraction_full 0.993
_diffrn_reflns_point_group_measured_fraction_max 0.987
_diffrn_reflns_point_group_measured_fraction_full 0.993
_reflns_number_total             16588
_reflns_number_gt                12746
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker APEX3'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXT 2014/4 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0958P)²+5.6042P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         16588
_refine_ls_number_parameters     1039
_refine_ls_number_restraints     917
_refine_ls_R_factor_all          0.0921
_refine_ls_R_factor_gt           0.0690
_refine_ls_wR_factor_ref         0.1954
_refine_ls_wR_factor_gt          0.1765
_refine_ls_goodness_of_fit_ref   1.072
_refine_ls_restrained_S_all      1.126
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.70264(2) 0.82103(2) 0.25113(2) 0.03050(10) Uani 1 1 d . . . . .
P1 P 0.76179(13) 0.63974(13) 0.13744(6) 0.0333(3) Uani 1 1 d . U . . .
P2 P 0.90413(14) 0.98772(15) 0.18226(6) 0.0401(4) Uani 1 1 d . U . . .
P3 P 0.55547(18) 1.02412(16) 0.31035(7) 0.0488(4) Uani 1 1 d . U . . .
C1 C 0.6733(4) 0.6565(5) 0.0708(2) 0.0292(10) Uani 1 1 d . U . . .
H1A H 0.625077 0.711903 0.076732 0.035 Uiso 1 1 calc R U . . .
H1B H 0.722713 0.678755 0.042041 0.035 Uiso 1 1 calc R U . . .
C2 C 0.5954(4) 0.5682(5) 0.0433(2) 0.0275(9) Uani 1 1 d . U . . .
C3 C 0.6607(4) 0.4825(5) 0.0254(2) 0.0302(9) Uani 1 1 d . U . . .
C4 C 0.7762(5) 0.4899(5) 0.0219(3) 0.0386(12) Uani 1 1 d . U . . .
H4 H 0.818219 0.550943 0.031009 0.046 Uiso 1 1 calc R U . . .
C5 C 0.8292(5) 0.4080(6) 0.0050(3) 0.0496(13) Uani 1 1 d . U . . .
H5 H 0.907876 0.413168 0.003119 0.059 Uiso 1 1 calc R U . . .
C6 C 0.7703(6) 0.3199(6) -0.0091(4) 0.0540(14) Uani 1 1 d . U . . .
H6 H 0.807693 0.264139 -0.020397 0.065 Uiso 1 1 calc R U . . .
C7 C 0.6556(5) 0.3123(6) -0.0068(3) 0.0461(13) Uani 1 1 d . U . . .
H7 H 0.614087 0.251294 -0.016823 0.055 Uiso 1 1 calc R U . . .
C8 C 0.6015(5) 0.3932(5) 0.0102(3) 0.0341(10) Uani 1 1 d . U . . .
C9 C 0.4767(4) 0.3873(5) 0.0136(2) 0.0297(10) Uani 1 1 d . U . . .
H9 H 0.452257 0.315548 0.016052 0.036 Uiso 1 1 calc R U . . .
C10 C 0.4568(5) 0.4376(5) 0.0685(2) 0.0332(10) Uani 1 1 d . U . . .
C11 C 0.3819(6) 0.3971(6) 0.1035(3) 0.0439(13) Uani 1 1 d . U . . .
H11 H 0.344663 0.334140 0.093730 0.053 Uiso 1 1 calc R U . . .
C12 C 0.3606(6) 0.4466(6) 0.1520(3) 0.0543(14) Uani 1 1 d . U . . .
H12 H 0.310225 0.417365 0.176013 0.065 Uiso 1 1 calc R U . . .
C13 C 0.4134(6) 0.5399(6) 0.1658(3) 0.0561(14) Uani 1 1 d . U . . .
H13 H 0.396531 0.576237 0.198190 0.067 Uiso 1 1 calc R U . . .
C14 C 0.4898(6) 0.5785(6) 0.1321(3) 0.0456(13) Uani 1 1 d . U . . .
H14 H 0.527652 0.641032 0.142299 0.055 Uiso 1 1 calc R U . . .
C15 C 0.5136(5) 0.5286(5) 0.0833(2) 0.0321(10) Uani 1 1 d . U . . .
C16 C 0.7190(8) 0.4886(7) 0.2057(3) 0.0641(17) Uani 1 1 d . U . . .
H16A H 0.680461 0.422402 0.196878 0.077 Uiso 1 1 calc R U . . .
H16B H 0.664081 0.532860 0.218845 0.077 Uiso 1 1 calc R U . . .
C17 C 0.8135(11) 0.4797(9) 0.2517(5) 0.105(3) Uani 1 1 d . U . . .
H17A H 0.866762 0.434382 0.239075 0.158 Uiso 1 1 calc R U . . .
H17B H 0.784864 0.453597 0.286311 0.158 Uiso 1 1 calc R U . . .
H17C H 0.851523 0.545240 0.260462 0.158 Uiso 1 1 calc R U . . .
C18 C 0.9796(6) 0.6486(7) 0.1641(4) 0.0635(17) Uani 1 1 d . U . . .
H18A H 1.010758 0.713819 0.180242 0.076 Uiso 1 1 calc R U . . .
H18B H 0.955465 0.608167 0.195866 0.076 Uiso 1 1 calc R U . . .
C19 C 1.0621(9) 0.6009(12) 0.1394(5) 0.120(3) Uani 1 1 d . U . . .
H19A H 1.032576 0.534665 0.125516 0.179 Uiso 1 1 calc R U . . .
H19B H 1.127872 0.594687 0.168169 0.179 Uiso 1 1 calc R U . . .
H19C H 1.084006 0.639836 0.107050 0.179 Uiso 1 1 calc R U . . .
C20 C 0.9782(5) 0.9358(5) 0.1281(2) 0.0338(10) Uani 1 1 d . U . . .
H20A H 1.058095 0.935266 0.144711 0.041 Uiso 1 1 calc R U . . .
H20B H 0.950211 0.865548 0.122474 0.041 Uiso 1 1 calc R U . . .
C21 C 0.9761(4) 0.9809(5) 0.0678(2) 0.0298(10) Uani 1 1 d . U . . .
C22 C 0.8581(4) 0.9791(5) 0.0349(2) 0.0283(9) Uani 1 1 d . U . . .
C23 C 0.7664(4) 0.9263(5) 0.0522(2) 0.0317(11) Uani 1 1 d . U . . .
H23 H 0.775825 0.888120 0.086204 0.038 Uiso 1 1 calc R U . . .
C24 C 0.6614(5) 0.9284(5) 0.0207(3) 0.0379(12) Uani 1 1 d . U . . .
H24 H 0.598929 0.892488 0.033245 0.045 Uiso 1 1 calc R U . . .
C25 C 0.6473(5) 0.9832(5) -0.0295(3) 0.0407(12) Uani 1 1 d . U . . .
H25 H 0.575184 0.985669 -0.051127 0.049 Uiso 1 1 calc R U . . .
C26 C 0.7395(5) 1.0339(5) -0.0474(3) 0.0372(11) Uani 1 1 d . U . . .
H26 H 0.730890 1.070241 -0.082085 0.045 Uiso 1 1 calc R U . . .
C27 C 0.8437(4) 1.0324(5) -0.0155(2) 0.0310(10) Uani 1 1 d . U . . .
C28 C 0.9453(4) 1.0876(5) -0.0340(2) 0.0303(10) Uani 1 1 d . U . . .
H28 H 0.917094 1.139904 -0.061247 0.036 Uiso 1 1 calc R U . . .
C29 C 1.0092(4) 1.1403(5) 0.0177(2) 0.0305(9) Uani 1 1 d . U . . .
C30 C 1.0507(5) 1.2374(5) 0.0154(3) 0.0362(11) Uani 1 1 d . U . . .
H30 H 1.039508 1.272288 -0.019715 0.043 Uiso 1 1 calc R U . . .
C31 C 1.1087(5) 1.2848(6) 0.0641(3) 0.0439(12) Uani 1 1 d . U . . .
H31 H 1.136659 1.351895 0.062650 0.053 Uiso 1 1 calc R U . . .
C32 C 1.1248(5) 1.2328(6) 0.1143(3) 0.0446(13) Uani 1 1 d . U . . .
H32 H 1.164653 1.264162 0.147826 0.054 Uiso 1 1 calc R U . . .
C33 C 1.0839(5) 1.1360(5) 0.1167(3) 0.0383(11) Uani 1 1 d . U . . .
H33 H 1.096771 1.101357 0.151814 0.046 Uiso 1 1 calc R U . . .
C34 C 1.0246(4) 1.0878(5) 0.0691(2) 0.0300(9) Uani 1 1 d . U . . .
C35 C 1.0031(8) 1.0652(8) 0.2803(3) 0.0735(19) Uani 1 1 d . U . . .
H35A H 0.937503 1.040836 0.298899 0.088 Uiso 1 1 calc R U . . .
H35B H 0.994261 1.136160 0.271301 0.088 Uiso 1 1 calc R U . . .
C36 C 1.1042(10) 1.0560(10) 0.3196(5) 0.106(3) Uani 1 1 d . U . . .
H36A H 1.102433 0.990369 0.337235 0.160 Uiso 1 1 calc R U . . .
H36B H 1.109305 1.107563 0.349660 0.160 Uiso 1 1 calc R U . . .
H36C H 1.169667 1.063747 0.298643 0.160 Uiso 1 1 calc R U . . .
C37 C 0.7383(8) 1.1064(8) 0.1600(4) 0.0766(19) Uani 1 1 d . U . . .
H37A H 0.690471 1.045159 0.149581 0.092 Uiso 1 1 calc R U . . .
H37B H 0.724809 1.128051 0.198851 0.092 Uiso 1 1 calc R U . . .
C38 C 0.7070(12) 1.1812(11) 0.1203(6) 0.120(4) Uani 1 1 d . U . . .
H38A H 0.742880 1.245182 0.134575 0.180 Uiso 1 1 calc R U . . .
H38B H 0.625163 1.185146 0.115703 0.180 Uiso 1 1 calc R U . . .
H38C H 0.731176 1.165114 0.083097 0.180 Uiso 1 1 calc R U . . .
C39 C 0.4958(6) 0.9597(5) 0.3668(2) 0.0413(8) Uani 1 1 d . U . . .
H39A H 0.414040 0.951154 0.354019 0.050 Uiso 1 1 calc R U . . .
H39B H 0.524757 0.892408 0.367466 0.050 Uiso 1 1 calc R U . . .
C40 C 0.5080(5) 0.9957(5) 0.4293(2) 0.0346(7) Uani 1 1 d . U . . .
C41 C 0.6306(5) 1.0119(5) 0.4570(3) 0.0347(8) Uani 1 1 d . U . . .
C42 C 0.7193(5) 0.9748(5) 0.4333(3) 0.0383(9) Uani 1 1 d . U . . .
H42 H 0.705125 0.939230 0.397756 0.046 Uiso 1 1 calc R U . . .
C43 C 0.8275(5) 0.9879(6) 0.4600(3) 0.0428(10) Uani 1 1 d . U . . .
H43 H 0.887767 0.961705 0.443246 0.051 Uiso 1 1 calc R U . . .
C44 C 0.8476(5) 1.0408(6) 0.5124(3) 0.0441(10) Uani 1 1 d . U . . .
H44 H 0.922177 1.051550 0.531253 0.053 Uiso 1 1 calc R U . . .
C45 C 0.7582(5) 1.0775(5) 0.5368(3) 0.0408(9) Uani 1 1 d . U . . .
H45 H 0.771765 1.113737 0.572130 0.049 Uiso 1 1 calc R U . . .
C46 C 0.6501(5) 1.0613(5) 0.5097(3) 0.0351(8) Uani 1 1 d . U . . .
C47 C 0.5514(4) 1.0931(5) 0.5370(2) 0.0334(8) Uani 1 1 d . U . . .
H47 H 0.579857 1.146158 0.566116 0.040 Uiso 1 1 calc R U . . .
C48 C 0.4705(5) 1.1395(5) 0.4920(2) 0.0342(8) Uani 1 1 d . U . . .
C49 C 0.4156(5) 1.2241(5) 0.5036(3) 0.0384(9) Uani 1 1 d . U . . .
H49 H 0.431036 1.255949 0.540305 0.046 Uiso 1 1 calc R U . . .
C50 C 0.3390(5) 1.2617(5) 0.4620(3) 0.0424(9) Uani 1 1 d . U . . .
H50 H 0.300705 1.318988 0.470049 0.051 Uiso 1 1 calc R U . . .
C51 C 0.3177(5) 1.2160(5) 0.4084(3) 0.0439(10) Uani 1 1 d . U . . .
H51 H 0.265648 1.242682 0.379491 0.053 Uiso 1 1 calc R U . . .
C52 C 0.3719(5) 1.1314(5) 0.3967(3) 0.0409(9) Uani 1 1 d . U . . .
H52 H 0.355946 1.100463 0.359785 0.049 Uiso 1 1 calc R U . . .
C53 C 0.4484(5) 1.0917(5) 0.4376(3) 0.0351(8) Uani 1 1 d . U . . .
C54 C 0.6925(10) 1.1647(8) 0.3427(5) 0.0853(14) Uani 1 1 d D U . . .
H54A H 0.746172 1.124778 0.325049 0.102 Uiso 1 1 calc R U . . .
H54B H 0.714387 1.167284 0.384872 0.102 Uiso 1 1 calc R U . . .
C55 C 0.6921(11) 1.2667(8) 0.3190(5) 0.106(2) Uani 1 1 d D U . . .
H55A H 0.745243 1.272935 0.290598 0.159 Uiso 1 1 calc R U . . .
H55B H 0.714265 1.315304 0.350222 0.159 Uiso 1 1 calc R U . . .
H55C H 0.616434 1.279060 0.300490 0.159 Uiso 1 1 calc R U . . .
C56 C 0.4475(9) 1.0815(8) 0.2142(4) 0.0815(14) Uani 1 1 d D U . . .
H56A H 0.426877 1.028077 0.184985 0.098 Uiso 1 1 calc R U . . .
H56B H 0.525504 1.106408 0.211060 0.098 Uiso 1 1 calc R U . . .
C57 C 0.3739(10) 1.1608(9) 0.2025(5) 0.104(2) Uani 1 1 d D U . . .
H57A H 0.296990 1.133098 0.191266 0.156 Uiso 1 1 calc R U . . .
H57B H 0.398057 1.200885 0.171163 0.156 Uiso 1 1 calc R U . . .
H57C H 0.376094 1.202559 0.237072 0.156 Uiso 1 1 calc R U . . .
C59 C 0.0411(8) 0.5341(6) 0.4386(4) 0.062(2) Uani 1 1 d D . . . .
C60 C 0.0219(7) 0.4216(7) 0.4318(4) 0.066(2) Uani 1 1 d . . . . .
C61 C -0.0033(13) 0.3747(11) 0.3805(6) 0.122(5) Uani 1 1 d . . . . .
H61 H -0.013259 0.411487 0.346022 0.146 Uiso 1 1 calc R U . . .
C62 C -0.0138(19) 0.2764(17) 0.3790(10) 0.199(11) Uani 1 1 d . . . . .
H62 H -0.026568 0.244493 0.342338 0.239 Uiso 1 1 calc R U . . .
C63 C -0.0079(17) 0.2189(11) 0.4251(12) 0.193(12) Uani 1 1 d . . . . .
H63 H -0.027424 0.149686 0.421943 0.231 Uiso 1 1 calc R U . . .
C64 C 0.0293(12) 0.2663(8) 0.4799(7) 0.114(5) Uani 1 1 d . . . . .
H64 H 0.046119 0.228081 0.513421 0.137 Uiso 1 1 calc R U . . .
C65 C 0.0399(7) 0.3682(6) 0.4825(4) 0.060(2) Uani 1 1 d . . . . .
C66 C 0.0707(8) 0.4238(7) 0.5365(4) 0.069(3) Uani 1 1 d . . . . .
H66 H 0.104045 0.376116 0.565384 0.083 Uiso 1 1 calc R U . . .
C67 C 0.1578(7) 0.4971(9) 0.5283(5) 0.087(3) Uani 1 1 d . . . . .
C68 C 0.2495(10) 0.5045(15) 0.5713(7) 0.155(7) Uani 1 1 d . . . . .
H68 H 0.253134 0.461818 0.603374 0.186 Uiso 1 1 calc R U . . .
C69 C 0.3286(15) 0.570(3) 0.5664(11) 0.251(16) Uani 1 1 d . . . . .
H69 H 0.390532 0.575528 0.595973 0.302 Uiso 1 1 calc R U . . .
C70 C 0.3284(11) 0.6328(15) 0.5206(8) 0.150(8) Uani 1 1 d . . . . .
H70 H 0.391665 0.676908 0.517293 0.180 Uiso 1 1 calc R U . . .
C71 C 0.2300(13) 0.6311(11) 0.4772(8) 0.138(6) Uani 1 1 d . . . . .
H71 H 0.223334 0.678775 0.447509 0.165 Uiso 1 1 calc R U . . .
C72 C 0.1441(8) 0.5548(7) 0.4810(5) 0.079(3) Uani 1 1 d . . . . .
C58 C 0.0599(13) 0.5941(10) 0.3834(5) 0.0756(8) Uani 0.708(3) 1 d D U P A 1
H58A H 0.072526 0.664740 0.395543 0.091 Uiso 0.708(3) 1 calc R U P A 1
H58B H -0.012240 0.588589 0.357706 0.091 Uiso 0.708(3) 1 calc R U P A 1
C73 C 0.3669(10) 0.4934(10) 0.3765(5) 0.0767(9) Uani 0.708(3) 1 d D U P A 1
H73A H 0.400588 0.562179 0.380293 0.092 Uiso 0.708(3) 1 calc R U P A 1
H73B H 0.397706 0.456288 0.410687 0.092 Uiso 0.708(3) 1 calc R U P A 1
C74 C 0.3965(12) 0.4483(11) 0.3265(5) 0.0776(10) Uani 0.708(3) 1 d D U P A 1
H74A H 0.366926 0.379003 0.323933 0.116 Uiso 0.708(3) 1 calc R U P A 1
H74B H 0.478558 0.450566 0.328323 0.116 Uiso 0.708(3) 1 calc R U P A 1
H74C H 0.364707 0.484022 0.292635 0.116 Uiso 0.708(3) 1 calc R U P A 1
C75 C 0.2803(11) 0.7166(9) 0.2926(5) 0.0764(10) Uani 0.708(3) 1 d D U P A 1
H75A H 0.361880 0.733788 0.301182 0.092 Uiso 0.708(3) 1 calc R U P A 1
H75B H 0.268463 0.670346 0.259109 0.092 Uiso 0.708(3) 1 calc R U P A 1
C76 C 0.2242(12) 0.8025(9) 0.2789(6) 0.0771(13) Uani 0.708(3) 1 d D U P A 1
H76A H 0.143862 0.785336 0.268545 0.116 Uiso 0.708(3) 1 calc R U P A 1
H76B H 0.254375 0.834647 0.246277 0.116 Uiso 0.708(3) 1 calc R U P A 1
H76C H 0.235019 0.848143 0.312120 0.116 Uiso 0.708(3) 1 calc R U P A 1
C58' C -0.001(2) 0.556(3) 0.3737(6) 0.0755(8) Uani 0.292(3) 1 d D U P A 2
H58C H -0.012719 0.628484 0.370894 0.091 Uiso 0.292(3) 1 calc R U P A 2
H58D H -0.075728 0.521238 0.363816 0.091 Uiso 0.292(3) 1 calc R U P A 2
C73' C 0.2940(15) 0.471(2) 0.3532(11) 0.0764(8) Uani 0.292(3) 1 d D U P A 2
H73C H 0.313739 0.542957 0.352965 0.092 Uiso 0.292(3) 1 calc R U P A 2
H73D H 0.328962 0.444241 0.390035 0.092 Uiso 0.292(3) 1 calc R U P A 2
C74' C 0.336(2) 0.424(3) 0.3074(13) 0.0768(10) Uani 0.292(3) 1 d D U P A 2
H74D H 0.339289 0.352845 0.314436 0.115 Uiso 0.292(3) 1 calc R U P A 2
H74E H 0.412336 0.452510 0.304247 0.115 Uiso 0.292(3) 1 calc R U P A 2
H74F H 0.287504 0.434956 0.271550 0.115 Uiso 0.292(3) 1 calc R U P A 2
C75' C 0.039(2) 0.3901(19) 0.2320(9) 0.0761(10) Uani 0.292(3) 1 d D U P A 2
H75C H -0.025477 0.343787 0.217956 0.091 Uiso 0.292(3) 1 calc R U P A 2
H75D H 0.056044 0.432029 0.199385 0.091 Uiso 0.292(3) 1 calc R U P A 2
C76' C 0.132(2) 0.335(2) 0.2492(13) 0.0761(14) Uani 0.292(3) 1 d D U P A 2
H76D H 0.156719 0.304279 0.215326 0.114 Uiso 0.292(3) 1 calc R U P A 2
H76E H 0.110640 0.282969 0.275431 0.114 Uiso 0.292(3) 1 calc R U P A 2
H76F H 0.192633 0.378680 0.268832 0.114 Uiso 0.292(3) 1 calc R U P A 2
N1 N 0.9060(5) 0.8229(5) 0.3304(2) 0.0453(14) Uani 1 1 d . . . . .
N2 N 0.6161(7) 0.6863(5) 0.3310(3) 0.0692(14) Uani 1 1 d . U . . .
N3 N 0.4943(5) 0.8347(5) 0.1762(3) 0.0527(16) Uani 1 1 d . . . . .
O1 O 0.7346(4) 0.7055(4) 0.18390(17) 0.0405(10) Uani 1 1 d . U . . .
O2 O 0.7592(4) 0.5289(4) 0.15336(19) 0.0475(10) Uani 1 1 d . U . . .
O3 O 0.8826(3) 0.6628(4) 0.12082(19) 0.0444(10) Uani 1 1 d . U . . .
O4 O 0.8195(4) 0.9171(4) 0.20160(18) 0.0418(10) Uani 1 1 d . U . . .
O5 O 1.0053(5) 1.0125(5) 0.2302(2) 0.0635(12) Uani 1 1 d . U . . .
O6 O 0.8551(4) 1.0844(4) 0.1613(2) 0.0561(11) Uani 1 1 d . U . . .
O7 O 0.6298(4) 0.9668(4) 0.28024(18) 0.0447(8) Uani 1 1 d . U . . .
O8 O 0.5911(6) 1.1265(5) 0.3303(3) 0.0749(10) Uani 1 1 d D U . . .
O9 O 0.4428(5) 1.0430(5) 0.2680(2) 0.0724(10) Uani 1 1 d D U . . .
O10 O 0.8387(4) 0.8920(4) 0.32782(19) 0.0451(11) Uani 1 1 d . . . . .
O11 O 0.8778(5) 0.7527(4) 0.2947(3) 0.0689(17) Uani 1 1 d . . . . .
O12 O 0.9905(5) 0.8245(5) 0.3644(3) 0.0749(19) Uani 1 1 d . . . . .
O13 O 0.6324(5) 0.7759(4) 0.3404(2) 0.0602(13) Uani 1 1 d . U . . .
O14 O 0.6446(6) 0.6544(4) 0.2846(2) 0.0744(15) Uani 1 1 d . U . . .
O15 O 0.5724(9) 0.6338(5) 0.3633(3) 0.115(3) Uani 1 1 d . U . . .
O16 O 0.5857(4) 0.8722(5) 0.1626(2) 0.0580(14) Uani 1 1 d . . . . .
O17 O 0.5004(4) 0.7870(4) 0.2228(2) 0.0524(13) Uani 1 1 d . . . . .
O18 O 0.4065(5) 0.8410(6) 0.1457(3) 0.094(2) Uani 1 1 d . . . . .
P4 P 0.1688(3) 0.5678(3) 0.33955(16) 0.0757(7) Uani 0.708(3) 1 d D U P A 1
O19 O 0.1249(8) 0.5335(7) 0.2809(4) 0.0766(9) Uani 0.708(3) 1 d D U P A 1
O20 O 0.2470(7) 0.4952(7) 0.3748(4) 0.0763(8) Uani 0.708(3) 1 d D U P A 1
O21 O 0.2411(7) 0.6683(6) 0.3414(4) 0.0761(8) Uani 0.708(3) 1 d D U P A 1
P4' P 0.0856(8) 0.5243(7) 0.3188(4) 0.0756(8) Uani 0.292(3) 1 d D U P A 2
O21' O 0.0070(14) 0.4529(13) 0.2763(7) 0.0759(9) Uani 0.292(3) 1 d D U P A 2
O19' O 0.1358(19) 0.6107(14) 0.2913(9) 0.0759(9) Uani 0.292(3) 1 d D U P A 2
O20' O 0.1740(14) 0.4543(14) 0.3489(9) 0.0760(8) Uani 0.292(3) 1 d D U P A 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O4 2.287(4) . ?
Dy1 O1 2.289(4) . ?
Dy1 O7 2.327(5) . ?
Dy1 O13 2.424(5) . ?
Dy1 O10 2.424(4) . ?
Dy1 O11 2.452(5) . ?
Dy1 O17 2.453(5) . ?
Dy1 O14 2.479(6) . ?
Dy1 O16 2.480(4) . ?
P1 O1 1.478(5) . ?
P1 O2 1.543(5) . ?
P1 O3 1.566(5) . ?
P1 C1 1.799(5) . ?
P2 O4 1.471(4) . ?
P2 O6 1.520(6) . ?
P2 O5 1.568(5) . ?
P2 C20 1.798(6) . ?
P3 O7 1.456(5) . ?
P3 O8 1.477(7) . ?
P3 O9 1.608(6) . ?
P3 C39 1.791(6) . ?
C1 C2 1.556(8) . ?
C2 C3 1.518(8) . ?
C2 C15 1.520(8) . ?
C2 C9 1.634(7) 2_665 ?
C3 C8 1.385(9) . ?
C3 C4 1.399(8) . ?
C4 C5 1.385(9) . ?
C5 C6 1.365(10) . ?
C6 C7 1.383(9) . ?
C7 C8 1.382(9) . ?
C8 C9 1.510(8) . ?
C9 C10 1.503(8) . ?
C10 C11 1.385(8) . ?
C10 C15 1.390(9) . ?
C11 C12 1.372(9) . ?
C12 C13 1.394(11) . ?
C13 C14 1.370(9) . ?
C14 C15 1.390(8) . ?
C16 O2 1.471(9) . ?
C16 C17 1.476(13) . ?
C18 C19 1.393(14) . ?
C18 O3 1.468(8) . ?
C20 C21 1.541(7) . ?
C21 C34 1.523(9) . ?
C21 C22 1.524(7) . ?
C21 C28 1.628(8) 2_775 ?
C22 C23 1.385(8) . ?
C22 C27 1.386(8) . ?
C23 C24 1.381(8) . ?
C24 C25 1.391(9) . ?
C25 C26 1.383(9) . ?
C26 C27 1.376(8) . ?
C27 C28 1.506(8) . ?
C28 C29 1.501(8) . ?
C29 C30 1.380(9) . ?
C29 C34 1.401(8) . ?
C30 C31 1.391(9) . ?
C31 C32 1.374(10) . ?
C32 C33 1.373(9) . ?
C33 C34 1.382(9) . ?
C35 O5 1.371(10) . ?
C35 C36 1.441(13) . ?
C37 C38 1.412(15) . ?
C37 O6 1.448(10) . ?
C39 C40 1.527(8) . ?
C40 C53 1.536(9) . ?
C40 C41 1.536(8) . ?
C40 C47 1.622(8) 2_676 ?
C41 C42 1.378(8) . ?
C41 C46 1.386(9) . ?
C42 C43 1.371(8) . ?
C43 C44 1.404(10) . ?
C44 C45 1.391(9) . ?
C45 C46 1.377(8) . ?
C46 C47 1.498(8) . ?
C47 C48 1.506(8) . ?
C48 C49 1.391(9) . ?
C48 C53 1.413(9) . ?
C49 C50 1.374(9) . ?
C50 C51 1.383(10) . ?
C51 C52 1.387(10) . ?
C52 C53 1.376(8) . ?
C54 O8 1.294(12) . ?
C54 C55 1.488(11) . ?
C56 O9 1.375(10) . ?
C56 C57 1.431(11) . ?
C59 C72 1.498(14) . ?
C59 C60 1.527(12) . ?
C59 C58 1.564(12) . ?
C59 C58' 1.579(15) . ?
C59 C66 1.657(12) 2_566 ?
C60 C61 1.346(14) . ?
C60 C65 1.395(12) . ?
C61 C62 1.32(2) . ?
C62 C63 1.33(3) . ?
C63 C64 1.44(2) . ?
C64 C65 1.373(13) . ?
C65 C66 1.461(13) . ?
C66 C67 1.432(14) . ?
C67 C72 1.359(15) . ?
C67 C68 1.395(14) . ?
C68 C69 1.28(3) . ?
C69 C70 1.37(3) . ?
C70 C71 1.46(2) . ?
C71 C72 1.427(14) . ?
C58 P4 1.812(12) . ?
C73 C74 1.410(12) . ?
C73 O20 1.438(11) . ?
C75 C76 1.392(12) . ?
C75 O21 1.439(11) . ?
C58' P4' 1.820(14) . ?
C73' C74' 1.403(14) . ?
C73' O20' 1.438(13) . ?
C75' C76' 1.390(14) . ?
C75' O21' 1.438(13) . ?
N1 O12 1.207(7) . ?
N1 O11 1.261(8) . ?
N1 O10 1.264(7) . ?
N2 O15 1.190(8) . ?
N2 O13 1.227(8) . ?
N2 O14 1.261(8) . ?
N3 O18 1.205(7) . ?
N3 O16 1.262(8) . ?
N3 O17 1.270(8) . ?
P4 O19 1.470(9) . ?
P4 O20 1.564(8) . ?
P4 O21 1.566(8) . ?
P4' O19' 1.473(12) . ?
P4' O20' 1.565(10) . ?
P4' O21' 1.567(10) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O4 Dy1 O1 81.39(17) . . ?
O4 Dy1 O7 87.89(17) . . ?
O1 Dy1 O7 153.47(16) . . ?
O4 Dy1 O13 150.37(19) . . ?
O1 Dy1 O13 122.55(17) . . ?
O7 Dy1 O13 76.62(17) . . ?
O4 Dy1 O10 77.87(16) . . ?
O1 Dy1 O10 126.53(16) . . ?
O7 Dy1 O10 73.85(17) . . ?
O13 Dy1 O10 73.65(19) . . ?
O4 Dy1 O11 83.8(2) . . ?
O1 Dy1 O11 77.61(17) . . ?
O7 Dy1 O11 125.45(17) . . ?
O13 Dy1 O11 84.9(2) . . ?
O10 Dy1 O11 51.67(17) . . ?
O4 Dy1 O17 125.51(16) . . ?
O1 Dy1 O17 88.35(17) . . ?
O7 Dy1 O17 78.24(18) . . ?
O13 Dy1 O17 76.28(19) . . ?
O10 Dy1 O17 142.74(17) . . ?
O11 Dy1 O17 145.4(2) . . ?
O4 Dy1 O14 148.7(2) . . ?
O1 Dy1 O14 71.62(17) . . ?
O7 Dy1 O14 123.20(18) . . ?
O13 Dy1 O14 51.00(18) . . ?
O10 Dy1 O14 105.6(2) . . ?
O11 Dy1 O14 75.4(2) . . ?
O17 Dy1 O14 70.2(2) . . ?
O4 Dy1 O16 73.95(17) . . ?
O1 Dy1 O16 76.51(18) . . ?
O7 Dy1 O16 77.22(18) . . ?
O13 Dy1 O16 125.22(19) . . ?
O10 Dy1 O16 139.95(19) . . ?
O11 Dy1 O16 148.0(2) . . ?
O17 Dy1 O16 51.66(17) . . ?
O14 Dy1 O16 113.3(2) . . ?
O1 P1 O2 113.3(3) . . ?
O1 P1 O3 113.0(3) . . ?
O2 P1 O3 104.6(3) . . ?
O1 P1 C1 112.2(3) . . ?
O2 P1 C1 110.1(3) . . ?
O3 P1 C1 102.8(2) . . ?
O4 P2 O6 112.7(3) . . ?
O4 P2 O5 112.4(3) . . ?
O6 P2 O5 108.6(3) . . ?
O4 P2 C20 112.9(3) . . ?
O6 P2 C20 109.9(3) . . ?
O5 P2 C20 99.6(3) . . ?
O7 P3 O8 119.8(4) . . ?
O7 P3 O9 109.7(3) . . ?
O8 P3 O9 101.0(4) . . ?
O7 P3 C39 115.0(3) . . ?
O8 P3 C39 108.7(3) . . ?
O9 P3 C39 99.8(3) . . ?
C2 C1 P1 119.7(4) . . ?
C3 C2 C15 108.3(5) . . ?
C3 C2 C1 112.6(4) . . ?
C15 C2 C1 112.3(4) . . ?
C3 C2 C9 109.3(4) . 2_665 ?
C15 C2 C9 108.4(4) . 2_665 ?
C1 C2 C9 105.8(5) . 2_665 ?
C8 C3 C4 118.5(6) . . ?
C8 C3 C2 117.8(5) . . ?
C4 C3 C2 123.6(6) . . ?
C5 C4 C3 119.9(6) . . ?
C6 C5 C4 121.0(6) . . ?
C5 C6 C7 119.6(7) . . ?
C8 C7 C6 120.1(7) . . ?
C7 C8 C3 120.8(6) . . ?
C7 C8 C9 121.5(6) . . ?
C3 C8 C9 117.7(5) . . ?
C10 C9 C8 108.2(5) . . ?
C10 C9 C2 113.1(5) . 2_665 ?
C8 C9 C2 112.5(4) . 2_665 ?
C11 C10 C15 119.8(6) . . ?
C11 C10 C9 121.9(6) . . ?
C15 C10 C9 118.3(5) . . ?
C12 C11 C10 121.0(7) . . ?
C11 C12 C13 119.6(6) . . ?
C14 C13 C12 119.2(7) . . ?
C13 C14 C15 121.8(7) . . ?
C14 C15 C10 118.4(5) . . ?
C14 C15 C2 124.5(6) . . ?
C10 C15 C2 117.1(5) . . ?
O2 C16 C17 110.7(8) . . ?
C19 C18 O3 110.2(8) . . ?
C21 C20 P2 122.0(4) . . ?
C34 C21 C22 107.6(5) . . ?
C34 C21 C20 113.1(5) . . ?
C22 C21 C20 112.7(4) . . ?
C34 C21 C28 108.5(4) . 2_775 ?
C22 C21 C28 109.6(4) . 2_775 ?
C20 C21 C28 105.3(5) . 2_775 ?
C23 C22 C27 119.0(5) . . ?
C23 C22 C21 123.6(5) . . ?
C27 C22 C21 117.4(5) . . ?
C24 C23 C22 120.8(6) . . ?
C23 C24 C25 119.9(6) . . ?
C26 C25 C24 119.2(5) . . ?
C27 C26 C25 120.7(6) . . ?
C26 C27 C22 120.5(5) . . ?
C26 C27 C28 121.7(5) . . ?
C22 C27 C28 117.9(5) . . ?
C29 C28 C27 108.4(4) . . ?
C29 C28 C21 112.7(4) . 2_775 ?
C27 C28 C21 114.3(5) . 2_775 ?
C30 C29 C34 120.5(6) . . ?
C30 C29 C28 121.7(5) . . ?
C34 C29 C28 117.7(5) . . ?
C29 C30 C31 120.6(6) . . ?
C32 C31 C30 118.8(7) . . ?
C31 C32 C33 120.8(7) . . ?
C32 C33 C34 121.5(6) . . ?
C33 C34 C29 117.8(6) . . ?
C33 C34 C21 125.1(5) . . ?
C29 C34 C21 117.1(5) . . ?
O5 C35 C36 111.7(9) . . ?
C38 C37 O6 112.4(9) . . ?
C40 C39 P3 124.6(5) . . ?
C39 C40 C53 113.3(5) . . ?
C39 C40 C41 113.7(5) . . ?
C53 C40 C41 107.9(5) . . ?
C39 C40 C47 104.7(5) . 2_676 ?
C53 C40 C47 108.8(4) . 2_676 ?
C41 C40 C47 108.2(4) . 2_676 ?
C42 C41 C46 119.6(5) . . ?
C42 C41 C40 122.8(6) . . ?
C46 C41 C40 117.4(5) . . ?
C43 C42 C41 121.4(6) . . ?
C42 C43 C44 118.9(6) . . ?
C45 C44 C43 119.8(6) . . ?
C46 C45 C44 120.1(6) . . ?
C45 C46 C41 120.0(6) . . ?
C45 C46 C47 121.3(6) . . ?
C41 C46 C47 118.6(5) . . ?
C46 C47 C48 109.0(5) . . ?
C46 C47 C40 113.1(5) . 2_676 ?
C48 C47 C40 112.7(4) . 2_676 ?
C49 C48 C53 120.6(5) . . ?
C49 C48 C47 121.9(6) . . ?
C53 C48 C47 117.5(6) . . ?
C50 C49 C48 120.0(6) . . ?
C49 C50 C51 119.9(7) . . ?
C50 C51 C52 120.4(6) . . ?
C53 C52 C51 121.0(6) . . ?
C52 C53 C48 118.2(6) . . ?
C52 C53 C40 124.5(6) . . ?
C48 C53 C40 117.3(5) . . ?
O8 C54 C55 106.1(9) . . ?
O9 C56 C57 112.3(8) . . ?
C72 C59 C60 107.6(7) . . ?
C72 C59 C58 106.6(9) . . ?
C60 C59 C58 117.3(9) . . ?
C72 C59 C58' 138.4(14) . . ?
C60 C59 C58' 95.0(15) . . ?
C72 C59 C66 110.5(7) . 2_566 ?
C60 C59 C66 107.3(7) . 2_566 ?
C58 C59 C66 107.5(7) . 2_566 ?
C58' C59 C66 94.6(8) . 2_566 ?
C61 C60 C65 121.0(11) . . ?
C61 C60 C59 123.3(10) . . ?
C65 C60 C59 115.5(8) . . ?
C62 C61 C60 118.7(16) . . ?
C61 C62 C63 124.9(18) . . ?
C62 C63 C64 117.0(13) . . ?
C65 C64 C63 118.3(14) . . ?
C64 C65 C60 119.2(11) . . ?
C64 C65 C66 122.7(10) . . ?
C60 C65 C66 118.1(8) . . ?
C67 C66 C65 108.2(8) . . ?
C67 C66 C59 115.7(8) . 2_566 ?
C65 C66 C59 111.6(7) . 2_566 ?
C72 C67 C68 125.4(12) . . ?
C72 C67 C66 118.5(8) . . ?
C68 C67 C66 116.1(12) . . ?
C69 C68 C67 118.5(19) . . ?
C68 C69 C70 123.2(19) . . ?
C69 C70 C71 119.2(13) . . ?
C72 C71 C70 117.3(15) . . ?
C67 C72 C71 115.9(12) . . ?
C67 C72 C59 117.8(8) . . ?
C71 C72 C59 126.3(12) . . ?
C59 C58 P4 122.7(9) . . ?
C74 C73 O20 111.4(11) . . ?
C76 C75 O21 111.5(10) . . ?
C59 C58' P4' 118.8(11) . . ?
C74' C73' O20' 111.1(15) . . ?
C76' C75' O21' 114.6(14) . . ?
O12 N1 O11 122.9(6) . . ?
O12 N1 O10 122.5(6) . . ?
O11 N1 O10 114.6(5) . . ?
O15 N2 O13 121.3(7) . . ?
O15 N2 O14 122.5(8) . . ?
O13 N2 O14 116.2(6) . . ?
O18 N3 O16 122.0(7) . . ?
O18 N3 O17 121.7(7) . . ?
O16 N3 O17 116.3(5) . . ?
P1 O1 Dy1 173.7(3) . . ?
C16 O2 P1 124.6(5) . . ?
C18 O3 P1 118.6(5) . . ?
P2 O4 Dy1 167.5(3) . . ?
C35 O5 P2 126.9(6) . . ?
C37 O6 P2 124.7(6) . . ?
P3 O7 Dy1 154.4(3) . . ?
C54 O8 P3 127.8(7) . . ?
C56 O9 P3 121.2(6) . . ?
N1 O10 Dy1 97.5(4) . . ?
N1 O11 Dy1 96.2(4) . . ?
N2 O13 Dy1 98.2(4) . . ?
N2 O14 Dy1 94.5(4) . . ?
N3 O16 Dy1 95.4(4) . . ?
N3 O17 Dy1 96.5(4) . . ?
O19 P4 O20 115.0(6) . . ?
O19 P4 O21 113.4(5) . . ?
O20 P4 O21 104.3(5) . . ?
O19 P4 C58 113.5(7) . . ?
O20 P4 C58 106.4(5) . . ?
O21 P4 C58 103.2(6) . . ?
C73 O20 P4 126.5(8) . . ?
C75 O21 P4 125.6(8) . . ?
O19' P4' O20' 113.8(12) . . ?
O19' P4' O21' 114.4(13) . . ?
O20' P4' O21' 103.6(12) . . ?
O19' P4' C58' 114.1(15) . . ?
O20' P4' C58' 105.5(10) . . ?
O21' P4' C58' 104.4(13) . . ?
C75' O21' P4' 127.4(13) . . ?
C73' O20' P4' 125.7(14) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O1 P1 C1 C2 -118.3(4) . . . . ?
O2 P1 C1 C2 8.9(5) . . . . ?
O3 P1 C1 C2 120.0(4) . . . . ?
P1 C1 C2 C3 -64.2(6) . . . . ?
P1 C1 C2 C15 58.4(6) . . . . ?
P1 C1 C2 C9 176.5(4) . . . 2_665 ?
C15 C2 C3 C8 43.8(6) . . . . ?
C1 C2 C3 C8 168.6(5) . . . . ?
C9 C2 C3 C8 -74.1(6) 2_665 . . . ?
C15 C2 C3 C4 -138.3(6) . . . . ?
C1 C2 C3 C4 -13.4(8) . . . . ?
C9 C2 C3 C4 103.8(6) 2_665 . . . ?
C8 C3 C4 C5 -1.9(9) . . . . ?
C2 C3 C4 C5 -179.8(6) . . . . ?
C3 C4 C5 C6 0.8(11) . . . . ?
C4 C5 C6 C7 0.4(12) . . . . ?
C5 C6 C7 C8 -0.5(12) . . . . ?
C6 C7 C8 C3 -0.5(11) . . . . ?
C6 C7 C8 C9 -179.5(7) . . . . ?
C4 C3 C8 C7 1.7(9) . . . . ?
C2 C3 C8 C7 179.8(6) . . . . ?
C4 C3 C8 C9 -179.2(5) . . . . ?
C2 C3 C8 C9 -1.2(8) . . . . ?
C7 C8 C9 C10 136.0(6) . . . . ?
C3 C8 C9 C10 -43.0(7) . . . . ?
C7 C8 C9 C2 -98.3(7) . . . 2_665 ?
C3 C8 C9 C2 82.7(6) . . . 2_665 ?
C8 C9 C10 C11 -136.8(6) . . . . ?
C2 C9 C10 C11 97.8(7) 2_665 . . . ?
C8 C9 C10 C15 45.0(7) . . . . ?
C2 C9 C10 C15 -80.4(6) 2_665 . . . ?
C15 C10 C11 C12 1.5(10) . . . . ?
C9 C10 C11 C12 -176.7(6) . . . . ?
C10 C11 C12 C13 1.3(12) . . . . ?
C11 C12 C13 C14 -3.1(13) . . . . ?
C12 C13 C14 C15 2.2(12) . . . . ?
C13 C14 C15 C10 0.6(10) . . . . ?
C13 C14 C15 C2 178.6(7) . . . . ?
C11 C10 C15 C14 -2.4(9) . . . . ?
C9 C10 C15 C14 175.8(6) . . . . ?
C11 C10 C15 C2 179.4(6) . . . . ?
C9 C10 C15 C2 -2.4(8) . . . . ?
C3 C2 C15 C14 140.2(6) . . . . ?
C1 C2 C15 C14 15.2(8) . . . . ?
C9 C2 C15 C14 -101.3(7) 2_665 . . . ?
C3 C2 C15 C10 -41.8(7) . . . . ?
C1 C2 C15 C10 -166.7(5) . . . . ?
C9 C2 C15 C10 76.7(6) 2_665 . . . ?
O4 P2 C20 C21 120.1(5) . . . . ?
O6 P2 C20 C21 -6.6(6) . . . . ?
O5 P2 C20 C21 -120.5(5) . . . . ?
P2 C20 C21 C34 60.8(6) . . . . ?
P2 C20 C21 C22 -61.4(7) . . . . ?
P2 C20 C21 C28 179.1(4) . . . 2_775 ?
C34 C21 C22 C23 -136.9(6) . . . . ?
C20 C21 C22 C23 -11.6(8) . . . . ?
C28 C21 C22 C23 105.3(6) 2_775 . . . ?
C34 C21 C22 C27 44.1(7) . . . . ?
C20 C21 C22 C27 169.4(5) . . . . ?
C28 C21 C22 C27 -73.7(7) 2_775 . . . ?
C27 C22 C23 C24 -1.6(9) . . . . ?
C21 C22 C23 C24 179.4(6) . . . . ?
C22 C23 C24 C25 0.7(10) . . . . ?
C23 C24 C25 C26 0.8(10) . . . . ?
C24 C25 C26 C27 -1.5(10) . . . . ?
C25 C26 C27 C22 0.6(10) . . . . ?
C25 C26 C27 C28 -179.6(6) . . . . ?
C23 C22 C27 C26 0.9(9) . . . . ?
C21 C22 C27 C26 180.0(6) . . . . ?
C23 C22 C27 C28 -178.9(5) . . . . ?
C21 C22 C27 C28 0.2(8) . . . . ?
C26 C27 C28 C29 135.7(6) . . . . ?
C22 C27 C28 C29 -44.5(7) . . . . ?
C26 C27 C28 C21 -97.7(7) . . . 2_775 ?
C22 C27 C28 C21 82.0(6) . . . 2_775 ?
C27 C28 C29 C30 -135.4(5) . . . . ?
C21 C28 C29 C30 97.1(6) 2_775 . . . ?
C27 C28 C29 C34 43.9(6) . . . . ?
C21 C28 C29 C34 -83.6(6) 2_775 . . . ?
C34 C29 C30 C31 0.1(8) . . . . ?
C28 C29 C30 C31 179.4(5) . . . . ?
C29 C30 C31 C32 0.6(9) . . . . ?
C30 C31 C32 C33 -0.4(10) . . . . ?
C31 C32 C33 C34 -0.6(10) . . . . ?
C32 C33 C34 C29 1.3(9) . . . . ?
C32 C33 C34 C21 -179.9(6) . . . . ?
C30 C29 C34 C33 -1.1(8) . . . . ?
C28 C29 C34 C33 179.7(5) . . . . ?
C30 C29 C34 C21 180.0(5) . . . . ?
C28 C29 C34 C21 0.7(7) . . . . ?
C22 C21 C34 C33 136.7(6) . . . . ?
C20 C21 C34 C33 11.6(8) . . . . ?
C28 C21 C34 C33 -104.8(6) 2_775 . . . ?
C22 C21 C34 C29 -44.5(6) . . . . ?
C20 C21 C34 C29 -169.6(5) . . . . ?
C28 C21 C34 C29 74.0(6) 2_775 . . . ?
O7 P3 C39 C40 123.0(5) . . . . ?
O8 P3 C39 C40 -14.5(7) . . . . ?
O9 P3 C39 C40 -119.7(6) . . . . ?
P3 C39 C40 C53 66.5(7) . . . . ?
P3 C39 C40 C41 -57.3(7) . . . . ?
P3 C39 C40 C47 -175.1(4) . . . 2_676 ?
C39 C40 C41 C42 -15.3(9) . . . . ?
C53 C40 C41 C42 -141.9(6) . . . . ?
C47 C40 C41 C42 100.6(7) 2_676 . . . ?
C39 C40 C41 C46 168.6(6) . . . . ?
C53 C40 C41 C46 41.9(7) . . . . ?
C47 C40 C41 C46 -75.6(7) 2_676 . . . ?
C46 C41 C42 C43 -1.9(10) . . . . ?
C40 C41 C42 C43 -178.0(6) . . . . ?
C41 C42 C43 C44 -0.2(10) . . . . ?
C42 C43 C44 C45 0.9(11) . . . . ?
C43 C44 C45 C46 0.5(11) . . . . ?
C44 C45 C46 C41 -2.7(10) . . . . ?
C44 C45 C46 C47 175.4(6) . . . . ?
C42 C41 C46 C45 3.4(10) . . . . ?
C40 C41 C46 C45 179.6(6) . . . . ?
C42 C41 C46 C47 -174.7(6) . . . . ?
C40 C41 C46 C47 1.6(9) . . . . ?
C45 C46 C47 C48 137.2(6) . . . . ?
C41 C46 C47 C48 -44.8(8) . . . . ?
C45 C46 C47 C40 -96.7(7) . . . 2_676 ?
C41 C46 C47 C40 81.4(7) . . . 2_676 ?
C46 C47 C48 C49 -139.2(6) . . . . ?
C40 C47 C48 C49 94.4(7) 2_676 . . . ?
C46 C47 C48 C53 43.2(7) . . . . ?
C40 C47 C48 C53 -83.2(6) 2_676 . . . ?
C53 C48 C49 C50 0.1(9) . . . . ?
C47 C48 C49 C50 -177.3(6) . . . . ?
C48 C49 C50 C51 -0.8(10) . . . . ?
C49 C50 C51 C52 1.0(10) . . . . ?
C50 C51 C52 C53 -0.6(10) . . . . ?
C51 C52 C53 C48 -0.1(9) . . . . ?
C51 C52 C53 C40 176.9(6) . . . . ?
C49 C48 C53 C52 0.3(9) . . . . ?
C47 C48 C53 C52 177.9(5) . . . . ?
C49 C48 C53 C40 -176.9(5) . . . . ?
C47 C48 C53 C40 0.7(8) . . . . ?
C39 C40 C53 C52 13.2(9) . . . . ?
C41 C40 C53 C52 140.1(6) . . . . ?
C47 C40 C53 C52 -102.8(7) 2_676 . . . ?
C39 C40 C53 C48 -169.7(5) . . . . ?
C41 C40 C53 C48 -42.8(7) . . . . ?
C47 C40 C53 C48 74.3(6) 2_676 . . . ?
C72 C59 C60 C61 -134.6(12) . . . . ?
C58 C59 C60 C61 -14.6(16) . . . . ?
C58' C59 C60 C61 10.0(15) . . . . ?
C66 C59 C60 C61 106.4(12) 2_566 . . . ?
C72 C59 C60 C65 41.0(10) . . . . ?
C58 C59 C60 C65 161.0(9) . . . . ?
C58' C59 C60 C65 -174.4(10) . . . . ?
C66 C59 C60 C65 -78.0(9) 2_566 . . . ?
C65 C60 C61 C62 2(2) . . . . ?
C59 C60 C61 C62 177.2(15) . . . . ?
C60 C61 C62 C63 4(3) . . . . ?
C61 C62 C63 C64 -10(4) . . . . ?
C62 C63 C64 C65 10(3) . . . . ?
C63 C64 C65 C60 -4.4(16) . . . . ?
C63 C64 C65 C66 176.3(11) . . . . ?
C61 C60 C65 C64 -1.4(16) . . . . ?
C59 C60 C65 C64 -177.1(9) . . . . ?
C61 C60 C65 C66 177.9(11) . . . . ?
C59 C60 C65 C66 2.2(12) . . . . ?
C64 C65 C66 C67 132.3(10) . . . . ?
C60 C65 C66 C67 -47.0(10) . . . . ?
C64 C65 C66 C59 -99.2(10) . . . 2_566 ?
C60 C65 C66 C59 81.5(9) . . . 2_566 ?
C65 C66 C67 C72 48.0(13) . . . . ?
C59 C66 C67 C72 -78.1(13) 2_566 . . . ?
C65 C66 C67 C68 -133.6(12) . . . . ?
C59 C66 C67 C68 100.4(12) 2_566 . . . ?
C72 C67 C68 C69 0(3) . . . . ?
C66 C67 C68 C69 -179(2) . . . . ?
C67 C68 C69 C70 -1(4) . . . . ?
C68 C69 C70 C71 5(4) . . . . ?
C69 C70 C71 C72 -8(3) . . . . ?
C68 C67 C72 C71 -3(2) . . . . ?
C66 C67 C72 C71 175.8(11) . . . . ?
C68 C67 C72 C59 178.4(13) . . . . ?
C66 C67 C72 C59 -3.3(16) . . . . ?
C70 C71 C72 C67 6.3(19) . . . . ?
C70 C71 C72 C59 -174.7(12) . . . . ?
C60 C59 C72 C67 -41.3(12) . . . . ?
C58 C59 C72 C67 -168.0(10) . . . . ?
C58' C59 C72 C67 -161.1(17) . . . . ?
C66 C59 C72 C67 75.5(11) 2_566 . . . ?
C60 C59 C72 C71 139.7(11) . . . . ?
C58 C59 C72 C71 13.1(15) . . . . ?
C58' C59 C72 C71 20(2) . . . . ?
C66 C59 C72 C71 -103.5(12) 2_566 . . . ?
C72 C59 C58 P4 65.0(13) . . . . ?
C60 C59 C58 P4 -55.6(15) . . . . ?
C66 C59 C58 P4 -176.4(10) 2_566 . . . ?
C72 C59 C58' P4' 53(3) . . . . ?
C60 C59 C58' P4' -71(2) . . . . ?
C66 C59 C58' P4' -179(2) 2_566 . . . ?
C17 C16 O2 P1 -94.8(9) . . . . ?
O1 P1 O2 C16 8.1(6) . . . . ?
O3 P1 O2 C16 131.7(6) . . . . ?
C1 P1 O2 C16 -118.5(6) . . . . ?
C19 C18 O3 P1 136.0(9) . . . . ?
O1 P1 O3 C18 63.8(6) . . . . ?
O2 P1 O3 C18 -60.0(6) . . . . ?
C1 P1 O3 C18 -175.0(6) . . . . ?
O6 P2 O4 Dy1 -96.8(15) . . . . ?
O5 P2 O4 Dy1 26.3(16) . . . . ?
C20 P2 O4 Dy1 138.0(14) . . . . ?
C36 C35 O5 P2 167.8(8) . . . . ?
O4 P2 O5 C35 -68.7(8) . . . . ?
O6 P2 O5 C35 56.6(8) . . . . ?
C20 P2 O5 C35 171.5(7) . . . . ?
C38 C37 O6 P2 -157.7(9) . . . . ?
O4 P2 O6 C37 -0.1(8) . . . . ?
O5 P2 O6 C37 -125.4(7) . . . . ?
C20 P2 O6 C37 126.6(7) . . . . ?
O8 P3 O7 Dy1 152.1(6) . . . . ?
O9 P3 O7 Dy1 -91.9(7) . . . . ?
C39 P3 O7 Dy1 19.6(8) . . . . ?
C55 C54 O8 P3 139.1(8) . . . . ?
O7 P3 O8 C54 -25.4(9) . . . . ?
O9 P3 O8 C54 -145.9(8) . . . . ?
C39 P3 O8 C54 109.7(8) . . . . ?
C57 C56 O9 P3 -132.6(9) . . . . ?
O7 P3 O9 C56 -51.3(8) . . . . ?
O8 P3 O9 C56 76.1(8) . . . . ?
C39 P3 O9 C56 -172.5(8) . . . . ?
O12 N1 O10 Dy1 -179.3(6) . . . . ?
O11 N1 O10 Dy1 0.9(7) . . . . ?
O12 N1 O11 Dy1 179.3(7) . . . . ?
O10 N1 O11 Dy1 -0.8(7) . . . . ?
O15 N2 O13 Dy1 -174.4(9) . . . . ?
O14 N2 O13 Dy1 3.3(9) . . . . ?
O15 N2 O14 Dy1 174.5(10) . . . . ?
O13 N2 O14 Dy1 -3.2(9) . . . . ?
O18 N3 O16 Dy1 179.0(7) . . . . ?
O17 N3 O16 Dy1 -3.4(7) . . . . ?
O18 N3 O17 Dy1 -179.0(7) . . . . ?
O16 N3 O17 Dy1 3.4(7) . . . . ?
C59 C58 P4 O19 115.9(12) . . . . ?
C59 C58 P4 O20 -11.5(14) . . . . ?
C59 C58 P4 O21 -120.9(11) . . . . ?
C74 C73 O20 P4 -77.1(14) . . . . ?
O19 P4 O20 C73 89.5(11) . . . . ?
O21 P4 O20 C73 -35.3(11) . . . . ?
C58 P4 O20 C73 -144.0(11) . . . . ?
C76 C75 O21 P4 109.2(13) . . . . ?
O19 P4 O21 C75 -10.7(12) . . . . ?
O20 P4 O21 C75 115.1(10) . . . . ?
C58 P4 O21 C75 -133.9(10) . . . . ?
C59 C58' P4' O19' -111(2) . . . . ?
C59 C58' P4' O20' 14(3) . . . . ?
C59 C58' P4' O21' 123(2) . . . . ?
C76' C75' O21' P4' 47(4) . . . . ?
O19' P4' O21' C75' 68(2) . . . . ?
O20' P4' O21' C75' -56(2) . . . . ?
C58' P4' O21' C75' -166(2) . . . . ?
C74' C73' O20' P4' -92(3) . . . . ?
O19' P4' O20' C73' 3(3) . . . . ?
O21' P4' O20' C73' 127(2) . . . . ?
C58' P4' O20' C73' -123(2) . . . . ?

_refine_diff_density_max         2.269
_refine_diff_density_min         -1.491
_refine_diff_density_rms         0.136


# start Validation Reply Form
_vrf_PLAT241_2                   
;
PROBLEM: High 'MainMol' Ueq as Compared to Neighbors of C69 Check
RESPONSE:This alert may originate from the disordered guest of depma2.
;
# end Validation Reply Form
_exptl_crystal_recrystallization_method desolvation
_chemical_properties_physical    
Heat-sensitive,Light-sensitive,Photo-sensitive
_exptl_crystal_preparation       Luminescent,mechanical
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_3
_database_code_depnum_ccdc_archive 'CCDC 2214248'
loop_
_audit_author_name
_audit_author_address
'Xinda Huang'
;Nanjing University
China
;
_audit_update_record             
;
2022-10-20 deposited with the CCDC.	2023-01-27 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        '[Dy(NO3)3(depma)(depma2)].(depma2)0.5'
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C57 H63 Dy N3 O18 P3, (C19 H21 O3 P)'
_chemical_formula_sum            'C76 H84 Dy N3 O21 P4'
_chemical_formula_weight         1661.84

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   12.1321(10)
_cell_length_b                   13.3341(10)
_cell_length_c                   23.3083(17)
_cell_angle_alpha                90.473(3)
_cell_angle_beta                 95.995(3)
_cell_angle_gamma                92.718(3)
_cell_volume                     3745.4(5)
_cell_formula_units_Z            2
_cell_measurement_temperature    193(2)
_cell_measurement_reflns_used    9942
_cell_measurement_theta_min      2.2235
_cell_measurement_theta_max      27.0235

_exptl_crystal_description       rod
_exptl_crystal_colour            'pale yellow'
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.474
_exptl_crystal_F_000             1710
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.500
_exptl_crystal_size_mid          0.150
_exptl_crystal_size_min          0.100
_exptl_absorpt_coefficient_mu    1.159
_shelx_estimated_absorpt_T_min   0.595
_shelx_estimated_absorpt_T_max   0.893
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.812
_exptl_absorpt_correction_T_max  0.893
_exptl_absorpt_process_details   'SADABS 2016/2'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      193(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker D8 Venture'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            34296
_diffrn_reflns_av_unetI/netI     0.0618
_diffrn_reflns_av_R_equivalents  0.0384
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_theta_min         2.223
_diffrn_reflns_theta_max         27.119
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.987
_diffrn_measured_fraction_theta_full 0.990
_diffrn_reflns_Laue_measured_fraction_max 0.987
_diffrn_reflns_Laue_measured_fraction_full 0.990
_diffrn_reflns_point_group_measured_fraction_max 0.987
_diffrn_reflns_point_group_measured_fraction_full 0.990
_reflns_number_total             16351
_reflns_number_gt                12311
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker APEX3'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXT 2014/4 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0805P)²+8.0170P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         16351
_refine_ls_number_parameters     954
_refine_ls_number_restraints     996
_refine_ls_R_factor_all          0.0827
_refine_ls_R_factor_gt           0.0581
_refine_ls_wR_factor_ref         0.1703
_refine_ls_wR_factor_gt          0.1485
_refine_ls_goodness_of_fit_ref   1.034
_refine_ls_restrained_S_all      1.095
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.18908(2) 0.32022(2) 0.25078(2) 0.04261(10) Uani 1 1 d . . . . .
P1 P 0.25666(12) 0.13793(10) 0.13750(6) 0.0411(3) Uani 1 1 d . U . . .
P2 P 0.39728(12) 0.48816(11) 0.18333(6) 0.0438(3) Uani 1 1 d . U . . .
P3 P 0.06754(16) 0.54179(14) 0.31146(6) 0.0577(4) Uani 1 1 d . U . . .
P4 P 0.6589(2) 0.07022(19) 0.33291(9) 0.0793(6) Uani 1 1 d . U . . .
C1 C 0.1672(4) 0.1565(3) 0.07184(19) 0.0312(9) Uani 1 1 d . U . . .
H1A H 0.117641 0.210761 0.079563 0.037 Uiso 1 1 calc R U . . .
H1B H 0.214746 0.181826 0.042559 0.037 Uiso 1 1 calc R U . . .
C2 C 0.0933(4) 0.0676(3) 0.04393(18) 0.0291(8) Uani 1 1 d . U . . .
C3 C 0.1602(4) -0.0164(3) 0.0237(2) 0.0326(8) Uani 1 1 d . U . . .
C4 C 0.2732(4) -0.0080(4) 0.0206(3) 0.0442(10) Uani 1 1 d . U . . .
H4 H 0.312802 0.053901 0.030736 0.053 Uiso 1 1 calc R U . . .
C5 C 0.3299(5) -0.0894(4) 0.0029(3) 0.0613(13) Uani 1 1 d . U . . .
H5 H 0.408042 -0.083571 0.001822 0.074 Uiso 1 1 calc R U . . .
C6 C 0.2717(5) -0.1788(5) -0.0131(4) 0.0664(14) Uani 1 1 d . U . . .
H6 H 0.309827 -0.234477 -0.025346 0.080 Uiso 1 1 calc R U . . .
C7 C 0.1582(5) -0.1873(4) -0.0114(3) 0.0538(12) Uani 1 1 d . U . . .
H7 H 0.118503 -0.248405 -0.023140 0.065 Uiso 1 1 calc R U . . .
C8 C 0.1021(4) -0.1081(3) 0.0072(2) 0.0350(9) Uani 1 1 d . U . . .
C9 C -0.0211(4) -0.1154(3) 0.01133(19) 0.0298(8) Uani 1 1 d . U . . .
H9 H -0.044042 -0.188331 0.012456 0.036 Uiso 1 1 calc R U . . .
C10 C -0.0418(4) -0.0692(4) 0.0679(2) 0.0350(9) Uani 1 1 d . U . . .
C11 C -0.1134(5) -0.1157(4) 0.1030(2) 0.0516(12) Uani 1 1 d . U . . .
H11 H -0.148399 -0.179179 0.092101 0.062 Uiso 1 1 calc R U . . .
C12 C -0.1340(6) -0.0698(5) 0.1539(3) 0.0687(14) Uani 1 1 d . U . . .
H12 H -0.183133 -0.101963 0.177937 0.082 Uiso 1 1 calc R U . . .
C13 C -0.0833(6) 0.0226(5) 0.1701(3) 0.0690(14) Uani 1 1 d . U . . .
H13 H -0.098158 0.054446 0.204885 0.083 Uiso 1 1 calc R U . . .
C14 C -0.0099(5) 0.0690(5) 0.1347(2) 0.0535(12) Uani 1 1 d . U . . .
H14 H 0.024441 0.132839 0.145510 0.064 Uiso 1 1 calc R U . . .
C15 C 0.0130(4) 0.0232(4) 0.0845(2) 0.0362(9) Uani 1 1 d . U . . .
C16 C 0.2247(7) -0.0177(6) 0.2048(3) 0.095(2) Uani 1 1 d D U . . .
H16A H 0.159769 0.017204 0.215958 0.114 Uiso 1 1 calc R U . . .
H16B H 0.200670 -0.088922 0.197109 0.114 Uiso 1 1 calc R U . . .
C17 C 0.3064(10) -0.0137(10) 0.2520(4) 0.147(4) Uani 1 1 d D U . . .
H17A H 0.361139 -0.063727 0.246600 0.220 Uiso 1 1 calc R U . . .
H17B H 0.271941 -0.027882 0.287414 0.220 Uiso 1 1 calc R U . . .
H17C H 0.343321 0.053443 0.254918 0.220 Uiso 1 1 calc R U . . .
C18 C 0.4736(5) 0.1466(5) 0.1598(3) 0.0670(15) Uani 1 1 d D U . . .
H18A H 0.518555 0.210126 0.167413 0.080 Uiso 1 1 calc R U . . .
H18B H 0.450025 0.122499 0.196929 0.080 Uiso 1 1 calc R U . . .
C19 C 0.5388(8) 0.0739(9) 0.1364(4) 0.122(3) Uani 1 1 d D U . . .
H19A H 0.491201 0.015153 0.122915 0.183 Uiso 1 1 calc R U . . .
H19B H 0.596248 0.053546 0.166099 0.183 Uiso 1 1 calc R U . . .
H19C H 0.573844 0.102879 0.103865 0.183 Uiso 1 1 calc R U . . .
C20 C 0.4720(4) 0.4350(4) 0.1288(2) 0.0357(10) Uani 1 1 d . U . . .
H20A H 0.550305 0.432771 0.145397 0.043 Uiso 1 1 calc R U . . .
H20B H 0.443508 0.364454 0.122866 0.043 Uiso 1 1 calc R U . . .
C21 C 0.4730(4) 0.4815(3) 0.06832(19) 0.0295(9) Uani 1 1 d . U . . .
C22 C 0.5214(4) 0.5898(3) 0.0694(2) 0.0326(9) Uani 1 1 d . U . . .
C23 C 0.5781(5) 0.6366(4) 0.1175(2) 0.0438(12) Uani 1 1 d . U . . .
H23 H 0.589800 0.600850 0.152507 0.053 Uiso 1 1 calc R U . . .
C24 C 0.6184(5) 0.7361(4) 0.1151(3) 0.0507(13) Uani 1 1 d . U . . .
H24 H 0.654335 0.768652 0.148880 0.061 Uiso 1 1 calc R U . . .
C25 C 0.6062(5) 0.7873(4) 0.0639(3) 0.0474(12) Uani 1 1 d . U . . .
H25 H 0.635199 0.854504 0.062040 0.057 Uiso 1 1 calc R U . . .
C26 C 0.5517(4) 0.7405(4) 0.0155(2) 0.0393(10) Uani 1 1 d . U . . .
H26 H 0.542657 0.775832 -0.019795 0.047 Uiso 1 1 calc R U . . .
C27 C 0.5097(4) 0.6420(3) 0.0177(2) 0.0320(9) Uani 1 1 d . U . . .
C28 C 0.4485(4) 0.5895(3) -0.0344(2) 0.0305(9) Uani 1 1 d . U . . .
H28 H 0.422008 0.642711 -0.061758 0.037 Uiso 1 1 calc R U . . .
C29 C 0.3465(4) 0.5337(3) -0.0161(2) 0.0312(9) Uani 1 1 d . U . . .
C30 C 0.2441(4) 0.5369(4) -0.0482(2) 0.0397(11) Uani 1 1 d . U . . .
H30 H 0.236912 0.574186 -0.082866 0.048 Uiso 1 1 calc R U . . .
C31 C 0.1521(4) 0.4859(4) -0.0301(2) 0.0435(11) Uani 1 1 d . U . . .
H31 H 0.082057 0.488491 -0.052373 0.052 Uiso 1 1 calc R U . . .
C32 C 0.1617(4) 0.4311(4) 0.0203(2) 0.0381(10) Uani 1 1 d . U . . .
H32 H 0.098672 0.395851 0.032607 0.046 Uiso 1 1 calc R U . . .
C33 C 0.2648(4) 0.4283(3) 0.0527(2) 0.0338(9) Uani 1 1 d . U . . .
H33 H 0.271771 0.390616 0.087174 0.041 Uiso 1 1 calc R U . . .
C34 C 0.3573(4) 0.4799(3) 0.0352(2) 0.0292(9) Uani 1 1 d . U . . .
C35 C 0.4864(6) 0.5685(7) 0.2820(3) 0.085(2) Uani 1 1 d D U . . .
H35A H 0.429214 0.533658 0.302988 0.101 Uiso 1 1 calc R U . . .
H35B H 0.462613 0.637263 0.273356 0.101 Uiso 1 1 calc R U . . .
C36 C 0.5892(8) 0.5736(10) 0.3169(4) 0.135(4) Uani 1 1 d D U . . .
H36A H 0.640029 0.528203 0.301138 0.202 Uiso 1 1 calc R U . . .
H36B H 0.577573 0.553517 0.356289 0.202 Uiso 1 1 calc R U . . .
H36C H 0.621289 0.642470 0.317559 0.202 Uiso 1 1 calc R U . . .
C37 C 0.2342(5) 0.6132(6) 0.1622(4) 0.079(2) Uani 1 1 d D U . . .
H37A H 0.184766 0.552055 0.155435 0.095 Uiso 1 1 calc R U . . .
H37B H 0.224668 0.640030 0.201005 0.095 Uiso 1 1 calc R U . . .
C38 C 0.2016(10) 0.6847(9) 0.1210(6) 0.147(5) Uani 1 1 d D U . . .
H38A H 0.209292 0.751766 0.138870 0.221 Uiso 1 1 calc R U . . .
H38B H 0.123977 0.670168 0.105830 0.221 Uiso 1 1 calc R U . . .
H38C H 0.248642 0.682233 0.089316 0.221 Uiso 1 1 calc R U . . .
C39 C 0.0291(7) 0.4908(5) 0.3782(2) 0.0644(16) Uani 1 1 d . U . . .
H39A H -0.051012 0.470992 0.372659 0.077 Uiso 1 1 calc R U . . .
H39B H 0.069604 0.428752 0.385853 0.077 Uiso 1 1 calc R U . . .
C40 C 0.0497(7) 0.5570(5) 0.4313(2) 0.0656(15) Uani 1 1 d . U . . .
C41 C 0.1502(8) 0.5554(5) 0.4660(3) 0.0697(16) Uani 1 1 d . U . . .
C42 C 0.2389(8) 0.4941(6) 0.4524(3) 0.084(2) Uani 1 1 d . U . . .
H42 H 0.229915 0.454762 0.417897 0.101 Uiso 1 1 calc R U . . .
C43 C 0.3346(10) 0.4913(7) 0.4876(4) 0.100(2) Uani 1 1 d . U . . .
H43 H 0.390839 0.448750 0.478087 0.120 Uiso 1 1 calc R U . . .
C44 C 0.3523(10) 0.5517(7) 0.5393(4) 0.100(2) Uani 1 1 d . U . . .
H44 H 0.420234 0.549921 0.563487 0.120 Uiso 1 1 calc R U . . .
C45 C 0.2732(9) 0.6103(7) 0.5530(3) 0.091(2) Uani 1 1 d . U . . .
H45 H 0.285678 0.650287 0.587168 0.110 Uiso 1 1 calc R U . . .
C46 C 0.1702(8) 0.6147(5) 0.5180(3) 0.0772(17) Uani 1 1 d . U . . .
C47 C 0.0878(8) 0.6754(5) 0.5324(3) 0.0784(18) Uani 1 1 d . U . . .
H47 H 0.100471 0.715236 0.566623 0.094 Uiso 1 1 calc R U . . .
C48 C -0.0109(8) 0.6800(5) 0.4992(3) 0.0750(17) Uani 1 1 d . U . . .
C49 C -0.0955(9) 0.7458(6) 0.5133(4) 0.088(2) Uani 1 1 d . U . . .
H49 H -0.082496 0.786808 0.547082 0.106 Uiso 1 1 calc R U . . .
C50 C -0.1894(9) 0.7501(8) 0.4808(4) 0.102(2) Uani 1 1 d . U . . .
H50 H -0.243513 0.794011 0.491492 0.122 Uiso 1 1 calc R U . . .
C51 C -0.2123(9) 0.6909(7) 0.4301(4) 0.098(2) Uani 1 1 d . U . . .
H51 H -0.281323 0.694738 0.407079 0.117 Uiso 1 1 calc R U . . .
C52 C -0.1353(8) 0.6284(6) 0.4142(3) 0.0812(19) Uani 1 1 d . U . . .
H52 H -0.151534 0.588887 0.380017 0.097 Uiso 1 1 calc R U . . .
C53 C -0.0325(7) 0.6206(5) 0.4470(3) 0.0697(16) Uani 1 1 d . U . . .
C54 C 0.1299(9) 0.7325(5) 0.3461(3) 0.098(2) Uani 1 1 d D U . . .
H54A H 0.185071 0.751606 0.379184 0.118 Uiso 1 1 calc R U . . .
H54B H 0.055707 0.727598 0.360255 0.118 Uiso 1 1 calc R U . . .
C55 C 0.1316(10) 0.8083(7) 0.3032(4) 0.125(4) Uani 1 1 d D U . . .
H55A H 0.204537 0.812482 0.288613 0.187 Uiso 1 1 calc R U . . .
H55B H 0.116919 0.873222 0.320145 0.187 Uiso 1 1 calc R U . . .
H55C H 0.074329 0.791289 0.271273 0.187 Uiso 1 1 calc R U . . .
C56 C -0.0572(9) 0.5912(11) 0.2202(3) 0.133(3) Uani 1 1 d D U . . .
H56A H -0.005250 0.645924 0.209698 0.159 Uiso 1 1 calc R U . . .
H56B H -0.036695 0.528696 0.201612 0.159 Uiso 1 1 calc R U . . .
C57 C -0.1626(10) 0.6125(13) 0.1978(5) 0.170(5) Uani 1 1 d D U . . .
H57A H -0.214852 0.558174 0.206892 0.255 Uiso 1 1 calc R U . . .
H57B H -0.164951 0.618921 0.155796 0.255 Uiso 1 1 calc R U . . .
H57C H -0.183069 0.675720 0.214584 0.255 Uiso 1 1 calc R U . . .
C58 C 0.5667(5) 0.0994(5) 0.3849(3) 0.0568(14) Uani 1 1 d . U . . .
H58A H 0.589243 0.168366 0.399048 0.068 Uiso 1 1 calc R U . . .
H58B H 0.492530 0.103491 0.363182 0.068 Uiso 1 1 calc R U . . .
C59 C 0.5491(5) 0.0371(4) 0.4390(3) 0.0467(12) Uani 1 1 d . U . . .
C60 C 0.6540(5) 0.0344(4) 0.4820(3) 0.0475(12) Uani 1 1 d . U . . .
C61 C 0.7500(5) 0.0936(4) 0.4791(3) 0.0612(16) Uani 1 1 d . U . . .
H61 H 0.752774 0.141520 0.449285 0.073 Uiso 1 1 calc R U . . .
C62 C 0.8416(6) 0.0846(5) 0.5186(4) 0.0740(19) Uani 1 1 d . U . . .
H62 H 0.907429 0.124479 0.514967 0.089 Uiso 1 1 calc R U . . .
C63 C 0.8382(6) 0.0173(5) 0.5637(4) 0.0705(18) Uani 1 1 d . U . . .
H63 H 0.901590 0.009890 0.590672 0.085 Uiso 1 1 calc R U . . .
C64 C 0.7406(5) -0.0387(4) 0.5687(3) 0.0581(15) Uani 1 1 d . U . . .
H64 H 0.735997 -0.082681 0.600284 0.070 Uiso 1 1 calc R U . . .
C65 C 0.6503(5) -0.0312(4) 0.5282(3) 0.0461(12) Uani 1 1 d . U . . .
C66 C 0.5456(5) -0.0955(4) 0.5308(2) 0.0444(12) Uani 1 1 d . U . . .
H66 H 0.565438 -0.154173 0.555542 0.053 Uiso 1 1 calc R U . . .
C67 C 0.5062(5) -0.1361(4) 0.4718(3) 0.0448(11) Uani 1 1 d . U . . .
C68 C 0.4673(6) -0.2354(5) 0.4632(3) 0.0599(15) Uani 1 1 d . U . . .
H68 H 0.466163 -0.279098 0.495077 0.072 Uiso 1 1 calc R U . . .
C69 C 0.4304(7) -0.2706(5) 0.4084(4) 0.0761(19) Uani 1 1 d . U . . .
H69 H 0.403175 -0.338273 0.402493 0.091 Uiso 1 1 calc R U . . .
C70 C 0.4334(7) -0.2069(6) 0.3620(4) 0.0787(19) Uani 1 1 d . U . . .
H70 H 0.408963 -0.230868 0.324148 0.094 Uiso 1 1 calc R U . . .
C71 C 0.4722(6) -0.1076(5) 0.3709(3) 0.0659(16) Uani 1 1 d . U . . .
H71 H 0.473199 -0.064021 0.338918 0.079 Uiso 1 1 calc R U . . .
C72 C 0.5092(5) -0.0715(4) 0.4253(3) 0.0478(12) Uani 1 1 d . U . . .
C73 C 0.7688(10) 0.2142(7) 0.2816(4) 0.114(3) Uani 1 1 d D U . . .
H73A H 0.850733 0.222364 0.287741 0.137 Uiso 1 1 calc R U . . .
H73B H 0.749204 0.166857 0.248755 0.137 Uiso 1 1 calc R U . . .
C74 C 0.7252(12) 0.3078(7) 0.2673(6) 0.142(4) Uani 1 1 d D U . . .
H74A H 0.646263 0.305921 0.273123 0.213 Uiso 1 1 calc R U . . .
H74B H 0.733730 0.322219 0.226788 0.213 Uiso 1 1 calc R U . . .
H74C H 0.765087 0.360330 0.291994 0.213 Uiso 1 1 calc R U . . .
C75 C 0.8236(12) -0.0702(11) 0.3618(6) 0.179(4) Uani 1 1 d D U . . .
H75A H 0.893958 -0.031318 0.373841 0.215 Uiso 1 1 calc R U . . .
H75B H 0.812953 -0.120261 0.392124 0.215 Uiso 1 1 calc R U . . .
C76 C 0.8365(17) -0.1212(13) 0.3119(7) 0.227(7) Uani 1 1 d D U . . .
H76A H 0.763380 -0.138368 0.291175 0.341 Uiso 1 1 calc R U . . .
H76B H 0.875016 -0.182897 0.321173 0.341 Uiso 1 1 calc R U . . .
H76C H 0.880113 -0.078918 0.287527 0.341 Uiso 1 1 calc R U . . .
N1 N 0.3787(5) 0.3185(4) 0.3346(2) 0.0687(10) Uani 1 1 d . U . . .
N2 N 0.0774(5) 0.1866(5) 0.3241(2) 0.0671(15) Uani 1 1 d . U . . .
N3 N -0.0033(4) 0.3337(4) 0.1680(2) 0.0507(11) Uani 1 1 d . U . . .
O1 O 0.2285(4) 0.2019(3) 0.18514(15) 0.0530(9) Uani 1 1 d . U . . .
O2 O 0.2553(4) 0.0249(3) 0.15218(18) 0.0634(11) Uani 1 1 d D U . . .
O3 O 0.3763(3) 0.1645(3) 0.11988(16) 0.0475(8) Uani 1 1 d D U . . .
O4 O 0.3142(3) 0.4160(3) 0.20450(15) 0.0462(9) Uani 1 1 d . U . . .
O5 O 0.4964(4) 0.5164(4) 0.23011(17) 0.0698(13) Uani 1 1 d D U . . .
O6 O 0.3467(4) 0.5861(3) 0.16125(19) 0.0596(11) Uani 1 1 d D U . . .
O7 O 0.1198(3) 0.4704(3) 0.27617(15) 0.0513(9) Uani 1 1 d . U . . .
O8 O 0.1545(5) 0.6374(4) 0.3237(2) 0.0852(15) Uani 1 1 d D U . . .
O9 O -0.0417(5) 0.5792(5) 0.2812(2) 0.0980(17) Uani 1 1 d D U . . .
O11 O 0.3584(4) 0.2498(3) 0.2975(2) 0.0742(11) Uani 1 1 d . U . . .
O10 O 0.3117(4) 0.3868(3) 0.33201(19) 0.0654(10) Uani 1 1 d . U . . .
O12 O 0.4597(5) 0.3192(4) 0.3704(2) 0.0921(16) Uani 1 1 d . U . . .
O14 O 0.1281(5) 0.1545(4) 0.2850(2) 0.0792(14) Uani 1 1 d . U . . .
O13 O 0.0901(5) 0.2799(4) 0.33354(19) 0.0796(15) Uani 1 1 d . U . . .
O15 O 0.0188(5) 0.1330(4) 0.3512(2) 0.0830(16) Uani 1 1 d . U . . .
O16 O 0.0891(4) 0.3741(4) 0.15839(16) 0.0580(11) Uani 1 1 d . U . . .
O17 O -0.0065(3) 0.2874(3) 0.21479(17) 0.0550(10) Uani 1 1 d . U . . .
O18 O -0.0852(4) 0.3397(4) 0.1340(2) 0.0780(15) Uani 1 1 d . U . . .
O19 O 0.6066(6) 0.0354(5) 0.2789(3) 0.1000(19) Uani 1 1 d . U . . .
O20 O 0.7293(7) 0.1731(6) 0.3314(3) 0.124(2) Uani 1 1 d D U . . .
O21 O 0.7381(7) -0.0049(7) 0.3608(3) 0.135(2) Uani 1 1 d D U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O1 2.290(4) . ?
Dy1 O4 2.298(3) . ?
Dy1 O7 2.304(4) . ?
Dy1 O10 2.418(4) . ?
Dy1 O13 2.428(4) . ?
Dy1 O17 2.450(4) . ?
Dy1 O11 2.454(5) . ?
Dy1 O14 2.462(5) . ?
Dy1 O16 2.488(4) . ?
P1 O1 1.472(4) . ?
P1 O2 1.548(4) . ?
P1 O3 1.574(4) . ?
P1 C1 1.807(4) . ?
P2 O4 1.485(4) . ?
P2 O6 1.539(4) . ?
P2 O5 1.567(4) . ?
P2 C20 1.796(5) . ?
P3 O7 1.462(4) . ?
P3 O9 1.541(6) . ?
P3 O8 1.620(6) . ?
P3 C39 1.800(5) . ?
P4 O19 1.413(7) . ?
P4 O21 1.524(7) . ?
P4 O20 1.583(7) . ?
P4 C58 1.786(7) . ?
C1 C2 1.548(6) . ?
C1 H1A 0.9900 . ?
C1 H1B 0.9900 . ?
C2 C3 1.515(7) . ?
C2 C15 1.530(6) . ?
C2 C9 1.632(6) 2 ?
C3 C4 1.380(7) . ?
C3 C8 1.411(6) . ?
C4 C5 1.395(8) . ?
C4 H4 0.9500 . ?
C5 C6 1.385(8) . ?
C5 H5 0.9500 . ?
C6 C7 1.381(9) . ?
C6 H6 0.9500 . ?
C7 C8 1.374(7) . ?
C7 H7 0.9500 . ?
C8 C9 1.507(7) . ?
C9 C10 1.501(7) . ?
C9 H9 1.0000 . ?
C10 C11 1.383(7) . ?
C10 C15 1.404(6) . ?
C11 C12 1.382(9) . ?
C11 H11 0.9500 . ?
C12 C13 1.382(9) . ?
C12 H12 0.9500 . ?
C13 C14 1.402(8) . ?
C13 H13 0.9500 . ?
C14 C15 1.374(7) . ?
C14 H14 0.9500 . ?
C16 C17 1.400(7) . ?
C16 O2 1.432(6) . ?
C16 H16A 0.9900 . ?
C16 H16B 0.9900 . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C18 C19 1.420(7) . ?
C18 O3 1.456(5) . ?
C18 H18A 0.9900 . ?
C18 H18B 0.9900 . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C20 C21 1.545(6) . ?
C20 H20A 0.9900 . ?
C20 H20B 0.9900 . ?
C21 C34 1.529(6) . ?
C21 C22 1.532(6) . ?
C21 C28 1.632(6) 2_665 ?
C22 C23 1.380(7) . ?
C22 C27 1.395(6) . ?
C23 C24 1.395(7) . ?
C23 H23 0.9500 . ?
C24 C25 1.378(8) . ?
C24 H24 0.9500 . ?
C25 C26 1.377(8) . ?
C25 H25 0.9500 . ?
C26 C27 1.390(6) . ?
C26 H26 0.9500 . ?
C27 C28 1.504(7) . ?
C28 C29 1.515(6) . ?
C28 H28 1.0000 . ?
C29 C30 1.386(7) . ?
C29 C34 1.397(6) . ?
C30 C31 1.384(7) . ?
C30 H30 0.9500 . ?
C31 C32 1.386(7) . ?
C31 H31 0.9500 . ?
C32 C33 1.394(7) . ?
C32 H32 0.9500 . ?
C33 C34 1.387(6) . ?
C33 H33 0.9500 . ?
C35 O5 1.410(6) . ?
C35 C36 1.415(7) . ?
C35 H35A 0.9900 . ?
C35 H35B 0.9900 . ?
C36 H36A 0.9800 . ?
C36 H36B 0.9800 . ?
C36 H36C 0.9800 . ?
C37 C38 1.401(7) . ?
C37 O6 1.431(6) . ?
C37 H37A 0.9900 . ?
C37 H37B 0.9900 . ?
C38 H38A 0.9800 . ?
C38 H38B 0.9800 . ?
C38 H38C 0.9800 . ?
C39 C40 1.507(8) . ?
C39 H39A 0.9900 . ?
C39 H39B 0.9900 . ?
C40 C41 1.392(11) . ?
C40 C53 1.413(11) . ?
C41 C46 1.435(9) . ?
C41 C42 1.441(12) . ?
C42 C43 1.354(13) . ?
C42 H42 0.9500 . ?
C43 C44 1.434(13) . ?
C43 H43 0.9500 . ?
C44 C45 1.328(14) . ?
C44 H44 0.9500 . ?
C45 C46 1.423(13) . ?
C45 H45 0.9500 . ?
C46 C47 1.382(12) . ?
C47 C48 1.361(12) . ?
C47 H47 0.9500 . ?
C48 C53 1.441(9) . ?
C48 C49 1.443(13) . ?
C49 C50 1.305(14) . ?
C49 H49 0.9500 . ?
C50 C51 1.413(12) . ?
C50 H50 0.9500 . ?
C51 C52 1.358(13) . ?
C51 H51 0.9500 . ?
C52 C53 1.400(12) . ?
C52 H52 0.9500 . ?
C54 O8 1.424(7) . ?
C54 C55 1.430(7) . ?
C54 H54A 0.9900 . ?
C54 H54B 0.9900 . ?
C55 H55A 0.9800 . ?
C55 H55B 0.9800 . ?
C55 H55C 0.9800 . ?
C56 C57 1.373(8) . ?
C56 O9 1.427(7) . ?
C56 H56A 0.9900 . ?
C56 H56B 0.9900 . ?
C57 H57A 0.9800 . ?
C57 H57B 0.9800 . ?
C57 H57C 0.9800 . ?
C58 C59 1.544(7) . ?
C58 H58A 0.9900 . ?
C58 H58B 0.9900 . ?
C59 C72 1.525(8) . ?
C59 C60 1.537(8) . ?
C59 C66 1.633(8) 2_656 ?
C60 C61 1.384(8) . ?
C60 C65 1.396(7) . ?
C61 C62 1.377(9) . ?
C61 H61 0.9500 . ?
C62 C63 1.391(10) . ?
C62 H62 0.9500 . ?
C63 C64 1.385(9) . ?
C63 H63 0.9500 . ?
C64 C65 1.377(8) . ?
C64 H64 0.9500 . ?
C65 C66 1.505(7) . ?
C66 C67 1.496(8) . ?
C66 H66 1.0000 . ?
C67 C68 1.389(8) . ?
C67 C72 1.394(7) . ?
C68 C69 1.380(10) . ?
C68 H68 0.9500 . ?
C69 C70 1.382(11) . ?
C69 H69 0.9500 . ?
C70 C71 1.390(10) . ?
C70 H70 0.9500 . ?
C71 C72 1.374(9) . ?
C71 H71 0.9500 . ?
C73 C74 1.407(8) . ?
C73 O20 1.407(7) . ?
C73 H73A 0.9900 . ?
C73 H73B 0.9900 . ?
C74 H74A 0.9800 . ?
C74 H74B 0.9800 . ?
C74 H74C 0.9800 . ?
C75 C76 1.371(8) . ?
C75 O21 1.383(7) . ?
C75 H75A 0.9900 . ?
C75 H75B 0.9900 . ?
C76 H76A 0.9800 . ?
C76 H76B 0.9800 . ?
C76 H76C 0.9800 . ?
N1 O12 1.221(6) . ?
N1 O10 1.247(7) . ?
N1 O11 1.251(7) . ?
N2 O15 1.212(7) . ?
N2 O14 1.236(8) . ?
N2 O13 1.260(7) . ?
N3 O18 1.210(6) . ?
N3 O17 1.261(6) . ?
N3 O16 1.263(6) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Dy1 O4 81.87(14) . . ?
O1 Dy1 O7 153.12(14) . . ?
O4 Dy1 O7 85.97(14) . . ?
O1 Dy1 O10 126.78(16) . . ?
O4 Dy1 O10 79.08(15) . . ?
O7 Dy1 O10 73.52(15) . . ?
O1 Dy1 O13 122.96(15) . . ?
O4 Dy1 O13 152.45(15) . . ?
O7 Dy1 O13 75.70(16) . . ?
O10 Dy1 O13 76.12(18) . . ?
O1 Dy1 O17 86.77(15) . . ?
O4 Dy1 O17 124.76(13) . . ?
O7 Dy1 O17 80.62(15) . . ?
O10 Dy1 O17 143.52(17) . . ?
O13 Dy1 O17 72.82(16) . . ?
O1 Dy1 O11 77.16(15) . . ?
O4 Dy1 O11 82.59(17) . . ?
O7 Dy1 O11 124.94(14) . . ?
O10 Dy1 O11 51.45(15) . . ?
O13 Dy1 O11 91.1(2) . . ?
O17 Dy1 O11 146.16(16) . . ?
O1 Dy1 O14 72.13(17) . . ?
O4 Dy1 O14 148.79(18) . . ?
O7 Dy1 O14 124.74(17) . . ?
O10 Dy1 O14 102.74(17) . . ?
O13 Dy1 O14 51.02(19) . . ?
O17 Dy1 O14 71.58(17) . . ?
O11 Dy1 O14 75.17(18) . . ?
O1 Dy1 O16 76.12(15) . . ?
O4 Dy1 O16 73.17(13) . . ?
O7 Dy1 O16 77.44(14) . . ?
O10 Dy1 O16 140.85(15) . . ?
O13 Dy1 O16 121.12(17) . . ?
O17 Dy1 O16 51.64(13) . . ?
O11 Dy1 O16 146.00(17) . . ?
O14 Dy1 O16 115.35(16) . . ?
O1 P1 O2 113.2(2) . . ?
O1 P1 O3 112.5(2) . . ?
O2 P1 O3 105.5(3) . . ?
O1 P1 C1 111.9(2) . . ?
O2 P1 C1 109.6(2) . . ?
O3 P1 C1 103.6(2) . . ?
O4 P2 O6 112.9(2) . . ?
O4 P2 O5 112.9(2) . . ?
O6 P2 O5 108.0(3) . . ?
O4 P2 C20 112.9(2) . . ?
O6 P2 C20 109.6(2) . . ?
O5 P2 C20 99.6(2) . . ?
O7 P3 O9 113.0(3) . . ?
O7 P3 O8 106.9(3) . . ?
O9 P3 O8 108.3(4) . . ?
O7 P3 C39 113.8(3) . . ?
O9 P3 C39 104.2(3) . . ?
O8 P3 C39 110.6(3) . . ?
O19 P4 O21 112.1(4) . . ?
O19 P4 O20 115.1(4) . . ?
O21 P4 O20 105.9(5) . . ?
O19 P4 C58 115.0(4) . . ?
O21 P4 C58 106.8(4) . . ?
O20 P4 C58 100.9(4) . . ?
C2 C1 P1 119.9(3) . . ?
C2 C1 H1A 107.3 . . ?
P1 C1 H1A 107.3 . . ?
C2 C1 H1B 107.3 . . ?
P1 C1 H1B 107.3 . . ?
H1A C1 H1B 106.9 . . ?
C3 C2 C15 108.3(4) . . ?
C3 C2 C1 112.7(4) . . ?
C15 C2 C1 112.5(4) . . ?
C3 C2 C9 109.7(4) . 2 ?
C15 C2 C9 108.5(4) . 2 ?
C1 C2 C9 105.0(3) . 2 ?
C4 C3 C8 119.0(5) . . ?
C4 C3 C2 123.8(4) . . ?
C8 C3 C2 117.2(4) . . ?
C3 C4 C5 120.7(5) . . ?
C3 C4 H4 119.7 . . ?
C5 C4 H4 119.7 . . ?
C6 C5 C4 119.6(6) . . ?
C6 C5 H5 120.2 . . ?
C4 C5 H5 120.2 . . ?
C7 C6 C5 120.1(6) . . ?
C7 C6 H6 119.9 . . ?
C5 C6 H6 119.9 . . ?
C8 C7 C6 120.6(5) . . ?
C8 C7 H7 119.7 . . ?
C6 C7 H7 119.7 . . ?
C7 C8 C3 120.0(5) . . ?
C7 C8 C9 122.1(4) . . ?
C3 C8 C9 117.9(4) . . ?
C10 C9 C8 107.9(4) . . ?
C10 C9 C2 113.2(4) . 2 ?
C8 C9 C2 113.2(4) . 2 ?
C10 C9 H9 107.4 . . ?
C8 C9 H9 107.4 . . ?
C2 C9 H9 107.4 2 . ?
C11 C10 C15 120.4(5) . . ?
C11 C10 C9 121.3(4) . . ?
C15 C10 C9 118.4(4) . . ?
C12 C11 C10 120.1(5) . . ?
C12 C11 H11 120.0 . . ?
C10 C11 H11 120.0 . . ?
C11 C12 C13 120.3(6) . . ?
C11 C12 H12 119.8 . . ?
C13 C12 H12 119.8 . . ?
C12 C13 C14 119.5(6) . . ?
C12 C13 H13 120.3 . . ?
C14 C13 H13 120.3 . . ?
C15 C14 C13 120.8(5) . . ?
C15 C14 H14 119.6 . . ?
C13 C14 H14 119.6 . . ?
C14 C15 C10 119.0(5) . . ?
C14 C15 C2 124.2(4) . . ?
C10 C15 C2 116.8(4) . . ?
C17 C16 O2 116.6(7) . . ?
C17 C16 H16A 108.1 . . ?
O2 C16 H16A 108.1 . . ?
C17 C16 H16B 108.1 . . ?
O2 C16 H16B 108.1 . . ?
H16A C16 H16B 107.3 . . ?
C16 C17 H17A 109.5 . . ?
C16 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C16 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C19 C18 O3 110.2(6) . . ?
C19 C18 H18A 109.6 . . ?
O3 C18 H18A 109.6 . . ?
C19 C18 H18B 109.6 . . ?
O3 C18 H18B 109.6 . . ?
H18A C18 H18B 108.1 . . ?
C18 C19 H19A 109.5 . . ?
C18 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
C18 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C21 C20 P2 122.0(4) . . ?
C21 C20 H20A 106.8 . . ?
P2 C20 H20A 106.8 . . ?
C21 C20 H20B 106.8 . . ?
P2 C20 H20B 106.8 . . ?
H20A C20 H20B 106.7 . . ?
C34 C21 C22 107.9(4) . . ?
C34 C21 C20 112.3(4) . . ?
C22 C21 C20 113.7(4) . . ?
C34 C21 C28 109.1(4) . 2_665 ?
C22 C21 C28 108.9(3) . 2_665 ?
C20 C21 C28 104.9(4) . 2_665 ?
C23 C22 C27 118.9(4) . . ?
C23 C22 C21 124.1(4) . . ?
C27 C22 C21 116.9(4) . . ?
C22 C23 C24 120.6(5) . . ?
C22 C23 H23 119.7 . . ?
C24 C23 H23 119.7 . . ?
C25 C24 C23 120.2(5) . . ?
C25 C24 H24 119.9 . . ?
C23 C24 H24 119.9 . . ?
C26 C25 C24 119.6(5) . . ?
C26 C25 H25 120.2 . . ?
C24 C25 H25 120.2 . . ?
C25 C26 C27 120.6(5) . . ?
C25 C26 H26 119.7 . . ?
C27 C26 H26 119.7 . . ?
C26 C27 C22 120.1(5) . . ?
C26 C27 C28 121.7(4) . . ?
C22 C27 C28 118.2(4) . . ?
C27 C28 C29 108.6(4) . . ?
C27 C28 C21 113.0(4) . 2_665 ?
C29 C28 C21 113.4(4) . 2_665 ?
C27 C28 H28 107.2 . . ?
C29 C28 H28 107.2 . . ?
C21 C28 H28 107.2 2_665 . ?
C30 C29 C34 120.1(4) . . ?
C30 C29 C28 121.5(4) . . ?
C34 C29 C28 118.3(4) . . ?
C31 C30 C29 120.3(5) . . ?
C31 C30 H30 119.9 . . ?
C29 C30 H30 119.9 . . ?
C30 C31 C32 120.3(5) . . ?
C30 C31 H31 119.9 . . ?
C32 C31 H31 119.9 . . ?
C31 C32 C33 119.3(4) . . ?
C31 C32 H32 120.3 . . ?
C33 C32 H32 120.3 . . ?
C34 C33 C32 120.8(4) . . ?
C34 C33 H33 119.6 . . ?
C32 C33 H33 119.6 . . ?
C33 C34 C29 119.1(4) . . ?
C33 C34 C21 124.3(4) . . ?
C29 C34 C21 116.6(4) . . ?
O5 C35 C36 110.1(6) . . ?
O5 C35 H35A 109.6 . . ?
C36 C35 H35A 109.6 . . ?
O5 C35 H35B 109.6 . . ?
C36 C35 H35B 109.6 . . ?
H35A C35 H35B 108.2 . . ?
C35 C36 H36A 109.5 . . ?
C35 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
C35 C36 H36C 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
C38 C37 O6 113.5(7) . . ?
C38 C37 H37A 108.9 . . ?
O6 C37 H37A 108.9 . . ?
C38 C37 H37B 108.9 . . ?
O6 C37 H37B 108.9 . . ?
H37A C37 H37B 107.7 . . ?
C37 C38 H38A 109.5 . . ?
C37 C38 H38B 109.5 . . ?
H38A C38 H38B 109.5 . . ?
C37 C38 H38C 109.5 . . ?
H38A C38 H38C 109.5 . . ?
H38B C38 H38C 109.5 . . ?
C40 C39 P3 117.5(4) . . ?
C40 C39 H39A 107.9 . . ?
P3 C39 H39A 107.9 . . ?
C40 C39 H39B 107.9 . . ?
P3 C39 H39B 107.9 . . ?
H39A C39 H39B 107.2 . . ?
C41 C40 C53 119.1(6) . . ?
C41 C40 C39 120.0(7) . . ?
C53 C40 C39 120.8(7) . . ?
C40 C41 C46 121.2(8) . . ?
C40 C41 C42 122.5(7) . . ?
C46 C41 C42 116.4(8) . . ?
C43 C42 C41 121.5(9) . . ?
C43 C42 H42 119.3 . . ?
C41 C42 H42 119.3 . . ?
C42 C43 C44 120.8(11) . . ?
C42 C43 H43 119.6 . . ?
C44 C43 H43 119.6 . . ?
C45 C44 C43 119.6(10) . . ?
C45 C44 H44 120.2 . . ?
C43 C44 H44 120.2 . . ?
C44 C45 C46 121.9(9) . . ?
C44 C45 H45 119.1 . . ?
C46 C45 H45 119.1 . . ?
C47 C46 C45 121.9(8) . . ?
C47 C46 C41 118.3(8) . . ?
C45 C46 C41 119.8(9) . . ?
C48 C47 C46 122.2(7) . . ?
C48 C47 H47 118.9 . . ?
C46 C47 H47 118.9 . . ?
C47 C48 C53 120.2(8) . . ?
C47 C48 C49 122.1(7) . . ?
C53 C48 C49 117.7(8) . . ?
C50 C49 C48 121.5(8) . . ?
C50 C49 H49 119.2 . . ?
C48 C49 H49 119.2 . . ?
C49 C50 C51 121.3(11) . . ?
C49 C50 H50 119.4 . . ?
C51 C50 H50 119.4 . . ?
C52 C51 C50 119.8(11) . . ?
C52 C51 H51 120.1 . . ?
C50 C51 H51 120.1 . . ?
C51 C52 C53 121.8(8) . . ?
C51 C52 H52 119.1 . . ?
C53 C52 H52 119.1 . . ?
C52 C53 C40 123.1(7) . . ?
C52 C53 C48 117.9(8) . . ?
C40 C53 C48 119.0(8) . . ?
O8 C54 C55 111.3(7) . . ?
O8 C54 H54A 109.4 . . ?
C55 C54 H54A 109.4 . . ?
O8 C54 H54B 109.4 . . ?
C55 C54 H54B 109.4 . . ?
H54A C54 H54B 108.0 . . ?
C54 C55 H55A 109.5 . . ?
C54 C55 H55B 109.5 . . ?
H55A C55 H55B 109.5 . . ?
C54 C55 H55C 109.5 . . ?
H55A C55 H55C 109.5 . . ?
H55B C55 H55C 109.5 . . ?
C57 C56 O9 115.6(8) . . ?
C57 C56 H56A 108.4 . . ?
O9 C56 H56A 108.4 . . ?
C57 C56 H56B 108.4 . . ?
O9 C56 H56B 108.4 . . ?
H56A C56 H56B 107.4 . . ?
C56 C57 H57A 109.5 . . ?
C56 C57 H57B 109.5 . . ?
H57A C57 H57B 109.5 . . ?
C56 C57 H57C 109.5 . . ?
H57A C57 H57C 109.5 . . ?
H57B C57 H57C 109.5 . . ?
C59 C58 P4 125.0(4) . . ?
C59 C58 H58A 106.1 . . ?
P4 C58 H58A 106.1 . . ?
C59 C58 H58B 106.1 . . ?
P4 C58 H58B 106.1 . . ?
H58A C58 H58B 106.3 . . ?
C72 C59 C60 107.2(4) . . ?
C72 C59 C58 113.5(5) . . ?
C60 C59 C58 113.2(5) . . ?
C72 C59 C66 109.9(4) . 2_656 ?
C60 C59 C66 108.9(5) . 2_656 ?
C58 C59 C66 104.1(4) . 2_656 ?
C61 C60 C65 117.9(5) . . ?
C61 C60 C59 125.0(5) . . ?
C65 C60 C59 117.1(5) . . ?
C62 C61 C60 121.4(6) . . ?
C62 C61 H61 119.3 . . ?
C60 C61 H61 119.3 . . ?
C61 C62 C63 120.3(6) . . ?
C61 C62 H62 119.8 . . ?
C63 C62 H62 119.8 . . ?
C64 C63 C62 118.7(6) . . ?
C64 C63 H63 120.6 . . ?
C62 C63 H63 120.6 . . ?
C65 C64 C63 120.6(6) . . ?
C65 C64 H64 119.7 . . ?
C63 C64 H64 119.7 . . ?
C64 C65 C60 120.9(5) . . ?
C64 C65 C66 121.6(5) . . ?
C60 C65 C66 117.4(5) . . ?
C67 C66 C65 109.5(5) . . ?
C67 C66 C59 113.4(5) . 2_656 ?
C65 C66 C59 112.5(4) . 2_656 ?
C67 C66 H66 107.0 . . ?
C65 C66 H66 107.0 . . ?
C59 C66 H66 107.0 2_656 . ?
C68 C67 C72 120.4(6) . . ?
C68 C67 C66 121.5(5) . . ?
C72 C67 C66 118.1(5) . . ?
C69 C68 C67 120.2(6) . . ?
C69 C68 H68 119.9 . . ?
C67 C68 H68 119.9 . . ?
C68 C69 C70 119.6(7) . . ?
C68 C69 H69 120.2 . . ?
C70 C69 H69 120.2 . . ?
C69 C70 C71 120.0(7) . . ?
C69 C70 H70 120.0 . . ?
C71 C70 H70 120.0 . . ?
C72 C71 C70 121.0(7) . . ?
C72 C71 H71 119.5 . . ?
C70 C71 H71 119.5 . . ?
C71 C72 C67 118.7(6) . . ?
C71 C72 C59 124.4(5) . . ?
C67 C72 C59 116.9(5) . . ?
C74 C73 O20 112.8(8) . . ?
C74 C73 H73A 109.0 . . ?
O20 C73 H73A 109.0 . . ?
C74 C73 H73B 109.0 . . ?
O20 C73 H73B 109.0 . . ?
H73A C73 H73B 107.8 . . ?
C73 C74 H74A 109.5 . . ?
C73 C74 H74B 109.5 . . ?
H74A C74 H74B 109.5 . . ?
C73 C74 H74C 109.5 . . ?
H74A C74 H74C 109.5 . . ?
H74B C74 H74C 109.5 . . ?
C76 C75 O21 117.7(11) . . ?
C76 C75 H75A 107.9 . . ?
O21 C75 H75A 107.9 . . ?
C76 C75 H75B 107.9 . . ?
O21 C75 H75B 107.9 . . ?
H75A C75 H75B 107.2 . . ?
C75 C76 H76A 109.5 . . ?
C75 C76 H76B 109.5 . . ?
H76A C76 H76B 109.5 . . ?
C75 C76 H76C 109.5 . . ?
H76A C76 H76C 109.5 . . ?
H76B C76 H76C 109.5 . . ?
O12 N1 O10 122.2(5) . . ?
O12 N1 O11 122.1(6) . . ?
O10 N1 O11 115.7(5) . . ?
O15 N2 O14 122.9(7) . . ?
O15 N2 O13 122.0(7) . . ?
O14 N2 O13 115.1(5) . . ?
O18 N3 O17 121.5(6) . . ?
O18 N3 O16 121.6(5) . . ?
O17 N3 O16 116.9(4) . . ?
P1 O1 Dy1 171.8(3) . . ?
C16 O2 P1 125.5(5) . . ?
C18 O3 P1 120.1(4) . . ?
P2 O4 Dy1 170.6(2) . . ?
C35 O5 P2 124.4(5) . . ?
C37 O6 P2 126.9(4) . . ?
P3 O7 Dy1 157.7(2) . . ?
C54 O8 P3 125.8(6) . . ?
C56 O9 P3 121.3(5) . . ?
N1 O11 Dy1 95.5(4) . . ?
N1 O10 Dy1 97.4(3) . . ?
N2 O14 Dy1 96.1(4) . . ?
N2 O13 Dy1 97.1(4) . . ?
N3 O16 Dy1 94.8(3) . . ?
N3 O17 Dy1 96.6(3) . . ?
C73 O20 P4 124.7(7) . . ?
C75 O21 P4 154.7(9) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O1 P1 C1 C2 -119.0(4) . . . . ?
O2 P1 C1 C2 7.4(5) . . . . ?
O3 P1 C1 C2 119.6(4) . . . . ?
P1 C1 C2 C3 -63.8(5) . . . . ?
P1 C1 C2 C15 59.0(5) . . . . ?
P1 C1 C2 C9 176.8(3) . . . 2 ?
C15 C2 C3 C4 -136.2(5) . . . . ?
C1 C2 C3 C4 -11.1(6) . . . . ?
C9 C2 C3 C4 105.6(5) 2 . . . ?
C15 C2 C3 C8 43.8(5) . . . . ?
C1 C2 C3 C8 169.0(4) . . . . ?
C9 C2 C3 C8 -74.4(5) 2 . . . ?
C8 C3 C4 C5 -1.6(8) . . . . ?
C2 C3 C4 C5 178.4(5) . . . . ?
C3 C4 C5 C6 1.6(10) . . . . ?
C4 C5 C6 C7 -0.2(12) . . . . ?
C5 C6 C7 C8 -1.2(12) . . . . ?
C6 C7 C8 C3 1.1(9) . . . . ?
C6 C7 C8 C9 -178.2(6) . . . . ?
C4 C3 C8 C7 0.2(8) . . . . ?
C2 C3 C8 C7 -179.8(5) . . . . ?
C4 C3 C8 C9 179.6(4) . . . . ?
C2 C3 C8 C9 -0.4(6) . . . . ?
C7 C8 C9 C10 135.2(5) . . . . ?
C3 C8 C9 C10 -44.1(5) . . . . ?
C7 C8 C9 C2 -98.7(6) . . . 2 ?
C3 C8 C9 C2 82.0(5) . . . 2 ?
C8 C9 C10 C11 -134.8(5) . . . . ?
C2 C9 C10 C11 99.1(6) 2 . . . ?
C8 C9 C10 C15 45.5(6) . . . . ?
C2 C9 C10 C15 -80.6(5) 2 . . . ?
C15 C10 C11 C12 2.0(9) . . . . ?
C9 C10 C11 C12 -177.7(6) . . . . ?
C10 C11 C12 C13 0.0(11) . . . . ?
C11 C12 C13 C14 -0.7(12) . . . . ?
C12 C13 C14 C15 -0.6(12) . . . . ?
C13 C14 C15 C10 2.6(10) . . . . ?
C13 C14 C15 C2 -179.0(6) . . . . ?
C11 C10 C15 C14 -3.2(8) . . . . ?
C9 C10 C15 C14 176.5(5) . . . . ?
C11 C10 C15 C2 178.2(5) . . . . ?
C9 C10 C15 C2 -2.1(7) . . . . ?
C3 C2 C15 C14 138.9(5) . . . . ?
C1 C2 C15 C14 13.7(7) . . . . ?
C9 C2 C15 C14 -102.1(6) 2 . . . ?
C3 C2 C15 C10 -42.6(6) . . . . ?
C1 C2 C15 C10 -167.8(4) . . . . ?
C9 C2 C15 C10 76.4(5) 2 . . . ?
O4 P2 C20 C21 122.5(4) . . . . ?
O6 P2 C20 C21 -4.3(4) . . . . ?
O5 P2 C20 C21 -117.5(4) . . . . ?
P2 C20 C21 C34 -62.6(5) . . . . ?
P2 C20 C21 C22 60.2(5) . . . . ?
P2 C20 C21 C28 179.1(3) . . . 2_665 ?
C34 C21 C22 C23 136.9(5) . . . . ?
C20 C21 C22 C23 11.7(7) . . . . ?
C28 C21 C22 C23 -104.8(5) 2_665 . . . ?
C34 C21 C22 C27 -45.2(5) . . . . ?
C20 C21 C22 C27 -170.5(4) . . . . ?
C28 C21 C22 C27 73.0(5) 2_665 . . . ?
C27 C22 C23 C24 3.0(8) . . . . ?
C21 C22 C23 C24 -179.1(5) . . . . ?
C22 C23 C24 C25 -2.9(9) . . . . ?
C23 C24 C25 C26 1.5(9) . . . . ?
C24 C25 C26 C27 -0.5(8) . . . . ?
C25 C26 C27 C22 0.7(8) . . . . ?
C25 C26 C27 C28 179.2(5) . . . . ?
C23 C22 C27 C26 -2.0(7) . . . . ?
C21 C22 C27 C26 -180.0(4) . . . . ?
C23 C22 C27 C28 179.5(5) . . . . ?
C21 C22 C27 C28 1.5(6) . . . . ?
C26 C27 C28 C29 -135.8(4) . . . . ?
C22 C27 C28 C29 42.7(5) . . . . ?
C26 C27 C28 C21 97.6(5) . . . 2_665 ?
C22 C27 C28 C21 -84.0(5) . . . 2_665 ?
C27 C28 C29 C30 135.3(5) . . . . ?
C21 C28 C29 C30 -98.2(5) 2_665 . . . ?
C27 C28 C29 C34 -43.3(5) . . . . ?
C21 C28 C29 C34 83.1(5) 2_665 . . . ?
C34 C29 C30 C31 -0.7(8) . . . . ?
C28 C29 C30 C31 -179.4(5) . . . . ?
C29 C30 C31 C32 -0.1(8) . . . . ?
C30 C31 C32 C33 0.3(8) . . . . ?
C31 C32 C33 C34 0.3(8) . . . . ?
C32 C33 C34 C29 -1.1(7) . . . . ?
C32 C33 C34 C21 179.5(4) . . . . ?
C30 C29 C34 C33 1.3(7) . . . . ?
C28 C29 C34 C33 180.0(4) . . . . ?
C30 C29 C34 C21 -179.3(4) . . . . ?
C28 C29 C34 C21 -0.6(6) . . . . ?
C22 C21 C34 C33 -136.1(5) . . . . ?
C20 C21 C34 C33 -10.1(6) . . . . ?
C28 C21 C34 C33 105.7(5) 2_665 . . . ?
C22 C21 C34 C29 44.5(5) . . . . ?
C20 C21 C34 C29 170.5(4) . . . . ?
C28 C21 C34 C29 -73.7(5) 2_665 . . . ?
O7 P3 C39 C40 139.0(6) . . . . ?
O9 P3 C39 C40 -97.5(7) . . . . ?
O8 P3 C39 C40 18.7(8) . . . . ?
P3 C39 C40 C41 -90.2(7) . . . . ?
P3 C39 C40 C53 90.4(7) . . . . ?
C53 C40 C41 C46 2.0(8) . . . . ?
C39 C40 C41 C46 -177.5(5) . . . . ?
C53 C40 C41 C42 -178.8(6) . . . . ?
C39 C40 C41 C42 1.7(9) . . . . ?
C40 C41 C42 C43 -177.8(7) . . . . ?
C46 C41 C42 C43 1.4(10) . . . . ?
C41 C42 C43 C44 -1.7(12) . . . . ?
C42 C43 C44 C45 0.8(13) . . . . ?
C43 C44 C45 C46 0.3(12) . . . . ?
C44 C45 C46 C47 179.8(7) . . . . ?
C44 C45 C46 C41 -0.5(11) . . . . ?
C40 C41 C46 C47 -1.4(9) . . . . ?
C42 C41 C46 C47 179.4(6) . . . . ?
C40 C41 C46 C45 179.0(6) . . . . ?
C42 C41 C46 C45 -0.3(9) . . . . ?
C45 C46 C47 C48 -179.9(6) . . . . ?
C41 C46 C47 C48 0.4(9) . . . . ?
C46 C47 C48 C53 -0.1(9) . . . . ?
C46 C47 C48 C49 -178.0(6) . . . . ?
C47 C48 C49 C50 179.4(8) . . . . ?
C53 C48 C49 C50 1.4(11) . . . . ?
C48 C49 C50 C51 -0.3(13) . . . . ?
C49 C50 C51 C52 -0.4(14) . . . . ?
C50 C51 C52 C53 0.0(12) . . . . ?
C51 C52 C53 C40 -179.4(7) . . . . ?
C51 C52 C53 C48 1.1(10) . . . . ?
C41 C40 C53 C52 178.9(6) . . . . ?
C39 C40 C53 C52 -1.7(9) . . . . ?
C41 C40 C53 C48 -1.6(8) . . . . ?
C39 C40 C53 C48 177.8(5) . . . . ?
C47 C48 C53 C52 -179.8(6) . . . . ?
C49 C48 C53 C52 -1.7(8) . . . . ?
C47 C48 C53 C40 0.7(9) . . . . ?
C49 C48 C53 C40 178.7(5) . . . . ?
O19 P4 C58 C59 108.5(6) . . . . ?
O21 P4 C58 C59 -16.6(8) . . . . ?
O20 P4 C58 C59 -127.0(6) . . . . ?
P4 C58 C59 C72 -58.7(7) . . . . ?
P4 C58 C59 C60 63.8(7) . . . . ?
P4 C58 C59 C66 -178.2(5) . . . 2_656 ?
C72 C59 C60 C61 136.2(6) . . . . ?
C58 C59 C60 C61 10.3(9) . . . . ?
C66 C59 C60 C61 -104.9(7) 2_656 . . . ?
C72 C59 C60 C65 -45.5(7) . . . . ?
C58 C59 C60 C65 -171.4(5) . . . . ?
C66 C59 C60 C65 73.4(6) 2_656 . . . ?
C65 C60 C61 C62 3.6(10) . . . . ?
C59 C60 C61 C62 -178.2(7) . . . . ?
C60 C61 C62 C63 -2.1(12) . . . . ?
C61 C62 C63 C64 -1.2(12) . . . . ?
C62 C63 C64 C65 2.9(11) . . . . ?
C63 C64 C65 C60 -1.3(10) . . . . ?
C63 C64 C65 C66 176.5(6) . . . . ?
C61 C60 C65 C64 -1.9(9) . . . . ?
C59 C60 C65 C64 179.8(6) . . . . ?
C61 C60 C65 C66 -179.8(6) . . . . ?
C59 C60 C65 C66 1.8(8) . . . . ?
C64 C65 C66 C67 -135.2(6) . . . . ?
C60 C65 C66 C67 42.7(7) . . . . ?
C64 C65 C66 C59 97.8(6) . . . 2_656 ?
C60 C65 C66 C59 -84.3(6) . . . 2_656 ?
C65 C66 C67 C68 137.2(6) . . . . ?
C59 C66 C67 C68 -96.3(6) 2_656 . . . ?
C65 C66 C67 C72 -42.9(7) . . . . ?
C59 C66 C67 C72 83.6(6) 2_656 . . . ?
C72 C67 C68 C69 -0.6(10) . . . . ?
C66 C67 C68 C69 179.4(6) . . . . ?
C67 C68 C69 C70 0.7(12) . . . . ?
C68 C69 C70 C71 -0.7(13) . . . . ?
C69 C70 C71 C72 0.7(13) . . . . ?
C70 C71 C72 C67 -0.7(11) . . . . ?
C70 C71 C72 C59 -177.7(7) . . . . ?
C68 C67 C72 C71 0.6(9) . . . . ?
C66 C67 C72 C71 -179.4(6) . . . . ?
C68 C67 C72 C59 177.8(6) . . . . ?
C66 C67 C72 C59 -2.1(8) . . . . ?
C60 C59 C72 C71 -137.3(6) . . . . ?
C58 C59 C72 C71 -11.6(9) . . . . ?
C66 C59 C72 C71 104.5(7) 2_656 . . . ?
C60 C59 C72 C67 45.6(7) . . . . ?
C58 C59 C72 C67 171.4(5) . . . . ?
C66 C59 C72 C67 -72.6(6) 2_656 . . . ?
C17 C16 O2 P1 -81.5(11) . . . . ?
O1 P1 O2 C16 3.2(6) . . . . ?
O3 P1 O2 C16 126.6(5) . . . . ?
C1 P1 O2 C16 -122.5(5) . . . . ?
C19 C18 O3 P1 116.5(8) . . . . ?
O1 P1 O3 C18 66.6(5) . . . . ?
O2 P1 O3 C18 -57.2(5) . . . . ?
C1 P1 O3 C18 -172.4(4) . . . . ?
C36 C35 O5 P2 174.5(7) . . . . ?
O4 P2 O5 C35 -64.7(7) . . . . ?
O6 P2 O5 C35 60.8(6) . . . . ?
C20 P2 O5 C35 175.2(6) . . . . ?
C38 C37 O6 P2 -156.6(8) . . . . ?
O4 P2 O6 C37 3.2(7) . . . . ?
O5 P2 O6 C37 -122.4(6) . . . . ?
C20 P2 O6 C37 130.0(6) . . . . ?
O9 P3 O7 Dy1 -118.3(7) . . . . ?
O8 P3 O7 Dy1 122.6(7) . . . . ?
C39 P3 O7 Dy1 0.2(8) . . . . ?
C55 C54 O8 P3 -110.0(8) . . . . ?
O7 P3 O8 C54 166.5(5) . . . . ?
O9 P3 O8 C54 44.5(6) . . . . ?
C39 P3 O8 C54 -69.1(6) . . . . ?
C57 C56 O9 P3 172.0(11) . . . . ?
O7 P3 O9 C56 -33.0(10) . . . . ?
O8 P3 O9 C56 85.2(9) . . . . ?
C39 P3 O9 C56 -157.1(9) . . . . ?
O12 N1 O11 Dy1 -179.5(7) . . . . ?
O10 N1 O11 Dy1 -0.5(7) . . . . ?
O12 N1 O10 Dy1 179.5(7) . . . . ?
O11 N1 O10 Dy1 0.5(7) . . . . ?
O15 N2 O14 Dy1 171.0(5) . . . . ?
O13 N2 O14 Dy1 -8.3(6) . . . . ?
O15 N2 O13 Dy1 -170.9(5) . . . . ?
O14 N2 O13 Dy1 8.5(6) . . . . ?
O18 N3 O16 Dy1 179.1(5) . . . . ?
O17 N3 O16 Dy1 -0.4(5) . . . . ?
O18 N3 O17 Dy1 -179.1(5) . . . . ?
O16 N3 O17 Dy1 0.5(5) . . . . ?
C74 C73 O20 P4 118.1(11) . . . . ?
O19 P4 O20 C73 -19.5(10) . . . . ?
O21 P4 O20 C73 105.0(9) . . . . ?
C58 P4 O20 C73 -143.9(8) . . . . ?
C76 C75 O21 P4 -33(4) . . . . ?
O19 P4 O21 C75 49(3) . . . . ?
O20 P4 O21 C75 -77(3) . . . . ?
C58 P4 O21 C75 176(2) . . . . ?

_refine_diff_density_max         1.767
_refine_diff_density_min         -2.208
_refine_diff_density_rms         0.108


_exptl_crystal_recrystallization_method 'solid state reaction'
_chemical_properties_physical    
Heat-sensitive,Light-sensitive,Photo-sensitive
_exptl_crystal_preparation       Luminescent,mechanical
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_reverse2
_database_code_depnum_ccdc_archive 'CCDC 2214249'
loop_
_audit_author_name
_audit_author_address
'Xinda Huang'
;Nanjing University
China
;
_audit_update_record             
;
2022-10-20 deposited with the CCDC.	2023-01-27 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        '[Dy(NO3)3(depma2)1.5].(depma2)0.5'
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C57 H63 Dy N3 O18 P3, (C19 H21 O3 P)'
_chemical_formula_sum            'C76 H84 Dy N3 O21 P4'
_chemical_formula_weight         1661.84

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0137 0.0067 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -5.9987 12.4498 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0241 0.0134 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0389 0.0241 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2543 0.3332 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   12.0667(5)
_cell_length_b                   13.4722(6)
_cell_length_c                   23.4814(10)
_cell_angle_alpha                90.745(2)
_cell_angle_beta                 97.128(2)
_cell_angle_gamma                93.145(2)
_cell_volume                     3781.3(3)
_cell_formula_units_Z            2
_cell_measurement_temperature    193(2)
_cell_measurement_reflns_used    9868
_cell_measurement_theta_min      3.2165
_cell_measurement_theta_max      53.807

_exptl_crystal_description       rod
_exptl_crystal_colour            colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.460
_exptl_crystal_F_000             1710
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.400
_exptl_crystal_size_mid          0.100
_exptl_crystal_size_min          0.100
_exptl_absorpt_coefficient_mu    6.043
_shelx_estimated_absorpt_T_min   0.196
_shelx_estimated_absorpt_T_max   0.583
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.508
_exptl_absorpt_correction_T_max  0.583
_exptl_absorpt_process_details   'SADABS 2016/2'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      193(2)
_diffrn_radiation_wavelength     1.34139
_diffrn_radiation_type           GaK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker D8 liquid'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            46556
_diffrn_reflns_av_unetI/netI     0.0650
_diffrn_reflns_av_R_equivalents  0.0635
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_theta_min         1.650
_diffrn_reflns_theta_max         53.947
_diffrn_reflns_theta_full        53.594
_diffrn_measured_fraction_theta_max 0.959
_diffrn_measured_fraction_theta_full 0.961
_diffrn_reflns_Laue_measured_fraction_max 0.959
_diffrn_reflns_Laue_measured_fraction_full 0.961
_diffrn_reflns_point_group_measured_fraction_max 0.959
_diffrn_reflns_point_group_measured_fraction_full 0.961
_reflns_number_total             13329
_reflns_number_gt                10442
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker APEX3'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXT 2014/4 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1366P)²+5.9722P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         13329
_refine_ls_number_parameters     954
_refine_ls_number_restraints     406
_refine_ls_R_factor_all          0.0941
_refine_ls_R_factor_gt           0.0755
_refine_ls_wR_factor_ref         0.2204
_refine_ls_wR_factor_gt          0.2062
_refine_ls_goodness_of_fit_ref   1.073
_refine_ls_restrained_S_all      1.140
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.20102(3) 0.82128(3) 0.75113(2) 0.03912(15) Uani 1 1 d . . . . .
P1 P 0.26197(16) 0.63958(15) 0.63766(8) 0.0410(4) Uani 1 1 d . U . . .
P2 P 0.40221(17) 0.98947(17) 0.68219(8) 0.0468(5) Uani 1 1 d . U . . .
P3 P 0.0558(2) 1.02690(19) 0.81062(9) 0.0596(6) Uani 1 1 d . U . . .
P4 P 0.6583(5) 0.5701(4) 0.8371(2) 0.1326(13) Uani 1 1 d . U . . .
C1 C 0.1722(6) 0.6568(5) 0.5710(3) 0.0366(15) Uani 1 1 d . . . . .
H1A H 0.123853 0.711870 0.577487 0.044 Uiso 1 1 calc R U . . .
H1B H 0.220733 0.679550 0.542138 0.044 Uiso 1 1 calc R U . . .
C2 C 0.0952(6) 0.5683(5) 0.5438(3) 0.0349(15) Uani 1 1 d . . . . .
C3 C 0.1609(5) 0.4826(5) 0.5250(3) 0.0348(15) Uani 1 1 d . . . . .
C4 C 0.2756(6) 0.4895(6) 0.5216(3) 0.0435(17) Uani 1 1 d . . . . .
H4 H 0.317125 0.550663 0.531085 0.052 Uiso 1 1 calc R U . . .
C5 C 0.3294(7) 0.4086(7) 0.5046(5) 0.063(2) Uani 1 1 d . . . . .
H5 H 0.407885 0.413892 0.503274 0.076 Uiso 1 1 calc R U . . .
C6 C 0.2693(7) 0.3197(7) 0.4894(5) 0.070(3) Uani 1 1 d . . . . .
H6 H 0.306365 0.264442 0.476954 0.084 Uiso 1 1 calc R U . . .
C7 C 0.1550(7) 0.3111(6) 0.4922(4) 0.053(2) Uani 1 1 d . . . . .
H7 H 0.113749 0.249883 0.482310 0.064 Uiso 1 1 calc R U . . .
C8 C 0.1015(6) 0.3924(6) 0.5096(3) 0.0404(16) Uani 1 1 d . . . . .
C9 C -0.0228(6) 0.3868(5) 0.5131(3) 0.0361(15) Uani 1 1 d . . . . .
H9 H -0.047085 0.314841 0.514981 0.043 Uiso 1 1 calc R U . . .
C10 C -0.0426(6) 0.4355(6) 0.5685(3) 0.0390(16) Uani 1 1 d . . . . .
C11 C -0.1172(7) 0.3942(7) 0.6027(3) 0.053(2) Uani 1 1 d . . . . .
H11 H -0.153905 0.331068 0.592632 0.063 Uiso 1 1 calc R U . . .
C12 C -0.1391(9) 0.4451(9) 0.6523(4) 0.076(3) Uani 1 1 d . . . . .
H12 H -0.189355 0.416299 0.676285 0.091 Uiso 1 1 calc R U . . .
C13 C -0.0869(9) 0.5373(9) 0.6656(4) 0.074(3) Uani 1 1 d . . . . .
H13 H -0.103559 0.573555 0.698142 0.089 Uiso 1 1 calc R U . . .
C14 C -0.0105(7) 0.5772(7) 0.6320(4) 0.056(2) Uani 1 1 d . . . . .
H14 H 0.025887 0.640430 0.642110 0.067 Uiso 1 1 calc R U . . .
C15 C 0.0144(6) 0.5272(6) 0.5837(3) 0.0397(16) Uani 1 1 d . . . . .
C16 C 0.2192(10) 0.4856(8) 0.7054(5) 0.076(2) Uani 1 1 d . U . . .
H16A H 0.160613 0.526822 0.717632 0.091 Uiso 1 1 calc R U . . .
H16B H 0.185854 0.417574 0.696505 0.091 Uiso 1 1 calc R U . . .
C17 C 0.3122(13) 0.4826(12) 0.7519(6) 0.112(4) Uani 1 1 d . U . . .
H17A H 0.366881 0.437077 0.740920 0.167 Uiso 1 1 calc R U . . .
H17B H 0.283577 0.459332 0.786918 0.167 Uiso 1 1 calc R U . . .
H17C H 0.348166 0.549395 0.758780 0.167 Uiso 1 1 calc R U . . .
C18 C 0.4808(8) 0.6511(9) 0.6637(5) 0.0695(19) Uani 1 1 d . U . . .
H18A H 0.515193 0.717152 0.676846 0.083 Uiso 1 1 calc R U . . .
H18B H 0.457522 0.616208 0.697519 0.083 Uiso 1 1 calc R U . . .
C19 C 0.5598(11) 0.5964(14) 0.6399(6) 0.119(4) Uani 1 1 d . U . . .
H19A H 0.531406 0.526961 0.634165 0.179 Uiso 1 1 calc R U . . .
H19B H 0.629922 0.599473 0.666063 0.179 Uiso 1 1 calc R U . . .
H19C H 0.573361 0.624421 0.602966 0.179 Uiso 1 1 calc R U . . .
C20 C 0.4762(6) 0.9375(6) 0.6276(3) 0.0415(17) Uani 1 1 d . . . . .
H20A H 0.555619 0.936709 0.644243 0.050 Uiso 1 1 calc R U . . .
H20B H 0.448184 0.867164 0.621879 0.050 Uiso 1 1 calc R U . . .
C21 C 0.4752(5) 0.9816(5) 0.5676(3) 0.0355(15) Uani 1 1 d . . . . .
C22 C 0.3573(5) 0.9794(5) 0.5349(3) 0.0344(15) Uani 1 1 d . . . . .
C23 C 0.2647(6) 0.9260(6) 0.5518(3) 0.0395(16) Uani 1 1 d . . . . .
H23 H 0.273475 0.887784 0.585658 0.047 Uiso 1 1 calc R U . . .
C24 C 0.1593(6) 0.9281(6) 0.5197(3) 0.0438(17) Uani 1 1 d . . . . .
H24 H 0.096572 0.892756 0.532074 0.053 Uiso 1 1 calc R U . . .
C25 C 0.1470(6) 0.9824(7) 0.4695(4) 0.0488(19) Uani 1 1 d . . . . .
H25 H 0.075669 0.984790 0.447486 0.059 Uiso 1 1 calc R U . . .
C26 C 0.2386(6) 1.0326(6) 0.4519(3) 0.0458(18) Uani 1 1 d . . . . .
H26 H 0.230280 1.068468 0.417199 0.055 Uiso 1 1 calc R U . . .
C27 C 0.3436(5) 1.0315(5) 0.4842(3) 0.0357(15) Uani 1 1 d . . . . .
C28 C 0.4461(6) 1.0881(5) 0.4658(3) 0.0359(15) Uani 1 1 d . . . . .
H28 H 0.418330 1.140035 0.438372 0.043 Uiso 1 1 calc R U . . .
C29 C 0.5088(6) 1.1410(5) 0.5173(3) 0.0368(16) Uani 1 1 d . . . . .
C30 C 0.5501(6) 1.2387(6) 0.5150(3) 0.0409(17) Uani 1 1 d . . . . .
H30 H 0.539589 1.272803 0.479724 0.049 Uiso 1 1 calc R U . . .
C31 C 0.6063(7) 1.2873(6) 0.5632(4) 0.051(2) Uani 1 1 d . . . . .
H31 H 0.632779 1.354787 0.561588 0.061 Uiso 1 1 calc R U . . .
C32 C 0.6234(7) 1.2360(7) 0.6140(4) 0.054(2) Uani 1 1 d . . . . .
H32 H 0.663894 1.267870 0.647099 0.064 Uiso 1 1 calc R U . . .
C33 C 0.5816(6) 1.1381(6) 0.6168(3) 0.0451(18) Uani 1 1 d . . . . .
H33 H 0.593140 1.103751 0.651891 0.054 Uiso 1 1 calc R U . . .
C34 C 0.5236(6) 1.0905(5) 0.5689(3) 0.0373(16) Uani 1 1 d . . . . .
C35 C 0.4988(10) 1.0684(10) 0.7799(5) 0.084(2) Uani 1 1 d . U . . .
H35A H 0.432115 1.044637 0.797582 0.100 Uiso 1 1 calc R U . . .
H35B H 0.491818 1.139857 0.771680 0.100 Uiso 1 1 calc R U . . .
C36 C 0.5968(13) 1.0571(13) 0.8197(6) 0.115(4) Uani 1 1 d . U . . .
H36A H 0.596451 0.988969 0.833787 0.173 Uiso 1 1 calc R U . . .
H36B H 0.597636 1.103885 0.852119 0.173 Uiso 1 1 calc R U . . .
H36C H 0.663478 1.070809 0.800527 0.173 Uiso 1 1 calc R U . . .
C37 C 0.2385(9) 1.1106(9) 0.6609(5) 0.079(2) Uani 1 1 d . U . . .
H37A H 0.190216 1.048495 0.655357 0.094 Uiso 1 1 calc R U . . .
H37B H 0.229567 1.139461 0.698926 0.094 Uiso 1 1 calc R U . . .
C38 C 0.2015(14) 1.1786(12) 0.6177(7) 0.117(4) Uani 1 1 d . U . . .
H38A H 0.246867 1.241291 0.623739 0.175 Uiso 1 1 calc R U . . .
H38B H 0.122790 1.191037 0.619749 0.175 Uiso 1 1 calc R U . . .
H38C H 0.209275 1.150324 0.579824 0.175 Uiso 1 1 calc R U . . .
C39 C -0.0024(7) 0.9601(7) 0.8671(3) 0.052(2) Uani 1 1 d . . . . .
H39A H -0.083615 0.949520 0.854362 0.063 Uiso 1 1 calc R U . . .
H39B H 0.028656 0.893586 0.867676 0.063 Uiso 1 1 calc R U . . .
C40 C 0.0087(6) 0.9967(6) 0.9298(3) 0.0443(18) Uani 1 1 d . . . . .
C41 C 0.1294(6) 1.0141(6) 0.9565(3) 0.0445(18) Uani 1 1 d . . . . .
C42 C 0.2193(7) 0.9777(7) 0.9335(4) 0.0502(19) Uani 1 1 d . . . . .
H42 H 0.206703 0.942341 0.897851 0.060 Uiso 1 1 calc R U . . .
C43 C 0.3272(7) 0.9915(7) 0.9611(4) 0.060(2) Uani 1 1 d . . . . .
H43 H 0.387868 0.966891 0.944024 0.072 Uiso 1 1 calc R U . . .
C44 C 0.3466(7) 1.0406(9) 1.0130(5) 0.071(3) Uani 1 1 d . . . . .
H44 H 0.420513 1.047653 1.032605 0.085 Uiso 1 1 calc R U . . .
C45 C 0.2584(7) 1.0807(7) 1.0377(4) 0.056(2) Uani 1 1 d . . . . .
H45 H 0.272412 1.118761 1.072431 0.067 Uiso 1 1 calc R U . . .
C46 C 0.1499(6) 1.0636(7) 1.0101(3) 0.0462(18) Uani 1 1 d . . . . .
C47 C 0.0510(6) 1.0952(6) 1.0375(3) 0.0459(18) Uani 1 1 d . . . . .
H47 H 0.078096 1.148309 1.066842 0.055 Uiso 1 1 calc R U . . .
C48 C -0.0312(6) 1.1402(7) 0.9919(3) 0.0480(19) Uani 1 1 d . . . . .
C49 C -0.0862(7) 1.2248(7) 1.0042(4) 0.055(2) Uani 1 1 d . . . . .
H49 H -0.069976 1.257159 1.040679 0.066 Uiso 1 1 calc R U . . .
C50 C -0.1644(8) 1.2614(7) 0.9628(4) 0.059(2) Uani 1 1 d . . . . .
H50 H -0.202689 1.318689 0.970844 0.071 Uiso 1 1 calc R U . . .
C51 C -0.1870(8) 1.2138(7) 0.9092(4) 0.063(2) Uani 1 1 d . . . . .
H51 H -0.240379 1.238905 0.880672 0.076 Uiso 1 1 calc R U . . .
C52 C -0.1320(7) 1.1303(7) 0.8977(4) 0.051(2) Uani 1 1 d . . . . .
H52 H -0.149136 1.097347 0.861411 0.061 Uiso 1 1 calc R U . . .
C53 C -0.0511(6) 1.0935(6) 0.9387(3) 0.0425(17) Uani 1 1 d . . . . .
C54 C 0.1811(16) 1.1760(11) 0.8442(7) 0.122(3) Uani 1 1 d D U . . .
H54A H 0.243962 1.145302 0.828599 0.146 Uiso 1 1 calc R U . . .
H54B H 0.196608 1.176135 0.886573 0.146 Uiso 1 1 calc R U . . .
C55 C 0.1765(18) 1.2746(11) 0.8259(9) 0.152(5) Uani 1 1 d D U . . .
H55A H 0.101422 1.285247 0.806609 0.228 Uiso 1 1 calc R U . . .
H55B H 0.231563 1.287495 0.799138 0.228 Uiso 1 1 calc R U . . .
H55C H 0.193301 1.319976 0.859194 0.228 Uiso 1 1 calc R U . . .
C56 C -0.0501(12) 1.0871(12) 0.7163(5) 0.105(2) Uani 1 1 d D U . . .
H56A H 0.019741 1.129567 0.716962 0.127 Uiso 1 1 calc R U . . .
H56B H -0.046379 1.031272 0.688953 0.127 Uiso 1 1 calc R U . . .
C57 C -0.1383(15) 1.1415(14) 0.6969(7) 0.143(4) Uani 1 1 d D U . . .
H57A H -0.202280 1.096649 0.682053 0.215 Uiso 1 1 calc R U . . .
H57B H -0.117718 1.184770 0.666238 0.215 Uiso 1 1 calc R U . . .
H57C H -0.158348 1.182273 0.728567 0.215 Uiso 1 1 calc R U . . .
C58 C 0.5566(15) 0.5959(12) 0.8850(6) 0.1163(19) Uani 1 1 d . U . . .
H58A H 0.572263 0.666003 0.898154 0.140 Uiso 1 1 calc R U . . .
H58B H 0.482695 0.592827 0.861307 0.140 Uiso 1 1 calc R U . . .
C59 C 0.5422(12) 0.5355(10) 0.9387(6) 0.0963(18) Uani 1 1 d . U . . .
C60 C 0.5178(12) 0.4245(11) 0.9299(6) 0.0988(19) Uani 1 1 d . U . . .
C61 C 0.4882(14) 0.3852(13) 0.8747(7) 0.116(2) Uani 1 1 d . U . . .
H61 H 0.486002 0.426348 0.842066 0.140 Uiso 1 1 calc R U . . .
C62 C 0.4645(16) 0.2931(13) 0.8695(8) 0.127(3) Uani 1 1 d . U . . .
H62 H 0.442049 0.268298 0.831486 0.152 Uiso 1 1 calc R U . . .
C63 C 0.4670(16) 0.2308(13) 0.9082(8) 0.124(3) Uani 1 1 d . U . . .
H63 H 0.442625 0.163279 0.899965 0.149 Uiso 1 1 calc R U . . .
C64 C 0.5103(14) 0.2658(11) 0.9689(7) 0.113(2) Uani 1 1 d . U . . .
H64 H 0.522153 0.220474 0.999477 0.136 Uiso 1 1 calc R U . . .
C65 C 0.5316(12) 0.3678(10) 0.9776(6) 0.0968(19) Uani 1 1 d . U . . .
C66 C 0.5647(11) 0.4173(10) 1.0343(6) 0.092(2) Uani 1 1 d . U . . .
H66 H 0.595527 0.366123 1.061366 0.111 Uiso 1 1 calc R U . . .
C67 C 0.6541(12) 0.4885(11) 1.0269(7) 0.0998(19) Uani 1 1 d . U . . .
C68 C 0.7465(13) 0.4810(13) 1.0691(7) 0.116(2) Uani 1 1 d . U . . .
H68 H 0.744515 0.436742 1.100185 0.139 Uiso 1 1 calc R U . . .
C69 C 0.8347(15) 0.5379(13) 1.0632(8) 0.123(3) Uani 1 1 d . U . . .
H69 H 0.902350 0.527602 1.087192 0.148 Uiso 1 1 calc R U . . .
C70 C 0.8342(14) 0.6148(13) 1.0224(7) 0.118(3) Uani 1 1 d . U . . .
H70 H 0.894981 0.663061 1.024106 0.142 Uiso 1 1 calc R U . . .
C71 C 0.7448(13) 0.6185(12) 0.9806(7) 0.113(2) Uani 1 1 d . U . . .
H71 H 0.745311 0.666051 0.951061 0.135 Uiso 1 1 calc R U . . .
C72 C 0.6475(12) 0.5474(11) 0.9820(6) 0.0994(19) Uani 1 1 d . U . . .
C73 C 0.8479(16) 0.4853(15) 0.8676(7) 0.149(3) Uani 1 1 d D U . . .
H73A H 0.881359 0.451812 0.902344 0.179 Uiso 1 1 calc R U . . .
H73B H 0.881947 0.553932 0.867838 0.179 Uiso 1 1 calc R U . . .
C74 C 0.8691(19) 0.4315(14) 0.8164(7) 0.157(4) Uani 1 1 d D U . . .
H74A H 0.839761 0.362413 0.817821 0.236 Uiso 1 1 calc R U . . .
H74B H 0.949850 0.432859 0.814474 0.236 Uiso 1 1 calc R U . . .
H74C H 0.832003 0.462909 0.782309 0.236 Uiso 1 1 calc R U . . .
C75 C 0.7769(17) 0.7197(14) 0.7911(7) 0.143(3) Uani 1 1 d D U . . .
H75A H 0.763629 0.672272 0.758108 0.171 Uiso 1 1 calc R U . . .
H75B H 0.858591 0.734743 0.799437 0.171 Uiso 1 1 calc R U . . .
C76 C 0.7229(18) 0.8104(13) 0.7756(9) 0.150(4) Uani 1 1 d D U . . .
H76A H 0.641667 0.796545 0.768834 0.225 Uiso 1 1 calc R U . . .
H76B H 0.749330 0.836408 0.740628 0.225 Uiso 1 1 calc R U . . .
H76C H 0.740930 0.859729 0.806907 0.225 Uiso 1 1 calc R U . . .
N1 N 0.4026(6) 0.8239(6) 0.8302(3) 0.0551(18) Uani 1 1 d . . . . .
N2 N 0.1115(9) 0.6856(6) 0.8296(4) 0.0821(17) Uani 1 1 d . U . . .
N3 N -0.0064(7) 0.8325(6) 0.6754(4) 0.062(2) Uani 1 1 d . . . . .
O1 O 0.2340(5) 0.7056(4) 0.6840(2) 0.0478(12) Uani 1 1 d . U . . .
O2 O 0.2607(5) 0.5283(4) 0.6535(3) 0.0570(12) Uani 1 1 d . U . . .
O3 O 0.3816(4) 0.6640(4) 0.6214(2) 0.0510(11) Uani 1 1 d . U . . .
O4 O 0.3193(5) 0.9179(4) 0.7019(2) 0.0500(12) Uani 1 1 d . U . . .
O5 O 0.5016(6) 1.0168(6) 0.7295(3) 0.0701(14) Uani 1 1 d . U . . .
O6 O 0.3532(5) 1.0867(5) 0.6606(3) 0.0609(12) Uani 1 1 d . U . . .
O7 O 0.1286(5) 0.9675(4) 0.7802(2) 0.0498(12) Uani 1 1 d . U . . .
O8 O 0.0937(9) 1.1244(7) 0.8291(4) 0.1042(18) Uani 1 1 d D U . . .
O9 O -0.0549(7) 1.0494(7) 0.7702(3) 0.0960(17) Uani 1 1 d D U . . .
O10 O 0.3366(5) 0.8937(5) 0.8277(2) 0.0568(15) Uani 1 1 d . . . . .
O11 O 0.3734(6) 0.7523(5) 0.7959(3) 0.076(2) Uani 1 1 d . . . . .
O12 O 0.4864(7) 0.8254(6) 0.8652(4) 0.096(3) Uani 1 1 d . . . . .
O13 O 0.1304(7) 0.7751(5) 0.8395(3) 0.0737(17) Uani 1 1 d . U . . .
O14 O 0.1409(8) 0.6536(5) 0.7832(3) 0.0846(18) Uani 1 1 d . U . . .
O15 O 0.0601(10) 0.6320(6) 0.8593(4) 0.118(3) Uani 1 1 d . U . . .
O16 O 0.0861(5) 0.8718(5) 0.6623(3) 0.0627(16) Uani 1 1 d . . . . .
O17 O -0.0004(5) 0.7880(5) 0.7221(3) 0.0602(15) Uani 1 1 d . . . . .
O18 O -0.0932(7) 0.8395(7) 0.6445(4) 0.096(3) Uani 1 1 d . . . . .
O19 O 0.6136(13) 0.5455(11) 0.7816(5) 0.155(3) Uani 1 1 d . U . . .
O20 O 0.7306(12) 0.4876(10) 0.8674(5) 0.144(2) Uani 1 1 d D U . . .
O21 O 0.7372(11) 0.6740(9) 0.8402(5) 0.144(2) Uani 1 1 d D U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O1 2.287(5) . ?
Dy1 O4 2.305(5) . ?
Dy1 O7 2.327(5) . ?
Dy1 O13 2.416(6) . ?
Dy1 O10 2.431(6) . ?
Dy1 O11 2.448(6) . ?
Dy1 O17 2.457(6) . ?
Dy1 O16 2.481(6) . ?
Dy1 O14 2.489(7) . ?
P1 O1 1.479(5) . ?
P1 O2 1.549(6) . ?
P1 O3 1.557(6) . ?
P1 C1 1.815(7) . ?
P2 O4 1.471(6) . ?
P2 O6 1.533(7) . ?
P2 O5 1.556(7) . ?
P2 C20 1.806(7) . ?
P3 O8 1.412(9) . ?
P3 O7 1.463(5) . ?
P3 O9 1.585(8) . ?
P3 C39 1.804(9) . ?
P4 O19 1.376(14) . ?
P4 O20 1.574(13) . ?
P4 O21 1.645(14) . ?
P4 C58 1.810(14) . ?
C1 C2 1.551(9) . ?
C1 H1A 0.9900 . ?
C1 H1B 0.9900 . ?
C2 C15 1.524(10) . ?
C2 C3 1.526(9) . ?
C2 C9 1.644(10) 2_566 ?
C3 C4 1.394(10) . ?
C3 C8 1.396(10) . ?
C4 C5 1.378(11) . ?
C4 H4 0.9500 . ?
C5 C6 1.385(13) . ?
C5 H5 0.9500 . ?
C6 C7 1.388(12) . ?
C6 H6 0.9500 . ?
C7 C8 1.383(10) . ?
C7 H7 0.9500 . ?
C8 C9 1.510(10) . ?
C9 C10 1.501(10) . ?
C9 H9 1.0000 . ?
C10 C11 1.378(11) . ?
C10 C15 1.401(10) . ?
C11 C12 1.404(12) . ?
C11 H11 0.9500 . ?
C12 C13 1.375(14) . ?
C12 H12 0.9500 . ?
C13 C14 1.379(12) . ?
C13 H13 0.9500 . ?
C14 C15 1.383(10) . ?
C14 H14 0.9500 . ?
C16 C17 1.467(17) . ?
C16 O2 1.485(12) . ?
C16 H16A 0.9900 . ?
C16 H16B 0.9900 . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C18 C19 1.401(17) . ?
C18 O3 1.478(10) . ?
C18 H18A 0.9900 . ?
C18 H18B 0.9900 . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C20 C21 1.536(10) . ?
C20 H20A 0.9900 . ?
C20 H20B 0.9900 . ?
C21 C22 1.529(10) . ?
C21 C34 1.547(10) . ?
C21 C28 1.630(9) 2_676 ?
C22 C27 1.388(10) . ?
C22 C23 1.398(10) . ?
C23 C24 1.397(10) . ?
C23 H23 0.9500 . ?
C24 C25 1.393(11) . ?
C24 H24 0.9500 . ?
C25 C26 1.373(11) . ?
C25 H25 0.9500 . ?
C26 C27 1.394(10) . ?
C26 H26 0.9500 . ?
C27 C28 1.529(9) . ?
C28 C29 1.496(10) . ?
C28 H28 1.0000 . ?
C29 C30 1.386(10) . ?
C29 C34 1.393(10) . ?
C30 C31 1.384(12) . ?
C30 H30 0.9500 . ?
C31 C32 1.383(13) . ?
C31 H31 0.9500 . ?
C32 C33 1.392(11) . ?
C32 H32 0.9500 . ?
C33 C34 1.379(11) . ?
C33 H33 0.9500 . ?
C35 O5 1.370(12) . ?
C35 C36 1.429(17) . ?
C35 H35A 0.9900 . ?
C35 H35B 0.9900 . ?
C36 H36A 0.9800 . ?
C36 H36B 0.9800 . ?
C36 H36C 0.9800 . ?
C37 C38 1.423(18) . ?
C37 O6 1.440(12) . ?
C37 H37A 0.9900 . ?
C37 H37B 0.9900 . ?
C38 H38A 0.9800 . ?
C38 H38B 0.9800 . ?
C38 H38C 0.9800 . ?
C39 C40 1.536(11) . ?
C39 H39A 0.9900 . ?
C39 H39B 0.9900 . ?
C40 C41 1.516(11) . ?
C40 C53 1.549(11) . ?
C40 C47 1.646(11) 2_577 ?
C41 C42 1.380(11) . ?
C41 C46 1.405(11) . ?
C42 C43 1.383(12) . ?
C42 H42 0.9500 . ?
C43 C44 1.368(15) . ?
C43 H43 0.9500 . ?
C44 C45 1.402(13) . ?
C44 H44 0.9500 . ?
C45 C46 1.392(11) . ?
C45 H45 0.9500 . ?
C46 C47 1.503(10) . ?
C47 C48 1.522(11) . ?
C47 H47 1.0000 . ?
C48 C53 1.378(11) . ?
C48 C49 1.395(12) . ?
C49 C50 1.384(13) . ?
C49 H49 0.9500 . ?
C50 C51 1.393(13) . ?
C50 H50 0.9500 . ?
C51 C52 1.377(13) . ?
C51 H51 0.9500 . ?
C52 C53 1.399(11) . ?
C52 H52 0.9500 . ?
C54 O8 1.241(17) . ?
C54 C55 1.403(15) . ?
C54 H54A 0.9900 . ?
C54 H54B 0.9900 . ?
C55 H55A 0.9800 . ?
C55 H55B 0.9800 . ?
C55 H55C 0.9800 . ?
C56 C57 1.360(14) . ?
C56 O9 1.376(13) . ?
C56 H56A 0.9900 . ?
C56 H56B 0.9900 . ?
C57 H57A 0.9800 . ?
C57 H57B 0.9800 . ?
C57 H57C 0.9800 . ?
C58 C59 1.532(17) . ?
C58 H58A 0.9900 . ?
C58 H58B 0.9900 . ?
C59 C60 1.515(19) . ?
C59 C72 1.53(2) . ?
C59 C66 1.659(17) 2_667 ?
C60 C65 1.361(18) . ?
C60 C61 1.39(2) . ?
C61 C62 1.26(2) . ?
C61 H61 0.9500 . ?
C62 C63 1.25(2) . ?
C62 H62 0.9500 . ?
C63 C64 1.52(2) . ?
C63 H63 0.9500 . ?
C64 C65 1.393(19) . ?
C64 H64 0.9500 . ?
C65 C66 1.480(19) . ?
C66 C67 1.432(19) . ?
C66 H66 1.0000 . ?
C67 C72 1.325(19) . ?
C67 C68 1.41(2) . ?
C68 C69 1.30(2) . ?
C68 H68 0.9500 . ?
C69 C70 1.42(2) . ?
C69 H69 0.9500 . ?
C70 C71 1.37(2) . ?
C70 H70 0.9500 . ?
C71 C72 1.48(2) . ?
C71 H71 0.9500 . ?
C73 O20 1.417(17) . ?
C73 C74 1.453(17) . ?
C73 H73A 0.9900 . ?
C73 H73B 0.9900 . ?
C74 H74A 0.9800 . ?
C74 H74B 0.9800 . ?
C74 H74C 0.9800 . ?
C75 O21 1.435(15) . ?
C75 C76 1.446(17) . ?
C75 H75A 0.9900 . ?
C75 H75B 0.9900 . ?
C76 H76A 0.9800 . ?
C76 H76B 0.9800 . ?
C76 H76C 0.9800 . ?
N1 O12 1.221(10) . ?
N1 O11 1.255(9) . ?
N1 O10 1.263(9) . ?
N2 O15 1.211(11) . ?
N2 O13 1.229(11) . ?
N2 O14 1.264(10) . ?
N3 O18 1.207(10) . ?
N3 O17 1.253(10) . ?
N3 O16 1.282(10) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Dy1 O4 81.30(19) . . ?
O1 Dy1 O7 153.5(2) . . ?
O4 Dy1 O7 87.78(19) . . ?
O1 Dy1 O13 122.2(2) . . ?
O4 Dy1 O13 150.6(2) . . ?
O7 Dy1 O13 77.2(2) . . ?
O1 Dy1 O10 126.37(19) . . ?
O4 Dy1 O10 77.3(2) . . ?
O7 Dy1 O10 73.7(2) . . ?
O13 Dy1 O10 74.3(2) . . ?
O1 Dy1 O11 77.9(2) . . ?
O4 Dy1 O11 84.4(3) . . ?
O7 Dy1 O11 125.2(2) . . ?
O13 Dy1 O11 84.0(3) . . ?
O10 Dy1 O11 51.7(2) . . ?
O1 Dy1 O17 88.6(2) . . ?
O4 Dy1 O17 125.4(2) . . ?
O7 Dy1 O17 78.2(2) . . ?
O13 Dy1 O17 76.4(3) . . ?
O10 Dy1 O17 143.0(2) . . ?
O11 Dy1 O17 145.2(2) . . ?
O1 Dy1 O16 76.3(2) . . ?
O4 Dy1 O16 74.0(2) . . ?
O7 Dy1 O16 77.5(2) . . ?
O13 Dy1 O16 125.5(2) . . ?
O10 Dy1 O16 139.6(2) . . ?
O11 Dy1 O16 148.4(2) . . ?
O17 Dy1 O16 51.5(2) . . ?
O1 Dy1 O14 71.3(2) . . ?
O4 Dy1 O14 148.7(2) . . ?
O7 Dy1 O14 123.4(2) . . ?
O13 Dy1 O14 51.0(2) . . ?
O10 Dy1 O14 106.8(3) . . ?
O11 Dy1 O14 75.3(3) . . ?
O17 Dy1 O14 70.0(3) . . ?
O16 Dy1 O14 112.6(3) . . ?
O1 P1 O2 113.6(3) . . ?
O1 P1 O3 112.6(3) . . ?
O2 P1 O3 104.7(3) . . ?
O1 P1 C1 111.3(3) . . ?
O2 P1 C1 110.6(3) . . ?
O3 P1 C1 103.3(3) . . ?
O4 P2 O6 113.8(3) . . ?
O4 P2 O5 112.5(4) . . ?
O6 P2 O5 107.7(4) . . ?
O4 P2 C20 112.7(4) . . ?
O6 P2 C20 109.0(3) . . ?
O5 P2 C20 100.3(4) . . ?
O8 P3 O7 118.7(5) . . ?
O8 P3 O9 100.2(6) . . ?
O7 P3 O9 111.0(4) . . ?
O8 P3 C39 111.0(5) . . ?
O7 P3 C39 113.1(4) . . ?
O9 P3 C39 100.6(4) . . ?
O19 P4 O20 113.8(8) . . ?
O19 P4 O21 111.5(8) . . ?
O20 P4 O21 107.7(8) . . ?
O19 P4 C58 114.9(9) . . ?
O20 P4 C58 105.2(7) . . ?
O21 P4 C58 102.9(7) . . ?
C2 C1 P1 119.4(5) . . ?
C2 C1 H1A 107.5 . . ?
P1 C1 H1A 107.5 . . ?
C2 C1 H1B 107.5 . . ?
P1 C1 H1B 107.5 . . ?
H1A C1 H1B 107.0 . . ?
C15 C2 C3 108.1(6) . . ?
C15 C2 C1 112.8(6) . . ?
C3 C2 C1 112.6(6) . . ?
C15 C2 C9 108.8(5) . 2_566 ?
C3 C2 C9 109.0(5) . 2_566 ?
C1 C2 C9 105.4(6) . 2_566 ?
C4 C3 C8 118.4(6) . . ?
C4 C3 C2 124.1(6) . . ?
C8 C3 C2 117.5(6) . . ?
C5 C4 C3 120.8(7) . . ?
C5 C4 H4 119.6 . . ?
C3 C4 H4 119.6 . . ?
C4 C5 C6 120.1(8) . . ?
C4 C5 H5 119.9 . . ?
C6 C5 H5 119.9 . . ?
C5 C6 C7 120.2(7) . . ?
C5 C6 H6 119.9 . . ?
C7 C6 H6 119.9 . . ?
C8 C7 C6 119.4(8) . . ?
C8 C7 H7 120.3 . . ?
C6 C7 H7 120.3 . . ?
C7 C8 C3 121.1(7) . . ?
C7 C8 C9 121.3(7) . . ?
C3 C8 C9 117.6(6) . . ?
C10 C9 C8 108.3(6) . . ?
C10 C9 C2 113.6(6) . 2_566 ?
C8 C9 C2 112.8(6) . 2_566 ?
C10 C9 H9 107.3 . . ?
C8 C9 H9 107.3 . . ?
C2 C9 H9 107.3 2_566 . ?
C11 C10 C15 120.4(7) . . ?
C11 C10 C9 121.8(7) . . ?
C15 C10 C9 117.7(6) . . ?
C10 C11 C12 120.2(8) . . ?
C10 C11 H11 119.9 . . ?
C12 C11 H11 119.9 . . ?
C13 C12 C11 119.2(8) . . ?
C13 C12 H12 120.4 . . ?
C11 C12 H12 120.4 . . ?
C12 C13 C14 120.3(8) . . ?
C12 C13 H13 119.9 . . ?
C14 C13 H13 119.9 . . ?
C13 C14 C15 121.4(8) . . ?
C13 C14 H14 119.3 . . ?
C15 C14 H14 119.3 . . ?
C14 C15 C10 118.4(7) . . ?
C14 C15 C2 124.1(7) . . ?
C10 C15 C2 117.4(6) . . ?
C17 C16 O2 109.7(10) . . ?
C17 C16 H16A 109.7 . . ?
O2 C16 H16A 109.7 . . ?
C17 C16 H16B 109.7 . . ?
O2 C16 H16B 109.7 . . ?
H16A C16 H16B 108.2 . . ?
C16 C17 H17A 109.5 . . ?
C16 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C16 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C19 C18 O3 111.1(10) . . ?
C19 C18 H18A 109.4 . . ?
O3 C18 H18A 109.4 . . ?
C19 C18 H18B 109.4 . . ?
O3 C18 H18B 109.4 . . ?
H18A C18 H18B 108.0 . . ?
C18 C19 H19A 109.5 . . ?
C18 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
C18 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C21 C20 P2 122.8(5) . . ?
C21 C20 H20A 106.6 . . ?
P2 C20 H20A 106.6 . . ?
C21 C20 H20B 106.6 . . ?
P2 C20 H20B 106.6 . . ?
H20A C20 H20B 106.6 . . ?
C22 C21 C20 112.1(6) . . ?
C22 C21 C34 107.4(6) . . ?
C20 C21 C34 113.1(6) . . ?
C22 C21 C28 110.0(6) . 2_676 ?
C20 C21 C28 105.2(5) . 2_676 ?
C34 C21 C28 109.1(5) . 2_676 ?
C27 C22 C23 118.6(6) . . ?
C27 C22 C21 117.0(6) . . ?
C23 C22 C21 124.3(6) . . ?
C24 C23 C22 120.9(7) . . ?
C24 C23 H23 119.6 . . ?
C22 C23 H23 119.6 . . ?
C25 C24 C23 119.5(7) . . ?
C25 C24 H24 120.3 . . ?
C23 C24 H24 120.3 . . ?
C26 C25 C24 119.7(7) . . ?
C26 C25 H25 120.2 . . ?
C24 C25 H25 120.2 . . ?
C25 C26 C27 121.0(7) . . ?
C25 C26 H26 119.5 . . ?
C27 C26 H26 119.5 . . ?
C22 C27 C26 120.3(6) . . ?
C22 C27 C28 118.0(6) . . ?
C26 C27 C28 121.7(6) . . ?
C29 C28 C27 108.4(5) . . ?
C29 C28 C21 112.8(5) . 2_676 ?
C27 C28 C21 113.5(5) . 2_676 ?
C29 C28 H28 107.3 . . ?
C27 C28 H28 107.3 . . ?
C21 C28 H28 107.3 2_676 . ?
C30 C29 C34 119.9(7) . . ?
C30 C29 C28 121.5(7) . . ?
C34 C29 C28 118.5(6) . . ?
C31 C30 C29 120.9(7) . . ?
C31 C30 H30 119.5 . . ?
C29 C30 H30 119.5 . . ?
C32 C31 C30 118.9(8) . . ?
C32 C31 H31 120.5 . . ?
C30 C31 H31 120.5 . . ?
C31 C32 C33 120.4(8) . . ?
C31 C32 H32 119.8 . . ?
C33 C32 H32 119.8 . . ?
C34 C33 C32 120.5(8) . . ?
C34 C33 H33 119.8 . . ?
C32 C33 H33 119.8 . . ?
C33 C34 C29 119.3(7) . . ?
C33 C34 C21 124.3(7) . . ?
C29 C34 C21 116.5(6) . . ?
O5 C35 C36 112.2(11) . . ?
O5 C35 H35A 109.2 . . ?
C36 C35 H35A 109.2 . . ?
O5 C35 H35B 109.2 . . ?
C36 C35 H35B 109.2 . . ?
H35A C35 H35B 107.9 . . ?
C35 C36 H36A 109.5 . . ?
C35 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
C35 C36 H36C 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
C38 C37 O6 113.4(10) . . ?
C38 C37 H37A 108.9 . . ?
O6 C37 H37A 108.9 . . ?
C38 C37 H37B 108.9 . . ?
O6 C37 H37B 108.9 . . ?
H37A C37 H37B 107.7 . . ?
C37 C38 H38A 109.5 . . ?
C37 C38 H38B 109.5 . . ?
H38A C38 H38B 109.5 . . ?
C37 C38 H38C 109.5 . . ?
H38A C38 H38C 109.5 . . ?
H38B C38 H38C 109.5 . . ?
C40 C39 P3 124.2(7) . . ?
C40 C39 H39A 106.3 . . ?
P3 C39 H39A 106.3 . . ?
C40 C39 H39B 106.3 . . ?
P3 C39 H39B 106.3 . . ?
H39A C39 H39B 106.4 . . ?
C41 C40 C39 113.0(6) . . ?
C41 C40 C53 107.4(7) . . ?
C39 C40 C53 113.9(7) . . ?
C41 C40 C47 109.3(6) . 2_577 ?
C39 C40 C47 103.5(7) . 2_577 ?
C53 C40 C47 109.6(6) . 2_577 ?
C42 C41 C46 118.0(7) . . ?
C42 C41 C40 124.0(8) . . ?
C46 C41 C40 117.8(6) . . ?
C41 C42 C43 121.7(9) . . ?
C41 C42 H42 119.2 . . ?
C43 C42 H42 119.2 . . ?
C44 C43 C42 119.9(8) . . ?
C44 C43 H43 120.0 . . ?
C42 C43 H43 120.0 . . ?
C43 C44 C45 120.6(9) . . ?
C43 C44 H44 119.7 . . ?
C45 C44 H44 119.7 . . ?
C46 C45 C44 118.6(9) . . ?
C46 C45 H45 120.7 . . ?
C44 C45 H45 120.7 . . ?
C45 C46 C41 121.0(7) . . ?
C45 C46 C47 121.0(8) . . ?
C41 C46 C47 117.9(7) . . ?
C46 C47 C48 108.8(6) . . ?
C46 C47 C40 112.3(7) . 2_577 ?
C48 C47 C40 111.7(6) . 2_577 ?
C46 C47 H47 107.9 . . ?
C48 C47 H47 107.9 . . ?
C40 C47 H47 107.9 2_577 . ?
C53 C48 C49 121.3(8) . . ?
C53 C48 C47 118.0(7) . . ?
C49 C48 C47 120.7(8) . . ?
C50 C49 C48 119.5(9) . . ?
C50 C49 H49 120.3 . . ?
C48 C49 H49 120.3 . . ?
C49 C50 C51 119.8(8) . . ?
C49 C50 H50 120.1 . . ?
C51 C50 H50 120.1 . . ?
C52 C51 C50 120.1(9) . . ?
C52 C51 H51 120.0 . . ?
C50 C51 H51 120.0 . . ?
C51 C52 C53 120.8(8) . . ?
C51 C52 H52 119.6 . . ?
C53 C52 H52 119.6 . . ?
C48 C53 C52 118.5(7) . . ?
C48 C53 C40 117.8(7) . . ?
C52 C53 C40 123.4(7) . . ?
O8 C54 C55 113.5(15) . . ?
O8 C54 H54A 108.9 . . ?
C55 C54 H54A 108.9 . . ?
O8 C54 H54B 108.9 . . ?
C55 C54 H54B 108.9 . . ?
H54A C54 H54B 107.7 . . ?
C54 C55 H55A 109.5 . . ?
C54 C55 H55B 109.5 . . ?
H55A C55 H55B 109.5 . . ?
C54 C55 H55C 109.5 . . ?
H55A C55 H55C 109.5 . . ?
H55B C55 H55C 109.5 . . ?
C57 C56 O9 114.1(12) . . ?
C57 C56 H56A 108.7 . . ?
O9 C56 H56A 108.7 . . ?
C57 C56 H56B 108.7 . . ?
O9 C56 H56B 108.7 . . ?
H56A C56 H56B 107.6 . . ?
C56 C57 H57A 109.5 . . ?
C56 C57 H57B 109.5 . . ?
H57A C57 H57B 109.5 . . ?
C56 C57 H57C 109.5 . . ?
H57A C57 H57C 109.5 . . ?
H57B C57 H57C 109.5 . . ?
C59 C58 P4 123.2(11) . . ?
C59 C58 H58A 106.5 . . ?
P4 C58 H58A 106.5 . . ?
C59 C58 H58B 106.5 . . ?
P4 C58 H58B 106.5 . . ?
H58A C58 H58B 106.5 . . ?
C60 C59 C72 105.7(12) . . ?
C60 C59 C58 116.8(13) . . ?
C72 C59 C58 110.5(13) . . ?
C60 C59 C66 108.4(11) . 2_667 ?
C72 C59 C66 110.1(11) . 2_667 ?
C58 C59 C66 105.2(11) . 2_667 ?
C65 C60 C61 123.5(15) . . ?
C65 C60 C59 116.8(13) . . ?
C61 C60 C59 119.7(13) . . ?
C62 C61 C60 117.6(18) . . ?
C62 C61 H61 121.2 . . ?
C60 C61 H61 121.2 . . ?
C63 C62 C61 128(2) . . ?
C63 C62 H62 116.2 . . ?
C61 C62 H62 116.2 . . ?
C62 C63 C64 118.0(17) . . ?
C62 C63 H63 121.0 . . ?
C64 C63 H63 121.0 . . ?
C65 C64 C63 116.5(15) . . ?
C65 C64 H64 121.8 . . ?
C63 C64 H64 121.8 . . ?
C60 C65 C64 116.3(15) . . ?
C60 C65 C66 119.1(13) . . ?
C64 C65 C66 124.7(14) . . ?
C67 C66 C65 106.3(12) . . ?
C67 C66 C59 114.4(12) . 2_667 ?
C65 C66 C59 112.8(12) . 2_667 ?
C67 C66 H66 107.7 . . ?
C65 C66 H66 107.7 . . ?
C59 C66 H66 107.7 2_667 . ?
C72 C67 C68 127.0(15) . . ?
C72 C67 C66 120.7(15) . . ?
C68 C67 C66 112.2(14) . . ?
C69 C68 C67 116.3(17) . . ?
C69 C68 H68 121.9 . . ?
C67 C68 H68 121.9 . . ?
C68 C69 C70 122.7(18) . . ?
C68 C69 H69 118.7 . . ?
C70 C69 H69 118.7 . . ?
C71 C70 C69 119.1(16) . . ?
C71 C70 H70 120.4 . . ?
C69 C70 H70 120.4 . . ?
C70 C71 C72 119.0(16) . . ?
C70 C71 H71 120.5 . . ?
C72 C71 H71 120.5 . . ?
C67 C72 C71 114.8(15) . . ?
C67 C72 C59 117.5(13) . . ?
C71 C72 C59 127.7(13) . . ?
O20 C73 C74 108.3(17) . . ?
O20 C73 H73A 110.0 . . ?
C74 C73 H73A 110.0 . . ?
O20 C73 H73B 110.0 . . ?
C74 C73 H73B 110.0 . . ?
H73A C73 H73B 108.4 . . ?
C73 C74 H74A 109.5 . . ?
C73 C74 H74B 109.5 . . ?
H74A C74 H74B 109.5 . . ?
C73 C74 H74C 109.5 . . ?
H74A C74 H74C 109.5 . . ?
H74B C74 H74C 109.5 . . ?
O21 C75 C76 112.6(15) . . ?
O21 C75 H75A 109.1 . . ?
C76 C75 H75A 109.1 . . ?
O21 C75 H75B 109.1 . . ?
C76 C75 H75B 109.1 . . ?
H75A C75 H75B 107.8 . . ?
C75 C76 H76A 109.5 . . ?
C75 C76 H76B 109.5 . . ?
H76A C76 H76B 109.5 . . ?
C75 C76 H76C 109.5 . . ?
H76A C76 H76C 109.5 . . ?
H76B C76 H76C 109.5 . . ?
O12 N1 O11 123.1(8) . . ?
O12 N1 O10 121.6(8) . . ?
O11 N1 O10 115.3(7) . . ?
O15 N2 O13 122.9(9) . . ?
O15 N2 O14 121.1(9) . . ?
O13 N2 O14 115.7(8) . . ?
O18 N3 O17 122.9(9) . . ?
O18 N3 O16 121.4(9) . . ?
O17 N3 O16 115.7(7) . . ?
P1 O1 Dy1 173.8(4) . . ?
C16 O2 P1 125.4(6) . . ?
C18 O3 P1 120.2(6) . . ?
P2 O4 Dy1 168.1(3) . . ?
C35 O5 P2 127.6(7) . . ?
C37 O6 P2 124.9(6) . . ?
P3 O7 Dy1 155.3(4) . . ?
C54 O8 P3 141.4(12) . . ?
C56 O9 P3 120.9(8) . . ?
N1 O10 Dy1 96.8(4) . . ?
N1 O11 Dy1 96.2(5) . . ?
N2 O13 Dy1 98.9(5) . . ?
N2 O14 Dy1 94.3(5) . . ?
N3 O16 Dy1 95.3(5) . . ?
N3 O17 Dy1 97.3(5) . . ?
C73 O20 P4 123.6(12) . . ?
C75 O21 P4 124.0(13) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O1 P1 C1 C2 -118.5(5) . . . . ?
O2 P1 C1 C2 8.8(6) . . . . ?
O3 P1 C1 C2 120.4(5) . . . . ?
P1 C1 C2 C15 58.4(7) . . . . ?
P1 C1 C2 C3 -64.3(7) . . . . ?
P1 C1 C2 C9 176.9(4) . . . 2_566 ?
C15 C2 C3 C4 -137.5(7) . . . . ?
C1 C2 C3 C4 -12.2(10) . . . . ?
C9 C2 C3 C4 104.4(8) 2_566 . . . ?
C15 C2 C3 C8 43.4(9) . . . . ?
C1 C2 C3 C8 168.6(6) . . . . ?
C9 C2 C3 C8 -74.7(8) 2_566 . . . ?
C8 C3 C4 C5 -1.3(12) . . . . ?
C2 C3 C4 C5 179.6(8) . . . . ?
C3 C4 C5 C6 1.4(15) . . . . ?
C4 C5 C6 C7 -1.2(17) . . . . ?
C5 C6 C7 C8 0.9(17) . . . . ?
C6 C7 C8 C3 -0.7(14) . . . . ?
C6 C7 C8 C9 179.7(9) . . . . ?
C4 C3 C8 C7 0.9(12) . . . . ?
C2 C3 C8 C7 -179.9(7) . . . . ?
C4 C3 C8 C9 -179.4(7) . . . . ?
C2 C3 C8 C9 -0.3(10) . . . . ?
C7 C8 C9 C10 135.3(8) . . . . ?
C3 C8 C9 C10 -44.3(9) . . . . ?
C7 C8 C9 C2 -98.1(9) . . . 2_566 ?
C3 C8 C9 C2 82.3(8) . . . 2_566 ?
C8 C9 C10 C11 -136.8(8) . . . . ?
C2 C9 C10 C11 97.0(9) 2_566 . . . ?
C8 C9 C10 C15 45.7(9) . . . . ?
C2 C9 C10 C15 -80.5(8) 2_566 . . . ?
C15 C10 C11 C12 1.8(13) . . . . ?
C9 C10 C11 C12 -175.7(9) . . . . ?
C10 C11 C12 C13 1.2(16) . . . . ?
C11 C12 C13 C14 -2.7(18) . . . . ?
C12 C13 C14 C15 1.1(17) . . . . ?
C13 C14 C15 C10 1.9(14) . . . . ?
C13 C14 C15 C2 178.1(9) . . . . ?
C11 C10 C15 C14 -3.3(12) . . . . ?
C9 C10 C15 C14 174.3(7) . . . . ?
C11 C10 C15 C2 -179.8(7) . . . . ?
C9 C10 C15 C2 -2.2(10) . . . . ?
C3 C2 C15 C14 141.7(8) . . . . ?
C1 C2 C15 C14 16.5(11) . . . . ?
C9 C2 C15 C14 -100.1(9) 2_566 . . . ?
C3 C2 C15 C10 -42.1(9) . . . . ?
C1 C2 C15 C10 -167.3(6) . . . . ?
C9 C2 C15 C10 76.2(8) 2_566 . . . ?
O4 P2 C20 C21 121.1(6) . . . . ?
O6 P2 C20 C21 -6.2(7) . . . . ?
O5 P2 C20 C21 -119.1(7) . . . . ?
P2 C20 C21 C22 -61.4(8) . . . . ?
P2 C20 C21 C34 60.2(8) . . . . ?
P2 C20 C21 C28 179.1(5) . . . 2_676 ?
C20 C21 C22 C27 169.9(6) . . . . ?
C34 C21 C22 C27 45.1(8) . . . . ?
C28 C21 C22 C27 -73.5(8) 2_676 . . . ?
C20 C21 C22 C23 -12.4(9) . . . . ?
C34 C21 C22 C23 -137.2(7) . . . . ?
C28 C21 C22 C23 104.3(7) 2_676 . . . ?
C27 C22 C23 C24 -2.6(10) . . . . ?
C21 C22 C23 C24 179.8(7) . . . . ?
C22 C23 C24 C25 1.4(11) . . . . ?
C23 C24 C25 C26 0.5(12) . . . . ?
C24 C25 C26 C27 -1.2(12) . . . . ?
C23 C22 C27 C26 1.8(10) . . . . ?
C21 C22 C27 C26 179.7(7) . . . . ?
C23 C22 C27 C28 -179.0(6) . . . . ?
C21 C22 C27 C28 -1.1(9) . . . . ?
C25 C26 C27 C22 0.0(11) . . . . ?
C25 C26 C27 C28 -179.1(7) . . . . ?
C22 C27 C28 C29 -43.5(8) . . . . ?
C26 C27 C28 C29 135.6(7) . . . . ?
C22 C27 C28 C21 82.6(8) . . . 2_676 ?
C26 C27 C28 C21 -98.2(8) . . . 2_676 ?
C27 C28 C29 C30 -135.7(6) . . . . ?
C21 C28 C29 C30 97.7(7) 2_676 . . . ?
C27 C28 C29 C34 43.1(8) . . . . ?
C21 C28 C29 C34 -83.5(7) 2_676 . . . ?
C34 C29 C30 C31 0.2(10) . . . . ?
C28 C29 C30 C31 178.9(6) . . . . ?
C29 C30 C31 C32 1.5(11) . . . . ?
C30 C31 C32 C33 -2.0(12) . . . . ?
C31 C32 C33 C34 0.6(12) . . . . ?
C32 C33 C34 C29 1.1(11) . . . . ?
C32 C33 C34 C21 179.3(7) . . . . ?
C30 C29 C34 C33 -1.5(10) . . . . ?
C28 C29 C34 C33 179.7(6) . . . . ?
C30 C29 C34 C21 -179.8(6) . . . . ?
C28 C29 C34 C21 1.4(8) . . . . ?
C22 C21 C34 C33 136.2(7) . . . . ?
C20 C21 C34 C33 12.0(9) . . . . ?
C28 C21 C34 C33 -104.7(7) 2_676 . . . ?
C22 C21 C34 C29 -45.6(7) . . . . ?
C20 C21 C34 C29 -169.8(6) . . . . ?
C28 C21 C34 C29 73.6(7) 2_676 . . . ?
O8 P3 C39 C40 -11.2(9) . . . . ?
O7 P3 C39 C40 125.0(7) . . . . ?
O9 P3 C39 C40 -116.5(7) . . . . ?
P3 C39 C40 C41 -58.1(9) . . . . ?
P3 C39 C40 C53 64.9(9) . . . . ?
P3 C39 C40 C47 -176.1(5) . . . 2_577 ?
C39 C40 C41 C42 -15.8(12) . . . . ?
C53 C40 C41 C42 -142.4(8) . . . . ?
C47 C40 C41 C42 98.8(9) 2_577 . . . ?
C39 C40 C41 C46 169.2(7) . . . . ?
C53 C40 C41 C46 42.7(9) . . . . ?
C47 C40 C41 C46 -76.1(9) 2_577 . . . ?
C46 C41 C42 C43 -1.8(13) . . . . ?
C40 C41 C42 C43 -176.7(8) . . . . ?
C41 C42 C43 C44 1.2(15) . . . . ?
C42 C43 C44 C45 -2.5(16) . . . . ?
C43 C44 C45 C46 4.3(15) . . . . ?
C44 C45 C46 C41 -5.0(13) . . . . ?
C44 C45 C46 C47 173.5(9) . . . . ?
C42 C41 C46 C45 3.7(12) . . . . ?
C40 C41 C46 C45 178.9(8) . . . . ?
C42 C41 C46 C47 -174.8(7) . . . . ?
C40 C41 C46 C47 0.5(11) . . . . ?
C45 C46 C47 C48 138.0(8) . . . . ?
C41 C46 C47 C48 -43.5(10) . . . . ?
C45 C46 C47 C40 -97.7(9) . . . 2_577 ?
C41 C46 C47 C40 80.7(9) . . . 2_577 ?
C46 C47 C48 C53 42.1(10) . . . . ?
C40 C47 C48 C53 -82.5(8) 2_577 . . . ?
C46 C47 C48 C49 -139.3(8) . . . . ?
C40 C47 C48 C49 96.2(9) 2_577 . . . ?
C53 C48 C49 C50 1.7(13) . . . . ?
C47 C48 C49 C50 -176.9(8) . . . . ?
C48 C49 C50 C51 -0.4(13) . . . . ?
C49 C50 C51 C52 0.4(14) . . . . ?
C50 C51 C52 C53 -1.5(14) . . . . ?
C49 C48 C53 C52 -2.8(12) . . . . ?
C47 C48 C53 C52 175.8(7) . . . . ?
C49 C48 C53 C40 -176.7(7) . . . . ?
C47 C48 C53 C40 1.9(10) . . . . ?
C51 C52 C53 C48 2.7(12) . . . . ?
C51 C52 C53 C40 176.3(8) . . . . ?
C41 C40 C53 C48 -44.1(9) . . . . ?
C39 C40 C53 C48 -170.1(7) . . . . ?
C47 C40 C53 C48 74.5(8) 2_577 . . . ?
C41 C40 C53 C52 142.3(7) . . . . ?
C39 C40 C53 C52 16.3(11) . . . . ?
C47 C40 C53 C52 -99.1(8) 2_577 . . . ?
O19 P4 C58 C59 118.9(15) . . . . ?
O20 P4 C58 C59 -7.1(18) . . . . ?
O21 P4 C58 C59 -119.7(15) . . . . ?
P4 C58 C59 C60 -56(2) . . . . ?
P4 C58 C59 C72 64.5(18) . . . . ?
P4 C58 C59 C66 -176.7(12) . . . 2_667 ?
C72 C59 C60 C65 41.2(16) . . . . ?
C58 C59 C60 C65 164.6(14) . . . . ?
C66 C59 C60 C65 -76.9(16) 2_667 . . . ?
C72 C59 C60 C61 -135.8(14) . . . . ?
C58 C59 C60 C61 -12(2) . . . . ?
C66 C59 C60 C61 106.1(15) 2_667 . . . ?
C65 C60 C61 C62 6(3) . . . . ?
C59 C60 C61 C62 -177.4(16) . . . . ?
C60 C61 C62 C63 -2(3) . . . . ?
C61 C62 C63 C64 -4(3) . . . . ?
C62 C63 C64 C65 7(2) . . . . ?
C61 C60 C65 C64 -2(2) . . . . ?
C59 C60 C65 C64 -179.3(13) . . . . ?
C61 C60 C65 C66 179.2(14) . . . . ?
C59 C60 C65 C66 2(2) . . . . ?
C63 C64 C65 C60 -4(2) . . . . ?
C63 C64 C65 C66 174.5(14) . . . . ?
C60 C65 C66 C67 -46.0(17) . . . . ?
C64 C65 C66 C67 135.7(15) . . . . ?
C60 C65 C66 C59 80.1(16) . . . 2_667 ?
C64 C65 C66 C59 -98.1(16) . . . 2_667 ?
C65 C66 C67 C72 45.2(18) . . . . ?
C59 C66 C67 C72 -80.0(18) 2_667 . . . ?
C65 C66 C67 C68 -130.3(14) . . . . ?
C59 C66 C67 C68 104.5(14) 2_667 . . . ?
C72 C67 C68 C69 0(3) . . . . ?
C66 C67 C68 C69 175.1(15) . . . . ?
C67 C68 C69 C70 10(3) . . . . ?
C68 C69 C70 C71 -12(3) . . . . ?
C69 C70 C71 C72 5(2) . . . . ?
C68 C67 C72 C71 -6(2) . . . . ?
C66 C67 C72 C71 178.8(13) . . . . ?
C68 C67 C72 C59 174.2(14) . . . . ?
C66 C67 C72 C59 -1(2) . . . . ?
C70 C71 C72 C67 4(2) . . . . ?
C70 C71 C72 C59 -177.1(15) . . . . ?
C60 C59 C72 C67 -43.2(16) . . . . ?
C58 C59 C72 C67 -170.5(13) . . . . ?
C66 C59 C72 C67 73.7(16) 2_667 . . . ?
C60 C59 C72 C71 137.5(14) . . . . ?
C58 C59 C72 C71 10(2) . . . . ?
C66 C59 C72 C71 -105.6(16) 2_667 . . . ?
C17 C16 O2 P1 -92.3(11) . . . . ?
O1 P1 O2 C16 9.2(8) . . . . ?
O3 P1 O2 C16 132.5(7) . . . . ?
C1 P1 O2 C16 -116.8(8) . . . . ?
C19 C18 O3 P1 130.2(11) . . . . ?
O1 P1 O3 C18 64.4(7) . . . . ?
O2 P1 O3 C18 -59.5(7) . . . . ?
C1 P1 O3 C18 -175.4(7) . . . . ?
O6 P2 O4 Dy1 -92.5(19) . . . . ?
O5 P2 O4 Dy1 30(2) . . . . ?
C20 P2 O4 Dy1 142.8(18) . . . . ?
C36 C35 O5 P2 164.2(10) . . . . ?
O4 P2 O5 C35 -67.0(10) . . . . ?
O6 P2 O5 C35 59.2(10) . . . . ?
C20 P2 O5 C35 173.1(9) . . . . ?
C38 C37 O6 P2 -153.2(10) . . . . ?
O4 P2 O6 C37 2.4(9) . . . . ?
O5 P2 O6 C37 -123.0(8) . . . . ?
C20 P2 O6 C37 129.1(8) . . . . ?
O8 P3 O7 Dy1 150.6(9) . . . . ?
O9 P3 O7 Dy1 -94.2(9) . . . . ?
C39 P3 O7 Dy1 18.0(11) . . . . ?
C55 C54 O8 P3 143.8(15) . . . . ?
O7 P3 O8 C54 -28.3(19) . . . . ?
O9 P3 O8 C54 -149.3(17) . . . . ?
C39 P3 O8 C54 105.1(17) . . . . ?
C57 C56 O9 P3 -152.9(14) . . . . ?
O8 P3 O9 C56 76.1(11) . . . . ?
O7 P3 O9 C56 -50.2(12) . . . . ?
C39 P3 O9 C56 -170.1(11) . . . . ?
O12 N1 O10 Dy1 -178.0(9) . . . . ?
O11 N1 O10 Dy1 -0.6(8) . . . . ?
O12 N1 O11 Dy1 178.0(9) . . . . ?
O10 N1 O11 Dy1 0.6(8) . . . . ?
O15 N2 O13 Dy1 -169.7(12) . . . . ?
O14 N2 O13 Dy1 4.5(12) . . . . ?
O15 N2 O14 Dy1 170.0(12) . . . . ?
O13 N2 O14 Dy1 -4.3(11) . . . . ?
O18 N3 O16 Dy1 178.0(8) . . . . ?
O17 N3 O16 Dy1 -1.1(8) . . . . ?
O18 N3 O17 Dy1 -178.0(8) . . . . ?
O16 N3 O17 Dy1 1.2(8) . . . . ?
C74 C73 O20 P4 -87.5(18) . . . . ?
O19 P4 O20 C73 92.6(16) . . . . ?
O21 P4 O20 C73 -31.5(15) . . . . ?
C58 P4 O20 C73 -140.8(14) . . . . ?
C76 C75 O21 P4 109.0(18) . . . . ?
O19 P4 O21 C75 -14.4(16) . . . . ?
O20 P4 O21 C75 111.2(14) . . . . ?
C58 P4 O21 C75 -138.0(13) . . . . ?

_refine_diff_density_max         2.781
_refine_diff_density_min         -1.257
_refine_diff_density_rms         0.123


# start Validation Reply Form
_vrf_PLAT971_reverse2            
;
PROBLEM: Check Calcd Resid. Dens. 1.16Ang From O19 2.91 eA-3
RESPONSE: No more atoms can be determined. The alert may originate 
from the slightly disordered guest of depma2.
;
# end Validation Reply Form
_exptl_crystal_recrystallization_method 'solid state photochemical reaction'
_chemical_properties_physical    
Heat-sensitive,Light-sensitive,Photo-sensitive
_exptl_crystal_preparation       Luminescent,mechanical
