# Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C.
# This journal is © The Royal Society of Chemistry 2022

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_wangyuan-b
_database_code_depnum_ccdc_archive 'CCDC 2087952'
loop_
_audit_author_name
_audit_author_address
'yuan wang'
;Hebei University of Technology
China
;
_audit_update_record             
;
2021-06-04 deposited with the CCDC.	2022-08-03 downloaded from the CCDC.
;
_audit_creation_date             2021-06-02
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6272)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C32 H16 Eu F12 O8 S4, C24 H20 P'
_chemical_formula_sum            'C56 H36 Eu F12 O8 P S4'
_chemical_formula_weight         1376.02
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -8.9294 11.1857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.3331 0.5567 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   12.5388(5)
_cell_length_b                   14.6688(6)
_cell_length_c                   16.2920(7)
_cell_angle_alpha                84.687(3)
_cell_angle_beta                 83.102(3)
_cell_angle_gamma                77.416(3)
_cell_volume                     2896.6(2)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    13282
_cell_measurement_temperature    109(15)
_cell_measurement_theta_max      75.1740
_cell_measurement_theta_min      3.9370
_shelx_estimated_absorpt_T_max   0.430
_shelx_estimated_absorpt_T_min   0.375
_exptl_absorpt_coefficient_mu    10.165
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.43245
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.40.84a (Rigaku Oxford Diffraction, 2020)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.578
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1372
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.11
_exptl_crystal_size_min          0.1
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0741
_diffrn_reflns_av_unetI/netI     0.0672
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.955
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            28843
_diffrn_reflns_point_group_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.955
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         76.150
_diffrn_reflns_theta_min         3.990
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      109(15)
_diffrn_detector                 'Hybrid Pixel Array Detector'
_diffrn_detector_area_resol_mean 10.0000
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.955
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω    -22.00  37.00   0.50    1.69    --    0.00  82.00-180.00  118
  2  ω    -23.00  39.00   0.50    1.69    --    0.00  82.00 -90.00  124
  3  ω    -34.00  39.00   0.50    1.69    --    0.00  82.00 120.00  146
  4  ω    -23.00  39.00   0.50    1.69    --    0.00  82.00 -30.00  124
  5  ω    -33.00  31.00   0.50    1.69    --    0.00  82.00  60.00  128
  6  ω      0.00  26.00   0.50    1.69    --    0.00  82.00-150.00   52
  7  ω     47.00 127.00   0.50    6.74    --  101.30 -57.00   0.00  160
  8  ω     12.00  39.00   0.50    6.74    --  101.30 -57.00   0.00   54
  9  ω     36.00 136.00   0.50    6.74    --  101.30 -82.00   0.00  200
 10  ω     41.00 107.00   0.50    6.74    --  101.30 -82.00 150.00  132
 11  ω     13.00 116.00   0.50    6.74    --  101.30 -19.00-150.00  206
 12  ω     18.00  50.00   0.50    6.74    --  101.30 -82.00  60.00   64
 13  ω     94.00 124.00   0.50    6.74    --  101.30 -82.00  60.00   60
 14  ω     19.00  74.00   0.50    6.74    --  101.30 -38.00-180.00  110
 15  ω     35.00  73.00   0.50    6.74    --  101.30 -82.00-180.00   76
 16  ω     38.00 129.00   0.50    6.74    --  101.30 -19.00  90.00  182
 17  ω     64.00 135.00   0.50    6.74    --  101.30 -82.00-150.00  142
 18  ω     67.00 191.00   0.50    6.74    --  101.30   0.00 -30.00  248
 19  ω     82.00 136.00   0.50    6.74    --  101.30 -82.00-180.00  108
 20  ω     63.00 106.00   0.50    6.74    --  101.30 -82.00 -60.00   86
 21  ω     36.00 136.00   0.50    6.74    --  101.30 -82.00 120.00  200
 22  ω     12.00  61.00   0.50    6.74    --  101.30   0.00 -30.00   98
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'XtaLAB AFC12 (RINC): Kappa single'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.0928835000
_diffrn_orient_matrix_UB_12      -0.0089313000
_diffrn_orient_matrix_UB_13      0.0693572000
_diffrn_orient_matrix_UB_21      0.0444886000
_diffrn_orient_matrix_UB_22      0.0621565000
_diffrn_orient_matrix_UB_23      0.0530606000
_diffrn_orient_matrix_UB_31      -0.0735558000
_diffrn_orient_matrix_UB_32      0.0877011000
_diffrn_orient_matrix_UB_33      -0.0385921000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.54184
_diffrn_source                   'Rotating-anode X-ray tube (dual wavelength)'
_diffrn_source_type              'Rigaku (Cu) X-ray DW Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                10023
_reflns_number_total             11592
_reflns_odcompleteness_completeness 99.66
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     66.97
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.40.84a (Rigaku OD, 2020)'
_computing_data_collection       'CrysAlisPro 1.171.40.84a (Rigaku OD, 2020)'
_computing_data_reduction        'CrysAlisPro 1.171.40.84a (Rigaku OD, 2020)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_refine_diff_density_max         3.108
_refine_diff_density_min         -2.159
_refine_diff_density_rms         0.136
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.047
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     904
_refine_ls_number_reflns         11592
_refine_ls_number_restraints     795
_refine_ls_R_factor_all          0.1013
_refine_ls_R_factor_gt           0.0903
_refine_ls_restrained_S_all      1.023
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1335P)²+15.5065P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2405
_refine_ls_wR_factor_ref         0.2469
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
2. Restrained distances
 C20A-C18 \\sim C20-C18
 with sigma of 0.02
 C20A-C12A \\sim C20-C12
 with sigma of 0.02
 C53-C49 \\sim C53A-C49A
 with sigma of 0.02
 S23A-C20A \\sim S23-C20
 with sigma of 0.02
 S23-C53 \\sim S23A-C53A
 with sigma of 0.02
 C49-C12 \\sim C49A-C12A
 with sigma of 0.02
 F12-F11 \\sim F11-F10 \\sim F12-F10
 with sigma of 0.02
 F11-C51 \\sim F12-C51 \\sim F10-C51
 with sigma of 0.02
 F11-C14 \\sim F12-C14 \\sim F10-C14
 with sigma of 0.02
 F12A-F10A \\sim F12A-F11A \\sim F11A-F10A
 with sigma of 0.02
 F12A-C51A \\sim F10A-C51A \\sim F11A-C51A
 with sigma of 0.02
 F11A-C48 \\sim F10A-C48 \\sim F12A-C48
 with sigma of 0.02
 C51A-C48 \\sim C51-C14
 with sigma of 0.02
 S24-C55 \\sim S24A-C55A
 with sigma of 0.02
 C37A-C14 \\sim C48-C37
 with sigma of 0.02
 C54-C56 \\sim C56A-C55A
 with sigma of 0.02
 S24A-C37A \\sim S24-C37
 with sigma of 0.02
 C37A-C54A \\sim C37-C54
 with sigma of 0.02
 S24-C56 \\sim S24A-C56A
 with sigma of 0.02
 S24A-C54A \\sim S24-C54
 with sigma of 0.02
 C54A-C55A \\sim C37A-C56A \\sim C37-C56 \\sim C54-C55
 with sigma of 0.02
 S22-C4 \\sim S22A-C4
 with sigma of 0.02
 C45A-C1A \\sim C45-C1
 with sigma of 0.02
 S22A-C40A \\sim S22-C40
 with sigma of 0.02
 C45A-C40A \\sim C45-C40
 with sigma of 0.02
 C4-C1A \\sim C4-C1
 with sigma of 0.02
3. Restrained planarity
 C20A, C12A, C49A, C53A, S23A, C18
 with sigma of 0.1
4. Uiso/Uaniso restraints and constraints
S24 \\sim C37 \\sim C54 \\sim C56 \\sim C55: within 2A with sigma of 0.02 and
sigma for terminal atoms of 0.04 within 2A
S23 \\sim C12 \\sim C20 \\sim C49 \\sim C53 \\sim C20A \\sim S23A \\sim C53A
\\sim C49A \\sim C12A: within 2A with sigma of 0.01 and sigma for terminal
atoms of 0.02 within 2A
F10 \\sim F11 \\sim F12 \\sim C51 \\sim C37A \\sim S24A \\sim C55A \\sim C56A
\\sim C54A \\sim S24 \\sim C37 \\sim C54 \\sim C55 \\sim C56 \\sim C51A \\sim
F12A \\sim F11A \\sim F10A: within 2A with sigma of 0.01 and sigma for terminal
atoms of 0.02 within 2A
S22 \\sim C1 \\sim C40 \\sim C45 \\sim S22A \\sim C1A \\sim C40A \\sim C45A:
within 2A with sigma of 0.01 and sigma for terminal atoms of 0.02 within 2A
5. Rigid body (RIGU) restrains
 C20A, C12A, C49A, S23A, C53A, C18
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.002
 S23, C53, C49, C12, C20, C18
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.002
 S24, F10, F11, F12, C14, C34, C37, C48, C51, C54, C55, C56
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.002
 C14, C34, C48, C51A, F12A, F11A, F10A, C37A, S24A, C55A, C56A, C54A
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.002
 C4, S22A, C1A, C40A, C45A
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.002
 S22, C1, C4, C40, C45
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.002
6. Others
 Sof(C20A)=Sof(S23A)=Sof(C53A)=Sof(H53A)=Sof(C49A)=Sof(H49A)=Sof(C12A)=
 Sof(H12A)=1-FVAR(1)
 Sof(S23)=Sof(C12)=Sof(H12)=Sof(C20)=Sof(C49)=Sof(H49)=Sof(C53)=Sof(H53)=FVAR(1)
 Sof(C51A)=Sof(F12A)=Sof(F11A)=Sof(F10A)=Sof(C37A)=Sof(S24A)=Sof(C55A)=
 Sof(H55A)=Sof(C56A)=Sof(H56A)=Sof(C54A)=Sof(H54A)=1-FVAR(2)
 Sof(S24)=Sof(F10)=Sof(F11)=Sof(F12)=Sof(C37)=Sof(C51)=Sof(C54)=Sof(H54)=
 Sof(C55)=Sof(H55)=Sof(C56)=Sof(H56)=FVAR(2)
 Sof(S22A)=Sof(C1A)=Sof(H1A)=Sof(C40A)=Sof(H40A)=Sof(C45A)=Sof(H45A)=1-FVAR(3)
 Sof(S22)=Sof(C1)=Sof(H1)=Sof(C40)=Sof(H40)=Sof(C45)=Sof(H45)=FVAR(3)
7.a Aromatic/amide H refined with riding coordinates:
 C1(H1), C2(H2), C7(H7), C8(H8), C12(H12), C13(H13), C16(H16), C19(H19),
 C21(H21), C23(H23), C24(H24), C27(H27), C28(H28), C30(H30), C31(H31), C32(H32),
  C33(H33), C34(H34), C35(H35), C36(H36), C38(H38), C39(H39), C40(H40),
 C41(H41), C42(H42), C43(H43), C44(H44), C45(H45), C47(H47), C49(H49), C50(H50),
  C52(H52), C53(H53), C54(H54), C55(H55), C56(H56), C53A(H53A), C49A(H49A),
 C12A(H12A), C55A(H55A), C56A(H56A), C54A(H54A), C1A(H1A), C40A(H40A),
 C45A(H45A)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.28650(4) 0.72368(3) 0.72657(3) 0.03888(17) Uani 1 1 d . . . . .
P1 P 0.18537(18) 0.81351(16) 0.22589(12) 0.0451(5) Uani 1 1 d . . . . .
S21 S 0.57236(19) 0.52175(17) 0.89742(13) 0.0544(5) Uani 1 1 d . . . . .
S22 S 0.3367(4) 0.3728(3) 0.6965(2) 0.0640(11) Uani 0.829(10) 1 d D U P A 1
S23 S 0.4149(4) 0.5880(3) 0.4428(2) 0.0640(12) Uani 0.714(9) 1 d D U P B 1
O13 O 0.4526(5) 0.6463(4) 0.7790(3) 0.0447(12) Uani 1 1 d . . . . .
O14 O 0.2859(5) 0.5591(4) 0.7487(3) 0.0425(12) Uani 1 1 d . . . . .
F1 F 0.0031(5) 0.5989(4) 0.9949(4) 0.0679(15) Uani 1 1 d . . . . .
O15 O 0.3341(6) 0.8376(4) 0.8045(4) 0.0556(15) Uani 1 1 d . . . . .
O16 O 0.2898(5) 0.6660(4) 0.5957(3) 0.0472(13) Uani 1 1 d . . . . .
O17 O 0.4344(5) 0.7713(5) 0.6402(3) 0.0496(14) Uani 1 1 d . . . . .
F2 F 0.5294(5) 0.9113(5) 0.5663(4) 0.0767(19) Uani 1 1 d . . . . .
O18 O 0.1904(5) 0.7003(4) 0.8600(3) 0.0423(12) Uani 1 1 d . . . . .
S24 S 0.0603(5) 1.0092(5) 0.5683(4) 0.111(2) Uani 0.650(6) 1 d D U P C 1
F3 F 0.6848(5) 0.8431(5) 0.6067(5) 0.084(2) Uani 1 1 d . . . . .
O19 O 0.2076(5) 0.8778(4) 0.6722(4) 0.0533(15) Uani 1 1 d . . . . .
O20 O 0.1022(5) 0.7229(5) 0.7050(4) 0.0522(15) Uani 1 1 d . . . . .
F4 F -0.1127(6) 0.7874(5) 0.6809(6) 0.101(3) Uani 1 1 d . . . . .
F5 F 0.0940(6) 0.6946(7) 1.0193(4) 0.100(3) Uani 1 1 d . . . . .
C1 C 0.2137(16) 0.3400(12) 0.8258(11) 0.063(2) Uani 0.829(10) 1 d D U P A 1
H1 H 0.162372 0.348562 0.872083 0.076 Uiso 0.829(10) 1 calc R U P A 1
F6 F -0.0278(7) 0.7342(6) 0.9362(5) 0.122(4) Uani 1 1 d . . . . .
F7 F 0.6100(7) 0.7818(6) 0.5171(4) 0.097(2) Uani 1 1 d . . . . .
F8 F -0.0799(7) 0.6542(7) 0.7568(6) 0.117(3) Uani 1 1 d . . . . .
C2 C 0.2834(8) 0.7895(6) 0.0632(5) 0.050(2) Uani 1 1 d . . . . .
H2 H 0.216276 0.820335 0.045519 0.060 Uiso 1 1 calc R U . . .
C3 C 0.2301(7) 0.5120(6) 0.7972(5) 0.0422(17) Uani 1 1 d . . . . .
F9 F -0.1115(6) 0.6589(6) 0.6282(8) 0.122(4) Uani 1 1 d . . . . .
C4 C 0.2495(7) 0.4122(6) 0.7824(5) 0.0478(17) Uani 1 1 d D . . . .
C5 C 0.2955(7) 0.7763(7) 0.1473(5) 0.0486(19) Uani 1 1 d . . . . .
C6 C 0.1396(6) 0.6365(6) 0.8873(5) 0.0400(16) Uani 1 1 d . . . . .
C7 C 0.3978(8) 0.7293(7) 0.1735(6) 0.056(2) Uani 1 1 d . . . . .
H7 H 0.406428 0.718852 0.229735 0.067 Uiso 1 1 calc R U . . .
F10 F 0.4929(10) 0.8960(8) 0.8654(8) 0.082(3) Uani 0.650(6) 1 d D U P C 1
C8 C 0.1519(7) 0.5469(6) 0.8628(5) 0.0418(17) Uani 1 1 d . . . . .
H8 H 0.107348 0.508312 0.890357 0.050 Uiso 1 1 calc R U . . .
C9 C 0.5444(7) 0.6670(6) 0.7793(5) 0.0456(18) Uani 1 1 d . . . . .
F11 F 0.3386(9) 0.9804(7) 0.9136(6) 0.081(2) Uani 0.650(6) 1 d D U P C 1
C10 C 0.6144(7) 0.6164(6) 0.8423(5) 0.0445(18) Uani 1 1 d . . . . .
C11 C 0.0523(7) 0.6664(6) 0.9601(5) 0.0474(19) Uani 1 1 d . . . . .
F12 F 0.4345(10) 1.0363(7) 0.8101(8) 0.092(3) Uani 0.650(6) 1 d D U P C 1
C12 C 0.2412(17) 0.5334(13) 0.4326(11) 0.070(2) Uani 0.714(9) 1 d D U P B 1
H12 H 0.169435 0.524312 0.438990 0.084 Uiso 0.714(9) 1 calc R U P B 1
C13 C 0.3706(8) 0.7573(7) 0.0057(6) 0.056(2) Uani 1 1 d . . . . .
H13 H 0.361144 0.765746 -0.050418 0.067 Uiso 1 1 calc R U . . .
C14 C 0.3473(9) 0.9189(7) 0.7862(6) 0.060(2) Uani 1 1 d D . . . .
C15 C 0.5290(7) 0.7731(7) 0.6545(5) 0.049(2) Uani 1 1 d . . . . .
C16 C 0.7108(8) 0.6346(7) 0.8707(5) 0.053(2) Uani 1 1 d . . . . .
H16 H 0.746065 0.682655 0.849749 0.064 Uiso 1 1 calc R U . . .
C17 C 0.0867(8) 0.9099(7) 0.1875(5) 0.050(2) Uani 1 1 d . . . . .
C18 C 0.2269(8) 0.6311(6) 0.5583(5) 0.0504(18) Uani 1 1 d D . . . .
C19 C -0.0686(9) 1.0588(8) 0.1260(6) 0.064(3) Uani 1 1 d . . . . .
H19 H -0.118496 1.108739 0.103808 0.077 Uiso 1 1 calc R U . . .
C20 C 0.277(2) 0.5825(13) 0.4851(9) 0.064(2) Uani 0.714(9) 1 d D U P B 1
C21 C 0.4715(8) 0.7125(7) 0.0305(6) 0.057(2) Uani 1 1 d . . . . .
H21 H 0.529815 0.691681 -0.008836 0.068 Uiso 1 1 calc R U . . .
C22 C 0.2469(8) 0.8474(7) 0.3084(5) 0.051(2) Uani 1 1 d . . . . .
C23 C 0.1136(9) 0.6417(8) 0.5839(8) 0.065(3) Uani 1 1 d . . . . .
H23 H 0.070544 0.617042 0.552754 0.079 Uiso 1 1 calc R U . . .
C24 C 0.4859(8) 0.6987(8) 0.1148(6) 0.059(2) Uani 1 1 d . . . . .
H24 H 0.553924 0.669228 0.131752 0.071 Uiso 1 1 calc R U . . .
C25 C 0.1157(7) 0.7191(6) 0.2578(5) 0.0488(19) Uani 1 1 d . . . . .
C26 C 0.5899(8) 0.8278(8) 0.5861(6) 0.061(3) Uani 1 1 d . . . . .
C27 C 0.7440(8) 0.5669(8) 0.9364(6) 0.058(2) Uani 1 1 d . . . . .
H27 H 0.805499 0.566270 0.963342 0.070 Uiso 1 1 calc R U . . .
C28 C 0.1516(8) 0.6340(7) 0.2232(6) 0.056(2) Uani 1 1 d . . . . .
H28 H 0.213850 0.623975 0.185214 0.068 Uiso 1 1 calc R U . . .
C29 C 0.0640(8) 0.6874(6) 0.6534(7) 0.058(2) Uani 1 1 d . . . . .
C30 C 0.0777(8) 1.0016(7) 0.2118(5) 0.053(2) Uani 1 1 d . . . . .
H30 H 0.124644 1.013216 0.247804 0.064 Uiso 1 1 calc R U . . .
C31 C 0.0940(9) 0.5642(8) 0.2459(7) 0.063(2) Uani 1 1 d . . . . .
H31 H 0.118657 0.506376 0.223462 0.075 Uiso 1 1 calc R U . . .
C32 C 0.6791(8) 0.5035(8) 0.9566(6) 0.059(2) Uani 1 1 d . . . . .
H32 H 0.691576 0.455494 0.998074 0.071 Uiso 1 1 calc R U . . .
C33 C 0.0000(9) 0.5783(8) 0.3013(8) 0.069(3) Uani 1 1 d . . . . .
H33 H -0.038989 0.531053 0.315444 0.082 Uiso 1 1 calc R U . . .
C34 C 0.3015(10) 0.9809(7) 0.7247(6) 0.065(2) Uani 1 1 d . . . . .
H34 H 0.316380 1.040653 0.717585 0.079 Uiso 1 1 calc R U . . .
C35 C 0.5873(7) 0.7299(6) 0.7203(5) 0.0483(19) Uani 1 1 d . . . . .
H35 H 0.655528 0.742823 0.725363 0.058 Uiso 1 1 calc R U . . .
C36 C 0.0207(9) 0.7359(8) 0.3118(9) 0.075(3) Uani 1 1 d . . . . .
H36 H -0.005584 0.794740 0.331992 0.090 Uiso 1 1 calc R U . . .
C37 C 0.1719(18) 1.0291(16) 0.6112(13) 0.093(3) Uani 0.650(6) 1 d D U P C 1
C38 C -0.0007(10) 1.0734(7) 0.1818(6) 0.066(3) Uani 1 1 d . . . . .
H38 H -0.008219 1.133166 0.199565 0.079 Uiso 1 1 calc R U . . .
C39 C -0.0616(9) 0.9689(8) 0.1035(6) 0.062(3) Uani 1 1 d . . . . .
H39 H -0.109242 0.958443 0.067538 0.075 Uiso 1 1 calc R U . . .
C40 C 0.3270(13) 0.2588(10) 0.7263(9) 0.070(2) Uani 0.829(10) 1 d D U P A 1
H40 H 0.364695 0.208057 0.696898 0.084 Uiso 0.829(10) 1 calc R U P A 1
C41 C 0.2248(11) 0.8150(7) 0.3917(6) 0.068(3) Uani 1 1 d . . . . .
H41 H 0.176700 0.774523 0.405338 0.082 Uiso 1 1 calc R U . . .
C42 C 0.0147(8) 0.8943(7) 0.1334(6) 0.055(2) Uani 1 1 d . . . . .
H42 H 0.018232 0.834273 0.117778 0.066 Uiso 1 1 calc R U . . .
C43 C 0.3213(10) 0.9048(10) 0.2902(7) 0.073(3) Uani 1 1 d . . . . .
H43 H 0.338679 0.924321 0.235206 0.088 Uiso 1 1 calc R U . . .
C44 C 0.2741(16) 0.8432(9) 0.4518(7) 0.096(5) Uani 1 1 d . . . . .
H44 H 0.259035 0.822512 0.506836 0.115 Uiso 1 1 calc R U . . .
C45 C 0.2594(13) 0.2500(10) 0.7965(9) 0.070(2) Uani 0.829(10) 1 d D U P A 1
H45 H 0.244963 0.193831 0.821604 0.084 Uiso 0.829(10) 1 calc R U P A 1
C46 C -0.0666(12) 0.6952(10) 0.6798(11) 0.092(4) Uani 1 1 d . . . . .
C47 C 0.3460(14) 0.9019(12) 0.4318(8) 0.096(5) Uani 1 1 d . . . . .
H47 H 0.379439 0.920735 0.473455 0.115 Uiso 1 1 calc R U . . .
C48 C 0.2346(9) 0.9562(7) 0.6736(6) 0.061(2) Uani 1 1 d D . . . .
C49 C 0.3196(15) 0.4955(13) 0.3657(11) 0.073(2) Uani 0.714(9) 1 d D U P B 1
H49 H 0.305719 0.457644 0.327206 0.087 Uiso 0.714(9) 1 calc R U P B 1
C50 C 0.3696(12) 0.9337(11) 0.3500(8) 0.086(4) Uani 1 1 d . . . . .
H50 H 0.417836 0.974051 0.336697 0.103 Uiso 1 1 calc R U . . .
C51 C 0.4048(13) 0.9582(10) 0.8444(11) 0.074(2) Uani 0.650(6) 1 d D U P C 1
C52 C -0.0348(10) 0.6648(10) 0.3353(10) 0.085(4) Uani 1 1 d . . . . .
H52 H -0.096009 0.674623 0.374269 0.102 Uiso 1 1 calc R U . . .
C53 C 0.4121(16) 0.5212(13) 0.3664(11) 0.070(2) Uani 0.714(9) 1 d D U P B 1
H53 H 0.471886 0.503777 0.327284 0.084 Uiso 0.714(9) 1 calc R U P B 1
C54 C 0.2005(17) 1.1135(15) 0.5795(11) 0.099(3) Uani 0.650(6) 1 d D U P C 1
H54 H 0.259376 1.135177 0.594529 0.118 Uiso 0.650(6) 1 calc R U P C 1
C55 C 0.0514(17) 1.1142(15) 0.5078(11) 0.109(4) Uani 0.650(6) 1 d D U P C 1
H55 H -0.000131 1.135906 0.470077 0.131 Uiso 0.650(6) 1 calc R U P C 1
C56 C 0.1298(18) 1.1610(15) 0.5226(11) 0.109(4) Uani 0.650(6) 1 d D U P C 1
H56 H 0.135312 1.219323 0.496921 0.130 Uiso 0.650(6) 1 calc R U P C 1
C20A C 0.276(3) 0.577(2) 0.4901(15) 0.066(3) Uani 0.286(9) 1 d D U P B 2
S23A S 0.1918(9) 0.5120(8) 0.4504(7) 0.070(2) Uani 0.286(9) 1 d D U P B 2
C53A C 0.296(3) 0.473(3) 0.382(2) 0.070(3) Uani 0.286(9) 1 d D U P B 2
H53A H 0.289870 0.434104 0.342073 0.084 Uiso 0.286(9) 1 calc R U P B 2
C49A C 0.388(3) 0.499(3) 0.386(2) 0.069(3) Uani 0.286(9) 1 d D U P B 2
H49A H 0.452249 0.480172 0.351487 0.082 Uiso 0.286(9) 1 calc R U P B 2
C12A C 0.377(3) 0.562(3) 0.451(2) 0.067(2) Uani 0.286(9) 1 d D U P B 2
H12A H 0.433104 0.588932 0.464461 0.080 Uiso 0.286(9) 1 calc R U P B 2
C51A C 0.1839(18) 1.0315(18) 0.6148(15) 0.088(3) Uani 0.350(6) 1 d D U P C 2
F12A F 0.2045(16) 1.1155(11) 0.6224(12) 0.091(4) Uani 0.350(6) 1 d D U P C 2
F11A F 0.2170(16) 1.0150(14) 0.5357(9) 0.099(4) Uani 0.350(6) 1 d D U P C 2
F10A F 0.0751(14) 1.0416(13) 0.6230(12) 0.094(4) Uani 0.350(6) 1 d D U P C 2
C37A C 0.437(3) 0.944(2) 0.837(2) 0.075(3) Uani 0.350(6) 1 d D U P C 2
S24A S 0.4295(9) 1.0605(7) 0.8533(6) 0.076(2) Uani 0.350(6) 1 d D U P C 2
C55A C 0.532(3) 1.0325(17) 0.919(2) 0.074(4) Uani 0.350(6) 1 d D U P C 2
H55A H 0.557041 1.075780 0.945938 0.089 Uiso 0.350(6) 1 calc R U P C 2
C56A C 0.572(2) 0.9370(17) 0.9257(19) 0.074(4) Uani 0.350(6) 1 d D U P C 2
H56A H 0.631362 0.909215 0.955054 0.089 Uiso 0.350(6) 1 calc R U P C 2
C54A C 0.516(4) 0.8857(18) 0.885(3) 0.074(3) Uani 0.350(6) 1 d D U P C 2
H54A H 0.528848 0.820676 0.888689 0.089 Uiso 0.350(6) 1 calc R U P C 2
S22A S 0.1955(19) 0.3312(13) 0.8476(12) 0.064(3) Uani 0.171(10) 1 d D U P A 2
C1A C 0.317(7) 0.373(5) 0.718(5) 0.066(3) Uani 0.171(10) 1 d D U P A 2
H1A H 0.371361 0.401002 0.687924 0.080 Uiso 0.171(10) 1 calc R U P A 2
C40A C 0.234(6) 0.256(4) 0.769(3) 0.066(3) Uani 0.171(10) 1 d D U P A 2
H40A H 0.212441 0.198770 0.772153 0.079 Uiso 0.171(10) 1 calc R U P A 2
C45A C 0.297(6) 0.285(4) 0.702(4) 0.067(3) Uani 0.171(10) 1 d D U P A 2
H45A H 0.321717 0.253229 0.654577 0.080 Uiso 0.171(10) 1 calc R U P A 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O13 2.361(5) . ?
Eu1 O14 2.409(6) . ?
Eu1 O15 2.402(6) . ?
Eu1 O16 2.358(6) . ?
Eu1 O17 2.379(6) . ?
Eu1 O18 2.389(5) . ?
Eu1 O19 2.395(6) . ?
Eu1 O20 2.381(6) . ?
P1 C5 1.794(9) . ?
P1 C17 1.784(9) . ?
P1 C22 1.787(9) . ?
P1 C25 1.799(10) . ?
S21 C10 1.728(9) . ?
S21 C32 1.703(10) . ?
S22 C4 1.731(9) . ?
S22 C40 1.724(14) . ?
S23 C20 1.80(3) . ?
S23 C53 1.662(17) . ?
O13 C9 1.254(10) . ?
O14 C3 1.252(10) . ?
F1 C11 1.327(10) . ?
O15 C14 1.243(11) . ?
O16 C18 1.268(10) . ?
O17 C15 1.242(10) . ?
F2 C26 1.327(13) . ?
O18 C6 1.262(9) . ?
S24 C37 1.73(3) . ?
S24 C55 1.740(18) . ?
F3 C26 1.344(11) . ?
O19 C48 1.271(12) . ?
O20 C29 1.222(12) . ?
F4 C46 1.352(15) . ?
F5 C11 1.290(11) . ?
C1 H1 0.9300 . ?
C1 C4 1.346(18) . ?
C1 C45 1.42(2) . ?
F6 C11 1.318(11) . ?
F7 C26 1.335(13) . ?
F8 C46 1.347(19) . ?
C2 H2 0.9300 . ?
C2 C5 1.387(12) . ?
C2 C13 1.381(13) . ?
C3 C4 1.469(12) . ?
C3 C8 1.414(12) . ?
F9 C46 1.278(16) . ?
C4 S22A 1.715(14) . ?
C4 C1A 1.35(3) . ?
C5 C7 1.412(13) . ?
C6 C8 1.380(12) . ?
C6 C11 1.539(12) . ?
C7 H7 0.9300 . ?
C7 C24 1.395(14) . ?
F10 C51 1.327(15) . ?
C8 H8 0.9300 . ?
C9 C10 1.472(11) . ?
C9 C35 1.412(12) . ?
F11 C51 1.339(15) . ?
C10 C16 1.429(13) . ?
F12 C51 1.335(14) . ?
C12 H12 0.9300 . ?
C12 C20 1.34(3) . ?
C12 C49 1.44(2) . ?
C13 H13 0.9300 . ?
C13 C21 1.381(14) . ?
C14 C34 1.380(15) . ?
C14 C51 1.48(2) . ?
C14 C37A 1.60(3) . ?
C15 C26 1.537(12) . ?
C15 C35 1.395(12) . ?
C16 H16 0.9300 . ?
C16 C27 1.426(13) . ?
C17 C30 1.415(13) . ?
C17 C42 1.400(13) . ?
C18 C20 1.450(15) . ?
C18 C23 1.411(15) . ?
C18 C20A 1.43(2) . ?
C19 H19 0.9300 . ?
C19 C38 1.378(16) . ?
C19 C39 1.383(16) . ?
C21 H21 0.9300 . ?
C21 C24 1.397(13) . ?
C22 C41 1.411(13) . ?
C22 C43 1.376(15) . ?
C23 H23 0.9300 . ?
C23 C29 1.381(16) . ?
C24 H24 0.9300 . ?
C25 C28 1.379(13) . ?
C25 C36 1.384(14) . ?
C27 H27 0.9300 . ?
C27 C32 1.359(15) . ?
C28 H28 0.9300 . ?
C28 C31 1.377(15) . ?
C29 C46 1.625(18) . ?
C30 H30 0.9300 . ?
C30 C38 1.372(14) . ?
C31 H31 0.9300 . ?
C31 C33 1.385(16) . ?
C32 H32 0.9300 . ?
C33 H33 0.9300 . ?
C33 C52 1.392(18) . ?
C34 H34 0.9300 . ?
C34 C48 1.371(16) . ?
C35 H35 0.9300 . ?
C36 H36 0.9300 . ?
C36 C52 1.377(16) . ?
C37 C48 1.56(2) . ?
C37 C54 1.40(3) . ?
C38 H38 0.9300 . ?
C39 H39 0.9300 . ?
C39 C42 1.380(14) . ?
C40 H40 0.9300 . ?
C40 C45 1.352(17) . ?
C41 H41 0.9300 . ?
C41 C44 1.358(17) . ?
C42 H42 0.9300 . ?
C43 H43 0.9300 . ?
C43 C50 1.352(15) . ?
C44 H44 0.9300 . ?
C44 C47 1.37(2) . ?
C45 H45 0.9300 . ?
C47 H47 0.9300 . ?
C47 C50 1.39(2) . ?
C48 C51A 1.48(3) . ?
C49 H49 0.9300 . ?
C49 C53 1.30(2) . ?
C50 H50 0.9300 . ?
C52 H52 0.9300 . ?
C53 H53 0.9300 . ?
C54 H54 0.9300 . ?
C54 C56 1.39(2) . ?
C55 H55 0.9300 . ?
C55 C56 1.37(3) . ?
C56 H56 0.9300 . ?
C20A S23A 1.78(4) . ?
C20A C12A 1.32(3) . ?
S23A C53A 1.65(2) . ?
C53A H53A 0.9300 . ?
C53A C49A 1.30(3) . ?
C49A H49A 0.9300 . ?
C49A C12A 1.45(3) . ?
C12A H12A 0.9300 . ?
C51A F12A 1.33(2) . ?
C51A F11A 1.33(2) . ?
C51A F10A 1.33(2) . ?
C37A S24A 1.74(3) . ?
C37A C54A 1.41(3) . ?
S24A C55A 1.73(2) . ?
C55A H55A 0.9300 . ?
C55A C56A 1.38(3) . ?
C56A H56A 0.9300 . ?
C56A C54A 1.39(3) . ?
C54A H54A 0.9300 . ?
S22A C40A 1.72(2) . ?
C1A H1A 0.9300 . ?
C1A C45A 1.43(3) . ?
C40A H40A 0.9300 . ?
C40A C45A 1.36(2) . ?
C45A H45A 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O13 Eu1 O14 71.54(19) . . ?
O13 Eu1 O15 75.5(2) . . ?
O13 Eu1 O17 71.70(19) . . ?
O13 Eu1 O18 89.55(19) . . ?
O13 Eu1 O19 137.4(2) . . ?
O13 Eu1 O20 149.1(2) . . ?
O15 Eu1 O14 135.14(19) . . ?
O16 Eu1 O13 106.1(2) . . ?
O16 Eu1 O14 72.53(19) . . ?
O16 Eu1 O15 147.3(2) . . ?
O16 Eu1 O17 72.98(19) . . ?
O16 Eu1 O18 134.64(19) . . ?
O16 Eu1 O19 89.9(2) . . ?
O16 Eu1 O20 72.3(2) . . ?
O17 Eu1 O14 118.8(2) . . ?
O17 Eu1 O15 76.9(2) . . ?
O17 Eu1 O18 151.22(19) . . ?
O17 Eu1 O19 76.1(2) . . ?
O17 Eu1 O20 132.99(19) . . ?
O18 Eu1 O14 72.80(19) . . ?
O18 Eu1 O15 77.4(2) . . ?
O18 Eu1 O19 107.0(2) . . ?
O19 Eu1 O14 150.5(2) . . ?
O19 Eu1 O15 70.6(2) . . ?
O20 Eu1 O14 78.8(2) . . ?
O20 Eu1 O15 123.0(2) . . ?
O20 Eu1 O18 73.0(2) . . ?
O20 Eu1 O19 73.2(2) . . ?
C5 P1 C25 109.3(4) . . ?
C17 P1 C5 111.2(4) . . ?
C17 P1 C22 110.2(4) . . ?
C17 P1 C25 107.4(4) . . ?
C22 P1 C5 106.1(4) . . ?
C22 P1 C25 112.6(4) . . ?
C32 S21 C10 91.9(5) . . ?
C40 S22 C4 90.9(6) . . ?
C53 S23 C20 92.8(9) . . ?
C9 O13 Eu1 133.9(5) . . ?
C3 O14 Eu1 134.0(5) . . ?
C14 O15 Eu1 132.7(6) . . ?
C18 O16 Eu1 137.1(6) . . ?
C15 O17 Eu1 131.1(5) . . ?
C6 O18 Eu1 129.5(5) . . ?
C37 S24 C55 90.7(12) . . ?
C48 O19 Eu1 132.0(6) . . ?
C29 O20 Eu1 131.8(7) . . ?
C4 C1 H1 122.1 . . ?
C4 C1 C45 115.8(14) . . ?
C45 C1 H1 122.1 . . ?
C5 C2 H2 119.8 . . ?
C13 C2 H2 119.8 . . ?
C13 C2 C5 120.4(9) . . ?
O14 C3 C4 115.4(7) . . ?
O14 C3 C8 125.7(8) . . ?
C8 C3 C4 118.9(7) . . ?
C1 C4 S22 110.0(9) . . ?
C1 C4 C3 131.8(10) . . ?
C3 C4 S22 118.1(6) . . ?
C3 C4 S22A 123.9(9) . . ?
C1A C4 C3 123(3) . . ?
C1A C4 S22A 113(3) . . ?
C2 C5 P1 123.0(7) . . ?
C2 C5 C7 119.3(9) . . ?
C7 C5 P1 117.6(7) . . ?
O18 C6 C8 130.2(8) . . ?
O18 C6 C11 112.5(7) . . ?
C8 C6 C11 117.4(7) . . ?
C5 C7 H7 120.1 . . ?
C24 C7 C5 119.8(8) . . ?
C24 C7 H7 120.1 . . ?
C3 C8 H8 119.0 . . ?
C6 C8 C3 122.1(7) . . ?
C6 C8 H8 119.0 . . ?
O13 C9 C10 116.8(7) . . ?
O13 C9 C35 124.5(7) . . ?
C35 C9 C10 118.5(7) . . ?
C9 C10 S21 116.8(6) . . ?
C16 C10 S21 112.0(6) . . ?
C16 C10 C9 131.1(8) . . ?
F1 C11 C6 114.3(7) . . ?
F5 C11 F1 105.4(7) . . ?
F5 C11 F6 108.3(10) . . ?
F5 C11 C6 111.8(7) . . ?
F6 C11 F1 105.1(8) . . ?
F6 C11 C6 111.5(7) . . ?
C20 C12 H12 121.7 . . ?
C20 C12 C49 117(2) . . ?
C49 C12 H12 121.7 . . ?
C2 C13 H13 119.6 . . ?
C2 C13 C21 120.9(8) . . ?
C21 C13 H13 119.6 . . ?
O15 C14 C34 127.1(10) . . ?
O15 C14 C51 116.2(9) . . ?
O15 C14 C37A 111.8(13) . . ?
C34 C14 C51 116.0(9) . . ?
C34 C14 C37A 120.8(14) . . ?
O17 C15 C26 113.4(7) . . ?
O17 C15 C35 129.5(8) . . ?
C35 C15 C26 117.1(8) . . ?
C10 C16 H16 125.6 . . ?
C27 C16 C10 108.9(9) . . ?
C27 C16 H16 125.6 . . ?
C30 C17 P1 121.5(7) . . ?
C42 C17 P1 119.4(7) . . ?
C42 C17 C30 119.0(8) . . ?
O16 C18 C20 116.2(14) . . ?
O16 C18 C23 122.2(9) . . ?
O16 C18 C20A 117(2) . . ?
C23 C18 C20 121.5(14) . . ?
C23 C18 C20A 121(2) . . ?
C38 C19 H19 120.4 . . ?
C38 C19 C39 119.1(9) . . ?
C39 C19 H19 120.4 . . ?
C12 C20 S23 105.0(13) . . ?
C12 C20 C18 134(2) . . ?
C18 C20 S23 120.6(16) . . ?
C13 C21 H21 120.1 . . ?
C13 C21 C24 119.8(9) . . ?
C24 C21 H21 120.1 . . ?
C41 C22 P1 122.3(8) . . ?
C43 C22 P1 119.1(7) . . ?
C43 C22 C41 118.6(9) . . ?
C18 C23 H23 118.7 . . ?
C29 C23 C18 122.6(9) . . ?
C29 C23 H23 118.7 . . ?
C7 C24 C21 119.8(9) . . ?
C7 C24 H24 120.1 . . ?
C21 C24 H24 120.1 . . ?
C28 C25 P1 120.1(7) . . ?
C28 C25 C36 120.8(9) . . ?
C36 C25 P1 118.9(8) . . ?
F2 C26 F3 106.3(8) . . ?
F2 C26 F7 106.0(8) . . ?
F2 C26 C15 111.7(9) . . ?
F3 C26 C15 113.8(8) . . ?
F7 C26 F3 109.1(9) . . ?
F7 C26 C15 109.5(8) . . ?
C16 C27 H27 122.5 . . ?
C32 C27 C16 115.0(9) . . ?
C32 C27 H27 122.5 . . ?
C25 C28 H28 120.5 . . ?
C31 C28 C25 119.0(9) . . ?
C31 C28 H28 120.5 . . ?
O20 C29 C23 131.2(9) . . ?
O20 C29 C46 109.0(10) . . ?
C23 C29 C46 119.7(9) . . ?
C17 C30 H30 120.2 . . ?
C38 C30 C17 119.6(9) . . ?
C38 C30 H30 120.2 . . ?
C28 C31 H31 119.3 . . ?
C28 C31 C33 121.4(10) . . ?
C33 C31 H31 119.3 . . ?
S21 C32 H32 123.9 . . ?
C27 C32 S21 112.3(7) . . ?
C27 C32 H32 123.9 . . ?
C31 C33 H33 120.7 . . ?
C31 C33 C52 118.6(10) . . ?
C52 C33 H33 120.7 . . ?
C14 C34 H34 119.3 . . ?
C48 C34 C14 121.5(10) . . ?
C48 C34 H34 119.3 . . ?
C9 C35 H35 119.5 . . ?
C15 C35 C9 121.1(8) . . ?
C15 C35 H35 119.5 . . ?
C25 C36 H36 120.3 . . ?
C52 C36 C25 119.5(11) . . ?
C52 C36 H36 120.3 . . ?
C48 C37 S24 121.9(15) . . ?
C54 C37 S24 112.2(14) . . ?
C54 C37 C48 126(2) . . ?
C19 C38 H38 119.3 . . ?
C30 C38 C19 121.4(10) . . ?
C30 C38 H38 119.3 . . ?
C19 C39 H39 119.3 . . ?
C42 C39 C19 121.3(10) . . ?
C42 C39 H39 119.3 . . ?
S22 C40 H40 123.2 . . ?
C45 C40 S22 113.7(12) . . ?
C45 C40 H40 123.2 . . ?
C22 C41 H41 120.2 . . ?
C44 C41 C22 119.6(12) . . ?
C44 C41 H41 120.2 . . ?
C17 C42 H42 120.3 . . ?
C39 C42 C17 119.5(10) . . ?
C39 C42 H42 120.3 . . ?
C22 C43 H43 119.1 . . ?
C50 C43 C22 121.8(11) . . ?
C50 C43 H43 119.1 . . ?
C41 C44 H44 119.8 . . ?
C41 C44 C47 120.3(11) . . ?
C47 C44 H44 119.8 . . ?
C1 C45 H45 125.3 . . ?
C40 C45 C1 109.5(14) . . ?
C40 C45 H45 125.3 . . ?
F4 C46 C29 106.7(11) . . ?
F8 C46 F4 109.2(14) . . ?
F8 C46 C29 108.3(9) . . ?
F9 C46 F4 108.8(11) . . ?
F9 C46 F8 111.5(14) . . ?
F9 C46 C29 112.1(13) . . ?
C44 C47 H47 119.6 . . ?
C44 C47 C50 120.7(11) . . ?
C50 C47 H47 119.6 . . ?
O19 C48 C34 128.4(9) . . ?
O19 C48 C37 109.9(13) . . ?
O19 C48 C51A 115.7(10) . . ?
C34 C48 C37 121.6(13) . . ?
C34 C48 C51A 115.9(10) . . ?
C12 C49 H49 124.5 . . ?
C53 C49 C12 111.0(17) . . ?
C53 C49 H49 124.5 . . ?
C43 C50 C47 118.9(13) . . ?
C43 C50 H50 120.6 . . ?
C47 C50 H50 120.6 . . ?
F10 C51 F11 108.2(13) . . ?
F10 C51 F12 109.8(13) . . ?
F10 C51 C14 110.3(12) . . ?
F11 C51 C14 110.5(12) . . ?
F12 C51 F11 107.5(12) . . ?
F12 C51 C14 110.4(13) . . ?
C33 C52 H52 119.7 . . ?
C36 C52 C33 120.6(11) . . ?
C36 C52 H52 119.7 . . ?
S23 C53 H53 122.8 . . ?
C49 C53 S23 114.5(16) . . ?
C49 C53 H53 122.8 . . ?
C37 C54 H54 124.3 . . ?
C56 C54 C37 111.4(17) . . ?
C56 C54 H54 124.3 . . ?
S24 C55 H55 124.2 . . ?
C56 C55 S24 111.5(12) . . ?
C56 C55 H55 124.2 . . ?
C54 C56 H56 122.9 . . ?
C55 C56 C54 114.2(15) . . ?
C55 C56 H56 122.9 . . ?
C18 C20A S23A 116(3) . . ?
C12A C20A C18 132(3) . . ?
C12A C20A S23A 112(2) . . ?
C53A S23A C20A 88.1(17) . . ?
S23A C53A H53A 121.1 . . ?
C49A C53A S23A 118(3) . . ?
C49A C53A H53A 121.1 . . ?
C53A C49A H49A 124.6 . . ?
C53A C49A C12A 111(4) . . ?
C12A C49A H49A 124.6 . . ?
C20A C12A C49A 111(3) . . ?
C20A C12A H12A 124.5 . . ?
C49A C12A H12A 124.5 . . ?
F12A C51A C48 115.1(17) . . ?
F12A C51A F11A 104.2(17) . . ?
F12A C51A F10A 106.7(18) . . ?
F11A C51A C48 113.3(17) . . ?
F10A C51A C48 110.9(16) . . ?
F10A C51A F11A 106.0(18) . . ?
C14 C37A S24A 118.1(17) . . ?
C54A C37A C14 131(2) . . ?
C54A C37A S24A 110.2(17) . . ?
C55A S24A C37A 92.3(13) . . ?
S24A C55A H55A 124.7 . . ?
C56A C55A S24A 110.5(15) . . ?
C56A C55A H55A 124.7 . . ?
C55A C56A H56A 122.8 . . ?
C55A C56A C54A 114.3(18) . . ?
C54A C56A H56A 122.8 . . ?
C37A C54A H54A 123.9 . . ?
C56A C54A C37A 112.3(17) . . ?
C56A C54A H54A 123.9 . . ?
C4 S22A C40A 87(2) . . ?
C4 C1A H1A 124.0 . . ?
C4 C1A C45A 112(5) . . ?
C45A C1A H1A 124.0 . . ?
S22A C40A H40A 121.9 . . ?
C45A C40A S22A 116(5) . . ?
C45A C40A H40A 121.9 . . ?
C1A C45A H45A 126.1 . . ?
C40A C45A C1A 108(6) . . ?
C40A C45A H45A 126.1 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Eu1 O13 C9 C10 159.1(6) . . . . ?
Eu1 O13 C9 C35 -25.6(13) . . . . ?
Eu1 O14 C3 C4 173.0(5) . . . . ?
Eu1 O14 C3 C8 -6.8(12) . . . . ?
Eu1 O15 C14 C34 25.4(16) . . . . ?
Eu1 O15 C14 C51 -164.3(7) . . . . ?
Eu1 O15 C14 C37A -148.4(16) . . . . ?
Eu1 O16 C18 C20 -164.0(10) . . . . ?
Eu1 O16 C18 C23 18.6(13) . . . . ?
Eu1 O16 C18 C20A -159.1(15) . . . . ?
Eu1 O17 C15 C26 -168.2(7) . . . . ?
Eu1 O17 C15 C35 14.9(16) . . . . ?
Eu1 O18 C6 C8 24.1(12) . . . . ?
Eu1 O18 C6 C11 -156.8(5) . . . . ?
Eu1 O19 C48 C34 -18.1(15) . . . . ?
Eu1 O19 C48 C37 166.5(9) . . . . ?
Eu1 O19 C48 C51A 164.4(8) . . . . ?
Eu1 O20 C29 C23 -6.8(15) . . . . ?
Eu1 O20 C29 C46 170.0(7) . . . . ?
P1 C5 C7 C24 179.8(8) . . . . ?
P1 C17 C30 C38 -178.9(7) . . . . ?
P1 C17 C42 C39 -179.9(8) . . . . ?
P1 C22 C41 C44 180.0(10) . . . . ?
P1 C22 C43 C50 179.3(11) . . . . ?
P1 C25 C28 C31 -177.1(8) . . . . ?
P1 C25 C36 C52 178.6(11) . . . . ?
S21 C10 C16 C27 0.7(10) . . . . ?
S22 C40 C45 C1 0.6(19) . . . . ?
O13 C9 C10 S21 10.1(11) . . . . ?
O13 C9 C10 C16 -165.8(9) . . . . ?
O13 C9 C35 C15 -1.4(15) . . . . ?
O14 C3 C4 S22 -5.2(10) . . . . ?
O14 C3 C4 C1 172.5(14) . . . . ?
O14 C3 C4 S22A 171.9(12) . . . . ?
O14 C3 C4 C1A -4(6) . . . . ?
O14 C3 C8 C6 -9.0(12) . . . . ?
O15 C14 C34 C48 -1.4(17) . . . . ?
O15 C14 C51 F10 45.4(14) . . . . ?
O15 C14 C51 F11 -74.2(12) . . . . ?
O15 C14 C51 F12 166.9(10) . . . . ?
O15 C14 C37A S24A -154.6(19) . . . . ?
O15 C14 C37A C54A 14(5) . . . . ?
O16 C18 C20 S23 -8.9(17) . . . . ?
O16 C18 C20 C12 175.9(19) . . . . ?
O16 C18 C23 C29 -2.8(15) . . . . ?
O16 C18 C20A S23A 169.4(13) . . . . ?
O16 C18 C20A C12A -8(3) . . . . ?
O17 C15 C26 F2 49.4(12) . . . . ?
O17 C15 C26 F3 169.9(9) . . . . ?
O17 C15 C26 F7 -67.8(12) . . . . ?
O17 C15 C35 C9 6.3(17) . . . . ?
O18 C6 C8 C3 -0.4(13) . . . . ?
O18 C6 C11 F1 -175.0(7) . . . . ?
O18 C6 C11 F5 -55.3(10) . . . . ?
O18 C6 C11 F6 66.0(10) . . . . ?
S24 C37 C48 O19 14.1(18) . . . . ?
S24 C37 C48 C34 -161.6(12) . . . . ?
S24 C37 C54 C56 1(2) . . . . ?
S24 C55 C56 C54 2(3) . . . . ?
O19 C48 C51A F12A 173.8(12) . . . . ?
O19 C48 C51A F11A -66.4(16) . . . . ?
O19 C48 C51A F10A 52.6(16) . . . . ?
O20 C29 C46 F4 61.1(13) . . . . ?
O20 C29 C46 F8 -56.4(12) . . . . ?
O20 C29 C46 F9 -179.9(11) . . . . ?
C2 C5 C7 C24 1.4(15) . . . . ?
C2 C13 C21 C24 0.7(15) . . . . ?
C3 C4 S22A C40A 167(3) . . . . ?
C3 C4 C1A C45A -162(6) . . . . ?
C4 S22 C40 C45 1.4(13) . . . . ?
C4 C1 C45 C40 -3(2) . . . . ?
C4 C3 C8 C6 171.3(7) . . . . ?
C4 S22A C40A C45A 8(6) . . . . ?
C4 C1A C45A C40A -15(12) . . . . ?
C5 P1 C17 C30 -107.1(8) . . . . ?
C5 P1 C17 C42 74.2(8) . . . . ?
C5 P1 C22 C41 -130.6(9) . . . . ?
C5 P1 C22 C43 47.3(10) . . . . ?
C5 P1 C25 C28 1.2(9) . . . . ?
C5 P1 C25 C36 -173.2(9) . . . . ?
C5 C2 C13 C21 -1.0(15) . . . . ?
C5 C7 C24 C21 -1.7(16) . . . . ?
C8 C3 C4 S22 174.6(6) . . . . ?
C8 C3 C4 C1 -7.7(18) . . . . ?
C8 C3 C4 S22A -8.3(15) . . . . ?
C8 C3 C4 C1A 176(6) . . . . ?
C8 C6 C11 F1 4.3(11) . . . . ?
C8 C6 C11 F5 123.9(9) . . . . ?
C8 C6 C11 F6 -114.7(10) . . . . ?
C9 C10 C16 C27 176.8(9) . . . . ?
C10 S21 C32 C27 0.6(8) . . . . ?
C10 C9 C35 C15 173.8(9) . . . . ?
C10 C16 C27 C32 -0.3(12) . . . . ?
C11 C6 C8 C3 -179.5(7) . . . . ?
C12 C49 C53 S23 1(2) . . . . ?
C13 C2 C5 P1 -178.4(7) . . . . ?
C13 C2 C5 C7 -0.1(14) . . . . ?
C13 C21 C24 C7 0.7(16) . . . . ?
C14 C34 C48 O19 -2.2(17) . . . . ?
C14 C34 C48 C37 172.7(12) . . . . ?
C14 C34 C48 C51A 175.3(11) . . . . ?
C14 C37A S24A C55A 173(3) . . . . ?
C14 C37A C54A C56A -174(3) . . . . ?
C16 C27 C32 S21 -0.3(12) . . . . ?
C17 P1 C5 C2 -26.4(9) . . . . ?
C17 P1 C5 C7 155.2(8) . . . . ?
C17 P1 C22 C41 108.9(9) . . . . ?
C17 P1 C22 C43 -73.2(10) . . . . ?
C17 P1 C25 C28 122.0(8) . . . . ?
C17 P1 C25 C36 -52.4(10) . . . . ?
C17 C30 C38 C19 -2.4(15) . . . . ?
C18 C23 C29 O20 -2.4(18) . . . . ?
C18 C23 C29 C46 -178.9(10) . . . . ?
C18 C20A S23A C53A -180(2) . . . . ?
C18 C20A C12A C49A 179(3) . . . . ?
C19 C39 C42 C17 -0.1(15) . . . . ?
C20 S23 C53 C49 1.5(16) . . . . ?
C20 C12 C49 C53 -4(2) . . . . ?
C20 C18 C23 C29 179.8(12) . . . . ?
C22 P1 C5 C2 -146.3(8) . . . . ?
C22 P1 C5 C7 35.4(9) . . . . ?
C22 P1 C17 C30 10.3(9) . . . . ?
C22 P1 C17 C42 -168.4(7) . . . . ?
C22 P1 C25 C28 -116.5(8) . . . . ?
C22 P1 C25 C36 69.0(10) . . . . ?
C22 C41 C44 C47 -1(2) . . . . ?
C22 C43 C50 C47 2(2) . . . . ?
C23 C18 C20 S23 168.6(9) . . . . ?
C23 C18 C20 C12 -7(3) . . . . ?
C23 C18 C20A S23A -8(3) . . . . ?
C23 C18 C20A C12A 174(2) . . . . ?
C23 C29 C46 F4 -121.7(11) . . . . ?
C23 C29 C46 F8 120.9(12) . . . . ?
C23 C29 C46 F9 -2.6(17) . . . . ?
C25 P1 C5 C2 92.0(9) . . . . ?
C25 P1 C5 C7 -86.3(8) . . . . ?
C25 P1 C17 C30 133.2(8) . . . . ?
C25 P1 C17 C42 -45.4(9) . . . . ?
C25 P1 C22 C41 -11.0(10) . . . . ?
C25 P1 C22 C43 166.9(9) . . . . ?
C25 C28 C31 C33 1.2(16) . . . . ?
C25 C36 C52 C33 -4(2) . . . . ?
C26 C15 C35 C9 -170.5(9) . . . . ?
C28 C25 C36 C52 4.2(18) . . . . ?
C28 C31 C33 C52 -1.1(17) . . . . ?
C30 C17 C42 C39 1.5(14) . . . . ?
C31 C33 C52 C36 3(2) . . . . ?
C32 S21 C10 C9 -177.4(7) . . . . ?
C32 S21 C10 C16 -0.8(7) . . . . ?
C34 C14 C51 F10 -143.3(11) . . . . ?
C34 C14 C51 F11 97.1(12) . . . . ?
C34 C14 C51 F12 -21.7(14) . . . . ?
C34 C14 C37A S24A 31(3) . . . . ?
C34 C14 C37A C54A -160(4) . . . . ?
C34 C48 C51A F12A -4.0(17) . . . . ?
C34 C48 C51A F11A 115.8(14) . . . . ?
C34 C48 C51A F10A -125.2(14) . . . . ?
C35 C9 C10 S21 -165.5(7) . . . . ?
C35 C9 C10 C16 18.6(14) . . . . ?
C35 C15 C26 F2 -133.3(9) . . . . ?
C35 C15 C26 F3 -12.8(15) . . . . ?
C35 C15 C26 F7 109.5(10) . . . . ?
C36 C25 C28 C31 -2.7(15) . . . . ?
C37 S24 C55 C56 -1.1(18) . . . . ?
C37 C54 C56 C55 -2(3) . . . . ?
C38 C19 C39 C42 -2.5(16) . . . . ?
C39 C19 C38 C30 3.7(16) . . . . ?
C40 S22 C4 C1 -3.1(12) . . . . ?
C40 S22 C4 C3 175.0(8) . . . . ?
C41 C22 C43 C50 -2.8(19) . . . . ?
C41 C44 C47 C50 0(2) . . . . ?
C42 C17 C30 C38 -0.2(14) . . . . ?
C43 C22 C41 C44 2.1(18) . . . . ?
C44 C47 C50 C43 -1(2) . . . . ?
C45 C1 C4 S22 4(2) . . . . ?
C45 C1 C4 C3 -173.7(12) . . . . ?
C48 C37 C54 C56 177.7(17) . . . . ?
C49 C12 C20 S23 4(2) . . . . ?
C49 C12 C20 C18 -180.0(18) . . . . ?
C51 C14 C34 C48 -171.7(10) . . . . ?
C53 S23 C20 C12 -3.2(14) . . . . ?
C53 S23 C20 C18 -179.7(14) . . . . ?
C54 C37 C48 O19 -161.8(18) . . . . ?
C54 C37 C48 C34 22(3) . . . . ?
C55 S24 C37 C48 -176.6(16) . . . . ?
C55 S24 C37 C54 -0.1(17) . . . . ?
C20A C18 C23 C29 174.8(16) . . . . ?
C20A S23A C53A C49A 2(3) . . . . ?
S23A C20A C12A C49A 1.5(17) . . . . ?
S23A C53A C49A C12A -2(3) . . . . ?
C53A C49A C12A C20A 0(2) . . . . ?
C12A C20A S23A C53A -2(2) . . . . ?
C37A C14 C34 C48 171.9(18) . . . . ?
C37A S24A C55A C56A 2(3) . . . . ?
S24A C37A C54A C56A -5(5) . . . . ?
S24A C55A C56A C54A -5(5) . . . . ?
C55A C56A C54A C37A 7(6) . . . . ?
C54A C37A S24A C55A 2(3) . . . . ?
S22A C4 C1A C45A 22(10) . . . . ?
S22A C40A C45A C1A 2(10) . . . . ?
C1A C4 S22A C40A -17(6) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 6.075
_oxdiff_exptl_absorpt_empirical_full_min 0.224
