# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2023

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_gar10289
_database_code_depnum_ccdc_archive 'CCDC 2164595'
loop_
_audit_author_name
_audit_author_address
'Constantin G. Daniliuc'
;Organisch Chemisches Institut WWU University of Muenster
Germany
;
_audit_update_record             
;
2022-04-05 deposited with the CCDC.	2023-04-19 downloaded from the CCDC.
;

_audit_creation_method           'APEX4 v2021.4-0'
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C24 H33 N O8 S Si'
_chemical_formula_iupac          ?
_chemical_formula_weight         523.66

_chemical_melting_point          ?

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   8.3042(4)
_cell_length_b                   11.0182(5)
_cell_length_c                   14.6172(7)
_cell_angle_alpha                105.403(3)
_cell_angle_beta                 96.905(3)
_cell_angle_gamma                95.290(3)
_cell_volume                     1269.23(11)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    5299
_cell_measurement_theta_min      3.1722
_cell_measurement_theta_max      66.5562
_cell_measurement_temperature    100.(2)

_exptl_crystal_description       plate
_exptl_crystal_colour            'pale yellow'
_exptl_crystal_size_max          0.113
_exptl_crystal_size_mid          0.079
_exptl_crystal_size_min          0.043
_exptl_crystal_density_diffrn    1.370
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             556

_exptl_absorpt_coefficient_mu    2.005
_exptl_absorpt_correction_type   Multi-Scan
_exptl_absorpt_process_details   
;
Krause, L., Herbst-Irmer, R., Sheldrick, G. M., Stalke, D. (2015).
"Comparison of silver and molybdenum microfocus X-ray sources for
single-crystal structure determination"
J. Appl. Cryst. 48, 3-10. doi:10.1107/S1600576714022985
;
_exptl_absorpt_correction_T_min  0.71
_exptl_absorpt_correction_T_max  0.92

_exptl_special_details           
;
;

_diffrn_ambient_temperature      100.(2)

_diffrn_source                   'Cu ImS'
_diffrn_source_type              'micro focus tube'
_diffrn_source_power             0.05
_diffrn_source_current           1.0
_diffrn_source_voltage           50

_diffrn_radiation_probe          'single crystal'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_radiation_monochromator  'MX mirror'

_diffrn_measurement_device       'Bruker D8 Venture Photon III'
_diffrn_measurement_device_type  'single crystal diffractometer'
_diffrn_measurement_method       'phi/omega scans'

_diffrn_detector_area_resol_mean 7.3910

_diffrn_reflns_number            23665
_diffrn_reflns_av_R_equivalents  0.1479
_diffrn_reflns_av_unetI/netI     0.0930
_diffrn_reflns_theta_min         3.17
_diffrn_reflns_theta_max         66.83
_diffrn_reflns_theta_full        66.83
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measured_fraction_theta_full 0.996
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_limit_l_max       17

_refine_special_details          
;

Reflections were merged by SHELXL according to the crystal
class for the calculation of statistics and refinement.

_reflns_Friedel_fraction is defined as the number of unique
Friedel pairs measured divided by the number that would be
possible theoretically, ignoring centric projections and
systematic absences.
;

_reflns_number_total             4482
_reflns_number_gt                3025
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_R_factor_all          0.1022
_refine_ls_R_factor_gt           0.0627
_refine_ls_wR_factor_gt          0.1467
_refine_ls_wR_factor_ref         0.1710
_refine_ls_goodness_of_fit_ref   1.031
_refine_ls_restrained_S_all      1.031
_refine_ls_number_reflns         4482
_refine_ls_number_parameters     325
_refine_ls_number_restraints     0
_refine_ls_number_constraints    ?
_refine_ls_hydrogen_treatment    constr
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0712P)²+1.5075P] where P=(Fo²+2Fc²)/3'

_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?

_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_diff_density_max         0.364
_refine_diff_density_min         -0.603
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_extinction_coef       0.0026(5)

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.3331 0.5567 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.2541 0.3302 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_computing_data_collection       'Bruker APEX4 v2021.4-0 Photon III'
_computing_cell_refinement       'SAINT V8.40B (Bruker AXS LLC, 2019)'
_computing_data_reduction        'SAINT V8.40B (Bruker AXS LLC, 2019)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    'shelXle (C.B. Huebschle, rev 1242)'
_computing_publication_material  'SHELXT 2018/2 (Sheldrick, 2018)'

loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_refinement_flags_posn
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
S S1 0.32634(11) 0.62038(9) 0.37865(7) 0.0235(3) Uani d . . . 1 . .
Si Si1 0.84330(13) 0.26058(10) 0.12972(8) 0.0249(3) Uani d . . . 1 . .
N N1 0.6248(4) 0.5751(3) 0.4339(2) 0.0229(7) Uani d . . . 1 . .
O O1 0.6925(3) 0.3353(2) 0.17328(19) 0.0237(6) Uani d . . . 1 . .
O O2 0.5574(3) 0.2573(2) 0.2801(2) 0.0251(6) Uani d . . . 1 . .
O O3 0.3009(3) 0.6739(3) 0.2991(2) 0.0284(7) Uani d . . . 1 . .
O O4 0.1855(3) 0.5606(3) 0.4062(2) 0.0269(7) Uani d . . . 1 . .
O O5 0.2399(4) 0.8528(3) 0.5149(2) 0.0328(7) Uani d . . . 1 . .
O O6 0.4959(3) 0.9249(2) 0.5964(2) 0.0273(6) Uani d . . . 1 . .
O O7 0.7955(4) 0.7435(3) 0.6310(2) 0.0290(7) Uani d . . . 1 . .
O O8 0.8018(3) 0.8700(2) 0.5324(2) 0.0264(6) Uani d . . . 1 . .
C C1 0.7823(5) 0.5578(4) 0.3938(3) 0.0239(9) Uani d . . . 1 . .
H H1 0.879265 0.593982 0.444710 0.029000 Uiso calc U . R 1 . .
C C2 0.4805(5) 0.5103(4) 0.3623(3) 0.0226(8) Uani d . . . 1 . .
H H2 0.438246 0.431427 0.377910 0.027000 Uiso calc U . R 1 . .
C C3 0.5315(5) 0.4729(4) 0.2625(3) 0.0221(8) Uani d . . . 1 . .
H H3 0.434365 0.443108 0.210964 0.026000 Uiso calc U . R 1 . .
C C4 0.6408(5) 0.5809(4) 0.2467(3) 0.0228(8) Uani d . . . 1 . .
C C5 0.6196(5) 0.6312(4) 0.1697(3) 0.0262(9) Uani d . . . 1 . .
H H5 0.523970 0.603716 0.123031 0.031000 Uiso calc U . R 1 . .
C C6 0.7403(5) 0.7231(4) 0.1611(3) 0.0298(9) Uani d . . . 1 . .
H H6 0.727824 0.757155 0.107787 0.036000 Uiso calc U . R 1 . .
C C7 0.8774(5) 0.7642(4) 0.2298(3) 0.0281(9) Uani d . . . 1 . .
H H7 0.958686 0.826686 0.223382 0.034000 Uiso calc U . R 1 . .
C C8 0.8983(5) 0.7157(4) 0.3081(3) 0.0238(9) Uani d . . . 1 . .
H H8 0.992849 0.744496 0.355437 0.029000 Uiso calc U . R 1 . .
C C9 0.7782(5) 0.6240(4) 0.3161(3) 0.0237(9) Uani d . . . 1 . .
C C10 0.7808(5) 0.4157(4) 0.3501(3) 0.0240(9) Uani d . . . 1 . .
H H10A 0.764536 0.370529 0.399193 0.029000 Uiso calc U . R 1 . .
H H10B 0.887300 0.399189 0.328585 0.029000 Uiso calc U . R 1 . .
C C11 0.6416(5) 0.3654(4) 0.2638(3) 0.0246(9) Uani d . . . 1 . .
C C12 0.8550(6) 0.1148(4) 0.1704(3) 0.0335(10) Uani d . . . 1 . .
H H12A 0.864320 0.137265 0.240513 0.050000 Uiso calc U . R 1 . .
H H12B 0.951029 0.075570 0.150320 0.050000 Uiso calc U . R 1 . .
H H12C 0.755916 0.054669 0.141755 0.050000 Uiso calc U . R 1 . .
C C13 1.0427(5) 0.3654(5) 0.1669(4) 0.0365(11) Uani d . . . 1 . .
H H13A 1.025194 0.452485 0.167815 0.055000 Uiso calc U . R 1 . .
H H13B 1.117340 0.335124 0.121252 0.055000 Uiso calc U . R 1 . .
H H13C 1.090387 0.363875 0.231169 0.055000 Uiso calc U . R 1 . .
C C14 0.7820(5) 0.2235(4) -0.0045(3) 0.0252(9) Uani d . . . 1 . .
C C15 0.5998(5) 0.1707(4) -0.0337(3) 0.0317(10) Uani d . . . 1 . .
H H15A 0.571170 0.150289 -0.103623 0.048000 Uiso calc U . R 1 . .
H H15B 0.533600 0.234441 -0.002960 0.048000 Uiso calc U . R 1 . .
H H15C 0.578338 0.093693 -0.013294 0.048000 Uiso calc U . R 1 . .
C C16 0.8812(6) 0.1226(4) -0.0561(3) 0.0337(10) Uani d . . . 1 . .
H H16A 0.862445 0.045987 -0.034854 0.051000 Uiso calc U . R 1 . .
H H16B 0.997880 0.155674 -0.040759 0.051000 Uiso calc U . R 1 . .
H H16C 0.846747 0.101895 -0.125550 0.051000 Uiso calc U . R 1 . .
C C17 0.8138(6) 0.3446(4) -0.0367(3) 0.0320(10) Uani d . . . 1 . .
H H17A 0.776539 0.325536 -0.105782 0.048000 Uiso calc U . R 1 . .
H H17B 0.931177 0.375172 -0.022872 0.048000 Uiso calc U . R 1 . .
H H17C 0.753898 0.410213 -0.001871 0.048000 Uiso calc U . R 1 . .
C C18 0.4269(5) 0.1865(4) 0.2058(3) 0.0314(10) Uani d . . . 1 . .
H H18A 0.341884 0.240603 0.198287 0.047000 Uiso calc U . R 1 . .
H H18B 0.380061 0.112410 0.223437 0.047000 Uiso calc U . R 1 . .
H H18C 0.469991 0.158153 0.145216 0.047000 Uiso calc U . R 1 . .
C C19 0.6022(5) 0.6932(4) 0.4871(3) 0.0231(8) Uani d . . . 1 . .
C C20 0.4507(5) 0.7296(4) 0.4765(3) 0.0244(9) Uani d . . . 1 . .
C C21 0.3832(5) 0.8407(4) 0.5303(3) 0.0258(9) Uani d . . . 1 . .
C C22 0.4333(6) 1.0323(4) 0.6550(3) 0.0301(10) Uani d . . . 1 . .
H H22A 0.361917 1.068711 0.613878 0.045000 Uiso calc U . R 1 . .
H H22B 0.524664 1.096578 0.690852 0.045000 Uiso calc U . R 1 . .
H H22C 0.370698 1.004384 0.700172 0.045000 Uiso calc U . R 1 . .
C C23 0.7451(5) 0.7706(4) 0.5593(3) 0.0234(9) Uani d . . . 1 . .
C C24 0.9212(5) 0.9622(4) 0.6037(3) 0.0330(10) Uani d . . . 1 . .
H H24A 0.878028 0.985790 0.664654 0.049000 Uiso calc U . R 1 . .
H H24B 0.943548 1.037886 0.581832 0.049000 Uiso calc U . R 1 . .
H H24C 1.022689 0.925087 0.612880 0.049000 Uiso calc U . R 1 . .


_geom_special_details            
;

All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix.  The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry.  An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
S1 O3 . 1.440(3) ?
S1 O4 . 1.440(3) ?
S1 C20 . 1.749(4) ?
S1 C2 . 1.836(4) ?
Si1 O1 . 1.660(3) ?
Si1 C12 . 1.862(4) ?
Si1 C13 . 1.862(5) ?
Si1 C14 . 1.889(4) ?
N1 C19 . 1.370(5) ?
N1 C2 . 1.479(5) ?
N1 C1 . 1.504(5) ?
O1 C11 . 1.402(5) ?
O2 C11 . 1.415(5) ?
O2 C18 . 1.440(5) ?
O5 C21 . 1.211(5) ?
O6 C21 . 1.348(5) ?
O6 C22 . 1.445(5) ?
O7 C23 . 1.203(5) ?
O8 C23 . 1.324(5) ?
O8 C24 . 1.451(5) ?
C1 C9 . 1.503(6) ?
C1 C10 . 1.524(5) ?
C1 H1 . 1.000000 ?
C2 C3 . 1.529(6) ?
C2 H2 . 1.000000 ?
C3 C4 . 1.513(5) ?
C3 C11 . 1.564(5) ?
C3 H3 . 1.000000 ?
C4 C5 . 1.382(6) ?
C4 C9 . 1.387(6) ?
C5 C6 . 1.399(6) ?
C5 H5 . 0.950000 ?
C6 C7 . 1.377(6) ?
C6 H6 . 0.950000 ?
C7 C8 . 1.386(6) ?
C7 H7 . 0.950000 ?
C8 C9 . 1.390(5) ?
C8 H8 . 0.950000 ?
C10 C11 . 1.548(6) ?
C10 H10A . 0.990000 ?
C10 H10B . 0.990000 ?
C12 H12A . 0.980000 ?
C12 H12B . 0.980000 ?
C12 H12C . 0.980000 ?
C13 H13A . 0.980000 ?
C13 H13B . 0.980000 ?
C13 H13C . 0.980000 ?
C14 C16 . 1.535(6) ?
C14 C15 . 1.536(6) ?
C14 C17 . 1.540(6) ?
C15 H15A . 0.980000 ?
C15 H15B . 0.980000 ?
C15 H15C . 0.980000 ?
C16 H16A . 0.980000 ?
C16 H16B . 0.980000 ?
C16 H16C . 0.980000 ?
C17 H17A . 0.980000 ?
C17 H17B . 0.980000 ?
C17 H17C . 0.980000 ?
C18 H18A . 0.980000 ?
C18 H18B . 0.980000 ?
C18 H18C . 0.980000 ?
C19 C20 . 1.358(6) ?
C19 C23 . 1.511(5) ?
C20 C21 . 1.468(6) ?
C22 H22A . 0.980000 ?
C22 H22B . 0.980000 ?
C22 H22C . 0.980000 ?
C24 H24A . 0.980000 ?
C24 H24B . 0.980000 ?
C24 H24C . 0.980000 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
O3 S1 O4 . . 118.15(17) ?
O3 S1 C20 . . 110.35(18) ?
O4 S1 C20 . . 112.40(19) ?
O3 S1 C2 . . 111.37(18) ?
O4 S1 C2 . . 108.87(17) ?
C20 S1 C2 . . 92.83(18) ?
O1 Si1 C12 . . 109.56(18) ?
O1 Si1 C13 . . 111.40(19) ?
C12 Si1 C13 . . 110.5(2) ?
O1 Si1 C14 . . 103.18(17) ?
C12 Si1 C14 . . 112.5(2) ?
C13 Si1 C14 . . 109.6(2) ?
C19 N1 C2 . . 112.9(3) ?
C19 N1 C1 . . 119.2(3) ?
C2 N1 C1 . . 112.1(3) ?
C11 O1 Si1 . . 133.5(2) ?
C11 O2 C18 . . 116.4(3) ?
C21 O6 C22 . . 115.3(3) ?
C23 O8 C24 . . 115.1(3) ?
C9 C1 N1 . . 106.1(3) ?
C9 C1 C10 . . 109.8(3) ?
N1 C1 C10 . . 107.0(3) ?
C9 C1 H1 . . 111.300000 ?
N1 C1 H1 . . 111.300000 ?
C10 C1 H1 . . 111.300000 ?
N1 C2 C3 . . 109.3(3) ?
N1 C2 S1 . . 105.5(2) ?
C3 C2 S1 . . 116.0(3) ?
N1 C2 H2 . . 108.600000 ?
C3 C2 H2 . . 108.600000 ?
S1 C2 H2 . . 108.600000 ?
C4 C3 C2 . . 110.9(3) ?
C4 C3 C11 . . 105.7(3) ?
C2 C3 C11 . . 105.3(3) ?
C4 C3 H3 . . 111.500000 ?
C2 C3 H3 . . 111.500000 ?
C11 C3 H3 . . 111.500000 ?
C5 C4 C9 . . 120.1(4) ?
C5 C4 C3 . . 126.4(4) ?
C9 C4 C3 . . 113.4(3) ?
C4 C5 C6 . . 119.3(4) ?
C4 C5 H5 . . 120.400000 ?
C6 C5 H5 . . 120.400000 ?
C7 C6 C5 . . 120.1(4) ?
C7 C6 H6 . . 119.900000 ?
C5 C6 H6 . . 119.900000 ?
C6 C7 C8 . . 120.9(4) ?
C6 C7 H7 . . 119.500000 ?
C8 C7 H7 . . 119.500000 ?
C7 C8 C9 . . 118.7(4) ?
C7 C8 H8 . . 120.600000 ?
C9 C8 H8 . . 120.600000 ?
C4 C9 C8 . . 120.8(4) ?
C4 C9 C1 . . 112.9(3) ?
C8 C9 C1 . . 126.2(4) ?
C1 C10 C11 . . 110.1(3) ?
C1 C10 H10A . . 109.600000 ?
C11 C10 H10A . . 109.600000 ?
C1 C10 H10B . . 109.600000 ?
C11 C10 H10B . . 109.600000 ?
H10A C10 H10B . . 108.200000 ?
O1 C11 O2 . . 111.0(3) ?
O1 C11 C10 . . 115.3(3) ?
O2 C11 C10 . . 105.0(3) ?
O1 C11 C3 . . 104.7(3) ?
O2 C11 C3 . . 112.8(3) ?
C10 C11 C3 . . 108.2(3) ?
Si1 C12 H12A . . 109.500000 ?
Si1 C12 H12B . . 109.500000 ?
H12A C12 H12B . . 109.500000 ?
Si1 C12 H12C . . 109.500000 ?
H12A C12 H12C . . 109.500000 ?
H12B C12 H12C . . 109.500000 ?
Si1 C13 H13A . . 109.500000 ?
Si1 C13 H13B . . 109.500000 ?
H13A C13 H13B . . 109.500000 ?
Si1 C13 H13C . . 109.500000 ?
H13A C13 H13C . . 109.500000 ?
H13B C13 H13C . . 109.500000 ?
C16 C14 C15 . . 107.9(3) ?
C16 C14 C17 . . 109.4(3) ?
C15 C14 C17 . . 108.9(3) ?
C16 C14 Si1 . . 109.8(3) ?
C15 C14 Si1 . . 110.8(3) ?
C17 C14 Si1 . . 110.0(3) ?
C14 C15 H15A . . 109.500000 ?
C14 C15 H15B . . 109.500000 ?
H15A C15 H15B . . 109.500000 ?
C14 C15 H15C . . 109.500000 ?
H15A C15 H15C . . 109.500000 ?
H15B C15 H15C . . 109.500000 ?
C14 C16 H16A . . 109.500000 ?
C14 C16 H16B . . 109.500000 ?
H16A C16 H16B . . 109.500000 ?
C14 C16 H16C . . 109.500000 ?
H16A C16 H16C . . 109.500000 ?
H16B C16 H16C . . 109.500000 ?
C14 C17 H17A . . 109.500000 ?
C14 C17 H17B . . 109.500000 ?
H17A C17 H17B . . 109.500000 ?
C14 C17 H17C . . 109.500000 ?
H17A C17 H17C . . 109.500000 ?
H17B C17 H17C . . 109.500000 ?
O2 C18 H18A . . 109.500000 ?
O2 C18 H18B . . 109.500000 ?
H18A C18 H18B . . 109.500000 ?
O2 C18 H18C . . 109.500000 ?
H18A C18 H18C . . 109.500000 ?
H18B C18 H18C . . 109.500000 ?
C20 C19 N1 . . 118.2(4) ?
C20 C19 C23 . . 124.3(4) ?
N1 C19 C23 . . 117.4(3) ?
C19 C20 C21 . . 131.1(4) ?
C19 C20 S1 . . 109.8(3) ?
C21 C20 S1 . . 119.0(3) ?
O5 C21 O6 . . 124.9(4) ?
O5 C21 C20 . . 121.8(4) ?
O6 C21 C20 . . 113.3(3) ?
O6 C22 H22A . . 109.500000 ?
O6 C22 H22B . . 109.500000 ?
H22A C22 H22B . . 109.500000 ?
O6 C22 H22C . . 109.500000 ?
H22A C22 H22C . . 109.500000 ?
H22B C22 H22C . . 109.500000 ?
O7 C23 O8 . . 126.5(4) ?
O7 C23 C19 . . 123.0(3) ?
O8 C23 C19 . . 110.5(3) ?
O8 C24 H24A . . 109.500000 ?
O8 C24 H24B . . 109.500000 ?
H24A C24 H24B . . 109.500000 ?
O8 C24 H24C . . 109.500000 ?
H24A C24 H24C . . 109.500000 ?
H24B C24 H24C . . 109.500000 ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion
_geom_torsion_publ_flag
C12 Si1 O1 C11 . . . . 44.4(4) ?
C13 Si1 O1 C11 . . . . -78.1(4) ?
C14 Si1 O1 C11 . . . . 164.4(3) ?
C19 N1 C1 C9 . . . . -70.1(4) ?
C2 N1 C1 C9 . . . . 64.9(4) ?
C19 N1 C1 C10 . . . . 172.8(3) ?
C2 N1 C1 C10 . . . . -52.2(4) ?
C19 N1 C2 C3 . . . . 124.1(3) ?
C1 N1 C2 C3 . . . . -13.8(4) ?
C19 N1 C2 S1 . . . . -1.2(4) ?
C1 N1 C2 S1 . . . . -139.1(3) ?
O3 S1 C2 N1 . . . . 109.7(3) ?
O4 S1 C2 N1 . . . . -118.3(3) ?
C20 S1 C2 N1 . . . . -3.4(3) ?
O3 S1 C2 C3 . . . . -11.4(3) ?
O4 S1 C2 C3 . . . . 120.6(3) ?
C20 S1 C2 C3 . . . . -124.5(3) ?
N1 C2 C3 C4 . . . . -44.8(4) ?
S1 C2 C3 C4 . . . . 74.2(4) ?
N1 C2 C3 C11 . . . . 69.1(4) ?
S1 C2 C3 C11 . . . . -171.9(2) ?
C2 C3 C4 C5 . . . . -128.2(4) ?
C11 C3 C4 C5 . . . . 118.2(4) ?
C2 C3 C4 C9 . . . . 55.8(4) ?
C11 C3 C4 C9 . . . . -57.9(4) ?
C9 C4 C5 C6 . . . . 1.9(6) ?
C3 C4 C5 C6 . . . . -173.9(4) ?
C4 C5 C6 C7 . . . . -1.1(6) ?
C5 C6 C7 C8 . . . . 0.1(7) ?
C6 C7 C8 C9 . . . . 0.2(6) ?
C5 C4 C9 C8 . . . . -1.7(6) ?
C3 C4 C9 C8 . . . . 174.7(4) ?
C5 C4 C9 C1 . . . . -179.3(4) ?
C3 C4 C9 C1 . . . . -2.9(5) ?
C7 C8 C9 C4 . . . . 0.6(6) ?
C7 C8 C9 C1 . . . . 177.8(4) ?
N1 C1 C9 C4 . . . . -55.7(4) ?
C10 C1 C9 C4 . . . . 59.6(4) ?
N1 C1 C9 C8 . . . . 126.9(4) ?
C10 C1 C9 C8 . . . . -117.8(4) ?
C9 C1 C10 C11 . . . . -49.7(4) ?
N1 C1 C10 C11 . . . . 64.9(4) ?
Si1 O1 C11 O2 . . . . -76.3(4) ?
Si1 O1 C11 C10 . . . . 42.9(5) ?
Si1 O1 C11 C3 . . . . 161.7(3) ?
C18 O2 C11 O1 . . . . -50.7(4) ?
C18 O2 C11 C10 . . . . -175.9(3) ?
C18 O2 C11 C3 . . . . 66.5(4) ?
C1 C10 C11 O1 . . . . 107.0(4) ?
C1 C10 C11 O2 . . . . -130.5(3) ?
C1 C10 C11 C3 . . . . -9.9(4) ?
C4 C3 C11 O1 . . . . -60.4(4) ?
C2 C3 C11 O1 . . . . -177.9(3) ?
C4 C3 C11 O2 . . . . 178.8(3) ?
C2 C3 C11 O2 . . . . 61.3(4) ?
C4 C3 C11 C10 . . . . 63.0(4) ?
C2 C3 C11 C10 . . . . -54.4(4) ?
O1 Si1 C14 C16 . . . . -164.1(3) ?
C12 Si1 C14 C16 . . . . -46.2(3) ?
C13 Si1 C14 C16 . . . . 77.1(3) ?
O1 Si1 C14 C15 . . . . -45.0(3) ?
C12 Si1 C14 C15 . . . . 73.0(3) ?
C13 Si1 C14 C15 . . . . -163.8(3) ?
O1 Si1 C14 C17 . . . . 75.5(3) ?
C12 Si1 C14 C17 . . . . -166.6(3) ?
C13 Si1 C14 C17 . . . . -43.3(3) ?
C2 N1 C19 C20 . . . . 7.4(5) ?
C1 N1 C19 C20 . . . . 142.1(4) ?
C2 N1 C19 C23 . . . . -177.1(3) ?
C1 N1 C19 C23 . . . . -42.4(5) ?
N1 C19 C20 C21 . . . . 171.5(4) ?
C23 C19 C20 C21 . . . . -3.8(7) ?
N1 C19 C20 S1 . . . . -10.0(5) ?
C23 C19 C20 S1 . . . . 174.8(3) ?
O3 S1 C20 C19 . . . . -106.7(3) ?
O4 S1 C20 C19 . . . . 119.1(3) ?
C2 S1 C20 C19 . . . . 7.3(3) ?
O3 S1 C20 C21 . . . . 72.1(3) ?
O4 S1 C20 C21 . . . . -62.1(4) ?
C2 S1 C20 C21 . . . . -173.9(3) ?
C22 O6 C21 O5 . . . . 3.7(6) ?
C22 O6 C21 C20 . . . . -176.5(3) ?
C19 C20 C21 O5 . . . . -174.3(4) ?
S1 C20 C21 O5 . . . . 7.2(6) ?
C19 C20 C21 O6 . . . . 5.9(6) ?
S1 C20 C21 O6 . . . . -172.6(3) ?
C24 O8 C23 O7 . . . . -8.8(6) ?
C24 O8 C23 C19 . . . . 170.3(3) ?
C20 C19 C23 O7 . . . . 106.1(5) ?
N1 C19 C23 O7 . . . . -69.1(5) ?
C20 C19 C23 O8 . . . . -73.0(5) ?
N1 C19 C23 O8 . . . . 111.7(4) ?



#=============================================================================
#  end of cif data for "gar10289"  
#=============================================================================
#=============================================================================
#  end of cif file
#=============================================================================

