# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2023

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_wxy101
_database_code_depnum_ccdc_archive 'CCDC 2240674'
loop_
_audit_author_name
_audit_author_address
wxy
;Sun Yatsen University
China
;
_audit_update_record             
;
2023-02-08 deposited with the CCDC.	2023-04-25 downloaded from the CCDC.
;
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_formula_moiety         'C23 H34 O4'
_chemical_formula_sum            'C23 H34 O4'
_chemical_formula_iupac          ?
_chemical_formula_weight         374.50

_chemical_melting_point          ?

_space_group_crystal_system      monoclinic
_space_group_name_H-M_alt        'P 1 21/n 1'
_space_group_name_Hall           '-P 2yn'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   9.1816(5)
_cell_length_b                   23.6417(12)
_cell_length_c                   10.0047(5)
_cell_angle_alpha                90
_cell_angle_beta                 102.444(2)
_cell_angle_gamma                90
_cell_volume                     2120.69(19)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    7340
_cell_measurement_theta_min      3.7393
_cell_measurement_theta_max      72.3499
_cell_measurement_temperature    100.(2)

_exptl_crystal_description       needle
_exptl_crystal_colour            'clear light colourless'
_exptl_crystal_size_max          0.730
_exptl_crystal_size_mid          0.070
_exptl_crystal_size_min          0.060
_exptl_crystal_density_diffrn    1.173
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             816

_exptl_absorpt_coefficient_mu    0.624
_exptl_absorpt_correction_type   Multi-Scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 - Bruker AXS area detector scaling and absorption correction
;
_exptl_absorpt_correction_T_min  0.69
_exptl_absorpt_correction_T_max  0.96

_exptl_special_details           
;
;

_diffrn_ambient_temperature      100.(2)

_diffrn_source                   'Ius Diamond'
_diffrn_source_type              Microfocus

_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.54178
_diffrn_radiation_monochromator  'Helixos MX multilayer Optic'

_diffrn_measurement_device_type  'Bruker D8 QUEST PHOTON II'
_diffrn_measurement_method       ?

_diffrn_detector_area_resol_mean 7.3910

_diffrn_reflns_number            21766
_diffrn_reflns_av_R_equivalents  0.1293
_diffrn_reflns_av_unetI/netI     0.0826
_diffrn_reflns_theta_min         3.74
_diffrn_reflns_theta_max         72.61
_diffrn_reflns_theta_full        72.61
_diffrn_measured_fraction_theta_max 0.988
_diffrn_measured_fraction_theta_full 0.988
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_k_min       -29
_diffrn_reflns_limit_k_max       29
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_limit_l_max       12

_refine_special_details          
;
;

_reflns_number_total             4182
_reflns_number_gt                3085
_reflns_threshold_expression     'I > 2σ(I)'

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_R_factor_all          0.1086
_refine_ls_R_factor_gt           0.0786
_refine_ls_wR_factor_gt          0.2113
_refine_ls_wR_factor_ref         0.2536
_refine_ls_goodness_of_fit_ref   1.114
_refine_ls_restrained_S_all      1.114
_refine_ls_number_reflns         4182
_refine_ls_number_parameters     250
_refine_ls_number_restraints     0
_refine_ls_number_constraints    ?
_refine_ls_hydrogen_treatment    constr
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1683P)²+0.0355P] where P=(Fo²+2Fc²)/3'

_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?

_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_diff_density_max         0.381
_refine_diff_density_min         -0.524
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_computing_data_collection       'Bruker Instrument Service vV6.2.9'
_computing_cell_refinement       'SAINT V8.38A (Bruker AXS Inc., 2017)'
_computing_data_reduction        'SAINT V8.38A (Bruker AXS Inc., 2017)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2017/1 (Sheldrick, 2017)'
_computing_molecular_graphics    'shelXle (C.B. Huebschle, rev 882)'
_computing_publication_material  ?

loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_refinement_flags_posn
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
O O1 0.74640(18) 0.26045(8) 0.92022(16) 0.0217(4) Uani d . . . 1 . .
O O2 0.8499(2) 0.30024(8) 0.60320(18) 0.0267(4) Uani d . . . 1 . .
O O3 0.94131(18) 0.22603(8) 0.73425(17) 0.0242(4) Uani d . . . 1 . .
O O4 0.3918(2) 0.30529(9) 0.83090(19) 0.0306(5) Uani d . . . 1 . .
C C1 0.7239(3) 0.04209(14) 0.3988(3) 0.0377(7) Uani d . . . 1 . .
H H14 0.730692 0.035825 0.496785 0.057 Uiso calc U . R 1 . .
H H15 0.806538 0.066302 0.386167 0.057 Uiso calc U . R 1 . .
H H1 0.729524 0.005693 0.353321 0.057 Uiso calc U . R 1 . .
C C2 0.5790(3) 0.07026(11) 0.3380(3) 0.0256(5) Uani d . . . 1 . .
C C3 0.4850(3) 0.09077(11) 0.4104(2) 0.0239(5) Uani d . . . 1 . .
H H13 0.397404 0.1082 0.359054 0.029 Uiso calc U . R 1 . .
C C4 0.4997(3) 0.08989(11) 0.5631(2) 0.0248(5) Uani d . . . 1 . .
H H11 0.590352 0.068391 0.605779 0.03 Uiso calc U . R 1 . .
H H12 0.412574 0.070135 0.584727 0.03 Uiso calc U . R 1 . .
C C5 0.5097(3) 0.14974(10) 0.6243(2) 0.0198(5) Uani d . . . 1 . .
H H21 0.424591 0.172146 0.570449 0.024 Uiso calc U . R 1 . .
C C6 0.6540(2) 0.17877(10) 0.6088(2) 0.0196(5) Uani d . . . 1 . .
H H20 0.651587 0.184169 0.510181 0.023 Uiso calc U . R 1 . .
H H19 0.739445 0.153818 0.646819 0.023 Uiso calc U . R 1 . .
C C7 0.6781(2) 0.23666(10) 0.6815(2) 0.0185(5) Uani d . . . 1 . .
C C8 0.5529(3) 0.27848(10) 0.6193(2) 0.0195(5) Uani d . . . 1 . .
H H27 0.556469 0.284609 0.522215 0.023 Uiso calc U . R 1 . .
H H26 0.45602 0.260341 0.620724 0.023 Uiso calc U . R 1 . .
C C9 0.5560(2) 0.33679(10) 0.6889(2) 0.0197(5) Uani d . . . 1 . .
H H28 0.66013 0.351951 0.70897 0.024 Uiso calc U . R 1 . .
C C10 0.4515(3) 0.37847(10) 0.5949(2) 0.0219(5) Uani d . . . 1 . .
H H32 0.354101 0.359852 0.560426 0.026 Uiso calc U . R 1 . .
H H7 0.43419 0.411767 0.649436 0.026 Uiso calc U . R 1 . .
C C11 0.5138(3) 0.39854(11) 0.4730(3) 0.0255(5) Uani d . . . 1 . .
H H6 0.614363 0.414547 0.508264 0.031 Uiso calc U . R 1 . .
H H5 0.525625 0.365184 0.416453 0.031 Uiso calc U . R 1 . .
C C12 0.4216(3) 0.44194(11) 0.3821(3) 0.0256(5) Uani d . . . 1 . .
C C13 0.4947(4) 0.46375(12) 0.2710(3) 0.0342(6) Uani d . . . 1 . .
H H33 0.429988 0.492026 0.216211 0.051 Uiso calc U . R 1 . .
H H2 0.510932 0.432298 0.212122 0.051 Uiso calc U . R 1 . .
H H34 0.590728 0.481108 0.312577 0.051 Uiso calc U . R 1 . .
C C14 0.2892(3) 0.46072(12) 0.3944(3) 0.0315(6) Uani d . . . 1 . .
H H3 0.244974 0.44662 0.465233 0.038 Uiso calc U . R 1 . .
H H4 0.238431 0.488283 0.332324 0.038 Uiso calc U . R 1 . .
C C15 0.6763(2) 0.22836(10) 0.8327(2) 0.0185(5) Uani d . . . 1 . .
C C16 0.5758(3) 0.18505(10) 0.8659(2) 0.0211(5) Uani d . . . 1 . .
H H22 0.567351 0.181495 0.958536 0.025 Uiso calc U . R 1 . .
C C17 0.4948(3) 0.15002(10) 0.7730(2) 0.0201(5) Uani d . . . 1 . .
C C18 0.3804(3) 0.11204(12) 0.8133(3) 0.0279(6) Uani d . . . 1 . .
H H8 0.415818 0.072837 0.81771 0.042 Uiso calc U . R 1 . .
H H10 0.286375 0.115025 0.745295 0.042 Uiso calc U . R 1 . .
H H9 0.364448 0.12348 0.903185 0.042 Uiso calc U . R 1 . .
C C19 0.5464(4) 0.07555(13) 0.1852(3) 0.0363(7) Uani d . . . 1 . .
H H17 0.447718 0.092552 0.153261 0.054 Uiso calc U . R 1 . .
H H16 0.548227 0.03797 0.144201 0.054 Uiso calc U . R 1 . .
H H18 0.622126 0.099586 0.158072 0.054 Uiso calc U . R 1 . .
C C20 0.8310(3) 0.25885(10) 0.6678(2) 0.0197(5) Uani d . . . 1 . .
C C21 1.0916(3) 0.24467(13) 0.7301(3) 0.0280(6) Uani d . . . 1 . .
H H24 1.109879 0.238131 0.638385 0.042 Uiso calc U . R 1 . .
H H25 1.164278 0.223303 0.797406 0.042 Uiso calc U . R 1 . .
H H23 1.101636 0.2851 0.751702 0.042 Uiso calc U . R 1 . .
C C22 0.4978(3) 0.33456(11) 0.8210(2) 0.0229(5) Uani d . . . 1 . .
C C23 0.5729(3) 0.37278(12) 0.9356(3) 0.0279(6) Uani d . . . 1 . .
H H30 0.513484 0.37424 1.005944 0.042 Uiso calc U . R 1 . .
H H29 0.581635 0.410903 0.899627 0.042 Uiso calc U . R 1 . .
H H31 0.672541 0.358084 0.975667 0.042 Uiso calc U . R 1 . .


_geom_special_details            
;

All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix.  The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry.  An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
O1 C15 . 1.231(3) ?
O2 C20 . 1.206(3) ?
O3 C20 . 1.334(3) ?
O3 C21 . 1.457(3) ?
O4 C22 . 1.215(3) ?
C1 C2 . 1.495(4) ?
C1 H14 . 0.98 ?
C1 H15 . 0.98 ?
C1 H1 . 0.98 ?
C2 C3 . 1.332(4) ?
C2 C19 . 1.499(4) ?
C3 C4 . 1.504(3) ?
C3 H13 . 0.95 ?
C4 C5 . 1.537(3) ?
C4 H11 . 0.99 ?
C4 H12 . 0.99 ?
C5 C17 . 1.522(3) ?
C5 C6 . 1.530(3) ?
C5 H21 . 1.0 ?
C6 C7 . 1.544(3) ?
C6 H20 . 0.99 ?
C6 H19 . 0.99 ?
C7 C15 . 1.528(3) ?
C7 C20 . 1.532(3) ?
C7 C8 . 1.542(3) ?
C8 C9 . 1.542(3) ?
C8 H27 . 0.99 ?
C8 H26 . 0.99 ?
C9 C22 . 1.531(3) ?
C9 C10 . 1.544(3) ?
C9 H28 . 1.0 ?
C10 C11 . 1.530(3) ?
C10 H32 . 0.99 ?
C10 H7 . 0.99 ?
C11 C12 . 1.505(4) ?
C11 H6 . 0.99 ?
C11 H5 . 0.99 ?
C12 C14 . 1.325(4) ?
C12 C13 . 1.507(3) ?
C13 H33 . 0.98 ?
C13 H2 . 0.98 ?
C13 H34 . 0.98 ?
C14 H3 . 0.95 ?
C14 H4 . 0.95 ?
C15 C16 . 1.464(3) ?
C16 C17 . 1.344(3) ?
C16 H22 . 0.95 ?
C17 C18 . 1.501(3) ?
C18 H8 . 0.98 ?
C18 H10 . 0.98 ?
C18 H9 . 0.98 ?
C19 H17 . 0.98 ?
C19 H16 . 0.98 ?
C19 H18 . 0.98 ?
C21 H24 . 0.98 ?
C21 H25 . 0.98 ?
C21 H23 . 0.98 ?
C22 C23 . 1.505(4) ?
C23 H30 . 0.98 ?
C23 H29 . 0.98 ?
C23 H31 . 0.98 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
C20 O3 C21 . . 115.6(2) ?
C2 C1 H14 . . 109.5 ?
C2 C1 H15 . . 109.5 ?
H14 C1 H15 . . 109.5 ?
C2 C1 H1 . . 109.5 ?
H14 C1 H1 . . 109.5 ?
H15 C1 H1 . . 109.5 ?
C3 C2 C1 . . 124.4(3) ?
C3 C2 C19 . . 121.0(3) ?
C1 C2 C19 . . 114.6(2) ?
C2 C3 C4 . . 128.3(2) ?
C2 C3 H13 . . 115.8 ?
C4 C3 H13 . . 115.8 ?
C3 C4 C5 . . 112.1(2) ?
C3 C4 H11 . . 109.2 ?
C5 C4 H11 . . 109.2 ?
C3 C4 H12 . . 109.2 ?
C5 C4 H12 . . 109.2 ?
H11 C4 H12 . . 107.9 ?
C17 C5 C6 . . 111.06(19) ?
C17 C5 C4 . . 112.55(19) ?
C6 C5 C4 . . 110.54(18) ?
C17 C5 H21 . . 107.5 ?
C6 C5 H21 . . 107.5 ?
C4 C5 H21 . . 107.5 ?
C5 C6 C7 . . 112.89(18) ?
C5 C6 H20 . . 109.0 ?
C7 C6 H20 . . 109.0 ?
C5 C6 H19 . . 109.0 ?
C7 C6 H19 . . 109.0 ?
H20 C6 H19 . . 107.8 ?
C15 C7 C20 . . 109.76(18) ?
C15 C7 C8 . . 108.40(18) ?
C20 C7 C8 . . 111.23(19) ?
C15 C7 C6 . . 108.78(19) ?
C20 C7 C6 . . 107.58(18) ?
C8 C7 C6 . . 111.07(18) ?
C9 C8 C7 . . 116.84(19) ?
C9 C8 H27 . . 108.1 ?
C7 C8 H27 . . 108.1 ?
C9 C8 H26 . . 108.1 ?
C7 C8 H26 . . 108.1 ?
H27 C8 H26 . . 107.3 ?
C22 C9 C8 . . 112.5(2) ?
C22 C9 C10 . . 105.13(18) ?
C8 C9 C10 . . 110.32(18) ?
C22 C9 H28 . . 109.6 ?
C8 C9 H28 . . 109.6 ?
C10 C9 H28 . . 109.6 ?
C11 C10 C9 . . 113.16(19) ?
C11 C10 H32 . . 108.9 ?
C9 C10 H32 . . 108.9 ?
C11 C10 H7 . . 108.9 ?
C9 C10 H7 . . 108.9 ?
H32 C10 H7 . . 107.8 ?
C12 C11 C10 . . 115.8(2) ?
C12 C11 H6 . . 108.3 ?
C10 C11 H6 . . 108.3 ?
C12 C11 H5 . . 108.3 ?
C10 C11 H5 . . 108.3 ?
H6 C11 H5 . . 107.4 ?
C14 C12 C11 . . 125.5(2) ?
C14 C12 C13 . . 121.1(3) ?
C11 C12 C13 . . 113.4(2) ?
C12 C13 H33 . . 109.5 ?
C12 C13 H2 . . 109.5 ?
H33 C13 H2 . . 109.5 ?
C12 C13 H34 . . 109.5 ?
H33 C13 H34 . . 109.5 ?
H2 C13 H34 . . 109.5 ?
C12 C14 H3 . . 120.0 ?
C12 C14 H4 . . 120.0 ?
H3 C14 H4 . . 120.0 ?
O1 C15 C16 . . 121.9(2) ?
O1 C15 C7 . . 120.6(2) ?
C16 C15 C7 . . 117.15(19) ?
C17 C16 C15 . . 123.8(2) ?
C17 C16 H22 . . 118.1 ?
C15 C16 H22 . . 118.1 ?
C16 C17 C18 . . 119.8(2) ?
C16 C17 C5 . . 121.7(2) ?
C18 C17 C5 . . 118.4(2) ?
C17 C18 H8 . . 109.5 ?
C17 C18 H10 . . 109.5 ?
H8 C18 H10 . . 109.5 ?
C17 C18 H9 . . 109.5 ?
H8 C18 H9 . . 109.5 ?
H10 C18 H9 . . 109.5 ?
C2 C19 H17 . . 109.5 ?
C2 C19 H16 . . 109.5 ?
H17 C19 H16 . . 109.5 ?
C2 C19 H18 . . 109.5 ?
H17 C19 H18 . . 109.5 ?
H16 C19 H18 . . 109.5 ?
O2 C20 O3 . . 123.9(2) ?
O2 C20 C7 . . 124.5(2) ?
O3 C20 C7 . . 111.62(19) ?
O3 C21 H24 . . 109.5 ?
O3 C21 H25 . . 109.5 ?
H24 C21 H25 . . 109.5 ?
O3 C21 H23 . . 109.5 ?
H24 C21 H23 . . 109.5 ?
H25 C21 H23 . . 109.5 ?
O4 C22 C23 . . 121.6(2) ?
O4 C22 C9 . . 121.6(2) ?
C23 C22 C9 . . 116.7(2) ?
C22 C23 H30 . . 109.5 ?
C22 C23 H29 . . 109.5 ?
H30 C23 H29 . . 109.5 ?
C22 C23 H31 . . 109.5 ?
H30 C23 H31 . . 109.5 ?
H29 C23 H31 . . 109.5 ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion
_geom_torsion_publ_flag
C1 C2 C3 C4 . . . . -1.0(4) ?
C19 C2 C3 C4 . . . . -179.3(3) ?
C2 C3 C4 C5 . . . . 116.9(3) ?
C3 C4 C5 C17 . . . . 169.1(2) ?
C3 C4 C5 C6 . . . . -66.1(3) ?
C17 C5 C6 C7 . . . . -48.4(3) ?
C4 C5 C6 C7 . . . . -174.09(19) ?
C5 C6 C7 C15 . . . . 56.8(2) ?
C5 C6 C7 C20 . . . . 175.62(18) ?
C5 C6 C7 C8 . . . . -62.4(2) ?
C15 C7 C8 C9 . . . . 56.2(3) ?
C20 C7 C8 C9 . . . . -64.5(2) ?
C6 C7 C8 C9 . . . . 175.66(18) ?
C7 C8 C9 C22 . . . . -77.7(2) ?
C7 C8 C9 C10 . . . . 165.20(18) ?
C22 C9 C10 C11 . . . . 165.0(2) ?
C8 C9 C10 C11 . . . . -73.5(2) ?
C9 C10 C11 C12 . . . . -176.5(2) ?
C10 C11 C12 C14 . . . . -4.7(4) ?
C10 C11 C12 C13 . . . . 175.1(2) ?
C20 C7 C15 O1 . . . . 34.4(3) ?
C8 C7 C15 O1 . . . . -87.3(2) ?
C6 C7 C15 O1 . . . . 151.8(2) ?
C20 C7 C15 C16 . . . . -152.1(2) ?
C8 C7 C15 C16 . . . . 86.2(2) ?
C6 C7 C15 C16 . . . . -34.6(3) ?
O1 C15 C16 C17 . . . . 178.5(2) ?
C7 C15 C16 C17 . . . . 5.1(3) ?
C15 C16 C17 C18 . . . . -172.2(2) ?
C15 C16 C17 C5 . . . . 4.5(4) ?
C6 C5 C17 C16 . . . . 17.4(3) ?
C4 C5 C17 C16 . . . . 141.9(2) ?
C6 C5 C17 C18 . . . . -165.9(2) ?
C4 C5 C17 C18 . . . . -41.3(3) ?
C21 O3 C20 O2 . . . . 2.8(3) ?
C21 O3 C20 C7 . . . . -178.40(19) ?
C15 C7 C20 O2 . . . . -127.9(2) ?
C8 C7 C20 O2 . . . . -7.9(3) ?
C6 C7 C20 O2 . . . . 113.9(3) ?
C15 C7 C20 O3 . . . . 53.3(3) ?
C8 C7 C20 O3 . . . . 173.23(18) ?
C6 C7 C20 O3 . . . . -64.9(2) ?
C8 C9 C22 O4 . . . . -39.0(3) ?
C10 C9 C22 O4 . . . . 81.1(3) ?
C8 C9 C22 C23 . . . . 144.2(2) ?
C10 C9 C22 C23 . . . . -95.7(2) ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_publ_flag
C9 H28 O2 . 1.00 2.54 3.124(3) 117.1 ?
C23 H31 O1 . 0.98 2.50 3.117(3) 120.7 ?



