# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2023

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
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data_mo_yu1_0m
_database_code_depnum_ccdc_archive 'CCDC 2210770'
loop_
_audit_author_name
_audit_author_address
'Kang Liu'
;institute of high energy physics
China
;
_audit_update_record             
;
2022-10-16 deposited with the CCDC.	2023-01-18 downloaded from the CCDC.
;
_audit_creation_date             2022-10-16
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6408)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        
;
 ?
;
_chemical_formula_moiety         'C34 H53 Dy N4 O Si3'
_chemical_formula_sum            'C34 H53 Dy N4 O Si3'
_chemical_formula_weight         780.57
_chemical_absolute_configuration ?
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           4
_space_group_name_H-M_alt        'P 1 21 1'
_space_group_name_Hall           'P 2yb'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z'

_cell_length_a                   10.0282(5)
_cell_length_b                   19.3323(9)
_cell_length_c                   19.4044(10)
_cell_angle_alpha                90
_cell_angle_beta                 101.790(2)
_cell_angle_gamma                90
_cell_volume                     3682.5(3)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9915
_cell_measurement_temperature    150.0
_cell_measurement_theta_max      27.00
_cell_measurement_theta_min      2.38
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    2.158
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear whiteish colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   whiteish
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.408
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1604
_exptl_crystal_size_max          ?
_exptl_crystal_size_mid          ?
_exptl_crystal_size_min          ?
_exptl_special_details           
;
 ?
;
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0556
_diffrn_reflns_av_unetI/netI     0.0492
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            76565
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.520
_diffrn_reflns_theta_min         1.503
_diffrn_ambient_temperature      150.0
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.939
_reflns_Friedel_fraction_full    0.999
_reflns_Friedel_fraction_max     0.994
_reflns_number_gt                15394
_reflns_number_total             16866
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences. Completness statistics refer to single and
 composite reflections containing twin component 1 only.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.40A (?, 2016)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.40A (?, 2016)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         0.398
_refine_diff_density_min         -0.506
_refine_diff_density_rms         0.070
_refine_ls_abs_structure_details 
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.124(5)
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.002
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     825
_refine_ls_number_reflns         16866
_refine_ls_number_restraints     49
_refine_ls_R_factor_all          0.0329
_refine_ls_R_factor_gt           0.0265
_refine_ls_restrained_S_all      1.004
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0110P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0456
_refine_ls_wR_factor_ref         0.0473
_refine_special_details          
;
 Refined as a 2-component inversion twin.
;
_olex2_refinement_description    
;
1. Twinned data refinement
 Scales: 0.876(5)
 0.124(5)
2. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
3. Uiso/Uaniso restraints and constraints
Uanis(C51) \\sim Ueq, Uanis(C71) \\sim Ueq, Uanis(C49) \\sim Ueq, Uanis(C69)
\\sim Ueq, Uanis(C50) \\sim Ueq: with sigma of 0.01 and sigma for terminal
atoms of 0.02
Uanis(C36) \\sim Ueq, Uanis(C35) \\sim Ueq, Uanis(C2) \\sim Ueq: with sigma of
0.01 and sigma for terminal atoms of 0.02
4. Others
 Sof(C69)=Sof(H69A)=Sof(H69B)=Sof(H69C)=Sof(C71)=Sof(H71A)=Sof(H71B)=Sof(H71C)=
 Sof(C70)=Sof(H70A)=Sof(H70B)=Sof(H70C)=1-FVAR(1)
 Sof(C49)=Sof(H49A)=Sof(H49B)=Sof(H49C)=Sof(C51)=Sof(H51A)=Sof(H51B)=Sof(H51C)=
 Sof(C50)=Sof(H50A)=Sof(H50B)=Sof(H50C)=FVAR(1)
5.a Secondary CH2 refined with riding coordinates:
 C59(H59A,H59B), C22(H22A,H22B), C15(H15A,H15B), C14(H14A,H14B), C58(H58A,
 H58B), C4(H4A,H4B), C39(H39A,H39B), C35(H35A,H35B), C1(H1A,H1B), C38(H38A,
 H38B), C36(H36A,H36B), C37(H37A,H37B), C2(H2A,H2B), C3(H3A,H3B)
5.b Aromatic/amide H refined with riding coordinates:
 C9(H9), C64(H64), C10(H10), C25(H25), C17(H17), C62(H62), C20(H20), C12(H12),
 C19(H19), C63(H63), C11(H11), C18(H18), C61(H61), C27(H27), C41(H41), C26(H26),
  C54(H54), C53(H53), C43(H43), C28(H28), C44(H44), C56(H56), C42(H42), C55(H55)
5.c Idealised Me refined as rotating group:
 C67(H67A,H67B,H67C), C48(H48A,H48B,H48C), C33(H33A,H33B,H33C), C5(H5A,H5B,
 H5C), C34(H34A,H34B,H34C), C30(H30A,H30B,H30C), C47(H47A,H47B,H47C), C66(H66A,
 H66B,H66C), C6(H6A,H6B,H6C), C7(H7A,H7B,H7C), C29(H29A,H29B,H29C), C68(H68A,
 H68B,H68C), C31(H31A,H31B,H31C), C46(H46A,H46B,H46C), C32(H32A,H32B,H32C),
 C49(H49A,H49B,H49C), C51(H51A,H51B,H51C), C50(H50A,H50B,H50C), C69(H69A,H69B,
 H69C), C71(H71A,H71B,H71C), C70(H70A,H70B,H70C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.74892(2) 0.62470(2) 0.47085(2) 0.01848(5) Uani 1 1 d . . . . .
Dy2 Dy 0.66889(2) 0.41207(2) 0.97786(2) 0.02224(5) Uani 1 1 d . . . . .
Si1 Si 0.47763(14) 0.74688(7) 0.42512(7) 0.0247(3) Uani 1 1 d . . . . .
Si6 Si 0.91743(14) 0.54260(7) 1.03865(8) 0.0263(3) Uani 1 1 d . . . . .
Si2 Si 1.01362(13) 0.70305(7) 0.59657(7) 0.0249(3) Uani 1 1 d . . . . .
Si3 Si 0.76827(12) 0.48002(6) 0.35546(7) 0.0212(3) Uani 1 1 d . . . . .
Si5 Si 0.64204(13) 0.26854(7) 1.09356(7) 0.0244(3) Uani 1 1 d . . . . .
Si4 Si 0.42880(14) 0.45830(7) 0.82050(8) 0.0301(3) Uani 1 1 d . . . . .
O1 O 0.8832(3) 0.67721(17) 0.39388(18) 0.0284(8) Uani 1 1 d . . . . .
N4 N 0.6278(4) 0.55493(19) 0.5474(2) 0.0207(8) Uani 1 1 d . . . . .
N8 N 0.8286(4) 0.3452(2) 0.9174(2) 0.0250(9) Uani 1 1 d . . . . .
O2 O 0.5020(3) 0.45930(18) 1.0383(2) 0.0365(9) Uani 1 1 d . . . . .
N7 N 0.8640(4) 0.45800(19) 1.03744(19) 0.0216(8) Uani 1 1 d . . . . .
C59 C 0.9736(5) 0.3632(2) 0.9480(2) 0.0264(11) Uani 1 1 d . . . . .
H59A H 0.991515 0.411007 0.934028 0.032 Uiso 1 1 calc R U . . .
H59B H 1.033887 0.331831 0.927935 0.032 Uiso 1 1 calc R U . . .
C24 C 0.4474(4) 0.6086(2) 0.4013(2) 0.0227(11) Uani 1 1 d . . . . .
N1 N 0.5390(4) 0.66393(19) 0.4238(2) 0.0226(9) Uani 1 1 d . . . . .
N5 N 0.5916(4) 0.4553(2) 0.8687(2) 0.0302(10) Uani 1 1 d . . . . .
C8 C 0.8779(4) 0.4843(2) 0.4963(2) 0.0197(10) Uani 1 1 d . . . . .
N3 N 0.8082(4) 0.52023(18) 0.43578(19) 0.0197(8) Uani 1 1 d . . . . .
C22 C 0.4776(4) 0.5663(2) 0.5277(2) 0.0255(11) Uani 1 1 d . . . . .
H22A H 0.456499 0.613453 0.542151 0.031 Uiso 1 1 calc R U . . .
H22B H 0.431481 0.532949 0.553730 0.031 Uiso 1 1 calc R U . . .
C15 C 0.6756(5) 0.5768(2) 0.6222(2) 0.0244(11) Uani 1 1 d . . . . .
H15A H 0.772729 0.563881 0.637407 0.029 Uiso 1 1 calc R U . . .
H15B H 0.623516 0.550932 0.651907 0.029 Uiso 1 1 calc R U . . .
N2 N 0.8469(4) 0.67610(19) 0.5735(2) 0.0242(9) Uani 1 1 d . . . . .
C9 C 1.0166(5) 0.4691(2) 0.5059(3) 0.0264(11) Uani 1 1 d . . . . .
H9 H 1.064273 0.480360 0.469819 0.032 Uiso 1 1 calc R U . . .
C21 C 0.7507(5) 0.6998(3) 0.6126(2) 0.0240(11) Uani 1 1 d . . . . .
C64 C 0.9991(4) 0.4011(3) 1.1425(2) 0.0293(11) Uani 1 1 d . . . . .
H64 H 0.965538 0.433695 1.171460 0.035 Uiso 1 1 calc R U . . .
C10 C 1.0862(5) 0.4380(2) 0.5673(3) 0.0325(12) Uani 1 1 d . . . . .
H10 H 1.180449 0.427896 0.572582 0.039 Uiso 1 1 calc R U . . .
C16 C 0.6613(5) 0.6524(3) 0.6347(3) 0.0262(11) Uani 1 1 d . . . . .
N6 N 0.6160(4) 0.30592(19) 1.0114(2) 0.0254(9) Uani 1 1 d . . . . .
C25 C 0.3830(5) 0.6001(3) 0.3301(3) 0.0319(13) Uani 1 1 d . . . . .
H25 H 0.396818 0.633748 0.296599 0.038 Uiso 1 1 calc R U . . .
C17 C 0.5650(5) 0.6757(3) 0.6721(3) 0.0298(12) Uani 1 1 d . . . . .
H17 H 0.504123 0.643472 0.686091 0.036 Uiso 1 1 calc R U . . .
C57 C 0.8048(5) 0.4390(3) 0.8268(2) 0.0268(11) Uani 1 1 d . . . . .
C62 C 1.1367(5) 0.3023(3) 1.1334(3) 0.0388(14) Uani 1 1 d . . . . .
H62 H 1.196542 0.266819 1.155048 0.047 Uiso 1 1 calc R U . . .
C20 C 0.7397(5) 0.7694(3) 0.6310(3) 0.0296(12) Uani 1 1 d . . . . .
H20 H 0.799033 0.802373 0.616799 0.036 Uiso 1 1 calc R U . . .
C67 C 0.7699(5) 0.5975(3) 0.9987(3) 0.0410(14) Uani 1 1 d . . . . .
H67A H 0.706189 0.570458 0.964003 0.061 Uiso 1 1 calc R U . . .
H67B H 0.801973 0.637427 0.975538 0.061 Uiso 1 1 calc R U . . .
H67C H 0.723657 0.613687 1.035624 0.061 Uiso 1 1 calc R U . . .
C12 C 0.8802(5) 0.4352(2) 0.6116(3) 0.0292(12) Uani 1 1 d . . . . .
H12 H 0.833952 0.423371 0.648033 0.035 Uiso 1 1 calc R U . . .
C14 C 0.6581(4) 0.4799(2) 0.5411(3) 0.0228(10) Uani 1 1 d . . . . .
H14A H 0.611365 0.463230 0.494150 0.027 Uiso 1 1 calc R U . . .
H14B H 0.621344 0.453823 0.576967 0.027 Uiso 1 1 calc R U . . .
C48 C 0.6823(5) 0.3392(3) 1.1607(3) 0.0327(13) Uani 1 1 d . . . . .
H48A H 0.736478 0.375004 1.143470 0.049 Uiso 1 1 calc R U . . .
H48B H 0.734179 0.320044 1.204889 0.049 Uiso 1 1 calc R U . . .
H48C H 0.597339 0.359490 1.168878 0.049 Uiso 1 1 calc R U . . .
C33 C 1.1247(5) 0.6314(3) 0.5768(3) 0.0358(13) Uani 1 1 d . . . . .
H33A H 1.115891 0.591510 0.606709 0.054 Uiso 1 1 calc R U . . .
H33B H 1.219669 0.646951 0.586132 0.054 Uiso 1 1 calc R U . . .
H33C H 1.096730 0.618157 0.527207 0.054 Uiso 1 1 calc R U . . .
C19 C 0.6455(5) 0.7916(2) 0.6690(3) 0.0294(12) Uani 1 1 d . . . . .
H19 H 0.641775 0.839067 0.681092 0.035 Uiso 1 1 calc R U . . .
C65 C 0.9576(4) 0.4064(3) 1.0689(2) 0.0229(10) Uani 1 1 d . . . . .
C5 C 0.6974(5) 0.5470(3) 0.2888(3) 0.0344(12) Uani 1 1 d . . . . .
H5A H 0.618309 0.569053 0.302097 0.052 Uiso 1 1 calc R U . . .
H5B H 0.669399 0.525166 0.242516 0.052 Uiso 1 1 calc R U . . .
H5C H 0.767144 0.582011 0.286738 0.052 Uiso 1 1 calc R U . . .
C63 C 1.0868(5) 0.3503(3) 1.1737(3) 0.0367(13) Uani 1 1 d . . . . .
H63 H 1.113118 0.348456 1.223593 0.044 Uiso 1 1 calc R U . . .
C23 C 0.4211(4) 0.5579(2) 0.4491(3) 0.0247(11) Uani 1 1 d . . . . .
C13 C 0.8091(5) 0.4654(2) 0.5507(2) 0.0222(10) Uani 1 1 d . . . . .
C34 C 1.0474(5) 0.7816(3) 0.5464(3) 0.0366(13) Uani 1 1 d . . . . .
H34A H 1.034940 0.770164 0.496275 0.055 Uiso 1 1 calc R U . . .
H34B H 1.141057 0.797325 0.563938 0.055 Uiso 1 1 calc R U . . .
H34C H 0.983778 0.818433 0.552672 0.055 Uiso 1 1 calc R U . . .
C60 C 1.0087(5) 0.3578(2) 1.0275(3) 0.0261(11) Uani 1 1 d . . . . .
C58 C 0.7987(5) 0.3630(3) 0.8406(3) 0.0310(12) Uani 1 1 d . . . . .
H58A H 0.865135 0.338989 0.817614 0.037 Uiso 1 1 calc R U . . .
H58B H 0.706756 0.345728 0.818967 0.037 Uiso 1 1 calc R U . . .
C11 C 1.0196(5) 0.4217(3) 0.6202(3) 0.0338(12) Uani 1 1 d . . . . .
H11 H 1.068024 0.401311 0.662543 0.041 Uiso 1 1 calc R U . . .
C52 C 0.6993(5) 0.4826(3) 0.8391(2) 0.0294(11) Uani 1 1 d . . . . .
C4 C 1.0071(5) 0.6477(3) 0.3777(3) 0.0385(14) Uani 1 1 d . . . . .
H4A H 1.003509 0.596559 0.378178 0.046 Uiso 1 1 calc R U . . .
H4B H 1.088290 0.663262 0.412275 0.046 Uiso 1 1 calc R U . . .
C30 C 0.6234(5) 0.8074(3) 0.4497(3) 0.0351(13) Uani 1 1 d . . . . .
H30A H 0.698687 0.783922 0.481127 0.053 Uiso 1 1 calc R U . . .
H30B H 0.595061 0.847727 0.473740 0.053 Uiso 1 1 calc R U . . .
H30C H 0.653450 0.822565 0.407099 0.053 Uiso 1 1 calc R U . . .
C40 C 0.6602(5) 0.2486(3) 0.9056(3) 0.0331(12) Uani 1 1 d . . . . .
C18 C 0.5567(5) 0.7450(3) 0.6894(3) 0.0338(12) Uani 1 1 d . . . . .
H18 H 0.490669 0.760221 0.714856 0.041 Uiso 1 1 calc R U . . .
C47 C 0.4897(5) 0.2212(3) 1.1105(3) 0.0369(13) Uani 1 1 d . . . . .
H47A H 0.411742 0.252739 1.104229 0.055 Uiso 1 1 calc R U . . .
H47B H 0.508898 0.203357 1.158821 0.055 Uiso 1 1 calc R U . . .
H47C H 0.468637 0.182516 1.077396 0.055 Uiso 1 1 calc R U . . .
C61 C 1.0984(5) 0.3062(3) 1.0604(3) 0.0343(13) Uani 1 1 d . . . . .
H61 H 1.133417 0.273341 1.032281 0.041 Uiso 1 1 calc R U . . .
C66 C 1.0526(5) 0.5537(3) 0.9869(3) 0.0436(15) Uani 1 1 d . . . . .
H66A H 1.123868 0.518914 1.001593 0.065 Uiso 1 1 calc R U . . .
H66B H 1.092042 0.600038 0.995038 0.065 Uiso 1 1 calc R U . . .
H66C H 1.013099 0.547833 0.936685 0.065 Uiso 1 1 calc R U . . .
C6 C 0.9163(5) 0.4401(2) 0.3261(3) 0.0308(12) Uani 1 1 d . . . . .
H6A H 0.978700 0.476557 0.317287 0.046 Uiso 1 1 calc R U . . .
H6B H 0.884065 0.413803 0.282784 0.046 Uiso 1 1 calc R U . . .
H6C H 0.964146 0.409056 0.362920 0.046 Uiso 1 1 calc R U . . .
C27 C 0.2790(5) 0.4940(3) 0.3545(3) 0.0382(14) Uani 1 1 d . . . . .
H27 H 0.224766 0.454664 0.338571 0.046 Uiso 1 1 calc R U . . .
C41 C 0.6106(6) 0.2121(3) 0.8441(3) 0.0443(15) Uani 1 1 d . . . . .
H41 H 0.670943 0.201378 0.813712 0.053 Uiso 1 1 calc R U . . .
C7 C 0.6365(4) 0.4118(3) 0.3539(3) 0.0333(11) Uani 1 1 d . . . . .
H7A H 0.672274 0.375670 0.388192 0.050 Uiso 1 1 calc R U . . .
H7B H 0.613050 0.391422 0.306720 0.050 Uiso 1 1 calc R U . . .
H7C H 0.554928 0.432285 0.366003 0.050 Uiso 1 1 calc R U . . .
C29 C 0.3650(5) 0.7561(3) 0.4895(3) 0.0404(14) Uani 1 1 d . . . . .
H29A H 0.294027 0.720487 0.480584 0.061 Uiso 1 1 calc R U . . .
H29B H 0.322462 0.801993 0.484531 0.061 Uiso 1 1 calc R U . . .
H29C H 0.418923 0.750781 0.537345 0.061 Uiso 1 1 calc R U . . .
C26 C 0.3005(5) 0.5442(3) 0.3083(3) 0.0373(14) Uani 1 1 d . . . . .
H26 H 0.257507 0.540372 0.260056 0.045 Uiso 1 1 calc R U . . .
C54 C 0.8151(5) 0.5791(3) 0.7962(3) 0.0377(13) Uani 1 1 d . . . . .
H54 H 0.817816 0.626984 0.785756 0.045 Uiso 1 1 calc R U . . .
C53 C 0.7084(5) 0.5530(3) 0.8230(3) 0.0325(12) Uani 1 1 d . . . . .
H53 H 0.638791 0.583619 0.830752 0.039 Uiso 1 1 calc R U . . .
C43 C 0.3883(6) 0.2052(3) 0.8697(3) 0.0517(17) Uani 1 1 d . . . . .
H43 H 0.295967 0.190558 0.858017 0.062 Uiso 1 1 calc R U . . .
C28 C 0.3380(5) 0.5018(3) 0.4250(3) 0.0324(12) Uani 1 1 d . . . . .
H28 H 0.321210 0.468037 0.457759 0.039 Uiso 1 1 calc R U . . .
C44 C 0.4366(6) 0.2417(3) 0.9320(3) 0.0416(15) Uani 1 1 d . . . . .
H44 H 0.375598 0.251134 0.962390 0.050 Uiso 1 1 calc R U . . .
C39 C 0.8071(5) 0.2692(2) 0.9252(3) 0.0330(12) Uani 1 1 d . . . . .
H39A H 0.843684 0.255615 0.974612 0.040 Uiso 1 1 calc R U . . .
H39B H 0.858901 0.243671 0.895009 0.040 Uiso 1 1 calc R U . . .
C56 C 0.9113(5) 0.4665(3) 0.7996(2) 0.0332(12) Uani 1 1 d . . . . .
H56 H 0.981579 0.436653 0.791140 0.040 Uiso 1 1 calc R U . . .
C42 C 0.4760(7) 0.1908(3) 0.8256(3) 0.0530(17) Uani 1 1 d . . . . .
H42 H 0.444617 0.166548 0.782768 0.064 Uiso 1 1 calc R U . . .
C35 C 0.3821(5) 0.4231(3) 1.0527(4) 0.0589(19) Uani 1 1 d . U . . .
H35A H 0.399372 0.372779 1.057567 0.071 Uiso 1 1 calc R U . . .
H35B H 0.302064 0.431020 1.014235 0.071 Uiso 1 1 calc R U . . .
C68 C 0.9855(6) 0.5771(3) 1.1293(3) 0.0526(17) Uani 1 1 d . . . . .
H68A H 0.914356 0.574664 1.157162 0.079 Uiso 1 1 calc R U . . .
H68B H 1.013830 0.625303 1.126145 0.079 Uiso 1 1 calc R U . . .
H68C H 1.063983 0.549322 1.152120 0.079 Uiso 1 1 calc R U . . .
C1 C 0.8458(6) 0.7372(3) 0.3495(3) 0.0439(15) Uani 1 1 d . . . . .
H1A H 0.850729 0.779687 0.378351 0.053 Uiso 1 1 calc R U . . .
H1B H 0.751888 0.732297 0.321587 0.053 Uiso 1 1 calc R U . . .
C31 C 0.3753(6) 0.7765(3) 0.3386(3) 0.0456(15) Uani 1 1 d . . . . .
H31A H 0.430436 0.772878 0.302506 0.068 Uiso 1 1 calc R U . . .
H31B H 0.347705 0.824744 0.342554 0.068 Uiso 1 1 calc R U . . .
H31C H 0.293990 0.747435 0.325439 0.068 Uiso 1 1 calc R U . . .
C45 C 0.5715(5) 0.2648(2) 0.9515(3) 0.0298(12) Uani 1 1 d . . . . .
C55 C 0.9174(5) 0.5364(3) 0.7844(3) 0.0385(14) Uani 1 1 d . . . . .
H55 H 0.991275 0.554460 0.766227 0.046 Uiso 1 1 calc R U . . .
C46 C 0.7848(5) 0.2051(3) 1.1063(3) 0.0379(13) Uani 1 1 d . . . . .
H46A H 0.765600 0.169561 1.069608 0.057 Uiso 1 1 calc R U . . .
H46B H 0.794332 0.183286 1.152664 0.057 Uiso 1 1 calc R U . . .
H46C H 0.869594 0.229056 1.103404 0.057 Uiso 1 1 calc R U . . .
C32 C 1.0652(5) 0.7206(3) 0.6926(3) 0.0424(14) Uani 1 1 d . . . . .
H32A H 1.022801 0.763677 0.703862 0.064 Uiso 1 1 calc R U . . .
H32B H 1.164529 0.724982 0.705608 0.064 Uiso 1 1 calc R U . . .
H32C H 1.035431 0.682313 0.718979 0.064 Uiso 1 1 calc R U . . .
C38 C 0.5105(7) 0.5246(3) 1.0753(4) 0.0567(18) Uani 1 1 d . . . . .
H38A H 0.499919 0.563326 1.041328 0.068 Uiso 1 1 calc R U . . .
H38B H 0.600442 0.528946 1.107495 0.068 Uiso 1 1 calc R U . . .
C36 C 0.3588(6) 0.4531(4) 1.1202(4) 0.067(2) Uani 1 1 d . U . . .
H36A H 0.261872 0.449159 1.123488 0.080 Uiso 1 1 calc R U . . .
H36B H 0.415776 0.429597 1.161192 0.080 Uiso 1 1 calc R U . . .
C37 C 0.3996(6) 0.5270(3) 1.1165(3) 0.0556(17) Uani 1 1 d . . . . .
H37A H 0.433604 0.546172 1.164181 0.067 Uiso 1 1 calc R U . . .
H37B H 0.322102 0.555477 1.092122 0.067 Uiso 1 1 calc R U . . .
C2 C 0.9463(8) 0.7404(4) 0.3019(4) 0.076(2) Uani 1 1 d . U . . .
H2A H 0.899108 0.750588 0.252990 0.091 Uiso 1 1 calc R U . . .
H2B H 1.014549 0.777132 0.317693 0.091 Uiso 1 1 calc R U . . .
C3 C 1.0112(7) 0.6739(4) 0.3056(4) 0.068(2) Uani 1 1 d . . . . .
H3A H 1.106317 0.678287 0.299313 0.081 Uiso 1 1 calc R U . . .
H3B H 0.961128 0.642472 0.269036 0.081 Uiso 1 1 calc R U . . .
C49 C 0.3587(10) 0.5407(6) 0.7844(8) 0.061(4) Uani 0.587(11) 1 d . U P A 1
H49A H 0.260764 0.535626 0.765555 0.092 Uiso 0.587(11) 1 calc R U P A 1
H49B H 0.404128 0.555096 0.746557 0.092 Uiso 0.587(11) 1 calc R U P A 1
H49C H 0.373381 0.575828 0.821624 0.092 Uiso 0.587(11) 1 calc R U P A 1
C51 C 0.4167(12) 0.3979(8) 0.7447(7) 0.075(5) Uani 0.587(11) 1 d . U P A 1
H51A H 0.325316 0.400720 0.714920 0.113 Uiso 0.587(11) 1 calc R U P A 1
H51B H 0.433885 0.350536 0.762236 0.113 Uiso 0.587(11) 1 calc R U P A 1
H51C H 0.484533 0.410714 0.717080 0.113 Uiso 0.587(11) 1 calc R U P A 1
C50 C 0.3116(10) 0.4244(8) 0.8751(7) 0.061(4) Uani 0.587(11) 1 d . U P A 1
H50A H 0.223822 0.412793 0.844670 0.091 Uiso 0.587(11) 1 calc R U P A 1
H50B H 0.297946 0.459580 0.909267 0.091 Uiso 0.587(11) 1 calc R U P A 1
H50C H 0.351129 0.382759 0.900047 0.091 Uiso 0.587(11) 1 calc R U P A 1
C69 C 0.3440(14) 0.5374(8) 0.8501(11) 0.058(6) Uani 0.413(11) 1 d . U P A 2
H69A H 0.245074 0.533870 0.833709 0.087 Uiso 0.413(11) 1 calc R U P A 2
H69B H 0.377319 0.579005 0.830244 0.087 Uiso 0.413(11) 1 calc R U P A 2
H69C H 0.365653 0.540143 0.901592 0.087 Uiso 0.413(11) 1 calc R U P A 2
C71 C 0.4182(16) 0.4596(10) 0.7248(7) 0.058(5) Uani 0.413(11) 1 d . U P A 2
H71A H 0.325186 0.471483 0.700964 0.086 Uiso 0.413(11) 1 calc R U P A 2
H71B H 0.442016 0.413900 0.709149 0.086 Uiso 0.413(11) 1 calc R U P A 2
H71C H 0.481741 0.494186 0.713321 0.086 Uiso 0.413(11) 1 calc R U P A 2
C70 C 0.3297(15) 0.3834(9) 0.8401(9) 0.045(4) Uani 0.413(11) 1 d . . P A 2
H70A H 0.233202 0.390491 0.819216 0.068 Uiso 0.413(11) 1 calc R U P A 2
H70B H 0.341044 0.378260 0.891240 0.068 Uiso 0.413(11) 1 calc R U P A 2
H70C H 0.362230 0.341466 0.820381 0.068 Uiso 0.413(11) 1 calc R U P A 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O1 2.428(3) . ?
Dy1 N4 2.498(4) . ?
Dy1 N1 2.248(4) . ?
Dy1 C8 3.004(4) . ?
Dy1 N3 2.250(3) . ?
Dy1 N2 2.263(4) . ?
Dy2 N8 2.526(4) . ?
Dy2 O2 2.411(4) . ?
Dy2 N7 2.242(4) . ?
Dy2 N5 2.263(4) . ?
Dy2 N6 2.249(4) . ?
Dy2 C45 3.019(5) . ?
Si1 N1 1.720(4) . ?
Si1 C30 1.857(5) . ?
Si1 C29 1.856(5) . ?
Si1 C31 1.870(5) . ?
Si6 N7 1.720(4) . ?
Si6 C67 1.857(5) . ?
Si6 C66 1.857(5) . ?
Si6 C68 1.875(6) . ?
Si2 N2 1.721(4) . ?
Si2 C33 1.865(5) . ?
Si2 C34 1.872(5) . ?
Si2 C32 1.861(5) . ?
Si3 N3 1.714(4) . ?
Si3 C5 1.866(5) . ?
Si3 C6 1.862(5) . ?
Si3 C7 1.863(5) . ?
Si5 N6 1.721(4) . ?
Si5 C48 1.874(5) . ?
Si5 C47 1.867(5) . ?
Si5 C46 1.863(5) . ?
Si4 N5 1.709(4) . ?
Si4 C49 1.824(10) . ?
Si4 C51 1.862(11) . ?
Si4 C50 1.855(11) . ?
Si4 C69 1.895(14) . ?
Si4 C71 1.838(14) . ?
Si4 C70 1.840(14) . ?
O1 C4 1.458(6) . ?
O1 C1 1.448(6) . ?
N4 C22 1.493(6) . ?
N4 C15 1.493(6) . ?
N4 C14 1.491(5) . ?
N8 C59 1.495(6) . ?
N8 C58 1.498(6) . ?
N8 C39 1.498(6) . ?
O2 C35 1.465(6) . ?
O2 C38 1.446(6) . ?
N7 C65 1.419(6) . ?
C59 H59A 0.9900 . ?
C59 H59B 0.9900 . ?
C59 C60 1.515(6) . ?
C24 N1 1.420(5) . ?
C24 C25 1.409(6) . ?
C24 C23 1.411(6) . ?
N5 C52 1.424(6) . ?
C8 N3 1.419(5) . ?
C8 C9 1.396(6) . ?
C8 C13 1.421(6) . ?
C22 H22A 0.9900 . ?
C22 H22B 0.9900 . ?
C22 C23 1.523(6) . ?
C15 H15A 0.9900 . ?
C15 H15B 0.9900 . ?
C15 C16 1.494(6) . ?
N2 C21 1.420(6) . ?
C9 H9 0.9500 . ?
C9 C10 1.388(7) . ?
C21 C16 1.408(7) . ?
C21 C20 1.402(7) . ?
C64 H64 0.9500 . ?
C64 C65 1.408(6) . ?
C64 C63 1.374(7) . ?
C10 H10 0.9500 . ?
C10 C11 1.371(7) . ?
C16 C17 1.396(7) . ?
N6 C45 1.404(6) . ?
C25 H25 0.9500 . ?
C25 C26 1.374(7) . ?
C17 H17 0.9500 . ?
C17 C18 1.388(7) . ?
C57 C58 1.497(7) . ?
C57 C52 1.411(7) . ?
C57 C56 1.390(7) . ?
C62 H62 0.9500 . ?
C62 C63 1.374(8) . ?
C62 C61 1.392(8) . ?
C20 H20 0.9500 . ?
C20 C19 1.380(7) . ?
C67 H67A 0.9800 . ?
C67 H67B 0.9800 . ?
C67 H67C 0.9800 . ?
C12 H12 0.9500 . ?
C12 C13 1.379(6) . ?
C12 C11 1.398(6) . ?
C14 H14A 0.9900 . ?
C14 H14B 0.9900 . ?
C14 C13 1.513(6) . ?
C48 H48A 0.9800 . ?
C48 H48B 0.9800 . ?
C48 H48C 0.9800 . ?
C33 H33A 0.9800 . ?
C33 H33B 0.9800 . ?
C33 H33C 0.9800 . ?
C19 H19 0.9500 . ?
C19 C18 1.380(7) . ?
C65 C60 1.399(6) . ?
C5 H5A 0.9800 . ?
C5 H5B 0.9800 . ?
C5 H5C 0.9800 . ?
C63 H63 0.9500 . ?
C23 C28 1.388(6) . ?
C34 H34A 0.9800 . ?
C34 H34B 0.9800 . ?
C34 H34C 0.9800 . ?
C60 C61 1.407(6) . ?
C58 H58A 0.9900 . ?
C58 H58B 0.9900 . ?
C11 H11 0.9500 . ?
C52 C53 1.404(7) . ?
C4 H4A 0.9900 . ?
C4 H4B 0.9900 . ?
C4 C3 1.496(8) . ?
C30 H30A 0.9800 . ?
C30 H30B 0.9800 . ?
C30 H30C 0.9800 . ?
C40 C41 1.388(7) . ?
C40 C39 1.498(7) . ?
C40 C45 1.416(7) . ?
C18 H18 0.9500 . ?
C47 H47A 0.9800 . ?
C47 H47B 0.9800 . ?
C47 H47C 0.9800 . ?
C61 H61 0.9500 . ?
C66 H66A 0.9800 . ?
C66 H66B 0.9800 . ?
C66 H66C 0.9800 . ?
C6 H6A 0.9800 . ?
C6 H6B 0.9800 . ?
C6 H6C 0.9800 . ?
C27 H27 0.9500 . ?
C27 C26 1.369(8) . ?
C27 C28 1.383(7) . ?
C41 H41 0.9500 . ?
C41 C42 1.387(8) . ?
C7 H7A 0.9800 . ?
C7 H7B 0.9800 . ?
C7 H7C 0.9800 . ?
C29 H29A 0.9800 . ?
C29 H29B 0.9800 . ?
C29 H29C 0.9800 . ?
C26 H26 0.9500 . ?
C54 H54 0.9500 . ?
C54 C53 1.377(7) . ?
C54 C55 1.371(7) . ?
C53 H53 0.9500 . ?
C43 H43 0.9500 . ?
C43 C44 1.398(7) . ?
C43 C42 1.376(8) . ?
C28 H28 0.9500 . ?
C44 H44 0.9500 . ?
C44 C45 1.401(7) . ?
C39 H39A 0.9900 . ?
C39 H39B 0.9900 . ?
C56 H56 0.9500 . ?
C56 C55 1.388(7) . ?
C42 H42 0.9500 . ?
C35 H35A 0.9900 . ?
C35 H35B 0.9900 . ?
C35 C36 1.493(9) . ?
C68 H68A 0.9800 . ?
C68 H68B 0.9800 . ?
C68 H68C 0.9800 . ?
C1 H1A 0.9900 . ?
C1 H1B 0.9900 . ?
C1 C2 1.501(8) . ?
C31 H31A 0.9800 . ?
C31 H31B 0.9800 . ?
C31 H31C 0.9800 . ?
C55 H55 0.9500 . ?
C46 H46A 0.9800 . ?
C46 H46B 0.9800 . ?
C46 H46C 0.9800 . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32 H32C 0.9800 . ?
C38 H38A 0.9900 . ?
C38 H38B 0.9900 . ?
C38 C37 1.497(8) . ?
C36 H36A 0.9900 . ?
C36 H36B 0.9900 . ?
C36 C37 1.493(8) . ?
C37 H37A 0.9900 . ?
C37 H37B 0.9900 . ?
C2 H2A 0.9900 . ?
C2 H2B 0.9900 . ?
C2 C3 1.436(9) . ?
C3 H3A 0.9900 . ?
C3 H3B 0.9900 . ?
C49 H49A 0.9800 . ?
C49 H49B 0.9800 . ?
C49 H49C 0.9800 . ?
C51 H51A 0.9800 . ?
C51 H51B 0.9800 . ?
C51 H51C 0.9800 . ?
C50 H50A 0.9800 . ?
C50 H50B 0.9800 . ?
C50 H50C 0.9800 . ?
C69 H69A 0.9800 . ?
C69 H69B 0.9800 . ?
C69 H69C 0.9800 . ?
C71 H71A 0.9800 . ?
C71 H71B 0.9800 . ?
C71 H71C 0.9800 . ?
C70 H70A 0.9800 . ?
C70 H70B 0.9800 . ?
C70 H70C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Dy1 N4 171.79(11) . . ?
O1 Dy1 C8 101.80(12) . . ?
N4 Dy1 C8 70.11(12) . . ?
N1 Dy1 O1 101.55(13) . . ?
N1 Dy1 N4 83.97(12) . . ?
N1 Dy1 C8 135.04(12) . . ?
N1 Dy1 N3 117.60(13) . . ?
N1 Dy1 N2 114.30(13) . . ?
N3 Dy1 O1 88.59(12) . . ?
N3 Dy1 N4 83.44(12) . . ?
N3 Dy1 C8 26.74(12) . . ?
N3 Dy1 N2 124.50(13) . . ?
N2 Dy1 O1 99.34(13) . . ?
N2 Dy1 N4 83.68(13) . . ?
N2 Dy1 C8 99.04(13) . . ?
N8 Dy2 C45 69.68(14) . . ?
O2 Dy2 N8 171.43(12) . . ?
O2 Dy2 C45 101.93(13) . . ?
N7 Dy2 N8 82.70(13) . . ?
N7 Dy2 O2 102.63(13) . . ?
N7 Dy2 N5 115.61(14) . . ?
N7 Dy2 N6 116.40(13) . . ?
N7 Dy2 C45 132.73(13) . . ?
N5 Dy2 N8 83.24(14) . . ?
N5 Dy2 O2 100.17(14) . . ?
N5 Dy2 C45 98.81(14) . . ?
N6 Dy2 N8 82.96(13) . . ?
N6 Dy2 O2 88.64(13) . . ?
N6 Dy2 N5 123.55(14) . . ?
N6 Dy2 C45 26.02(13) . . ?
N1 Si1 C30 109.0(2) . . ?
N1 Si1 C29 111.6(2) . . ?
N1 Si1 C31 113.9(2) . . ?
C30 Si1 C31 107.2(3) . . ?
C29 Si1 C30 108.8(2) . . ?
C29 Si1 C31 106.1(3) . . ?
N7 Si6 C67 108.6(2) . . ?
N7 Si6 C66 111.2(2) . . ?
N7 Si6 C68 113.8(2) . . ?
C67 Si6 C68 107.1(3) . . ?
C66 Si6 C67 108.4(3) . . ?
C66 Si6 C68 107.5(3) . . ?
N2 Si2 C33 108.1(2) . . ?
N2 Si2 C34 112.3(2) . . ?
N2 Si2 C32 111.8(2) . . ?
C33 Si2 C34 108.4(2) . . ?
C32 Si2 C33 106.6(2) . . ?
C32 Si2 C34 109.3(3) . . ?
N3 Si3 C5 107.5(2) . . ?
N3 Si3 C6 114.4(2) . . ?
N3 Si3 C7 111.6(2) . . ?
C6 Si3 C5 106.9(2) . . ?
C6 Si3 C7 108.0(2) . . ?
C7 Si3 C5 108.2(2) . . ?
N6 Si5 C48 108.0(2) . . ?
N6 Si5 C47 113.2(2) . . ?
N6 Si5 C46 111.5(2) . . ?
C47 Si5 C48 107.6(2) . . ?
C46 Si5 C48 109.7(2) . . ?
C46 Si5 C47 106.7(2) . . ?
N5 Si4 C49 119.3(4) . . ?
N5 Si4 C51 108.2(4) . . ?
N5 Si4 C50 108.8(4) . . ?
N5 Si4 C69 107.4(5) . . ?
N5 Si4 C71 113.9(5) . . ?
N5 Si4 C70 110.9(5) . . ?
C49 Si4 C51 106.7(6) . . ?
C49 Si4 C50 106.8(6) . . ?
C50 Si4 C51 106.4(6) . . ?
C71 Si4 C69 111.0(8) . . ?
C71 Si4 C70 107.3(7) . . ?
C70 Si4 C69 106.1(7) . . ?
C4 O1 Dy1 125.0(3) . . ?
C1 O1 Dy1 126.3(3) . . ?
C1 O1 C4 108.3(4) . . ?
C22 N4 Dy1 110.8(3) . . ?
C15 N4 Dy1 109.0(3) . . ?
C15 N4 C22 108.4(4) . . ?
C14 N4 Dy1 110.1(3) . . ?
C14 N4 C22 109.5(3) . . ?
C14 N4 C15 109.0(3) . . ?
C59 N8 Dy2 110.8(3) . . ?
C59 N8 C58 108.8(4) . . ?
C59 N8 C39 109.6(4) . . ?
C58 N8 Dy2 109.1(3) . . ?
C39 N8 Dy2 109.7(3) . . ?
C39 N8 C58 108.8(4) . . ?
C35 O2 Dy2 126.2(3) . . ?
C38 O2 Dy2 126.6(3) . . ?
C38 O2 C35 106.8(4) . . ?
Si6 N7 Dy2 128.34(19) . . ?
C65 N7 Dy2 112.0(3) . . ?
C65 N7 Si6 119.0(3) . . ?
N8 C59 H59A 108.9 . . ?
N8 C59 H59B 108.9 . . ?
N8 C59 C60 113.2(4) . . ?
H59A C59 H59B 107.8 . . ?
C60 C59 H59A 108.9 . . ?
C60 C59 H59B 108.9 . . ?
C25 C24 N1 121.8(4) . . ?
C25 C24 C23 117.0(4) . . ?
C23 C24 N1 121.2(4) . . ?
Si1 N1 Dy1 128.08(19) . . ?
C24 N1 Dy1 111.4(3) . . ?
C24 N1 Si1 119.8(3) . . ?
Si4 N5 Dy2 129.1(2) . . ?
C52 N5 Dy2 111.8(3) . . ?
C52 N5 Si4 119.1(3) . . ?
N3 C8 Dy1 45.49(19) . . ?
N3 C8 C13 120.5(4) . . ?
C9 C8 Dy1 126.5(3) . . ?
C9 C8 N3 121.5(4) . . ?
C9 C8 C13 117.9(4) . . ?
C13 C8 Dy1 95.5(3) . . ?
Si3 N3 Dy1 130.93(19) . . ?
C8 N3 Dy1 107.8(3) . . ?
C8 N3 Si3 120.9(3) . . ?
N4 C22 H22A 109.0 . . ?
N4 C22 H22B 109.0 . . ?
N4 C22 C23 113.0(4) . . ?
H22A C22 H22B 107.8 . . ?
C23 C22 H22A 109.0 . . ?
C23 C22 H22B 109.0 . . ?
N4 C15 H15A 108.7 . . ?
N4 C15 H15B 108.7 . . ?
N4 C15 C16 114.4(4) . . ?
H15A C15 H15B 107.6 . . ?
C16 C15 H15A 108.7 . . ?
C16 C15 H15B 108.7 . . ?
Si2 N2 Dy1 125.9(2) . . ?
C21 N2 Dy1 113.1(3) . . ?
C21 N2 Si2 119.6(3) . . ?
C8 C9 H9 119.4 . . ?
C10 C9 C8 121.2(5) . . ?
C10 C9 H9 119.4 . . ?
C16 C21 N2 119.8(4) . . ?
C20 C21 N2 122.9(5) . . ?
C20 C21 C16 117.4(5) . . ?
C65 C64 H64 119.0 . . ?
C63 C64 H64 119.0 . . ?
C63 C64 C65 122.0(5) . . ?
C9 C10 H10 119.8 . . ?
C11 C10 C9 120.4(5) . . ?
C11 C10 H10 119.8 . . ?
C21 C16 C15 119.9(5) . . ?
C17 C16 C15 120.0(5) . . ?
C17 C16 C21 120.0(5) . . ?
Si5 N6 Dy2 130.6(2) . . ?
C45 N6 Dy2 109.3(3) . . ?
C45 N6 Si5 119.5(3) . . ?
C24 C25 H25 119.3 . . ?
C26 C25 C24 121.3(5) . . ?
C26 C25 H25 119.3 . . ?
C16 C17 H17 119.4 . . ?
C18 C17 C16 121.2(5) . . ?
C18 C17 H17 119.4 . . ?
C52 C57 C58 119.8(5) . . ?
C56 C57 C58 120.3(5) . . ?
C56 C57 C52 119.8(5) . . ?
C63 C62 H62 120.5 . . ?
C63 C62 C61 119.1(5) . . ?
C61 C62 H62 120.5 . . ?
C21 C20 H20 118.9 . . ?
C19 C20 C21 122.1(5) . . ?
C19 C20 H20 118.9 . . ?
Si6 C67 H67A 109.5 . . ?
Si6 C67 H67B 109.5 . . ?
Si6 C67 H67C 109.5 . . ?
H67A C67 H67B 109.5 . . ?
H67A C67 H67C 109.5 . . ?
H67B C67 H67C 109.5 . . ?
C13 C12 H12 119.6 . . ?
C13 C12 C11 120.7(5) . . ?
C11 C12 H12 119.6 . . ?
N4 C14 H14A 109.1 . . ?
N4 C14 H14B 109.1 . . ?
N4 C14 C13 112.7(4) . . ?
H14A C14 H14B 107.8 . . ?
C13 C14 H14A 109.1 . . ?
C13 C14 H14B 109.1 . . ?
Si5 C48 H48A 109.5 . . ?
Si5 C48 H48B 109.5 . . ?
Si5 C48 H48C 109.5 . . ?
H48A C48 H48B 109.5 . . ?
H48A C48 H48C 109.5 . . ?
H48B C48 H48C 109.5 . . ?
Si2 C33 H33A 109.5 . . ?
Si2 C33 H33B 109.5 . . ?
Si2 C33 H33C 109.5 . . ?
H33A C33 H33B 109.5 . . ?
H33A C33 H33C 109.5 . . ?
H33B C33 H33C 109.5 . . ?
C20 C19 H19 119.9 . . ?
C20 C19 C18 120.2(5) . . ?
C18 C19 H19 119.9 . . ?
C64 C65 N7 121.3(4) . . ?
C60 C65 N7 120.8(4) . . ?
C60 C65 C64 117.8(4) . . ?
Si3 C5 H5A 109.5 . . ?
Si3 C5 H5B 109.5 . . ?
Si3 C5 H5C 109.5 . . ?
H5A C5 H5B 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
C64 C63 C62 120.5(5) . . ?
C64 C63 H63 119.8 . . ?
C62 C63 H63 119.8 . . ?
C24 C23 C22 120.2(4) . . ?
C28 C23 C24 120.1(4) . . ?
C28 C23 C22 119.7(4) . . ?
C8 C13 C14 119.1(4) . . ?
C12 C13 C8 120.0(4) . . ?
C12 C13 C14 120.9(4) . . ?
Si2 C34 H34A 109.5 . . ?
Si2 C34 H34B 109.5 . . ?
Si2 C34 H34C 109.5 . . ?
H34A C34 H34B 109.5 . . ?
H34A C34 H34C 109.5 . . ?
H34B C34 H34C 109.5 . . ?
C65 C60 C59 120.2(4) . . ?
C65 C60 C61 119.4(5) . . ?
C61 C60 C59 120.3(5) . . ?
N8 C58 H58A 108.9 . . ?
N8 C58 H58B 108.9 . . ?
C57 C58 N8 113.3(4) . . ?
C57 C58 H58A 108.9 . . ?
C57 C58 H58B 108.9 . . ?
H58A C58 H58B 107.7 . . ?
C10 C11 C12 119.7(5) . . ?
C10 C11 H11 120.2 . . ?
C12 C11 H11 120.2 . . ?
C57 C52 N5 120.2(5) . . ?
C53 C52 N5 122.5(5) . . ?
C53 C52 C57 117.2(5) . . ?
O1 C4 H4A 110.8 . . ?
O1 C4 H4B 110.8 . . ?
O1 C4 C3 104.9(4) . . ?
H4A C4 H4B 108.9 . . ?
C3 C4 H4A 110.8 . . ?
C3 C4 H4B 110.8 . . ?
Si1 C30 H30A 109.5 . . ?
Si1 C30 H30B 109.5 . . ?
Si1 C30 H30C 109.5 . . ?
H30A C30 H30B 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
C41 C40 C39 120.9(5) . . ?
C41 C40 C45 119.6(5) . . ?
C45 C40 C39 119.5(4) . . ?
C17 C18 H18 120.5 . . ?
C19 C18 C17 119.1(5) . . ?
C19 C18 H18 120.5 . . ?
Si5 C47 H47A 109.5 . . ?
Si5 C47 H47B 109.5 . . ?
Si5 C47 H47C 109.5 . . ?
H47A C47 H47B 109.5 . . ?
H47A C47 H47C 109.5 . . ?
H47B C47 H47C 109.5 . . ?
C62 C61 C60 121.2(5) . . ?
C62 C61 H61 119.4 . . ?
C60 C61 H61 119.4 . . ?
Si6 C66 H66A 109.5 . . ?
Si6 C66 H66B 109.5 . . ?
Si6 C66 H66C 109.5 . . ?
H66A C66 H66B 109.5 . . ?
H66A C66 H66C 109.5 . . ?
H66B C66 H66C 109.5 . . ?
Si3 C6 H6A 109.5 . . ?
Si3 C6 H6B 109.5 . . ?
Si3 C6 H6C 109.5 . . ?
H6A C6 H6B 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
C26 C27 H27 120.7 . . ?
C26 C27 C28 118.6(5) . . ?
C28 C27 H27 120.7 . . ?
C40 C41 H41 118.9 . . ?
C42 C41 C40 122.2(6) . . ?
C42 C41 H41 118.9 . . ?
Si3 C7 H7A 109.5 . . ?
Si3 C7 H7B 109.5 . . ?
Si3 C7 H7C 109.5 . . ?
H7A C7 H7B 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
Si1 C29 H29A 109.5 . . ?
Si1 C29 H29B 109.5 . . ?
Si1 C29 H29C 109.5 . . ?
H29A C29 H29B 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
C25 C26 H26 119.3 . . ?
C27 C26 C25 121.4(5) . . ?
C27 C26 H26 119.3 . . ?
C53 C54 H54 119.7 . . ?
C55 C54 H54 119.7 . . ?
C55 C54 C53 120.6(5) . . ?
C52 C53 H53 119.0 . . ?
C54 C53 C52 122.0(5) . . ?
C54 C53 H53 119.0 . . ?
C44 C43 H43 120.4 . . ?
C42 C43 H43 120.4 . . ?
C42 C43 C44 119.2(6) . . ?
C23 C28 H28 119.2 . . ?
C27 C28 C23 121.6(5) . . ?
C27 C28 H28 119.2 . . ?
C43 C44 H44 118.7 . . ?
C43 C44 C45 122.7(6) . . ?
C45 C44 H44 118.7 . . ?
N8 C39 C40 112.9(4) . . ?
N8 C39 H39A 109.0 . . ?
N8 C39 H39B 109.0 . . ?
C40 C39 H39A 109.0 . . ?
C40 C39 H39B 109.0 . . ?
H39A C39 H39B 107.8 . . ?
C57 C56 H56 119.2 . . ?
C55 C56 C57 121.5(5) . . ?
C55 C56 H56 119.2 . . ?
C41 C42 H42 120.3 . . ?
C43 C42 C41 119.4(5) . . ?
C43 C42 H42 120.3 . . ?
O2 C35 H35A 110.7 . . ?
O2 C35 H35B 110.7 . . ?
O2 C35 C36 105.3(5) . . ?
H35A C35 H35B 108.8 . . ?
C36 C35 H35A 110.7 . . ?
C36 C35 H35B 110.7 . . ?
Si6 C68 H68A 109.5 . . ?
Si6 C68 H68B 109.5 . . ?
Si6 C68 H68C 109.5 . . ?
H68A C68 H68B 109.5 . . ?
H68A C68 H68C 109.5 . . ?
H68B C68 H68C 109.5 . . ?
O1 C1 H1A 110.5 . . ?
O1 C1 H1B 110.5 . . ?
O1 C1 C2 105.9(5) . . ?
H1A C1 H1B 108.7 . . ?
C2 C1 H1A 110.5 . . ?
C2 C1 H1B 110.5 . . ?
Si1 C31 H31A 109.5 . . ?
Si1 C31 H31B 109.5 . . ?
Si1 C31 H31C 109.5 . . ?
H31A C31 H31B 109.5 . . ?
H31A C31 H31C 109.5 . . ?
H31B C31 H31C 109.5 . . ?
N6 C45 Dy2 44.7(2) . . ?
N6 C45 C40 120.8(4) . . ?
C40 C45 Dy2 95.3(3) . . ?
C44 C45 Dy2 127.4(4) . . ?
C44 C45 N6 122.0(5) . . ?
C44 C45 C40 117.1(5) . . ?
C54 C55 C56 118.9(5) . . ?
C54 C55 H55 120.5 . . ?
C56 C55 H55 120.5 . . ?
Si5 C46 H46A 109.5 . . ?
Si5 C46 H46B 109.5 . . ?
Si5 C46 H46C 109.5 . . ?
H46A C46 H46B 109.5 . . ?
H46A C46 H46C 109.5 . . ?
H46B C46 H46C 109.5 . . ?
Si2 C32 H32A 109.5 . . ?
Si2 C32 H32B 109.5 . . ?
Si2 C32 H32C 109.5 . . ?
H32A C32 H32B 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
O2 C38 H38A 110.0 . . ?
O2 C38 H38B 110.0 . . ?
O2 C38 C37 108.5(5) . . ?
H38A C38 H38B 108.4 . . ?
C37 C38 H38A 110.0 . . ?
C37 C38 H38B 110.0 . . ?
C35 C36 H36A 111.0 . . ?
C35 C36 H36B 111.0 . . ?
H36A C36 H36B 109.0 . . ?
C37 C36 C35 103.6(5) . . ?
C37 C36 H36A 111.0 . . ?
C37 C36 H36B 111.0 . . ?
C38 C37 H37A 111.0 . . ?
C38 C37 H37B 111.0 . . ?
C36 C37 C38 103.6(5) . . ?
C36 C37 H37A 111.0 . . ?
C36 C37 H37B 111.0 . . ?
H37A C37 H37B 109.0 . . ?
C1 C2 H2A 110.4 . . ?
C1 C2 H2B 110.4 . . ?
H2A C2 H2B 108.6 . . ?
C3 C2 C1 106.6(5) . . ?
C3 C2 H2A 110.4 . . ?
C3 C2 H2B 110.4 . . ?
C4 C3 H3A 110.8 . . ?
C4 C3 H3B 110.8 . . ?
C2 C3 C4 104.5(5) . . ?
C2 C3 H3A 110.8 . . ?
C2 C3 H3B 110.8 . . ?
H3A C3 H3B 108.9 . . ?
Si4 C49 H49A 109.5 . . ?
Si4 C49 H49B 109.5 . . ?
Si4 C49 H49C 109.5 . . ?
H49A C49 H49B 109.5 . . ?
H49A C49 H49C 109.5 . . ?
H49B C49 H49C 109.5 . . ?
Si4 C51 H51A 109.5 . . ?
Si4 C51 H51B 109.5 . . ?
Si4 C51 H51C 109.5 . . ?
H51A C51 H51B 109.5 . . ?
H51A C51 H51C 109.5 . . ?
H51B C51 H51C 109.5 . . ?
Si4 C50 H50A 109.5 . . ?
Si4 C50 H50B 109.5 . . ?
Si4 C50 H50C 109.5 . . ?
H50A C50 H50B 109.5 . . ?
H50A C50 H50C 109.5 . . ?
H50B C50 H50C 109.5 . . ?
Si4 C69 H69A 109.5 . . ?
Si4 C69 H69B 109.5 . . ?
Si4 C69 H69C 109.5 . . ?
H69A C69 H69B 109.5 . . ?
H69A C69 H69C 109.5 . . ?
H69B C69 H69C 109.5 . . ?
Si4 C71 H71A 109.5 . . ?
Si4 C71 H71B 109.5 . . ?
Si4 C71 H71C 109.5 . . ?
H71A C71 H71B 109.5 . . ?
H71A C71 H71C 109.5 . . ?
H71B C71 H71C 109.5 . . ?
Si4 C70 H70A 109.5 . . ?
Si4 C70 H70B 109.5 . . ?
Si4 C70 H70C 109.5 . . ?
H70A C70 H70B 109.5 . . ?
H70A C70 H70C 109.5 . . ?
H70B C70 H70C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Dy1 O1 C4 C3 151.2(4) . . . . ?
Dy1 O1 C1 C2 -168.7(4) . . . . ?
Dy1 N4 C22 C23 50.2(4) . . . . ?
Dy1 N4 C15 C16 55.2(5) . . . . ?
Dy1 N4 C14 C13 50.1(4) . . . . ?
Dy1 C8 N3 Si3 -173.8(4) . . . . ?
Dy1 C8 C9 C10 120.5(4) . . . . ?
Dy1 C8 C13 C12 -134.7(4) . . . . ?
Dy1 C8 C13 C14 44.4(4) . . . . ?
Dy1 N2 C21 C16 59.8(5) . . . . ?
Dy1 N2 C21 C20 -120.3(4) . . . . ?
Dy2 N8 C59 C60 51.0(4) . . . . ?
Dy2 N8 C58 C57 55.2(5) . . . . ?
Dy2 N8 C39 C40 49.6(5) . . . . ?
Dy2 O2 C35 C36 148.8(4) . . . . ?
Dy2 O2 C38 C37 -169.0(4) . . . . ?
Dy2 N7 C65 C64 -115.9(4) . . . . ?
Dy2 N7 C65 C60 62.2(5) . . . . ?
Dy2 N5 C52 C57 62.1(5) . . . . ?
Dy2 N5 C52 C53 -115.9(4) . . . . ?
Dy2 N6 C45 C40 63.2(5) . . . . ?
Dy2 N6 C45 C44 -112.8(5) . . . . ?
Si6 N7 C65 C64 72.6(5) . . . . ?
Si6 N7 C65 C60 -109.3(4) . . . . ?
Si2 N2 C21 C16 -133.3(4) . . . . ?
Si2 N2 C21 C20 46.6(6) . . . . ?
Si5 N6 C45 Dy2 -172.1(4) . . . . ?
Si5 N6 C45 C40 -108.8(5) . . . . ?
Si5 N6 C45 C44 75.2(6) . . . . ?
Si4 N5 C52 C57 -117.5(4) . . . . ?
Si4 N5 C52 C53 64.5(6) . . . . ?
O1 C4 C3 C2 31.1(7) . . . . ?
O1 C1 C2 C3 16.1(8) . . . . ?
N4 C22 C23 C24 -72.4(5) . . . . ?
N4 C22 C23 C28 110.7(5) . . . . ?
N4 C15 C16 C21 -73.9(6) . . . . ?
N4 C15 C16 C17 110.1(5) . . . . ?
N4 C14 C13 C8 -72.8(5) . . . . ?
N4 C14 C13 C12 106.3(5) . . . . ?
N8 C59 C60 C65 -71.3(6) . . . . ?
N8 C59 C60 C61 111.9(5) . . . . ?
O2 C35 C36 C37 34.6(6) . . . . ?
O2 C38 C37 C36 18.1(7) . . . . ?
N7 C65 C60 C59 5.1(7) . . . . ?
N7 C65 C60 C61 -178.2(4) . . . . ?
C59 N8 C58 C57 -65.8(5) . . . . ?
C59 N8 C39 C40 171.5(4) . . . . ?
C59 C60 C61 C62 177.1(5) . . . . ?
C24 C25 C26 C27 -0.9(8) . . . . ?
C24 C23 C28 C27 -0.1(7) . . . . ?
N1 C24 C25 C26 176.3(4) . . . . ?
N1 C24 C23 C22 7.4(6) . . . . ?
N1 C24 C23 C28 -175.8(4) . . . . ?
N5 C52 C53 C54 178.2(5) . . . . ?
C8 C9 C10 C11 -0.4(7) . . . . ?
N3 C8 C9 C10 175.8(4) . . . . ?
N3 C8 C13 C12 -175.1(4) . . . . ?
N3 C8 C13 C14 4.0(6) . . . . ?
C22 N4 C15 C16 -65.6(5) . . . . ?
C22 N4 C14 C13 172.2(4) . . . . ?
C22 C23 C28 C27 176.7(4) . . . . ?
C15 N4 C22 C23 169.8(4) . . . . ?
C15 N4 C14 C13 -69.4(5) . . . . ?
C15 C16 C17 C18 174.9(5) . . . . ?
N2 C21 C16 C15 5.1(7) . . . . ?
N2 C21 C16 C17 -178.9(4) . . . . ?
N2 C21 C20 C19 179.9(4) . . . . ?
C9 C8 N3 Dy1 -112.1(4) . . . . ?
C9 C8 N3 Si3 74.0(5) . . . . ?
C9 C8 C13 C12 2.1(6) . . . . ?
C9 C8 C13 C14 -178.8(4) . . . . ?
C9 C10 C11 C12 1.4(7) . . . . ?
C21 C16 C17 C18 -1.1(7) . . . . ?
C21 C20 C19 C18 -1.0(8) . . . . ?
C64 C65 C60 C59 -176.8(4) . . . . ?
C64 C65 C60 C61 0.0(7) . . . . ?
C16 C21 C20 C19 -0.1(7) . . . . ?
C16 C17 C18 C19 0.0(8) . . . . ?
C25 C24 N1 Dy1 -117.9(4) . . . . ?
C25 C24 N1 Si1 71.6(5) . . . . ?
C25 C24 C23 C22 -175.1(4) . . . . ?
C25 C24 C23 C28 1.7(6) . . . . ?
C57 C52 C53 C54 0.1(7) . . . . ?
C57 C56 C55 C54 -0.5(8) . . . . ?
C20 C21 C16 C15 -174.8(4) . . . . ?
C20 C21 C16 C17 1.1(7) . . . . ?
C20 C19 C18 C17 1.0(8) . . . . ?
C67 Si6 N7 Dy2 13.5(3) . . . . ?
C67 Si6 N7 C65 -176.5(3) . . . . ?
C14 N4 C22 C23 -71.5(5) . . . . ?
C14 N4 C15 C16 175.4(4) . . . . ?
C48 Si5 N6 Dy2 15.8(3) . . . . ?
C48 Si5 N6 C45 -174.1(4) . . . . ?
C33 Si2 N2 Dy1 -47.6(3) . . . . ?
C33 Si2 N2 C21 147.3(4) . . . . ?
C65 C64 C63 C62 -0.3(8) . . . . ?
C65 C60 C61 C62 0.4(7) . . . . ?
C5 Si3 N3 Dy1 14.6(3) . . . . ?
C5 Si3 N3 C8 -173.2(3) . . . . ?
C63 C64 C65 N7 178.2(4) . . . . ?
C63 C64 C65 C60 0.0(7) . . . . ?
C63 C62 C61 C60 -0.7(8) . . . . ?
C23 C24 N1 Dy1 59.5(5) . . . . ?
C23 C24 N1 Si1 -111.0(4) . . . . ?
C23 C24 C25 C26 -1.3(7) . . . . ?
C13 C8 N3 Dy1 64.9(4) . . . . ?
C13 C8 N3 Si3 -108.9(4) . . . . ?
C13 C8 C9 C10 -1.4(7) . . . . ?
C13 C12 C11 C10 -0.7(7) . . . . ?
C34 Si2 N2 Dy1 72.0(3) . . . . ?
C34 Si2 N2 C21 -93.1(4) . . . . ?
C58 N8 C59 C60 171.0(4) . . . . ?
C58 N8 C39 C40 -69.7(5) . . . . ?
C58 C57 C52 N5 3.9(7) . . . . ?
C58 C57 C52 C53 -177.9(4) . . . . ?
C58 C57 C56 C55 178.2(5) . . . . ?
C11 C12 C13 C8 -1.0(7) . . . . ?
C11 C12 C13 C14 179.9(4) . . . . ?
C52 C57 C58 N8 -73.7(6) . . . . ?
C52 C57 C56 C55 0.5(8) . . . . ?
C4 O1 C1 C2 3.8(6) . . . . ?
C30 Si1 N1 Dy1 16.0(3) . . . . ?
C30 Si1 N1 C24 -175.3(4) . . . . ?
C40 C41 C42 C43 -1.0(10) . . . . ?
C47 Si5 N6 Dy2 134.9(3) . . . . ?
C47 Si5 N6 C45 -55.0(4) . . . . ?
C61 C62 C63 C64 0.7(8) . . . . ?
C66 Si6 N7 Dy2 -105.8(3) . . . . ?
C66 Si6 N7 C65 64.2(4) . . . . ?
C6 Si3 N3 Dy1 133.1(3) . . . . ?
C6 Si3 N3 C8 -54.7(4) . . . . ?
C41 C40 C39 N8 108.1(6) . . . . ?
C41 C40 C45 Dy2 -136.2(5) . . . . ?
C41 C40 C45 N6 -175.3(5) . . . . ?
C41 C40 C45 C44 0.9(8) . . . . ?
C7 Si3 N3 Dy1 -103.9(3) . . . . ?
C7 Si3 N3 C8 68.3(4) . . . . ?
C29 Si1 N1 Dy1 -104.2(3) . . . . ?
C29 Si1 N1 C24 64.5(4) . . . . ?
C26 C27 C28 C23 -2.1(7) . . . . ?
C53 C54 C55 C56 0.4(8) . . . . ?
C43 C44 C45 Dy2 120.3(6) . . . . ?
C43 C44 C45 N6 175.0(5) . . . . ?
C43 C44 C45 C40 -1.2(8) . . . . ?
C28 C27 C26 C25 2.5(8) . . . . ?
C44 C43 C42 C41 0.7(10) . . . . ?
C39 N8 C59 C60 -70.2(5) . . . . ?
C39 N8 C58 C57 174.8(4) . . . . ?
C39 C40 C41 C42 178.3(5) . . . . ?
C39 C40 C45 Dy2 45.6(5) . . . . ?
C39 C40 C45 N6 6.5(7) . . . . ?
C39 C40 C45 C44 -177.3(5) . . . . ?
C56 C57 C58 N8 108.6(5) . . . . ?
C56 C57 C52 N5 -178.4(4) . . . . ?
C56 C57 C52 C53 -0.2(7) . . . . ?
C42 C43 C44 C45 0.4(9) . . . . ?
C35 O2 C38 C37 3.3(7) . . . . ?
C35 C36 C37 C38 -31.8(7) . . . . ?
C68 Si6 N7 Dy2 132.7(3) . . . . ?
C68 Si6 N7 C65 -57.3(4) . . . . ?
C1 O1 C4 C3 -21.4(6) . . . . ?
C1 C2 C3 C4 -29.0(8) . . . . ?
C31 Si1 N1 Dy1 135.7(3) . . . . ?
C31 Si1 N1 C24 -55.6(4) . . . . ?
C45 C40 C41 C42 0.2(9) . . . . ?
C45 C40 C39 N8 -73.8(6) . . . . ?
C55 C54 C53 C52 -0.2(8) . . . . ?
C46 Si5 N6 Dy2 -104.8(3) . . . . ?
C46 Si5 N6 C45 65.3(4) . . . . ?
C32 Si2 N2 Dy1 -164.7(3) . . . . ?
C32 Si2 N2 C21 30.2(4) . . . . ?
C38 O2 C35 C36 -23.6(6) . . . . ?
C49 Si4 N5 Dy2 126.8(6) . . . . ?
C49 Si4 N5 C52 -53.6(7) . . . . ?
C51 Si4 N5 Dy2 -111.1(6) . . . . ?
C51 Si4 N5 C52 68.4(7) . . . . ?
C50 Si4 N5 Dy2 4.1(6) . . . . ?
C50 Si4 N5 C52 -176.4(6) . . . . ?
C69 Si4 N5 Dy2 83.4(7) . . . . ?
C69 Si4 N5 C52 -97.0(8) . . . . ?
C71 Si4 N5 Dy2 -153.3(7) . . . . ?
C71 Si4 N5 C52 26.2(8) . . . . ?
C70 Si4 N5 Dy2 -32.2(7) . . . . ?
C70 Si4 N5 C52 147.4(7) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
loop_
_twin_individual_id
_twin_individual_mass_fraction_refined
1 0.876(5)
2 0.124(5)
# start Validation Reply Form
_vrf_PLAT058_mo_yu1_0m           
;
PROBLEM: Maximum Transmission Factor Missing ............          ?       
RESPONSE:Solved as a twin with treated disorder.
;
_vrf_PLAT059_mo_yu1_0m           
;
PROBLEM: Minimum Transmission Factor Missing ............          ?       
RESPONSE: Solved as a twin with treated disorder.
;
# end Validation Reply Form
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_trapentmsdy_pridine_0m_c
_database_code_depnum_ccdc_archive 'CCDC 2210771'
loop_
_audit_author_name
_audit_author_address
'Kang Liu'
;institute of high energy physics
China
;
_audit_update_record             
;
2022-10-03 deposited with the CCDC.	2023-01-18 downloaded from the CCDC.
;
_audit_creation_date             2022-07-07
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6272)
;
_shelxl_version_number           2014-3
_chemical_name_common            ?
_chemical_name_systematic        
;
 ?
;
_chemical_formula_moiety         'C35 H50 Dy N5 Si3'
_chemical_formula_sum            'C35 H50 Dy N5 Si3'
_chemical_formula_weight         787.57
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -9.8046 9.8477 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.2541 0.3302 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   15.7628(5)
_cell_length_b                   12.1123(4)
_cell_length_c                   19.7909(7)
_cell_angle_alpha                90
_cell_angle_beta                 91.746(2)
_cell_angle_gamma                90
_cell_volume                     3776.8(2)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9960
_cell_measurement_temperature    170.0
_cell_measurement_theta_max      68.28
_cell_measurement_theta_min      5.16
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    11.719
_exptl_absorpt_correction_T_max  0.7531
_exptl_absorpt_correction_T_min  0.6415
_exptl_absorpt_correction_type   none
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.0714 before and 0.0544 after correction.
The Ratio of minimum to maximum transmission is 0.8518.
The λ/2 correction factor is Not present.
;
_exptl_crystal_colour            'clear whiteish white'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   whiteish
_exptl_crystal_colour_primary    white
_exptl_crystal_density_diffrn    1.385
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1612
_exptl_crystal_size_max          ?
_exptl_crystal_size_mid          ?
_exptl_crystal_size_min          ?
_exptl_special_details           
;
 ?
;
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0470
_diffrn_reflns_av_unetI/netI     0.0314
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            40780
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        67.679
_diffrn_reflns_theta_max         68.440
_diffrn_reflns_theta_min         2.805
_diffrn_ambient_temperature      170.0
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_source                   ?
_diffrn_source_current           0.95
_diffrn_source_power             0.0475
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                5839
_reflns_number_total             6905
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.38A (Bruker, 2018)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.38A (Bruker, 2018)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL  (Sheldrick, 2008)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_refine_diff_density_max         0.730
_refine_diff_density_min         -0.686
_refine_diff_density_rms         0.063
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.025
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     406
_refine_ls_number_reflns         6905
_refine_ls_number_restraints     24
_refine_ls_R_factor_all          0.0394
_refine_ls_R_factor_gt           0.0291
_refine_ls_restrained_S_all      1.126
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0300P)²+3.9429P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0665
_refine_ls_wR_factor_ref         0.0716
_refine_special_details          
;
 ?
;
_olex2_refinement_description    
;
1. Uiso/Uaniso restraints and constraints
C31 \\sim C32 \\sim C33 \\sim C34 \\sim C35: within 2A with sigma of 0.002 and
sigma for terminal atoms of 0.004 within 2A
2.a Secondary CH2 refined with riding coordinates:
 C11(H11A,H11B), C21(H21A,H21B), C1(H1A,H1B)
2.b Aromatic/amide H refined with riding coordinates:
 C4(H4), C14(H14), C17(H17), C26(H26), C15(H15), C23(H23), C5(H5), C31(H31),
 C25(H25), C6(H6), C7(H7), C16(H16), C24(H24), C32(H32), C33(H33), C34(H34),
 C35(H35)
2.c Idealised Me refined as rotating group:
 C18(H18A,H18B,H18C), C9(H9A,H9B,H9C), C8(H8A,H8B,H8C), C20(H20A,H20B,H20C),
 C29(H29A,H29B,H29C), C28(H28A,H28B,H28C), C10(H10A,H10B,H10C), C30(H30A,H30B,
 H30C), C19(H19A,H19B,H19C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.26860(2) 0.26910(2) 0.32295(2) 0.02479(6) Uani 1 1 d . . . . .
Si1 Si 0.21720(6) 0.54597(8) 0.38664(5) 0.0335(2) Uani 1 1 d . . . . .
Si2 Si 0.21994(6) 0.03368(7) 0.42496(5) 0.0336(2) Uani 1 1 d . . . . .
Si3 Si 0.40338(6) 0.23638(8) 0.17967(5) 0.0343(2) Uani 1 1 d . . . . .
N3 N 0.32655(16) 0.3051(2) 0.22268(13) 0.0291(6) Uani 1 1 d . . . . .
N4 N 0.13397(15) 0.2517(2) 0.25371(13) 0.0271(6) Uani 1 1 d . . . . .
N1 N 0.20126(16) 0.4069(2) 0.37640(14) 0.0320(6) Uani 1 1 d . . . . .
N2 N 0.24205(16) 0.0923(2) 0.34845(13) 0.0294(6) Uani 1 1 d . . . . .
N5 N 0.41020(18) 0.2684(3) 0.38685(17) 0.0439(7) Uani 1 1 d . . . . .
C3 C 0.2309(2) 0.0279(3) 0.28914(16) 0.0316(7) Uani 1 1 d . . . . .
C13 C 0.2832(2) 0.3939(3) 0.19075(16) 0.0294(7) Uani 1 1 d . . . . .
C12 C 0.1959(2) 0.3866(3) 0.17333(16) 0.0315(7) Uani 1 1 d . . . . .
C11 C 0.1498(2) 0.2796(3) 0.18180(16) 0.0335(7) Uani 1 1 d . . . . .
H11A H 0.0947 0.2834 0.1565 0.040 Uiso 1 1 calc R U . . .
H11B H 0.1835 0.2195 0.1618 0.040 Uiso 1 1 calc R U . . .
C21 C 0.07087(19) 0.3304(3) 0.28091(17) 0.0337(8) Uani 1 1 d . . . . .
H21A H 0.0150 0.3170 0.2581 0.040 Uiso 1 1 calc R U . . .
H21B H 0.0884 0.4067 0.2700 0.040 Uiso 1 1 calc R U . . .
C4 C 0.2870(2) -0.0582(3) 0.27462(19) 0.0425(9) Uani 1 1 d . . . . .
H4 H 0.3328 -0.0739 0.3054 0.051 Uiso 1 1 calc R U . . .
C22 C 0.06130(19) 0.3209(3) 0.35629(17) 0.0332(7) Uani 1 1 d . . . . .
C2 C 0.1640(2) 0.0495(3) 0.24212(17) 0.0352(8) Uani 1 1 d . . . . .
C1 C 0.0999(2) 0.1370(3) 0.25745(18) 0.0349(8) Uani 1 1 d . . . . .
H1A H 0.0511 0.1299 0.2251 0.042 Uiso 1 1 calc R U . . .
H1B H 0.0788 0.1242 0.3034 0.042 Uiso 1 1 calc R U . . .
C14 C 0.3245(2) 0.4945(3) 0.17754(17) 0.0403(8) Uani 1 1 d . . . . .
H14 H 0.3832 0.5020 0.1889 0.048 Uiso 1 1 calc R U . . .
C17 C 0.1537(2) 0.4782(3) 0.14477(18) 0.0461(10) Uani 1 1 d . . . . .
H17 H 0.0947 0.4736 0.1341 0.055 Uiso 1 1 calc R U . . .
C27 C 0.1248(2) 0.3628(3) 0.40110(17) 0.0328(7) Uani 1 1 d . . . . .
C26 C 0.1098(2) 0.3560(3) 0.47066(18) 0.0411(8) Uani 1 1 d . . . . .
H26 H 0.1519 0.3824 0.5020 0.049 Uiso 1 1 calc R U . . .
C18 C 0.3557(3) 0.1519(3) 0.1091(2) 0.0515(10) Uani 1 1 d . . . . .
H18A H 0.3228 0.0911 0.1279 0.077 Uiso 1 1 calc R U . . .
H18B H 0.4010 0.1219 0.0817 0.077 Uiso 1 1 calc R U . . .
H18C H 0.3183 0.1985 0.0808 0.077 Uiso 1 1 calc R U . . .
C15 C 0.2810(3) 0.5828(3) 0.1482(2) 0.0521(11) Uani 1 1 d . . . . .
H15 H 0.3103 0.6495 0.1393 0.063 Uiso 1 1 calc R U . . .
C23 C -0.0124(2) 0.2756(3) 0.3816(2) 0.0429(9) Uani 1 1 d . . . . .
H23 H -0.0545 0.2468 0.3511 0.052 Uiso 1 1 calc R U . . .
C9 C 0.2483(3) 0.1371(3) 0.49189(18) 0.0495(10) Uani 1 1 d . . . . .
H9A H 0.3015 0.1151 0.5151 0.074 Uiso 1 1 calc R U . . .
H9B H 0.2029 0.1406 0.5246 0.074 Uiso 1 1 calc R U . . .
H9C H 0.2554 0.2098 0.4711 0.074 Uiso 1 1 calc R U . . .
C5 C 0.2771(3) -0.1211(3) 0.2161(2) 0.0543(11) Uani 1 1 d . . . . .
H5 H 0.3155 -0.1795 0.2076 0.065 Uiso 1 1 calc R U . . .
C31 C 0.4432(3) 0.1776(4) 0.4144(2) 0.0658(10) Uani 1 1 d . U . . .
H31 H 0.4109 0.1115 0.4116 0.079 Uiso 1 1 calc R U . . .
C25 C 0.0356(3) 0.3120(3) 0.4947(2) 0.0517(10) Uani 1 1 d . . . . .
H25 H 0.0269 0.3096 0.5419 0.062 Uiso 1 1 calc R U . . .
C8 C 0.1056(2) -0.0058(4) 0.4294(2) 0.0592(11) Uani 1 1 d . . . . .
H8A H 0.0701 0.0602 0.4240 0.089 Uiso 1 1 calc R U . . .
H8B H 0.0955 -0.0399 0.4734 0.089 Uiso 1 1 calc R U . . .
H8C H 0.0912 -0.0585 0.3933 0.089 Uiso 1 1 calc R U . . .
C6 C 0.2120(3) -0.0988(3) 0.1707(2) 0.0544(11) Uani 1 1 d . . . . .
H6 H 0.2054 -0.1414 0.1306 0.065 Uiso 1 1 calc R U . . .
C20 C 0.4607(2) 0.1402(4) 0.2389(2) 0.0555(11) Uani 1 1 d . . . . .
H20A H 0.4978 0.1827 0.2698 0.083 Uiso 1 1 calc R U . . .
H20B H 0.4950 0.0887 0.2130 0.083 Uiso 1 1 calc R U . . .
H20C H 0.4195 0.0988 0.2649 0.083 Uiso 1 1 calc R U . . .
C7 C 0.1562(3) -0.0143(3) 0.18359(19) 0.0456(9) Uani 1 1 d . . . . .
H7 H 0.1113 0.0009 0.1518 0.055 Uiso 1 1 calc R U . . .
C16 C 0.1967(3) 0.5748(3) 0.1319(2) 0.0566(12) Uani 1 1 d . . . . .
H16 H 0.1676 0.6356 0.1118 0.068 Uiso 1 1 calc R U . . .
C29 C 0.2201(3) 0.5911(3) 0.4773(2) 0.0532(10) Uani 1 1 d . . . . .
H29A H 0.1648 0.5774 0.4969 0.080 Uiso 1 1 calc R U . . .
H29B H 0.2333 0.6700 0.4799 0.080 Uiso 1 1 calc R U . . .
H29C H 0.2639 0.5492 0.5025 0.080 Uiso 1 1 calc R U . . .
C24 C -0.0256(2) 0.2718(3) 0.4502(2) 0.0496(10) Uani 1 1 d . . . . .
H24 H -0.0766 0.2415 0.4666 0.060 Uiso 1 1 calc R U . . .
C28 C 0.1310(3) 0.6265(3) 0.3425(3) 0.0641(13) Uani 1 1 d . . . . .
H28A H 0.1342 0.6155 0.2935 0.096 Uiso 1 1 calc R U . . .
H28B H 0.1379 0.7051 0.3530 0.096 Uiso 1 1 calc R U . . .
H28C H 0.0757 0.6010 0.3576 0.096 Uiso 1 1 calc R U . . .
C10 C 0.2825(3) -0.0942(3) 0.4436(2) 0.0531(10) Uani 1 1 d . . . . .
H10A H 0.2665 -0.1516 0.4107 0.080 Uiso 1 1 calc R U . . .
H10B H 0.2706 -0.1202 0.4893 0.080 Uiso 1 1 calc R U . . .
H10C H 0.3432 -0.0781 0.4406 0.080 Uiso 1 1 calc R U . . .
C30 C 0.3205(2) 0.5869(3) 0.3509(2) 0.0549(11) Uani 1 1 d . . . . .
H30A H 0.3666 0.5710 0.3838 0.082 Uiso 1 1 calc R U . . .
H30B H 0.3198 0.6661 0.3407 0.082 Uiso 1 1 calc R U . . .
H30C H 0.3296 0.5452 0.3093 0.082 Uiso 1 1 calc R U . . .
C19 C 0.4839(3) 0.3286(4) 0.1420(2) 0.0603(12) Uani 1 1 d . . . . .
H19A H 0.4564 0.3748 0.1071 0.090 Uiso 1 1 calc R U . . .
H19B H 0.5282 0.2837 0.1217 0.090 Uiso 1 1 calc R U . . .
H19C H 0.5094 0.3757 0.1773 0.090 Uiso 1 1 calc R U . . .
C32 C 0.5216(3) 0.1739(4) 0.4468(3) 0.0713(9) Uani 1 1 d . U . . .
H32 H 0.5432 0.1061 0.4642 0.086 Uiso 1 1 calc R U . . .
C33 C 0.5664(3) 0.2654(4) 0.4534(3) 0.0805(10) Uani 1 1 d . U . . .
H33 H 0.6171 0.2670 0.4806 0.097 Uiso 1 1 calc R U . . .
C34 C 0.5389(3) 0.3552(5) 0.4212(4) 0.1047(11) Uani 1 1 d . U . . .
H34 H 0.5735 0.4193 0.4197 0.126 Uiso 1 1 calc R U . . .
C35 C 0.4581(3) 0.3544(5) 0.3892(4) 0.1056(13) Uani 1 1 d . U . . .
H35 H 0.4379 0.4204 0.3683 0.127 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 N3 2.253(3) . ?
Dy1 N4 2.500(2) . ?
Dy1 N1 2.258(3) . ?
Dy1 N2 2.242(3) . ?
Dy1 N5 2.532(3) . ?
Dy1 C27 3.005(3) . ?
Si1 N1 1.715(3) . ?
Si1 C29 1.875(4) . ?
Si1 C28 1.868(4) . ?
Si1 C30 1.862(4) . ?
Si2 N2 1.718(3) . ?
Si2 C9 1.868(4) . ?
Si2 C8 1.870(4) . ?
Si2 C10 1.867(4) . ?
Si3 N3 1.717(3) . ?
Si3 C18 1.870(4) . ?
Si3 C20 1.866(4) . ?
Si3 C19 1.863(4) . ?
N3 C13 1.412(4) . ?
N4 C11 1.491(4) . ?
N4 C21 1.491(4) . ?
N4 C1 1.491(4) . ?
N1 C27 1.419(4) . ?
N2 C3 1.416(4) . ?
N5 C31 1.326(5) . ?
N5 C35 1.287(6) . ?
C3 C4 1.403(5) . ?
C3 C2 1.409(5) . ?
C13 C12 1.411(4) . ?
C13 C14 1.410(5) . ?
C12 C11 1.499(5) . ?
C12 C17 1.403(5) . ?
C11 H11A 0.9900 . ?
C11 H11B 0.9900 . ?
C21 H21A 0.9900 . ?
C21 H21B 0.9900 . ?
C21 C22 1.508(5) . ?
C4 H4 0.9500 . ?
C4 C5 1.391(5) . ?
C22 C27 1.411(5) . ?
C22 C23 1.393(5) . ?
C2 C1 1.502(5) . ?
C2 C7 1.394(5) . ?
C1 H1A 0.9900 . ?
C1 H1B 0.9900 . ?
C14 H14 0.9500 . ?
C14 C15 1.389(5) . ?
C17 H17 0.9500 . ?
C17 C16 1.380(6) . ?
C27 C26 1.406(5) . ?
C26 H26 0.9500 . ?
C26 C25 1.383(5) . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C15 H15 0.9500 . ?
C15 C16 1.360(6) . ?
C23 H23 0.9500 . ?
C23 C24 1.379(5) . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
C5 H5 0.9500 . ?
C5 C6 1.370(6) . ?
C31 H31 0.9500 . ?
C31 C32 1.375(5) . ?
C25 H25 0.9500 . ?
C25 C24 1.375(6) . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C6 H6 0.9500 . ?
C6 C7 1.379(6) . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C7 H7 0.9500 . ?
C16 H16 0.9500 . ?
C29 H29A 0.9800 . ?
C29 H29B 0.9800 . ?
C29 H29C 0.9800 . ?
C24 H24 0.9500 . ?
C28 H28A 0.9800 . ?
C28 H28B 0.9800 . ?
C28 H28C 0.9800 . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C30 H30A 0.9800 . ?
C30 H30B 0.9800 . ?
C30 H30C 0.9800 . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C32 H32 0.9500 . ?
C32 C33 1.318(6) . ?
C33 H33 0.9500 . ?
C33 C34 1.327(7) . ?
C34 H34 0.9500 . ?
C34 C35 1.405(6) . ?
C35 H35 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N3 Dy1 N4 83.90(9) . . ?
N3 Dy1 N1 118.59(10) . . ?
N3 Dy1 N5 93.77(10) . . ?
N3 Dy1 C27 135.46(9) . . ?
N4 Dy1 N5 173.91(9) . . ?
N4 Dy1 C27 70.92(9) . . ?
N1 Dy1 N4 85.18(9) . . ?
N1 Dy1 N5 100.86(10) . . ?
N1 Dy1 C27 26.77(9) . . ?
N2 Dy1 N3 117.83(9) . . ?
N2 Dy1 N4 83.20(9) . . ?
N2 Dy1 N1 120.44(10) . . ?
N2 Dy1 N5 92.98(10) . . ?
N2 Dy1 C27 95.50(9) . . ?
N5 Dy1 C27 114.31(10) . . ?
N1 Si1 C29 113.49(17) . . ?
N1 Si1 C28 110.85(17) . . ?
N1 Si1 C30 110.09(16) . . ?
C28 Si1 C29 107.0(2) . . ?
C30 Si1 C29 106.82(19) . . ?
C30 Si1 C28 108.4(2) . . ?
N2 Si2 C9 107.29(15) . . ?
N2 Si2 C8 111.68(16) . . ?
N2 Si2 C10 113.40(16) . . ?
C9 Si2 C8 110.4(2) . . ?
C10 Si2 C9 107.62(19) . . ?
C10 Si2 C8 106.4(2) . . ?
N3 Si3 C18 111.23(16) . . ?
N3 Si3 C20 109.09(16) . . ?
N3 Si3 C19 114.02(17) . . ?
C20 Si3 C18 107.66(19) . . ?
C19 Si3 C18 107.0(2) . . ?
C19 Si3 C20 107.6(2) . . ?
Si3 N3 Dy1 130.84(14) . . ?
C13 N3 Dy1 109.75(19) . . ?
C13 N3 Si3 119.1(2) . . ?
C11 N4 Dy1 109.88(17) . . ?
C11 N4 C1 109.2(2) . . ?
C21 N4 Dy1 108.21(18) . . ?
C21 N4 C11 109.4(2) . . ?
C21 N4 C1 109.5(2) . . ?
C1 N4 Dy1 110.61(18) . . ?
Si1 N1 Dy1 135.42(14) . . ?
C27 N1 Dy1 107.4(2) . . ?
C27 N1 Si1 116.9(2) . . ?
Si2 N2 Dy1 129.61(14) . . ?
C3 N2 Dy1 111.05(19) . . ?
C3 N2 Si2 118.6(2) . . ?
C31 N5 Dy1 122.5(3) . . ?
C35 N5 Dy1 121.5(3) . . ?
C35 N5 C31 115.7(4) . . ?
C4 C3 N2 121.1(3) . . ?
C4 C3 C2 117.8(3) . . ?
C2 C3 N2 121.1(3) . . ?
C12 C13 N3 121.1(3) . . ?
C14 C13 N3 121.4(3) . . ?
C14 C13 C12 117.4(3) . . ?
C13 C12 C11 119.9(3) . . ?
C17 C12 C13 119.7(3) . . ?
C17 C12 C11 120.3(3) . . ?
N4 C11 C12 113.5(3) . . ?
N4 C11 H11A 108.9 . . ?
N4 C11 H11B 108.9 . . ?
C12 C11 H11A 108.9 . . ?
C12 C11 H11B 108.9 . . ?
H11A C11 H11B 107.7 . . ?
N4 C21 H21A 108.9 . . ?
N4 C21 H21B 108.9 . . ?
N4 C21 C22 113.4(3) . . ?
H21A C21 H21B 107.7 . . ?
C22 C21 H21A 108.9 . . ?
C22 C21 H21B 108.9 . . ?
C3 C4 H4 119.3 . . ?
C5 C4 C3 121.5(4) . . ?
C5 C4 H4 119.3 . . ?
C27 C22 C21 120.3(3) . . ?
C23 C22 C21 119.7(3) . . ?
C23 C22 C27 119.9(3) . . ?
C3 C2 C1 119.4(3) . . ?
C7 C2 C3 119.4(3) . . ?
C7 C2 C1 121.0(3) . . ?
N4 C1 C2 113.7(3) . . ?
N4 C1 H1A 108.8 . . ?
N4 C1 H1B 108.8 . . ?
C2 C1 H1A 108.8 . . ?
C2 C1 H1B 108.8 . . ?
H1A C1 H1B 107.7 . . ?
C13 C14 H14 119.4 . . ?
C15 C14 C13 121.2(4) . . ?
C15 C14 H14 119.4 . . ?
C12 C17 H17 119.5 . . ?
C16 C17 C12 121.0(4) . . ?
C16 C17 H17 119.5 . . ?
N1 C27 Dy1 45.79(14) . . ?
C22 C27 Dy1 94.2(2) . . ?
C22 C27 N1 120.8(3) . . ?
C26 C27 Dy1 129.3(2) . . ?
C26 C27 N1 121.9(3) . . ?
C26 C27 C22 117.2(3) . . ?
C27 C26 H26 119.1 . . ?
C25 C26 C27 121.9(4) . . ?
C25 C26 H26 119.1 . . ?
Si3 C18 H18A 109.5 . . ?
Si3 C18 H18B 109.5 . . ?
Si3 C18 H18C 109.5 . . ?
H18A C18 H18B 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C14 C15 H15 119.7 . . ?
C16 C15 C14 120.7(4) . . ?
C16 C15 H15 119.7 . . ?
C22 C23 H23 119.3 . . ?
C24 C23 C22 121.3(4) . . ?
C24 C23 H23 119.3 . . ?
Si2 C9 H9A 109.5 . . ?
Si2 C9 H9B 109.5 . . ?
Si2 C9 H9C 109.5 . . ?
H9A C9 H9B 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
C4 C5 H5 119.9 . . ?
C6 C5 C4 120.1(4) . . ?
C6 C5 H5 119.9 . . ?
N5 C31 H31 118.1 . . ?
N5 C31 C32 123.7(4) . . ?
C32 C31 H31 118.1 . . ?
C26 C25 H25 120.0 . . ?
C24 C25 C26 120.0(4) . . ?
C24 C25 H25 120.0 . . ?
Si2 C8 H8A 109.5 . . ?
Si2 C8 H8B 109.5 . . ?
Si2 C8 H8C 109.5 . . ?
H8A C8 H8B 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
C5 C6 H6 120.2 . . ?
C5 C6 C7 119.6(4) . . ?
C7 C6 H6 120.2 . . ?
Si3 C20 H20A 109.5 . . ?
Si3 C20 H20B 109.5 . . ?
Si3 C20 H20C 109.5 . . ?
H20A C20 H20B 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C2 C7 H7 119.2 . . ?
C6 C7 C2 121.6(4) . . ?
C6 C7 H7 119.2 . . ?
C17 C16 H16 120.0 . . ?
C15 C16 C17 119.9(4) . . ?
C15 C16 H16 120.0 . . ?
Si1 C29 H29A 109.5 . . ?
Si1 C29 H29B 109.5 . . ?
Si1 C29 H29C 109.5 . . ?
H29A C29 H29B 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
C23 C24 H24 120.2 . . ?
C25 C24 C23 119.6(3) . . ?
C25 C24 H24 120.2 . . ?
Si1 C28 H28A 109.5 . . ?
Si1 C28 H28B 109.5 . . ?
Si1 C28 H28C 109.5 . . ?
H28A C28 H28B 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
Si2 C10 H10A 109.5 . . ?
Si2 C10 H10B 109.5 . . ?
Si2 C10 H10C 109.5 . . ?
H10A C10 H10B 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
Si1 C30 H30A 109.5 . . ?
Si1 C30 H30B 109.5 . . ?
Si1 C30 H30C 109.5 . . ?
H30A C30 H30B 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
Si3 C19 H19A 109.5 . . ?
Si3 C19 H19B 109.5 . . ?
Si3 C19 H19C 109.5 . . ?
H19A C19 H19B 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C31 C32 H32 120.4 . . ?
C33 C32 C31 119.3(5) . . ?
C33 C32 H32 120.4 . . ?
C32 C33 H33 120.8 . . ?
C32 C33 C34 118.4(5) . . ?
C34 C33 H33 120.8 . . ?
C33 C34 H34 120.3 . . ?
C33 C34 C35 119.3(5) . . ?
C35 C34 H34 120.3 . . ?
N5 C35 C34 123.0(5) . . ?
N5 C35 H35 118.5 . . ?
C34 C35 H35 118.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Dy1 N3 C13 C12 -61.0(3) . . . . ?
Dy1 N3 C13 C14 116.4(3) . . . . ?
Dy1 N4 C11 C12 -50.1(3) . . . . ?
Dy1 N4 C21 C22 -50.8(3) . . . . ?
Dy1 N4 C1 C2 -51.3(3) . . . . ?
Dy1 N1 C27 C22 -62.4(3) . . . . ?
Dy1 N1 C27 C26 115.8(3) . . . . ?
Dy1 N2 C3 C4 116.4(3) . . . . ?
Dy1 N2 C3 C2 -62.4(3) . . . . ?
Dy1 N5 C31 C32 177.0(4) . . . . ?
Dy1 N5 C35 C34 -176.6(5) . . . . ?
Dy1 C27 C26 C25 -122.8(3) . . . . ?
Si1 N1 C27 Dy1 175.0(3) . . . . ?
Si1 N1 C27 C22 112.6(3) . . . . ?
Si1 N1 C27 C26 -69.2(4) . . . . ?
Si2 N2 C3 C4 -72.3(4) . . . . ?
Si2 N2 C3 C2 108.9(3) . . . . ?
Si3 N3 C13 C12 113.2(3) . . . . ?
Si3 N3 C13 C14 -69.4(4) . . . . ?
N3 C13 C12 C11 -6.6(5) . . . . ?
N3 C13 C12 C17 176.8(3) . . . . ?
N3 C13 C14 C15 -177.9(3) . . . . ?
N4 C21 C22 C27 74.6(4) . . . . ?
N4 C21 C22 C23 -108.6(3) . . . . ?
N1 C27 C26 C25 -179.4(3) . . . . ?
N2 C3 C4 C5 -179.2(3) . . . . ?
N2 C3 C2 C1 -4.4(5) . . . . ?
N2 C3 C2 C7 178.6(3) . . . . ?
N5 C31 C32 C33 2.4(9) . . . . ?
C3 C4 C5 C6 0.8(6) . . . . ?
C3 C2 C1 N4 71.3(4) . . . . ?
C3 C2 C7 C6 0.5(5) . . . . ?
C13 C12 C11 N4 73.4(4) . . . . ?
C13 C12 C17 C16 1.5(5) . . . . ?
C13 C14 C15 C16 0.7(6) . . . . ?
C12 C13 C14 C15 -0.3(5) . . . . ?
C12 C17 C16 C15 -1.2(6) . . . . ?
C11 N4 C21 C22 -170.5(3) . . . . ?
C11 N4 C1 C2 69.8(3) . . . . ?
C11 C12 C17 C16 -175.1(3) . . . . ?
C21 N4 C11 C12 68.6(3) . . . . ?
C21 N4 C1 C2 -170.4(3) . . . . ?
C21 C22 C27 Dy1 -44.3(3) . . . . ?
C21 C22 C27 N1 -4.7(5) . . . . ?
C21 C22 C27 C26 177.0(3) . . . . ?
C21 C22 C23 C24 -176.0(3) . . . . ?
C4 C3 C2 C1 176.9(3) . . . . ?
C4 C3 C2 C7 -0.2(5) . . . . ?
C4 C5 C6 C7 -0.4(6) . . . . ?
C22 C27 C26 C25 -1.1(5) . . . . ?
C22 C23 C24 C25 -0.9(6) . . . . ?
C2 C3 C4 C5 -0.5(5) . . . . ?
C1 N4 C11 C12 -171.6(3) . . . . ?
C1 N4 C21 C22 69.8(3) . . . . ?
C1 C2 C7 C6 -176.5(3) . . . . ?
C14 C13 C12 C11 175.9(3) . . . . ?
C14 C13 C12 C17 -0.7(5) . . . . ?
C14 C15 C16 C17 0.1(6) . . . . ?
C17 C12 C11 N4 -110.1(3) . . . . ?
C27 C22 C23 C24 0.8(5) . . . . ?
C27 C26 C25 C24 1.0(6) . . . . ?
C26 C25 C24 C23 0.0(6) . . . . ?
C18 Si3 N3 Dy1 102.3(2) . . . . ?
C18 Si3 N3 C13 -70.5(3) . . . . ?
C23 C22 C27 Dy1 138.9(3) . . . . ?
C23 C22 C27 N1 178.5(3) . . . . ?
C23 C22 C27 C26 0.2(5) . . . . ?
C9 Si2 N2 Dy1 -14.3(2) . . . . ?
C9 Si2 N2 C3 176.2(2) . . . . ?
C5 C6 C7 C2 -0.2(6) . . . . ?
C31 N5 C35 C34 -2.7(10) . . . . ?
C31 C32 C33 C34 -8.3(10) . . . . ?
C8 Si2 N2 Dy1 106.8(2) . . . . ?
C8 Si2 N2 C3 -62.7(3) . . . . ?
C20 Si3 N3 Dy1 -16.3(2) . . . . ?
C20 Si3 N3 C13 170.9(3) . . . . ?
C7 C2 C1 N4 -111.7(3) . . . . ?
C29 Si1 N1 Dy1 -126.3(2) . . . . ?
C29 Si1 N1 C27 60.4(3) . . . . ?
C28 Si1 N1 Dy1 113.2(2) . . . . ?
C28 Si1 N1 C27 -60.0(3) . . . . ?
C10 Si2 N2 Dy1 -133.0(2) . . . . ?
C10 Si2 N2 C3 57.5(3) . . . . ?
C30 Si1 N1 Dy1 -6.7(3) . . . . ?
C30 Si1 N1 C27 -179.9(3) . . . . ?
C19 Si3 N3 Dy1 -136.6(2) . . . . ?
C19 Si3 N3 C13 50.6(3) . . . . ?
C32 C33 C34 C35 8.8(11) . . . . ?
C33 C34 C35 N5 -3.3(12) . . . . ?
C35 N5 C31 C32 3.2(8) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_mo_20220308_trapentmsdy_me3no__a
_database_code_depnum_ccdc_archive 'CCDC 2210772'
loop_
_audit_author_name
_audit_author_address
'Kang Liu'
;institute of high energy physics
China
;
_audit_update_record             
;
2022-10-03 deposited with the CCDC.	2023-01-18 downloaded from the CCDC.
;
_audit_creation_date             2022-09-18
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6272)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C33 H54 Dy N5 O Si3'
_chemical_formula_sum            'C33 H54 Dy N5 O Si3'
_chemical_formula_weight         783.58
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   10.176(2)
_cell_length_b                   19.387(6)
_cell_length_c                   20.093(5)
_cell_angle_alpha                90
_cell_angle_beta                 102.988(9)
_cell_angle_gamma                90
_cell_volume                     3862.3(17)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9928
_cell_measurement_temperature    170.0
_cell_measurement_theta_max      27.49
_cell_measurement_theta_min      2.94
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    2.058
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.6192
_exptl_absorpt_correction_type   none
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.0813 before and 0.0535 after correction.
The Ratio of minimum to maximum transmission is 0.8305.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'metallic whiteish white'
_exptl_crystal_colour_lustre     metallic
_exptl_crystal_colour_modifier   whiteish
_exptl_crystal_colour_primary    white
_exptl_crystal_density_diffrn    1.348
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1612
_exptl_crystal_size_max          ?
_exptl_crystal_size_mid          ?
_exptl_crystal_size_min          ?
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0396
_diffrn_reflns_av_unetI/netI     0.0181
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            86187
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.462
_diffrn_reflns_theta_min         2.714
_diffrn_ambient_temperature      170.0
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           30.0
_diffrn_source_power             1.5
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                8028
_reflns_number_total             8828
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.40B (?, 2016)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.40B (?, 2016)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         0.474
_refine_diff_density_min         -0.669
_refine_diff_density_rms         0.060
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.078
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     400
_refine_ls_number_reflns         8828
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0255
_refine_ls_R_factor_gt           0.0211
_refine_ls_restrained_S_all      1.078
_refine_ls_shift/su_max          0.005
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0132P)²+3.4969P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0443
_refine_ls_wR_factor_ref         0.0459
_refine_special_details          ?
_olex2_refinement_description    
;
1.a Secondary CH2 refined with riding coordinates:
 C26(H26A,H26B), C19(H19A,H19B), C33(H33A,H33B)
1.b Aromatic/amide H refined with riding coordinates:
 C21(H21), C31(H31), C24(H24), C28(H28), C22(H22), C17(H17), C14(H14),
 C23(H23), C30(H30), C29(H29), C16(H16), C15(H15)
1.c Idealised Me refined as rotating group:
 C9(H9A,H9B,H9C), C6(H6A,H6B,H6C), C1(H1A,H1B,H1C), C12(H12A,H12B,H12C),
 C3(H3A,H3B,H3C), C2(H2A,H2B,H2C), C8(H8A,H8B,H8C), C7(H7A,H7B,H7C), C5(H5A,H5B,
 H5C), C11(H11A,H11B,H11C), C4(H4A,H4B,H4C), C10(H10A,H10B,H10C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.45606(2) 0.74317(2) 0.35075(2) 0.01937(3) Uani 1 1 d . . . . .
Si2 Si 0.64625(6) 0.59476(3) 0.31721(3) 0.02645(12) Uani 1 1 d . . . . .
Si1 Si 0.56603(6) 0.85862(3) 0.49318(3) 0.02703(12) Uani 1 1 d . . . . .
Si3 Si 0.16807(6) 0.79590(3) 0.22685(3) 0.02928(13) Uani 1 1 d . . . . .
O1 O 0.57690(15) 0.80371(8) 0.29609(8) 0.0303(3) Uani 1 1 d . . . . .
N4 N 0.31692(17) 0.66972(9) 0.41772(8) 0.0237(3) Uani 1 1 d . . . . .
N5 N 0.66110(17) 0.83867(9) 0.26276(9) 0.0280(4) Uani 1 1 d . . . . .
N3 N 0.25009(17) 0.79175(9) 0.31123(9) 0.0270(4) Uani 1 1 d . . . . .
N2 N 0.49414(17) 0.63580(9) 0.31139(9) 0.0252(4) Uani 1 1 d . . . . .
N1 N 0.55722(17) 0.77749(9) 0.45795(9) 0.0236(3) Uani 1 1 d . . . . .
C32 C 0.1520(2) 0.76830(12) 0.40997(12) 0.0312(5) Uani 1 1 d . . . . .
C26 C 0.3221(2) 0.59512(10) 0.39956(11) 0.0271(4) Uani 1 1 d . . . . .
H26A H 0.260928 0.568888 0.422197 0.033 Uiso 1 1 calc R U . . .
H26B H 0.414789 0.577704 0.417397 0.033 Uiso 1 1 calc R U . . .
C25 C 0.2826(2) 0.58193(10) 0.32380(11) 0.0263(4) Uani 1 1 d . . . . .
C20 C 0.3728(2) 0.60083(10) 0.28262(11) 0.0258(4) Uani 1 1 d . . . . .
C21 C 0.3330(2) 0.58603(12) 0.21229(11) 0.0326(5) Uani 1 1 d . . . . .
H21 H 0.391553 0.598097 0.183378 0.039 Uiso 1 1 calc R U . . .
C9 C 0.7866(2) 0.65640(12) 0.35262(13) 0.0375(5) Uani 1 1 d . . . . .
H9A H 0.812218 0.681279 0.315016 0.056 Uiso 1 1 calc R U . . .
H9B H 0.864478 0.630707 0.378390 0.056 Uiso 1 1 calc R U . . .
H9C H 0.756292 0.689416 0.382950 0.056 Uiso 1 1 calc R U . . .
C27 C 0.1866(2) 0.81508(12) 0.36308(12) 0.0303(5) Uani 1 1 d . . . . .
C19 C 0.3747(2) 0.67770(11) 0.49257(10) 0.0284(4) Uani 1 1 d . . . . .
H19A H 0.331100 0.644020 0.517739 0.034 Uiso 1 1 calc R U . . .
H19B H 0.353725 0.724521 0.506886 0.034 Uiso 1 1 calc R U . . .
C31 C 0.0937(2) 0.79222(15) 0.46234(13) 0.0412(6) Uani 1 1 d . . . . .
H31 H 0.070406 0.760153 0.493556 0.049 Uiso 1 1 calc R U . . .
C24 C 0.1596(2) 0.54997(11) 0.29437(12) 0.0312(5) Uani 1 1 d . . . . .
H24 H 0.100076 0.537428 0.322600 0.037 Uiso 1 1 calc R U . . .
C18 C 0.5252(2) 0.66700(11) 0.51172(10) 0.0274(4) Uani 1 1 d . . . . .
C33 C 0.1724(2) 0.69182(12) 0.40184(12) 0.0306(5) Uani 1 1 d . . . . .
H33A H 0.124784 0.666564 0.432236 0.037 Uiso 1 1 calc R U . . .
H33B H 0.130475 0.678491 0.354239 0.037 Uiso 1 1 calc R U . . .
C6 C 0.4509(3) 0.86589(13) 0.55341(12) 0.0377(5) Uani 1 1 d . . . . .
H6A H 0.357390 0.859432 0.528240 0.056 Uiso 1 1 calc R U . . .
H6B H 0.460761 0.911638 0.574706 0.056 Uiso 1 1 calc R U . . .
H6C H 0.474163 0.830422 0.588856 0.056 Uiso 1 1 calc R U . . .
C13 C 0.6109(2) 0.71938(11) 0.49666(10) 0.0251(4) Uani 1 1 d . . . . .
C1 C 0.6804(3) 0.79498(14) 0.20440(13) 0.0453(6) Uani 1 1 d . . . . .
H1A H 0.716194 0.749858 0.221578 0.068 Uiso 1 1 calc R U . . .
H1B H 0.744155 0.817627 0.181428 0.068 Uiso 1 1 calc R U . . .
H1C H 0.593686 0.788831 0.171930 0.068 Uiso 1 1 calc R U . . .
C28 C 0.1602(2) 0.88569(13) 0.37146(13) 0.0393(6) Uani 1 1 d . . . . .
H28 H 0.182641 0.918446 0.340651 0.047 Uiso 1 1 calc R U . . .
C12 C 0.2875(3) 0.77033(15) 0.17255(13) 0.0442(6) Uani 1 1 d . . . . .
H12A H 0.346808 0.809273 0.168715 0.066 Uiso 1 1 calc R U . . .
H12B H 0.236232 0.757288 0.126970 0.066 Uiso 1 1 calc R U . . .
H12C H 0.342083 0.731068 0.193562 0.066 Uiso 1 1 calc R U . . .
C22 C 0.2108(3) 0.55433(12) 0.18397(12) 0.0378(5) Uani 1 1 d . . . . .
H22 H 0.187277 0.544964 0.136358 0.045 Uiso 1 1 calc R U . . .
C3 C 0.7913(2) 0.85199(14) 0.31224(15) 0.0469(7) Uani 1 1 d . . . . .
H3A H 0.774969 0.880162 0.350060 0.070 Uiso 1 1 calc R U . . .
H3B H 0.852582 0.876562 0.289147 0.070 Uiso 1 1 calc R U . . .
H3C H 0.832151 0.808026 0.330055 0.070 Uiso 1 1 calc R U . . .
C2 C 0.5951(3) 0.90550(12) 0.23702(14) 0.0418(6) Uani 1 1 d . . . . .
H2A H 0.508654 0.896211 0.205270 0.063 Uiso 1 1 calc R U . . .
H2B H 0.653789 0.931246 0.213335 0.063 Uiso 1 1 calc R U . . .
H2C H 0.579548 0.932774 0.275591 0.063 Uiso 1 1 calc R U . . .
C17 C 0.5817(3) 0.60687(12) 0.54518(11) 0.0389(6) Uani 1 1 d . . . . .
H17 H 0.524024 0.571612 0.554934 0.047 Uiso 1 1 calc R U . . .
C8 C 0.6761(3) 0.56135(14) 0.23409(13) 0.0418(6) Uani 1 1 d . . . . .
H8A H 0.610677 0.524915 0.216656 0.063 Uiso 1 1 calc R U . . .
H8B H 0.767712 0.542609 0.241380 0.063 Uiso 1 1 calc R U . . .
H8C H 0.665616 0.599094 0.200863 0.063 Uiso 1 1 calc R U . . .
C14 C 0.7513(2) 0.70900(13) 0.51784(12) 0.0348(5) Uani 1 1 d . . . . .
H14 H 0.810880 0.743938 0.509318 0.042 Uiso 1 1 calc R U . . .
C7 C 0.6637(3) 0.51971(12) 0.37787(13) 0.0391(5) Uani 1 1 d . . . . .
H7A H 0.667923 0.536710 0.424231 0.059 Uiso 1 1 calc R U . . .
H7B H 0.746515 0.494275 0.376934 0.059 Uiso 1 1 calc R U . . .
H7C H 0.585814 0.489024 0.364043 0.059 Uiso 1 1 calc R U . . .
C5 C 0.5127(3) 0.92244(12) 0.42227(13) 0.0425(6) Uani 1 1 d . . . . .
H5A H 0.590825 0.935399 0.404023 0.064 Uiso 1 1 calc R U . . .
H5B H 0.475890 0.963596 0.439794 0.064 Uiso 1 1 calc R U . . .
H5C H 0.443508 0.901706 0.385884 0.064 Uiso 1 1 calc R U . . .
C11 C 0.0232(2) 0.73376(13) 0.20806(14) 0.0396(6) Uani 1 1 d . . . . .
H11A H 0.057874 0.686500 0.209287 0.059 Uiso 1 1 calc R U . . .
H11B H -0.033067 0.743395 0.162659 0.059 Uiso 1 1 calc R U . . .
H11C H -0.030869 0.738896 0.242430 0.059 Uiso 1 1 calc R U . . .
C23 C 0.1231(2) 0.53627(12) 0.22483(13) 0.0374(5) Uani 1 1 d . . . . .
H23 H 0.039192 0.514857 0.205522 0.045 Uiso 1 1 calc R U . . .
C30 C 0.0690(2) 0.86199(16) 0.46956(15) 0.0494(7) Uani 1 1 d . . . . .
H30 H 0.030008 0.877692 0.505554 0.059 Uiso 1 1 calc R U . . .
C29 C 0.1021(2) 0.90812(15) 0.42370(15) 0.0481(7) Uani 1 1 d . . . . .
H29 H 0.084884 0.955890 0.427991 0.058 Uiso 1 1 calc R U . . .
C16 C 0.7206(3) 0.59793(13) 0.56430(12) 0.0473(7) Uani 1 1 d . . . . .
H16 H 0.757416 0.556753 0.586570 0.057 Uiso 1 1 calc R U . . .
C15 C 0.8042(3) 0.64921(14) 0.55071(13) 0.0455(6) Uani 1 1 d . . . . .
H15 H 0.899255 0.643472 0.564027 0.055 Uiso 1 1 calc R U . . .
C4 C 0.7378(3) 0.88416(15) 0.54285(16) 0.0527(7) Uani 1 1 d . . . . .
H4A H 0.768385 0.851284 0.580161 0.079 Uiso 1 1 calc R U . . .
H4B H 0.733751 0.930506 0.561768 0.079 Uiso 1 1 calc R U . . .
H4C H 0.801085 0.884061 0.512586 0.079 Uiso 1 1 calc R U . . .
C10 C 0.1034(3) 0.88493(13) 0.19875(15) 0.0494(7) Uani 1 1 d . . . . .
H10A H 0.028580 0.896606 0.220079 0.074 Uiso 1 1 calc R U . . .
H10B H 0.071718 0.885789 0.148952 0.074 Uiso 1 1 calc R U . . .
H10C H 0.176184 0.918609 0.212643 0.074 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O1 2.1686(14) . ?
Dy1 N4 2.5884(17) . ?
Dy1 N3 2.2720(17) . ?
Dy1 N2 2.2904(18) . ?
Dy1 N1 2.2684(17) . ?
Si2 N2 1.7208(18) . ?
Si2 C9 1.875(2) . ?
Si2 C8 1.879(2) . ?
Si2 C7 1.881(2) . ?
Si1 N1 1.7188(18) . ?
Si1 C6 1.869(2) . ?
Si1 C5 1.873(3) . ?
Si1 C4 1.874(3) . ?
Si3 N3 1.7150(19) . ?
Si3 C12 1.874(3) . ?
Si3 C11 1.875(2) . ?
Si3 C10 1.888(3) . ?
O1 N5 1.378(2) . ?
N4 C26 1.495(3) . ?
N4 C19 1.495(3) . ?
N4 C33 1.496(3) . ?
N5 C1 1.495(3) . ?
N5 C3 1.490(3) . ?
N5 C2 1.497(3) . ?
N3 C27 1.418(3) . ?
N2 C20 1.414(3) . ?
N1 C13 1.407(3) . ?
C32 C27 1.408(3) . ?
C32 C31 1.399(3) . ?
C32 C33 1.511(3) . ?
C26 H26A 0.9900 . ?
C26 H26B 0.9900 . ?
C26 C25 1.506(3) . ?
C25 C20 1.415(3) . ?
C25 C24 1.402(3) . ?
C20 C21 1.409(3) . ?
C21 H21 0.9500 . ?
C21 C22 1.389(3) . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
C27 C28 1.412(3) . ?
C19 H19A 0.9900 . ?
C19 H19B 0.9900 . ?
C19 C18 1.506(3) . ?
C31 H31 0.9500 . ?
C31 C30 1.389(4) . ?
C24 H24 0.9500 . ?
C24 C23 1.388(3) . ?
C18 C13 1.415(3) . ?
C18 C17 1.403(3) . ?
C33 H33A 0.9900 . ?
C33 H33B 0.9900 . ?
C6 H6A 0.9800 . ?
C6 H6B 0.9800 . ?
C6 H6C 0.9800 . ?
C13 C14 1.411(3) . ?
C1 H1A 0.9800 . ?
C1 H1B 0.9800 . ?
C1 H1C 0.9800 . ?
C28 H28 0.9500 . ?
C28 C29 1.385(4) . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
C22 H22 0.9500 . ?
C22 C23 1.387(4) . ?
C3 H3A 0.9800 . ?
C3 H3B 0.9800 . ?
C3 H3C 0.9800 . ?
C2 H2A 0.9800 . ?
C2 H2B 0.9800 . ?
C2 H2C 0.9800 . ?
C17 H17 0.9500 . ?
C17 C16 1.389(4) . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C14 H14 0.9500 . ?
C14 C15 1.382(3) . ?
C7 H7A 0.9800 . ?
C7 H7B 0.9800 . ?
C7 H7C 0.9800 . ?
C5 H5A 0.9800 . ?
C5 H5B 0.9800 . ?
C5 H5C 0.9800 . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C23 H23 0.9500 . ?
C30 H30 0.9500 . ?
C30 C29 1.379(4) . ?
C29 H29 0.9500 . ?
C16 H16 0.9500 . ?
C16 C15 1.376(4) . ?
C15 H15 0.9500 . ?
C4 H4A 0.9800 . ?
C4 H4B 0.9800 . ?
C4 H4C 0.9800 . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Dy1 N4 178.67(6) . . ?
O1 Dy1 N3 100.50(6) . . ?
O1 Dy1 N2 99.08(6) . . ?
O1 Dy1 N1 97.71(6) . . ?
N3 Dy1 N4 80.82(6) . . ?
N3 Dy1 N2 118.06(6) . . ?
N2 Dy1 N4 80.46(6) . . ?
N1 Dy1 N4 81.50(6) . . ?
N1 Dy1 N3 113.35(6) . . ?
N1 Dy1 N2 121.23(6) . . ?
N2 Si2 C9 109.13(10) . . ?
N2 Si2 C8 114.95(10) . . ?
N2 Si2 C7 110.76(10) . . ?
C9 Si2 C8 107.18(12) . . ?
C9 Si2 C7 107.11(12) . . ?
C8 Si2 C7 107.38(12) . . ?
N1 Si1 C6 110.69(10) . . ?
N1 Si1 C5 108.17(10) . . ?
N1 Si1 C4 114.65(11) . . ?
C6 Si1 C5 109.03(12) . . ?
C6 Si1 C4 106.29(13) . . ?
C5 Si1 C4 107.85(14) . . ?
N3 Si3 C12 109.15(10) . . ?
N3 Si3 C11 110.78(11) . . ?
N3 Si3 C10 113.45(11) . . ?
C12 Si3 C11 107.24(12) . . ?
C12 Si3 C10 107.22(14) . . ?
C11 Si3 C10 108.76(12) . . ?
N5 O1 Dy1 175.81(13) . . ?
C26 N4 Dy1 110.60(11) . . ?
C26 N4 C33 108.17(16) . . ?
C19 N4 Dy1 109.18(11) . . ?
C19 N4 C26 108.55(16) . . ?
C19 N4 C33 109.31(16) . . ?
C33 N4 Dy1 110.98(12) . . ?
O1 N5 C1 107.96(17) . . ?
O1 N5 C3 108.54(17) . . ?
O1 N5 C2 108.29(16) . . ?
C1 N5 C2 110.32(19) . . ?
C3 N5 C1 111.6(2) . . ?
C3 N5 C2 110.08(19) . . ?
Si3 N3 Dy1 124.80(9) . . ?
C27 N3 Dy1 114.34(13) . . ?
C27 N3 Si3 120.72(14) . . ?
Si2 N2 Dy1 128.03(9) . . ?
C20 N2 Dy1 112.15(13) . . ?
C20 N2 Si2 119.73(14) . . ?
Si1 N1 Dy1 129.04(9) . . ?
C13 N1 Dy1 109.08(12) . . ?
C13 N1 Si1 121.81(14) . . ?
C27 C32 C33 119.91(19) . . ?
C31 C32 C27 120.2(2) . . ?
C31 C32 C33 119.9(2) . . ?
N4 C26 H26A 108.9 . . ?
N4 C26 H26B 108.9 . . ?
N4 C26 C25 113.25(17) . . ?
H26A C26 H26B 107.7 . . ?
C25 C26 H26A 108.9 . . ?
C25 C26 H26B 108.9 . . ?
C20 C25 C26 119.06(18) . . ?
C24 C25 C26 120.77(19) . . ?
C24 C25 C20 120.1(2) . . ?
N2 C20 C25 120.46(19) . . ?
C21 C20 N2 122.36(19) . . ?
C21 C20 C25 117.12(19) . . ?
C20 C21 H21 119.0 . . ?
C22 C21 C20 122.0(2) . . ?
C22 C21 H21 119.0 . . ?
Si2 C9 H9A 109.5 . . ?
Si2 C9 H9B 109.5 . . ?
Si2 C9 H9C 109.5 . . ?
H9A C9 H9B 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
C32 C27 N3 120.7(2) . . ?
C32 C27 C28 117.5(2) . . ?
C28 C27 N3 121.8(2) . . ?
N4 C19 H19A 109.0 . . ?
N4 C19 H19B 109.0 . . ?
N4 C19 C18 112.98(17) . . ?
H19A C19 H19B 107.8 . . ?
C18 C19 H19A 109.0 . . ?
C18 C19 H19B 109.0 . . ?
C32 C31 H31 119.4 . . ?
C30 C31 C32 121.2(3) . . ?
C30 C31 H31 119.4 . . ?
C25 C24 H24 119.3 . . ?
C23 C24 C25 121.4(2) . . ?
C23 C24 H24 119.3 . . ?
C13 C18 C19 119.10(18) . . ?
C17 C18 C19 121.4(2) . . ?
C17 C18 C13 119.5(2) . . ?
N4 C33 C32 114.21(17) . . ?
N4 C33 H33A 108.7 . . ?
N4 C33 H33B 108.7 . . ?
C32 C33 H33A 108.7 . . ?
C32 C33 H33B 108.7 . . ?
H33A C33 H33B 107.6 . . ?
Si1 C6 H6A 109.5 . . ?
Si1 C6 H6B 109.5 . . ?
Si1 C6 H6C 109.5 . . ?
H6A C6 H6B 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
N1 C13 C18 120.76(18) . . ?
N1 C13 C14 121.4(2) . . ?
C14 C13 C18 117.7(2) . . ?
N5 C1 H1A 109.5 . . ?
N5 C1 H1B 109.5 . . ?
N5 C1 H1C 109.5 . . ?
H1A C1 H1B 109.5 . . ?
H1A C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
C27 C28 H28 119.3 . . ?
C29 C28 C27 121.3(3) . . ?
C29 C28 H28 119.3 . . ?
Si3 C12 H12A 109.5 . . ?
Si3 C12 H12B 109.5 . . ?
Si3 C12 H12C 109.5 . . ?
H12A C12 H12B 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
C21 C22 H22 119.8 . . ?
C23 C22 C21 120.4(2) . . ?
C23 C22 H22 119.8 . . ?
N5 C3 H3A 109.5 . . ?
N5 C3 H3B 109.5 . . ?
N5 C3 H3C 109.5 . . ?
H3A C3 H3B 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
N5 C2 H2A 109.5 . . ?
N5 C2 H2B 109.5 . . ?
N5 C2 H2C 109.5 . . ?
H2A C2 H2B 109.5 . . ?
H2A C2 H2C 109.5 . . ?
H2B C2 H2C 109.5 . . ?
C18 C17 H17 119.4 . . ?
C16 C17 C18 121.2(2) . . ?
C16 C17 H17 119.4 . . ?
Si2 C8 H8A 109.5 . . ?
Si2 C8 H8B 109.5 . . ?
Si2 C8 H8C 109.5 . . ?
H8A C8 H8B 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
C13 C14 H14 119.2 . . ?
C15 C14 C13 121.6(2) . . ?
C15 C14 H14 119.2 . . ?
Si2 C7 H7A 109.5 . . ?
Si2 C7 H7B 109.5 . . ?
Si2 C7 H7C 109.5 . . ?
H7A C7 H7B 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
Si1 C5 H5A 109.5 . . ?
Si1 C5 H5B 109.5 . . ?
Si1 C5 H5C 109.5 . . ?
H5A C5 H5B 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
Si3 C11 H11A 109.5 . . ?
Si3 C11 H11B 109.5 . . ?
Si3 C11 H11C 109.5 . . ?
H11A C11 H11B 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
C24 C23 H23 120.5 . . ?
C22 C23 C24 119.0(2) . . ?
C22 C23 H23 120.5 . . ?
C31 C30 H30 120.5 . . ?
C29 C30 C31 119.0(2) . . ?
C29 C30 H30 120.5 . . ?
C28 C29 H29 119.6 . . ?
C30 C29 C28 120.8(2) . . ?
C30 C29 H29 119.6 . . ?
C17 C16 H16 120.3 . . ?
C15 C16 C17 119.4(2) . . ?
C15 C16 H16 120.3 . . ?
C14 C15 H15 119.7 . . ?
C16 C15 C14 120.6(2) . . ?
C16 C15 H15 119.7 . . ?
Si1 C4 H4A 109.5 . . ?
Si1 C4 H4B 109.5 . . ?
Si1 C4 H4C 109.5 . . ?
H4A C4 H4B 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
Si3 C10 H10A 109.5 . . ?
Si3 C10 H10B 109.5 . . ?
Si3 C10 H10C 109.5 . . ?
H10A C10 H10B 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Dy1 N4 C26 C25 -52.99(19) . . . . ?
Dy1 N4 C19 C18 -49.66(19) . . . . ?
Dy1 N4 C33 C32 -51.8(2) . . . . ?
Dy1 N3 C27 C32 -62.6(2) . . . . ?
Dy1 N3 C27 C28 115.1(2) . . . . ?
Dy1 N2 C20 C25 -64.8(2) . . . . ?
Dy1 N2 C20 C21 112.29(19) . . . . ?
Dy1 N1 C13 C18 -64.9(2) . . . . ?
Dy1 N1 C13 C14 110.84(19) . . . . ?
Si2 N2 C20 C25 112.04(19) . . . . ?
Si2 N2 C20 C21 -70.9(2) . . . . ?
Si1 N1 C13 C18 112.27(19) . . . . ?
Si1 N1 C13 C14 -72.0(2) . . . . ?
Si3 N3 C27 C32 113.2(2) . . . . ?
Si3 N3 C27 C28 -69.1(3) . . . . ?
N4 C26 C25 C20 72.9(2) . . . . ?
N4 C26 C25 C24 -108.6(2) . . . . ?
N4 C19 C18 C13 75.0(2) . . . . ?
N4 C19 C18 C17 -106.2(2) . . . . ?
N3 C27 C28 C29 -177.9(2) . . . . ?
N2 C20 C21 C22 -177.1(2) . . . . ?
N1 C13 C14 C15 -174.3(2) . . . . ?
C32 C27 C28 C29 -0.1(3) . . . . ?
C32 C31 C30 C29 0.5(4) . . . . ?
C26 N4 C19 C18 71.0(2) . . . . ?
C26 N4 C33 C32 -173.33(17) . . . . ?
C26 C25 C20 N2 -4.3(3) . . . . ?
C26 C25 C20 C21 178.52(19) . . . . ?
C26 C25 C24 C23 -178.7(2) . . . . ?
C25 C20 C21 C22 0.0(3) . . . . ?
C25 C24 C23 C22 0.4(3) . . . . ?
C20 C25 C24 C23 -0.2(3) . . . . ?
C20 C21 C22 C23 0.2(4) . . . . ?
C21 C22 C23 C24 -0.4(4) . . . . ?
C9 Si2 N2 Dy1 -7.03(15) . . . . ?
C9 Si2 N2 C20 176.71(16) . . . . ?
C27 C32 C31 C30 -0.3(3) . . . . ?
C27 C32 C33 N4 70.9(3) . . . . ?
C27 C28 C29 C30 0.4(4) . . . . ?
C19 N4 C26 C25 -172.75(16) . . . . ?
C19 N4 C33 C32 68.6(2) . . . . ?
C19 C18 C13 N1 -6.7(3) . . . . ?
C19 C18 C13 C14 177.38(19) . . . . ?
C19 C18 C17 C16 -178.4(2) . . . . ?
C31 C32 C27 N3 177.8(2) . . . . ?
C31 C32 C27 C28 0.1(3) . . . . ?
C31 C32 C33 N4 -111.8(2) . . . . ?
C31 C30 C29 C28 -0.6(4) . . . . ?
C24 C25 C20 N2 177.18(19) . . . . ?
C24 C25 C20 C21 0.0(3) . . . . ?
C18 C13 C14 C15 1.5(3) . . . . ?
C18 C17 C16 C15 0.5(4) . . . . ?
C33 N4 C26 C25 68.7(2) . . . . ?
C33 N4 C19 C18 -171.24(17) . . . . ?
C33 C32 C27 N3 -4.9(3) . . . . ?
C33 C32 C27 C28 177.39(19) . . . . ?
C33 C32 C31 C30 -177.6(2) . . . . ?
C6 Si1 N1 Dy1 105.78(13) . . . . ?
C6 Si1 N1 C13 -70.77(19) . . . . ?
C13 C18 C17 C16 0.5(3) . . . . ?
C13 C14 C15 C16 -0.6(4) . . . . ?
C12 Si3 N3 Dy1 -10.96(15) . . . . ?
C12 Si3 N3 C27 173.72(17) . . . . ?
C17 C18 C13 N1 174.41(19) . . . . ?
C17 C18 C13 C14 -1.5(3) . . . . ?
C17 C16 C15 C14 -0.5(4) . . . . ?
C8 Si2 N2 Dy1 -127.44(13) . . . . ?
C8 Si2 N2 C20 56.29(19) . . . . ?
C7 Si2 N2 Dy1 110.65(13) . . . . ?
C7 Si2 N2 C20 -65.62(19) . . . . ?
C5 Si1 N1 Dy1 -13.61(15) . . . . ?
C5 Si1 N1 C13 169.84(17) . . . . ?
C11 Si3 N3 Dy1 106.90(13) . . . . ?
C11 Si3 N3 C27 -68.42(19) . . . . ?
C4 Si1 N1 Dy1 -134.00(14) . . . . ?
C4 Si1 N1 C13 49.5(2) . . . . ?
C10 Si3 N3 Dy1 -130.45(13) . . . . ?
C10 Si3 N3 C27 54.2(2) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
