# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2023

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_SrAgPS4
_database_code_depnum_ccdc_archive 'CCDC 2240396'
loop_
_audit_author_name
_audit_author_address
'Jian Tang'
;Institute of Chemical Materials, China Academy of Engineering Physics
China
;
_audit_update_record             
;
2023-02-07 deposited with the CCDC.	2023-04-19 downloaded from the CCDC.
;
_audit_creation_date             2021-11-23
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2014/7
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         '0.25(Ag4 P4 S16 Sr4)'
_chemical_formula_sum            'Ag P S4 Sr'
_chemical_formula_weight         354.70
_chemical_absolute_configuration ?
_chemical_melting_point          ?
_chemical_oxdiff_formula         AgSrPS
_chemical_oxdiff_usercomment     RT
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Ag Ag 0.1306 4.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.3331 0.5567 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sr Sr -0.3528 1.8200 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           40
_space_group_name_H-M_alt        'A m a 2'
_space_group_name_Hall           'A 2 -2a'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, z'
'x+1/2, -y, z'
'-x+1/2, y, z'
'x, y+1/2, z+1/2'
'-x, -y+1/2, z+1/2'
'x+1/2, -y+1/2, z+1/2'
'-x+1/2, y+1/2, z+1/2'

_cell_length_a                   10.0941(3)
_cell_length_b                   10.0305(2)
_cell_length_c                   6.4002(2)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     648.01(3)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    1788
_cell_measurement_temperature    295.66(10)
_cell_measurement_theta_max      73.2550
_cell_measurement_theta_min      8.2080
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    48.431
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.72672
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.41.112a (Rigaku Oxford Diffraction, 2021)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'translucent light white'
_exptl_crystal_density_diffrn    3.636
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             656
_exptl_crystal_size_max          0.1
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.1
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0429
_diffrn_reflns_av_unetI/netI     0.0403
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.979
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       7
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       7
_diffrn_reflns_limit_l_min       -7
_diffrn_reflns_number            2530
_diffrn_reflns_point_group_measured_fraction_full 0.969
_diffrn_reflns_point_group_measured_fraction_max 0.934
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         73.965
_diffrn_reflns_theta_min         8.215
_diffrn_ambient_environment      air
_diffrn_ambient_temperature      295.66(10)
_diffrn_detector                 'Hybrid Pixel Array Detector'
_diffrn_detector_area_resol_mean 10.0000
_diffrn_detector_type            HyPix
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.979
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω     44.00  70.00   0.50    0.07    --   47.84-125.00-180.00   52
  2  ω     79.00 112.00   0.50    0.29    --  109.10-125.00 150.00   66
  3  ω     97.00 122.00   0.50    0.29    --  109.10 125.00 -60.00   50
  4  ω    153.00 178.00   0.50    0.29    --  109.10 125.00 -60.00   50
  5  ω     97.00 161.00   0.50    0.29    --  109.10 125.00-180.00  128
  6  ω     77.00 110.00   0.50    0.29    --  109.10-125.00 -60.00   66
  7  ω     45.00 104.00   0.50    0.29    --  109.10 -99.00 -60.00  118
  8  ω     42.00 100.00   0.50    0.29    --  109.10-125.00  30.00  116
  9  ω     63.00 107.00   0.50    0.29    --  109.10-125.00 120.00   88
 10  ω     37.00  74.00   0.50    0.29    --  109.10-125.00 150.00   74
 11  ω     72.00 105.00   0.50    0.29    --  109.10 -77.00 150.00   66
 12  ω     38.00  64.00   0.50    0.29    --  109.10 -57.00   0.00   52
 13  ω    -10.00  17.00   0.50    0.07    --   47.84 -19.00 -60.00   54
 14  ω    -20.00  11.00   0.50    0.07    --  -47.84  19.00-150.00   62
 15  ω     -5.00  21.00   0.50    0.07    --  -47.84   0.00-180.00   52
 16  ω    -26.00  26.00   0.50    0.07    --  -47.84  19.00 150.00  104
 17  ω   -117.00 -39.00   0.50    0.07    --  -47.84   0.00-180.00  156
 18  ω    -57.00 -25.00   0.50    0.29    --  -91.75  57.00-150.00   64
 19  ω    -53.00 -28.00   0.50    0.29    --  -91.75  57.00-120.00   50
 20  ω    -73.00 -21.00   0.50    0.29    --  -91.75 125.00 -90.00  104
 21  ω    -84.00 -48.00   0.50    0.29    --  -91.75 125.00 120.00   72
 22  ω   -157.00 -79.00   0.50    0.29    --  -91.75 -19.00-120.00  156
 23  ω   -163.00-110.00   0.50    0.29    --  -91.75 -77.00-120.00  106
 24  ω   -100.00 -69.00   0.50    0.29    --  -91.75 -77.00-120.00   62
 25  ω   -116.00 -90.00   0.50    0.29    --  -91.75 -77.00   0.00   52
 26  ω   -161.00-119.00   0.50    0.29    --  -91.75 -77.00   0.00   84
 27  ω   -109.00 -73.00   0.50    0.29    --  -91.75-125.00 150.00   72
 28  ω   -157.00-131.00   0.50    0.29    --  -91.75-125.00 150.00   52
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'XtaLAB Synergy, Dualflex, HyPix'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.0157286000
_diffrn_orient_matrix_UB_12      0.0387774000
_diffrn_orient_matrix_UB_13      -0.1473285000
_diffrn_orient_matrix_UB_21      -0.2253041000
_diffrn_orient_matrix_UB_22      0.0491451000
_diffrn_orient_matrix_UB_23      0.0224306000
_diffrn_orient_matrix_UB_31      0.0832571000
_diffrn_orient_matrix_UB_32      0.1402687000
_diffrn_orient_matrix_UB_33      0.0328347000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'PhotonJet (Cu) X-ray Source'
_reflns_Friedel_coverage         0.746
_reflns_Friedel_fraction_full    0.932
_reflns_Friedel_fraction_max     0.879
_reflns_number_gt                651
_reflns_number_total             660
_reflns_odcompleteness_completeness 100.00
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     66.97
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.41.112a (Rigaku OD, 2021)'
_computing_data_collection       'CrysAlisPro 1.171.41.112a (Rigaku OD, 2021)'
_computing_data_reduction        'CrysAlisPro 1.171.41.112a (Rigaku OD, 2021)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         1.332
_refine_diff_density_min         -0.404
_refine_diff_density_rms         0.126
_refine_ls_abs_structure_details 
;
 Flack x determined using 272 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   0.007(18)
_refine_ls_extinction_coef       0.00123(17)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2014/7 (Sheldrick 2014'
_refine_ls_goodness_of_fit_ref   1.110
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     50
_refine_ls_number_reflns         660
_refine_ls_number_restraints     13
_refine_ls_R_factor_all          0.0237
_refine_ls_R_factor_gt           0.0233
_refine_ls_restrained_S_all      1.179
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0231P)²+0.4240P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0570
_refine_ls_wR_factor_ref         0.0572
_refine_special_details          ?
_olex2_refinement_description    
;
1. Uiso/Uaniso restraints and constraints
Uanis(Ag1A) \\sim Ueq, Uanis(Ag1B) \\sim Ueq: with sigma of 0.01 and sigma for
terminal atoms of 0.02
2. Others
 Sof(Ag1B)=0.5*(1-FVAR(2))
 Sof(Ag1A)=0.5*FVAR(2)
;
_atom_sites_solution_hydrogens   .
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Sr1 Sr 0.5000 0.5000 0.29624(17) 0.0166(3) Uani 1 2 d S T P A .
Ag1A Ag 0.7500 0.6626(7) 0.8624(9) 0.047(4) Uani 0.43(5) 2 d S TU P A 1
S1 S 0.7500 0.6093(2) 0.4851(4) 0.0119(5) Uani 1 2 d S T P . .
S3 S 0.7500 0.9349(2) 0.5402(4) 0.0154(5) Uani 1 2 d S T P . .
P1 P 0.7500 0.78618(19) 0.3208(4) 0.0087(5) Uani 1 2 d S T P A .
S2 S 0.58308(18) 0.78863(16) 0.1413(3) 0.0166(4) Uani 1 1 d . . . . .
Ag1B Ag 0.817(3) 0.6560(9) 0.8489(13) 0.054(4) Uani 0.28(3) 1 d . U . A 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Sr1 S1 3.0053(12) . ?
Sr1 S1 3.0053(12) 2_665 ?
Sr1 S3 3.0789(15) 6_664 ?
Sr1 S3 3.0789(15) 5_544 ?
Sr1 S2 3.1731(16) 2_665 ?
Sr1 S2 3.1740(18) 5_545 ?
Sr1 S2 3.1740(18) 6_665 ?
Sr1 S2 3.1731(17) . ?
Sr1 Ag1B 3.750(13) 3_464 ?
Sr1 Ag1B 3.929(9) 8_644 ?
Sr1 Ag1B 3.929(9) 7_464 ?
Sr1 Ag1B 3.750(13) 4_654 ?
Ag1A S1 2.473(6) . ?
Ag1A S3 2.552(7) 5_545 ?
Ag1A S2 2.761(5) 4_656 ?
Ag1A S2 2.761(5) 1_556 ?
S1 Sr1 3.0053(12) 3_565 ?
S1 P1 2.062(3) . ?
S1 Ag1B 2.469(5) . ?
S1 Ag1B 2.469(5) 4_655 ?
S3 Sr1 3.0789(15) 7_565 ?
S3 Sr1 3.0789(15) 5 ?
S3 Ag1A 2.552(7) 5_554 ?
S3 P1 2.049(3) . ?
S3 Ag1B 2.622(7) 5_554 ?
S3 Ag1B 2.622(7) 8_654 ?
P1 S2 2.040(2) . ?
P1 S2 2.040(2) 4_655 ?
S2 Sr1 3.1740(18) 5_554 ?
S2 Ag1A 2.761(5) 1_554 ?
S2 Ag1B 2.509(5) 4_654 ?
Ag1B Sr1 3.750(13) 3_566 ?
Ag1B Sr1 3.929(9) 7_565 ?
Ag1B S3 2.622(7) 5_545 ?
Ag1B S2 2.509(5) 4_656 ?
Ag1B Ag1B 1.35(6) 4_655 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
S1 Sr1 S1 132.57(9) . 2_665 ?
S1 Sr1 S3 66.62(5) 2_665 6_664 ?
S1 Sr1 S3 66.62(5) . 5_544 ?
S1 Sr1 S3 145.57(6) . 6_664 ?
S1 Sr1 S3 145.57(6) 2_665 5_544 ?
S1 Sr1 S2 75.06(5) . 5_545 ?
S1 Sr1 S2 75.06(5) 2_665 6_665 ?
S1 Sr1 S2 132.89(5) 2_665 . ?
S1 Sr1 S2 64.59(5) 2_665 2_665 ?
S1 Sr1 S2 64.59(5) . . ?
S1 Sr1 S2 72.44(5) 2_665 5_545 ?
S1 Sr1 S2 132.89(5) . 2_665 ?
S1 Sr1 S2 72.44(5) . 6_665 ?
S1 Sr1 Ag1B 150.8(4) . 3_464 ?
S1 Sr1 Ag1B 83.7(4) 2_665 7_464 ?
S1 Sr1 Ag1B 92.3(4) 2_665 8_644 ?
S1 Sr1 Ag1B 75.0(4) . 4_654 ?
S1 Sr1 Ag1B 83.7(4) . 8_644 ?
S1 Sr1 Ag1B 150.8(4) 2_665 4_654 ?
S1 Sr1 Ag1B 92.3(4) . 7_464 ?
S1 Sr1 Ag1B 75.0(4) 2_665 3_464 ?
S3 Sr1 S3 115.70(9) 6_664 5_544 ?
S3 Sr1 S2 79.09(5) 5_544 . ?
S3 Sr1 S2 79.09(5) 6_664 2_665 ?
S3 Sr1 S2 81.76(5) 6_664 . ?
S3 Sr1 S2 81.76(5) 5_544 2_665 ?
S3 Sr1 S2 136.76(5) 6_664 5_545 ?
S3 Sr1 S2 90.68(6) 6_664 6_665 ?
S3 Sr1 S2 90.68(6) 5_544 5_545 ?
S3 Sr1 S2 136.76(5) 5_544 6_665 ?
S3 Sr1 Ag1B 84.8(4) 6_664 4_654 ?
S3 Sr1 Ag1B 58.2(3) 6_664 7_464 ?
S3 Sr1 Ag1B 128.1(4) 5_544 7_464 ?
S3 Sr1 Ag1B 43.8(2) 5_544 4_654 ?
S3 Sr1 Ag1B 43.8(2) 6_664 3_464 ?
S3 Sr1 Ag1B 84.8(4) 5_544 3_464 ?
S3 Sr1 Ag1B 128.1(4) 6_664 8_644 ?
S3 Sr1 Ag1B 58.2(3) 5_544 8_644 ?
S2 Sr1 S2 139.21(6) . 5_545 ?
S2 Sr1 S2 139.21(6) 2_665 6_665 ?
S2 Sr1 S2 71.21(3) 2_665 5_545 ?
S2 Sr1 S2 91.83(7) 6_665 5_545 ?
S2 Sr1 S2 143.57(8) 2_665 . ?
S2 Sr1 S2 71.21(3) . 6_665 ?
S2 Sr1 Ag1B 105.8(2) . 3_464 ?
S2 Sr1 Ag1B 41.45(12) . 4_654 ?
S2 Sr1 Ag1B 134.7(4) . 8_644 ?
S2 Sr1 Ag1B 132.8(3) 6_665 3_464 ?
S2 Sr1 Ag1B 132.8(3) 5_545 4_654 ?
S2 Sr1 Ag1B 112.51(15) 5_545 3_464 ?
S2 Sr1 Ag1B 130.64(17) 6_665 8_644 ?
S2 Sr1 Ag1B 134.7(4) 2_665 7_464 ?
S2 Sr1 Ag1B 112.51(15) 6_665 4_654 ?
S2 Sr1 Ag1B 49.4(4) . 7_464 ?
S2 Sr1 Ag1B 49.4(4) 2_665 8_644 ?
S2 Sr1 Ag1B 39.60(9) 6_665 7_464 ?
S2 Sr1 Ag1B 39.60(9) 5_545 8_644 ?
S2 Sr1 Ag1B 130.64(17) 5_545 7_464 ?
S2 Sr1 Ag1B 105.8(2) 2_665 4_654 ?
S2 Sr1 Ag1B 41.45(12) 2_665 3_464 ?
Ag1B Sr1 Ag1B 80.4(8) 3_464 4_654 ?
Ag1B Sr1 Ag1B 170.2(2) 7_464 8_644 ?
Ag1B Sr1 Ag1B 101.5(4) 4_654 8_644 ?
Ag1B Sr1 Ag1B 101.5(4) 3_464 7_464 ?
Ag1B Sr1 Ag1B 86.0(5) 4_654 7_464 ?
Ag1B Sr1 Ag1B 86.0(5) 3_464 8_644 ?
S1 Ag1A S3 104.0(3) . 5_545 ?
S1 Ag1A S2 136.89(15) . 1_556 ?
S1 Ag1A S2 136.89(15) . 4_656 ?
S3 Ag1A S2 96.99(18) 5_545 4_656 ?
S3 Ag1A S2 96.99(18) 5_545 1_556 ?
S2 Ag1A S2 75.22(17) 4_656 1_556 ?
Sr1 S1 Sr1 114.21(7) 3_565 . ?
Ag1A S1 Sr1 118.13(7) . . ?
Ag1A S1 Sr1 118.13(7) . 3_565 ?
P1 S1 Sr1 96.25(6) . 3_565 ?
P1 S1 Sr1 96.25(6) . . ?
P1 S1 Ag1A 108.2(2) . . ?
P1 S1 Ag1B 108.55(16) . 4_655 ?
P1 S1 Ag1B 108.55(16) . . ?
Ag1B S1 Sr1 102.6(7) . 3_565 ?
Ag1B S1 Sr1 132.7(6) 4_655 3_565 ?
Ag1B S1 Sr1 102.6(7) 4_655 . ?
Ag1B S1 Sr1 132.7(6) . . ?
Ag1B S1 Ag1B 31.7(14) 4_655 . ?
Sr1 S3 Sr1 110.09(8) 7_565 5 ?
Ag1A S3 Sr1 92.72(9) 5_554 7_565 ?
Ag1A S3 Sr1 92.72(9) 5_554 5 ?
P1 S3 Sr1 121.29(5) . 7_565 ?
P1 S3 Sr1 121.29(5) . 5 ?
P1 S3 Ag1A 110.23(19) . 5_554 ?
P1 S3 Ag1B 107.2(3) . 8_654 ?
P1 S3 Ag1B 107.2(3) . 5_554 ?
Ag1B S3 Sr1 106.3(7) 8_654 7_565 ?
Ag1B S3 Sr1 81.8(4) 5_554 7_565 ?
Ag1B S3 Sr1 106.3(7) 5_554 5 ?
Ag1B S3 Sr1 81.8(4) 8_654 5 ?
Ag1B S3 Ag1B 29.8(13) 5_554 8_654 ?
S3 P1 S1 106.05(14) . . ?
S2 P1 S1 107.32(8) 4_655 . ?
S2 P1 S1 107.32(8) . . ?
S2 P1 S3 112.18(9) . . ?
S2 P1 S3 112.18(9) 4_655 . ?
S2 P1 S2 111.41(15) . 4_655 ?
Sr1 S2 Sr1 139.21(6) . 5_554 ?
Ag1A S2 Sr1 91.00(14) 1_554 5_554 ?
Ag1A S2 Sr1 86.87(14) 1_554 . ?
P1 S2 Sr1 91.79(8) . . ?
P1 S2 Sr1 128.19(9) . 5_554 ?
P1 S2 Ag1A 81.63(11) . 1_554 ?
P1 S2 Ag1B 94.7(7) . 4_654 ?
Ag1B S2 Sr1 81.7(3) 4_654 . ?
Ag1B S2 Sr1 86.7(2) 4_654 5_554 ?
Sr1 Ag1B Sr1 101.5(4) 3_566 7_565 ?
S1 Ag1B Sr1 102.4(3) . 7_565 ?
S1 Ag1B Sr1 140.9(7) . 3_566 ?
S1 Ag1B S3 102.1(2) . 5_545 ?
S1 Ag1B S2 156.1(3) . 4_656 ?
S3 Ag1B Sr1 54.36(19) 5_545 3_566 ?
S3 Ag1B Sr1 154.7(3) 5_545 7_565 ?
S2 Ag1B Sr1 53.74(16) 4_656 7_565 ?
S2 Ag1B Sr1 56.9(2) 4_656 3_566 ?
S2 Ag1B S3 101.76(18) 4_656 5_545 ?
Ag1B Ag1B Sr1 118.1(4) 4_655 7_565 ?
Ag1B Ag1B Sr1 119.5(4) 4_655 3_566 ?
Ag1B Ag1B S1 74.1(7) 4_655 . ?
Ag1B Ag1B S3 75.1(6) 4_655 5_545 ?
Ag1B Ag1B S2 113.7(7) 4_655 4_656 ?

_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.424
_oxdiff_exptl_absorpt_empirical_full_min 0.793
