# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2023

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_Complex1
_audit_block_doi                 10.5517/ccdc.csd.cc28vlc3
_database_code_depnum_ccdc_archive 'CCDC 2110925'
loop_
_audit_author_name
_audit_author_address
'SHASHI KANT'
;Indian Institute of Technology Kanpur
India
;
_audit_update_record             
;
2023-04-14 deposited with the CCDC.	2023-07-26 downloaded from the CCDC.
;
# start Validation Reply Form
_vrf_PLAT911_Complex1            
;
PROBLEM: Missing FCF Refl Between Thmin & STh/L=    0.600         11 Report
RESPONSE:  Reflections having (Iobs-Icalc)/Sigma(W) > 10 and affected by the beamstop were omitted.
;
# Added during the CSD deposition process: Friday 14 April 2023 02:11 PM
# end Validation Reply Form

_audit_creation_date             2023-04-13
_audit_creation_method           
;
Olex2 1.5
(compiled 2023.03.06 svn.rbb2c1857 for OlexSys, GUI svn.r6748)
;
_shelx_SHELXL_version_number     2018/3
loop_
_audit_author_email
rnm@iitk.ac.in
_chemical_name_common            Complex1
_chemical_name_systematic        Co4
_chemical_formula_moiety         'C28 H46 Cl2 Co4 N4 O14'
_chemical_formula_sum            'C28 H46 Cl2 Co4 N4 O14'
_chemical_formula_weight         969.31
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/n 1'
_space_group_name_Hall           '-P 2yn'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   7.694(5)
_cell_length_b                   13.188(5)
_cell_length_c                   18.365(5)
_cell_angle_alpha                90
_cell_angle_beta                 96.099(5)
_cell_angle_gamma                90
_cell_volume                     1852.9(15)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    3436
_cell_measurement_temperature    100
_cell_measurement_theta_max      28.32
_cell_measurement_theta_min      2.45
_shelx_estimated_absorpt_T_max   0.743
_shelx_estimated_absorpt_T_min   0.694
_exptl_absorpt_coefficient_mu    1.973
_exptl_absorpt_correction_T_max  0.729
_exptl_absorpt_correction_T_min  0.681
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   
'SADABS-2016/2 (Bruker,2016/2) was used for absorption correction. wR2(int) was 0.1064 before'
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'metallic dark violet'
_exptl_crystal_colour_lustre     metallic
_exptl_crystal_colour_modifier   dark
_exptl_crystal_colour_primary    violet
_exptl_crystal_density_diffrn    1.737
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    .
_exptl_crystal_description       block
_exptl_crystal_F_000             992
_exptl_crystal_preparation       'Vapour diffusion'
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.16
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0383
_diffrn_reflns_av_unetI/netI     0.0464
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            9843
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_theta_full        25.240
_diffrn_reflns_theta_max         25.498
_diffrn_reflns_theta_min         1.905
_diffrn_ambient_temperature      100(2)
_diffrn_detector                 'CCD area detector'
_diffrn_detector_area_resol_mean 7.9
_diffrn_detector_type            'Bruker SMART CCD 1K area detector'
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device       'three-circle diffractometer'
_diffrn_measurement_device_type  'Bruker SMART CCD 1K area detector'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_source                   'sealed X-ray tube'
_diffrn_source_target            Mo
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                2712
_reflns_number_total             3436
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.38A (Bruker, 2018)'
_computing_data_collection       'SAINT V8.38A (Bruker, 2018)'
_computing_data_reduction        'SAINT V8.38A (Bruker, 2018)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT  (Sheldrick, 2015)'
_refine_diff_density_max         0.915
_refine_diff_density_min         -0.366
_refine_diff_density_rms         0.105
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.037
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     247
_refine_ls_number_reflns         3436
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0546
_refine_ls_R_factor_gt           0.0404
_refine_ls_restrained_S_all      1.037
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0603P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0975
_refine_ls_wR_factor_ref         0.1075
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Secondary CH2 refined with riding coordinates:
 C10(H10A,H10B), C11(H11A,H11B), C8(H8A,H8B), C7(H7A,H7B), C6(H6A,H6B)
2.b Me refined with riding coordinates:
 C13(H13A,H13B,H13C), C14(H14A,H14B,H14C)
2.c Aromatic/amide H refined with riding coordinates:
 C2(H2), C1(H1), C3(H3), C4(H4)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     geom
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Co1 Co 0.57473(6) 0.15025(3) 0.10699(2) 0.01945(16) Uani 1 1 d . . . . .
Co2 Co 0.45014(6) 0.08118(3) -0.05902(2) 0.01976(16) Uani 1 1 d . . . . .
Cl1 Cl 0.84025(12) 0.11148(7) 0.18715(5) 0.0277(2) Uani 1 1 d . . . . .
O2 O 0.1335(3) 0.25141(18) -0.03594(14) 0.0276(6) Uani 1 1 d . . . . .
O1 O 0.3600(3) 0.17293(17) 0.02422(13) 0.0215(5) Uani 1 1 d . . . . .
O4 O 0.2884(4) -0.08765(19) 0.19672(16) 0.0401(8) Uani 1 1 d . . . . .
N1 N 0.6691(4) 0.2975(2) 0.08827(16) 0.0225(7) Uani 1 1 d . . . . .
C9 C 0.2415(5) 0.2412(3) 0.01850(19) 0.0222(8) Uani 1 1 d . . . . .
O3 O 0.4510(3) 0.01732(17) 0.13764(12) 0.0219(5) Uani 1 1 d . . . . .
N2 N 0.4435(4) 0.2320(2) 0.18539(15) 0.0216(7) Uani 1 1 d . . . . .
O5 O 0.6467(3) 0.05661(16) 0.02421(12) 0.0190(5) Uani 1 1 d . . . . .
C10 C 0.4399(5) 0.1709(3) 0.2540(2) 0.0288(9) Uani 1 1 d . . . . .
H10A H 0.397566 0.214962 0.292061 0.035 Uiso 1 1 calc R U . . .
H10B H 0.561194 0.150721 0.271405 0.035 Uiso 1 1 calc R U . . .
C11 C 0.3267(5) 0.0756(3) 0.2469(2) 0.0280(9) Uani 1 1 d . . . . .
H11A H 0.338004 0.041691 0.295219 0.034 Uiso 1 1 calc R U . . .
H11B H 0.203488 0.097734 0.236813 0.034 Uiso 1 1 calc R U . . .
C2 C 0.8048(5) 0.4290(3) 0.0253(2) 0.0299(9) Uani 1 1 d . . . . .
H2 H 0.859897 0.449917 -0.016068 0.036 Uiso 1 1 calc R U . . .
C8 C 0.2370(5) 0.3125(3) 0.08340(19) 0.0262(8) Uani 1 1 d . . . . .
H8A H 0.330290 0.363864 0.081447 0.031 Uiso 1 1 calc R U . . .
H8B H 0.123688 0.348772 0.078308 0.031 Uiso 1 1 calc R U . . .
C7 C 0.2604(5) 0.2619(3) 0.1577(2) 0.0281(9) Uani 1 1 d . . . . .
H7A H 0.216169 0.308426 0.193786 0.034 Uiso 1 1 calc R U . . .
H7B H 0.186435 0.200279 0.155533 0.034 Uiso 1 1 calc R U . . .
C1 C 0.7499(5) 0.3300(3) 0.0318(2) 0.0254(8) Uani 1 1 d . . . . .
H1 H 0.770429 0.282978 -0.005515 0.030 Uiso 1 1 calc R U . . .
C13 C 0.8205(5) 0.0539(3) 0.0040(2) 0.0276(9) Uani 1 1 d . . . . .
H13A H 0.902765 0.041861 0.047609 0.041 Uiso 1 1 calc R U . . .
H13B H 0.830507 -0.000794 -0.031431 0.041 Uiso 1 1 calc R U . . .
H13C H 0.847605 0.118883 -0.018141 0.041 Uiso 1 1 calc R U . . .
C12 C 0.3594(5) -0.0043(3) 0.1897(2) 0.0270(9) Uani 1 1 d . . . . .
C5 C 0.6395(5) 0.3645(2) 0.1415(2) 0.0233(8) Uani 1 1 d . . . . .
C6 C 0.5533(5) 0.3232(3) 0.2052(2) 0.0277(9) Uani 1 1 d . . . . .
H6A H 0.644669 0.305220 0.245167 0.033 Uiso 1 1 calc R U . . .
H6B H 0.479169 0.376729 0.223689 0.033 Uiso 1 1 calc R U . . .
C3 C 0.7778(5) 0.4975(3) 0.0807(2) 0.0341(10) Uani 1 1 d . . . . .
H3 H 0.816619 0.565689 0.078310 0.041 Uiso 1 1 calc R U . . .
C4 C 0.6934(5) 0.4644(3) 0.1393(2) 0.0317(9) Uani 1 1 d . . . . .
H4 H 0.672731 0.509824 0.177591 0.038 Uiso 1 1 calc R U . . .
O7 O 0.5823(3) 0.20164(18) -0.10308(14) 0.0261(6) Uani 1 1 d . . . . .
O6 O 0.2285(4) 0.1122(2) -0.13118(14) 0.0271(6) Uani 1 1 d . . . . .
C14 C 0.5001(6) 0.2916(3) -0.1323(2) 0.0388(10) Uani 1 1 d . . . . .
H14A H 0.588272 0.336723 -0.149598 0.058 Uiso 1 1 calc R U . . .
H14B H 0.413212 0.274112 -0.173319 0.058 Uiso 1 1 calc R U . . .
H14C H 0.442257 0.325970 -0.094178 0.058 Uiso 1 1 calc R U . . .
H7 H 0.642(5) 0.167(3) -0.137(2) 0.033(11) Uiso 1 1 d . . . . .
H6C H 0.179(5) 0.058(3) -0.143(2) 0.023(11) Uiso 1 1 d . . . . .
H6D H 0.169(6) 0.154(4) -0.103(3) 0.064(16) Uiso 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Co1 Cl1 2.4420(15) . ?
Co1 O1 2.144(3) . ?
Co1 N1 2.115(3) . ?
Co1 O3 2.100(2) . ?
Co1 N2 2.136(3) . ?
Co1 O5 2.079(2) . ?
Co2 O1 2.123(2) . ?
Co2 O3 2.141(2) 3_655 ?
Co2 O5 2.090(2) 3_655 ?
Co2 O5 2.058(2) . ?
Co2 O7 2.095(2) . ?
Co2 O6 2.086(3) . ?
O2 C9 1.238(4) . ?
O1 C9 1.278(4) . ?
O4 C12 1.241(4) . ?
N1 C1 1.334(4) . ?
N1 C5 1.355(4) . ?
C9 C8 1.522(5) . ?
O3 C12 1.278(4) . ?
N2 C10 1.498(4) . ?
N2 C7 1.499(5) . ?
N2 C6 1.493(4) . ?
O5 C13 1.426(4) . ?
C10 H10A 0.9900 . ?
C10 H10B 0.9900 . ?
C10 C11 1.527(5) . ?
C11 H11A 0.9900 . ?
C11 H11B 0.9900 . ?
C11 C12 1.527(5) . ?
C2 H2 0.9500 . ?
C2 C1 1.382(5) . ?
C2 C3 1.392(5) . ?
C8 H8A 0.9900 . ?
C8 H8B 0.9900 . ?
C8 C7 1.513(5) . ?
C7 H7A 0.9900 . ?
C7 H7B 0.9900 . ?
C1 H1 0.9500 . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C13 H13C 0.9800 . ?
C5 C6 1.506(5) . ?
C5 C4 1.383(5) . ?
C6 H6A 0.9900 . ?
C6 H6B 0.9900 . ?
C3 H3 0.9500 . ?
C3 C4 1.386(5) . ?
C4 H4 0.9500 . ?
O7 C14 1.423(4) . ?
O7 H7 0.93(4) . ?
O6 H6C 0.83(4) . ?
O6 H6D 0.91(5) . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Co1 Cl1 171.49(7) . . ?
N1 Co1 Cl1 90.61(9) . . ?
N1 Co1 O1 90.50(10) . . ?
N1 Co1 N2 80.86(11) . . ?
O3 Co1 Cl1 92.16(8) . . ?
O3 Co1 O1 88.25(10) . . ?
O3 Co1 N1 169.63(10) . . ?
O3 Co1 N2 88.87(10) . . ?
N2 Co1 Cl1 97.15(9) . . ?
N2 Co1 O1 91.36(10) . . ?
O5 Co1 Cl1 92.63(7) . . ?
O5 Co1 O1 79.00(9) . . ?
O5 Co1 N1 107.71(10) . . ?
O5 Co1 O3 82.16(9) . . ?
O5 Co1 N2 166.98(10) . . ?
O1 Co2 O3 176.38(9) . 3_655 ?
O5 Co2 O1 96.95(9) 3_655 . ?
O5 Co2 O1 79.94(9) . . ?
O5 Co2 O3 96.88(9) . 3_655 ?
O5 Co2 O3 80.93(9) 3_655 3_655 ?
O5 Co2 O5 83.89(10) . 3_655 ?
O5 Co2 O7 93.31(10) . . ?
O5 Co2 O7 168.86(10) 3_655 . ?
O5 Co2 O6 171.53(10) . . ?
O7 Co2 O1 93.15(10) . . ?
O7 Co2 O3 88.73(10) . 3_655 ?
O6 Co2 O1 92.18(11) . . ?
O6 Co2 O3 90.90(11) . 3_655 ?
O6 Co2 O5 94.08(10) . 3_655 ?
O6 Co2 O7 90.20(11) . . ?
Co2 O1 Co1 98.35(10) . . ?
C9 O1 Co1 130.2(2) . . ?
C9 O1 Co2 128.8(2) . . ?
C1 N1 Co1 128.1(2) . . ?
C1 N1 C5 118.7(3) . . ?
C5 N1 Co1 113.2(2) . . ?
O2 C9 O1 123.7(3) . . ?
O2 C9 C8 119.7(3) . . ?
O1 C9 C8 116.5(3) . . ?
Co1 O3 Co2 97.01(9) . 3_655 ?
C12 O3 Co1 133.5(2) . . ?
C12 O3 Co2 129.2(2) . 3_655 ?
C10 N2 Co1 110.4(2) . . ?
C10 N2 C7 109.0(3) . . ?
C7 N2 Co1 113.5(2) . . ?
C6 N2 Co1 106.0(2) . . ?
C6 N2 C10 106.8(3) . . ?
C6 N2 C7 111.0(3) . . ?
Co1 O5 Co2 99.30(9) . 3_655 ?
Co2 O5 Co1 102.59(10) . . ?
Co2 O5 Co2 96.11(10) . 3_655 ?
C13 O5 Co1 122.4(2) . . ?
C13 O5 Co2 115.6(2) . 3_655 ?
C13 O5 Co2 116.5(2) . . ?
N2 C10 H10A 108.4 . . ?
N2 C10 H10B 108.4 . . ?
N2 C10 C11 115.5(3) . . ?
H10A C10 H10B 107.5 . . ?
C11 C10 H10A 108.4 . . ?
C11 C10 H10B 108.4 . . ?
C10 C11 H11A 107.4 . . ?
C10 C11 H11B 107.4 . . ?
H11A C11 H11B 107.0 . . ?
C12 C11 C10 119.5(3) . . ?
C12 C11 H11A 107.4 . . ?
C12 C11 H11B 107.4 . . ?
C1 C2 H2 120.7 . . ?
C1 C2 C3 118.7(4) . . ?
C3 C2 H2 120.7 . . ?
C9 C8 H8A 108.5 . . ?
C9 C8 H8B 108.5 . . ?
H8A C8 H8B 107.5 . . ?
C7 C8 C9 115.0(3) . . ?
C7 C8 H8A 108.5 . . ?
C7 C8 H8B 108.5 . . ?
N2 C7 C8 116.1(3) . . ?
N2 C7 H7A 108.3 . . ?
N2 C7 H7B 108.3 . . ?
C8 C7 H7A 108.3 . . ?
C8 C7 H7B 108.3 . . ?
H7A C7 H7B 107.4 . . ?
N1 C1 C2 122.8(3) . . ?
N1 C1 H1 118.6 . . ?
C2 C1 H1 118.6 . . ?
O5 C13 H13A 109.5 . . ?
O5 C13 H13B 109.5 . . ?
O5 C13 H13C 109.5 . . ?
H13A C13 H13B 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
O4 C12 O3 124.0(3) . . ?
O4 C12 C11 115.7(3) . . ?
O3 C12 C11 120.3(3) . . ?
N1 C5 C6 116.5(3) . . ?
N1 C5 C4 121.7(3) . . ?
C4 C5 C6 121.7(3) . . ?
N2 C6 C5 112.8(3) . . ?
N2 C6 H6A 109.0 . . ?
N2 C6 H6B 109.0 . . ?
C5 C6 H6A 109.0 . . ?
C5 C6 H6B 109.0 . . ?
H6A C6 H6B 107.8 . . ?
C2 C3 H3 120.6 . . ?
C4 C3 C2 118.8(3) . . ?
C4 C3 H3 120.6 . . ?
C5 C4 C3 119.3(3) . . ?
C5 C4 H4 120.3 . . ?
C3 C4 H4 120.3 . . ?
Co2 O7 H7 100(2) . . ?
C14 O7 Co2 124.3(2) . . ?
C14 O7 H7 113(2) . . ?
Co2 O6 H6C 109(3) . . ?
Co2 O6 H6D 100(3) . . ?
H6C O6 H6D 115(4) . . ?
O7 C14 H14A 109.5 . . ?
O7 C14 H14B 109.5 . . ?
O7 C14 H14C 109.5 . . ?
H14A C14 H14B 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Co1 O1 C9 O2 172.9(2) . . . . ?
Co1 O1 C9 C8 -7.1(4) . . . . ?
Co1 N1 C1 C2 179.5(3) . . . . ?
Co1 N1 C5 C6 2.4(4) . . . . ?
Co1 N1 C5 C4 179.3(3) . . . . ?
Co1 O3 C12 O4 176.0(3) . . . . ?
Co1 O3 C12 C11 -2.0(5) . . . . ?
Co1 N2 C10 C11 -68.0(3) . . . . ?
Co1 N2 C7 C8 -49.0(4) . . . . ?
Co1 N2 C6 C5 35.0(3) . . . . ?
Co2 O1 C9 O2 15.2(5) . . . . ?
Co2 O1 C9 C8 -164.8(2) . . . . ?
Co2 O3 C12 O4 -11.5(6) 3_655 . . . ?
Co2 O3 C12 C11 170.5(2) 3_655 . . . ?
O2 C9 C8 C7 136.7(3) . . . . ?
O1 C9 C8 C7 -43.3(4) . . . . ?
N1 C5 C6 N2 -26.3(5) . . . . ?
N1 C5 C4 C3 0.9(6) . . . . ?
C9 C8 C7 N2 77.1(4) . . . . ?
N2 C10 C11 C12 56.0(5) . . . . ?
C10 N2 C7 C8 -172.4(3) . . . . ?
C10 N2 C6 C5 152.7(3) . . . . ?
C10 C11 C12 O4 165.9(4) . . . . ?
C10 C11 C12 O3 -15.9(5) . . . . ?
C2 C3 C4 C5 0.4(6) . . . . ?
C7 N2 C10 C11 57.3(4) . . . . ?
C7 N2 C6 C5 -88.6(3) . . . . ?
C1 N1 C5 C6 -178.1(3) . . . . ?
C1 N1 C5 C4 -1.2(5) . . . . ?
C1 C2 C3 C4 -1.5(6) . . . . ?
C5 N1 C1 C2 0.1(5) . . . . ?
C6 N2 C10 C11 177.3(3) . . . . ?
C6 N2 C7 C8 70.2(4) . . . . ?
C6 C5 C4 C3 177.6(4) . . . . ?
C3 C2 C1 N1 1.2(6) . . . . ?
C4 C5 C6 N2 156.8(3) . . . . ?

_olex2_submission_original_sample_id Complex1
_olex2_submission_special_instructions 'No special instructions were received'
