# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2023

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_shelx
_database_code_depnum_ccdc_archive 'CCDC 2270185'
loop_
_audit_author_name
_audit_author_address
'Akhilesh Kumar Singh'
;Indian Institute of Technology Bhubaneswar
India
;
_audit_update_record             
;
2023-06-17 deposited with the CCDC.	2023-11-13 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C15 H24 Co N9 O10.50'
_chemical_formula_weight         557.36

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   9.863(3)
_cell_length_b                   10.865(3)
_cell_length_c                   12.144(4)
_cell_angle_alpha                82.801(9)
_cell_angle_beta                 67.950(9)
_cell_angle_gamma                71.802(9)
_cell_volume                     1145.8(6)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    17032
_cell_measurement_theta_min      1.809
_cell_measurement_theta_max      27.930

_exptl_crystal_description       BLOCK
_exptl_crystal_colour            'Light Pink'
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.615
_exptl_crystal_F_000             576
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.320
_exptl_crystal_size_mid          0.250
_exptl_crystal_size_min          0.200
_exptl_absorpt_coefficient_mu    0.823
_shelx_estimated_absorpt_T_min   0.779
_shelx_estimated_absorpt_T_max   0.853
_exptl_absorpt_correction_type   ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'fine-focus sealed tube'
_diffrn_measurement_device_type  'Bruker D8 Venture'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            17032
_diffrn_reflns_av_unetI/netI     0.1119
_diffrn_reflns_av_R_equivalents  0.0958
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_theta_min         1.809
_diffrn_reflns_theta_max         27.930
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.978
_diffrn_measured_fraction_theta_full 0.995
_diffrn_reflns_Laue_measured_fraction_max 0.978
_diffrn_reflns_Laue_measured_fraction_full 0.995
_diffrn_reflns_point_group_measured_fraction_max 0.978
_diffrn_reflns_point_group_measured_fraction_full 0.995
_reflns_number_total             5357
_reflns_number_gt                2960
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1595P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         5357
_refine_ls_number_parameters     256
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1361
_refine_ls_R_factor_gt           0.0634
_refine_ls_wR_factor_ref         0.2415
_refine_ls_wR_factor_gt          0.1710
_refine_ls_goodness_of_fit_ref   0.875
_refine_ls_restrained_S_all      0.875
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Co1 Co 0.724180 0.792010 0.138730 0.038 Uani 1 1 d . . . . .
O1 O 0.702450 0.864970 -0.018890 0.045 Uani 1 1 d . . . . .
O2 O 0.893290 0.888670 0.087740 0.050 Uani 1 1 d . . . . .
O4 O 0.538830 0.892960 0.272730 0.046 Uani 1 1 d . . . . .
N1 N 0.809400 0.593990 0.154370 0.044 Uani 1 1 d . . . . .
N4 N 0.802310 0.765740 0.294130 0.042 Uani 1 1 d . . . . .
N2 N 0.550860 0.698420 0.113080 0.042 Uani 1 1 d . . . . .
N5 N 1.039890 0.971910 0.141970 0.058 Uani 1 1 d . . . . .
H5A H 1.082938 0.995896 0.070354 0.069 Uiso 1 1 calc R U . . .
H5B H 1.065751 0.986837 0.198076 0.069 Uiso 1 1 calc R U . . .
N3 N 0.5940(5) 0.8803(4) -0.1533(4) 0.0540(11) Uani 1 1 d . . . . .
H3A H 0.661308 0.913641 -0.204215 0.065 Uiso 1 1 calc R U . . .
H3B H 0.523273 0.868401 -0.172142 0.065 Uiso 1 1 calc R U . . .
O3 O 0.2890(5) 0.6156(5) 0.1385(4) 0.0740(12) Uani 1 1 d . . . . .
N9 N 0.0752(6) 1.0911(6) 0.3847(4) 0.0617(13) Uani 1 1 d . . . . .
N7 N 0.4024(5) 0.8961(5) 0.4662(4) 0.0613(13) Uani 1 1 d . . . . .
H7A H 0.321750 0.946833 0.455468 0.074 Uiso 1 1 calc R U . . .
H7B H 0.399562 0.870187 0.536694 0.074 Uiso 1 1 calc R U . . .
C8 C 0.9347(6) 0.9125(5) 0.1657(4) 0.0441(11) Uani 1 1 d . . . . .
O9 O 0.1671(6) 1.0034(5) 0.3136(5) 0.0888(14) Uani 1 1 d . . . . .
C14 C 0.5281(6) 0.8587(5) 0.3762(4) 0.0436(11) Uani 1 1 d . . . . .
C13 C 0.6646(6) 0.7657(5) 0.3985(4) 0.0459(12) Uani 1 1 d . . . . .
H13A H 0.673893 0.791794 0.468284 0.055 Uiso 1 1 calc R U . . .
H13B H 0.652355 0.679283 0.412638 0.056 Uiso 1 1 calc R U . . .
C9 C 0.5992(6) 0.8481(4) -0.0482(4) 0.0430(11) Uani 1 1 d . . . . .
O7 O 0.5845(7) 0.1760(5) 0.2971(5) 0.1017(18) Uani 1 1 d . . . . .
N6 N 0.2377(6) 0.5792(7) 0.3282(5) 0.094(2) Uani 1 1 d . . . . .
H6A H 0.162141 0.551648 0.334837 0.113 Uiso 1 1 calc R U . . .
H6B H 0.260335 0.581407 0.389634 0.113 Uiso 1 1 calc R U . . .
O5 O 0.5459(7) 0.3631(6) 0.3619(5) 0.1004(17) Uani 1 1 d . . . . .
N8 N 0.5509(7) 0.2927(6) 0.2855(5) 0.0721(15) Uani 1 1 d . . . . .
C1 C 0.7738(6) 0.5149(4) 0.0993(5) 0.0473(12) Uani 1 1 d . . . . .
C5 C 0.9031(6) 0.5463(5) 0.2138(5) 0.0497(12) Uani 1 1 d . . . . .
C7 C 0.8583(6) 0.8773(5) 0.2922(4) 0.0489(12) Uani 1 1 d . . . . .
H7C H 0.930285 0.855092 0.333299 0.059 Uiso 1 1 calc R U . . .
H7D H 0.773587 0.950326 0.332102 0.059 Uiso 1 1 calc R U . . .
C11 C 0.4410(6) 0.6714(5) 0.2286(5) 0.0505(12) Uani 1 1 d . . . . .
H11A H 0.390995 0.751065 0.273582 0.061 Uiso 1 1 calc R U . . .
H11B H 0.497889 0.610066 0.272258 0.061 Uiso 1 1 calc R U . . .
C10 C 0.4808(6) 0.7917(5) 0.0382(4) 0.0473(12) Uani 1 1 d . . . . .
H10A H 0.396398 0.859493 0.086700 0.057 Uiso 1 1 calc R U . . .
H10B H 0.441840 0.748786 -0.003638 0.057 Uiso 1 1 calc R U . . .
O6 O 0.5182(8) 0.3432(6) 0.1986(5) 0.110(2) Uani 1 1 d . . . . .
C15 C 0.6538(6) 0.5789(5) 0.0461(5) 0.0490(12) Uani 1 1 d . . . . .
H15A H 0.701652 0.600395 -0.036675 0.059 Uiso 1 1 calc R U . . .
H15B H 0.595479 0.520251 0.049783 0.059 Uiso 1 1 calc R U . . .
C6 C 0.9262(6) 0.6435(5) 0.2772(5) 0.0543(13) Uani 1 1 d . . . . .
H6C H 0.929546 0.608505 0.353986 0.065 Uiso 1 1 calc R U . . .
H6D H 1.023261 0.660161 0.231508 0.065 Uiso 1 1 calc R U . . .
O10 O -0.0578(7) 1.1212(6) 0.3914(6) 0.1136(19) Uani 1 1 d . . . . .
C12 C 0.3190(7) 0.6181(7) 0.2237(6) 0.0653(16) Uani 1 1 d . . . . .
C4 C 0.9734(7) 0.4148(6) 0.2142(6) 0.0649(16) Uani 1 1 d . . . . .
H4 H 1.037873 0.381142 0.257048 0.078 Uiso 1 1 calc R U . . .
O8 O 0.1199(9) 1.1417(8) 0.4395(6) 0.141(3) Uani 1 1 d . . . . .
C2 C 0.8451(7) 0.3840(5) 0.0937(5) 0.0644(16) Uani 1 1 d . . . . .
H2 H 0.824677 0.330050 0.052055 0.077 Uiso 1 1 calc R U . . .
C3 C 0.9474(8) 0.3347(6) 0.1513(6) 0.0705(18) Uani 1 1 d . . . . .
H3 H 0.998920 0.246635 0.147339 0.085 Uiso 1 1 calc R U . . .
O11 O 0.2572(9) 0.6331(9) 0.5219(6) 0.066(2) Uani 0.5 1 d G . P . .
H11C H 0.288565 0.677471 0.459939 0.056 Uiso 0.5 1 d G U P . .
H11D H 0.338076 0.586994 0.533333 0.056 Uiso 0.5 1 d G U P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Co1 O4 2.0382 . ?
Co1 O1 2.0395 . ?
Co1 N1 2.0639 . ?
Co1 O2 2.1034 . ?
Co1 N4 2.2486 . ?
Co1 N2 2.3703 . ?
O1 C9 1.266(5) . ?
O2 C8 1.243(5) . ?
O4 C14 1.239(5) . ?
N1 C5 1.323(5) . ?
N1 C1 1.348(5) . ?
N4 C13 1.470(5) . ?
N4 C6 1.472(5) . ?
N4 C7 1.475(5) . ?
N2 C10 1.461(5) . ?
N2 C11 1.478(5) . ?
N2 C15 1.483(5) . ?
N5 C8 1.313(5) . ?
N5 H5A 0.8600 . ?
N5 H5B 0.8600 . ?
N3 C9 1.296(6) . ?
N3 H3A 0.8600 . ?
N3 H3B 0.8600 . ?
O3 C12 1.183(7) . ?
N9 O8 1.184(8) . ?
N9 O10 1.222(7) . ?
N9 O9 1.247(7) . ?
N7 C14 1.294(6) . ?
N7 H7A 0.8600 . ?
N7 H7B 0.8600 . ?
C8 C7 1.496(7) . ?
C14 C13 1.504(7) . ?
C13 H13A 0.9700 . ?
C13 H13B 0.9700 . ?
C9 C10 1.485(7) . ?
O7 N8 1.211(7) . ?
N6 C12 1.321(7) . ?
N6 H6A 0.8600 . ?
N6 H6B 0.8600 . ?
O5 N8 1.252(7) . ?
N8 O6 1.232(7) . ?
C1 C2 1.373(7) . ?
C1 C15 1.500(7) . ?
C5 C4 1.379(7) . ?
C5 C6 1.500(8) . ?
C7 H7C 0.9700 . ?
C7 H7D 0.9700 . ?
C11 C12 1.511(8) . ?
C11 H11A 0.9700 . ?
C11 H11B 0.9700 . ?
C10 H10A 0.9700 . ?
C10 H10B 0.9700 . ?
C15 H15A 0.9700 . ?
C15 H15B 0.9700 . ?
C6 H6C 0.9700 . ?
C6 H6D 0.9700 . ?
C4 C3 1.364(9) . ?
C4 H4 0.9300 . ?
C2 C3 1.376(9) . ?
C2 H2 0.9300 . ?
C3 H3 0.9300 . ?
O11 H11C 0.8500 . ?
O11 H11D 0.8500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O4 Co1 O1 108.2 . . ?
O4 Co1 N1 120.0 . . ?
O1 Co1 N1 118.1 . . ?
O4 Co1 O2 108.5 . . ?
O1 Co1 O2 82.8 . . ?
N1 Co1 O2 113.1 . . ?
O4 Co1 N4 75.4 . . ?
O1 Co1 N4 157.7 . . ?
N1 Co1 N4 75.5 . . ?
O2 Co1 N4 75.4 . . ?
O4 Co1 N2 85.0 . . ?
O1 Co1 N2 74.8 . . ?
N1 Co1 N2 73.2 . . ?
O2 Co1 N2 156.6 . . ?
N4 Co1 N2 127.4 . . ?
C9 O1 Co1 119.8(2) . . ?
C8 O2 Co1 118.2(2) . . ?
C14 O4 Co1 117.8(2) . . ?
C5 N1 C1 120.8(3) . . ?
C5 N1 Co1 119.8(2) . . ?
C1 N1 Co1 119.3(2) . . ?
C13 N4 C6 114.1(3) . . ?
C13 N4 C7 112.4(3) . . ?
C6 N4 C7 111.0(3) . . ?
C13 N4 Co1 104.5(2) . . ?
C6 N4 Co1 107.7(2) . . ?
C7 N4 Co1 106.6(2) . . ?
C10 N2 C11 114.3(3) . . ?
C10 N2 C15 110.7(3) . . ?
C11 N2 C15 112.7(3) . . ?
C10 N2 Co1 104.3(2) . . ?
C11 N2 Co1 111.3(2) . . ?
C15 N2 Co1 102.6(2) . . ?
C8 N5 H5A 120.0 . . ?
C8 N5 H5B 120.0 . . ?
H5A N5 H5B 120.0 . . ?
C9 N3 H3A 120.0 . . ?
C9 N3 H3B 120.0 . . ?
H3A N3 H3B 120.0 . . ?
O8 N9 O10 123.9(7) . . ?
O8 N9 O9 119.7(6) . . ?
O10 N9 O9 116.4(6) . . ?
C14 N7 H7A 120.0 . . ?
C14 N7 H7B 120.0 . . ?
H7A N7 H7B 120.0 . . ?
O2 C8 N5 122.5(4) . . ?
O2 C8 C7 119.3(4) . . ?
N5 C8 C7 118.2(4) . . ?
O4 C14 N7 122.8(5) . . ?
O4 C14 C13 119.0(4) . . ?
N7 C14 C13 118.2(4) . . ?
N4 C13 C14 108.9(4) . . ?
N4 C13 H13A 109.9 . . ?
C14 C13 H13A 109.9 . . ?
N4 C13 H13B 109.9 . . ?
C14 C13 H13B 109.9 . . ?
H13A C13 H13B 108.3 . . ?
O1 C9 N3 120.9(4) . . ?
O1 C9 C10 120.3(4) . . ?
N3 C9 C10 118.8(5) . . ?
C12 N6 H6A 120.0 . . ?
C12 N6 H6B 120.0 . . ?
H6A N6 H6B 120.0 . . ?
O7 N8 O6 119.6(6) . . ?
O7 N8 O5 120.9(6) . . ?
O6 N8 O5 119.5(6) . . ?
N1 C1 C2 120.7(5) . . ?
N1 C1 C15 116.0(4) . . ?
C2 C1 C15 123.3(5) . . ?
N1 C5 C4 120.3(5) . . ?
N1 C5 C6 115.7(4) . . ?
C4 C5 C6 124.0(5) . . ?
N4 C7 C8 108.7(4) . . ?
N4 C7 H7C 110.0 . . ?
C8 C7 H7C 110.0 . . ?
N4 C7 H7D 110.0 . . ?
C8 C7 H7D 110.0 . . ?
H7C C7 H7D 108.3 . . ?
N2 C11 C12 116.2(4) . . ?
N2 C11 H11A 108.2 . . ?
C12 C11 H11A 108.2 . . ?
N2 C11 H11B 108.2 . . ?
C12 C11 H11B 108.2 . . ?
H11A C11 H11B 107.4 . . ?
N2 C10 C9 108.2(4) . . ?
N2 C10 H10A 110.1 . . ?
C9 C10 H10A 110.1 . . ?
N2 C10 H10B 110.1 . . ?
C9 C10 H10B 110.1 . . ?
H10A C10 H10B 108.4 . . ?
N2 C15 C1 109.1(4) . . ?
N2 C15 H15A 109.9 . . ?
C1 C15 H15A 109.9 . . ?
N2 C15 H15B 109.9 . . ?
C1 C15 H15B 109.9 . . ?
H15A C15 H15B 108.3 . . ?
N4 C6 C5 111.1(4) . . ?
N4 C6 H6C 109.4 . . ?
C5 C6 H6C 109.4 . . ?
N4 C6 H6D 109.4 . . ?
C5 C6 H6D 109.4 . . ?
H6C C6 H6D 108.0 . . ?
O3 C12 N6 120.7(6) . . ?
O3 C12 C11 125.8(6) . . ?
N6 C12 C11 113.4(5) . . ?
C3 C4 C5 119.5(6) . . ?
C3 C4 H4 120.3 . . ?
C5 C4 H4 120.3 . . ?
C1 C2 C3 118.4(6) . . ?
C1 C2 H2 120.8 . . ?
C3 C2 H2 120.8 . . ?
C4 C3 C2 120.0(5) . . ?
C4 C3 H3 120.0 . . ?
C2 C3 H3 120.0 . . ?
H11C O11 H11D 104.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Co1 O2 C8 N5 179.7(3) . . . . ?
Co1 O2 C8 C7 -2.8(5) . . . . ?
Co1 O4 C14 N7 -164.8(4) . . . . ?
Co1 O4 C14 C13 12.8(5) . . . . ?
C6 N4 C13 C14 -152.5(4) . . . . ?
C7 N4 C13 C14 80.0(4) . . . . ?
Co1 N4 C13 C14 -35.3(4) . . . . ?
O4 C14 C13 N4 18.5(6) . . . . ?
N7 C14 C13 N4 -163.8(4) . . . . ?
Co1 O1 C9 N3 -172.0(3) . . . . ?
Co1 O1 C9 C10 8.4(5) . . . . ?
C5 N1 C1 C2 -6.3(6) . . . . ?
Co1 N1 C1 C2 170.8(4) . . . . ?
C5 N1 C1 C15 173.6(4) . . . . ?
Co1 N1 C1 C15 -9.3(5) . . . . ?
C1 N1 C5 C4 4.0(6) . . . . ?
Co1 N1 C5 C4 -173.1(4) . . . . ?
C1 N1 C5 C6 -176.4(4) . . . . ?
Co1 N1 C5 C6 6.5(5) . . . . ?
C13 N4 C7 C8 -149.7(4) . . . . ?
C6 N4 C7 C8 81.2(5) . . . . ?
Co1 N4 C7 C8 -35.8(4) . . . . ?
O2 C8 C7 N4 27.9(6) . . . . ?
N5 C8 C7 N4 -154.4(3) . . . . ?
C10 N2 C11 C12 59.0(6) . . . . ?
C15 N2 C11 C12 -68.5(5) . . . . ?
Co1 N2 C11 C12 176.8(4) . . . . ?
C11 N2 C10 C9 158.0(4) . . . . ?
C15 N2 C10 C9 -73.5(4) . . . . ?
Co1 N2 C10 C9 36.2(4) . . . . ?
O1 C9 C10 N2 -33.5(6) . . . . ?
N3 C9 C10 N2 146.9(4) . . . . ?
C10 N2 C15 C1 154.1(4) . . . . ?
C11 N2 C15 C1 -76.6(4) . . . . ?
Co1 N2 C15 C1 43.3(4) . . . . ?
N1 C1 C15 N2 -27.3(5) . . . . ?
C2 C1 C15 N2 152.6(5) . . . . ?
C13 N4 C6 C5 83.2(4) . . . . ?
C7 N4 C6 C5 -148.5(4) . . . . ?
Co1 N4 C6 C5 -32.2(4) . . . . ?
N1 C5 C6 N4 19.2(6) . . . . ?
C4 C5 C6 N4 -161.2(5) . . . . ?
N2 C11 C12 O3 -12.7(10) . . . . ?
N2 C11 C12 N6 171.2(5) . . . . ?
N1 C5 C4 C3 1.1(8) . . . . ?
C6 C5 C4 C3 -178.5(6) . . . . ?
N1 C1 C2 C3 3.5(8) . . . . ?
C15 C1 C2 C3 -176.4(6) . . . . ?
C5 C4 C3 C2 -3.8(10) . . . . ?
C1 C2 C3 C4 1.5(10) . . . . ?

_refine_diff_density_max         0.550
_refine_diff_density_min         -0.568
_refine_diff_density_rms         0.123

