# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2023

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 2285440'
loop_
_audit_author_name
_audit_author_address
'jian zhou'
;Chongqing Normal University
China
;
_audit_update_record             
;
2023-07-30 deposited with the CCDC.	2023-09-28 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C12 H36 Dy N8, Sb Se4'
_chemical_formula_sum            'C12 H36 Dy N8 Sb Se4'
_chemical_formula_weight         892.59

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Se Se -0.0929 2.2259 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   9.2552(5)
_cell_length_b                   13.4633(6)
_cell_length_c                   19.6938(9)
_cell_angle_alpha                90
_cell_angle_beta                 92.7433(19)
_cell_angle_gamma                90
_cell_volume                     2451.1(2)
_cell_formula_units_Z            4
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    6380
_cell_measurement_theta_min      2.83
_cell_measurement_theta_max      27.67

_exptl_crystal_description       block
_exptl_crystal_colour            red
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    2.419
_exptl_crystal_F_000             1668
_exptl_transmission_factor_min   0.516
_exptl_transmission_factor_max   0.673
_exptl_crystal_size_max          0.066
_exptl_crystal_size_mid          0.062
_exptl_crystal_size_min          0.039
_exptl_absorpt_coefficient_mu    10.081
_shelx_estimated_absorpt_T_min   0.556
_shelx_estimated_absorpt_T_max   0.695
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   'SADABS 2014/5'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            22640
_diffrn_reflns_av_unetI/netI     0.0438
_diffrn_reflns_av_R_equivalents  0.0664
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_theta_min         2.565
_diffrn_reflns_theta_max         25.092
_diffrn_reflns_theta_full        25.092
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             4352
_reflns_number_gt                3426
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_computing_structure_refinement  'SHELXL-2014 (Sheldrick 2014)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0162P)²+0.7658P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         4352
_refine_ls_number_parameters     235
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0478
_refine_ls_R_factor_gt           0.0292
_refine_ls_wR_factor_ref         0.0503
_refine_ls_wR_factor_gt          0.0458
_refine_ls_goodness_of_fit_ref   1.024
_refine_ls_restrained_S_all      1.024
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.25933(3) 0.25698(2) 0.35583(2) 0.01343(7) Uani 1 1 d . . . . .
Sb1 Sb 0.70449(4) 0.27166(2) 0.62287(2) 0.01673(9) Uani 1 1 d . . . . .
Se1 Se 0.59288(7) 0.11379(4) 0.65783(3) 0.03377(17) Uani 1 1 d . . . . .
Se2 Se 0.52845(7) 0.38317(4) 0.56402(3) 0.02846(15) Uani 1 1 d . . . . .
Se3 Se 0.90421(6) 0.23707(5) 0.54839(3) 0.03244(16) Uani 1 1 d . . . . .
Se4 Se 0.78729(7) 0.36347(4) 0.72700(3) 0.02644(15) Uani 1 1 d . . . . .
N1 N 0.0064(5) 0.1874(3) 0.3747(2) 0.0249(11) Uani 1 1 d . . . . .
H1A H -0.0331 0.2211 0.4080 0.030 Uiso 1 1 calc R U . . .
H1B H -0.0493 0.1956 0.3370 0.030 Uiso 1 1 calc R U . . .
N2 N 0.2670(5) 0.0995(3) 0.4233(2) 0.0206(11) Uani 1 1 d . . . . .
H2 H 0.2993 0.0482 0.3921 0.025 Uiso 1 1 calc R U . . .
N3 N 0.4960(4) 0.2384(3) 0.4191(2) 0.0185(10) Uani 1 1 d . . . . .
H3 H 0.4912 0.2833 0.4581 0.022 Uiso 1 1 calc R U . . .
N4 N 0.4458(5) 0.3837(3) 0.3209(2) 0.0285(12) Uani 1 1 d . . . . .
H4A H 0.4587 0.3765 0.2766 0.034 Uiso 1 1 calc R U . . .
H4B H 0.4102 0.4442 0.3270 0.034 Uiso 1 1 calc R U . . .
N5 N 0.2069(5) 0.3365(3) 0.4668(2) 0.0234(11) Uani 1 1 d . . . . .
H5A H 0.1423 0.2998 0.4876 0.028 Uiso 1 1 calc R U . . .
H5B H 0.2876 0.3380 0.4932 0.028 Uiso 1 1 calc R U . . .
N6 N 0.1094(5) 0.4093(3) 0.3380(2) 0.0196(10) Uani 1 1 d . . . . .
H6 H 0.1780 0.4619 0.3275 0.023 Uiso 1 1 calc R U . . .
N7 N 0.1417(5) 0.2612(3) 0.2385(2) 0.0212(10) Uani 1 1 d . . . . .
H7 H 0.0552 0.2196 0.2402 0.025 Uiso 1 1 calc R U . . .
N8 N 0.3874(5) 0.1431(3) 0.2754(2) 0.0333(13) Uani 1 1 d . . . . .
H8A H 0.4687 0.1718 0.2631 0.040 Uiso 1 1 calc R U . . .
H8B H 0.4108 0.0866 0.2966 0.040 Uiso 1 1 calc R U . . .
C1 C 0.0121(6) 0.0802(4) 0.3926(3) 0.0295(15) Uani 1 1 d . . . . .
H1C H 0.0332 0.0413 0.3528 0.035 Uiso 1 1 calc R U . . .
H1D H -0.0808 0.0590 0.4082 0.035 Uiso 1 1 calc R U . . .
C2 C 0.1266(6) 0.0636(4) 0.4472(3) 0.0284(15) Uani 1 1 d . . . . .
H2A H 0.1026 0.0992 0.4880 0.034 Uiso 1 1 calc R U . . .
H2B H 0.1332 -0.0066 0.4580 0.034 Uiso 1 1 calc R U . . .
C3 C 0.3806(6) 0.1050(4) 0.4782(3) 0.0287(14) Uani 1 1 d . . . . .
H3A H 0.3939 0.0403 0.4992 0.034 Uiso 1 1 calc R U . . .
H3B H 0.3521 0.1515 0.5128 0.034 Uiso 1 1 calc R U . . .
C4 C 0.5201(6) 0.1388(4) 0.4490(3) 0.0279(14) Uani 1 1 d . . . . .
H4C H 0.5963 0.1415 0.4845 0.033 Uiso 1 1 calc R U . . .
H4D H 0.5489 0.0926 0.4144 0.033 Uiso 1 1 calc R U . . .
C5 C 0.6207(6) 0.2735(4) 0.3817(3) 0.0245(13) Uani 1 1 d . . . . .
H5C H 0.6357 0.2305 0.3431 0.029 Uiso 1 1 calc R U . . .
H5D H 0.7077 0.2728 0.4111 0.029 Uiso 1 1 calc R U . . .
C6 C 0.5886(6) 0.3770(4) 0.3578(3) 0.0313(15) Uani 1 1 d . . . . .
H6A H 0.5903 0.4213 0.3967 0.038 Uiso 1 1 calc R U . . .
H6B H 0.6633 0.3984 0.3281 0.038 Uiso 1 1 calc R U . . .
C7 C 0.1503(7) 0.4390(4) 0.4582(3) 0.0343(16) Uani 1 1 d . . . . .
H7A H 0.2294 0.4839 0.4495 0.041 Uiso 1 1 calc R U . . .
H7B H 0.1069 0.4601 0.4996 0.041 Uiso 1 1 calc R U . . .
C8 C 0.0396(6) 0.4435(4) 0.4000(3) 0.0307(15) Uani 1 1 d . . . . .
H8C H -0.0420 0.4011 0.4092 0.037 Uiso 1 1 calc R U . . .
H8D H 0.0047 0.5110 0.3939 0.037 Uiso 1 1 calc R U . . .
C9 C 0.0089(6) 0.4035(4) 0.2782(3) 0.0281(14) Uani 1 1 d . . . . .
H9A H -0.0284 0.4690 0.2669 0.034 Uiso 1 1 calc R U . . .
H9B H -0.0720 0.3607 0.2878 0.034 Uiso 1 1 calc R U . . .
C10 C 0.0892(7) 0.3619(4) 0.2192(3) 0.0295(14) Uani 1 1 d . . . . .
H10A H 0.0252 0.3583 0.1789 0.035 Uiso 1 1 calc R U . . .
H10B H 0.1702 0.4045 0.2096 0.035 Uiso 1 1 calc R U . . .
C11 C 0.2314(7) 0.2159(4) 0.1861(3) 0.0289(14) Uani 1 1 d . . . . .
H11A H 0.3083 0.2611 0.1748 0.035 Uiso 1 1 calc R U . . .
H11B H 0.1723 0.2025 0.1452 0.035 Uiso 1 1 calc R U . . .
C12 C 0.2942(7) 0.1213(4) 0.2143(3) 0.0329(15) Uani 1 1 d . . . . .
H12A H 0.2170 0.0767 0.2259 0.039 Uiso 1 1 calc R U . . .
H12B H 0.3506 0.0891 0.1803 0.039 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 N3 2.481(4) . ?
Dy1 N6 2.492(4) . ?
Dy1 N2 2.501(4) . ?
Dy1 N5 2.502(4) . ?
Dy1 N7 2.507(4) . ?
Dy1 N8 2.539(4) . ?
Dy1 N4 2.545(4) . ?
Dy1 N1 2.565(4) . ?
Sb1 Se3 2.4586(6) . ?
Sb1 Se2 2.4639(7) . ?
Sb1 Se1 2.4753(7) . ?
Sb1 Se4 2.4840(7) . ?
N1 C1 1.486(7) . ?
N1 H1A 0.8900 . ?
N1 H1B 0.8900 . ?
N2 C3 1.474(7) . ?
N2 C2 1.484(6) . ?
N2 H2 0.9800 . ?
N3 C4 1.477(6) . ?
N3 C5 1.477(6) . ?
N3 H3 0.9800 . ?
N4 C6 1.481(7) . ?
N4 H4A 0.8900 . ?
N4 H4B 0.8900 . ?
N5 C7 1.483(7) . ?
N5 H5A 0.8900 . ?
N5 H5B 0.8900 . ?
N6 C9 1.467(7) . ?
N6 C8 1.481(6) . ?
N6 H6 0.9800 . ?
N7 C10 1.483(6) . ?
N7 C11 1.485(6) . ?
N7 H7 0.9800 . ?
N8 C12 1.477(7) . ?
N8 H8A 0.8900 . ?
N8 H8B 0.8900 . ?
C1 C2 1.489(8) . ?
C1 H1C 0.9700 . ?
C1 H1D 0.9700 . ?
C2 H2A 0.9700 . ?
C2 H2B 0.9700 . ?
C3 C4 1.508(7) . ?
C3 H3A 0.9700 . ?
C3 H3B 0.9700 . ?
C4 H4C 0.9700 . ?
C4 H4D 0.9700 . ?
C5 C6 1.495(7) . ?
C5 H5C 0.9700 . ?
C5 H5D 0.9700 . ?
C6 H6A 0.9700 . ?
C6 H6B 0.9700 . ?
C7 C8 1.501(8) . ?
C7 H7A 0.9700 . ?
C7 H7B 0.9700 . ?
C8 H8C 0.9700 . ?
C8 H8D 0.9700 . ?
C9 C10 1.516(7) . ?
C9 H9A 0.9700 . ?
C9 H9B 0.9700 . ?
C10 H10A 0.9700 . ?
C10 H10B 0.9700 . ?
C11 C12 1.495(8) . ?
C11 H11A 0.9700 . ?
C11 H11B 0.9700 . ?
C12 H12A 0.9700 . ?
C12 H12B 0.9700 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N3 Dy1 N6 128.78(14) . . ?
N3 Dy1 N2 69.25(14) . . ?
N6 Dy1 N2 140.70(13) . . ?
N3 Dy1 N5 78.91(14) . . ?
N6 Dy1 N5 68.95(14) . . ?
N2 Dy1 N5 84.29(14) . . ?
N3 Dy1 N7 143.07(13) . . ?
N6 Dy1 N7 68.73(13) . . ?
N2 Dy1 N7 120.58(14) . . ?
N5 Dy1 N7 134.55(14) . . ?
N3 Dy1 N8 79.93(15) . . ?
N6 Dy1 N8 133.07(14) . . ?
N2 Dy1 N8 79.46(14) . . ?
N5 Dy1 N8 156.82(15) . . ?
N7 Dy1 N8 68.52(14) . . ?
N3 Dy1 N4 67.02(14) . . ?
N6 Dy1 N4 77.92(14) . . ?
N2 Dy1 N4 135.20(14) . . ?
N5 Dy1 N4 96.44(15) . . ?
N7 Dy1 N4 90.31(15) . . ?
N8 Dy1 N4 83.85(15) . . ?
N3 Dy1 N1 132.88(14) . . ?
N6 Dy1 N1 79.33(14) . . ?
N2 Dy1 N1 67.43(14) . . ?
N5 Dy1 N1 79.24(14) . . ?
N7 Dy1 N1 77.46(14) . . ?
N8 Dy1 N1 109.05(15) . . ?
N4 Dy1 N1 156.86(14) . . ?
Se3 Sb1 Se2 109.51(2) . . ?
Se3 Sb1 Se1 109.81(2) . . ?
Se2 Sb1 Se1 112.25(3) . . ?
Se3 Sb1 Se4 112.07(2) . . ?
Se2 Sb1 Se4 104.84(2) . . ?
Se1 Sb1 Se4 108.31(2) . . ?
C1 N1 Dy1 111.5(3) . . ?
C1 N1 H1A 109.3 . . ?
Dy1 N1 H1A 109.3 . . ?
C1 N1 H1B 109.3 . . ?
Dy1 N1 H1B 109.3 . . ?
H1A N1 H1B 108.0 . . ?
C3 N2 C2 112.8(4) . . ?
C3 N2 Dy1 110.4(3) . . ?
C2 N2 Dy1 116.2(3) . . ?
C3 N2 H2 105.5 . . ?
C2 N2 H2 105.5 . . ?
Dy1 N2 H2 105.5 . . ?
C4 N3 C5 112.5(4) . . ?
C4 N3 Dy1 113.9(3) . . ?
C5 N3 Dy1 114.1(3) . . ?
C4 N3 H3 105.0 . . ?
C5 N3 H3 105.0 . . ?
Dy1 N3 H3 105.0 . . ?
C6 N4 Dy1 115.3(3) . . ?
C6 N4 H4A 108.5 . . ?
Dy1 N4 H4A 108.5 . . ?
C6 N4 H4B 108.5 . . ?
Dy1 N4 H4B 108.5 . . ?
H4A N4 H4B 107.5 . . ?
C7 N5 Dy1 112.3(3) . . ?
C7 N5 H5A 109.1 . . ?
Dy1 N5 H5A 109.1 . . ?
C7 N5 H5B 109.1 . . ?
Dy1 N5 H5B 109.1 . . ?
H5A N5 H5B 107.9 . . ?
C9 N6 C8 113.2(4) . . ?
C9 N6 Dy1 113.3(3) . . ?
C8 N6 Dy1 113.7(3) . . ?
C9 N6 H6 105.2 . . ?
C8 N6 H6 105.2 . . ?
Dy1 N6 H6 105.2 . . ?
C10 N7 C11 112.7(4) . . ?
C10 N7 Dy1 112.3(3) . . ?
C11 N7 Dy1 113.5(3) . . ?
C10 N7 H7 105.9 . . ?
C11 N7 H7 105.9 . . ?
Dy1 N7 H7 105.9 . . ?
C12 N8 Dy1 110.9(3) . . ?
C12 N8 H8A 109.5 . . ?
Dy1 N8 H8A 109.5 . . ?
C12 N8 H8B 109.5 . . ?
Dy1 N8 H8B 109.5 . . ?
H8A N8 H8B 108.1 . . ?
N1 C1 C2 109.5(4) . . ?
N1 C1 H1C 109.8 . . ?
C2 C1 H1C 109.8 . . ?
N1 C1 H1D 109.8 . . ?
C2 C1 H1D 109.8 . . ?
H1C C1 H1D 108.2 . . ?
N2 C2 C1 109.0(4) . . ?
N2 C2 H2A 109.9 . . ?
C1 C2 H2A 109.9 . . ?
N2 C2 H2B 109.9 . . ?
C1 C2 H2B 109.9 . . ?
H2A C2 H2B 108.3 . . ?
N2 C3 C4 109.2(4) . . ?
N2 C3 H3A 109.8 . . ?
C4 C3 H3A 109.8 . . ?
N2 C3 H3B 109.8 . . ?
C4 C3 H3B 109.8 . . ?
H3A C3 H3B 108.3 . . ?
N3 C4 C3 108.1(4) . . ?
N3 C4 H4C 110.1 . . ?
C3 C4 H4C 110.1 . . ?
N3 C4 H4D 110.1 . . ?
C3 C4 H4D 110.1 . . ?
H4C C4 H4D 108.4 . . ?
N3 C5 C6 107.9(4) . . ?
N3 C5 H5C 110.1 . . ?
C6 C5 H5C 110.1 . . ?
N3 C5 H5D 110.1 . . ?
C6 C5 H5D 110.1 . . ?
H5C C5 H5D 108.4 . . ?
N4 C6 C5 111.7(5) . . ?
N4 C6 H6A 109.3 . . ?
C5 C6 H6A 109.3 . . ?
N4 C6 H6B 109.3 . . ?
C5 C6 H6B 109.3 . . ?
H6A C6 H6B 107.9 . . ?
N5 C7 C8 110.5(5) . . ?
N5 C7 H7A 109.6 . . ?
C8 C7 H7A 109.6 . . ?
N5 C7 H7B 109.6 . . ?
C8 C7 H7B 109.6 . . ?
H7A C7 H7B 108.1 . . ?
N6 C8 C7 107.9(4) . . ?
N6 C8 H8C 110.1 . . ?
C7 C8 H8C 110.1 . . ?
N6 C8 H8D 110.1 . . ?
C7 C8 H8D 110.1 . . ?
H8C C8 H8D 108.4 . . ?
N6 C9 C10 108.6(4) . . ?
N6 C9 H9A 110.0 . . ?
C10 C9 H9A 110.0 . . ?
N6 C9 H9B 110.0 . . ?
C10 C9 H9B 110.0 . . ?
H9A C9 H9B 108.3 . . ?
N7 C10 C9 108.0(4) . . ?
N7 C10 H10A 110.1 . . ?
C9 C10 H10A 110.1 . . ?
N7 C10 H10B 110.1 . . ?
C9 C10 H10B 110.1 . . ?
H10A C10 H10B 108.4 . . ?
N7 C11 C12 108.2(4) . . ?
N7 C11 H11A 110.1 . . ?
C12 C11 H11A 110.1 . . ?
N7 C11 H11B 110.1 . . ?
C12 C11 H11B 110.1 . . ?
H11A C11 H11B 108.4 . . ?
N8 C12 C11 109.6(5) . . ?
N8 C12 H12A 109.8 . . ?
C11 C12 H12A 109.8 . . ?
N8 C12 H12B 109.8 . . ?
C11 C12 H12B 109.8 . . ?
H12A C12 H12B 108.2 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Dy1 N1 C1 C2 48.1(5) . . . . ?
C3 N2 C2 C1 168.4(4) . . . . ?
Dy1 N2 C2 C1 39.4(5) . . . . ?
N1 C1 C2 N2 -57.6(6) . . . . ?
C2 N2 C3 C4 178.2(4) . . . . ?
Dy1 N2 C3 C4 -50.0(5) . . . . ?
C5 N3 C4 C3 -173.0(4) . . . . ?
Dy1 N3 C4 C3 -41.1(5) . . . . ?
N2 C3 C4 N3 60.8(6) . . . . ?
C4 N3 C5 C6 -176.2(4) . . . . ?
Dy1 N3 C5 C6 52.0(5) . . . . ?
Dy1 N4 C6 C5 28.2(6) . . . . ?
N3 C5 C6 N4 -51.6(6) . . . . ?
Dy1 N5 C7 C8 43.6(5) . . . . ?
C9 N6 C8 C7 175.9(4) . . . . ?
Dy1 N6 C8 C7 44.7(5) . . . . ?
N5 C7 C8 N6 -58.4(6) . . . . ?
C8 N6 C9 C10 -176.5(4) . . . . ?
Dy1 N6 C9 C10 -45.2(5) . . . . ?
C11 N7 C10 C9 -175.9(5) . . . . ?
Dy1 N7 C10 C9 -46.4(5) . . . . ?
N6 C9 C10 N7 60.6(6) . . . . ?
C10 N7 C11 C12 172.7(5) . . . . ?
Dy1 N7 C11 C12 43.8(5) . . . . ?
Dy1 N8 C12 C11 48.1(5) . . . . ?
N7 C11 C12 N8 -61.4(6) . . . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
N1 H1A Se3 0.89 2.86 3.654(4) 149.3 1_455
N1 H1B Se4 0.89 2.70 3.532(5) 155.8 4_465
N2 H2 Se1 0.98 2.61 3.560(4) 163.4 3_656
N3 H3 Se2 0.98 2.49 3.457(4) 168.3 .
N4 H4A Se1 0.89 2.70 3.547(4) 158.4 4_565
N5 H5A Se3 0.89 2.69 3.557(4) 163.8 1_455
N5 H5B Se2 0.89 2.64 3.517(4) 167.7 .
N6 H6 Se4 0.98 2.61 3.468(4) 146.2 3_666
N7 H7 Se4 0.98 2.72 3.682(4) 167.0 4_465
N8 H8A Se4 0.89 3.10 3.867(5) 145.2 4_565
N8 H8B Se1 0.89 2.84 3.701(5) 162.4 3_656

_refine_diff_density_max         0.670
_refine_diff_density_min         -0.974
_refine_diff_density_rms         0.153

