# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2023

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_sdv_ptcomplex
_database_code_depnum_ccdc_archive 'CCDC 2259177'
loop_
_audit_author_name
_audit_author_address
'Dr. Joydev Dinda'
;Utkal University, Bhubaneswar, India
India
;
_audit_update_record             
;
2023-04-26 deposited with the CCDC.	2023-12-05 downloaded from the CCDC.
;
_audit_creation_date             2022-12-03
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6272)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C63 H60 Ag3 N18, 3(F6 P1), 0.5(C4 H4 N2)'
_chemical_formula_sum            'C65 H62 Ag3 F18 N19 P3'
_chemical_formula_weight         1867.85
_chemical_melting_point          ?
_chemical_oxdiff_formula         'C H N P F Ag'
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      trigonal
_space_group_IT_number           165
_space_group_name_H-M_alt        'P -3 c 1'
_space_group_name_Hall           '-P 3 2"c'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'y, x, -z+1/2'
'x-y, -y, -z+1/2'
'-x, -x+y, -z+1/2'
'-x, -y, -z'
'y, -x+y, -z'
'x-y, x, -z'
'-y, -x, z-1/2'
'-x+y, y, z-1/2'
'x, x-y, z-1/2'

_cell_length_a                   23.0541(3)
_cell_length_b                   23.0541(3)
_cell_length_c                   23.7591(4)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_volume                     10936.0(3)
_cell_formula_units_Z            6
_cell_measurement_reflns_used    34615
_cell_measurement_temperature    100.01(10)
_cell_measurement_theta_max      30.6820
_cell_measurement_theta_min      1.9630
_shelx_estimated_absorpt_T_max   0.910
_shelx_estimated_absorpt_T_min   0.830
_exptl_absorpt_coefficient_mu    0.965
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.52328
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.40.67a (Rigaku Oxford Diffraction, 2019)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            white
_exptl_crystal_colour_lustre     .
_exptl_crystal_colour_modifier   .
_exptl_crystal_colour_primary    white
_exptl_crystal_density_diffrn    1.702
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             5598
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.1
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0345
_diffrn_reflns_av_unetI/netI     0.0183
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.854
_diffrn_reflns_limit_h_max       28
_diffrn_reflns_limit_h_min       -29
_diffrn_reflns_limit_k_max       32
_diffrn_reflns_limit_k_min       -31
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            81962
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.854
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         30.589
_diffrn_reflns_theta_min         1.964
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      100.01(10)
_diffrn_detector                 'Hybrid Pixel Array Detector'
_diffrn_detector_area_resol_mean 5.8140
_diffrn_detector_type            'Pilatus 200K'
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.854
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω    -72.00  -1.00   0.50   80.18    --   -4.29 -31.00 -59.00  142
  2  ω      1.00  67.00   0.50   80.18    --    3.67  37.00 150.00  132
  3  ω     -8.00  55.00   0.50   80.18    --    3.67  57.00   0.00  126
  4  ω    -14.00  27.00   0.50   80.18    --   -4.29 -99.00-150.00   82
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  
'SuperNova, Dual, Cu at home/near, Pilatus 200K'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.0325015000
_diffrn_orient_matrix_UB_12      -0.0205809000
_diffrn_orient_matrix_UB_13      0.0112946000
_diffrn_orient_matrix_UB_21      -0.0033959000
_diffrn_orient_matrix_UB_22      0.0286467000
_diffrn_orient_matrix_UB_23      0.0040922000
_diffrn_orient_matrix_UB_31      -0.0139304000
_diffrn_orient_matrix_UB_32      -0.0042117000
_diffrn_orient_matrix_UB_33      -0.0273216000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'SuperNova (Mo) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                8104
_reflns_number_total             9586
_reflns_odcompleteness_completeness 99.90
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     26.32
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.40.67a (Rigaku OD, 2019)'
_computing_data_collection       'CrysAlisPro 1.171.40.67a (Rigaku OD, 2019)'
_computing_data_reduction        'CrysAlisPro 1.171.40.67a (Rigaku OD, 2019)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         1.207
_refine_diff_density_min         -0.865
_refine_diff_density_rms         0.089
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.023
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     501
_refine_ls_number_reflns         9586
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0413
_refine_ls_R_factor_gt           0.0324
_refine_ls_restrained_S_all      1.023
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0319P)²+21.7346P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0760
_refine_ls_wR_factor_ref         0.0813
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Others
 Fixed Sof: N10(0.5) H33A(0.5) H33B(0.5) C34(0.5)
3.a Secondary CH2 refined with riding coordinates:
 C30(H30A,H30B), C9(H9A,H9B), C13(H13A,H13B), C33(H33A,H33B)
3.b Aromatic/amide H refined with riding coordinates:
 C32(H32), C10(H10), C11(H11), C16(H16), C2(H2), C19(H19), C23(H23), C17(H17),
 C18(H18), C26(H26), C3(H3), C5(H5), C24(H24), C4(H4), C25(H25)
3.c Idealised Me refined as rotating group:
 C8(H8A,H8B,H8C), C29(H29A,H29B,H29C), C21(H21A,H21B,H21C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag2 Ag 0.93103(2) 1.000000 0.250000 0.01209(5) Uani 1 2 d S T P . .
Ag1 Ag 0.33034(2) 0.59578(2) 0.26886(2) 0.01318(5) Uani 1 1 d . . . . .
P3 P 1.000000 1.000000 0.500000 0.0147(2) Uani 1 6 d S T P . .
P2 P 0.333333 0.666667 0.51374(4) 0.01775(18) Uani 1 3 d S T P . .
P1 P 0.67121(3) 0.67067(3) 0.40880(3) 0.02277(12) Uani 1 1 d . . . . .
F9 F 0.93482(7) 0.96207(8) 0.46093(6) 0.0270(3) Uani 1 1 d . . . . .
F7 F 0.37099(8) 0.63917(8) 0.47497(6) 0.0299(3) Uani 1 1 d . . . . .
F8 F 0.30598(9) 0.60155(8) 0.55286(7) 0.0360(4) Uani 1 1 d . . . . .
F1 F 0.67496(8) 0.66520(7) 0.34157(6) 0.0358(4) Uani 1 1 d . . . . .
F3 F 0.66645(8) 0.67613(9) 0.47511(6) 0.0406(4) Uani 1 1 d . . . . .
N9 N 0.84847(9) 0.85534(8) 0.20539(7) 0.0146(3) Uani 1 1 d . . . . .
N3 N 0.47298(9) 0.65504(9) 0.21806(8) 0.0162(3) Uani 1 1 d . . . . .
N8 N 0.81784(9) 0.94256(9) 0.09053(8) 0.0189(4) Uani 1 1 d . . . . .
N1 N 0.34161(9) 0.54072(9) 0.19112(8) 0.0195(4) Uani 1 1 d . . . . .
N6 N 0.51822(9) 0.77682(9) 0.42836(7) 0.0181(4) Uani 1 1 d . . . . .
N4 N 0.48485(9) 0.66601(9) 0.30717(8) 0.0173(3) Uani 1 1 d . . . . .
N2 N 0.38606(9) 0.53366(9) 0.10978(8) 0.0170(3) Uani 1 1 d . . . . .
N7 N 0.85910(10) 0.98241(9) 0.17580(8) 0.0202(4) Uani 1 1 d . . . . .
F2 F 0.63362(14) 0.71118(15) 0.39909(8) 0.0736(8) Uani 1 1 d . . . . .
N5 N 0.47769(10) 0.78216(9) 0.34429(8) 0.0200(4) Uani 1 1 d . . . . .
C31 C 0.88827(12) 0.88827(12) 0.250000 0.0132(5) Uani 1 2 d S T P . .
C12 C 0.44282(11) 0.66116(10) 0.26514(9) 0.0152(4) Uani 1 1 d . . . . .
C30 C 0.86226(11) 0.88037(11) 0.14751(8) 0.0173(4) Uani 1 1 d . . . . .
H30A H 0.835484 0.843008 0.121268 0.021 Uiso 1 1 calc R U . . .
H30B H 0.910210 0.897807 0.138991 0.021 Uiso 1 1 calc R U . . .
C9 C 0.44383(11) 0.64448(10) 0.16160(9) 0.0176(4) Uani 1 1 d . . . . .
H9A H 0.479231 0.656216 0.133012 0.021 Uiso 1 1 calc R U . . .
H9B H 0.424563 0.673996 0.155970 0.021 Uiso 1 1 calc R U . . .
C7 C 0.38995(11) 0.57251(10) 0.15434(9) 0.0162(4) Uani 1 1 d . . . . .
C28 C 0.84566(10) 0.93511(11) 0.13854(9) 0.0167(4) Uani 1 1 d . . . . .
F6 F 0.73999(10) 0.73870(14) 0.40834(8) 0.0927(11) Uani 1 1 d . . . . .
C32 C 0.79195(11) 0.79659(10) 0.22195(9) 0.0196(4) Uani 1 1 d . . . . .
H32 H 0.756807 0.765658 0.198316 0.024 Uiso 1 1 calc R U . . .
C20 C 0.52135(10) 0.83831(11) 0.42609(9) 0.0189(4) Uani 1 1 d . . . . .
C14 C 0.49111(10) 0.74557(11) 0.37869(9) 0.0178(4) Uani 1 1 d . . . . .
C13 C 0.47434(12) 0.67508(11) 0.36641(9) 0.0200(4) Uani 1 1 d . . . . .
H13A H 0.502635 0.663704 0.390025 0.024 Uiso 1 1 calc R U . . .
H13B H 0.426954 0.644051 0.376404 0.024 Uiso 1 1 calc R U . . .
C27 C 0.81406(10) 1.00027(12) 0.09730(10) 0.0220(5) Uani 1 1 d . . . . .
C10 C 0.53207(11) 0.65647(12) 0.23041(10) 0.0227(5) Uani 1 1 d . . . . .
H10 H 0.561488 0.652960 0.204432 0.027 Uiso 1 1 calc R U . . .
C6 C 0.33013(11) 0.47150(11) 0.11875(10) 0.0200(4) Uani 1 1 d . . . . .
C1 C 0.30276(11) 0.47646(11) 0.16985(10) 0.0207(4) Uani 1 1 d . . . . .
C11 C 0.53985(11) 0.66382(12) 0.28659(10) 0.0231(5) Uani 1 1 d . . . . .
H11 H 0.576110 0.666909 0.307970 0.028 Uiso 1 1 calc R U . . .
C15 C 0.49654(10) 0.84128(11) 0.37306(9) 0.0184(4) Uani 1 1 d . . . . .
C22 C 0.83927(11) 1.02431(11) 0.15100(10) 0.0226(5) Uani 1 1 d . . . . .
C16 C 0.49308(11) 0.89747(11) 0.35681(11) 0.0239(5) Uani 1 1 d . . . . .
H16 H 0.477120 0.900404 0.320656 0.029 Uiso 1 1 calc R U . . .
C2 C 0.24524(12) 0.42208(12) 0.19197(12) 0.0299(5) Uani 1 1 d . . . . .
H2 H 0.226722 0.425039 0.226834 0.036 Uiso 1 1 calc R U . . .
C19 C 0.54321(11) 0.89039(12) 0.46497(10) 0.0241(5) Uani 1 1 d . . . . .
H19 H 0.560399 0.888191 0.500757 0.029 Uiso 1 1 calc R U . . .
C23 C 0.84136(13) 1.08170(13) 0.17226(13) 0.0315(6) Uani 1 1 d . . . . .
H23 H 0.858005 1.098022 0.208901 0.038 Uiso 1 1 calc R U . . .
C17 C 0.51393(12) 0.94901(12) 0.39566(11) 0.0275(5) Uani 1 1 d . . . . .
H17 H 0.511462 0.987732 0.386104 0.033 Uiso 1 1 calc R U . . .
C8 C 0.42940(13) 0.55493(12) 0.06018(9) 0.0231(5) Uani 1 1 d . . . . .
H8A H 0.426950 0.591460 0.041333 0.035 Uiso 1 1 calc R U . . .
H8B H 0.414591 0.517087 0.034216 0.035 Uiso 1 1 calc R U . . .
H8C H 0.475694 0.570505 0.071741 0.035 Uiso 1 1 calc R U . . .
C29 C 0.79673(11) 0.89937(13) 0.04085(9) 0.0249(5) Uani 1 1 d . . . . .
H29A H 0.835181 0.897629 0.025247 0.037 Uiso 1 1 calc R U . . .
H29B H 0.779081 0.917392 0.012514 0.037 Uiso 1 1 calc R U . . .
H29C H 0.761771 0.854134 0.051478 0.037 Uiso 1 1 calc R U . . .
C21 C 0.53821(12) 0.75114(12) 0.47648(9) 0.0229(5) Uani 1 1 d . . . . .
H21A H 0.561287 0.786935 0.504252 0.034 Uiso 1 1 calc R U . . .
H21B H 0.568389 0.735391 0.463714 0.034 Uiso 1 1 calc R U . . .
H21C H 0.498334 0.713889 0.493699 0.034 Uiso 1 1 calc R U . . .
C18 C 0.53849(12) 0.94534(13) 0.44858(11) 0.0286(5) Uani 1 1 d . . . . .
H18 H 0.552333 0.981736 0.473989 0.034 Uiso 1 1 calc R U . . .
F5 F 0.60216(15) 0.60439(13) 0.40924(10) 0.1210(15) Uani 1 1 d . . . . .
C26 C 0.78967(12) 1.03200(14) 0.06239(12) 0.0325(6) Uani 1 1 d . . . . .
H26 H 0.771949 1.015200 0.026091 0.039 Uiso 1 1 calc R U . . .
C3 C 0.21643(14) 0.36361(13) 0.16075(14) 0.0386(7) Uani 1 1 d . . . . .
H3 H 0.176732 0.325715 0.174136 0.046 Uiso 1 1 calc R U . . .
C5 C 0.30189(13) 0.41214(12) 0.08778(11) 0.0284(5) Uani 1 1 d . . . . .
H5 H 0.321070 0.408476 0.053520 0.034 Uiso 1 1 calc R U . . .
C24 C 0.81801(14) 1.11384(14) 0.13742(15) 0.0405(7) Uani 1 1 d . . . . .
H24 H 0.819136 1.153416 0.150263 0.049 Uiso 1 1 calc R U . . .
C4 C 0.24450(15) 0.35907(13) 0.10984(14) 0.0383(7) Uani 1 1 d . . . . .
H4 H 0.223242 0.317939 0.089744 0.046 Uiso 1 1 calc R U . . .
C25 C 0.79281(14) 1.08913(15) 0.08370(14) 0.0414(7) Uani 1 1 d . . . . .
H25 H 0.777299 1.112602 0.061093 0.050 Uiso 1 1 calc R U . . .
F4 F 0.7063(2) 0.6289(2) 0.41713(12) 0.1449(18) Uani 1 1 d . . . . .
N10 N 0.4473(4) 0.4861(4) 0.2204(3) 0.0599(17) Uani 0.5 1 d . . P . .
C33 C 0.3625(4) 0.3625(4) 0.250000 0.126(4) Uani 1 2 d S T P . .
H33A H 0.324009 0.355319 0.273480 0.151 Uiso 0.5 1 calc R U P . .
H33B H 0.355319 0.324009 0.226520 0.151 Uiso 0.5 1 calc R U P . .
C34 C 0.4091(4) 0.4316(5) 0.2288(3) 0.0574(19) Uani 0.5 1 d . . P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag2 Ag2 2.7539(3) 2_765 ?
Ag2 Ag2 2.7539(3) 3_675 ?
Ag2 N7 2.3129(18) . ?
Ag2 N7 2.3129(18) 5_675 ?
Ag2 C31 2.251(2) 3_675 ?
Ag2 C31 2.251(2) . ?
Ag1 Ag1 2.7725(3) 2_665 ?
Ag1 Ag1 2.7726(3) 3_565 ?
Ag1 N1 2.3281(18) . ?
Ag1 N5 2.3294(18) 3_565 ?
Ag1 C12 2.257(2) . ?
Ag1 C12 2.273(2) 3_565 ?
P3 F9 1.6032(13) 3_675 ?
P3 F9 1.6032(13) 8_566 ?
P3 F9 1.6032(13) 2_765 ?
P3 F9 1.6032(13) 9_656 ?
P3 F9 1.6032(13) 7_776 ?
P3 F9 1.6032(13) . ?
P2 F7 1.5983(15) 2_665 ?
P2 F7 1.5983(15) 3_565 ?
P2 F7 1.5983(15) . ?
P2 F8 1.6027(15) 3_565 ?
P2 F8 1.6027(15) . ?
P2 F8 1.6027(15) 2_665 ?
P1 F1 1.6080(16) . ?
P1 F3 1.5887(16) . ?
P1 F2 1.577(2) . ?
P1 F6 1.577(2) . ?
P1 F5 1.561(2) . ?
P1 F4 1.551(2) . ?
N9 C31 1.358(2) . ?
N9 C30 1.463(3) . ?
N9 C32 1.386(3) . ?
N3 C12 1.361(3) . ?
N3 C9 1.465(3) . ?
N3 C10 1.378(3) . ?
N8 C28 1.361(3) . ?
N8 C27 1.385(3) . ?
N8 C29 1.462(3) . ?
N1 C7 1.314(3) . ?
N1 C1 1.388(3) . ?
N6 C20 1.384(3) . ?
N6 C14 1.361(3) . ?
N6 C21 1.464(3) . ?
N4 C12 1.357(3) . ?
N4 C13 1.461(3) . ?
N4 C11 1.383(3) . ?
N2 C7 1.361(3) . ?
N2 C6 1.383(3) . ?
N2 C8 1.462(3) . ?
N7 C28 1.316(3) . ?
N7 C22 1.390(3) . ?
N5 C14 1.318(3) . ?
N5 C15 1.386(3) . ?
C30 H30A 0.9900 . ?
C30 H30B 0.9900 . ?
C30 C28 1.506(3) . ?
C9 H9A 0.9900 . ?
C9 H9B 0.9900 . ?
C9 C7 1.505(3) . ?
C32 C32 1.346(4) 4 ?
C32 H32 0.9500 . ?
C20 C15 1.400(3) . ?
C20 C19 1.394(3) . ?
C14 C13 1.499(3) . ?
C13 H13A 0.9900 . ?
C13 H13B 0.9900 . ?
C27 C22 1.397(3) . ?
C27 C26 1.397(3) . ?
C10 H10 0.9500 . ?
C10 C11 1.346(3) . ?
C6 C1 1.399(3) . ?
C6 C5 1.395(3) . ?
C1 C2 1.394(3) . ?
C11 H11 0.9500 . ?
C15 C16 1.392(3) . ?
C22 C23 1.394(3) . ?
C16 H16 0.9500 . ?
C16 C17 1.387(3) . ?
C2 H2 0.9500 . ?
C2 C3 1.383(4) . ?
C19 H19 0.9500 . ?
C19 C18 1.381(4) . ?
C23 H23 0.9500 . ?
C23 C24 1.387(4) . ?
C17 H17 0.9500 . ?
C17 C18 1.399(4) . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C29 H29A 0.9800 . ?
C29 H29B 0.9800 . ?
C29 H29C 0.9800 . ?
C21 H21A 0.9800 . ?
C21 H21B 0.9800 . ?
C21 H21C 0.9800 . ?
C18 H18 0.9500 . ?
C26 H26 0.9500 . ?
C26 C25 1.379(4) . ?
C3 H3 0.9500 . ?
C3 C4 1.400(4) . ?
C5 H5 0.9500 . ?
C5 C4 1.380(4) . ?
C24 H24 0.9500 . ?
C24 C25 1.400(5) . ?
C4 H4 0.9500 . ?
C25 H25 0.9500 . ?
N10 C34 1.134(10) . ?
C33 H33A 0.9900 . ?
C33 H33B 0.9900 . ?
C33 C34 1.494(11) 4 ?
C33 C34 1.494(11) . ?
C34 C34 1.352(15) 4 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ag2 Ag2 Ag2 60.000(1) 3_675 2_765 ?
N7 Ag2 Ag2 117.97(5) . 2_765 ?
N7 Ag2 Ag2 128.38(5) 5_675 2_765 ?
N7 Ag2 Ag2 117.97(5) 5_675 3_675 ?
N7 Ag2 Ag2 128.38(5) . 3_675 ?
N7 Ag2 N7 102.01(10) . 5_675 ?
C31 Ag2 Ag2 112.29(4) 3_675 2_765 ?
C31 Ag2 Ag2 52.29(4) 3_675 3_675 ?
C31 Ag2 Ag2 52.29(4) . 2_765 ?
C31 Ag2 Ag2 112.29(4) . 3_675 ?
C31 Ag2 N7 86.21(5) 3_675 5_675 ?
C31 Ag2 N7 103.59(5) 3_675 . ?
C31 Ag2 N7 103.59(5) . 5_675 ?
C31 Ag2 N7 86.21(5) . . ?
C31 Ag2 C31 164.58(9) . 3_675 ?
Ag1 Ag1 Ag1 60.0 2_665 3_565 ?
N1 Ag1 Ag1 117.22(5) . 2_665 ?
N1 Ag1 Ag1 125.21(5) . 3_565 ?
N1 Ag1 N5 105.76(7) . 3_565 ?
N5 Ag1 Ag1 115.22(5) 3_565 3_565 ?
N5 Ag1 Ag1 128.70(5) 3_565 2_665 ?
C12 Ag1 Ag1 52.01(5) 3_565 3_565 ?
C12 Ag1 Ag1 52.53(5) . 2_665 ?
C12 Ag1 Ag1 112.48(5) . 3_565 ?
C12 Ag1 Ag1 111.96(5) 3_565 2_665 ?
C12 Ag1 N1 99.80(7) 3_565 . ?
C12 Ag1 N1 85.92(7) . . ?
C12 Ag1 N5 85.27(7) 3_565 3_565 ?
C12 Ag1 N5 107.86(7) . 3_565 ?
C12 Ag1 C12 163.84(7) . 3_565 ?
F9 P3 F9 89.83(7) 2_765 3_675 ?
F9 P3 F9 90.16(7) 8_566 . ?
F9 P3 F9 89.83(7) 7_776 8_566 ?
F9 P3 F9 180.00(8) 8_566 2_765 ?
F9 P3 F9 89.83(7) 8_566 9_656 ?
F9 P3 F9 89.83(7) 3_675 . ?
F9 P3 F9 89.84(7) 2_765 . ?
F9 P3 F9 180.0 7_776 . ?
F9 P3 F9 90.17(7) 9_656 . ?
F9 P3 F9 89.83(7) 7_776 9_656 ?
F9 P3 F9 90.17(7) 8_566 3_675 ?
F9 P3 F9 90.17(7) 2_765 9_656 ?
F9 P3 F9 90.17(7) 7_776 2_765 ?
F9 P3 F9 180.00(8) 9_656 3_675 ?
F9 P3 F9 90.17(7) 7_776 3_675 ?
F7 P2 F7 90.11(9) 2_665 3_565 ?
F7 P2 F7 90.10(9) 2_665 . ?
F7 P2 F7 90.10(9) 3_565 . ?
F7 P2 F8 90.00(8) 2_665 2_665 ?
F7 P2 F8 179.73(10) 3_565 2_665 ?
F7 P2 F8 179.72(10) . 3_565 ?
F7 P2 F8 90.00(8) . . ?
F7 P2 F8 90.15(8) 2_665 3_565 ?
F7 P2 F8 90.15(8) . 2_665 ?
F7 P2 F8 90.15(8) 3_565 . ?
F7 P2 F8 90.00(8) 3_565 3_565 ?
F7 P2 F8 179.72(12) 2_665 . ?
F8 P2 F8 89.74(9) 3_565 . ?
F8 P2 F8 89.75(9) 3_565 2_665 ?
F8 P2 F8 89.74(9) 2_665 . ?
F3 P1 F1 179.10(10) . . ?
F2 P1 F1 88.17(10) . . ?
F2 P1 F3 91.04(11) . . ?
F2 P1 F6 89.26(17) . . ?
F6 P1 F1 90.25(10) . . ?
F6 P1 F3 90.18(10) . . ?
F5 P1 F1 89.91(10) . . ?
F5 P1 F3 89.65(11) . . ?
F5 P1 F2 89.3(2) . . ?
F5 P1 F6 178.5(2) . . ?
F4 P1 F1 90.73(12) . . ?
F4 P1 F3 90.05(13) . . ?
F4 P1 F2 178.1(2) . . ?
F4 P1 F6 92.4(2) . . ?
F4 P1 F5 89.1(2) . . ?
C31 N9 C30 124.05(18) . . ?
C31 N9 C32 111.52(18) . . ?
C32 N9 C30 124.39(18) . . ?
C12 N3 C9 123.64(18) . . ?
C12 N3 C10 111.88(18) . . ?
C10 N3 C9 124.40(18) . . ?
C28 N8 C27 106.49(18) . . ?
C28 N8 C29 127.5(2) . . ?
C27 N8 C29 126.04(19) . . ?
C7 N1 Ag1 121.22(14) . . ?
C7 N1 C1 105.54(18) . . ?
C1 N1 Ag1 133.05(15) . . ?
C20 N6 C21 125.37(18) . . ?
C14 N6 C20 106.46(18) . . ?
C14 N6 C21 128.12(19) . . ?
C12 N4 C13 123.93(18) . . ?
C12 N4 C11 111.52(18) . . ?
C11 N4 C13 124.50(19) . . ?
C7 N2 C6 106.42(18) . . ?
C7 N2 C8 126.68(19) . . ?
C6 N2 C8 126.75(18) . . ?
C28 N7 Ag2 120.63(14) . . ?
C28 N7 C22 105.53(18) . . ?
C22 N7 Ag2 131.11(15) . . ?
C14 N5 Ag1 121.59(14) . 2_665 ?
C14 N5 C15 105.36(18) . . ?
C15 N5 Ag1 129.74(15) . 2_665 ?
Ag2 C31 Ag2 75.43(9) . 2_765 ?
N9 C31 Ag2 123.37(9) 4 . ?
N9 C31 Ag2 123.37(9) . 2_765 ?
N9 C31 Ag2 115.24(9) . . ?
N9 C31 Ag2 115.25(9) 4 2_765 ?
N9 C31 N9 103.8(2) 4 . ?
Ag1 C12 Ag1 75.46(7) . 2_665 ?
N3 C12 Ag1 121.30(14) . 2_665 ?
N3 C12 Ag1 116.02(14) . . ?
N4 C12 Ag1 116.06(14) . 2_665 ?
N4 C12 Ag1 124.12(15) . . ?
N4 C12 N3 103.45(18) . . ?
N9 C30 H30A 109.3 . . ?
N9 C30 H30B 109.3 . . ?
N9 C30 C28 111.55(17) . . ?
H30A C30 H30B 108.0 . . ?
C28 C30 H30A 109.3 . . ?
C28 C30 H30B 109.3 . . ?
N3 C9 H9A 109.6 . . ?
N3 C9 H9B 109.6 . . ?
N3 C9 C7 110.20(17) . . ?
H9A C9 H9B 108.1 . . ?
C7 C9 H9A 109.6 . . ?
C7 C9 H9B 109.6 . . ?
N1 C7 N2 113.08(19) . . ?
N1 C7 C9 122.76(18) . . ?
N2 C7 C9 124.16(19) . . ?
N8 C28 C30 123.90(19) . . ?
N7 C28 N8 112.96(19) . . ?
N7 C28 C30 123.09(18) . . ?
N9 C32 H32 126.7 . . ?
C32 C32 N9 106.59(12) 4 . ?
C32 C32 H32 126.7 4 . ?
N6 C20 C15 105.78(18) . . ?
N6 C20 C19 131.9(2) . . ?
C19 C20 C15 122.3(2) . . ?
N6 C14 C13 122.95(19) . . ?
N5 C14 N6 113.1(2) . . ?
N5 C14 C13 123.87(19) . . ?
N4 C13 C14 111.80(18) . . ?
N4 C13 H13A 109.3 . . ?
N4 C13 H13B 109.3 . . ?
C14 C13 H13A 109.3 . . ?
C14 C13 H13B 109.3 . . ?
H13A C13 H13B 107.9 . . ?
N8 C27 C22 105.88(19) . . ?
N8 C27 C26 132.0(2) . . ?
C26 C27 C22 122.1(2) . . ?
N3 C10 H10 126.8 . . ?
C11 C10 N3 106.4(2) . . ?
C11 C10 H10 126.8 . . ?
N2 C6 C1 105.90(18) . . ?
N2 C6 C5 132.1(2) . . ?
C5 C6 C1 122.0(2) . . ?
N1 C1 C6 109.1(2) . . ?
N1 C1 C2 129.7(2) . . ?
C2 C1 C6 121.2(2) . . ?
N4 C11 H11 126.6 . . ?
C10 C11 N4 106.75(19) . . ?
C10 C11 H11 126.6 . . ?
N5 C15 C20 109.31(19) . . ?
N5 C15 C16 130.0(2) . . ?
C16 C15 C20 120.7(2) . . ?
N7 C22 C27 109.1(2) . . ?
N7 C22 C23 129.7(2) . . ?
C23 C22 C27 121.2(2) . . ?
C15 C16 H16 121.4 . . ?
C17 C16 C15 117.1(2) . . ?
C17 C16 H16 121.4 . . ?
C1 C2 H2 121.6 . . ?
C3 C2 C1 116.9(3) . . ?
C3 C2 H2 121.6 . . ?
C20 C19 H19 121.9 . . ?
C18 C19 C20 116.3(2) . . ?
C18 C19 H19 121.9 . . ?
C22 C23 H23 121.6 . . ?
C24 C23 C22 116.9(3) . . ?
C24 C23 H23 121.6 . . ?
C16 C17 H17 119.2 . . ?
C16 C17 C18 121.6(2) . . ?
C18 C17 H17 119.2 . . ?
N2 C8 H8A 109.5 . . ?
N2 C8 H8B 109.5 . . ?
N2 C8 H8C 109.5 . . ?
H8A C8 H8B 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
N8 C29 H29A 109.5 . . ?
N8 C29 H29B 109.5 . . ?
N8 C29 H29C 109.5 . . ?
H29A C29 H29B 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
N6 C21 H21A 109.5 . . ?
N6 C21 H21B 109.5 . . ?
N6 C21 H21C 109.5 . . ?
H21A C21 H21B 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C19 C18 C17 121.9(2) . . ?
C19 C18 H18 119.0 . . ?
C17 C18 H18 119.0 . . ?
C27 C26 H26 122.0 . . ?
C25 C26 C27 116.1(3) . . ?
C25 C26 H26 122.0 . . ?
C2 C3 H3 119.3 . . ?
C2 C3 C4 121.4(3) . . ?
C4 C3 H3 119.3 . . ?
C6 C5 H5 122.0 . . ?
C4 C5 C6 116.1(2) . . ?
C4 C5 H5 122.0 . . ?
C23 C24 H24 119.3 . . ?
C23 C24 C25 121.3(3) . . ?
C25 C24 H24 119.3 . . ?
C3 C4 H4 118.8 . . ?
C5 C4 C3 122.4(2) . . ?
C5 C4 H4 118.8 . . ?
C26 C25 C24 122.4(2) . . ?
C26 C25 H25 118.8 . . ?
C24 C25 H25 118.8 . . ?
H33A C33 H33B 115.6 . . ?
C34 C33 H33A 118.4 4 . ?
C34 C33 H33A 118.4 . . ?
C34 C33 H33B 118.4 4 . ?
C34 C33 H33B 118.4 . . ?
C34 C33 C34 53.8(7) 4 . ?
N10 C34 C33 170.3(8) . . ?
N10 C34 C34 108.8(5) . 4 ?
C34 C34 C33 63.1(3) 4 . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ag2 N7 C28 N8 -163.52(14) . . . . ?
Ag2 N7 C28 C30 14.0(3) . . . . ?
Ag2 N7 C22 C27 160.25(16) . . . . ?
Ag2 N7 C22 C23 -20.2(4) . . . . ?
Ag1 N1 C7 N2 -175.75(13) . . . . ?
Ag1 N1 C7 C9 4.5(3) . . . . ?
Ag1 N1 C1 C6 174.87(15) . . . . ?
Ag1 N1 C1 C2 -5.1(4) . . . . ?
Ag1 N5 C14 N6 -161.83(14) 2_665 . . . ?
Ag1 N5 C14 C13 14.4(3) 2_665 . . . ?
Ag1 N5 C15 C20 158.86(15) 2_665 . . . ?
Ag1 N5 C15 C16 -20.4(4) 2_665 . . . ?
N9 C30 C28 N8 -142.1(2) . . . . ?
N9 C30 C28 N7 40.6(3) . . . . ?
N3 C9 C7 N1 49.5(3) . . . . ?
N3 C9 C7 N2 -130.2(2) . . . . ?
N3 C10 C11 N4 0.6(3) . . . . ?
N8 C27 C22 N7 1.1(2) . . . . ?
N8 C27 C22 C23 -178.5(2) . . . . ?
N8 C27 C26 C25 178.8(2) . . . . ?
N1 C1 C2 C3 179.3(2) . . . . ?
N6 C20 C15 N5 1.0(2) . . . . ?
N6 C20 C15 C16 -179.7(2) . . . . ?
N6 C20 C19 C18 -179.3(2) . . . . ?
N6 C14 C13 N4 -145.8(2) . . . . ?
N2 C6 C1 N1 0.2(2) . . . . ?
N2 C6 C1 C2 -179.8(2) . . . . ?
N2 C6 C5 C4 -179.6(2) . . . . ?
N7 C22 C23 C24 179.8(2) . . . . ?
N5 C14 C13 N4 38.4(3) . . . . ?
N5 C15 C16 C17 177.9(2) . . . . ?
C31 N9 C30 C28 -76.5(2) . . . . ?
C31 N9 C32 C32 -0.8(3) . . . 4 ?
C12 N3 C9 C7 -77.8(2) . . . . ?
C12 N3 C10 C11 -0.1(3) . . . . ?
C12 N4 C13 C14 -75.9(3) . . . . ?
C12 N4 C11 C10 -0.9(3) . . . . ?
C30 N9 C31 Ag2 40.0(2) . . . . ?
C30 N9 C31 Ag2 -48.8(2) . . . 2_765 ?
C30 N9 C31 N9 177.8(2) . . . 4 ?
C30 N9 C32 C32 -178.3(2) . . . 4 ?
C9 N3 C12 Ag1 -51.1(2) . . . 2_665 ?
C9 N3 C12 Ag1 37.1(2) . . . . ?
C9 N3 C12 N4 176.47(18) . . . . ?
C9 N3 C10 C11 -176.96(19) . . . . ?
C7 N1 C1 C6 -0.1(2) . . . . ?
C7 N1 C1 C2 179.9(2) . . . . ?
C7 N2 C6 C1 -0.2(2) . . . . ?
C7 N2 C6 C5 -179.3(2) . . . . ?
C28 N8 C27 C22 -1.2(2) . . . . ?
C28 N8 C27 C26 -179.3(2) . . . . ?
C28 N7 C22 C27 -0.5(3) . . . . ?
C28 N7 C22 C23 179.0(3) . . . . ?
C32 N9 C31 Ag2 -137.60(15) . . . . ?
C32 N9 C31 Ag2 133.70(16) . . . 2_765 ?
C32 N9 C31 N9 0.28(11) . . . 4 ?
C32 N9 C30 C28 100.7(2) . . . . ?
C20 N6 C14 N5 1.2(2) . . . . ?
C20 N6 C14 C13 -175.1(2) . . . . ?
C20 C15 C16 C17 -1.2(3) . . . . ?
C20 C19 C18 C17 -0.8(4) . . . . ?
C14 N6 C20 C15 -1.3(2) . . . . ?
C14 N6 C20 C19 178.7(2) . . . . ?
C14 N5 C15 C20 -0.3(2) . . . . ?
C14 N5 C15 C16 -179.6(2) . . . . ?
C13 N4 C12 Ag1 -46.5(3) . . . . ?
C13 N4 C12 Ag1 43.1(2) . . . 2_665 ?
C13 N4 C12 N3 178.50(19) . . . . ?
C13 N4 C11 C10 -178.6(2) . . . . ?
C27 N8 C28 N7 1.0(2) . . . . ?
C27 N8 C28 C30 -176.55(19) . . . . ?
C27 C22 C23 C24 -0.7(4) . . . . ?
C27 C26 C25 C24 -0.9(4) . . . . ?
C10 N3 C12 Ag1 -139.72(16) . . . . ?
C10 N3 C12 Ag1 132.01(17) . . . 2_665 ?
C10 N3 C12 N4 -0.4(2) . . . . ?
C10 N3 C9 C7 98.7(2) . . . . ?
C6 N2 C7 N1 0.2(2) . . . . ?
C6 N2 C7 C9 179.97(19) . . . . ?
C6 C1 C2 C3 -0.7(4) . . . . ?
C6 C5 C4 C3 -1.0(4) . . . . ?
C1 N1 C7 N2 -0.1(3) . . . . ?
C1 N1 C7 C9 -179.9(2) . . . . ?
C1 C6 C5 C4 1.5(4) . . . . ?
C1 C2 C3 C4 1.1(4) . . . . ?
C11 N4 C12 Ag1 135.75(17) . . . . ?
C11 N4 C12 Ag1 -134.60(16) . . . 2_665 ?
C11 N4 C12 N3 0.8(2) . . . . ?
C11 N4 C13 C14 101.6(2) . . . . ?
C15 N5 C14 N6 -0.5(2) . . . . ?
C15 N5 C14 C13 175.7(2) . . . . ?
C15 C20 C19 C18 0.6(3) . . . . ?
C15 C16 C17 C18 1.1(4) . . . . ?
C22 N7 C28 N8 -0.3(3) . . . . ?
C22 N7 C28 C30 177.3(2) . . . . ?
C22 C27 C26 C25 0.9(4) . . . . ?
C22 C23 C24 C25 0.8(4) . . . . ?
C16 C17 C18 C19 -0.1(4) . . . . ?
C2 C3 C4 C5 -0.2(5) . . . . ?
C19 C20 C15 N5 -178.9(2) . . . . ?
C19 C20 C15 C16 0.4(3) . . . . ?
C23 C24 C25 C26 0.0(5) . . . . ?
C8 N2 C7 N1 175.9(2) . . . . ?
C8 N2 C7 C9 -4.3(3) . . . . ?
C8 N2 C6 C1 -175.9(2) . . . . ?
C8 N2 C6 C5 5.0(4) . . . . ?
C29 N8 C28 N7 -179.9(2) . . . . ?
C29 N8 C28 C30 2.6(3) . . . . ?
C29 N8 C27 C22 179.6(2) . . . . ?
C29 N8 C27 C26 1.5(4) . . . . ?
C21 N6 C20 C15 -179.1(2) . . . . ?
C21 N6 C20 C19 0.8(4) . . . . ?
C21 N6 C14 N5 178.9(2) . . . . ?
C21 N6 C14 C13 2.7(3) . . . . ?
C26 C27 C22 N7 179.4(2) . . . . ?
C26 C27 C22 C23 -0.2(4) . . . . ?
C5 C6 C1 N1 179.4(2) . . . . ?
C5 C6 C1 C2 -0.6(4) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.493
_oxdiff_exptl_absorpt_empirical_full_min 0.637
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_jd-3_r2
_database_code_depnum_ccdc_archive 'CCDC 2259178'
loop_
_audit_author_name
_audit_author_address
'Dr. Joydev Dinda'
;Utkal University, Bhubaneswar, India
India
;
_audit_update_record             
;
2023-04-26 deposited with the CCDC.	2023-12-05 downloaded from the CCDC.
;
_audit_creation_date             2022-12-13
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6272)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         
'C42 H40 Ag2 Au Cl N12, 2(F6 P), C2.5 H5 N O0.5'
_chemical_formula_sum            'C44.50 H45 Ag2 Au Cl F12 N13 O0.50 P2'
_chemical_formula_weight         1508.03
_chemical_melting_point          ?
_chemical_oxdiff_formula         'C H N O Ag Au P F Cl'
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           12
_space_group_name_H-M_alt        'I 1 2/m 1'
_space_group_name_Hall           '-I 2y'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z+1/2'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z+1/2'
'x+1/2, -y+1/2, z+1/2'

_cell_length_a                   14.2719(4)
_cell_length_b                   24.7697(6)
_cell_length_c                   14.7213(4)
_cell_angle_alpha                90
_cell_angle_beta                 96.862(3)
_cell_angle_gamma                90
_cell_volume                     5166.9(2)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    14497
_cell_measurement_temperature    100.00(10)
_cell_measurement_theta_max      30.6130
_cell_measurement_theta_min      3.7680
_shelx_estimated_absorpt_T_max   0.703
_shelx_estimated_absorpt_T_min   0.518
_exptl_absorpt_coefficient_mu    3.789
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.61963
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.40.67a (Rigaku Oxford Diffraction, 2019)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear light silver'
_exptl_crystal_density_diffrn    1.939
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             2940
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.1
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0750
_diffrn_reflns_av_unetI/netI     0.0573
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.819
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       32
_diffrn_reflns_limit_k_min       -32
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            30536
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.819
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         30.330
_diffrn_reflns_theta_min         3.313
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      '100.00 (10)'
_diffrn_detector                 'Hybrid Pixel Array Detector'
_diffrn_detector_area_resol_mean 5.8140
_diffrn_detector_type            'Pilatus 200K'
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.819
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω    -65.00   7.00   0.50   23.71    --    3.35 -24.00 121.00  144
  2  ω      0.00  73.00   0.50   23.71    --    3.35  24.00 -74.00  146
  3  ω    -15.00  39.00   0.50   23.71    --    3.35 -99.00 -90.00  108
  4  ω     -5.00  23.00   0.50   23.71    --   -4.29 -99.00-180.00   56
  5  ω    -27.00   7.00   0.50   23.71    --   -4.29  77.00  60.00   68
  6  ω    -24.00  18.00   0.50   23.71    --   -4.29 -77.00-120.00   84
  7  ω    -25.00  11.00   0.50   23.71    --   -4.29  77.00   0.00   72
  8  ω     -3.00  30.00   0.50   23.71    --   -4.29 -99.00   0.00   66
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  
'SuperNova, Dual, Cu at home/near, Pilatus 200K'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.0447157000
_diffrn_orient_matrix_UB_12      -0.0082127000
_diffrn_orient_matrix_UB_13      -0.0218735000
_diffrn_orient_matrix_UB_21      0.0197072000
_diffrn_orient_matrix_UB_22      -0.0036233000
_diffrn_orient_matrix_UB_23      -0.0415693000
_diffrn_orient_matrix_UB_31      0.0108884000
_diffrn_orient_matrix_UB_32      -0.0271984000
_diffrn_orient_matrix_UB_33      0.0121378000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'SuperNova (Mo) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                5596
_reflns_number_total             6503
_reflns_odcompleteness_completeness 99.54
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     26.32
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.40.67a (Rigaku OD, 2019)'
_computing_data_collection       'CrysAlisPro 1.171.40.67a (Rigaku OD, 2019)'
_computing_data_reduction        'CrysAlisPro 1.171.40.67a (Rigaku OD, 2019)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         2.001
_refine_diff_density_min         -1.226
_refine_diff_density_rms         0.164
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.050
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     380
_refine_ls_number_reflns         6503
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.0529
_refine_ls_R_factor_gt           0.0427
_refine_ls_restrained_S_all      1.053
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0256P)²+49.6891P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0927
_refine_ls_wR_factor_ref         0.0959
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 N7-C24
 1.3 with sigma of 0.02
3. Others
 Fixed Sof: F9(0.85) O1(0.25) C24(0.25) C23(0.5) H23A(0.5) H23B(0.5) H23C(0.5)
 C22(0.5) H22A(0.5) H22B(0.5) F8(0.15)
4.a Secondary CH2 refined with riding coordinates:
 C13(H13A,H13B), C9(H9A,H9B), C22(H22A,H22B)
4.b Aromatic/amide H refined with riding coordinates:
 C12(H12), C19(H19), C18(H18), C16(H16), C2(H2), C17(H17), C11(H11), C4(H4),
 C3(H3), C5(H5)
4.c Idealised Me refined as rotating group:
 C21(H21A,H21B,H21C), C7(H7A,H7B,H7C), C23(H23A,H23B,H23C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 1.000000 0.58628(2) 0.500000 0.01843(8) Uani 1 2 d S T P . .
Ag1 Ag 1.11114(3) 0.69119(2) 0.47091(2) 0.02155(10) Uani 1 1 d . . . . .
Cl1 Cl 1.000000 0.76808(6) 0.500000 0.0218(3) Uani 1 2 d S T P . .
P1 P 0.50316(13) 0.500000 0.69311(13) 0.0242(4) Uani 1 2 d S T P . .
P2 P 1.12455(17) 0.500000 0.8493(2) 0.0421(6) Uani 1 2 d S T P . .
F2 F 0.5615(3) 0.500000 0.6066(3) 0.0374(11) Uani 1 2 d S T P . .
F3 F 0.5701(3) 0.45486(13) 0.7416(3) 0.0496(10) Uani 1 1 d . . . . .
N5 N 0.7691(3) 0.68521(15) 0.4173(3) 0.0192(8) Uani 1 1 d . . . . .
N1 N 0.8807(3) 0.68288(15) 0.6793(3) 0.0183(8) Uani 1 1 d . . . . .
N4 N 0.7848(3) 0.57624(14) 0.4748(3) 0.0193(8) Uani 1 1 d . . . . .
N3 N 0.8390(3) 0.57511(14) 0.6166(3) 0.0191(8) Uani 1 1 d . . . . .
F7 F 1.0134(4) 0.500000 0.8558(4) 0.0454(13) Uani 1 2 d S T P . .
F4 F 0.4441(4) 0.500000 0.7781(3) 0.0455(12) Uani 1 2 d S T P . .
C10 C 0.8652(4) 0.58129(17) 0.5316(3) 0.0196(9) Uani 1 1 d . . . . .
N6 N 0.6755(3) 0.66106(16) 0.2908(3) 0.0221(8) Uani 1 1 d . . . . .
N2 N 0.8943(3) 0.65460(16) 0.8238(3) 0.0231(9) Uani 1 1 d . . . . .
C14 C 0.7391(3) 0.64515(18) 0.3621(3) 0.0196(9) Uani 1 1 d . . . . .
N7 N 0.7190(5) 1.000000 0.6641(5) 0.0381(16) Uani 1 2 d DS T P . .
C13 C 0.7749(4) 0.58827(18) 0.3766(3) 0.0220(10) Uani 1 1 d . . . . .
H13A H 0.729991 0.562661 0.343101 0.026 Uiso 1 1 calc R U . . .
H13B H 0.836652 0.584452 0.353001 0.026 Uiso 1 1 calc R U . . .
C12 C 0.7082(4) 0.56831(18) 0.5233(3) 0.0225(10) Uani 1 1 d . . . . .
H12 H 0.643983 0.564364 0.498660 0.027 Uiso 1 1 calc R U . . .
C20 C 0.6637(3) 0.71651(19) 0.3025(3) 0.0215(10) Uani 1 1 d . . . . .
C19 C 0.6094(4) 0.7535(2) 0.2475(4) 0.0275(11) Uani 1 1 d . . . . .
H19 H 0.571492 0.743262 0.192756 0.033 Uiso 1 1 calc R U . . .
F1 F 0.4380(4) 0.5459(3) 0.6454(3) 0.092(2) Uani 1 1 d . . . . .
F5 F 1.2333(5) 0.500000 0.8357(7) 0.098(3) Uani 1 2 d S T P . .
F6 F 1.1425(4) 0.5435(2) 0.9316(4) 0.0824(16) Uani 1 1 d . . . . .
C9 C 0.9004(4) 0.58374(18) 0.7019(3) 0.0222(10) Uani 1 1 d . . . . .
H9A H 0.966726 0.576642 0.692261 0.027 Uiso 1 1 calc R U . . .
H9B H 0.883018 0.558369 0.749108 0.027 Uiso 1 1 calc R U . . .
C15 C 0.7212(3) 0.73072(18) 0.3809(3) 0.0207(10) Uani 1 1 d . . . . .
C8 C 0.8908(3) 0.64129(18) 0.7344(3) 0.0196(9) Uani 1 1 d . . . . .
C18 C 0.6151(4) 0.8067(2) 0.2792(4) 0.0295(12) Uani 1 1 d . . . . .
H18 H 0.578737 0.833724 0.245366 0.035 Uiso 1 1 calc R U . . .
C1 C 0.8779(3) 0.72762(18) 0.7369(3) 0.0200(9) Uani 1 1 d . . . . .
C16 C 0.7267(4) 0.78406(19) 0.4111(3) 0.0231(10) Uani 1 1 d . . . . .
H16 H 0.766050 0.794136 0.465028 0.028 Uiso 1 1 calc R U . . .
C2 C 0.8700(4) 0.78237(19) 0.7146(4) 0.0257(11) Uani 1 1 d . . . . .
H2 H 0.863484 0.794373 0.652837 0.031 Uiso 1 1 calc R U . . .
F9 F 1.1095(4) 0.5504(3) 0.7857(4) 0.087(2) Uani 0.85 1 d . . P . .
C17 C 0.6725(4) 0.8217(2) 0.3592(4) 0.0267(11) Uani 1 1 d . . . . .
H17 H 0.674177 0.858352 0.378038 0.032 Uiso 1 1 calc R U . . .
C11 C 0.7435(4) 0.56734(17) 0.6121(3) 0.0217(10) Uani 1 1 d . . . . .
H11 H 0.708617 0.562209 0.662459 0.026 Uiso 1 1 calc R U . . .
C21 C 0.6270(4) 0.6290(2) 0.2161(4) 0.0316(12) Uani 1 1 d . . . . .
H21A H 0.659785 0.594436 0.212059 0.047 Uiso 1 1 calc R U . . .
H21B H 0.626961 0.648665 0.158321 0.047 Uiso 1 1 calc R U . . .
H21C H 0.561819 0.622297 0.227702 0.047 Uiso 1 1 calc R U . . .
C6 C 0.8876(4) 0.7104(2) 0.8267(4) 0.0244(10) Uani 1 1 d . . . . .
C4 C 0.8836(4) 0.8005(2) 0.8779(4) 0.0372(14) Uani 1 1 d . . . . .
H4 H 0.885822 0.826395 0.925654 0.045 Uiso 1 1 calc R U . . .
C3 C 0.8723(4) 0.8183(2) 0.7868(4) 0.0336(13) Uani 1 1 d . . . . .
H3 H 0.865978 0.855815 0.774427 0.040 Uiso 1 1 calc R U . . .
C7 C 0.9076(5) 0.6188(2) 0.9025(4) 0.0398(14) Uani 1 1 d . . . . .
H7A H 0.857915 0.591240 0.896873 0.060 Uiso 1 1 calc R U . . .
H7B H 0.904404 0.639696 0.958543 0.060 Uiso 1 1 calc R U . . .
H7C H 0.969399 0.601211 0.905155 0.060 Uiso 1 1 calc R U . . .
C5 C 0.8915(4) 0.7465(2) 0.9000(4) 0.0341(13) Uani 1 1 d . . . . .
H5 H 0.899286 0.734555 0.961720 0.041 Uiso 1 1 calc R U . . .
O1 O 0.8640(9) 1.000000 0.5497(8) 0.039(3) Uani 0.5 2 d S T P . .
C24 C 0.7796(11) 1.000000 0.6161(11) 0.056(6) Uani 0.5 2 d DS T P . .
C23 C 0.8655(12) 0.9029(5) 0.5457(9) 0.050(4) Uani 0.5 1 d . . P . .
H23A H 0.810115 0.899099 0.499913 0.076 Uiso 0.5 1 calc R U P . .
H23B H 0.844994 0.906256 0.606644 0.076 Uiso 0.5 1 calc R U P . .
H23C H 0.905796 0.870923 0.543986 0.076 Uiso 0.5 1 calc R U P . .
C22 C 0.9196(12) 0.9519(6) 0.5253(12) 0.060(4) Uani 0.5 1 d . . P . .
H22A H 0.928223 0.952878 0.459571 0.072 Uiso 0.5 1 calc R U P . .
H22B H 0.982537 0.951701 0.561673 0.072 Uiso 0.5 1 calc R U P . .
F8 F 1.0854(12) 0.500000 0.7145(13) 0.044(4) Uani 0.3 2 d S T P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 Ag1 3.1007(4) 2_756 ?
Au1 Ag1 3.1006(4) . ?
Au1 C10 2.037(5) . ?
Au1 C10 2.037(5) 2_756 ?
Ag1 Cl1 2.5474(11) . ?
Ag1 N5 2.231(4) 2_756 ?
Ag1 N1 2.238(4) 2_756 ?
P1 F2 1.604(5) . ?
P1 F3 1.584(4) 6_565 ?
P1 F3 1.584(4) . ?
P1 F4 1.590(5) . ?
P1 F1 1.580(4) . ?
P1 F1 1.580(4) 6_565 ?
P2 F7 1.601(6) . ?
P2 F5 1.588(7) . ?
P2 F6 1.619(5) . ?
P2 F6 1.619(5) 6_565 ?
P2 F9 1.559(5) . ?
P2 F9 1.559(5) 6_565 ?
P2 F8 1.995(19) . ?
N5 C14 1.321(6) . ?
N5 C15 1.393(6) . ?
N1 C8 1.308(6) . ?
N1 C1 1.398(6) . ?
N4 C10 1.342(6) . ?
N4 C13 1.467(6) . ?
N4 C12 1.388(6) . ?
N3 C10 1.357(6) . ?
N3 C9 1.458(6) . ?
N3 C11 1.371(6) . ?
N6 C14 1.361(6) . ?
N6 C20 1.397(6) . ?
N6 C21 1.463(6) . ?
N2 C8 1.352(6) . ?
N2 C6 1.385(6) . ?
N2 C7 1.454(7) . ?
C14 C13 1.505(6) . ?
N7 C24 1.180(16) . ?
C13 H13A 0.9900 . ?
C13 H13B 0.9900 . ?
C12 H12 0.9500 . ?
C12 C11 1.344(7) . ?
C20 C19 1.394(7) . ?
C20 C15 1.379(7) . ?
C19 H19 0.9500 . ?
C19 C18 1.398(8) . ?
C9 H9A 0.9900 . ?
C9 H9B 0.9900 . ?
C9 C8 1.515(6) . ?
C15 C16 1.393(7) . ?
C18 H18 0.9500 . ?
C18 C17 1.401(8) . ?
C1 C2 1.397(7) . ?
C1 C6 1.381(7) . ?
C16 H16 0.9500 . ?
C16 C17 1.381(7) . ?
C2 H2 0.9500 . ?
C2 C3 1.384(7) . ?
F9 F8 1.639(14) . ?
C17 H17 0.9500 . ?
C11 H11 0.9500 . ?
C21 H21A 0.9800 . ?
C21 H21B 0.9800 . ?
C21 H21C 0.9800 . ?
C6 C5 1.398(7) . ?
C4 H4 0.9500 . ?
C4 C3 1.402(9) . ?
C4 C5 1.377(9) . ?
C3 H3 0.9500 . ?
C7 H7A 0.9800 . ?
C7 H7B 0.9800 . ?
C7 H7C 0.9800 . ?
C5 H5 0.9500 . ?
O1 C24 1.64(2) . ?
O1 C22 1.498(18) . ?
O1 C22 1.498(18) 6_575 ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C23 C22 1.49(2) . ?
C22 H22A 0.9900 . ?
C22 H22B 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ag1 Au1 Ag1 66.130(14) . 2_756 ?
C10 Au1 Ag1 60.43(12) 2_756 . ?
C10 Au1 Ag1 126.54(12) 2_756 2_756 ?
C10 Au1 Ag1 60.43(12) . 2_756 ?
C10 Au1 Ag1 126.54(12) . . ?
C10 Au1 C10 173.0(2) 2_756 . ?
Cl1 Ag1 Au1 105.32(3) . . ?
N5 Ag1 Au1 101.64(10) 2_756 . ?
N5 Ag1 Cl1 111.28(10) 2_756 . ?
N5 Ag1 N1 126.66(15) 2_756 2_756 ?
N1 Ag1 Au1 98.47(10) 2_756 . ?
N1 Ag1 Cl1 110.00(10) 2_756 . ?
Ag1 Cl1 Ag1 83.23(5) 2_756 . ?
F3 P1 F2 90.9(2) . . ?
F3 P1 F2 90.9(2) 6_565 . ?
F3 P1 F3 89.8(3) . 6_565 ?
F3 P1 F4 89.6(2) 6_565 . ?
F3 P1 F4 89.6(2) . . ?
F4 P1 F2 179.3(3) . . ?
F1 P1 F2 88.9(2) . . ?
F1 P1 F2 88.9(2) 6_565 . ?
F1 P1 F3 89.1(3) 6_565 . ?
F1 P1 F3 89.1(3) . 6_565 ?
F1 P1 F3 178.8(3) . . ?
F1 P1 F3 178.8(3) 6_565 6_565 ?
F1 P1 F4 90.6(2) . . ?
F1 P1 F4 90.6(2) 6_565 . ?
F1 P1 F1 92.1(5) 6_565 . ?
F7 P2 F6 91.4(3) . . ?
F7 P2 F6 91.4(3) . 6_565 ?
F7 P2 F8 84.1(6) . . ?
F5 P2 F7 176.2(5) . . ?
F5 P2 F6 91.4(4) . 6_565 ?
F5 P2 F6 91.4(4) . . ?
F5 P2 F8 92.1(6) . . ?
F6 P2 F6 83.4(4) 6_565 . ?
F6 P2 F8 138.1(2) . . ?
F6 P2 F8 138.1(2) 6_565 . ?
F9 P2 F7 88.2(3) . . ?
F9 P2 F7 88.2(3) 6_565 . ?
F9 P2 F5 89.5(3) 6_565 . ?
F9 P2 F5 89.5(3) . . ?
F9 P2 F6 168.5(4) . 6_565 ?
F9 P2 F6 85.1(4) . . ?
F9 P2 F6 85.1(4) 6_565 6_565 ?
F9 P2 F6 168.5(4) 6_565 . ?
F9 P2 F9 106.3(6) . 6_565 ?
F9 P2 F8 53.2(3) . . ?
F9 P2 F8 53.2(3) 6_565 . ?
C14 N5 Ag1 131.9(3) . 2_756 ?
C14 N5 C15 105.2(4) . . ?
C15 N5 Ag1 121.9(3) . 2_756 ?
C8 N1 Ag1 132.0(3) . 2_756 ?
C8 N1 C1 105.0(4) . . ?
C1 N1 Ag1 122.3(3) . 2_756 ?
C10 N4 C13 124.7(4) . . ?
C10 N4 C12 111.1(4) . . ?
C12 N4 C13 123.1(4) . . ?
C10 N3 C9 125.1(4) . . ?
C10 N3 C11 110.6(4) . . ?
C11 N3 C9 123.6(4) . . ?
N4 C10 Au1 128.7(3) . . ?
N4 C10 N3 104.8(4) . . ?
N3 C10 Au1 126.1(4) . . ?
C14 N6 C20 105.6(4) . . ?
C14 N6 C21 129.4(4) . . ?
C20 N6 C21 125.0(4) . . ?
C8 N2 C6 106.2(4) . . ?
C8 N2 C7 127.8(4) . . ?
C6 N2 C7 125.9(4) . . ?
N5 C14 N6 113.2(4) . . ?
N5 C14 C13 122.4(4) . . ?
N6 C14 C13 124.3(4) . . ?
N4 C13 C14 108.7(4) . . ?
N4 C13 H13A 109.9 . . ?
N4 C13 H13B 109.9 . . ?
C14 C13 H13A 109.9 . . ?
C14 C13 H13B 109.9 . . ?
H13A C13 H13B 108.3 . . ?
N4 C12 H12 127.0 . . ?
C11 C12 N4 106.0(5) . . ?
C11 C12 H12 127.0 . . ?
C19 C20 N6 129.9(5) . . ?
C15 C20 N6 106.6(4) . . ?
C15 C20 C19 123.5(5) . . ?
C20 C19 H19 122.6 . . ?
C20 C19 C18 114.8(5) . . ?
C18 C19 H19 122.6 . . ?
N3 C9 H9A 109.7 . . ?
N3 C9 H9B 109.7 . . ?
N3 C9 C8 110.0(4) . . ?
H9A C9 H9B 108.2 . . ?
C8 C9 H9A 109.7 . . ?
C8 C9 H9B 109.7 . . ?
N5 C15 C16 129.7(5) . . ?
C20 C15 N5 109.4(4) . . ?
C20 C15 C16 121.0(4) . . ?
N1 C8 N2 113.5(4) . . ?
N1 C8 C9 123.6(4) . . ?
N2 C8 C9 122.8(4) . . ?
C19 C18 H18 118.9 . . ?
C19 C18 C17 122.3(5) . . ?
C17 C18 H18 118.9 . . ?
C2 C1 N1 129.4(5) . . ?
C6 C1 N1 109.1(4) . . ?
C6 C1 C2 121.5(5) . . ?
C15 C16 H16 121.4 . . ?
C17 C16 C15 117.1(5) . . ?
C17 C16 H16 121.4 . . ?
C1 C2 H2 121.7 . . ?
C3 C2 C1 116.7(5) . . ?
C3 C2 H2 121.7 . . ?
P2 F9 F8 77.1(6) . . ?
C18 C17 H17 119.4 . . ?
C16 C17 C18 121.3(5) . . ?
C16 C17 H17 119.4 . . ?
N3 C11 H11 126.3 . . ?
C12 C11 N3 107.4(4) . . ?
C12 C11 H11 126.3 . . ?
N6 C21 H21A 109.5 . . ?
N6 C21 H21B 109.5 . . ?
N6 C21 H21C 109.5 . . ?
H21A C21 H21B 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
N2 C6 C5 131.8(5) . . ?
C1 C6 N2 106.1(4) . . ?
C1 C6 C5 122.0(5) . . ?
C3 C4 H4 119.1 . . ?
C5 C4 H4 119.1 . . ?
C5 C4 C3 121.9(5) . . ?
C2 C3 C4 121.5(5) . . ?
C2 C3 H3 119.2 . . ?
C4 C3 H3 119.2 . . ?
N2 C7 H7A 109.5 . . ?
N2 C7 H7B 109.5 . . ?
N2 C7 H7C 109.5 . . ?
H7A C7 H7B 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
C6 C5 H5 121.8 . . ?
C4 C5 C6 116.4(5) . . ?
C4 C5 H5 121.8 . . ?
C22 O1 C24 126.2(7) . . ?
C22 O1 C24 126.2(7) 6_575 . ?
C22 O1 C22 105.4(15) 6_575 . ?
N7 C24 O1 179.8(14) . . ?
H23A C23 H23B 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C22 C23 H23A 109.5 . . ?
C22 C23 H23B 109.5 . . ?
C22 C23 H23C 109.5 . . ?
O1 C22 H22A 110.2 . . ?
O1 C22 H22B 110.2 . . ?
C23 C22 O1 107.4(13) . . ?
C23 C22 H22A 110.2 . . ?
C23 C22 H22B 110.2 . . ?
H22A C22 H22B 108.5 . . ?
F9 F8 P2 49.6(5) . . ?
F9 F8 P2 49.6(5) 6_565 . ?
F9 F8 F9 99.2(10) . 6_565 ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ag1 N5 C14 N6 -167.3(3) 2_756 . . . ?
Ag1 N5 C14 C13 11.0(7) 2_756 . . . ?
Ag1 N5 C15 C20 168.7(3) 2_756 . . . ?
Ag1 N5 C15 C16 -9.5(7) 2_756 . . . ?
Ag1 N1 C8 N2 170.6(3) 2_756 . . . ?
Ag1 N1 C8 C9 -7.8(7) 2_756 . . . ?
Ag1 N1 C1 C2 7.1(7) 2_756 . . . ?
Ag1 N1 C1 C6 -170.9(3) 2_756 . . . ?
P2 F9 F8 F9 -3.4(7) . . . 6_565 ?
N5 C14 C13 N4 40.0(6) . . . . ?
N5 C15 C16 C17 177.9(5) . . . . ?
N1 C1 C2 C3 -177.9(5) . . . . ?
N1 C1 C6 N2 -1.2(6) . . . . ?
N1 C1 C6 C5 177.1(5) . . . . ?
N4 C12 C11 N3 0.6(5) . . . . ?
N3 C9 C8 N1 -37.9(6) . . . . ?
N3 C9 C8 N2 143.9(5) . . . . ?
F7 P2 F9 F8 -84.0(7) . . . . ?
C10 N4 C13 C14 -95.0(5) . . . . ?
C10 N4 C12 C11 -1.3(5) . . . . ?
C10 N3 C9 C8 92.5(5) . . . . ?
C10 N3 C11 C12 0.3(5) . . . . ?
N6 C14 C13 N4 -141.8(5) . . . . ?
N6 C20 C19 C18 -179.0(5) . . . . ?
N6 C20 C15 N5 0.7(5) . . . . ?
N6 C20 C15 C16 179.1(4) . . . . ?
N2 C6 C5 C4 179.0(6) . . . . ?
C14 N5 C15 C20 -1.0(5) . . . . ?
C14 N5 C15 C16 -179.2(5) . . . . ?
C14 N6 C20 C19 177.4(5) . . . . ?
C14 N6 C20 C15 -0.2(5) . . . . ?
C13 N4 C10 Au1 -18.0(6) . . . . ?
C13 N4 C10 N3 169.9(4) . . . . ?
C13 N4 C12 C11 -170.0(4) . . . . ?
C12 N4 C10 Au1 173.5(3) . . . . ?
C12 N4 C10 N3 1.5(5) . . . . ?
C12 N4 C13 C14 72.1(5) . . . . ?
C20 N6 C14 N5 -0.4(6) . . . . ?
C20 N6 C14 C13 -178.7(4) . . . . ?
C20 C19 C18 C17 1.2(8) . . . . ?
C20 C15 C16 C17 -0.1(7) . . . . ?
C19 C20 C15 N5 -177.0(4) . . . . ?
C19 C20 C15 C16 1.4(8) . . . . ?
C19 C18 C17 C16 -0.1(8) . . . . ?
F5 P2 F9 F8 93.0(7) . . . . ?
F6 P2 F9 F8 -172.4(17) 6_565 . . . ?
F6 P2 F9 F8 -175.5(7) . . . . ?
C9 N3 C10 Au1 15.5(6) . . . . ?
C9 N3 C10 N4 -172.2(4) . . . . ?
C9 N3 C11 C12 171.6(4) . . . . ?
C15 N5 C14 N6 0.9(5) . . . . ?
C15 N5 C14 C13 179.2(4) . . . . ?
C15 C20 C19 C18 -1.8(7) . . . . ?
C15 C16 C17 C18 -0.5(8) . . . . ?
C8 N1 C1 C2 178.5(5) . . . . ?
C8 N1 C1 C6 0.5(5) . . . . ?
C8 N2 C6 C1 1.4(5) . . . . ?
C8 N2 C6 C5 -176.7(6) . . . . ?
C1 N1 C8 N2 0.4(5) . . . . ?
C1 N1 C8 C9 -178.0(4) . . . . ?
C1 C2 C3 C4 1.1(8) . . . . ?
C1 C6 C5 C4 1.1(8) . . . . ?
C2 C1 C6 N2 -179.4(5) . . . . ?
C2 C1 C6 C5 -1.0(8) . . . . ?
F9 P2 F9 F8 3.7(8) 6_565 . . . ?
C11 N3 C10 Au1 -173.4(3) . . . . ?
C11 N3 C10 N4 -1.1(5) . . . . ?
C11 N3 C9 C8 -77.5(5) . . . . ?
C21 N6 C14 N5 179.8(5) . . . . ?
C21 N6 C14 C13 1.5(8) . . . . ?
C21 N6 C20 C19 -2.8(8) . . . . ?
C21 N6 C20 C15 179.6(5) . . . . ?
C6 N2 C8 N1 -1.2(6) . . . . ?
C6 N2 C8 C9 177.2(4) . . . . ?
C6 C1 C2 C3 -0.1(8) . . . . ?
C3 C4 C5 C6 -0.1(9) . . . . ?
C7 N2 C8 N1 -178.2(5) . . . . ?
C7 N2 C8 C9 0.2(8) . . . . ?
C7 N2 C6 C1 178.5(5) . . . . ?
C7 N2 C6 C5 0.4(9) . . . . ?
C5 C4 C3 C2 -1.0(9) . . . . ?
C24 O1 C22 C23 18.1(18) . . . . ?
C22 O1 C22 C23 -178.3(7) 6_575 . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 2.108
_oxdiff_exptl_absorpt_empirical_full_min 0.195
