# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2023

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_Dy4MOF
_database_code_depnum_ccdc_archive 'CCDC 2296744'
loop_
_audit_author_name
_audit_author_address
'Dong Shao'
;Huanggang Normal University
China
;
_audit_update_record             
;
2023-11-07 deposited with the CCDC.	2023-11-13 downloaded from the CCDC.
;
_audit_creation_date             2023-11-06
_audit_creation_method           
;
Olex2 1.5
(compiled 2023.03.06 svn.rbb2c1857 for OlexSys, GUI svn.r6748)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C32 H20 Dy4 O32, 8.5[C3H7NO]'
_chemical_formula_sum            'C57.50 H79.50 Dy4 N8.50 O40.50'
_chemical_formula_weight         2187.79
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           11
_space_group_name_H-M_alt        'P 1 21/m 1'
_space_group_name_Hall           '-P 2yb'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z'
'-x, -y, -z'
'x, -y-1/2, z'

_cell_length_a                   13.442(4)
_cell_length_b                   21.256(6)
_cell_length_c                   17.195(5)
_cell_angle_alpha                90
_cell_angle_beta                 108.984(11)
_cell_angle_gamma                90
_cell_volume                     4646(2)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    9288
_cell_measurement_temperature    281.00
_cell_measurement_theta_max      26.480
_cell_measurement_theta_min      2.497
_shelx_estimated_absorpt_T_max   0.696
_shelx_estimated_absorpt_T_min   0.640
_exptl_absorpt_coefficient_mu    3.263
_exptl_absorpt_correction_T_max  0.0453
_exptl_absorpt_correction_T_min  0.0199
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1520 before and 0.1153 after correction.
The Ratio of minimum to maximum transmission is 0.4393.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear light yellow'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.564
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             2144
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.12
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0620
_diffrn_reflns_av_unetI/netI     0.0628
_diffrn_reflns_Laue_measured_fraction_full 0.988
_diffrn_reflns_Laue_measured_fraction_max 0.947
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_k_min       -26
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            34784
_diffrn_reflns_point_group_measured_fraction_full 0.988
_diffrn_reflns_point_group_measured_fraction_max 0.947
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.589
_diffrn_reflns_theta_min         1.916
_diffrn_ambient_temperature      281.00
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.988
_diffrn_measured_fraction_theta_max 0.947
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           1.4
_diffrn_source_power             0.07
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                7113
_reflns_number_total             9459
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.38A (Bruker, 2018)'
_computing_data_collection       'SAINT V8.38A (Bruker, 2018)'
_computing_data_reduction        'SAINT V8.38A (Bruker, 2018)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL  (Sheldrick, 2008)'
_computing_structure_solution    'SHELXT 2014/4 (Sheldrick, 2014)'
_refine_diff_density_max         1.213
_refine_diff_density_min         -1.212
_refine_diff_density_rms         0.143
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.994
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     340
_refine_ls_number_reflns         9459
_refine_ls_number_restraints     78
_refine_ls_R_factor_all          0.0508
_refine_ls_R_factor_gt           0.0391
_refine_ls_restrained_S_all      1.005
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0634P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1070
_refine_ls_wR_factor_ref         0.1122
_refine_special_details          ?
_olex2_refinement_description    
;
1. Uiso/Uaniso restraints and constraints
Uanis(O5) \\sim Ueq, Uanis(O15) \\sim Ueq, Uanis(O19) \\sim Ueq, Uanis(O2)
\\sim Ueq, Uanis(O11) \\sim Ueq, Uanis(O7) \\sim Ueq, Uanis(O18) \\sim Ueq,
Uanis(O17) \\sim Ueq, Uanis(O9) \\sim Ueq, Uanis(O13) \\sim Ueq, Uanis(O21)
\\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(O5) \\sim Ueq, Uanis(O13) \\sim Ueq, Uanis(C2) \\sim Ueq, Uanis(C15)
\\sim Ueq: with sigma of 0.005 and sigma for terminal atoms of 0.01
Uanis(C15) = Uanis(C2) = Uanis(O13) = Uanis(O5)
2. Others
 Sof(H15)=Sof(O13)=Sof(H13A)=1-FVAR(1)
 Sof(H2)=Sof(O5)=Sof(H5)=FVAR(1)
 Fixed Sof: H8(0.5) H9(0.5) H11(0.5) H7(0.5) O2(0.5) H2A(0.5) O17(0.5)
 H17(0.5) O9(0.5) H9A(0.5) O19(0.5) H19(0.5)
3.a Rotating group:
 O3(H3A,H3B)
3.b Aromatic/amide H refined with riding coordinates:
 C8(H8), C9(H9), C11(H11), C13(H13), C7(H7), C15(H15), C2(H2)
3.c Idealised tetrahedral OH refined as rotating group:
 O13(H13A), O7(H7A), O2(H2A), O17(H17), O9(H9A), O19(H19), O5(H5)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.68479(2) 0.16253(2) 0.29585(2) 0.02816(9) Uani 1 1 d . . . . .
Dy3 Dy 0.45191(3) 0.250000 0.14631(2) 0.02871(10) Uani 1 2 d S T P . .
Dy2 Dy 0.50919(3) 0.250000 0.38750(3) 0.03795(11) Uani 1 2 d S T P . .
O1 O 0.6833(4) 0.250000 0.3781(3) 0.0307(12) Uani 1 2 d S T P . .
O4 O 0.5037(3) 0.18785(15) 0.2697(2) 0.0346(9) Uani 1 1 d . . . . .
O6 O 0.6339(4) 0.250000 0.2033(3) 0.0264(11) Uani 1 2 d S T P . .
O8 O 0.6236(3) 0.10660(17) 0.1744(3) 0.0473(11) Uani 1 1 d . . . . .
O10 O 0.8061(3) 0.07253(17) 0.3166(3) 0.0437(10) Uani 1 1 d . . . . .
O12 O 0.8407(3) 0.19877(18) 0.2760(3) 0.0496(11) Uani 1 1 d . . . . .
O14 O 0.8216(3) 0.13290(18) 0.4276(3) 0.0468(10) Uani 1 1 d . . . . .
O16 O 1.2926(3) 0.30042(18) 0.1550(3) 0.0510(11) Uani 1 1 d . . . . .
O18 O 0.6123(4) 0.4195(2) 0.3562(3) 0.0606(13) Uani 1 1 d . U . . .
O20 O 0.4820(4) 0.15283(18) 0.0913(3) 0.0540(12) Uani 1 1 d . . . . .
O21 O 0.5839(4) 0.3488(2) 0.4425(3) 0.0652(14) Uani 1 1 d . U . . .
C1 C 0.8781(7) 0.250000 0.2661(5) 0.0379(19) Uani 1 2 d S T P . .
O11 O 0.3519(7) 0.250000 0.0023(4) 0.082(3) Uani 1 2 d S TU P . .
C4 C 0.8449(5) 0.0835(3) 0.3932(4) 0.0420(15) Uani 1 1 d . . . . .
C6 C 1.2517(6) 0.250000 0.1637(5) 0.0378(19) Uani 1 2 d S T P . .
O3 O 0.3634(4) 0.1861(3) 0.3749(4) 0.0879(19) Uani 1 1 d . . . . .
H3A H 0.294368 0.197297 0.388481 0.132 Uiso 1 1 d R U . . .
H3B H 0.350346 0.138969 0.354562 0.132 Uiso 1 1 d R U . . .
C8 C 1.0188(5) 0.3063(3) 0.2247(4) 0.0498(17) Uani 1 1 d . . . . .
H8 H 0.989909 0.344650 0.232280 0.060 Uiso 0.5 1 calc R U P A 1
C10 C 0.9713(7) 0.250000 0.2381(6) 0.043(2) Uani 1 2 d S T P H .
C12 C 0.5433(5) 0.1078(3) 0.1102(4) 0.0427(14) Uani 1 1 d . . . . .
C14 C 0.9263(5) 0.0406(2) 0.4496(4) 0.0394(14) Uani 1 1 d . . . . .
C16 C 0.5822(5) 0.4045(3) 0.4169(5) 0.0519(17) Uani 1 1 d . . . . .
C18 C 0.5220(5) 0.0517(2) 0.0537(4) 0.0431(15) Uani 1 1 d . . . . .
C9 C 0.9606(5) 0.0485(3) 0.5353(4) 0.0503(17) Uani 1 1 d . . . . .
H9 H 0.932790 0.080909 0.558084 0.060 Uiso 0.5 1 calc R U P B 2
C5 C 0.5396(5) 0.4545(3) 0.4595(4) 0.0501(17) Uani 1 1 d . . . . .
C11 C 1.0354(6) 0.0088(3) 0.5865(5) 0.0540(17) Uani 1 1 d . . . . .
H11 H 1.059344 0.014755 0.643138 0.065 Uiso 0.5 1 calc R U P C 1
C3 C 1.1516(7) 0.250000 0.1867(6) 0.046(2) Uani 1 2 d S T P I .
C13 C 0.5058(6) 0.5614(3) 0.4800(5) 0.061(2) Uani 1 1 d . . . . .
H13 H 0.507591 0.603398 0.465241 0.074 Uiso 1 1 calc R U . . .
C7 C 1.1081(5) 0.3057(3) 0.2004(5) 0.0493(17) Uani 1 1 d . . . . .
H7 H 1.138647 0.343522 0.193231 0.059 Uiso 0.5 1 calc R U P D 2
C15 C 0.4365(6) 0.0525(3) -0.0211(5) 0.0671(12) Uani 1 1 d . U . . .
H15 H 0.394191 0.088141 -0.035159 0.081 Uiso 0.782(7) 1 calc R U P E 1
C2 C 0.4150(6) 0.0010(3) -0.0736(5) 0.0671(12) Uani 1 1 d . U . . .
H2 H 0.358145 0.001965 -0.122114 0.081 Uiso 0.218(7) 1 calc R U P E 2
O13 O 0.3283(5) 0.0062(3) -0.1433(4) 0.0671(12) Uani 0.782(7) 1 d . U P E 1
H13A H 0.298540 -0.027977 -0.153768 0.101 Uiso 0.782(7) 1 calc R U P E 1
O7 O 0.5908(8) 0.5366(3) 0.3818(6) 0.124(3) Uani 1 1 d . U . F 2
H7A H 0.595463 0.506809 0.352847 0.185 Uiso 1 1 calc R U . F 2
C17 C 0.5483(7) 0.5158(3) 0.4416(5) 0.064(2) Uani 1 1 d . . . . .
O15 O 0.5326(11) 0.250000 0.5370(7) 0.139(4) Uani 1 2 d S TU P . .
O2 O 0.9217(8) 0.0941(4) 0.5757(5) 0.056(3) Uani 0.5 1 d . U P G 1
H2A H 0.870727 0.111399 0.542811 0.084 Uiso 0.5 1 calc R U P G 1
O17 O 0.9852(8) 0.3663(4) 0.2394(9) 0.078(3) Uani 0.5 1 d . U P H 2
H17 H 0.920854 0.368312 0.220264 0.117 Uiso 0.5 1 calc R U P H 2
O9 O 1.1436(9) 0.3635(4) 0.1917(8) 0.080(3) Uani 0.5 1 d . U P I 1
H9A H 1.116806 0.375224 0.144023 0.119 Uiso 0.5 1 calc R U P I 1
O19 O 1.0740(14) 0.0224(7) 0.6710(9) 0.115(5) Uani 0.5 1 d . U P J 2
H19 H 1.128616 0.002702 0.692335 0.173 Uiso 0.5 1 calc R U P J 2
O5 O 0.3611(19) 0.0939(10) -0.0329(15) 0.0671(12) Uani 0.218(7) 1 d . U P E 2
H5 H 0.334390 0.090644 0.003488 0.101 Uiso 0.218(7) 1 calc R U P E 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 Dy1 3.7186(11) 4_565 ?
Dy1 Dy3 3.8251(9) . ?
Dy1 Dy2 3.7326(8) . ?
Dy1 O1 2.340(3) . ?
Dy1 O4 2.388(4) . ?
Dy1 O6 2.398(3) . ?
Dy1 O8 2.309(4) . ?
Dy1 O10 2.463(4) . ?
Dy1 O12 2.359(4) . ?
Dy1 O14 2.490(4) . ?
Dy1 O18 2.392(4) 4_565 ?
Dy1 C4 2.813(6) . ?
Dy3 Dy2 3.9644(14) . ?
Dy3 O4 2.403(4) 4_565 ?
Dy3 O4 2.403(4) . ?
Dy3 O6 2.321(5) . ?
Dy3 O16 2.442(4) 4_465 ?
Dy3 O16 2.442(4) 1_455 ?
Dy3 O20 2.361(4) . ?
Dy3 O20 2.361(4) 4_565 ?
Dy3 O11 2.403(7) . ?
Dy3 C6 2.802(8) 1_455 ?
Dy2 O1 2.397(5) . ?
Dy2 O4 2.399(4) . ?
Dy2 O4 2.399(4) 4_565 ?
Dy2 O21 2.387(5) 4_565 ?
Dy2 O21 2.387(5) . ?
Dy2 O3 2.336(5) . ?
Dy2 O3 2.336(5) 4_565 ?
Dy2 O15 2.486(11) . ?
O8 C12 1.269(7) . ?
O10 C4 1.270(8) . ?
O12 C1 1.234(5) . ?
O14 C4 1.293(7) . ?
O16 C6 1.235(6) . ?
O18 C16 1.279(8) . ?
O20 C12 1.236(7) . ?
O21 C16 1.259(8) . ?
C1 C10 1.480(12) . ?
C4 C14 1.510(8) . ?
C6 C3 1.522(12) . ?
O3 H3A 1.0554 . ?
O3 H3B 1.0562 . ?
C8 H8 0.9300 . ?
C8 C10 1.410(8) . ?
C8 C7 1.394(8) . ?
C8 O17 1.404(11) . ?
C12 C18 1.505(8) . ?
C14 C9 1.403(9) . ?
C14 C11 1.400(8) 3_756 ?
C16 C5 1.506(8) . ?
C18 C15 1.419(9) . ?
C18 C2 1.378(8) 3_655 ?
C9 H9 0.9300 . ?
C9 C11 1.386(8) . ?
C9 O2 1.391(10) . ?
C5 C13 1.410(9) 3_666 ?
C5 C17 1.352(9) . ?
C11 H11 0.9300 . ?
C11 O19 1.406(15) . ?
C3 C7 1.373(7) 4_565 ?
C3 C7 1.373(7) . ?
C13 H13 0.9300 . ?
C13 C17 1.394(9) . ?
C7 H7 0.9300 . ?
C7 O9 1.344(10) . ?
C15 H15 0.9300 . ?
C15 C2 1.390(9) . ?
C15 O5 1.31(2) . ?
C2 H2 0.9300 . ?
C2 O13 1.378(9) . ?
O13 H13A 0.8200 . ?
O7 H7A 0.8200 . ?
O7 C17 1.400(9) . ?
O2 H2A 0.8200 . ?
O17 H17 0.8200 . ?
O9 H9A 0.8200 . ?
O19 H19 0.8200 . ?
O5 H5 0.8200 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Dy1 Dy1 Dy3 60.917(10) 4_565 . ?
Dy1 Dy1 Dy2 60.124(10) 4_565 . ?
Dy2 Dy1 Dy3 63.26(2) . . ?
O1 Dy1 Dy1 37.39(10) . 4_565 ?
O1 Dy1 Dy3 81.60(12) . . ?
O1 Dy1 Dy2 38.56(12) . . ?
O1 Dy1 O4 74.09(16) . . ?
O1 Dy1 O6 74.24(15) . . ?
O1 Dy1 O10 131.69(16) . . ?
O1 Dy1 O12 90.62(16) . . ?
O1 Dy1 O14 78.48(15) . . ?
O1 Dy1 O18 103.45(17) . 4_565 ?
O1 Dy1 C4 105.69(18) . . ?
O4 Dy1 Dy1 76.98(8) . 4_565 ?
O4 Dy1 Dy3 37.16(9) . . ?
O4 Dy1 Dy2 38.87(9) . . ?
O4 Dy1 O6 69.36(14) . . ?
O4 Dy1 O10 142.02(12) . . ?
O4 Dy1 O14 129.33(13) . . ?
O4 Dy1 O18 73.27(14) . 4_565 ?
O4 Dy1 C4 141.45(15) . . ?
O6 Dy1 Dy1 39.16(10) . 4_565 ?
O6 Dy1 Dy3 35.18(11) . . ?
O6 Dy1 Dy2 79.12(10) . . ?
O6 Dy1 O10 136.95(15) . . ?
O6 Dy1 O14 140.06(14) . . ?
O6 Dy1 C4 148.85(16) . . ?
O8 Dy1 Dy1 120.99(10) . 4_565 ?
O8 Dy1 Dy3 70.70(10) . . ?
O8 Dy1 Dy2 123.37(11) . . ?
O8 Dy1 O1 152.24(15) . . ?
O8 Dy1 O4 84.52(14) . . ?
O8 Dy1 O6 81.85(14) . . ?
O8 Dy1 O10 75.85(14) . . ?
O8 Dy1 O12 96.27(16) . . ?
O8 Dy1 O14 129.27(13) . . ?
O8 Dy1 O18 86.62(18) . 4_565 ?
O8 Dy1 C4 102.07(17) . . ?
O10 Dy1 Dy1 140.96(10) . 4_565 ?
O10 Dy1 Dy3 146.44(11) . . ?
O10 Dy1 Dy2 143.65(10) . . ?
O10 Dy1 O14 54.10(14) . . ?
O10 Dy1 C4 26.83(16) . . ?
O12 Dy1 Dy1 70.94(10) . 4_565 ?
O12 Dy1 Dy3 108.36(11) . . ?
O12 Dy1 Dy2 127.72(10) . . ?
O12 Dy1 O4 142.93(13) . . ?
O12 Dy1 O6 74.07(15) . . ?
O12 Dy1 O10 72.39(14) . . ?
O12 Dy1 O14 77.68(15) . . ?
O12 Dy1 O18 143.78(15) . 4_565 ?
O12 Dy1 C4 74.79(16) . . ?
O14 Dy1 Dy1 104.65(9) . 4_565 ?
O14 Dy1 Dy3 159.27(9) . . ?
O14 Dy1 Dy2 97.07(10) . . ?
O14 Dy1 C4 27.36(16) . . ?
O18 Dy1 Dy1 136.82(12) 4_565 4_565 ?
O18 Dy1 Dy3 106.64(12) 4_565 . ?
O18 Dy1 Dy2 77.16(12) 4_565 . ?
O18 Dy1 O6 141.70(16) 4_565 . ?
O18 Dy1 O10 73.40(15) 4_565 . ?
O18 Dy1 O14 72.87(16) 4_565 . ?
O18 Dy1 C4 69.33(17) 4_565 . ?
C4 Dy1 Dy1 126.67(12) . 4_565 ?
C4 Dy1 Dy3 172.20(13) . . ?
C4 Dy1 Dy2 120.85(14) . . ?
Dy1 Dy3 Dy1 58.17(2) . 4_565 ?
Dy1 Dy3 Dy2 57.230(15) . . ?
Dy1 Dy3 Dy2 57.230(15) 4_565 . ?
O4 Dy3 Dy1 74.62(9) . 4_565 ?
O4 Dy3 Dy1 36.90(9) 4_565 4_565 ?
O4 Dy3 Dy1 36.90(9) . . ?
O4 Dy3 Dy1 74.62(9) 4_565 . ?
O4 Dy3 Dy2 34.31(8) 4_565 . ?
O4 Dy3 Dy2 34.31(8) . . ?
O4 Dy3 O4 66.71(17) 4_565 . ?
O4 Dy3 O16 101.26(14) 4_565 4_465 ?
O4 Dy3 O16 73.30(15) 4_565 1_455 ?
O4 Dy3 O16 101.26(14) . 1_455 ?
O4 Dy3 O16 73.30(15) . 4_465 ?
O4 Dy3 C6 85.30(17) 4_565 1_455 ?
O4 Dy3 C6 85.30(17) . 1_455 ?
O6 Dy3 Dy1 36.53(7) . 4_565 ?
O6 Dy3 Dy1 36.53(7) . . ?
O6 Dy3 Dy2 74.87(12) . . ?
O6 Dy3 O4 70.39(14) . 4_565 ?
O6 Dy3 O4 70.39(14) . . ?
O6 Dy3 O16 143.04(14) . 4_465 ?
O6 Dy3 O16 143.04(14) . 1_455 ?
O6 Dy3 O20 82.81(13) . 4_565 ?
O6 Dy3 O20 82.81(13) . . ?
O6 Dy3 O11 126.5(3) . . ?
O6 Dy3 C6 150.7(2) . 1_455 ?
O16 Dy3 Dy1 135.59(12) 1_455 . ?
O16 Dy3 Dy1 135.59(12) 4_465 4_565 ?
O16 Dy3 Dy1 106.72(11) 1_455 4_565 ?
O16 Dy3 Dy1 106.72(11) 4_465 . ?
O16 Dy3 Dy2 79.15(12) 1_455 . ?
O16 Dy3 Dy2 79.15(12) 4_465 . ?
O16 Dy3 O16 52.06(19) 4_465 1_455 ?
O16 Dy3 C6 26.11(9) 1_455 1_455 ?
O16 Dy3 C6 26.11(9) 4_465 1_455 ?
O20 Dy3 Dy1 68.58(11) 4_565 4_565 ?
O20 Dy3 Dy1 68.57(11) . . ?
O20 Dy3 Dy1 119.04(12) . 4_565 ?
O20 Dy3 Dy1 119.04(12) 4_565 . ?
O20 Dy3 Dy2 114.76(12) . . ?
O20 Dy3 Dy2 114.76(12) 4_565 . ?
O20 Dy3 O4 142.82(14) . 4_565 ?
O20 Dy3 O4 80.48(14) . . ?
O20 Dy3 O4 142.82(14) 4_565 . ?
O20 Dy3 O4 80.48(14) 4_565 4_565 ?
O20 Dy3 O16 84.73(15) 4_565 1_455 ?
O20 Dy3 O16 132.55(16) . 1_455 ?
O20 Dy3 O16 132.54(16) 4_565 4_465 ?
O20 Dy3 O16 84.73(15) . 4_465 ?
O20 Dy3 O20 122.1(2) 4_565 . ?
O20 Dy3 O11 72.45(15) 4_565 . ?
O20 Dy3 O11 72.45(15) . . ?
O20 Dy3 C6 109.76(14) . 1_455 ?
O20 Dy3 C6 109.76(14) 4_565 1_455 ?
O11 Dy3 Dy1 138.93(15) . . ?
O11 Dy3 Dy1 138.93(15) . 4_565 ?
O11 Dy3 Dy2 158.6(2) . . ?
O11 Dy3 O4 144.55(11) . . ?
O11 Dy3 O4 144.55(11) . 4_565 ?
O11 Dy3 O16 81.7(2) . 1_455 ?
O11 Dy3 O16 81.7(2) . 4_465 ?
O11 Dy3 C6 82.8(3) . 1_455 ?
C6 Dy3 Dy1 122.17(15) 1_455 . ?
C6 Dy3 Dy1 122.17(15) 1_455 4_565 ?
C6 Dy3 Dy2 75.81(18) 1_455 . ?
Dy1 Dy2 Dy1 59.75(2) 4_565 . ?
Dy1 Dy2 Dy3 59.508(15) 4_565 . ?
Dy1 Dy2 Dy3 59.507(15) . . ?
O1 Dy2 Dy1 37.47(7) . 4_565 ?
O1 Dy2 Dy1 37.47(7) . . ?
O1 Dy2 Dy3 77.94(13) . . ?
O1 Dy2 O4 72.88(14) . . ?
O1 Dy2 O4 72.88(14) . 4_565 ?
O1 Dy2 O15 105.8(3) . . ?
O4 Dy2 Dy1 76.58(8) . 4_565 ?
O4 Dy2 Dy1 38.67(9) . . ?
O4 Dy2 Dy1 38.67(9) 4_565 4_565 ?
O4 Dy2 Dy1 76.58(8) 4_565 . ?
O4 Dy2 Dy3 34.38(8) . . ?
O4 Dy2 Dy3 34.38(8) 4_565 . ?
O4 Dy2 O4 66.83(16) . 4_565 ?
O4 Dy2 O15 146.27(9) . . ?
O4 Dy2 O15 146.27(9) 4_565 . ?
O21 Dy2 Dy1 111.29(13) . . ?
O21 Dy2 Dy1 111.29(13) 4_565 4_565 ?
O21 Dy2 Dy1 59.09(13) 4_565 . ?
O21 Dy2 Dy1 59.09(13) . 4_565 ?
O21 Dy2 Dy3 109.13(14) . . ?
O21 Dy2 Dy3 109.13(14) 4_565 . ?
O21 Dy2 O1 74.48(13) 4_565 . ?
O21 Dy2 O1 74.48(13) . . ?
O21 Dy2 O4 75.11(16) . 4_565 ?
O21 Dy2 O4 75.10(16) 4_565 . ?
O21 Dy2 O4 135.42(16) 4_565 4_565 ?
O21 Dy2 O4 135.42(16) . . ?
O21 Dy2 O21 123.3(2) . 4_565 ?
O21 Dy2 O15 72.26(19) 4_565 . ?
O21 Dy2 O15 72.26(19) . . ?
O3 Dy2 Dy1 107.32(15) . . ?
O3 Dy2 Dy1 151.32(16) 4_565 . ?
O3 Dy2 Dy1 151.32(16) . 4_565 ?
O3 Dy2 Dy1 107.32(15) 4_565 4_565 ?
O3 Dy2 Dy3 91.81(16) 4_565 . ?
O3 Dy2 Dy3 91.81(16) . . ?
O3 Dy2 O1 143.26(15) 4_565 . ?
O3 Dy2 O1 143.26(15) . . ?
O3 Dy2 O4 116.60(19) 4_565 . ?
O3 Dy2 O4 78.87(17) 4_565 4_565 ?
O3 Dy2 O4 116.60(19) . 4_565 ?
O3 Dy2 O4 78.87(17) . . ?
O3 Dy2 O21 75.9(2) 4_565 . ?
O3 Dy2 O21 141.3(2) . . ?
O3 Dy2 O21 75.9(2) . 4_565 ?
O3 Dy2 O21 141.3(2) 4_565 4_565 ?
O3 Dy2 O3 71.2(3) . 4_565 ?
O3 Dy2 O15 85.2(3) 4_565 . ?
O3 Dy2 O15 85.2(3) . . ?
O15 Dy2 Dy1 123.5(3) . 4_565 ?
O15 Dy2 Dy1 123.5(3) . . ?
O15 Dy2 Dy3 176.3(3) . . ?
Dy1 O1 Dy1 105.2(2) 4_565 . ?
Dy1 O1 Dy2 103.97(15) . . ?
Dy1 O1 Dy2 103.97(15) 4_565 . ?
Dy1 O4 Dy3 105.94(13) . . ?
Dy1 O4 Dy2 102.47(15) . . ?
Dy2 O4 Dy3 111.31(13) . . ?
Dy1 O6 Dy1 101.68(19) . 4_565 ?
Dy3 O6 Dy1 108.30(13) . . ?
Dy3 O6 Dy1 108.30(13) . 4_565 ?
C12 O8 Dy1 136.8(4) . . ?
C4 O10 Dy1 92.1(3) . . ?
C1 O12 Dy1 136.8(4) . . ?
C4 O14 Dy1 90.4(4) . . ?
C6 O16 Dy3 93.4(4) . 1_655 ?
C16 O18 Dy1 117.0(4) . 4_565 ?
C12 O20 Dy3 139.4(4) . . ?
C16 O21 Dy2 137.0(5) . . ?
O12 C1 O12 123.8(8) . 4_565 ?
O12 C1 C10 118.1(4) 4_565 . ?
O12 C1 C10 118.1(4) . . ?
O10 C4 Dy1 61.0(3) . . ?
O10 C4 O14 123.0(5) . . ?
O10 C4 C14 121.5(5) . . ?
O14 C4 Dy1 62.3(3) . . ?
O14 C4 C14 115.4(6) . . ?
C14 C4 Dy1 175.9(5) . . ?
O16 C6 Dy3 60.5(4) 4_565 1_655 ?
O16 C6 Dy3 60.5(4) . 1_655 ?
O16 C6 O16 120.4(8) . 4_565 ?
O16 C6 C3 119.8(4) 4_565 . ?
O16 C6 C3 119.8(4) . . ?
C3 C6 Dy3 171.5(6) . 1_655 ?
Dy2 O3 H3A 128.3 . . ?
Dy2 O3 H3B 128.8 . . ?
H3A O3 H3B 102.9 . . ?
C10 C8 H8 119.3 . . ?
C7 C8 H8 119.3 . . ?
C7 C8 C10 121.4(6) . . ?
C7 C8 O17 115.0(6) . . ?
O17 C8 C10 123.5(7) . . ?
C8 C10 C1 121.9(4) . . ?
C8 C10 C1 121.9(4) 4_565 . ?
C8 C10 C8 116.1(8) . 4_565 ?
O8 C12 C18 118.4(5) . . ?
O20 C12 O8 123.3(5) . . ?
O20 C12 C18 118.3(6) . . ?
C9 C14 C4 121.7(5) . . ?
C11 C14 C4 117.5(6) 3_756 . ?
C11 C14 C9 120.8(5) 3_756 . ?
O18 C16 C5 119.4(6) . . ?
O21 C16 O18 123.1(6) . . ?
O21 C16 C5 117.5(7) . . ?
C15 C18 C12 120.2(5) . . ?
C2 C18 C12 120.7(6) 3_655 . ?
C2 C18 C15 119.2(6) 3_655 . ?
C14 C9 H9 119.4 . . ?
C11 C9 C14 121.2(6) . . ?
C11 C9 H9 119.4 . . ?
C11 C9 O2 114.8(7) . . ?
O2 C9 C14 124.0(6) . . ?
C13 C5 C16 120.9(6) 3_666 . ?
C17 C5 C16 119.7(7) . . ?
C17 C5 C13 119.3(6) . 3_666 ?
C14 C11 H11 121.0 3_756 . ?
C14 C11 O19 123.2(8) 3_756 . ?
C9 C11 C14 118.0(7) . 3_756 ?
C9 C11 H11 121.0 . . ?
C9 C11 O19 118.7(8) . . ?
C7 C3 C6 120.4(4) 4_565 . ?
C7 C3 C6 120.4(4) . . ?
C7 C3 C7 119.0(8) 4_565 . ?
C5 C13 H13 119.2 3_666 . ?
C17 C13 C5 121.7(6) . 3_666 ?
C17 C13 H13 119.2 . . ?
C8 C7 H7 119.5 . . ?
C3 C7 C8 121.1(6) . . ?
C3 C7 H7 119.5 . . ?
O9 C7 C8 113.3(7) . . ?
O9 C7 C3 125.6(7) . . ?
C18 C15 H15 119.5 . . ?
C2 C15 C18 121.0(6) . . ?
C2 C15 H15 119.5 . . ?
O5 C15 C18 120.6(12) . . ?
O5 C15 C2 116.3(12) . . ?
C18 C2 C15 119.8(7) 3_655 . ?
C18 C2 H2 120.1 3_655 . ?
C15 C2 H2 120.1 . . ?
O13 C2 C18 124.0(6) . 3_655 ?
O13 C2 C15 116.1(6) . . ?
C2 O13 H13A 109.5 . . ?
C17 O7 H7A 109.5 . . ?
C5 C17 C13 118.9(7) . . ?
C5 C17 O7 123.8(6) . . ?
C13 C17 O7 117.1(6) . . ?
C9 O2 H2A 109.5 . . ?
C8 O17 H17 109.5 . . ?
C7 O9 H9A 109.5 . . ?
C11 O19 H19 109.5 . . ?
C15 O5 H5 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Dy1 O8 C12 O20 15.4(11) . . . . ?
Dy1 O8 C12 C18 -165.0(4) . . . . ?
Dy1 O10 C4 O14 -6.8(6) . . . . ?
Dy1 O10 C4 C14 176.3(5) . . . . ?
Dy1 O12 C1 O12 10.8(15) . . . 4_565 ?
Dy1 O12 C1 C10 -167.2(5) . . . . ?
Dy1 O14 C4 O10 6.8(6) . . . . ?
Dy1 O14 C4 C14 -176.2(5) . . . . ?
Dy1 O18 C16 O21 -3.9(9) 4_565 . . . ?
Dy1 O18 C16 C5 177.7(4) 4_565 . . . ?
Dy3 O16 C6 O16 -8.7(9) 1_655 . . 4_565 ?
Dy3 O16 C6 C3 170.3(7) 1_655 . . . ?
Dy3 O20 C12 O8 -6.0(11) . . . . ?
Dy3 O20 C12 C18 174.5(4) . . . . ?
Dy2 O21 C16 O18 -58.7(10) . . . . ?
Dy2 O21 C16 C5 119.7(6) . . . . ?
O8 C12 C18 C15 -176.5(7) . . . . ?
O8 C12 C18 C2 3.4(10) . . . 3_655 ?
O10 C4 C14 C9 -172.7(6) . . . . ?
O10 C4 C14 C11 5.5(9) . . . 3_756 ?
O12 C1 C10 C8 -179.6(8) 4_565 . . 4_565 ?
O12 C1 C10 C8 -1.5(13) . . . 4_565 ?
O12 C1 C10 C8 179.6(8) . . . . ?
O12 C1 C10 C8 1.5(13) 4_565 . . . ?
O14 C4 C14 C9 10.2(9) . . . . ?
O14 C4 C14 C11 -171.6(6) . . . 3_756 ?
O16 C6 C3 C7 177.0(8) 4_565 . . . ?
O16 C6 C3 C7 -177.0(8) . . . 4_565 ?
O16 C6 C3 C7 2.0(13) 4_565 . . 4_565 ?
O16 C6 C3 C7 -2.0(13) . . . . ?
O18 C16 C5 C13 172.4(7) . . . 3_666 ?
O18 C16 C5 C17 -9.9(11) . . . . ?
O20 C12 C18 C15 3.1(10) . . . . ?
O20 C12 C18 C2 -177.0(7) . . . 3_655 ?
O21 C16 C5 C13 -6.1(10) . . . 3_666 ?
O21 C16 C5 C17 171.6(7) . . . . ?
C4 C14 C9 C11 179.9(6) . . . . ?
C4 C14 C9 O2 2.0(11) . . . . ?
C6 C3 C7 C8 -177.4(7) . . . . ?
C6 C3 C7 O9 3.2(15) . . . . ?
C10 C8 C7 C3 1.5(12) . . . . ?
C10 C8 C7 O9 -179.0(9) . . . . ?
C12 C18 C15 C2 -179.3(7) . . . . ?
C12 C18 C15 O5 -16.7(18) . . . . ?
C14 C9 C11 C14 -1.7(11) . . . 3_756 ?
C14 C9 C11 O19 174.1(11) . . . . ?
C16 C5 C17 C13 178.2(7) . . . . ?
C16 C5 C17 O7 3.2(13) . . . . ?
C18 C15 C2 C18 -0.7(14) . . . 3_655 ?
C18 C15 C2 O13 178.2(8) . . . . ?
C5 C13 C17 C5 4.1(14) 3_666 . . . ?
C5 C13 C17 O7 179.5(8) 3_666 . . . ?
C11 C14 C9 C11 1.7(12) 3_756 . . . ?
C11 C14 C9 O2 -176.2(8) 3_756 . . . ?
C13 C5 C17 C13 -4.0(14) 3_666 . . . ?
C13 C5 C17 O7 -179.1(9) 3_666 . . . ?
C7 C8 C10 C1 178.4(8) . . . . ?
C7 C8 C10 C8 -0.5(14) . . . 4_565 ?
C7 C3 C7 C8 -2.4(15) 4_565 . . . ?
C7 C3 C7 O9 178.2(8) 4_565 . . . ?
C2 C18 C15 C2 0.7(14) 3_655 . . . ?
C2 C18 C15 O5 163.4(16) 3_655 . . . ?
O2 C9 C11 C14 176.4(7) . . . 3_756 ?
O17 C8 C10 C1 2.5(14) . . . . ?
O17 C8 C10 C8 -176.4(8) . . . 4_565 ?
O17 C8 C7 C3 177.7(9) . . . . ?
O5 C15 C2 C18 -164.1(15) . . . 3_655 ?

_smtbx_masks_special_details     ?
loop_
_smtbx_masks_void_nr
_smtbx_masks_void_average_x
_smtbx_masks_void_average_y
_smtbx_masks_void_average_z
_smtbx_masks_void_volume
_smtbx_masks_void_count_electrons
_smtbx_masks_void_content
1 -0.575 -0.768 -0.337 2829.0 669.6 '17 DMF'

_smtbx_masks_void_probe_radius   1.2
_smtbx_masks_void_truncation_radius 1.2
# end Validation Reply Form
_olex2_submission_special_instructions 'No special instructions were received'
# start Validation Reply Form
_vrf_PLAT420_4                   
;
PROBLEM: D-H Bond Without Acceptor  O3       --H3A      .     Please Check 
RESPONSE: The solvent molecules are highly disordered, which supposed to 
form hydrogen bond with water molecules have been removed by the SQUEEZE 
routine in the PLATON software package.
;
