# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2023

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_wanghaol_1025_auto
_database_code_depnum_ccdc_archive 'CCDC 2130928'
loop_
_audit_author_name
_audit_author_address
'Haolong Wang'
;Lanzhou University
China
;
_audit_update_record             
;
2023-10-27 deposited with the CCDC.	2023-11-22 downloaded from the CCDC.
;
_audit_creation_date             2023-10-27
_audit_creation_method           
;
Olex2 1.5-ac5-024
(compiled 2022.04.12 svn.rca3783a0 for Rigaku Oxford Diffraction, GUI svn.r6498)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C22 H22 Eu N8 O10'
_chemical_formula_sum            'C22 H22 Eu N8 O10'
_chemical_formula_weight         710.43
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/n 1'
_space_group_name_Hall           '-P 2yn'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   9.1272(3)
_cell_length_b                   14.1154(4)
_cell_length_c                   20.6307(7)
_cell_angle_alpha                90
_cell_angle_beta                 95.093(3)
_cell_angle_gamma                90
_cell_volume                     2647.44(14)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    12564
_cell_measurement_temperature    301.74(10)
_cell_measurement_theta_max      31.1070
_cell_measurement_theta_min      1.7640
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    2.440
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.94732
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.42.93a (Rigaku Oxford Diffraction, 2023)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear light colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.782
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1412
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.07
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0335
_diffrn_reflns_av_unetI/netI     0.0373
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.795
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            19329
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.795
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         30.937
_diffrn_reflns_theta_min         1.750
_diffrn_ambient_environment      air
_diffrn_ambient_temperature      301.74(10)
_diffrn_detector                 'Hybrid Pixel Array Detector'
_diffrn_detector_area_resol_mean 10.0000
_diffrn_detector_type            HyPix
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.795
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω      4.00  61.00   0.50    1.86    --    3.89  57.00  60.00  114
  2  ω    -13.00  49.00   0.50    1.86    --   -6.24  57.00 150.00  124
  3  ω     10.00  36.00   0.50    1.86    --    3.89 -99.00  30.00   52
  4  ω    -61.00   6.00   0.50    1.86    --   -6.24 -57.00-180.00  134
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'XtaLAB Synergy R, DW system, HyPix'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      0.0363083000
_diffrn_orient_matrix_UB_12      0.0395193000
_diffrn_orient_matrix_UB_13      0.0153689000
_diffrn_orient_matrix_UB_21      0.0418831000
_diffrn_orient_matrix_UB_22      -0.0309177000
_diffrn_orient_matrix_UB_23      0.0214753000
_diffrn_orient_matrix_UB_31      0.0548717000
_diffrn_orient_matrix_UB_32      -0.0025551000
_diffrn_orient_matrix_UB_33      -0.0222174000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'Rotating-anode X-ray tube'
_diffrn_source_type              'Rigaku (Mo) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                5297
_reflns_number_total             6680
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.42.93a (Rigaku OD, 2023)'
_computing_data_collection       'CrysAlisPro 1.171.42.93a (Rigaku OD, 2023)'
_computing_data_reduction        'CrysAlisPro 1.171.42.93a (Rigaku OD, 2023)'
_computing_molecular_graphics    'Olex2 1.5-ac5-024 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5-ac5-024 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         0.878
_refine_diff_density_min         -0.559
_refine_diff_density_rms         0.089
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.018
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     373
_refine_ls_number_reflns         6680
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0409
_refine_ls_R_factor_gt           0.0282
_refine_ls_restrained_S_all      1.018
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0283P)²+1.9660P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0652
_refine_ls_wR_factor_ref         0.0708
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Secondary CH2 refined with riding coordinates:
 C2(H2A,H2B), C9(H9A,H9B), C17(H17A,H17B)
2.b Aromatic/amide H refined with riding coordinates:
 C3(H3), C7(H7), C10(H10), C11(H11), C13(H13), C15(H15), C16(H16)
2.c Idealised Me refined as rotating group:
 C5(H5A,H5B,H5C), C19(H19A,H19B,H19C), C21(H21A,H21B,H21C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.37615(2) 0.73068(2) 0.33526(2) 0.03020(5) Uani 1 1 d . . . . .
O1 O 0.5664(2) 0.62051(15) 0.31599(10) 0.0391(5) Uani 1 1 d . . . . .
O2 O 0.3805(4) 0.8849(2) 0.16147(12) 0.0785(10) Uani 1 1 d . . . . .
O3 O 0.4620(3) 0.76489(18) 0.21882(12) 0.0505(6) Uani 1 1 d . . . . .
O4 O 0.5653(3) 0.75994(18) 0.42734(11) 0.0496(6) Uani 1 1 d . . . . .
O5 O 0.2924(3) 0.85120(19) 0.25260(10) 0.0510(6) Uani 1 1 d . . . . .
O6 O 0.5887(3) 0.84094(19) 0.34131(11) 0.0537(6) Uani 1 1 d . . . . .
O7 O 0.0394(3) 0.5717(2) 0.24102(15) 0.0750(9) Uani 1 1 d . . . . .
O8 O 0.2668(2) 0.61337(18) 0.25410(11) 0.0470(6) Uani 1 1 d . . . . .
O9 O 0.7582(4) 0.8465(3) 0.42165(16) 0.0972(12) Uani 1 1 d . . . . .
O10 O 0.1128(3) 0.6783(2) 0.31330(12) 0.0545(6) Uani 1 1 d . . . . .
N1 N 0.2410(3) 0.71912(17) 0.44308(11) 0.0330(5) Uani 1 1 d . . . . .
N2 N 0.6412(3) 0.8173(2) 0.39761(14) 0.0507(7) Uani 1 1 d . . . . .
N3 N 0.3793(3) 0.8345(2) 0.20908(11) 0.0432(6) Uani 1 1 d . . . . .
N4 N 0.3743(3) 0.56980(17) 0.39374(11) 0.0319(5) Uani 1 1 d . . . . .
N5 N 0.6016(3) 0.47407(19) 0.27741(12) 0.0380(6) Uani 1 1 d . . . . .
N6 N 0.3012(3) 0.97194(19) 0.36673(12) 0.0442(6) Uani 1 1 d . . . . .
N7 N 0.1369(3) 0.6195(2) 0.26889(13) 0.0463(7) Uani 1 1 d . . . . .
N8 N 0.2715(3) 0.88125(19) 0.38107(12) 0.0415(6) Uani 1 1 d . . . . .
C1 C 0.4537(3) 0.4998(2) 0.37218(14) 0.0350(6) Uani 1 1 d . . . . .
C2 C 0.5576(4) 0.3748(2) 0.26431(16) 0.0445(8) Uani 1 1 d . . . . .
H2A H 0.532788 0.367155 0.217903 0.053 Uiso 1 1 calc R U . . .
H2B H 0.469725 0.361495 0.285964 0.053 Uiso 1 1 calc R U . . .
C3 C 0.0807(4) 0.7028(3) 0.55128(15) 0.0471(8) Uani 1 1 d . . . . .
H3 H 0.025100 0.697873 0.586768 0.057 Uiso 1 1 calc R U . . .
C4 C 0.2138(3) 0.8851(2) 0.43828(13) 0.0363(6) Uani 1 1 d . . . . .
C5 C 0.6219(5) 0.5510(4) 0.17014(19) 0.0763(14) Uani 1 1 d . . . . .
H5A H 0.691981 0.572206 0.141263 0.114 Uiso 1 1 calc R U . . .
H5B H 0.559441 0.602799 0.179930 0.114 Uiso 1 1 calc R U . . .
H5C H 0.563217 0.501021 0.149711 0.114 Uiso 1 1 calc R U . . .
C6 C 0.1810(3) 0.7949(2) 0.46859(14) 0.0360(6) Uani 1 1 d . . . . .
C7 C 0.0975(4) 0.7887(2) 0.52238(15) 0.0446(8) Uani 1 1 d . . . . .
H7 H 0.054007 0.842568 0.538199 0.054 Uiso 1 1 calc R U . . .
C8 C 0.2245(3) 0.6345(2) 0.47202(13) 0.0327(6) Uani 1 1 d . . . . .
C9 C 0.3091(5) 1.1348(3) 0.41204(19) 0.0597(10) Uani 1 1 d . . . . .
H9A H 0.263827 1.168975 0.445823 0.072 Uiso 1 1 calc R U . . .
H9B H 0.273819 1.161762 0.370313 0.072 Uiso 1 1 calc R U . . .
C10 C 0.2085(4) 0.9783(2) 0.46076(15) 0.0446(8) Uani 1 1 d . . . . .
H10 H 0.172571 0.999208 0.499063 0.054 Uiso 1 1 calc R U . . .
C11 C 0.3842(4) 0.3947(2) 0.45500(16) 0.0441(7) Uani 1 1 d . . . . .
H11 H 0.387944 0.335506 0.474937 0.053 Uiso 1 1 calc R U . . .
C12 C 0.2985(3) 0.5544(2) 0.44614(13) 0.0331(6) Uani 1 1 d . . . . .
C13 C 0.2149(4) 0.4566(2) 0.53421(15) 0.0431(7) Uani 1 1 d . . . . .
H13 H 0.211235 0.398063 0.554649 0.052 Uiso 1 1 calc R U . . .
C14 C 0.5446(3) 0.5332(2) 0.31829(14) 0.0339(6) Uani 1 1 d . . . . .
C15 C 0.1434(4) 0.5309(2) 0.55726(15) 0.0425(7) Uani 1 1 d . . . . .
H15 H 0.090328 0.522748 0.593301 0.051 Uiso 1 1 calc R U . . .
C16 C 0.4636(4) 0.4115(2) 0.40290(16) 0.0434(7) Uani 1 1 d . . . . .
H16 H 0.523733 0.364548 0.388064 0.052 Uiso 1 1 calc R U . . .
C17 C 0.7019(4) 0.5147(3) 0.23204(18) 0.0531(9) Uani 1 1 d . . . . .
H17A H 0.771730 0.466585 0.221434 0.064 Uiso 1 1 calc R U . . .
H17B H 0.756966 0.566374 0.253553 0.064 Uiso 1 1 calc R U . . .
C18 C 0.2681(4) 1.0331(2) 0.41391(15) 0.0442(7) Uani 1 1 d . . . . .
C19 C 0.6745(4) 0.3034(3) 0.2865(2) 0.0606(10) Uani 1 1 d . . . . .
H19A H 0.762210 0.316189 0.265613 0.091 Uiso 1 1 calc R U . . .
H19B H 0.639940 0.240757 0.275213 0.091 Uiso 1 1 calc R U . . .
H19C H 0.695562 0.307729 0.332838 0.091 Uiso 1 1 calc R U . . .
C20 C 0.1474(3) 0.6219(2) 0.52747(14) 0.0374(7) Uani 1 1 d . . . . .
C21 C 0.4766(6) 1.1444(4) 0.4225(3) 0.0905(16) Uani 1 1 d . . . . .
H21A H 0.520686 1.112496 0.387991 0.136 Uiso 1 1 calc R U . . .
H21B H 0.511150 1.116489 0.463438 0.136 Uiso 1 1 calc R U . . .
H21C H 0.502955 1.210232 0.422529 0.136 Uiso 1 1 calc R U . . .
C22 C 0.2973(3) 0.4668(2) 0.47813(14) 0.0371(6) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O1 2.390(2) . ?
Eu1 O3 2.637(2) . ?
Eu1 O4 2.485(2) . ?
Eu1 O5 2.481(2) . ?
Eu1 O6 2.481(2) . ?
Eu1 O8 2.499(2) . ?
Eu1 O10 2.518(2) . ?
Eu1 N1 2.643(2) . ?
Eu1 N2 2.907(3) . ?
Eu1 N4 2.572(2) . ?
Eu1 N7 2.928(3) . ?
Eu1 N8 2.546(3) . ?
O1 C14 1.250(4) . ?
O2 N3 1.214(3) . ?
O3 N3 1.244(4) . ?
O4 N2 1.260(4) . ?
O5 N3 1.272(3) . ?
O6 N2 1.262(4) . ?
O7 N7 1.220(4) . ?
O8 N7 1.254(3) . ?
O9 N2 1.209(4) . ?
O10 N7 1.270(4) . ?
N1 C6 1.332(4) . ?
N1 C8 1.349(4) . ?
N4 C1 1.326(4) . ?
N4 C12 1.352(3) . ?
N5 C2 1.476(4) . ?
N5 C14 1.325(4) . ?
N5 C17 1.482(4) . ?
N6 N8 1.347(4) . ?
N6 C18 1.355(4) . ?
N8 C4 1.336(3) . ?
C1 C14 1.520(4) . ?
C1 C16 1.397(4) . ?
C2 C19 1.509(5) . ?
C3 C7 1.366(5) . ?
C3 C20 1.402(5) . ?
C4 C6 1.461(4) . ?
C4 C10 1.397(4) . ?
C5 C17 1.503(6) . ?
C6 C7 1.404(4) . ?
C8 C12 1.444(4) . ?
C8 C20 1.407(4) . ?
C9 C18 1.485(5) . ?
C9 C21 1.531(7) . ?
C10 C18 1.386(5) . ?
C11 C16 1.370(4) . ?
C11 C22 1.400(5) . ?
C12 C22 1.402(4) . ?
C13 C15 1.344(5) . ?
C13 C22 1.442(4) . ?
C15 C20 1.426(4) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Eu1 O3 71.85(7) . . ?
O1 Eu1 O4 76.69(8) . . ?
O1 Eu1 O5 121.05(7) . . ?
O1 Eu1 O6 80.81(8) . . ?
O1 Eu1 O8 73.15(7) . . ?
O1 Eu1 O10 118.37(8) . . ?
O1 Eu1 N1 120.01(7) . . ?
O1 Eu1 N2 76.06(8) . . ?
O1 Eu1 N4 62.53(7) . . ?
O1 Eu1 N7 95.52(8) . . ?
O1 Eu1 N8 155.07(8) . . ?
O3 Eu1 N1 167.66(8) . . ?
O3 Eu1 N2 91.32(8) . . ?
O3 Eu1 N7 86.66(8) . . ?
O4 Eu1 O3 115.06(8) . . ?
O4 Eu1 O8 146.22(8) . . ?
O4 Eu1 O10 140.69(8) . . ?
O4 Eu1 N1 73.22(8) . . ?
O4 Eu1 N2 25.53(8) . . ?
O4 Eu1 N4 79.70(7) . . ?
O4 Eu1 N7 152.25(8) . . ?
O4 Eu1 N8 80.54(9) . . ?
O5 Eu1 O3 49.20(7) . . ?
O5 Eu1 O4 124.21(8) . . ?
O5 Eu1 O6 78.24(8) . . ?
O5 Eu1 O8 85.03(9) . . ?
O5 Eu1 O10 81.18(9) . . ?
O5 Eu1 N1 118.85(7) . . ?
O5 Eu1 N2 102.08(9) . . ?
O5 Eu1 N4 155.97(8) . . ?
O5 Eu1 N7 82.79(9) . . ?
O5 Eu1 N8 65.16(8) . . ?
O6 Eu1 O3 68.69(8) . . ?
O6 Eu1 O4 50.99(7) . . ?
O6 Eu1 O8 135.49(8) . . ?
O6 Eu1 O10 157.36(9) . . ?
O6 Eu1 N1 114.69(8) . . ?
O6 Eu1 N2 25.55(8) . . ?
O6 Eu1 N4 124.59(8) . . ?
O6 Eu1 N7 155.06(8) . . ?
O6 Eu1 N8 77.01(9) . . ?
O8 Eu1 O3 69.15(8) . . ?
O8 Eu1 O10 50.71(7) . . ?
O8 Eu1 N1 109.55(7) . . ?
O8 Eu1 N2 147.39(8) . . ?
O8 Eu1 N4 73.17(8) . . ?
O8 Eu1 N7 25.15(7) . . ?
O8 Eu1 N8 131.39(8) . . ?
O10 Eu1 O3 104.25(8) . . ?
O10 Eu1 N1 67.89(8) . . ?
O10 Eu1 N2 161.28(8) . . ?
O10 Eu1 N4 77.25(8) . . ?
O10 Eu1 N7 25.56(7) . . ?
O10 Eu1 N8 85.88(9) . . ?
N1 Eu1 N2 94.93(8) . . ?
N1 Eu1 N7 88.62(8) . . ?
N2 Eu1 N7 171.54(9) . . ?
N4 Eu1 O3 127.14(8) . . ?
N4 Eu1 N1 61.82(7) . . ?
N4 Eu1 N2 101.75(8) . . ?
N4 Eu1 N7 73.18(8) . . ?
N8 Eu1 O3 109.69(8) . . ?
N8 Eu1 N1 61.35(8) . . ?
N8 Eu1 N2 79.02(9) . . ?
N8 Eu1 N4 123.00(8) . . ?
N8 Eu1 N7 109.39(9) . . ?
C14 O1 Eu1 121.00(18) . . ?
N3 O3 Eu1 93.83(16) . . ?
N2 O4 Eu1 96.29(18) . . ?
N3 O5 Eu1 100.63(18) . . ?
N2 O6 Eu1 96.44(18) . . ?
N7 O8 Eu1 96.95(17) . . ?
N7 O10 Eu1 95.62(17) . . ?
C6 N1 Eu1 121.47(19) . . ?
C6 N1 C8 118.1(2) . . ?
C8 N1 Eu1 120.38(18) . . ?
O4 N2 Eu1 58.18(15) . . ?
O4 N2 O6 115.9(3) . . ?
O6 N2 Eu1 58.01(15) . . ?
O9 N2 Eu1 174.2(3) . . ?
O9 N2 O4 121.6(3) . . ?
O9 N2 O6 122.5(3) . . ?
O2 N3 Eu1 173.4(3) . . ?
O2 N3 O3 123.0(3) . . ?
O2 N3 O5 120.9(3) . . ?
O3 N3 Eu1 61.64(15) . . ?
O3 N3 O5 116.1(3) . . ?
O5 N3 Eu1 54.65(14) . . ?
C1 N4 Eu1 118.32(18) . . ?
C1 N4 C12 118.8(3) . . ?
C12 N4 Eu1 122.84(19) . . ?
C2 N5 C17 115.2(3) . . ?
C14 N5 C2 126.8(3) . . ?
C14 N5 C17 117.2(3) . . ?
N8 N6 C18 112.6(2) . . ?
O7 N7 Eu1 178.6(3) . . ?
O7 N7 O8 120.9(3) . . ?
O7 N7 O10 122.4(3) . . ?
O8 N7 Eu1 57.89(15) . . ?
O8 N7 O10 116.7(3) . . ?
O10 N7 Eu1 58.82(15) . . ?
N6 N8 Eu1 128.46(18) . . ?
C4 N8 Eu1 123.5(2) . . ?
C4 N8 N6 105.0(2) . . ?
N4 C1 C14 111.4(3) . . ?
N4 C1 C16 121.9(3) . . ?
C16 C1 C14 126.2(3) . . ?
N5 C2 C19 113.9(3) . . ?
C7 C3 C20 120.1(3) . . ?
N8 C4 C6 117.0(3) . . ?
N8 C4 C10 111.1(3) . . ?
C10 C4 C6 131.6(3) . . ?
N1 C6 C4 115.1(2) . . ?
N1 C6 C7 122.2(3) . . ?
C7 C6 C4 122.6(3) . . ?
C3 C7 C6 119.4(3) . . ?
N1 C8 C12 117.1(2) . . ?
N1 C8 C20 123.7(3) . . ?
C20 C8 C12 119.1(3) . . ?
C18 C9 C21 109.4(4) . . ?
C18 C10 C4 105.4(3) . . ?
C16 C11 C22 119.7(3) . . ?
N4 C12 C8 117.3(3) . . ?
N4 C12 C22 123.0(3) . . ?
C22 C12 C8 119.5(3) . . ?
C15 C13 C22 120.7(3) . . ?
O1 C14 Eu1 39.55(13) . . ?
O1 C14 N5 121.6(3) . . ?
O1 C14 C1 115.6(2) . . ?
N5 C14 Eu1 146.4(2) . . ?
N5 C14 C1 122.7(3) . . ?
C1 C14 Eu1 83.80(16) . . ?
C13 C15 C20 121.2(3) . . ?
C11 C16 C1 119.6(3) . . ?
N5 C17 C5 112.8(3) . . ?
N6 C18 C9 121.6(3) . . ?
N6 C18 C10 105.8(3) . . ?
C10 C18 C9 132.3(3) . . ?
C3 C20 C8 116.5(3) . . ?
C3 C20 C15 123.6(3) . . ?
C8 C20 C15 119.9(3) . . ?
C11 C22 C12 116.9(3) . . ?
C11 C22 C13 123.5(3) . . ?
C12 C22 C13 119.5(3) . . ?

_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.115
_oxdiff_exptl_absorpt_empirical_full_min 0.935
