# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2024

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_3
_database_code_depnum_ccdc_archive 'CCDC 2305339'
loop_
_audit_author_name
_audit_author_address
'Stefano Zacchini'
;Universita di Bologna
Italy
;
_audit_update_record             
;
2023-11-02 deposited with the CCDC.	2024-01-18 downloaded from the CCDC.
;
# start Validation Reply Form
_vrf_PLAT971_3                   
;
PROBLEM:  Check Calcd Resid. Dens
RESPONSE: This alert is due to high values for 
the residual electron density. This maximum is located close
to the Au atoms, in a position which is not realistic for 
any atom, and this is a series termination error, 
common with heavy atoms.
;
# end Validation Reply Form 
_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C58 H55 Au2 Cl4 N O12 P2 Ru4'
_chemical_formula_weight         1959.98

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   14.5146(8)
_cell_length_b                   14.8691(8)
_cell_length_c                   15.0629(9)
_cell_angle_alpha                90.759(2)
_cell_angle_beta                 95.483(2)
_cell_angle_gamma                96.132(2)
_cell_volume                     3216.6(3)
_cell_formula_units_Z            2
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    9804
_cell_measurement_theta_min      2.3705
_cell_measurement_theta_max      28.767

_exptl_crystal_description       prism
_exptl_crystal_colour            black
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    2.024
_exptl_crystal_F_000             1876
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.190
_exptl_crystal_size_mid          0.150
_exptl_crystal_size_min          0.120
_exptl_absorpt_coefficient_mu    5.733
_shelx_estimated_absorpt_T_min   0.409
_shelx_estimated_absorpt_T_max   0.546
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_correction_T_min  0.0915
_exptl_absorpt_correction_T_max  0.2346
_exptl_absorpt_process_details   
;
 Data were corrected for Lorentz polarization and absorption
 effects (empirical absorption corrections SADABS).
 R(int) = 0.1504 (selected reflections only, before parameter refinement)
 R(int) = 0.0578 (selected reflections only, after parameter refinement)
;
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'fine-focus sealed tube'
_diffrn_measurement_device_type  'PHOTON2 area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            42391
_diffrn_reflns_av_unetI/netI     0.0461
_diffrn_reflns_av_R_equivalents  0.0490
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_theta_min         1.866
_diffrn_reflns_theta_max         25.999
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             12625
_reflns_number_gt                11117
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'APEX2 (Bruker AXS, 2006)'
_computing_cell_refinement       'APEX2 (Bruker AXS, 2006)'
_computing_data_reduction        'SAINT (Bruker AXS, 2004)'
_computing_structure_solution    'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    'SCHAKAL99 (Keller, 1999)'
_computing_publication_material  'XCIF (Bruker AXS, 2001)'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0282P)²+11.0737P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         12625
_refine_ls_number_parameters     755
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.0422
_refine_ls_R_factor_gt           0.0346
_refine_ls_wR_factor_ref         0.0808
_refine_ls_wR_factor_gt          0.0783
_refine_ls_goodness_of_fit_ref   1.071
_refine_ls_restrained_S_all      1.073
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.80229(2) 0.70788(2) 0.68217(2) 0.01617(6) Uani 1 1 d . . . . .
Au2 Au 0.61170(2) 0.71670(2) 0.70586(2) 0.02085(6) Uani 1 1 d . . . . .
Ru1 Ru 0.70648(3) 0.42785(3) 0.78415(3) 0.02319(11) Uani 1 1 d . U . . .
H1 H 0.652(4) 0.526(4) 0.769(4) 0.028 Uiso 1 1 d . U . . .
Ru2 Ru 0.86350(3) 0.55176(3) 0.75705(3) 0.01645(9) Uani 1 1 d . . . . .
Ru3 Ru 0.71601(3) 0.62316(3) 0.83368(3) 0.01592(9) Uani 1 1 d . . . . .
Ru4 Ru 0.67416(3) 0.55523(3) 0.65120(3) 0.01945(10) Uani 1 1 d . . . . .
C1 C 0.7340(5) 0.4247(4) 0.9092(5) 0.0365(17) Uani 1 1 d . . . . .
C2 C 0.7703(4) 0.3309(4) 0.7477(5) 0.0295(14) Uani 1 1 d . . . . .
C3 C 0.5868(5) 0.3618(4) 0.7848(5) 0.0362(16) Uani 1 1 d . . . . .
C4 C 0.8887(5) 0.5176(4) 0.6402(4) 0.0295(14) Uani 1 1 d . . . . .
C5 C 0.9247(4) 0.4661(4) 0.8257(4) 0.0226(12) Uani 1 1 d . . . . .
C6 C 0.9606(4) 0.6484(4) 0.7684(4) 0.0228(12) Uani 1 1 d . . . . .
C7 C 0.8349(4) 0.5988(4) 0.8968(4) 0.0209(12) Uani 1 1 d . . . . .
C8 C 0.7369(4) 0.7457(4) 0.8651(4) 0.0257(13) Uani 1 1 d . . . . .
C9 C 0.6313(4) 0.6064(4) 0.9195(4) 0.0230(12) Uani 1 1 d . . . . .
C10 C 0.5463(4) 0.5388(5) 0.6179(4) 0.0384(17) Uani 1 1 d . . . . .
C11 C 0.6966(6) 0.4347(5) 0.6190(6) 0.051(2) Uani 1 1 d . U . . .
C12 C 0.6951(4) 0.6031(5) 0.5403(4) 0.0308(15) Uani 1 1 d . . . . .
O1 O 0.7514(4) 0.4157(3) 0.9847(3) 0.0491(14) Uani 1 1 d . . . . .
O2 O 0.8074(4) 0.2731(3) 0.7240(4) 0.0452(13) Uani 1 1 d . . . . .
O3 O 0.5159(4) 0.3201(4) 0.7842(4) 0.0570(16) Uani 1 1 d . . . . .
O4 O 0.9128(4) 0.5008(3) 0.5727(3) 0.0476(14) Uani 1 1 d . . . . .
O5 O 0.9660(3) 0.4177(3) 0.8672(3) 0.0334(10) Uani 1 1 d . . . . .
O6 O 1.0260(3) 0.6993(3) 0.7820(3) 0.0285(10) Uani 1 1 d . . . . .
O7 O 0.8822(3) 0.6039(3) 0.9639(3) 0.0275(9) Uani 1 1 d . . . . .
O8 O 0.7500(3) 0.8202(3) 0.8915(3) 0.0345(11) Uani 1 1 d . . . . .
O9 O 0.5806(3) 0.5952(3) 0.9737(3) 0.0388(11) Uani 1 1 d . . . . .
O10 O 0.4672(3) 0.5279(5) 0.5949(4) 0.065(2) Uani 1 1 d . . . . .
O11 O 0.7082(5) 0.3819(3) 0.5642(4) 0.0676(19) Uani 1 1 d . . . . .
O12 O 0.7044(4) 0.6242(4) 0.4696(3) 0.0656(19) Uani 1 1 d . . . . .
P1 P 0.87091(9) 0.82635(9) 0.60787(9) 0.0150(3) Uani 1 1 d . . . . .
P2 P 0.51452(10) 0.82793(10) 0.70222(10) 0.0210(3) Uani 1 1 d . . . . .
C101 C 0.9879(4) 0.8081(3) 0.5800(4) 0.0155(10) Uani 1 1 d . . . . .
C102 C 0.9994(4) 0.7265(4) 0.5393(4) 0.0193(11) Uani 1 1 d . . . . .
H102 H 0.9480 0.6813 0.5289 0.023 Uiso 1 1 calc R U . . .
C103 C 1.0856(4) 0.7105(4) 0.5136(4) 0.0251(13) Uani 1 1 d . . . . .
H103 H 1.0929 0.6550 0.4845 0.030 Uiso 1 1 calc R U . . .
C104 C 1.1608(4) 0.7756(4) 0.5306(4) 0.0249(13) Uani 1 1 d . . . . .
H104 H 1.2200 0.7647 0.5135 0.030 Uiso 1 1 calc R U . . .
C105 C 1.1501(4) 0.8562(4) 0.5724(4) 0.0234(12) Uani 1 1 d . . . . .
H105 H 1.2021 0.9005 0.5849 0.028 Uiso 1 1 calc R U . . .
C106 C 1.0637(4) 0.8728(4) 0.5963(4) 0.0204(12) Uani 1 1 d . . . . .
H106 H 1.0563 0.9290 0.6240 0.025 Uiso 1 1 calc R U . . .
C107 C 0.8925(4) 0.9343(4) 0.6680(4) 0.0175(11) Uani 1 1 d . . . . .
C108 C 0.9235(4) 0.9341(4) 0.7584(4) 0.0224(12) Uani 1 1 d . . . . .
H108 H 0.9241 0.8783 0.7885 0.027 Uiso 1 1 calc R U . . .
C109 C 0.9531(4) 1.0138(4) 0.8042(4) 0.0288(14) Uani 1 1 d . . . . .
H109 H 0.9758 1.0129 0.8655 0.035 Uiso 1 1 calc R U . . .
C110 C 0.9500(4) 1.0964(4) 0.7615(4) 0.0291(14) Uani 1 1 d . . . . .
H110 H 0.9718 1.1515 0.7930 0.035 Uiso 1 1 calc R U . . .
C111 C 0.9151(4) 1.0973(4) 0.6729(4) 0.0262(13) Uani 1 1 d . . . . .
H111 H 0.9106 1.1533 0.6440 0.031 Uiso 1 1 calc R U . . .
C112 C 0.8865(4) 1.0165(4) 0.6262(4) 0.0214(12) Uani 1 1 d . . . . .
H112 H 0.8627 1.0174 0.5652 0.026 Uiso 1 1 calc R U . . .
C113 C 0.8117(4) 0.8492(3) 0.4996(4) 0.0184(11) Uani 1 1 d . . . . .
C114 C 0.8605(4) 0.8800(4) 0.4286(4) 0.0198(11) Uani 1 1 d . . . . .
H114 H 0.9265 0.8905 0.4364 0.024 Uiso 1 1 calc R U . . .
C115 C 0.8131(4) 0.8954(4) 0.3466(4) 0.0251(13) Uani 1 1 d . . . . .
H115 H 0.8469 0.9170 0.2988 0.030 Uiso 1 1 calc R U . . .
C116 C 0.7179(4) 0.8796(4) 0.3341(4) 0.0306(14) Uani 1 1 d . . . . .
H116 H 0.6862 0.8888 0.2774 0.037 Uiso 1 1 calc R U . . .
C117 C 0.6681(5) 0.8504(5) 0.4039(5) 0.0416(18) Uani 1 1 d . . . . .
H117 H 0.6020 0.8415 0.3957 0.050 Uiso 1 1 calc R U . . .
C118 C 0.7149(4) 0.8342(5) 0.4862(5) 0.0316(15) Uani 1 1 d . . . . .
H118 H 0.6805 0.8128 0.5336 0.038 Uiso 1 1 calc R U . . .
C201 C 0.4187(4) 0.7976(4) 0.7697(4) 0.0209(12) Uani 1 1 d . . . . .
C202 C 0.4410(5) 0.7742(5) 0.8573(5) 0.0336(15) Uani 1 1 d . . . . .
H202 H 0.5043 0.7743 0.8802 0.040 Uiso 1 1 calc R U . . .
C203 C 0.3706(5) 0.7505(5) 0.9112(5) 0.0389(17) Uani 1 1 d . . . . .
H203 H 0.3856 0.7346 0.9713 0.047 Uiso 1 1 calc R U . . .
C204 C 0.2796(5) 0.7500(5) 0.8779(5) 0.0407(18) Uani 1 1 d . . . . .
H204 H 0.2317 0.7334 0.9153 0.049 Uiso 1 1 calc R U . . .
C205 C 0.2567(5) 0.7727(5) 0.7924(5) 0.0409(18) Uani 1 1 d . . . . .
H205 H 0.1931 0.7726 0.7705 0.049 Uiso 1 1 calc R U . . .
C206 C 0.3264(4) 0.7962(5) 0.7366(5) 0.0332(15) Uani 1 1 d . . . . .
H206 H 0.3106 0.8110 0.6763 0.040 Uiso 1 1 calc R U . . .
C207 C 0.5640(4) 0.9382(4) 0.7504(4) 0.0243(13) Uani 1 1 d . . . . .
C208 C 0.6593(4) 0.9608(4) 0.7548(4) 0.0251(13) Uani 1 1 d . . . . .
H208 H 0.6978 0.9195 0.7327 0.030 Uiso 1 1 calc R U . . .
C209 C 0.6982(4) 1.0435(5) 0.7913(5) 0.0333(15) Uani 1 1 d . . . . .
H209 H 0.7638 1.0585 0.7952 0.040 Uiso 1 1 calc R U . . .
C210 C 0.6426(5) 1.1050(5) 0.8222(4) 0.0337(15) Uani 1 1 d . . . . .
H210 H 0.6698 1.1622 0.8460 0.040 Uiso 1 1 calc R U . . .
C211 C 0.5490(5) 1.0830(5) 0.8182(5) 0.0390(16) Uani 1 1 d . . . . .
H211 H 0.5109 1.1251 0.8395 0.047 Uiso 1 1 calc R U . . .
C212 C 0.5083(4) 0.9992(4) 0.7832(5) 0.0311(14) Uani 1 1 d . . . . .
H212 H 0.4429 0.9838 0.7817 0.037 Uiso 1 1 calc R U . . .
C213 C 0.4600(4) 0.8499(4) 0.5914(4) 0.0263(13) Uani 1 1 d . . . . .
C214 C 0.4216(4) 0.9289(5) 0.5713(5) 0.0369(16) Uani 1 1 d . . . . .
H214 H 0.4245 0.9756 0.6156 0.044 Uiso 1 1 calc R U . . .
C215 C 0.3784(5) 0.9404(6) 0.4861(5) 0.047(2) Uani 1 1 d . . . . .
H215 H 0.3500 0.9940 0.4733 0.056 Uiso 1 1 calc R U . . .
C216 C 0.3768(5) 0.8758(6) 0.4216(5) 0.048(2) Uani 1 1 d . . . . .
H216 H 0.3488 0.8849 0.3632 0.058 Uiso 1 1 calc R U . . .
C217 C 0.4159(5) 0.7968(6) 0.4408(5) 0.047(2) Uani 1 1 d . . . . .
H217 H 0.4137 0.7510 0.3959 0.056 Uiso 1 1 calc R U . . .
C218 C 0.4583(4) 0.7839(5) 0.5255(4) 0.0344(16) Uani 1 1 d . . . . .
H218 H 0.4860 0.7299 0.5383 0.041 Uiso 1 1 calc R U . . .
N1 N 0.7749(3) 0.5740(3) 0.2325(3) 0.0213(10) Uani 1 1 d . . . . .
C301 C 0.8216(4) 0.4870(4) 0.2397(4) 0.0286(14) Uani 1 1 d . . . . .
H30A H 0.7904 0.4434 0.1932 0.034 Uiso 1 1 calc R U . . .
H30B H 0.8872 0.5006 0.2268 0.034 Uiso 1 1 calc R U . . .
C302 C 0.8204(6) 0.4423(5) 0.3284(5) 0.0442(18) Uani 1 1 d . . . . .
H30C H 0.8515 0.4845 0.3753 0.066 Uiso 1 1 calc R U . . .
H30D H 0.8531 0.3880 0.3273 0.066 Uiso 1 1 calc R U . . .
H30E H 0.7558 0.4253 0.3407 0.066 Uiso 1 1 calc R U . . .
C303 C 0.8215(4) 0.6430(4) 0.3020(4) 0.0250(13) Uani 1 1 d . . . . .
H30F H 0.8145 0.6179 0.3618 0.030 Uiso 1 1 calc R U . . .
H30G H 0.7883 0.6978 0.2975 0.030 Uiso 1 1 calc R U . . .
C304 C 0.9248(4) 0.6711(4) 0.2948(5) 0.0319(15) Uani 1 1 d . . . . .
H30H H 0.9599 0.6190 0.3067 0.048 Uiso 1 1 calc R U . . .
H30I H 0.9474 0.7198 0.3385 0.048 Uiso 1 1 calc R U . . .
H30J H 0.9334 0.6925 0.2346 0.048 Uiso 1 1 calc R U . . .
C305 C 0.6734(4) 0.5581(4) 0.2512(4) 0.0268(13) Uani 1 1 d . . . . .
H30K H 0.6709 0.5394 0.3139 0.032 Uiso 1 1 calc R U . . .
H30L H 0.6458 0.6160 0.2451 0.032 Uiso 1 1 calc R U . . .
C306 C 0.6144(4) 0.4877(5) 0.1913(5) 0.0360(16) Uani 1 1 d . . . . .
H30M H 0.6146 0.5063 0.1292 0.054 Uiso 1 1 calc R U . . .
H30N H 0.5505 0.4816 0.2080 0.054 Uiso 1 1 calc R U . . .
H30O H 0.6399 0.4294 0.1980 0.054 Uiso 1 1 calc R U . . .
C307 C 0.7843(4) 0.6087(4) 0.1390(4) 0.0284(13) Uani 1 1 d . . . . .
H30P H 0.8507 0.6122 0.1277 0.034 Uiso 1 1 calc R U . . .
H30Q H 0.7491 0.5641 0.0956 0.034 Uiso 1 1 calc R U . . .
C308 C 0.7510(6) 0.6989(5) 0.1216(5) 0.0411(17) Uani 1 1 d . . . . .
H30R H 0.6838 0.6948 0.1257 0.062 Uiso 1 1 calc R U . . .
H30S H 0.7645 0.7179 0.0617 0.062 Uiso 1 1 calc R U . . .
H30T H 0.7830 0.7433 0.1659 0.062 Uiso 1 1 calc R U . . .
C401 C 0.7274(7) 0.9964(6) 0.0234(6) 0.059(2) Uani 1 1 d . . . . .
H40A H 0.7109 1.0587 0.0140 0.071 Uiso 1 1 calc R U . . .
H40B H 0.7535 0.9765 -0.0310 0.071 Uiso 1 1 calc R U . . .
Cl1 Cl 0.8121(3) 0.9979(3) 0.1131(2) 0.1053(11) Uani 1 1 d . . . . .
Cl2 Cl 0.6283(3) 0.9268(3) 0.0377(3) 0.1375(17) Uani 1 1 d . . . . .
C411 C 0.0480(5) 0.7687(6) -0.0133(6) 0.052(2) Uani 1 1 d . . . . .
H41A H 0.0677 0.7763 -0.0741 0.063 Uiso 1 1 calc R U . . .
H41B H 0.0254 0.7041 -0.0071 0.063 Uiso 1 1 calc R U . . .
Cl3 Cl 0.14428(13) 0.79688(15) 0.06405(13) 0.0505(5) Uani 1 1 d . . . . .
Cl4 Cl -0.04296(14) 0.83324(15) -0.00133(16) 0.0589(6) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 P1 2.2887(13) . ?
Au1 Ru4 2.7808(5) . ?
Au1 Ru2 2.7873(5) . ?
Au1 Au2 2.8393(3) . ?
Au1 Ru3 2.9408(5) . ?
Au2 P2 2.2835(15) . ?
Au2 Ru4 2.7964(5) . ?
Au2 Ru3 2.8103(5) . ?
Ru1 C1 1.891(8) . ?
Ru1 C2 1.898(7) . ?
Ru1 C3 1.903(7) . ?
Ru1 C11 2.482(9) . ?
Ru1 Ru4 2.8156(7) . ?
Ru1 Ru2 2.8383(6) . ?
Ru1 Ru3 2.9743(6) . ?
Ru1 H1 1.73(6) . ?
Ru2 C5 1.893(6) . ?
Ru2 C6 1.896(6) . ?
Ru2 C4 1.905(6) . ?
Ru2 C7 2.299(6) . ?
Ru2 Ru3 2.8227(6) . ?
Ru2 Ru4 3.0483(6) . ?
Ru3 C8 1.862(6) . ?
Ru3 C9 1.869(6) . ?
Ru3 C7 1.961(6) . ?
Ru3 Ru4 2.9018(6) . ?
Ru3 H1 1.84(6) . ?
Ru4 C12 1.863(6) . ?
Ru4 C10 1.865(6) . ?
Ru4 C11 1.920(7) . ?
Ru4 H1 1.89(6) . ?
C1 O1 1.154(8) . ?
C2 O2 1.132(8) . ?
C3 O3 1.142(8) . ?
C4 O4 1.140(8) . ?
C5 O5 1.140(7) . ?
C6 O6 1.150(7) . ?
C7 O7 1.162(7) . ?
C8 O8 1.162(7) . ?
C9 O9 1.153(7) . ?
C10 O10 1.160(8) . ?
C11 O11 1.167(10) . ?
C12 O12 1.130(8) . ?
P1 C107 1.815(5) . ?
P1 C113 1.823(6) . ?
P1 C101 1.835(5) . ?
P2 C201 1.821(6) . ?
P2 C213 1.827(6) . ?
P2 C207 1.830(6) . ?
C101 C106 1.382(7) . ?
C101 C102 1.385(8) . ?
C102 C103 1.388(8) . ?
C102 H102 0.9500 . ?
C103 C104 1.381(8) . ?
C103 H103 0.9500 . ?
C104 C105 1.378(8) . ?
C104 H104 0.9500 . ?
C105 C106 1.383(8) . ?
C105 H105 0.9500 . ?
C106 H106 0.9500 . ?
C107 C112 1.390(8) . ?
C107 C108 1.393(8) . ?
C108 C109 1.371(8) . ?
C108 H108 0.9500 . ?
C109 C110 1.397(9) . ?
C109 H109 0.9500 . ?
C110 C111 1.382(9) . ?
C110 H110 0.9500 . ?
C111 C112 1.388(8) . ?
C111 H111 0.9500 . ?
C112 H112 0.9500 . ?
C113 C118 1.394(8) . ?
C113 C114 1.394(8) . ?
C114 C115 1.390(8) . ?
C114 H114 0.9500 . ?
C115 C116 1.371(9) . ?
C115 H115 0.9500 . ?
C116 C117 1.380(10) . ?
C116 H116 0.9500 . ?
C117 C118 1.392(9) . ?
C117 H117 0.9500 . ?
C118 H118 0.9500 . ?
C201 C206 1.382(8) . ?
C201 C202 1.386(9) . ?
C202 C203 1.384(9) . ?
C202 H202 0.9500 . ?
C203 C204 1.367(10) . ?
C203 H203 0.9500 . ?
C204 C205 1.355(11) . ?
C204 H204 0.9500 . ?
C205 C206 1.396(9) . ?
C205 H205 0.9500 . ?
C206 H206 0.9500 . ?
C207 C208 1.383(8) . ?
C207 C212 1.393(9) . ?
C208 C209 1.383(9) . ?
C208 H208 0.9500 . ?
C209 C210 1.387(10) . ?
C209 H209 0.9500 . ?
C210 C211 1.359(9) . ?
C210 H210 0.9500 . ?
C211 C212 1.394(9) . ?
C211 H211 0.9500 . ?
C212 H212 0.9500 . ?
C213 C214 1.379(9) . ?
C213 C218 1.383(10) . ?
C214 C215 1.394(10) . ?
C214 H214 0.9500 . ?
C215 C216 1.354(12) . ?
C215 H215 0.9500 . ?
C216 C217 1.381(12) . ?
C216 H216 0.9500 . ?
C217 C218 1.387(10) . ?
C217 H217 0.9500 . ?
C218 H218 0.9500 . ?
N1 C303 1.515(7) . ?
N1 C307 1.520(8) . ?
N1 C305 1.521(7) . ?
N1 C301 1.524(7) . ?
C301 C302 1.501(9) . ?
C301 H30A 0.9900 . ?
C301 H30B 0.9900 . ?
C302 H30C 0.9800 . ?
C302 H30D 0.9800 . ?
C302 H30E 0.9800 . ?
C303 C304 1.527(8) . ?
C303 H30F 0.9900 . ?
C303 H30G 0.9900 . ?
C304 H30H 0.9800 . ?
C304 H30I 0.9800 . ?
C304 H30J 0.9800 . ?
C305 C306 1.509(8) . ?
C305 H30K 0.9900 . ?
C305 H30L 0.9900 . ?
C306 H30M 0.9800 . ?
C306 H30N 0.9800 . ?
C306 H30O 0.9800 . ?
C307 C308 1.491(9) . ?
C307 H30P 0.9900 . ?
C307 H30Q 0.9900 . ?
C308 H30R 0.9800 . ?
C308 H30S 0.9800 . ?
C308 H30T 0.9800 . ?
C401 Cl2 1.713(10) . ?
C401 Cl1 1.736(9) . ?
C401 H40A 0.9900 . ?
C401 H40B 0.9900 . ?
C411 Cl4 1.735(8) . ?
C411 Cl3 1.742(8) . ?
C411 H41A 0.9900 . ?
C411 H41B 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Au1 Ru4 140.55(4) . . ?
P1 Au1 Ru2 134.36(4) . . ?
Ru4 Au1 Ru2 66.387(14) . . ?
P1 Au1 Au2 115.06(4) . . ?
Ru4 Au1 Au2 59.668(12) . . ?
Ru2 Au1 Au2 110.578(12) . . ?
P1 Au1 Ru3 154.48(4) . . ?
Ru4 Au1 Ru3 60.874(13) . . ?
Ru2 Au1 Ru3 58.974(13) . . ?
Au2 Au1 Ru3 58.151(10) . . ?
P2 Au2 Ru4 155.64(4) . . ?
P2 Au2 Ru3 138.34(4) . . ?
Ru4 Au2 Ru3 62.337(14) . . ?
P2 Au2 Au1 135.62(4) . . ?
Ru4 Au2 Au1 59.126(11) . . ?
Ru3 Au2 Au1 62.734(11) . . ?
C1 Ru1 C2 100.3(3) . . ?
C1 Ru1 C3 94.2(3) . . ?
C2 Ru1 C3 97.4(3) . . ?
C1 Ru1 C11 171.2(3) . . ?
C2 Ru1 C11 75.0(3) . . ?
C3 Ru1 C11 93.8(3) . . ?
C1 Ru1 Ru4 139.03(19) . . ?
C2 Ru1 Ru4 114.3(2) . . ?
C3 Ru1 Ru4 102.1(2) . . ?
C11 Ru1 Ru4 41.92(17) . . ?
C1 Ru1 Ru2 94.84(19) . . ?
C2 Ru1 Ru2 89.91(18) . . ?
C3 Ru1 Ru2 167.2(2) . . ?
C11 Ru1 Ru2 77.90(19) . . ?
Ru4 Ru1 Ru2 65.251(16) . . ?
C1 Ru1 Ru3 78.96(19) . . ?
C2 Ru1 Ru3 147.48(18) . . ?
C3 Ru1 Ru3 115.1(2) . . ?
C11 Ru1 Ru3 100.94(17) . . ?
Ru4 Ru1 Ru3 60.082(15) . . ?
Ru2 Ru1 Ru3 58.049(15) . . ?
C1 Ru1 H1 103(2) . . ?
C2 Ru1 H1 155(2) . . ?
C3 Ru1 H1 89(2) . . ?
C11 Ru1 H1 81(2) . . ?
Ru4 Ru1 H1 41(2) . . ?
Ru2 Ru1 H1 80(2) . . ?
Ru3 Ru1 H1 35(2) . . ?
C5 Ru2 C6 98.3(2) . . ?
C5 Ru2 C4 100.5(3) . . ?
C6 Ru2 C4 93.6(3) . . ?
C5 Ru2 C7 81.0(2) . . ?
C6 Ru2 C7 84.5(2) . . ?
C4 Ru2 C7 177.7(2) . . ?
C5 Ru2 Au1 166.11(18) . . ?
C6 Ru2 Au1 69.39(17) . . ?
C4 Ru2 Au1 86.99(18) . . ?
C7 Ru2 Au1 91.18(14) . . ?
C5 Ru2 Ru3 115.91(18) . . ?
C6 Ru2 Ru3 103.75(17) . . ?
C4 Ru2 Ru3 136.2(2) . . ?
C7 Ru2 Ru3 43.54(14) . . ?
Au1 Ru2 Ru3 63.226(13) . . ?
C5 Ru2 Ru1 81.10(16) . . ?
C6 Ru2 Ru1 164.44(18) . . ?
C4 Ru2 Ru1 101.81(19) . . ?
C7 Ru2 Ru1 80.06(13) . . ?
Au1 Ru2 Ru1 108.979(18) . . ?
Ru3 Ru2 Ru1 63.390(16) . . ?
C5 Ru2 Ru4 136.07(17) . . ?
C6 Ru2 Ru4 125.64(17) . . ?
C4 Ru2 Ru4 78.0(2) . . ?
C7 Ru2 Ru4 102.11(14) . . ?
Au1 Ru2 Ru4 56.703(12) . . ?
Ru3 Ru2 Ru4 59.092(15) . . ?
Ru1 Ru2 Ru4 57.016(15) . . ?
C8 Ru3 C9 89.7(3) . . ?
C8 Ru3 C7 92.1(2) . . ?
C9 Ru3 C7 104.2(2) . . ?
C8 Ru3 Au2 72.48(18) . . ?
C9 Ru3 Au2 99.88(18) . . ?
C7 Ru3 Au2 151.33(16) . . ?
C8 Ru3 Ru2 115.2(2) . . ?
C9 Ru3 Ru2 145.12(18) . . ?
C7 Ru3 Ru2 53.86(17) . . ?
Au2 Ru3 Ru2 110.394(18) . . ?
C8 Ru3 Ru4 123.65(18) . . ?
C9 Ru3 Ru4 122.86(18) . . ?
C7 Ru3 Ru4 117.50(17) . . ?
Au2 Ru3 Ru4 58.597(14) . . ?
Ru2 Ru3 Ru4 64.333(16) . . ?
C8 Ru3 Au1 75.53(19) . . ?
C9 Ru3 Au1 156.96(18) . . ?
C7 Ru3 Au1 94.11(16) . . ?
Au2 Ru3 Au1 59.116(11) . . ?
Ru2 Ru3 Au1 57.800(13) . . ?
Ru4 Ru3 Au1 56.838(13) . . ?
C8 Ru3 Ru1 173.34(19) . . ?
C9 Ru3 Ru1 94.93(18) . . ?
C7 Ru3 Ru1 82.11(16) . . ?
Au2 Ru3 Ru1 111.299(18) . . ?
Ru2 Ru3 Ru1 58.561(15) . . ?
Ru4 Ru3 Ru1 57.246(16) . . ?
Au1 Ru3 Ru1 101.462(17) . . ?
C8 Ru3 H1 153(2) . . ?
C9 Ru3 H1 89(2) . . ?
C7 Ru3 H1 115(2) . . ?
Au2 Ru3 H1 81(2) . . ?
Ru2 Ru3 H1 79(2) . . ?
Ru4 Ru3 H1 39(2) . . ?
Au1 Ru3 H1 96(2) . . ?
Ru1 Ru3 H1 33(2) . . ?
C12 Ru4 C10 90.5(3) . . ?
C12 Ru4 C11 94.8(4) . . ?
C10 Ru4 C11 95.7(3) . . ?
C12 Ru4 Au1 72.99(18) . . ?
C10 Ru4 Au1 133.2(3) . . ?
C11 Ru4 Au1 128.4(3) . . ?
C12 Ru4 Au2 90.8(2) . . ?
C10 Ru4 Au2 76.0(2) . . ?
C11 Ru4 Au2 170.1(3) . . ?
Au1 Ru4 Au2 61.206(11) . . ?
C12 Ru4 Ru1 150.6(2) . . ?
C10 Ru4 Ru1 105.5(2) . . ?
C11 Ru4 Ru1 59.7(3) . . ?
Au1 Ru4 Ru1 109.824(19) . . ?
Au2 Ru4 Ru1 116.67(2) . . ?
C12 Ru4 Ru3 133.96(19) . . ?
C10 Ru4 Ru3 111.7(2) . . ?
C11 Ru4 Ru3 120.8(2) . . ?
Au1 Ru4 Ru3 62.288(13) . . ?
Au2 Ru4 Ru3 59.066(13) . . ?
Ru1 Ru4 Ru3 62.672(17) . . ?
C12 Ru4 Ru2 107.4(2) . . ?
C10 Ru4 Ru2 162.0(2) . . ?
C11 Ru4 Ru2 81.6(2) . . ?
Au1 Ru4 Ru2 56.910(12) . . ?
Au2 Ru4 Ru2 104.545(16) . . ?
Ru1 Ru4 Ru2 57.733(15) . . ?
Ru3 Ru4 Ru2 56.575(15) . . ?
C12 Ru4 H1 171(2) . . ?
C10 Ru4 H1 89.9(19) . . ?
C11 Ru4 H1 94(2) . . ?
Au1 Ru4 H1 100.3(19) . . ?
Au2 Ru4 H1 80.5(19) . . ?
Ru1 Ru4 H1 37.0(19) . . ?
Ru3 Ru4 H1 38.3(19) . . ?
Ru2 Ru4 H1 72.7(19) . . ?
O1 C1 Ru1 174.6(6) . . ?
O2 C2 Ru1 178.4(6) . . ?
O3 C3 Ru1 178.1(7) . . ?
O4 C4 Ru2 173.1(6) . . ?
O5 C5 Ru2 176.2(5) . . ?
O6 C6 Ru2 170.9(5) . . ?
O7 C7 Ru3 146.7(5) . . ?
O7 C7 Ru2 130.6(4) . . ?
Ru3 C7 Ru2 82.6(2) . . ?
O8 C8 Ru3 174.7(5) . . ?
O9 C9 Ru3 178.4(6) . . ?
O10 C10 Ru4 178.1(6) . . ?
O11 C11 Ru4 149.4(7) . . ?
O11 C11 Ru1 132.1(6) . . ?
Ru4 C11 Ru1 78.4(3) . . ?
O12 C12 Ru4 173.3(6) . . ?
C107 P1 C113 106.0(3) . . ?
C107 P1 C101 101.9(2) . . ?
C113 P1 C101 102.6(2) . . ?
C107 P1 Au1 116.40(18) . . ?
C113 P1 Au1 115.53(17) . . ?
C101 P1 Au1 112.69(17) . . ?
C201 P2 C213 105.6(3) . . ?
C201 P2 C207 102.3(3) . . ?
C213 P2 C207 106.1(3) . . ?
C201 P2 Au2 110.34(19) . . ?
C213 P2 Au2 114.7(2) . . ?
C207 P2 Au2 116.5(2) . . ?
C106 C101 C102 119.3(5) . . ?
C106 C101 P1 122.7(4) . . ?
C102 C101 P1 118.0(4) . . ?
C101 C102 C103 120.4(5) . . ?
C101 C102 H102 119.8 . . ?
C103 C102 H102 119.8 . . ?
C104 C103 C102 119.7(5) . . ?
C104 C103 H103 120.2 . . ?
C102 C103 H103 120.2 . . ?
C105 C104 C103 120.1(5) . . ?
C105 C104 H104 119.9 . . ?
C103 C104 H104 119.9 . . ?
C104 C105 C106 120.0(5) . . ?
C104 C105 H105 120.0 . . ?
C106 C105 H105 120.0 . . ?
C101 C106 C105 120.4(5) . . ?
C101 C106 H106 119.8 . . ?
C105 C106 H106 119.8 . . ?
C112 C107 C108 119.2(5) . . ?
C112 C107 P1 122.7(4) . . ?
C108 C107 P1 117.9(4) . . ?
C109 C108 C107 120.3(5) . . ?
C109 C108 H108 119.8 . . ?
C107 C108 H108 119.8 . . ?
C108 C109 C110 120.4(6) . . ?
C108 C109 H109 119.8 . . ?
C110 C109 H109 119.8 . . ?
C111 C110 C109 119.5(5) . . ?
C111 C110 H110 120.3 . . ?
C109 C110 H110 120.3 . . ?
C110 C111 C112 120.1(5) . . ?
C110 C111 H111 120.0 . . ?
C112 C111 H111 120.0 . . ?
C111 C112 C107 120.3(6) . . ?
C111 C112 H112 119.8 . . ?
C107 C112 H112 119.8 . . ?
C118 C113 C114 118.5(5) . . ?
C118 C113 P1 119.6(4) . . ?
C114 C113 P1 121.9(4) . . ?
C115 C114 C113 120.4(5) . . ?
C115 C114 H114 119.8 . . ?
C113 C114 H114 119.8 . . ?
C116 C115 C114 120.4(6) . . ?
C116 C115 H115 119.8 . . ?
C114 C115 H115 119.8 . . ?
C115 C116 C117 120.1(6) . . ?
C115 C116 H116 119.9 . . ?
C117 C116 H116 119.9 . . ?
C116 C117 C118 119.9(6) . . ?
C116 C117 H117 120.1 . . ?
C118 C117 H117 120.1 . . ?
C117 C118 C113 120.6(6) . . ?
C117 C118 H118 119.7 . . ?
C113 C118 H118 119.7 . . ?
C206 C201 C202 119.7(5) . . ?
C206 C201 P2 122.6(5) . . ?
C202 C201 P2 117.6(4) . . ?
C203 C202 C201 119.8(6) . . ?
C203 C202 H202 120.1 . . ?
C201 C202 H202 120.1 . . ?
C204 C203 C202 120.0(7) . . ?
C204 C203 H203 120.0 . . ?
C202 C203 H203 120.0 . . ?
C205 C204 C203 121.0(6) . . ?
C205 C204 H204 119.5 . . ?
C203 C204 H204 119.5 . . ?
C204 C205 C206 120.1(7) . . ?
C204 C205 H205 120.0 . . ?
C206 C205 H205 120.0 . . ?
C201 C206 C205 119.4(6) . . ?
C201 C206 H206 120.3 . . ?
C205 C206 H206 120.3 . . ?
C208 C207 C212 119.6(6) . . ?
C208 C207 P2 118.7(5) . . ?
C212 C207 P2 121.7(4) . . ?
C209 C208 C207 119.7(6) . . ?
C209 C208 H208 120.1 . . ?
C207 C208 H208 120.1 . . ?
C208 C209 C210 120.7(6) . . ?
C208 C209 H209 119.7 . . ?
C210 C209 H209 119.7 . . ?
C211 C210 C209 119.7(6) . . ?
C211 C210 H210 120.2 . . ?
C209 C210 H210 120.2 . . ?
C210 C211 C212 120.6(7) . . ?
C210 C211 H211 119.7 . . ?
C212 C211 H211 119.7 . . ?
C207 C212 C211 119.6(6) . . ?
C207 C212 H212 120.2 . . ?
C211 C212 H212 120.2 . . ?
C214 C213 C218 119.4(6) . . ?
C214 C213 P2 122.8(5) . . ?
C218 C213 P2 117.8(5) . . ?
C213 C214 C215 120.0(8) . . ?
C213 C214 H214 120.0 . . ?
C215 C214 H214 120.0 . . ?
C216 C215 C214 120.6(8) . . ?
C216 C215 H215 119.7 . . ?
C214 C215 H215 119.7 . . ?
C215 C216 C217 119.9(7) . . ?
C215 C216 H216 120.1 . . ?
C217 C216 H216 120.1 . . ?
C216 C217 C218 120.3(8) . . ?
C216 C217 H217 119.9 . . ?
C218 C217 H217 119.9 . . ?
C213 C218 C217 119.8(7) . . ?
C213 C218 H218 120.1 . . ?
C217 C218 H218 120.1 . . ?
C303 N1 C307 110.8(4) . . ?
C303 N1 C305 106.1(4) . . ?
C307 N1 C305 111.4(4) . . ?
C303 N1 C301 110.1(5) . . ?
C307 N1 C301 107.1(4) . . ?
C305 N1 C301 111.4(4) . . ?
C302 C301 N1 115.3(5) . . ?
C302 C301 H30A 108.5 . . ?
N1 C301 H30A 108.5 . . ?
C302 C301 H30B 108.5 . . ?
N1 C301 H30B 108.5 . . ?
H30A C301 H30B 107.5 . . ?
C301 C302 H30C 109.5 . . ?
C301 C302 H30D 109.5 . . ?
H30C C302 H30D 109.5 . . ?
C301 C302 H30E 109.5 . . ?
H30C C302 H30E 109.5 . . ?
H30D C302 H30E 109.5 . . ?
N1 C303 C304 115.3(5) . . ?
N1 C303 H30F 108.5 . . ?
C304 C303 H30F 108.5 . . ?
N1 C303 H30G 108.5 . . ?
C304 C303 H30G 108.5 . . ?
H30F C303 H30G 107.5 . . ?
C303 C304 H30H 109.5 . . ?
C303 C304 H30I 109.5 . . ?
H30H C304 H30I 109.5 . . ?
C303 C304 H30J 109.5 . . ?
H30H C304 H30J 109.5 . . ?
H30I C304 H30J 109.5 . . ?
C306 C305 N1 114.8(5) . . ?
C306 C305 H30K 108.6 . . ?
N1 C305 H30K 108.6 . . ?
C306 C305 H30L 108.6 . . ?
N1 C305 H30L 108.6 . . ?
H30K C305 H30L 107.5 . . ?
C305 C306 H30M 109.5 . . ?
C305 C306 H30N 109.5 . . ?
H30M C306 H30N 109.5 . . ?
C305 C306 H30O 109.5 . . ?
H30M C306 H30O 109.5 . . ?
H30N C306 H30O 109.5 . . ?
C308 C307 N1 115.3(5) . . ?
C308 C307 H30P 108.5 . . ?
N1 C307 H30P 108.5 . . ?
C308 C307 H30Q 108.5 . . ?
N1 C307 H30Q 108.5 . . ?
H30P C307 H30Q 107.5 . . ?
C307 C308 H30R 109.5 . . ?
C307 C308 H30S 109.5 . . ?
H30R C308 H30S 109.5 . . ?
C307 C308 H30T 109.5 . . ?
H30R C308 H30T 109.5 . . ?
H30S C308 H30T 109.5 . . ?
Cl2 C401 Cl1 113.5(5) . . ?
Cl2 C401 H40A 108.9 . . ?
Cl1 C401 H40A 108.9 . . ?
Cl2 C401 H40B 108.9 . . ?
Cl1 C401 H40B 108.9 . . ?
H40A C401 H40B 107.7 . . ?
Cl4 C411 Cl3 113.6(4) . . ?
Cl4 C411 H41A 108.8 . . ?
Cl3 C411 H41A 108.8 . . ?
Cl4 C411 H41B 108.8 . . ?
Cl3 C411 H41B 108.8 . . ?
H41A C411 H41B 107.7 . . ?

_refine_diff_density_max         2.636
_refine_diff_density_min         -1.149
_refine_diff_density_rms         0.154

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_5CH2Cl2
_database_code_depnum_ccdc_archive 'CCDC 2305342'
loop_
_audit_author_name
_audit_author_address
'Stefano Zacchini'
;Universita di Bologna
Italy
;
_audit_update_record             
;
2023-11-02 deposited with the CCDC.	2024-01-18 downloaded from the CCDC.
;
# start Validation Reply Form
_vrf_PLAT971_5CH2Cl2             
;
PROBLEM:  Check Calcd Resid. Dens
RESPONSE: This alert is due to high values for 
the residual electron density. This maximum is located close
to the cluster core, in a position which is not realistic for 
any atom, and this is a series termination error, 
common with heavy atoms.
;
_vrf_PLAT972_5CH2Cl2             
;
PROBLEM:  Check Calcd Resid. Dens
RESPONSE: This alert is due to high values for 
the residual electron density. This maximum is located close
to the cluster core, in a position which is not realistic for 
any atom, and this is a series termination error, 
common with heavy atoms.
;
_vrf_PLAT342_5CH2Cl2             
;
PROBLEM: Low Bond Precision on  C-C Bonds
RESPONSE: This alert refers to some Ph groups of the PPh3
ligands, which display some minor disorder, which has 
not been possible to model. 
;
# end Validation Reply Form   
_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C84.50 H61 Au4 Cl O12 P4 Ru4'
_chemical_formula_weight         2619.81

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'C 2/c'
_space_group_name_Hall           '-C 2yc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   24.253(2)
_cell_length_b                   14.1328(12)
_cell_length_c                   50.610(4)
_cell_angle_alpha                90
_cell_angle_beta                 95.833(3)
_cell_angle_gamma                90
_cell_volume                     17258(3)
_cell_formula_units_Z            8
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    9769
_cell_measurement_theta_min      2.556
_cell_measurement_theta_max      26.425

_exptl_crystal_description       plate
_exptl_crystal_colour            orange
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    2.017
_exptl_crystal_F_000             9864
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.210
_exptl_crystal_size_mid          0.140
_exptl_crystal_size_min          0.080
_exptl_absorpt_coefficient_mu    7.615
_shelx_estimated_absorpt_T_min   0.298
_shelx_estimated_absorpt_T_max   0.581
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_correction_T_min  0.0811
_exptl_absorpt_correction_T_max  0.1660
_exptl_absorpt_process_details   
;
 Data were corrected for Lorentz polarization and absorption
 effects (empirical absorption corrections SADABS).
 R(int) = 0.1593 (selected reflections only, before parameter refinement)
 R(int) = 0.0794 (selected reflections only, after parameter refinement)
;
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'fine-focus sealed tube'
_diffrn_measurement_device_type  'PHOTON2 area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            103921
_diffrn_reflns_av_unetI/netI     0.0446
_diffrn_reflns_av_R_equivalents  0.0757
_diffrn_reflns_limit_h_min       -28
_diffrn_reflns_limit_h_max       28
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_l_min       -60
_diffrn_reflns_limit_l_max       60
_diffrn_reflns_theta_min         1.670
_diffrn_reflns_theta_max         25.049
_diffrn_reflns_theta_full        25.049
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measured_fraction_theta_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_point_group_measured_fraction_full 0.996
_reflns_number_total             15231
_reflns_number_gt                13581
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'APEX2 (Bruker AXS, 2006)'
_computing_cell_refinement       'APEX2 (Bruker AXS, 2006)'
_computing_data_reduction        'SAINT (Bruker AXS, 2004)'
_computing_structure_solution    'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    'SCHAKAL99 (Keller, 1999)'
_computing_publication_material  'XCIF (Bruker AXS, 2001)'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0342P)²+1306.0150P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         15231
_refine_ls_number_parameters     835
_refine_ls_number_restraints     708
_refine_ls_R_factor_all          0.0852
_refine_ls_R_factor_gt           0.0771
_refine_ls_wR_factor_ref         0.1689
_refine_ls_wR_factor_gt          0.1647
_refine_ls_goodness_of_fit_ref   1.140
_refine_ls_restrained_S_all      1.143
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.47967(2) 0.34823(3) 0.37392(2) 0.02297(13) Uani 1 1 d . . . . .
Au2 Au 0.57343(3) 0.36004(6) 0.34485(2) 0.0532(2) Uani 1 1 d . . . . .
Au3 Au 0.48208(4) 0.17634(4) 0.40224(2) 0.0507(2) Uani 1 1 d . . . . .
Au4 Au 0.37846(2) 0.37285(5) 0.34012(2) 0.04016(17) Uani 1 1 d . . . . .
Ru1 Ru 0.46508(9) 0.10637(12) 0.31195(3) 0.0663(5) Uani 1 1 d . . . . .
Ru2 Ru 0.53840(7) 0.17795(10) 0.35602(3) 0.0490(4) Uani 1 1 d . . . . .
Ru3 Ru 0.41166(6) 0.18666(9) 0.35479(2) 0.0399(3) Uani 1 1 d . . . . .
Ru4 Ru 0.47199(5) 0.30933(9) 0.31635(2) 0.0295(3) Uani 1 1 d . . . . .
C1 C 0.4060(14) 0.091(2) 0.2851(7) 0.112(8) Uani 1 1 d . U . . .
C2 C 0.4533(18) -0.021(3) 0.3190(8) 0.147(10) Uani 1 1 d . U . . .
C3 C 0.5178(11) 0.0843(18) 0.2880(5) 0.083(6) Uani 1 1 d . U . . .
C4 C 0.5951(11) 0.164(2) 0.3334(5) 0.094(7) Uani 1 1 d . U . . .
C5 C 0.5429(15) 0.050(2) 0.3634(6) 0.115(8) Uani 1 1 d . U . . .
C6 C 0.5861(11) 0.2034(19) 0.3867(5) 0.084(6) Uani 1 1 d . U . . .
C7 C 0.4127(11) 0.0622(13) 0.3679(4) 0.079(6) Uani 1 1 d . U . . .
C8 C 0.3502(9) 0.1606(18) 0.3295(4) 0.077(6) Uani 1 1 d . U . . .
C9 C 0.3648(9) 0.2330(15) 0.3800(4) 0.066(5) Uani 1 1 d . U . . .
C10 C 0.4113(7) 0.3059(19) 0.2900(3) 0.071(6) Uani 1 1 d . U . . .
C11 C 0.5219(7) 0.2931(14) 0.2904(3) 0.048(4) Uani 1 1 d . U . . .
C12 C 0.4796(9) 0.4426(11) 0.3156(3) 0.052(4) Uani 1 1 d . U . . .
O1 O 0.3691(9) 0.0837(18) 0.2687(4) 0.126(6) Uani 1 1 d . U . . .
O2 O 0.4672(12) -0.1059(19) 0.3265(5) 0.152(8) Uani 1 1 d . U . . .
O3 O 0.5498(8) 0.0672(13) 0.2735(3) 0.097(5) Uani 1 1 d . U . . .
O4 O 0.6308(7) 0.1535(15) 0.3205(3) 0.105(6) Uani 1 1 d . U . . .
O5 O 0.5456(11) -0.0301(15) 0.3681(4) 0.126(6) Uani 1 1 d . U . . .
O6 O 0.6209(7) 0.2110(14) 0.4043(3) 0.101(5) Uani 1 1 d . U . . .
O7 O 0.4097(8) -0.0143(10) 0.3752(3) 0.097(5) Uani 1 1 d . U . . .
O8 O 0.3103(7) 0.1434(14) 0.3168(3) 0.100(6) Uani 1 1 d . U . . .
O9 O 0.3322(6) 0.2481(11) 0.3946(3) 0.074(4) Uani 1 1 d . U . . .
O10 O 0.3763(6) 0.3016(15) 0.2737(3) 0.091(5) Uani 1 1 d . U . . .
O11 O 0.5504(5) 0.2855(10) 0.2738(2) 0.055(3) Uani 1 1 d . U . . .
O12 O 0.4819(7) 0.5210(9) 0.3116(3) 0.069(4) Uani 1 1 d . U . . .
P1 P 0.48621(17) 0.4628(3) 0.40708(7) 0.0326(8) Uani 1 1 d . U . . .
C101 C 0.4460(4) 0.4334(9) 0.43478(18) 0.046(3) Uani 1 1 d G U . . .
C102 C 0.4670(4) 0.4410(9) 0.4613(2) 0.056(3) Uani 1 1 d G U . . .
H102 H 0.5048 0.4577 0.4658 0.067 Uiso 1 1 calc R U . . .
C103 C 0.4329(5) 0.4241(9) 0.48122(16) 0.060(4) Uani 1 1 d G U . . .
H103 H 0.4472 0.4293 0.4993 0.073 Uiso 1 1 calc R U . . .
C104 C 0.3777(5) 0.3997(9) 0.4746(2) 0.060(4) Uani 1 1 d G U . . .
H104 H 0.3543 0.3881 0.4883 0.072 Uiso 1 1 calc R U . . .
C105 C 0.3566(4) 0.3921(10) 0.4481(2) 0.066(4) Uani 1 1 d G U . . .
H105 H 0.3189 0.3753 0.4436 0.079 Uiso 1 1 calc R U . . .
C106 C 0.3908(5) 0.4090(9) 0.42821(17) 0.059(3) Uani 1 1 d G U . . .
H106 H 0.3765 0.4038 0.4101 0.071 Uiso 1 1 calc R U . . .
C111 C 0.4611(5) 0.5774(6) 0.3963(2) 0.046(3) Uani 1 1 d G U . . .
C112 C 0.4327(5) 0.6360(8) 0.41231(19) 0.056(3) Uani 1 1 d G U . . .
H112 H 0.4255 0.6154 0.4295 0.068 Uiso 1 1 calc R U . . .
C113 C 0.4149(6) 0.7248(8) 0.4032(3) 0.069(4) Uani 1 1 d G U . . .
H113 H 0.3955 0.7648 0.4141 0.083 Uiso 1 1 calc R U . . .
C114 C 0.4255(7) 0.7549(7) 0.3781(3) 0.081(4) Uani 1 1 d G U . . .
H114 H 0.4133 0.8156 0.3718 0.098 Uiso 1 1 calc R U . . .
C115 C 0.4539(7) 0.6963(9) 0.3620(2) 0.084(4) Uani 1 1 d G U . . .
H115 H 0.4612 0.7169 0.3449 0.100 Uiso 1 1 calc R U . . .
C116 C 0.4717(6) 0.6075(8) 0.3712(2) 0.069(4) Uani 1 1 d G U . . .
H116 H 0.4912 0.5675 0.3602 0.083 Uiso 1 1 calc R U . . .
C121 C 0.5562(4) 0.4891(8) 0.4226(2) 0.042(3) Uani 1 1 d G U . . .
C122 C 0.5992(5) 0.4251(7) 0.4207(2) 0.062(4) Uani 1 1 d G U . . .
H122 H 0.5929 0.3689 0.4106 0.074 Uiso 1 1 calc R U . . .
C123 C 0.6515(4) 0.4436(9) 0.4336(3) 0.073(4) Uani 1 1 d G U . . .
H123 H 0.6808 0.3999 0.4323 0.088 Uiso 1 1 calc R U . . .
C124 C 0.6607(4) 0.5259(9) 0.4484(3) 0.070(4) Uani 1 1 d G U . . .
H124 H 0.6965 0.5385 0.4572 0.084 Uiso 1 1 calc R U . . .
C125 C 0.6178(5) 0.5898(7) 0.4503(3) 0.067(4) Uani 1 1 d G U . . .
H125 H 0.6241 0.6461 0.4604 0.081 Uiso 1 1 calc R U . . .
C126 C 0.5655(4) 0.5714(7) 0.4374(3) 0.058(3) Uani 1 1 d G U . . .
H126 H 0.5362 0.6151 0.4387 0.069 Uiso 1 1 calc R U . . .
P2 P 0.6473(2) 0.4610(5) 0.34288(11) 0.0669(15) Uani 1 1 d . U . . .
C201 C 0.6770(7) 0.4494(14) 0.3112(3) 0.089(4) Uani 1 1 d G U . . .
C202 C 0.7053(8) 0.5223(11) 0.3000(4) 0.106(5) Uani 1 1 d G U . . .
H202 H 0.7076 0.5829 0.3082 0.127 Uiso 1 1 calc R U . . .
C203 C 0.7303(8) 0.5066(13) 0.2769(4) 0.112(5) Uani 1 1 d G U . . .
H203 H 0.7496 0.5565 0.2692 0.134 Uiso 1 1 calc R U . . .
C204 C 0.7270(8) 0.4180(15) 0.2649(3) 0.114(5) Uani 1 1 d G U . . .
H204 H 0.7440 0.4072 0.2491 0.136 Uiso 1 1 calc R U . . .
C205 C 0.6987(8) 0.3451(11) 0.2761(4) 0.108(5) Uani 1 1 d G U . . .
H205 H 0.6964 0.2845 0.2679 0.130 Uiso 1 1 calc R U . . .
C206 C 0.6737(7) 0.3608(12) 0.2993(4) 0.096(5) Uani 1 1 d G U . . .
H206 H 0.6544 0.3109 0.3069 0.116 Uiso 1 1 calc R U . . .
C211 C 0.7071(5) 0.4313(14) 0.3665(3) 0.084(4) Uani 1 1 d G U . . .
C212 C 0.7158(7) 0.3405(12) 0.3766(4) 0.104(5) Uani 1 1 d G U . . .
H212 H 0.6906 0.2912 0.3711 0.125 Uiso 1 1 calc R U . . .
C213 C 0.7612(8) 0.3219(12) 0.3949(4) 0.113(5) Uani 1 1 d G U . . .
H213 H 0.7671 0.2598 0.4018 0.135 Uiso 1 1 calc R U . . .
C214 C 0.7980(6) 0.3941(15) 0.4031(3) 0.112(5) Uani 1 1 d G U . . .
H214 H 0.8291 0.3814 0.4155 0.134 Uiso 1 1 calc R U . . .
C215 C 0.7894(6) 0.4849(13) 0.3929(4) 0.108(5) Uani 1 1 d G U . . .
H215 H 0.8145 0.5342 0.3985 0.129 Uiso 1 1 calc R U . . .
C216 C 0.7439(7) 0.5035(11) 0.3746(3) 0.098(5) Uani 1 1 d G U . . .
H216 H 0.7380 0.5656 0.3677 0.118 Uiso 1 1 calc R U . . .
C221 C 0.6333(8) 0.5752(11) 0.3488(4) 0.093(4) Uani 1 1 d G U . . .
C222 C 0.6089(8) 0.6259(15) 0.3272(3) 0.116(5) Uani 1 1 d G U . . .
H222 H 0.6053 0.5981 0.3100 0.139 Uiso 1 1 calc R U . . .
C223 C 0.5898(9) 0.7173(15) 0.3307(4) 0.128(6) Uani 1 1 d G U . . .
H223 H 0.5731 0.7520 0.3159 0.154 Uiso 1 1 calc R U . . .
C224 C 0.5951(9) 0.7580(11) 0.3558(5) 0.127(6) Uani 1 1 d G U . . .
H224 H 0.5820 0.8204 0.3582 0.152 Uiso 1 1 calc R U . . .
C225 C 0.6195(9) 0.7072(14) 0.3775(3) 0.121(6) Uani 1 1 d G U . . .
H225 H 0.6231 0.7350 0.3946 0.145 Uiso 1 1 calc R U . . .
C226 C 0.6386(8) 0.6158(14) 0.3739(3) 0.108(5) Uani 1 1 d G U . . .
H226 H 0.6553 0.5811 0.3887 0.129 Uiso 1 1 calc R U . . .
P3 P 0.4914(3) 0.1139(3) 0.44437(9) 0.0587(13) Uani 1 1 d . U . . .
C301 C 0.5200(7) 0.1914(9) 0.4714(2) 0.073(3) Uani 1 1 d G U . . .
C302 C 0.4980(6) 0.1939(9) 0.4957(3) 0.079(4) Uani 1 1 d G U . . .
H302 H 0.4667 0.1563 0.4985 0.095 Uiso 1 1 calc R U . . .
C303 C 0.5219(7) 0.2515(10) 0.51604(19) 0.087(5) Uani 1 1 d G U . . .
H303 H 0.5069 0.2533 0.5326 0.104 Uiso 1 1 calc R U . . .
C304 C 0.5678(7) 0.3066(10) 0.5120(2) 0.097(5) Uani 1 1 d G U . . .
H304 H 0.5842 0.3460 0.5259 0.116 Uiso 1 1 calc R U . . .
C305 C 0.5898(6) 0.3041(11) 0.4877(3) 0.097(5) Uani 1 1 d G U . . .
H305 H 0.6212 0.3417 0.4850 0.116 Uiso 1 1 calc R U . . .
C306 C 0.5659(7) 0.2465(11) 0.4674(2) 0.088(4) Uani 1 1 d G U . . .
H306 H 0.5810 0.2448 0.4508 0.106 Uiso 1 1 calc R U . . .
C311 C 0.5357(6) 0.0115(7) 0.4452(2) 0.062(3) Uani 1 1 d G U . . .
C312 C 0.5225(5) -0.0613(9) 0.4272(2) 0.066(4) Uani 1 1 d G U . . .
H312 H 0.4896 -0.0581 0.4153 0.079 Uiso 1 1 calc R U . . .
C313 C 0.5576(6) -0.1389(7) 0.4265(2) 0.073(4) Uani 1 1 d G U . . .
H313 H 0.5486 -0.1887 0.4142 0.088 Uiso 1 1 calc R U . . .
C314 C 0.6058(6) -0.1437(8) 0.4438(3) 0.077(4) Uani 1 1 d G U . . .
H314 H 0.6298 -0.1967 0.4433 0.093 Uiso 1 1 calc R U . . .
C315 C 0.6190(5) -0.0708(10) 0.4618(3) 0.081(4) Uani 1 1 d G U . . .
H315 H 0.6520 -0.0741 0.4736 0.097 Uiso 1 1 calc R U . . .
C316 C 0.5840(6) 0.0067(8) 0.4625(2) 0.073(4) Uani 1 1 d G U . . .
H316 H 0.5930 0.0565 0.4748 0.088 Uiso 1 1 calc R U . . .
C321 C 0.4268(5) 0.0692(10) 0.4531(3) 0.068(3) Uani 1 1 d G U . . .
C322 C 0.3814(7) 0.1296(8) 0.4502(3) 0.083(4) Uani 1 1 d G U . . .
H322 H 0.3853 0.1920 0.4436 0.100 Uiso 1 1 calc R U . . .
C323 C 0.3302(6) 0.0987(11) 0.4569(3) 0.094(5) Uani 1 1 d G U . . .
H323 H 0.2991 0.1400 0.4549 0.112 Uiso 1 1 calc R U . . .
C324 C 0.3244(5) 0.0075(12) 0.4665(3) 0.091(5) Uani 1 1 d G U . . .
H324 H 0.2894 -0.0136 0.4710 0.109 Uiso 1 1 calc R U . . .
C325 C 0.3699(7) -0.0529(8) 0.4693(3) 0.085(4) Uani 1 1 d G U . . .
H325 H 0.3659 -0.1153 0.4759 0.102 Uiso 1 1 calc R U . . .
C326 C 0.4211(6) -0.0221(9) 0.4627(3) 0.075(4) Uani 1 1 d G U . . .
H326 H 0.4521 -0.0634 0.4646 0.089 Uiso 1 1 calc R U . . .
P4 P 0.3030(2) 0.4719(5) 0.33421(11) 0.0771(17) Uani 1 1 d . U . . .
C401 C 0.2703(7) 0.4959(15) 0.3641(3) 0.091(4) Uani 1 1 d G U . . .
C402 C 0.3021(5) 0.5370(14) 0.3855(3) 0.102(5) Uani 1 1 d G U . . .
H402 H 0.3395 0.5539 0.3839 0.122 Uiso 1 1 calc R U . . .
C403 C 0.2791(7) 0.5534(15) 0.4091(3) 0.110(5) Uani 1 1 d G U . . .
H403 H 0.3008 0.5815 0.4237 0.131 Uiso 1 1 calc R U . . .
C404 C 0.2243(7) 0.5287(16) 0.4114(3) 0.114(5) Uani 1 1 d G U . . .
H404 H 0.2086 0.5400 0.4275 0.136 Uiso 1 1 calc R U . . .
C405 C 0.1925(6) 0.4876(16) 0.3900(4) 0.120(5) Uani 1 1 d G U . . .
H405 H 0.1551 0.4707 0.3915 0.144 Uiso 1 1 calc R U . . .
C406 C 0.2155(6) 0.4712(15) 0.3664(3) 0.114(5) Uani 1 1 d G U . . .
H406 H 0.1938 0.4431 0.3518 0.137 Uiso 1 1 calc R U . . .
C411 C 0.2488(6) 0.4208(13) 0.3090(3) 0.093(4) Uani 1 1 d G U . . .
C412 C 0.2046(8) 0.4775(11) 0.2991(4) 0.107(5) Uani 1 1 d G U . . .
H412 H 0.2030 0.5417 0.3045 0.129 Uiso 1 1 calc R U . . .
C413 C 0.1627(6) 0.4402(14) 0.2814(4) 0.109(5) Uani 1 1 d G U . . .
H413 H 0.1325 0.4789 0.2746 0.131 Uiso 1 1 calc R U . . .
C414 C 0.1651(7) 0.3462(14) 0.2734(4) 0.115(5) Uani 1 1 d G U . . .
H414 H 0.1364 0.3207 0.2613 0.138 Uiso 1 1 calc R U . . .
C415 C 0.2093(8) 0.2895(11) 0.2833(4) 0.114(5) Uani 1 1 d G U . . .
H415 H 0.2109 0.2253 0.2779 0.136 Uiso 1 1 calc R U . . .
C416 C 0.2512(6) 0.3268(13) 0.3010(4) 0.104(5) Uani 1 1 d G U . . .
H416 H 0.2814 0.2881 0.3078 0.125 Uiso 1 1 calc R U . . .
C421 C 0.3219(8) 0.5932(11) 0.3219(4) 0.094(4) Uani 1 1 d G U . . .
C422 C 0.2997(7) 0.6758(15) 0.3314(3) 0.109(5) Uani 1 1 d G U . . .
H422 H 0.2762 0.6727 0.3452 0.131 Uiso 1 1 calc R U . . .
C423 C 0.3119(8) 0.7627(12) 0.3205(4) 0.118(5) Uani 1 1 d G U . . .
H423 H 0.2968 0.8191 0.3270 0.142 Uiso 1 1 calc R U . . .
C424 C 0.3463(9) 0.7672(12) 0.3002(4) 0.120(5) Uani 1 1 d G U . . .
H424 H 0.3547 0.8266 0.2928 0.144 Uiso 1 1 calc R U . . .
C425 C 0.3685(7) 0.6846(15) 0.2907(3) 0.115(5) Uani 1 1 d G U . . .
H425 H 0.3920 0.6877 0.2768 0.138 Uiso 1 1 calc R U . . .
C426 C 0.3562(8) 0.5977(12) 0.3015(4) 0.107(5) Uani 1 1 d G U . . .
H426 H 0.3714 0.5413 0.2951 0.129 Uiso 1 1 calc R U . . .
C501 C 0.5000 0.585(3) 0.2500 0.093(11) Uiso 1 2 d S . P . .
H50A H 0.4971 0.6254 0.2657 0.112 Uiso 0.5 1 calc R U P . .
H50B H 0.5029 0.6254 0.2343 0.112 Uiso 0.5 1 calc R U P . .
Cl1 Cl 0.4406(3) 0.5066(6) 0.24466(16) 0.108(2) Uiso 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 P1 2.325(4) . ?
Au1 Au3 2.8180(8) . ?
Au1 Au2 2.8364(8) . ?
Au1 Au4 2.8671(8) . ?
Au1 Ru3 2.9237(13) . ?
Au1 Ru4 2.9523(12) . ?
Au1 Ru2 2.9838(14) . ?
Au2 P2 2.301(5) . ?
Au2 Ru2 2.7861(18) . ?
Au2 Ru4 2.8151(13) . ?
Au3 P3 2.297(4) . ?
Au3 Ru3 2.8057(15) . ?
Au3 Ru2 2.8262(16) . ?
Au4 P4 2.300(5) . ?
Au4 Ru4 2.8201(13) . ?
Au4 Ru3 2.8288(16) . ?
Ru1 C2 1.87(4) . ?
Ru1 C3 1.88(2) . ?
Ru1 C1 1.89(3) . ?
Ru1 Ru3 2.870(2) . ?
Ru1 Ru4 2.881(2) . ?
Ru1 Ru2 2.890(2) . ?
Ru2 C5 1.84(3) . ?
Ru2 C6 1.88(3) . ?
Ru2 C4 1.89(2) . ?
Ru2 Ru4 3.0685(18) . ?
Ru2 Ru3 3.071(2) . ?
Ru3 C7 1.88(2) . ?
Ru3 C8 1.90(2) . ?
Ru3 C9 1.91(2) . ?
Ru3 Ru4 3.0838(16) . ?
Ru4 C10 1.884(17) . ?
Ru4 C11 1.888(16) . ?
Ru4 C12 1.893(16) . ?
C1 O1 1.16(3) . ?
C2 O2 1.29(4) . ?
C3 O3 1.15(3) . ?
C4 O4 1.14(3) . ?
C5 O5 1.16(3) . ?
C6 O6 1.17(3) . ?
C7 O7 1.15(2) . ?
C8 O8 1.13(2) . ?
C9 O9 1.16(2) . ?
C10 O10 1.12(2) . ?
C11 O11 1.147(18) . ?
C12 O12 1.129(19) . ?
P1 C111 1.796(8) . ?
P1 C101 1.835(8) . ?
P1 C121 1.836(10) . ?
C101 C102 1.3900 . ?
C101 C106 1.3900 . ?
C102 C103 1.3900 . ?
C102 H102 0.9500 . ?
C103 C104 1.3900 . ?
C103 H103 0.9500 . ?
C104 C105 1.3900 . ?
C104 H104 0.9500 . ?
C105 C106 1.3900 . ?
C105 H105 0.9500 . ?
C106 H106 0.9500 . ?
C111 C112 1.3900 . ?
C111 C116 1.3900 . ?
C112 C113 1.3900 . ?
C112 H112 0.9500 . ?
C113 C114 1.3900 . ?
C113 H113 0.9500 . ?
C114 C115 1.3900 . ?
C114 H114 0.9500 . ?
C115 C116 1.3900 . ?
C115 H115 0.9500 . ?
C116 H116 0.9500 . ?
C121 C122 1.3900 . ?
C121 C126 1.3900 . ?
C122 C123 1.3900 . ?
C122 H122 0.9500 . ?
C123 C124 1.3900 . ?
C123 H123 0.9500 . ?
C124 C125 1.3900 . ?
C124 H124 0.9500 . ?
C125 C126 1.3900 . ?
C125 H125 0.9500 . ?
C126 H126 0.9500 . ?
P2 C221 1.681(15) . ?
P2 C201 1.830(13) . ?
P2 C211 1.833(14) . ?
C201 C202 1.3900 . ?
C201 C206 1.3900 . ?
C202 C203 1.3900 . ?
C202 H202 0.9500 . ?
C203 C204 1.3900 . ?
C203 H203 0.9500 . ?
C204 C205 1.3900 . ?
C204 H204 0.9500 . ?
C205 C206 1.3900 . ?
C205 H205 0.9500 . ?
C206 H206 0.9500 . ?
C211 C212 1.3900 . ?
C211 C216 1.3900 . ?
C212 C213 1.3900 . ?
C212 H212 0.9500 . ?
C213 C214 1.3900 . ?
C213 H213 0.9500 . ?
C214 C215 1.3900 . ?
C214 H214 0.9500 . ?
C215 C216 1.3900 . ?
C215 H215 0.9500 . ?
C216 H216 0.9500 . ?
C221 C222 1.3900 . ?
C221 C226 1.3900 . ?
C222 C223 1.3900 . ?
C222 H222 0.9500 . ?
C223 C224 1.3900 . ?
C223 H223 0.9500 . ?
C224 C225 1.3900 . ?
C224 H224 0.9500 . ?
C225 C226 1.3900 . ?
C225 H225 0.9500 . ?
C226 H226 0.9500 . ?
P3 C321 1.785(13) . ?
P3 C311 1.801(10) . ?
P3 C301 1.835(11) . ?
C301 C302 1.3900 . ?
C301 C306 1.3900 . ?
C302 C303 1.3900 . ?
C302 H302 0.9500 . ?
C303 C304 1.3900 . ?
C303 H303 0.9500 . ?
C304 C305 1.3900 . ?
C304 H304 0.9500 . ?
C305 C306 1.3900 . ?
C305 H305 0.9500 . ?
C306 H306 0.9500 . ?
C311 C312 1.3900 . ?
C311 C316 1.3900 . ?
C312 C313 1.3900 . ?
C312 H312 0.9500 . ?
C313 C314 1.3900 . ?
C313 H313 0.9500 . ?
C314 C315 1.3900 . ?
C314 H314 0.9500 . ?
C315 C316 1.3900 . ?
C315 H315 0.9500 . ?
C316 H316 0.9500 . ?
C321 C322 1.3900 . ?
C321 C326 1.3900 . ?
C322 C323 1.3900 . ?
C322 H322 0.9500 . ?
C323 C324 1.3900 . ?
C323 H323 0.9500 . ?
C324 C325 1.3900 . ?
C324 H324 0.9500 . ?
C325 C326 1.3900 . ?
C325 H325 0.9500 . ?
C326 H326 0.9500 . ?
P4 C401 1.809(12) . ?
P4 C411 1.881(14) . ?
P4 C421 1.897(16) . ?
C401 C402 1.3900 . ?
C401 C406 1.3900 . ?
C402 C403 1.3900 . ?
C402 H402 0.9500 . ?
C403 C404 1.3900 . ?
C403 H403 0.9500 . ?
C404 C405 1.3900 . ?
C404 H404 0.9500 . ?
C405 C406 1.3900 . ?
C405 H405 0.9500 . ?
C406 H406 0.9500 . ?
C411 C412 1.3900 . ?
C411 C416 1.3900 . ?
C412 C413 1.3900 . ?
C412 H412 0.9500 . ?
C413 C414 1.3900 . ?
C413 H413 0.9500 . ?
C414 C415 1.3900 . ?
C414 H414 0.9500 . ?
C415 C416 1.3900 . ?
C415 H415 0.9500 . ?
C416 H416 0.9500 . ?
C421 C422 1.3900 . ?
C421 C426 1.3900 . ?
C422 C423 1.3900 . ?
C422 H422 0.9500 . ?
C423 C424 1.3900 . ?
C423 H423 0.9500 . ?
C424 C425 1.3900 . ?
C424 H424 0.9500 . ?
C425 C426 1.3900 . ?
C425 H425 0.9500 . ?
C426 H426 0.9500 . ?
C501 Cl1 1.81(2) . ?
C501 Cl1 1.81(2) 2_655 ?
C501 H50A 0.9900 . ?
C501 H50B 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Au1 Au3 103.70(10) . . ?
P1 Au1 Au2 109.51(10) . . ?
Au3 Au1 Au2 109.77(3) . . ?
P1 Au1 Au4 109.73(11) . . ?
Au3 Au1 Au4 112.35(3) . . ?
Au2 Au1 Au4 111.48(3) . . ?
P1 Au1 Ru3 141.04(10) . . ?
Au3 Au1 Ru3 58.47(3) . . ?
Au2 Au1 Ru3 109.22(3) . . ?
Au4 Au1 Ru3 58.47(3) . . ?
P1 Au1 Ru4 146.57(10) . . ?
Au3 Au1 Ru4 109.72(3) . . ?
Au2 Au1 Ru4 58.15(3) . . ?
Au4 Au1 Ru4 57.95(3) . . ?
Ru3 Au1 Ru4 63.31(3) . . ?
P1 Au1 Ru2 141.35(11) . . ?
Au3 Au1 Ru2 58.22(3) . . ?
Au2 Au1 Ru2 57.13(4) . . ?
Au4 Au1 Ru2 108.84(4) . . ?
Ru3 Au1 Ru2 62.63(5) . . ?
Ru4 Au1 Ru2 62.25(4) . . ?
P2 Au2 Ru2 146.80(18) . . ?
P2 Au2 Ru4 141.23(17) . . ?
Ru2 Au2 Ru4 66.43(4) . . ?
P2 Au2 Au1 136.70(13) . . ?
Ru2 Au2 Au1 64.10(3) . . ?
Ru4 Au2 Au1 62.98(3) . . ?
P3 Au3 Ru3 143.92(17) . . ?
P3 Au3 Au1 142.94(12) . . ?
Ru3 Au3 Au1 62.65(3) . . ?
P3 Au3 Ru2 139.56(15) . . ?
Ru3 Au3 Ru2 66.08(4) . . ?
Au1 Au3 Ru2 63.83(3) . . ?
P4 Au4 Ru4 143.36(14) . . ?
P4 Au4 Ru3 143.3(2) . . ?
Ru4 Au4 Ru3 66.17(4) . . ?
P4 Au4 Au1 140.65(18) . . ?
Ru4 Au4 Au1 62.54(3) . . ?
Ru3 Au4 Au1 61.76(3) . . ?
C2 Ru1 C3 95.2(15) . . ?
C2 Ru1 C1 84.6(17) . . ?
C3 Ru1 C1 91.8(12) . . ?
C2 Ru1 Ru3 98.5(12) . . ?
C3 Ru1 Ru3 160.7(8) . . ?
C1 Ru1 Ru3 102.9(10) . . ?
C2 Ru1 Ru4 163.0(12) . . ?
C3 Ru1 Ru4 100.2(8) . . ?
C1 Ru1 Ru4 101.8(11) . . ?
Ru3 Ru1 Ru4 64.86(5) . . ?
C2 Ru1 Ru2 106.6(13) . . ?
C3 Ru1 Ru2 98.7(8) . . ?
C1 Ru1 Ru2 163.7(11) . . ?
Ru3 Ru1 Ru2 64.42(5) . . ?
Ru4 Ru1 Ru2 64.24(5) . . ?
C5 Ru2 C6 90.0(13) . . ?
C5 Ru2 C4 89.4(13) . . ?
C6 Ru2 C4 95.5(11) . . ?
C5 Ru2 Au2 158.8(11) . . ?
C6 Ru2 Au2 79.4(9) . . ?
C4 Ru2 Au2 73.6(9) . . ?
C5 Ru2 Au3 81.3(10) . . ?
C6 Ru2 Au3 68.0(8) . . ?
C4 Ru2 Au3 160.9(7) . . ?
Au2 Ru2 Au3 111.01(5) . . ?
C5 Ru2 Ru1 80.4(11) . . ?
C6 Ru2 Ru1 170.4(8) . . ?
C4 Ru2 Ru1 85.6(9) . . ?
Au2 Ru2 Ru1 110.06(6) . . ?
Au3 Ru2 Ru1 108.94(7) . . ?
C5 Ru2 Au1 138.4(10) . . ?
C6 Ru2 Au1 82.4(7) . . ?
C4 Ru2 Au1 131.9(9) . . ?
Au2 Ru2 Au1 58.77(3) . . ?
Au3 Ru2 Au1 57.95(3) . . ?
Ru1 Ru2 Au1 103.96(6) . . ?
C5 Ru2 Ru4 137.8(11) . . ?
C6 Ru2 Ru4 131.7(8) . . ?
C4 Ru2 Ru4 91.8(7) . . ?
Au2 Ru2 Ru4 57.24(4) . . ?
Au3 Ru2 Ru4 106.30(5) . . ?
Ru1 Ru2 Ru4 57.72(5) . . ?
Au1 Ru2 Ru4 58.37(3) . . ?
C5 Ru2 Ru3 94.7(11) . . ?
C6 Ru2 Ru3 122.8(8) . . ?
C4 Ru2 Ru3 141.4(8) . . ?
Au2 Ru2 Ru3 106.51(5) . . ?
Au3 Ru2 Ru3 56.64(4) . . ?
Ru1 Ru2 Ru3 57.47(5) . . ?
Au1 Ru2 Ru3 57.73(4) . . ?
Ru4 Ru2 Ru3 60.31(4) . . ?
C7 Ru3 C8 92.1(11) . . ?
C7 Ru3 C9 94.2(9) . . ?
C8 Ru3 C9 92.2(9) . . ?
C7 Ru3 Au3 70.4(7) . . ?
C8 Ru3 Au3 159.1(7) . . ?
C9 Ru3 Au3 78.3(7) . . ?
C7 Ru3 Au4 163.0(8) . . ?
C8 Ru3 Au4 79.7(8) . . ?
C9 Ru3 Au4 71.5(6) . . ?
Au3 Ru3 Au4 113.91(5) . . ?
C7 Ru3 Ru1 84.6(7) . . ?
C8 Ru3 Ru1 78.3(7) . . ?
C9 Ru3 Ru1 170.3(7) . . ?
Au3 Ru3 Ru1 110.11(7) . . ?
Au4 Ru3 Ru1 107.93(6) . . ?
C7 Ru3 Au1 128.9(8) . . ?
C8 Ru3 Au1 138.8(8) . . ?
C9 Ru3 Au1 82.2(6) . . ?
Au3 Ru3 Au1 58.88(3) . . ?
Au4 Ru3 Au1 59.76(3) . . ?
Ru1 Ru3 Au1 106.03(5) . . ?
C7 Ru3 Ru2 88.8(8) . . ?
C8 Ru3 Ru2 136.1(6) . . ?
C9 Ru3 Ru2 131.5(7) . . ?
Au3 Ru3 Ru2 57.28(4) . . ?
Au4 Ru3 Ru2 107.48(5) . . ?
Ru1 Ru3 Ru2 58.11(5) . . ?
Au1 Ru3 Ru2 59.65(4) . . ?
C7 Ru3 Ru4 139.4(7) . . ?
C8 Ru3 Ru4 94.3(6) . . ?
C9 Ru3 Ru4 125.6(6) . . ?
Au3 Ru3 Ru4 106.41(5) . . ?
Au4 Ru3 Ru4 56.78(3) . . ?
Ru1 Ru3 Ru4 57.74(5) . . ?
Au1 Ru3 Ru4 58.80(3) . . ?
Ru2 Ru3 Ru4 59.81(4) . . ?
C10 Ru4 C11 90.9(8) . . ?
C10 Ru4 C12 94.7(10) . . ?
C11 Ru4 C12 92.1(8) . . ?
C10 Ru4 Au2 161.6(7) . . ?
C11 Ru4 Au2 78.4(5) . . ?
C12 Ru4 Au2 71.0(6) . . ?
C10 Ru4 Au4 72.8(6) . . ?
C11 Ru4 Au4 159.3(6) . . ?
C12 Ru4 Au4 77.0(5) . . ?
Au2 Ru4 Au4 113.55(4) . . ?
C10 Ru4 Ru1 83.4(8) . . ?
C11 Ru4 Ru1 82.1(6) . . ?
C12 Ru4 Ru1 173.8(5) . . ?
Au2 Ru4 Ru1 109.52(6) . . ?
Au4 Ru4 Ru1 107.87(5) . . ?
C10 Ru4 Au1 132.0(6) . . ?
C11 Ru4 Au1 136.7(5) . . ?
C12 Ru4 Au1 80.6(5) . . ?
Au2 Ru4 Au1 58.86(3) . . ?
Au4 Ru4 Au1 59.51(3) . . ?
Ru1 Ru4 Au1 105.01(5) . . ?
C10 Ru4 Ru2 140.2(8) . . ?
C11 Ru4 Ru2 92.9(6) . . ?
C12 Ru4 Ru2 124.7(6) . . ?
Au2 Ru4 Ru2 56.33(4) . . ?
Au4 Ru4 Ru2 107.76(4) . . ?
Ru1 Ru4 Ru2 58.03(5) . . ?
Au1 Ru4 Ru2 59.38(3) . . ?
C10 Ru4 Ru3 92.6(6) . . ?
C11 Ru4 Ru3 138.5(6) . . ?
C12 Ru4 Ru3 128.6(5) . . ?
Au2 Ru4 Ru3 105.43(5) . . ?
Au4 Ru4 Ru3 57.05(4) . . ?
Ru1 Ru4 Ru3 57.40(4) . . ?
Au1 Ru4 Ru3 57.89(3) . . ?
Ru2 Ru4 Ru3 59.88(5) . . ?
O1 C1 Ru1 178(3) . . ?
O2 C2 Ru1 156(4) . . ?
O3 C3 Ru1 177(2) . . ?
O4 C4 Ru2 177(2) . . ?
O5 C5 Ru2 180(4) . . ?
O6 C6 Ru2 171(2) . . ?
O7 C7 Ru3 175(3) . . ?
O8 C8 Ru3 172.3(18) . . ?
O9 C9 Ru3 169.5(18) . . ?
O10 C10 Ru4 177(2) . . ?
O11 C11 Ru4 176.7(17) . . ?
O12 C12 Ru4 170.6(17) . . ?
C111 P1 C101 104.3(6) . . ?
C111 P1 C121 102.6(6) . . ?
C101 P1 C121 105.0(6) . . ?
C111 P1 Au1 114.4(4) . . ?
C101 P1 Au1 113.0(4) . . ?
C121 P1 Au1 116.2(4) . . ?
C102 C101 C106 120.0 . . ?
C102 C101 P1 123.3(6) . . ?
C106 C101 P1 116.5(6) . . ?
C103 C102 C101 120.0 . . ?
C103 C102 H102 120.0 . . ?
C101 C102 H102 120.0 . . ?
C104 C103 C102 120.0 . . ?
C104 C103 H103 120.0 . . ?
C102 C103 H103 120.0 . . ?
C103 C104 C105 120.0 . . ?
C103 C104 H104 120.0 . . ?
C105 C104 H104 120.0 . . ?
C106 C105 C104 120.0 . . ?
C106 C105 H105 120.0 . . ?
C104 C105 H105 120.0 . . ?
C105 C106 C101 120.0 . . ?
C105 C106 H106 120.0 . . ?
C101 C106 H106 120.0 . . ?
C112 C111 C116 120.0 . . ?
C112 C111 P1 122.2(6) . . ?
C116 C111 P1 117.8(6) . . ?
C113 C112 C111 120.0 . . ?
C113 C112 H112 120.0 . . ?
C111 C112 H112 120.0 . . ?
C112 C113 C114 120.0 . . ?
C112 C113 H113 120.0 . . ?
C114 C113 H113 120.0 . . ?
C115 C114 C113 120.0 . . ?
C115 C114 H114 120.0 . . ?
C113 C114 H114 120.0 . . ?
C114 C115 C116 120.0 . . ?
C114 C115 H115 120.0 . . ?
C116 C115 H115 120.0 . . ?
C115 C116 C111 120.0 . . ?
C115 C116 H116 120.0 . . ?
C111 C116 H116 120.0 . . ?
C122 C121 C126 120.0 . . ?
C122 C121 P1 120.4(6) . . ?
C126 C121 P1 119.5(6) . . ?
C121 C122 C123 120.0 . . ?
C121 C122 H122 120.0 . . ?
C123 C122 H122 120.0 . . ?
C124 C123 C122 120.0 . . ?
C124 C123 H123 120.0 . . ?
C122 C123 H123 120.0 . . ?
C125 C124 C123 120.0 . . ?
C125 C124 H124 120.0 . . ?
C123 C124 H124 120.0 . . ?
C124 C125 C126 120.0 . . ?
C124 C125 H125 120.0 . . ?
C126 C125 H125 120.0 . . ?
C125 C126 C121 120.0 . . ?
C125 C126 H126 120.0 . . ?
C121 C126 H126 120.0 . . ?
C221 P2 C201 110.3(10) . . ?
C221 P2 C211 105.3(9) . . ?
C201 P2 C211 101.2(8) . . ?
C221 P2 Au2 114.6(7) . . ?
C201 P2 Au2 111.1(6) . . ?
C211 P2 Au2 113.5(7) . . ?
C202 C201 C206 120.0 . . ?
C202 C201 P2 123.0(11) . . ?
C206 C201 P2 116.8(11) . . ?
C201 C202 C203 120.0 . . ?
C201 C202 H202 120.0 . . ?
C203 C202 H202 120.0 . . ?
C204 C203 C202 120.0 . . ?
C204 C203 H203 120.0 . . ?
C202 C203 H203 120.0 . . ?
C203 C204 C205 120.0 . . ?
C203 C204 H204 120.0 . . ?
C205 C204 H204 120.0 . . ?
C206 C205 C204 120.0 . . ?
C206 C205 H205 120.0 . . ?
C204 C205 H205 120.0 . . ?
C205 C206 C201 120.0 . . ?
C205 C206 H206 120.0 . . ?
C201 C206 H206 120.0 . . ?
C212 C211 C216 120.0 . . ?
C212 C211 P2 122.1(11) . . ?
C216 C211 P2 117.9(11) . . ?
C213 C212 C211 120.0 . . ?
C213 C212 H212 120.0 . . ?
C211 C212 H212 120.0 . . ?
C212 C213 C214 120.0 . . ?
C212 C213 H213 120.0 . . ?
C214 C213 H213 120.0 . . ?
C215 C214 C213 120.0 . . ?
C215 C214 H214 120.0 . . ?
C213 C214 H214 120.0 . . ?
C216 C215 C214 120.0 . . ?
C216 C215 H215 120.0 . . ?
C214 C215 H215 120.0 . . ?
C215 C216 C211 120.0 . . ?
C215 C216 H216 120.0 . . ?
C211 C216 H216 120.0 . . ?
C222 C221 C226 120.0 . . ?
C222 C221 P2 115.6(13) . . ?
C226 C221 P2 123.9(13) . . ?
C223 C222 C221 120.0 . . ?
C223 C222 H222 120.0 . . ?
C221 C222 H222 120.0 . . ?
C224 C223 C222 120.0 . . ?
C224 C223 H223 120.0 . . ?
C222 C223 H223 120.0 . . ?
C225 C224 C223 120.0 . . ?
C225 C224 H224 120.0 . . ?
C223 C224 H224 120.0 . . ?
C226 C225 C224 120.0 . . ?
C226 C225 H225 120.0 . . ?
C224 C225 H225 120.0 . . ?
C225 C226 C221 120.0 . . ?
C225 C226 H226 120.0 . . ?
C221 C226 H226 120.0 . . ?
C321 P3 C311 104.3(7) . . ?
C321 P3 C301 107.6(7) . . ?
C311 P3 C301 106.4(7) . . ?
C321 P3 Au3 111.0(5) . . ?
C311 P3 Au3 109.4(5) . . ?
C301 P3 Au3 117.3(5) . . ?
C302 C301 C306 120.0 . . ?
C302 C301 P3 121.7(8) . . ?
C306 C301 P3 118.3(8) . . ?
C303 C302 C301 120.0 . . ?
C303 C302 H302 120.0 . . ?
C301 C302 H302 120.0 . . ?
C304 C303 C302 120.0 . . ?
C304 C303 H303 120.0 . . ?
C302 C303 H303 120.0 . . ?
C305 C304 C303 120.0 . . ?
C305 C304 H304 120.0 . . ?
C303 C304 H304 120.0 . . ?
C306 C305 C304 120.0 . . ?
C306 C305 H305 120.0 . . ?
C304 C305 H305 120.0 . . ?
C305 C306 C301 120.0 . . ?
C305 C306 H306 120.0 . . ?
C301 C306 H306 120.0 . . ?
C312 C311 C316 120.0 . . ?
C312 C311 P3 118.9(8) . . ?
C316 C311 P3 121.0(8) . . ?
C311 C312 C313 120.0 . . ?
C311 C312 H312 120.0 . . ?
C313 C312 H312 120.0 . . ?
C312 C313 C314 120.0 . . ?
C312 C313 H313 120.0 . . ?
C314 C313 H313 120.0 . . ?
C315 C314 C313 120.0 . . ?
C315 C314 H314 120.0 . . ?
C313 C314 H314 120.0 . . ?
C316 C315 C314 120.0 . . ?
C316 C315 H315 120.0 . . ?
C314 C315 H315 120.0 . . ?
C315 C316 C311 120.0 . . ?
C315 C316 H316 120.0 . . ?
C311 C316 H316 120.0 . . ?
C322 C321 C326 120.0 . . ?
C322 C321 P3 117.5(8) . . ?
C326 C321 P3 122.5(8) . . ?
C321 C322 C323 120.0 . . ?
C321 C322 H322 120.0 . . ?
C323 C322 H322 120.0 . . ?
C324 C323 C322 120.0 . . ?
C324 C323 H323 120.0 . . ?
C322 C323 H323 120.0 . . ?
C323 C324 C325 120.0 . . ?
C323 C324 H324 120.0 . . ?
C325 C324 H324 120.0 . . ?
C326 C325 C324 120.0 . . ?
C326 C325 H325 120.0 . . ?
C324 C325 H325 120.0 . . ?
C325 C326 C321 120.0 . . ?
C325 C326 H326 120.0 . . ?
C321 C326 H326 120.0 . . ?
C401 P4 C411 107.7(9) . . ?
C401 P4 C421 104.3(10) . . ?
C411 P4 C421 107.4(9) . . ?
C401 P4 Au4 114.6(6) . . ?
C411 P4 Au4 110.2(6) . . ?
C421 P4 Au4 112.2(7) . . ?
C402 C401 C406 120.0 . . ?
C402 C401 P4 118.2(10) . . ?
C406 C401 P4 121.7(10) . . ?
C403 C402 C401 120.0 . . ?
C403 C402 H402 120.0 . . ?
C401 C402 H402 120.0 . . ?
C402 C403 C404 120.0 . . ?
C402 C403 H403 120.0 . . ?
C404 C403 H403 120.0 . . ?
C403 C404 C405 120.0 . . ?
C403 C404 H404 120.0 . . ?
C405 C404 H404 120.0 . . ?
C406 C405 C404 120.0 . . ?
C406 C405 H405 120.0 . . ?
C404 C405 H405 120.0 . . ?
C405 C406 C401 120.0 . . ?
C405 C406 H406 120.0 . . ?
C401 C406 H406 120.0 . . ?
C412 C411 C416 120.0 . . ?
C412 C411 P4 118.8(10) . . ?
C416 C411 P4 121.1(10) . . ?
C413 C412 C411 120.0 . . ?
C413 C412 H412 120.0 . . ?
C411 C412 H412 120.0 . . ?
C412 C413 C414 120.0 . . ?
C412 C413 H413 120.0 . . ?
C414 C413 H413 120.0 . . ?
C415 C414 C413 120.0 . . ?
C415 C414 H414 120.0 . . ?
C413 C414 H414 120.0 . . ?
C414 C415 C416 120.0 . . ?
C414 C415 H415 120.0 . . ?
C416 C415 H415 120.0 . . ?
C415 C416 C411 120.0 . . ?
C415 C416 H416 120.0 . . ?
C411 C416 H416 120.0 . . ?
C422 C421 C426 120.0 . . ?
C422 C421 P4 122.0(11) . . ?
C426 C421 P4 117.9(11) . . ?
C423 C422 C421 120.0 . . ?
C423 C422 H422 120.0 . . ?
C421 C422 H422 120.0 . . ?
C422 C423 C424 120.0 . . ?
C422 C423 H423 120.0 . . ?
C424 C423 H423 120.0 . . ?
C425 C424 C423 120.0 . . ?
C425 C424 H424 120.0 . . ?
C423 C424 H424 120.0 . . ?
C426 C425 C424 120.0 . . ?
C426 C425 H425 120.0 . . ?
C424 C425 H425 120.0 . . ?
C425 C426 C421 120.0 . . ?
C425 C426 H426 120.0 . . ?
C421 C426 H426 120.0 . . ?
Cl1 C501 Cl1 105(2) . 2_655 ?
Cl1 C501 H50A 110.7 . . ?
Cl1 C501 H50A 110.7 2_655 . ?
Cl1 C501 H50B 110.7 . . ?
Cl1 C501 H50B 110.7 2_655 . ?
H50A C501 H50B 108.8 . . ?

_refine_diff_density_max         3.530
_refine_diff_density_min         -5.878
_refine_diff_density_rms         0.254


####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_4CH2Cl2
_database_code_depnum_ccdc_archive 'CCDC 2305340'
loop_
_audit_author_name
_audit_author_address
'Stefano Zacchini'
;Universita di Bologna
Italy
;
_audit_update_record             
;
2023-11-02 deposited with the CCDC.	2024-01-18 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C68 H50 Au3 Cl4 O12 P3 Ru4'
_chemical_formula_weight         2288.97

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/n'
_space_group_name_Hall           '-P 2yn'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   13.8772(12)
_cell_length_b                   21.705(2)
_cell_length_c                   23.920(2)
_cell_angle_alpha                90
_cell_angle_beta                 96.818(3)
_cell_angle_gamma                90
_cell_volume                     7153.7(11)
_cell_formula_units_Z            4
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    9005
_cell_measurement_theta_min      2.389
_cell_measurement_theta_max      31.1035

_exptl_crystal_description       prism
_exptl_crystal_colour            dark-orange
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    2.125
_exptl_crystal_F_000             4320
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.220
_exptl_crystal_size_mid          0.180
_exptl_crystal_size_min          0.140
_exptl_absorpt_coefficient_mu    7.225
_shelx_estimated_absorpt_T_min   0.299
_shelx_estimated_absorpt_T_max   0.431
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_correction_T_min  0.0368
_exptl_absorpt_correction_T_max  0.1007
_exptl_absorpt_process_details   
;
 Data were corrected for Lorentz polarization and absorption
 effects (empirical absorption corrections SADABS).
 R(int) = 0.1707 (selected reflections only, before parameter refinement)
 R(int) = 0.0658 (selected reflections only, after parameter refinement)
;
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'fine-focus sealed tube'
_diffrn_measurement_device_type  'PHOTON2 area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            98857
_diffrn_reflns_av_unetI/netI     0.0291
_diffrn_reflns_av_R_equivalents  0.0459
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_k_min       -27
_diffrn_reflns_limit_k_max       27
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_theta_min         1.618
_diffrn_reflns_theta_max         27.000
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.984
_diffrn_measured_fraction_theta_full 0.995
_diffrn_reflns_Laue_measured_fraction_max 0.984
_diffrn_reflns_Laue_measured_fraction_full 0.995
_diffrn_reflns_point_group_measured_fraction_max 0.984
_diffrn_reflns_point_group_measured_fraction_full 0.995
_reflns_number_total             15372
_reflns_number_gt                14440
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'APEX2 (Bruker AXS, 2006)'
_computing_cell_refinement       'APEX2 (Bruker AXS, 2006)'
_computing_data_reduction        'SAINT (Bruker AXS, 2004)'
_computing_structure_solution    'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    'SCHAKAL99 (Keller, 1999)'
_computing_publication_material  'XCIF (Bruker AXS, 2001)'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0135P)²+39.4056P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         15372
_refine_ls_number_parameters     860
_refine_ls_number_restraints     86
_refine_ls_R_factor_all          0.0359
_refine_ls_R_factor_gt           0.0328
_refine_ls_wR_factor_ref         0.0689
_refine_ls_wR_factor_gt          0.0680
_refine_ls_goodness_of_fit_ref   1.204
_refine_ls_restrained_S_all      1.209
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.50220(2) 0.31432(2) 0.27954(2) 0.01498(5) Uani 1 1 d . . . . .
Au2 Au 0.66092(2) 0.35891(2) 0.35364(2) 0.01580(5) Uani 1 1 d . . . . .
Au3 Au 0.35712(2) 0.40564(2) 0.24791(2) 0.01753(5) Uani 1 1 d . . . . .
Ru1 Ru 0.38898(3) 0.38686(2) 0.44070(2) 0.01614(8) Uani 1 1 d D . . . .
H1 H 0.356(3) 0.409(2) 0.3648(8) 0.019 Uiso 1 1 d D U . . .
Ru2 Ru 0.50918(3) 0.29737(2) 0.40203(2) 0.01450(8) Uani 1 1 d . . . . .
Ru3 Ru 0.48245(3) 0.42042(2) 0.34625(2) 0.01243(8) Uani 1 1 d D . . . .
Ru4 Ru 0.32114(3) 0.32920(2) 0.33907(2) 0.01522(8) Uani 1 1 d D . . . .
C1 C 0.3152(4) 0.4606(3) 0.4427(2) 0.0204(11) Uani 1 1 d . . . . .
C2 C 0.3085(4) 0.3456(3) 0.4865(2) 0.0238(11) Uani 1 1 d . . . . .
C3 C 0.4795(4) 0.4092(3) 0.5031(2) 0.0231(11) Uani 1 1 d . . . . .
C4 C 0.4409(4) 0.2541(3) 0.4531(2) 0.0260(12) Uani 1 1 d . . . . .
C5 C 0.6093(4) 0.3232(2) 0.4580(2) 0.0192(10) Uani 1 1 d . . . . .
C6 C 0.5784(4) 0.2277(3) 0.3792(2) 0.0232(11) Uani 1 1 d . . . . .
C7 C 0.5632(4) 0.4579(2) 0.4060(2) 0.0207(11) Uani 1 1 d . . . . .
C8 C 0.3960(4) 0.4882(2) 0.3401(2) 0.0183(10) Uani 1 1 d . . . . .
C9 C 0.5541(4) 0.4500(2) 0.2877(2) 0.0178(10) Uani 1 1 d . . . . .
C10 C 0.2286(4) 0.3920(3) 0.3447(2) 0.0230(11) Uani 1 1 d . . . . .
C11 C 0.2515(4) 0.2723(3) 0.3780(2) 0.0257(12) Uani 1 1 d . . . . .
C12 C 0.2679(4) 0.2954(3) 0.2677(2) 0.0205(11) Uani 1 1 d . . . . .
O1 O 0.2705(3) 0.50347(19) 0.44642(16) 0.0254(8) Uani 1 1 d . . . . .
O2 O 0.2584(3) 0.3239(2) 0.51591(19) 0.0382(11) Uani 1 1 d . . . . .
O3 O 0.5308(3) 0.4217(2) 0.54235(17) 0.0289(9) Uani 1 1 d . . . . .
O4 O 0.4056(3) 0.2221(2) 0.48330(19) 0.0381(11) Uani 1 1 d . . . . .
O5 O 0.6693(3) 0.33529(19) 0.49326(16) 0.0276(9) Uani 1 1 d . . . . .
O6 O 0.6184(3) 0.18230(19) 0.3727(2) 0.0332(10) Uani 1 1 d . . . . .
O7 O 0.6133(3) 0.48464(19) 0.43870(16) 0.0270(9) Uani 1 1 d . . . . .
O8 O 0.3499(3) 0.53178(18) 0.33603(16) 0.0242(8) Uani 1 1 d . . . . .
O9 O 0.5959(3) 0.47595(19) 0.25612(17) 0.0263(9) Uani 1 1 d . . . . .
O10 O 0.1663(3) 0.4267(2) 0.34540(18) 0.0323(10) Uani 1 1 d . . . . .
O11 O 0.2071(3) 0.2368(2) 0.3993(2) 0.0441(12) Uani 1 1 d . . . . .
O12 O 0.2230(3) 0.2736(2) 0.22919(18) 0.0334(10) Uani 1 1 d . . . . .
P1 P 0.54849(9) 0.25739(6) 0.20665(5) 0.0150(2) Uani 1 1 d . . . . .
P2 P 0.82612(9) 0.36789(6) 0.35911(6) 0.0183(3) Uani 1 1 d . . . . .
P3 P 0.28256(10) 0.45095(7) 0.16809(6) 0.0195(3) Uani 1 1 d . . . . .
C101 C 0.6419(4) 0.2002(2) 0.2267(2) 0.0193(10) Uani 1 1 d . . . . .
C102 C 0.7261(4) 0.2186(3) 0.2598(3) 0.0331(14) Uani 1 1 d . . . . .
H102 H 0.7327 0.2600 0.2727 0.040 Uiso 1 1 calc R U . . .
C103 C 0.8001(5) 0.1770(3) 0.2741(3) 0.0438(18) Uani 1 1 d . . . . .
H103 H 0.8575 0.1900 0.2966 0.053 Uiso 1 1 calc R U . . .
C104 C 0.7914(5) 0.1169(3) 0.2559(3) 0.0439(18) Uani 1 1 d . . . . .
H104 H 0.8427 0.0886 0.2661 0.053 Uiso 1 1 calc R U . . .
C105 C 0.7089(5) 0.0974(3) 0.2232(3) 0.0391(16) Uani 1 1 d . . . . .
H105 H 0.7029 0.0558 0.2109 0.047 Uiso 1 1 calc R U . . .
C106 C 0.6341(4) 0.1392(3) 0.2082(3) 0.0295(13) Uani 1 1 d . . . . .
H106 H 0.5773 0.1260 0.1852 0.035 Uiso 1 1 calc R U . . .
C111 C 0.5988(4) 0.3022(2) 0.1527(2) 0.0181(10) Uani 1 1 d . . . . .
C112 C 0.6663(4) 0.2772(3) 0.1204(2) 0.0246(11) Uani 1 1 d . . . . .
H112 H 0.6879 0.2359 0.1264 0.029 Uiso 1 1 calc R U . . .
C113 C 0.7020(4) 0.3130(3) 0.0791(2) 0.0262(12) Uani 1 1 d . . . . .
H113 H 0.7479 0.2959 0.0570 0.031 Uiso 1 1 calc R U . . .
C114 C 0.6713(4) 0.3730(3) 0.0701(2) 0.0284(13) Uani 1 1 d . . . . .
H114 H 0.6963 0.3973 0.0420 0.034 Uiso 1 1 calc R U . . .
C115 C 0.6036(4) 0.3976(3) 0.1022(2) 0.0265(12) Uani 1 1 d . . . . .
H115 H 0.5812 0.4386 0.0956 0.032 Uiso 1 1 calc R U . . .
C116 C 0.5686(4) 0.3626(3) 0.1439(2) 0.0219(11) Uani 1 1 d . . . . .
H116 H 0.5238 0.3801 0.1665 0.026 Uiso 1 1 calc R U . . .
C121 C 0.4512(3) 0.2125(2) 0.1687(2) 0.0166(10) Uani 1 1 d . . . . .
C122 C 0.4420(4) 0.2033(3) 0.1108(2) 0.0203(11) Uani 1 1 d . . . . .
H122 H 0.4861 0.2228 0.0889 0.024 Uiso 1 1 calc R U . . .
C123 C 0.3689(4) 0.1657(3) 0.0847(2) 0.0223(11) Uani 1 1 d . . . . .
H123 H 0.3625 0.1599 0.0450 0.027 Uiso 1 1 calc R U . . .
C124 C 0.3057(4) 0.1369(3) 0.1167(3) 0.0269(12) Uani 1 1 d . . . . .
H124 H 0.2558 0.1111 0.0990 0.032 Uiso 1 1 calc R U . . .
C125 C 0.3145(4) 0.1455(3) 0.1742(3) 0.0254(12) Uani 1 1 d . . . . .
H125 H 0.2714 0.1249 0.1960 0.031 Uiso 1 1 calc R U . . .
C126 C 0.3854(4) 0.1835(2) 0.2003(2) 0.0212(11) Uani 1 1 d . . . . .
H126 H 0.3897 0.1902 0.2398 0.025 Uiso 1 1 calc R U . . .
C201 C 0.8760(4) 0.4406(2) 0.3869(2) 0.0194(10) Uani 1 1 d . . . . .
C202 C 0.9515(4) 0.4700(3) 0.3643(2) 0.0228(11) Uani 1 1 d . . . . .
H202 H 0.9763 0.4530 0.3323 0.027 Uiso 1 1 calc R U . . .
C203 C 0.9908(4) 0.5238(3) 0.3882(2) 0.0250(12) Uani 1 1 d . . . . .
H203 H 1.0433 0.5432 0.3730 0.030 Uiso 1 1 calc R U . . .
C204 C 0.9539(4) 0.5492(3) 0.4340(3) 0.0323(13) Uani 1 1 d . . . . .
H204 H 0.9798 0.5869 0.4494 0.039 Uiso 1 1 calc R U . . .
C205 C 0.8799(4) 0.5206(3) 0.4575(3) 0.0319(13) Uani 1 1 d . . . . .
H205 H 0.8561 0.5379 0.4897 0.038 Uiso 1 1 calc R U . . .
C206 C 0.8398(4) 0.4663(3) 0.4339(2) 0.0279(12) Uani 1 1 d . . . . .
H206 H 0.7881 0.4467 0.4497 0.033 Uiso 1 1 calc R U . . .
C211 C 0.8893(4) 0.3109(3) 0.4057(2) 0.0220(11) Uani 1 1 d . . . . .
C212 C 0.9808(4) 0.3208(3) 0.4345(2) 0.0242(12) Uani 1 1 d . . . . .
H212 H 1.0139 0.3583 0.4293 0.029 Uiso 1 1 calc R U . . .
C213 C 1.0241(4) 0.2765(3) 0.4709(2) 0.0294(13) Uani 1 1 d . . . . .
H213 H 1.0869 0.2837 0.4902 0.035 Uiso 1 1 calc R U . . .
C214 C 0.9771(4) 0.2223(3) 0.4792(3) 0.0335(14) Uani 1 1 d . . . . .
H214 H 1.0069 0.1923 0.5046 0.040 Uiso 1 1 calc R U . . .
C215 C 0.8863(5) 0.2114(3) 0.4507(3) 0.0444(18) Uani 1 1 d . . . . .
H215 H 0.8537 0.1737 0.4559 0.053 Uiso 1 1 calc R U . . .
C216 C 0.8427(4) 0.2560(3) 0.4141(3) 0.0328(14) Uani 1 1 d . . . . .
H216 H 0.7800 0.2486 0.3947 0.039 Uiso 1 1 calc R U . . .
C221 C 0.8712(4) 0.3608(3) 0.2913(2) 0.0220(11) Uani 1 1 d . . . . .
C222 C 0.9548(4) 0.3283(3) 0.2829(3) 0.0304(13) Uani 1 1 d . . . . .
H222 H 0.9902 0.3070 0.3134 0.036 Uiso 1 1 calc R U . . .
C223 C 0.9863(5) 0.3269(4) 0.2297(3) 0.0436(18) Uani 1 1 d . . . . .
H223 H 1.0437 0.3050 0.2240 0.052 Uiso 1 1 calc R U . . .
C224 C 0.9340(5) 0.3574(4) 0.1852(3) 0.0409(17) Uani 1 1 d . . . . .
H224 H 0.9556 0.3561 0.1490 0.049 Uiso 1 1 calc R U . . .
C225 C 0.8516(4) 0.3893(3) 0.1928(3) 0.0365(15) Uani 1 1 d . . . . .
H225 H 0.8165 0.4106 0.1622 0.044 Uiso 1 1 calc R U . . .
C226 C 0.8195(4) 0.3903(3) 0.2458(2) 0.0285(13) Uani 1 1 d . . . . .
H226 H 0.7613 0.4114 0.2509 0.034 Uiso 1 1 calc R U . . .
C301 C 0.3619(4) 0.4938(3) 0.1281(3) 0.0294(13) Uani 1 1 d . . . . .
C302 C 0.4294(5) 0.5334(3) 0.1561(3) 0.0393(16) Uani 1 1 d . . . . .
H302 H 0.4357 0.5359 0.1960 0.047 Uiso 1 1 calc R U . . .
C303 C 0.4874(5) 0.5692(4) 0.1264(4) 0.054(2) Uani 1 1 d . . . . .
H303 H 0.5324 0.5971 0.1457 0.064 Uiso 1 1 calc R U . . .
C304 C 0.4803(6) 0.5646(4) 0.0683(3) 0.052(2) Uani 1 1 d . . . . .
H304 H 0.5204 0.5894 0.0479 0.062 Uiso 1 1 calc R U . . .
C305 C 0.4153(5) 0.5242(4) 0.0399(3) 0.0464(18) Uani 1 1 d . . . . .
H305 H 0.4114 0.5206 0.0001 0.056 Uiso 1 1 calc R U . . .
C306 C 0.3564(5) 0.4893(3) 0.0694(3) 0.0377(15) Uani 1 1 d . . . . .
H306 H 0.3112 0.4616 0.0498 0.045 Uiso 1 1 calc R U . . .
C311 C 0.1875(4) 0.5058(2) 0.1802(2) 0.0214(11) Uani 1 1 d . . . . .
C312 C 0.1183(4) 0.4872(3) 0.2143(2) 0.0299(13) Uani 1 1 d . . . . .
H312 H 0.1237 0.4481 0.2323 0.036 Uiso 1 1 calc R U . . .
C313 C 0.0415(5) 0.5258(4) 0.2217(3) 0.0380(16) Uani 1 1 d . . . . .
H313 H -0.0057 0.5133 0.2451 0.046 Uiso 1 1 calc R U . . .
C314 C 0.0334(5) 0.5822(3) 0.1955(3) 0.0364(15) Uani 1 1 d . . . . .
H314 H -0.0198 0.6082 0.2008 0.044 Uiso 1 1 calc R U . . .
C315 C 0.1012(5) 0.6014(3) 0.1618(3) 0.0379(15) Uani 1 1 d . . . . .
H315 H 0.0952 0.6406 0.1441 0.046 Uiso 1 1 calc R U . . .
C316 C 0.1787(5) 0.5631(3) 0.1538(3) 0.0295(13) Uani 1 1 d . . . . .
H316 H 0.2255 0.5759 0.1302 0.035 Uiso 1 1 calc R U . . .
C321 C 0.2217(4) 0.3974(3) 0.1174(2) 0.0249(12) Uani 1 1 d . . . . .
C322 C 0.2658(5) 0.3415(3) 0.1087(3) 0.0346(15) Uani 1 1 d . . . . .
H322 H 0.3257 0.3313 0.1302 0.042 Uiso 1 1 calc R U . . .
C323 C 0.2230(6) 0.3005(4) 0.0689(3) 0.054(2) Uani 1 1 d . . . . .
H323 H 0.2541 0.2626 0.0626 0.065 Uiso 1 1 calc R U . . .
C324 C 0.1355(6) 0.3147(4) 0.0387(4) 0.055(2) Uani 1 1 d . . . . .
H324 H 0.1065 0.2868 0.0110 0.066 Uiso 1 1 calc R U . . .
C325 C 0.0897(5) 0.3692(3) 0.0484(3) 0.047(2) Uani 1 1 d . . . . .
H325 H 0.0283 0.3782 0.0281 0.057 Uiso 1 1 calc R U . . .
C326 C 0.1316(5) 0.4105(3) 0.0869(3) 0.0356(15) Uani 1 1 d . . . . .
H326 H 0.0996 0.4482 0.0930 0.043 Uiso 1 1 calc R U . . .
C401 C 0.8579(7) 0.5429(5) 0.0794(5) 0.085(4) Uani 1 1 d . . . . .
H40A H 0.8986 0.5413 0.1163 0.102 Uiso 1 1 calc R U . . .
H40B H 0.8755 0.5806 0.0596 0.102 Uiso 1 1 calc R U . . .
Cl1 Cl 0.88263(16) 0.47799(11) 0.03951(13) 0.0722(7) Uani 1 1 d . . . . .
Cl2 Cl 0.73747(17) 0.54685(11) 0.09023(12) 0.0686(6) Uani 1 1 d . . . . .
C411 C 0.4450(7) 0.6784(5) 0.3417(4) 0.071(2) Uani 0.868(3) 1 d D U P A 1
H41A H 0.4008 0.7142 0.3422 0.086 Uiso 0.868(3) 1 calc R U P A 1
H41B H 0.4172 0.6445 0.3623 0.086 Uiso 0.868(3) 1 calc R U P A 1
Cl3 Cl 0.5557(3) 0.6981(2) 0.37714(17) 0.1148(15) Uani 0.868(3) 1 d D U P A 1
Cl4 Cl 0.44790(19) 0.65540(12) 0.27159(11) 0.0602(6) Uani 0.868(3) 1 d D U P A
1
C421 C 0.434(2) 0.655(2) 0.350(3) 0.071(2) Uani 0.132(3) 1 d D U P A 2
H42A H 0.3851 0.6648 0.3175 0.086 Uiso 0.132(3) 1 calc R U P A 2
H42B H 0.4087 0.6211 0.3722 0.086 Uiso 0.132(3) 1 calc R U P A 2
Cl5 Cl 0.4659(17) 0.7191(11) 0.3910(10) 0.1148(15) Uani 0.132(3) 1 d D U P A 2
Cl6 Cl 0.5455(12) 0.6359(8) 0.3284(7) 0.0602(6) Uani 0.132(3) 1 d D U P A 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 P1 2.2902(13) . ?
Au1 Au2 2.8288(3) . ?
Au1 Ru3 2.8333(5) . ?
Au1 Au3 2.8623(3) . ?
Au1 Ru2 2.9431(5) . ?
Au1 Ru4 3.0487(5) . ?
Au2 P2 2.2890(13) . ?
Au2 Ru3 2.8006(5) . ?
Au2 Ru2 2.8524(5) . ?
Au3 P3 2.2835(13) . ?
Au3 Ru3 2.7730(5) . ?
Au3 Ru4 2.8311(5) . ?
Ru1 C2 1.882(6) . ?
Ru1 C3 1.897(5) . ?
Ru1 C1 1.903(6) . ?
Ru1 Ru2 2.7887(6) . ?
Ru1 Ru4 2.7964(6) . ?
Ru1 Ru3 2.8308(6) . ?
Ru1 H1 1.88(3) . ?
Ru2 C4 1.884(6) . ?
Ru2 C5 1.895(5) . ?
Ru2 C6 1.905(6) . ?
Ru2 Ru4 2.9363(6) . ?
Ru2 Ru3 2.9888(6) . ?
Ru3 C7 1.892(5) . ?
Ru3 C8 1.893(5) . ?
Ru3 C9 1.921(5) . ?
Ru3 Ru4 2.9782(6) . ?
Ru3 H1 1.88(3) . ?
Ru4 C11 1.881(6) . ?
Ru4 C10 1.889(6) . ?
Ru4 C12 1.923(5) . ?
Ru4 H1 1.88(3) . ?
C1 O1 1.128(7) . ?
C2 O2 1.147(7) . ?
C3 O3 1.141(7) . ?
C4 O4 1.151(7) . ?
C5 O5 1.143(6) . ?
C6 O6 1.151(7) . ?
C7 O7 1.141(6) . ?
C8 O8 1.140(6) . ?
C9 O9 1.154(6) . ?
C10 O10 1.148(7) . ?
C11 O11 1.144(7) . ?
C12 O12 1.150(6) . ?
P1 C101 1.817(5) . ?
P1 C121 1.818(5) . ?
P1 C111 1.821(5) . ?
P2 C221 1.814(6) . ?
P2 C201 1.817(5) . ?
P2 C211 1.820(6) . ?
P3 C301 1.801(6) . ?
P3 C321 1.814(6) . ?
P3 C311 1.826(5) . ?
C101 C102 1.391(7) . ?
C101 C106 1.398(8) . ?
C102 C103 1.379(8) . ?
C102 H102 0.9500 . ?
C103 C104 1.376(10) . ?
C103 H103 0.9500 . ?
C104 C105 1.374(9) . ?
C104 H104 0.9500 . ?
C105 C106 1.392(8) . ?
C105 H105 0.9500 . ?
C106 H106 0.9500 . ?
C111 C116 1.385(8) . ?
C111 C112 1.393(7) . ?
C112 C113 1.392(8) . ?
C112 H112 0.9500 . ?
C113 C114 1.379(9) . ?
C113 H113 0.9500 . ?
C114 C115 1.390(8) . ?
C114 H114 0.9500 . ?
C115 C116 1.387(8) . ?
C115 H115 0.9500 . ?
C116 H116 0.9500 . ?
C121 C122 1.391(7) . ?
C121 C126 1.401(7) . ?
C122 C123 1.391(7) . ?
C122 H122 0.9500 . ?
C123 C124 1.381(8) . ?
C123 H123 0.9500 . ?
C124 C125 1.380(8) . ?
C124 H124 0.9500 . ?
C125 C126 1.376(8) . ?
C125 H125 0.9500 . ?
C126 H126 0.9500 . ?
C201 C202 1.390(7) . ?
C201 C206 1.400(8) . ?
C202 C203 1.382(8) . ?
C202 H202 0.9500 . ?
C203 C204 1.379(8) . ?
C203 H203 0.9500 . ?
C204 C205 1.377(8) . ?
C204 H204 0.9500 . ?
C205 C206 1.394(8) . ?
C205 H205 0.9500 . ?
C206 H206 0.9500 . ?
C211 C216 1.380(8) . ?
C211 C212 1.388(7) . ?
C212 C213 1.385(8) . ?
C212 H212 0.9500 . ?
C213 C214 1.372(9) . ?
C213 H213 0.9500 . ?
C214 C215 1.381(9) . ?
C214 H214 0.9500 . ?
C215 C216 1.394(9) . ?
C215 H215 0.9500 . ?
C216 H216 0.9500 . ?
C221 C226 1.386(8) . ?
C221 C222 1.392(8) . ?
C222 C223 1.393(9) . ?
C222 H222 0.9500 . ?
C223 C224 1.384(10) . ?
C223 H223 0.9500 . ?
C224 C225 1.368(10) . ?
C224 H224 0.9500 . ?
C225 C226 1.393(8) . ?
C225 H225 0.9500 . ?
C226 H226 0.9500 . ?
C301 C302 1.385(9) . ?
C301 C306 1.400(9) . ?
C302 C303 1.376(10) . ?
C302 H302 0.9500 . ?
C303 C304 1.384(12) . ?
C303 H303 0.9500 . ?
C304 C305 1.377(11) . ?
C304 H304 0.9500 . ?
C305 C306 1.370(9) . ?
C305 H305 0.9500 . ?
C306 H306 0.9500 . ?
C311 C312 1.391(8) . ?
C311 C316 1.393(8) . ?
C312 C313 1.384(9) . ?
C312 H312 0.9500 . ?
C313 C314 1.372(10) . ?
C313 H313 0.9500 . ?
C314 C315 1.375(10) . ?
C314 H314 0.9500 . ?
C315 C316 1.390(9) . ?
C315 H315 0.9500 . ?
C316 H316 0.9500 . ?
C321 C322 1.384(8) . ?
C321 C326 1.400(8) . ?
C322 C323 1.386(9) . ?
C322 H322 0.9500 . ?
C323 C324 1.373(9) . ?
C323 H323 0.9500 . ?
C324 C325 1.375(9) . ?
C324 H324 0.9500 . ?
C325 C326 1.365(9) . ?
C325 H325 0.9500 . ?
C326 H326 0.9500 . ?
C401 Cl2 1.723(10) . ?
C401 Cl1 1.758(11) . ?
C401 H40A 0.9900 . ?
C401 H40B 0.9900 . ?
C411 Cl3 1.719(8) . ?
C411 Cl4 1.756(9) . ?
C411 H41A 0.9900 . ?
C411 H41B 0.9900 . ?
C421 Cl5 1.736(13) . ?
C421 Cl6 1.739(13) . ?
C421 H42A 0.9900 . ?
C421 H42B 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Au1 Au2 113.18(3) . . ?
P1 Au1 Ru3 157.20(3) . . ?
Au2 Au1 Ru3 59.289(10) . . ?
P1 Au1 Au3 115.12(3) . . ?
Au2 Au1 Au3 113.557(10) . . ?
Ru3 Au1 Au3 58.267(10) . . ?
P1 Au1 Ru2 135.34(3) . . ?
Au2 Au1 Ru2 59.193(10) . . ?
Ru3 Au1 Ru2 62.282(12) . . ?
Au3 Au1 Ru2 106.778(11) . . ?
P1 Au1 Ru4 137.21(3) . . ?
Au2 Au1 Ru4 107.141(12) . . ?
Ru3 Au1 Ru4 60.707(11) . . ?
Au3 Au1 Ru4 57.129(10) . . ?
Ru2 Au1 Ru4 58.655(11) . . ?
P2 Au2 Ru3 146.63(4) . . ?
P2 Au2 Au1 139.91(4) . . ?
Ru3 Au2 Au1 60.437(10) . . ?
P2 Au2 Ru2 143.06(4) . . ?
Ru3 Au2 Ru2 63.828(13) . . ?
Au1 Au2 Ru2 62.401(11) . . ?
P3 Au3 Ru3 146.70(4) . . ?
P3 Au3 Ru4 142.43(4) . . ?
Ru3 Au3 Ru4 64.195(13) . . ?
P3 Au3 Au1 138.93(4) . . ?
Ru3 Au3 Au1 60.344(10) . . ?
Ru4 Au3 Au1 64.751(10) . . ?
C2 Ru1 C3 92.7(2) . . ?
C2 Ru1 C1 91.6(2) . . ?
C3 Ru1 C1 94.2(2) . . ?
C2 Ru1 Ru2 106.33(17) . . ?
C3 Ru1 Ru2 94.20(16) . . ?
C1 Ru1 Ru2 159.82(15) . . ?
C2 Ru1 Ru4 97.53(17) . . ?
C3 Ru1 Ru4 157.24(16) . . ?
C1 Ru1 Ru4 105.74(15) . . ?
Ru2 Ru1 Ru4 63.434(15) . . ?
C2 Ru1 Ru3 161.26(17) . . ?
C3 Ru1 Ru3 103.85(17) . . ?
C1 Ru1 Ru3 95.89(15) . . ?
Ru2 Ru1 Ru3 64.257(15) . . ?
Ru4 Ru1 Ru3 63.907(15) . . ?
C2 Ru1 H1 126.1(6) . . ?
C3 Ru1 H1 139.3(4) . . ?
C1 Ru1 H1 74.9(15) . . ?
Ru2 Ru1 H1 86.8(15) . . ?
Ru4 Ru1 H1 42.0(10) . . ?
Ru3 Ru1 H1 41.2(10) . . ?
C4 Ru2 C5 94.2(2) . . ?
C4 Ru2 C6 95.7(3) . . ?
C5 Ru2 C6 94.9(2) . . ?
C4 Ru2 Ru1 76.45(18) . . ?
C5 Ru2 Ru1 88.69(16) . . ?
C6 Ru2 Ru1 171.64(17) . . ?
C4 Ru2 Au2 161.65(16) . . ?
C5 Ru2 Au2 68.51(16) . . ?
C6 Ru2 Au2 80.42(17) . . ?
Ru1 Ru2 Au2 107.933(17) . . ?
C4 Ru2 Ru4 88.01(16) . . ?
C5 Ru2 Ru4 145.57(16) . . ?
C6 Ru2 Ru4 119.12(16) . . ?
Ru1 Ru2 Ru4 58.410(14) . . ?
Au2 Ru2 Ru4 109.610(16) . . ?
C4 Ru2 Au1 138.45(17) . . ?
C5 Ru2 Au1 126.92(16) . . ?
C6 Ru2 Au1 76.79(17) . . ?
Ru1 Ru2 Au1 107.029(16) . . ?
Au2 Ru2 Au1 58.406(10) . . ?
Ru4 Ru2 Au1 62.469(12) . . ?
C4 Ru2 Ru3 133.64(18) . . ?
C5 Ru2 Ru3 95.33(15) . . ?
C6 Ru2 Ru3 128.37(18) . . ?
Ru1 Ru2 Ru3 58.554(14) . . ?
Au2 Ru2 Ru3 57.242(11) . . ?
Ru4 Ru2 Ru3 60.343(13) . . ?
Au1 Ru2 Ru3 57.057(11) . . ?
C7 Ru3 C8 92.1(2) . . ?
C7 Ru3 C9 95.5(2) . . ?
C8 Ru3 C9 93.6(2) . . ?
C7 Ru3 Au3 161.07(16) . . ?
C8 Ru3 Au3 72.33(15) . . ?
C9 Ru3 Au3 75.35(15) . . ?
C7 Ru3 Au2 73.59(15) . . ?
C8 Ru3 Au2 157.36(15) . . ?
C9 Ru3 Au2 71.03(15) . . ?
Au3 Ru3 Au2 117.342(15) . . ?
C7 Ru3 Ru1 78.14(17) . . ?
C8 Ru3 Ru1 85.14(15) . . ?
C9 Ru3 Ru1 173.41(15) . . ?
Au3 Ru3 Ru1 110.277(16) . . ?
Au2 Ru3 Ru1 108.214(16) . . ?
C7 Ru3 Au1 133.38(16) . . ?
C8 Ru3 Au1 133.71(15) . . ?
C9 Ru3 Au1 76.58(15) . . ?
Au3 Ru3 Au1 61.389(10) . . ?
Au2 Ru3 Au1 60.275(10) . . ?
Ru1 Ru3 Au1 108.937(16) . . ?
C7 Ru3 Ru4 134.70(17) . . ?
C8 Ru3 Ru4 92.70(15) . . ?
C9 Ru3 Ru4 129.08(15) . . ?
Au3 Ru3 Ru4 58.849(12) . . ?
Au2 Ru3 Ru4 109.861(17) . . ?
Ru1 Ru3 Ru4 57.485(14) . . ?
Au1 Ru3 Ru4 63.224(13) . . ?
C7 Ru3 Ru2 90.94(17) . . ?
C8 Ru3 Ru2 140.61(15) . . ?
C9 Ru3 Ru2 125.18(15) . . ?
Au3 Ru3 Ru2 107.905(15) . . ?
Au2 Ru3 Ru2 58.930(12) . . ?
Ru1 Ru3 Ru2 57.190(14) . . ?
Au1 Ru3 Ru2 60.661(13) . . ?
Ru4 Ru3 Ru2 58.955(13) . . ?
C7 Ru3 H1 111.4(4) . . ?
C8 Ru3 H1 61.3(15) . . ?
C9 Ru3 H1 142.7(12) . . ?
Au3 Ru3 H1 71.0(6) . . ?
Au2 Ru3 H1 140.0(16) . . ?
Ru1 Ru3 H1 41.2(10) . . ?
Au1 Ru3 H1 100.4(10) . . ?
Ru4 Ru3 H1 37.6(11) . . ?
Ru2 Ru3 H1 81.1(16) . . ?
C11 Ru4 C10 92.6(2) . . ?
C11 Ru4 C12 91.3(2) . . ?
C10 Ru4 C12 98.4(2) . . ?
C11 Ru4 Ru1 90.20(18) . . ?
C10 Ru4 Ru1 77.09(16) . . ?
C12 Ru4 Ru1 175.29(16) . . ?
C11 Ru4 Au3 156.03(17) . . ?
C10 Ru4 Au3 79.37(17) . . ?
C12 Ru4 Au3 67.90(17) . . ?
Ru1 Ru4 Au3 109.590(17) . . ?
C11 Ru4 Ru2 93.97(17) . . ?
C10 Ru4 Ru2 134.73(16) . . ?
C12 Ru4 Ru2 126.14(15) . . ?
Ru1 Ru4 Ru2 58.156(14) . . ?
Au3 Ru4 Ru2 107.797(16) . . ?
C11 Ru4 Ru3 146.58(17) . . ?
C10 Ru4 Ru3 91.66(17) . . ?
C12 Ru4 Ru3 120.75(16) . . ?
Ru1 Ru4 Ru3 58.608(14) . . ?
Au3 Ru4 Ru3 56.956(12) . . ?
Ru2 Ru4 Ru3 60.702(14) . . ?
C11 Ru4 Au1 131.44(18) . . ?
C10 Ru4 Au1 135.64(17) . . ?
C12 Ru4 Au1 78.21(15) . . ?
Ru1 Ru4 Au1 104.025(15) . . ?
Au3 Ru4 Au1 58.120(10) . . ?
Ru2 Ru4 Au1 58.876(13) . . ?
Ru3 Ru4 Au1 56.068(11) . . ?
C11 Ru4 H1 124.7(5) . . ?
C10 Ru4 H1 57.5(15) . . ?
C12 Ru4 H1 134.3(11) . . ?
Ru1 Ru4 H1 42.0(10) . . ?
Au3 Ru4 H1 69.6(6) . . ?
Ru2 Ru4 H1 82.6(16) . . ?
Ru3 Ru4 H1 37.6(11) . . ?
Au1 Ru4 H1 93.3(10) . . ?
O1 C1 Ru1 176.6(5) . . ?
O2 C2 Ru1 175.7(5) . . ?
O3 C3 Ru1 176.7(5) . . ?
O4 C4 Ru2 172.4(5) . . ?
O5 C5 Ru2 175.8(5) . . ?
O6 C6 Ru2 170.3(5) . . ?
O7 C7 Ru3 173.9(5) . . ?
O8 C8 Ru3 174.8(5) . . ?
O9 C9 Ru3 170.1(5) . . ?
O10 C10 Ru4 173.8(5) . . ?
O11 C11 Ru4 176.9(5) . . ?
O12 C12 Ru4 169.0(5) . . ?
C101 P1 C121 103.3(2) . . ?
C101 P1 C111 103.3(2) . . ?
C121 P1 C111 104.9(2) . . ?
C101 P1 Au1 115.04(17) . . ?
C121 P1 Au1 114.21(17) . . ?
C111 P1 Au1 114.68(18) . . ?
C221 P2 C201 104.1(2) . . ?
C221 P2 C211 107.3(3) . . ?
C201 P2 C211 103.4(2) . . ?
C221 P2 Au2 113.04(17) . . ?
C201 P2 Au2 115.49(17) . . ?
C211 P2 Au2 112.54(18) . . ?
C301 P3 C321 104.0(3) . . ?
C301 P3 C311 104.3(3) . . ?
C321 P3 C311 103.7(2) . . ?
C301 P3 Au3 114.94(18) . . ?
C321 P3 Au3 114.28(19) . . ?
C311 P3 Au3 114.33(18) . . ?
C102 C101 C106 118.8(5) . . ?
C102 C101 P1 118.6(4) . . ?
C106 C101 P1 122.6(4) . . ?
C103 C102 C101 120.2(6) . . ?
C103 C102 H102 119.9 . . ?
C101 C102 H102 119.9 . . ?
C104 C103 C102 120.5(6) . . ?
C104 C103 H103 119.7 . . ?
C102 C103 H103 119.7 . . ?
C105 C104 C103 120.5(6) . . ?
C105 C104 H104 119.7 . . ?
C103 C104 H104 119.7 . . ?
C104 C105 C106 119.5(6) . . ?
C104 C105 H105 120.3 . . ?
C106 C105 H105 120.3 . . ?
C105 C106 C101 120.5(5) . . ?
C105 C106 H106 119.7 . . ?
C101 C106 H106 119.7 . . ?
C116 C111 C112 119.8(5) . . ?
C116 C111 P1 118.5(4) . . ?
C112 C111 P1 121.7(4) . . ?
C113 C112 C111 119.7(5) . . ?
C113 C112 H112 120.2 . . ?
C111 C112 H112 120.2 . . ?
C114 C113 C112 120.6(5) . . ?
C114 C113 H113 119.7 . . ?
C112 C113 H113 119.7 . . ?
C113 C114 C115 119.5(5) . . ?
C113 C114 H114 120.2 . . ?
C115 C114 H114 120.2 . . ?
C116 C115 C114 120.3(6) . . ?
C116 C115 H115 119.8 . . ?
C114 C115 H115 119.8 . . ?
C111 C116 C115 120.1(5) . . ?
C111 C116 H116 120.0 . . ?
C115 C116 H116 120.0 . . ?
C122 C121 C126 119.0(5) . . ?
C122 C121 P1 123.3(4) . . ?
C126 C121 P1 117.7(4) . . ?
C123 C122 C121 120.5(5) . . ?
C123 C122 H122 119.8 . . ?
C121 C122 H122 119.8 . . ?
C124 C123 C122 119.6(5) . . ?
C124 C123 H123 120.2 . . ?
C122 C123 H123 120.2 . . ?
C125 C124 C123 120.4(5) . . ?
C125 C124 H124 119.8 . . ?
C123 C124 H124 119.8 . . ?
C126 C125 C124 120.5(5) . . ?
C126 C125 H125 119.8 . . ?
C124 C125 H125 119.8 . . ?
C125 C126 C121 120.0(5) . . ?
C125 C126 H126 120.0 . . ?
C121 C126 H126 120.0 . . ?
C202 C201 C206 119.2(5) . . ?
C202 C201 P2 121.9(4) . . ?
C206 C201 P2 118.8(4) . . ?
C203 C202 C201 120.4(5) . . ?
C203 C202 H202 119.8 . . ?
C201 C202 H202 119.8 . . ?
C204 C203 C202 120.1(5) . . ?
C204 C203 H203 120.0 . . ?
C202 C203 H203 120.0 . . ?
C205 C204 C203 120.6(6) . . ?
C205 C204 H204 119.7 . . ?
C203 C204 H204 119.7 . . ?
C204 C205 C206 119.8(6) . . ?
C204 C205 H205 120.1 . . ?
C206 C205 H205 120.1 . . ?
C205 C206 C201 119.9(5) . . ?
C205 C206 H206 120.1 . . ?
C201 C206 H206 120.1 . . ?
C216 C211 C212 118.6(5) . . ?
C216 C211 P2 118.4(4) . . ?
C212 C211 P2 123.0(4) . . ?
C213 C212 C211 120.5(6) . . ?
C213 C212 H212 119.8 . . ?
C211 C212 H212 119.8 . . ?
C214 C213 C212 120.6(5) . . ?
C214 C213 H213 119.7 . . ?
C212 C213 H213 119.7 . . ?
C213 C214 C215 119.8(6) . . ?
C213 C214 H214 120.1 . . ?
C215 C214 H214 120.1 . . ?
C214 C215 C216 119.6(6) . . ?
C214 C215 H215 120.2 . . ?
C216 C215 H215 120.2 . . ?
C211 C216 C215 121.0(6) . . ?
C211 C216 H216 119.5 . . ?
C215 C216 H216 119.5 . . ?
C226 C221 C222 118.9(5) . . ?
C226 C221 P2 117.5(4) . . ?
C222 C221 P2 123.6(5) . . ?
C221 C222 C223 120.0(6) . . ?
C221 C222 H222 120.0 . . ?
C223 C222 H222 120.0 . . ?
C224 C223 C222 119.9(6) . . ?
C224 C223 H223 120.0 . . ?
C222 C223 H223 120.0 . . ?
C225 C224 C223 120.7(6) . . ?
C225 C224 H224 119.6 . . ?
C223 C224 H224 119.6 . . ?
C224 C225 C226 119.4(6) . . ?
C224 C225 H225 120.3 . . ?
C226 C225 H225 120.3 . . ?
C221 C226 C225 121.1(6) . . ?
C221 C226 H226 119.5 . . ?
C225 C226 H226 119.5 . . ?
C302 C301 C306 118.9(6) . . ?
C302 C301 P3 119.0(5) . . ?
C306 C301 P3 122.1(5) . . ?
C303 C302 C301 120.2(7) . . ?
C303 C302 H302 119.9 . . ?
C301 C302 H302 119.9 . . ?
C302 C303 C304 120.1(7) . . ?
C302 C303 H303 119.9 . . ?
C304 C303 H303 119.9 . . ?
C305 C304 C303 120.3(7) . . ?
C305 C304 H304 119.8 . . ?
C303 C304 H304 119.8 . . ?
C306 C305 C304 119.7(7) . . ?
C306 C305 H305 120.2 . . ?
C304 C305 H305 120.2 . . ?
C305 C306 C301 120.7(7) . . ?
C305 C306 H306 119.6 . . ?
C301 C306 H306 119.6 . . ?
C312 C311 C316 119.7(5) . . ?
C312 C311 P3 117.7(4) . . ?
C316 C311 P3 122.4(5) . . ?
C313 C312 C311 119.6(6) . . ?
C313 C312 H312 120.2 . . ?
C311 C312 H312 120.2 . . ?
C314 C313 C312 120.3(6) . . ?
C314 C313 H313 119.8 . . ?
C312 C313 H313 119.8 . . ?
C313 C314 C315 120.9(6) . . ?
C313 C314 H314 119.6 . . ?
C315 C314 H314 119.6 . . ?
C314 C315 C316 119.6(6) . . ?
C314 C315 H315 120.2 . . ?
C316 C315 H315 120.2 . . ?
C315 C316 C311 119.9(6) . . ?
C315 C316 H316 120.1 . . ?
C311 C316 H316 120.1 . . ?
C322 C321 C326 118.9(5) . . ?
C322 C321 P3 118.9(4) . . ?
C326 C321 P3 122.3(5) . . ?
C321 C322 C323 120.4(6) . . ?
C321 C322 H322 119.8 . . ?
C323 C322 H322 119.8 . . ?
C324 C323 C322 119.8(6) . . ?
C324 C323 H323 120.1 . . ?
C322 C323 H323 120.1 . . ?
C323 C324 C325 120.1(6) . . ?
C323 C324 H324 119.9 . . ?
C325 C324 H324 119.9 . . ?
C326 C325 C324 120.7(6) . . ?
C326 C325 H325 119.7 . . ?
C324 C325 H325 119.7 . . ?
C325 C326 C321 120.1(6) . . ?
C325 C326 H326 120.0 . . ?
C321 C326 H326 120.0 . . ?
Cl2 C401 Cl1 112.1(5) . . ?
Cl2 C401 H40A 109.2 . . ?
Cl1 C401 H40A 109.2 . . ?
Cl2 C401 H40B 109.2 . . ?
Cl1 C401 H40B 109.2 . . ?
H40A C401 H40B 107.9 . . ?
Cl3 C411 Cl4 114.9(6) . . ?
Cl3 C411 H41A 108.5 . . ?
Cl4 C411 H41A 108.5 . . ?
Cl3 C411 H41B 108.5 . . ?
Cl4 C411 H41B 108.5 . . ?
H41A C411 H41B 107.5 . . ?
Cl5 C421 Cl6 100.3(17) . . ?
Cl5 C421 H42A 111.7 . . ?
Cl6 C421 H42A 111.7 . . ?
Cl5 C421 H42B 111.7 . . ?
Cl6 C421 H42B 111.7 . . ?
H42A C421 H42B 109.5 . . ?

_refine_diff_density_max         1.417
_refine_diff_density_min         -1.485
_refine_diff_density_rms         0.155

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_4
_database_code_depnum_ccdc_archive 'CCDC 2305341'
loop_
_audit_author_name
_audit_author_address
'Stefano Zacchini'
;Universita di Bologna
Italy
;
_audit_update_record             
;
2023-11-02 deposited with the CCDC.	2024-01-18 downloaded from the CCDC.
;
# start Validation Reply Form
_vrf_PLAT971_4                   
;
PROBLEM:  Check Calcd Resid. Dens
RESPONSE: This alert is due to high values for 
the residual electron density. This maximum is located close
to the cluster core, in a position which is not realistic for 
any atom, and this is a series termination error, 
common with heavy atoms.
;
_vrf_PLAT972_4                   
;
PROBLEM:  Check Calcd Resid. Dens
RESPONSE: This alert is due to high values for 
the residual electron density. This maximum is located close
to the cluster core, in a position which is not realistic for 
any atom, and this is a series termination error, 
common with heavy atoms.
;
# end Validation Reply Form  
_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C66 H46 Au3 O12 P3 Ru4'
_chemical_formula_weight         2119.11

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   13.2702(19)
_cell_length_b                   14.563(2)
_cell_length_c                   18.762(3)
_cell_angle_alpha                108.410(4)
_cell_angle_beta                 98.613(4)
_cell_angle_gamma                109.110(4)
_cell_volume                     3118.3(8)
_cell_formula_units_Z            2
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    9963
_cell_measurement_theta_min      2.2455
_cell_measurement_theta_max      26.4585

_exptl_crystal_description       plate
_exptl_crystal_colour            black
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    2.257
_exptl_crystal_F_000             1992
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.110
_exptl_crystal_size_mid          0.070
_exptl_crystal_size_min          0.015
_exptl_absorpt_coefficient_mu    8.111
_shelx_estimated_absorpt_T_min   0.469
_shelx_estimated_absorpt_T_max   0.888
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_correction_T_min  0.1190
_exptl_absorpt_correction_T_max  0.2065
_exptl_absorpt_process_details   
;
 Data were corrected for Lorentz polarization and absorption
 effects (empirical absorption corrections SADABS).
 R(int) = 0.1573 (selected reflections only, before parameter refinement)
 R(int) = 0.0718 (selected reflections only, after parameter refinement)
;
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'fine-focus sealed tube'
_diffrn_measurement_device_type  'PHOTON2 area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            31342
_diffrn_reflns_av_unetI/netI     0.0931
_diffrn_reflns_av_R_equivalents  0.0816
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_theta_min         1.608
_diffrn_reflns_theta_max         25.100
_diffrn_reflns_theta_full        25.100
_diffrn_measured_fraction_theta_max 0.984
_diffrn_measured_fraction_theta_full 0.984
_diffrn_reflns_Laue_measured_fraction_max 0.984
_diffrn_reflns_Laue_measured_fraction_full 0.984
_diffrn_reflns_point_group_measured_fraction_max 0.984
_diffrn_reflns_point_group_measured_fraction_full 0.984
_reflns_number_total             10940
_reflns_number_gt                8946
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'APEX2 (Bruker AXS, 2006)'
_computing_cell_refinement       'APEX2 (Bruker AXS, 2006)'
_computing_data_reduction        'SAINT (Bruker AXS, 2004)'
_computing_structure_solution    'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    'SCHAKAL99 (Keller, 1999)'
_computing_publication_material  'XCIF (Bruker AXS, 2001)'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+272.1556P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         10940
_refine_ls_number_parameters     688
_refine_ls_number_restraints     495
_refine_ls_R_factor_all          0.0985
_refine_ls_R_factor_gt           0.0820
_refine_ls_wR_factor_ref         0.1891
_refine_ls_wR_factor_gt          0.1826
_refine_ls_goodness_of_fit_ref   1.136
_refine_ls_restrained_S_all      1.115
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.45995(6) 0.51074(6) 0.25729(4) 0.01377(19) Uani 1 1 d . . . . .
Au2 Au 0.68836(6) 0.55467(6) 0.24415(5) 0.01398(19) Uani 1 1 d . . . . .
Au3 Au 0.36528(6) 0.28537(6) 0.22588(5) 0.01383(19) Uani 1 1 d . . . . .
Ru1 Ru 0.58705(13) 0.40797(12) 0.30549(9) 0.0119(3) Uani 1 1 d . . . . .
Ru2 Ru 0.50842(13) 0.36823(12) 0.14069(9) 0.0117(3) Uani 1 1 d D . . . .
H1 H 0.5890(15) 0.2890(17) 0.1360(17) 0.014 Uiso 1 1 d D U . . .
Ru3 Ru 0.72081(13) 0.35934(13) 0.21030(9) 0.0143(3) Uani 1 1 d D . . . .
Ru4 Ru 0.50789(13) 0.19199(12) 0.16803(9) 0.0134(3) Uani 1 1 d D . . . .
C1 C 0.6208(18) 0.5383(18) 0.3842(12) 0.022(4) Uani 1 1 d . U . . .
C2 C 0.5228(17) 0.3526(16) 0.3748(12) 0.017(4) Uani 1 1 d . U . . .
C3 C 0.7291(18) 0.3995(17) 0.3379(14) 0.024(5) Uani 1 1 d . U . . .
C4 C 0.371(2) 0.3708(19) 0.0954(13) 0.026(5) Uani 1 1 d . U . . .
C5 C 0.571(2) 0.440(2) 0.0791(13) 0.030(5) Uani 1 1 d . U . . .
C6 C 0.4524(18) 0.2245(16) 0.0658(12) 0.019(4) Uani 1 1 d . U . . .
C7 C 0.8665(18) 0.4778(16) 0.2413(12) 0.018(4) Uani 1 1 d . U . . .
C8 C 0.7094(18) 0.3221(19) 0.1022(13) 0.026(5) Uani 1 1 d . U . . .
C9 C 0.7754(19) 0.2599(19) 0.2231(15) 0.029(5) Uani 1 1 d . U . . .
C10 C 0.5568(17) 0.1758(16) 0.2625(12) 0.019(4) Uani 1 1 d . U . . .
C11 C 0.3662(18) 0.0845(17) 0.1298(12) 0.021(4) Uani 1 1 d . U . . .
C12 C 0.5673(19) 0.1071(18) 0.1048(14) 0.026(5) Uani 1 1 d . U . . .
O1 O 0.6477(14) 0.6191(12) 0.4365(9) 0.030(4) Uani 1 1 d . U . . .
O2 O 0.4925(12) 0.3280(12) 0.4195(8) 0.020(3) Uani 1 1 d . U . . .
O3 O 0.7952(12) 0.4094(12) 0.3903(8) 0.022(3) Uani 1 1 d . U . . .
O4 O 0.2946(14) 0.3652(15) 0.0638(9) 0.036(4) Uani 1 1 d . U . . .
O5 O 0.6044(14) 0.4763(14) 0.0384(10) 0.036(4) Uani 1 1 d . U . . .
O6 O 0.4013(14) 0.1652(11) -0.0012(9) 0.027(4) Uani 1 1 d . U . . .
O7 O 0.9495(13) 0.5362(13) 0.2593(10) 0.032(4) Uani 1 1 d . U . . .
O8 O 0.7153(14) 0.2977(16) 0.0389(10) 0.040(4) Uani 1 1 d . U . . .
O9 O 0.8055(13) 0.1982(13) 0.2276(11) 0.038(4) Uani 1 1 d . U . . .
O10 O 0.5809(13) 0.1533(12) 0.3142(9) 0.025(3) Uani 1 1 d . U . . .
O11 O 0.2799(13) 0.0092(13) 0.1035(9) 0.029(4) Uani 1 1 d . U . . .
O12 O 0.6061(14) 0.0570(13) 0.0672(10) 0.036(4) Uani 1 1 d . U . . .
P1 P 0.3602(4) 0.6113(4) 0.2518(3) 0.0149(10) Uani 1 1 d . U . . .
C101 C 0.4191(12) 0.7120(10) 0.2147(8) 0.020(3) Uani 1 1 d G U . . .
C102 C 0.4930(12) 0.7004(10) 0.1708(9) 0.029(4) Uani 1 1 d G U . . .
H102 H 0.5172 0.6445 0.1650 0.035 Uiso 1 1 calc R U . . .
C103 C 0.5315(12) 0.7705(12) 0.1354(8) 0.029(4) Uani 1 1 d G U . . .
H103 H 0.5820 0.7626 0.1054 0.035 Uiso 1 1 calc R U . . .
C104 C 0.4961(13) 0.8522(11) 0.1440(9) 0.032(4) Uani 1 1 d G U . . .
H104 H 0.5223 0.9001 0.1198 0.039 Uiso 1 1 calc R U . . .
C105 C 0.4221(13) 0.8638(10) 0.1879(9) 0.031(4) Uani 1 1 d G U . . .
H105 H 0.3979 0.9197 0.1937 0.037 Uiso 1 1 calc R U . . .
C106 C 0.3837(11) 0.7937(11) 0.2233(8) 0.023(4) Uani 1 1 d G U . . .
H106 H 0.3332 0.8017 0.2533 0.028 Uiso 1 1 calc R U . . .
C111 C 0.2238(9) 0.5331(10) 0.1829(7) 0.018(3) Uani 1 1 d G U . . .
C112 C 0.1975(11) 0.5411(11) 0.1112(8) 0.030(4) Uani 1 1 d G U . . .
H112 H 0.2499 0.5922 0.0991 0.036 Uiso 1 1 calc R U . . .
C113 C 0.0946(13) 0.4744(13) 0.0571(7) 0.038(5) Uani 1 1 d G U . . .
H113 H 0.0766 0.4799 0.0081 0.045 Uiso 1 1 calc R U . . .
C114 C 0.0180(10) 0.3996(12) 0.0747(8) 0.038(5) Uani 1 1 d G U . . .
H114 H -0.0523 0.3540 0.0378 0.045 Uiso 1 1 calc R U . . .
C115 C 0.0443(10) 0.3916(11) 0.1465(9) 0.035(4) Uani 1 1 d G U . . .
H115 H -0.0081 0.3405 0.1585 0.041 Uiso 1 1 calc R U . . .
C116 C 0.1472(12) 0.4583(11) 0.2006(7) 0.027(4) Uani 1 1 d G U . . .
H116 H 0.1651 0.4528 0.2496 0.033 Uiso 1 1 calc R U . . .
C121 C 0.3336(11) 0.6808(10) 0.3419(6) 0.016(3) Uani 1 1 d G U . . .
C122 C 0.2358(10) 0.6966(11) 0.3412(6) 0.021(4) Uani 1 1 d G U . . .
H122 H 0.1788 0.6674 0.2934 0.025 Uiso 1 1 calc R U . . .
C123 C 0.2213(9) 0.7552(11) 0.4103(7) 0.021(4) Uani 1 1 d G U . . .
H123 H 0.1544 0.7660 0.4098 0.025 Uiso 1 1 calc R U . . .
C124 C 0.3046(11) 0.7979(11) 0.4803(6) 0.024(4) Uani 1 1 d G U . . .
H124 H 0.2947 0.8379 0.5276 0.028 Uiso 1 1 calc R U . . .
C125 C 0.4025(10) 0.7821(11) 0.4811(6) 0.025(4) Uani 1 1 d G U . . .
H125 H 0.4594 0.8113 0.5289 0.030 Uiso 1 1 calc R U . . .
C126 C 0.4170(9) 0.7235(11) 0.4119(7) 0.019(4) Uani 1 1 d G U . . .
H126 H 0.4839 0.7127 0.4124 0.023 Uiso 1 1 calc R U . . .
P2 P 0.8238(4) 0.7241(4) 0.2918(3) 0.0164(11) Uani 1 1 d . U . . .
C201 C 0.9143(10) 0.7590(9) 0.3880(6) 0.017(3) Uani 1 1 d G U . . .
C202 C 0.9886(11) 0.8626(8) 0.4330(7) 0.018(4) Uani 1 1 d G U . . .
H202 H 0.9929 0.9163 0.4136 0.022 Uiso 1 1 calc R U . . .
C203 C 1.0565(10) 0.8877(7) 0.5062(7) 0.018(4) Uani 1 1 d G U . . .
H203 H 1.1072 0.9585 0.5370 0.021 Uiso 1 1 calc R U . . .
C204 C 1.0501(10) 0.8091(10) 0.5346(6) 0.020(4) Uani 1 1 d G U . . .
H204 H 1.0965 0.8263 0.5847 0.024 Uiso 1 1 calc R U . . .
C205 C 0.9758(11) 0.7055(8) 0.4897(7) 0.021(4) Uani 1 1 d G U . . .
H205 H 0.9715 0.6519 0.5090 0.025 Uiso 1 1 calc R U . . .
C206 C 0.9079(10) 0.6805(7) 0.4164(7) 0.016(3) Uani 1 1 d G U . . .
H206 H 0.8572 0.6097 0.3857 0.020 Uiso 1 1 calc R U . . .
C211 C 0.9118(10) 0.7459(12) 0.2273(7) 0.020(3) Uani 1 1 d G U . . .
C212 C 1.0270(10) 0.7968(12) 0.2542(6) 0.026(4) Uani 1 1 d G U . . .
H212 H 1.0639 0.8190 0.3079 0.031 Uiso 1 1 calc R U . . .
C213 C 1.0883(8) 0.8150(12) 0.2024(7) 0.027(4) Uani 1 1 d G U . . .
H213 H 1.1670 0.8498 0.2208 0.033 Uiso 1 1 calc R U . . .
C214 C 1.0343(11) 0.7825(13) 0.1238(7) 0.029(4) Uani 1 1 d G U . . .
H214 H 1.0762 0.7950 0.0885 0.035 Uiso 1 1 calc R U . . .
C215 C 0.9191(11) 0.7316(13) 0.0970(6) 0.034(4) Uani 1 1 d G U . . .
H215 H 0.8823 0.7094 0.0432 0.041 Uiso 1 1 calc R U . . .
C216 C 0.8579(8) 0.7133(13) 0.1487(8) 0.030(4) Uani 1 1 d G U . . .
H216 H 0.7791 0.6786 0.1303 0.036 Uiso 1 1 calc R U . . .
C221 C 0.7734(12) 0.8269(10) 0.3088(8) 0.020(3) Uani 1 1 d G U . . .
C222 C 0.6955(12) 0.8227(9) 0.3510(8) 0.026(4) Uani 1 1 d G U . . .
H222 H 0.6742 0.7690 0.3710 0.031 Uiso 1 1 calc R U . . .
C223 C 0.6489(11) 0.8971(11) 0.3640(8) 0.031(4) Uani 1 1 d G U . . .
H223 H 0.5957 0.8943 0.3929 0.037 Uiso 1 1 calc R U . . .
C224 C 0.6802(12) 0.9756(10) 0.3349(9) 0.028(4) Uani 1 1 d G U . . .
H224 H 0.6484 1.0265 0.3438 0.034 Uiso 1 1 calc R U . . .
C225 C 0.7581(13) 0.9798(10) 0.2927(9) 0.035(4) Uani 1 1 d G U . . .
H225 H 0.7794 1.0334 0.2728 0.042 Uiso 1 1 calc R U . . .
C226 C 0.8047(11) 0.9054(11) 0.2797(8) 0.034(4) Uani 1 1 d G U . . .
H226 H 0.8579 0.9082 0.2508 0.041 Uiso 1 1 calc R U . . .
P3 P 0.2095(4) 0.2200(4) 0.2647(3) 0.0145(10) Uani 1 1 d . U . . .
C301 C 0.1762(10) 0.3240(9) 0.3259(7) 0.016(3) Uani 1 1 d G U . . .
C302 C 0.0669(9) 0.3150(8) 0.3156(7) 0.022(4) Uani 1 1 d G U . . .
H302 H 0.0082 0.2528 0.2773 0.027 Uiso 1 1 calc R U . . .
C303 C 0.0435(8) 0.3968(10) 0.3614(8) 0.020(4) Uani 1 1 d G U . . .
H303 H -0.0311 0.3907 0.3544 0.024 Uiso 1 1 calc R U . . .
C304 C 0.1294(11) 0.4877(9) 0.4176(7) 0.021(4) Uani 1 1 d G U . . .
H304 H 0.1134 0.5437 0.4489 0.025 Uiso 1 1 calc R U . . .
C305 C 0.2387(9) 0.4968(8) 0.4278(7) 0.025(4) Uani 1 1 d G U . . .
H305 H 0.2974 0.5589 0.4662 0.030 Uiso 1 1 calc R U . . .
C306 C 0.2621(8) 0.4149(10) 0.3820(8) 0.020(4) Uani 1 1 d G U . . .
H306 H 0.3368 0.4211 0.3890 0.024 Uiso 1 1 calc R U . . .
C311 C 0.0843(9) 0.1320(11) 0.1857(7) 0.023(3) Uani 1 1 d G U . . .
C312 C 0.0680(10) 0.1558(10) 0.1198(8) 0.025(4) Uani 1 1 d G U . . .
H312 H 0.1249 0.2119 0.1154 0.031 Uiso 1 1 calc R U . . .
C313 C -0.0314(12) 0.0973(12) 0.0604(7) 0.036(5) Uani 1 1 d G U . . .
H313 H -0.0425 0.1135 0.0154 0.043 Uiso 1 1 calc R U . . .
C314 C -0.1145(10) 0.0151(12) 0.0668(7) 0.033(4) Uani 1 1 d G U . . .
H314 H -0.1824 -0.0249 0.0262 0.040 Uiso 1 1 calc R U . . .
C315 C -0.0983(11) -0.0087(11) 0.1327(8) 0.034(4) Uani 1 1 d G U . . .
H315 H -0.1551 -0.0649 0.1371 0.041 Uiso 1 1 calc R U . . .
C316 C 0.0011(12) 0.0498(12) 0.1921(7) 0.028(4) Uani 1 1 d G U . . .
H316 H 0.0122 0.0335 0.2371 0.033 Uiso 1 1 calc R U . . .
C321 C 0.2289(11) 0.1464(10) 0.3257(7) 0.017(3) Uani 1 1 d G U . . .
C322 C 0.2918(11) 0.0866(11) 0.3098(7) 0.020(4) Uani 1 1 d G U . . .
H322 H 0.3214 0.0812 0.2663 0.024 Uiso 1 1 calc R U . . .
C323 C 0.3114(11) 0.0346(10) 0.3575(8) 0.022(4) Uani 1 1 d G U . . .
H323 H 0.3544 -0.0063 0.3467 0.027 Uiso 1 1 calc R U . . .
C324 C 0.2681(12) 0.0424(11) 0.4212(7) 0.027(4) Uani 1 1 d G U . . .
H324 H 0.2815 0.0068 0.4538 0.032 Uiso 1 1 calc R U . . .
C325 C 0.2052(12) 0.1022(12) 0.4371(7) 0.026(4) Uani 1 1 d G U . . .
H325 H 0.1755 0.1075 0.4806 0.031 Uiso 1 1 calc R U . . .
C326 C 0.1855(11) 0.1542(11) 0.3893(8) 0.027(4) Uani 1 1 d G U . . .
H326 H 0.1425 0.1951 0.4002 0.033 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 P1 2.286(5) . ?
Au1 Ru2 2.8168(17) . ?
Au1 Ru1 2.8201(17) . ?
Au1 Au3 2.9247(11) . ?
Au1 Au2 2.9515(12) . ?
Au2 P2 2.311(5) . ?
Au2 Ru1 2.7984(18) . ?
Au2 Ru2 2.8069(18) . ?
Au2 Ru3 2.9022(18) . ?
Au3 P3 2.304(5) . ?
Au3 Ru1 2.7637(18) . ?
Au3 Ru4 2.8242(18) . ?
Au3 Ru2 2.8715(18) . ?
Ru1 C1 1.86(2) . ?
Ru1 C2 1.90(2) . ?
Ru1 C3 1.95(2) . ?
Ru1 Ru3 2.796(2) . ?
Ru1 Ru2 2.914(2) . ?
Ru1 Ru4 3.090(2) . ?
Ru2 C5 1.90(2) . ?
Ru2 C4 1.91(2) . ?
Ru2 C6 1.93(2) . ?
Ru2 Ru4 2.770(2) . ?
Ru2 Ru3 2.985(2) . ?
Ru2 H1 1.80(2) . ?
Ru3 C9 1.88(3) . ?
Ru3 C8 1.89(2) . ?
Ru3 C7 1.97(2) . ?
Ru3 C3 2.25(2) . ?
Ru3 Ru4 2.855(2) . ?
Ru3 H1 1.80(2) . ?
Ru4 C11 1.86(2) . ?
Ru4 C12 1.88(2) . ?
Ru4 C10 1.91(2) . ?
Ru4 C6 2.20(2) . ?
Ru4 H1 1.80(2) . ?
C1 O1 1.17(3) . ?
C2 O2 1.09(2) . ?
C3 O3 1.15(3) . ?
C4 O4 1.06(3) . ?
C5 O5 1.12(3) . ?
C6 O6 1.21(3) . ?
C7 O7 1.07(3) . ?
C8 O8 1.15(3) . ?
C9 O9 1.12(3) . ?
C10 O10 1.15(3) . ?
C11 O11 1.19(3) . ?
C12 O12 1.15(3) . ?
P1 C111 1.807(11) . ?
P1 C101 1.817(11) . ?
P1 C121 1.829(10) . ?
C101 C102 1.3900 . ?
C101 C106 1.3900 . ?
C102 C103 1.3900 . ?
C102 H102 0.9500 . ?
C103 C104 1.3900 . ?
C103 H103 0.9500 . ?
C104 C105 1.3900 . ?
C104 H104 0.9500 . ?
C105 C106 1.3900 . ?
C105 H105 0.9500 . ?
C106 H106 0.9500 . ?
C111 C112 1.3900 . ?
C111 C116 1.3900 . ?
C112 C113 1.3900 . ?
C112 H112 0.9500 . ?
C113 C114 1.3900 . ?
C113 H113 0.9500 . ?
C114 C115 1.3900 . ?
C114 H114 0.9500 . ?
C115 C116 1.3900 . ?
C115 H115 0.9500 . ?
C116 H116 0.9500 . ?
C121 C122 1.3900 . ?
C121 C126 1.3900 . ?
C122 C123 1.3900 . ?
C122 H122 0.9500 . ?
C123 C124 1.3900 . ?
C123 H123 0.9500 . ?
C124 C125 1.3900 . ?
C124 H124 0.9500 . ?
C125 C126 1.3900 . ?
C125 H125 0.9500 . ?
C126 H126 0.9500 . ?
P2 C221 1.790(11) . ?
P2 C201 1.826(10) . ?
P2 C211 1.830(11) . ?
C201 C202 1.3900 . ?
C201 C206 1.3900 . ?
C202 C203 1.3900 . ?
C202 H202 0.9500 . ?
C203 C204 1.3900 . ?
C203 H203 0.9500 . ?
C204 C205 1.3900 . ?
C204 H204 0.9500 . ?
C205 C206 1.3900 . ?
C205 H205 0.9500 . ?
C206 H206 0.9500 . ?
C211 C212 1.3900 . ?
C211 C216 1.3900 . ?
C212 C213 1.3900 . ?
C212 H212 0.9500 . ?
C213 C214 1.3900 . ?
C213 H213 0.9500 . ?
C214 C215 1.3900 . ?
C214 H214 0.9500 . ?
C215 C216 1.3900 . ?
C215 H215 0.9500 . ?
C216 H216 0.9500 . ?
C221 C222 1.3900 . ?
C221 C226 1.3900 . ?
C222 C223 1.3900 . ?
C222 H222 0.9500 . ?
C223 C224 1.3900 . ?
C223 H223 0.9500 . ?
C224 C225 1.3900 . ?
C224 H224 0.9500 . ?
C225 C226 1.3900 . ?
C225 H225 0.9500 . ?
C226 H226 0.9500 . ?
P3 C311 1.808(11) . ?
P3 C301 1.817(10) . ?
P3 C321 1.842(11) . ?
C301 C302 1.3900 . ?
C301 C306 1.3900 . ?
C302 C303 1.3900 . ?
C302 H302 0.9500 . ?
C303 C304 1.3900 . ?
C303 H303 0.9500 . ?
C304 C305 1.3900 . ?
C304 H304 0.9500 . ?
C305 C306 1.3900 . ?
C305 H305 0.9500 . ?
C306 H306 0.9500 . ?
C311 C312 1.3900 . ?
C311 C316 1.3900 . ?
C312 C313 1.3900 . ?
C312 H312 0.9500 . ?
C313 C314 1.3900 . ?
C313 H313 0.9500 . ?
C314 C315 1.3900 . ?
C314 H314 0.9500 . ?
C315 C316 1.3900 . ?
C315 H315 0.9500 . ?
C316 H316 0.9500 . ?
C321 C322 1.3900 . ?
C321 C326 1.3900 . ?
C322 C323 1.3900 . ?
C322 H322 0.9500 . ?
C323 C324 1.3900 . ?
C323 H323 0.9500 . ?
C324 C325 1.3900 . ?
C324 H324 0.9500 . ?
C325 C326 1.3900 . ?
C325 H325 0.9500 . ?
C326 H326 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Au1 Ru2 132.48(14) . . ?
P1 Au1 Ru1 165.23(14) . . ?
Ru2 Au1 Ru1 62.26(5) . . ?
P1 Au1 Au3 125.38(14) . . ?
Ru2 Au1 Au3 59.98(4) . . ?
Ru1 Au1 Au3 57.48(4) . . ?
P1 Au1 Au2 127.32(14) . . ?
Ru2 Au1 Au2 58.18(4) . . ?
Ru1 Au1 Au2 57.95(4) . . ?
Au3 Au1 Au2 104.47(3) . . ?
P2 Au2 Ru1 137.14(14) . . ?
P2 Au2 Ru2 159.56(14) . . ?
Ru1 Au2 Ru2 62.65(5) . . ?
P2 Au2 Ru3 127.44(14) . . ?
Ru1 Au2 Ru3 58.70(5) . . ?
Ru2 Au2 Ru3 63.02(5) . . ?
P2 Au2 Au1 122.38(14) . . ?
Ru1 Au2 Au1 58.67(4) . . ?
Ru2 Au2 Au1 58.51(4) . . ?
Ru3 Au2 Au1 107.57(4) . . ?
P3 Au3 Ru1 133.59(14) . . ?
P3 Au3 Ru4 131.28(13) . . ?
Ru1 Au3 Ru4 67.14(5) . . ?
P3 Au3 Ru2 161.92(14) . . ?
Ru1 Au3 Ru2 62.24(5) . . ?
Ru4 Au3 Ru2 58.19(5) . . ?
P3 Au3 Au1 118.46(13) . . ?
Ru1 Au3 Au1 59.36(4) . . ?
Ru4 Au3 Au1 109.70(4) . . ?
Ru2 Au3 Au1 58.14(4) . . ?
C1 Ru1 C2 84.3(9) . . ?
C1 Ru1 C3 96.5(9) . . ?
C2 Ru1 C3 95.2(9) . . ?
C1 Ru1 Au3 117.1(7) . . ?
C2 Ru1 Au3 73.8(6) . . ?
C3 Ru1 Au3 142.6(6) . . ?
C1 Ru1 Ru3 126.0(7) . . ?
C2 Ru1 Ru3 134.6(6) . . ?
C3 Ru1 Ru3 53.2(7) . . ?
Au3 Ru1 Ru3 110.20(6) . . ?
C1 Ru1 Au2 75.7(7) . . ?
C2 Ru1 Au2 159.8(6) . . ?
C3 Ru1 Au2 89.4(7) . . ?
Au3 Ru1 Au2 113.27(6) . . ?
Ru3 Ru1 Au2 62.50(5) . . ?
C1 Ru1 Au1 69.2(6) . . ?
C2 Ru1 Au1 107.4(6) . . ?
C3 Ru1 Au1 151.3(7) . . ?
Au3 Ru1 Au1 63.16(4) . . ?
Ru3 Ru1 Au1 114.49(7) . . ?
Au2 Ru1 Au1 63.38(4) . . ?
C1 Ru1 Ru2 121.5(6) . . ?
C2 Ru1 Ru2 133.9(6) . . ?
C3 Ru1 Ru2 116.2(7) . . ?
Au3 Ru1 Ru2 60.69(5) . . ?
Ru3 Ru1 Ru2 63.00(6) . . ?
Au2 Ru1 Ru2 58.82(5) . . ?
Au1 Ru1 Ru2 58.82(5) . . ?
C1 Ru1 Ru4 174.1(6) . . ?
C2 Ru1 Ru4 95.6(6) . . ?
C3 Ru1 Ru4 89.4(6) . . ?
Au3 Ru1 Ru4 57.37(4) . . ?
Ru3 Ru1 Ru4 57.77(5) . . ?
Au2 Ru1 Ru4 104.12(6) . . ?
Au1 Ru1 Ru4 105.29(6) . . ?
Ru2 Ru1 Ru4 54.85(5) . . ?
C5 Ru2 C4 86.6(11) . . ?
C5 Ru2 C6 99.8(10) . . ?
C4 Ru2 C6 86.8(9) . . ?
C5 Ru2 Ru4 135.7(8) . . ?
C4 Ru2 Ru4 119.6(7) . . ?
C6 Ru2 Ru4 52.1(6) . . ?
C5 Ru2 Au2 73.1(7) . . ?
C4 Ru2 Au2 121.1(7) . . ?
C6 Ru2 Au2 149.9(7) . . ?
Ru4 Ru2 Au2 112.90(6) . . ?
C5 Ru2 Au1 107.1(8) . . ?
C4 Ru2 Au1 71.8(7) . . ?
C6 Ru2 Au1 144.1(7) . . ?
Ru4 Ru2 Au1 114.59(7) . . ?
Au2 Ru2 Au1 63.31(4) . . ?
C5 Ru2 Au3 162.6(8) . . ?
C4 Ru2 Au3 77.2(7) . . ?
C6 Ru2 Au3 85.9(6) . . ?
Ru4 Ru2 Au3 60.05(5) . . ?
Au2 Ru2 Au3 109.78(6) . . ?
Au1 Ru2 Au3 61.87(4) . . ?
C5 Ru2 Ru1 131.0(7) . . ?
C4 Ru2 Ru1 123.6(7) . . ?
C6 Ru2 Ru1 117.7(6) . . ?
Ru4 Ru2 Ru1 65.81(6) . . ?
Au2 Ru2 Ru1 58.53(5) . . ?
Au1 Ru2 Ru1 58.93(5) . . ?
Au3 Ru2 Ru1 57.06(5) . . ?
C5 Ru2 Ru3 94.0(8) . . ?
C4 Ru2 Ru3 178.8(7) . . ?
C6 Ru2 Ru3 92.1(6) . . ?
Ru4 Ru2 Ru3 59.35(5) . . ?
Au2 Ru2 Ru3 60.05(5) . . ?
Au1 Ru2 Ru3 108.95(6) . . ?
Au3 Ru2 Ru3 102.24(6) . . ?
Ru1 Ru2 Ru3 56.56(5) . . ?
C5 Ru2 H1 97.9(11) . . ?
C4 Ru2 H1 144.8(10) . . ?
C6 Ru2 H1 58.1(10) . . ?
Ru4 Ru2 H1 39.8(7) . . ?
Au2 Ru2 H1 93.3(7) . . ?
Au1 Ru2 H1 137.5(9) . . ?
Au3 Ru2 H1 99.0(7) . . ?
Ru1 Ru2 H1 78.7(9) . . ?
Ru3 Ru2 H1 34.1(7) . . ?
C9 Ru3 C8 96.7(11) . . ?
C9 Ru3 C7 96.9(9) . . ?
C8 Ru3 C7 92.7(9) . . ?
C9 Ru3 C3 83.1(9) . . ?
C8 Ru3 C3 178.2(9) . . ?
C7 Ru3 C3 89.1(8) . . ?
C9 Ru3 Ru1 115.5(7) . . ?
C8 Ru3 Ru1 135.2(7) . . ?
C7 Ru3 Ru1 112.2(6) . . ?
C3 Ru3 Ru1 43.8(6) . . ?
C9 Ru3 Ru4 84.2(7) . . ?
C8 Ru3 Ru4 88.3(7) . . ?
C7 Ru3 Ru4 178.4(6) . . ?
C3 Ru3 Ru4 89.9(6) . . ?
Ru1 Ru3 Ru4 66.30(6) . . ?
C9 Ru3 Au2 160.3(8) . . ?
C8 Ru3 Au2 99.3(8) . . ?
C7 Ru3 Au2 70.9(6) . . ?
C3 Ru3 Au2 81.3(5) . . ?
Ru1 Ru3 Au2 58.80(5) . . ?
Ru4 Ru3 Au2 107.65(6) . . ?
C9 Ru3 Ru2 139.6(7) . . ?
C8 Ru3 Ru2 74.8(7) . . ?
C7 Ru3 Ru2 122.5(6) . . ?
C3 Ru3 Ru2 104.2(6) . . ?
Ru1 Ru3 Ru2 60.44(5) . . ?
Ru4 Ru3 Ru2 56.57(5) . . ?
Au2 Ru3 Ru2 56.93(4) . . ?
C9 Ru3 H1 108.1(10) . . ?
C8 Ru3 H1 57.6(11) . . ?
C7 Ru3 H1 142.4(9) . . ?
C3 Ru3 H1 120.7(11) . . ?
Ru1 Ru3 H1 82.2(9) . . ?
Ru4 Ru3 H1 37.6(7) . . ?
Au2 Ru3 H1 90.3(7) . . ?
Ru2 Ru3 H1 34.2(8) . . ?
C11 Ru4 C12 92.8(9) . . ?
C11 Ru4 C10 98.8(9) . . ?
C12 Ru4 C10 97.5(10) . . ?
C11 Ru4 C6 83.4(9) . . ?
C12 Ru4 C6 87.1(9) . . ?
C10 Ru4 C6 174.8(8) . . ?
C11 Ru4 Ru2 111.6(7) . . ?
C12 Ru4 Ru2 117.3(7) . . ?
C10 Ru4 Ru2 131.2(6) . . ?
C6 Ru4 Ru2 43.8(5) . . ?
C11 Ru4 Au3 73.8(6) . . ?
C12 Ru4 Au3 163.8(7) . . ?
C10 Ru4 Au3 93.6(6) . . ?
C6 Ru4 Au3 82.4(6) . . ?
Ru2 Ru4 Au3 61.76(5) . . ?
C11 Ru4 Ru3 173.6(7) . . ?
C12 Ru4 Ru3 85.5(7) . . ?
C10 Ru4 Ru3 87.5(7) . . ?
C6 Ru4 Ru3 90.4(6) . . ?
Ru2 Ru4 Ru3 64.08(6) . . ?
Au3 Ru4 Ru3 106.80(6) . . ?
C11 Ru4 Ru1 126.9(6) . . ?
C12 Ru4 Ru1 139.7(7) . . ?
C10 Ru4 Ru1 71.9(6) . . ?
C6 Ru4 Ru1 103.0(5) . . ?
Ru2 Ru4 Ru1 59.34(5) . . ?
Au3 Ru4 Ru1 55.50(4) . . ?
Ru3 Ru4 Ru1 55.93(5) . . ?
C11 Ru4 H1 136.1(10) . . ?
C12 Ru4 H1 82.5(11) . . ?
C10 Ru4 H1 125.1(10) . . ?
C6 Ru4 H1 52.9(9) . . ?
Ru2 Ru4 H1 39.9(7) . . ?
Au3 Ru4 H1 100.7(8) . . ?
Ru3 Ru4 H1 37.6(7) . . ?
Ru1 Ru4 H1 73.8(9) . . ?
O1 C1 Ru1 175.3(18) . . ?
O2 C2 Ru1 174.1(19) . . ?
O3 C3 Ru1 144.8(19) . . ?
O3 C3 Ru3 132.1(17) . . ?
Ru1 C3 Ru3 83.1(8) . . ?
O4 C4 Ru2 173(2) . . ?
O5 C5 Ru2 175(2) . . ?
O6 C6 Ru2 144.9(16) . . ?
O6 C6 Ru4 130.6(15) . . ?
Ru2 C6 Ru4 84.1(8) . . ?
O7 C7 Ru3 173.5(19) . . ?
O8 C8 Ru3 171(2) . . ?
O9 C9 Ru3 177(2) . . ?
O10 C10 Ru4 171.8(18) . . ?
O11 C11 Ru4 174.0(19) . . ?
O12 C12 Ru4 178(2) . . ?
C111 P1 C101 102.6(7) . . ?
C111 P1 C121 104.3(7) . . ?
C101 P1 C121 104.9(7) . . ?
C111 P1 Au1 111.5(5) . . ?
C101 P1 Au1 114.0(5) . . ?
C121 P1 Au1 118.0(5) . . ?
C102 C101 C106 120.0 . . ?
C102 C101 P1 118.5(8) . . ?
C106 C101 P1 121.2(8) . . ?
C101 C102 C103 120.0 . . ?
C101 C102 H102 120.0 . . ?
C103 C102 H102 120.0 . . ?
C104 C103 C102 120.0 . . ?
C104 C103 H103 120.0 . . ?
C102 C103 H103 120.0 . . ?
C105 C104 C103 120.0 . . ?
C105 C104 H104 120.0 . . ?
C103 C104 H104 120.0 . . ?
C104 C105 C106 120.0 . . ?
C104 C105 H105 120.0 . . ?
C106 C105 H105 120.0 . . ?
C105 C106 C101 120.0 . . ?
C105 C106 H106 120.0 . . ?
C101 C106 H106 120.0 . . ?
C112 C111 C116 120.0 . . ?
C112 C111 P1 121.4(8) . . ?
C116 C111 P1 118.5(8) . . ?
C113 C112 C111 120.0 . . ?
C113 C112 H112 120.0 . . ?
C111 C112 H112 120.0 . . ?
C114 C113 C112 120.0 . . ?
C114 C113 H113 120.0 . . ?
C112 C113 H113 120.0 . . ?
C113 C114 C115 120.0 . . ?
C113 C114 H114 120.0 . . ?
C115 C114 H114 120.0 . . ?
C116 C115 C114 120.0 . . ?
C116 C115 H115 120.0 . . ?
C114 C115 H115 120.0 . . ?
C115 C116 C111 120.0 . . ?
C115 C116 H116 120.0 . . ?
C111 C116 H116 120.0 . . ?
C122 C121 C126 120.0 . . ?
C122 C121 P1 121.7(7) . . ?
C126 C121 P1 118.2(7) . . ?
C123 C122 C121 120.0 . . ?
C123 C122 H122 120.0 . . ?
C121 C122 H122 120.0 . . ?
C122 C123 C124 120.0 . . ?
C122 C123 H123 120.0 . . ?
C124 C123 H123 120.0 . . ?
C123 C124 C125 120.0 . . ?
C123 C124 H124 120.0 . . ?
C125 C124 H124 120.0 . . ?
C126 C125 C124 120.0 . . ?
C126 C125 H125 120.0 . . ?
C124 C125 H125 120.0 . . ?
C125 C126 C121 120.0 . . ?
C125 C126 H126 120.0 . . ?
C121 C126 H126 120.0 . . ?
C221 P2 C201 102.8(7) . . ?
C221 P2 C211 104.8(7) . . ?
C201 P2 C211 107.9(7) . . ?
C221 P2 Au2 115.3(5) . . ?
C201 P2 Au2 111.7(5) . . ?
C211 P2 Au2 113.6(5) . . ?
C202 C201 C206 120.0 . . ?
C202 C201 P2 120.8(7) . . ?
C206 C201 P2 119.2(7) . . ?
C203 C202 C201 120.0 . . ?
C203 C202 H202 120.0 . . ?
C201 C202 H202 120.0 . . ?
C204 C203 C202 120.0 . . ?
C204 C203 H203 120.0 . . ?
C202 C203 H203 120.0 . . ?
C203 C204 C205 120.0 . . ?
C203 C204 H204 120.0 . . ?
C205 C204 H204 120.0 . . ?
C206 C205 C204 120.0 . . ?
C206 C205 H205 120.0 . . ?
C204 C205 H205 120.0 . . ?
C205 C206 C201 120.0 . . ?
C205 C206 H206 120.0 . . ?
C201 C206 H206 120.0 . . ?
C212 C211 C216 120.0 . . ?
C212 C211 P2 123.1(8) . . ?
C216 C211 P2 116.8(8) . . ?
C211 C212 C213 120.0 . . ?
C211 C212 H212 120.0 . . ?
C213 C212 H212 120.0 . . ?
C212 C213 C214 120.0 . . ?
C212 C213 H213 120.0 . . ?
C214 C213 H213 120.0 . . ?
C213 C214 C215 120.0 . . ?
C213 C214 H214 120.0 . . ?
C215 C214 H214 120.0 . . ?
C216 C215 C214 120.0 . . ?
C216 C215 H215 120.0 . . ?
C214 C215 H215 120.0 . . ?
C215 C216 C211 120.0 . . ?
C215 C216 H216 120.0 . . ?
C211 C216 H216 120.0 . . ?
C222 C221 C226 120.0 . . ?
C222 C221 P2 116.4(8) . . ?
C226 C221 P2 123.5(8) . . ?
C221 C222 C223 120.0 . . ?
C221 C222 H222 120.0 . . ?
C223 C222 H222 120.0 . . ?
C224 C223 C222 120.0 . . ?
C224 C223 H223 120.0 . . ?
C222 C223 H223 120.0 . . ?
C223 C224 C225 120.0 . . ?
C223 C224 H224 120.0 . . ?
C225 C224 H224 120.0 . . ?
C226 C225 C224 120.0 . . ?
C226 C225 H225 120.0 . . ?
C224 C225 H225 120.0 . . ?
C225 C226 C221 120.0 . . ?
C225 C226 H226 120.0 . . ?
C221 C226 H226 120.0 . . ?
C311 P3 C301 106.0(7) . . ?
C311 P3 C321 106.1(7) . . ?
C301 P3 C321 104.4(7) . . ?
C311 P3 Au3 115.0(5) . . ?
C301 P3 Au3 112.4(5) . . ?
C321 P3 Au3 112.1(5) . . ?
C302 C301 C306 120.0 . . ?
C302 C301 P3 120.9(7) . . ?
C306 C301 P3 119.1(7) . . ?
C303 C302 C301 120.0 . . ?
C303 C302 H302 120.0 . . ?
C301 C302 H302 120.0 . . ?
C302 C303 C304 120.0 . . ?
C302 C303 H303 120.0 . . ?
C304 C303 H303 120.0 . . ?
C305 C304 C303 120.0 . . ?
C305 C304 H304 120.0 . . ?
C303 C304 H304 120.0 . . ?
C306 C305 C304 120.0 . . ?
C306 C305 H305 120.0 . . ?
C304 C305 H305 120.0 . . ?
C305 C306 C301 120.0 . . ?
C305 C306 H306 120.0 . . ?
C301 C306 H306 120.0 . . ?
C312 C311 C316 120.0 . . ?
C312 C311 P3 117.3(8) . . ?
C316 C311 P3 122.4(8) . . ?
C313 C312 C311 120.0 . . ?
C313 C312 H312 120.0 . . ?
C311 C312 H312 120.0 . . ?
C312 C313 C314 120.0 . . ?
C312 C313 H313 120.0 . . ?
C314 C313 H313 120.0 . . ?
C313 C314 C315 120.0 . . ?
C313 C314 H314 120.0 . . ?
C315 C314 H314 120.0 . . ?
C316 C315 C314 120.0 . . ?
C316 C315 H315 120.0 . . ?
C314 C315 H315 120.0 . . ?
C315 C316 C311 120.0 . . ?
C315 C316 H316 120.0 . . ?
C311 C316 H316 120.0 . . ?
C322 C321 C326 120.0 . . ?
C322 C321 P3 119.4(7) . . ?
C326 C321 P3 120.6(7) . . ?
C321 C322 C323 120.0 . . ?
C321 C322 H322 120.0 . . ?
C323 C322 H322 120.0 . . ?
C324 C323 C322 120.0 . . ?
C324 C323 H323 120.0 . . ?
C322 C323 H323 120.0 . . ?
C323 C324 C325 120.0 . . ?
C323 C324 H324 120.0 . . ?
C325 C324 H324 120.0 . . ?
C324 C325 C326 120.0 . . ?
C324 C325 H325 120.0 . . ?
C326 C325 H325 120.0 . . ?
C325 C326 C321 120.0 . . ?
C325 C326 H326 120.0 . . ?
C321 C326 H326 120.0 . . ?

_refine_diff_density_max         3.419
_refine_diff_density_min         -4.098
_refine_diff_density_rms         0.389

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_5solv
_database_code_depnum_ccdc_archive 'CCDC 2305343'
loop_
_audit_author_name
_audit_author_address
'Stefano Zacchini'
;Universita di Bologna
Italy
;
_audit_update_record             
;
2023-11-02 deposited with the CCDC.	2024-01-18 downloaded from the CCDC.
;
# start Validation Reply Form
_vrf_PLAT971_5solv               
;
PROBLEM:  Check Calcd Resid. Dens
RESPONSE: This alert is due to high values for 
the residual electron density. This maximum is located close
to the cluster core, in a position which is not realistic for 
any atom, and this is a series termination error, 
common with heavy atoms.
;
_vrf_PLAT972_5solv               
;
PROBLEM:  Check Calcd Resid. Dens
RESPONSE: This alert is due to high values for 
the residual electron density. This maximum is located close
to the cluster core, in a position which is not realistic for 
any atom, and this is a series termination error, 
common with heavy atoms.
;
_vrf_PLAT342_5solv               
;
PROBLEM: Low Bond Precision on  C-C Bonds
RESPONSE: This alert refers to some Ph groups of the PPh3
ligands, which display some minor disorder, which has 
not been possible to model. 
;
# end Validation Reply Form    
_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C84 H60 Au4 O12 P4 Ru4'
_chemical_formula_weight         2577.34

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   21.680(12)
_cell_length_b                   15.264(9)
_cell_length_c                   28.654(17)
_cell_angle_alpha                90
_cell_angle_beta                 92.504(15)
_cell_angle_gamma                90
_cell_volume                     9473(9)
_cell_formula_units_Z            4
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    9771
_cell_measurement_theta_min      2.192
_cell_measurement_theta_max      27.216

_exptl_crystal_description       prism
_exptl_crystal_colour            brown
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.807
_exptl_crystal_F_000             4848
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.150
_exptl_crystal_size_mid          0.140
_exptl_crystal_size_min          0.100
_exptl_absorpt_coefficient_mu    6.908
_shelx_estimated_absorpt_T_min   0.424
_shelx_estimated_absorpt_T_max   0.545
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_correction_T_min  0.0390
_exptl_absorpt_correction_T_max  0.1363
_exptl_absorpt_process_details   
;
 Data were corrected for Lorentz polarization and absorption
 effects (empirical absorption corrections SADABS).
 R(int) = 0.1693 (selected reflections only, before parameter refinement)
 R(int) = 0.1010 (selected reflections only, after parameter refinement)
;
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'fine-focus sealed tube'
_diffrn_measurement_device_type  'PHOTON2 area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            51811
_diffrn_reflns_av_unetI/netI     0.0876
_diffrn_reflns_av_R_equivalents  0.0902
_diffrn_reflns_limit_h_min       -25
_diffrn_reflns_limit_h_max       25
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_l_min       -34
_diffrn_reflns_limit_l_max       31
_diffrn_reflns_theta_min         1.512
_diffrn_reflns_theta_max         25.000
_diffrn_reflns_theta_full        25.000
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measured_fraction_theta_full 0.994
_diffrn_reflns_Laue_measured_fraction_max 0.994
_diffrn_reflns_Laue_measured_fraction_full 0.994
_diffrn_reflns_point_group_measured_fraction_max 0.994
_diffrn_reflns_point_group_measured_fraction_full 0.994
_reflns_number_total             16593
_reflns_number_gt                13261
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'APEX2 (Bruker AXS, 2006)'
_computing_cell_refinement       'APEX2 (Bruker AXS, 2006)'
_computing_data_reduction        'SAINT (Bruker AXS, 2004)'
_computing_structure_solution    'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    'SCHAKAL99 (Keller, 1999)'
_computing_publication_material  'XCIF (Bruker AXS, 2001)'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0851P)²+150.7820P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         16593
_refine_ls_number_parameters     973
_refine_ls_number_restraints     438
_refine_ls_R_factor_all          0.0853
_refine_ls_R_factor_gt           0.0683
_refine_ls_wR_factor_ref         0.1826
_refine_ls_wR_factor_gt          0.1711
_refine_ls_goodness_of_fit_ref   1.041
_refine_ls_restrained_S_all      1.029
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.27281(2) 0.35900(3) 0.27195(2) 0.02657(14) Uani 1 1 d . . . . .
Au2 Au 0.27798(2) 0.22550(3) 0.20038(2) 0.03020(14) Uani 1 1 d . . . . .
Au3 Au 0.35258(2) 0.33652(4) 0.35451(2) 0.03018(14) Uani 1 1 d . . . . .
Au4 Au 0.29585(2) 0.51657(3) 0.22206(2) 0.03214(15) Uani 1 1 d . . . . .
P1 P 0.17097(15) 0.3760(2) 0.29212(13) 0.0281(7) Uani 1 1 d . . . . .
P2 P 0.20797(16) 0.1274(2) 0.16528(13) 0.0318(8) Uani 1 1 d . . . . .
P3 P 0.34809(18) 0.3303(3) 0.43588(13) 0.0356(8) Uani 1 1 d . . . . .
P4 P 0.25157(17) 0.6442(2) 0.19188(15) 0.0345(8) Uani 1 1 d . . . . .
Ru1 Ru 0.47669(5) 0.34085(8) 0.23344(4) 0.0317(3) Uani 1 1 d . . . . .
Ru2 Ru 0.39162(5) 0.44978(7) 0.28229(4) 0.0247(2) Uani 1 1 d . . . . .
Ru3 Ru 0.35760(5) 0.36735(7) 0.18600(4) 0.0262(2) Uani 1 1 d . . . . .
Ru4 Ru 0.37604(5) 0.24139(7) 0.27113(4) 0.0248(2) Uani 1 1 d . . . . .
C1 C 0.5126(7) 0.2532(12) 0.1927(6) 0.045(4) Uani 1 1 d . . . . .
C2 C 0.5267(7) 0.4326(10) 0.2082(6) 0.042(4) Uani 1 1 d . . . . .
C3 C 0.5328(7) 0.3174(12) 0.2863(6) 0.049(4) Uani 1 1 d . . . . .
C4 C 0.3425(6) 0.5283(9) 0.3193(5) 0.034(3) Uani 1 1 d . . . . .
C5 C 0.4278(6) 0.5451(9) 0.2490(5) 0.032(3) Uani 1 1 d . . . . .
C6 C 0.4585(7) 0.4511(9) 0.3282(5) 0.034(3) Uani 1 1 d . . . . .
C7 C 0.2814(7) 0.4020(10) 0.1506(5) 0.039(4) Uani 1 1 d . . . . .
C8 C 0.4078(6) 0.4489(10) 0.1535(5) 0.033(3) Uani 1 1 d . . . . .
C9 C 0.3795(7) 0.2788(8) 0.1443(5) 0.034(3) Uani 1 1 d . . . . .
C10 C 0.4067(6) 0.1543(9) 0.2307(5) 0.031(3) Uani 1 1 d . . . . .
C11 C 0.4333(7) 0.2084(11) 0.3202(5) 0.042(4) Uani 1 1 d . . . . .
C12 C 0.3134(6) 0.1672(9) 0.2941(5) 0.033(3) Uani 1 1 d . . . . .
O1 O 0.5339(6) 0.2058(9) 0.1698(5) 0.069(4) Uani 1 1 d . . . . .
O2 O 0.5576(6) 0.4854(8) 0.1966(5) 0.059(3) Uani 1 1 d . . . . .
O3 O 0.5642(5) 0.3061(9) 0.3181(5) 0.061(3) Uani 1 1 d . . . . .
O4 O 0.3246(6) 0.5796(8) 0.3435(4) 0.056(3) Uani 1 1 d . . . . .
O5 O 0.4475(5) 0.6044(7) 0.2318(4) 0.047(3) Uani 1 1 d . . . . .
O6 O 0.4965(5) 0.4620(8) 0.3576(4) 0.050(3) Uani 1 1 d . . . . .
O7 O 0.2440(5) 0.4189(7) 0.1230(4) 0.045(3) Uani 1 1 d . . . . .
O8 O 0.4347(5) 0.4936(7) 0.1306(4) 0.051(3) Uani 1 1 d . . . . .
O9 O 0.3946(6) 0.2305(8) 0.1164(4) 0.054(3) Uani 1 1 d . . . . .
O10 O 0.4233(5) 0.0955(7) 0.2096(4) 0.046(3) Uani 1 1 d . . . . .
O11 O 0.4665(5) 0.1790(8) 0.3497(4) 0.052(3) Uani 1 1 d . . . . .
O12 O 0.2834(6) 0.1152(7) 0.3096(4) 0.058(3) Uani 1 1 d . . . . .
C101 C 0.1504(6) 0.3041(10) 0.3395(5) 0.033(3) Uani 1 1 d . U . . .
C102 C 0.1263(9) 0.3320(11) 0.3808(6) 0.052(4) Uani 1 1 d . U . . .
H102 H 0.1222 0.3932 0.3859 0.062 Uiso 1 1 calc R U . . .
C103 C 0.1082(10) 0.2753(14) 0.4146(7) 0.066(5) Uani 1 1 d . U . . .
H103 H 0.0896 0.2976 0.4415 0.079 Uiso 1 1 calc R U . . .
C104 C 0.1166(9) 0.1860(14) 0.4098(7) 0.067(5) Uani 1 1 d . U . . .
H104 H 0.1062 0.1463 0.4337 0.080 Uiso 1 1 calc R U . . .
C105 C 0.1402(9) 0.1572(12) 0.3697(7) 0.056(5) Uani 1 1 d . U . . .
H105 H 0.1455 0.0960 0.3654 0.067 Uiso 1 1 calc R U . . .
C106 C 0.1574(8) 0.2147(12) 0.3340(7) 0.054(4) Uani 1 1 d . U . . .
H106 H 0.1736 0.1920 0.3062 0.065 Uiso 1 1 calc R U . . .
C107 C 0.1128(5) 0.3516(8) 0.2452(4) 0.022(3) Uani 1 1 d . U . . .
C108 C 0.1266(7) 0.3585(8) 0.1987(5) 0.036(3) Uani 1 1 d . U . . .
H108 H 0.1680 0.3700 0.1910 0.043 Uiso 1 1 calc R U . . .
C109 C 0.0817(7) 0.3492(9) 0.1627(5) 0.037(3) Uani 1 1 d . U . . .
H109 H 0.0920 0.3562 0.1311 0.044 Uiso 1 1 calc R U . . .
C110 C 0.0225(7) 0.3297(10) 0.1737(6) 0.045(4) Uani 1 1 d . U . . .
H110 H -0.0080 0.3218 0.1493 0.054 Uiso 1 1 calc R U . . .
C111 C 0.0062(7) 0.3214(9) 0.2196(6) 0.045(4) Uani 1 1 d . U . . .
H111 H -0.0353 0.3083 0.2266 0.054 Uiso 1 1 calc R U . . .
C112 C 0.0517(6) 0.3325(8) 0.2560(5) 0.029(3) Uani 1 1 d . U . . .
H112 H 0.0410 0.3269 0.2876 0.034 Uiso 1 1 calc R U . . .
C113 C 0.1498(6) 0.4858(9) 0.3115(5) 0.033(3) Uani 1 1 d . U . . .
C114 C 0.1858(8) 0.5268(11) 0.3490(6) 0.052(4) Uani 1 1 d . U . . .
H114 H 0.2196 0.4961 0.3636 0.063 Uiso 1 1 calc R U . . .
C115 C 0.1723(9) 0.6061(12) 0.3633(7) 0.063(5) Uani 1 1 d . U . . .
H115 H 0.1962 0.6315 0.3884 0.076 Uiso 1 1 calc R U . . .
C116 C 0.1230(10) 0.6542(12) 0.3423(7) 0.066(5) Uani 1 1 d . U . . .
H116 H 0.1117 0.7099 0.3540 0.079 Uiso 1 1 calc R U . . .
C117 C 0.0916(10) 0.6176(12) 0.3039(8) 0.072(6) Uani 1 1 d . U . . .
H117 H 0.0607 0.6513 0.2876 0.087 Uiso 1 1 calc R U . . .
C118 C 0.1036(8) 0.5347(11) 0.2886(7) 0.063(5) Uani 1 1 d . U . . .
H118 H 0.0807 0.5108 0.2626 0.075 Uiso 1 1 calc R U . . .
C201 C 0.1568(7) 0.0766(9) 0.2066(6) 0.041(4) Uani 1 1 d . U . . .
C202 C 0.1037(7) 0.1219(11) 0.2193(6) 0.042(4) Uani 1 1 d . U . . .
H202 H 0.0922 0.1753 0.2043 0.050 Uiso 1 1 calc R U . . .
C203 C 0.0682(7) 0.0876(11) 0.2543(6) 0.049(4) Uani 1 1 d . U . . .
H203 H 0.0319 0.1170 0.2632 0.059 Uiso 1 1 calc R U . . .
C204 C 0.0861(8) 0.0108(11) 0.2759(7) 0.053(4) Uani 1 1 d . U . . .
H204 H 0.0607 -0.0133 0.2989 0.064 Uiso 1 1 calc R U . . .
C205 C 0.1387(8) -0.0317(12) 0.2658(7) 0.057(4) Uani 1 1 d . U . . .
H205 H 0.1508 -0.0826 0.2829 0.069 Uiso 1 1 calc R U . . .
C206 C 0.1749(7) -0.0014(10) 0.2306(6) 0.046(4) Uani 1 1 d . U . . .
H206 H 0.2112 -0.0320 0.2228 0.055 Uiso 1 1 calc R U . . .
C207 C 0.2442(7) 0.0351(9) 0.1374(5) 0.034(3) Uani 1 1 d . U . . .
C208 C 0.3083(6) 0.0330(9) 0.1317(6) 0.037(3) Uani 1 1 d . U . . .
H208 H 0.3337 0.0788 0.1441 0.045 Uiso 1 1 calc R U . . .
C209 C 0.3338(7) -0.0340(10) 0.1086(6) 0.042(4) Uani 1 1 d . U . . .
H209 H 0.3771 -0.0338 0.1048 0.051 Uiso 1 1 calc R U . . .
C210 C 0.2997(8) -0.1021(10) 0.0904(6) 0.047(4) Uani 1 1 d . U . . .
H210 H 0.3190 -0.1480 0.0740 0.057 Uiso 1 1 calc R U . . .
C211 C 0.2349(8) -0.1035(11) 0.0963(6) 0.051(4) Uani 1 1 d . U . . .
H211 H 0.2104 -0.1508 0.0845 0.062 Uiso 1 1 calc R U . . .
C212 C 0.2083(6) -0.0346(9) 0.1195(5) 0.036(3) Uani 1 1 d . U . . .
H212 H 0.1650 -0.0345 0.1234 0.043 Uiso 1 1 calc R U . . .
C213 C 0.1602(6) 0.1744(10) 0.1166(5) 0.034(3) Uani 1 1 d . U . . .
C214 C 0.0975(8) 0.1492(11) 0.1068(6) 0.050(4) Uani 1 1 d . U . . .
H214 H 0.0782 0.1065 0.1253 0.060 Uiso 1 1 calc R U . . .
C215 C 0.0654(8) 0.1888(13) 0.0694(7) 0.060(5) Uani 1 1 d . U . . .
H215 H 0.0239 0.1723 0.0620 0.072 Uiso 1 1 calc R U . . .
C216 C 0.0929(10) 0.2514(13) 0.0428(6) 0.061(5) Uani 1 1 d . U . . .
H216 H 0.0697 0.2794 0.0182 0.074 Uiso 1 1 calc R U . . .
C217 C 0.1537(9) 0.2740(12) 0.0517(6) 0.058(5) Uani 1 1 d . U . . .
H217 H 0.1731 0.3166 0.0332 0.070 Uiso 1 1 calc R U . . .
C218 C 0.1849(8) 0.2345(11) 0.0869(6) 0.048(4) Uani 1 1 d . U . . .
H218 H 0.2273 0.2489 0.0919 0.058 Uiso 1 1 calc R U . . .
C301 C 0.4211(8) 0.3528(11) 0.4683(6) 0.047(4) Uani 1 1 d . U . . .
C302 C 0.4767(7) 0.3301(11) 0.4470(6) 0.046(4) Uani 1 1 d . U . . .
H302 H 0.4772 0.3073 0.4162 0.056 Uiso 1 1 calc R U . . .
C303 C 0.5305(9) 0.3436(13) 0.4741(8) 0.071(6) Uani 1 1 d . U . . .
H303 H 0.5687 0.3285 0.4612 0.085 Uiso 1 1 calc R U . . .
C304 C 0.5317(9) 0.3764(14) 0.5172(8) 0.072(6) Uani 1 1 d . U . . .
H304 H 0.5706 0.3846 0.5333 0.086 Uiso 1 1 calc R U . . .
C305 C 0.4787(10) 0.3989(14) 0.5395(7) 0.067(5) Uani 1 1 d . U . . .
H305 H 0.4807 0.4182 0.5710 0.081 Uiso 1 1 calc R U . . .
C306 C 0.4208(9) 0.3924(13) 0.5138(6) 0.058(5) Uani 1 1 d . U . . .
H306 H 0.3837 0.4134 0.5263 0.070 Uiso 1 1 calc R U . . .
C307 C 0.3262(8) 0.2250(10) 0.4587(5) 0.042(4) Uani 1 1 d . U . . .
C308 C 0.2846(8) 0.1731(10) 0.4316(6) 0.054(5) Uani 1 1 d . U . . .
H308 H 0.2699 0.1935 0.4019 0.065 Uiso 1 1 calc R U . . .
C309 C 0.2650(10) 0.0935(14) 0.4476(9) 0.082(6) Uani 1 1 d . U . . .
H309 H 0.2376 0.0582 0.4288 0.098 Uiso 1 1 calc R U . . .
C310 C 0.2866(10) 0.0646(13) 0.4928(8) 0.070(5) Uani 1 1 d . U . . .
H310 H 0.2731 0.0099 0.5044 0.084 Uiso 1 1 calc R U . . .
C311 C 0.3249(11) 0.1131(14) 0.5186(8) 0.080(6) Uani 1 1 d . U . . .
H311 H 0.3385 0.0929 0.5487 0.096 Uiso 1 1 calc R U . . .
C312 C 0.3461(9) 0.1935(12) 0.5026(6) 0.055(4) Uani 1 1 d . U . . .
H312 H 0.3741 0.2271 0.5217 0.066 Uiso 1 1 calc R U . . .
C313 C 0.2944(7) 0.4082(11) 0.4586(5) 0.041(3) Uani 1 1 d . U . . .
C314 C 0.3064(7) 0.4975(11) 0.4513(6) 0.048(4) Uani 1 1 d . U . . .
H314 H 0.3435 0.5143 0.4371 0.057 Uiso 1 1 calc R U . . .
C315 C 0.2651(11) 0.5621(14) 0.4644(7) 0.071(6) Uani 1 1 d . U . . .
H315 H 0.2727 0.6223 0.4585 0.085 Uiso 1 1 calc R U . . .
C316 C 0.2118(9) 0.5356(15) 0.4867(7) 0.068(5) Uani 1 1 d . U . . .
H316 H 0.1837 0.5785 0.4969 0.082 Uiso 1 1 calc R U . . .
C317 C 0.2000(10) 0.4490(16) 0.4941(8) 0.076(6) Uani 1 1 d . U . . .
H317 H 0.1633 0.4318 0.5086 0.091 Uiso 1 1 calc R U . . .
C318 C 0.2416(9) 0.3861(15) 0.4802(7) 0.067(5) Uani 1 1 d . U . . .
H318 H 0.2331 0.3261 0.4858 0.081 Uiso 1 1 calc R U . . .
C401 C 0.2837(7) 0.6606(9) 0.1334(6) 0.039(3) Uani 1 1 d . U . . .
C402 C 0.3460(7) 0.6606(9) 0.1298(6) 0.042(4) Uani 1 1 d . U . . .
H402 H 0.3722 0.6565 0.1571 0.051 Uiso 1 1 calc R U . . .
C403 C 0.3706(8) 0.6665(11) 0.0877(7) 0.054(4) Uani 1 1 d . U . . .
H403 H 0.4142 0.6673 0.0853 0.064 Uiso 1 1 calc R U . . .
C404 C 0.3318(9) 0.6714(11) 0.0467(7) 0.057(5) Uani 1 1 d . U . . .
H404 H 0.3496 0.6741 0.0171 0.069 Uiso 1 1 calc R U . . .
C405 C 0.2692(10) 0.6723(10) 0.0494(6) 0.054(4) Uani 1 1 d . U . . .
H405 H 0.2430 0.6766 0.0220 0.065 Uiso 1 1 calc R U . . .
C406 C 0.2450(8) 0.6669(9) 0.0927(6) 0.044(4) Uani 1 1 d . U . . .
H406 H 0.2015 0.6673 0.0953 0.053 Uiso 1 1 calc R U . . .
C407 C 0.2738(6) 0.7374(10) 0.2285(5) 0.039(3) Uani 1 1 d . U . . .
C408 C 0.2594(9) 0.7316(13) 0.2771(6) 0.061(5) Uani 1 1 d . U . . .
H408 H 0.2397 0.6810 0.2888 0.073 Uiso 1 1 calc R U . . .
C409 C 0.2750(10) 0.8019(12) 0.3068(7) 0.065(5) Uani 1 1 d . U . . .
H409 H 0.2654 0.7999 0.3388 0.078 Uiso 1 1 calc R U . . .
C410 C 0.3043(9) 0.8740(12) 0.2892(7) 0.064(5) Uani 1 1 d . U . . .
H410 H 0.3153 0.9205 0.3099 0.076 Uiso 1 1 calc R U . . .
C411 C 0.3186(7) 0.8821(11) 0.2429(6) 0.049(4) Uani 1 1 d . U . . .
H411 H 0.3378 0.9337 0.2319 0.059 Uiso 1 1 calc R U . . .
C412 C 0.3039(7) 0.8118(11) 0.2121(6) 0.047(4) Uani 1 1 d . U . . .
H412 H 0.3145 0.8151 0.1803 0.056 Uiso 1 1 calc R U . . .
C413 C 0.1692(7) 0.6569(10) 0.1834(6) 0.045(4) Uani 1 1 d . U . . .
C414 C 0.1324(7) 0.5859(12) 0.1715(7) 0.059(5) Uani 1 1 d . U . . .
H414 H 0.1507 0.5294 0.1700 0.071 Uiso 1 1 calc R U . . .
C415 C 0.0687(10) 0.5947(15) 0.1615(8) 0.076(6) Uani 1 1 d . U . . .
H415 H 0.0434 0.5448 0.1556 0.091 Uiso 1 1 calc R U . . .
C416 C 0.0439(10) 0.6781(17) 0.1606(8) 0.077(6) Uani 1 1 d . U . . .
H416 H 0.0014 0.6857 0.1521 0.092 Uiso 1 1 calc R U . . .
C417 C 0.0786(8) 0.7486(14) 0.1717(8) 0.066(5) Uani 1 1 d . U . . .
H417 H 0.0597 0.8047 0.1728 0.079 Uiso 1 1 calc R U . . .
C418 C 0.1417(7) 0.7411(11) 0.1814(7) 0.054(4) Uani 1 1 d . U . . .
H418 H 0.1663 0.7920 0.1867 0.064 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 P1 2.321(4) . ?
Au1 Au4 2.8531(14) . ?
Au1 Ru4 2.8699(16) . ?
Au1 Au3 2.8892(15) . ?
Au1 Au2 2.8966(14) . ?
Au1 Ru2 2.9285(17) . ?
Au1 Ru3 3.1396(18) . ?
Au2 P2 2.329(3) . ?
Au2 Ru3 2.8107(16) . ?
Au2 Ru4 2.8829(16) . ?
Au3 P3 2.340(4) . ?
Au3 Ru2 2.8533(16) . ?
Au3 Ru4 2.8603(17) . ?
Au4 P4 2.322(4) . ?
Au4 C7 2.700(15) . ?
Au4 Ru2 2.8311(16) . ?
Au4 Ru3 2.8581(16) . ?
P1 C101 1.815(14) . ?
P1 C113 1.831(15) . ?
P1 C107 1.840(12) . ?
P2 C207 1.816(14) . ?
P2 C201 1.830(17) . ?
P2 C213 1.845(14) . ?
P3 C313 1.804(15) . ?
P3 C307 1.807(15) . ?
P3 C301 1.832(16) . ?
P4 C413 1.801(16) . ?
P4 C407 1.820(16) . ?
P4 C401 1.860(17) . ?
Ru1 C2 1.931(17) . ?
Ru1 C3 1.935(17) . ?
Ru1 C1 1.959(17) . ?
Ru1 Ru2 2.8899(18) . ?
Ru1 Ru3 2.893(2) . ?
Ru1 Ru4 2.9049(19) . ?
Ru2 C6 1.914(14) . ?
Ru2 C5 1.926(14) . ?
Ru2 C4 1.946(14) . ?
Ru2 Ru3 3.092(2) . ?
Ru3 C9 1.880(14) . ?
Ru3 C8 1.921(14) . ?
Ru3 C7 1.972(15) . ?
Ru3 Ru4 3.118(2) . ?
Ru4 C10 1.902(15) . ?
Ru4 C11 1.902(16) . ?
Ru4 C12 1.906(13) . ?
C1 O1 1.093(19) . ?
C2 O2 1.109(19) . ?
C3 O3 1.126(19) . ?
C4 O4 1.128(17) . ?
C5 O5 1.123(17) . ?
C6 O6 1.165(17) . ?
C7 O7 1.139(17) . ?
C8 O8 1.126(17) . ?
C9 O9 1.143(17) . ?
C10 O10 1.149(17) . ?
C11 O11 1.175(18) . ?
C12 O12 1.131(17) . ?
C101 C102 1.38(2) . ?
C101 C106 1.38(2) . ?
C102 C103 1.37(2) . ?
C102 H102 0.9500 . ?
C103 C104 1.38(3) . ?
C103 H103 0.9500 . ?
C104 C105 1.35(3) . ?
C104 H104 0.9500 . ?
C105 C106 1.41(2) . ?
C105 H105 0.9500 . ?
C106 H106 0.9500 . ?
C107 C108 1.38(2) . ?
C107 C112 1.403(17) . ?
C108 C109 1.39(2) . ?
C108 H108 0.9500 . ?
C109 C110 1.37(2) . ?
C109 H109 0.9500 . ?
C110 C111 1.38(2) . ?
C110 H110 0.9500 . ?
C111 C112 1.42(2) . ?
C111 H111 0.9500 . ?
C112 H112 0.9500 . ?
C113 C118 1.39(2) . ?
C113 C114 1.44(2) . ?
C114 C115 1.32(2) . ?
C114 H114 0.9500 . ?
C115 C116 1.41(3) . ?
C115 H115 0.9500 . ?
C116 C117 1.39(3) . ?
C116 H116 0.9500 . ?
C117 C118 1.37(2) . ?
C117 H117 0.9500 . ?
C118 H118 0.9500 . ?
C201 C202 1.40(2) . ?
C201 C206 1.42(2) . ?
C202 C203 1.39(2) . ?
C202 H202 0.9500 . ?
C203 C204 1.37(2) . ?
C203 H203 0.9500 . ?
C204 C205 1.35(2) . ?
C204 H204 0.9500 . ?
C205 C206 1.38(2) . ?
C205 H205 0.9500 . ?
C206 H206 0.9500 . ?
C207 C212 1.402(19) . ?
C207 C208 1.41(2) . ?
C208 C209 1.35(2) . ?
C208 H208 0.9500 . ?
C209 C210 1.36(2) . ?
C209 H209 0.9500 . ?
C210 C211 1.42(2) . ?
C210 H210 0.9500 . ?
C211 C212 1.38(2) . ?
C211 H211 0.9500 . ?
C212 H212 0.9500 . ?
C213 C218 1.37(2) . ?
C213 C214 1.43(2) . ?
C214 C215 1.39(2) . ?
C214 H214 0.9500 . ?
C215 C216 1.37(3) . ?
C215 H215 0.9500 . ?
C216 C217 1.38(3) . ?
C216 H216 0.9500 . ?
C217 C218 1.33(2) . ?
C217 H217 0.9500 . ?
C218 H218 0.9500 . ?
C301 C302 1.42(2) . ?
C301 C306 1.44(2) . ?
C302 C303 1.39(2) . ?
C302 H302 0.9500 . ?
C303 C304 1.33(3) . ?
C303 H303 0.9500 . ?
C304 C305 1.38(3) . ?
C304 H304 0.9500 . ?
C305 C306 1.43(2) . ?
C305 H305 0.9500 . ?
C306 H306 0.9500 . ?
C307 C312 1.40(2) . ?
C307 C308 1.41(2) . ?
C308 C309 1.37(3) . ?
C308 H308 0.9500 . ?
C309 C310 1.43(3) . ?
C309 H309 0.9500 . ?
C310 C311 1.32(3) . ?
C310 H310 0.9500 . ?
C311 C312 1.40(3) . ?
C311 H311 0.9500 . ?
C312 H312 0.9500 . ?
C313 C318 1.37(2) . ?
C313 C314 1.41(2) . ?
C314 C315 1.40(3) . ?
C314 H314 0.9500 . ?
C315 C316 1.40(3) . ?
C315 H315 0.9500 . ?
C316 C317 1.36(3) . ?
C316 H316 0.9500 . ?
C317 C318 1.39(3) . ?
C317 H317 0.9500 . ?
C318 H318 0.9500 . ?
C401 C402 1.36(2) . ?
C401 C406 1.41(2) . ?
C402 C403 1.34(2) . ?
C402 H402 0.9500 . ?
C403 C404 1.41(3) . ?
C403 H403 0.9500 . ?
C404 C405 1.36(3) . ?
C404 H404 0.9500 . ?
C405 C406 1.37(2) . ?
C405 H405 0.9500 . ?
C406 H406 0.9500 . ?
C407 C412 1.40(2) . ?
C407 C408 1.44(2) . ?
C408 C409 1.40(3) . ?
C408 H408 0.9500 . ?
C409 C410 1.38(3) . ?
C409 H409 0.9500 . ?
C410 C411 1.38(3) . ?
C410 H410 0.9500 . ?
C411 C412 1.42(2) . ?
C411 H411 0.9500 . ?
C412 H412 0.9500 . ?
C413 C414 1.38(2) . ?
C413 C418 1.42(2) . ?
C414 C415 1.40(3) . ?
C414 H414 0.9500 . ?
C415 C416 1.38(3) . ?
C415 H415 0.9500 . ?
C416 C417 1.34(3) . ?
C416 H416 0.9500 . ?
C417 C418 1.39(2) . ?
C417 H417 0.9500 . ?
C418 H418 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Au1 Au4 102.71(9) . . ?
P1 Au1 Ru4 145.33(9) . . ?
Au4 Au1 Ru4 111.69(4) . . ?
P1 Au1 Au3 110.56(10) . . ?
Au4 Au1 Au3 113.50(3) . . ?
Ru4 Au1 Au3 59.56(3) . . ?
P1 Au1 Au2 108.75(9) . . ?
Au4 Au1 Au2 103.02(5) . . ?
Ru4 Au1 Au2 59.99(3) . . ?
Au3 Au1 Au2 117.12(4) . . ?
P1 Au1 Ru2 139.82(10) . . ?
Au4 Au1 Ru2 58.62(3) . . ?
Ru4 Au1 Ru2 67.30(5) . . ?
Au3 Au1 Ru2 58.74(3) . . ?
Au2 Au1 Ru2 110.09(4) . . ?
P1 Au1 Ru3 141.89(9) . . ?
Au4 Au1 Ru3 56.73(3) . . ?
Ru4 Au1 Ru3 62.32(4) . . ?
Au3 Au1 Ru3 107.28(5) . . ?
Au2 Au1 Ru3 55.33(3) . . ?
Ru2 Au1 Ru3 61.16(4) . . ?
P2 Au2 Ru3 145.56(10) . . ?
P2 Au2 Ru4 143.56(10) . . ?
Ru3 Au2 Ru4 66.40(4) . . ?
P2 Au2 Au1 135.51(10) . . ?
Ru3 Au2 Au1 66.73(4) . . ?
Ru4 Au2 Au1 59.55(3) . . ?
P3 Au3 Ru2 140.71(10) . . ?
P3 Au3 Ru4 145.94(11) . . ?
Ru2 Au3 Ru4 68.44(5) . . ?
P3 Au3 Au1 140.47(10) . . ?
Ru2 Au3 Au1 61.32(4) . . ?
Ru4 Au3 Au1 59.88(4) . . ?
P4 Au4 C7 103.2(3) . . ?
P4 Au4 Ru2 144.03(10) . . ?
C7 Au4 Ru2 106.6(3) . . ?
P4 Au4 Au1 144.61(10) . . ?
C7 Au4 Au1 79.4(3) . . ?
Ru2 Au4 Au1 62.02(3) . . ?
P4 Au4 Ru3 136.59(11) . . ?
C7 Au4 Ru3 41.4(3) . . ?
Ru2 Au4 Ru3 65.85(4) . . ?
Au1 Au4 Ru3 66.70(4) . . ?
C101 P1 C113 104.7(7) . . ?
C101 P1 C107 103.9(6) . . ?
C113 P1 C107 103.5(6) . . ?
C101 P1 Au1 112.7(4) . . ?
C113 P1 Au1 115.5(4) . . ?
C107 P1 Au1 115.1(4) . . ?
C207 P2 C201 104.0(7) . . ?
C207 P2 C213 102.0(6) . . ?
C201 P2 C213 108.5(7) . . ?
C207 P2 Au2 113.7(5) . . ?
C201 P2 Au2 113.3(5) . . ?
C213 P2 Au2 114.2(5) . . ?
C313 P3 C307 105.8(8) . . ?
C313 P3 C301 104.5(8) . . ?
C307 P3 C301 102.6(7) . . ?
C313 P3 Au3 112.8(5) . . ?
C307 P3 Au3 114.8(5) . . ?
C301 P3 Au3 115.1(6) . . ?
C413 P4 C407 103.2(7) . . ?
C413 P4 C401 105.8(8) . . ?
C407 P4 C401 108.3(7) . . ?
C413 P4 Au4 122.1(5) . . ?
C407 P4 Au4 110.3(5) . . ?
C401 P4 Au4 106.5(5) . . ?
C2 Ru1 C3 94.8(7) . . ?
C2 Ru1 C1 91.6(7) . . ?
C3 Ru1 C1 95.1(7) . . ?
C2 Ru1 Ru2 98.3(4) . . ?
C3 Ru1 Ru2 96.9(5) . . ?
C1 Ru1 Ru2 163.8(5) . . ?
C2 Ru1 Ru3 103.1(4) . . ?
C3 Ru1 Ru3 155.7(5) . . ?
C1 Ru1 Ru3 100.7(5) . . ?
Ru2 Ru1 Ru3 64.65(5) . . ?
C2 Ru1 Ru4 164.0(4) . . ?
C3 Ru1 Ru4 94.0(5) . . ?
C1 Ru1 Ru4 100.9(5) . . ?
Ru2 Ru1 Ru4 67.35(5) . . ?
Ru3 Ru1 Ru4 65.06(5) . . ?
C6 Ru2 C5 91.1(6) . . ?
C6 Ru2 C4 92.0(6) . . ?
C5 Ru2 C4 92.8(6) . . ?
C6 Ru2 Au4 158.1(4) . . ?
C5 Ru2 Au4 74.3(4) . . ?
C4 Ru2 Au4 72.9(4) . . ?
C6 Ru2 Au3 75.4(4) . . ?
C5 Ru2 Au3 163.2(4) . . ?
C4 Ru2 Au3 78.0(4) . . ?
Au4 Ru2 Au3 115.30(5) . . ?
C6 Ru2 Ru1 81.9(4) . . ?
C5 Ru2 Ru1 85.0(4) . . ?
C4 Ru2 Ru1 173.4(4) . . ?
Au4 Ru2 Ru1 112.24(6) . . ?
Au3 Ru2 Ru1 102.62(5) . . ?
C6 Ru2 Au1 135.3(4) . . ?
C5 Ru2 Au1 133.1(4) . . ?
C4 Ru2 Au1 81.2(4) . . ?
Au4 Ru2 Au1 59.36(4) . . ?
Au3 Ru2 Au1 59.95(3) . . ?
Ru1 Ru2 Au1 104.82(5) . . ?
C6 Ru2 Ru3 139.6(4) . . ?
C5 Ru2 Ru3 87.2(4) . . ?
C4 Ru2 Ru3 128.4(4) . . ?
Au4 Ru2 Ru3 57.50(4) . . ?
Au3 Ru2 Ru3 109.50(5) . . ?
Ru1 Ru2 Ru3 57.73(4) . . ?
Au1 Ru2 Ru3 62.79(3) . . ?
C9 Ru3 C8 89.6(6) . . ?
C9 Ru3 C7 95.5(7) . . ?
C8 Ru3 C7 93.3(6) . . ?
C9 Ru3 Au2 73.3(4) . . ?
C8 Ru3 Au2 159.2(4) . . ?
C7 Ru3 Au2 77.1(4) . . ?
C9 Ru3 Au4 159.8(4) . . ?
C8 Ru3 Au4 86.8(5) . . ?
C7 Ru3 Au4 65.0(5) . . ?
Au2 Ru3 Au4 105.10(5) . . ?
C9 Ru3 Ru1 87.3(5) . . ?
C8 Ru3 Ru1 78.8(4) . . ?
C7 Ru3 Ru1 171.6(4) . . ?
Au2 Ru3 Ru1 111.38(5) . . ?
Au4 Ru3 Ru1 111.35(5) . . ?
C9 Ru3 Ru2 143.4(5) . . ?
C8 Ru3 Ru2 92.9(4) . . ?
C7 Ru3 Ru2 120.7(5) . . ?
Au2 Ru3 Ru2 107.86(5) . . ?
Au4 Ru3 Ru2 56.66(3) . . ?
Ru1 Ru3 Ru2 57.62(4) . . ?
C9 Ru3 Ru4 91.5(4) . . ?
C8 Ru3 Ru4 136.3(4) . . ?
C7 Ru3 Ru4 130.0(4) . . ?
Au2 Ru3 Ru4 57.91(4) . . ?
Au4 Ru3 Ru4 104.75(5) . . ?
Ru1 Ru3 Ru4 57.65(4) . . ?
Ru2 Ru3 Ru4 62.32(5) . . ?
C9 Ru3 Au1 130.0(4) . . ?
C8 Ru3 Au1 140.4(5) . . ?
C7 Ru3 Au1 84.7(5) . . ?
Au2 Ru3 Au1 57.94(3) . . ?
Au4 Ru3 Au1 56.58(3) . . ?
Ru1 Ru3 Au1 99.60(6) . . ?
Ru2 Ru3 Au1 56.05(4) . . ?
Ru4 Ru3 Au1 54.60(4) . . ?
C10 Ru4 C11 91.7(6) . . ?
C10 Ru4 C12 93.9(6) . . ?
C11 Ru4 C12 92.3(7) . . ?
C10 Ru4 Au3 160.5(4) . . ?
C11 Ru4 Au3 69.6(5) . . ?
C12 Ru4 Au3 81.9(5) . . ?
C10 Ru4 Au1 137.4(4) . . ?
C11 Ru4 Au1 130.1(5) . . ?
C12 Ru4 Au1 78.6(4) . . ?
Au3 Ru4 Au1 60.56(3) . . ?
C10 Ru4 Au2 77.3(4) . . ?
C11 Ru4 Au2 159.2(5) . . ?
C12 Ru4 Au2 71.2(4) . . ?
Au3 Ru4 Au2 118.52(5) . . ?
Au1 Ru4 Au2 60.46(4) . . ?
C10 Ru4 Ru1 81.4(4) . . ?
C11 Ru4 Ru1 86.3(5) . . ?
C12 Ru4 Ru1 175.1(4) . . ?
Au3 Ru4 Ru1 102.07(5) . . ?
Au1 Ru4 Ru1 105.95(6) . . ?
Au2 Ru4 Ru1 108.99(6) . . ?
C10 Ru4 Ru3 89.5(4) . . ?
C11 Ru4 Ru3 143.0(5) . . ?
C12 Ru4 Ru3 124.6(4) . . ?
Au3 Ru4 Ru3 108.61(6) . . ?
Au1 Ru4 Ru3 63.08(4) . . ?
Au2 Ru4 Ru3 55.69(4) . . ?
Ru1 Ru4 Ru3 57.29(4) . . ?
O1 C1 Ru1 178.1(16) . . ?
O2 C2 Ru1 175.1(16) . . ?
O3 C3 Ru1 177.3(17) . . ?
O4 C4 Ru2 167.1(12) . . ?
O5 C5 Ru2 175.3(14) . . ?
O6 C6 Ru2 171.6(13) . . ?
O7 C7 Ru3 166.8(14) . . ?
O7 C7 Au4 115.9(12) . . ?
Ru3 C7 Au4 73.6(4) . . ?
O8 C8 Ru3 173.4(13) . . ?
O9 C9 Ru3 174.1(13) . . ?
O10 C10 Ru4 172.9(13) . . ?
O11 C11 Ru4 172.9(14) . . ?
O12 C12 Ru4 169.8(13) . . ?
C102 C101 C106 116.7(15) . . ?
C102 C101 P1 124.6(12) . . ?
C106 C101 P1 118.7(12) . . ?
C103 C102 C101 122.8(17) . . ?
C103 C102 H102 118.6 . . ?
C101 C102 H102 118.6 . . ?
C102 C103 C104 120.6(19) . . ?
C102 C103 H103 119.7 . . ?
C104 C103 H103 119.7 . . ?
C105 C104 C103 117.5(18) . . ?
C105 C104 H104 121.3 . . ?
C103 C104 H104 121.3 . . ?
C104 C105 C106 122.5(18) . . ?
C104 C105 H105 118.8 . . ?
C106 C105 H105 118.8 . . ?
C101 C106 C105 119.8(17) . . ?
C101 C106 H106 120.1 . . ?
C105 C106 H106 120.1 . . ?
C108 C107 C112 118.3(12) . . ?
C108 C107 P1 121.2(10) . . ?
C112 C107 P1 120.3(10) . . ?
C107 C108 C109 122.1(14) . . ?
C107 C108 H108 118.9 . . ?
C109 C108 H108 118.9 . . ?
C110 C109 C108 118.9(15) . . ?
C110 C109 H109 120.5 . . ?
C108 C109 H109 120.5 . . ?
C109 C110 C111 121.5(14) . . ?
C109 C110 H110 119.3 . . ?
C111 C110 H110 119.3 . . ?
C110 C111 C112 119.3(14) . . ?
C110 C111 H111 120.3 . . ?
C112 C111 H111 120.3 . . ?
C107 C112 C111 119.9(14) . . ?
C107 C112 H112 120.1 . . ?
C111 C112 H112 120.1 . . ?
C118 C113 C114 118.3(14) . . ?
C118 C113 P1 122.2(11) . . ?
C114 C113 P1 119.2(11) . . ?
C115 C114 C113 120.7(15) . . ?
C115 C114 H114 119.7 . . ?
C113 C114 H114 119.7 . . ?
C114 C115 C116 121.4(16) . . ?
C114 C115 H115 119.3 . . ?
C116 C115 H115 119.3 . . ?
C117 C116 C115 117.8(17) . . ?
C117 C116 H116 121.1 . . ?
C115 C116 H116 121.1 . . ?
C118 C117 C116 122.2(17) . . ?
C118 C117 H117 118.9 . . ?
C116 C117 H117 118.9 . . ?
C117 C118 C113 119.3(16) . . ?
C117 C118 H118 120.4 . . ?
C113 C118 H118 120.4 . . ?
C202 C201 C206 119.9(16) . . ?
C202 C201 P2 119.1(12) . . ?
C206 C201 P2 120.4(12) . . ?
C203 C202 C201 119.2(15) . . ?
C203 C202 H202 120.4 . . ?
C201 C202 H202 120.4 . . ?
C204 C203 C202 119.4(15) . . ?
C204 C203 H203 120.3 . . ?
C202 C203 H203 120.3 . . ?
C205 C204 C203 122.4(17) . . ?
C205 C204 H204 118.8 . . ?
C203 C204 H204 118.8 . . ?
C204 C205 C206 120.4(17) . . ?
C204 C205 H205 119.8 . . ?
C206 C205 H205 119.8 . . ?
C205 C206 C201 118.7(15) . . ?
C205 C206 H206 120.7 . . ?
C201 C206 H206 120.7 . . ?
C212 C207 C208 118.4(13) . . ?
C212 C207 P2 120.4(11) . . ?
C208 C207 P2 121.2(11) . . ?
C209 C208 C207 120.2(13) . . ?
C209 C208 H208 119.9 . . ?
C207 C208 H208 119.9 . . ?
C208 C209 C210 122.5(15) . . ?
C208 C209 H209 118.8 . . ?
C210 C209 H209 118.8 . . ?
C209 C210 C211 119.2(15) . . ?
C209 C210 H210 120.4 . . ?
C211 C210 H210 120.4 . . ?
C212 C211 C210 118.7(15) . . ?
C212 C211 H211 120.6 . . ?
C210 C211 H211 120.6 . . ?
C211 C212 C207 121.0(14) . . ?
C211 C212 H212 119.5 . . ?
C207 C212 H212 119.5 . . ?
C218 C213 C214 116.7(14) . . ?
C218 C213 P2 120.4(11) . . ?
C214 C213 P2 122.8(13) . . ?
C215 C214 C213 118.3(17) . . ?
C215 C214 H214 120.9 . . ?
C213 C214 H214 120.9 . . ?
C216 C215 C214 121.1(17) . . ?
C216 C215 H215 119.5 . . ?
C214 C215 H215 119.5 . . ?
C215 C216 C217 120.4(17) . . ?
C215 C216 H216 119.8 . . ?
C217 C216 H216 119.8 . . ?
C218 C217 C216 118.5(19) . . ?
C218 C217 H217 120.8 . . ?
C216 C217 H217 120.8 . . ?
C217 C218 C213 124.9(18) . . ?
C217 C218 H218 117.6 . . ?
C213 C218 H218 117.6 . . ?
C302 C301 C306 122.0(15) . . ?
C302 C301 P3 117.9(12) . . ?
C306 C301 P3 120.1(14) . . ?
C303 C302 C301 115.6(17) . . ?
C303 C302 H302 122.2 . . ?
C301 C302 H302 122.2 . . ?
C304 C303 C302 124(2) . . ?
C304 C303 H303 118.1 . . ?
C302 C303 H303 118.1 . . ?
C303 C304 C305 122.5(18) . . ?
C303 C304 H304 118.7 . . ?
C305 C304 H304 118.7 . . ?
C304 C305 C306 118.3(18) . . ?
C304 C305 H305 120.8 . . ?
C306 C305 H305 120.8 . . ?
C305 C306 C301 117.2(19) . . ?
C305 C306 H306 121.4 . . ?
C301 C306 H306 121.4 . . ?
C312 C307 C308 117.9(15) . . ?
C312 C307 P3 123.7(13) . . ?
C308 C307 P3 118.3(12) . . ?
C309 C308 C307 121.0(16) . . ?
C309 C308 H308 119.5 . . ?
C307 C308 H308 119.5 . . ?
C308 C309 C310 118.8(18) . . ?
C308 C309 H309 120.6 . . ?
C310 C309 H309 120.6 . . ?
C311 C310 C309 120.7(18) . . ?
C311 C310 H310 119.6 . . ?
C309 C310 H310 119.6 . . ?
C310 C311 C312 121.2(19) . . ?
C310 C311 H311 119.4 . . ?
C312 C311 H311 119.4 . . ?
C311 C312 C307 120.3(17) . . ?
C311 C312 H312 119.8 . . ?
C307 C312 H312 119.8 . . ?
C318 C313 C314 118.0(16) . . ?
C318 C313 P3 124.6(15) . . ?
C314 C313 P3 117.3(12) . . ?
C315 C314 C313 121.3(17) . . ?
C315 C314 H314 119.3 . . ?
C313 C314 H314 119.3 . . ?
C314 C315 C316 118(2) . . ?
C314 C315 H315 121.0 . . ?
C316 C315 H315 121.0 . . ?
C317 C316 C315 121(2) . . ?
C317 C316 H316 119.5 . . ?
C315 C316 H316 119.5 . . ?
C316 C317 C318 120(2) . . ?
C316 C317 H317 120.1 . . ?
C318 C317 H317 120.1 . . ?
C313 C318 C317 122(2) . . ?
C313 C318 H318 119.1 . . ?
C317 C318 H318 119.1 . . ?
C402 C401 C406 119.6(16) . . ?
C402 C401 P4 118.7(12) . . ?
C406 C401 P4 121.5(12) . . ?
C403 C402 C401 120.2(16) . . ?
C403 C402 H402 119.9 . . ?
C401 C402 H402 119.9 . . ?
C402 C403 C404 120.2(17) . . ?
C402 C403 H403 119.9 . . ?
C404 C403 H403 119.9 . . ?
C405 C404 C403 120.8(19) . . ?
C405 C404 H404 119.6 . . ?
C403 C404 H404 119.6 . . ?
C404 C405 C406 118.2(18) . . ?
C404 C405 H405 120.9 . . ?
C406 C405 H405 120.9 . . ?
C405 C406 C401 121.0(16) . . ?
C405 C406 H406 119.5 . . ?
C401 C406 H406 119.5 . . ?
C412 C407 C408 119.8(16) . . ?
C412 C407 P4 123.8(12) . . ?
C408 C407 P4 116.4(12) . . ?
C409 C408 C407 118.8(18) . . ?
C409 C408 H408 120.6 . . ?
C407 C408 H408 120.6 . . ?
C410 C409 C408 119(2) . . ?
C410 C409 H409 120.3 . . ?
C408 C409 H409 120.3 . . ?
C409 C410 C411 123.4(18) . . ?
C409 C410 H410 118.3 . . ?
C411 C410 H410 118.3 . . ?
C410 C411 C412 118.5(17) . . ?
C410 C411 H411 120.7 . . ?
C412 C411 H411 120.7 . . ?
C407 C412 C411 120.0(16) . . ?
C407 C412 H412 120.0 . . ?
C411 C412 H412 120.0 . . ?
C414 C413 C418 117.7(15) . . ?
C414 C413 P4 120.5(12) . . ?
C418 C413 P4 121.1(12) . . ?
C413 C414 C415 121.8(17) . . ?
C413 C414 H414 119.1 . . ?
C415 C414 H414 119.1 . . ?
C416 C415 C414 118(2) . . ?
C416 C415 H415 121.0 . . ?
C414 C415 H415 121.0 . . ?
C417 C416 C415 121(2) . . ?
C417 C416 H416 119.3 . . ?
C415 C416 H416 119.3 . . ?
C416 C417 C418 121.2(19) . . ?
C416 C417 H417 119.4 . . ?
C418 C417 H417 119.4 . . ?
C417 C418 C413 119.5(17) . . ?
C417 C418 H418 120.2 . . ?
C413 C418 H418 120.2 . . ?

_refine_diff_density_max         3.251
_refine_diff_density_min         -2.325
_refine_diff_density_rms         0.274





