# Electronic Supplementary Material (ESI) for New Journal of Chemistry.
# This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2024

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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data_jmy_13_1_0m
_database_code_depnum_ccdc_archive 'CCDC 1943516'
loop_
_audit_author_name
_audit_author_address
'Lise-Marie Chamoreau'
;Sorbonne Universite,CNRS,IPCM
France
;
_audit_update_record             
;
2019-07-26 deposited with the CCDC.	2024-02-28 downloaded from the CCDC.
;
_audit_creation_date             2019-07-26
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2017/1
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C38 H29 Cu P2'
_chemical_formula_sum            'C38 H29 Cu P2'
_chemical_formula_weight         611.09
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu -1.9646 0.5888 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   10.7851(3)
_cell_length_b                   12.7214(4)
_cell_length_c                   12.9752(4)
_cell_angle_alpha                66.4000(10)
_cell_angle_beta                 73.5420(10)
_cell_angle_gamma                72.6740(10)
_cell_volume                     1529.66(8)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    9907
_cell_measurement_temperature    200(2)
_cell_measurement_theta_max      68.21
_cell_measurement_theta_min      4.37
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    2.179
_exptl_absorpt_correction_T_max  0.7530
_exptl_absorpt_correction_T_min  0.6764
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
'SADABS-2012/1 (Bruker,2012) was used for absorption correction. wR2(int) was 0.0460 before and 0.0256 after correction. The Ratio of minimum to maximum transmission is 0.8983. The λ/2 correction factor is 0.0015.'
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            yellow
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.327
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    ?
_exptl_crystal_description       prism
_exptl_crystal_F_000             632
_exptl_crystal_preparation       ?
_exptl_crystal_size_max          0.21
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.16
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0162
_diffrn_reflns_av_unetI/netI     0.0133
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.994
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            28238
_diffrn_reflns_point_group_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.994
_diffrn_reflns_theta_full        67.679
_diffrn_reflns_theta_max         68.206
_diffrn_reflns_theta_min         3.785
_diffrn_ambient_temperature      200.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_source                   ?
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                5445
_reflns_number_total             5556
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'Sir92 (Giacovazzo, 1994)'
_refine_diff_density_max         0.260
_refine_diff_density_min         -0.266
_refine_diff_density_rms         0.040
_refine_ls_extinction_coef       0.00250(16)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2017/1 (Sheldrick 2017)'
_refine_ls_goodness_of_fit_ref   1.044
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     371
_refine_ls_number_reflns         5556
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0254
_refine_ls_R_factor_gt           0.0250
_refine_ls_restrained_S_all      1.044
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0337P)²+0.7178P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0675
_refine_ls_wR_factor_ref         0.0680
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C4(H4), C5(H5), C6(H6), C7(H7), C8(H8), C11(H11), C12(H12), C13(H13),
 C14(H14), C16(H16), C17(H17), C18(H18), C19(H19), C20(H20), C22(H22), C23(H23),
  C24(H24), C25(H25), C26(H26), C28(H28), C29(H29), C30(H30), C31(H31),
 C32(H32), C34(H34), C35(H35), C36(H36), C37(H37), C38(H38)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Cu1 Cu 1.01656(2) 0.07981(2) 0.41270(2) 0.02398(8) Uani 1 1 d . . . . .
P1 P 0.88088(3) 0.24768(3) 0.32669(3) 0.02280(9) Uani 1 1 d . . . . .
P2 P 1.12801(3) 0.09106(3) 0.23486(3) 0.02251(9) Uani 1 1 d . . . . .
C1 C 0.90451(14) -0.05537(12) 0.45647(12) 0.0273(3) Uani 1 1 d . . . . .
C2 C 0.84865(15) -0.07454(13) 0.40027(13) 0.0308(3) Uani 1 1 d . . . . .
C3 C 0.78460(15) -0.10278(15) 0.33437(13) 0.0341(3) Uani 1 1 d . . . . .
C4 C 0.83177(18) -0.20870(19) 0.31400(18) 0.0498(5) Uani 1 1 d . . . . .
H4 H 0.908172 -0.261118 0.341828 0.060 Uiso 1 1 calc R . . . .
C5 C 0.7682(2) -0.2381(2) 0.2536(2) 0.0634(6) Uani 1 1 d . . . . .
H5 H 0.801742 -0.310266 0.239795 0.076 Uiso 1 1 calc R . . . .
C6 C 0.6575(2) -0.1642(2) 0.21346(18) 0.0628(6) Uani 1 1 d . . . . .
H6 H 0.613425 -0.185839 0.173509 0.075 Uiso 1 1 calc R . . . .
C7 C 0.6100(2) -0.0585(2) 0.23100(18) 0.0609(6) Uani 1 1 d . . . . .
H7 H 0.533765 -0.006761 0.202358 0.073 Uiso 1 1 calc R . . . .
C8 C 0.67350(19) -0.02751(17) 0.29063(16) 0.0478(4) Uani 1 1 d . . . . .
H8 H 0.640759 0.046002 0.301747 0.057 Uiso 1 1 calc R . . . .
C9 C 0.88302(13) 0.22735(11) 0.19367(11) 0.0231(3) Uani 1 1 d . . . . .
C10 C 0.99410(13) 0.15275(11) 0.15288(11) 0.0232(3) Uani 1 1 d . . . . .
C11 C 0.99396(15) 0.12567(12) 0.05891(12) 0.0285(3) Uani 1 1 d . . . . .
H11 H 1.069247 0.076115 0.030662 0.034 Uiso 1 1 calc R . . . .
C12 C 0.88452(16) 0.17063(13) 0.00631(13) 0.0322(3) Uani 1 1 d . . . . .
H12 H 0.884493 0.150900 -0.056979 0.039 Uiso 1 1 calc R . . . .
C13 C 0.77565(15) 0.24411(13) 0.04617(13) 0.0327(3) Uani 1 1 d . . . . .
H13 H 0.700931 0.274925 0.009969 0.039 Uiso 1 1 calc R . . . .
C14 C 0.77471(14) 0.27313(12) 0.13853(12) 0.0281(3) Uani 1 1 d . . . . .
H14 H 0.699821 0.324569 0.164586 0.034 Uiso 1 1 calc R . . . .
C15 C 0.70597(14) 0.30322(14) 0.37379(12) 0.0309(3) Uani 1 1 d . . . . .
C16 C 0.64994(17) 0.42206(15) 0.35067(15) 0.0439(4) Uani 1 1 d . . . . .
H16 H 0.703722 0.478488 0.309529 0.053 Uiso 1 1 calc R . . . .
C17 C 0.5160(2) 0.4582(2) 0.38749(18) 0.0615(6) Uani 1 1 d . . . . .
H17 H 0.478072 0.539383 0.371950 0.074 Uiso 1 1 calc R . . . .
C18 C 0.4379(2) 0.3771(2) 0.44634(19) 0.0684(7) Uani 1 1 d . . . . .
H18 H 0.345720 0.402407 0.470365 0.082 Uiso 1 1 calc R . . . .
C19 C 0.4923(2) 0.2591(2) 0.47080(19) 0.0636(6) Uani 1 1 d . . . . .
H19 H 0.437793 0.203318 0.511937 0.076 Uiso 1 1 calc R . . . .
C20 C 0.62687(17) 0.22171(17) 0.43538(15) 0.0454(4) Uani 1 1 d . . . . .
H20 H 0.664603 0.140268 0.453384 0.054 Uiso 1 1 calc R . . . .
C21 C 0.95630(14) 0.37335(12) 0.28269(12) 0.0264(3) Uani 1 1 d . . . . .
C22 C 0.97052(16) 0.45532(13) 0.17232(13) 0.0320(3) Uani 1 1 d . . . . .
H22 H 0.935853 0.449729 0.115493 0.038 Uiso 1 1 calc R . . . .
C23 C 1.03495(18) 0.54498(14) 0.14492(15) 0.0407(4) Uani 1 1 d . . . . .
H23 H 1.045208 0.600046 0.069153 0.049 Uiso 1 1 calc R . . . .
C24 C 1.08434(19) 0.55470(15) 0.22718(16) 0.0446(4) Uani 1 1 d . . . . .
H24 H 1.128648 0.616216 0.208074 0.054 Uiso 1 1 calc R . . . .
C25 C 1.0691(2) 0.47453(16) 0.33760(17) 0.0497(5) Uani 1 1 d . . . . .
H25 H 1.101298 0.482028 0.394782 0.060 Uiso 1 1 calc R . . . .
C26 C 1.00696(18) 0.38340(15) 0.36482(15) 0.0409(4) Uani 1 1 d . . . . .
H26 H 0.998907 0.327364 0.440187 0.049 Uiso 1 1 calc R . . . .
C27 C 1.22358(13) -0.04065(12) 0.20248(12) 0.0266(3) Uani 1 1 d . . . . .
C28 C 1.31534(15) -0.04019(14) 0.10226(13) 0.0310(3) Uani 1 1 d . . . . .
H28 H 1.328911 0.032222 0.043891 0.037 Uiso 1 1 calc R . . . .
C29 C 1.38701(15) -0.14515(14) 0.08737(14) 0.0351(3) Uani 1 1 d . . . . .
H29 H 1.449179 -0.144454 0.018681 0.042 Uiso 1 1 calc R . . . .
C30 C 1.36814(16) -0.25055(14) 0.17217(15) 0.0376(4) Uani 1 1 d . . . . .
H30 H 1.417826 -0.322274 0.161962 0.045 Uiso 1 1 calc R . . . .
C31 C 1.27737(17) -0.25205(14) 0.27168(16) 0.0422(4) Uani 1 1 d . . . . .
H31 H 1.264041 -0.324794 0.329551 0.051 Uiso 1 1 calc R . . . .
C32 C 1.20542(16) -0.14751(14) 0.28747(14) 0.0365(3) Uani 1 1 d . . . . .
H32 H 1.143603 -0.148872 0.356468 0.044 Uiso 1 1 calc R . . . .
C33 C 1.23539(14) 0.19726(12) 0.16294(13) 0.0282(3) Uani 1 1 d . . . . .
C34 C 1.24155(16) 0.26993(14) 0.04863(14) 0.0371(3) Uani 1 1 d . . . . .
H34 H 1.192300 0.262546 0.002578 0.044 Uiso 1 1 calc R . . . .
C35 C 1.31976(18) 0.35312(16) 0.00211(18) 0.0509(5) Uani 1 1 d . . . . .
H35 H 1.323603 0.402860 -0.075733 0.061 Uiso 1 1 calc R . . . .
C36 C 1.3913(2) 0.36372(18) 0.0679(2) 0.0624(6) Uani 1 1 d . . . . .
H36 H 1.444875 0.420595 0.035397 0.075 Uiso 1 1 calc R . . . .
C37 C 1.3860(2) 0.2928(2) 0.1804(2) 0.0661(6) Uani 1 1 d . . . . .
H37 H 1.436296 0.300455 0.225533 0.079 Uiso 1 1 calc R . . . .
C38 C 1.30744(18) 0.20971(18) 0.22877(16) 0.0459(4) Uani 1 1 d . . . . .
H38 H 1.303145 0.161394 0.307076 0.055 Uiso 1 1 calc R . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Cu1 Cu1 2.3819(4) 2_756 ?
Cu1 P1 2.2590(4) . ?
Cu1 P2 2.2487(4) . ?
Cu1 C1 1.9853(14) 2_756 ?
Cu1 C1 2.1926(14) . ?
P1 C9 1.8378(14) . ?
P1 C15 1.8248(15) . ?
P1 C21 1.8233(14) . ?
P2 C10 1.8330(14) . ?
P2 C27 1.8265(14) . ?
P2 C33 1.8296(14) . ?
C1 C2 1.197(2) . ?
C2 C3 1.437(2) . ?
C3 C4 1.394(3) . ?
C3 C8 1.393(2) . ?
C4 H4 0.9500 . ?
C4 C5 1.385(3) . ?
C5 H5 0.9500 . ?
C5 C6 1.368(3) . ?
C6 H6 0.9500 . ?
C6 C7 1.374(3) . ?
C7 H7 0.9500 . ?
C7 C8 1.389(3) . ?
C8 H8 0.9500 . ?
C9 C10 1.4077(19) . ?
C9 C14 1.3965(19) . ?
C10 C11 1.3940(19) . ?
C11 H11 0.9500 . ?
C11 C12 1.388(2) . ?
C12 H12 0.9500 . ?
C12 C13 1.382(2) . ?
C13 H13 0.9500 . ?
C13 C14 1.385(2) . ?
C14 H14 0.9500 . ?
C15 C16 1.391(2) . ?
C15 C20 1.385(2) . ?
C16 H16 0.9500 . ?
C16 C17 1.385(3) . ?
C17 H17 0.9500 . ?
C17 C18 1.371(3) . ?
C18 H18 0.9500 . ?
C18 C19 1.377(3) . ?
C19 H19 0.9500 . ?
C19 C20 1.389(3) . ?
C20 H20 0.9500 . ?
C21 C22 1.392(2) . ?
C21 C26 1.390(2) . ?
C22 H22 0.9500 . ?
C22 C23 1.385(2) . ?
C23 H23 0.9500 . ?
C23 C24 1.380(3) . ?
C24 H24 0.9500 . ?
C24 C25 1.384(3) . ?
C25 H25 0.9500 . ?
C25 C26 1.385(2) . ?
C26 H26 0.9500 . ?
C27 C28 1.392(2) . ?
C27 C32 1.392(2) . ?
C28 H28 0.9500 . ?
C28 C29 1.387(2) . ?
C29 H29 0.9500 . ?
C29 C30 1.380(2) . ?
C30 H30 0.9500 . ?
C30 C31 1.379(3) . ?
C31 H31 0.9500 . ?
C31 C32 1.388(2) . ?
C32 H32 0.9500 . ?
C33 C34 1.393(2) . ?
C33 C38 1.384(2) . ?
C34 H34 0.9500 . ?
C34 C35 1.388(2) . ?
C35 H35 0.9500 . ?
C35 C36 1.367(3) . ?
C36 H36 0.9500 . ?
C36 C37 1.371(3) . ?
C37 H37 0.9500 . ?
C37 C38 1.389(3) . ?
C38 H38 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Cu1 Cu1 132.952(16) . 2_756 ?
P2 Cu1 Cu1 133.383(16) . 2_756 ?
P2 Cu1 P1 85.894(14) . . ?
C1 Cu1 Cu1 51.24(4) . 2_756 ?
C1 Cu1 Cu1 59.45(4) 2_756 2_756 ?
C1 Cu1 P1 103.50(4) . . ?
C1 Cu1 P1 124.03(4) 2_756 . ?
C1 Cu1 P2 102.55(4) . . ?
C1 Cu1 P2 125.74(4) 2_756 . ?
C1 Cu1 C1 110.69(5) 2_756 . ?
C9 P1 Cu1 101.33(4) . . ?
C15 P1 Cu1 129.64(5) . . ?
C15 P1 C9 103.03(6) . . ?
C21 P1 Cu1 110.74(5) . . ?
C21 P1 C9 105.72(6) . . ?
C21 P1 C15 104.00(7) . . ?
C10 P2 Cu1 101.85(4) . . ?
C27 P2 Cu1 121.07(5) . . ?
C27 P2 C10 106.53(6) . . ?
C27 P2 C33 104.79(6) . . ?
C33 P2 Cu1 117.43(5) . . ?
C33 P2 C10 103.20(6) . . ?
Cu1 C1 Cu1 69.31(5) 2_756 . ?
C2 C1 Cu1 159.19(13) . 2_756 ?
C2 C1 Cu1 131.20(12) . . ?
C1 C2 C3 177.51(16) . . ?
C4 C3 C2 120.23(15) . . ?
C8 C3 C2 121.79(16) . . ?
C8 C3 C4 117.97(15) . . ?
C3 C4 H4 119.7 . . ?
C5 C4 C3 120.55(19) . . ?
C5 C4 H4 119.7 . . ?
C4 C5 H5 119.7 . . ?
C6 C5 C4 120.6(2) . . ?
C6 C5 H5 119.7 . . ?
C5 C6 H6 120.0 . . ?
C5 C6 C7 119.99(18) . . ?
C7 C6 H6 120.0 . . ?
C6 C7 H7 120.0 . . ?
C6 C7 C8 120.0(2) . . ?
C8 C7 H7 120.0 . . ?
C3 C8 H8 119.6 . . ?
C7 C8 C3 120.87(19) . . ?
C7 C8 H8 119.6 . . ?
C10 C9 P1 117.86(10) . . ?
C14 C9 P1 122.77(11) . . ?
C14 C9 C10 119.06(13) . . ?
C9 C10 P2 115.99(10) . . ?
C11 C10 P2 124.29(11) . . ?
C11 C10 C9 119.64(12) . . ?
C10 C11 H11 119.8 . . ?
C12 C11 C10 120.44(14) . . ?
C12 C11 H11 119.8 . . ?
C11 C12 H12 120.1 . . ?
C13 C12 C11 119.89(14) . . ?
C13 C12 H12 120.1 . . ?
C12 C13 H13 119.8 . . ?
C12 C13 C14 120.44(14) . . ?
C14 C13 H13 119.8 . . ?
C9 C14 H14 119.7 . . ?
C13 C14 C9 120.50(14) . . ?
C13 C14 H14 119.7 . . ?
C16 C15 P1 123.17(13) . . ?
C20 C15 P1 117.46(12) . . ?
C20 C15 C16 119.37(15) . . ?
C15 C16 H16 119.9 . . ?
C17 C16 C15 120.13(18) . . ?
C17 C16 H16 119.9 . . ?
C16 C17 H17 119.9 . . ?
C18 C17 C16 120.1(2) . . ?
C18 C17 H17 119.9 . . ?
C17 C18 H18 119.8 . . ?
C17 C18 C19 120.32(18) . . ?
C19 C18 H18 119.8 . . ?
C18 C19 H19 120.0 . . ?
C18 C19 C20 120.1(2) . . ?
C20 C19 H19 120.0 . . ?
C15 C20 C19 119.94(19) . . ?
C15 C20 H20 120.0 . . ?
C19 C20 H20 120.0 . . ?
C22 C21 P1 124.17(11) . . ?
C26 C21 P1 116.78(11) . . ?
C26 C21 C22 118.99(14) . . ?
C21 C22 H22 119.8 . . ?
C23 C22 C21 120.33(14) . . ?
C23 C22 H22 119.8 . . ?
C22 C23 H23 119.8 . . ?
C24 C23 C22 120.30(15) . . ?
C24 C23 H23 119.8 . . ?
C23 C24 H24 120.1 . . ?
C23 C24 C25 119.79(15) . . ?
C25 C24 H24 120.1 . . ?
C24 C25 H25 120.0 . . ?
C24 C25 C26 120.08(16) . . ?
C26 C25 H25 120.0 . . ?
C21 C26 H26 119.8 . . ?
C25 C26 C21 120.48(16) . . ?
C25 C26 H26 119.8 . . ?
C28 C27 P2 124.44(11) . . ?
C32 C27 P2 116.31(11) . . ?
C32 C27 C28 119.18(13) . . ?
C27 C28 H28 119.9 . . ?
C29 C28 C27 120.21(15) . . ?
C29 C28 H28 119.9 . . ?
C28 C29 H29 119.9 . . ?
C30 C29 C28 120.10(15) . . ?
C30 C29 H29 119.9 . . ?
C29 C30 H30 119.9 . . ?
C31 C30 C29 120.18(14) . . ?
C31 C30 H30 119.9 . . ?
C30 C31 H31 119.9 . . ?
C30 C31 C32 120.14(16) . . ?
C32 C31 H31 119.9 . . ?
C27 C32 H32 119.9 . . ?
C31 C32 C27 120.19(15) . . ?
C31 C32 H32 119.9 . . ?
C34 C33 P2 123.41(12) . . ?
C38 C33 P2 117.30(12) . . ?
C38 C33 C34 119.17(15) . . ?
C33 C34 H34 120.0 . . ?
C35 C34 C33 119.92(17) . . ?
C35 C34 H34 120.0 . . ?
C34 C35 H35 119.9 . . ?
C36 C35 C34 120.25(19) . . ?
C36 C35 H35 119.9 . . ?
C35 C36 H36 119.8 . . ?
C35 C36 C37 120.39(17) . . ?
C37 C36 H36 119.8 . . ?
C36 C37 H37 119.9 . . ?
C36 C37 C38 120.2(2) . . ?
C38 C37 H37 119.9 . . ?
C33 C38 C37 120.07(19) . . ?
C33 C38 H38 120.0 . . ?
C37 C38 H38 120.0 . . ?

_olex2_exptl_crystal_mounting_method cryoloop
_olex2_submission_special_instructions 'No special instructions were received'
