# Electronic Supplementary Material (ESI) for New Journal of Chemistry.
# This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2024

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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data_C4Et4RhC10H8
_database_code_depnum_ccdc_archive 'CCDC 2302268'
loop_
_audit_author_name
_audit_author_address
'Yulia Nelyubina'
;AN Nesmeyanov Institute of Organoelement Compounds
Russia
;
_audit_update_record             
;
2023-10-19 deposited with the CCDC.	2024-02-05 downloaded from the CCDC.
;
_vrf_PLAT342_C4Et4RhC10H8        
;
PROBLEM: Low Bond Precision on  C-C Bonds ...............    0.02091 Ang.  
RESPONSE: The ethyl groups of the complex cations are severely disordered.
;
_audit_creation_date             2023-10-19
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6408)
;
_shelxl_version_number           2014/6
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C22 H28 Rh, F6 P'
_chemical_formula_sum            'C22 H28 F6 P Rh'
_chemical_formula_weight         540.32
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   15.9090(14)
_cell_length_b                   17.5486(17)
_cell_length_c                   15.8848(16)
_cell_angle_alpha                90
_cell_angle_beta                 90.557(6)
_cell_angle_gamma                90
_cell_volume                     4434.5(7)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    9838
_cell_measurement_temperature    100
_cell_measurement_theta_max      30.69
_cell_measurement_theta_min      2.56
_shelx_estimated_absorpt_T_max   0.956
_shelx_estimated_absorpt_T_min   0.744
_exptl_absorpt_coefficient_mu    0.898
_exptl_absorpt_correction_T_max  0.4330
_exptl_absorpt_correction_T_min  0.3388
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1074 before and 0.0696 after correction.
The Ratio of minimum to maximum transmission is 0.7824.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            yellow
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.619
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    ?
_exptl_crystal_description       plate
_exptl_crystal_F_000             2192
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.35
_exptl_crystal_size_min          0.05
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0697
_diffrn_reflns_av_unetI/netI     0.0666
_diffrn_reflns_Laue_measured_fraction_full 0.979
_diffrn_reflns_Laue_measured_fraction_max 0.979
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            30655
_diffrn_reflns_point_group_measured_fraction_full 0.979
_diffrn_reflns_point_group_measured_fraction_max 0.979
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.000
_diffrn_reflns_theta_min         1.821
_diffrn_ambient_temperature      100
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.979
_diffrn_measured_fraction_theta_max 0.979
_diffrn_measurement_device_type  'Bruker Quest D8'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           1.4
_diffrn_source_power             0.07
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                6571
_reflns_number_total             7725
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL  (Sheldrick, 2008)'
_computing_structure_solution    'SHELXT  (Sheldrick, 2015)'
_refine_diff_density_max         1.965
_refine_diff_density_min         -1.959
_refine_diff_density_rms         0.168
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.038
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     617
_refine_ls_number_reflns         7725
_refine_ls_number_restraints     126
_refine_ls_R_factor_all          0.0978
_refine_ls_R_factor_gt           0.0840
_refine_ls_restrained_S_all      1.039
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1678P)²+49.5686P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2455
_refine_ls_wR_factor_ref         0.2683
_refine_special_details          
;
 Refined as a 2-component twin.
;
_olex2_refinement_description    
;
1. Twinned data refinement
 Scales: 0.649(2)
 0.351(2)
2. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
3. Restrained distances
 C32'-C31' \\sim C31-C32
 with sigma of 0.02
 C31-C25 \\sim C25-C31'
 with sigma of 0.02
 C23-C27 \\sim C23-C27'
 with sigma of 0.02
 C11'-C12' \\sim C12-C11
 with sigma of 0.02
 C6-C5 \\sim C5'-C6'
 with sigma of 0.02
 C1-C5 \\sim C1-C5'
 with sigma of 0.02
 C26-C33' \\sim C33-C26
 with sigma of 0.02
 C33-C34 \\sim C34'-C33'
 with sigma of 0.02
 C30'-C29' \\sim C30-C29
 with sigma of 0.02
 C24-C29' \\sim C24-C29
 with sigma of 0.02
 P2-F12 \\sim P2-F12'
 with sigma of 0.02
 P2-F8' \\sim P2-F8
 with sigma of 0.02
 P2-F10 \\sim P2-F10'
 with sigma of 0.02
 P2-F7 \\sim P2-F7'
 with sigma of 0.02
 P2-F9 \\sim P2-F9'
 with sigma of 0.02
 P2-F11 \\sim P2-F11'
 with sigma of 0.02
 C6'-C5' \\sim C6-C5
 with sigma of 0.02
 C5'-C1 \\sim C5-C1
 with sigma of 0.02
 C27'-C23 \\sim C27-C23
 with sigma of 0.02
 C12'-C11' \\sim C12-C11
 with sigma of 0.02
 C34'-C33' \\sim C34-C33
 with sigma of 0.02
 C30-C29 \\sim C30'-C29'
 with sigma of 0.02
 C33'-C26 \\sim C33-C26
 with sigma of 0.02
 C32'-C31' \\sim C32-C31
 with sigma of 0.02
 C29'-C24 \\sim C29-C24
 with sigma of 0.02
 C4-C11' \\sim C4-C11
 with sigma of 0.02
 C31'-C25 \\sim C31-C25
 with sigma of 0.02
 C28-C27 \\sim C28'-C27'
 with sigma of 0.02
4. Uiso/Uaniso restraints and constraints
Uanis(C21) \\sim Ueq, Uanis(C20) \\sim Ueq: with sigma of 0.01 and sigma for
terminal atoms of 0.02
Uanis(C12') \\sim Ueq, Uanis(C12) \\sim Ueq: with sigma of 0.01 and sigma for
terminal atoms of 0.02
Uanis(C31) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(C27) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(C11') \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(C5) \\sim Ueq, Uanis(C6) \\sim Ueq: with sigma of 0.01 and sigma for
terminal atoms of 0.02
Uanis(C34) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(C29') \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(C30') \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(F10') \\sim Ueq, Uanis(F12) \\sim Ueq: with sigma of 0.01 and sigma for
terminal atoms of 0.02
Uanis(F12) \\sim Ueq, Uanis(F9) \\sim Ueq, Uanis(F8') \\sim Ueq: with sigma of
0.01 and sigma for terminal atoms of 0.02
Uanis(F12) \\sim Ueq: with sigma of 0.005 and sigma for terminal atoms of 0.01
Uanis(F9') \\sim Ueq: with sigma of 0.005 and sigma for terminal atoms of 0.01
Uanis(F11') \\sim Ueq: with sigma of 0.005 and sigma for terminal atoms of 0.01
Uanis(C11) = Uanis(C11')
Uanis(C12') = Uanis(C12)
Uanis(C31') = Uanis(C31)
Uanis(C32') = Uanis(C32)
Uanis(C27') = Uanis(C27)
Uanis(C28') = Uanis(C28)
Uanis(C6) = Uanis(C6')
Uanis(C5') = Uanis(C5)
Uanis(C33') = Uanis(C33)
Uanis(C34) = Uanis(C34')
Uanis(C30') = Uanis(C30)
Uanis(C29) = Uanis(C29')
Uanis(F9) = Uanis(F9')
Uanis(F10') = Uanis(F10)
Uanis(F8) = Uanis(F8')
Uanis(F12') = Uanis(F12)
Uanis(F7) = Uanis(F7')
Uanis(F11') = Uanis(F11)
5. Others
 Sof(C31')=Sof(H31C)=Sof(H31D)=Sof(C32')=Sof(H32D)=Sof(H32E)=Sof(H32F)=1-FVAR(1)
 Sof(C31)=Sof(H31A)=Sof(H31B)=Sof(C32)=Sof(H32A)=Sof(H32B)=Sof(H32C)=FVAR(1)
 Sof(C27')=Sof(H27C)=Sof(H27D)=Sof(C28')=Sof(H28D)=Sof(H28E)=Sof(H28F)=1-FVAR(2)
 Sof(C27)=Sof(H27A)=Sof(H27B)=Sof(C28)=Sof(H28A)=Sof(H28B)=Sof(H28C)=FVAR(2)
 Sof(C11)=Sof(H11C)=Sof(H11D)=Sof(C12)=Sof(H12D)=Sof(H12E)=Sof(H12F)=1-FVAR(3)
 Sof(C11')=Sof(H11A)=Sof(H11B)=Sof(C12')=Sof(H12A)=Sof(H12B)=Sof(H12C)=FVAR(3)
 Sof(C5)=Sof(H5A)=Sof(H5B)=Sof(C6)=Sof(H6A)=Sof(H6B)=Sof(H6C)=1-FVAR(4)
 Sof(C5')=Sof(H5'A)=Sof(H5'B)=Sof(C6')=Sof(H6'A)=Sof(H6'B)=Sof(H6'C)=FVAR(4)
 Sof(C33')=Sof(H33C)=Sof(H33D)=Sof(C34')=Sof(H34D)=Sof(H34E)=Sof(H34F)=1-FVAR(5)
 Sof(C33)=Sof(H33A)=Sof(H33B)=Sof(C34)=Sof(H34A)=Sof(H34B)=Sof(H34C)=FVAR(5)
 Sof(C29)=Sof(H29A)=Sof(H29B)=Sof(C30)=Sof(H30A)=Sof(H30B)=Sof(H30C)=1-FVAR(6)
 Sof(C29')=Sof(H29C)=Sof(H29D)=Sof(C30')=Sof(H30D)=Sof(H30E)=Sof(H30F)=FVAR(6)
 Sof(F7)=Sof(F8)=Sof(F9)=Sof(F10)=Sof(F11)=Sof(F12)=1-FVAR(7)
 Sof(F7')=Sof(F8')=Sof(F9')=Sof(F10')=Sof(F11')=Sof(F12')=FVAR(7)
6.a Secondary CH2 refined with riding coordinates:
 C7(H7A,H7B), C9(H9A,H9B), C5'(H5'A,H5'B), C11'(H11A,H11B), C5(H5A,H5B),
 C11(H11C,H11D), C27(H27A,H27B), C29(H29A,H29B), C31(H31A,H31B), C33(H33A,H33B),
  C27'(H27C,H27D), C29'(H29C,H29D), C31'(H31C,H31D), C33'(H33C,H33D)
6.b Aromatic/amide H refined with riding coordinates:
 C14(H14), C15(H15), C16(H16), C17(H17), C19(H19), C20(H20), C21(H21),
 C22(H22), C36(H36), C37(H37), C38(H38), C39(H39), C41(H41), C42(H42), C43(H43),
  C44(H44)
6.c Idealised Me refined as rotating group:
 C8(H8A,H8B,H8C), C10(H10A,H10B,H10C), C6'(H6'A,H6'B,H6'C), C12'(H12A,H12B,
 H12C), C6(H6A,H6B,H6C), C12(H12D,H12E,H12F), C28(H28A,H28B,H28C), C30(H30A,
 H30B,H30C), C32(H32A,H32B,H32C), C34(H34A,H34B,H34C), C28'(H28D,H28E,H28F),
 C30'(H30D,H30E,H30F), C32'(H32D,H32E,H32F), C34'(H34D,H34E,H34F)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.30561(6) 0.59559(4) 0.87258(6) 0.0262(3) Uani 1 1 d . . . . .
C1 C 0.3128(9) 0.7161(7) 0.8782(9) 0.037(3) Uani 1 1 d D . . . .
C2 C 0.2806(8) 0.6915(6) 0.7966(8) 0.028(3) Uani 1 1 d . . . . .
C3 C 0.3627(8) 0.6611(7) 0.7781(10) 0.036(3) Uani 1 1 d . . . . .
C4 C 0.3931(9) 0.6838(7) 0.8603(11) 0.046(4) Uani 1 1 d D . . . .
C7 C 0.1994(8) 0.7020(7) 0.7481(8) 0.033(3) Uani 1 1 d . . . . .
H7A H 0.1518 0.7015 0.7878 0.040 Uiso 1 1 calc R U . . .
H7B H 0.1918 0.6588 0.7086 0.040 Uiso 1 1 calc R U . . .
C8 C 0.1982(9) 0.7765(7) 0.6987(9) 0.040(3) Uani 1 1 d . . . . .
H8A H 0.2434 0.7761 0.6572 0.060 Uiso 1 1 calc R U . . .
H8B H 0.2066 0.8193 0.7375 0.060 Uiso 1 1 calc R U . . .
H8C H 0.1439 0.7820 0.6697 0.060 Uiso 1 1 calc R U . . .
C9 C 0.4069(9) 0.6317(8) 0.7039(11) 0.043(3) Uani 1 1 d . . . . .
H9A H 0.4456 0.5906 0.7220 0.052 Uiso 1 1 calc R U . . .
H9B H 0.4412 0.6732 0.6797 0.052 Uiso 1 1 calc R U . . .
C10 C 0.3479(11) 0.6007(8) 0.6355(11) 0.048(4) Uani 1 1 d . . . . .
H10A H 0.3811 0.5799 0.5892 0.071 Uiso 1 1 calc R U . . .
H10B H 0.3119 0.6419 0.6143 0.071 Uiso 1 1 calc R U . . .
H10C H 0.3127 0.5603 0.6592 0.071 Uiso 1 1 calc R U . . .
C13 C 0.1859(8) 0.5214(7) 0.9018(9) 0.034(3) Uani 1 1 d . . . . .
C14 C 0.2304(9) 0.4895(7) 0.8364(9) 0.037(3) Uani 1 1 d . . . . .
H14 H 0.2044 0.4826 0.7828 0.044 Uiso 1 1 calc R U . . .
C15 C 0.3149(9) 0.4674(7) 0.8496(11) 0.044(4) Uani 1 1 d . . . . .
H15 H 0.3433 0.4405 0.8065 0.053 Uiso 1 1 calc R U . . .
C16 C 0.3578(9) 0.4841(7) 0.9245(11) 0.045(4) Uani 1 1 d . . . . .
H16 H 0.4157 0.4718 0.9307 0.054 Uiso 1 1 calc R U . . .
C17 C 0.3153(9) 0.5183(8) 0.9886(10) 0.047(4) Uani 1 1 d . . . . .
H17 H 0.3449 0.5310 1.0389 0.057 Uiso 1 1 calc R U . . .
C18 C 0.2271(9) 0.5357(8) 0.9823(9) 0.038(3) Uani 1 1 d . . . . .
C19 C 0.1832(11) 0.5670(11) 1.0479(11) 0.062(5) Uani 1 1 d . . . . .
H19 H 0.2111 0.5785 1.0995 0.074 Uiso 1 1 calc R U . . .
C20 C 0.0989(14) 0.5815(13) 1.0384(15) 0.078(6) Uani 1 1 d . U . . .
H20 H 0.0676 0.6000 1.0848 0.093 Uiso 1 1 calc R U . . .
C21 C 0.0574(13) 0.5687(13) 0.9574(14) 0.074(5) Uani 1 1 d . U . . .
H21 H -0.0007 0.5804 0.9511 0.089 Uiso 1 1 calc R U . . .
C22 C 0.0994(9) 0.5408(9) 0.8922(13) 0.056(5) Uani 1 1 d . . . . .
H22 H 0.0718 0.5339 0.8395 0.067 Uiso 1 1 calc R U . . .
C5' C 0.264(3) 0.761(2) 0.944(2) 0.034(5) Uani 0.40(5) 1 d D . P A 1
H5'A H 0.2836 0.7427 0.9994 0.041 Uiso 0.40(5) 1 calc R U P A 1
H5'B H 0.2821 0.8145 0.9388 0.041 Uiso 0.40(5) 1 calc R U P A 1
C6' C 0.169(3) 0.762(4) 0.947(4) 0.056(8) Uani 0.40(5) 1 d D . P A 1
H6'A H 0.1474 0.7998 0.9068 0.084 Uiso 0.40(5) 1 calc R U P A 1
H6'B H 0.1512 0.7754 1.0038 0.084 Uiso 0.40(5) 1 calc R U P A 1
H6'C H 0.1471 0.7115 0.9320 0.084 Uiso 0.40(5) 1 calc R U P A 1
C11' C 0.468(2) 0.695(2) 0.920(2) 0.037(6) Uani 0.46(4) 1 d D U P B 1
H11A H 0.4993 0.7419 0.9048 0.045 Uiso 0.46(4) 1 calc R U P B 1
H11B H 0.4480 0.7011 0.9789 0.045 Uiso 0.46(4) 1 calc R U P B 1
C12' C 0.524(2) 0.626(2) 0.913(3) 0.047(6) Uani 0.46(4) 1 d D U P B 1
H12A H 0.5123 0.5997 0.8597 0.071 Uiso 0.46(4) 1 calc R U P B 1
H12B H 0.5127 0.5908 0.9599 0.071 Uiso 0.46(4) 1 calc R U P B 1
H12C H 0.5830 0.6414 0.9152 0.071 Uiso 0.46(4) 1 calc R U P B 1
C5 C 0.294(2) 0.7697(14) 0.9498(14) 0.034(5) Uani 0.60(5) 1 d D U P A 2
H5A H 0.3177 0.8207 0.9380 0.041 Uiso 0.60(5) 1 calc R U P A 2
H5B H 0.3197 0.7503 1.0027 0.041 Uiso 0.60(5) 1 calc R U P A 2
C6 C 0.200(3) 0.775(2) 0.958(3) 0.056(8) Uani 0.60(5) 1 d D U P A 2
H6A H 0.1753 0.7969 0.9071 0.084 Uiso 0.60(5) 1 calc R U P A 2
H6B H 0.1859 0.8066 1.0068 0.084 Uiso 0.60(5) 1 calc R U P A 2
H6C H 0.1766 0.7234 0.9667 0.084 Uiso 0.60(5) 1 calc R U P A 2
C11 C 0.4837(14) 0.6873(18) 0.896(2) 0.037(6) Uani 0.54(4) 1 d D . P B 2
H11C H 0.5085 0.7361 0.8767 0.045 Uiso 0.54(4) 1 calc R U P B 2
H11D H 0.4799 0.6899 0.9577 0.045 Uiso 0.54(4) 1 calc R U P B 2
C12 C 0.5456(19) 0.6247(17) 0.875(3) 0.047(6) Uani 0.54(4) 1 d D U P B 2
H12D H 0.5781 0.6395 0.8251 0.071 Uiso 0.54(4) 1 calc R U P B 2
H12E H 0.5149 0.5774 0.8624 0.071 Uiso 0.54(4) 1 calc R U P B 2
H12F H 0.5838 0.6166 0.9225 0.071 Uiso 0.54(4) 1 calc R U P B 2
Rh2 Rh 0.20901(6) 0.40222(5) 0.39364(7) 0.0281(3) Uani 1 1 d . . . . .
C23 C 0.1581(9) 0.2932(8) 0.4041(10) 0.040(3) Uani 1 1 d D . . . .
C24 C 0.2255(7) 0.2915(7) 0.3468(10) 0.036(3) Uani 1 1 d D . . . .
C25 C 0.1768(11) 0.3358(8) 0.2852(10) 0.048(4) Uani 1 1 d D . . . .
C26 C 0.1093(8) 0.3383(8) 0.3420(10) 0.042(3) Uani 1 1 d D . . . .
C35 C 0.3302(9) 0.4607(7) 0.4564(10) 0.040(3) Uani 1 1 d . . . . .
C36 C 0.3055(10) 0.4992(8) 0.3829(11) 0.047(4) Uani 1 1 d . . . . .
H36 H 0.3446 0.5048 0.3385 0.057 Uiso 1 1 calc R U . . .
C37 C 0.2237(10) 0.5299(7) 0.3734(10) 0.045(4) Uani 1 1 d . . . . .
H37 H 0.2089 0.5575 0.3240 0.054 Uiso 1 1 calc R U . . .
C38 C 0.1648(11) 0.5196(8) 0.4369(12) 0.050(4) Uani 1 1 d . . . . .
H38 H 0.1106 0.5418 0.4316 0.060 Uiso 1 1 calc R U . . .
C39 C 0.1855(9) 0.4759(7) 0.5095(10) 0.042(3) Uani 1 1 d . . . . .
H39 H 0.1443 0.4662 0.5510 0.050 Uiso 1 1 calc R U . . .
C40 C 0.2694(8) 0.4464(7) 0.5196(10) 0.036(3) Uani 1 1 d . . . . .
C41 C 0.2940(9) 0.4041(7) 0.5929(9) 0.036(3) Uani 1 1 d . . . . .
H41 H 0.2529 0.3923 0.6339 0.043 Uiso 1 1 calc R U . . .
C42 C 0.3745(10) 0.3802(8) 0.6055(10) 0.044(4) Uani 1 1 d . . . . .
H42 H 0.3898 0.3523 0.6546 0.053 Uiso 1 1 calc R U . . .
C43 C 0.4352(10) 0.3981(9) 0.5433(13) 0.054(5) Uani 1 1 d . . . . .
H43 H 0.4922 0.3838 0.5524 0.065 Uiso 1 1 calc R U . . .
C44 C 0.4144(9) 0.4337(9) 0.4744(12) 0.052(4) Uani 1 1 d . . . . .
H44 H 0.4567 0.4424 0.4338 0.063 Uiso 1 1 calc R U . . .
C27 C 0.1344(18) 0.2568(14) 0.4863(15) 0.055(6) Uani 0.68(3) 1 d D U P C 1
H27A H 0.0777 0.2731 0.5040 0.065 Uiso 0.68(3) 1 calc R U P C 1
H27B H 0.1755 0.2697 0.5313 0.065 Uiso 0.68(3) 1 calc R U P C 1
C28 C 0.136(2) 0.1623(13) 0.4639(19) 0.066(8) Uani 0.68(3) 1 d D . P C 1
H28A H 0.1880 0.1503 0.4334 0.100 Uiso 0.68(3) 1 calc R U P C 1
H28B H 0.0875 0.1491 0.4291 0.100 Uiso 0.68(3) 1 calc R U P C 1
H28C H 0.1352 0.1331 0.5165 0.100 Uiso 0.68(3) 1 calc R U P C 1
C29 C 0.3086(11) 0.2503(13) 0.3406(13) 0.050(5) Uani 0.87(4) 1 d D . P D 1
H29A H 0.3492 0.2834 0.3111 0.060 Uiso 0.87(4) 1 calc R U P D 1
H29B H 0.3006 0.2037 0.3064 0.060 Uiso 0.87(4) 1 calc R U P D 1
C30 C 0.3450(16) 0.2284(13) 0.4256(15) 0.064(7) Uani 0.87(4) 1 d D . P D 1
H30A H 0.3998 0.2039 0.4179 0.096 Uiso 0.87(4) 1 calc R U P D 1
H30B H 0.3068 0.1929 0.4536 0.096 Uiso 0.87(4) 1 calc R U P D 1
H30C H 0.3520 0.2742 0.4603 0.096 Uiso 0.87(4) 1 calc R U P D 1
C31 C 0.1755(17) 0.3632(18) 0.1935(15) 0.055(6) Uani 0.63(2) 1 d D U P E 1
H31A H 0.1457 0.3255 0.1577 0.066 Uiso 0.63(2) 1 calc R U P E 1
H31B H 0.1451 0.4123 0.1894 0.066 Uiso 0.63(2) 1 calc R U P E 1
C32 C 0.2645(19) 0.3732(16) 0.163(2) 0.069(7) Uani 0.63(2) 1 d D . P E 1
H32A H 0.2644 0.4062 0.1132 0.103 Uiso 0.63(2) 1 calc R U P E 1
H32B H 0.2879 0.3233 0.1482 0.103 Uiso 0.63(2) 1 calc R U P E 1
H32C H 0.2988 0.3964 0.2076 0.103 Uiso 0.63(2) 1 calc R U P E 1
C33 C 0.0217(11) 0.3659(13) 0.3256(12) 0.044(5) Uani 0.77(3) 1 d D . P F 1
H33A H 0.0250 0.4105 0.2875 0.053 Uiso 0.77(3) 1 calc R U P F 1
H33B H -0.0090 0.3253 0.2949 0.053 Uiso 0.77(3) 1 calc R U P F 1
C34 C -0.0247(17) 0.3861(18) 0.392(2) 0.064(8) Uani 0.77(3) 1 d D U P F 1
H34A H -0.0729 0.4166 0.3734 0.096 Uiso 0.77(3) 1 calc R U P F 1
H34B H 0.0098 0.4163 0.4315 0.096 Uiso 0.77(3) 1 calc R U P F 1
H34C H -0.0448 0.3403 0.4211 0.096 Uiso 0.77(3) 1 calc R U P F 1
C27' C 0.170(3) 0.244(3) 0.482(3) 0.055(6) Uani 0.32(3) 1 d D . P C 2
H27C H 0.1787 0.2747 0.5331 0.065 Uiso 0.32(3) 1 calc R U P C 2
H27D H 0.2177 0.2079 0.4753 0.065 Uiso 0.32(3) 1 calc R U P C 2
C28' C 0.076(4) 0.198(3) 0.482(4) 0.066(8) Uani 0.32(3) 1 d D . P C 2
H28D H 0.0762 0.1583 0.4385 0.100 Uiso 0.32(3) 1 calc R U P C 2
H28E H 0.0313 0.2347 0.4698 0.100 Uiso 0.32(3) 1 calc R U P C 2
H28F H 0.0675 0.1749 0.5371 0.100 Uiso 0.32(3) 1 calc R U P C 2
C29' C 0.292(6) 0.233(5) 0.367(11) 0.050(5) Uani 0.13(4) 1 d D U P D 2
H29C H 0.2959 0.1978 0.3186 0.060 Uiso 0.13(4) 1 calc R U P D 2
H29D H 0.2722 0.2026 0.4156 0.060 Uiso 0.13(4) 1 calc R U P D 2
C30' C 0.380(7) 0.260(8) 0.388(11) 0.064(7) Uani 0.13(4) 1 d D U P D 2
H30D H 0.3775 0.3059 0.4227 0.096 Uiso 0.13(4) 1 calc R U P D 2
H30E H 0.4101 0.2710 0.3358 0.096 Uiso 0.13(4) 1 calc R U P D 2
H30F H 0.4103 0.2198 0.4192 0.096 Uiso 0.13(4) 1 calc R U P D 2
C31' C 0.206(3) 0.342(2) 0.1931(18) 0.055(6) Uani 0.37(2) 1 d D . P E 2
H31C H 0.2668 0.3319 0.1912 0.066 Uiso 0.37(2) 1 calc R U P E 2
H31D H 0.1770 0.3025 0.1595 0.066 Uiso 0.37(2) 1 calc R U P E 2
C32' C 0.190(4) 0.418(2) 0.152(4) 0.069(7) Uani 0.37(2) 1 d D . P E 2
H32D H 0.2313 0.4271 0.1081 0.103 Uiso 0.37(2) 1 calc R U P E 2
H32E H 0.1938 0.4588 0.1944 0.103 Uiso 0.37(2) 1 calc R U P E 2
H32F H 0.1331 0.4186 0.1268 0.103 Uiso 0.37(2) 1 calc R U P E 2
C33' C 0.022(2) 0.331(4) 0.376(4) 0.044(5) Uani 0.23(3) 1 d D . P F 2
H33C H -0.0116 0.3220 0.3238 0.053 Uiso 0.23(3) 1 calc R U P F 2
H33D H 0.0240 0.2815 0.4046 0.053 Uiso 0.23(3) 1 calc R U P F 2
C34' C -0.033(6) 0.370(7) 0.423(7) 0.064(8) Uani 0.23(3) 1 d D . P F 2
H34D H -0.0846 0.3797 0.3904 0.096 Uiso 0.23(3) 1 calc R U P F 2
H34E H -0.0082 0.4184 0.4410 0.096 Uiso 0.23(3) 1 calc R U P F 2
H34F H -0.0470 0.3396 0.4731 0.096 Uiso 0.23(3) 1 calc R U P F 2
P1 P 0.4377(2) 0.6139(2) 1.2066(2) 0.0352(8) Uani 1 1 d . . . . .
F1 F 0.4641(6) 0.5808(7) 1.1186(7) 0.073(3) Uani 1 1 d . . . . .
F2 F 0.4773(6) 0.5429(6) 1.2549(8) 0.069(3) Uani 1 1 d . . . . .
F3 F 0.4112(6) 0.6476(5) 1.2945(7) 0.059(3) Uani 1 1 d . . . . .
F4 F 0.3982(6) 0.6858(6) 1.1599(7) 0.064(3) Uani 1 1 d . . . . .
F5 F 0.5252(6) 0.6593(7) 1.2159(7) 0.076(3) Uani 1 1 d . . . . .
F6 F 0.3488(5) 0.5709(5) 1.1990(6) 0.051(2) Uani 1 1 d . . . . .
P2 P 0.0331(3) 0.3673(3) 0.7041(3) 0.0464(10) Uani 1 1 d D . . . .
F7' F 0.1251(18) 0.332(3) 0.712(2) 0.050(5) Uani 0.384(11) 1 d D . P G 1
F8' F 0.032(4) 0.383(6) 0.6072(16) 0.068(7) Uani 0.384(11) 1 d D U P G 1
F9' F -0.0674(11) 0.3825(17) 0.691(2) 0.062(4) Uani 0.384(11) 1 d D U P G 1
F10' F 0.016(2) 0.328(2) 0.7931(15) 0.081(5) Uani 0.384(11) 1 d D U P G 1
F11' F 0.0512(17) 0.4502(12) 0.738(2) 0.057(4) Uani 0.384(11) 1 d D U P G 1
F12' F 0.004(2) 0.2848(13) 0.671(2) 0.079(5) Uani 0.384(11) 1 d D . P G 1
F7 F 0.1217(11) 0.3336(18) 0.6775(11) 0.050(5) Uani 0.616(11) 1 d D . P G 2
F8 F 0.008(2) 0.379(3) 0.6096(12) 0.068(7) Uani 0.616(11) 1 d D . P G 2
F9 F -0.0494(9) 0.4171(11) 0.7296(12) 0.062(4) Uani 0.616(11) 1 d D U P G 2
F10 F 0.0645(15) 0.3749(13) 0.8004(10) 0.081(5) Uani 0.616(11) 1 d D . P G 2
F11 F 0.0819(10) 0.4504(8) 0.6946(11) 0.057(4) Uani 0.616(11) 1 d D . P G 2
F12 F -0.0091(13) 0.2880(10) 0.7144(15) 0.079(5) Uani 0.616(11) 1 d D U P G 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 C1 2.120(12) . ?
Rh1 C2 2.107(11) . ?
Rh1 C3 2.103(13) . ?
Rh1 C4 2.093(13) . ?
Rh1 C13 2.357(13) . ?
Rh1 C14 2.283(13) . ?
Rh1 C15 2.284(13) . ?
Rh1 C16 2.277(13) . ?
Rh1 C17 2.292(14) . ?
Rh1 C18 2.397(14) . ?
C1 C2 1.455(18) . ?
C1 C3 2.03(2) . ?
C1 C4 1.43(2) . ?
C1 C5' 1.52(2) . ?
C1 C5 1.51(2) . ?
C2 C3 1.444(19) . ?
C2 C7 1.508(17) . ?
C3 C4 1.44(2) . ?
C3 C9 1.47(2) . ?
C4 C11' 1.53(2) . ?
C4 C11 1.54(2) . ?
C7 H7A 0.9900 . ?
C7 H7B 0.9900 . ?
C7 C8 1.525(17) . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C9 H9A 0.9900 . ?
C9 H9B 0.9900 . ?
C9 C10 1.53(2) . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C13 C14 1.38(2) . ?
C13 C18 1.453(19) . ?
C13 C22 1.423(19) . ?
C14 H14 0.9500 . ?
C14 C15 1.41(2) . ?
C15 H15 0.9500 . ?
C15 C16 1.40(2) . ?
C16 H16 0.9500 . ?
C16 C17 1.37(2) . ?
C17 H17 0.9500 . ?
C17 C18 1.44(2) . ?
C18 C19 1.37(2) . ?
C19 H19 0.9500 . ?
C19 C20 1.37(3) . ?
C20 H20 0.9500 . ?
C20 C21 1.46(3) . ?
C21 H21 0.9500 . ?
C21 C22 1.33(3) . ?
C22 H22 0.9500 . ?
C5' H5'A 0.9900 . ?
C5' H5'B 0.9900 . ?
C5' C6' 1.51(3) . ?
C6' H6'A 0.9800 . ?
C6' H6'B 0.9800 . ?
C6' H6'C 0.9800 . ?
C11' H11A 0.9900 . ?
C11' H11B 0.9900 . ?
C11' C12' 1.52(3) . ?
C12' H12A 0.9800 . ?
C12' H12B 0.9800 . ?
C12' H12C 0.9800 . ?
C5 H5A 0.9900 . ?
C5 H5B 0.9900 . ?
C5 C6 1.51(3) . ?
C6 H6A 0.9800 . ?
C6 H6B 0.9800 . ?
C6 H6C 0.9800 . ?
C11 H11C 0.9900 . ?
C11 H11D 0.9900 . ?
C11 C12 1.52(3) . ?
C12 H12D 0.9800 . ?
C12 H12E 0.9800 . ?
C12 H12F 0.9800 . ?
Rh2 C23 2.085(13) . ?
Rh2 C24 2.097(12) . ?
Rh2 C25 2.139(14) . ?
Rh2 C26 2.103(13) . ?
Rh2 C35 2.392(12) . ?
Rh2 C36 2.299(13) . ?
Rh2 C37 2.275(12) . ?
Rh2 C38 2.284(14) . ?
Rh2 C39 2.283(14) . ?
Rh2 C40 2.342(14) . ?
C23 C24 1.41(2) . ?
C23 C26 1.48(2) . ?
C23 C27 1.50(3) . ?
C23 C27' 1.52(3) . ?
C24 C25 1.47(2) . ?
C24 C26 2.024(18) . ?
C24 C29 1.511(19) . ?
C24 C29' 1.51(3) . ?
C25 C26 1.41(2) . ?
C25 C31 1.53(3) . ?
C25 C31' 1.54(3) . ?
C26 C33 1.50(2) . ?
C26 C33' 1.50(3) . ?
C35 C36 1.40(2) . ?
C35 C40 1.42(2) . ?
C35 C44 1.45(2) . ?
C36 H36 0.9500 . ?
C36 C37 1.42(2) . ?
C37 H37 0.9500 . ?
C37 C38 1.39(3) . ?
C38 H38 0.9500 . ?
C38 C39 1.42(2) . ?
C39 H39 0.9500 . ?
C39 C40 1.438(19) . ?
C40 C41 1.43(2) . ?
C41 H41 0.9500 . ?
C41 C42 1.36(2) . ?
C42 H42 0.9500 . ?
C42 C43 1.42(3) . ?
C43 H43 0.9500 . ?
C43 C44 1.30(3) . ?
C44 H44 0.9500 . ?
C27 H27A 0.9900 . ?
C27 H27B 0.9900 . ?
C27 C28 1.70(3) . ?
C28 H28A 0.9800 . ?
C28 H28B 0.9800 . ?
C28 H28C 0.9800 . ?
C29 H29A 0.9900 . ?
C29 H29B 0.9900 . ?
C29 C30 1.51(3) . ?
C30 H30A 0.9800 . ?
C30 H30B 0.9800 . ?
C30 H30C 0.9800 . ?
C31 H31A 0.9900 . ?
C31 H31B 0.9900 . ?
C31 C32 1.51(3) . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32 H32C 0.9800 . ?
C33 H33A 0.9900 . ?
C33 H33B 0.9900 . ?
C33 C34 1.35(3) . ?
C34 H34A 0.9800 . ?
C34 H34B 0.9800 . ?
C34 H34C 0.9800 . ?
C27' H27C 0.9900 . ?
C27' H27D 0.9900 . ?
C27' C28' 1.69(3) . ?
C28' H28D 0.9800 . ?
C28' H28E 0.9800 . ?
C28' H28F 0.9800 . ?
C29' H29C 0.9900 . ?
C29' H29D 0.9900 . ?
C29' C30' 1.51(3) . ?
C30' H30D 0.9800 . ?
C30' H30E 0.9800 . ?
C30' H30F 0.9800 . ?
C31' H31C 0.9900 . ?
C31' H31D 0.9900 . ?
C31' C32' 1.50(3) . ?
C32' H32D 0.9800 . ?
C32' H32E 0.9800 . ?
C32' H32F 0.9800 . ?
C33' H33C 0.9900 . ?
C33' H33D 0.9900 . ?
C33' C34' 1.34(3) . ?
C34' H34D 0.9800 . ?
C34' H34E 0.9800 . ?
C34' H34F 0.9800 . ?
P1 F1 1.575(11) . ?
P1 F2 1.591(10) . ?
P1 F3 1.578(11) . ?
P1 F4 1.590(10) . ?
P1 F5 1.609(10) . ?
P1 F6 1.607(9) . ?
P2 F7' 1.592(16) . ?
P2 F8' 1.562(19) . ?
P2 F9' 1.633(17) . ?
P2 F10' 1.60(2) . ?
P2 F11' 1.577(17) . ?
P2 F12' 1.608(19) . ?
P2 F7 1.589(12) . ?
P2 F8 1.562(16) . ?
P2 F9 1.631(13) . ?
P2 F10 1.611(16) . ?
P2 F11 1.659(14) . ?
P2 F12 1.556(15) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Rh1 C13 125.9(5) . . ?
C1 Rh1 C14 148.4(5) . . ?
C1 Rh1 C15 170.3(6) . . ?
C1 Rh1 C16 145.4(5) . . ?
C1 Rh1 C17 123.6(6) . . ?
C1 Rh1 C18 115.8(5) . . ?
C2 Rh1 C1 40.3(5) . . ?
C2 Rh1 C13 113.9(5) . . ?
C2 Rh1 C14 114.3(5) . . ?
C2 Rh1 C15 135.0(5) . . ?
C2 Rh1 C16 163.8(6) . . ?
C2 Rh1 C17 160.7(6) . . ?
C2 Rh1 C18 132.0(5) . . ?
C3 Rh1 C1 57.4(6) . . ?
C3 Rh1 C2 40.1(5) . . ?
C3 Rh1 C13 142.9(5) . . ?
C3 Rh1 C14 119.6(5) . . ?
C3 Rh1 C15 113.3(6) . . ?
C3 Rh1 C16 124.7(6) . . ?
C3 Rh1 C17 150.6(5) . . ?
C3 Rh1 C18 171.9(5) . . ?
C4 Rh1 C1 39.7(6) . . ?
C4 Rh1 C2 58.5(5) . . ?
C4 Rh1 C3 40.3(6) . . ?
C4 Rh1 C13 165.2(6) . . ?
C4 Rh1 C14 158.0(6) . . ?
C4 Rh1 C15 132.0(6) . . ?
C4 Rh1 C16 115.4(5) . . ?
C4 Rh1 C17 118.2(5) . . ?
C4 Rh1 C18 138.1(6) . . ?
C13 Rh1 C18 35.6(5) . . ?
C14 Rh1 C13 34.6(5) . . ?
C14 Rh1 C15 36.1(5) . . ?
C14 Rh1 C17 75.6(5) . . ?
C14 Rh1 C18 63.3(5) . . ?
C15 Rh1 C13 62.7(5) . . ?
C15 Rh1 C17 62.7(6) . . ?
C15 Rh1 C18 73.7(5) . . ?
C16 Rh1 C13 75.3(5) . . ?
C16 Rh1 C14 65.1(5) . . ?
C16 Rh1 C15 35.6(6) . . ?
C16 Rh1 C17 34.8(6) . . ?
C16 Rh1 C18 63.3(5) . . ?
C17 Rh1 C13 64.1(5) . . ?
C17 Rh1 C18 35.6(5) . . ?
C2 C1 Rh1 69.4(7) . . ?
C2 C1 C3 45.4(7) . . ?
C2 C1 C5' 126(2) . . ?
C2 C1 C5 141.9(17) . . ?
C3 C1 Rh1 60.9(5) . . ?
C4 C1 Rh1 69.1(7) . . ?
C4 C1 C2 90.7(12) . . ?
C4 C1 C3 45.4(8) . . ?
C4 C1 C5' 144(2) . . ?
C4 C1 C5 125.5(19) . . ?
C5' C1 Rh1 121(2) . . ?
C5' C1 C3 171(2) . . ?
C5 C1 Rh1 130.0(14) . . ?
C5 C1 C3 165.9(18) . . ?
C1 C2 Rh1 70.4(7) . . ?
C1 C2 C7 135.3(12) . . ?
C3 C2 Rh1 69.8(7) . . ?
C3 C2 C1 88.8(10) . . ?
C3 C2 C7 135.5(12) . . ?
C7 C2 Rh1 123.1(8) . . ?
C1 C3 Rh1 61.7(6) . . ?
C2 C3 Rh1 70.1(7) . . ?
C2 C3 C1 45.8(7) . . ?
C2 C3 C4 90.6(12) . . ?
C2 C3 C9 137.1(13) . . ?
C4 C3 Rh1 69.5(8) . . ?
C4 C3 C1 44.8(9) . . ?
C4 C3 C9 131.5(13) . . ?
C9 C3 Rh1 126.4(9) . . ?
C9 C3 C1 171.2(10) . . ?
C1 C4 Rh1 71.2(8) . . ?
C1 C4 C3 89.8(11) . . ?
C1 C4 C11' 121(2) . . ?
C1 C4 C11 138.3(18) . . ?
C3 C4 Rh1 70.2(7) . . ?
C3 C4 C11' 148(2) . . ?
C3 C4 C11 130(2) . . ?
C11' C4 Rh1 123.6(18) . . ?
C11 C4 Rh1 128.0(14) . . ?
C2 C7 H7A 109.2 . . ?
C2 C7 H7B 109.2 . . ?
C2 C7 C8 111.9(11) . . ?
H7A C7 H7B 107.9 . . ?
C8 C7 H7A 109.2 . . ?
C8 C7 H7B 109.2 . . ?
C7 C8 H8A 109.5 . . ?
C7 C8 H8B 109.5 . . ?
C7 C8 H8C 109.5 . . ?
H8A C8 H8B 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
C3 C9 H9A 108.9 . . ?
C3 C9 H9B 108.9 . . ?
C3 C9 C10 113.5(12) . . ?
H9A C9 H9B 107.7 . . ?
C10 C9 H9A 108.9 . . ?
C10 C9 H9B 108.9 . . ?
C9 C10 H10A 109.5 . . ?
C9 C10 H10B 109.5 . . ?
C9 C10 H10C 109.5 . . ?
H10A C10 H10B 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
C14 C13 Rh1 69.7(8) . . ?
C14 C13 C18 120.1(12) . . ?
C14 C13 C22 121.2(13) . . ?
C18 C13 Rh1 73.7(7) . . ?
C22 C13 Rh1 128.9(10) . . ?
C22 C13 C18 118.7(13) . . ?
Rh1 C14 H14 123.6 . . ?
C13 C14 Rh1 75.6(8) . . ?
C13 C14 H14 120.2 . . ?
C13 C14 C15 119.6(13) . . ?
C15 C14 Rh1 72.0(8) . . ?
C15 C14 H14 120.2 . . ?
Rh1 C15 H15 129.6 . . ?
C14 C15 Rh1 71.9(8) . . ?
C14 C15 H15 119.1 . . ?
C16 C15 Rh1 71.9(8) . . ?
C16 C15 C14 121.7(15) . . ?
C16 C15 H15 119.1 . . ?
Rh1 C16 H16 125.6 . . ?
C15 C16 Rh1 72.4(8) . . ?
C15 C16 H16 120.5 . . ?
C17 C16 Rh1 73.2(8) . . ?
C17 C16 C15 119.0(13) . . ?
C17 C16 H16 120.5 . . ?
Rh1 C17 H17 124.5 . . ?
C16 C17 Rh1 72.0(9) . . ?
C16 C17 H17 118.9 . . ?
C16 C17 C18 122.1(14) . . ?
C18 C17 Rh1 76.2(8) . . ?
C18 C17 H17 118.9 . . ?
C13 C18 Rh1 70.7(8) . . ?
C17 C18 Rh1 68.2(8) . . ?
C17 C18 C13 117.1(13) . . ?
C19 C18 Rh1 130.4(12) . . ?
C19 C18 C13 120.5(13) . . ?
C19 C18 C17 122.3(15) . . ?
C18 C19 H19 120.2 . . ?
C18 C19 C20 119.7(16) . . ?
C20 C19 H19 120.2 . . ?
C19 C20 H20 119.9 . . ?
C19 C20 C21 120.2(19) . . ?
C21 C20 H20 119.9 . . ?
C20 C21 H21 119.5 . . ?
C22 C21 C20 121.0(19) . . ?
C22 C21 H21 119.5 . . ?
C13 C22 H22 120.1 . . ?
C21 C22 C13 119.8(16) . . ?
C21 C22 H22 120.1 . . ?
C1 C5' H5'A 106.5 . . ?
C1 C5' H5'B 106.5 . . ?
H5'A C5' H5'B 106.5 . . ?
C6' C5' C1 123(4) . . ?
C6' C5' H5'A 106.5 . . ?
C6' C5' H5'B 106.5 . . ?
C5' C6' H6'A 109.5 . . ?
C5' C6' H6'B 109.5 . . ?
C5' C6' H6'C 109.5 . . ?
H6'A C6' H6'B 109.5 . . ?
H6'A C6' H6'C 109.5 . . ?
H6'B C6' H6'C 109.5 . . ?
C4 C11' H11A 110.2 . . ?
C4 C11' H11B 110.2 . . ?
H11A C11' H11B 108.5 . . ?
C12' C11' C4 107(2) . . ?
C12' C11' H11A 110.2 . . ?
C12' C11' H11B 110.2 . . ?
C11' C12' H12A 109.5 . . ?
C11' C12' H12B 109.5 . . ?
C11' C12' H12C 109.5 . . ?
H12A C12' H12B 109.5 . . ?
H12A C12' H12C 109.5 . . ?
H12B C12' H12C 109.5 . . ?
C1 C5 H5A 110.1 . . ?
C1 C5 H5B 110.1 . . ?
C1 C5 C6 108(2) . . ?
H5A C5 H5B 108.5 . . ?
C6 C5 H5A 110.1 . . ?
C6 C5 H5B 110.1 . . ?
C5 C6 H6A 109.5 . . ?
C5 C6 H6B 109.5 . . ?
C5 C6 H6C 109.5 . . ?
H6A C6 H6B 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
C4 C11 H11C 107.4 . . ?
C4 C11 H11D 107.4 . . ?
H11C C11 H11D 106.9 . . ?
C12 C11 C4 120(2) . . ?
C12 C11 H11C 107.4 . . ?
C12 C11 H11D 107.4 . . ?
C11 C12 H12D 109.5 . . ?
C11 C12 H12E 109.5 . . ?
C11 C12 H12F 109.5 . . ?
H12D C12 H12E 109.5 . . ?
H12D C12 H12F 109.5 . . ?
H12E C12 H12F 109.5 . . ?
C23 Rh2 C24 39.5(6) . . ?
C23 Rh2 C25 58.2(6) . . ?
C23 Rh2 C26 41.4(6) . . ?
C23 Rh2 C35 132.2(5) . . ?
C23 Rh2 C36 161.0(6) . . ?
C23 Rh2 C37 162.8(6) . . ?
C23 Rh2 C38 133.0(7) . . ?
C23 Rh2 C39 112.9(6) . . ?
C23 Rh2 C40 113.1(5) . . ?
C24 Rh2 C25 40.5(6) . . ?
C24 Rh2 C26 57.6(5) . . ?
C24 Rh2 C35 116.2(5) . . ?
C24 Rh2 C36 125.0(5) . . ?
C24 Rh2 C37 148.0(6) . . ?
C24 Rh2 C38 169.0(5) . . ?
C24 Rh2 C39 146.3(6) . . ?
C24 Rh2 C40 123.9(5) . . ?
C25 Rh2 C35 139.1(6) . . ?
C25 Rh2 C36 119.9(6) . . ?
C25 Rh2 C37 116.6(5) . . ?
C25 Rh2 C38 131.4(6) . . ?
C25 Rh2 C39 156.7(6) . . ?
C25 Rh2 C40 164.1(5) . . ?
C26 Rh2 C25 38.8(6) . . ?
C26 Rh2 C35 173.2(5) . . ?
C26 Rh2 C36 150.2(6) . . ?
C26 Rh2 C37 123.2(6) . . ?
C26 Rh2 C38 111.4(5) . . ?
C26 Rh2 C39 119.2(6) . . ?
C26 Rh2 C40 144.2(6) . . ?
C36 Rh2 C35 34.7(5) . . ?
C36 Rh2 C40 63.2(5) . . ?
C37 Rh2 C35 63.5(5) . . ?
C37 Rh2 C36 36.0(6) . . ?
C37 Rh2 C38 35.6(6) . . ?
C37 Rh2 C39 64.8(6) . . ?
C37 Rh2 C40 75.7(5) . . ?
C38 Rh2 C35 74.8(5) . . ?
C38 Rh2 C36 64.1(6) . . ?
C38 Rh2 C40 64.5(5) . . ?
C39 Rh2 C35 63.8(5) . . ?
C39 Rh2 C36 75.8(6) . . ?
C39 Rh2 C38 36.3(6) . . ?
C39 Rh2 C40 36.2(5) . . ?
C40 Rh2 C35 35.0(5) . . ?
C24 C23 Rh2 70.7(7) . . ?
C24 C23 C26 88.7(12) . . ?
C24 C23 C27 138.4(17) . . ?
C24 C23 C27' 115(3) . . ?
C26 C23 Rh2 70.0(7) . . ?
C26 C23 C27 132.2(17) . . ?
C26 C23 C27' 155(2) . . ?
C27 C23 Rh2 124.0(13) . . ?
C27' C23 Rh2 123(2) . . ?
C23 C24 Rh2 69.8(7) . . ?
C23 C24 C25 91.1(12) . . ?
C23 C24 C26 47.0(9) . . ?
C23 C24 C29 136.2(15) . . ?
C23 C24 C29' 114(7) . . ?
C25 C24 Rh2 71.3(7) . . ?
C25 C24 C26 44.2(9) . . ?
C25 C24 C29 131.9(16) . . ?
C25 C24 C29' 150(7) . . ?
C26 C24 Rh2 61.3(5) . . ?
C29 C24 Rh2 125.4(11) . . ?
C29 C24 C26 172.4(12) . . ?
C29' C24 Rh2 130(5) . . ?
C29' C24 C26 158(5) . . ?
C24 C25 Rh2 68.2(7) . . ?
C24 C25 C31 143.4(18) . . ?
C24 C25 C31' 121(2) . . ?
C26 C25 Rh2 69.2(8) . . ?
C26 C25 C24 89.5(12) . . ?
C26 C25 C31 126.5(17) . . ?
C26 C25 C31' 147(2) . . ?
C31 C25 Rh2 126.5(14) . . ?
C31' C25 Rh2 131(2) . . ?
C23 C26 Rh2 68.6(7) . . ?
C23 C26 C24 44.3(8) . . ?
C23 C26 C33 140.5(16) . . ?
C23 C26 C33' 102(3) . . ?
C24 C26 Rh2 61.1(5) . . ?
C25 C26 Rh2 72.0(8) . . ?
C25 C26 C23 90.7(11) . . ?
C25 C26 C24 46.4(8) . . ?
C25 C26 C33 127.8(16) . . ?
C25 C26 C33' 160(3) . . ?
C33 C26 Rh2 126.4(11) . . ?
C33 C26 C24 170.9(12) . . ?
C33' C26 Rh2 127(2) . . ?
C33' C26 C24 143(3) . . ?
C36 C35 Rh2 69.0(7) . . ?
C36 C35 C40 119.0(13) . . ?
C36 C35 C44 125.0(16) . . ?
C40 C35 Rh2 70.6(7) . . ?
C40 C35 C44 115.9(14) . . ?
C44 C35 Rh2 133.1(10) . . ?
Rh2 C36 H36 125.0 . . ?
C35 C36 Rh2 76.3(7) . . ?
C35 C36 H36 119.3 . . ?
C35 C36 C37 121.5(15) . . ?
C37 C36 Rh2 71.1(7) . . ?
C37 C36 H36 119.3 . . ?
Rh2 C37 H37 126.4 . . ?
C36 C37 Rh2 72.9(7) . . ?
C36 C37 H37 120.1 . . ?
C38 C37 Rh2 72.5(8) . . ?
C38 C37 C36 119.8(13) . . ?
C38 C37 H37 120.1 . . ?
Rh2 C38 H38 128.8 . . ?
C37 C38 Rh2 71.8(8) . . ?
C37 C38 H38 119.9 . . ?
C37 C38 C39 120.3(14) . . ?
C39 C38 Rh2 71.8(8) . . ?
C39 C38 H38 119.9 . . ?
Rh2 C39 H39 125.3 . . ?
C38 C39 Rh2 71.9(8) . . ?
C38 C39 H39 120.3 . . ?
C38 C39 C40 119.5(15) . . ?
C40 C39 Rh2 74.2(8) . . ?
C40 C39 H39 120.3 . . ?
C35 C40 Rh2 74.4(8) . . ?
C35 C40 C39 119.7(13) . . ?
C35 C40 C41 118.8(12) . . ?
C39 C40 Rh2 69.6(8) . . ?
C41 C40 Rh2 129.0(8) . . ?
C41 C40 C39 121.5(14) . . ?
C40 C41 H41 119.0 . . ?
C42 C41 C40 121.9(14) . . ?
C42 C41 H41 119.0 . . ?
C41 C42 H42 120.9 . . ?
C41 C42 C43 118.3(14) . . ?
C43 C42 H42 120.9 . . ?
C42 C43 H43 119.3 . . ?
C44 C43 C42 121.4(14) . . ?
C44 C43 H43 119.3 . . ?
C35 C44 H44 118.3 . . ?
C43 C44 C35 123.5(17) . . ?
C43 C44 H44 118.3 . . ?
C23 C27 H27A 111.1 . . ?
C23 C27 H27B 111.1 . . ?
C23 C27 C28 103.2(18) . . ?
H27A C27 H27B 109.1 . . ?
C28 C27 H27A 111.1 . . ?
C28 C27 H27B 111.1 . . ?
C27 C28 H28A 109.5 . . ?
C27 C28 H28B 109.5 . . ?
C27 C28 H28C 109.5 . . ?
H28A C28 H28B 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
C24 C29 H29A 109.0 . . ?
C24 C29 H29B 109.0 . . ?
C24 C29 C30 113.0(17) . . ?
H29A C29 H29B 107.8 . . ?
C30 C29 H29A 109.0 . . ?
C30 C29 H29B 109.0 . . ?
C29 C30 H30A 109.5 . . ?
C29 C30 H30B 109.5 . . ?
C29 C30 H30C 109.5 . . ?
H30A C30 H30B 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
C25 C31 H31A 109.7 . . ?
C25 C31 H31B 109.7 . . ?
H31A C31 H31B 108.2 . . ?
C32 C31 C25 110(2) . . ?
C32 C31 H31A 109.7 . . ?
C32 C31 H31B 109.7 . . ?
C31 C32 H32A 109.5 . . ?
C31 C32 H32B 109.5 . . ?
C31 C32 H32C 109.5 . . ?
H32A C32 H32B 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
C26 C33 H33A 107.9 . . ?
C26 C33 H33B 107.9 . . ?
H33A C33 H33B 107.2 . . ?
C34 C33 C26 117.7(19) . . ?
C34 C33 H33A 107.9 . . ?
C34 C33 H33B 107.9 . . ?
C33 C34 H34A 109.5 . . ?
C33 C34 H34B 109.5 . . ?
C33 C34 H34C 109.5 . . ?
H34A C34 H34B 109.5 . . ?
H34A C34 H34C 109.5 . . ?
H34B C34 H34C 109.5 . . ?
C23 C27' H27C 111.8 . . ?
C23 C27' H27D 111.8 . . ?
C23 C27' C28' 100(3) . . ?
H27C C27' H27D 109.6 . . ?
C28' C27' H27C 111.8 . . ?
C28' C27' H27D 111.8 . . ?
C27' C28' H28D 109.5 . . ?
C27' C28' H28E 109.5 . . ?
C27' C28' H28F 109.5 . . ?
H28D C28' H28E 109.5 . . ?
H28D C28' H28F 109.5 . . ?
H28E C28' H28F 109.5 . . ?
C24 C29' H29C 107.6 . . ?
C24 C29' H29D 107.6 . . ?
C24 C29' C30' 119(8) . . ?
H29C C29' H29D 107.0 . . ?
C30' C29' H29C 107.6 . . ?
C30' C29' H29D 107.6 . . ?
C29' C30' H30D 109.5 . . ?
C29' C30' H30E 109.5 . . ?
C29' C30' H30F 109.5 . . ?
H30D C30' H30E 109.5 . . ?
H30D C30' H30F 109.5 . . ?
H30E C30' H30F 109.5 . . ?
C25 C31' H31C 108.5 . . ?
C25 C31' H31D 108.5 . . ?
H31C C31' H31D 107.5 . . ?
C32' C31' C25 115(3) . . ?
C32' C31' H31C 108.5 . . ?
C32' C31' H31D 108.5 . . ?
C31' C32' H32D 109.5 . . ?
C31' C32' H32E 109.5 . . ?
C31' C32' H32F 109.5 . . ?
H32D C32' H32E 109.5 . . ?
H32D C32' H32F 109.5 . . ?
H32E C32' H32F 109.5 . . ?
C26 C33' H33C 101.9 . . ?
C26 C33' H33D 101.9 . . ?
H33C C33' H33D 104.7 . . ?
C34' C33' C26 141(7) . . ?
C34' C33' H33C 101.9 . . ?
C34' C33' H33D 101.9 . . ?
C33' C34' H34D 109.5 . . ?
C33' C34' H34E 109.5 . . ?
C33' C34' H34F 109.5 . . ?
H34D C34' H34E 109.5 . . ?
H34D C34' H34F 109.5 . . ?
H34E C34' H34F 109.5 . . ?
F1 P1 F2 91.8(7) . . ?
F1 P1 F3 179.6(7) . . ?
F1 P1 F4 89.2(7) . . ?
F1 P1 F5 91.5(7) . . ?
F1 P1 F6 90.1(6) . . ?
F2 P1 F5 90.4(6) . . ?
F2 P1 F6 90.7(6) . . ?
F3 P1 F2 88.6(6) . . ?
F3 P1 F4 90.4(6) . . ?
F3 P1 F5 88.4(6) . . ?
F3 P1 F6 90.0(5) . . ?
F4 P1 F2 179.0(7) . . ?
F4 P1 F5 89.3(6) . . ?
F4 P1 F6 89.6(5) . . ?
F6 P1 F5 178.1(6) . . ?
F7' P2 F9' 166(3) . . ?
F7' P2 F10' 85.9(17) . . ?
F7' P2 F12' 86(3) . . ?
F8' P2 F7' 99(3) . . ?
F8' P2 F9' 81(3) . . ?
F8' P2 F10' 161(4) . . ?
F8' P2 F11' 100(4) . . ?
F8' P2 F12' 80(4) . . ?
F10' P2 F9' 90.6(16) . . ?
F10' P2 F12' 81.5(18) . . ?
F11' P2 F7' 100(2) . . ?
F11' P2 F9' 94.0(15) . . ?
F11' P2 F10' 97.1(18) . . ?
F11' P2 F12' 173.8(17) . . ?
F12' P2 F9' 80.0(17) . . ?
F7 P2 F9 169.5(14) . . ?
F7 P2 F10 90.9(11) . . ?
F7 P2 F11 83.5(14) . . ?
F8 P2 F7 90.7(16) . . ?
F8 P2 F9 88.3(18) . . ?
F8 P2 F10 167(2) . . ?
F8 P2 F11 85(2) . . ?
F9 P2 F11 86.0(9) . . ?
F10 P2 F9 87.8(11) . . ?
F10 P2 F11 82.7(11) . . ?
F12 P2 F7 94.6(15) . . ?
F12 P2 F8 97(2) . . ?
F12 P2 F9 95.9(11) . . ?
F12 P2 F10 95.9(12) . . ?
F12 P2 F11 177.6(11) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Rh1 C1 C2 C3 -68.9(7) . . . . ?
Rh1 C1 C2 C7 117.6(14) . . . . ?
Rh1 C1 C4 C3 69.1(7) . . . . ?
Rh1 C1 C4 C11' -119(2) . . . . ?
Rh1 C1 C4 C11 -127(3) . . . . ?
Rh1 C1 C5' C6' -63(5) . . . . ?
Rh1 C1 C5 C6 -75(3) . . . . ?
Rh1 C2 C3 C1 -69.5(7) . . . . ?
Rh1 C2 C3 C4 -67.9(7) . . . . ?
Rh1 C2 C3 C9 122.5(16) . . . . ?
Rh1 C2 C7 C8 179.8(9) . . . . ?
Rh1 C3 C4 C1 -70.0(8) . . . . ?
Rh1 C3 C4 C11' 123(3) . . . . ?
Rh1 C3 C4 C11 124(2) . . . . ?
Rh1 C3 C9 C10 75.0(15) . . . . ?
Rh1 C4 C11' C12' 63(3) . . . . ?
Rh1 C4 C11 C12 55(4) . . . . ?
Rh1 C13 C14 C15 59.2(11) . . . . ?
Rh1 C13 C18 C17 -51.6(11) . . . . ?
Rh1 C13 C18 C19 126.3(15) . . . . ?
Rh1 C13 C22 C21 -94(2) . . . . ?
Rh1 C14 C15 C16 54.2(12) . . . . ?
Rh1 C15 C16 C17 58.5(12) . . . . ?
Rh1 C16 C17 C18 59.9(13) . . . . ?
Rh1 C17 C18 C13 52.8(11) . . . . ?
Rh1 C17 C18 C19 -125.0(15) . . . . ?
Rh1 C18 C19 C20 93(2) . . . . ?
C1 C2 C3 Rh1 69.5(7) . . . . ?
C1 C2 C3 C4 1.6(10) . . . . ?
C1 C2 C3 C9 -168.0(15) . . . . ?
C1 C2 C7 C8 84.7(18) . . . . ?
C1 C3 C4 Rh1 70.0(8) . . . . ?
C1 C3 C4 C11' -167(4) . . . . ?
C1 C3 C4 C11 -166(2) . . . . ?
C1 C4 C11' C12' 150(2) . . . . ?
C1 C4 C11 C12 161(2) . . . . ?
C2 C1 C4 Rh1 -67.6(7) . . . . ?
C2 C1 C4 C3 1.6(10) . . . . ?
C2 C1 C4 C11' 174(2) . . . . ?
C2 C1 C4 C11 166(2) . . . . ?
C2 C1 C5' C6' 22(6) . . . . ?
C2 C1 C5 C6 34(4) . . . . ?
C2 C3 C4 Rh1 68.4(7) . . . . ?
C2 C3 C4 C1 -1.6(10) . . . . ?
C2 C3 C4 C11' -169(3) . . . . ?
C2 C3 C4 C11 -168.0(19) . . . . ?
C2 C3 C9 C10 -25(2) . . . . ?
C3 C1 C2 Rh1 68.9(7) . . . . ?
C3 C1 C2 C7 -173.4(18) . . . . ?
C3 C1 C4 Rh1 -69.1(7) . . . . ?
C3 C1 C4 C11' 172(2) . . . . ?
C3 C1 C4 C11 164(3) . . . . ?
C3 C1 C5 C6 148(5) . . . . ?
C3 C2 C7 C8 -85.9(17) . . . . ?
C3 C4 C11' C12' -45(5) . . . . ?
C3 C4 C11 C12 -40(4) . . . . ?
C4 C1 C2 Rh1 67.3(7) . . . . ?
C4 C1 C2 C3 -1.6(10) . . . . ?
C4 C1 C2 C7 -175.0(14) . . . . ?
C4 C1 C5' C6' -160(4) . . . . ?
C4 C1 C5 C6 -167(2) . . . . ?
C4 C3 C9 C10 169.1(13) . . . . ?
C7 C2 C3 Rh1 -117.1(14) . . . . ?
C7 C2 C3 C1 173.4(18) . . . . ?
C7 C2 C3 C4 175.0(14) . . . . ?
C7 C2 C3 C9 5(3) . . . . ?
C9 C3 C4 Rh1 -121.0(14) . . . . ?
C9 C3 C4 C1 169.0(14) . . . . ?
C9 C3 C4 C11' 2(4) . . . . ?
C9 C3 C4 C11 3(3) . . . . ?
C13 C14 C15 Rh1 -61.1(12) . . . . ?
C13 C14 C15 C16 -7(2) . . . . ?
C13 C18 C19 C20 3(3) . . . . ?
C14 C13 C18 Rh1 54.1(12) . . . . ?
C14 C13 C18 C17 2.5(19) . . . . ?
C14 C13 C18 C19 -179.7(15) . . . . ?
C14 C13 C22 C21 177.4(17) . . . . ?
C14 C15 C16 Rh1 -54.2(12) . . . . ?
C14 C15 C16 C17 4(2) . . . . ?
C15 C16 C17 Rh1 -58.1(12) . . . . ?
C15 C16 C17 C18 2(2) . . . . ?
C16 C17 C18 Rh1 -57.9(12) . . . . ?
C16 C17 C18 C13 -5(2) . . . . ?
C16 C17 C18 C19 177.1(15) . . . . ?
C17 C18 C19 C20 -179.2(18) . . . . ?
C18 C13 C14 Rh1 -56.0(12) . . . . ?
C18 C13 C14 C15 3(2) . . . . ?
C18 C13 C22 C21 -3(2) . . . . ?
C18 C19 C20 C21 -4(3) . . . . ?
C19 C20 C21 C22 2(4) . . . . ?
C20 C21 C22 C13 2(3) . . . . ?
C22 C13 C14 Rh1 124.0(14) . . . . ?
C22 C13 C14 C15 -176.8(13) . . . . ?
C22 C13 C18 Rh1 -125.9(13) . . . . ?
C22 C13 C18 C17 -177.5(13) . . . . ?
C22 C13 C18 C19 0(2) . . . . ?
C5' C1 C2 Rh1 -114(3) . . . . ?
C5' C1 C2 C3 177(2) . . . . ?
C5' C1 C2 C7 4(3) . . . . ?
C5' C1 C4 Rh1 114(3) . . . . ?
C5' C1 C4 C3 -177(3) . . . . ?
C5' C1 C4 C11' -4(4) . . . . ?
C5 C1 C2 Rh1 -129(3) . . . . ?
C5 C1 C2 C3 162(3) . . . . ?
C5 C1 C2 C7 -12(3) . . . . ?
C5 C1 C4 Rh1 125.0(18) . . . . ?
C5 C1 C4 C3 -165.9(18) . . . . ?
C5 C1 C4 C11 -2(3) . . . . ?
Rh2 C23 C24 C25 -69.6(7) . . . . ?
Rh2 C23 C24 C26 -69.2(7) . . . . ?
Rh2 C23 C24 C29 120.5(18) . . . . ?
Rh2 C23 C24 C29' 126(6) . . . . ?
Rh2 C23 C26 C24 69.9(7) . . . . ?
Rh2 C23 C26 C25 70.3(8) . . . . ?
Rh2 C23 C26 C33 -122(2) . . . . ?
Rh2 C23 C26 C33' -125(2) . . . . ?
Rh2 C23 C27 C28 -157.3(15) . . . . ?
Rh2 C23 C27' C28' 146(3) . . . . ?
Rh2 C24 C25 C26 -67.8(8) . . . . ?
Rh2 C24 C25 C31 122(3) . . . . ?
Rh2 C24 C25 C31' 125(2) . . . . ?
Rh2 C24 C29 C30 70(3) . . . . ?
Rh2 C24 C29' C30' -34(20) . . . . ?
Rh2 C25 C26 C23 -67.2(7) . . . . ?
Rh2 C25 C26 C24 -66.9(7) . . . . ?
Rh2 C25 C26 C33 122.5(16) . . . . ?
Rh2 C25 C26 C33' 164(9) . . . . ?
Rh2 C25 C31 C32 73(3) . . . . ?
Rh2 C25 C31' C32' -57(5) . . . . ?
Rh2 C26 C33 C34 -64(3) . . . . ?
Rh2 C26 C33' C34' 25(13) . . . . ?
Rh2 C35 C36 C37 57.3(11) . . . . ?
Rh2 C35 C40 C39 -54.9(10) . . . . ?
Rh2 C35 C40 C41 126.3(11) . . . . ?
Rh2 C35 C44 C43 -87(2) . . . . ?
Rh2 C36 C37 C38 57.4(11) . . . . ?
Rh2 C37 C38 C39 55.1(11) . . . . ?
Rh2 C38 C39 C40 59.1(10) . . . . ?
Rh2 C39 C40 C35 57.3(11) . . . . ?
Rh2 C39 C40 C41 -124.0(11) . . . . ?
Rh2 C40 C41 C42 96.0(14) . . . . ?
C23 C24 C25 Rh2 68.2(7) . . . . ?
C23 C24 C25 C26 0.4(10) . . . . ?
C23 C24 C25 C31 -169(3) . . . . ?
C23 C24 C25 C31' -167(2) . . . . ?
C23 C24 C29 C30 -28(3) . . . . ?
C23 C24 C29' C30' -117(14) . . . . ?
C23 C26 C33 C34 36(3) . . . . ?
C23 C26 C33' C34' 97(11) . . . . ?
C24 C23 C26 Rh2 -69.9(7) . . . . ?
C24 C23 C26 C25 0.4(10) . . . . ?
C24 C23 C26 C33 168.3(19) . . . . ?
C24 C23 C26 C33' 165(3) . . . . ?
C24 C23 C27 C28 -58(3) . . . . ?
C24 C23 C27' C28' -132(3) . . . . ?
C24 C25 C26 Rh2 66.9(7) . . . . ?
C24 C25 C26 C23 -0.4(10) . . . . ?
C24 C25 C26 C33 -170.7(16) . . . . ?
C24 C25 C26 C33' -129(9) . . . . ?
C24 C25 C31 C32 -30(4) . . . . ?
C24 C25 C31' C32' -144(4) . . . . ?
C24 C26 C33' C34' 115(11) . . . . ?
C25 C24 C29 C30 166.0(18) . . . . ?
C25 C24 C29' C30' 96(17) . . . . ?
C25 C26 C33 C34 -159(2) . . . . ?
C25 C26 C33' C34' -136(10) . . . . ?
C26 C23 C24 Rh2 69.2(7) . . . . ?
C26 C23 C24 C25 -0.4(10) . . . . ?
C26 C23 C24 C29 -170.3(18) . . . . ?
C26 C23 C24 C29' -165(6) . . . . ?
C26 C23 C27 C28 110(2) . . . . ?
C26 C23 C27' C28' 30(9) . . . . ?
C26 C24 C25 Rh2 67.8(8) . . . . ?
C26 C24 C25 C31 -170(3) . . . . ?
C26 C24 C25 C31' -167(3) . . . . ?
C26 C24 C29' C30' -147(9) . . . . ?
C26 C25 C31 C32 162.7(19) . . . . ?
C26 C25 C31' C32' 61(6) . . . . ?
C35 C36 C37 Rh2 -59.8(11) . . . . ?
C35 C36 C37 C38 -2.4(19) . . . . ?
C35 C40 C41 C42 3.0(18) . . . . ?
C36 C35 C40 Rh2 51.0(11) . . . . ?
C36 C35 C40 C39 -4.0(18) . . . . ?
C36 C35 C40 C41 177.3(11) . . . . ?
C36 C35 C44 C43 180.0(15) . . . . ?
C36 C37 C38 Rh2 -57.6(11) . . . . ?
C36 C37 C38 C39 -2.4(19) . . . . ?
C37 C38 C39 Rh2 -55.1(11) . . . . ?
C37 C38 C39 C40 3.9(19) . . . . ?
C38 C39 C40 Rh2 -58.0(10) . . . . ?
C38 C39 C40 C35 -0.7(17) . . . . ?
C38 C39 C40 C41 178.0(11) . . . . ?
C39 C40 C41 C42 -175.7(12) . . . . ?
C40 C35 C36 Rh2 -51.7(11) . . . . ?
C40 C35 C36 C37 5.6(19) . . . . ?
C40 C35 C44 C43 0(2) . . . . ?
C40 C41 C42 C43 -0.2(19) . . . . ?
C41 C42 C43 C44 -3(2) . . . . ?
C42 C43 C44 C35 3(2) . . . . ?
C44 C35 C36 Rh2 128.6(14) . . . . ?
C44 C35 C36 C37 -174.1(13) . . . . ?
C44 C35 C40 Rh2 -129.4(12) . . . . ?
C44 C35 C40 C39 175.7(12) . . . . ?
C44 C35 C40 C41 -3.1(17) . . . . ?
C27 C23 C24 Rh2 -120(2) . . . . ?
C27 C23 C24 C25 171(2) . . . . ?
C27 C23 C24 C26 171(2) . . . . ?
C27 C23 C24 C29 1(3) . . . . ?
C27 C23 C26 Rh2 118.2(18) . . . . ?
C27 C23 C26 C24 -172(2) . . . . ?
C27 C23 C26 C25 -171.4(18) . . . . ?
C27 C23 C26 C33 -4(3) . . . . ?
C29 C24 C25 Rh2 -121.2(17) . . . . ?
C29 C24 C25 C26 171.0(16) . . . . ?
C29 C24 C25 C31 1(3) . . . . ?
C31 C25 C26 Rh2 -120.7(19) . . . . ?
C31 C25 C26 C23 172.1(19) . . . . ?
C31 C25 C26 C24 172(2) . . . . ?
C31 C25 C26 C33 2(3) . . . . ?
C27' C23 C24 Rh2 -118(3) . . . . ?
C27' C23 C24 C25 172(3) . . . . ?
C27' C23 C24 C26 173(3) . . . . ?
C27' C23 C24 C29' 8(6) . . . . ?
C27' C23 C26 Rh2 126(6) . . . . ?
C27' C23 C26 C24 -164(7) . . . . ?
C27' C23 C26 C25 -163(6) . . . . ?
C27' C23 C26 C33' 1(7) . . . . ?
C29' C24 C25 Rh2 -141(9) . . . . ?
C29' C24 C25 C26 151(9) . . . . ?
C29' C24 C25 C31' -16(10) . . . . ?
C31' C25 C26 Rh2 -134(4) . . . . ?
C31' C25 C26 C23 159(4) . . . . ?
C31' C25 C26 C24 159(4) . . . . ?
C31' C25 C26 C33' 30(10) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
loop_
_twin_individual_id
_twin_individual_mass_fraction_refined
1 0.649(2)
2 0.351(2)

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_CbRh(PPh3)2+
_database_code_depnum_ccdc_archive 'CCDC 2302269'
loop_
_audit_author_name
_audit_author_address
'Yulia Nelyubina'
;AN Nesmeyanov Institute of Organoelement Compounds
Russia
;
_audit_update_record             
;
2023-10-19 deposited with the CCDC.	2024-02-05 downloaded from the CCDC.
;
_audit_creation_date             2023-10-19
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6408)
;
_shelxl_version_number           2014/6
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C48 H50 P2 Rh, B F4'
_chemical_formula_sum            'C48 H50 B F4 P2 Rh'
_chemical_formula_weight         878.54
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/n 1'
_space_group_name_Hall           '-P 2yn'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   10.7322(2)
_cell_length_b                   26.2556(5)
_cell_length_c                   14.7421(3)
_cell_angle_alpha                90
_cell_angle_beta                 96.0350(10)
_cell_angle_gamma                90
_cell_volume                     4131.01(14)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    6511
_cell_measurement_temperature    100
_cell_measurement_theta_max      30.31
_cell_measurement_theta_min      2.37
_shelx_estimated_absorpt_T_max   0.948
_shelx_estimated_absorpt_T_min   0.923
_exptl_absorpt_coefficient_mu    0.543
_exptl_absorpt_correction_T_max  0.7460
_exptl_absorpt_correction_T_min  0.6085
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2008/1 (Bruker,2008) was used for absorption correction.
wR2(int) was 0.0776 before and 0.0383 after correction.
The Ratio of minimum to maximum transmission is 0.8157.
The λ/2 correction factor is 0.0015.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            red
_exptl_crystal_colour_primary    red
_exptl_crystal_density_diffrn    1.413
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    ?
_exptl_crystal_description       prism
_exptl_crystal_F_000             1816
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.1
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0999
_diffrn_reflns_av_unetI/netI     0.0775
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       34
_diffrn_reflns_limit_k_min       -34
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            51256
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.998
_diffrn_reflns_theta_min         2.060
_diffrn_ambient_temperature      100
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker Quest D8'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           1.4
_diffrn_source_power             0.07
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                7183
_reflns_number_total             9965
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL  (Sheldrick, 2008)'
_computing_structure_solution    'SHELXT 2014/4 (Sheldrick, 2014)'
_refine_diff_density_max         0.534
_refine_diff_density_min         -0.663
_refine_diff_density_rms         0.097
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.047
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     509
_refine_ls_number_reflns         9965
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0742
_refine_ls_R_factor_gt           0.0428
_refine_ls_restrained_S_all      1.047
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0162P)²+2.7780P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0762
_refine_ls_wR_factor_ref         0.0884
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Secondary CH2 refined with riding coordinates:
 C5(H5A,H5B), C7(H7A,H7B), C9(H9A,H9B), C11(H11A,H11B)
2.b Aromatic/amide H refined with riding coordinates:
 C14(H14), C15(H15), C16(H16), C17(H17), C18(H18), C20(H20), C21(H21),
 C22(H22), C23(H23), C24(H24), C26(H26), C27(H27), C28(H28), C29(H29), C30(H30),
  C32(H32), C33(H33), C34(H34), C35(H35), C36(H36), C38(H38), C39(H39),
 C40(H40), C41(H41), C42(H42), C44(H44), C45(H45), C46(H46), C47(H47), C48(H48)
2.c Idealised Me refined as rotating group:
 C6(H6A,H6B,H6C), C8(H8A,H8B,H8C), C10(H10A,H10B,H10C), C12(H12A,H12B,H12C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.36381(2) 0.36921(2) 0.17783(2) 0.01269(6) Uani 1 1 d . . . . .
P1 P 0.42876(7) 0.42709(3) 0.29522(5) 0.01288(16) Uani 1 1 d . . . . .
P2 P 0.17366(7) 0.33749(3) 0.22639(5) 0.01375(16) Uani 1 1 d . . . . .
C1 C 0.4796(3) 0.38750(11) 0.0736(2) 0.0148(6) Uani 1 1 d . . . . .
C2 C 0.3575(3) 0.36861(11) 0.03180(19) 0.0141(6) Uani 1 1 d . . . . .
C3 C 0.3851(3) 0.31850(11) 0.06656(19) 0.0139(6) Uani 1 1 d . . . . .
C4 C 0.5080(3) 0.33698(11) 0.1069(2) 0.0165(6) Uani 1 1 d . . . . .
C5 C 0.5571(3) 0.43239(11) 0.0548(2) 0.0180(7) Uani 1 1 d . . . . .
H5A H 0.6355 0.4324 0.0967 0.022 Uiso 1 1 calc R U . . .
H5B H 0.5107 0.4641 0.0650 0.022 Uiso 1 1 calc R U . . .
C6 C 0.5881(3) 0.43011(12) -0.0444(2) 0.0209(7) Uani 1 1 d . . . . .
H6A H 0.5103 0.4317 -0.0856 0.031 Uiso 1 1 calc R U . . .
H6B H 0.6319 0.3982 -0.0544 0.031 Uiso 1 1 calc R U . . .
H6C H 0.6418 0.4590 -0.0564 0.031 Uiso 1 1 calc R U . . .
C7 C 0.2583(3) 0.38920(11) -0.0365(2) 0.0173(7) Uani 1 1 d . . . . .
H7A H 0.1783 0.3719 -0.0282 0.021 Uiso 1 1 calc R U . . .
H7B H 0.2801 0.3807 -0.0983 0.021 Uiso 1 1 calc R U . . .
C8 C 0.2385(3) 0.44674(11) -0.0310(2) 0.0216(7) Uani 1 1 d . . . . .
H8A H 0.1664 0.4566 -0.0737 0.032 Uiso 1 1 calc R U . . .
H8B H 0.3136 0.4644 -0.0469 0.032 Uiso 1 1 calc R U . . .
H8C H 0.2227 0.4560 0.0312 0.032 Uiso 1 1 calc R U . . .
C9 C 0.3330(3) 0.26740(11) 0.0387(2) 0.0169(6) Uani 1 1 d . . . . .
H9A H 0.2411 0.2675 0.0407 0.020 Uiso 1 1 calc R U . . .
H9B H 0.3695 0.2412 0.0819 0.020 Uiso 1 1 calc R U . . .
C10 C 0.3628(3) 0.25406(11) -0.0581(2) 0.0205(7) Uani 1 1 d . . . . .
H10A H 0.3227 0.2789 -0.1014 0.031 Uiso 1 1 calc R U . . .
H10B H 0.3309 0.2199 -0.0743 0.031 Uiso 1 1 calc R U . . .
H10C H 0.4537 0.2548 -0.0605 0.031 Uiso 1 1 calc R U . . .
C11 C 0.6227(3) 0.31119(12) 0.1504(2) 0.0240(8) Uani 1 1 d . . . . .
H11A H 0.6008 0.2899 0.2017 0.029 Uiso 1 1 calc R U . . .
H11B H 0.6841 0.3371 0.1751 0.029 Uiso 1 1 calc R U . . .
C12 C 0.6813(3) 0.27799(13) 0.0815(2) 0.0294(8) Uani 1 1 d . . . . .
H12A H 0.6990 0.2988 0.0292 0.044 Uiso 1 1 calc R U . . .
H12B H 0.6231 0.2506 0.0608 0.044 Uiso 1 1 calc R U . . .
H12C H 0.7596 0.2632 0.1102 0.044 Uiso 1 1 calc R U . . .
C13 C 0.4992(3) 0.39215(11) 0.39420(19) 0.0134(6) Uani 1 1 d . . . . .
C14 C 0.5078(3) 0.33949(11) 0.3875(2) 0.0171(7) Uani 1 1 d . . . . .
H14 H 0.4714 0.3228 0.3340 0.021 Uiso 1 1 calc R U . . .
C15 C 0.5688(3) 0.31109(12) 0.4576(2) 0.0192(7) Uani 1 1 d . . . . .
H15 H 0.5737 0.2751 0.4522 0.023 Uiso 1 1 calc R U . . .
C16 C 0.6227(3) 0.33506(12) 0.5355(2) 0.0227(7) Uani 1 1 d . . . . .
H16 H 0.6638 0.3156 0.5840 0.027 Uiso 1 1 calc R U . . .
C17 C 0.6166(3) 0.38776(12) 0.5426(2) 0.0219(7) Uani 1 1 d . . . . .
H17 H 0.6541 0.4042 0.5960 0.026 Uiso 1 1 calc R U . . .
C18 C 0.5561(3) 0.41649(12) 0.4723(2) 0.0184(7) Uani 1 1 d . . . . .
H18 H 0.5534 0.4525 0.4771 0.022 Uiso 1 1 calc R U . . .
C19 C 0.5537(3) 0.47380(11) 0.28432(19) 0.0146(6) Uani 1 1 d . . . . .
C20 C 0.6733(3) 0.45542(12) 0.2743(2) 0.0186(7) Uani 1 1 d . . . . .
H20 H 0.6865 0.4198 0.2700 0.022 Uiso 1 1 calc R U . . .
C21 C 0.7730(3) 0.48856(12) 0.2708(2) 0.0219(7) Uani 1 1 d . . . . .
H21 H 0.8542 0.4755 0.2642 0.026 Uiso 1 1 calc R U . . .
C22 C 0.7548(3) 0.54094(12) 0.2767(2) 0.0229(7) Uani 1 1 d . . . . .
H22 H 0.8229 0.5638 0.2739 0.027 Uiso 1 1 calc R U . . .
C23 C 0.6370(3) 0.55909(12) 0.2868(2) 0.0251(8) Uani 1 1 d . . . . .
H23 H 0.6243 0.5948 0.2913 0.030 Uiso 1 1 calc R U . . .
C24 C 0.5357(3) 0.52614(11) 0.2904(2) 0.0199(7) Uani 1 1 d . . . . .
H24 H 0.4547 0.5394 0.2970 0.024 Uiso 1 1 calc R U . . .
C25 C 0.3020(3) 0.46613(11) 0.3305(2) 0.0162(6) Uani 1 1 d . . . . .
C26 C 0.2326(3) 0.49445(12) 0.2626(2) 0.0204(7) Uani 1 1 d . . . . .
H26 H 0.2549 0.4935 0.2019 0.024 Uiso 1 1 calc R U . . .
C27 C 0.1316(3) 0.52397(12) 0.2822(3) 0.0283(8) Uani 1 1 d . . . . .
H27 H 0.0861 0.5437 0.2359 0.034 Uiso 1 1 calc R U . . .
C28 C 0.0980(3) 0.52421(13) 0.3704(2) 0.0286(8) Uani 1 1 d . . . . .
H28 H 0.0280 0.5438 0.3843 0.034 Uiso 1 1 calc R U . . .
C29 C 0.1646(3) 0.49660(13) 0.4380(2) 0.0280(8) Uani 1 1 d . . . . .
H29 H 0.1408 0.4973 0.4983 0.034 Uiso 1 1 calc R U . . .
C30 C 0.2669(3) 0.46756(12) 0.4187(2) 0.0206(7) Uani 1 1 d . . . . .
H30 H 0.3129 0.4486 0.4659 0.025 Uiso 1 1 calc R U . . .
C31 C 0.1599(3) 0.26848(11) 0.23979(19) 0.0152(6) Uani 1 1 d . . . . .
C32 C 0.0435(3) 0.24649(11) 0.2477(2) 0.0179(7) Uani 1 1 d . . . . .
H32 H -0.0294 0.2672 0.2420 0.021 Uiso 1 1 calc R U . . .
C33 C 0.0325(3) 0.19471(12) 0.2638(2) 0.0198(7) Uani 1 1 d . . . . .
H33 H -0.0473 0.1800 0.2686 0.024 Uiso 1 1 calc R U . . .
C34 C 0.1396(3) 0.16467(12) 0.2726(2) 0.0187(7) Uani 1 1 d . . . . .
H34 H 0.1327 0.1292 0.2833 0.022 Uiso 1 1 calc R U . . .
C35 C 0.2559(3) 0.18589(11) 0.2661(2) 0.0178(7) Uani 1 1 d . . . . .
H35 H 0.3287 0.1651 0.2729 0.021 Uiso 1 1 calc R U . . .
C36 C 0.2664(3) 0.23804(11) 0.24949(19) 0.0152(6) Uani 1 1 d . . . . .
H36 H 0.3464 0.2527 0.2448 0.018 Uiso 1 1 calc R U . . .
C37 C 0.0558(3) 0.35467(11) 0.1333(2) 0.0145(6) Uani 1 1 d . . . . .
C38 C 0.0228(3) 0.40585(12) 0.1207(2) 0.0206(7) Uani 1 1 d . . . . .
H38 H 0.0531 0.4302 0.1653 0.025 Uiso 1 1 calc R U . . .
C39 C -0.0533(3) 0.42148(13) 0.0445(2) 0.0252(8) Uani 1 1 d . . . . .
H39 H -0.0771 0.4562 0.0376 0.030 Uiso 1 1 calc R U . . .
C40 C -0.0947(3) 0.38637(13) -0.0220(2) 0.0263(8) Uani 1 1 d . . . . .
H40 H -0.1443 0.3973 -0.0756 0.032 Uiso 1 1 calc R U . . .
C41 C -0.0641(3) 0.33521(13) -0.0107(2) 0.0238(7) Uani 1 1 d . . . . .
H41 H -0.0932 0.3111 -0.0561 0.029 Uiso 1 1 calc R U . . .
C42 C 0.0093(3) 0.31947(12) 0.0677(2) 0.0177(7) Uani 1 1 d . . . . .
H42 H 0.0280 0.2843 0.0765 0.021 Uiso 1 1 calc R U . . .
C43 C 0.1055(3) 0.35642(10) 0.3301(2) 0.0156(6) Uani 1 1 d . . . . .
C44 C 0.1768(3) 0.34597(11) 0.4133(2) 0.0199(7) Uani 1 1 d . . . . .
H44 H 0.2602 0.3339 0.4134 0.024 Uiso 1 1 calc R U . . .
C45 C 0.1267(3) 0.35312(12) 0.4951(2) 0.0243(8) Uani 1 1 d . . . . .
H45 H 0.1752 0.3455 0.5511 0.029 Uiso 1 1 calc R U . . .
C46 C 0.0056(3) 0.37147(12) 0.4951(2) 0.0281(8) Uani 1 1 d . . . . .
H46 H -0.0293 0.3760 0.5512 0.034 Uiso 1 1 calc R U . . .
C47 C -0.0644(3) 0.38317(12) 0.4138(2) 0.0272(8) Uani 1 1 d . . . . .
H47 H -0.1465 0.3966 0.4141 0.033 Uiso 1 1 calc R U . . .
C48 C -0.0151(3) 0.37530(12) 0.3316(2) 0.0225(7) Uani 1 1 d . . . . .
H48 H -0.0643 0.3829 0.2759 0.027 Uiso 1 1 calc R U . . .
F1 F 0.71700(17) 0.16839(7) 0.24391(13) 0.0274(4) Uani 1 1 d . . . . .
F2 F 0.54448(17) 0.12761(7) 0.28489(13) 0.0288(4) Uani 1 1 d . . . . .
F3 F 0.58085(19) 0.21018(7) 0.32655(13) 0.0326(5) Uani 1 1 d . . . . .
F4 F 0.52332(18) 0.19045(8) 0.17926(13) 0.0318(5) Uani 1 1 d . . . . .
B1 B 0.5926(3) 0.17397(14) 0.2587(2) 0.0190(8) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 P1 2.3529(8) . ?
Rh1 P2 2.3827(8) . ?
Rh1 C1 2.130(3) . ?
Rh1 C2 2.147(3) . ?
Rh1 C3 2.143(3) . ?
Rh1 C4 2.132(3) . ?
P1 C13 1.819(3) . ?
P1 C19 1.837(3) . ?
P1 C25 1.822(3) . ?
P2 C31 1.830(3) . ?
P2 C37 1.823(3) . ?
P2 C43 1.832(3) . ?
C1 C2 1.474(4) . ?
C1 C4 1.436(4) . ?
C1 C5 1.485(4) . ?
C2 C3 1.432(4) . ?
C2 C4 2.036(4) . ?
C2 C7 1.488(4) . ?
C3 C4 1.471(4) . ?
C3 C9 1.495(4) . ?
C4 C11 1.490(4) . ?
C5 H5A 0.9900 . ?
C5 H5B 0.9900 . ?
C5 C6 1.534(4) . ?
C6 H6A 0.9800 . ?
C6 H6B 0.9800 . ?
C6 H6C 0.9800 . ?
C7 H7A 0.9900 . ?
C7 H7B 0.9900 . ?
C7 C8 1.529(4) . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C9 H9A 0.9900 . ?
C9 H9B 0.9900 . ?
C9 C10 1.535(4) . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C11 H11A 0.9900 . ?
C11 H11B 0.9900 . ?
C11 C12 1.523(4) . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
C13 C14 1.390(4) . ?
C13 C18 1.400(4) . ?
C14 H14 0.9500 . ?
C14 C15 1.382(4) . ?
C15 H15 0.9500 . ?
C15 C16 1.381(4) . ?
C16 H16 0.9500 . ?
C16 C17 1.390(4) . ?
C17 H17 0.9500 . ?
C17 C18 1.387(4) . ?
C18 H18 0.9500 . ?
C19 C20 1.393(4) . ?
C19 C24 1.392(4) . ?
C20 H20 0.9500 . ?
C20 C21 1.385(4) . ?
C21 H21 0.9500 . ?
C21 C22 1.393(4) . ?
C22 H22 0.9500 . ?
C22 C23 1.373(5) . ?
C23 H23 0.9500 . ?
C23 C24 1.395(4) . ?
C24 H24 0.9500 . ?
C25 C26 1.398(4) . ?
C25 C30 1.393(4) . ?
C26 H26 0.9500 . ?
C26 C27 1.388(4) . ?
C27 H27 0.9500 . ?
C27 C28 1.385(5) . ?
C28 H28 0.9500 . ?
C28 C29 1.371(5) . ?
C29 H29 0.9500 . ?
C29 C30 1.390(4) . ?
C30 H30 0.9500 . ?
C31 C32 1.393(4) . ?
C31 C36 1.389(4) . ?
C32 H32 0.9500 . ?
C32 C33 1.387(4) . ?
C33 H33 0.9500 . ?
C33 C34 1.389(4) . ?
C34 H34 0.9500 . ?
C34 C35 1.379(4) . ?
C35 H35 0.9500 . ?
C35 C36 1.398(4) . ?
C36 H36 0.9500 . ?
C37 C38 1.397(4) . ?
C37 C42 1.392(4) . ?
C38 H38 0.9500 . ?
C38 C39 1.380(4) . ?
C39 H39 0.9500 . ?
C39 C40 1.384(4) . ?
C40 H40 0.9500 . ?
C40 C41 1.389(5) . ?
C41 H41 0.9500 . ?
C41 C42 1.391(4) . ?
C42 H42 0.9500 . ?
C43 C44 1.402(4) . ?
C43 C48 1.388(4) . ?
C44 H44 0.9500 . ?
C44 C45 1.384(4) . ?
C45 H45 0.9500 . ?
C45 C46 1.386(5) . ?
C46 H46 0.9500 . ?
C46 C47 1.381(5) . ?
C47 H47 0.9500 . ?
C47 C48 1.388(4) . ?
C48 H48 0.9500 . ?
F1 B1 1.382(4) . ?
F2 B1 1.393(4) . ?
F3 B1 1.396(4) . ?
F4 B1 1.389(4) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Rh1 P2 101.63(3) . . ?
C1 Rh1 P1 103.57(8) . . ?
C1 Rh1 P2 151.47(8) . . ?
C1 Rh1 C2 40.32(10) . . ?
C1 Rh1 C3 58.05(11) . . ?
C1 Rh1 C4 39.37(11) . . ?
C2 Rh1 P1 135.88(8) . . ?
C2 Rh1 P2 111.17(8) . . ?
C3 Rh1 P1 156.47(8) . . ?
C3 Rh1 P2 100.16(8) . . ?
C3 Rh1 C2 38.98(11) . . ?
C4 Rh1 P1 116.29(8) . . ?
C4 Rh1 P2 134.22(8) . . ?
C4 Rh1 C2 56.84(11) . . ?
C4 Rh1 C3 40.25(11) . . ?
C13 P1 Rh1 109.28(10) . . ?
C13 P1 C19 99.28(13) . . ?
C13 P1 C25 108.32(14) . . ?
C19 P1 Rh1 121.97(10) . . ?
C25 P1 Rh1 113.64(10) . . ?
C25 P1 C19 102.89(14) . . ?
C31 P2 Rh1 117.36(10) . . ?
C31 P2 C43 97.74(13) . . ?
C37 P2 Rh1 103.64(10) . . ?
C37 P2 C31 105.59(13) . . ?
C37 P2 C43 104.78(14) . . ?
C43 P2 Rh1 125.86(10) . . ?
C2 C1 Rh1 70.46(16) . . ?
C2 C1 C5 132.8(3) . . ?
C4 C1 Rh1 70.39(17) . . ?
C4 C1 C2 88.8(2) . . ?
C4 C1 C5 134.0(3) . . ?
C5 C1 Rh1 134.0(2) . . ?
C1 C2 Rh1 69.22(16) . . ?
C1 C2 C4 44.82(16) . . ?
C1 C2 C7 134.6(3) . . ?
C3 C2 Rh1 70.38(16) . . ?
C3 C2 C1 91.0(2) . . ?
C3 C2 C4 46.24(16) . . ?
C3 C2 C7 133.0(3) . . ?
C4 C2 Rh1 61.21(12) . . ?
C7 C2 Rh1 128.3(2) . . ?
C7 C2 C4 170.4(2) . . ?
C2 C3 Rh1 70.63(16) . . ?
C2 C3 C4 89.1(2) . . ?
C2 C3 C9 132.0(3) . . ?
C4 C3 Rh1 69.45(16) . . ?
C4 C3 C9 134.5(3) . . ?
C9 C3 Rh1 134.5(2) . . ?
C1 C4 Rh1 70.24(17) . . ?
C1 C4 C2 46.36(16) . . ?
C1 C4 C3 91.0(2) . . ?
C1 C4 C11 134.7(3) . . ?
C2 C4 Rh1 61.95(12) . . ?
C3 C4 Rh1 70.30(16) . . ?
C3 C4 C2 44.66(16) . . ?
C3 C4 C11 133.6(3) . . ?
C11 C4 Rh1 125.4(2) . . ?
C11 C4 C2 172.5(3) . . ?
C1 C5 H5A 109.8 . . ?
C1 C5 H5B 109.8 . . ?
C1 C5 C6 109.2(2) . . ?
H5A C5 H5B 108.3 . . ?
C6 C5 H5A 109.8 . . ?
C6 C5 H5B 109.8 . . ?
C5 C6 H6A 109.5 . . ?
C5 C6 H6B 109.5 . . ?
C5 C6 H6C 109.5 . . ?
H6A C6 H6B 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
C2 C7 H7A 108.6 . . ?
C2 C7 H7B 108.6 . . ?
C2 C7 C8 114.7(3) . . ?
H7A C7 H7B 107.6 . . ?
C8 C7 H7A 108.6 . . ?
C8 C7 H7B 108.6 . . ?
C7 C8 H8A 109.5 . . ?
C7 C8 H8B 109.5 . . ?
C7 C8 H8C 109.5 . . ?
H8A C8 H8B 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
C3 C9 H9A 109.5 . . ?
C3 C9 H9B 109.5 . . ?
C3 C9 C10 110.6(2) . . ?
H9A C9 H9B 108.1 . . ?
C10 C9 H9A 109.5 . . ?
C10 C9 H9B 109.5 . . ?
C9 C10 H10A 109.5 . . ?
C9 C10 H10B 109.5 . . ?
C9 C10 H10C 109.5 . . ?
H10A C10 H10B 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
C4 C11 H11A 109.5 . . ?
C4 C11 H11B 109.5 . . ?
C4 C11 C12 110.7(3) . . ?
H11A C11 H11B 108.1 . . ?
C12 C11 H11A 109.5 . . ?
C12 C11 H11B 109.5 . . ?
C11 C12 H12A 109.5 . . ?
C11 C12 H12B 109.5 . . ?
C11 C12 H12C 109.5 . . ?
H12A C12 H12B 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
C14 C13 P1 118.0(2) . . ?
C14 C13 C18 119.1(3) . . ?
C18 C13 P1 122.6(2) . . ?
C13 C14 H14 119.6 . . ?
C15 C14 C13 120.9(3) . . ?
C15 C14 H14 119.6 . . ?
C14 C15 H15 120.0 . . ?
C16 C15 C14 120.0(3) . . ?
C16 C15 H15 120.0 . . ?
C15 C16 H16 120.1 . . ?
C15 C16 C17 119.9(3) . . ?
C17 C16 H16 120.1 . . ?
C16 C17 H17 119.8 . . ?
C18 C17 C16 120.4(3) . . ?
C18 C17 H17 119.8 . . ?
C13 C18 H18 120.1 . . ?
C17 C18 C13 119.7(3) . . ?
C17 C18 H18 120.1 . . ?
C20 C19 P1 117.8(2) . . ?
C24 C19 P1 123.1(2) . . ?
C24 C19 C20 119.0(3) . . ?
C19 C20 H20 119.6 . . ?
C21 C20 C19 120.7(3) . . ?
C21 C20 H20 119.6 . . ?
C20 C21 H21 119.9 . . ?
C20 C21 C22 120.2(3) . . ?
C22 C21 H21 119.9 . . ?
C21 C22 H22 120.5 . . ?
C23 C22 C21 119.1(3) . . ?
C23 C22 H22 120.5 . . ?
C22 C23 H23 119.4 . . ?
C22 C23 C24 121.3(3) . . ?
C24 C23 H23 119.4 . . ?
C19 C24 C23 119.7(3) . . ?
C19 C24 H24 120.2 . . ?
C23 C24 H24 120.2 . . ?
C26 C25 P1 116.9(2) . . ?
C30 C25 P1 124.4(2) . . ?
C30 C25 C26 118.6(3) . . ?
C25 C26 H26 119.4 . . ?
C27 C26 C25 121.1(3) . . ?
C27 C26 H26 119.4 . . ?
C26 C27 H27 120.5 . . ?
C28 C27 C26 119.0(3) . . ?
C28 C27 H27 120.5 . . ?
C27 C28 H28 119.6 . . ?
C29 C28 C27 120.8(3) . . ?
C29 C28 H28 119.6 . . ?
C28 C29 H29 119.9 . . ?
C28 C29 C30 120.3(3) . . ?
C30 C29 H29 119.9 . . ?
C25 C30 H30 119.9 . . ?
C29 C30 C25 120.2(3) . . ?
C29 C30 H30 119.9 . . ?
C32 C31 P2 120.2(2) . . ?
C36 C31 P2 120.4(2) . . ?
C36 C31 C32 119.2(3) . . ?
C31 C32 H32 119.5 . . ?
C33 C32 C31 120.9(3) . . ?
C33 C32 H32 119.5 . . ?
C32 C33 H33 120.4 . . ?
C32 C33 C34 119.2(3) . . ?
C34 C33 H33 120.4 . . ?
C33 C34 H34 119.7 . . ?
C35 C34 C33 120.7(3) . . ?
C35 C34 H34 119.7 . . ?
C34 C35 H35 120.1 . . ?
C34 C35 C36 119.9(3) . . ?
C36 C35 H35 120.1 . . ?
C31 C36 C35 120.1(3) . . ?
C31 C36 H36 120.0 . . ?
C35 C36 H36 120.0 . . ?
C38 C37 P2 118.9(2) . . ?
C42 C37 P2 121.9(2) . . ?
C42 C37 C38 118.7(3) . . ?
C37 C38 H38 119.5 . . ?
C39 C38 C37 120.9(3) . . ?
C39 C38 H38 119.5 . . ?
C38 C39 H39 120.1 . . ?
C38 C39 C40 119.8(3) . . ?
C40 C39 H39 120.1 . . ?
C39 C40 H40 119.8 . . ?
C39 C40 C41 120.3(3) . . ?
C41 C40 H40 119.8 . . ?
C40 C41 H41 120.2 . . ?
C40 C41 C42 119.6(3) . . ?
C42 C41 H41 120.2 . . ?
C37 C42 H42 119.7 . . ?
C41 C42 C37 120.7(3) . . ?
C41 C42 H42 119.7 . . ?
C44 C43 P2 116.6(2) . . ?
C48 C43 P2 124.4(2) . . ?
C48 C43 C44 118.7(3) . . ?
C43 C44 H44 119.7 . . ?
C45 C44 C43 120.6(3) . . ?
C45 C44 H44 119.7 . . ?
C44 C45 H45 120.1 . . ?
C44 C45 C46 119.9(3) . . ?
C46 C45 H45 120.1 . . ?
C45 C46 H46 120.0 . . ?
C47 C46 C45 120.1(3) . . ?
C47 C46 H46 120.0 . . ?
C46 C47 H47 119.9 . . ?
C46 C47 C48 120.1(3) . . ?
C48 C47 H47 119.9 . . ?
C43 C48 C47 120.6(3) . . ?
C43 C48 H48 119.7 . . ?
C47 C48 H48 119.7 . . ?
F1 B1 F2 110.1(3) . . ?
F1 B1 F3 110.3(3) . . ?
F1 B1 F4 109.9(3) . . ?
F2 B1 F3 109.4(3) . . ?
F4 B1 F2 108.9(3) . . ?
F4 B1 F3 108.1(3) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Rh1 P1 C13 C14 1.5(3) . . . . ?
Rh1 P1 C13 C18 174.6(2) . . . . ?
Rh1 P1 C19 C20 -62.7(3) . . . . ?
Rh1 P1 C19 C24 120.8(2) . . . . ?
Rh1 P1 C25 C26 -55.8(3) . . . . ?
Rh1 P1 C25 C30 121.0(2) . . . . ?
Rh1 P2 C31 C32 -165.6(2) . . . . ?
Rh1 P2 C31 C36 19.6(3) . . . . ?
Rh1 P2 C37 C38 -71.0(3) . . . . ?
Rh1 P2 C37 C42 100.8(3) . . . . ?
Rh1 P2 C43 C44 -62.3(3) . . . . ?
Rh1 P2 C43 C48 124.5(2) . . . . ?
Rh1 C1 C2 C3 -68.52(17) . . . . ?
Rh1 C1 C2 C4 -69.58(17) . . . . ?
Rh1 C1 C2 C7 123.9(3) . . . . ?
Rh1 C1 C4 C2 69.65(16) . . . . ?
Rh1 C1 C4 C3 68.62(17) . . . . ?
Rh1 C1 C4 C11 -120.7(4) . . . . ?
Rh1 C1 C5 C6 -163.5(2) . . . . ?
Rh1 C2 C3 C4 -68.49(16) . . . . ?
Rh1 C2 C3 C9 133.2(3) . . . . ?
Rh1 C2 C7 C8 62.5(4) . . . . ?
Rh1 C3 C4 C1 -68.56(17) . . . . ?
Rh1 C3 C4 C2 -69.62(16) . . . . ?
Rh1 C3 C4 C11 120.6(4) . . . . ?
Rh1 C3 C9 C10 169.2(2) . . . . ?
Rh1 C4 C11 C12 161.0(2) . . . . ?
P1 C13 C14 C15 175.0(2) . . . . ?
P1 C13 C18 C17 -175.0(2) . . . . ?
P1 C19 C20 C21 -176.5(2) . . . . ?
P1 C19 C24 C23 176.2(2) . . . . ?
P1 C25 C26 C27 177.8(2) . . . . ?
P1 C25 C30 C29 -176.7(2) . . . . ?
P2 C31 C32 C33 -175.8(2) . . . . ?
P2 C31 C36 C35 175.5(2) . . . . ?
P2 C37 C38 C39 171.4(3) . . . . ?
P2 C37 C42 C41 -169.1(2) . . . . ?
P2 C43 C44 C45 -172.0(2) . . . . ?
P2 C43 C48 C47 172.5(2) . . . . ?
C1 C2 C3 Rh1 67.46(16) . . . . ?
C1 C2 C3 C4 -1.0(2) . . . . ?
C1 C2 C3 C9 -159.4(3) . . . . ?
C1 C2 C7 C8 -35.8(5) . . . . ?
C1 C4 C11 C12 -102.2(4) . . . . ?
C2 C1 C4 Rh1 -69.65(16) . . . . ?
C2 C1 C4 C3 -1.0(2) . . . . ?
C2 C1 C4 C11 169.7(4) . . . . ?
C2 C1 C5 C6 -58.4(4) . . . . ?
C2 C3 C4 Rh1 69.62(16) . . . . ?
C2 C3 C4 C1 1.1(2) . . . . ?
C2 C3 C4 C11 -169.8(4) . . . . ?
C2 C3 C9 C10 64.1(4) . . . . ?
C3 C2 C7 C8 161.3(3) . . . . ?
C3 C4 C11 C12 65.0(5) . . . . ?
C4 C1 C2 Rh1 69.58(17) . . . . ?
C4 C1 C2 C3 1.1(2) . . . . ?
C4 C1 C2 C7 -166.5(3) . . . . ?
C4 C1 C5 C6 90.1(4) . . . . ?
C4 C2 C3 Rh1 68.49(16) . . . . ?
C4 C2 C3 C9 -158.4(4) . . . . ?
C4 C3 C9 C10 -84.7(4) . . . . ?
C5 C1 C2 Rh1 -132.5(3) . . . . ?
C5 C1 C2 C3 159.0(3) . . . . ?
C5 C1 C2 C4 157.9(4) . . . . ?
C5 C1 C2 C7 -8.6(6) . . . . ?
C5 C1 C4 Rh1 132.9(4) . . . . ?
C5 C1 C4 C2 -157.5(4) . . . . ?
C5 C1 C4 C3 -158.5(3) . . . . ?
C5 C1 C4 C11 12.2(6) . . . . ?
C7 C2 C3 Rh1 -124.6(3) . . . . ?
C7 C2 C3 C4 166.9(3) . . . . ?
C7 C2 C3 C9 8.5(6) . . . . ?
C9 C3 C4 Rh1 -133.0(4) . . . . ?
C9 C3 C4 C1 158.5(3) . . . . ?
C9 C3 C4 C2 157.4(4) . . . . ?
C9 C3 C4 C11 -12.4(6) . . . . ?
C13 P1 C19 C20 57.0(3) . . . . ?
C13 P1 C19 C24 -119.5(3) . . . . ?
C13 P1 C25 C26 -177.4(2) . . . . ?
C13 P1 C25 C30 -0.6(3) . . . . ?
C13 C14 C15 C16 -0.3(5) . . . . ?
C14 C13 C18 C17 -2.0(5) . . . . ?
C14 C15 C16 C17 -0.7(5) . . . . ?
C15 C16 C17 C18 0.4(5) . . . . ?
C16 C17 C18 C13 1.0(5) . . . . ?
C18 C13 C14 C15 1.7(5) . . . . ?
C19 P1 C13 C14 -127.2(3) . . . . ?
C19 P1 C13 C18 45.9(3) . . . . ?
C19 P1 C25 C26 78.1(3) . . . . ?
C19 P1 C25 C30 -105.1(3) . . . . ?
C19 C20 C21 C22 -0.3(5) . . . . ?
C20 C19 C24 C23 -0.2(5) . . . . ?
C20 C21 C22 C23 0.4(5) . . . . ?
C21 C22 C23 C24 -0.5(5) . . . . ?
C22 C23 C24 C19 0.4(5) . . . . ?
C24 C19 C20 C21 0.2(5) . . . . ?
C25 P1 C13 C14 125.8(3) . . . . ?
C25 P1 C13 C18 -61.1(3) . . . . ?
C25 P1 C19 C20 168.4(2) . . . . ?
C25 P1 C19 C24 -8.1(3) . . . . ?
C25 C26 C27 C28 -1.5(5) . . . . ?
C26 C25 C30 C29 0.1(5) . . . . ?
C26 C27 C28 C29 1.3(5) . . . . ?
C27 C28 C29 C30 -0.4(5) . . . . ?
C28 C29 C30 C25 -0.3(5) . . . . ?
C30 C25 C26 C27 0.8(5) . . . . ?
C31 P2 C37 C38 165.0(2) . . . . ?
C31 P2 C37 C42 -23.2(3) . . . . ?
C31 P2 C43 C44 69.8(2) . . . . ?
C31 P2 C43 C48 -103.4(3) . . . . ?
C31 C32 C33 C34 0.4(5) . . . . ?
C32 C31 C36 C35 0.6(4) . . . . ?
C32 C33 C34 C35 0.4(5) . . . . ?
C33 C34 C35 C36 -0.7(4) . . . . ?
C34 C35 C36 C31 0.2(4) . . . . ?
C36 C31 C32 C33 -0.9(4) . . . . ?
C37 P2 C31 C32 -50.7(3) . . . . ?
C37 P2 C31 C36 134.5(2) . . . . ?
C37 P2 C43 C44 178.3(2) . . . . ?
C37 P2 C43 C48 5.0(3) . . . . ?
C37 C38 C39 C40 -1.9(5) . . . . ?
C38 C37 C42 C41 2.6(5) . . . . ?
C38 C39 C40 C41 2.5(5) . . . . ?
C39 C40 C41 C42 -0.5(5) . . . . ?
C40 C41 C42 C37 -2.1(5) . . . . ?
C42 C37 C38 C39 -0.6(5) . . . . ?
C43 P2 C31 C32 57.1(3) . . . . ?
C43 P2 C31 C36 -117.8(2) . . . . ?
C43 P2 C37 C38 62.4(3) . . . . ?
C43 P2 C37 C42 -125.8(3) . . . . ?
C43 C44 C45 C46 -0.9(5) . . . . ?
C44 C43 C48 C47 -0.6(5) . . . . ?
C44 C45 C46 C47 -0.8(5) . . . . ?
C45 C46 C47 C48 1.7(5) . . . . ?
C46 C47 C48 C43 -1.0(5) . . . . ?
C48 C43 C44 C45 1.6(4) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
