# Electronic Supplementary Material (ESI) for Nanoscale.
# This journal is © The Royal Society of Chemistry 2023

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 2237651'
loop_
_audit_author_name
_audit_author_address
'Jian-Hong Liao'
;Department of Chemistry, National Dong Hwa University
Taiwan
;
_audit_update_record             
;
2023-01-23 deposited with the CCDC.	2023-03-02 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C114 H158 Ag12 Au5 F12 O14 P13 S14'
_chemical_formula_weight         5111.12

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   30.034(3)
_cell_length_b                   27.879(3)
_cell_length_c                   18.1905(18)
_cell_angle_alpha                90
_cell_angle_beta                 97.624(2)
_cell_angle_gamma                90
_cell_volume                     15097(3)
_cell_formula_units_Z            4
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    9906
_cell_measurement_theta_min      2.26
_cell_measurement_theta_max      25.38

_exptl_crystal_description       plate
_exptl_crystal_colour            red
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    2.249
_exptl_crystal_F_000             9760
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.150
_exptl_crystal_size_mid          0.090
_exptl_crystal_size_min          0.040
_exptl_absorpt_coefficient_mu    6.753
_shelx_estimated_absorpt_T_min   0.431
_shelx_estimated_absorpt_T_max   0.774
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.5643
_exptl_absorpt_correction_T_max  0.7453
_exptl_absorpt_process_details   SADABS
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            95474
_diffrn_reflns_av_unetI/netI     0.1219
_diffrn_reflns_av_R_equivalents  0.1240
_diffrn_reflns_limit_h_min       -35
_diffrn_reflns_limit_h_max       35
_diffrn_reflns_limit_k_min       -29
_diffrn_reflns_limit_k_max       33
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_theta_min         1.001
_diffrn_reflns_theta_max         25.000
_diffrn_reflns_theta_full        25.000
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measured_fraction_theta_full 0.995
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_Laue_measured_fraction_full 0.995
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_point_group_measured_fraction_full 0.995
_reflns_number_total             26457
_reflns_number_gt                13745
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
; 
 Reflections were merged by SHELXL according to the crystal 
 class for the calculation of statistics and refinement. 
  
 _reflns_Friedel_fraction is defined as the number of unique 
 Friedel pairs measured divided by the number that would be 
 possible theoretically, ignoring centric projections and 
 systematic absences. 
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0798P)²+1285.1500P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         26457
_refine_ls_number_parameters     1399
_refine_ls_number_restraints     1519
_refine_ls_R_factor_all          0.2054
_refine_ls_R_factor_gt           0.1084
_refine_ls_wR_factor_ref         0.3172
_refine_ls_wR_factor_gt          0.2490
_refine_ls_goodness_of_fit_ref   1.104
_refine_ls_restrained_S_all      1.080
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag -0.30593(9) 0.08763(8) 0.29687(12) 0.0436(6) Uani 1 1 d . . . . .
Ag2 Ag -0.25628(9) 0.05861(9) 0.18106(12) 0.0489(7) Uani 1 1 d . . . . .
Ag3 Ag -0.30699(8) -0.08282(8) 0.29943(12) 0.0400(6) Uani 1 1 d . . . . .
Ag4 Ag -0.25950(8) -0.05250(9) 0.43889(12) 0.0437(6) Uani 1 1 d . . . . .
Ag5 Ag -0.20910(10) 0.08821(10) 0.32859(14) 0.0580(7) Uani 1 1 d . . . . .
Ag6 Ag -0.18018(8) 0.00381(11) 0.24629(13) 0.0550(7) Uani 1 1 d . . . . .
Ag7 Ag -0.21065(8) -0.08428(10) 0.31556(13) 0.0502(7) Uani 1 1 d . . . . .
Ag8 Ag -0.18156(8) 0.00065(11) 0.40194(12) 0.0538(7) Uani 1 1 d . . . . .
Ag9 Ag -0.20804(16) 0.15327(13) 0.20032(19) 0.1003(13) Uani 1 1 d . . . . .
Ag10 Ag -0.11620(14) 0.08253(18) 0.2772(2) 0.1156(16) Uani 1 1 d . . . . .
Ag11 Ag -0.23066(12) -0.15354(12) 0.43855(17) 0.0744(9) Uani 1 1 d . . . . .
Ag12 Ag -0.13567(11) -0.09140(15) 0.44077(17) 0.0857(11) Uani 1 1 d . . . . .
Au1 Au -0.26071(4) 0.00212(4) 0.30882(5) 0.0339(3) Uani 1 1 d . . . . .
Au2 Au -0.25934(4) -0.04815(5) 0.18145(6) 0.0436(3) Uani 1 1 d . . . . .
Au3 Au -0.33667(4) 0.00488(4) 0.20876(6) 0.0386(3) Uani 1 1 d . . . . .
Au4 Au -0.33840(4) 0.00205(4) 0.36940(5) 0.0343(3) Uani 1 1 d . . . . .
Au5 Au -0.26104(5) 0.05253(5) 0.43727(6) 0.0459(3) Uani 1 1 d . . . . .
C1 C -0.002(2) 0.053(2) 0.439(3) 0.16(2) Uani 1 1 d D U . . .
H1A H 0.015346 0.028120 0.467584 0.194 Uiso 1 1 calc R U . . .
H1B H -0.018978 0.072362 0.472150 0.194 Uiso 1 1 calc R U . . .
C2 C 0.027(2) 0.085(2) 0.396(4) 0.18(2) Uani 1 1 d D U . . .
H2A H 0.057853 0.086864 0.423568 0.221 Uiso 1 1 calc R U . . .
H2B H 0.029320 0.070820 0.346813 0.221 Uiso 1 1 calc R U . . .
C3 C 0.008(3) 0.136(2) 0.386(4) 0.23(4) Uani 1 1 d D U . . .
H3A H -0.017845 0.135983 0.346053 0.352 Uiso 1 1 calc R U . . .
H3B H 0.030934 0.157972 0.371959 0.352 Uiso 1 1 calc R U . . .
H3C H -0.002200 0.147043 0.431924 0.352 Uiso 1 1 calc R U . . .
C4 C -0.008(2) -0.080(2) 0.342(3) 0.17(2) Uani 1 1 d D U . . .
H4A H 0.019295 -0.059917 0.344599 0.199 Uiso 1 1 calc R U . . .
H4B H -0.022161 -0.081215 0.289999 0.199 Uiso 1 1 calc R U . . .
C5 C 0.005(2) -0.131(2) 0.369(4) 0.18(2) Uani 1 1 d D U . . .
H5A H 0.004238 -0.149560 0.322272 0.221 Uiso 1 1 calc R U . . .
H5B H 0.037534 -0.128104 0.388264 0.221 Uiso 1 1 calc R U . . .
C6 C -0.013(3) -0.166(3) 0.423(4) 0.26(4) Uani 1 1 d D U . . .
H6A H -0.032675 -0.148905 0.452543 0.393 Uiso 1 1 calc R U . . .
H6B H 0.012156 -0.180262 0.455452 0.393 Uiso 1 1 calc R U . . .
H6C H -0.030008 -0.191595 0.394476 0.393 Uiso 1 1 calc R U . . .
C7 C -0.1100(18) -0.220(2) 0.215(4) 0.18(2) Uani 1 1 d D U . . .
H7A H -0.084730 -0.207524 0.250114 0.211 Uiso 1 1 calc R U . . .
H7B H -0.115747 -0.197162 0.173123 0.211 Uiso 1 1 calc R U . . .
C8 C -0.097(2) -0.269(2) 0.185(4) 0.18(2) Uani 1 1 d D U . . .
H8A H -0.066223 -0.267490 0.171013 0.216 Uiso 1 1 calc R U . . .
H8B H -0.117959 -0.277875 0.140694 0.216 Uiso 1 1 calc R U . . .
C9 C -0.099(4) -0.307(3) 0.246(5) 0.28(4) Uani 1 1 d D U . . .
H9A H -0.076934 -0.299008 0.289391 0.425 Uiso 1 1 calc R U . . .
H9B H -0.090921 -0.338743 0.227103 0.425 Uiso 1 1 calc R U . . .
H9C H -0.128855 -0.308452 0.260396 0.425 Uiso 1 1 calc R U . . .
C10 C -0.144(2) -0.2576(19) 0.423(4) 0.19(2) Uani 1 1 d D U . . .
H10A H -0.143264 -0.283121 0.385247 0.224 Uiso 1 1 calc R U . . .
H10B H -0.174391 -0.257658 0.439355 0.224 Uiso 1 1 calc R U . . .
C11 C -0.107(2) -0.266(3) 0.489(4) 0.20(3) Uani 1 1 d D U . . .
H11A H -0.104493 -0.236863 0.521216 0.242 Uiso 1 1 calc R U . . .
H11B H -0.115648 -0.293188 0.519277 0.242 Uiso 1 1 calc R U . . .
C12 C -0.063(3) -0.276(4) 0.460(5) 0.27(4) Uani 1 1 d D U . . .
H12A H -0.039055 -0.281192 0.501633 0.400 Uiso 1 1 calc R U . . .
H12B H -0.065800 -0.304746 0.428535 0.400 Uiso 1 1 calc R U . . .
H12C H -0.054677 -0.248585 0.430469 0.400 Uiso 1 1 calc R U . . .
C13 C -0.131(3) -0.0292(17) 0.674(3) 0.229(17) Uani 1 1 d D U . . .
H13A H -0.160501 -0.012876 0.675426 0.275 Uiso 1 1 calc R U . . .
H13B H -0.112669 -0.009403 0.645226 0.275 Uiso 1 1 calc R U . . .
C14 C -0.1073(19) -0.036(3) 0.754(4) 0.231(17) Uani 1 1 d D U . . .
H14A H -0.079638 -0.016749 0.763620 0.277 Uiso 1 1 calc R U . . .
H14B H -0.099968 -0.070455 0.764698 0.277 Uiso 1 1 calc R U . . .
C15 C -0.144(2) -0.018(3) 0.798(3) 0.241(19) Uani 1 1 d D U . . .
H15A H -0.134130 -0.020235 0.851049 0.361 Uiso 1 1 calc R U . . .
H15B H -0.151426 0.015496 0.784492 0.361 Uiso 1 1 calc R U . . .
H15C H -0.171533 -0.037621 0.785558 0.361 Uiso 1 1 calc R U . . .
C16 C -0.232(2) -0.141(3) 0.668(4) 0.21(2) Uani 1 1 d D U . . .
H16A H -0.227569 -0.163900 0.628269 0.247 Uiso 1 1 calc R U . . .
H16B H -0.258485 -0.121015 0.649234 0.247 Uiso 1 1 calc R U . . .
C17 C -0.245(3) -0.170(3) 0.734(4) 0.20(2) Uani 1 1 d D U . . .
H17A H -0.275542 -0.184411 0.721978 0.244 Uiso 1 1 calc R U . . .
H17B H -0.223300 -0.196672 0.747397 0.244 Uiso 1 1 calc R U . . .
C18 C -0.244(3) -0.133(3) 0.797(4) 0.24(3) Uani 1 1 d D U . . .
H18A H -0.251561 -0.148925 0.841408 0.354 Uiso 1 1 calc R U . . .
H18B H -0.213403 -0.119808 0.806765 0.354 Uiso 1 1 calc R U . . .
H18C H -0.265252 -0.107640 0.781537 0.354 Uiso 1 1 calc R U . . .
C19 C -0.3926(17) -0.188(3) 0.500(2) 0.17(2) Uani 1 1 d D U . . .
H19A H -0.385031 -0.162618 0.538926 0.205 Uiso 1 1 calc R U . . .
H19B H -0.369901 -0.213415 0.507681 0.205 Uiso 1 1 calc R U . . .
C20 C -0.4403(16) -0.207(3) 0.502(3) 0.17(2) Uani 1 1 d D U . . .
H20A H -0.445117 -0.237965 0.475098 0.205 Uiso 1 1 calc R U . . .
H20B H -0.463661 -0.183920 0.482458 0.205 Uiso 1 1 calc R U . . .
C21 C -0.439(2) -0.214(2) 0.587(3) 0.17(2) Uani 1 1 d D U . . .
H21A H -0.409200 -0.226731 0.607418 0.258 Uiso 1 1 calc R U . . .
H21B H -0.462092 -0.236988 0.596494 0.258 Uiso 1 1 calc R U . . .
H21C H -0.443851 -0.183347 0.609989 0.258 Uiso 1 1 calc R U . . .
C22 C -0.3267(19) -0.2625(18) 0.365(3) 0.145(19) Uani 1 1 d D U . . .
H22A H -0.309034 -0.289271 0.389914 0.174 Uiso 1 1 calc R U . . .
H22B H -0.311027 -0.250857 0.323770 0.174 Uiso 1 1 calc R U . . .
C23 C -0.374(2) -0.280(3) 0.334(4) 0.19(3) Uani 1 1 d D U . . .
H23A H -0.380262 -0.301317 0.375447 0.222 Uiso 1 1 calc R U . . .
H23B H -0.391647 -0.250553 0.341776 0.222 Uiso 1 1 calc R U . . .
C24 C -0.405(3) -0.303(4) 0.270(5) 0.30(5) Uani 1 1 d D U . . .
H24A H -0.435883 -0.290714 0.269390 0.449 Uiso 1 1 calc R U . . .
H24B H -0.405237 -0.337878 0.276226 0.449 Uiso 1 1 calc R U . . .
H24C H -0.394413 -0.294987 0.222874 0.449 Uiso 1 1 calc R U . . .
C25 C -0.0591(15) 0.058(3) 0.064(4) 0.22(3) Uani 1 1 d D U . . .
H25A H -0.052637 0.092281 0.073893 0.263 Uiso 1 1 calc R U . . .
H25B H -0.063483 0.053503 0.009774 0.263 Uiso 1 1 calc R U . . .
C26 C -0.017(3) 0.029(2) 0.096(5) 0.24(3) Uani 1 1 d D U . . .
H26A H -0.004260 0.011540 0.056048 0.284 Uiso 1 1 calc R U . . .
H26B H -0.023297 0.006665 0.134634 0.284 Uiso 1 1 calc R U . . .
C27 C 0.015(2) 0.070(4) 0.128(6) 0.32(4) Uani 1 1 d D U . . .
H27A H 0.043878 0.055538 0.149917 0.484 Uiso 1 1 calc R U . . .
H27B H 0.020598 0.091854 0.088331 0.484 Uiso 1 1 calc R U . . .
H27C H 0.001725 0.087021 0.166240 0.484 Uiso 1 1 calc R U . . .
C28 C -0.155(2) 0.076(3) -0.054(4) 0.27(2) Uani 1 1 d D U . . .
H28A H -0.163085 0.042192 -0.045413 0.330 Uiso 1 1 calc R U . . .
H28B H -0.127412 0.076959 -0.077579 0.330 Uiso 1 1 calc R U . . .
C29 C -0.194(3) 0.1018(19) -0.103(3) 0.28(2) Uani 1 1 d D U . . .
H29A H -0.210651 0.123662 -0.073106 0.334 Uiso 1 1 calc R U . . .
H29B H -0.183329 0.119729 -0.143780 0.334 Uiso 1 1 calc R U . . .
C30 C -0.2224(17) 0.0578(19) -0.131(4) 0.29(2) Uani 1 1 d D U . . .
H30A H -0.249138 0.068396 -0.163218 0.429 Uiso 1 1 calc R U . . .
H30B H -0.204498 0.036552 -0.158034 0.429 Uiso 1 1 calc R U . . .
H30C H -0.231520 0.040442 -0.088133 0.429 Uiso 1 1 calc R U . . .
C31 C -0.3931(18) 0.178(2) 0.076(4) 0.23(2) Uani 1 1 d D U . . .
H31A H -0.406056 0.157028 0.111541 0.273 Uiso 1 1 calc R U . . .
H31B H -0.388385 0.159593 0.030742 0.273 Uiso 1 1 calc R U . . .
C32 C -0.419(2) 0.225(2) 0.059(5) 0.21(3) Uani 1 1 d D U . . .
H32A H -0.410602 0.249494 0.097136 0.251 Uiso 1 1 calc R U . . .
H32B H -0.414923 0.237870 0.009487 0.251 Uiso 1 1 calc R U . . .
C33 C -0.468(2) 0.208(3) 0.060(5) 0.24(3) Uani 1 1 d D U . . .
H33A H -0.488502 0.235172 0.049511 0.363 Uiso 1 1 calc R U . . .
H33B H -0.475364 0.183170 0.021960 0.363 Uiso 1 1 calc R U . . .
H33C H -0.471082 0.194687 0.108800 0.363 Uiso 1 1 calc R U . . .
C34 C -0.314(2) 0.266(2) 0.222(4) 0.194(18) Uani 1 1 d D U . . .
H34A H -0.333980 0.253792 0.257142 0.233 Uiso 1 1 calc R U . . .
H34B H -0.331545 0.289157 0.187923 0.233 Uiso 1 1 calc R U . . .
C35 C -0.273(2) 0.291(3) 0.264(4) 0.201(18) Uani 1 1 d D U . . .
H35A H -0.253718 0.303646 0.228187 0.241 Uiso 1 1 calc R U . . .
H35B H -0.254594 0.266656 0.295322 0.241 Uiso 1 1 calc R U . . .
C36 C -0.286(3) 0.3317(18) 0.314(2) 0.22(2) Uani 1 1 d D U . . .
H36A H -0.258338 0.346475 0.339831 0.329 Uiso 1 1 calc R U . . .
H36B H -0.302950 0.355887 0.283138 0.329 Uiso 1 1 calc R U . . .
H36C H -0.303825 0.318918 0.350234 0.329 Uiso 1 1 calc R U . . .
C37 C -0.0766(15) 0.228(3) 0.320(3) 0.19(2) Uani 1 1 d D U . . .
H37A H -0.053850 0.204296 0.339767 0.225 Uiso 1 1 calc R U . . .
H37B H -0.075115 0.256170 0.353470 0.225 Uiso 1 1 calc R U . . .
C38 C -0.0699(18) 0.244(3) 0.241(3) 0.19(3) Uani 1 1 d D U . . .
H38A H -0.081677 0.276151 0.228492 0.232 Uiso 1 1 calc R U . . .
H38B H -0.083755 0.220549 0.202779 0.232 Uiso 1 1 calc R U . . .
C39 C -0.0182(19) 0.242(4) 0.248(4) 0.25(4) Uani 1 1 d D U . . .
H39A H -0.005657 0.263392 0.288577 0.377 Uiso 1 1 calc R U . . .
H39B H -0.008157 0.252544 0.201735 0.377 Uiso 1 1 calc R U . . .
H39C H -0.007787 0.209170 0.259440 0.377 Uiso 1 1 calc R U . . .
C40 C -0.149(2) 0.2597(16) 0.449(3) 0.17(2) Uani 1 1 d D U . . .
H40A H -0.182181 0.261572 0.439718 0.205 Uiso 1 1 calc R U . . .
H40B H -0.136122 0.280560 0.413568 0.205 Uiso 1 1 calc R U . . .
C41 C -0.132(2) 0.2748(19) 0.530(3) 0.18(2) Uani 1 1 d D U . . .
H41A H -0.142722 0.307139 0.541382 0.217 Uiso 1 1 calc R U . . .
H41B H -0.140592 0.251395 0.566324 0.217 Uiso 1 1 calc R U . . .
C42 C -0.0811(18) 0.274(3) 0.526(4) 0.24(4) Uani 1 1 d D U . . .
H42A H -0.064962 0.283349 0.574617 0.353 Uiso 1 1 calc R U . . .
H42B H -0.071836 0.241969 0.513184 0.353 Uiso 1 1 calc R U . . .
H42C H -0.073943 0.297110 0.488512 0.353 Uiso 1 1 calc R U . . .
C43 C -0.1956(7) -0.0967(13) 0.0568(14) 0.097(6) Uani 1 1 d G . . . .
C44 C -0.1608(9) -0.0968(13) 0.1153(10) 0.097(6) Uani 1 1 d G . . . .
H44 H -0.167350 -0.096262 0.165019 0.117 Uiso 1 1 calc R U . . .
C45 C -0.1165(8) -0.0976(13) 0.1012(12) 0.097(6) Uani 1 1 d G . . . .
H45 H -0.092675 -0.097671 0.141261 0.117 Uiso 1 1 calc R U . . .
C46 C -0.1069(7) -0.0984(13) 0.0285(14) 0.097(6) Uani 1 1 d G . . . .
H46 H -0.076578 -0.098979 0.018892 0.117 Uiso 1 1 calc R U . . .
C47 C -0.1417(9) -0.0983(13) -0.0300(10) 0.097(6) Uani 1 1 d G . . . .
H47 H -0.135155 -0.098880 -0.079721 0.117 Uiso 1 1 calc R U . . .
C48 C -0.1860(8) -0.0975(13) -0.0159(12) 0.097(6) Uani 1 1 d G . . . .
H48 H -0.209830 -0.097471 -0.055965 0.117 Uiso 1 1 calc R U . . .
C49 C -0.2668(11) -0.1553(7) 0.0888(17) 0.098(6) Uani 1 1 d G . . . .
C50 C -0.3034(10) -0.1652(8) 0.1258(17) 0.098(6) Uani 1 1 d G . . . .
H50 H -0.319014 -0.139723 0.145873 0.117 Uiso 1 1 calc R U . . .
C51 C -0.3172(9) -0.2123(10) 0.1334(16) 0.098(6) Uani 1 1 d G . . . .
H51 H -0.342170 -0.219078 0.158692 0.117 Uiso 1 1 calc R U . . .
C52 C -0.2943(11) -0.2496(7) 0.1041(17) 0.098(6) Uani 1 1 d G . . . .
H52 H -0.303720 -0.281811 0.109281 0.117 Uiso 1 1 calc R U . . .
C53 C -0.2577(10) -0.2397(8) 0.0671(17) 0.098(6) Uani 1 1 d G . . . .
H53 H -0.242114 -0.265189 0.047051 0.117 Uiso 1 1 calc R U . . .
C54 C -0.2440(9) -0.1926(10) 0.0595(16) 0.098(6) Uani 1 1 d G . . . .
H54 H -0.218957 -0.185834 0.034231 0.117 Uiso 1 1 calc R U . . .
C55 C -0.2861(9) -0.0737(12) -0.0048(12) 0.099(6) Uani 1 1 d G . . . .
C56 C -0.3243(10) -0.0988(10) -0.0341(13) 0.099(6) Uani 1 1 d G . . . .
H56 H -0.332906 -0.126905 -0.010030 0.119 Uiso 1 1 calc R U . . .
C57 C -0.3500(8) -0.0828(11) -0.0987(14) 0.099(6) Uani 1 1 d G . . . .
H57 H -0.376146 -0.099972 -0.118682 0.119 Uiso 1 1 calc R U . . .
C58 C -0.3374(9) -0.0417(11) -0.1339(12) 0.099(6) Uani 1 1 d G . . . .
H58 H -0.354991 -0.030742 -0.178014 0.119 Uiso 1 1 calc R U . . .
C59 C -0.2992(10) -0.0166(10) -0.1046(13) 0.099(6) Uani 1 1 d G . . . .
H59 H -0.290596 0.011555 -0.128694 0.119 Uiso 1 1 calc R U . . .
C60 C -0.2735(8) -0.0325(12) -0.0401(14) 0.099(6) Uani 1 1 d G . . . .
H60 H -0.247356 -0.015377 -0.020042 0.119 Uiso 1 1 calc R U . . .
C61 C -0.4159(8) -0.0542(6) 0.0934(10) 0.047(7) Uani 1 1 d G . . . .
C62 C -0.4150(7) -0.0888(7) 0.1486(8) 0.049(7) Uani 1 1 d G . . . .
H62 H -0.404378 -0.080732 0.198590 0.059 Uiso 1 1 calc R U . . .
C63 C -0.4296(8) -0.1351(7) 0.1306(11) 0.067(10) Uani 1 1 d G . . . .
H63 H -0.429011 -0.158776 0.168374 0.080 Uiso 1 1 calc R U . . .
C64 C -0.4452(9) -0.1469(6) 0.0575(13) 0.079(11) Uani 1 1 d G . . . .
H64 H -0.455163 -0.178599 0.045200 0.094 Uiso 1 1 calc R U . . .
C65 C -0.4461(9) -0.1123(8) 0.0022(9) 0.074(10) Uani 1 1 d G . . . .
H65 H -0.456682 -0.120377 -0.047758 0.089 Uiso 1 1 calc R U . . .
C66 C -0.4314(9) -0.0660(7) 0.0202(9) 0.070(10) Uani 1 1 d G . . . .
H66 H -0.432049 -0.042332 -0.017543 0.084 Uiso 1 1 calc R U . . .
C67 C -0.3962(14) 0.0412(16) 0.038(2) 0.076(5) Uani 1 1 d . . . . .
C68 C -0.3566(14) 0.0508(15) 0.019(2) 0.076(5) Uani 1 1 d . . . . .
H68 H -0.330531 0.042367 0.052135 0.091 Uiso 1 1 calc R U . . .
C69 C -0.3520(14) 0.0718(15) -0.043(2) 0.076(5) Uani 1 1 d . . . . .
H69 H -0.324240 0.070074 -0.062746 0.091 Uiso 1 1 calc R U . . .
C70 C -0.3910(13) 0.0985(16) -0.084(2) 0.076(5) Uani 1 1 d . . . . .
H70 H -0.387352 0.122409 -0.120115 0.091 Uiso 1 1 calc R U . . .
C71 C -0.4319(14) 0.0861(15) -0.066(2) 0.076(5) Uani 1 1 d . . . . .
H71 H -0.458735 0.095936 -0.095744 0.091 Uiso 1 1 calc R U . . .
C72 C -0.4333(14) 0.0591(15) -0.004(2) 0.076(5) Uani 1 1 d . . . . .
H72 H -0.461905 0.052485 0.010768 0.091 Uiso 1 1 calc R U . . .
C73 C -0.4494(10) 0.0309(11) 0.1553(15) 0.042(5) Uani 1 1 d . . . . .
C74 C -0.4905(10) 0.0097(13) 0.1542(16) 0.049(6) Uani 1 1 d . . . . .
H74 H -0.493609 -0.022940 0.139387 0.058 Uiso 1 1 calc R U . . .
C75 C -0.5281(12) 0.0334(14) 0.1737(17) 0.058(7) Uani 1 1 d . . . . .
H75 H -0.556272 0.017512 0.169623 0.069 Uiso 1 1 calc R U . . .
C76 C -0.5243(13) 0.0788(15) 0.1983(17) 0.064(8) Uani 1 1 d . . . . .
H76 H -0.549883 0.094607 0.212387 0.076 Uiso 1 1 calc R U . . .
C77 C -0.4835(12) 0.1032(14) 0.2035(19) 0.062(8) Uani 1 1 d . . . . .
H77 H -0.481118 0.135311 0.220972 0.075 Uiso 1 1 calc R U . . .
C78 C -0.4475(13) 0.0803(14) 0.183(2) 0.074(10) Uani 1 1 d . . . . .
H78 H -0.419694 0.096951 0.187161 0.089 Uiso 1 1 calc R U . . .
C79 C -0.4499(11) -0.0267(11) 0.3693(16) 0.045(6) Uani 1 1 d . . . . .
C80 C -0.4452(12) -0.0718(14) 0.341(3) 0.077(12) Uani 1 1 d . . . . .
H80 H -0.416043 -0.085661 0.348762 0.092 Uiso 1 1 calc R U . . .
C81 C -0.4778(13) -0.0981(15) 0.303(2) 0.073(10) Uani 1 1 d . . . . .
H81 H -0.471987 -0.128839 0.283851 0.087 Uiso 1 1 calc R U . . .
C82 C -0.5213(12) -0.0777(13) 0.2936(17) 0.056(7) Uani 1 1 d . . . . .
H82 H -0.545634 -0.095010 0.267247 0.067 Uiso 1 1 calc R U . . .
C83 C -0.5287(11) -0.0332(13) 0.3220(15) 0.050(7) Uani 1 1 d . . . . .
H83 H -0.558200 -0.020313 0.315215 0.060 Uiso 1 1 calc R U . . .
C84 C -0.4937(10) -0.0064(11) 0.3606(15) 0.043(6) Uani 1 1 d . . . . .
H84 H -0.499118 0.024340 0.380231 0.051 Uiso 1 1 calc R U . . .
C85 C -0.4205(11) 0.0618(11) 0.4401(17) 0.047(7) Uani 1 1 d . . . . .
C86 C -0.4214(14) 0.0946(13) 0.3847(19) 0.071(12) Uani 1 1 d . . . . .
H86 H -0.413218 0.084880 0.338338 0.085 Uiso 1 1 calc R U . . .
C87 C -0.4335(15) 0.1404(14) 0.393(2) 0.079(13) Uani 1 1 d . . . . .
H87 H -0.431923 0.162656 0.354295 0.094 Uiso 1 1 calc R U . . .
C88 C -0.4485(16) 0.1561(12) 0.459(2) 0.076(12) Uani 1 1 d . . . . .
H88 H -0.458306 0.188137 0.464169 0.091 Uiso 1 1 calc R U . . .
C89 C -0.4485(12) 0.1244(11) 0.5149(19) 0.054(8) Uani 1 1 d . . . . .
H89 H -0.457465 0.134633 0.560545 0.065 Uiso 1 1 calc R U . . .
C90 C -0.4354(9) 0.0763(10) 0.5066(16) 0.035(6) Uani 1 1 d . . . . .
H90 H -0.436636 0.054015 0.545771 0.042 Uiso 1 1 calc R U . . .
C91 C -0.3978(10) -0.0302(10) 0.5114(16) 0.039(6) Uani 1 1 d . . . . .
C92 C -0.4342(11) -0.0555(12) 0.5341(15) 0.045(7) Uani 1 1 d . . . . .
H92 H -0.462887 -0.054872 0.504981 0.054 Uiso 1 1 calc R U . . .
C93 C -0.4272(13) -0.0811(12) 0.5997(17) 0.056(8) Uani 1 1 d . . . . .
H93 H -0.451080 -0.099980 0.613687 0.067 Uiso 1 1 calc R U . . .
C94 C -0.3880(12) -0.0803(14) 0.6442(16) 0.060(9) Uani 1 1 d . . . . .
H94 H -0.385004 -0.096273 0.690707 0.072 Uiso 1 1 calc R U . . .
C95 C -0.3517(13) -0.0560(15) 0.6222(18) 0.069(10) Uani 1 1 d . . . . .
H95 H -0.323365 -0.056859 0.652470 0.083 Uiso 1 1 calc R U . . .
C96 C -0.3567(11) -0.0297(13) 0.5538(17) 0.052(8) Uani 1 1 d . . . . .
H96 H -0.332217 -0.012420 0.538491 0.063 Uiso 1 1 calc R U . . .
C97 C -0.2955(9) 0.0873(10) 0.6085(12) 0.081(5) Uani 1 1 d G . . . .
C98 C -0.2813(8) 0.0517(10) 0.6597(14) 0.081(5) Uani 1 1 d G . . . .
H98 H -0.254219 0.034720 0.656085 0.097 Uiso 1 1 calc R U . . .
C99 C -0.3066(9) 0.0409(9) 0.7162(12) 0.081(5) Uani 1 1 d G . . . .
H99 H -0.296867 0.016567 0.751158 0.097 Uiso 1 1 calc R U . . .
C100 C -0.3462(9) 0.0658(10) 0.7214(11) 0.081(5) Uani 1 1 d G . . . .
H100 H -0.363491 0.058400 0.760010 0.097 Uiso 1 1 calc R U . . .
C101 C -0.3604(8) 0.1014(10) 0.6702(14) 0.081(5) Uani 1 1 d G . . . .
H101 H -0.387467 0.118387 0.673788 0.097 Uiso 1 1 calc R U . . .
C102 C -0.3351(9) 0.1122(9) 0.6137(12) 0.081(5) Uani 1 1 d G . . . .
H102 H -0.344819 0.136540 0.578714 0.097 Uiso 1 1 calc R U . . .
C103 C -0.2734(16) 0.1638(10) 0.508(2) 0.156(15) Uani 1 1 d G . . . .
C104 C -0.3133(15) 0.1684(10) 0.461(2) 0.153(18) Uani 1 1 d G . . . .
H104 H -0.329869 0.140579 0.443524 0.183 Uiso 1 1 calc R U . . .
C105 C -0.3289(15) 0.2136(13) 0.438(2) 0.187(19) Uani 1 1 d G . . . .
H105 H -0.356204 0.216711 0.404952 0.225 Uiso 1 1 calc R U . . .
C106 C -0.3047(18) 0.2542(9) 0.463(2) 0.21(3) Uani 1 1 d DG . . . .
H106 H -0.315406 0.285135 0.446950 0.257 Uiso 1 1 calc R U . . .
C107 C -0.2648(17) 0.2496(12) 0.510(2) 0.22(3) Uani 1 1 d G . . . .
H107 H -0.248272 0.277427 0.527521 0.259 Uiso 1 1 calc R U . . .
C108 C -0.2492(14) 0.2044(16) 0.533(2) 0.18(2) Uani 1 1 d G . . . .
H108 H -0.221937 0.201295 0.566094 0.218 Uiso 1 1 calc R U . . .
C109 C -0.2028(10) 0.108(2) 0.5910(19) 0.207(14) Uani 1 1 d G . . . .
C110 C -0.1971(11) 0.128(2) 0.662(2) 0.207(14) Uani 1 1 d G . . . .
H110 H -0.222440 0.139129 0.682681 0.248 Uiso 1 1 calc R U . . .
C111 C -0.1544(13) 0.131(2) 0.7013(16) 0.207(14) Uani 1 1 d G . . . .
H111 H -0.150504 0.145052 0.749497 0.248 Uiso 1 1 calc R U . . .
C112 C -0.1173(10) 0.115(2) 0.6704(19) 0.207(14) Uani 1 1 d G . . . .
H112 H -0.088142 0.117213 0.697491 0.248 Uiso 1 1 calc R U . . .
C113 C -0.1230(11) 0.0948(19) 0.600(2) 0.207(14) Uani 1 1 d G . . . .
H113 H -0.097715 0.083451 0.578669 0.248 Uiso 1 1 calc R U . . .
C114 C -0.1658(13) 0.091(2) 0.5601(17) 0.207(14) Uani 1 1 d G . . . .
H114 H -0.169650 0.077528 0.511851 0.248 Uiso 1 1 calc R U . . .
F1 F 0.5378(14) 0.3303(10) 0.3178(17) 0.158(11) Uani 1 1 d . U . . .
F2 F 0.5313(16) 0.2571(12) 0.3636(18) 0.176(11) Uani 1 1 d . U . . .
F3 F 0.5382(15) 0.2253(10) 0.255(2) 0.165(11) Uani 1 1 d . U . . .
F4 F 0.5906(15) 0.2746(17) 0.310(3) 0.229(14) Uani 1 1 d . U . . .
F5 F 0.4860(12) 0.2825(11) 0.263(2) 0.147(9) Uani 1 1 d . U . . .
F6 F 0.5412(15) 0.3001(12) 0.2046(19) 0.164(11) Uani 1 1 d . U . . .
F7 F 0.0453(18) 0.5771(14) 0.655(3) 0.274(18) Uani 1 1 d D U . . .
F8 F 0.0453(18) 0.6509(19) 0.7104(19) 0.236(16) Uani 1 1 d D U . . .
F9 F 0.0075(18) 0.612(2) 0.5528(18) 0.247(17) Uani 1 1 d D U . . .
F10 F 0.0119(18) 0.6809(13) 0.608(3) 0.234(15) Uani 1 1 d D U . . .
F11 F 0.0767(11) 0.639(2) 0.612(3) 0.261(17) Uani 1 1 d D U . . .
F12 F -0.0167(11) 0.619(2) 0.664(3) 0.278(18) Uani 1 1 d D U . . .
O1 O -0.0320(11) 0.0334(15) 0.378(2) 0.155(13) Uani 1 1 d D . . . .
O2 O -0.0387(11) -0.0579(14) 0.3862(17) 0.135(10) Uani 1 1 d D . . . .
O3 O -0.1492(11) -0.2239(13) 0.2514(19) 0.114(11) Uani 1 1 d D . . . .
O4 O -0.1347(12) -0.2119(14) 0.3932(19) 0.123(12) Uani 1 1 d D . . . .
O5 O -0.1381(12) -0.0759(18) 0.642(2) 0.179(12) Uani 1 1 d D U . . .
O6 O -0.1939(16) -0.1101(17) 0.6788(19) 0.156(12) Uani 1 1 d D U . . .
O7 O -0.3955(12) -0.1676(13) 0.428(2) 0.122(12) Uani 1 1 d D . . . .
O8 O -0.3308(14) -0.2246(10) 0.4165(19) 0.125(11) Uani 1 1 d D . . . .
O9 O -0.1007(13) 0.0472(15) 0.091(2) 0.153(13) Uani 1 1 d D . . . .
O10 O -0.1499(16) 0.1025(19) 0.014(2) 0.200(15) Uani 1 1 d D . . . .
O11 O -0.3542(14) 0.2038(16) 0.108(3) 0.189(14) Uani 1 1 d D U . . .
O12 O -0.2978(17) 0.2275(14) 0.181(3) 0.179(13) Uani 1 1 d D U . . .
O13 O -0.1206(13) 0.2078(13) 0.309(2) 0.137(13) Uani 1 1 d D . . . .
O14 O -0.1340(14) 0.2114(14) 0.4443(19) 0.136(13) Uani 1 1 d D . . . .
P1 P -0.0660(4) -0.0097(7) 0.3745(7) 0.115(5) Uani 1 1 d D . . . .
P2 P -0.1612(5) -0.1909(5) 0.3203(7) 0.094(4) Uani 1 1 d . . . . .
P3 P -0.1831(5) -0.0930(6) 0.6048(6) 0.105(5) Uani 1 1 d D . . . .
P4 P -0.3455(4) -0.1714(3) 0.4055(6) 0.065(3) Uani 1 1 d . . . . .
P5 P -0.1432(6) 0.0781(6) 0.0905(8) 0.119(5) Uani 1 1 d D . . . .
P6 P -0.3212(7) 0.1788(5) 0.1672(7) 0.117(5) Uani 1 1 d D . . . .
P7 P -0.1450(6) 0.1821(6) 0.3708(8) 0.109(4) Uani 1 1 d . . . . .
P8 P -0.2516(3) -0.0938(4) 0.0785(5) 0.066(3) Uani 1 1 d . . . . .
P9 P -0.4015(3) 0.0065(3) 0.1227(4) 0.0398(18) Uani 1 1 d . . . . .
P10 P -0.4034(3) 0.0012(3) 0.4235(4) 0.0386(17) Uani 1 1 d . . . . .
P11 P -0.2578(4) 0.1025(5) 0.5389(6) 0.082(4) Uani 1 1 d . . . . .
P12 P 0.5393(6) 0.2788(4) 0.2842(8) 0.108(4) Uani 1 1 d . U . . .
P13 P 0.0284(8) 0.6289(11) 0.6323(13) 0.179(8) Uani 1 1 d D U . . .
S1 S -0.0940(4) -0.0043(6) 0.2704(7) 0.111(5) Uani 1 1 d . . . . .
S2 S -0.1025(3) -0.0082(6) 0.4599(6) 0.093(4) Uani 1 1 d . . . . .
S3 S -0.2269(4) -0.1908(5) 0.3153(6) 0.090(4) Uani 1 1 d . . . . .
S4 S -0.1332(4) -0.1269(5) 0.3121(6) 0.083(3) Uani 1 1 d . . . . .
S5 S -0.1634(4) -0.1430(5) 0.5362(6) 0.093(4) Uani 1 1 d . . . . .
S6 S -0.2202(6) -0.0413(6) 0.5683(8) 0.123(5) Uani 1 1 d . U . . .
S7 S -0.3037(4) -0.1328(3) 0.4793(5) 0.063(2) Uani 1 1 d . . . . .
S8 S -0.3520(4) -0.1546(3) 0.2989(5) 0.062(2) Uani 1 1 d . . . . .
S9 S -0.1923(4) 0.0305(4) 0.1001(5) 0.083(3) Uani 1 1 d . . . . .
S10 S -0.1324(6) 0.1323(6) 0.1639(9) 0.130(6) Uani 1 1 d . . . . .
S11 S -0.2795(5) 0.1380(4) 0.1160(5) 0.084(4) Uani 1 1 d . . . . .
S12 S -0.3459(4) 0.1590(3) 0.2570(7) 0.083(3) Uani 1 1 d . . . . .
S13 S -0.2102(5) 0.1826(5) 0.3303(7) 0.101(4) Uani 1 1 d . . . . .
S14 S -0.1194(5) 0.1184(6) 0.4002(7) 0.112(4) Uani 1 1 d . . . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 S12 2.386(10) . ?
Ag1 Au1 2.738(3) . ?
Ag1 Ag2 2.855(3) . ?
Ag1 Ag5 2.889(4) . ?
Ag1 Au3 2.890(3) . ?
Ag1 Au5 2.896(3) . ?
Ag1 Au4 2.954(2) . ?
Ag2 S11 2.562(11) . ?
Ag2 S9 2.688(11) . ?
Ag2 Au1 2.825(2) . ?
Ag2 Ag6 2.872(4) . ?
Ag2 Au3 2.941(3) . ?
Ag2 Au2 2.978(3) . ?
Ag2 Ag5 2.980(4) . ?
Ag2 Ag9 3.008(4) . ?
Ag3 S8 2.416(9) . ?
Ag3 Au1 2.740(3) . ?
Ag3 Ag4 2.868(3) . ?
Ag3 Ag7 2.870(3) . ?
Ag3 Au2 2.899(2) . ?
Ag3 Au4 2.903(3) . ?
Ag3 Au3 3.017(3) . ?
Ag4 S6 2.509(14) . ?
Ag4 S7 2.753(10) . ?
Ag4 Au1 2.810(2) . ?
Ag4 Ag8 2.923(4) . ?
Ag4 Au5 2.929(3) . ?
Ag4 Ag11 2.947(4) . ?
Ag4 Au4 2.955(3) . ?
Ag4 Ag7 2.974(3) . ?
Ag5 S13 2.631(14) . ?
Ag5 Ag8 2.851(4) . ?
Ag5 Au1 2.854(3) . ?
Ag5 Au5 2.855(3) . ?
Ag5 S14 2.956(15) . ?
Ag5 Ag9 2.959(4) . ?
Ag5 Ag6 2.979(4) . ?
Ag5 Ag10 3.062(5) . ?
Ag6 S1 2.576(12) . ?
Ag6 S9 2.739(10) . ?
Ag6 Au1 2.806(3) . ?
Ag6 Ag8 2.838(3) . ?
Ag6 Au2 2.898(3) . ?
Ag6 Ag10 2.922(5) . ?
Ag6 Ag7 2.960(4) . ?
Ag7 S4 2.621(10) . ?
Ag7 Au1 2.833(3) . ?
Ag7 Au2 2.856(3) . ?
Ag7 Ag8 2.911(4) . ?
Ag7 Ag12 2.990(4) . ?
Ag7 Ag11 3.074(4) . ?
Ag8 S2 2.480(10) . ?
Ag8 Au1 2.730(2) . ?
Ag8 Au5 2.934(3) . ?
Ag8 Ag12 2.954(5) . ?
Ag9 S11 2.503(14) . ?
Ag9 S13 2.511(12) . ?
Ag9 S10 2.518(17) . ?
Ag10 S14 2.464(14) . ?
Ag10 S10 2.478(18) . ?
Ag10 S1 2.519(18) . ?
Ag11 S7 2.475(11) . ?
Ag11 S3 2.486(12) . ?
Ag11 S5 2.523(12) . ?
Ag11 Ag12 3.333(5) . ?
Ag12 S5 2.482(13) . ?
Ag12 S2 2.530(16) . ?
Ag12 S4 2.552(11) . ?
Au1 Au4 2.7095(15) . ?
Au1 Au2 2.7128(16) . ?
Au1 Au3 2.7244(15) . ?
Au1 Au5 2.7279(16) . ?
Au2 P8 2.301(10) . ?
Au2 Au3 2.8520(17) . ?
Au3 P9 2.331(7) . ?
Au3 Au4 2.9304(14) . ?
Au4 P10 2.301(8) . ?
Au4 Au5 2.8535(17) . ?
Au5 P11 2.307(10) . ?
C1 O1 1.427(10) . ?
C1 C2 1.540(10) . ?
C2 C3 1.538(10) . ?
C4 O2 1.432(10) . ?
C4 C5 1.539(10) . ?
C5 C6 1.537(10) . ?
C7 O3 1.431(10) . ?
C7 C8 1.540(10) . ?
C8 C9 1.541(10) . ?
C10 O4 1.429(10) . ?
C10 C11 1.541(10) . ?
C11 C12 1.539(10) . ?
C13 O5 1.433(10) . ?
C13 C14 1.541(10) . ?
C14 C15 1.543(10) . ?
C16 O6 1.429(10) . ?
C16 C17 1.542(10) . ?
C17 C18 1.537(10) . ?
C19 O7 1.429(10) . ?
C19 C20 1.539(10) . ?
C20 C21 1.542(10) . ?
C22 O8 1.431(10) . ?
C22 C23 1.540(10) . ?
C23 C24 1.539(10) . ?
C25 O9 1.428(10) . ?
C25 C26 1.540(10) . ?
C26 C27 1.543(10) . ?
C28 O10 1.431(10) . ?
C28 C29 1.542(10) . ?
C29 C30 1.540(10) . ?
C31 O11 1.432(10) . ?
C31 C32 1.540(10) . ?
C32 C33 1.538(10) . ?
C34 O12 1.433(10) . ?
C34 C35 1.538(10) . ?
C35 C36 1.539(10) . ?
C37 O13 1.429(10) . ?
C37 C38 1.540(10) . ?
C38 C39 1.541(10) . ?
C40 O14 1.426(10) . ?
C40 C41 1.542(10) . ?
C41 C42 1.539(10) . ?
C43 C44 1.3900 . ?
C43 C48 1.3900 . ?
C43 P8 1.78(2) . ?
C44 C45 1.3900 . ?
C45 C46 1.3900 . ?
C46 C47 1.3900 . ?
C47 C48 1.3900 . ?
C49 C50 1.3900 . ?
C49 C54 1.3900 . ?
C49 P8 1.79(2) . ?
C50 C51 1.3900 . ?
C51 C52 1.3900 . ?
C52 C53 1.3900 . ?
C53 C54 1.3900 . ?
C55 C56 1.3900 . ?
C55 C60 1.3900 . ?
C55 P8 1.81(2) . ?
C56 C57 1.3900 . ?
C57 C58 1.3900 . ?
C58 C59 1.3900 . ?
C59 C60 1.3900 . ?
C61 C62 1.3900 . ?
C61 C66 1.3900 . ?
C61 P9 1.810(17) . ?
C62 C63 1.3900 . ?
C63 C64 1.3900 . ?
C64 C65 1.3900 . ?
C65 C66 1.3900 . ?
C67 C68 1.31(5) . ?
C67 C72 1.36(5) . ?
C67 P9 1.84(3) . ?
C68 C69 1.30(5) . ?
C69 C70 1.50(5) . ?
C70 C71 1.36(5) . ?
C71 C72 1.36(5) . ?
C73 C74 1.37(4) . ?
C73 C78 1.47(5) . ?
C73 P9 1.76(3) . ?
C74 C75 1.39(4) . ?
C75 C76 1.34(5) . ?
C76 C77 1.39(5) . ?
C77 C78 1.35(5) . ?
C79 C80 1.38(5) . ?
C79 C84 1.42(4) . ?
C79 P10 1.78(3) . ?
C80 C81 1.34(5) . ?
C81 C82 1.42(5) . ?
C82 C83 1.37(5) . ?
C83 C84 1.40(4) . ?
C85 C86 1.36(4) . ?
C85 C90 1.40(4) . ?
C85 P10 1.80(3) . ?
C86 C87 1.34(5) . ?
C87 C88 1.40(5) . ?
C88 C89 1.34(5) . ?
C89 C90 1.41(4) . ?
C91 C96 1.37(4) . ?
C91 C92 1.41(4) . ?
C91 P10 1.81(3) . ?
C92 C93 1.38(4) . ?
C93 C94 1.34(5) . ?
C94 C95 1.39(5) . ?
C95 C96 1.44(4) . ?
C97 C98 1.3900 . ?
C97 C102 1.3900 . ?
C97 P11 1.86(2) . ?
C98 C99 1.3900 . ?
C99 C100 1.3900 . ?
C100 C101 1.3900 . ?
C101 C102 1.3900 . ?
C103 C104 1.3900 . ?
C103 C108 1.3900 . ?
C103 P11 1.84(3) . ?
C104 C105 1.3900 . ?
C105 C106 1.3900 . ?
C106 C107 1.3900 . ?
C107 C108 1.3900 . ?
C109 C110 1.3900 . ?
C109 C114 1.3900 . ?
C109 P11 1.80(3) . ?
C110 C111 1.3900 . ?
C111 C112 1.3900 . ?
C112 C113 1.3900 . ?
C113 C114 1.3900 . ?
F1 P12 1.56(3) . ?
F2 P12 1.61(4) . ?
F3 P12 1.58(3) . ?
F4 P12 1.55(4) . ?
F5 P12 1.60(4) . ?
F6 P12 1.57(3) . ?
F7 P13 1.568(10) . ?
F8 P13 1.569(10) . ?
F9 P13 1.570(10) . ?
F10 P13 1.574(10) . ?
F11 P13 1.570(10) . ?
F12 P13 1.567(10) . ?
O1 P1 1.57(3) . ?
O2 P1 1.57(3) . ?
O3 P2 1.63(3) . ?
O4 P2 1.57(3) . ?
O5 P3 1.51(3) . ?
O6 P3 1.50(3) . ?
O7 P4 1.61(4) . ?
O8 P4 1.55(3) . ?
O9 P5 1.54(3) . ?
O10 P5 1.54(3) . ?
O11 P6 1.53(3) . ?
O12 P6 1.53(3) . ?
O13 P7 1.59(3) . ?
O14 P7 1.56(3) . ?
P1 S1 1.974(19) . ?
P1 S2 2.015(16) . ?
P2 S3 1.966(18) . ?
P2 S4 1.99(2) . ?
P3 S6 1.89(2) . ?
P3 S5 2.012(19) . ?
P4 S8 1.979(14) . ?
P4 S7 2.022(15) . ?
P5 S9 2.009(19) . ?
P5 S10 2.01(2) . ?
P6 S12 1.962(16) . ?
P6 S11 2.011(18) . ?
P7 S14 1.98(2) . ?
P7 S13 2.00(2) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
S12 Ag1 Au1 167.0(3) . . ?
S12 Ag1 Ag2 107.6(3) . . ?
Au1 Ag1 Ag2 60.64(7) . . ?
S12 Ag1 Ag5 120.6(3) . . ?
Au1 Ag1 Ag5 60.88(8) . . ?
Ag2 Ag1 Ag5 62.51(9) . . ?
S12 Ag1 Au3 112.7(3) . . ?
Au1 Ag1 Au3 57.83(6) . . ?
Ag2 Ag1 Au3 61.59(7) . . ?
Ag5 Ag1 Au3 110.75(10) . . ?
S12 Ag1 Au5 134.9(3) . . ?
Au1 Ag1 Au5 57.84(6) . . ?
Ag2 Ag1 Au5 109.11(10) . . ?
Ag5 Ag1 Au5 59.14(7) . . ?
Au3 Ag1 Au5 107.24(8) . . ?
S12 Ag1 Au4 128.8(3) . . ?
Au1 Ag1 Au4 56.70(5) . . ?
Ag2 Ag1 Au4 109.65(9) . . ?
Ag5 Ag1 Au4 107.37(9) . . ?
Au3 Ag1 Au4 60.18(6) . . ?
Au5 Ag1 Au4 58.38(5) . . ?
S11 Ag2 S9 99.7(4) . . ?
S11 Ag2 Au1 145.3(3) . . ?
S9 Ag2 Au1 113.8(3) . . ?
S11 Ag2 Ag1 87.7(3) . . ?
S9 Ag2 Ag1 165.6(3) . . ?
Au1 Ag2 Ag1 57.64(7) . . ?
S11 Ag2 Ag6 143.4(3) . . ?
S9 Ag2 Ag6 58.9(3) . . ?
Au1 Ag2 Ag6 59.02(7) . . ?
Ag1 Ag2 Ag6 108.11(10) . . ?
S11 Ag2 Au3 109.9(3) . . ?
S9 Ag2 Au3 127.4(3) . . ?
Au1 Ag2 Au3 56.34(5) . . ?
Ag1 Ag2 Au3 59.79(7) . . ?
Ag6 Ag2 Au3 106.54(9) . . ?
S11 Ag2 Au2 149.1(3) . . ?
S9 Ag2 Au2 74.6(3) . . ?
Au1 Ag2 Au2 55.67(5) . . ?
Ag1 Ag2 Au2 105.20(9) . . ?
Ag6 Ag2 Au2 59.36(8) . . ?
Au3 Ag2 Au2 57.60(6) . . ?
S11 Ag2 Ag5 104.2(3) . . ?
S9 Ag2 Ag5 106.6(3) . . ?
Au1 Ag2 Ag5 58.82(7) . . ?
Ag1 Ag2 Ag5 59.30(9) . . ?
Ag6 Ag2 Ag5 61.18(9) . . ?
Au3 Ag2 Ag5 106.84(8) . . ?
Au2 Ag2 Ag5 106.61(9) . . ?
S11 Ag2 Ag9 52.7(3) . . ?
S9 Ag2 Ag9 87.2(3) . . ?
Au1 Ag2 Ag9 117.89(11) . . ?
Ag1 Ag2 Ag9 87.48(11) . . ?
Ag6 Ag2 Ag9 94.24(13) . . ?
Au3 Ag2 Ag9 145.12(13) . . ?
Au2 Ag2 Ag9 153.00(14) . . ?
Ag5 Ag2 Ag9 59.21(10) . . ?
S8 Ag3 Au1 174.8(3) . . ?
S8 Ag3 Ag4 117.4(3) . . ?
Au1 Ag3 Ag4 60.09(7) . . ?
S8 Ag3 Ag7 123.0(3) . . ?
Au1 Ag3 Ag7 60.63(8) . . ?
Ag4 Ag3 Ag7 62.44(8) . . ?
S8 Ag3 Au2 127.2(3) . . ?
Au1 Ag3 Au2 57.44(5) . . ?
Ag4 Ag3 Au2 108.68(9) . . ?
Ag7 Ag3 Au2 59.35(7) . . ?
S8 Ag3 Au4 117.6(3) . . ?
Au1 Ag3 Au4 57.31(5) . . ?
Ag4 Ag3 Au4 61.60(7) . . ?
Ag7 Ag3 Au4 110.41(10) . . ?
Au2 Ag3 Au4 105.90(8) . . ?
S8 Ag3 Au3 123.0(3) . . ?
Au1 Ag3 Au3 56.24(5) . . ?
Ag4 Ag3 Au3 108.72(9) . . ?
Ag7 Ag3 Au3 106.75(9) . . ?
Au2 Ag3 Au3 57.60(5) . . ?
Au4 Ag3 Au3 59.30(5) . . ?
S6 Ag4 S7 92.0(5) . . ?
S6 Ag4 Au1 132.4(4) . . ?
S7 Ag4 Au1 135.5(2) . . ?
S6 Ag4 Ag3 169.6(4) . . ?
S7 Ag4 Ag3 78.2(2) . . ?
Au1 Ag4 Ag3 57.69(6) . . ?
S6 Ag4 Ag8 82.0(4) . . ?
S7 Ag4 Ag8 154.6(2) . . ?
Au1 Ag4 Ag8 56.83(7) . . ?
Ag3 Ag4 Ag8 105.40(9) . . ?
S6 Ag4 Au5 83.7(4) . . ?
S7 Ag4 Au5 144.0(2) . . ?
Au1 Ag4 Au5 56.72(6) . . ?
Ag3 Ag4 Au5 106.29(9) . . ?
Ag8 Ag4 Au5 60.19(8) . . ?
S6 Ag4 Ag11 91.1(4) . . ?
S7 Ag4 Ag11 51.3(2) . . ?
Au1 Ag4 Ag11 119.15(10) . . ?
Ag3 Ag4 Ag11 80.11(10) . . ?
Ag8 Ag4 Ag11 103.86(11) . . ?
Au5 Ag4 Ag11 163.70(12) . . ?
S6 Ag4 Au4 126.0(4) . . ?
S7 Ag4 Au4 98.4(2) . . ?
Au1 Ag4 Au4 56.00(5) . . ?
Ag3 Ag4 Au4 59.79(7) . . ?
Ag8 Ag4 Au4 105.19(9) . . ?
Au5 Ag4 Au4 58.03(6) . . ?
Ag11 Ag4 Au4 135.26(12) . . ?
S6 Ag4 Ag7 121.8(4) . . ?
S7 Ag4 Ag7 105.2(2) . . ?
Au1 Ag4 Ag7 58.58(7) . . ?
Ag3 Ag4 Ag7 58.81(8) . . ?
Ag8 Ag4 Ag7 59.16(9) . . ?
Au5 Ag4 Ag7 107.40(9) . . ?
Ag11 Ag4 Ag7 62.56(9) . . ?
Au4 Ag4 Ag7 106.17(8) . . ?
S13 Ag5 Ag8 148.6(3) . . ?
S13 Ag5 Au1 146.6(4) . . ?
Ag8 Ag5 Au1 57.18(8) . . ?
S13 Ag5 Au5 109.3(3) . . ?
Ag8 Ag5 Au5 61.89(8) . . ?
Au1 Ag5 Au5 57.09(6) . . ?
S13 Ag5 Ag1 89.6(4) . . ?
Ag8 Ag5 Ag1 108.09(10) . . ?
Au1 Ag5 Ag1 56.95(7) . . ?
Au5 Ag5 Ag1 60.55(7) . . ?
S13 Ag5 S14 73.9(5) . . ?
Ag8 Ag5 S14 81.2(3) . . ?
Au1 Ag5 S14 138.0(3) . . ?
Au5 Ag5 S14 110.1(3) . . ?
Ag1 Ag5 S14 157.6(3) . . ?
S13 Ag5 Ag9 53.0(3) . . ?
Ag8 Ag5 Ag9 149.43(14) . . ?
Au1 Ag5 Ag9 118.60(12) . . ?
Au5 Ag5 Ag9 145.46(15) . . ?
Ag1 Ag5 Ag9 87.81(13) . . ?
S14 Ag5 Ag9 93.9(3) . . ?
S13 Ag5 Ag6 143.2(3) . . ?
Ag8 Ag5 Ag6 58.21(9) . . ?
Au1 Ag5 Ag6 57.46(7) . . ?
Au5 Ag5 Ag6 107.17(10) . . ?
Ag1 Ag5 Ag6 104.37(11) . . ?
S14 Ag5 Ag6 97.8(3) . . ?
Ag9 Ag5 Ag6 93.07(11) . . ?
S13 Ag5 Ag2 106.4(3) . . ?
Ag8 Ag5 Ag2 104.96(11) . . ?
Au1 Ag5 Ag2 57.88(7) . . ?
Au5 Ag5 Ag2 106.80(10) . . ?
Ag1 Ag5 Ag2 58.19(8) . . ?
S14 Ag5 Ag2 140.6(3) . . ?
Ag9 Ag5 Ag2 60.87(10) . . ?
Ag6 Ag5 Ag2 57.61(9) . . ?
S13 Ag5 Ag10 94.0(3) . . ?
Ag8 Ag5 Ag10 83.05(14) . . ?
Au1 Ag5 Ag10 114.81(13) . . ?
Au5 Ag5 Ag10 142.86(15) . . ?
Ag1 Ag5 Ag10 150.77(13) . . ?
S14 Ag5 Ag10 48.3(3) . . ?
Ag9 Ag5 Ag10 71.66(15) . . ?
Ag6 Ag5 Ag10 57.83(11) . . ?
Ag2 Ag5 Ag10 93.12(12) . . ?
S1 Ag6 S9 101.0(4) . . ?
S1 Ag6 Au1 146.1(3) . . ?
S9 Ag6 Au1 112.8(3) . . ?
S1 Ag6 Ag8 88.6(3) . . ?
S9 Ag6 Ag8 163.6(3) . . ?
Au1 Ag6 Ag8 57.85(7) . . ?
S1 Ag6 Ag2 147.5(4) . . ?
S9 Ag6 Ag2 57.2(3) . . ?
Au1 Ag6 Ag2 59.67(7) . . ?
Ag8 Ag6 Ag2 108.21(11) . . ?
S1 Ag6 Au2 140.9(4) . . ?
S9 Ag6 Au2 75.2(3) . . ?
Au1 Ag6 Au2 56.77(6) . . ?
Ag8 Ag6 Au2 105.71(9) . . ?
Ag2 Ag6 Au2 62.14(8) . . ?
S1 Ag6 Ag10 54.1(4) . . ?
S9 Ag6 Ag10 89.0(3) . . ?
Au1 Ag6 Ag10 120.99(13) . . ?
Ag8 Ag6 Ag10 85.85(12) . . ?
Ag2 Ag6 Ag10 98.45(15) . . ?
Au2 Ag6 Ag10 159.52(15) . . ?
S1 Ag6 Ag7 102.4(4) . . ?
S9 Ag6 Ag7 129.0(3) . . ?
Au1 Ag6 Ag7 58.79(7) . . ?
Ag8 Ag6 Ag7 60.23(9) . . ?
Ag2 Ag6 Ag7 110.08(10) . . ?
Au2 Ag6 Ag7 58.35(7) . . ?
Ag10 Ag6 Ag7 140.70(14) . . ?
S1 Ag6 Ag5 109.7(4) . . ?
S9 Ag6 Ag5 105.3(3) . . ?
Au1 Ag6 Ag5 59.02(7) . . ?
Ag8 Ag6 Ag5 58.63(9) . . ?
Ag2 Ag6 Ag5 61.21(10) . . ?
Au2 Ag6 Ag5 108.73(10) . . ?
Ag10 Ag6 Ag5 62.50(11) . . ?
Ag7 Ag6 Ag5 108.31(10) . . ?
S4 Ag7 Au1 148.4(3) . . ?
S4 Ag7 Au2 119.7(2) . . ?
Au1 Ag7 Au2 56.95(6) . . ?
S4 Ag7 Ag3 152.9(3) . . ?
Au1 Ag7 Ag3 57.41(7) . . ?
Au2 Ag7 Ag3 60.83(7) . . ?
S4 Ag7 Ag8 100.3(3) . . ?
Au1 Ag7 Ag8 56.73(8) . . ?
Au2 Ag7 Ag8 104.90(10) . . ?
Ag3 Ag7 Ag8 105.66(10) . . ?
S4 Ag7 Ag6 92.3(3) . . ?
Au1 Ag7 Ag6 57.90(8) . . ?
Au2 Ag7 Ag6 59.74(7) . . ?
Ag3 Ag7 Ag6 108.01(10) . . ?
Ag8 Ag7 Ag6 57.81(9) . . ?
S4 Ag7 Ag4 133.0(2) . . ?
Au1 Ag7 Ag4 57.81(7) . . ?
Au2 Ag7 Ag4 106.94(9) . . ?
Ag3 Ag7 Ag4 58.75(8) . . ?
Ag8 Ag7 Ag4 59.56(8) . . ?
Ag6 Ag7 Ag4 106.57(11) . . ?
S4 Ag7 Ag12 53.6(2) . . ?
Au1 Ag7 Ag12 115.54(12) . . ?
Au2 Ag7 Ag12 157.33(13) . . ?
Ag3 Ag7 Ag12 136.57(11) . . ?
Ag8 Ag7 Ag12 60.06(11) . . ?
Ag6 Ag7 Ag12 97.77(12) . . ?
Ag4 Ag7 Ag12 80.92(10) . . ?
S4 Ag7 Ag11 89.6(3) . . ?
Au1 Ag7 Ag11 114.30(10) . . ?
Au2 Ag7 Ag11 135.70(12) . . ?
Ag3 Ag7 Ag11 77.97(10) . . ?
Ag8 Ag7 Ag11 101.05(11) . . ?
Ag6 Ag7 Ag11 158.77(13) . . ?
Ag4 Ag7 Ag11 58.30(9) . . ?
Ag12 Ag7 Ag11 66.68(11) . . ?
S2 Ag8 Au1 166.2(3) . . ?
S2 Ag8 Ag6 106.7(3) . . ?
Au1 Ag8 Ag6 60.49(7) . . ?
S2 Ag8 Ag5 119.1(4) . . ?
Au1 Ag8 Ag5 61.46(8) . . ?
Ag6 Ag8 Ag5 63.15(10) . . ?
S2 Ag8 Ag7 110.5(4) . . ?
Au1 Ag8 Ag7 60.20(7) . . ?
Ag6 Ag8 Ag7 61.96(9) . . ?
Ag5 Ag8 Ag7 113.33(10) . . ?
S2 Ag8 Ag4 127.1(3) . . ?
Au1 Ag8 Ag4 59.49(7) . . ?
Ag6 Ag8 Ag4 111.29(10) . . ?
Ag5 Ag8 Ag4 110.49(11) . . ?
Ag7 Ag8 Ag4 61.29(9) . . ?
S2 Ag8 Au5 135.8(3) . . ?
Au1 Ag8 Au5 57.44(6) . . ?
Ag6 Ag8 Au5 108.85(10) . . ?
Ag5 Ag8 Au5 59.11(8) . . ?
Ag7 Ag8 Au5 108.93(9) . . ?
Ag4 Ag8 Au5 59.99(7) . . ?
S2 Ag8 Ag12 54.7(4) . . ?
Au1 Ag8 Ag12 120.10(13) . . ?
Ag6 Ag8 Ag12 101.38(12) . . ?
Ag5 Ag8 Ag12 162.33(12) . . ?
Ag7 Ag8 Ag12 61.28(10) . . ?
Ag4 Ag8 Ag12 82.36(11) . . ?
Au5 Ag8 Ag12 138.00(12) . . ?
S11 Ag9 S13 120.4(5) . . ?
S11 Ag9 S10 121.9(5) . . ?
S13 Ag9 S10 117.4(5) . . ?
S11 Ag9 Ag5 106.3(3) . . ?
S13 Ag9 Ag5 56.8(3) . . ?
S10 Ag9 Ag5 99.8(4) . . ?
S11 Ag9 Ag2 54.5(3) . . ?
S13 Ag9 Ag2 108.8(3) . . ?
S10 Ag9 Ag2 101.7(4) . . ?
Ag5 Ag9 Ag2 59.92(9) . . ?
S14 Ag10 S10 120.1(6) . . ?
S14 Ag10 S1 118.5(5) . . ?
S10 Ag10 S1 121.4(5) . . ?
S14 Ag10 Ag6 112.1(3) . . ?
S10 Ag10 Ag6 102.1(4) . . ?
S1 Ag10 Ag6 55.9(3) . . ?
S14 Ag10 Ag5 63.6(4) . . ?
S10 Ag10 Ag5 98.0(4) . . ?
S1 Ag10 Ag5 108.8(3) . . ?
Ag6 Ag10 Ag5 59.67(10) . . ?
S7 Ag11 S3 121.0(4) . . ?
S7 Ag11 S5 114.9(4) . . ?
S3 Ag11 S5 123.8(4) . . ?
S7 Ag11 Ag4 60.3(2) . . ?
S3 Ag11 Ag4 116.7(3) . . ?
S5 Ag11 Ag4 95.5(3) . . ?
S7 Ag11 Ag7 109.8(2) . . ?
S3 Ag11 Ag7 64.5(3) . . ?
S5 Ag11 Ag7 102.9(3) . . ?
Ag4 Ag11 Ag7 59.14(9) . . ?
S7 Ag11 Ag12 131.8(3) . . ?
S3 Ag11 Ag12 95.0(3) . . ?
S5 Ag11 Ag12 47.7(3) . . ?
Ag4 Ag11 Ag12 75.79(11) . . ?
Ag7 Ag11 Ag12 55.44(9) . . ?
S5 Ag12 S2 126.7(4) . . ?
S5 Ag12 S4 118.0(5) . . ?
S2 Ag12 S4 115.0(4) . . ?
S5 Ag12 Ag8 118.8(3) . . ?
S2 Ag12 Ag8 53.1(3) . . ?
S4 Ag12 Ag8 100.8(3) . . ?
S5 Ag12 Ag7 106.4(3) . . ?
S2 Ag12 Ag7 106.7(3) . . ?
S4 Ag12 Ag7 55.8(2) . . ?
Ag8 Ag12 Ag7 58.65(9) . . ?
S5 Ag12 Ag11 48.8(3) . . ?
S2 Ag12 Ag11 143.1(3) . . ?
S4 Ag12 Ag11 85.2(3) . . ?
Ag8 Ag12 Ag11 94.43(11) . . ?
Ag7 Ag12 Ag11 57.88(10) . . ?
Au4 Au1 Au2 117.29(5) . . ?
Au4 Au1 Au3 65.27(4) . . ?
Au2 Au1 Au3 63.27(4) . . ?
Au4 Au1 Au5 63.31(4) . . ?
Au2 Au1 Au5 179.34(6) . . ?
Au3 Au1 Au5 117.37(6) . . ?
Au4 Au1 Ag8 118.27(6) . . ?
Au2 Au1 Ag8 114.30(7) . . ?
Au3 Au1 Ag8 176.39(7) . . ?
Au5 Au1 Ag8 65.04(7) . . ?
Au4 Au1 Ag1 65.67(6) . . ?
Au2 Au1 Ag1 116.46(6) . . ?
Au3 Au1 Ag1 63.88(6) . . ?
Au5 Au1 Ag1 63.98(6) . . ?
Ag8 Au1 Ag1 116.37(9) . . ?
Au4 Au1 Ag3 64.37(6) . . ?
Au2 Au1 Ag3 64.24(6) . . ?
Au3 Au1 Ag3 67.03(6) . . ?
Au5 Au1 Ag3 116.05(6) . . ?
Ag8 Au1 Ag3 114.75(9) . . ?
Ag1 Au1 Ag3 120.36(8) . . ?
Au4 Au1 Ag6 179.07(8) . . ?
Au2 Au1 Ag6 63.32(6) . . ?
Au3 Au1 Ag6 114.78(6) . . ?
Au5 Au1 Ag6 116.09(7) . . ?
Ag8 Au1 Ag6 61.67(7) . . ?
Ag1 Au1 Ag6 113.47(9) . . ?
Ag3 Au1 Ag6 116.53(9) . . ?
Au4 Au1 Ag4 64.71(6) . . ?
Au2 Au1 Ag4 116.06(7) . . ?
Au3 Au1 Ag4 119.60(7) . . ?
Au5 Au1 Ag4 63.83(6) . . ?
Ag8 Au1 Ag4 63.68(8) . . ?
Ag1 Au1 Ag4 119.31(8) . . ?
Ag3 Au1 Ag4 62.22(7) . . ?
Ag6 Au1 Ag4 115.78(8) . . ?
Au4 Au1 Ag2 118.17(7) . . ?
Au2 Au1 Ag2 65.02(6) . . ?
Au3 Au1 Ag2 63.98(6) . . ?
Au5 Au1 Ag2 115.05(7) . . ?
Ag8 Au1 Ag2 112.74(8) . . ?
Ag1 Au1 Ag2 61.73(7) . . ?
Ag3 Au1 Ag2 120.63(8) . . ?
Ag6 Au1 Ag2 61.32(8) . . ?
Ag4 Au1 Ag2 176.42(9) . . ?
Au4 Au1 Ag7 117.55(7) . . ?
Au2 Au1 Ag7 61.95(6) . . ?
Au3 Au1 Ag7 116.46(7) . . ?
Au5 Au1 Ag7 117.59(7) . . ?
Ag8 Au1 Ag7 63.07(9) . . ?
Ag1 Au1 Ag7 176.73(8) . . ?
Ag3 Au1 Ag7 61.96(8) . . ?
Ag6 Au1 Ag7 63.32(8) . . ?
Ag4 Au1 Ag7 63.60(7) . . ?
Ag2 Au1 Ag7 115.27(8) . . ?
Au4 Au1 Ag5 115.59(7) . . ?
Au2 Au1 Ag5 118.20(7) . . ?
Au3 Au1 Ag5 116.94(8) . . ?
Au5 Au1 Ag5 61.47(6) . . ?
Ag8 Au1 Ag5 61.36(9) . . ?
Ag1 Au1 Ag5 62.17(9) . . ?
Ag3 Au1 Ag5 175.84(9) . . ?
Ag6 Au1 Ag5 63.52(9) . . ?
Ag4 Au1 Ag5 113.80(8) . . ?
Ag2 Au1 Ag5 63.30(8) . . ?
Ag7 Au1 Ag5 115.68(9) . . ?
P8 Au2 Au1 174.4(3) . . ?
P8 Au2 Au3 127.0(3) . . ?
Au1 Au2 Au3 58.56(4) . . ?
P8 Au2 Ag7 113.8(3) . . ?
Au1 Au2 Ag7 61.10(6) . . ?
Au3 Au2 Ag7 111.75(6) . . ?
P8 Au2 Ag6 116.2(3) . . ?
Au1 Au2 Ag6 59.91(6) . . ?
Au3 Au2 Ag6 108.24(7) . . ?
Ag7 Au2 Ag6 61.91(8) . . ?
P8 Au2 Ag3 122.1(3) . . ?
Au1 Au2 Ag3 58.33(6) . . ?
Au3 Au2 Ag3 63.28(6) . . ?
Ag7 Au2 Ag3 59.81(7) . . ?
Ag6 Au2 Ag3 108.92(7) . . ?
P8 Au2 Ag2 123.0(3) . . ?
Au1 Au2 Ag2 59.31(5) . . ?
Au3 Au2 Ag2 60.55(6) . . ?
Ag7 Au2 Ag2 110.00(8) . . ?
Ag6 Au2 Ag2 58.49(8) . . ?
Ag3 Au2 Ag2 110.70(7) . . ?
P9 Au3 Au1 179.4(2) . . ?
P9 Au3 Au2 121.3(2) . . ?
Au1 Au3 Au2 58.16(4) . . ?
P9 Au3 Ag1 122.3(2) . . ?
Au1 Au3 Ag1 58.29(6) . . ?
Au2 Au3 Ag1 107.63(7) . . ?
P9 Au3 Au4 123.12(19) . . ?
Au1 Au3 Au4 57.12(4) . . ?
Au2 Au3 Au4 106.40(5) . . ?
Ag1 Au3 Au4 61.00(5) . . ?
P9 Au3 Ag2 120.4(2) . . ?
Au1 Au3 Ag2 59.67(6) . . ?
Au2 Au3 Ag2 61.84(6) . . ?
Ag1 Au3 Ag2 58.62(7) . . ?
Au4 Au3 Ag2 107.94(6) . . ?
P9 Au3 Ag3 122.9(2) . . ?
Au1 Au3 Ag3 56.72(6) . . ?
Au2 Au3 Ag3 59.12(5) . . ?
Ag1 Au3 Ag3 107.11(7) . . ?
Au4 Au3 Ag3 58.40(5) . . ?
Ag2 Au3 Ag3 108.46(8) . . ?
P10 Au4 Au1 178.6(2) . . ?
P10 Au4 Au5 120.6(2) . . ?
Au1 Au4 Au5 58.66(4) . . ?
P10 Au4 Ag3 121.5(2) . . ?
Au1 Au4 Ag3 58.31(6) . . ?
Au5 Au4 Ag3 107.36(7) . . ?
P10 Au4 Au3 123.73(19) . . ?
Au1 Au4 Au3 57.61(4) . . ?
Au5 Au4 Au3 107.28(5) . . ?
Ag3 Au4 Au3 62.29(5) . . ?
P10 Au4 Ag1 123.3(2) . . ?
Au1 Au4 Ag1 57.63(6) . . ?
Au5 Au4 Ag1 59.79(6) . . ?
Ag3 Au4 Ag1 108.47(7) . . ?
Au3 Au4 Ag1 58.82(5) . . ?
P10 Au4 Ag4 119.3(2) . . ?
Au1 Au4 Ag4 59.29(5) . . ?
Au5 Au4 Ag4 60.53(6) . . ?
Ag3 Au4 Ag4 58.62(7) . . ?
Au3 Au4 Ag4 108.73(6) . . ?
Ag1 Au4 Ag4 108.26(8) . . ?
P11 Au5 Au1 173.3(3) . . ?
P11 Au5 Au4 126.1(3) . . ?
Au1 Au5 Au4 58.03(4) . . ?
P11 Au5 Ag5 112.1(3) . . ?
Au1 Au5 Ag5 61.44(6) . . ?
Au4 Au5 Ag5 111.13(7) . . ?
P11 Au5 Ag1 117.9(4) . . ?
Au1 Au5 Ag1 58.18(6) . . ?
Au4 Au5 Ag1 61.83(6) . . ?
Ag5 Au5 Ag1 60.31(8) . . ?
P11 Au5 Ag4 126.7(3) . . ?
Au1 Au5 Ag4 59.44(6) . . ?
Au4 Au5 Ag4 61.45(6) . . ?
Ag5 Au5 Ag4 110.25(9) . . ?
Ag1 Au5 Ag4 110.59(8) . . ?
P11 Au5 Ag8 121.6(4) . . ?
Au1 Au5 Ag8 57.52(6) . . ?
Au4 Au5 Ag8 107.55(7) . . ?
Ag5 Au5 Ag8 59.00(8) . . ?
Ag1 Au5 Ag8 105.69(7) . . ?
Ag4 Au5 Ag8 59.82(8) . . ?
O1 C1 C2 100(4) . . ?
C3 C2 C1 111(6) . . ?
O2 C4 C5 112(5) . . ?
C6 C5 C4 134(7) . . ?
O3 C7 C8 111(4) . . ?
C7 C8 C9 109(6) . . ?
O4 C10 C11 105(5) . . ?
C12 C11 C10 109(6) . . ?
O5 C13 C14 107(5) . . ?
C13 C14 C15 99.3(9) . . ?
O6 C16 C17 120(6) . . ?
C18 C17 C16 103(6) . . ?
O7 C19 C20 103(4) . . ?
C19 C20 C21 99.3(9) . . ?
O8 C22 C23 108(5) . . ?
C24 C23 C22 148(7) . . ?
O9 C25 C26 119(6) . . ?
C25 C26 C27 102.1(9) . . ?
O10 C28 C29 104.3(10) . . ?
C30 C29 C28 99.3(9) . . ?
O11 C31 C32 91(4) . . ?
C33 C32 C31 101(6) . . ?
O12 C34 C35 106(5) . . ?
C34 C35 C36 112(5) . . ?
O13 C37 C38 103(4) . . ?
C37 C38 C39 99.4(9) . . ?
O14 C40 C41 104.6(10) . . ?
C42 C41 C40 99.4(9) . . ?
C44 C43 C48 120.0 . . ?
C44 C43 P8 117.8(15) . . ?
C48 C43 P8 122.2(15) . . ?
C45 C44 C43 120.0 . . ?
C44 C45 C46 120.0 . . ?
C47 C46 C45 120.0 . . ?
C46 C47 C48 120.0 . . ?
C47 C48 C43 120.0 . . ?
C50 C49 C54 120.0 . . ?
C50 C49 P8 118.0(17) . . ?
C54 C49 P8 122.0(17) . . ?
C51 C50 C49 120.0 . . ?
C52 C51 C50 120.0 . . ?
C51 C52 C53 120.0 . . ?
C54 C53 C52 120.0 . . ?
C53 C54 C49 120.0 . . ?
C56 C55 C60 120.0 . . ?
C56 C55 P8 121.2(17) . . ?
C60 C55 P8 118.8(17) . . ?
C55 C56 C57 120.0 . . ?
C56 C57 C58 120.0 . . ?
C59 C58 C57 120.0 . . ?
C58 C59 C60 120.0 . . ?
C59 C60 C55 120.0 . . ?
C62 C61 C66 120.0 . . ?
C62 C61 P9 117.0(11) . . ?
C66 C61 P9 122.7(11) . . ?
C61 C62 C63 120.0 . . ?
C64 C63 C62 120.0 . . ?
C65 C64 C63 120.0 . . ?
C64 C65 C66 120.0 . . ?
C65 C66 C61 120.0 . . ?
C68 C67 C72 119(3) . . ?
C68 C67 P9 121(3) . . ?
C72 C67 P9 121(3) . . ?
C69 C68 C67 122(4) . . ?
C68 C69 C70 119(4) . . ?
C71 C70 C69 115(3) . . ?
C70 C71 C72 118(4) . . ?
C71 C72 C67 124(4) . . ?
C74 C73 C78 114(3) . . ?
C74 C73 P9 127(3) . . ?
C78 C73 P9 119(3) . . ?
C73 C74 C75 123(3) . . ?
C76 C75 C74 120(4) . . ?
C75 C76 C77 121(4) . . ?
C78 C77 C76 119(4) . . ?
C77 C78 C73 123(4) . . ?
C80 C79 C84 117(3) . . ?
C80 C79 P10 120(3) . . ?
C84 C79 P10 122(2) . . ?
C81 C80 C79 126(4) . . ?
C80 C81 C82 116(4) . . ?
C83 C82 C81 121(3) . . ?
C82 C83 C84 122(3) . . ?
C83 C84 C79 118(3) . . ?
C86 C85 C90 118(3) . . ?
C86 C85 P10 119(2) . . ?
C90 C85 P10 123(2) . . ?
C87 C86 C85 122(3) . . ?
C86 C87 C88 121(3) . . ?
C89 C88 C87 118(3) . . ?
C88 C89 C90 121(3) . . ?
C85 C90 C89 119(3) . . ?
C96 C91 C92 121(3) . . ?
C96 C91 P10 118(2) . . ?
C92 C91 P10 121(2) . . ?
C93 C92 C91 118(3) . . ?
C94 C93 C92 122(3) . . ?
C93 C94 C95 120(3) . . ?
C94 C95 C96 120(3) . . ?
C91 C96 C95 118(3) . . ?
C98 C97 C102 120.0 . . ?
C98 C97 P11 117.3(17) . . ?
C102 C97 P11 122.5(17) . . ?
C99 C98 C97 120.0 . . ?
C98 C99 C100 120.0 . . ?
C101 C100 C99 120.0 . . ?
C102 C101 C100 120.0 . . ?
C101 C102 C97 120.0 . . ?
C104 C103 C108 120.0 . . ?
C104 C103 P11 116(3) . . ?
C108 C103 P11 124(3) . . ?
C105 C104 C103 120.0 . . ?
C104 C105 C106 120.0 . . ?
C107 C106 C105 120.0 . . ?
C106 C107 C108 120.0 . . ?
C107 C108 C103 120.0 . . ?
C110 C109 C114 120.0 . . ?
C110 C109 P11 121(2) . . ?
C114 C109 P11 119(2) . . ?
C111 C110 C109 120.0 . . ?
C110 C111 C112 120.0 . . ?
C113 C112 C111 120.0 . . ?
C112 C113 C114 120.0 . . ?
C113 C114 C109 120.0 . . ?
C1 O1 P1 132(4) . . ?
C4 O2 P1 131(4) . . ?
C7 O3 P2 126(3) . . ?
C10 O4 P2 123(4) . . ?
C13 O5 P3 123(5) . . ?
C16 O6 P3 110(4) . . ?
C19 O7 P4 105(3) . . ?
C22 O8 P4 132(4) . . ?
C25 O9 P5 130(5) . . ?
C28 O10 P5 123(6) . . ?
C31 O11 P6 118(2) . . ?
C34 O12 P6 125(5) . . ?
C37 O13 P7 126(3) . . ?
C40 O14 P7 121(3) . . ?
O1 P1 O2 109(2) . . ?
O1 P1 S1 100.2(18) . . ?
O2 P1 S1 110.0(15) . . ?
O1 P1 S2 111.4(16) . . ?
O2 P1 S2 103.9(15) . . ?
S1 P1 S2 122.1(8) . . ?
O4 P2 O3 107.5(19) . . ?
O4 P2 S3 115.7(16) . . ?
O3 P2 S3 106.7(15) . . ?
O4 P2 S4 103.1(18) . . ?
O3 P2 S4 108.0(16) . . ?
S3 P2 S4 115.4(8) . . ?
O6 P3 O5 89(3) . . ?
O6 P3 S6 112(2) . . ?
O5 P3 S6 112(2) . . ?
O6 P3 S5 117(2) . . ?
O5 P3 S5 100.3(19) . . ?
S6 P3 S5 121.3(8) . . ?
O8 P4 O7 107(2) . . ?
O8 P4 S8 109.9(14) . . ?
O7 P4 S8 104.8(14) . . ?
O8 P4 S7 106.3(16) . . ?
O7 P4 S7 108.5(16) . . ?
S8 P4 S7 119.8(6) . . ?
O10 P5 O9 105(2) . . ?
O10 P5 S9 111(2) . . ?
O9 P5 S9 104.4(19) . . ?
O10 P5 S10 105(2) . . ?
O9 P5 S10 111(2) . . ?
S9 P5 S10 119.6(8) . . ?
O11 P6 O12 87(2) . . ?
O11 P6 S12 116(2) . . ?
O12 P6 S12 109(2) . . ?
O11 P6 S11 108(2) . . ?
O12 P6 S11 106(2) . . ?
S12 P6 S11 123.6(7) . . ?
O14 P7 O13 108(2) . . ?
O14 P7 S14 102.1(19) . . ?
O13 P7 S14 113.3(18) . . ?
O14 P7 S13 113.3(19) . . ?
O13 P7 S13 104.8(18) . . ?
S14 P7 S13 115.6(9) . . ?
C43 P8 C49 103.9(16) . . ?
C43 P8 C55 106.3(14) . . ?
C49 P8 C55 105.0(16) . . ?
C43 P8 Au2 114.1(11) . . ?
C49 P8 Au2 112.9(10) . . ?
C55 P8 Au2 113.7(11) . . ?
C73 P9 C61 106.6(14) . . ?
C73 P9 C67 104.0(17) . . ?
C61 P9 C67 106.8(16) . . ?
C73 P9 Au3 115.3(10) . . ?
C61 P9 Au3 109.0(8) . . ?
C67 P9 Au3 114.5(13) . . ?
C79 P10 C85 106.4(16) . . ?
C79 P10 C91 104.7(14) . . ?
C85 P10 C91 107.5(14) . . ?
C79 P10 Au4 114.6(10) . . ?
C85 P10 Au4 109.8(11) . . ?
C91 P10 Au4 113.4(10) . . ?
C109 P11 C103 105(2) . . ?
C109 P11 C97 105.1(17) . . ?
C103 P11 C97 105.3(15) . . ?
C109 P11 Au5 114.1(15) . . ?
C103 P11 Au5 109.8(13) . . ?
C97 P11 Au5 116.4(10) . . ?
F4 P12 F1 92(2) . . ?
F4 P12 F6 99(3) . . ?
F1 P12 F6 91.1(18) . . ?
F4 P12 F3 90(2) . . ?
F1 P12 F3 175(3) . . ?
F6 P12 F3 93(2) . . ?
F4 P12 F5 177(3) . . ?
F1 P12 F5 88(2) . . ?
F6 P12 F5 85(2) . . ?
F3 P12 F5 90(2) . . ?
F4 P12 F2 88(3) . . ?
F1 P12 F2 89(2) . . ?
F6 P12 F2 174(3) . . ?
F3 P12 F2 86.8(19) . . ?
F5 P12 F2 89(2) . . ?
F12 P13 F7 90.0(11) . . ?
F12 P13 F8 86(3) . . ?
F7 P13 F8 94(3) . . ?
F12 P13 F11 172(4) . . ?
F7 P13 F11 87(3) . . ?
F8 P13 F11 87(3) . . ?
F12 P13 F9 91(3) . . ?
F7 P13 F9 92(4) . . ?
F8 P13 F9 173(4) . . ?
F11 P13 F9 96(3) . . ?
F12 P13 F10 91(3) . . ?
F7 P13 F10 179(3) . . ?
F8 P13 F10 87(3) . . ?
F11 P13 F10 92(3) . . ?
F9 P13 F10 87(3) . . ?
P1 S1 Ag10 96.2(8) . . ?
P1 S1 Ag6 117.4(6) . . ?
Ag10 S1 Ag6 70.0(4) . . ?
P1 S2 Ag8 105.2(6) . . ?
P1 S2 Ag12 96.9(7) . . ?
Ag8 S2 Ag12 72.3(3) . . ?
P2 S3 Ag11 97.1(6) . . ?
P2 S4 Ag12 102.4(6) . . ?
P2 S4 Ag7 91.1(6) . . ?
Ag12 S4 Ag7 70.6(3) . . ?
P3 S5 Ag12 100.7(8) . . ?
P3 S5 Ag11 104.1(6) . . ?
Ag12 S5 Ag11 83.5(3) . . ?
P3 S6 Ag4 114.6(8) . . ?
P4 S7 Ag11 100.1(5) . . ?
P4 S7 Ag4 122.3(5) . . ?
Ag11 S7 Ag4 68.4(3) . . ?
P4 S8 Ag3 102.1(5) . . ?
P5 S9 Ag2 116.2(7) . . ?
P5 S9 Ag6 105.0(7) . . ?
Ag2 S9 Ag6 63.9(2) . . ?
P5 S10 Ag10 97.3(8) . . ?
P5 S10 Ag9 106.1(8) . . ?
Ag10 S10 Ag9 89.8(4) . . ?
P6 S11 Ag9 99.0(7) . . ?
P6 S11 Ag2 115.0(5) . . ?
Ag9 S11 Ag2 72.9(3) . . ?
P6 S12 Ag1 105.0(6) . . ?
P7 S13 Ag9 101.4(7) . . ?
P7 S13 Ag5 89.1(7) . . ?
Ag9 S13 Ag5 70.2(3) . . ?
P7 S14 Ag10 100.3(7) . . ?
P7 S14 Ag5 80.7(7) . . ?
Ag10 S14 Ag5 68.1(3) . . ?

_refine_diff_density_max         2.809
_refine_diff_density_min         -5.870
_refine_diff_density_rms         0.317


# start Validation Reply Form
_vrf_PLAT971_1                   
;
PROBLEM: Check Calcd Resid. Dens.  1.52Ang From C96             3.18 eA-3 
RESPONSE: It could arise from strong absorption effects that were not 
fully corrected for.

;
_vrf_PLAT972_1                   
;
PROBLEM: Check Calcd Resid. Dens.  1.37Ang From C30            -4.15 eA-3 
RESPONSE: It could arise from strong absorption effects that were not 
fully corrected for.

;
_vrf_PLAT973_1                   
;
PROBLEM: Check Calcd Positive Resid. Density on       Au5       2.17 eA-3 
RESPONSE: It could arise from strong absorption effects that were not 
fully corrected for.

;
_vrf_PLAT220_1                   
;
PROBLEM: NonSolvent   Resd 1  C   Ueq(max)/Ueq(min) Range        9.4 Ratio 
RESPONSE: Large Uiso presented on the extensive alkyl chains showed the 
potentiality of disorder, which remain unresolved.

;
_vrf_PLAT342_1                   
;
PROBLEM: Low Bond Precision on  C-C Bonds ...............      0.058 Ang. 
RESPONSE: This problem could be caused by weak diffraction at high 
angles (possibly due to the small crystal size), resulting in 
relatively imprecision diffraction data and the limitation of the 
structural model with potential disorder on the alkyl side chains.

;

# end Validation Reply Form



####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_2
_database_code_depnum_ccdc_archive 'CCDC 2237652'
loop_
_audit_author_name
_audit_author_address
'Jian-Hong Liao'
;Department of Chemistry, National Dong Hwa University
Taiwan
;
_audit_update_record             
;
2023-01-23 deposited with the CCDC.	2023-03-02 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C114 H158 Ag10.75 Au4.25 O14 P11 Pt S14'
_chemical_formula_weight         4733.70

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   15.878(3)
_cell_length_b                   17.651(3)
_cell_length_c                   27.489(5)
_cell_angle_alpha                89.453(4)
_cell_angle_beta                 84.379(5)
_cell_angle_gamma                70.430(6)
_cell_volume                     7222(2)
_cell_formula_units_Z            2
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    9945
_cell_measurement_theta_min      2.19
_cell_measurement_theta_max      26.44

_exptl_crystal_description       plate
_exptl_crystal_colour            red
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    2.177
_exptl_crystal_F_000             4524
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.180
_exptl_crystal_size_mid          0.090
_exptl_crystal_size_min          0.050
_exptl_absorpt_coefficient_mu    7.059
_shelx_estimated_absorpt_T_min   0.363
_shelx_estimated_absorpt_T_max   0.719
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.4840
_exptl_absorpt_correction_T_max  0.7454
_exptl_absorpt_process_details   SADABS
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            68384
_diffrn_reflns_av_unetI/netI     0.0491
_diffrn_reflns_av_R_equivalents  0.0358
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_l_min       -34
_diffrn_reflns_limit_l_max       34
_diffrn_reflns_theta_min         0.745
_diffrn_reflns_theta_max         26.395
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measured_fraction_theta_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.994
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.994
_diffrn_reflns_point_group_measured_fraction_full 0.997
_reflns_number_total             29435
_reflns_number_gt                24153
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
; 
 Reflections were merged by SHELXL according to the crystal 
 class for the calculation of statistics and refinement. 
  
 _reflns_Friedel_fraction is defined as the number of unique 
 Friedel pairs measured divided by the number that would be 
 possible theoretically, ignoring centric projections and 
 systematic absences. 
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0261P)²+100.8518P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         29435
_refine_ls_number_parameters     1556
_refine_ls_number_restraints     696
_refine_ls_R_factor_all          0.0529
_refine_ls_R_factor_gt           0.0387
_refine_ls_wR_factor_ref         0.0929
_refine_ls_wR_factor_gt          0.0863
_refine_ls_goodness_of_fit_ref   1.024
_refine_ls_restrained_S_all      1.014
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.30004(2) 0.41036(2) 0.25003(2) 0.00927(6) Uani 1 1 d . . . . .
Au2 Au 0.46500(2) 0.28596(2) 0.27041(2) 0.00975(6) Uani 1 1 d . . . . .
Au3 Au 0.48595(2) 0.15061(2) 0.20525(2) 0.00983(6) Uani 1 1 d . . . . .
Au4 Au 0.34340(2) 0.09207(2) 0.22976(2) 0.00955(6) Uani 1 1 d . . . . .
Pt1 Pt 0.32399(2) 0.25060(2) 0.24272(2) 0.00734(6) Uani 1 1 d . . . . .
Ag1 Ag 0.41329(4) 0.31106(3) 0.16984(2) 0.00920(11) Uani 1 1 d . . . . .
Ag2 Ag 0.21912(4) 0.35463(3) 0.17605(2) 0.01023(11) Uani 1 1 d . . . . .
Ag3 Ag 0.33978(4) 0.19294(3) 0.14231(2) 0.01126(11) Uani 1 1 d . . . . .
Ag4 Ag 0.18342(3) 0.21585(3) 0.20971(2) 0.00974(10) Uani 0.85 1 d . . P A 1
Ag5 Ag 0.15224(3) 0.34750(3) 0.27675(2) 0.01008(10) Uani 0.9 1 d . . P A 1
Au4B Au 0.18342(3) 0.21585(3) 0.20971(2) 0.00974(10) Uani 0.15 1 d . . P A 2
Au5B Au 0.15224(3) 0.34750(3) 0.27675(2) 0.01008(10) Uani 0.1 1 d . . P A 2
Ag6 Ag 0.22844(4) 0.18389(3) 0.30946(2) 0.01035(11) Uani 1 1 d . . . . .
Ag7 Ag 0.29628(4) 0.31808(3) 0.33628(2) 0.01017(11) Uani 1 1 d . . . . .
Ag8 Ag 0.41698(4) 0.15320(3) 0.31319(2) 0.01129(11) Uani 1 1 d . . . . .
Ag9 Ag 0.28344(4) 0.20366(3) 0.41072(2) 0.01662(12) Uani 1 1 d . . . . .
Ag10 Ag 0.10381(4) 0.29949(3) 0.37620(2) 0.01575(12) Uani 1 1 d . . . . .
Ag11 Ag 0.02745(4) 0.34957(3) 0.19903(2) 0.01813(13) Uani 1 1 d . . . . .
S1 S 0.41859(14) 0.23767(11) 0.42819(7) 0.0170(4) Uani 1 1 d . . . . .
S2 S 0.52212(14) 0.05967(11) 0.36638(7) 0.0163(4) Uani 1 1 d . . . . .
S3 S 0.27873(15) 0.06571(12) 0.40068(9) 0.0244(5) Uani 1 1 d . . . . .
S4 S 0.08357(13) 0.16571(11) 0.35153(7) 0.0156(4) Uani 1 1 d . . . . .
S5 S 0.14793(14) 0.31005(11) 0.46028(7) 0.0159(4) Uani 1 1 d . . . . .
S6 S 0.25498(14) 0.43022(11) 0.39891(7) 0.0187(4) Uani 1 1 d . . . . .
S7 S 0.01987(14) 0.42974(11) 0.33455(8) 0.0194(4) Uani 1 1 d . . . . .
S8 S -0.06367(14) 0.30872(14) 0.27359(8) 0.0227(4) Uani 1 1 d . . . . .
S9 S -0.02687(15) 0.48863(12) 0.17505(8) 0.0220(4) Uani 1 1 d . . . . .
S10 S 0.17933(14) 0.44600(12) 0.10736(8) 0.0203(4) Uani 1 1 d . . . . .
S11 S 0.05414(13) 0.20230(11) 0.17060(7) 0.0176(4) Uani 1 1 d . . . . .
S12 S 0.25476(13) 0.10181(11) 0.10594(7) 0.0170(4) Uani 1 1 d . . . . .
S13 S 0.47163(15) 0.36494(11) 0.09772(7) 0.0181(4) Uani 1 1 d . . . . .
S14 S 0.41947(14) 0.20158(11) 0.05702(7) 0.0171(4) Uani 1 1 d . . . . .
P1 P 0.49729(14) 0.12249(11) 0.42936(7) 0.0159(4) Uani 1 1 d . . . . .
P2 P 0.14695(14) 0.08891(12) 0.40138(8) 0.0165(4) Uani 1 1 d . . . . .
P3 P 0.16809(13) 0.41700(11) 0.45246(7) 0.0137(4) Uani 1 1 d . . . . .
P4 P -0.08432(15) 0.39033(16) 0.32441(8) 0.0281(5) Uani 1 1 d . . . . .
P5 P 0.04662(14) 0.49638(12) 0.11279(8) 0.0160(4) Uani 1 1 d . . . . .
P6 P 0.12817(14) 0.17121(12) 0.10456(7) 0.0153(4) Uani 1 1 d . . . . .
P7 P 0.48059(14) 0.28218(11) 0.04591(7) 0.0132(4) Uani 1 1 d . . . . .
P8 P 0.27976(13) 0.54651(11) 0.25539(7) 0.0120(4) Uani 1 1 d . . . . .
P9 P 0.59278(13) 0.31003(11) 0.28914(7) 0.0113(4) Uani 1 1 d . . . . .
P10 P 0.62443(13) 0.06863(11) 0.17061(7) 0.0125(4) Uani 1 1 d . . . . .
P11 P 0.34481(13) -0.03892(11) 0.22004(7) 0.0118(4) Uani 1 1 d . . . . .
O1 O 0.5880(4) 0.1177(3) 0.4507(2) 0.0224(13) Uani 1 1 d . . . . .
O2 O 0.4579(4) 0.0747(3) 0.46921(19) 0.0203(13) Uani 1 1 d . . . . .
O3 O 0.1286(4) 0.0063(3) 0.3950(2) 0.0230(13) Uani 1 1 d . . . . .
O4 O 0.0929(5) 0.1209(4) 0.4527(2) 0.0289(14) Uani 1 1 d D . . . .
O5 O 0.1934(4) 0.4415(3) 0.5035(2) 0.0203(12) Uani 1 1 d . . . . .
O6 O 0.0701(4) 0.4794(3) 0.4516(2) 0.0178(12) Uani 1 1 d . . . . .
O7 O -0.1132(5) 0.3522(4) 0.3749(2) 0.0342(16) Uani 1 1 d . . . . .
O8 O -0.1715(4) 0.4647(4) 0.3210(3) 0.0379(16) Uani 1 1 d D . . . .
O9 O 0.0194(4) 0.5905(3) 0.1015(2) 0.0238(13) Uani 1 1 d . . . . .
O10 O 0.0152(4) 0.4651(3) 0.0662(2) 0.0207(12) Uani 1 1 d . . . . .
O11 O 0.1143(4) 0.2522(3) 0.0767(2) 0.0211(12) Uani 1 1 d . . . . .
O12 O 0.0769(4) 0.1279(3) 0.0737(2) 0.0238(13) Uani 1 1 d . . . . .
O13 O 0.4519(4) 0.3300(3) -0.00311(19) 0.0162(11) Uani 1 1 d . . . . .
O14 O 0.5833(4) 0.2338(3) 0.02867(19) 0.0155(11) Uani 1 1 d . . . . .
C1 C 0.6463(6) 0.1599(6) 0.4278(4) 0.031(2) Uani 1 1 d . . . . .
H1A H 0.609202 0.213432 0.417187 0.038 Uiso 1 1 calc R U . . .
H1B H 0.682417 0.128892 0.398646 0.038 Uiso 1 1 calc R U . . .
C2 C 0.7065(11) 0.1694(10) 0.4634(5) 0.072(4) Uani 1 1 d . . . . .
H2A H 0.743453 0.115091 0.472931 0.086 Uiso 1 1 calc R U . . .
H2B H 0.747848 0.194811 0.446629 0.086 Uiso 1 1 calc R U . . .
C3 C 0.6658(14) 0.2137(16) 0.5053(7) 0.151(11) Uani 1 1 d . . . . .
H3A H 0.607769 0.252688 0.498720 0.226 Uiso 1 1 calc R U . . .
H3B H 0.704281 0.242252 0.516038 0.226 Uiso 1 1 calc R U . . .
H3C H 0.656264 0.177680 0.530989 0.226 Uiso 1 1 calc R U . . .
C4 C 0.4296(7) 0.1071(5) 0.5198(3) 0.0271(19) Uani 1 1 d . . . . .
H4A H 0.431192 0.162546 0.521762 0.033 Uiso 1 1 calc R U . . .
H4B H 0.471301 0.073485 0.542209 0.033 Uiso 1 1 calc R U . . .
C5 C 0.3367(7) 0.1071(6) 0.5343(3) 0.037(2) Uani 1 1 d . . . . .
H5A H 0.334468 0.052415 0.528923 0.045 Uiso 1 1 calc R U . . .
H5B H 0.294817 0.144241 0.513360 0.045 Uiso 1 1 calc R U . . .
C6 C 0.3057(8) 0.1328(7) 0.5882(4) 0.051(3) Uani 1 1 d . . . . .
H6A H 0.343357 0.093208 0.609222 0.076 Uiso 1 1 calc R U . . .
H6B H 0.242903 0.136031 0.595549 0.076 Uiso 1 1 calc R U . . .
H6C H 0.311026 0.185574 0.594159 0.076 Uiso 1 1 calc R U . . .
C7 C 0.1781(7) -0.0475(5) 0.3544(3) 0.029(2) Uani 1 1 d . . . . .
H7A H 0.239844 -0.077381 0.362318 0.034 Uiso 1 1 calc R U . . .
H7B H 0.181991 -0.016222 0.324708 0.034 Uiso 1 1 calc R U . . .
C8 C 0.1291(7) -0.1058(6) 0.3456(5) 0.043(3) Uani 1 1 d . . . . .
H8A H 0.065763 -0.074849 0.340963 0.051 Uiso 1 1 calc R U . . .
H8B H 0.156846 -0.137271 0.315030 0.051 Uiso 1 1 calc R U . . .
C9 C 0.1311(9) -0.1618(7) 0.3862(6) 0.065(4) Uani 1 1 d . . . . .
H9A H 0.193594 -0.192196 0.391182 0.097 Uiso 1 1 calc R U . . .
H9B H 0.100380 -0.199123 0.378106 0.097 Uiso 1 1 calc R U . . .
H9C H 0.100630 -0.131159 0.416155 0.097 Uiso 1 1 calc R U . . .
C10 C 0.126(2) 0.0659(13) 0.4923(6) 0.037(4) Uani 0.5 1 d D . P B 1
H10A H 0.192553 0.041329 0.486583 0.044 Uiso 0.5 1 calc R U P B 1
H10B H 0.100259 0.022170 0.492808 0.044 Uiso 0.5 1 calc R U P B 1
C11 C 0.1009(15) 0.1114(12) 0.5404(6) 0.039(3) Uani 0.5 1 d D . P B 1
H11A H 0.036217 0.143921 0.542689 0.047 Uiso 0.5 1 calc R U P B 1
H11B H 0.135008 0.149076 0.541221 0.047 Uiso 0.5 1 calc R U P B 1
C12 C 0.1181(18) 0.0586(17) 0.5847(8) 0.059(5) Uani 0.5 1 d D . P B 1
H12A H 0.072976 0.031783 0.589393 0.089 Uiso 0.5 1 calc R U P B 1
H12B H 0.114213 0.091759 0.613740 0.089 Uiso 0.5 1 calc R U P B 1
H12C H 0.178131 0.018006 0.579515 0.089 Uiso 0.5 1 calc R U P B 1
C10B C 0.113(2) 0.0926(14) 0.5013(6) 0.037(4) Uani 0.5 1 d D . P B 2
H10C H 0.092766 0.138734 0.524825 0.044 Uiso 0.5 1 calc R U P B 2
H10D H 0.178492 0.066339 0.501659 0.044 Uiso 0.5 1 calc R U P B 2
C11B C 0.0659(15) 0.0338(13) 0.5161(7) 0.039(3) Uani 0.5 1 d D . P B 2
H11C H 0.087941 -0.013802 0.493614 0.047 Uiso 0.5 1 calc R U P B 2
H11D H 0.000358 0.059096 0.514568 0.047 Uiso 0.5 1 calc R U P B 2
C12B C 0.0853(17) 0.0087(18) 0.5679(7) 0.059(5) Uani 0.5 1 d D . P B 2
H12D H 0.150193 -0.017095 0.568885 0.089 Uiso 0.5 1 calc R U P B 2
H12E H 0.054521 -0.029194 0.578558 0.089 Uiso 0.5 1 calc R U P B 2
H12F H 0.063757 0.056323 0.589777 0.089 Uiso 0.5 1 calc R U P B 2
C13 C 0.2842(6) 0.4086(5) 0.5169(3) 0.027(2) Uani 1 1 d . . . . .
H13A H 0.308563 0.452662 0.521050 0.033 Uiso 1 1 calc R U . . .
H13B H 0.322659 0.371795 0.490390 0.033 Uiso 1 1 calc R U . . .
C14 C 0.2859(8) 0.3635(6) 0.5636(4) 0.047(3) Uani 1 1 d . . . . .
H14A H 0.262200 0.319021 0.559390 0.056 Uiso 1 1 calc R U . . .
H14B H 0.247074 0.400115 0.590086 0.056 Uiso 1 1 calc R U . . .
C15 C 0.3820(9) 0.3296(7) 0.5777(5) 0.060(4) Uani 1 1 d . . . . .
H15A H 0.421714 0.299144 0.549796 0.090 Uiso 1 1 calc R U . . .
H15B H 0.383958 0.294046 0.605440 0.090 Uiso 1 1 calc R U . . .
H15C H 0.401932 0.373954 0.586780 0.090 Uiso 1 1 calc R U . . .
C16 C 0.0556(6) 0.5658(5) 0.4487(3) 0.0240(19) Uani 1 1 d . . . . .
H16A H 0.112813 0.574254 0.437255 0.029 Uiso 1 1 calc R U . . .
H16B H 0.034529 0.591682 0.481517 0.029 Uiso 1 1 calc R U . . .
C17 C -0.0133(8) 0.6026(6) 0.4138(4) 0.041(3) Uani 1 1 d . . . . .
H17A H -0.069756 0.592513 0.424867 0.049 Uiso 1 1 calc R U . . .
H17B H 0.008632 0.577257 0.380910 0.049 Uiso 1 1 calc R U . . .
C18 C -0.0317(8) 0.6926(6) 0.4109(4) 0.043(3) Uani 1 1 d . . . . .
H18A H -0.054111 0.717701 0.443394 0.064 Uiso 1 1 calc R U . . .
H18B H -0.076781 0.715549 0.388074 0.064 Uiso 1 1 calc R U . . .
H18C H 0.024013 0.702481 0.399425 0.064 Uiso 1 1 calc R U . . .
C19 C -0.1263(7) 0.3946(6) 0.4212(3) 0.032(2) Uani 1 1 d . . . . .
H19A H -0.166539 0.450821 0.418593 0.038 Uiso 1 1 calc R U . . .
H19B H -0.068037 0.395504 0.430551 0.038 Uiso 1 1 calc R U . . .
C20 C -0.1674(7) 0.3520(6) 0.4589(4) 0.038(2) Uani 1 1 d . . . . .
H20A H -0.221657 0.345718 0.446965 0.045 Uiso 1 1 calc R U . . .
H20B H -0.186671 0.385547 0.489247 0.045 Uiso 1 1 calc R U . . .
C21 C -0.1044(6) 0.2703(6) 0.4706(4) 0.033(2) Uani 1 1 d . . . . .
H21A H -0.083176 0.237271 0.440459 0.049 Uiso 1 1 calc R U . . .
H21B H -0.136132 0.244067 0.493739 0.049 Uiso 1 1 calc R U . . .
H21C H -0.053004 0.276290 0.485086 0.049 Uiso 1 1 calc R U . . .
C22 C -0.176(4) 0.517(5) 0.281(3) 0.046(3) Uani 0.5 1 d D U P C 1
H22A H -0.157303 0.485388 0.249445 0.055 Uiso 0.5 1 calc R U P C 1
H22B H -0.137378 0.549708 0.283590 0.055 Uiso 0.5 1 calc R U P C 1
C23 C -0.2741(19) 0.5701(13) 0.2824(9) 0.053(4) Uani 0.5 1 d D U P C 1
H23A H -0.311427 0.535488 0.280043 0.063 Uiso 0.5 1 calc R U P C 1
H23B H -0.291918 0.598817 0.314483 0.063 Uiso 0.5 1 calc R U P C 1
C24 C -0.294(2) 0.6302(16) 0.2434(10) 0.067(5) Uani 0.5 1 d D U P C 1
H24A H -0.255702 0.663450 0.244338 0.100 Uiso 0.5 1 calc R U P C 1
H24B H -0.357333 0.664504 0.248576 0.100 Uiso 0.5 1 calc R U P C 1
H24C H -0.282632 0.602460 0.211464 0.100 Uiso 0.5 1 calc R U P C 1
C22B C -0.180(5) 0.518(4) 0.281(3) 0.046(3) Uani 0.5 1 d D . P C 2
H22C H -0.196413 0.491313 0.253673 0.055 Uiso 0.5 1 calc R U P C 2
H22D H -0.119183 0.519731 0.271113 0.055 Uiso 0.5 1 calc R U P C 2
C23B C -0.2430(15) 0.6039(15) 0.2839(10) 0.053(4) Uani 0.5 1 d D . P C 2
H23C H -0.229962 0.633009 0.311245 0.063 Uiso 0.5 1 calc R U P C 2
H23D H -0.233793 0.631176 0.253204 0.063 Uiso 0.5 1 calc R U P C 2
C24B C -0.3363(18) 0.6058(17) 0.2915(11) 0.067(5) Uani 0.5 1 d D . P C 2
H24D H -0.368953 0.633422 0.264414 0.100 Uiso 0.5 1 calc R U P C 2
H24E H -0.364928 0.634679 0.322332 0.100 Uiso 0.5 1 calc R U P C 2
H24F H -0.337541 0.550718 0.292927 0.100 Uiso 0.5 1 calc R U P C 2
C25 C 0.0221(8) 0.6455(6) 0.1404(4) 0.039(3) Uani 1 1 d . . . . .
H25A H 0.073965 0.619729 0.159190 0.047 Uiso 1 1 calc R U . . .
H25B H -0.033506 0.658898 0.163133 0.047 Uiso 1 1 calc R U . . .
C26 C 0.0304(7) 0.7206(5) 0.1178(4) 0.031(2) Uani 1 1 d . . . . .
H26A H -0.017271 0.741825 0.095598 0.037 Uiso 1 1 calc R U . . .
H26B H 0.021002 0.761744 0.143838 0.037 Uiso 1 1 calc R U . . .
C27 C 0.1200(9) 0.7064(8) 0.0896(6) 0.075(5) Uani 1 1 d . . . . .
H27A H 0.167506 0.684778 0.111299 0.112 Uiso 1 1 calc R U . . .
H27B H 0.123064 0.757283 0.076386 0.112 Uiso 1 1 calc R U . . .
H27C H 0.128310 0.667803 0.062651 0.112 Uiso 1 1 calc R U . . .
C28 C -0.0776(6) 0.4960(5) 0.0540(3) 0.0239(18) Uani 1 1 d . . . . .
H28A H -0.085982 0.543324 0.032953 0.029 Uiso 1 1 calc R U . . .
H28B H -0.119059 0.513108 0.084223 0.029 Uiso 1 1 calc R U . . .
C29 C -0.0982(6) 0.4312(5) 0.0276(3) 0.0237(18) Uani 1 1 d . . . . .
H29A H -0.048877 0.406692 0.001581 0.028 Uiso 1 1 calc R U . . .
H29B H -0.154020 0.455658 0.011701 0.028 Uiso 1 1 calc R U . . .
C30 C -0.1095(7) 0.3653(6) 0.0612(4) 0.034(2) Uani 1 1 d . . . . .
H30A H -0.055604 0.342575 0.078351 0.051 Uiso 1 1 calc R U . . .
H30B H -0.118387 0.322849 0.041781 0.051 Uiso 1 1 calc R U . . .
H30C H -0.161871 0.388165 0.085185 0.051 Uiso 1 1 calc R U . . .
C31 C 0.1717(6) 0.2594(5) 0.0324(3) 0.0254(18) Uani 1 1 d . . . . .
H31A H 0.234218 0.223750 0.035000 0.031 Uiso 1 1 calc R U . . .
H31B H 0.171713 0.315397 0.030223 0.031 Uiso 1 1 calc R U . . .
C32 C 0.1393(6) 0.2370(6) -0.0133(3) 0.030(2) Uani 1 1 d . . . . .
H32A H 0.076678 0.272344 -0.015986 0.036 Uiso 1 1 calc R U . . .
H32B H 0.140045 0.180746 -0.011516 0.036 Uiso 1 1 calc R U . . .
C33 C 0.1995(7) 0.2460(6) -0.0579(4) 0.037(2) Uani 1 1 d . . . . .
H33A H 0.197012 0.302173 -0.060075 0.056 Uiso 1 1 calc R U . . .
H33B H 0.178817 0.230348 -0.087401 0.056 Uiso 1 1 calc R U . . .
H33C H 0.261449 0.211377 -0.054906 0.056 Uiso 1 1 calc R U . . .
C34 C 0.0643(6) 0.0533(5) 0.0909(3) 0.028(2) Uani 1 1 d . . . . .
H34A H 0.045617 0.057927 0.126477 0.033 Uiso 1 1 calc R U . . .
H34B H 0.121304 0.007768 0.084784 0.033 Uiso 1 1 calc R U . . .
C35 C -0.0071(8) 0.0390(7) 0.0637(4) 0.043(3) Uani 1 1 d . . . . .
H35A H -0.063469 0.085355 0.069673 0.051 Uiso 1 1 calc R U . . .
H35B H 0.012030 0.035066 0.028207 0.051 Uiso 1 1 calc R U . . .
C36 C -0.0247(7) -0.0367(6) 0.0794(4) 0.041(3) Uani 1 1 d . . . . .
H36A H 0.030978 -0.082702 0.073752 0.061 Uiso 1 1 calc R U . . .
H36B H -0.070292 -0.044644 0.060322 0.061 Uiso 1 1 calc R U . . .
H36C H -0.046385 -0.032036 0.114210 0.061 Uiso 1 1 calc R U . . .
C37 C 0.3581(5) 0.3754(5) -0.0058(3) 0.0195(17) Uani 1 1 d . . . . .
H37A H 0.331906 0.405921 0.025281 0.023 Uiso 1 1 calc R U . . .
H37B H 0.324469 0.338662 -0.011413 0.023 Uiso 1 1 calc R U . . .
C38 C 0.3519(6) 0.4329(5) -0.0479(3) 0.0223(17) Uani 1 1 d . . . . .
H38A H 0.288355 0.456482 -0.054595 0.027 Uiso 1 1 calc R U . . .
H38B H 0.386380 0.402208 -0.077526 0.027 Uiso 1 1 calc R U . . .
C39 C 0.3876(7) 0.5005(5) -0.0377(4) 0.032(2) Uani 1 1 d . . . . .
H39A H 0.348155 0.536087 -0.011543 0.048 Uiso 1 1 calc R U . . .
H39B H 0.389164 0.531357 -0.067427 0.048 Uiso 1 1 calc R U . . .
H39C H 0.448367 0.477749 -0.027639 0.048 Uiso 1 1 calc R U . . .
C40 C 0.6477(6) 0.2758(5) 0.0168(3) 0.0212(17) Uani 1 1 d . . . . .
H40A H 0.646814 0.311435 0.044555 0.025 Uiso 1 1 calc R U . . .
H40B H 0.631418 0.309334 -0.012199 0.025 Uiso 1 1 calc R U . . .
C41 C 0.7401(6) 0.2143(6) 0.0063(3) 0.029(2) Uani 1 1 d . . . . .
H41A H 0.754349 0.179461 0.034927 0.035 Uiso 1 1 calc R U . . .
H41B H 0.784807 0.242209 0.001404 0.035 Uiso 1 1 calc R U . . .
C42 C 0.7476(7) 0.1617(6) -0.0391(4) 0.034(2) Uani 1 1 d . . . . .
H42A H 0.711089 0.127017 -0.032341 0.051 Uiso 1 1 calc R U . . .
H42B H 0.810500 0.128374 -0.047431 0.051 Uiso 1 1 calc R U . . .
H42C H 0.725992 0.196196 -0.066584 0.051 Uiso 1 1 calc R U . . .
C43 C 0.3351(5) 0.5845(4) 0.2043(3) 0.0142(15) Uani 1 1 d . . . . .
C44 C 0.3352(5) 0.5533(5) 0.1573(3) 0.0165(15) Uani 1 1 d . . . . .
H44 H 0.310110 0.512032 0.153624 0.020 Uiso 1 1 calc R U . . .
C45 C 0.3721(6) 0.5826(5) 0.1161(3) 0.0237(18) Uani 1 1 d . . . . .
H45 H 0.372309 0.561034 0.084516 0.028 Uiso 1 1 calc R U . . .
C46 C 0.4086(5) 0.6437(5) 0.1213(3) 0.0190(16) Uani 1 1 d . . . . .
H46 H 0.432532 0.664397 0.093229 0.023 Uiso 1 1 calc R U . . .
C47 C 0.4099(6) 0.6742(4) 0.1676(3) 0.0195(16) Uani 1 1 d . . . . .
H47 H 0.435881 0.714819 0.171317 0.023 Uiso 1 1 calc R U . . .
C48 C 0.3729(5) 0.6448(4) 0.2087(3) 0.0161(15) Uani 1 1 d . . . . .
H48 H 0.373395 0.666269 0.240165 0.019 Uiso 1 1 calc R U . . .
C49 C 0.1628(5) 0.6144(4) 0.2587(3) 0.0151(15) Uani 1 1 d . . . . .
C50 C 0.0941(6) 0.5832(5) 0.2687(3) 0.0214(17) Uani 1 1 d . . . . .
H50 H 0.107147 0.526763 0.270628 0.026 Uiso 1 1 calc R U . . .
C51 C 0.0056(6) 0.6352(5) 0.2759(4) 0.028(2) Uani 1 1 d . . . . .
H51 H -0.041547 0.613802 0.283329 0.034 Uiso 1 1 calc R U . . .
C52 C -0.0148(6) 0.7176(5) 0.2723(3) 0.0249(18) Uani 1 1 d . . . . .
H52 H -0.075472 0.752486 0.276933 0.030 Uiso 1 1 calc R U . . .
C53 C 0.0545(6) 0.7489(5) 0.2620(4) 0.030(2) Uani 1 1 d . . . . .
H53 H 0.041264 0.805300 0.259574 0.036 Uiso 1 1 calc R U . . .
C54 C 0.1426(6) 0.6976(5) 0.2551(4) 0.030(2) Uani 1 1 d . . . . .
H54 H 0.189711 0.719140 0.247967 0.036 Uiso 1 1 calc R U . . .
C55 C 0.3185(6) 0.5765(4) 0.3103(3) 0.0171(15) Uani 1 1 d . . . . .
C56 C 0.2585(6) 0.6129(5) 0.3507(3) 0.0216(17) Uani 1 1 d . . . . .
H56 H 0.195726 0.625428 0.349515 0.026 Uiso 1 1 calc R U . . .
C57 C 0.2918(7) 0.6309(5) 0.3936(3) 0.0304(19) Uani 1 1 d . . . . .
H57 H 0.251175 0.655766 0.421104 0.037 Uiso 1 1 calc R U . . .
C58 C 0.3814(7) 0.6129(5) 0.3954(3) 0.0304(19) Uani 1 1 d . . . . .
H58 H 0.403058 0.625487 0.424184 0.036 Uiso 1 1 calc R U . . .
C59 C 0.4416(7) 0.5766(5) 0.3558(3) 0.029(2) Uani 1 1 d . . . . .
H59 H 0.504120 0.564469 0.357628 0.035 Uiso 1 1 calc R U . . .
C60 C 0.4113(6) 0.5574(4) 0.3131(3) 0.0218(17) Uani 1 1 d . . . . .
H60 H 0.452957 0.531675 0.286113 0.026 Uiso 1 1 calc R U . . .
C61 C 0.5815(5) 0.3714(4) 0.3440(3) 0.0149(15) Uani 1 1 d . . . . .
C62 C 0.5146(6) 0.3745(5) 0.3810(3) 0.0178(16) Uani 1 1 d . . . . .
H62 H 0.471379 0.349908 0.375545 0.021 Uiso 1 1 calc R U . . .
C63 C 0.5088(6) 0.4125(5) 0.4258(3) 0.0210(17) Uani 1 1 d . . . . .
H63 H 0.461909 0.414335 0.450498 0.025 Uiso 1 1 calc R U . . .
C64 C 0.5721(6) 0.4476(5) 0.4338(3) 0.0201(16) Uani 1 1 d . . . . .
H64 H 0.570567 0.471555 0.464867 0.024 Uiso 1 1 calc R U . . .
C65 C 0.6380(5) 0.4480(5) 0.3969(3) 0.0213(17) Uani 1 1 d . . . . .
H65 H 0.679669 0.474354 0.402218 0.026 Uiso 1 1 calc R U . . .
C66 C 0.6432(6) 0.4100(5) 0.3521(3) 0.0200(16) Uani 1 1 d . . . . .
H66 H 0.688603 0.410108 0.326908 0.024 Uiso 1 1 calc R U . . .
C67 C 0.6303(5) 0.3655(4) 0.2405(3) 0.0107(14) Uani 1 1 d . . . . .
C68 C 0.7216(5) 0.3609(5) 0.2293(3) 0.0174(16) Uani 1 1 d . . . . .
H68 H 0.767340 0.325450 0.246580 0.021 Uiso 1 1 calc R U . . .
C69 C 0.7430(6) 0.4081(5) 0.1933(3) 0.0184(16) Uani 1 1 d . . . . .
H69 H 0.804112 0.403646 0.185396 0.022 Uiso 1 1 calc R U . . .
C70 C 0.6782(6) 0.4615(5) 0.1684(3) 0.0214(17) Uani 1 1 d . . . . .
H70 H 0.694226 0.494898 0.144487 0.026 Uiso 1 1 calc R U . . .
C71 C 0.5880(6) 0.4664(5) 0.1786(3) 0.0200(16) Uani 1 1 d . . . . .
H71 H 0.542222 0.502279 0.161520 0.024 Uiso 1 1 calc R U . . .
C72 C 0.5680(5) 0.4176(4) 0.2139(3) 0.0119(14) Uani 1 1 d . . . . .
H72 H 0.507202 0.420248 0.220268 0.014 Uiso 1 1 calc R U . . .
C73 C 0.6880(5) 0.2202(4) 0.3001(3) 0.0143(15) Uani 1 1 d . . . . .
C74 C 0.7671(5) 0.2229(5) 0.3183(3) 0.0220(17) Uani 1 1 d . . . . .
H74 H 0.772315 0.273585 0.325392 0.026 Uiso 1 1 calc R U . . .
C75 C 0.8367(6) 0.1538(5) 0.3259(3) 0.0235(18) Uani 1 1 d . . . . .
H75 H 0.890632 0.156996 0.336457 0.028 Uiso 1 1 calc R U . . .
C76 C 0.8277(6) 0.0790(5) 0.3182(3) 0.0223(17) Uani 1 1 d . . . . .
H76 H 0.875477 0.031228 0.323713 0.027 Uiso 1 1 calc R U . . .
C77 C 0.7479(5) 0.0742(5) 0.3021(3) 0.0203(17) Uani 1 1 d . . . . .
H77 H 0.740386 0.023539 0.297973 0.024 Uiso 1 1 calc R U . . .
C78 C 0.6805(5) 0.1452(5) 0.2924(3) 0.0183(16) Uani 1 1 d . . . . .
H78 H 0.627803 0.142254 0.280086 0.022 Uiso 1 1 calc R U . . .
C79 C 0.7071(5) 0.1201(4) 0.1655(3) 0.0137(15) Uani 1 1 d . . . . .
C80 C 0.6810(5) 0.1948(5) 0.1439(3) 0.0188(16) Uani 1 1 d . . . . .
H80 H 0.622291 0.216970 0.133872 0.023 Uiso 1 1 calc R U . . .
C81 C 0.7408(6) 0.2371(5) 0.1369(3) 0.0207(17) Uani 1 1 d . . . . .
H81 H 0.723522 0.287212 0.121068 0.025 Uiso 1 1 calc R U . . .
C82 C 0.8250(6) 0.2066(5) 0.1529(3) 0.0248(18) Uani 1 1 d . . . . .
H82 H 0.865296 0.236123 0.148592 0.030 Uiso 1 1 calc R U . . .
C83 C 0.8504(5) 0.1335(5) 0.1751(3) 0.0240(18) Uani 1 1 d . . . . .
H83 H 0.908350 0.112942 0.186375 0.029 Uiso 1 1 calc R U . . .
C84 C 0.7924(5) 0.0891(5) 0.1814(3) 0.0183(16) Uani 1 1 d . . . . .
H84 H 0.810875 0.038170 0.196322 0.022 Uiso 1 1 calc R U . . .
C85 C 0.6714(5) -0.0239(4) 0.2029(3) 0.0148(15) Uani 1 1 d . . . . .
C86 C 0.6275(5) -0.0340(5) 0.2484(3) 0.0164(15) Uani 1 1 d . . . . .
H86 H 0.575384 0.007645 0.262022 0.020 Uiso 1 1 calc R U . . .
C87 C 0.6607(6) -0.1050(5) 0.2731(3) 0.0222(17) Uani 1 1 d . . . . .
H87 H 0.631776 -0.111260 0.304056 0.027 Uiso 1 1 calc R U . . .
C88 C 0.7352(6) -0.1667(5) 0.2534(4) 0.0275(19) Uani 1 1 d . . . . .
H88 H 0.757025 -0.215012 0.270833 0.033 Uiso 1 1 calc R U . . .
C89 C 0.7780(6) -0.1585(5) 0.2087(4) 0.032(2) Uani 1 1 d . . . . .
H89 H 0.829302 -0.201130 0.195153 0.038 Uiso 1 1 calc R U . . .
C90 C 0.7459(6) -0.0876(5) 0.1834(3) 0.027(2) Uani 1 1 d . . . . .
H90 H 0.775076 -0.082489 0.152270 0.032 Uiso 1 1 calc R U . . .
C91 C 0.6285(5) 0.0313(4) 0.1084(3) 0.0147(15) Uani 1 1 d . . . . .
C92 C 0.7021(6) 0.0225(5) 0.0743(3) 0.0233(18) Uani 1 1 d . . . . .
H92 H 0.749980 0.039260 0.082507 0.028 Uiso 1 1 calc R U . . .
C93 C 0.7056(6) -0.0111(5) 0.0281(3) 0.0233(18) Uani 1 1 d . . . . .
H93 H 0.755527 -0.016454 0.004689 0.028 Uiso 1 1 calc R U . . .
C94 C 0.6363(6) -0.0367(5) 0.0163(3) 0.0241(17) Uani 1 1 d . . . . .
H94 H 0.639705 -0.061472 -0.014664 0.029 Uiso 1 1 calc R U . . .
C95 C 0.5621(6) -0.0259(4) 0.0499(3) 0.0213(17) Uani 1 1 d . . . . .
H95 H 0.513528 -0.041287 0.041243 0.026 Uiso 1 1 calc R U . . .
C96 C 0.5578(6) 0.0072(5) 0.0964(3) 0.0193(16) Uani 1 1 d . . . . .
H96 H 0.507373 0.013354 0.119521 0.023 Uiso 1 1 calc R U . . .
C97 C 0.3755(5) -0.0996(4) 0.2741(3) 0.0158(15) Uani 1 1 d . . . . .
C98 C 0.4152(6) -0.0734(5) 0.3102(3) 0.0174(16) Uani 1 1 d . . . . .
H98 H 0.424474 -0.023056 0.307302 0.021 Uiso 1 1 calc R U . . .
C99 C 0.4418(6) -0.1205(5) 0.3508(3) 0.0218(17) Uani 1 1 d . . . . .
H99 H 0.470234 -0.102914 0.375022 0.026 Uiso 1 1 calc R U . . .
C100 C 0.4263(6) -0.1931(5) 0.3554(3) 0.0240(18) Uani 1 1 d . . . . .
H100 H 0.444074 -0.225184 0.382965 0.029 Uiso 1 1 calc R U . . .
C101 C 0.3848(6) -0.2194(5) 0.3197(3) 0.0237(18) Uani 1 1 d . . . . .
H101 H 0.373176 -0.268621 0.323389 0.028 Uiso 1 1 calc R U . . .
C102 C 0.3606(6) -0.1738(4) 0.2790(3) 0.0209(17) Uani 1 1 d . . . . .
H102 H 0.333992 -0.192513 0.254347 0.025 Uiso 1 1 calc R U . . .
C103 C 0.2339(5) -0.0452(4) 0.2117(3) 0.0145(15) Uani 1 1 d . . . . .
C104 C 0.1591(5) 0.0153(4) 0.2330(3) 0.0179(16) Uani 1 1 d . . . . .
H104 H 0.166732 0.060377 0.248121 0.022 Uiso 1 1 calc R U . . .
C105 C 0.0737(6) 0.0116(5) 0.2327(3) 0.0233(18) Uani 1 1 d . . . . .
H105 H 0.023818 0.052973 0.248608 0.028 Uiso 1 1 calc R U . . .
C106 C 0.0603(6) -0.0524(5) 0.2093(3) 0.0249(18) Uani 1 1 d . . . . .
H106 H 0.001562 -0.054735 0.208555 0.030 Uiso 1 1 calc R U . . .
C107 C 0.1351(6) -0.1131(5) 0.1869(3) 0.0229(17) Uani 1 1 d . . . . .
H107 H 0.127032 -0.156920 0.170463 0.027 Uiso 1 1 calc R U . . .
C108 C 0.2223(6) -0.1101(5) 0.1884(3) 0.0176(16) Uani 1 1 d . . . . .
H108 H 0.272833 -0.152049 0.173522 0.021 Uiso 1 1 calc R U . . .
C109 C 0.4227(5) -0.1038(4) 0.1715(3) 0.0155(15) Uani 1 1 d . . . . .
C110 C 0.4000(6) -0.1071(5) 0.1241(3) 0.0175(16) Uani 1 1 d . . . . .
H110 H 0.342587 -0.074314 0.115862 0.021 Uiso 1 1 calc R U . . .
C111 C 0.4606(6) -0.1580(5) 0.0888(3) 0.0220(17) Uani 1 1 d . . . . .
H111 H 0.443404 -0.161872 0.057031 0.026 Uiso 1 1 calc R U . . .
C112 C 0.5461(6) -0.2031(5) 0.0998(3) 0.0251(18) Uani 1 1 d . . . . .
H112 H 0.587930 -0.236813 0.075294 0.030 Uiso 1 1 calc R U . . .
C113 C 0.5703(6) -0.1991(5) 0.1462(3) 0.0236(17) Uani 1 1 d . . . . .
H113 H 0.628982 -0.230170 0.153566 0.028 Uiso 1 1 calc R U . . .
C114 C 0.5096(5) -0.1498(4) 0.1824(3) 0.0162(15) Uani 1 1 d . . . . .
H114 H 0.526868 -0.147250 0.214350 0.019 Uiso 1 1 calc R U . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 P8 2.3194(19) . ?
Au1 Pt1 2.7229(6) . ?
Au1 Ag2 2.8551(7) . ?
Au1 Ag7 2.8708(7) . ?
Au1 Ag1 2.8896(7) . ?
Au1 Au2 2.8995(5) . ?
Au1 Au5B 2.9443(7) . ?
Au1 Ag5 2.9443(7) . ?
Au2 P9 2.313(2) . ?
Au2 Pt1 2.6946(5) . ?
Au2 Ag8 2.9023(7) . ?
Au2 Au3 2.9083(5) . ?
Au2 Ag1 2.9480(8) . ?
Au2 Ag7 2.9712(7) . ?
Au3 P10 2.3066(19) . ?
Au3 Pt1 2.6953(5) . ?
Au3 Au4 2.8106(5) . ?
Au3 Ag1 2.8771(7) . ?
Au3 Ag3 2.9221(7) . ?
Au3 Ag8 3.0558(8) . ?
Au4 P11 2.3225(19) . ?
Au4 Pt1 2.7333(6) . ?
Au4 Ag6 2.8392(7) . ?
Au4 Ag4 2.8395(6) . ?
Au4 Au4B 2.8395(6) . ?
Au4 Ag3 2.9713(7) . ?
Au4 Ag8 3.0340(7) . ?
Pt1 Au4B 2.7396(7) . ?
Pt1 Ag4 2.7396(7) . ?
Pt1 Ag1 2.7530(7) . ?
Pt1 Au5B 2.7646(7) . ?
Pt1 Ag5 2.7646(7) . ?
Pt1 Ag6 2.7685(7) . ?
Pt1 Ag8 2.7722(7) . ?
Pt1 Ag7 2.7771(7) . ?
Ag1 S13 2.427(2) . ?
Ag1 Ag3 2.8488(8) . ?
Ag1 Ag2 2.9046(9) . ?
Ag2 S10 2.461(2) . ?
Ag2 Au4B 2.8218(8) . ?
Ag2 Ag4 2.8218(8) . ?
Ag2 Au5B 2.8835(8) . ?
Ag2 Ag5 2.8835(8) . ?
Ag2 Ag3 2.9521(8) . ?
Ag2 Ag11 3.0779(10) . ?
Ag3 S14 2.581(2) . ?
Ag3 S12 2.676(2) . ?
Ag3 Au4B 2.8637(8) . ?
Ag3 Ag4 2.8637(8) . ?
Ag4 S11 2.489(2) . ?
Ag4 Ag11 2.8291(8) . ?
Ag4 Ag5 2.8590(7) . ?
Ag4 Ag6 2.9038(8) . ?
Ag5 S7 2.529(2) . ?
Ag5 Ag7 2.8460(8) . ?
Ag5 Ag6 2.9043(8) . ?
Ag5 Ag10 2.9602(9) . ?
Ag5 Ag11 3.0449(9) . ?
Au4B S11 2.489(2) . ?
Au4B Ag11 2.8291(8) . ?
Au4B Au5B 2.8590(7) . ?
Au4B Ag6 2.9038(8) . ?
Au5B S7 2.529(2) . ?
Au5B Ag7 2.8460(8) . ?
Au5B Ag6 2.9043(8) . ?
Au5B Ag10 2.9602(9) . ?
Au5B Ag11 3.0449(9) . ?
Ag6 S4 2.588(2) . ?
Ag6 Ag10 2.8461(8) . ?
Ag6 Ag8 2.8704(9) . ?
Ag6 Ag7 3.0353(8) . ?
Ag6 Ag9 3.0547(9) . ?
Ag7 S6 2.5072(19) . ?
Ag7 Ag9 2.9022(9) . ?
Ag7 Ag8 2.9335(8) . ?
Ag7 Ag10 3.2649(10) . ?
Ag8 S2 2.4972(19) . ?
Ag8 Ag9 3.1849(9) . ?
Ag9 S3 2.480(2) . ?
Ag9 S1 2.503(2) . ?
Ag9 S5 2.604(2) . ?
Ag9 Ag10 3.0271(9) . ?
Ag10 S5 2.506(2) . ?
Ag10 S7 2.563(2) . ?
Ag10 S4 2.592(2) . ?
Ag11 S9 2.422(2) . ?
Ag11 S11 2.604(2) . ?
Ag11 S8 2.628(2) . ?
S1 P1 2.000(3) . ?
S2 P1 1.998(3) . ?
S3 P2 1.991(3) . ?
S4 P2 2.012(3) . ?
S5 P3 2.024(3) . ?
S6 P3 1.984(3) . ?
S7 P4 2.040(3) . ?
S8 P4 1.941(3) . ?
S9 P5 2.005(3) . ?
S10 P5 1.985(3) . ?
S11 P6 2.036(3) . ?
S12 P6 1.977(3) . ?
S13 P7 2.011(3) . ?
S14 P7 1.979(3) . ?
P1 O2 1.582(6) . ?
P1 O1 1.585(6) . ?
P2 O4 1.580(6) . ?
P2 O3 1.594(6) . ?
P3 O6 1.579(6) . ?
P3 O5 1.600(6) . ?
P4 O8 1.566(7) . ?
P4 O7 1.629(7) . ?
P5 O10 1.586(6) . ?
P5 O9 1.605(6) . ?
P6 O11 1.575(6) . ?
P6 O12 1.592(6) . ?
P7 O14 1.593(6) . ?
P7 O13 1.606(6) . ?
P8 C43 1.825(8) . ?
P8 C55 1.832(8) . ?
P8 C49 1.836(8) . ?
P9 C67 1.819(8) . ?
P9 C61 1.824(8) . ?
P9 C73 1.835(8) . ?
P10 C85 1.817(8) . ?
P10 C79 1.824(8) . ?
P10 C91 1.827(8) . ?
P11 C97 1.832(8) . ?
P11 C109 1.837(8) . ?
P11 C103 1.838(8) . ?
O1 C1 1.465(11) . ?
O2 C4 1.476(9) . ?
O3 C7 1.452(10) . ?
O4 C10B 1.449(16) . ?
O4 C10 1.469(16) . ?
O5 C13 1.445(10) . ?
O6 C16 1.466(9) . ?
O7 C19 1.444(11) . ?
O8 C22B 1.424(16) . ?
O8 C22 1.428(16) . ?
O9 C25 1.466(11) . ?
O10 C28 1.462(10) . ?
O11 C31 1.478(10) . ?
O12 C34 1.464(10) . ?
O13 C37 1.445(9) . ?
O14 C40 1.463(10) . ?
C1 C2 1.480(15) . ?
C2 C3 1.37(2) . ?
C4 C5 1.491(14) . ?
C5 C6 1.536(13) . ?
C7 C8 1.517(13) . ?
C8 C9 1.480(17) . ?
C10 C11 1.50(2) . ?
C11 C12 1.52(2) . ?
C10B C11B 1.50(3) . ?
C11B C12B 1.52(2) . ?
C13 C14 1.503(14) . ?
C14 C15 1.528(15) . ?
C16 C17 1.504(13) . ?
C17 C18 1.518(13) . ?
C19 C20 1.500(14) . ?
C20 C21 1.507(13) . ?
C22 C23 1.52(4) . ?
C23 C24 1.48(3) . ?
C22B C23B 1.51(4) . ?
C23B C24B 1.46(3) . ?
C25 C26 1.498(13) . ?
C26 C27 1.496(15) . ?
C28 C29 1.502(12) . ?
C29 C30 1.525(13) . ?
C31 C32 1.507(13) . ?
C32 C33 1.521(13) . ?
C34 C35 1.506(14) . ?
C35 C36 1.504(14) . ?
C37 C38 1.520(11) . ?
C38 C39 1.521(12) . ?
C40 C41 1.506(12) . ?
C41 C42 1.534(12) . ?
C43 C48 1.397(11) . ?
C43 C44 1.409(11) . ?
C44 C45 1.399(12) . ?
C45 C46 1.400(12) . ?
C46 C47 1.392(12) . ?
C47 C48 1.397(11) . ?
C49 C50 1.381(11) . ?
C49 C54 1.400(11) . ?
C50 C51 1.394(12) . ?
C51 C52 1.385(12) . ?
C52 C53 1.392(13) . ?
C53 C54 1.384(12) . ?
C55 C56 1.395(11) . ?
C55 C60 1.407(12) . ?
C56 C57 1.418(12) . ?
C57 C58 1.356(14) . ?
C58 C59 1.381(14) . ?
C59 C60 1.397(12) . ?
C61 C62 1.384(11) . ?
C61 C66 1.401(11) . ?
C62 C63 1.388(11) . ?
C63 C64 1.382(12) . ?
C64 C65 1.386(12) . ?
C65 C66 1.391(11) . ?
C67 C72 1.370(10) . ?
C67 C68 1.427(11) . ?
C68 C69 1.379(11) . ?
C69 C70 1.375(12) . ?
C70 C71 1.405(12) . ?
C71 C72 1.376(11) . ?
C73 C78 1.388(11) . ?
C73 C74 1.411(11) . ?
C74 C75 1.375(11) . ?
C75 C76 1.394(12) . ?
C76 C77 1.411(12) . ?
C77 C78 1.393(11) . ?
C79 C80 1.390(11) . ?
C79 C84 1.393(11) . ?
C80 C81 1.389(12) . ?
C81 C82 1.378(12) . ?
C82 C83 1.373(12) . ?
C83 C84 1.395(12) . ?
C85 C90 1.396(11) . ?
C85 C86 1.410(11) . ?
C86 C87 1.387(11) . ?
C87 C88 1.378(12) . ?
C88 C89 1.377(14) . ?
C89 C90 1.392(12) . ?
C91 C92 1.389(11) . ?
C91 C96 1.394(11) . ?
C92 C93 1.395(11) . ?
C93 C94 1.388(13) . ?
C94 C95 1.384(12) . ?
C95 C96 1.396(11) . ?
C97 C98 1.386(11) . ?
C97 C102 1.410(11) . ?
C98 C99 1.398(11) . ?
C99 C100 1.384(12) . ?
C100 C101 1.398(12) . ?
C101 C102 1.378(12) . ?
C103 C104 1.385(11) . ?
C103 C108 1.392(10) . ?
C104 C105 1.379(12) . ?
C105 C106 1.392(12) . ?
C106 C107 1.399(13) . ?
C107 C108 1.407(12) . ?
C109 C110 1.392(11) . ?
C109 C114 1.407(11) . ?
C110 C111 1.390(11) . ?
C111 C112 1.385(13) . ?
C112 C113 1.378(13) . ?
C113 C114 1.395(11) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P8 Au1 Pt1 179.41(5) . . ?
P8 Au1 Ag2 118.70(5) . . ?
Pt1 Au1 Ag2 60.835(14) . . ?
P8 Au1 Ag7 121.13(5) . . ?
Pt1 Au1 Ag7 59.464(15) . . ?
Ag2 Au1 Ag7 109.23(2) . . ?
P8 Au1 Ag1 120.85(5) . . ?
Pt1 Au1 Ag1 58.659(14) . . ?
Ag2 Au1 Ag1 60.74(2) . . ?
Ag7 Au1 Ag1 111.20(2) . . ?
P8 Au1 Au2 123.00(5) . . ?
Pt1 Au1 Au2 57.172(13) . . ?
Ag2 Au1 Au2 109.899(17) . . ?
Ag7 Au1 Au2 61.982(15) . . ?
Ag1 Au1 Au2 61.225(16) . . ?
P8 Au1 Au5B 121.95(5) . . ?
Pt1 Au1 Au5B 58.238(14) . . ?
Ag2 Au1 Au5B 59.606(18) . . ?
Ag7 Au1 Au5B 58.587(17) . . ?
Ag1 Au1 Au5B 107.354(19) . . ?
Au2 Au1 Au5B 107.083(18) . . ?
P8 Au1 Ag5 121.95(5) . . ?
Pt1 Au1 Ag5 58.238(14) . . ?
Ag2 Au1 Ag5 59.606(18) . . ?
Ag7 Au1 Ag5 58.587(17) . . ?
Ag1 Au1 Ag5 107.354(19) . . ?
Au2 Au1 Ag5 107.083(18) . . ?
P9 Au2 Pt1 175.54(5) . . ?
P9 Au2 Au1 124.36(5) . . ?
Pt1 Au2 Au1 58.115(15) . . ?
P9 Au2 Ag8 120.93(5) . . ?
Pt1 Au2 Ag8 59.241(15) . . ?
Au1 Au2 Ag8 107.532(19) . . ?
P9 Au2 Au3 118.38(5) . . ?
Pt1 Au2 Au3 57.355(12) . . ?
Au1 Au2 Au3 106.227(15) . . ?
Ag8 Au2 Au3 63.457(17) . . ?
P9 Au2 Ag1 119.10(5) . . ?
Pt1 Au2 Ag1 58.198(14) . . ?
Au1 Au2 Ag1 59.223(14) . . ?
Ag8 Au2 Ag1 110.194(18) . . ?
Au3 Au2 Ag1 58.845(15) . . ?
P9 Au2 Ag7 125.84(5) . . ?
Pt1 Au2 Ag7 58.458(17) . . ?
Au1 Au2 Ag7 58.536(16) . . ?
Ag8 Au2 Ag7 59.914(17) . . ?
Au3 Au2 Ag7 108.936(16) . . ?
Ag1 Au2 Ag7 106.83(2) . . ?
P10 Au3 Pt1 177.66(5) . . ?
P10 Au3 Au4 121.95(5) . . ?
Pt1 Au3 Au4 59.486(15) . . ?
P10 Au3 Ag1 118.61(5) . . ?
Pt1 Au3 Ag1 59.106(15) . . ?
Au4 Au3 Ag1 108.389(18) . . ?
P10 Au3 Au2 122.49(5) . . ?
Pt1 Au3 Au2 57.333(12) . . ?
Au4 Au3 Au2 108.739(14) . . ?
Ag1 Au3 Au2 61.266(17) . . ?
P10 Au3 Ag3 116.43(5) . . ?
Pt1 Au3 Ag3 62.231(17) . . ?
Au4 Au3 Ag3 62.402(17) . . ?
Ag1 Au3 Ag3 58.838(17) . . ?
Au2 Au3 Ag3 109.667(17) . . ?
P10 Au3 Ag8 124.93(5) . . ?
Pt1 Au3 Ag8 57.224(14) . . ?
Au4 Au3 Ag8 62.123(14) . . ?
Ag1 Au3 Ag8 107.904(17) . . ?
Au2 Au3 Ag8 58.175(15) . . ?
Ag3 Au3 Ag8 111.94(2) . . ?
P11 Au4 Pt1 174.44(5) . . ?
P11 Au4 Au3 127.26(5) . . ?
Pt1 Au4 Au3 58.159(12) . . ?
P11 Au4 Ag6 116.55(5) . . ?
Pt1 Au4 Ag6 59.543(15) . . ?
Au3 Au4 Ag6 109.923(17) . . ?
P11 Au4 Ag4 116.14(5) . . ?
Pt1 Au4 Ag4 58.855(15) . . ?
Au3 Au4 Ag4 106.882(19) . . ?
Ag6 Au4 Ag4 61.508(18) . . ?
P11 Au4 Au4B 116.14(5) . . ?
Pt1 Au4 Au4B 58.855(15) . . ?
Au3 Au4 Au4B 106.882(19) . . ?
Ag6 Au4 Au4B 61.508(18) . . ?
P11 Au4 Ag3 119.25(5) . . ?
Pt1 Au4 Ag3 61.159(15) . . ?
Au3 Au4 Ag3 60.639(15) . . ?
Ag6 Au4 Ag3 110.68(2) . . ?
Ag4 Au4 Ag3 59.000(17) . . ?
Au4B Au4 Ag3 59.000(17) . . ?
P11 Au4 Ag8 125.16(5) . . ?
Pt1 Au4 Ag8 57.172(13) . . ?
Au3 Au4 Ag8 62.909(16) . . ?
Ag6 Au4 Ag8 58.402(19) . . ?
Ag4 Au4 Ag8 107.072(19) . . ?
Au4B Au4 Ag8 107.072(19) . . ?
Ag3 Au4 Ag8 111.18(2) . . ?
Au2 Pt1 Au3 65.311(16) . . ?
Au2 Pt1 Au1 64.713(12) . . ?
Au3 Pt1 Au1 118.038(15) . . ?
Au2 Pt1 Au4 117.831(14) . . ?
Au3 Pt1 Au4 62.355(13) . . ?
Au1 Pt1 Au4 176.319(14) . . ?
Au2 Pt1 Au4B 177.068(17) . . ?
Au3 Pt1 Au4B 113.240(18) . . ?
Au1 Pt1 Au4B 114.803(16) . . ?
Au4 Pt1 Au4B 62.507(14) . . ?
Au2 Pt1 Ag4 177.068(17) . . ?
Au3 Pt1 Ag4 113.240(18) . . ?
Au1 Pt1 Ag4 114.803(16) . . ?
Au4 Pt1 Ag4 62.507(14) . . ?
Au2 Pt1 Ag1 65.514(17) . . ?
Au3 Pt1 Ag1 63.740(17) . . ?
Au1 Pt1 Ag1 63.697(15) . . ?
Au4 Pt1 Ag1 114.447(17) . . ?
Au4B Pt1 Ag1 111.60(2) . . ?
Ag4 Pt1 Ag1 111.60(2) . . ?
Au2 Pt1 Au5B 118.843(18) . . ?
Au3 Pt1 Au5B 175.809(17) . . ?
Au1 Pt1 Au5B 64.894(15) . . ?
Au4 Pt1 Au5B 114.508(17) . . ?
Au4B Pt1 Au5B 62.584(18) . . ?
Ag1 Pt1 Au5B 116.84(2) . . ?
Au2 Pt1 Ag5 118.843(18) . . ?
Au3 Pt1 Ag5 175.809(17) . . ?
Au1 Pt1 Ag5 64.894(15) . . ?
Au4 Pt1 Ag5 114.508(17) . . ?
Ag4 Pt1 Ag5 62.584(18) . . ?
Ag1 Pt1 Ag5 116.84(2) . . ?
Au2 Pt1 Ag6 119.238(19) . . ?
Au3 Pt1 Ag6 115.688(19) . . ?
Au1 Pt1 Ag6 119.475(17) . . ?
Au4 Pt1 Ag6 62.130(15) . . ?
Au4B Pt1 Ag6 63.629(19) . . ?
Ag4 Pt1 Ag6 63.629(19) . . ?
Ag1 Pt1 Ag6 174.86(2) . . ?
Au5B Pt1 Ag6 63.322(19) . . ?
Ag5 Pt1 Ag6 63.322(19) . . ?
Au2 Pt1 Ag8 64.113(17) . . ?
Au3 Pt1 Ag8 67.943(17) . . ?
Au1 Pt1 Ag8 116.776(18) . . ?
Au4 Pt1 Ag8 66.880(16) . . ?
Au4B Pt1 Ag8 118.02(2) . . ?
Ag4 Pt1 Ag8 118.02(2) . . ?
Ag1 Pt1 Ag8 120.54(2) . . ?
Au5B Pt1 Ag8 113.89(2) . . ?
Ag5 Pt1 Ag8 113.89(2) . . ?
Ag6 Pt1 Ag8 62.40(2) . . ?
Au2 Pt1 Ag7 65.757(16) . . ?
Au3 Pt1 Ag7 121.931(18) . . ?
Au1 Pt1 Ag7 62.919(14) . . ?
Au4 Pt1 Ag7 120.292(16) . . ?
Au4B Pt1 Ag7 116.807(19) . . ?
Ag4 Pt1 Ag7 116.807(19) . . ?
Ag1 Pt1 Ag7 118.51(2) . . ?
Au5B Pt1 Ag7 61.801(18) . . ?
Ag5 Pt1 Ag7 61.801(18) . . ?
Ag6 Pt1 Ag7 66.367(19) . . ?
Ag8 Pt1 Ag7 63.83(2) . . ?
S13 Ag1 Pt1 170.45(6) . . ?
S13 Ag1 Ag3 110.24(5) . . ?
Pt1 Ag1 Ag3 62.551(19) . . ?
S13 Ag1 Au3 126.36(5) . . ?
Pt1 Ag1 Au3 57.154(15) . . ?
Ag3 Ag1 Au3 61.370(19) . . ?
S13 Ag1 Au1 123.42(5) . . ?
Pt1 Ag1 Au1 57.644(17) . . ?
Ag3 Ag1 Au1 110.10(2) . . ?
Au3 Ag1 Au1 107.32(2) . . ?
S13 Ag1 Ag2 111.69(6) . . ?
Pt1 Ag1 Ag2 59.873(18) . . ?
Ag3 Ag1 Ag2 61.73(2) . . ?
Au3 Ag1 Ag2 108.27(2) . . ?
Au1 Ag1 Ag2 59.042(17) . . ?
S13 Ag1 Au2 133.16(6) . . ?
Pt1 Ag1 Au2 56.289(15) . . ?
Ag3 Ag1 Au2 110.61(2) . . ?
Au3 Ag1 Au2 59.890(14) . . ?
Au1 Ag1 Au2 59.552(16) . . ?
Ag2 Ag1 Au2 107.21(2) . . ?
S10 Ag2 Au4B 136.31(6) . . ?
S10 Ag2 Ag4 136.31(6) . . ?
S10 Ag2 Pt1 160.21(5) . . ?
Au4B Ag2 Pt1 58.030(17) . . ?
Ag4 Ag2 Pt1 58.030(17) . . ?
S10 Ag2 Au1 114.63(6) . . ?
Au4B Ag2 Au1 108.32(2) . . ?
Ag4 Ag2 Au1 108.32(2) . . ?
Pt1 Ag2 Au1 57.271(17) . . ?
S10 Ag2 Au5B 137.54(5) . . ?
Au4B Ag2 Au5B 60.135(18) . . ?
Pt1 Ag2 Au5B 57.907(18) . . ?
Au1 Ag2 Au5B 61.736(19) . . ?
S10 Ag2 Ag5 137.54(5) . . ?
Ag4 Ag2 Ag5 60.135(18) . . ?
Pt1 Ag2 Ag5 57.907(18) . . ?
Au1 Ag2 Ag5 61.736(19) . . ?
S10 Ag2 Ag1 102.82(5) . . ?
Au4B Ag2 Ag1 104.98(2) . . ?
Ag4 Ag2 Ag1 104.98(2) . . ?
Pt1 Ag2 Ag1 57.400(17) . . ?
Au1 Ag2 Ag1 60.218(18) . . ?
Au5B Ag2 Ag1 108.60(2) . . ?
Ag5 Ag2 Ag1 108.60(2) . . ?
S10 Ag2 Ag3 111.67(6) . . ?
Au4B Ag2 Ag3 59.42(2) . . ?
Ag4 Ag2 Ag3 59.42(2) . . ?
Pt1 Ag2 Ag3 60.414(18) . . ?
Au1 Ag2 Ag3 108.17(2) . . ?
Au5B Ag2 Ag3 108.97(2) . . ?
Ag5 Ag2 Ag3 108.97(2) . . ?
Ag1 Ag2 Ag3 58.204(19) . . ?
S10 Ag2 Ag11 93.82(5) . . ?
Au4B Ag2 Ag11 57.112(18) . . ?
Ag4 Ag2 Ag11 57.112(18) . . ?
Pt1 Ag2 Ag11 105.87(2) . . ?
Au1 Ag2 Ag11 119.12(2) . . ?
Au5B Ag2 Ag11 61.328(19) . . ?
Ag5 Ag2 Ag11 61.328(19) . . ?
Ag1 Ag2 Ag11 161.80(2) . . ?
Ag3 Ag2 Ag11 108.82(2) . . ?
S14 Ag3 S12 91.15(6) . . ?
S14 Ag3 Ag1 84.19(5) . . ?
S12 Ag3 Ag1 169.87(5) . . ?
S14 Ag3 Au4B 152.99(5) . . ?
S12 Ag3 Au4B 75.11(5) . . ?
Ag1 Ag3 Au4B 105.36(2) . . ?
S14 Ag3 Ag4 152.99(5) . . ?
S12 Ag3 Ag4 75.11(5) . . ?
Ag1 Ag3 Ag4 105.36(2) . . ?
S14 Ag3 Pt1 140.97(5) . . ?
S12 Ag3 Pt1 127.85(5) . . ?
Ag1 Ag3 Pt1 57.112(16) . . ?
Au4B Ag3 Pt1 56.654(17) . . ?
Ag4 Ag3 Pt1 56.654(17) . . ?
S14 Ag3 Au3 103.27(5) . . ?
S12 Ag3 Au3 130.23(5) . . ?
Ag1 Ag3 Au3 59.792(18) . . ?
Au4B Ag3 Au3 103.33(2) . . ?
Ag4 Ag3 Au3 103.33(2) . . ?
Pt1 Ag3 Au3 55.057(15) . . ?
S14 Ag3 Ag2 109.62(5) . . ?
S12 Ag3 Ag2 113.63(5) . . ?
Ag1 Ag3 Ag2 60.06(2) . . ?
Au4B Ag3 Ag2 58.026(19) . . ?
Ag4 Ag3 Ag2 58.026(19) . . ?
Pt1 Ag3 Ag2 57.653(16) . . ?
Au3 Ag3 Ag2 105.80(2) . . ?
S14 Ag3 Au4 144.69(5) . . ?
S12 Ag3 Au4 84.13(5) . . ?
Ag1 Ag3 Au4 104.83(2) . . ?
Au4B Ag3 Au4 58.204(17) . . ?
Ag4 Ag3 Au4 58.204(17) . . ?
Pt1 Ag3 Au4 55.383(17) . . ?
Au3 Ag3 Au4 56.959(15) . . ?
Ag2 Ag3 Au4 104.26(2) . . ?
S11 Ag4 Pt1 170.80(5) . . ?
S11 Ag4 Ag2 109.81(5) . . ?
Pt1 Ag4 Ag2 61.069(17) . . ?
S11 Ag4 Ag11 58.23(5) . . ?
Pt1 Ag4 Ag11 115.66(2) . . ?
Ag2 Ag4 Ag11 66.01(2) . . ?
S11 Ag4 Au4 127.93(5) . . ?
Pt1 Ag4 Au4 58.639(17) . . ?
Ag2 Ag4 Au4 111.37(2) . . ?
Ag11 Ag4 Au4 173.21(2) . . ?
S11 Ag4 Ag5 118.78(5) . . ?
Pt1 Ag4 Ag5 59.136(16) . . ?
Ag2 Ag4 Ag5 61.00(2) . . ?
Ag11 Ag4 Ag5 64.73(2) . . ?
Au4 Ag4 Ag5 108.48(2) . . ?
S11 Ag4 Ag3 113.21(5) . . ?
Pt1 Ag4 Ag3 62.51(2) . . ?
Ag2 Ag4 Ag3 62.558(19) . . ?
Ag11 Ag4 Ag3 118.96(2) . . ?
Au4 Ag4 Ag3 62.796(18) . . ?
Ag5 Ag4 Ag3 112.20(2) . . ?
S11 Ag4 Ag6 129.30(5) . . ?
Pt1 Ag4 Ag6 58.670(16) . . ?
Ag2 Ag4 Ag6 110.57(2) . . ?
Ag11 Ag4 Ag6 115.19(2) . . ?
Au4 Ag4 Ag6 59.240(16) . . ?
Ag5 Ag4 Ag6 60.521(19) . . ?
Ag3 Ag4 Ag6 111.94(2) . . ?
S7 Ag5 Pt1 160.56(5) . . ?
S7 Ag5 Ag7 101.62(6) . . ?
Pt1 Ag5 Ag7 59.316(19) . . ?
S7 Ag5 Ag4 134.52(5) . . ?
Pt1 Ag5 Ag4 58.280(16) . . ?
Ag7 Ag5 Ag4 110.91(2) . . ?
S7 Ag5 Ag2 136.87(5) . . ?
Pt1 Ag5 Ag2 60.012(16) . . ?
Ag7 Ag5 Ag2 109.13(2) . . ?
Ag4 Ag5 Ag2 58.862(19) . . ?
S7 Ag5 Ag6 111.68(5) . . ?
Pt1 Ag5 Ag6 58.405(16) . . ?
Ag7 Ag5 Ag6 63.710(19) . . ?
Ag4 Ag5 Ag6 60.50(2) . . ?
Ag2 Ag5 Ag6 108.82(2) . . ?
S7 Ag5 Au1 118.97(5) . . ?
Pt1 Ag5 Au1 56.868(17) . . ?
Ag7 Ag5 Au1 59.415(18) . . ?
Ag4 Ag5 Au1 104.92(2) . . ?
Ag2 Ag5 Au1 58.658(16) . . ?
Ag6 Ag5 Au1 108.38(2) . . ?
S7 Ag5 Ag10 54.99(5) . . ?
Pt1 Ag5 Ag10 109.82(2) . . ?
Ag7 Ag5 Ag10 68.40(2) . . ?
Ag4 Ag5 Ag10 109.07(2) . . ?
Ag2 Ag5 Ag10 166.69(2) . . ?
Ag6 Ag5 Ag10 58.055(18) . . ?
Au1 Ag5 Ag10 124.90(2) . . ?
S7 Ag5 Ag11 90.47(6) . . ?
Pt1 Ag5 Ag11 108.37(2) . . ?
Ag7 Ag5 Ag11 167.47(2) . . ?
Ag4 Ag5 Ag11 57.162(18) . . ?
Ag2 Ag5 Ag11 62.49(2) . . ?
Ag6 Ag5 Ag11 108.87(2) . . ?
Au1 Ag5 Ag11 117.35(2) . . ?
Ag10 Ag5 Ag11 117.39(3) . . ?
S11 Au4B Pt1 170.80(5) . . ?
S11 Au4B Ag2 109.81(5) . . ?
Pt1 Au4B Ag2 61.069(17) . . ?
S11 Au4B Ag11 58.23(5) . . ?
Pt1 Au4B Ag11 115.66(2) . . ?
Ag2 Au4B Ag11 66.01(2) . . ?
S11 Au4B Au4 127.93(5) . . ?
Pt1 Au4B Au4 58.639(17) . . ?
Ag2 Au4B Au4 111.37(2) . . ?
Ag11 Au4B Au4 173.21(2) . . ?
S11 Au4B Au5B 118.78(5) . . ?
Pt1 Au4B Au5B 59.136(16) . . ?
Ag2 Au4B Au5B 61.00(2) . . ?
Ag11 Au4B Au5B 64.73(2) . . ?
Au4 Au4B Au5B 108.48(2) . . ?
S11 Au4B Ag3 113.21(5) . . ?
Pt1 Au4B Ag3 62.51(2) . . ?
Ag2 Au4B Ag3 62.558(19) . . ?
Ag11 Au4B Ag3 118.96(2) . . ?
Au4 Au4B Ag3 62.796(18) . . ?
Au5B Au4B Ag3 112.20(2) . . ?
S11 Au4B Ag6 129.30(5) . . ?
Pt1 Au4B Ag6 58.670(16) . . ?
Ag2 Au4B Ag6 110.57(2) . . ?
Ag11 Au4B Ag6 115.19(2) . . ?
Au4 Au4B Ag6 59.240(16) . . ?
Au5B Au4B Ag6 60.521(19) . . ?
Ag3 Au4B Ag6 111.94(2) . . ?
S7 Au5B Pt1 160.56(5) . . ?
S7 Au5B Ag7 101.62(6) . . ?
Pt1 Au5B Ag7 59.316(19) . . ?
S7 Au5B Au4B 134.52(5) . . ?
Pt1 Au5B Au4B 58.280(16) . . ?
Ag7 Au5B Au4B 110.91(2) . . ?
S7 Au5B Ag2 136.87(5) . . ?
Pt1 Au5B Ag2 60.012(16) . . ?
Ag7 Au5B Ag2 109.13(2) . . ?
Au4B Au5B Ag2 58.862(19) . . ?
S7 Au5B Ag6 111.68(5) . . ?
Pt1 Au5B Ag6 58.405(16) . . ?
Ag7 Au5B Ag6 63.710(19) . . ?
Au4B Au5B Ag6 60.50(2) . . ?
Ag2 Au5B Ag6 108.82(2) . . ?
S7 Au5B Au1 118.97(5) . . ?
Pt1 Au5B Au1 56.868(17) . . ?
Ag7 Au5B Au1 59.415(18) . . ?
Au4B Au5B Au1 104.92(2) . . ?
Ag2 Au5B Au1 58.658(16) . . ?
Ag6 Au5B Au1 108.38(2) . . ?
S7 Au5B Ag10 54.99(5) . . ?
Pt1 Au5B Ag10 109.82(2) . . ?
Ag7 Au5B Ag10 68.40(2) . . ?
Au4B Au5B Ag10 109.07(2) . . ?
Ag2 Au5B Ag10 166.69(2) . . ?
Ag6 Au5B Ag10 58.055(18) . . ?
Au1 Au5B Ag10 124.90(2) . . ?
S7 Au5B Ag11 90.47(6) . . ?
Pt1 Au5B Ag11 108.37(2) . . ?
Ag7 Au5B Ag11 167.47(2) . . ?
Au4B Au5B Ag11 57.162(18) . . ?
Ag2 Au5B Ag11 62.49(2) . . ?
Ag6 Au5B Ag11 108.87(2) . . ?
Au1 Au5B Ag11 117.35(2) . . ?
Ag10 Au5B Ag11 117.39(3) . . ?
S4 Ag6 Pt1 154.29(5) . . ?
S4 Ag6 Au4 127.48(5) . . ?
Pt1 Ag6 Au4 58.327(17) . . ?
S4 Ag6 Ag10 56.75(4) . . ?
Pt1 Ag6 Ag10 113.13(2) . . ?
Au4 Ag6 Ag10 169.10(3) . . ?
S4 Ag6 Ag8 146.42(5) . . ?
Pt1 Ag6 Ag8 58.860(18) . . ?
Au4 Ag6 Ag8 64.197(19) . . ?
Ag10 Ag6 Ag8 118.72(3) . . ?
S4 Ag6 Ag4 101.62(5) . . ?
Pt1 Ag6 Ag4 57.701(17) . . ?
Au4 Ag6 Ag4 59.251(18) . . ?
Ag10 Ag6 Ag4 111.05(2) . . ?
Ag8 Ag6 Ag4 109.83(2) . . ?
S4 Ag6 Au4B 101.62(5) . . ?
Pt1 Ag6 Au4B 57.701(17) . . ?
Au4 Ag6 Au4B 59.251(18) . . ?
Ag10 Ag6 Au4B 111.05(2) . . ?
Ag8 Ag6 Au4B 109.83(2) . . ?
S4 Ag6 Au5B 99.02(5) . . ?
Pt1 Ag6 Au5B 58.273(18) . . ?
Au4 Ag6 Au5B 107.24(2) . . ?
Ag10 Ag6 Au5B 61.96(2) . . ?
Ag8 Ag6 Au5B 106.96(2) . . ?
Au4B Ag6 Au5B 58.975(17) . . ?
S4 Ag6 Ag5 99.02(5) . . ?
Pt1 Ag6 Ag5 58.273(18) . . ?
Au4 Ag6 Ag5 107.24(2) . . ?
Ag10 Ag6 Ag5 61.96(2) . . ?
Ag8 Ag6 Ag5 106.96(2) . . ?
Ag4 Ag6 Ag5 58.975(17) . . ?
S4 Ag6 Ag7 123.60(5) . . ?
Pt1 Ag6 Ag7 56.953(18) . . ?
Au4 Ag6 Ag7 108.85(2) . . ?
Ag10 Ag6 Ag7 67.35(2) . . ?
Ag8 Ag6 Ag7 59.49(2) . . ?
Ag4 Ag6 Ag7 104.57(2) . . ?
Au4B Ag6 Ag7 104.57(2) . . ?
Au5B Ag6 Ag7 57.21(2) . . ?
Ag5 Ag6 Ag7 57.21(2) . . ?
S4 Ag6 Ag9 88.54(5) . . ?
Pt1 Ag6 Ag9 107.67(2) . . ?
Au4 Ag6 Ag9 125.78(2) . . ?
Ag10 Ag6 Ag9 61.61(2) . . ?
Ag8 Ag6 Ag9 64.94(2) . . ?
Ag4 Ag6 Ag9 161.29(2) . . ?
Au4B Ag6 Ag9 161.29(2) . . ?
Au5B Ag6 Ag9 104.23(2) . . ?
Ag5 Ag6 Ag9 104.23(2) . . ?
Ag7 Ag6 Ag9 56.919(18) . . ?
S6 Ag7 Pt1 155.76(5) . . ?
S6 Ag7 Au5B 108.15(5) . . ?
Pt1 Ag7 Au5B 58.883(17) . . ?
S6 Ag7 Ag5 108.15(5) . . ?
Pt1 Ag7 Ag5 58.883(17) . . ?
S6 Ag7 Au1 98.56(5) . . ?
Pt1 Ag7 Au1 57.617(17) . . ?
Au5B Ag7 Au1 61.998(18) . . ?
Ag5 Ag7 Au1 61.998(18) . . ?
S6 Ag7 Ag9 91.52(5) . . ?
Pt1 Ag7 Ag9 111.83(2) . . ?
Au5B Ag7 Ag9 109.84(3) . . ?
Ag5 Ag7 Ag9 109.84(3) . . ?
Au1 Ag7 Ag9 168.62(2) . . ?
S6 Ag7 Ag8 143.29(6) . . ?
Pt1 Ag7 Ag8 58.004(16) . . ?
Au5B Ag7 Ag8 106.82(2) . . ?
Ag5 Ag7 Ag8 106.82(2) . . ?
Au1 Ag7 Ag8 107.46(2) . . ?
Ag9 Ag7 Ag8 66.15(2) . . ?
S6 Ag7 Au2 118.65(5) . . ?
Pt1 Ag7 Au2 55.785(14) . . ?
Au5B Ag7 Au2 107.78(2) . . ?
Ag5 Ag7 Au2 107.78(2) . . ?
Au1 Ag7 Au2 59.483(15) . . ?
Ag9 Ag7 Au2 119.78(2) . . ?
Ag8 Ag7 Au2 58.876(17) . . ?
S6 Ag7 Ag6 137.74(5) . . ?
Pt1 Ag7 Ag6 56.680(16) . . ?
Au5B Ag7 Ag6 59.080(19) . . ?
Ag5 Ag7 Ag6 59.080(19) . . ?
Au1 Ag7 Ag6 106.82(2) . . ?
Ag9 Ag7 Ag6 61.88(2) . . ?
Ag8 Ag7 Ag6 57.46(2) . . ?
Au2 Ag7 Ag6 103.38(2) . . ?
S6 Ag7 Ag10 84.96(5) . . ?
Pt1 Ag7 Ag10 101.40(2) . . ?
Au5B Ag7 Ag10 57.46(2) . . ?
Ag5 Ag7 Ag10 57.46(2) . . ?
Au1 Ag7 Ag10 116.98(2) . . ?
Ag9 Ag7 Ag10 58.440(19) . . ?
Ag8 Ag7 Ag10 104.90(2) . . ?
Au2 Ag7 Ag10 156.15(2) . . ?
Ag6 Ag7 Ag10 53.561(18) . . ?
S2 Ag8 Pt1 170.70(5) . . ?
S2 Ag8 Ag6 129.09(5) . . ?
Pt1 Ag8 Ag6 58.735(17) . . ?
S2 Ag8 Au2 118.50(5) . . ?
Pt1 Ag8 Au2 56.646(15) . . ?
Ag6 Ag8 Au2 109.46(2) . . ?
S2 Ag8 Ag7 128.19(5) . . ?
Pt1 Ag8 Ag7 58.170(17) . . ?
Ag6 Ag8 Ag7 63.05(2) . . ?
Au2 Ag8 Ag7 61.210(19) . . ?
S2 Ag8 Au4 121.87(5) . . ?
Pt1 Ag8 Au4 55.948(16) . . ?
Ag6 Ag8 Au4 57.402(17) . . ?
Au2 Ag8 Au4 103.06(2) . . ?
Ag7 Ag8 Au4 106.42(2) . . ?
S2 Ag8 Au3 116.02(5) . . ?
Pt1 Ag8 Au3 54.833(15) . . ?
Ag6 Ag8 Au3 102.58(2) . . ?
Au2 Ag8 Au3 58.368(14) . . ?
Ag7 Ag8 Au3 106.03(2) . . ?
Au4 Ag8 Au3 54.969(15) . . ?
S2 Ag8 Ag9 85.06(5) . . ?
Pt1 Ag8 Ag9 104.10(2) . . ?
Ag6 Ag8 Ag9 60.33(2) . . ?
Au2 Ag8 Ag9 113.09(2) . . ?
Ag7 Ag8 Ag9 56.451(18) . . ?
Au4 Ag8 Ag9 115.05(2) . . ?
Au3 Ag8 Ag9 158.92(2) . . ?
S3 Ag9 S1 125.38(7) . . ?
S3 Ag9 S5 118.37(7) . . ?
S1 Ag9 S5 105.27(7) . . ?
S3 Ag9 Ag7 129.04(6) . . ?
S1 Ag9 Ag7 76.17(5) . . ?
S5 Ag9 Ag7 92.38(5) . . ?
S3 Ag9 Ag10 99.64(6) . . ?
S1 Ag9 Ag10 133.85(5) . . ?
S5 Ag9 Ag10 52.20(5) . . ?
Ag7 Ag9 Ag10 66.78(2) . . ?
S3 Ag9 Ag6 70.62(6) . . ?
S1 Ag9 Ag6 125.97(5) . . ?
S5 Ag9 Ag6 107.95(5) . . ?
Ag7 Ag9 Ag6 61.20(2) . . ?
Ag10 Ag9 Ag6 55.802(19) . . ?
S3 Ag9 Ag8 82.22(6) . . ?
S1 Ag9 Ag8 75.24(5) . . ?
S5 Ag9 Ag8 149.20(5) . . ?
Ag7 Ag9 Ag8 57.40(2) . . ?
Ag10 Ag9 Ag8 104.67(3) . . ?
Ag6 Ag9 Ag8 54.73(2) . . ?
S5 Ag10 S7 118.11(7) . . ?
S5 Ag10 S4 117.30(7) . . ?
S7 Ag10 S4 119.60(7) . . ?
S5 Ag10 Ag6 117.71(5) . . ?
S7 Ag10 Ag6 112.52(5) . . ?
S4 Ag10 Ag6 56.60(5) . . ?
S5 Ag10 Au5B 136.43(5) . . ?
S7 Ag10 Au5B 53.92(5) . . ?
S4 Ag10 Au5B 97.51(5) . . ?
Ag6 Ag10 Au5B 59.99(2) . . ?
S5 Ag10 Ag5 136.43(5) . . ?
S7 Ag10 Ag5 53.92(5) . . ?
S4 Ag10 Ag5 97.51(5) . . ?
Ag6 Ag10 Ag5 59.99(2) . . ?
S5 Ag10 Ag9 55.18(5) . . ?
S7 Ag10 Ag9 143.41(5) . . ?
S4 Ag10 Ag9 89.05(5) . . ?
Ag6 Ag10 Ag9 62.59(2) . . ?
Au5B Ag10 Ag9 103.56(3) . . ?
Ag5 Ag10 Ag9 103.56(3) . . ?
S5 Ag10 Ag7 86.11(5) . . ?
S7 Ag10 Ag7 90.57(5) . . ?
S4 Ag10 Ag7 115.26(5) . . ?
Ag6 Ag10 Ag7 59.09(2) . . ?
Au5B Ag10 Ag7 54.142(18) . . ?
Ag5 Ag10 Ag7 54.142(18) . . ?
Ag9 Ag10 Ag7 54.78(2) . . ?
S9 Ag11 S11 143.87(8) . . ?
S9 Ag11 S8 116.92(7) . . ?
S11 Ag11 S8 81.88(7) . . ?
S9 Ag11 Ag4 144.35(6) . . ?
S11 Ag11 Ag4 54.33(5) . . ?
S8 Ag11 Ag4 92.52(5) . . ?
S9 Ag11 Au4B 144.35(6) . . ?
S11 Ag11 Au4B 54.33(5) . . ?
S8 Ag11 Au4B 92.52(5) . . ?
S9 Ag11 Au5B 104.33(6) . . ?
S11 Ag11 Au5B 109.00(5) . . ?
S8 Ag11 Au5B 81.68(5) . . ?
Au4B Ag11 Au5B 58.110(19) . . ?
S9 Ag11 Ag5 104.33(6) . . ?
S11 Ag11 Ag5 109.00(5) . . ?
S8 Ag11 Ag5 81.68(5) . . ?
Ag4 Ag11 Ag5 58.110(19) . . ?
S9 Ag11 Ag2 87.47(6) . . ?
S11 Ag11 Ag2 99.55(5) . . ?
S8 Ag11 Ag2 136.17(5) . . ?
Ag4 Ag11 Ag2 56.88(2) . . ?
Au4B Ag11 Ag2 56.88(2) . . ?
Au5B Ag11 Ag2 56.187(19) . . ?
Ag5 Ag11 Ag2 56.187(19) . . ?
P1 S1 Ag9 93.70(10) . . ?
P1 S2 Ag8 102.68(9) . . ?
P2 S3 Ag9 100.57(10) . . ?
P2 S4 Ag6 94.71(10) . . ?
P2 S4 Ag10 102.91(10) . . ?
Ag6 S4 Ag10 66.65(5) . . ?
P3 S5 Ag10 97.26(9) . . ?
P3 S5 Ag9 106.68(10) . . ?
Ag10 S5 Ag9 72.62(5) . . ?
P3 S6 Ag7 111.34(10) . . ?
P4 S7 Ag5 106.84(10) . . ?
P4 S7 Au5B 106.84(10) . . ?
P4 S7 Ag10 92.03(10) . . ?
Ag5 S7 Ag10 71.09(5) . . ?
Au5B S7 Ag10 71.09(5) . . ?
P4 S8 Ag11 106.34(12) . . ?
P5 S9 Ag11 106.82(10) . . ?
P5 S10 Ag2 108.18(11) . . ?
P6 S11 Ag4 92.31(10) . . ?
P6 S11 Au4B 92.31(10) . . ?
P6 S11 Ag11 113.63(10) . . ?
Ag4 S11 Ag11 67.44(5) . . ?
Au4B S11 Ag11 67.44(5) . . ?
P6 S12 Ag3 106.48(10) . . ?
P7 S13 Ag1 102.02(10) . . ?
P7 S14 Ag3 119.56(10) . . ?
O2 P1 O1 100.6(3) . . ?
O2 P1 S2 107.2(2) . . ?
O1 P1 S2 110.9(2) . . ?
O2 P1 S1 111.3(2) . . ?
O1 P1 S1 109.1(2) . . ?
S2 P1 S1 116.47(13) . . ?
O4 P2 O3 101.6(3) . . ?
O4 P2 S3 113.5(3) . . ?
O3 P2 S3 108.8(2) . . ?
O4 P2 S4 106.4(3) . . ?
O3 P2 S4 108.3(3) . . ?
S3 P2 S4 117.01(13) . . ?
O6 P3 O5 100.5(3) . . ?
O6 P3 S6 113.7(2) . . ?
O5 P3 S6 109.3(3) . . ?
O6 P3 S5 103.6(2) . . ?
O5 P3 S5 108.1(2) . . ?
S6 P3 S5 119.78(12) . . ?
O8 P4 O7 99.8(4) . . ?
O8 P4 S8 113.9(3) . . ?
O7 P4 S8 106.0(3) . . ?
O8 P4 S7 109.1(3) . . ?
O7 P4 S7 109.3(3) . . ?
S8 P4 S7 117.06(14) . . ?
O10 P5 O9 100.2(3) . . ?
O10 P5 S10 105.7(2) . . ?
O9 P5 S10 110.1(3) . . ?
O10 P5 S9 113.0(3) . . ?
O9 P5 S9 106.1(2) . . ?
S10 P5 S9 119.93(13) . . ?
O11 P6 O12 102.0(3) . . ?
O11 P6 S12 114.9(2) . . ?
O12 P6 S12 110.0(3) . . ?
O11 P6 S11 106.0(2) . . ?
O12 P6 S11 106.5(3) . . ?
S12 P6 S11 116.29(13) . . ?
O14 P7 O13 99.5(3) . . ?
O14 P7 S14 106.8(2) . . ?
O13 P7 S14 110.1(2) . . ?
O14 P7 S13 110.1(2) . . ?
O13 P7 S13 106.9(2) . . ?
S14 P7 S13 121.29(13) . . ?
C43 P8 C55 105.3(4) . . ?
C43 P8 C49 103.3(3) . . ?
C55 P8 C49 102.1(4) . . ?
C43 P8 Au1 114.9(2) . . ?
C55 P8 Au1 114.1(2) . . ?
C49 P8 Au1 115.6(3) . . ?
C67 P9 C61 103.8(3) . . ?
C67 P9 C73 108.1(3) . . ?
C61 P9 C73 101.9(3) . . ?
C67 P9 Au2 110.2(2) . . ?
C61 P9 Au2 116.5(3) . . ?
C73 P9 Au2 115.3(3) . . ?
C85 P10 C79 107.7(4) . . ?
C85 P10 C91 102.1(3) . . ?
C79 P10 C91 103.5(4) . . ?
C85 P10 Au3 114.2(3) . . ?
C79 P10 Au3 112.0(2) . . ?
C91 P10 Au3 116.3(3) . . ?
C97 P11 C109 101.5(3) . . ?
C97 P11 C103 102.6(4) . . ?
C109 P11 C103 105.6(4) . . ?
C97 P11 Au4 113.0(3) . . ?
C109 P11 Au4 118.9(3) . . ?
C103 P11 Au4 113.3(2) . . ?
C1 O1 P1 121.2(5) . . ?
C4 O2 P1 120.6(5) . . ?
C7 O3 P2 118.3(5) . . ?
C10B O4 P2 129.8(13) . . ?
C10 O4 P2 112.4(9) . . ?
C13 O5 P3 120.7(5) . . ?
C16 O6 P3 120.3(5) . . ?
C19 O7 P4 120.8(6) . . ?
C22B O8 P4 121.4(13) . . ?
C22 O8 P4 119.4(12) . . ?
C25 O9 P5 118.2(5) . . ?
C28 O10 P5 122.3(5) . . ?
C31 O11 P6 123.4(5) . . ?
C34 O12 P6 119.9(5) . . ?
C37 O13 P7 118.3(5) . . ?
C40 O14 P7 121.0(5) . . ?
O1 C1 C2 109.3(9) . . ?
C3 C2 C1 116.5(15) . . ?
O2 C4 C5 109.1(8) . . ?
C4 C5 C6 112.1(9) . . ?
O3 C7 C8 108.3(8) . . ?
C9 C8 C7 112.9(10) . . ?
O4 C10 C11 109.6(15) . . ?
C10 C11 C12 114.2(19) . . ?
O4 C10B C11B 109.9(18) . . ?
C10B C11B C12B 108.0(18) . . ?
O5 C13 C14 110.4(8) . . ?
C13 C14 C15 109.9(10) . . ?
O6 C16 C17 109.2(7) . . ?
C16 C17 C18 110.6(9) . . ?
O7 C19 C20 108.2(8) . . ?
C19 C20 C21 113.3(9) . . ?
O8 C22 C23 106(3) . . ?
C24 C23 C22 115(2) . . ?
O8 C22B C23B 123(4) . . ?
C24B C23B C22B 110(5) . . ?
O9 C25 C26 108.8(8) . . ?
C27 C26 C25 112.4(9) . . ?
O10 C28 C29 109.2(6) . . ?
C28 C29 C30 113.0(8) . . ?
O11 C31 C32 111.5(7) . . ?
C31 C32 C33 109.8(8) . . ?
O12 C34 C35 108.3(8) . . ?
C36 C35 C34 111.9(9) . . ?
O13 C37 C38 107.8(6) . . ?
C37 C38 C39 113.1(7) . . ?
O14 C40 C41 108.7(7) . . ?
C40 C41 C42 112.3(8) . . ?
C48 C43 C44 118.6(7) . . ?
C48 C43 P8 124.3(6) . . ?
C44 C43 P8 117.1(6) . . ?
C45 C44 C43 120.4(8) . . ?
C44 C45 C46 120.0(8) . . ?
C47 C46 C45 120.0(8) . . ?
C46 C47 C48 119.8(8) . . ?
C47 C48 C43 121.3(7) . . ?
C50 C49 C54 119.7(7) . . ?
C50 C49 P8 119.2(6) . . ?
C54 C49 P8 120.9(6) . . ?
C49 C50 C51 119.6(8) . . ?
C52 C51 C50 121.0(9) . . ?
C51 C52 C53 119.3(8) . . ?
C54 C53 C52 120.0(8) . . ?
C53 C54 C49 120.5(8) . . ?
C56 C55 C60 119.3(8) . . ?
C56 C55 P8 121.5(7) . . ?
C60 C55 P8 119.0(6) . . ?
C55 C56 C57 119.7(9) . . ?
C58 C57 C56 120.2(9) . . ?
C57 C58 C59 120.8(9) . . ?
C58 C59 C60 120.6(9) . . ?
C59 C60 C55 119.4(8) . . ?
C62 C61 C66 118.3(7) . . ?
C62 C61 P9 119.2(6) . . ?
C66 C61 P9 122.3(6) . . ?
C61 C62 C63 121.9(8) . . ?
C64 C63 C62 119.0(8) . . ?
C63 C64 C65 120.3(7) . . ?
C64 C65 C66 120.2(8) . . ?
C65 C66 C61 120.1(8) . . ?
C72 C67 C68 116.9(7) . . ?
C72 C67 P9 119.2(6) . . ?
C68 C67 P9 123.8(6) . . ?
C69 C68 C67 119.6(7) . . ?
C70 C69 C68 121.7(8) . . ?
C69 C70 C71 119.4(8) . . ?
C72 C71 C70 118.1(8) . . ?
C67 C72 C71 124.1(7) . . ?
C78 C73 C74 117.9(7) . . ?
C78 C73 P9 118.4(6) . . ?
C74 C73 P9 123.6(6) . . ?
C75 C74 C73 121.5(8) . . ?
C74 C75 C76 119.7(8) . . ?
C75 C76 C77 120.2(8) . . ?
C78 C77 C76 118.6(8) . . ?
C73 C78 C77 122.0(7) . . ?
C80 C79 C84 119.6(8) . . ?
C80 C79 P10 116.1(6) . . ?
C84 C79 P10 124.4(6) . . ?
C81 C80 C79 120.0(8) . . ?
C82 C81 C80 120.3(8) . . ?
C83 C82 C81 119.8(8) . . ?
C82 C83 C84 120.8(8) . . ?
C79 C84 C83 119.4(8) . . ?
C90 C85 C86 118.4(7) . . ?
C90 C85 P10 122.8(6) . . ?
C86 C85 P10 118.7(6) . . ?
C87 C86 C85 119.7(7) . . ?
C88 C87 C86 120.9(8) . . ?
C89 C88 C87 120.2(8) . . ?
C88 C89 C90 119.7(8) . . ?
C89 C90 C85 121.0(8) . . ?
C92 C91 C96 120.2(8) . . ?
C92 C91 P10 121.5(6) . . ?
C96 C91 P10 118.2(6) . . ?
C91 C92 C93 120.0(8) . . ?
C94 C93 C92 120.1(8) . . ?
C95 C94 C93 119.8(8) . . ?
C94 C95 C96 120.8(8) . . ?
C91 C96 C95 119.2(8) . . ?
C98 C97 C102 119.4(7) . . ?
C98 C97 P11 120.1(6) . . ?
C102 C97 P11 120.6(6) . . ?
C97 C98 C99 120.6(7) . . ?
C100 C99 C98 119.5(8) . . ?
C99 C100 C101 120.4(8) . . ?
C102 C101 C100 120.0(8) . . ?
C101 C102 C97 120.1(8) . . ?
C104 C103 C108 119.1(7) . . ?
C104 C103 P11 117.6(6) . . ?
C108 C103 P11 123.2(6) . . ?
C105 C104 C103 121.6(7) . . ?
C104 C105 C106 120.4(8) . . ?
C105 C106 C107 118.6(8) . . ?
C106 C107 C108 120.7(8) . . ?
C103 C108 C107 119.5(8) . . ?
C110 C109 C114 118.9(7) . . ?
C110 C109 P11 122.6(6) . . ?
C114 C109 P11 118.5(6) . . ?
C111 C110 C109 120.6(8) . . ?
C112 C111 C110 120.2(8) . . ?
C113 C112 C111 119.9(8) . . ?
C112 C113 C114 120.7(8) . . ?
C113 C114 C109 119.7(8) . . ?

_refine_diff_density_max         2.805
_refine_diff_density_min         -3.028
_refine_diff_density_rms         0.229


# start Validation Reply Form
_vrf_PLAT971_2                   
;
PROBLEM: Check Calcd Resid. Dens.  1.29Ang From Au2             2.57 eA-3 
RESPONSE: It could arise from strong absorption effects that were not 
fully corrected for.

;
_vrf_PLAT972_2                   
;
PROBLEM: Check Calcd Resid. Dens.  1.50Ang From C105           -2.86 eA-3 
RESPONSE: It could arise from strong absorption effects that were not 
fully corrected for.

;
_vrf_PLAT220_2                   
;
PROBLEM: NonSolvent   Resd 1  C   Ueq(max)/Ueq(min) Range       10.0 Ratio
RESPONSE: Large Uiso presented on the extensive alkyl chains showed the 
potentiality of disorder, which remain unresolved.

;
# end Validation Reply Form





