# Electronic Supplementary Material (ESI) for Inorganic Chemistry Frontiers.
# This journal is © the Partner Organisations 2023

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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data_1
_database_code_depnum_ccdc_archive 'CCDC 2176115'
loop_
_audit_author_name
_audit_author_address
'Wang shuyu'
;Yunnan university
China
;
_audit_update_record             
;
2022-10-01 deposited with the CCDC.	2023-04-28 downloaded from the CCDC.
;
_audit_creation_date             2020-04-10
_audit_creation_method           
;
Olex2 1.3
(compiled Nov 21 2019 18:26:39 for OlexSys, GUI svn.r6003)
;
_shelx_SHELXL_version_number     2014/7
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C88 H67 Eu2 N O15, 3(C4 H9 N O), 2(H2 O)'
_chemical_formula_sum            'C100 H98 Eu2 N4 O20'
_chemical_formula_weight         1979.74
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   15.3422(4)
_cell_length_b                   15.6473(3)
_cell_length_c                   21.0007(5)
_cell_angle_alpha                98.4890(10)
_cell_angle_beta                 97.8940(10)
_cell_angle_gamma                111.6850(10)
_cell_volume                     4531.28(19)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    9977
_cell_measurement_temperature    170(2)
_cell_measurement_theta_max      26.03
_cell_measurement_theta_min      2.37
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    1.445
_exptl_absorpt_correction_T_max  0.7453
_exptl_absorpt_correction_T_min  0.6540
_exptl_absorpt_correction_type   none
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1271 before and 0.0515 after correction.
The Ratio of minimum to maximum transmission is 0.8775.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear whiteish white'
_exptl_crystal_density_diffrn    1.451
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             2024
_exptl_crystal_size_max          0.043
_exptl_crystal_size_mid          0.014
_exptl_crystal_size_min          0.006
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0471
_diffrn_reflns_av_unetI/netI     0.0561
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.993
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            51634
_diffrn_reflns_point_group_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.993
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.063
_diffrn_reflns_theta_min         2.221
_diffrn_ambient_temperature      170.0
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                13901
_reflns_number_total             17790
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.38A (?, 2016)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.38A (?, 2016)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2014/7 (Sheldrick, 2015)'
_computing_structure_solution    'olex2.solve 1.3 (Bourhis et al., 2015)'
_refine_diff_density_max         1.886
_refine_diff_density_min         -1.168
_refine_diff_density_rms         0.106
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.057
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1152
_refine_ls_number_reflns         17790
_refine_ls_number_restraints     12
_refine_ls_R_factor_all          0.0584
_refine_ls_R_factor_gt           0.0380
_refine_ls_restrained_S_all      1.069
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0193P)²+9.4484P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0723
_refine_ls_wR_factor_ref         0.0829
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups, All O(H,H) groups
2. Uiso/Uaniso restraints and constraints
Uanis(C91) \\sim Ueq: with sigma of 0.005 and sigma for terminal atoms of 0.01
Uanis(N031) \\sim Ueq: with sigma of 0.005 and sigma for terminal atoms of 0.01
3.a Free rotating group:
 O17(H17a,H17b), O16(H16a,H16b)
3.b Rotating group:
 O11(H11a,H11b), O10(H10a,H10b)
3.c Aromatic/amide H refined with riding coordinates:
 C3(H3), C39(H39), C7(H7), C71(H71), C4(H4), C65(H65), C40(H40), C42(H42),
 C43(H43), C32(H32), C72(H72), C68(H68), C36(H36), C67(H67), C26(H26), C64(H64),
  C6(H6), C25(H25), C35(H35), C84(H84), C80(H80), C33(H33), C15(H15), C61(H61),
 C74(H74), C22(H22), C78(H78), C77(H77), C75(H75), C83(H83), C21(H21), C62(H62),
  C51(H51), C81(H81), C76(H76), C45(H45), C49(H49), C55(H55), C16(H16),
 C53(H53), C9(H9), C48(H48), C54(H54), C47(H47), C46(H46), C13(H13), C82(H82),
 C52(H52), C19(H19), C10(H10), C17(H17), C18(H18), C12(H12), C11(H11)
3.d Idealised Me refined as rotating group:
 C90(H90a,H90b,H90c), C89(H89a,H89b,H89c), C102(H10c,H10d,H10e), C97(H97a,H97b,
 H97c), C88(H88a,H88b,H88c), C93(H93a,H93b,H93c), C92(H92a,H92b,H92c),
 C101(H10f,H10g,H10h), C96(H96a,H96b,H96c), C94(H94a,H94b,H94c), C99(H99a,H99b,
 H99c), C103(H10i,H10j,H10k)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     iterative
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu01 Eu 0.34677(2) 0.35877(2) 0.46304(2) 0.01565(5) Uani 1 1 d . . . . .
Eu02 Eu -0.06623(2) 0.91115(2) 0.55768(2) 0.01527(5) Uani 1 1 d . . . . .
O4 O -0.00503(19) 1.07347(18) 0.56983(13) 0.0222(6) Uani 1 1 d . . . . .
O11 O 0.2682(2) 0.28797(19) 0.55237(13) 0.0254(6) Uani 1 1 d . . . . .
H11A H 0.2673 0.2308 0.5504 0.038 Uiso 1 1 d R U . . .
H11B H 0.2069 0.2785 0.5446 0.038 Uiso 1 1 d R U . . .
O14 O 0.90174(18) 0.04421(18) 0.43670(13) 0.0206(6) Uani 1 1 d . . . . .
O15 O 0.81708(19) -0.08576(18) 0.46883(13) 0.0215(6) Uani 1 1 d . . . . .
O8 O 0.41115(19) 0.48475(19) 0.55037(13) 0.0232(6) Uani 1 1 d . . . . .
O3 O 0.06022(19) 1.20251(18) 0.53310(13) 0.0226(6) Uani 1 1 d . . . . .
O10 O 0.46810(19) 0.33276(18) 0.53779(13) 0.0240(6) Uani 1 1 d . . . . .
H10A H 0.4862 0.2917 0.5162 0.036 Uiso 1 1 d R U . . .
H10B H 0.4424 0.3050 0.5682 0.036 Uiso 1 1 d R U . . .
O7 O -0.20066(19) 0.60589(19) 0.54126(13) 0.0241(6) Uani 1 1 d . . . . .
O2 O -0.28541(19) 1.63578(18) 0.65272(13) 0.0226(6) Uani 1 1 d . . . . .
O6 O -0.1332(2) 0.76027(18) 0.57515(13) 0.0233(6) Uani 1 1 d . . . . .
O9 O 0.52522(19) 0.62862(19) 0.59150(14) 0.0248(6) Uani 1 1 d . . . . .
O1 O -0.37858(19) 1.50120(18) 0.58439(13) 0.0230(6) Uani 1 1 d . . . . .
O12 O 0.31320(19) 0.19945(18) 0.42794(13) 0.0247(6) Uani 1 1 d . . . . .
O5 O 0.0039(2) 0.9444(2) 0.67118(13) 0.0326(7) Uani 1 1 d . . . . .
O13 O 0.18367(19) 0.06756(19) 0.38777(14) 0.0273(7) Uani 1 1 d . . . . .
C70 C -0.3188(3) 1.5468(3) 0.63775(19) 0.0210(9) Uani 1 1 d . . . . .
C37 C -0.1305(3) 0.6796(3) 0.57119(18) 0.0193(8) Uani 1 1 d . . . . .
C3 C 0.7540(3) 0.0140(3) 0.33382(19) 0.0223(9) Uani 1 1 d . . . . .
H3 H 0.8174 0.0495 0.3296 0.027 Uiso 1 1 calc R U . . .
C1 C 0.8251(3) -0.0259(3) 0.43280(18) 0.0193(8) Uani 1 1 d . . . . .
C59 C 0.0156(3) 1.1601(3) 0.57315(18) 0.0176(8) Uani 1 1 d . . . . .
C30 C 0.4438(3) 0.5661(3) 0.58735(17) 0.0179(8) Uani 1 1 d . . . . .
C2 C 0.7397(3) -0.0358(3) 0.38384(18) 0.0191(8) Uani 1 1 d . . . . .
C38 C -0.0428(3) 0.6739(3) 0.60912(18) 0.0187(8) Uani 1 1 d . . . . .
C39 C -0.0551(3) 0.6054(3) 0.64594(19) 0.0232(9) Uani 1 1 d . . . . .
H39 H -0.1166 0.5565 0.6409 0.028 Uiso 1 1 calc R U . . .
C7 C 0.6457(3) -0.0890(3) 0.38822(19) 0.0211(9) Uani 1 1 d . . . . .
H7 H 0.6344 -0.1253 0.4210 0.025 Uiso 1 1 calc R U . . .
C60 C -0.0143(3) 1.2133(3) 0.62465(17) 0.0180(8) Uani 1 1 d . . . . .
O19 O 0.4429(3) 0.7940(3) 0.46712(19) 0.0575(11) Uani 1 1 d . . . . .
C24 C 0.2714(3) 0.1178(3) 0.39353(18) 0.0184(8) Uani 1 1 d . . . . .
C23 C 0.3289(3) 0.0765(3) 0.35678(18) 0.0181(8) Uani 1 1 d . . . . .
C58 C 0.1980(3) 0.6717(3) 0.73896(19) 0.0204(9) Uani 1 1 d . . . . .
C71 C -0.2137(3) 1.5404(3) 0.73824(19) 0.0230(9) Uani 1 1 d . . . . .
H71 H -0.2024 1.6035 0.7572 0.028 Uiso 1 1 calc R U . . .
C85 C -0.0925(3) 1.3611(3) 0.83332(18) 0.0206(9) Uani 1 1 d . . . . .
C41 C 0.1140(3) 0.6737(3) 0.69453(18) 0.0201(9) Uani 1 1 d . . . . .
C4 C 0.6774(3) 0.0126(3) 0.29036(19) 0.0232(9) Uani 1 1 d . . . . .
H4 H 0.6886 0.0468 0.2564 0.028 Uiso 1 1 calc R U . . .
C65 C -0.0559(3) 1.1704(3) 0.67158(19) 0.0254(10) Uani 1 1 d . . . . .
H65 H -0.0641 1.1072 0.6716 0.030 Uiso 1 1 calc R U . . .
C66 C -0.1783(3) 1.4024(3) 0.74121(18) 0.0208(9) Uani 1 1 d . . . . .
C69 C -0.2805(3) 1.4941(3) 0.67982(19) 0.0207(9) Uani 1 1 d . . . . .
C40 C 0.0220(3) 0.6081(3) 0.6900(2) 0.0230(9) Uani 1 1 d . . . . .
H40 H 0.0117 0.5640 0.7177 0.028 Uiso 1 1 calc R U . . .
C56 C 0.2130(3) 0.6935(3) 0.80494(19) 0.0233(9) Uani 1 1 d . . . . .
C86 C -0.1149(3) 1.3581(3) 0.76844(19) 0.0223(9) Uani 1 1 d . . . . .
N017 N 0.0137(3) 1.0106(3) 0.77471(19) 0.0446(11) Uani 1 1 d . . . . .
C5 C 0.5834(3) -0.0383(3) 0.29563(19) 0.0208(9) Uani 1 1 d . . . . .
C42 C 0.1263(3) 0.7378(3) 0.6540(2) 0.0282(10) Uani 1 1 d . . . . .
H42 H 0.1892 0.7806 0.6541 0.034 Uiso 1 1 calc R U . . .
C43 C 0.0490(3) 0.7407(3) 0.6137(2) 0.0251(9) Uani 1 1 d . . . . .
H43 H 0.0586 0.7884 0.5890 0.030 Uiso 1 1 calc R U . . .
C32 C 0.2844(3) 0.5321(3) 0.6192(2) 0.0243(9) Uani 1 1 d . . . . .
H32 H 0.2584 0.4739 0.5879 0.029 Uiso 1 1 calc R U . . .
C63 C -0.0776(3) 1.3095(3) 0.71879(18) 0.0185(8) Uani 1 1 d . . . . .
C31 C 0.3802(3) 0.5897(3) 0.62877(18) 0.0184(8) Uani 1 1 d . . . . .
C72 C -0.1633(3) 1.4949(3) 0.76905(19) 0.0224(9) Uani 1 1 d . . . . .
H72 H -0.1183 1.5269 0.8094 0.027 Uiso 1 1 calc R U . . .
C29 C 0.4854(3) -0.0546(3) 0.1851(2) 0.0253(9) Uani 1 1 d . . . . .
C68 C -0.3011(3) 1.3998(3) 0.6551(2) 0.0246(9) Uani 1 1 d . . . . .
H68 H -0.3508 1.3660 0.6173 0.030 Uiso 1 1 calc R U . . .
C79 C -0.0145(3) 1.3351(3) 0.86224(18) 0.0250(10) Uani 1 1 d . . . . .
C36 C 0.4174(3) 0.6742(3) 0.67499(19) 0.0230(9) Uani 1 1 d . . . . .
H36 H 0.4832 0.7146 0.6813 0.028 Uiso 1 1 calc R U . . .
C67 C -0.2500(3) 1.3549(3) 0.68484(19) 0.0247(9) Uani 1 1 d . . . . .
H67 H -0.2638 1.2908 0.6667 0.030 Uiso 1 1 calc R U . . .
C26 C 0.4814(3) 0.0806(3) 0.33821(19) 0.0225(9) Uani 1 1 d . . . . .
H26 H 0.5494 0.1099 0.3497 0.027 Uiso 1 1 calc R U . . .
C34 C 0.2634(3) 0.6429(3) 0.70218(18) 0.0193(8) Uani 1 1 d . . . . .
C28 C 0.4996(3) -0.0347(3) 0.25170(19) 0.0213(9) Uani 1 1 d . . . . .
C64 C -0.0861(3) 1.2180(3) 0.7190(2) 0.0278(10) Uani 1 1 d . . . . .
H64 H -0.1129 1.1877 0.7519 0.033 Uiso 1 1 calc R U . . .
C6 C 0.5695(3) -0.0890(3) 0.34518(19) 0.0239(9) Uani 1 1 d . . . . .
H6 H 0.5061 -0.1245 0.3494 0.029 Uiso 1 1 calc R U . . .
C27 C 0.4375(3) -0.0002(3) 0.28825(19) 0.0206(9) Uani 1 1 d . . . . .
C73 C -0.1461(3) 1.3911(3) 0.88062(18) 0.0231(9) Uani 1 1 d . . . . .
C25 C 0.4282(3) 0.1192(3) 0.37151(19) 0.0224(9) Uani 1 1 d . . . . .
H25 H 0.4599 0.1754 0.4046 0.027 Uiso 1 1 calc R U . . .
C35 C 0.3597(3) 0.7001(3) 0.7119(2) 0.0251(9) Uani 1 1 d . . . . .
H35 H 0.3863 0.7574 0.7441 0.030 Uiso 1 1 calc R U . . .
C84 C 0.0764(3) 1.3735(3) 0.8486(2) 0.0317(11) Uani 1 1 d . . . . .
H84 H 0.0885 1.4169 0.8203 0.038 Uiso 1 1 calc R U . . .
C50 C 0.1506(3) 0.7305(3) 0.83882(19) 0.0260(10) Uani 1 1 d . . . . .
C80 C -0.0300(4) 1.2727(3) 0.9046(2) 0.0348(11) Uani 1 1 d . . . . .
H80 H -0.0911 1.2469 0.9156 0.042 Uiso 1 1 calc R U . . .
C33 C 0.2262(3) 0.5591(3) 0.6551(2) 0.0251(9) Uani 1 1 d . . . . .
H33 H 0.1599 0.5198 0.6475 0.030 Uiso 1 1 calc R U . . .
O18 O 0.3684(4) 0.3768(4) 0.8342(2) 0.0918(16) Uani 1 1 d . . . . .
O01Z O 0.8072(3) 0.8152(3) 0.8763(2) 0.0649(12) Uani 1 1 d . . . . .
C15 C 0.3470(3) -0.1237(4) 0.0902(2) 0.0381(12) Uani 1 1 d . . . . .
H15 H 0.3625 -0.1773 0.0831 0.046 Uiso 1 1 calc R U . . .
C57 C 0.2920(3) 0.6848(3) 0.8499(2) 0.0304(10) Uani 1 1 d . . . . .
C8 C 0.5505(3) -0.0829(3) 0.1487(2) 0.0324(11) Uani 1 1 d . . . . .
C61 C -0.0049(3) 1.3046(3) 0.6242(2) 0.0292(10) Uani 1 1 d . . . . .
H61 H 0.0243 1.3355 0.5923 0.035 Uiso 1 1 calc R U . . .
C14 C 0.4045(3) -0.0476(3) 0.1407(2) 0.0335(11) Uani 1 1 d . . . . .
C74 C -0.2450(3) 1.3458(3) 0.8718(2) 0.0318(11) Uani 1 1 d . . . . .
H74 H -0.2799 1.2957 0.8348 0.038 Uiso 1 1 calc R U . . .
C22 C 0.2854(3) -0.0047(3) 0.3077(2) 0.0363(12) Uani 1 1 d . . . . .
H22 H 0.2174 -0.0346 0.2967 0.044 Uiso 1 1 calc R U . . .
C78 C -0.0965(4) 1.4654(3) 0.9350(2) 0.0328(11) Uani 1 1 d . . . . .
H78 H -0.0288 1.4973 0.9418 0.039 Uiso 1 1 calc R U . . .
C87 C -0.0228(4) 0.9392(4) 0.7246(2) 0.0422(13) Uani 1 1 d . . . . .
C77 C -0.1456(4) 1.4924(4) 0.9787(2) 0.0445(13) Uani 1 1 d . . . . .
H77 H -0.1114 1.5432 1.0154 0.053 Uiso 1 1 calc R U . . .
C75 C -0.2930(4) 1.3730(4) 0.9168(2) 0.0382(12) Uani 1 1 d . . . . .
H75 H -0.3605 1.3407 0.9109 0.046 Uiso 1 1 calc R U . . .
C83 C 0.1500(4) 1.3496(4) 0.8755(2) 0.0452(14) Uani 1 1 d . . . . .
H83 H 0.2119 1.3769 0.8661 0.054 Uiso 1 1 calc R U . . .
C21 C 0.3381(3) -0.0433(3) 0.2742(2) 0.0368(12) Uani 1 1 d . . . . .
H21 H 0.3061 -0.0998 0.2414 0.044 Uiso 1 1 calc R U . . .
N02D N 0.4481(4) 0.3732(4) 0.7526(2) 0.0662(15) Uani 1 1 d . . . . .
C62 C -0.0377(3) 1.3512(3) 0.6701(2) 0.0306(10) Uani 1 1 d . . . . .
H62 H -0.0327 1.4131 0.6682 0.037 Uiso 1 1 calc R U . . .
C51 C 0.1499(4) 0.8169(4) 0.8335(2) 0.0467(14) Uani 1 1 d . . . . .
H51 H 0.1879 0.8522 0.8068 0.056 Uiso 1 1 calc R U . . .
C81 C 0.0436(5) 1.2479(4) 0.9309(2) 0.0487(15) Uani 1 1 d . . . . .
H81 H 0.0322 1.2046 0.9592 0.058 Uiso 1 1 calc R U . . .
C90 C 0.0924(4) 1.0954(4) 0.7690(3) 0.0533(15) Uani 1 1 d . . . . .
H90A H 0.1506 1.1053 0.8003 0.080 Uiso 1 1 calc R U . . .
H90B H 0.0755 1.1499 0.7788 0.080 Uiso 1 1 calc R U . . .
H90C H 0.1038 1.0880 0.7242 0.080 Uiso 1 1 calc R U . . .
C76 C -0.2433(4) 1.4467(4) 0.9699(2) 0.0455(14) Uani 1 1 d . . . . .
H76 H -0.2764 1.4659 1.0004 0.055 Uiso 1 1 calc R U . . .
C45 C 0.3112(4) 0.6044(4) 0.8424(2) 0.0374(11) Uani 1 1 d . . . . .
H45 H 0.2731 0.5521 0.8074 0.045 Uiso 1 1 calc R U . . .
C49 C 0.3480(4) 0.7591(4) 0.9028(2) 0.0462(13) Uani 1 1 d . . . . .
H49 H 0.3349 0.8142 0.9098 0.055 Uiso 1 1 calc R U . . .
C55 C 0.0958(4) 0.6808(4) 0.8785(2) 0.0407(12) Uani 1 1 d . . . . .
H55 H 0.0978 0.6224 0.8843 0.049 Uiso 1 1 calc R U . . .
C16 C 0.2678(4) -0.1242(5) 0.0499(3) 0.0593(17) Uani 1 1 d . . . . .
H16 H 0.2291 -0.1778 0.0160 0.071 Uiso 1 1 calc R U . . .
C89 C -0.0224(5) 1.0143(4) 0.8365(2) 0.0618(18) Uani 1 1 d . . . . .
H89A H -0.0578 1.0552 0.8374 0.093 Uiso 1 1 calc R U . . .
H89B H 0.0319 1.0396 0.8742 0.093 Uiso 1 1 calc R U . . .
H89C H -0.0650 0.9508 0.8386 0.093 Uiso 1 1 calc R U . . .
C53 C 0.0381(4) 0.8020(4) 0.9040(3) 0.0526(15) Uani 1 1 d . . . . .
H53 H -0.0010 0.8262 0.9258 0.063 Uiso 1 1 calc R U . . .
C9 C 0.5762(4) -0.1550(4) 0.1599(3) 0.0478(14) Uani 1 1 d . . . . .
H9 H 0.5530 -0.1888 0.1922 0.057 Uiso 1 1 calc R U . . .
N02Q N 0.6704(4) 0.7146(4) 0.8099(3) 0.0713(16) Uani 1 1 d . . . . .
C102 C 0.4544(5) 0.3636(5) 0.6837(3) 0.0713(19) Uani 1 1 d . . . . .
H10C H 0.3923 0.3527 0.6567 0.107 Uiso 1 1 calc R U . . .
H10D H 0.4716 0.3102 0.6703 0.107 Uiso 1 1 calc R U . . .
H10E H 0.5036 0.4214 0.6775 0.107 Uiso 1 1 calc R U . . .
C48 C 0.4225(4) 0.7538(5) 0.9451(3) 0.0649(18) Uani 1 1 d . . . . .
H48 H 0.4607 0.8055 0.9805 0.078 Uiso 1 1 calc R U . . .
C54 C 0.0377(4) 0.7155(4) 0.9102(2) 0.0499(14) Uani 1 1 d . . . . .
H54 H -0.0019 0.6796 0.9359 0.060 Uiso 1 1 calc R U . . .
C47 C 0.4415(4) 0.6745(5) 0.9364(3) 0.0657(19) Uani 1 1 d . . . . .
H47 H 0.4929 0.6712 0.9653 0.079 Uiso 1 1 calc R U . . .
C97 C 0.6706(5) 0.7804(5) 0.7683(3) 0.071(2) Uani 1 1 d . . . . .
H97A H 0.7272 0.8394 0.7856 0.107 Uiso 1 1 calc R U . . .
H97B H 0.6125 0.7930 0.7677 0.107 Uiso 1 1 calc R U . . .
H97C H 0.6721 0.7535 0.7235 0.107 Uiso 1 1 calc R U . . .
C46 C 0.3855(4) 0.5996(5) 0.8853(3) 0.0544(15) Uani 1 1 d . . . . .
H46 H 0.3979 0.5441 0.8795 0.065 Uiso 1 1 calc R U . . .
C100 C 0.3694(5) 0.3682(5) 0.7746(3) 0.0634(17) Uani 1 1 d . . . . .
C13 C 0.5852(4) -0.0360(4) 0.1002(3) 0.0523(15) Uani 1 1 d . . . . .
H13 H 0.5659 0.0126 0.0905 0.063 Uiso 1 1 calc R U . . .
C88 C -0.0969(5) 0.8480(4) 0.7324(3) 0.080(2) Uani 1 1 d . . . . .
H88A H -0.1611 0.8429 0.7135 0.120 Uiso 1 1 calc R U . . .
H88B H -0.0920 0.8468 0.7793 0.120 Uiso 1 1 calc R U . . .
H88C H -0.0857 0.7949 0.7095 0.120 Uiso 1 1 calc R U . . .
C82 C 0.1325(4) 1.2863(4) 0.9159(2) 0.0506(16) Uani 1 1 d . . . . .
H82 H 0.1823 1.2689 0.9337 0.061 Uiso 1 1 calc R U . . .
N031 N 0.3171(5) 0.8219(6) 0.4837(3) 0.111(2) Uani 1 1 d . U . . .
C52 C 0.0945(4) 0.8531(4) 0.8666(3) 0.0576(16) Uani 1 1 d . . . . .
H52 H 0.0959 0.9134 0.8633 0.069 Uiso 1 1 calc R U . . .
C19 C 0.3845(5) 0.0315(5) 0.1469(3) 0.0656(19) Uani 1 1 d . . . . .
H19 H 0.4254 0.0867 0.1789 0.079 Uiso 1 1 calc R U . . .
C10 C 0.6380(4) -0.1792(5) 0.1229(3) 0.0613(17) Uani 1 1 d . . . . .
H10 H 0.6555 -0.2297 0.1302 0.074 Uiso 1 1 calc R U . . .
C17 C 0.2454(5) -0.0478(6) 0.0590(3) 0.078(2) Uani 1 1 d . . . . .
H17 H 0.1892 -0.0489 0.0328 0.094 Uiso 1 1 calc R U . . .
C95 C 0.7405(5) 0.7370(5) 0.8617(3) 0.0643(17) Uani 1 1 d . . . . .
C93 C 0.2284(5) 0.8189(6) 0.5002(3) 0.083(2) Uani 1 1 d . . . . .
H93A H 0.1801 0.7541 0.4869 0.125 Uiso 1 1 calc R U . . .
H93B H 0.2062 0.8596 0.4772 0.125 Uiso 1 1 calc R U . . .
H93C H 0.2382 0.8410 0.5478 0.125 Uiso 1 1 calc R U . . .
C92 C 0.3059(6) 0.6928(5) 0.5133(3) 0.083(2) Uani 1 1 d . . . . .
H92A H 0.3426 0.6533 0.5149 0.124 Uiso 1 1 calc R U . . .
H92B H 0.2421 0.6560 0.4853 0.124 Uiso 1 1 calc R U . . .
H92C H 0.2993 0.7147 0.5579 0.124 Uiso 1 1 calc R U . . .
C101 C 0.2807(5) 0.3477(6) 0.7245(3) 0.090(2) Uani 1 1 d . . . . .
H10F H 0.2627 0.2865 0.6949 0.134 Uiso 1 1 calc R U . . .
H10G H 0.2931 0.3970 0.6990 0.134 Uiso 1 1 calc R U . . .
H10H H 0.2283 0.3461 0.7469 0.134 Uiso 1 1 calc R U . . .
C18 C 0.3038(6) 0.0309(6) 0.1061(3) 0.090(3) Uani 1 1 d . . . . .
H18 H 0.2896 0.0854 0.1110 0.108 Uiso 1 1 calc R U . . .
C12 C 0.6471(5) -0.0587(6) 0.0659(3) 0.078(2) Uani 1 1 d . . . . .
H12 H 0.6725 -0.0244 0.0342 0.093 Uiso 1 1 calc R U . . .
C11 C 0.6712(5) -0.1310(6) 0.0781(3) 0.077(2) Uani 1 1 d . . . . .
H11 H 0.7128 -0.1476 0.0540 0.092 Uiso 1 1 calc R U . . .
C91 C 0.3620(7) 0.7838(6) 0.4830(4) 0.093(2) Uani 1 1 d . U . . .
C96 C 0.7380(6) 0.6637(5) 0.9029(3) 0.095(3) Uani 1 1 d . . . . .
H96A H 0.8006 0.6841 0.9325 0.142 Uiso 1 1 calc R U . . .
H96B H 0.7233 0.6030 0.8738 0.142 Uiso 1 1 calc R U . . .
H96C H 0.6884 0.6570 0.9290 0.142 Uiso 1 1 calc R U . . .
C94 C 0.3759(6) 0.9188(5) 0.4550(4) 0.099(3) Uani 1 1 d . . . . .
H94A H 0.3368 0.9181 0.4138 0.148 Uiso 1 1 calc R U . . .
H94B H 0.4373 0.9186 0.4471 0.148 Uiso 1 1 calc R U . . .
H94C H 0.3875 0.9756 0.4876 0.148 Uiso 1 1 calc R U . . .
C99 C 0.5881(5) 0.6228(6) 0.7913(4) 0.106(3) Uani 1 1 d . . . . .
H99A H 0.5312 0.6304 0.8027 0.159 Uiso 1 1 calc R U . . .
H99B H 0.6025 0.5785 0.8150 0.159 Uiso 1 1 calc R U . . .
H99C H 0.5760 0.5983 0.7437 0.159 Uiso 1 1 calc R U . . .
C103 C 0.5357(5) 0.3856(6) 0.7983(4) 0.106(3) Uani 1 1 d . . . . .
H10I H 0.5517 0.3309 0.7868 0.158 Uiso 1 1 calc R U . . .
H10J H 0.5250 0.3913 0.8434 0.158 Uiso 1 1 calc R U . . .
H10K H 0.5887 0.4427 0.7952 0.158 Uiso 1 1 calc R U . . .
O17 O 0.9040(4) 0.9255(3) 1.00004(19) 0.0730(13) Uani 1 1 d G . . . .
H17A H 0.8765 0.8867 0.9621 0.110 Uiso 1 1 d G U . . .
H17B H 0.9475 0.9739 0.9911 0.110 Uiso 1 1 d G U . . .
O16 O 0.4108(8) 0.4201(7) 0.9733(4) 0.263(6) Uani 1 1 d . . . . .
H16A H 0.4118 0.3733 0.9458 0.394 Uiso 1 1 d R U . . .
H16B H 0.4348 0.4145 1.0117 0.394 Uiso 1 1 d R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu01 O11 2.539(3) . ?
Eu01 O8 2.285(3) . ?
Eu01 O10 2.458(3) . ?
Eu01 O7 2.493(3) 2_566 ?
Eu01 O2 2.509(3) 2_576 ?
Eu01 O6 3.030(3) 2_566 ?
Eu01 O9 2.368(3) 2_666 ?
Eu01 O1 2.453(3) 2_576 ?
Eu01 O12 2.330(3) . ?
Eu01 C70 2.827(4) 2_576 ?
Eu01 C37 3.104(4) 2_566 ?
Eu02 Eu02 4.1105(4) 2_576 ?
Eu02 O4 3.037(3) 2_576 ?
Eu02 O4 2.319(3) . ?
Eu02 O14 2.337(3) 2_666 ?
Eu02 O15 2.421(3) 1_465 ?
Eu02 O3 2.444(2) 2_576 ?
Eu02 O6 2.309(3) . ?
Eu02 O5 2.372(3) . ?
Eu02 O13 2.360(3) 2_566 ?
Eu02 C59 3.118(4) 2_576 ?
O4 Eu02 3.037(3) 2_576 ?
O4 C59 1.262(4) . ?
O11 H11A 0.8838 . ?
O11 H11B 0.8834 . ?
O14 Eu02 2.337(3) 2_666 ?
O14 C1 1.260(4) . ?
O15 Eu02 2.421(3) 1_645 ?
O15 C1 1.270(4) . ?
O8 C30 1.266(4) . ?
O3 Eu02 2.444(2) 2_576 ?
O3 C59 1.266(4) . ?
O10 H10A 0.8809 . ?
O10 H10B 0.8814 . ?
O7 Eu01 2.493(3) 2_566 ?
O7 C37 1.251(5) . ?
O2 Eu01 2.509(3) 2_576 ?
O2 C70 1.265(4) . ?
O6 Eu01 3.030(3) 2_566 ?
O6 C37 1.270(4) . ?
O9 Eu01 2.368(3) 2_666 ?
O9 C30 1.252(5) . ?
O1 Eu01 2.453(3) 2_576 ?
O1 C70 1.267(5) . ?
O12 C24 1.250(4) . ?
O5 C87 1.250(6) . ?
O13 Eu02 2.360(3) 2_566 ?
O13 C24 1.261(5) . ?
C70 Eu01 2.827(4) 2_576 ?
C70 C69 1.495(5) . ?
C37 Eu01 3.104(4) 2_566 ?
C37 C38 1.505(5) . ?
C3 H3 0.9500 . ?
C3 C2 1.393(5) . ?
C3 C4 1.377(5) . ?
C1 C2 1.493(5) . ?
C59 Eu02 3.118(4) 2_576 ?
C59 C60 1.491(5) . ?
C30 C31 1.500(5) . ?
C2 C7 1.397(5) . ?
C38 C39 1.385(5) . ?
C38 C43 1.390(5) . ?
C39 H39 0.9500 . ?
C39 C40 1.381(6) . ?
C7 H7 0.9500 . ?
C7 C6 1.376(5) . ?
C60 C65 1.371(5) . ?
C60 C61 1.384(5) . ?
O19 C91 1.288(10) . ?
C24 C23 1.500(5) . ?
C23 C25 1.386(5) . ?
C23 C22 1.386(5) . ?
C58 C41 1.497(6) . ?
C58 C56 1.343(5) . ?
C58 C34 1.499(5) . ?
C71 H71 0.9500 . ?
C71 C69 1.387(5) . ?
C71 C72 1.389(6) . ?
C85 C86 1.348(5) . ?
C85 C79 1.483(6) . ?
C85 C73 1.502(5) . ?
C41 C40 1.385(5) . ?
C41 C42 1.386(6) . ?
C4 H4 0.9500 . ?
C4 C5 1.395(5) . ?
C65 H65 0.9500 . ?
C65 C64 1.387(5) . ?
C66 C86 1.489(6) . ?
C66 C72 1.399(5) . ?
C66 C67 1.393(5) . ?
C69 C68 1.390(5) . ?
C40 H40 0.9500 . ?
C56 C50 1.495(5) . ?
C56 C57 1.493(6) . ?
C86 C63 1.499(5) . ?
N017 C87 1.302(6) . ?
N017 C90 1.462(7) . ?
N017 C89 1.480(6) . ?
C5 C28 1.500(5) . ?
C5 C6 1.392(6) . ?
C42 H42 0.9500 . ?
C42 C43 1.378(6) . ?
C43 H43 0.9500 . ?
C32 H32 0.9500 . ?
C32 C31 1.378(5) . ?
C32 C33 1.384(6) . ?
C63 C64 1.389(5) . ?
C63 C62 1.386(6) . ?
C31 C36 1.388(5) . ?
C72 H72 0.9500 . ?
C29 C28 1.355(5) . ?
C29 C8 1.488(6) . ?
C29 C14 1.496(6) . ?
C68 H68 0.9500 . ?
C68 C67 1.379(6) . ?
C79 C84 1.389(6) . ?
C79 C80 1.395(6) . ?
C36 H36 0.9500 . ?
C36 C35 1.381(5) . ?
C67 H67 0.9500 . ?
C26 H26 0.9500 . ?
C26 C27 1.392(5) . ?
C26 C25 1.385(5) . ?
C34 C35 1.383(5) . ?
C34 C33 1.390(5) . ?
C28 C27 1.499(5) . ?
C64 H64 0.9500 . ?
C6 H6 0.9500 . ?
C27 C21 1.387(6) . ?
C73 C74 1.388(6) . ?
C73 C78 1.396(6) . ?
C25 H25 0.9500 . ?
C35 H35 0.9500 . ?
C84 H84 0.9500 . ?
C84 C83 1.391(6) . ?
C50 C51 1.376(6) . ?
C50 C55 1.381(6) . ?
C80 H80 0.9500 . ?
C80 C81 1.395(7) . ?
C33 H33 0.9500 . ?
O18 C100 1.241(7) . ?
O01Z C95 1.232(8) . ?
C15 H15 0.9500 . ?
C15 C14 1.384(6) . ?
C15 C16 1.379(7) . ?
C57 C45 1.385(6) . ?
C57 C49 1.394(6) . ?
C8 C9 1.365(7) . ?
C8 C13 1.394(7) . ?
C61 H61 0.9500 . ?
C61 C62 1.382(6) . ?
C14 C19 1.374(7) . ?
C74 H74 0.9500 . ?
C74 C75 1.386(6) . ?
C22 H22 0.9500 . ?
C22 C21 1.379(6) . ?
C78 H78 0.9500 . ?
C78 C77 1.379(6) . ?
C87 C88 1.509(8) . ?
C77 H77 0.9500 . ?
C77 C76 1.373(7) . ?
C75 H75 0.9500 . ?
C75 C76 1.376(7) . ?
C83 H83 0.9500 . ?
C83 C82 1.374(8) . ?
C21 H21 0.9500 . ?
N02D C102 1.453(7) . ?
N02D C100 1.332(8) . ?
N02D C103 1.471(8) . ?
C62 H62 0.9500 . ?
C51 H51 0.9500 . ?
C51 C52 1.389(7) . ?
C81 H81 0.9500 . ?
C81 C82 1.375(8) . ?
C90 H90A 0.9800 . ?
C90 H90B 0.9800 . ?
C90 H90C 0.9800 . ?
C76 H76 0.9500 . ?
C45 H45 0.9500 . ?
C45 C46 1.386(7) . ?
C49 H49 0.9500 . ?
C49 C48 1.384(7) . ?
C55 H55 0.9500 . ?
C55 C54 1.395(7) . ?
C16 H16 0.9500 . ?
C16 C17 1.355(9) . ?
C89 H89A 0.9800 . ?
C89 H89B 0.9800 . ?
C89 H89C 0.9800 . ?
C53 H53 0.9500 . ?
C53 C54 1.377(8) . ?
C53 C52 1.366(8) . ?
C9 H9 0.9500 . ?
C9 C10 1.423(7) . ?
N02Q C97 1.443(8) . ?
N02Q C95 1.323(8) . ?
N02Q C99 1.473(9) . ?
C102 H10C 0.9800 . ?
C102 H10D 0.9800 . ?
C102 H10E 0.9800 . ?
C48 H48 0.9500 . ?
C48 C47 1.368(9) . ?
C54 H54 0.9500 . ?
C47 H47 0.9500 . ?
C47 C46 1.376(8) . ?
C97 H97A 0.9800 . ?
C97 H97B 0.9800 . ?
C97 H97C 0.9800 . ?
C46 H46 0.9500 . ?
C100 C101 1.499(9) . ?
C13 H13 0.9500 . ?
C13 C12 1.382(8) . ?
C88 H88A 0.9800 . ?
C88 H88B 0.9800 . ?
C88 H88C 0.9800 . ?
C82 H82 0.9500 . ?
N031 C93 1.436(9) . ?
N031 C91 1.066(9) . ?
N031 C94 1.698(10) . ?
C52 H52 0.9500 . ?
C19 H19 0.9500 . ?
C19 C18 1.402(8) . ?
C10 H10 0.9500 . ?
C10 C11 1.330(9) . ?
C17 H17 0.9500 . ?
C17 C18 1.371(9) . ?
C95 C96 1.529(9) . ?
C93 H93A 0.9800 . ?
C93 H93B 0.9800 . ?
C93 H93C 0.9800 . ?
C92 H92A 0.9800 . ?
C92 H92B 0.9800 . ?
C92 H92C 0.9800 . ?
C92 C91 1.639(11) . ?
C101 H10F 0.9800 . ?
C101 H10G 0.9800 . ?
C101 H10H 0.9800 . ?
C18 H18 0.9500 . ?
C12 H12 0.9500 . ?
C12 C11 1.361(10) . ?
C11 H11 0.9500 . ?
C96 H96A 0.9800 . ?
C96 H96B 0.9800 . ?
C96 H96C 0.9800 . ?
C94 H94A 0.9800 . ?
C94 H94B 0.9800 . ?
C94 H94C 0.9800 . ?
C99 H99A 0.9800 . ?
C99 H99B 0.9800 . ?
C99 H99C 0.9800 . ?
C103 H10I 0.9800 . ?
C103 H10J 0.9800 . ?
C103 H10K 0.9800 . ?
O17 H17A 0.8700 . ?
O17 H17B 0.8700 . ?
O16 H16A 0.8695 . ?
O16 H16B 0.8702 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O11 Eu01 O6 63.48(8) . 2_566 ?
O11 Eu01 C70 141.30(10) . 2_576 ?
O11 Eu01 C37 71.69(9) . 2_566 ?
O8 Eu01 O11 78.55(9) . . ?
O8 Eu01 O10 72.60(9) . . ?
O8 Eu01 O7 84.01(9) . 2_566 ?
O8 Eu01 O2 125.32(9) . 2_576 ?
O8 Eu01 O6 121.73(8) . 2_566 ?
O8 Eu01 O9 104.27(10) . 2_666 ?
O8 Eu01 O1 74.18(9) . 2_576 ?
O8 Eu01 O12 145.19(10) . . ?
O8 Eu01 C70 98.98(11) . 2_576 ?
O8 Eu01 C37 105.02(10) . 2_566 ?
O10 Eu01 O11 72.46(9) . . ?
O10 Eu01 O7 142.86(9) . 2_566 ?
O10 Eu01 O2 146.54(9) . 2_576 ?
O10 Eu01 O6 127.35(8) . 2_566 ?
O10 Eu01 C70 144.28(10) . 2_576 ?
O10 Eu01 C37 143.76(10) . 2_566 ?
O7 Eu01 O11 74.94(9) 2_566 . ?
O7 Eu01 O2 70.58(9) 2_566 2_576 ?
O7 Eu01 O6 45.77(8) 2_566 2_566 ?
O7 Eu01 C70 66.42(10) 2_566 2_576 ?
O7 Eu01 C37 22.64(9) 2_566 2_566 ?
O2 Eu01 O11 134.28(9) 2_576 . ?
O2 Eu01 O6 71.00(8) 2_576 2_566 ?
O2 Eu01 C70 26.57(9) 2_576 2_576 ?
O2 Eu01 C37 64.86(9) 2_576 2_566 ?
O6 Eu01 C37 23.85(8) 2_566 2_566 ?
O9 Eu01 O11 142.68(9) 2_666 . ?
O9 Eu01 O10 73.09(10) 2_666 . ?
O9 Eu01 O7 142.14(9) 2_666 2_566 ?
O9 Eu01 O2 74.86(9) 2_666 2_576 ?
O9 Eu01 O6 132.92(8) 2_666 2_566 ?
O9 Eu01 O1 73.49(9) 2_666 2_576 ?
O9 Eu01 C70 75.76(10) 2_666 2_576 ?
O9 Eu01 C37 138.96(10) 2_666 2_566 ?
O1 Eu01 O11 139.95(9) 2_576 . ?
O1 Eu01 O10 124.31(9) 2_576 . ?
O1 Eu01 O7 73.54(9) 2_576 2_566 ?
O1 Eu01 O2 52.72(8) 2_576 2_576 ?
O1 Eu01 O6 108.04(8) 2_576 2_566 ?
O1 Eu01 C70 26.57(10) 2_576 2_576 ?
O1 Eu01 C37 87.62(9) 2_576 2_566 ?
O12 Eu01 O11 77.72(9) . . ?
O12 Eu01 O10 76.17(9) . . ?
O12 Eu01 O7 113.59(9) . 2_566 ?
O12 Eu01 O2 89.40(9) . 2_576 ?
O12 Eu01 O6 67.84(8) . 2_566 ?
O12 Eu01 O9 80.55(9) . 2_666 ?
O12 Eu01 O1 138.22(9) . 2_576 ?
O12 Eu01 C70 115.43(11) . 2_576 ?
O12 Eu01 C37 91.22(10) . 2_566 ?
C70 Eu01 O6 87.06(9) 2_576 2_566 ?
C70 Eu01 C37 71.80(11) 2_576 2_566 ?
O4 Eu02 Eu02 33.82(5) 2_576 2_576 ?
O4 Eu02 Eu02 46.80(7) . 2_576 ?
O4 Eu02 O4 80.63(8) . 2_576 ?
O4 Eu02 O14 75.15(9) . 2_666 ?
O4 Eu02 O15 83.56(9) . 1_465 ?
O4 Eu02 O3 126.38(9) . 2_576 ?
O4 Eu02 O5 84.87(10) . . ?
O4 Eu02 O13 84.81(9) . 2_566 ?
O4 Eu02 C59 23.62(8) 2_576 2_576 ?
O4 Eu02 C59 103.99(10) . 2_576 ?
O14 Eu02 Eu02 60.87(6) 2_666 2_576 ?
O14 Eu02 O4 62.41(8) 2_666 2_576 ?
O14 Eu02 O15 127.19(9) 2_666 1_465 ?
O14 Eu02 O3 76.98(9) 2_666 2_576 ?
O14 Eu02 O5 74.31(9) 2_666 . ?
O14 Eu02 O13 144.99(9) 2_666 2_566 ?
O14 Eu02 C59 66.20(9) 2_666 2_576 ?
O15 Eu02 Eu02 69.24(6) 1_465 2_576 ?
O15 Eu02 O4 66.79(8) 1_465 2_576 ?
O15 Eu02 O3 78.23(9) 1_465 2_576 ?
O15 Eu02 C59 73.33(9) 1_465 2_576 ?
O3 Eu02 Eu02 79.61(6) 2_576 2_576 ?
O3 Eu02 O4 45.82(8) 2_576 2_576 ?
O3 Eu02 C59 22.40(9) 2_576 2_576 ?
O6 Eu02 Eu02 149.19(7) . 2_576 ?
O6 Eu02 O4 115.39(8) . 2_576 ?
O6 Eu02 O4 163.90(9) . . ?
O6 Eu02 O14 109.91(10) . 2_666 ?
O6 Eu02 O15 103.76(9) . 1_465 ?
O6 Eu02 O3 69.58(9) . 2_576 ?
O6 Eu02 O5 82.01(10) . . ?
O6 Eu02 O13 82.91(10) . 2_566 ?
O6 Eu02 C59 91.92(10) . 2_576 ?
O5 Eu02 Eu02 119.07(7) . 2_576 ?
O5 Eu02 O4 136.54(9) . 2_576 ?
O5 Eu02 O15 151.27(10) . 1_465 ?
O5 Eu02 O3 129.12(10) . 2_576 ?
O5 Eu02 C59 135.17(10) . 2_576 ?
O13 Eu02 Eu02 122.29(7) 2_566 2_576 ?
O13 Eu02 O4 142.37(9) 2_566 2_576 ?
O13 Eu02 O15 77.26(9) 2_566 1_465 ?
O13 Eu02 O3 137.17(9) 2_566 2_576 ?
O13 Eu02 O5 75.56(10) 2_566 . ?
O13 Eu02 C59 147.97(10) 2_566 2_576 ?
C59 Eu02 Eu02 57.28(7) 2_576 2_576 ?
Eu02 O4 Eu02 99.37(8) . 2_576 ?
C59 O4 Eu02 171.4(3) . . ?
C59 O4 Eu02 81.8(2) . 2_576 ?
Eu01 O11 H11A 109.9 . . ?
Eu01 O11 H11B 110.1 . . ?
H11A O11 H11B 103.9 . . ?
C1 O14 Eu02 142.7(3) . 2_666 ?
C1 O15 Eu02 129.7(2) . 1_645 ?
C30 O8 Eu01 165.1(3) . . ?
C59 O3 Eu02 110.2(2) . 2_576 ?
Eu01 O10 H10A 109.6 . . ?
Eu01 O10 H10B 110.1 . . ?
H10A O10 H10B 103.9 . . ?
C37 O7 Eu01 107.3(2) . 2_566 ?
C70 O2 Eu01 90.9(2) . 2_576 ?
Eu02 O6 Eu01 122.67(10) . 2_566 ?
C37 O6 Eu01 81.3(2) . 2_566 ?
C37 O6 Eu02 148.2(3) . . ?
C30 O9 Eu01 134.6(2) . 2_666 ?
C70 O1 Eu01 93.4(2) . 2_576 ?
C24 O12 Eu01 157.8(3) . . ?
C87 O5 Eu02 138.3(3) . . ?
C24 O13 Eu02 131.9(2) . 2_566 ?
O2 C70 Eu01 62.6(2) . 2_576 ?
O2 C70 O1 121.1(4) . . ?
O2 C70 C69 120.0(3) . . ?
O1 C70 Eu01 60.0(2) . 2_576 ?
O1 C70 C69 118.6(3) . . ?
C69 C70 Eu01 162.0(3) . 2_576 ?
O7 C37 Eu01 50.08(19) . 2_566 ?
O7 C37 O6 121.9(4) . . ?
O7 C37 C38 120.2(3) . . ?
O6 C37 Eu01 74.8(2) . 2_566 ?
O6 C37 C38 117.7(3) . . ?
C38 C37 Eu01 155.0(3) . 2_566 ?
C2 C3 H3 119.5 . . ?
C4 C3 H3 119.5 . . ?
C4 C3 C2 120.9(4) . . ?
O14 C1 O15 123.6(4) . . ?
O14 C1 C2 116.7(3) . . ?
O15 C1 C2 119.7(3) . . ?
O4 C59 Eu02 74.6(2) . 2_576 ?
O4 C59 O3 121.2(3) . . ?
O4 C59 C60 119.4(3) . . ?
O3 C59 Eu02 47.36(17) . 2_576 ?
O3 C59 C60 119.5(3) . . ?
C60 C59 Eu02 163.5(3) . 2_576 ?
O8 C30 C31 117.8(3) . . ?
O9 C30 O8 124.7(4) . . ?
O9 C30 C31 117.5(3) . . ?
C3 C2 C1 118.7(3) . . ?
C3 C2 C7 118.5(4) . . ?
C7 C2 C1 122.7(3) . . ?
C39 C38 C37 118.6(3) . . ?
C39 C38 C43 118.9(4) . . ?
C43 C38 C37 122.2(4) . . ?
C38 C39 H39 120.0 . . ?
C40 C39 C38 120.1(4) . . ?
C40 C39 H39 120.0 . . ?
C2 C7 H7 119.9 . . ?
C6 C7 C2 120.2(4) . . ?
C6 C7 H7 119.9 . . ?
C65 C60 C59 120.1(3) . . ?
C65 C60 C61 118.9(3) . . ?
C61 C60 C59 120.9(3) . . ?
O12 C24 O13 124.0(4) . . ?
O12 C24 C23 118.2(3) . . ?
O13 C24 C23 117.7(3) . . ?
C25 C23 C24 120.2(3) . . ?
C22 C23 C24 121.8(3) . . ?
C22 C23 C25 118.0(4) . . ?
C41 C58 C34 113.0(3) . . ?
C56 C58 C41 123.2(4) . . ?
C56 C58 C34 123.7(4) . . ?
C69 C71 H71 119.9 . . ?
C69 C71 C72 120.3(4) . . ?
C72 C71 H71 119.9 . . ?
C86 C85 C79 122.5(4) . . ?
C86 C85 C73 121.3(4) . . ?
C79 C85 C73 116.1(3) . . ?
C40 C41 C58 120.9(4) . . ?
C40 C41 C42 117.9(4) . . ?
C42 C41 C58 121.1(4) . . ?
C3 C4 H4 119.6 . . ?
C3 C4 C5 120.8(4) . . ?
C5 C4 H4 119.6 . . ?
C60 C65 H65 119.5 . . ?
C60 C65 C64 121.0(4) . . ?
C64 C65 H65 119.5 . . ?
C72 C66 C86 120.8(3) . . ?
C67 C66 C86 120.7(3) . . ?
C67 C66 C72 118.4(4) . . ?
C71 C69 C70 121.2(4) . . ?
C71 C69 C68 119.1(4) . . ?
C68 C69 C70 119.0(3) . . ?
C39 C40 C41 121.3(4) . . ?
C39 C40 H40 119.3 . . ?
C41 C40 H40 119.3 . . ?
C58 C56 C50 121.2(4) . . ?
C58 C56 C57 123.9(4) . . ?
C57 C56 C50 114.8(3) . . ?
C85 C86 C66 122.5(4) . . ?
C85 C86 C63 122.0(4) . . ?
C66 C86 C63 115.5(3) . . ?
C87 N017 C90 118.5(4) . . ?
C87 N017 C89 124.5(5) . . ?
C90 N017 C89 116.8(4) . . ?
C4 C5 C28 121.2(4) . . ?
C6 C5 C4 118.0(4) . . ?
C6 C5 C28 120.7(4) . . ?
C41 C42 H42 119.3 . . ?
C43 C42 C41 121.3(4) . . ?
C43 C42 H42 119.3 . . ?
C38 C43 H43 119.9 . . ?
C42 C43 C38 120.1(4) . . ?
C42 C43 H43 119.9 . . ?
C31 C32 H32 120.0 . . ?
C31 C32 C33 119.9(4) . . ?
C33 C32 H32 120.0 . . ?
C64 C63 C86 119.9(3) . . ?
C62 C63 C86 122.2(4) . . ?
C62 C63 C64 117.8(4) . . ?
C32 C31 C30 121.4(3) . . ?
C32 C31 C36 119.4(4) . . ?
C36 C31 C30 119.1(3) . . ?
C71 C72 C66 120.5(4) . . ?
C71 C72 H72 119.7 . . ?
C66 C72 H72 119.7 . . ?
C28 C29 C8 123.4(4) . . ?
C28 C29 C14 123.6(4) . . ?
C8 C29 C14 113.0(4) . . ?
C69 C68 H68 119.7 . . ?
C67 C68 C69 120.6(4) . . ?
C67 C68 H68 119.7 . . ?
C84 C79 C85 120.8(4) . . ?
C84 C79 C80 118.3(4) . . ?
C80 C79 C85 120.9(4) . . ?
C31 C36 H36 119.7 . . ?
C35 C36 C31 120.6(4) . . ?
C35 C36 H36 119.7 . . ?
C66 C67 H67 119.7 . . ?
C68 C67 C66 120.7(4) . . ?
C68 C67 H67 119.7 . . ?
C27 C26 H26 119.3 . . ?
C25 C26 H26 119.3 . . ?
C25 C26 C27 121.5(4) . . ?
C35 C34 C58 121.4(3) . . ?
C35 C34 C33 118.8(4) . . ?
C33 C34 C58 119.8(4) . . ?
C29 C28 C5 122.9(4) . . ?
C29 C28 C27 123.2(4) . . ?
C27 C28 C5 113.7(3) . . ?
C65 C64 C63 120.7(4) . . ?
C65 C64 H64 119.7 . . ?
C63 C64 H64 119.7 . . ?
C7 C6 C5 121.5(4) . . ?
C7 C6 H6 119.3 . . ?
C5 C6 H6 119.3 . . ?
C26 C27 C28 118.5(4) . . ?
C21 C27 C26 117.9(4) . . ?
C21 C27 C28 123.7(4) . . ?
C74 C73 C85 121.2(4) . . ?
C74 C73 C78 118.7(4) . . ?
C78 C73 C85 120.1(4) . . ?
C23 C25 H25 119.8 . . ?
C26 C25 C23 120.4(4) . . ?
C26 C25 H25 119.8 . . ?
C36 C35 C34 120.3(4) . . ?
C36 C35 H35 119.8 . . ?
C34 C35 H35 119.8 . . ?
C79 C84 H84 119.4 . . ?
C79 C84 C83 121.1(5) . . ?
C83 C84 H84 119.4 . . ?
C51 C50 C56 120.6(4) . . ?
C51 C50 C55 118.7(4) . . ?
C55 C50 C56 120.7(4) . . ?
C79 C80 H80 119.8 . . ?
C81 C80 C79 120.4(5) . . ?
C81 C80 H80 119.8 . . ?
C32 C33 C34 121.0(4) . . ?
C32 C33 H33 119.5 . . ?
C34 C33 H33 119.5 . . ?
C14 C15 H15 119.0 . . ?
C16 C15 H15 119.0 . . ?
C16 C15 C14 122.0(5) . . ?
C45 C57 C56 122.7(4) . . ?
C45 C57 C49 118.0(4) . . ?
C49 C57 C56 119.3(4) . . ?
C9 C8 C29 122.5(5) . . ?
C9 C8 C13 118.2(5) . . ?
C13 C8 C29 119.3(4) . . ?
C60 C61 H61 119.9 . . ?
C62 C61 C60 120.3(4) . . ?
C62 C61 H61 119.9 . . ?
C15 C14 C29 119.0(4) . . ?
C19 C14 C29 123.2(4) . . ?
C19 C14 C15 117.8(5) . . ?
C73 C74 H74 119.8 . . ?
C75 C74 C73 120.5(4) . . ?
C75 C74 H74 119.8 . . ?
C23 C22 H22 119.1 . . ?
C21 C22 C23 121.9(4) . . ?
C21 C22 H22 119.1 . . ?
C73 C78 H78 120.0 . . ?
C77 C78 C73 120.0(5) . . ?
C77 C78 H78 120.0 . . ?
O5 C87 N017 121.3(5) . . ?
O5 C87 C88 119.8(4) . . ?
N017 C87 C88 118.9(5) . . ?
C78 C77 H77 119.5 . . ?
C76 C77 C78 120.9(5) . . ?
C76 C77 H77 119.5 . . ?
C74 C75 H75 119.9 . . ?
C76 C75 C74 120.3(5) . . ?
C76 C75 H75 119.9 . . ?
C84 C83 H83 120.2 . . ?
C82 C83 C84 119.6(5) . . ?
C82 C83 H83 120.2 . . ?
C27 C21 H21 119.8 . . ?
C22 C21 C27 120.4(4) . . ?
C22 C21 H21 119.8 . . ?
C102 N02D C103 115.0(6) . . ?
C100 N02D C102 124.4(5) . . ?
C100 N02D C103 120.5(6) . . ?
C63 C62 H62 119.3 . . ?
C61 C62 C63 121.3(4) . . ?
C61 C62 H62 119.3 . . ?
C50 C51 H51 119.6 . . ?
C50 C51 C52 120.9(5) . . ?
C52 C51 H51 119.6 . . ?
C80 C81 H81 120.0 . . ?
C82 C81 C80 120.0(5) . . ?
C82 C81 H81 120.0 . . ?
N017 C90 H90A 109.5 . . ?
N017 C90 H90B 109.5 . . ?
N017 C90 H90C 109.5 . . ?
H90A C90 H90B 109.5 . . ?
H90A C90 H90C 109.5 . . ?
H90B C90 H90C 109.5 . . ?
C77 C76 C75 119.6(4) . . ?
C77 C76 H76 120.2 . . ?
C75 C76 H76 120.2 . . ?
C57 C45 H45 119.7 . . ?
C57 C45 C46 120.7(5) . . ?
C46 C45 H45 119.7 . . ?
C57 C49 H49 119.6 . . ?
C48 C49 C57 120.8(5) . . ?
C48 C49 H49 119.6 . . ?
C50 C55 H55 119.7 . . ?
C50 C55 C54 120.6(5) . . ?
C54 C55 H55 119.7 . . ?
C15 C16 H16 120.2 . . ?
C17 C16 C15 119.6(6) . . ?
C17 C16 H16 120.2 . . ?
N017 C89 H89A 109.5 . . ?
N017 C89 H89B 109.5 . . ?
N017 C89 H89C 109.5 . . ?
H89A C89 H89B 109.5 . . ?
H89A C89 H89C 109.5 . . ?
H89B C89 H89C 109.5 . . ?
C54 C53 H53 120.0 . . ?
C52 C53 H53 120.0 . . ?
C52 C53 C54 120.1(5) . . ?
C8 C9 H9 120.1 . . ?
C8 C9 C10 119.8(6) . . ?
C10 C9 H9 120.1 . . ?
C97 N02Q C99 116.2(6) . . ?
C95 N02Q C97 121.1(6) . . ?
C95 N02Q C99 122.7(7) . . ?
N02D C102 H10C 109.5 . . ?
N02D C102 H10D 109.5 . . ?
N02D C102 H10E 109.5 . . ?
H10C C102 H10D 109.5 . . ?
H10C C102 H10E 109.5 . . ?
H10D C102 H10E 109.5 . . ?
C49 C48 H48 119.8 . . ?
C47 C48 C49 120.5(6) . . ?
C47 C48 H48 119.8 . . ?
C55 C54 H54 120.2 . . ?
C53 C54 C55 119.6(5) . . ?
C53 C54 H54 120.2 . . ?
C48 C47 H47 120.2 . . ?
C48 C47 C46 119.5(5) . . ?
C46 C47 H47 120.2 . . ?
N02Q C97 H97A 109.5 . . ?
N02Q C97 H97B 109.5 . . ?
N02Q C97 H97C 109.5 . . ?
H97A C97 H97B 109.5 . . ?
H97A C97 H97C 109.5 . . ?
H97B C97 H97C 109.5 . . ?
C45 C46 H46 119.7 . . ?
C47 C46 C45 120.5(6) . . ?
C47 C46 H46 119.7 . . ?
O18 C100 N02D 121.4(6) . . ?
O18 C100 C101 121.2(6) . . ?
N02D C100 C101 117.4(6) . . ?
C8 C13 H13 119.3 . . ?
C12 C13 C8 121.3(6) . . ?
C12 C13 H13 119.3 . . ?
C87 C88 H88A 109.5 . . ?
C87 C88 H88B 109.5 . . ?
C87 C88 H88C 109.5 . . ?
H88A C88 H88B 109.5 . . ?
H88A C88 H88C 109.5 . . ?
H88B C88 H88C 109.5 . . ?
C83 C82 C81 120.5(5) . . ?
C83 C82 H82 119.7 . . ?
C81 C82 H82 119.7 . . ?
C93 N031 C94 113.4(7) . . ?
C91 N031 C93 142.2(11) . . ?
C91 N031 C94 104.5(9) . . ?
C51 C52 H52 120.0 . . ?
C53 C52 C51 120.1(6) . . ?
C53 C52 H52 120.0 . . ?
C14 C19 H19 120.0 . . ?
C14 C19 C18 120.1(6) . . ?
C18 C19 H19 120.0 . . ?
C9 C10 H10 120.0 . . ?
C11 C10 C9 120.0(6) . . ?
C11 C10 H10 120.0 . . ?
C16 C17 H17 120.0 . . ?
C16 C17 C18 120.0(6) . . ?
C18 C17 H17 120.0 . . ?
O01Z C95 N02Q 120.8(7) . . ?
O01Z C95 C96 120.3(6) . . ?
N02Q C95 C96 118.9(7) . . ?
N031 C93 H93A 109.5 . . ?
N031 C93 H93B 109.5 . . ?
N031 C93 H93C 109.5 . . ?
H93A C93 H93B 109.5 . . ?
H93A C93 H93C 109.5 . . ?
H93B C93 H93C 109.5 . . ?
H92A C92 H92B 109.5 . . ?
H92A C92 H92C 109.5 . . ?
H92B C92 H92C 109.5 . . ?
C91 C92 H92A 109.5 . . ?
C91 C92 H92B 109.5 . . ?
C91 C92 H92C 109.5 . . ?
C100 C101 H10F 109.5 . . ?
C100 C101 H10G 109.5 . . ?
C100 C101 H10H 109.5 . . ?
H10F C101 H10G 109.5 . . ?
H10F C101 H10H 109.5 . . ?
H10G C101 H10H 109.5 . . ?
C19 C18 H18 119.8 . . ?
C17 C18 C19 120.3(6) . . ?
C17 C18 H18 119.8 . . ?
C13 C12 H12 120.6 . . ?
C11 C12 C13 118.9(6) . . ?
C11 C12 H12 120.6 . . ?
C10 C11 C12 121.8(6) . . ?
C10 C11 H11 119.1 . . ?
C12 C11 H11 119.1 . . ?
O19 C91 C92 119.5(7) . . ?
N031 C91 O19 136.9(11) . . ?
N031 C91 C92 103.6(10) . . ?
C95 C96 H96A 109.5 . . ?
C95 C96 H96B 109.5 . . ?
C95 C96 H96C 109.5 . . ?
H96A C96 H96B 109.5 . . ?
H96A C96 H96C 109.5 . . ?
H96B C96 H96C 109.5 . . ?
N031 C94 H94A 109.5 . . ?
N031 C94 H94B 109.5 . . ?
N031 C94 H94C 109.5 . . ?
H94A C94 H94B 109.5 . . ?
H94A C94 H94C 109.5 . . ?
H94B C94 H94C 109.5 . . ?
N02Q C99 H99A 109.5 . . ?
N02Q C99 H99B 109.5 . . ?
N02Q C99 H99C 109.5 . . ?
H99A C99 H99B 109.5 . . ?
H99A C99 H99C 109.5 . . ?
H99B C99 H99C 109.5 . . ?
N02D C103 H10I 109.5 . . ?
N02D C103 H10J 109.5 . . ?
N02D C103 H10K 109.5 . . ?
H10I C103 H10J 109.5 . . ?
H10I C103 H10K 109.5 . . ?
H10J C103 H10K 109.5 . . ?
H17A O17 H17B 104.5 . . ?
H16A O16 H16B 104.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Eu01 O8 C30 O9 -77.1(11) . . . . ?
Eu01 O8 C30 C31 102.3(10) . . . . ?
Eu01 O7 C37 O6 -22.6(4) 2_566 . . . ?
Eu01 O7 C37 C38 151.7(3) 2_566 . . . ?
Eu01 O2 C70 O1 -14.1(4) 2_576 . . . ?
Eu01 O2 C70 C69 159.7(3) 2_576 . . . ?
Eu01 O6 C37 O7 17.8(3) 2_566 . . . ?
Eu01 O6 C37 C38 -156.7(3) 2_566 . . . ?
Eu01 O9 C30 O8 3.9(6) 2_666 . . . ?
Eu01 O9 C30 C31 -175.5(2) 2_666 . . . ?
Eu01 O1 C70 O2 14.5(4) 2_576 . . . ?
Eu01 O1 C70 C69 -159.4(3) 2_576 . . . ?
Eu01 O12 C24 O13 -61.1(9) . . . . ?
Eu01 O12 C24 C23 119.0(6) . . . . ?
Eu01 C70 C69 C71 98.3(9) 2_576 . . . ?
Eu01 C70 C69 C68 -71.8(10) 2_576 . . . ?
Eu01 C37 C38 C39 18.5(8) 2_566 . . . ?
Eu01 C37 C38 C43 -154.9(5) 2_566 . . . ?
Eu02 O4 C59 O3 -8.9(3) 2_576 . . . ?
Eu02 O4 C59 C60 170.4(3) 2_576 . . . ?
Eu02 O14 C1 O15 47.4(6) 2_666 . . . ?
Eu02 O14 C1 C2 -134.2(3) 2_666 . . . ?
Eu02 O15 C1 O14 2.8(5) 1_645 . . . ?
Eu02 O15 C1 C2 -175.6(2) 1_645 . . . ?
Eu02 O3 C59 O4 11.7(4) 2_576 . . . ?
Eu02 O3 C59 C60 -167.6(3) 2_576 . . . ?
Eu02 O6 C37 Eu01 -142.3(4) . . . 2_566 ?
Eu02 O6 C37 O7 -124.5(4) . . . . ?
Eu02 O6 C37 C38 61.0(6) . . . . ?
Eu02 O5 C87 N017 -130.0(4) . . . . ?
Eu02 O5 C87 C88 51.7(8) . . . . ?
Eu02 O13 C24 O12 -8.0(6) 2_566 . . . ?
Eu02 O13 C24 C23 172.0(2) 2_566 . . . ?
Eu02 C59 C60 C65 151.4(7) 2_576 . . . ?
Eu02 C59 C60 C61 -25.6(11) 2_576 . . . ?
O4 C59 C60 C65 6.0(6) . . . . ?
O4 C59 C60 C61 -171.0(4) . . . . ?
O14 C1 C2 C3 17.9(5) . . . . ?
O14 C1 C2 C7 -158.5(4) . . . . ?
O15 C1 C2 C3 -163.6(4) . . . . ?
O15 C1 C2 C7 20.0(6) . . . . ?
O8 C30 C31 C32 -10.9(6) . . . . ?
O8 C30 C31 C36 173.0(4) . . . . ?
O3 C59 C60 C65 -174.8(4) . . . . ?
O3 C59 C60 C61 8.2(6) . . . . ?
O7 C37 C38 C39 -40.9(5) . . . . ?
O7 C37 C38 C43 145.7(4) . . . . ?
O2 C70 C69 C71 5.0(6) . . . . ?
O2 C70 C69 C68 -165.1(4) . . . . ?
O6 C37 C38 C39 133.6(4) . . . . ?
O6 C37 C38 C43 -39.7(5) . . . . ?
O9 C30 C31 C32 168.6(4) . . . . ?
O9 C30 C31 C36 -7.5(5) . . . . ?
O1 C70 C69 C71 178.9(4) . . . . ?
O1 C70 C69 C68 8.9(6) . . . . ?
O12 C24 C23 C25 13.4(6) . . . . ?
O12 C24 C23 C22 -166.7(4) . . . . ?
O13 C24 C23 C25 -166.5(4) . . . . ?
O13 C24 C23 C22 13.4(6) . . . . ?
C70 C69 C68 C67 164.6(4) . . . . ?
C37 C38 C39 C40 -168.9(4) . . . . ?
C37 C38 C43 C42 173.8(4) . . . . ?
C3 C2 C7 C6 -2.1(6) . . . . ?
C3 C4 C5 C28 175.5(4) . . . . ?
C3 C4 C5 C6 -1.3(6) . . . . ?
C1 C2 C7 C6 174.2(4) . . . . ?
C59 C60 C65 C64 -178.5(4) . . . . ?
C59 C60 C61 C62 176.5(4) . . . . ?
C30 C31 C36 C35 177.1(4) . . . . ?
C2 C3 C4 C5 0.4(6) . . . . ?
C2 C7 C6 C5 1.3(6) . . . . ?
C38 C39 C40 C41 -5.4(6) . . . . ?
C39 C38 C43 C42 0.4(6) . . . . ?
C60 C65 C64 C63 2.0(7) . . . . ?
C60 C61 C62 C63 2.2(7) . . . . ?
C24 C23 C25 C26 179.2(4) . . . . ?
C24 C23 C22 C21 -179.4(4) . . . . ?
C23 C22 C21 C27 -1.3(8) . . . . ?
C58 C41 C40 C39 -175.7(4) . . . . ?
C58 C41 C42 C43 -179.1(4) . . . . ?
C58 C56 C50 C51 -65.5(6) . . . . ?
C58 C56 C50 C55 117.5(5) . . . . ?
C58 C56 C57 C45 -48.6(7) . . . . ?
C58 C56 C57 C49 132.8(5) . . . . ?
C58 C34 C35 C36 -176.7(4) . . . . ?
C58 C34 C33 C32 178.2(4) . . . . ?
C71 C69 C68 C67 -5.7(6) . . . . ?
C85 C86 C63 C64 50.1(6) . . . . ?
C85 C86 C63 C62 -132.6(5) . . . . ?
C85 C79 C84 C83 180.0(4) . . . . ?
C85 C79 C80 C81 179.3(4) . . . . ?
C85 C73 C74 C75 178.5(4) . . . . ?
C85 C73 C78 C77 -179.4(4) . . . . ?
C41 C58 C56 C50 -6.0(6) . . . . ?
C41 C58 C56 C57 175.1(4) . . . . ?
C41 C58 C34 C35 123.2(4) . . . . ?
C41 C58 C34 C33 -54.0(5) . . . . ?
C41 C42 C43 C38 -5.0(6) . . . . ?
C4 C3 C2 C1 -175.3(4) . . . . ?
C4 C3 C2 C7 1.3(6) . . . . ?
C4 C5 C28 C29 54.6(6) . . . . ?
C4 C5 C28 C27 -121.2(4) . . . . ?
C4 C5 C6 C7 0.4(6) . . . . ?
C65 C60 C61 C62 -0.6(7) . . . . ?
C66 C86 C63 C64 -129.8(4) . . . . ?
C66 C86 C63 C62 47.5(6) . . . . ?
C69 C71 C72 C66 0.8(6) . . . . ?
C69 C68 C67 C66 1.6(7) . . . . ?
C40 C41 C42 C43 4.4(6) . . . . ?
C56 C58 C41 C40 -69.4(5) . . . . ?
C56 C58 C41 C42 114.2(5) . . . . ?
C56 C58 C34 C35 -56.9(6) . . . . ?
C56 C58 C34 C33 126.0(4) . . . . ?
C56 C50 C51 C52 -177.9(5) . . . . ?
C56 C50 C55 C54 179.9(4) . . . . ?
C56 C57 C45 C46 179.9(5) . . . . ?
C56 C57 C49 C48 -179.4(5) . . . . ?
C86 C85 C79 C84 50.3(6) . . . . ?
C86 C85 C79 C80 -130.7(4) . . . . ?
C86 C85 C73 C74 56.4(6) . . . . ?
C86 C85 C73 C78 -124.2(4) . . . . ?
C86 C66 C72 C71 171.0(4) . . . . ?
C86 C66 C67 C68 -172.2(4) . . . . ?
C86 C63 C64 C65 177.1(4) . . . . ?
C86 C63 C62 C61 -179.1(4) . . . . ?
C5 C28 C27 C26 47.1(5) . . . . ?
C5 C28 C27 C21 -134.2(4) . . . . ?
C42 C41 C40 C39 0.9(6) . . . . ?
C43 C38 C39 C40 4.7(6) . . . . ?
C32 C31 C36 C35 1.0(6) . . . . ?
C31 C32 C33 C34 -1.5(6) . . . . ?
C31 C36 C35 C34 -1.5(6) . . . . ?
C72 C71 C69 C70 -165.6(4) . . . . ?
C72 C71 C69 C68 4.4(6) . . . . ?
C72 C66 C86 C85 48.3(6) . . . . ?
C72 C66 C86 C63 -131.8(4) . . . . ?
C72 C66 C67 C68 3.7(6) . . . . ?
C29 C28 C27 C26 -128.6(4) . . . . ?
C29 C28 C27 C21 50.0(6) . . . . ?
C29 C8 C9 C10 179.3(5) . . . . ?
C29 C8 C13 C12 178.9(5) . . . . ?
C29 C14 C19 C18 -176.0(6) . . . . ?
C79 C85 C86 C66 -166.9(4) . . . . ?
C79 C85 C86 C63 13.2(6) . . . . ?
C79 C85 C73 C74 -123.6(4) . . . . ?
C79 C85 C73 C78 55.9(5) . . . . ?
C79 C84 C83 C82 0.6(7) . . . . ?
C79 C80 C81 C82 1.0(7) . . . . ?
C67 C66 C86 C85 -135.9(4) . . . . ?
C67 C66 C86 C63 44.0(5) . . . . ?
C67 C66 C72 C71 -4.9(6) . . . . ?
C26 C27 C21 C22 2.1(7) . . . . ?
C34 C58 C41 C40 110.5(4) . . . . ?
C34 C58 C41 C42 -65.9(5) . . . . ?
C34 C58 C56 C50 174.1(4) . . . . ?
C34 C58 C56 C57 -4.9(7) . . . . ?
C28 C5 C6 C7 -176.4(4) . . . . ?
C28 C29 C8 C9 52.4(7) . . . . ?
C28 C29 C8 C13 -129.2(5) . . . . ?
C28 C29 C14 C15 -128.5(5) . . . . ?
C28 C29 C14 C19 52.2(7) . . . . ?
C28 C27 C21 C22 -176.5(4) . . . . ?
C64 C63 C62 C61 -1.7(7) . . . . ?
C6 C5 C28 C29 -128.7(4) . . . . ?
C6 C5 C28 C27 55.5(5) . . . . ?
C27 C26 C25 C23 1.7(6) . . . . ?
C73 C85 C86 C66 13.2(6) . . . . ?
C73 C85 C86 C63 -166.7(4) . . . . ?
C73 C85 C79 C84 -129.8(4) . . . . ?
C73 C85 C79 C80 49.2(5) . . . . ?
C73 C74 C75 C76 1.3(7) . . . . ?
C73 C78 C77 C76 0.4(8) . . . . ?
C25 C23 C22 C21 0.5(7) . . . . ?
C25 C26 C27 C28 176.4(4) . . . . ?
C25 C26 C27 C21 -2.3(6) . . . . ?
C35 C34 C33 C32 1.0(6) . . . . ?
C84 C79 C80 C81 -1.7(6) . . . . ?
C84 C83 C82 C81 -1.3(7) . . . . ?
C50 C56 C57 C45 132.4(5) . . . . ?
C50 C56 C57 C49 -46.2(6) . . . . ?
C50 C51 C52 C53 -1.4(9) . . . . ?
C50 C55 C54 C53 -2.7(8) . . . . ?
C80 C79 C84 C83 0.9(6) . . . . ?
C80 C81 C82 C83 0.5(7) . . . . ?
C33 C32 C31 C30 -175.5(4) . . . . ?
C33 C32 C31 C36 0.5(6) . . . . ?
C33 C34 C35 C36 0.5(6) . . . . ?
C15 C14 C19 C18 4.7(9) . . . . ?
C15 C16 C17 C18 3.0(10) . . . . ?
C57 C56 C50 C51 113.5(5) . . . . ?
C57 C56 C50 C55 -63.5(5) . . . . ?
C57 C45 C46 C47 0.1(8) . . . . ?
C57 C49 C48 C47 -1.0(9) . . . . ?
C8 C29 C28 C5 0.6(7) . . . . ?
C8 C29 C28 C27 175.9(4) . . . . ?
C8 C29 C14 C15 53.4(6) . . . . ?
C8 C29 C14 C19 -126.0(5) . . . . ?
C8 C9 C10 C11 0.7(9) . . . . ?
C8 C13 C12 C11 2.8(10) . . . . ?
C61 C60 C65 C64 -1.5(6) . . . . ?
C14 C29 C28 C5 -177.4(4) . . . . ?
C14 C29 C28 C27 -2.1(7) . . . . ?
C14 C29 C8 C9 -129.4(5) . . . . ?
C14 C29 C8 C13 49.0(6) . . . . ?
C14 C15 C16 C17 0.8(9) . . . . ?
C14 C19 C18 C17 -1.1(11) . . . . ?
C74 C73 C78 C77 0.0(7) . . . . ?
C74 C75 C76 C77 -0.9(8) . . . . ?
C22 C23 C25 C26 -0.7(6) . . . . ?
C78 C73 C74 C75 -0.9(6) . . . . ?
C78 C77 C76 C75 0.0(8) . . . . ?
C62 C63 C64 C65 -0.4(6) . . . . ?
C51 C50 C55 C54 2.9(7) . . . . ?
C90 N017 C87 O5 -4.6(7) . . . . ?
C90 N017 C87 C88 173.8(5) . . . . ?
C45 C57 C49 C48 2.0(8) . . . . ?
C49 C57 C45 C46 -1.6(7) . . . . ?
C49 C48 C47 C46 -0.5(10) . . . . ?
C55 C50 C51 C52 -0.8(8) . . . . ?
C16 C15 C14 C29 176.0(4) . . . . ?
C16 C15 C14 C19 -4.6(8) . . . . ?
C16 C17 C18 C19 -2.9(12) . . . . ?
C89 N017 C87 O5 171.8(5) . . . . ?
C89 N017 C87 C88 -9.9(8) . . . . ?
C9 C8 C13 C12 -2.6(8) . . . . ?
C9 C10 C11 C12 -0.5(11) . . . . ?
C102 N02D C100 O18 179.8(6) . . . . ?
C102 N02D C100 C101 2.3(10) . . . . ?
C48 C47 C46 C45 0.9(9) . . . . ?
C54 C53 C52 C51 1.5(9) . . . . ?
C97 N02Q C95 O01Z 0.9(9) . . . . ?
C97 N02Q C95 C96 -178.5(6) . . . . ?
C13 C8 C9 C10 0.9(7) . . . . ?
C13 C12 C11 C10 -1.2(11) . . . . ?
C52 C53 C54 C55 0.5(8) . . . . ?
C93 N031 C91 O19 -179.3(8) . . . . ?
C93 N031 C91 C92 -1.7(15) . . . . ?
C94 N031 C91 O19 0.4(13) . . . . ?
C94 N031 C91 C92 178.0(5) . . . . ?
C99 N02Q C95 O01Z -178.7(6) . . . . ?
C99 N02Q C95 C96 2.0(10) . . . . ?
C103 N02D C100 O18 2.5(10) . . . . ?
C103 N02D C100 C101 -175.1(7) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_2
_database_code_depnum_ccdc_archive 'CCDC 2176116'
loop_
_audit_author_name
_audit_author_address
'Wang shuyu'
;Yunnan university
China
;
_audit_update_record             
;
2022-10-01 deposited with the CCDC.	2023-04-28 downloaded from the CCDC.
;
_audit_creation_date             2022-09-17
_audit_creation_method           
;
Olex2 1.5
(compiled 2021.08.20 svn.r13c46975 for OlexSys, GUI svn.r6392)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C60 H50 Eu N O7'
_chemical_formula_sum            'C60 H50 Eu N O7'
_chemical_formula_weight         1048.97
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   9.3725(4)
_cell_length_b                   10.8238(4)
_cell_length_c                   25.4977(9)
_cell_angle_alpha                91.7070(10)
_cell_angle_beta                 98.2090(10)
_cell_angle_gamma                106.9890(10)
_cell_volume                     2441.42(16)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    9960
_cell_measurement_temperature    100.0
_cell_measurement_theta_max      27.49
_cell_measurement_theta_min      2.32
_shelx_estimated_absorpt_T_max   0.991
_shelx_estimated_absorpt_T_min   0.907
_exptl_absorpt_coefficient_mu    1.341
_exptl_absorpt_correction_T_max  0.2616
_exptl_absorpt_correction_T_min  0.1956
_exptl_absorpt_correction_type   none
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1168 before and 0.0656 after correction.
The Ratio of minimum to maximum transmission is 0.7477.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear whiteish white'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   whiteish
_exptl_crystal_colour_primary    white
_exptl_crystal_density_diffrn    1.427
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    ?
_exptl_crystal_description       needle
_exptl_crystal_F_000             1072
_exptl_crystal_preparation       ?
_exptl_crystal_size_max          0.074
_exptl_crystal_size_mid          0.012
_exptl_crystal_size_min          0.007
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0493
_diffrn_reflns_av_unetI/netI     0.0570
_diffrn_reflns_Laue_measured_fraction_full 0.993
_diffrn_reflns_Laue_measured_fraction_max 0.993
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            24851
_diffrn_reflns_point_group_measured_fraction_full 0.993
_diffrn_reflns_point_group_measured_fraction_max 0.993
_diffrn_reflns_theta_full        25.024
_diffrn_reflns_theta_max         25.024
_diffrn_reflns_theta_min         2.315
_diffrn_ambient_temperature      100.0
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           1.4
_diffrn_source_power             0.07
_diffrn_source_voltage           50.0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                7870
_reflns_number_total             8563
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.38A (Bruker, 2018)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.38A (Bruker, 2018)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         9.627
_refine_diff_density_min         -2.742
_refine_diff_density_rms         0.187
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.101
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     626
_refine_ls_number_reflns         8563
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0711
_refine_ls_R_factor_gt           0.0668
_refine_ls_restrained_S_all      1.101
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0974P)²+10.4726P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1600
_refine_ls_wR_factor_ref         0.1642
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C00A(H00A), C00E(H00E), C00I(H00I), C00N(H00N), C00S(H00S), C00V(H00V),
 C00W(H00W), C00Y(H00Y), C00Z(H00Z), C010(H010), C011(H011), C012(H012),
 C013(H013), C014(H014), C015(H015), C016(H016), C017(H017), C018(H018),
 C019(H019), C01B(H01B), C01C(H01C), C01D(H01D), C01E(H01E), C01F(H01F),
 C01G(H01G), C01H(H01H), C01I(H01I), C01J(H01J), C01K(H01K), C01L(H01L),
 C01M(H01M), C01O(H01P), C01P(H01Q), C01Q(H01R), C01R(H01S), C01S(H01T),
 C01T(H01U), C01V(H01Y)
2.b Idealised Me refined as rotating group:
 C01N(H01A,H01N,H01O), C01U(H01V,H01W,H01X), C01W(H01Z,H,HA), C01X(H01,HB,HC)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu01 Eu 0.53967(3) 0.76200(2) 0.50501(2) 0.01352(13) Uani 1 1 d . . . . .
O002 O 0.5919(5) 1.1387(4) 0.44428(16) 0.0166(9) Uani 1 1 d . . . . .
O003 O 0.4359(5) 0.3798(4) 0.56122(16) 0.0212(9) Uani 1 1 d . . . . .
O004 O 0.5176(5) 0.5941(4) 0.55910(15) 0.0180(9) Uani 1 1 d . . . . .
O005 O 0.5469(5) 0.9269(4) 0.45078(16) 0.0222(10) Uani 1 1 d . . . . .
O006 O 0.8101(5) 0.8123(4) 0.50622(18) 0.0261(10) Uani 1 1 d . . . . .
O007 O 0.7385(5) 0.8924(4) 0.57407(18) 0.0279(10) Uani 1 1 d . . . . .
O008 O 0.2920(6) 0.6653(4) 0.4659(2) 0.0307(11) Uani 1 1 d . . . . .
C009 C 0.7225(7) 0.9856(5) 0.1798(2) 0.0152(12) Uani 1 1 d . . . . .
C00A C 0.5048(6) 0.6284(5) 0.6671(2) 0.0129(11) Uani 1 1 d . . . . .
H00A H 0.549705 0.702728 0.649500 0.015 Uiso 1 1 calc R U . . .
C00B C 0.4711(6) 0.4926(5) 0.5823(2) 0.0119(11) Uani 1 1 d . . . . .
C00C C 0.1322(6) 0.4791(6) 0.7875(2) 0.0143(12) Uani 1 1 d . . . . .
C00D C 0.5708(6) 1.0257(6) 0.4247(2) 0.0144(12) Uani 1 1 d . . . . .
C00E C 0.8566(7) 0.6910(6) 0.8954(2) 0.0221(13) Uani 1 1 d . . . . .
H00E H 0.956030 0.724140 0.914785 0.026 Uiso 1 1 calc R U . . .
C00F C 0.2812(7) 0.5139(6) 0.8231(2) 0.0157(12) Uani 1 1 d . . . . .
N00G N 0.0556(6) 0.5412(6) 0.4360(2) 0.0274(13) Uani 1 1 d . . . . .
C00H C 0.5772(6) 1.0073(5) 0.3667(2) 0.0138(11) Uani 1 1 d . . . . .
C00I C 0.3845(7) 0.3992(5) 0.6651(2) 0.0158(12) Uani 1 1 d . . . . .
H00I H 0.349064 0.316032 0.646465 0.019 Uiso 1 1 calc R U . . .
C00J C 0.8725(7) 1.0184(6) 0.2145(2) 0.0153(12) Uani 1 1 d . . . . .
C00K C 0.5651(6) 0.5945(5) 0.8382(2) 0.0139(11) Uani 1 1 d . . . . .
C00L C 0.8437(7) 0.8774(6) 0.5511(3) 0.0217(13) Uani 1 1 d . . . . .
C00M C 0.4545(6) 0.5080(5) 0.6397(2) 0.0099(11) Uani 1 1 d . . . . .
C00N C 0.1501(7) 0.8144(6) 0.1072(2) 0.0222(13) Uani 1 1 d . . . . .
H00N H 0.051369 0.782512 0.087287 0.027 Uiso 1 1 calc R U . . .
C00O C 0.7281(6) 0.9933(6) 0.1217(2) 0.0160(12) Uani 1 1 d . . . . .
C00P C 0.4125(6) 0.5466(5) 0.8041(2) 0.0136(11) Uani 1 1 d . . . . .
C00Q C 0.4399(7) 0.9072(6) 0.1662(2) 0.0158(12) Uani 1 1 d . . . . .
C00R C 0.5899(6) 0.9725(6) 0.2582(2) 0.0139(11) Uani 1 1 d . . . . .
C00S C 0.7479(7) 0.7497(6) 0.9033(2) 0.0213(13) Uani 1 1 d . . . . .
H00S H 0.772549 0.823474 0.927760 0.026 Uiso 1 1 calc R U . . .
C00T C 0.2739(7) 0.5056(6) 0.8812(2) 0.0165(12) Uani 1 1 d . . . . .
C00U C 0.4207(6) 0.5338(5) 0.7462(2) 0.0129(11) Uani 1 1 d . . . . .
C00V C 0.6018(7) 0.7002(6) 0.8751(2) 0.0185(12) Uani 1 1 d . . . . .
H00V H 0.526587 0.739366 0.881230 0.022 Uiso 1 1 calc R U . . .
C00W C 0.2580(7) 0.7531(7) 0.1006(2) 0.0227(14) Uani 1 1 d . . . . .
H00W H 0.233577 0.679489 0.076028 0.027 Uiso 1 1 calc R U . . .
C00X C 0.5924(7) 0.9553(5) 0.2001(2) 0.0149(12) Uani 1 1 d . . . . .
C00Y C 0.5066(7) 0.8873(6) 0.3388(2) 0.0176(12) Uani 1 1 d . . . . .
H00Y H 0.455799 0.816251 0.356958 0.021 Uiso 1 1 calc R U . . .
C00Z C 0.5095(6) 0.8697(6) 0.2847(2) 0.0149(11) Uani 1 1 d . . . . .
H00Z H 0.457040 0.788324 0.265872 0.018 Uiso 1 1 calc R U . . .
C010 C 0.4021(7) 0.8002(6) 0.1301(2) 0.0210(13) Uani 1 1 d . . . . .
H010 H 0.475906 0.758322 0.125334 0.025 Uiso 1 1 calc R U . . .
C011 C 0.1943(7) 0.5738(7) 0.9057(2) 0.0224(14) Uani 1 1 d . . . . .
H011 H 0.148508 0.628766 0.885766 0.027 Uiso 1 1 calc R U . . .
C012 C 0.1859(7) 0.9211(6) 0.1427(3) 0.0228(14) Uani 1 1 d . . . . .
H012 H 0.112067 0.963395 0.146813 0.027 Uiso 1 1 calc R U . . .
C013 C 0.8090(7) 0.9281(6) 0.0965(2) 0.0201(13) Uani 1 1 d . . . . .
H013 H 0.856925 0.874025 0.116113 0.024 Uiso 1 1 calc R U . . .
C014 C 0.4901(6) 0.6413(5) 0.7203(2) 0.0147(11) Uani 1 1 d . . . . .
H014 H 0.527651 0.724275 0.739131 0.018 Uiso 1 1 calc R U . . .
C015 C 0.3671(6) 0.4137(5) 0.7178(2) 0.0152(12) Uani 1 1 d . . . . .
H015 H 0.317630 0.339894 0.734841 0.018 Uiso 1 1 calc R U . . .
C016 C 0.9834(7) 1.1339(6) 0.2095(3) 0.0225(13) Uani 1 1 d . . . . .
H016 H 0.963308 1.190224 0.183436 0.027 Uiso 1 1 calc R U . . .
C017 C 0.3294(7) 0.9675(6) 0.1725(2) 0.0194(13) Uani 1 1 d . . . . .
H017 H 0.352706 1.040575 0.197344 0.023 Uiso 1 1 calc R U . . .
C018 C 0.6534(7) 1.1092(6) 0.3401(2) 0.0176(12) Uani 1 1 d . . . . .
H018 H 0.700711 1.191929 0.358508 0.021 Uiso 1 1 calc R U . . .
C019 C 0.0233(7) 0.3621(6) 0.7907(3) 0.0225(13) Uani 1 1 d . . . . .
H019 H 0.044304 0.303790 0.815603 0.027 Uiso 1 1 calc R U . . .
C01A C 0.1583(7) 0.6547(6) 0.4464(3) 0.0226(14) Uani 1 1 d . . . . .
C01B C 0.8209(7) 0.5842(6) 0.8595(2) 0.0215(13) Uani 1 1 d . . . . .
H01B H 0.895231 0.543099 0.854540 0.026 Uiso 1 1 calc R U . . .
C01C C 0.6761(7) 0.5371(6) 0.8307(2) 0.0184(12) Uani 1 1 d . . . . .
H01C H 0.652599 0.464769 0.805508 0.022 Uiso 1 1 calc R U . . .
C01D C 0.6612(7) 1.0913(6) 0.2867(2) 0.0201(13) Uani 1 1 d . . . . .
H01D H 0.716454 1.161579 0.269201 0.024 Uiso 1 1 calc R U . . .
C01E C 1.1551(7) 1.0863(6) 0.2796(3) 0.0249(14) Uani 1 1 d . . . . .
H01E H 1.250121 1.110280 0.302250 0.030 Uiso 1 1 calc R U . . .
C01F C 1.1232(8) 1.1672(6) 0.2422(3) 0.0262(14) Uani 1 1 d . . . . .
H01F H 1.197172 1.246688 0.238675 0.031 Uiso 1 1 calc R U . . .
C01G C 0.9085(7) 0.9379(6) 0.2521(3) 0.0238(14) Uani 1 1 d . . . . .
H01G H 0.835072 0.858467 0.256105 0.029 Uiso 1 1 calc R U . . .
C01H C 0.7541(8) 1.0189(6) 0.0143(2) 0.0246(14) Uani 1 1 d . . . . .
H01H H 0.763392 1.027943 -0.022156 0.030 Uiso 1 1 calc R U . . .
C01I C 0.0962(7) 0.5627(6) 0.7515(3) 0.0251(14) Uani 1 1 d . . . . .
H01I H 0.168897 0.643423 0.748606 0.030 Uiso 1 1 calc R U . . .
C01J C 0.2451(8) 0.4821(6) 0.9883(2) 0.0258(14) Uani 1 1 d . . . . .
H01J H 0.235041 0.473943 1.024697 0.031 Uiso 1 1 calc R U . . .
C01K C -0.1158(8) 0.3292(7) 0.7580(3) 0.0297(15) Uani 1 1 d . . . . .
H01K H -0.188233 0.247917 0.760100 0.036 Uiso 1 1 calc R U . . .
C01L C -0.1494(7) 0.4139(7) 0.7223(3) 0.0257(14) Uani 1 1 d . . . . .
H01L H -0.244696 0.391447 0.699875 0.031 Uiso 1 1 calc R U . . .
C01M C 0.8220(7) 0.9397(7) 0.0434(2) 0.0264(15) Uani 1 1 d . . . . .
H01M H 0.877572 0.893306 0.026942 0.032 Uiso 1 1 calc R U . . .
C01N C 1.0042(9) 0.9358(8) 0.5748(3) 0.0393(18) Uani 1 1 d . . . . .
H01A H 1.011809 0.953583 0.613170 0.059 Uiso 1 1 calc R U . . .
H01N H 1.045929 1.016966 0.558649 0.059 Uiso 1 1 calc R U . . .
H01O H 1.061191 0.875618 0.568237 0.059 Uiso 1 1 calc R U . . .
C01O C 0.6595(9) 1.0711(7) 0.0921(3) 0.0329(17) Uani 1 1 d . . . . .
H01P H 0.602259 1.116216 0.108261 0.039 Uiso 1 1 calc R U . . .
C01P C 0.1805(8) 0.5628(7) 0.9591(2) 0.0266(15) Uani 1 1 d . . . . .
H01Q H 0.126574 0.611011 0.975417 0.032 Uiso 1 1 calc R U . . .
C01Q C 0.3384(9) 0.4258(7) 0.9113(3) 0.0331(17) Uani 1 1 d . . . . .
H01R H 0.393639 0.378281 0.895334 0.040 Uiso 1 1 calc R U . . .
C01R C 0.6734(9) 1.0841(8) 0.0386(3) 0.0356(18) Uani 1 1 d . . . . .
H01S H 0.626410 1.138719 0.018835 0.043 Uiso 1 1 calc R U . . .
C01S C 1.0484(7) 0.9701(7) 0.2841(3) 0.0269(15) Uani 1 1 d . . . . .
H01T H 1.070876 0.912242 0.308971 0.032 Uiso 1 1 calc R U . . .
C01T C -0.0436(8) 0.5310(7) 0.7195(3) 0.0283(15) Uani 1 1 d . . . . .
H01U H -0.066470 0.590582 0.695514 0.034 Uiso 1 1 calc R U . . .
C01U C 0.1156(10) 0.7765(8) 0.4360(4) 0.046(2) Uani 1 1 d . . . . .
H01V H 0.039666 0.782840 0.457816 0.069 Uiso 1 1 calc R U . . .
H01W H 0.073811 0.773957 0.398318 0.069 Uiso 1 1 calc R U . . .
H01X H 0.205405 0.851956 0.444960 0.069 Uiso 1 1 calc R U . . .
C01V C 0.3239(10) 0.4137(8) 0.9646(3) 0.0383(19) Uani 1 1 d . . . . .
H01Y H 0.368619 0.358049 0.984558 0.046 Uiso 1 1 calc R U . . .
C01W C 0.0977(8) 0.4219(7) 0.4427(3) 0.0350(17) Uani 1 1 d . . . . .
H01Z H 0.100643 0.383076 0.407765 0.052 Uiso 1 1 calc R U . . .
H H 0.023112 0.360868 0.460108 0.052 Uiso 1 1 calc R U . . .
HA H 0.197610 0.442058 0.464566 0.052 Uiso 1 1 calc R U . . .
C01X C -0.1018(8) 0.5247(10) 0.4130(4) 0.048(2) Uani 1 1 d . . . . .
H01 H -0.127361 0.604107 0.420916 0.071 Uiso 1 1 calc R U . . .
HB H -0.168355 0.452020 0.428208 0.071 Uiso 1 1 calc R U . . .
HC H -0.114991 0.507097 0.374363 0.071 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu01 O002 2.344(4) 2_676 ?
Eu01 O003 2.328(4) 2_666 ?
Eu01 O004 2.293(4) . ?
Eu01 O005 2.281(4) . ?
Eu01 O006 2.428(4) . ?
Eu01 O007 2.438(4) . ?
Eu01 O008 2.310(5) . ?
O002 C00D 1.256(7) . ?
O003 C00B 1.250(7) . ?
O004 C00B 1.257(7) . ?
O005 C00D 1.258(7) . ?
O006 C00L 1.275(8) . ?
O007 C00L 1.262(8) . ?
O008 C01A 1.250(8) . ?
C009 C00J 1.490(8) . ?
C009 C00O 1.494(8) . ?
C009 C00X 1.348(8) . ?
C00A H00A 0.9500 . ?
C00A C00M 1.378(8) . ?
C00A C014 1.391(8) . ?
C00B C00M 1.504(7) . ?
C00C C00F 1.492(8) . ?
C00C C019 1.388(9) . ?
C00C C01I 1.385(9) . ?
C00D C00H 1.498(8) . ?
C00E H00E 0.9500 . ?
C00E C00S 1.382(9) . ?
C00E C01B 1.382(9) . ?
C00F C00P 1.342(8) . ?
C00F C00T 1.496(8) . ?
N00G C01A 1.313(9) . ?
N00G C01W 1.463(9) . ?
N00G C01X 1.465(9) . ?
C00H C00Y 1.393(9) . ?
C00H C018 1.383(8) . ?
C00I H00I 0.9500 . ?
C00I C00M 1.398(8) . ?
C00I C015 1.386(8) . ?
C00J C016 1.396(9) . ?
C00J C01G 1.386(9) . ?
C00K C00P 1.502(8) . ?
C00K C00V 1.388(8) . ?
C00K C01C 1.390(8) . ?
C00L C01N 1.480(10) . ?
C00N H00N 0.9500 . ?
C00N C00W 1.388(9) . ?
C00N C012 1.374(9) . ?
C00O C013 1.382(8) . ?
C00O C01O 1.382(9) . ?
C00P C00U 1.493(7) . ?
C00Q C00X 1.499(9) . ?
C00Q C010 1.385(9) . ?
C00Q C017 1.400(8) . ?
C00R C00X 1.491(8) . ?
C00R C00Z 1.402(8) . ?
C00R C01D 1.390(9) . ?
C00S H00S 0.9500 . ?
C00S C00V 1.394(9) . ?
C00T C011 1.385(8) . ?
C00T C01Q 1.383(9) . ?
C00U C014 1.393(8) . ?
C00U C015 1.388(8) . ?
C00V H00V 0.9500 . ?
C00W H00W 0.9500 . ?
C00W C010 1.391(9) . ?
C00Y H00Y 0.9500 . ?
C00Y C00Z 1.391(8) . ?
C00Z H00Z 0.9500 . ?
C010 H010 0.9500 . ?
C011 H011 0.9500 . ?
C011 C01P 1.390(8) . ?
C012 H012 0.9500 . ?
C012 C017 1.390(9) . ?
C013 H013 0.9500 . ?
C013 C01M 1.382(9) . ?
C014 H014 0.9500 . ?
C015 H015 0.9500 . ?
C016 H016 0.9500 . ?
C016 C01F 1.392(9) . ?
C017 H017 0.9500 . ?
C018 H018 0.9500 . ?
C018 C01D 1.385(8) . ?
C019 H019 0.9500 . ?
C019 C01K 1.386(10) . ?
C01A C01U 1.506(9) . ?
C01B H01B 0.9500 . ?
C01B C01C 1.390(9) . ?
C01C H01C 0.9500 . ?
C01D H01D 0.9500 . ?
C01E H01E 0.9500 . ?
C01E C01F 1.374(10) . ?
C01E C01S 1.379(10) . ?
C01F H01F 0.9500 . ?
C01G H01G 0.9500 . ?
C01G C01S 1.384(9) . ?
C01H H01H 0.9500 . ?
C01H C01M 1.383(9) . ?
C01H C01R 1.369(10) . ?
C01I H01I 0.9500 . ?
C01I C01T 1.383(10) . ?
C01J H01J 0.9500 . ?
C01J C01P 1.381(9) . ?
C01J C01V 1.371(10) . ?
C01K H01K 0.9500 . ?
C01K C01L 1.380(10) . ?
C01L H01L 0.9500 . ?
C01L C01T 1.374(10) . ?
C01M H01M 0.9500 . ?
C01N H01A 0.9800 . ?
C01N H01N 0.9800 . ?
C01N H01O 0.9800 . ?
C01O H01P 0.9500 . ?
C01O C01R 1.396(10) . ?
C01P H01Q 0.9500 . ?
C01Q H01R 0.9500 . ?
C01Q C01V 1.390(9) . ?
C01R H01S 0.9500 . ?
C01S H01T 0.9500 . ?
C01T H01U 0.9500 . ?
C01U H01V 0.9800 . ?
C01U H01W 0.9800 . ?
C01U H01X 0.9800 . ?
C01V H01Y 0.9500 . ?
C01W H01Z 0.9800 . ?
C01W H 0.9800 . ?
C01W HA 0.9800 . ?
C01X H01 0.9800 . ?
C01X HB 0.9800 . ?
C01X HC 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O002 Eu01 O006 129.05(15) 2_676 . ?
O002 Eu01 O007 77.11(15) 2_676 . ?
O003 Eu01 O002 155.51(16) 2_666 2_676 ?
O003 Eu01 O006 75.32(15) 2_666 . ?
O003 Eu01 O007 127.17(16) 2_666 . ?
O004 Eu01 O002 92.10(14) . 2_676 ?
O004 Eu01 O003 86.59(14) . 2_666 ?
O004 Eu01 O006 96.30(15) . . ?
O004 Eu01 O007 87.18(16) . . ?
O004 Eu01 O008 88.61(16) . . ?
O005 Eu01 O002 85.83(14) . 2_676 ?
O005 Eu01 O003 94.21(14) . 2_666 ?
O005 Eu01 O004 176.67(15) . . ?
O005 Eu01 O006 87.03(16) . . ?
O005 Eu01 O007 94.89(17) . . ?
O005 Eu01 O008 88.40(17) . . ?
O006 Eu01 O007 53.40(15) . . ?
O008 Eu01 O002 78.01(16) . 2_676 ?
O008 Eu01 O003 77.51(16) . 2_666 ?
O008 Eu01 O006 152.02(16) . . ?
O008 Eu01 O007 154.58(17) . . ?
C00D O002 Eu01 135.0(4) . 2_676 ?
C00B O003 Eu01 148.9(4) . 2_666 ?
C00B O004 Eu01 165.1(4) . . ?
C00D O005 Eu01 171.2(4) . . ?
C00L O006 Eu01 93.9(4) . . ?
C00L O007 Eu01 93.7(4) . . ?
C01A O008 Eu01 159.2(4) . . ?
C00J C009 C00O 115.1(5) . . ?
C00X C009 C00J 121.8(5) . . ?
C00X C009 C00O 123.1(5) . . ?
C00M C00A H00A 119.9 . . ?
C00M C00A C014 120.2(5) . . ?
C014 C00A H00A 119.9 . . ?
O003 C00B O004 125.1(5) . . ?
O003 C00B C00M 117.4(5) . . ?
O004 C00B C00M 117.4(5) . . ?
C019 C00C C00F 120.5(5) . . ?
C01I C00C C00F 121.7(6) . . ?
C01I C00C C019 117.8(6) . . ?
O002 C00D O005 124.3(5) . . ?
O002 C00D C00H 118.1(5) . . ?
O005 C00D C00H 117.6(5) . . ?
C00S C00E H00E 120.0 . . ?
C00S C00E C01B 120.1(6) . . ?
C01B C00E H00E 120.0 . . ?
C00C C00F C00T 115.4(5) . . ?
C00P C00F C00C 122.1(5) . . ?
C00P C00F C00T 122.5(5) . . ?
C01A N00G C01W 120.4(5) . . ?
C01A N00G C01X 123.3(6) . . ?
C01W N00G C01X 116.1(6) . . ?
C00Y C00H C00D 120.6(5) . . ?
C018 C00H C00D 120.5(5) . . ?
C018 C00H C00Y 118.9(5) . . ?
C00M C00I H00I 120.3 . . ?
C015 C00I H00I 120.3 . . ?
C015 C00I C00M 119.5(5) . . ?
C016 C00J C009 119.8(5) . . ?
C01G C00J C009 122.6(5) . . ?
C01G C00J C016 117.6(6) . . ?
C00V C00K C00P 121.6(5) . . ?
C00V C00K C01C 118.7(6) . . ?
C01C C00K C00P 119.6(5) . . ?
O006 C00L C01N 119.7(6) . . ?
O007 C00L O006 119.0(6) . . ?
O007 C00L C01N 121.3(6) . . ?
C00A C00M C00B 120.7(5) . . ?
C00A C00M C00I 119.8(5) . . ?
C00I C00M C00B 119.4(5) . . ?
C00W C00N H00N 120.0 . . ?
C012 C00N H00N 120.0 . . ?
C012 C00N C00W 120.0(6) . . ?
C013 C00O C009 121.0(5) . . ?
C01O C00O C009 121.2(5) . . ?
C01O C00O C013 117.7(5) . . ?
C00F C00P C00K 124.1(5) . . ?
C00F C00P C00U 122.7(5) . . ?
C00U C00P C00K 113.1(5) . . ?
C010 C00Q C00X 121.7(5) . . ?
C010 C00Q C017 118.5(6) . . ?
C017 C00Q C00X 119.7(5) . . ?
C00Z C00R C00X 120.3(5) . . ?
C01D C00R C00X 121.2(5) . . ?
C01D C00R C00Z 118.5(5) . . ?
C00E C00S H00S 120.1 . . ?
C00E C00S C00V 119.8(6) . . ?
C00V C00S H00S 120.1 . . ?
C011 C00T C00F 120.1(5) . . ?
C01Q C00T C00F 121.8(5) . . ?
C01Q C00T C011 118.0(5) . . ?
C014 C00U C00P 120.6(5) . . ?
C015 C00U C00P 120.8(5) . . ?
C015 C00U C014 118.5(5) . . ?
C00K C00V C00S 120.7(6) . . ?
C00K C00V H00V 119.6 . . ?
C00S C00V H00V 119.6 . . ?
C00N C00W H00W 120.2 . . ?
C00N C00W C010 119.6(6) . . ?
C010 C00W H00W 120.2 . . ?
C009 C00X C00Q 122.9(5) . . ?
C009 C00X C00R 122.1(5) . . ?
C00R C00X C00Q 114.9(5) . . ?
C00H C00Y H00Y 119.5 . . ?
C00Z C00Y C00H 121.1(5) . . ?
C00Z C00Y H00Y 119.5 . . ?
C00R C00Z H00Z 120.1 . . ?
C00Y C00Z C00R 119.7(5) . . ?
C00Y C00Z H00Z 120.1 . . ?
C00Q C010 C00W 121.1(6) . . ?
C00Q C010 H010 119.4 . . ?
C00W C010 H010 119.4 . . ?
C00T C011 H011 119.5 . . ?
C00T C011 C01P 120.9(6) . . ?
C01P C011 H011 119.5 . . ?
C00N C012 H012 119.8 . . ?
C00N C012 C017 120.4(6) . . ?
C017 C012 H012 119.8 . . ?
C00O C013 H013 119.1 . . ?
C01M C013 C00O 121.7(6) . . ?
C01M C013 H013 119.1 . . ?
C00A C014 C00U 120.6(5) . . ?
C00A C014 H014 119.7 . . ?
C00U C014 H014 119.7 . . ?
C00I C015 C00U 121.3(5) . . ?
C00I C015 H015 119.4 . . ?
C00U C015 H015 119.4 . . ?
C00J C016 H016 119.7 . . ?
C01F C016 C00J 120.5(6) . . ?
C01F C016 H016 119.7 . . ?
C00Q C017 H017 119.8 . . ?
C012 C017 C00Q 120.3(6) . . ?
C012 C017 H017 119.8 . . ?
C00H C018 H018 119.8 . . ?
C00H C018 C01D 120.3(6) . . ?
C01D C018 H018 119.8 . . ?
C00C C019 H019 119.5 . . ?
C01K C019 C00C 121.0(6) . . ?
C01K C019 H019 119.5 . . ?
O008 C01A N00G 121.7(6) . . ?
O008 C01A C01U 118.4(7) . . ?
N00G C01A C01U 119.9(6) . . ?
C00E C01B H01B 120.1 . . ?
C00E C01B C01C 119.9(6) . . ?
C01C C01B H01B 120.1 . . ?
C00K C01C H01C 119.6 . . ?
C01B C01C C00K 120.8(6) . . ?
C01B C01C H01C 119.6 . . ?
C00R C01D H01D 119.3 . . ?
C018 C01D C00R 121.4(5) . . ?
C018 C01D H01D 119.3 . . ?
C01F C01E H01E 120.2 . . ?
C01F C01E C01S 119.6(6) . . ?
C01S C01E H01E 120.2 . . ?
C016 C01F H01F 119.7 . . ?
C01E C01F C016 120.6(6) . . ?
C01E C01F H01F 119.7 . . ?
C00J C01G H01G 119.1 . . ?
C01S C01G C00J 121.8(6) . . ?
C01S C01G H01G 119.1 . . ?
C01M C01H H01H 120.4 . . ?
C01R C01H H01H 120.4 . . ?
C01R C01H C01M 119.2(6) . . ?
C00C C01I H01I 119.4 . . ?
C01T C01I C00C 121.3(6) . . ?
C01T C01I H01I 119.4 . . ?
C01P C01J H01J 120.2 . . ?
C01V C01J H01J 120.2 . . ?
C01V C01J C01P 119.7(6) . . ?
C019 C01K H01K 119.8 . . ?
C01L C01K C019 120.3(6) . . ?
C01L C01K H01K 119.8 . . ?
C01K C01L H01L 120.4 . . ?
C01T C01L C01K 119.3(6) . . ?
C01T C01L H01L 120.4 . . ?
C013 C01M C01H 120.0(6) . . ?
C013 C01M H01M 120.0 . . ?
C01H C01M H01M 120.0 . . ?
C00L C01N H01A 109.5 . . ?
C00L C01N H01N 109.5 . . ?
C00L C01N H01O 109.5 . . ?
H01A C01N H01N 109.5 . . ?
H01A C01N H01O 109.5 . . ?
H01N C01N H01O 109.5 . . ?
C00O C01O H01P 119.6 . . ?
C00O C01O C01R 120.8(6) . . ?
C01R C01O H01P 119.6 . . ?
C011 C01P H01Q 120.0 . . ?
C01J C01P C011 120.1(6) . . ?
C01J C01P H01Q 120.0 . . ?
C00T C01Q H01R 119.4 . . ?
C00T C01Q C01V 121.3(6) . . ?
C01V C01Q H01R 119.4 . . ?
C01H C01R C01O 120.6(6) . . ?
C01H C01R H01S 119.7 . . ?
C01O C01R H01S 119.7 . . ?
C01E C01S C01G 119.8(6) . . ?
C01E C01S H01T 120.1 . . ?
C01G C01S H01T 120.1 . . ?
C01I C01T H01U 119.8 . . ?
C01L C01T C01I 120.3(6) . . ?
C01L C01T H01U 119.8 . . ?
C01A C01U H01V 109.5 . . ?
C01A C01U H01W 109.5 . . ?
C01A C01U H01X 109.5 . . ?
H01V C01U H01W 109.5 . . ?
H01V C01U H01X 109.5 . . ?
H01W C01U H01X 109.5 . . ?
C01J C01V C01Q 120.0(6) . . ?
C01J C01V H01Y 120.0 . . ?
C01Q C01V H01Y 120.0 . . ?
N00G C01W H01Z 109.5 . . ?
N00G C01W H 109.5 . . ?
N00G C01W HA 109.5 . . ?
H01Z C01W H 109.5 . . ?
H01Z C01W HA 109.5 . . ?
H C01W HA 109.5 . . ?
N00G C01X H01 109.5 . . ?
N00G C01X HB 109.5 . . ?
N00G C01X HC 109.5 . . ?
H01 C01X HB 109.5 . . ?
H01 C01X HC 109.5 . . ?
HB C01X HC 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Eu01 O002 C00D O005 -53.5(8) 2_676 . . . ?
Eu01 O002 C00D C00H 127.6(5) 2_676 . . . ?
Eu01 O003 C00B O004 24.2(11) 2_666 . . . ?
Eu01 O003 C00B C00M -156.6(5) 2_666 . . . ?
Eu01 O004 C00B O003 67.8(16) . . . . ?
Eu01 O004 C00B C00M -111.4(13) . . . . ?
Eu01 O006 C00L O007 -1.8(6) . . . . ?
Eu01 O006 C00L C01N 179.3(6) . . . . ?
Eu01 O007 C00L O006 1.8(6) . . . . ?
Eu01 O007 C00L C01N -179.3(6) . . . . ?
Eu01 O008 C01A N00G -169.0(9) . . . . ?
Eu01 O008 C01A C01U 9.9(17) . . . . ?
O002 C00D C00H C00Y -158.0(5) . . . . ?
O002 C00D C00H C018 22.1(8) . . . . ?
O003 C00B C00M C00A 173.6(5) . . . . ?
O003 C00B C00M C00I -7.7(7) . . . . ?
O004 C00B C00M C00A -7.2(7) . . . . ?
O004 C00B C00M C00I 171.5(5) . . . . ?
O005 C00D C00H C00Y 23.1(8) . . . . ?
O005 C00D C00H C018 -156.8(5) . . . . ?
C009 C00J C016 C01F 178.8(6) . . . . ?
C009 C00J C01G C01S -180.0(6) . . . . ?
C009 C00O C013 C01M -176.5(6) . . . . ?
C009 C00O C01O C01R 175.9(7) . . . . ?
C00C C00F C00P C00K 173.9(5) . . . . ?
C00C C00F C00P C00U -8.6(9) . . . . ?
C00C C00F C00T C011 -55.5(8) . . . . ?
C00C C00F C00T C01Q 121.1(7) . . . . ?
C00C C019 C01K C01L -1.3(11) . . . . ?
C00C C01I C01T C01L -1.2(11) . . . . ?
C00D C00H C00Y C00Z 178.8(5) . . . . ?
C00D C00H C018 C01D 178.9(5) . . . . ?
C00E C00S C00V C00K -1.6(9) . . . . ?
C00E C01B C01C C00K -1.3(9) . . . . ?
C00F C00C C019 C01K 179.7(6) . . . . ?
C00F C00C C01I C01T -178.4(6) . . . . ?
C00F C00P C00U C014 122.1(6) . . . . ?
C00F C00P C00U C015 -61.5(8) . . . . ?
C00F C00T C011 C01P 177.1(6) . . . . ?
C00F C00T C01Q C01V -176.5(7) . . . . ?
C00H C00Y C00Z C00R 2.8(8) . . . . ?
C00H C018 C01D C00R 1.8(9) . . . . ?
C00J C009 C00O C013 52.9(8) . . . . ?
C00J C009 C00O C01O -123.6(7) . . . . ?
C00J C009 C00X C00Q -172.8(5) . . . . ?
C00J C009 C00X C00R 9.8(8) . . . . ?
C00J C016 C01F C01E 0.9(10) . . . . ?
C00J C01G C01S C01E 1.4(10) . . . . ?
C00K C00P C00U C014 -60.1(7) . . . . ?
C00K C00P C00U C015 116.2(6) . . . . ?
C00M C00A C014 C00U -1.8(8) . . . . ?
C00M C00I C015 C00U -1.3(9) . . . . ?
C00N C00W C010 C00Q 0.2(10) . . . . ?
C00N C012 C017 C00Q 1.0(9) . . . . ?
C00O C009 C00J C016 51.5(7) . . . . ?
C00O C009 C00J C01G -128.0(6) . . . . ?
C00O C009 C00X C00Q 9.4(9) . . . . ?
C00O C009 C00X C00R -168.1(5) . . . . ?
C00O C013 C01M C01H 0.5(10) . . . . ?
C00O C01O C01R C01H 0.7(13) . . . . ?
C00P C00F C00T C011 126.3(7) . . . . ?
C00P C00F C00T C01Q -57.0(9) . . . . ?
C00P C00K C00V C00S -174.7(5) . . . . ?
C00P C00K C01C C01B 176.2(5) . . . . ?
C00P C00U C014 C00A 176.6(5) . . . . ?
C00P C00U C015 C00I -175.1(5) . . . . ?
C00S C00E C01B C01C 1.0(9) . . . . ?
C00T C00F C00P C00K -8.0(9) . . . . ?
C00T C00F C00P C00U 169.5(5) . . . . ?
C00T C011 C01P C01J -0.7(11) . . . . ?
C00T C01Q C01V C01J -0.3(13) . . . . ?
C00V C00K C00P C00F -54.7(8) . . . . ?
C00V C00K C00P C00U 127.5(6) . . . . ?
C00V C00K C01C C01B 0.1(9) . . . . ?
C00W C00N C012 C017 -0.8(9) . . . . ?
C00X C009 C00J C016 -126.5(6) . . . . ?
C00X C009 C00J C01G 53.9(8) . . . . ?
C00X C009 C00O C013 -129.1(6) . . . . ?
C00X C009 C00O C01O 54.4(9) . . . . ?
C00X C00Q C010 C00W 177.1(6) . . . . ?
C00X C00Q C017 C012 -177.8(5) . . . . ?
C00X C00R C00Z C00Y -179.3(5) . . . . ?
C00X C00R C01D C018 177.0(5) . . . . ?
C00Y C00H C018 C01D -1.0(8) . . . . ?
C00Z C00R C00X C009 -128.3(6) . . . . ?
C00Z C00R C00X C00Q 54.0(7) . . . . ?
C00Z C00R C01D C018 -0.2(9) . . . . ?
C010 C00Q C00X C009 54.6(8) . . . . ?
C010 C00Q C00X C00R -127.7(6) . . . . ?
C010 C00Q C017 C012 -0.5(9) . . . . ?
C011 C00T C01Q C01V 0.1(11) . . . . ?
C012 C00N C00W C010 0.2(9) . . . . ?
C013 C00O C01O C01R -0.7(11) . . . . ?
C014 C00A C00M C00B -179.4(5) . . . . ?
C014 C00A C00M C00I 1.9(8) . . . . ?
C014 C00U C015 C00I 1.4(8) . . . . ?
C015 C00I C00M C00A -0.3(8) . . . . ?
C015 C00I C00M C00B -179.0(5) . . . . ?
C015 C00U C014 C00A 0.2(8) . . . . ?
C016 C00J C01G C01S 0.5(9) . . . . ?
C017 C00Q C00X C009 -128.2(6) . . . . ?
C017 C00Q C00X C00R 49.4(7) . . . . ?
C017 C00Q C010 C00W -0.1(9) . . . . ?
C018 C00H C00Y C00Z -1.3(8) . . . . ?
C019 C00C C00F C00P 125.3(6) . . . . ?
C019 C00C C00F C00T -52.9(7) . . . . ?
C019 C00C C01I C01T -0.1(10) . . . . ?
C019 C01K C01L C01T 0.1(11) . . . . ?
C01B C00E C00S C00V 0.5(9) . . . . ?
C01C C00K C00P C00F 129.3(6) . . . . ?
C01C C00K C00P C00U -48.4(7) . . . . ?
C01C C00K C00V C00S 1.3(9) . . . . ?
C01D C00R C00X C009 54.5(8) . . . . ?
C01D C00R C00X C00Q -123.2(6) . . . . ?
C01D C00R C00Z C00Y -2.0(8) . . . . ?
C01F C01E C01S C01G -2.2(10) . . . . ?
C01G C00J C016 C01F -1.6(9) . . . . ?
C01I C00C C00F C00P -56.4(8) . . . . ?
C01I C00C C00F C00T 125.4(6) . . . . ?
C01I C00C C019 C01K 1.3(9) . . . . ?
C01K C01L C01T C01I 1.2(11) . . . . ?
C01M C01H C01R C01O 0.0(12) . . . . ?
C01O C00O C013 C01M 0.1(10) . . . . ?
C01P C01J C01V C01Q 0.0(12) . . . . ?
C01Q C00T C011 C01P 0.4(10) . . . . ?
C01R C01H C01M C013 -0.6(11) . . . . ?
C01S C01E C01F C016 1.1(10) . . . . ?
C01V C01J C01P C011 0.6(11) . . . . ?
C01W N00G C01A O008 -5.1(10) . . . . ?
C01W N00G C01A C01U 176.0(6) . . . . ?
C01X N00G C01A O008 -179.7(7) . . . . ?
C01X N00G C01A C01U 1.4(10) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_3
_database_code_depnum_ccdc_archive 'CCDC 2176117'
loop_
_audit_author_name
_audit_author_address
'Wang shuyu'
;Yunnan university
China
;
_audit_update_record             
;
2022-10-01 deposited with the CCDC.	2023-04-28 downloaded from the CCDC.
;
_audit_creation_date             2022-09-17
_audit_creation_method           
;
Olex2 1.5
(compiled 2021.08.20 svn.r13c46975 for OlexSys, GUI svn.r6392)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         '2(C97 H76 Eu N3 O8), H2 O'
_chemical_formula_sum            'C194 H154 Eu2 N6 O17'
_chemical_formula_weight         3145.14
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0030 0.0020 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1580 3.6680 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0060 0.0030 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0110 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   26.5569(9)
_cell_length_b                   15.4748(6)
_cell_length_c                   19.2252(8)
_cell_angle_alpha                90
_cell_angle_beta                 96.4520(10)
_cell_angle_gamma                90
_cell_volume                     7850.8(5)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    9912
_cell_measurement_temperature    170.15
_cell_measurement_theta_max      26.35
_cell_measurement_theta_min      2.37
_shelx_estimated_absorpt_T_max   0.992
_shelx_estimated_absorpt_T_min   0.980
_exptl_absorpt_coefficient_mu    0.861
_exptl_absorpt_correction_T_max  0.7454
_exptl_absorpt_correction_T_min  0.6484
_exptl_absorpt_correction_type   none
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.0693 before and 0.0594 after correction.
The Ratio of minimum to maximum transmission is 0.8699.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear whiteish white'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   whiteish
_exptl_crystal_colour_primary    white
_exptl_crystal_density_diffrn    1.330
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             3244
_exptl_crystal_preparation       ?
_exptl_crystal_size_max          0.023
_exptl_crystal_size_mid          0.012
_exptl_crystal_size_min          0.009
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0797
_diffrn_reflns_av_unetI/netI     0.0654
_diffrn_reflns_Laue_measured_fraction_full 0.988
_diffrn_reflns_Laue_measured_fraction_max 0.988
_diffrn_reflns_limit_h_max       31
_diffrn_reflns_limit_h_min       -31
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            53541
_diffrn_reflns_point_group_measured_fraction_full 0.988
_diffrn_reflns_point_group_measured_fraction_max 0.988
_diffrn_reflns_theta_full        25.000
_diffrn_reflns_theta_max         25.000
_diffrn_reflns_theta_min         1.910
_diffrn_ambient_temperature      170.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.988
_diffrn_measured_fraction_theta_max 0.988
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           1.4
_diffrn_source_power             0.07
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                10198
_reflns_number_total             13668
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.40A (Bruker, 2019)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.40A (Bruker, 2019)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_refine_diff_density_max         2.030
_refine_diff_density_min         -0.968
_refine_diff_density_rms         0.101
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.088
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1047
_refine_ls_number_reflns         13668
_refine_ls_number_restraints     321
_refine_ls_R_factor_all          0.0794
_refine_ls_R_factor_gt           0.0504
_refine_ls_restrained_S_all      1.105
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0756P)²+4.5089P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1289
_refine_ls_wR_factor_ref         0.1468
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups, All O(H,H) groups
2. Restrained distances
 O8-C96
 1.2 with sigma of 0.02
 O8A-C98
 1.2 with sigma of 0.02
 N8A-O8A
 2.3 with sigma of 0.02
 C95-C96 = N8-C96 = N8-C97 = N8-C9
 1.48 with sigma of 0.01
 C99-C98 = N8A-C98 = N8A-C100 = N8A-C101
 1.48 with sigma of 0.01
 C98-C100
 2.5 with sigma of 0.02
 C101-C98
 2.5 with sigma of 0.01
 C100-C101
 2.5 with sigma of 0.01
 N8A-C99
 2.5 with sigma of 0.02
3. Uiso/Uaniso restraints and constraints
O8 \\sim N8 \\sim C9 \\sim C95 \\sim C96 \\sim C97 \\sim O8A \\sim C98 \\sim
C99 \\sim N8A \\sim C100 \\sim C101: within 2A with sigma of 0.01 and sigma for
terminal atoms of 0.02 within 2A
Uanis(O10) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(O8) \\sim Ueq, Uanis(N8) \\sim Ueq, Uanis(C9) \\sim Ueq, Uanis(C95) \\sim
Ueq, Uanis(C96) \\sim Ueq, Uanis(C97) \\sim Ueq, Uanis(O8A) \\sim Ueq,
Uanis(C98) \\sim Ueq, Uanis(C99) \\sim Ueq, Uanis(N8A) \\sim Ueq, Uanis(C100)
\\sim Ueq, Uanis(C101) \\sim Ueq: with sigma of 0.01 and sigma for terminal
atoms of 0.02
4. Rigid body (RIGU) restrains
 O8, N8, C9, C95, C96, C97, O8A, C98, C99, N8A, C100, C101
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.01
5. Others
 Sof(O8A)=Sof(C98)=Sof(C99)=Sof(H99A)=Sof(H99B)=Sof(H99C)=Sof(N8A)=Sof(C100)=
 Sof(H10A)=Sof(H10B)=Sof(H10C)=Sof(C101)=Sof(H10D)=Sof(H10E)=Sof(H10F)=1-FVAR(1)
 Sof(O8)=Sof(N8)=Sof(C9)=Sof(H9C)=Sof(H9D)=Sof(H9E)=Sof(C95)=Sof(H95A)=
 Sof(H95B)=Sof(H95C)=Sof(C96)=Sof(C97)=Sof(H97A)=Sof(H97B)=Sof(H97C)=FVAR(1)
 Fixed Sof: O10(0.5) H10G(0.5) H10H(0.5)
6.a Riding coordinates:
 O9(H9A,H9B), O10(H10G,H10H)
6.b Me refined with riding coordinates:
 C9(H9C,H9D,H9E), C95(H95A,H95B,H95C), C99(H99A,H99B,H99C), C100(H10A,H10B,
 H10C), C101(H10D,H10E,H10F)
6.c Aromatic/amide H refined with riding coordinates:
 C1(H1), C6(H6), C17(H17), C20(H20), C23(H23), C25(H25), C26(H26), C28(H28),
 C31(H31), C32(H32), C33(H33), C37(H37), C38(H38), C39(H39), C41(H41), C42(H42),
  C43(H43), C44(H44), C46(H46), C47(H47), C49(H49), C50(H50), C51(H51),
 C52(H52), C53(H53), C54(H54), C55(H55), C56(H56), C57(H57), C58(H58), C59(H59),
  C60(H60), C62(H62), C63(H63), C64(H64), C65(H65), C66(H66), C67(H67),
 C68(H68), C69(H69), C70(H70), C71(H71), C72(H72), C73(H73), C74(H74), C75(H75),
  C76(H76), C77(H77), C78(H78), C79(H79), C80(H80), C81(H81), C82(H82),
 C83(H83), C84(H84), C85(H85), C86(H86), C87(H87), C88(H88), C89(H89), C90(H90),
  C91(H91), C92(H92), C93(H93), C94(H94)
6.d Idealised Me refined as rotating group:
 C97(H97A,H97B,H97C)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.48555(2) 0.67015(2) 0.30241(2) 0.02867(10) Uani 1 1 d . . . . .
O4 O 0.44125(12) 0.5464(2) 0.26953(16) 0.0365(8) Uani 1 1 d . . . . .
O2 O 0.56306(12) 0.5801(2) 0.31456(17) 0.0380(8) Uani 1 1 d . . . . .
O6 O 0.40717(12) 0.7216(2) 0.33114(19) 0.0408(8) Uani 1 1 d . . . . .
O9 O 0.48701(12) 0.8240(2) 0.2881(2) 0.0422(9) Uani 1 1 d . . . . .
H9A H 0.511947 0.846823 0.316564 0.063 Uiso 1 1 d R U . . .
H9B H 0.459477 0.846883 0.302414 0.063 Uiso 1 1 d R U . . .
O3 O 0.56851(12) 0.7087(2) 0.26642(18) 0.0394(8) Uani 1 1 d . . . . .
O5 O 0.43864(13) 0.4409(2) 0.1909(2) 0.0513(10) Uani 1 1 d . . . . .
N1 N 0.46361(14) 0.5988(2) 0.41936(19) 0.0298(8) Uani 1 1 d . . . . .
O7 O 0.39276(16) 0.8607(3) 0.3066(4) 0.100(2) Uani 1 1 d . . . . .
O8 O 0.4648(3) 0.6736(5) 0.1819(3) 0.0635(19) Uani 0.653(7) 1 d D U P A 1
N2 N 0.53450(14) 0.7242(2) 0.4205(2) 0.0324(9) Uani 1 1 d . . . . .
C1 C 0.33468(16) 0.5422(3) 0.2667(2) 0.0301(10) Uani 1 1 d . . . . .
H1 H 0.351136 0.593068 0.285220 0.036 Uiso 1 1 calc R U . . .
C2 C 0.36188(16) 0.4811(3) 0.2331(2) 0.0268(9) Uani 1 1 d . . . . .
C3 C 0.64218(17) 0.6194(3) 0.2748(2) 0.0308(10) Uani 1 1 d . . . . .
C4 C 0.19015(17) 0.4316(3) 0.3214(2) 0.0316(10) Uani 1 1 d . . . . .
C5 C 0.17250(18) 0.7525(3) 0.3865(2) 0.0322(11) Uani 1 1 d . . . . .
C6 C 0.42608(18) 0.5412(3) 0.4192(3) 0.0382(11) Uani 1 1 d . . . . .
H6 H 0.409633 0.522019 0.375506 0.046 Uiso 1 1 calc R U . . .
N8 N 0.4447(4) 0.6331(8) 0.0693(5) 0.097(3) Uani 0.653(7) 1 d D U P A 1
C7 C 0.48648(16) 0.6258(3) 0.4831(2) 0.0284(10) Uani 1 1 d . . . . .
C8 C 0.22673(17) 0.7621(3) 0.3748(2) 0.0310(10) Uani 1 1 d . . . . .
C9 C 0.4179(7) 0.6250(12) 0.0000(6) 0.133(5) Uani 0.653(7) 1 d D U P A 1
H9C H 0.435580 0.583651 -0.027273 0.199 Uiso 0.653(7) 1 calc R U P A 1
H9D H 0.383336 0.604495 0.003415 0.199 Uiso 0.653(7) 1 calc R U P A 1
H9E H 0.416527 0.681453 -0.023312 0.199 Uiso 0.653(7) 1 calc R U P A 1
C10 C 0.13665(17) 0.7491(3) 0.3213(2) 0.0303(10) Uani 1 1 d . . . . .
C11 C 0.52479(18) 0.6907(3) 0.4831(2) 0.0314(11) Uani 1 1 d . . . . .
C12 C 0.47338(19) 0.5932(3) 0.5467(2) 0.0363(11) Uani 1 1 d . . . . .
C13 C 0.22617(18) 0.4298(3) 0.3870(2) 0.0340(11) Uani 1 1 d . . . . .
C14 C 0.15724(17) 0.7478(3) 0.4514(2) 0.0324(11) Uani 1 1 d . . . . .
C15 C 0.81698(18) 0.5775(3) 0.1828(2) 0.0324(11) Uani 1 1 d . . . . .
C16 C 0.20486(17) 0.4380(3) 0.2567(2) 0.0301(10) Uani 1 1 d . . . . .
C17 C 0.66924(19) 0.6797(3) 0.2403(3) 0.0351(11) Uani 1 1 d . . . . .
H17 H 0.653246 0.731774 0.223570 0.042 Uiso 1 1 calc R U . . .
C18 C 0.13635(18) 0.4200(3) 0.3339(2) 0.0359(11) Uani 1 1 d . . . . .
C19 C 0.58842(17) 0.6366(3) 0.2857(2) 0.0313(10) Uani 1 1 d . . . . .
C20 C 0.71689(17) 0.5313(3) 0.2912(2) 0.0308(10) Uani 1 1 d . . . . .
H20 H 0.733440 0.481113 0.310854 0.037 Uiso 1 1 calc R U . . .
C21 C 0.79813(17) 0.5738(3) 0.2456(2) 0.0312(10) Uani 1 1 d . . . . .
C22 C 0.83166(17) 0.5574(3) 0.3124(2) 0.0324(11) Uani 1 1 d . . . . .
C23 C 0.66649(16) 0.5448(3) 0.2992(2) 0.0294(10) Uani 1 1 d . . . . .
H23 H 0.648350 0.502244 0.321885 0.035 Uiso 1 1 calc R U . . .
C24 C 0.74402(17) 0.5900(3) 0.2547(2) 0.0313(10) Uani 1 1 d . . . . .
C25 C 0.5003(2) 0.6231(4) 0.6111(3) 0.0486(14) Uani 1 1 d . . . . .
H25 H 0.492036 0.599802 0.654122 0.058 Uiso 1 1 calc R U . . .
C26 C 0.28425(17) 0.5296(3) 0.2734(2) 0.0318(10) Uani 1 1 d . . . . .
H26 H 0.266227 0.571846 0.296457 0.038 Uiso 1 1 calc R U . . .
C27 C 0.41865(17) 0.4905(3) 0.2301(2) 0.0327(11) Uani 1 1 d . . . . .
C28 C 0.24056(18) 0.8269(3) 0.3317(3) 0.0345(11) Uani 1 1 d . . . . .
H28 H 0.215508 0.865958 0.311360 0.041 Uiso 1 1 calc R U . . .
C29 C 0.16933(17) 0.4245(3) 0.1919(2) 0.0320(10) Uani 1 1 d . . . . .
C30 C 0.5494(2) 0.7201(3) 0.5475(3) 0.0407(12) Uani 1 1 d . . . . .
C31 C 0.21785(19) 0.4819(4) 0.4434(3) 0.0421(12) Uani 1 1 d . . . . .
H31 H 0.191002 0.522776 0.438538 0.050 Uiso 1 1 calc R U . . .
C32 C 0.43413(19) 0.5331(3) 0.5445(3) 0.0424(13) Uani 1 1 d . . . . .
H32 H 0.424311 0.510044 0.586716 0.051 Uiso 1 1 calc R U . . .
C33 C 0.31374(18) 0.7121(3) 0.3874(3) 0.0356(11) Uani 1 1 d . . . . .
H33 H 0.338681 0.671682 0.405891 0.043 Uiso 1 1 calc R U . . .
C34 C 0.25889(16) 0.4548(3) 0.2464(2) 0.0290(10) Uani 1 1 d . . . . .
C35 C 0.78445(18) 0.5853(3) 0.1144(2) 0.0349(11) Uani 1 1 d . . . . .
C36 C 0.87229(18) 0.5732(3) 0.1770(3) 0.0352(11) Uani 1 1 d . . . . .
C37 C 0.33674(18) 0.4088(3) 0.2047(2) 0.0369(11) Uani 1 1 d . . . . .
H37 H 0.354837 0.367005 0.181145 0.044 Uiso 1 1 calc R U . . .
C38 C 0.26418(18) 0.7046(3) 0.4033(3) 0.0341(11) Uani 1 1 d . . . . .
H38 H 0.255614 0.659951 0.433809 0.041 Uiso 1 1 calc R U . . .
C39 C 0.5366(2) 0.6832(4) 0.6121(3) 0.0504(15) Uani 1 1 d . . . . .
H39 H 0.554082 0.701434 0.655416 0.061 Uiso 1 1 calc R U . . .
C40 C 0.10363(17) 0.7304(3) 0.4620(2) 0.0348(11) Uani 1 1 d . . . . .
C41 C 0.71889(18) 0.6647(3) 0.2302(3) 0.0361(11) Uani 1 1 d . . . . .
H41 H 0.736480 0.706362 0.205833 0.043 Uiso 1 1 calc R U . . .
C42 C 0.0718(2) 0.7484(4) 0.1965(3) 0.0461(13) Uani 1 1 d . . . . .
H42 H 0.049682 0.748031 0.154128 0.055 Uiso 1 1 calc R U . . .
C43 C 0.89131(19) 0.5166(4) 0.1297(3) 0.0423(12) Uani 1 1 d . . . . .
H43 H 0.868546 0.479656 0.102047 0.051 Uiso 1 1 calc R U . . .
C44 C 0.09238(18) 0.7978(3) 0.3134(3) 0.0375(11) Uani 1 1 d . . . . .
H44 H 0.084139 0.832251 0.351401 0.045 Uiso 1 1 calc R U . . .
C45 C 0.19294(17) 0.7629(3) 0.5168(2) 0.0325(11) Uani 1 1 d . . . . .
C46 C 0.28984(18) 0.8364(3) 0.3176(3) 0.0349(11) Uani 1 1 d . . . . .
H46 H 0.298688 0.882844 0.289080 0.042 Uiso 1 1 calc R U . . .
C47 C 0.14790(18) 0.7005(3) 0.2644(3) 0.0375(11) Uani 1 1 d . . . . .
H47 H 0.178126 0.667210 0.267786 0.045 Uiso 1 1 calc R U . . .
C48 C 0.32670(17) 0.7784(3) 0.3447(3) 0.0349(11) Uani 1 1 d . . . . .
C49 C 0.1232(2) 0.3496(4) 0.3732(3) 0.0451(13) Uani 1 1 d . . . . .
H49 H 0.148717 0.309680 0.390724 0.054 Uiso 1 1 calc R U . . .
C50 C 0.86225(17) 0.4841(3) 0.3220(3) 0.0354(11) Uani 1 1 d . . . . .
H50 H 0.862240 0.442905 0.285381 0.042 Uiso 1 1 calc R U . . .
C51 C 0.28552(18) 0.3961(3) 0.2100(2) 0.0352(11) Uani 1 1 d . . . . .
H51 H 0.268673 0.347134 0.188576 0.042 Uiso 1 1 calc R U . . .
C52 C 0.89254(18) 0.4710(4) 0.3844(3) 0.0468(14) Uani 1 1 d . . . . .
H52 H 0.913631 0.421382 0.390175 0.056 Uiso 1 1 calc R U . . .
C53 C 0.40977(19) 0.5075(3) 0.4814(3) 0.0428(13) Uani 1 1 d . . . . .
H53 H 0.382379 0.467768 0.479320 0.051 Uiso 1 1 calc R U . . .
C54 C 0.0603(2) 0.7976(4) 0.2524(3) 0.0436(13) Uani 1 1 d . . . . .
H54 H 0.030207 0.831264 0.248615 0.052 Uiso 1 1 calc R U . . .
C55 C 0.16832(18) 0.4828(3) 0.1367(2) 0.0392(12) Uani 1 1 d . . . . .
H55 H 0.190843 0.530714 0.140149 0.047 Uiso 1 1 calc R U . . .
C56 C 0.90718(19) 0.6269(3) 0.2156(3) 0.0420(12) Uani 1 1 d . . . . .
H56 H 0.895500 0.666648 0.247805 0.050 Uiso 1 1 calc R U . . .
C57 C 0.1153(2) 0.7002(4) 0.2025(3) 0.0432(13) Uani 1 1 d . . . . .
H57 H 0.123289 0.666226 0.164031 0.052 Uiso 1 1 calc R U . . .
C58 C 0.8922(2) 0.5302(4) 0.4385(3) 0.0506(15) Uani 1 1 d . . . . .
H58 H 0.912944 0.521010 0.481466 0.061 Uiso 1 1 calc R U . . .
C59 C 0.0017(2) 0.7021(4) 0.4742(3) 0.0521(15) Uani 1 1 d . . . . .
H59 H -0.033481 0.693536 0.476366 0.062 Uiso 1 1 calc R U . . .
C60 C 0.56877(19) 0.7868(4) 0.4214(3) 0.0459(13) Uani 1 1 d . . . . .
H60 H 0.575960 0.810480 0.378004 0.055 Uiso 1 1 calc R U . . .
C61 C 0.3797(2) 0.7885(4) 0.3260(3) 0.0513(15) Uani 1 1 d . . . . .
C62 C 0.19381(19) 0.7047(3) 0.5719(3) 0.0392(12) Uani 1 1 d . . . . .
H62 H 0.172507 0.655254 0.566998 0.047 Uiso 1 1 calc R U . . .
C63 C 0.73947(19) 0.5384(3) 0.0999(3) 0.0440(13) Uani 1 1 d . . . . .
H63 H 0.728011 0.502277 0.134880 0.053 Uiso 1 1 calc R U . . .
C64 C 0.8622(2) 0.6016(4) 0.4299(3) 0.0489(14) Uani 1 1 d . . . . .
H64 H 0.862707 0.642747 0.466571 0.059 Uiso 1 1 calc R U . . .
C65 C 0.07705(19) 0.7873(4) 0.4995(3) 0.0431(13) Uani 1 1 d . . . . .
H65 H 0.093786 0.835936 0.521662 0.052 Uiso 1 1 calc R U . . .
C66 C 0.22364(19) 0.8361(3) 0.5258(3) 0.0397(12) Uani 1 1 d . . . . .
H66 H 0.223716 0.877342 0.489217 0.048 Uiso 1 1 calc R U . . .
C67 C 0.5853(2) 0.7867(4) 0.5457(3) 0.0574(16) Uani 1 1 d . . . . .
H67 H 0.602710 0.808596 0.587863 0.069 Uiso 1 1 calc R U . . .
C68 C 0.2656(2) 0.3695(4) 0.3958(3) 0.0448(13) Uani 1 1 d . . . . .
H68 H 0.271905 0.333193 0.357850 0.054 Uiso 1 1 calc R U . . .
C69 C 0.2864(2) 0.4152(4) 0.5147(3) 0.0538(16) Uani 1 1 d . . . . .
H69 H 0.306812 0.409992 0.558334 0.065 Uiso 1 1 calc R U . . .
C70 C 0.83080(19) 0.6149(3) 0.3681(3) 0.0403(12) Uani 1 1 d . . . . .
H70 H 0.808655 0.663267 0.363728 0.048 Uiso 1 1 calc R U . . .
C71 C 0.7993(2) 0.6370(4) 0.0617(3) 0.0485(14) Uani 1 1 d . . . . .
H71 H 0.829843 0.669035 0.070058 0.058 Uiso 1 1 calc R U . . .
C72 C 0.1377(2) 0.3533(4) 0.1838(3) 0.0494(14) Uani 1 1 d . . . . .
H72 H 0.138804 0.311072 0.219800 0.059 Uiso 1 1 calc R U . . .
C73 C 0.2249(2) 0.7171(4) 0.6335(3) 0.0470(13) Uani 1 1 d . . . . .
H73 H 0.225285 0.675845 0.670190 0.056 Uiso 1 1 calc R U . . .
C74 C 0.0984(2) 0.4764(4) 0.3083(3) 0.0472(13) Uani 1 1 d . . . . .
H74 H 0.106014 0.524051 0.280161 0.057 Uiso 1 1 calc R U . . .
C75 C 0.0786(2) 0.6569(3) 0.4338(3) 0.0421(12) Uani 1 1 d . . . . .
H75 H 0.096799 0.615834 0.409643 0.051 Uiso 1 1 calc R U . . .
C76 C 0.2482(2) 0.4749(4) 0.5065(3) 0.0510(15) Uani 1 1 d . . . . .
H76 H 0.242540 0.511768 0.544386 0.061 Uiso 1 1 calc R U . . .
C77 C 0.9758(2) 0.5675(4) 0.1615(3) 0.0559(16) Uani 1 1 d . . . . .
H77 H 1.010962 0.565904 0.156170 0.067 Uiso 1 1 calc R U . . .
C78 C 0.0252(2) 0.7734(4) 0.5052(3) 0.0493(14) Uani 1 1 d . . . . .
H78 H 0.006667 0.813135 0.530124 0.059 Uiso 1 1 calc R U . . .
C79 C 0.0741(2) 0.3365(4) 0.3871(3) 0.0565(16) Uani 1 1 d . . . . .
H79 H 0.065876 0.287596 0.413487 0.068 Uiso 1 1 calc R U . . .
C80 C 0.2554(2) 0.7895(4) 0.6418(3) 0.0502(14) Uani 1 1 d . . . . .
H80 H 0.277120 0.798302 0.684014 0.060 Uiso 1 1 calc R U . . .
C81 C 0.2541(2) 0.8482(4) 0.5885(3) 0.0485(14) Uani 1 1 d . . . . .
H81 H 0.274458 0.898634 0.594624 0.058 Uiso 1 1 calc R U . . .
C82 C 0.1027(2) 0.4013(4) 0.0701(3) 0.0595(17) Uani 1 1 d . . . . .
H82 H 0.079812 0.393648 0.028916 0.071 Uiso 1 1 calc R U . . .
C83 C 0.9580(2) 0.6237(4) 0.2082(3) 0.0531(15) Uani 1 1 d . . . . .
H83 H 0.980940 0.660671 0.235558 0.064 Uiso 1 1 calc R U . . .
C84 C 0.1347(2) 0.4717(4) 0.0767(3) 0.0544(15) Uani 1 1 d . . . . .
H84 H 0.133734 0.512907 0.039986 0.065 Uiso 1 1 calc R U . . .
C85 C 0.0374(2) 0.3938(5) 0.3631(3) 0.0583(17) Uani 1 1 d . . . . .
H85 H 0.003603 0.385586 0.373616 0.070 Uiso 1 1 calc R U . . .
C86 C 0.0489(2) 0.4635(4) 0.3237(3) 0.0567(16) Uani 1 1 d . . . . .
H86 H 0.023048 0.503116 0.306844 0.068 Uiso 1 1 calc R U . . .
C87 C 0.7115(2) 0.5444(4) 0.0345(3) 0.0585(16) Uani 1 1 d . . . . .
H87 H 0.681243 0.511620 0.024701 0.070 Uiso 1 1 calc R U . . .
C88 C 0.9424(2) 0.5130(4) 0.1221(3) 0.0533(15) Uani 1 1 d . . . . .
H88 H 0.954548 0.473367 0.090104 0.064 Uiso 1 1 calc R U . . .
C89 C 0.0285(2) 0.6427(4) 0.4401(3) 0.0526(14) Uani 1 1 d . . . . .
H89 H 0.012319 0.591985 0.420873 0.063 Uiso 1 1 calc R U . . .
C90 C 0.7274(3) 0.5974(5) -0.0158(3) 0.069(2) Uani 1 1 d . . . . .
H90 H 0.707647 0.601901 -0.060080 0.082 Uiso 1 1 calc R U . . .
C91 C 0.2954(2) 0.3623(4) 0.4593(3) 0.0516(14) Uani 1 1 d . . . . .
H91 H 0.322087 0.321143 0.464893 0.062 Uiso 1 1 calc R U . . .
C92 C 0.1044(2) 0.3431(5) 0.1232(3) 0.0650(19) Uani 1 1 d . . . . .
H92 H 0.082443 0.294469 0.118891 0.078 Uiso 1 1 calc R U . . .
C93 C 0.5947(2) 0.8194(4) 0.4828(3) 0.0552(16) Uani 1 1 d . . . . .
H93 H 0.618904 0.864244 0.480796 0.066 Uiso 1 1 calc R U . . .
C94 C 0.7708(3) 0.6433(5) -0.0032(3) 0.0642(18) Uani 1 1 d . . . . .
H94 H 0.781625 0.679612 -0.038484 0.077 Uiso 1 1 calc R U . . .
C95 C 0.3907(5) 0.7416(9) 0.1020(8) 0.102(4) Uani 0.653(7) 1 d D U P A 1
H95A H 0.378293 0.724771 0.053959 0.153 Uiso 0.653(7) 1 calc R U P A 1
H95B H 0.363453 0.735098 0.131937 0.153 Uiso 0.653(7) 1 calc R U P A 1
H95C H 0.401891 0.801960 0.102563 0.153 Uiso 0.653(7) 1 calc R U P A 1
C96 C 0.4340(4) 0.6853(7) 0.1285(5) 0.073(2) Uani 0.653(7) 1 d D U P A 1
O10 O 0.3848(5) 1.0123(8) 0.3834(6) 0.111(4) Uani 0.5 1 d . U P . .
H10G H 0.362400 1.042056 0.356902 0.167 Uiso 0.5 1 d R U P . .
H10H H 0.410190 1.000086 0.360332 0.167 Uiso 0.5 1 d R U P . .
C97 C 0.4890(5) 0.5735(8) 0.0842(8) 0.118(4) Uani 0.653(7) 1 d D U P A 1
H97A H 0.477046 0.513541 0.083738 0.178 Uiso 0.653(7) 1 calc R U P A 1
H97B H 0.506908 0.586897 0.130357 0.178 Uiso 0.653(7) 1 calc R U P A 1
H97C H 0.512139 0.580944 0.048376 0.178 Uiso 0.653(7) 1 calc R U P A 1
O8A O 0.4413(6) 0.7140(11) 0.1930(7) 0.077(3) Uani 0.347(7) 1 d D U P A 2
C98 C 0.4079(8) 0.7415(13) 0.1440(8) 0.085(3) Uani 0.347(7) 1 d D U P A 2
C99 C 0.3707(8) 0.8103(12) 0.1410(13) 0.099(5) Uani 0.347(7) 1 d D U P A 2
H99A H 0.351714 0.811918 0.094240 0.149 Uiso 0.347(7) 1 calc R U P A 2
H99B H 0.347302 0.799835 0.176005 0.149 Uiso 0.347(7) 1 calc R U P A 2
H99C H 0.387964 0.865707 0.150649 0.149 Uiso 0.347(7) 1 calc R U P A 2
N8A N 0.4151(7) 0.6811(11) 0.0864(7) 0.089(3) Uani 0.347(7) 1 d D U P A 2
C100 C 0.4622(6) 0.6319(11) 0.1082(9) 0.066(4) Uani 0.347(7) 1 d D U P A 2
H10A H 0.468940 0.632302 0.159415 0.100 Uiso 0.347(7) 1 calc R U P A 2
H10B H 0.458184 0.572208 0.091628 0.100 Uiso 0.347(7) 1 calc R U P A 2
H10C H 0.490674 0.658875 0.088078 0.100 Uiso 0.347(7) 1 calc R U P A 2
C101 C 0.3938(10) 0.6942(18) 0.0172(8) 0.122(5) Uani 0.347(7) 1 d D U P A 2
H10D H 0.403452 0.646460 -0.012079 0.183 Uiso 0.347(7) 1 calc R U P A 2
H10E H 0.356843 0.696529 0.015501 0.183 Uiso 0.347(7) 1 calc R U P A 2
H10F H 0.406331 0.748777 -0.000190 0.183 Uiso 0.347(7) 1 calc R U P A 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O4 2.299(3) . ?
Eu1 O2 2.475(3) . ?
Eu1 O6 2.352(3) . ?
Eu1 O9 2.398(3) . ?
Eu1 O3 2.456(3) . ?
Eu1 N1 2.629(4) . ?
Eu1 O8 2.321(6) . ?
Eu1 N2 2.623(4) . ?
Eu1 C19 2.834(5) . ?
Eu1 O8A 2.390(14) . ?
O4 C27 1.258(5) . ?
O2 C19 1.269(6) . ?
O6 C61 1.264(6) . ?
O9 H9A 0.8833 . ?
O9 H9B 0.8831 . ?
O3 C19 1.272(6) . ?
O5 C27 1.236(6) . ?
N1 C6 1.337(6) . ?
N1 C7 1.371(6) . ?
O7 C61 1.240(7) . ?
O8 C96 1.252(10) . ?
N2 C11 1.361(6) . ?
N2 C60 1.328(6) . ?
C1 H1 0.9500 . ?
C1 C2 1.392(6) . ?
C1 C26 1.374(6) . ?
C2 C27 1.522(6) . ?
C2 C37 1.384(6) . ?
C3 C17 1.391(7) . ?
C3 C19 1.490(6) . ?
C3 C23 1.379(6) . ?
C4 C13 1.495(6) . ?
C4 C16 1.349(7) . ?
C4 C18 1.486(6) . ?
C5 C8 1.490(6) . ?
C5 C10 1.486(6) . ?
C5 C14 1.357(7) . ?
C6 H6 0.9500 . ?
C6 C53 1.415(7) . ?
N8 C9 1.444(9) . ?
N8 C96 1.449(9) . ?
N8 C97 1.499(9) . ?
C7 C11 1.430(7) . ?
C7 C12 1.402(7) . ?
C8 C28 1.376(7) . ?
C8 C38 1.400(6) . ?
C9 H9C 0.9800 . ?
C9 H9D 0.9800 . ?
C9 H9E 0.9800 . ?
C10 C44 1.390(7) . ?
C10 C47 1.387(7) . ?
C11 C30 1.410(6) . ?
C12 C25 1.434(7) . ?
C12 C32 1.394(7) . ?
C13 C31 1.387(7) . ?
C13 C68 1.398(7) . ?
C14 C40 1.485(6) . ?
C14 C45 1.505(6) . ?
C15 C21 1.359(7) . ?
C15 C35 1.495(6) . ?
C15 C36 1.487(7) . ?
C16 C29 1.491(6) . ?
C16 C34 1.493(6) . ?
C17 H17 0.9500 . ?
C17 C41 1.374(7) . ?
C18 C49 1.393(7) . ?
C18 C74 1.381(7) . ?
C20 H20 0.9500 . ?
C20 C23 1.381(6) . ?
C20 C24 1.396(6) . ?
C21 C22 1.500(6) . ?
C21 C24 1.488(6) . ?
C22 C50 1.396(6) . ?
C22 C70 1.393(7) . ?
C23 H23 0.9500 . ?
C24 C41 1.390(6) . ?
C25 H25 0.9500 . ?
C25 C39 1.339(8) . ?
C26 H26 0.9500 . ?
C26 C34 1.408(6) . ?
C28 H28 0.9500 . ?
C28 C46 1.374(7) . ?
C29 C55 1.390(7) . ?
C29 C72 1.384(7) . ?
C30 C39 1.441(8) . ?
C30 C67 1.407(8) . ?
C31 H31 0.9500 . ?
C31 C76 1.385(7) . ?
C32 H32 0.9500 . ?
C32 C53 1.368(7) . ?
C33 H33 0.9500 . ?
C33 C38 1.389(7) . ?
C33 C48 1.381(7) . ?
C34 C51 1.388(6) . ?
C35 C63 1.399(7) . ?
C35 C71 1.384(7) . ?
C36 C43 1.397(7) . ?
C36 C56 1.394(7) . ?
C37 H37 0.9500 . ?
C37 C51 1.389(7) . ?
C38 H38 0.9500 . ?
C39 H39 0.9500 . ?
C40 C65 1.382(7) . ?
C40 C75 1.395(7) . ?
C41 H41 0.9500 . ?
C42 H42 0.9500 . ?
C42 C54 1.378(8) . ?
C42 C57 1.370(8) . ?
C43 H43 0.9500 . ?
C43 C88 1.382(7) . ?
C44 H44 0.9500 . ?
C44 C54 1.370(7) . ?
C45 C62 1.389(7) . ?
C45 C66 1.395(7) . ?
C46 H46 0.9500 . ?
C46 C48 1.386(7) . ?
C47 H47 0.9500 . ?
C47 C57 1.391(7) . ?
C48 C61 1.499(7) . ?
C49 H49 0.9500 . ?
C49 C79 1.375(8) . ?
C50 H50 0.9500 . ?
C50 C52 1.382(7) . ?
C51 H51 0.9500 . ?
C52 H52 0.9500 . ?
C52 C58 1.387(8) . ?
C53 H53 0.9500 . ?
C54 H54 0.9500 . ?
C55 H55 0.9500 . ?
C55 C84 1.387(7) . ?
C56 H56 0.9500 . ?
C56 C83 1.374(7) . ?
C57 H57 0.9500 . ?
C58 H58 0.9500 . ?
C58 C64 1.362(8) . ?
C59 H59 0.9500 . ?
C59 C78 1.370(8) . ?
C59 C89 1.373(9) . ?
C60 H60 0.9500 . ?
C60 C93 1.394(8) . ?
C62 H62 0.9500 . ?
C62 C73 1.379(7) . ?
C63 H63 0.9500 . ?
C63 C87 1.390(7) . ?
C64 H64 0.9500 . ?
C64 C70 1.388(7) . ?
C65 H65 0.9500 . ?
C65 C78 1.410(7) . ?
C66 H66 0.9500 . ?
C66 C81 1.387(7) . ?
C67 H67 0.9500 . ?
C67 C93 1.358(9) . ?
C68 H68 0.9500 . ?
C68 C91 1.383(7) . ?
C69 H69 0.9500 . ?
C69 C76 1.368(8) . ?
C69 C91 1.384(8) . ?
C70 H70 0.9500 . ?
C71 H71 0.9500 . ?
C71 C94 1.388(8) . ?
C72 H72 0.9500 . ?
C72 C92 1.389(8) . ?
C73 H73 0.9500 . ?
C73 C80 1.382(8) . ?
C74 H74 0.9500 . ?
C74 C86 1.393(8) . ?
C75 H75 0.9500 . ?
C75 C89 1.367(7) . ?
C76 H76 0.9500 . ?
C77 H77 0.9500 . ?
C77 C83 1.372(9) . ?
C77 C88 1.386(8) . ?
C78 H78 0.9500 . ?
C79 H79 0.9500 . ?
C79 C85 1.361(9) . ?
C80 H80 0.9500 . ?
C80 C81 1.367(8) . ?
C81 H81 0.9500 . ?
C82 H82 0.9500 . ?
C82 C84 1.378(8) . ?
C82 C92 1.360(9) . ?
C83 H83 0.9500 . ?
C84 H84 0.9500 . ?
C85 H85 0.9500 . ?
C85 C86 1.372(9) . ?
C86 H86 0.9500 . ?
C87 H87 0.9500 . ?
C87 C90 1.371(9) . ?
C88 H88 0.9500 . ?
C89 H89 0.9500 . ?
C90 H90 0.9500 . ?
C90 C94 1.353(10) . ?
C91 H91 0.9500 . ?
C92 H92 0.9500 . ?
C93 H93 0.9500 . ?
C94 H94 0.9500 . ?
C95 H95A 0.9800 . ?
C95 H95B 0.9800 . ?
C95 H95C 0.9800 . ?
C95 C96 1.485(9) . ?
O10 H10G 0.8700 . ?
O10 H10H 0.8698 . ?
C97 H97A 0.9800 . ?
C97 H97B 0.9800 . ?
C97 H97C 0.9800 . ?
O8A C98 1.292(15) . ?
C98 C99 1.449(10) . ?
C98 N8A 1.477(9) . ?
C99 H99A 0.9800 . ?
C99 H99B 0.9800 . ?
C99 H99C 0.9800 . ?
N8A C100 1.484(9) . ?
N8A C101 1.401(9) . ?
C100 H10A 0.9800 . ?
C100 H10B 0.9800 . ?
C100 H10C 0.9800 . ?
C101 H10D 0.9800 . ?
C101 H10E 0.9800 . ?
C101 H10F 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O4 Eu1 O2 87.21(11) . . ?
O4 Eu1 O6 84.70(12) . . ?
O4 Eu1 O9 144.12(11) . . ?
O4 Eu1 O3 124.93(12) . . ?
O4 Eu1 N1 74.29(11) . . ?
O4 Eu1 O8 71.81(19) . . ?
O4 Eu1 N2 133.80(12) . . ?
O4 Eu1 C19 106.63(13) . . ?
O4 Eu1 O8A 79.0(4) . . ?
O2 Eu1 N1 86.82(11) . . ?
O2 Eu1 N2 76.81(12) . . ?
O2 Eu1 C19 26.55(12) . . ?
O6 Eu1 O2 156.52(11) . . ?
O6 Eu1 O9 73.53(11) . . ?
O6 Eu1 O3 146.06(12) . . ?
O6 Eu1 N1 69.78(11) . . ?
O6 Eu1 N2 93.12(12) . . ?
O6 Eu1 C19 168.10(13) . . ?
O6 Eu1 O8A 75.5(4) . . ?
O9 Eu1 O2 123.09(11) . . ?
O9 Eu1 O3 72.54(11) . . ?
O9 Eu1 N1 121.55(12) . . ?
O9 Eu1 N2 76.68(12) . . ?
O9 Eu1 C19 98.10(13) . . ?
O3 Eu1 O2 53.16(11) . . ?
O3 Eu1 N1 129.43(11) . . ?
O3 Eu1 N2 78.07(12) . . ?
O3 Eu1 C19 26.62(12) . . ?
N1 Eu1 C19 109.21(12) . . ?
O8 Eu1 O2 102.1(2) . . ?
O8 Eu1 O6 96.3(2) . . ?
O8 Eu1 O9 82.4(2) . . ?
O8 Eu1 O3 80.4(2) . . ?
O8 Eu1 N1 144.37(19) . . ?
O8 Eu1 N2 153.59(19) . . ?
O8 Eu1 C19 90.9(2) . . ?
N2 Eu1 N1 61.94(11) . . ?
N2 Eu1 C19 76.48(13) . . ?
O8A Eu1 O2 124.4(4) . . ?
O8A Eu1 O9 68.3(4) . . ?
O8A Eu1 O3 92.9(4) . . ?
O8A Eu1 N1 137.6(4) . . ?
O8A Eu1 N2 144.9(4) . . ?
O8A Eu1 C19 109.7(4) . . ?
C27 O4 Eu1 159.0(3) . . ?
C19 O2 Eu1 92.7(3) . . ?
C61 O6 Eu1 141.0(3) . . ?
Eu1 O9 H9A 110.3 . . ?
Eu1 O9 H9B 109.7 . . ?
H9A O9 H9B 103.7 . . ?
C19 O3 Eu1 93.5(3) . . ?
C6 N1 Eu1 121.0(3) . . ?
C6 N1 C7 117.4(4) . . ?
C7 N1 Eu1 121.2(3) . . ?
C96 O8 Eu1 151.9(8) . . ?
C11 N2 Eu1 121.3(3) . . ?
C60 N2 Eu1 121.1(3) . . ?
C60 N2 C11 117.6(4) . . ?
C2 C1 H1 119.7 . . ?
C26 C1 H1 119.7 . . ?
C26 C1 C2 120.6(4) . . ?
C1 C2 C27 121.4(4) . . ?
C37 C2 C1 118.7(4) . . ?
C37 C2 C27 119.8(4) . . ?
C17 C3 C19 120.1(4) . . ?
C23 C3 C17 118.5(4) . . ?
C23 C3 C19 121.4(4) . . ?
C16 C4 C13 123.7(4) . . ?
C16 C4 C18 122.8(4) . . ?
C18 C4 C13 113.4(4) . . ?
C10 C5 C8 114.5(4) . . ?
C14 C5 C8 122.5(4) . . ?
C14 C5 C10 122.9(4) . . ?
N1 C6 H6 118.6 . . ?
N1 C6 C53 122.9(5) . . ?
C53 C6 H6 118.6 . . ?
C9 N8 C96 130.8(12) . . ?
C9 N8 C97 114.8(12) . . ?
C96 N8 C97 114.3(10) . . ?
N1 C7 C11 117.2(4) . . ?
N1 C7 C12 122.8(4) . . ?
C12 C7 C11 120.0(4) . . ?
C28 C8 C5 119.4(4) . . ?
C28 C8 C38 118.2(4) . . ?
C38 C8 C5 122.2(4) . . ?
N8 C9 H9C 109.5 . . ?
N8 C9 H9D 109.5 . . ?
N8 C9 H9E 109.5 . . ?
H9C C9 H9D 109.5 . . ?
H9C C9 H9E 109.5 . . ?
H9D C9 H9E 109.5 . . ?
C44 C10 C5 121.8(4) . . ?
C47 C10 C5 120.6(4) . . ?
C47 C10 C44 117.5(4) . . ?
N2 C11 C7 118.3(4) . . ?
N2 C11 C30 122.6(5) . . ?
C30 C11 C7 119.0(4) . . ?
C7 C12 C25 119.2(5) . . ?
C32 C12 C7 118.1(4) . . ?
C32 C12 C25 122.7(5) . . ?
C31 C13 C4 120.3(4) . . ?
C31 C13 C68 118.5(4) . . ?
C68 C13 C4 120.8(4) . . ?
C5 C14 C40 121.7(4) . . ?
C5 C14 C45 122.3(4) . . ?
C40 C14 C45 115.9(4) . . ?
C21 C15 C35 123.4(4) . . ?
C21 C15 C36 122.1(4) . . ?
C36 C15 C35 114.5(4) . . ?
C4 C16 C29 122.6(4) . . ?
C4 C16 C34 121.2(4) . . ?
C29 C16 C34 116.1(4) . . ?
C3 C17 H17 119.7 . . ?
C41 C17 C3 120.6(4) . . ?
C41 C17 H17 119.7 . . ?
C49 C18 C4 119.1(5) . . ?
C74 C18 C4 122.9(5) . . ?
C74 C18 C49 118.0(5) . . ?
O2 C19 Eu1 60.7(2) . . ?
O2 C19 O3 120.5(4) . . ?
O2 C19 C3 120.2(4) . . ?
O3 C19 Eu1 59.9(2) . . ?
O3 C19 C3 119.3(4) . . ?
C3 C19 Eu1 178.4(3) . . ?
C23 C20 H20 119.3 . . ?
C23 C20 C24 121.3(4) . . ?
C24 C20 H20 119.3 . . ?
C15 C21 C22 121.7(4) . . ?
C15 C21 C24 123.7(4) . . ?
C24 C21 C22 114.6(4) . . ?
C50 C22 C21 122.1(4) . . ?
C70 C22 C21 119.4(4) . . ?
C70 C22 C50 118.5(4) . . ?
C3 C23 C20 120.7(4) . . ?
C3 C23 H23 119.6 . . ?
C20 C23 H23 119.6 . . ?
C20 C24 C21 120.6(4) . . ?
C41 C24 C20 117.1(4) . . ?
C41 C24 C21 122.2(4) . . ?
C12 C25 H25 119.2 . . ?
C39 C25 C12 121.6(5) . . ?
C39 C25 H25 119.2 . . ?
C1 C26 H26 119.5 . . ?
C1 C26 C34 120.9(4) . . ?
C34 C26 H26 119.5 . . ?
O4 C27 C2 116.7(4) . . ?
O5 C27 O4 125.9(4) . . ?
O5 C27 C2 117.4(4) . . ?
C8 C28 H28 119.3 . . ?
C46 C28 C8 121.4(4) . . ?
C46 C28 H28 119.3 . . ?
C55 C29 C16 120.2(4) . . ?
C72 C29 C16 121.7(4) . . ?
C72 C29 C55 118.2(4) . . ?
C11 C30 C39 119.9(5) . . ?
C67 C30 C11 117.6(5) . . ?
C67 C30 C39 122.6(5) . . ?
C13 C31 H31 119.6 . . ?
C76 C31 C13 120.7(5) . . ?
C76 C31 H31 119.6 . . ?
C12 C32 H32 120.1 . . ?
C53 C32 C12 119.9(5) . . ?
C53 C32 H32 120.1 . . ?
C38 C33 H33 120.1 . . ?
C48 C33 H33 120.1 . . ?
C48 C33 C38 119.9(4) . . ?
C26 C34 C16 121.4(4) . . ?
C51 C34 C16 120.3(4) . . ?
C51 C34 C26 118.3(4) . . ?
C63 C35 C15 122.0(4) . . ?
C71 C35 C15 120.5(5) . . ?
C71 C35 C63 117.4(5) . . ?
C43 C36 C15 120.6(4) . . ?
C56 C36 C15 122.4(4) . . ?
C56 C36 C43 116.9(5) . . ?
C2 C37 H37 119.4 . . ?
C2 C37 C51 121.2(4) . . ?
C51 C37 H37 119.4 . . ?
C8 C38 H38 119.7 . . ?
C33 C38 C8 120.7(4) . . ?
C33 C38 H38 119.7 . . ?
C25 C39 C30 120.2(5) . . ?
C25 C39 H39 119.9 . . ?
C30 C39 H39 119.9 . . ?
C65 C40 C14 120.6(5) . . ?
C65 C40 C75 118.3(5) . . ?
C75 C40 C14 121.1(4) . . ?
C17 C41 C24 121.6(4) . . ?
C17 C41 H41 119.2 . . ?
C24 C41 H41 119.2 . . ?
C54 C42 H42 120.2 . . ?
C57 C42 H42 120.2 . . ?
C57 C42 C54 119.7(5) . . ?
C36 C43 H43 119.2 . . ?
C88 C43 C36 121.7(5) . . ?
C88 C43 H43 119.2 . . ?
C10 C44 H44 119.0 . . ?
C54 C44 C10 122.0(5) . . ?
C54 C44 H44 119.0 . . ?
C62 C45 C14 119.4(4) . . ?
C62 C45 C66 118.2(4) . . ?
C66 C45 C14 122.3(4) . . ?
C28 C46 H46 119.8 . . ?
C28 C46 C48 120.3(4) . . ?
C48 C46 H46 119.8 . . ?
C10 C47 H47 119.7 . . ?
C10 C47 C57 120.6(5) . . ?
C57 C47 H47 119.7 . . ?
C33 C48 C46 119.5(4) . . ?
C33 C48 C61 121.6(4) . . ?
C46 C48 C61 119.0(4) . . ?
C18 C49 H49 119.3 . . ?
C79 C49 C18 121.4(6) . . ?
C79 C49 H49 119.3 . . ?
C22 C50 H50 119.8 . . ?
C52 C50 C22 120.5(5) . . ?
C52 C50 H50 119.8 . . ?
C34 C51 C37 120.2(4) . . ?
C34 C51 H51 119.9 . . ?
C37 C51 H51 119.9 . . ?
C50 C52 H52 119.9 . . ?
C50 C52 C58 120.2(5) . . ?
C58 C52 H52 119.9 . . ?
C6 C53 H53 120.6 . . ?
C32 C53 C6 118.9(5) . . ?
C32 C53 H53 120.6 . . ?
C42 C54 H54 120.1 . . ?
C44 C54 C42 119.8(5) . . ?
C44 C54 H54 120.1 . . ?
C29 C55 H55 119.7 . . ?
C84 C55 C29 120.6(5) . . ?
C84 C55 H55 119.7 . . ?
C36 C56 H56 119.1 . . ?
C83 C56 C36 121.7(5) . . ?
C83 C56 H56 119.1 . . ?
C42 C57 C47 120.5(5) . . ?
C42 C57 H57 119.8 . . ?
C47 C57 H57 119.8 . . ?
C52 C58 H58 120.1 . . ?
C64 C58 C52 119.8(5) . . ?
C64 C58 H58 120.1 . . ?
C78 C59 H59 119.6 . . ?
C78 C59 C89 120.8(5) . . ?
C89 C59 H59 119.6 . . ?
N2 C60 H60 118.4 . . ?
N2 C60 C93 123.2(5) . . ?
C93 C60 H60 118.4 . . ?
O6 C61 C48 116.4(5) . . ?
O7 C61 O6 125.6(5) . . ?
O7 C61 C48 118.0(5) . . ?
C45 C62 H62 119.2 . . ?
C73 C62 C45 121.5(5) . . ?
C73 C62 H62 119.2 . . ?
C35 C63 H63 119.9 . . ?
C87 C63 C35 120.3(5) . . ?
C87 C63 H63 119.9 . . ?
C58 C64 H64 119.6 . . ?
C58 C64 C70 120.8(5) . . ?
C70 C64 H64 119.6 . . ?
C40 C65 H65 119.9 . . ?
C40 C65 C78 120.2(5) . . ?
C78 C65 H65 119.9 . . ?
C45 C66 H66 120.2 . . ?
C81 C66 C45 119.5(5) . . ?
C81 C66 H66 120.2 . . ?
C30 C67 H67 120.4 . . ?
C93 C67 C30 119.2(5) . . ?
C93 C67 H67 120.4 . . ?
C13 C68 H68 119.8 . . ?
C91 C68 C13 120.4(5) . . ?
C91 C68 H68 119.8 . . ?
C76 C69 H69 120.0 . . ?
C76 C69 C91 120.1(5) . . ?
C91 C69 H69 120.0 . . ?
C22 C70 H70 119.9 . . ?
C64 C70 C22 120.2(5) . . ?
C64 C70 H70 119.9 . . ?
C35 C71 H71 119.0 . . ?
C35 C71 C94 121.9(6) . . ?
C94 C71 H71 119.0 . . ?
C29 C72 H72 119.8 . . ?
C29 C72 C92 120.4(5) . . ?
C92 C72 H72 119.8 . . ?
C62 C73 H73 120.0 . . ?
C62 C73 C80 119.9(5) . . ?
C80 C73 H73 120.0 . . ?
C18 C74 H74 119.9 . . ?
C18 C74 C86 120.1(6) . . ?
C86 C74 H74 119.9 . . ?
C40 C75 H75 119.3 . . ?
C89 C75 C40 121.5(5) . . ?
C89 C75 H75 119.3 . . ?
C31 C76 H76 119.9 . . ?
C69 C76 C31 120.3(5) . . ?
C69 C76 H76 119.9 . . ?
C83 C77 H77 120.1 . . ?
C83 C77 C88 119.8(5) . . ?
C88 C77 H77 120.1 . . ?
C59 C78 C65 119.3(5) . . ?
C59 C78 H78 120.4 . . ?
C65 C78 H78 120.4 . . ?
C49 C79 H79 120.1 . . ?
C85 C79 C49 119.8(6) . . ?
C85 C79 H79 120.1 . . ?
C73 C80 H80 120.5 . . ?
C81 C80 C73 119.1(5) . . ?
C81 C80 H80 120.5 . . ?
C66 C81 H81 119.1 . . ?
C80 C81 C66 121.8(5) . . ?
C80 C81 H81 119.1 . . ?
C84 C82 H82 120.5 . . ?
C92 C82 H82 120.5 . . ?
C92 C82 C84 119.1(5) . . ?
C56 C83 H83 119.8 . . ?
C77 C83 C56 120.3(6) . . ?
C77 C83 H83 119.8 . . ?
C55 C84 H84 119.7 . . ?
C82 C84 C55 120.5(5) . . ?
C82 C84 H84 119.7 . . ?
C79 C85 H85 119.9 . . ?
C79 C85 C86 120.3(5) . . ?
C86 C85 H85 119.9 . . ?
C74 C86 H86 119.9 . . ?
C85 C86 C74 120.3(6) . . ?
C85 C86 H86 119.9 . . ?
C63 C87 H87 119.9 . . ?
C90 C87 C63 120.2(6) . . ?
C90 C87 H87 119.9 . . ?
C43 C88 C77 119.6(5) . . ?
C43 C88 H88 120.2 . . ?
C77 C88 H88 120.2 . . ?
C59 C89 H89 120.1 . . ?
C75 C89 C59 119.8(6) . . ?
C75 C89 H89 120.1 . . ?
C87 C90 H90 119.6 . . ?
C94 C90 C87 120.8(6) . . ?
C94 C90 H90 119.6 . . ?
C68 C91 C69 120.0(5) . . ?
C68 C91 H91 120.0 . . ?
C69 C91 H91 120.0 . . ?
C72 C92 H92 119.4 . . ?
C82 C92 C72 121.2(6) . . ?
C82 C92 H92 119.4 . . ?
C60 C93 H93 120.1 . . ?
C67 C93 C60 119.8(5) . . ?
C67 C93 H93 120.1 . . ?
C71 C94 H94 120.3 . . ?
C90 C94 C71 119.4(6) . . ?
C90 C94 H94 120.3 . . ?
H95A C95 H95B 109.5 . . ?
H95A C95 H95C 109.5 . . ?
H95B C95 H95C 109.5 . . ?
C96 C95 H95A 109.5 . . ?
C96 C95 H95B 109.5 . . ?
C96 C95 H95C 109.5 . . ?
O8 C96 N8 113.3(9) . . ?
O8 C96 C95 140.8(11) . . ?
N8 C96 C95 105.7(10) . . ?
H10G O10 H10H 109.5 . . ?
N8 C97 H97A 109.5 . . ?
N8 C97 H97B 109.5 . . ?
N8 C97 H97C 109.5 . . ?
H97A C97 H97B 109.5 . . ?
H97A C97 H97C 109.5 . . ?
H97B C97 H97C 109.5 . . ?
C98 O8A Eu1 164.9(14) . . ?
O8A C98 C99 132.8(16) . . ?
O8A C98 N8A 101.6(11) . . ?
C99 C98 N8A 125.5(13) . . ?
C98 C99 H99A 109.5 . . ?
C98 C99 H99B 109.5 . . ?
C98 C99 H99C 109.5 . . ?
H99A C99 H99B 109.5 . . ?
H99A C99 H99C 109.5 . . ?
H99B C99 H99C 109.5 . . ?
C98 N8A C100 106.8(9) . . ?
C101 N8A C98 123.2(10) . . ?
C101 N8A C100 125.5(10) . . ?
N8A C100 H10A 109.5 . . ?
N8A C100 H10B 109.5 . . ?
N8A C100 H10C 109.5 . . ?
H10A C100 H10B 109.5 . . ?
H10A C100 H10C 109.5 . . ?
H10B C100 H10C 109.5 . . ?
N8A C101 H10D 109.5 . . ?
N8A C101 H10E 109.5 . . ?
N8A C101 H10F 109.5 . . ?
H10D C101 H10E 109.5 . . ?
H10D C101 H10F 109.5 . . ?
H10E C101 H10F 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Eu1 O4 C27 O5 69.0(10) . . . . ?
Eu1 O4 C27 C2 -113.4(8) . . . . ?
Eu1 O2 C19 O3 2.2(5) . . . . ?
Eu1 O2 C19 C3 -178.5(4) . . . . ?
Eu1 O6 C61 O7 -9.6(11) . . . . ?
Eu1 O6 C61 C48 169.9(3) . . . . ?
Eu1 O3 C19 O2 -2.3(5) . . . . ?
Eu1 O3 C19 C3 178.5(4) . . . . ?
Eu1 N1 C6 C53 -173.7(4) . . . . ?
Eu1 N1 C7 C11 -3.6(5) . . . . ?
Eu1 N1 C7 C12 175.8(3) . . . . ?
Eu1 O8 C96 N8 -150.4(11) . . . . ?
Eu1 O8 C96 C95 36(3) . . . . ?
Eu1 N2 C11 C7 -0.9(6) . . . . ?
Eu1 N2 C11 C30 -178.1(3) . . . . ?
Eu1 N2 C60 C93 178.1(4) . . . . ?
Eu1 O8A C98 C99 40(7) . . . . ?
Eu1 O8A C98 N8A -139(5) . . . . ?
N1 C6 C53 C32 -1.6(8) . . . . ?
N1 C7 C11 N2 2.9(6) . . . . ?
N1 C7 C11 C30 -179.7(4) . . . . ?
N1 C7 C12 C25 178.1(4) . . . . ?
N1 C7 C12 C32 -2.4(7) . . . . ?
N2 C11 C30 C39 178.7(5) . . . . ?
N2 C11 C30 C67 0.0(7) . . . . ?
N2 C60 C93 C67 0.0(9) . . . . ?
C1 C2 C27 O4 12.6(6) . . . . ?
C1 C2 C27 O5 -169.7(4) . . . . ?
C1 C2 C37 C51 -0.8(7) . . . . ?
C1 C26 C34 C16 176.6(4) . . . . ?
C1 C26 C34 C51 -3.0(7) . . . . ?
C2 C1 C26 C34 -0.1(7) . . . . ?
C2 C37 C51 C34 -2.4(7) . . . . ?
C3 C17 C41 C24 -1.0(8) . . . . ?
C4 C13 C31 C76 174.0(5) . . . . ?
C4 C13 C68 C91 -173.2(5) . . . . ?
C4 C16 C29 C55 133.1(5) . . . . ?
C4 C16 C29 C72 -48.8(7) . . . . ?
C4 C16 C34 C26 -59.3(6) . . . . ?
C4 C16 C34 C51 120.3(5) . . . . ?
C4 C18 C49 C79 179.1(5) . . . . ?
C4 C18 C74 C86 -178.0(5) . . . . ?
C5 C8 C28 C46 -177.7(4) . . . . ?
C5 C8 C38 C33 175.6(4) . . . . ?
C5 C10 C44 C54 177.3(5) . . . . ?
C5 C10 C47 C57 -177.4(4) . . . . ?
C5 C14 C40 C65 -123.3(5) . . . . ?
C5 C14 C40 C75 55.9(7) . . . . ?
C5 C14 C45 C62 -132.0(5) . . . . ?
C5 C14 C45 C66 51.5(7) . . . . ?
C6 N1 C7 C11 -176.8(4) . . . . ?
C6 N1 C7 C12 2.5(6) . . . . ?
C7 N1 C6 C53 -0.5(7) . . . . ?
C7 C11 C30 C39 1.5(7) . . . . ?
C7 C11 C30 C67 -177.2(5) . . . . ?
C7 C12 C25 C39 1.8(8) . . . . ?
C7 C12 C32 C53 0.2(7) . . . . ?
C8 C5 C10 C44 -133.3(5) . . . . ?
C8 C5 C10 C47 42.9(6) . . . . ?
C8 C5 C14 C40 -174.4(4) . . . . ?
C8 C5 C14 C45 7.6(7) . . . . ?
C8 C28 C46 C48 2.3(7) . . . . ?
C9 N8 C96 O8 177.5(13) . . . . ?
C9 N8 C96 C95 -6.7(18) . . . . ?
C10 C5 C8 C28 51.2(6) . . . . ?
C10 C5 C8 C38 -125.4(5) . . . . ?
C10 C5 C14 C40 6.1(7) . . . . ?
C10 C5 C14 C45 -171.8(4) . . . . ?
C10 C44 C54 C42 -0.4(8) . . . . ?
C10 C47 C57 C42 0.6(8) . . . . ?
C11 N2 C60 C93 -0.2(8) . . . . ?
C11 C7 C12 C25 -2.5(7) . . . . ?
C11 C7 C12 C32 176.9(4) . . . . ?
C11 C30 C39 C25 -2.3(8) . . . . ?
C11 C30 C67 C93 -0.2(8) . . . . ?
C12 C7 C11 N2 -176.4(4) . . . . ?
C12 C7 C11 C30 0.9(7) . . . . ?
C12 C25 C39 C30 0.6(8) . . . . ?
C12 C32 C53 C6 1.7(7) . . . . ?
C13 C4 C16 C29 169.2(4) . . . . ?
C13 C4 C16 C34 -7.6(7) . . . . ?
C13 C4 C18 C49 -52.4(6) . . . . ?
C13 C4 C18 C74 127.4(5) . . . . ?
C13 C31 C76 C69 -1.2(8) . . . . ?
C13 C68 C91 C69 -0.1(9) . . . . ?
C14 C5 C8 C28 -128.3(5) . . . . ?
C14 C5 C8 C38 55.1(7) . . . . ?
C14 C5 C10 C44 46.2(7) . . . . ?
C14 C5 C10 C47 -137.6(5) . . . . ?
C14 C40 C65 C78 175.5(4) . . . . ?
C14 C40 C75 C89 -176.4(5) . . . . ?
C14 C45 C62 C73 -178.2(5) . . . . ?
C14 C45 C66 C81 177.1(5) . . . . ?
C15 C21 C22 C50 -56.9(6) . . . . ?
C15 C21 C22 C70 126.1(5) . . . . ?
C15 C21 C24 C20 129.3(5) . . . . ?
C15 C21 C24 C41 -53.2(7) . . . . ?
C15 C35 C63 C87 -177.0(5) . . . . ?
C15 C35 C71 C94 177.8(5) . . . . ?
C15 C36 C43 C88 178.4(5) . . . . ?
C15 C36 C56 C83 -178.2(5) . . . . ?
C16 C4 C13 C31 132.5(5) . . . . ?
C16 C4 C13 C68 -54.4(7) . . . . ?
C16 C4 C18 C49 124.0(5) . . . . ?
C16 C4 C18 C74 -56.1(7) . . . . ?
C16 C29 C55 C84 -178.7(5) . . . . ?
C16 C29 C72 C92 179.0(5) . . . . ?
C16 C34 C51 C37 -175.4(4) . . . . ?
C17 C3 C19 O2 177.1(4) . . . . ?
C17 C3 C19 O3 -3.6(7) . . . . ?
C17 C3 C23 C20 1.6(7) . . . . ?
C18 C4 C13 C31 -51.2(6) . . . . ?
C18 C4 C13 C68 122.0(5) . . . . ?
C18 C4 C16 C29 -6.9(7) . . . . ?
C18 C4 C16 C34 176.4(4) . . . . ?
C18 C49 C79 C85 -0.9(8) . . . . ?
C18 C74 C86 C85 -1.4(8) . . . . ?
C19 C3 C17 C41 179.8(4) . . . . ?
C19 C3 C23 C20 -177.4(4) . . . . ?
C20 C24 C41 C17 -1.0(7) . . . . ?
C21 C15 C35 C63 -41.7(7) . . . . ?
C21 C15 C35 C71 141.1(5) . . . . ?
C21 C15 C36 C43 130.9(5) . . . . ?
C21 C15 C36 C56 -51.7(7) . . . . ?
C21 C22 C50 C52 -179.8(4) . . . . ?
C21 C22 C70 C64 -178.9(5) . . . . ?
C21 C24 C41 C17 -178.6(4) . . . . ?
C22 C21 C24 C20 -53.9(6) . . . . ?
C22 C21 C24 C41 123.5(5) . . . . ?
C22 C50 C52 C58 1.0(7) . . . . ?
C23 C3 C17 C41 0.7(7) . . . . ?
C23 C3 C19 O2 -3.9(7) . . . . ?
C23 C3 C19 O3 175.3(4) . . . . ?
C23 C20 C24 C21 -179.1(4) . . . . ?
C23 C20 C24 C41 3.4(7) . . . . ?
C24 C20 C23 C3 -3.7(7) . . . . ?
C24 C21 C22 C50 126.3(5) . . . . ?
C24 C21 C22 C70 -50.7(6) . . . . ?
C25 C12 C32 C53 179.7(5) . . . . ?
C26 C1 C2 C27 -175.3(4) . . . . ?
C26 C1 C2 C37 2.0(7) . . . . ?
C26 C34 C51 C37 4.2(7) . . . . ?
C27 C2 C37 C51 176.5(4) . . . . ?
C28 C8 C38 C33 -1.1(7) . . . . ?
C28 C46 C48 C33 -1.4(7) . . . . ?
C28 C46 C48 C61 177.7(5) . . . . ?
C29 C16 C34 C26 123.7(5) . . . . ?
C29 C16 C34 C51 -56.7(6) . . . . ?
C29 C55 C84 C82 -1.8(9) . . . . ?
C29 C72 C92 C82 1.4(10) . . . . ?
C30 C67 C93 C60 0.2(9) . . . . ?
C31 C13 C68 C91 0.0(8) . . . . ?
C32 C12 C25 C39 -177.6(5) . . . . ?
C33 C48 C61 O6 22.1(8) . . . . ?
C33 C48 C61 O7 -158.4(6) . . . . ?
C34 C16 C29 C55 -50.0(6) . . . . ?
C34 C16 C29 C72 128.2(5) . . . . ?
C35 C15 C21 C22 174.0(4) . . . . ?
C35 C15 C21 C24 -9.4(7) . . . . ?
C35 C15 C36 C43 -48.6(6) . . . . ?
C35 C15 C36 C56 128.8(5) . . . . ?
C35 C63 C87 C90 -1.0(8) . . . . ?
C35 C71 C94 C90 -0.5(10) . . . . ?
C36 C15 C21 C22 -5.4(7) . . . . ?
C36 C15 C21 C24 171.2(4) . . . . ?
C36 C15 C35 C63 137.7(5) . . . . ?
C36 C15 C35 C71 -39.4(6) . . . . ?
C36 C43 C88 C77 -0.9(8) . . . . ?
C36 C56 C83 C77 0.7(8) . . . . ?
C37 C2 C27 O4 -164.7(4) . . . . ?
C37 C2 C27 O5 13.1(7) . . . . ?
C38 C8 C28 C46 -1.0(7) . . . . ?
C38 C33 C48 C46 -0.6(7) . . . . ?
C38 C33 C48 C61 -179.7(5) . . . . ?
C39 C30 C67 C93 -178.9(6) . . . . ?
C40 C14 C45 C62 50.0(6) . . . . ?
C40 C14 C45 C66 -126.6(5) . . . . ?
C40 C65 C78 C59 1.3(8) . . . . ?
C40 C75 C89 C59 0.7(8) . . . . ?
C43 C36 C56 C83 -0.7(8) . . . . ?
C44 C10 C47 C57 -1.0(7) . . . . ?
C45 C14 C40 C65 54.7(6) . . . . ?
C45 C14 C40 C75 -126.0(5) . . . . ?
C45 C62 C73 C80 1.1(8) . . . . ?
C45 C66 C81 C80 1.0(8) . . . . ?
C46 C48 C61 O6 -157.0(5) . . . . ?
C46 C48 C61 O7 22.5(9) . . . . ?
C47 C10 C44 C54 0.9(7) . . . . ?
C48 C33 C38 C8 1.9(7) . . . . ?
C49 C18 C74 C86 1.9(7) . . . . ?
C49 C79 C85 C86 1.5(9) . . . . ?
C50 C22 C70 C64 4.0(7) . . . . ?
C50 C52 C58 C64 -0.4(8) . . . . ?
C52 C58 C64 C70 1.6(8) . . . . ?
C54 C42 C57 C47 0.0(8) . . . . ?
C55 C29 C72 C92 -2.9(8) . . . . ?
C56 C36 C43 C88 0.9(7) . . . . ?
C57 C42 C54 C44 -0.1(8) . . . . ?
C58 C64 C70 C22 -3.5(8) . . . . ?
C60 N2 C11 C7 177.4(4) . . . . ?
C60 N2 C11 C30 0.2(7) . . . . ?
C62 C45 C66 C81 0.5(7) . . . . ?
C62 C73 C80 C81 0.4(8) . . . . ?
C63 C35 C71 C94 0.6(8) . . . . ?
C63 C87 C90 C94 1.2(10) . . . . ?
C65 C40 C75 C89 2.8(8) . . . . ?
C66 C45 C62 C73 -1.5(7) . . . . ?
C67 C30 C39 C25 176.4(5) . . . . ?
C68 C13 C31 C76 0.7(8) . . . . ?
C70 C22 C50 C52 -2.7(7) . . . . ?
C71 C35 C63 C87 0.2(7) . . . . ?
C72 C29 C55 C84 3.1(8) . . . . ?
C73 C80 C81 C66 -1.4(8) . . . . ?
C74 C18 C49 C79 -0.8(8) . . . . ?
C75 C40 C65 C78 -3.8(7) . . . . ?
C76 C69 C91 C68 -0.4(9) . . . . ?
C78 C59 C89 C75 -3.3(9) . . . . ?
C79 C85 C86 C74 -0.3(9) . . . . ?
C83 C77 C88 C43 0.8(9) . . . . ?
C84 C82 C92 C72 0.0(10) . . . . ?
C87 C90 C94 C71 -0.4(10) . . . . ?
C88 C77 C83 C56 -0.7(9) . . . . ?
C89 C59 C78 C65 2.3(8) . . . . ?
C91 C69 C76 C31 1.1(9) . . . . ?
C92 C82 C84 C55 0.2(10) . . . . ?
C97 N8 C96 O8 2.0(14) . . . . ?
C97 N8 C96 C95 177.7(10) . . . . ?
O8A C98 N8A C100 -11(2) . . . . ?
O8A C98 N8A C101 -168(2) . . . . ?
C99 C98 N8A C100 171(2) . . . . ?
C99 C98 N8A C101 14(3) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
