# Electronic Supplementary Material (ESI) for Inorganic Chemistry Frontiers.
# This journal is © the Partner Organisations 2023

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 2277762'
loop_
_audit_author_name
_audit_author_address
'Mohamed Saber Lassoued'
;School of Chemistry
China
;
_audit_update_record             
;
2023-06-29 deposited with the CCDC.	2023-09-11 downloaded from the CCDC.
;
_audit_creation_date             2023-03-24
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_chemical_name_common            ?
_chemical_name_systematic        
;
 ? 
;
_chemical_formula_moiety         '2(Cl7 Pb2.5), 2(C6 H16 N2)'
_chemical_formula_sum            'C12 H32 Cl14 N4 Pb5'
_chemical_formula_weight         1764.72
_chemical_absolute_configuration ad
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pb Pb -3.3944 10.1111 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      orthorhombic
_space_group_IT_number           46
_space_group_name_H-M_alt        'I m a 2'
_space_group_name_Hall           'I 2 -2a'
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 'x, y, z'
2 '-x, -y, z'
3 '-x+1/2, y, z'
4 'x+1/2, -y, z'
5 'x+1/2, y+1/2, z+1/2'
6 '-x+1/2, -y+1/2, z+1/2'
7 '-x+1, y+1/2, z+1/2'
8 'x+1, -y+1/2, z+1/2'

_cell_length_a                   33.357(7)
_cell_length_b                   11.422(2)
_cell_length_c                   18.500(4)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_volume                     7049(2)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    9079
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      28.86
_cell_measurement_theta_min      2.20
_exptl_absorpt_coefficient_mu    24.881
_exptl_absorpt_correction_T_max  0.7458
_exptl_absorpt_correction_T_min  0.4171
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2008/1 (Bruker,2008) was used for absorption correction.
wR2(int) was 0.1261 before and 0.0651 after correction.
The Ratio of minimum to maximum transmission is 0.5593.
The λ/2 correction factor is 0.0015.
;
_exptl_crystal_colour            ?
_exptl_crystal_density_diffrn    3.326
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             6240
_exptl_crystal_size_max          0.34
_exptl_crystal_size_mid          0.27
_exptl_crystal_size_min          0.14
_exptl_special_details           
;
 ? 
;
_diffrn_reflns_av_R_equivalents  0.0473
_diffrn_reflns_av_unetI/netI     0.0535
_diffrn_reflns_limit_h_max       44
_diffrn_reflns_limit_h_min       -44
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            30330
_diffrn_reflns_theta_full        28.89
_diffrn_reflns_theta_max         28.89
_diffrn_reflns_theta_min         1.88
_diffrn_ambient_temperature      296.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.950
_diffrn_measured_fraction_theta_max 0.950
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'fine-focus sealed tube'
_diffrn_standards_decay_%        ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_number         0
_reflns_number_gt                7919
_reflns_number_total             8704
_reflns_threshold_expression     >2sigma(I)
_computing_cell_refinement       'SAINT V8.18C (?, 2016)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.18C (?, 2016)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL (Sheldrick, 2008)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         1.501
_refine_diff_density_min         -2.220
_refine_diff_density_rms         0.273
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.340(9)
_refine_ls_extinction_coef       ?
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.063
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_parameters     331
_refine_ls_number_reflns         8704
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.0467
_refine_ls_R_factor_gt           0.0402
_refine_ls_restrained_S_all      1.063
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0250P)²+219.2989P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0886
_refine_ls_wR_factor_ref         0.0909
_refine_special_details          
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;
_olex2_refinement_description    
;
1. Others
 Fixed U12: Pb2(0) Pb4(0) Pb3(0) Cl10(0) Cl6(0) Cl7(0) Cl9(0) Cl2(0) Cl4(0)
 Fixed U13: Pb2(0) Pb4(0) Pb3(0) Pb7(0) Cl10(0) Cl6(0) Cl7(0) Cl9(0) Cl2(0)
 Cl4(0) Cl13(0) Cl16(0)
 Fixed U23: Pb7(0) Cl13(0) Cl16(0)
 Fixed Uiso: H3(0.022) H1(0.022) H4A(0.031) H4B(0.031) H4C(0.031) H7A(0.027)
 H7B(0.027) H4D(0.023) H4E(0.023) H2A(0.027) H2B(0.027) H2C(0.027) H8A(0.027)
 H8B(0.027) H9(0.021) H10A(0.021) H10B(0.021) H1A(0.02) H2D(0.021) H2E(0.021)
 H12A(0.064) H12B(0.064) H12C(0.064) H5A(0.023) H5B(0.023) H11A(0.027)
 H11B(0.027) H6A(0.046) H6B(0.046) H6C(0.046) H3A(0.019) H3B(0.019)
 Fixed X: Pb2(0.25) Pb4(0.25) Pb3(0.25) Pb7(0.5) Cl10(0.25) Cl6(0.25)
 Cl7(0.25) Cl9(0.25) Cl2(0.25) Cl4(0.25) Cl13(0.5) Cl16(0.5) H3(0.3719)
 H1(0.3812) H4A(0.4408) H4B(0.431) H4C(0.3995) H7A(0.4431) H7B(0.4004)
 H4D(0.3534) H4E(0.3108) H2A(0.3088) H2B(0.3081) H2C(0.346) H8A(0.3842)
 H8B(0.4257) H9(0.4596) H10A(0.3835) H10B(0.4241) H1A(0.288) H2D(0.364)
 H2E(0.3231) H12A(0.3883) H12B(0.3917) H12C(0.4304) H5A(0.3248) H5B(0.3655)
 H11A(0.446) H11B(0.4057) H6A(0.3308) H6B(0.3687) H6C(0.3737) H3A(0.3036)
 H3B(0.3422)
 Fixed Y: Pb7(1) Cl13(1) Cl16(1.5) H3(-0.1352) H1(1.1093) H4A(0.2346)
 H4B(0.1835) H4C(0.2056) H7A(-0.0721) H7B(-0.0549) H4D(1.0256) H4E(1.0539)
 H2A(0.8246) H2B(0.7624) H2C(0.8009) H8A(0.0859) H8B(0.1209) H9(0.0506) H10A(-
 0.0126) H10B(-0.0281) H1A(0.9472) H2D(1.0125) H2E(1.0356) H12A(-0.2648) H12B(-
 0.3254) H12C(-0.2814) H5A(0.8608) H5B(0.8944) H11A(-0.1651) H11B(-0.2085)
 H6A(1.264) H6B(1.302) H6C(1.2314) H3A(1.1591) H3B(1.2071)
 Fixed Z: H3(0.3289) H1(0.6703) H4A(0.3913) H4B(0.461) H4C(0.4085) H7A(0.2619)
 H7B(0.2277) H4D(0.771) H4E(0.7398) H2A(0.5327) H2B(0.6013) H2C(0.571)
 H8A(0.3113) H8B(0.2779) H9(0.3798) H10A(0.4359) H10B(0.4777) H1A(0.6225)
 H2D(0.5637) H2E(0.5241) H12A(0.2417) H12B(0.3175) H12C(0.2778) H5A(0.7169)
 H5B(0.6795) H11A(0.3902) H11B(0.4252) H6A(0.7377) H6B(0.6935) H6C(0.7656)
 H3A(0.621) H3B(0.582)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   difmap
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_disorder_assembly
_atom_site_disorder_group
_atom_site_site_symmetry_order
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
Pb2 Pb 0.2500 0.78320(6) 0.35641(4) 0.01623(14) Uani 1 d . . 2 S T P
Pb1 Pb 0.311377(17) 0.47466(4) 0.45888(2) 0.01668(11) Uani 1 d . . 1 . . .
Pb4 Pb 0.2500 1.15013(6) 0.37287(4) 0.01723(15) Uani 1 d . . 2 S T P
Pb5 Pb 0.562430(18) 1.49422(4) 0.54149(3) 0.01952(12) Uani 1 d . . 1 . . .
Pb3 Pb 0.2500 1.00352(6) 0.16741(4) 0.0243(2) Uani 1 d . . 2 S T P
Pb7 Pb 0.5000 1.0000 0.83224(4) 0.0279(2) Uani 1 d . . 2 S T P
Pb6 Pb 0.501727(15) 1.18253(6) 0.63068(3) 0.02733(14) Uani 1 d . . 1 . . .
Cl10 Cl 0.2500 0.9477(4) 0.4710(2) 0.0176(9) Uani 1 d . . 2 S T P
Cl6 Cl 0.2500 0.6277(4) 0.5196(2) 0.0132(8) Uani 1 d . . 2 S T P
Cl7 Cl 0.2500 0.7565(4) 0.1949(2) 0.0186(9) Uani 1 d . . 2 S T P
Cl9 Cl 0.2500 1.2362(4) 0.2290(3) 0.0225(10) Uani 1 d . . 2 S T P
Cl3 Cl 0.33064(10) 0.2333(3) 0.41287(18) 0.0207(7) Uani 1 d . . 1 . . .
Cl2 Cl 0.2500 0.3270(4) 0.5236(3) 0.0178(9) Uani 1 d . . 2 S T P
Cl8 Cl 0.30236(11) 0.9780(3) 0.29674(19) 0.0174(7) Uani 1 d . . 1 . . .
Cl5 Cl 0.32795(9) 0.7196(3) 0.40960(18) 0.0203(6) Uani 1 d . . 1 . . .
Cl4 Cl 0.2500 0.4950(5) 0.3469(3) 0.0265(12) Uani 1 d . . 2 S T P
Cl12 Cl 0.55233(11) 0.9989(3) 0.70014(19) 0.0198(7) Uani 1 d . . 1 . . .
Cl17 Cl 0.50330(10) 1.3494(3) 0.4777(2) 0.0209(7) Uani 1 d . . 1 . . .
Cl14 Cl 0.42420(10) 1.2512(3) 0.58382(18) 0.0248(7) Uani 1 d . . 1 . . .
Cl15 Cl 0.58478(10) 1.2576(3) 0.58607(18) 0.0248(7) Uani 1 d . . 1 . . .
Cl13 Cl 0.5000 1.0000 0.5270(3) 0.0351(14) Uani 1 d . . 2 S T P
Cl11 Cl 0.50835(11) 0.7589(3) 0.7875(2) 0.0256(7) Uani 1 d . . 1 . . .
Cl1 Cl 0.33959(16) 0.5011(4) 0.6025(3) 0.0407(11) Uani 1 d . . 1 . . .
Cl16 Cl 0.5000 1.5000 0.6520(3) 0.0324(13) Uani 1 d . . 2 S T P
Cl18 Cl 0.58960(15) 1.5257(3) 0.3984(2) 0.0375(11) Uani 1 d . . 1 . . .
N3 N 0.3985(3) -0.1496(10) 0.3227(6) 0.019(2) Uani 1 d . . 1 . . .
H3 H 0.3719 -0.1352 0.3289 0.022 Uiso 1 d . . 1 . . .
N1 N 0.3556(3) 1.1300(9) 0.6820(6) 0.019(2) Uani 1 d . . 1 . . .
H1 H 0.3812 1.1093 0.6703 0.022 Uiso 1 d . . 1 . . .
N4 N 0.4250(3) 0.1841(10) 0.4142(7) 0.026(3) Uani 1 d . . 1 . . .
H4A H 0.4408 0.2346 0.3913 0.031 Uiso 1 d . . 1 . . .
H4B H 0.4310 0.1835 0.4610 0.031 Uiso 1 d . . 1 . . .
H4C H 0.3995 0.2056 0.4085 0.031 Uiso 1 d . . 1 . . .
C7 C 0.4152(4) -0.0547(13) 0.2729(7) 0.022(3) Uani 1 d . . 1 . . .
H7A H 0.4431 -0.0721 0.2619 0.027 Uiso 1 d . . 1 . . .
H7B H 0.4004 -0.0549 0.2277 0.027 Uiso 1 d . . 1 . . .
C4 C 0.3381(4) 1.0336(12) 0.7268(7) 0.019(3) Uani 1 d . . 1 . . .
H4D H 0.3534 1.0256 0.7710 0.023 Uiso 1 d . . 1 . . .
H4E H 0.3108 1.0539 0.7398 0.023 Uiso 1 d . . 1 . . .
N2 N 0.3201(3) 0.8185(10) 0.5761(6) 0.023(2) Uani 1 d . . 1 . . .
H2A H 0.3088 0.8246 0.5327 0.027 Uiso 1 d . . 1 . . .
H2B H 0.3081 0.7624 0.6013 0.027 Uiso 1 d . . 1 . . .
H2C H 0.3460 0.8009 0.5710 0.027 Uiso 1 d . . 1 . . .
C8 C 0.4122(4) 0.0635(12) 0.3078(7) 0.022(3) Uani 1 d . . 1 . . .
H8A H 0.3842 0.0859 0.3113 0.027 Uiso 1 d . . 1 . . .
H8B H 0.4257 0.1209 0.2779 0.027 Uiso 1 d . . 1 . . .
C9 C 0.4307(4) 0.0661(11) 0.3838(7) 0.017(3) Uani 1 d . . 1 . . .
H9 H 0.4596 0.0506 0.3798 0.021 Uiso 1 d . . 1 . . .
C10 C 0.4118(4) -0.0285(12) 0.4301(7) 0.017(3) Uani 1 d . . 1 . . .
H10A H 0.3835 -0.0126 0.4359 0.021 Uiso 1 d . . 1 . . .
H10B H 0.4241 -0.0281 0.4777 0.021 Uiso 1 d . . 1 . . .
C1 C 0.3163(3) 0.9298(12) 0.6144(7) 0.016(3) Uani 1 d . . 1 . . .
H1A H 0.2880 0.9472 0.6225 0.020 Uiso 1 d . . 1 . . .
C2 C 0.3357(4) 1.0294(12) 0.5711(7) 0.018(3) Uani 1 d . . 1 . . .
H2D H 0.3640 1.0125 0.5637 0.021 Uiso 1 d . . 1 . . .
H2E H 0.3231 1.0356 0.5241 0.021 Uiso 1 d . . 1 . . .
C12 C 0.4025(5) -0.2654(16) 0.2870(9) 0.043(5) Uani 1 d . . 1 . . .
H12A H 0.3883 -0.2648 0.2417 0.064 Uiso 1 d . . 1 . . .
H12B H 0.3917 -0.3254 0.3175 0.064 Uiso 1 d . . 1 . . .
H12C H 0.4304 -0.2814 0.2778 0.064 Uiso 1 d . . 1 . . .
C5 C 0.3380(4) 0.9197(11) 0.6875(7) 0.019(3) Uani 1 d . . 1 . . .
H5A H 0.3248 0.8608 0.7169 0.023 Uiso 1 d . . 1 . . .
H5B H 0.3655 0.8944 0.6795 0.023 Uiso 1 d . . 1 . . .
C11 C 0.4176(4) -0.1483(12) 0.3949(7) 0.022(3) Uani 1 d . . 1 . . .
H11A H 0.4460 -0.1651 0.3902 0.027 Uiso 1 d . . 1 . . .
H11B H 0.4057 -0.2085 0.4252 0.027 Uiso 1 d . . 1 . . .
C6 C 0.3573(4) 1.2417(14) 0.7233(8) 0.031(3) Uani 1 d . . 1 . . .
H6A H 0.3308 1.2640 0.7377 0.046 Uiso 1 d . . 1 . . .
H6B H 0.3687 1.3020 0.6935 0.046 Uiso 1 d . . 1 . . .
H6C H 0.3737 1.2314 0.7656 0.046 Uiso 1 d . . 1 . . .
C3 C 0.3315(4) 1.1434(10) 0.6106(7) 0.016(2) Uani 1 d . . 1 . . .
H3A H 0.3036 1.1591 0.6210 0.019 Uiso 1 d . . 1 . . .
H3B H 0.3422 1.2071 0.5820 0.019 Uiso 1 d . . 1 . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pb2 Cl10 2.832(4) . ?
Pb2 Cl7 3.004(4) . ?
Pb2 Cl8 3.036(3) 3 ?
Pb2 Cl8 3.036(3) . ?
Pb2 Cl5 2.873(3) 3 ?
Pb2 Cl5 2.873(3) . ?
Pb1 Cl6 2.917(3) . ?
Pb1 Cl3 2.955(3) . ?
Pb1 Cl2 2.910(3) . ?
Pb1 Cl5 2.994(3) . ?
Pb1 Cl4 2.922(4) . ?
Pb1 Cl1 2.834(5) . ?
Pb4 Cl10 2.939(4) . ?
Pb4 Cl9 2.836(5) . ?
Pb4 Cl3 2.947(3) 3_565 ?
Pb4 Cl3 2.947(3) 1_565 ?
Pb4 Cl8 2.983(3) 3 ?
Pb4 Cl8 2.983(3) . ?
Pb5 Cl17 2.832(3) . ?
Pb5 Cl17 3.064(4) 2_685 ?
Pb5 Cl14 3.044(4) 2_685 ?
Pb5 Cl15 2.923(4) . ?
Pb5 Cl16 2.920(4) . ?
Pb5 Cl18 2.820(4) . ?
Pb3 Cl7 2.867(4) . ?
Pb3 Cl9 2.892(4) . ?
Pb3 Cl8 2.976(4) 3 ?
Pb3 Cl8 2.976(4) . ?
Pb7 Cl12 3.003(4) . ?
Pb7 Cl12 3.003(4) 2_675 ?
Pb7 Cl11 2.889(3) . ?
Pb7 Cl11 2.889(3) 2_675 ?
Pb6 Cl12 3.032(4) 2_675 ?
Pb6 Cl12 2.983(4) . ?
Pb6 Cl14 2.838(3) . ?
Pb6 Cl15 3.015(3) . ?
Pb6 Cl13 2.834(3) . ?
Pb6 Cl11 2.996(4) 2_675 ?
Cl6 Pb1 2.917(3) 3 ?
Cl3 Pb4 2.947(3) 1_545 ?
Cl2 Pb1 2.910(3) 3 ?
Cl4 Pb1 2.922(4) 3 ?
Cl12 Pb6 3.032(4) 2_675 ?
Cl17 Pb5 3.064(4) 2_685 ?
Cl14 Pb5 3.044(4) 2_685 ?
Cl13 Pb6 2.834(3) 2_675 ?
Cl11 Pb6 2.996(4) 2_675 ?
Cl16 Pb5 2.920(4) 2_685 ?
N3 C7 1.529(17) . ?
N3 C12 1.485(19) . ?
N3 C11 1.481(17) . ?
N1 C4 1.497(17) . ?
N1 C6 1.488(17) . ?
N1 C3 1.553(16) . ?
N4 C9 1.473(17) . ?
C7 C8 1.50(2) . ?
C4 C5 1.491(18) . ?
N2 C1 1.461(17) . ?
C8 C9 1.536(18) . ?
C9 C10 1.516(18) . ?
C10 C11 1.529(19) . ?
C1 C2 1.534(18) . ?
C1 C5 1.538(18) . ?
C2 C3 1.500(18) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Cl10 Pb2 Cl7 144.27(12) . . ?
Cl10 Pb2 Cl8 77.64(10) . 3 ?
Cl10 Pb2 Cl8 77.64(10) . . ?
Cl10 Pb2 Cl5 84.92(8) . . ?
Cl10 Pb2 Cl5 84.92(8) . 3 ?
Cl7 Pb2 Cl8 73.31(10) . 3 ?
Cl7 Pb2 Cl8 73.31(10) . . ?
Cl8 Pb2 Cl8 70.23(13) . 3 ?
Cl5 Pb2 Cl7 108.36(7) . . ?
Cl5 Pb2 Cl7 108.36(7) 3 . ?
Cl5 Pb2 Cl8 77.84(9) 3 3 ?
Cl5 Pb2 Cl8 77.84(9) . . ?
Cl5 Pb2 Cl8 146.13(9) 3 . ?
Cl5 Pb2 Cl8 146.13(9) . 3 ?
Cl5 Pb2 Cl5 129.61(13) 3 . ?
Cl6 Pb1 Cl3 145.33(9) . . ?
Cl6 Pb1 Cl5 71.74(10) . . ?
Cl6 Pb1 Cl4 74.54(11) . . ?
Cl3 Pb1 Cl5 138.05(10) . . ?
Cl2 Pb1 Cl6 72.25(11) . . ?
Cl2 Pb1 Cl3 74.40(11) . . ?
Cl2 Pb1 Cl5 142.81(9) . . ?
Cl2 Pb1 Cl4 81.08(12) . . ?
Cl4 Pb1 Cl3 91.28(12) . . ?
Cl4 Pb1 Cl5 80.74(12) . . ?
Cl1 Pb1 Cl6 78.96(13) . . ?
Cl1 Pb1 Cl3 107.29(11) . . ?
Cl1 Pb1 Cl2 84.83(14) . . ?
Cl1 Pb1 Cl5 97.15(11) . . ?
Cl1 Pb1 Cl4 152.71(14) . . ?
Cl10 Pb4 Cl3 95.66(8) . 3_565 ?
Cl10 Pb4 Cl3 95.66(8) . 1_565 ?
Cl10 Pb4 Cl8 76.88(10) . 3 ?
Cl10 Pb4 Cl8 76.88(10) . . ?
Cl9 Pb4 Cl10 148.41(13) . . ?
Cl9 Pb4 Cl3 97.11(8) . 3_565 ?
Cl9 Pb4 Cl3 97.11(8) . 1_565 ?
Cl9 Pb4 Cl8 77.62(10) . 3 ?
Cl9 Pb4 Cl8 77.62(10) . . ?
Cl3 Pb4 Cl3 131.76(12) 1_565 3_565 ?
Cl3 Pb4 Cl8 78.28(9) 3_565 3 ?
Cl3 Pb4 Cl8 149.92(9) 1_565 3 ?
Cl3 Pb4 Cl8 149.92(9) 3_565 . ?
Cl3 Pb4 Cl8 78.28(9) 1_565 . ?
Cl8 Pb4 Cl8 71.66(14) 3 . ?
Cl17 Pb5 Cl17 71.45(12) . 2_685 ?
Cl17 Pb5 Cl14 140.11(10) . 2_685 ?
Cl17 Pb5 Cl15 75.81(10) . . ?
Cl17 Pb5 Cl16 78.94(10) . . ?
Cl14 Pb5 Cl17 69.33(9) 2_685 2_685 ?
Cl15 Pb5 Cl17 146.13(9) . 2_685 ?
Cl15 Pb5 Cl14 140.66(10) . 2_685 ?
Cl16 Pb5 Cl17 75.30(10) . 2_685 ?
Cl16 Pb5 Cl14 84.41(7) . 2_685 ?
Cl16 Pb5 Cl15 90.30(8) . . ?
Cl18 Pb5 Cl17 78.13(12) . 2_685 ?
Cl18 Pb5 Cl17 84.69(13) . . ?
Cl18 Pb5 Cl14 94.15(10) . 2_685 ?
Cl18 Pb5 Cl15 107.51(11) . . ?
Cl18 Pb5 Cl16 152.08(13) . . ?
Cl7 Pb3 Cl9 146.56(13) . . ?
Cl7 Pb3 Cl8 76.17(9) . . ?
Cl7 Pb3 Cl8 76.17(9) . 3 ?
Cl9 Pb3 Cl8 76.89(10) . 3 ?
Cl9 Pb3 Cl8 76.89(10) . . ?
Cl8 Pb3 Cl8 71.85(14) . 3 ?
Cl12 Pb7 Cl12 71.07(14) . 2_675 ?
Cl11 Pb7 Cl12 72.94(10) . . ?
Cl11 Pb7 Cl12 80.03(10) . 2_675 ?
Cl11 Pb7 Cl12 80.03(10) 2_675 . ?
Cl11 Pb7 Cl12 72.94(10) 2_675 2_675 ?
Cl11 Pb7 Cl11 146.70(15) . 2_675 ?
Cl12 Pb6 Cl12 70.94(13) . 2_675 ?
Cl12 Pb6 Cl15 78.34(10) . . ?
Cl12 Pb6 Cl11 78.66(9) . 2_675 ?
Cl14 Pb6 Cl12 147.30(10) . . ?
Cl14 Pb6 Cl12 77.09(10) . 2_675 ?
Cl14 Pb6 Cl15 132.45(10) . . ?
Cl14 Pb6 Cl11 97.58(10) . 2_675 ?
Cl15 Pb6 Cl12 148.93(10) . 2_675 ?
Cl13 Pb6 Cl12 76.83(9) . 2_675 ?
Cl13 Pb6 Cl12 77.63(9) . . ?
Cl13 Pb6 Cl14 88.75(8) . . ?
Cl13 Pb6 Cl15 92.43(8) . . ?
Cl13 Pb6 Cl11 144.83(10) . 2_675 ?
Cl11 Pb6 Cl12 71.06(9) 2_675 2_675 ?
Cl11 Pb6 Cl15 107.74(10) 2_675 . ?
Pb2 Cl10 Pb4 93.43(12) . . ?
Pb1 Cl6 Pb1 89.15(11) 3 . ?
Pb3 Cl7 Pb2 94.38(13) . . ?
Pb4 Cl9 Pb3 92.94(13) . . ?
Pb4 Cl3 Pb1 100.06(10) 1_545 . ?
Pb1 Cl2 Pb1 89.43(13) . 3 ?
Pb4 Cl8 Pb2 88.54(10) . . ?
Pb3 Cl8 Pb2 91.53(10) . . ?
Pb3 Cl8 Pb4 88.36(10) . . ?
Pb2 Cl5 Pb1 99.99(10) . . ?
Pb1 Cl4 Pb1 88.95(16) . 3 ?
Pb7 Cl12 Pb6 90.13(10) . 2_675 ?
Pb6 Cl12 Pb7 91.07(10) . . ?
Pb6 Cl12 Pb6 87.79(10) . 2_675 ?
Pb5 Cl17 Pb5 89.85(10) . 2_685 ?
Pb6 Cl14 Pb5 102.08(10) . 2_685 ?
Pb5 Cl15 Pb6 96.07(10) . . ?
Pb6 Cl13 Pb6 94.78(14) 2_675 . ?
Pb7 Cl11 Pb6 93.09(10) . 2_675 ?
Pb5 Cl16 Pb5 91.07(16) 2_685 . ?
C12 N3 C7 109.2(10) . . ?
C11 N3 C7 112.3(10) . . ?
C11 N3 C12 111.8(12) . . ?
C4 N1 C3 110.0(9) . . ?
C6 N1 C4 111.1(10) . . ?
C6 N1 C3 111.8(10) . . ?
C8 C7 N3 110.7(11) . . ?
C5 C4 N1 111.8(10) . . ?
C7 C8 C9 112.7(11) . . ?
N4 C9 C8 108.3(11) . . ?
N4 C9 C10 112.5(11) . . ?
C10 C9 C8 109.6(10) . . ?
C9 C10 C11 110.2(11) . . ?
N2 C1 C2 110.9(10) . . ?
N2 C1 C5 108.7(11) . . ?
C2 C1 C5 108.4(10) . . ?
C3 C2 C1 110.6(11) . . ?
C4 C5 C1 111.4(11) . . ?
N3 C11 C10 109.8(11) . . ?
C2 C3 N1 106.3(10) . . ?

_olex2_submission_special_instructions 'No special instructions were received'
