# Electronic Supplementary Material (ESI) for RSC Advances.
# This journal is © The Royal Society of Chemistry 2023

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 2240602'
loop_
_audit_author_name
_audit_author_address
'Victor Khrustalev'
;Peoples Friendship University of Russia (RUDN University, Moscow)
Russia
;
_audit_update_record             
;
2023-02-08 deposited with the CCDC.	2023-08-29 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2013
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         
'C56 H58 Dy Eu3 N8 O36 Si8, 2(C8 H20 N), 4(C2 H3 N)'
_chemical_formula_sum            'C80 H110 Dy Eu3 N14 O36 Si8'
_chemical_formula_weight         2686.95

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   13.27830(13)
_cell_length_b                   13.34642(15)
_cell_length_c                   16.09392(18)
_cell_angle_alpha                68.0627(10)
_cell_angle_beta                 85.3464(9)
_cell_angle_gamma                80.1123(9)
_cell_volume                     2605.87(5)
_cell_formula_units_Z            1
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    66606
_cell_measurement_theta_min      2.1
_cell_measurement_theta_max      35.3

_exptl_crystal_description       prism
_exptl_crystal_colour            colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.712
_exptl_crystal_F_000             1343
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.12
_exptl_absorpt_coefficient_mu    2.668
_shelx_estimated_absorpt_T_min   0.690
_shelx_estimated_absorpt_T_max   0.740
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.633
_exptl_absorpt_correction_T_max  0.696
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.41.117a (Rigaku Oxford Diffraction, 2021)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_measurement_device_type  'XtaLAB Synergy, Dualflex, HyPix'
_diffrn_measurement_method       'φ and ω'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            99913
_diffrn_reflns_av_unetI/netI     0.0424
_diffrn_reflns_av_R_equivalents  0.0477
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_theta_min         2.051
_diffrn_reflns_theta_max         35.300
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.918
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.918
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.918
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             21545
_reflns_number_gt                17201
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'CrysAlisPro 1.171.41.117a (Rigaku OD, 2021)'
_computing_cell_refinement       'CrysAlisPro 1.171.41.117a (Rigaku OD, 2021)'
_computing_data_reduction        'CrysAlisPro 1.171.41.117a (Rigaku OD, 2021)'
_computing_structure_solution    'SHELXT (Sheldrick, 2015)'
_computing_structure_refinement  'SHELXL (Sheldrick, 2015)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2015)'
_computing_publication_material  'SHELXTL (Sheldrick, 2015)'

_refine_special_details          
;
 ?
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0251P)²+1.9774P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     difmap
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         21545
_refine_ls_number_parameters     713
_refine_ls_number_restraints     33
_refine_ls_R_factor_all          0.0439
_refine_ls_R_factor_gt           0.0282
_refine_ls_wR_factor_ref         0.0656
_refine_ls_wR_factor_gt          0.0615
_refine_ls_goodness_of_fit_ref   1.040
_refine_ls_restrained_S_all      1.052
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.001

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.5086(2) 0.3606(2) 0.1648(2) 0.01063(4) Uani 0.75 1 d . . P A 1
Dy2 Dy 0.5092(7) 0.3620(6) 0.1648(6) 0.01063(4) Uani 0.25 1 d . . P A 2
Eu2 Eu 0.2945(2) 0.5156(2) 0.0095(2) 0.01081(3) Uani 0.75 1 d . . P A 1
Dy1 Dy 0.2953(7) 0.5151(6) 0.0096(6) 0.01081(3) Uani 0.25 1 d . . P A 2
Si1 Si 0.60417(4) 0.59529(4) 0.15487(4) 0.01216(9) Uani 1 1 d . . . . .
Si2 Si 0.37823(4) 0.61325(4) 0.16578(4) 0.01212(9) Uani 1 1 d . . . . .
Si3 Si 0.36700(4) 0.77273(4) -0.02516(4) 0.01176(9) Uani 1 1 d . . . . .
Si4 Si 0.59258(4) 0.75700(4) -0.03519(4) 0.01163(9) Uani 1 1 d . . . . .
O1 O 0.49127(11) 0.60774(11) 0.20279(9) 0.0141(3) Uani 1 1 d . . . . .
O2 O 0.34754(11) 0.72991(11) 0.08338(9) 0.0137(3) Uani 1 1 d . . . . .
O3 O 0.47491(11) 0.82209(11) -0.05072(10) 0.0141(3) Uani 1 1 d . . . . .
O4 O 0.61385(11) 0.71056(11) 0.07211(9) 0.0140(3) Uani 1 1 d . . . . .
O5 O 0.61270(11) 0.49615(11) 0.11894(9) 0.0128(2) Uani 1 1 d . . . . .
O6 O 0.38268(10) 0.51410(11) 0.13010(9) 0.0129(2) Uani 1 1 d . . . . .
O7 O 0.37409(10) 0.67049(11) -0.05747(9) 0.0128(2) Uani 1 1 d . . . . .
O8 O 0.60508(10) 0.65714(11) -0.07101(9) 0.0126(2) Uani 1 1 d . . . . .
O9 O 0.67094(12) 0.26010(13) 0.25377(11) 0.0206(3) Uani 1 1 d . . . . .
O10 O 0.55736(12) 0.16220(12) 0.25217(11) 0.0218(3) Uani 1 1 d . . . . .
O11 O 0.68593(16) 0.08823(15) 0.34189(14) 0.0392(5) Uani 1 1 d . . . . .
O12 O 0.48425(12) 0.34310(14) 0.32285(11) 0.0218(3) Uani 1 1 d . . . . .
O13 O 0.36661(12) 0.28862(13) 0.27198(10) 0.0198(3) Uani 1 1 d . . . . .
O14 O 0.36336(15) 0.26822(16) 0.41250(11) 0.0316(4) Uani 1 1 d . . . . .
O15 O 0.17682(12) 0.43542(13) 0.14344(11) 0.0220(3) Uani 1 1 d . . . . .
O16 O 0.14947(12) 0.60961(13) 0.06812(11) 0.0218(3) Uani 1 1 d . . . . .
O17 O 0.04467(13) 0.53610(16) 0.17731(12) 0.0299(4) Uani 1 1 d . . . . .
O18 O 0.18644(12) 0.64297(13) -0.11505(11) 0.0186(3) Uani 1 1 d . . . . .
H18O H 0.219(2) 0.673(2) -0.154(2) 0.028 Uiso 1 1 d . U . . .
N1 N 0.64019(15) 0.16733(15) 0.28435(13) 0.0224(4) Uani 1 1 d . . . . .
N2 N 0.40293(15) 0.29890(15) 0.33779(12) 0.0204(4) Uani 1 1 d . . . . .
N3 N 0.12137(14) 0.52586(16) 0.13202(13) 0.0193(3) Uani 1 1 d . . . . .
N4 N 0.17690(14) 0.40242(15) -0.02252(13) 0.0195(3) Uani 1 1 d . . . . .
C1 C 0.70666(16) 0.57234(16) 0.23462(13) 0.0149(3) Uani 1 1 d . . . . .
C2 C 0.76096(17) 0.65656(17) 0.22742(16) 0.0211(4) Uani 1 1 d . . . . .
H2 H 0.7421 0.7274 0.1836 0.025 Uiso 1 1 calc R U . . .
C3 C 0.84213(18) 0.63781(19) 0.28364(17) 0.0254(5) Uani 1 1 d . . . . .
H3 H 0.8777 0.6960 0.2782 0.030 Uiso 1 1 calc R U . . .
C4 C 0.87117(17) 0.53546(19) 0.34709(15) 0.0215(4) Uani 1 1 d . . . . .
H4 H 0.9266 0.5229 0.3853 0.026 Uiso 1 1 calc R U . . .
C5 C 0.81899(19) 0.4512(2) 0.35467(15) 0.0250(5) Uani 1 1 d . . . . .
H5 H 0.8390 0.3804 0.3981 0.030 Uiso 1 1 calc R U . . .
C6 C 0.73783(18) 0.46925(18) 0.29944(15) 0.0218(4) Uani 1 1 d . . . . .
H6 H 0.7026 0.4105 0.3057 0.026 Uiso 1 1 calc R U . . .
C7 C 0.28603(16) 0.61157(16) 0.25960(13) 0.0148(3) Uani 1 1 d . . . . .
C8 C 0.31281(19) 0.54673(19) 0.34783(15) 0.0241(5) Uani 1 1 d . . . . .
H8 H 0.3786 0.5038 0.3598 0.029 Uiso 1 1 calc R U . . .
C9 C 0.2440(2) 0.5443(2) 0.41878(16) 0.0298(5) Uani 1 1 d . . . . .
H9 H 0.2629 0.4992 0.4785 0.036 Uiso 1 1 calc R U . . .
C10 C 0.14835(19) 0.6075(2) 0.40204(16) 0.0262(5) Uani 1 1 d . . . . .
H10 H 0.1013 0.6055 0.4502 0.031 Uiso 1 1 calc R U . . .
C11 C 0.12129(17) 0.6735(2) 0.31517(16) 0.0232(4) Uani 1 1 d . . . . .
H11 H 0.0560 0.7177 0.3038 0.028 Uiso 1 1 calc R U . . .
C12 C 0.18942(16) 0.67548(18) 0.24433(14) 0.0192(4) Uani 1 1 d . . . . .
H12 H 0.1700 0.7208 0.1849 0.023 Uiso 1 1 calc R U . . .
C13 C 0.26112(16) 0.88486(16) -0.07786(14) 0.0153(4) Uani 1 1 d . . . . .
C14 C 0.16059(17) 0.87754(18) -0.04562(16) 0.0219(4) Uani 1 1 d . . . . .
H14 H 0.1468 0.8152 0.0045 0.026 Uiso 1 1 calc R U . . .
C15 C 0.08025(18) 0.9598(2) -0.0855(2) 0.0290(5) Uani 1 1 d . . . . .
H15 H 0.0125 0.9534 -0.0624 0.035 Uiso 1 1 calc R U . . .
C16 C 0.0989(2) 1.0506(2) -0.1588(2) 0.0338(6) Uani 1 1 d . . . . .
H16 H 0.0441 1.1067 -0.1864 0.041 Uiso 1 1 calc R U . . .
C17 C 0.1983(2) 1.0595(2) -0.1918(2) 0.0362(6) Uani 1 1 d . . . . .
H17 H 0.2116 1.1217 -0.2422 0.043 Uiso 1 1 calc R U . . .
C18 C 0.27816(19) 0.97758(18) -0.15126(17) 0.0252(5) Uani 1 1 d . . . . .
H18 H 0.3459 0.9849 -0.1741 0.030 Uiso 1 1 calc R U . . .
C19 C 0.68106(15) 0.85605(15) -0.09429(13) 0.0138(3) Uani 1 1 d . . . . .
C20 C 0.74151(16) 0.84547(16) -0.16685(14) 0.0161(4) Uani 1 1 d . . . . .
H20 H 0.7380 0.7862 -0.1851 0.019 Uiso 1 1 calc R U . . .
C21 C 0.80691(17) 0.92066(18) -0.21283(15) 0.0208(4) Uani 1 1 d . . . . .
H21 H 0.8475 0.9124 -0.2619 0.025 Uiso 1 1 calc R U . . .
C22 C 0.81262(18) 1.00761(18) -0.18666(16) 0.0228(4) Uani 1 1 d . . . . .
H22 H 0.8564 1.0594 -0.2184 0.027 Uiso 1 1 calc R U . . .
C23 C 0.75443(18) 1.01882(18) -0.11442(16) 0.0228(4) Uani 1 1 d . . . . .
H23 H 0.7589 1.0779 -0.0962 0.027 Uiso 1 1 calc R U . . .
C24 C 0.68940(17) 0.94373(17) -0.06837(15) 0.0185(4) Uani 1 1 d . . . . .
H24 H 0.6501 0.9519 -0.0187 0.022 Uiso 1 1 calc R U . . .
C25 C 0.09044(17) 0.6378(2) -0.14827(16) 0.0253(5) Uani 1 1 d . . . . .
H25A H 0.0409 0.6165 -0.0977 0.030 Uiso 1 1 calc R U . . .
H25B H 0.1009 0.5811 -0.1753 0.030 Uiso 1 1 calc R U . . .
C26 C 0.0476(2) 0.7452(2) -0.2168(2) 0.0394(7) Uani 1 1 d . . . . .
H26A H -0.0207 0.7413 -0.2333 0.059 Uiso 1 1 calc R U . . .
H26B H 0.0925 0.7622 -0.2701 0.059 Uiso 1 1 calc R U . . .
H26C H 0.0428 0.8026 -0.1919 0.059 Uiso 1 1 calc R U . . .
C27 C 0.13445(17) 0.33607(18) -0.02457(15) 0.0199(4) Uani 1 1 d . . . . .
C28 C 0.08177(19) 0.2493(2) -0.02526(19) 0.0290(5) Uani 1 1 d . . . . .
H28A H 0.0079 0.2700 -0.0188 0.044 Uiso 1 1 calc R U . . .
H28B H 0.1053 0.1816 0.0246 0.044 Uiso 1 1 calc R U . . .
H28C H 0.0966 0.2379 -0.0820 0.044 Uiso 1 1 calc R U . . .
N5 N 0.54562(13) 0.15516(14) 0.62883(11) 0.0282(4) Uani 1 1 d D . . . .
C29 C 0.4340(3) 0.1843(4) 0.6138(4) 0.0376(10) Uani 0.5 1 d D . P B 1
H29A H 0.3976 0.1391 0.6672 0.045 Uiso 0.5 1 calc R U P B 1
H29B H 0.4177 0.1673 0.5621 0.045 Uiso 0.5 1 calc R U P B 1
C30 C 0.3962(4) 0.3041(4) 0.5962(4) 0.0667(18) Uani 0.5 1 d D . P B 1
H30A H 0.3258 0.3229 0.5750 0.100 Uiso 0.5 1 calc R U P B 1
H30B H 0.4401 0.3489 0.5505 0.100 Uiso 0.5 1 calc R U P B 1
H30C H 0.3982 0.3178 0.6517 0.100 Uiso 0.5 1 calc R U P B 1
C31 C 0.5723(5) 0.1838(5) 0.7055(3) 0.0410(14) Uani 0.5 1 d D . P B 1
H31A H 0.5634 0.2643 0.6872 0.049 Uiso 0.5 1 calc R U P B 1
H31B H 0.6449 0.1546 0.7208 0.049 Uiso 0.5 1 calc R U P B 1
C32 C 0.5050(12) 0.1369(9) 0.7875(3) 0.0328(9) Uani 0.5 1 d D . P B 1
H32A H 0.5252 0.1549 0.8369 0.049 Uiso 0.5 1 calc R U P B 1
H32B H 0.5132 0.0573 0.8053 0.049 Uiso 0.5 1 calc R U P B 1
H32C H 0.4334 0.1683 0.7732 0.049 Uiso 0.5 1 calc R U P B 1
C33 C 0.5806(5) 0.0370(3) 0.6529(3) 0.0419(14) Uani 0.5 1 d D . P B 1
H33A H 0.5379 -0.0042 0.7033 0.050 Uiso 0.5 1 calc R U P B 1
H33B H 0.6522 0.0192 0.6732 0.050 Uiso 0.5 1 calc R U P B 1
C34 C 0.5746(8) 0.0014(4) 0.5742(4) 0.072(3) Uani 0.5 1 d D . P B 1
H34A H 0.6306 -0.0581 0.5772 0.107 Uiso 0.5 1 calc R U P B 1
H34B H 0.5802 0.0634 0.5180 0.107 Uiso 0.5 1 calc R U P B 1
H34C H 0.5090 -0.0241 0.5768 0.107 Uiso 0.5 1 calc R U P B 1
C35 C 0.5998(4) 0.2265(4) 0.5507(4) 0.060(2) Uani 0.5 1 d D . P B 1
H35A H 0.5837 0.3028 0.5483 0.072 Uiso 0.5 1 calc R U P B 1
H35B H 0.5750 0.2246 0.4950 0.072 Uiso 0.5 1 calc R U P B 1
C36 C 0.7147(4) 0.1914(7) 0.5553(6) 0.080(3) Uani 0.5 1 d D . P B 1
H36A H 0.7485 0.2501 0.5123 0.120 Uiso 0.5 1 calc R U P B 1
H36B H 0.7325 0.1254 0.5408 0.120 Uiso 0.5 1 calc R U P B 1
H36C H 0.7373 0.1760 0.6159 0.120 Uiso 0.5 1 calc R U P B 1
C29' C 0.4561(3) 0.2411(3) 0.5955(4) 0.0376(10) Uani 0.5 1 d D . P B 2
H29C H 0.4644 0.2795 0.5302 0.045 Uiso 0.5 1 calc R U P B 2
H29D H 0.4533 0.2953 0.6244 0.045 Uiso 0.5 1 calc R U P B 2
C30' C 0.3563(2) 0.1952(6) 0.6143(4) 0.0667(18) Uani 0.5 1 d D . P B 2
H30D H 0.2989 0.2555 0.5976 0.100 Uiso 0.5 1 calc R U P B 2
H30E H 0.3507 0.1512 0.6782 0.100 Uiso 0.5 1 calc R U P B 2
H30F H 0.3547 0.1494 0.5791 0.100 Uiso 0.5 1 calc R U P B 2
C31' C 0.5364(4) 0.0809(3) 0.72375(19) 0.0189(8) Uani 0.5 1 d D . P B 2
H31C H 0.6007 0.0289 0.7413 0.023 Uiso 0.5 1 calc R U P B 2
H31D H 0.4805 0.0381 0.7296 0.023 Uiso 0.5 1 calc R U P B 2
C32' C 0.5145(13) 0.1440(8) 0.7867(3) 0.0328(9) Uani 0.5 1 d D . P B 2
H32D H 0.5142 0.0923 0.8489 0.049 Uiso 0.5 1 calc R U P B 2
H32E H 0.4477 0.1904 0.7733 0.049 Uiso 0.5 1 calc R U P B 2
H32F H 0.5676 0.1897 0.7785 0.049 Uiso 0.5 1 calc R U P B 2
C33' C 0.5472(3) 0.0841(3) 0.5741(3) 0.0268(10) Uani 0.5 1 d D . P B 2
H33C H 0.5432 0.1307 0.5097 0.032 Uiso 0.5 1 calc R U P B 2
H33D H 0.4868 0.0459 0.5905 0.032 Uiso 0.5 1 calc R U P B 2
C34' C 0.6435(4) 0.0007(4) 0.5901(4) 0.0449(16) Uani 0.5 1 d D . P B 2
H34D H 0.6479 -0.0360 0.5471 0.067 Uiso 0.5 1 calc R U P B 2
H34E H 0.6417 -0.0534 0.6512 0.067 Uiso 0.5 1 calc R U P B 2
H34F H 0.7033 0.0376 0.5823 0.067 Uiso 0.5 1 calc R U P B 2
C35' C 0.6402(3) 0.2042(5) 0.6119(3) 0.0351(12) Uani 0.5 1 d D . P B 2
H35C H 0.6986 0.1459 0.6369 0.042 Uiso 0.5 1 calc R U P B 2
H35D H 0.6350 0.2559 0.6435 0.042 Uiso 0.5 1 calc R U P B 2
C36' C 0.6608(5) 0.2643(6) 0.5132(3) 0.056(2) Uani 0.5 1 d D . P B 2
H36D H 0.7241 0.2954 0.5058 0.084 Uiso 0.5 1 calc R U P B 2
H36E H 0.6038 0.3231 0.4882 0.084 Uiso 0.5 1 calc R U P B 2
H36F H 0.6679 0.2131 0.4817 0.084 Uiso 0.5 1 calc R U P B 2
N6 N 0.0965(3) 0.2981(3) 0.53404(16) 0.0586(8) Uani 1 1 d D . . . .
C37 C 0.1100(2) 0.3193(3) 0.45891(16) 0.0404(7) Uani 1 1 d D . . . .
C38 C 0.1262(2) 0.3470(3) 0.36284(15) 0.0420(7) Uani 1 1 d D . . . .
H38A H 0.1650 0.2837 0.3516 0.063 Uiso 1 1 calc R U . . .
H38B H 0.1647 0.4086 0.3388 0.063 Uiso 1 1 calc R U . . .
H38C H 0.0600 0.3673 0.3335 0.063 Uiso 1 1 calc R U . . .
N7 N 1.0976(4) -0.0866(6) 0.4281(5) 0.0601(8) Uani 0.5 1 d D . P C 1
C39 C 1.0126(4) -0.0587(7) 0.4143(6) 0.0601(8) Uani 0.5 1 d D . P C 1
C40 C 0.9040(4) -0.0209(10) 0.3959(6) 0.0601(8) Uani 0.5 1 d D . P C 1
H40A H 0.8681 -0.0841 0.4116 0.090 Uiso 0.5 1 calc R U P C 1
H40B H 0.8953 0.0235 0.3321 0.090 Uiso 0.5 1 calc R U P C 1
H40C H 0.8756 0.0231 0.4316 0.090 Uiso 0.5 1 calc R U P C 1
N7' N 0.8733(5) -0.0612(6) 0.5518(4) 0.0601(8) Uani 0.5 1 d D . P D 2
C39' C 0.8950(6) -0.0503(7) 0.4791(4) 0.0601(8) Uani 0.5 1 d D . P D 2
C40' C 0.9288(7) -0.0349(10) 0.3871(4) 0.0601(8) Uani 0.5 1 d D . P D 2
H40D H 0.9327 -0.1038 0.3775 0.090 Uiso 0.5 1 calc R U P D 2
H40E H 0.9965 -0.0119 0.3765 0.090 Uiso 0.5 1 calc R U P D 2
H40F H 0.8801 0.0214 0.3454 0.090 Uiso 0.5 1 calc R U P D 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O8 2.318(4) 2_665 ?
Eu1 O5 2.329(3) . ?
Eu1 O6 2.330(3) . ?
Eu1 O7 2.336(3) 2_665 ?
Eu1 O12 2.466(4) . ?
Eu1 O10 2.486(3) . ?
Eu1 O13 2.512(3) . ?
Eu1 O9 2.563(3) . ?
Eu1 N2 2.907(3) . ?
Eu1 N1 2.949(3) . ?
Dy2 O5 2.310(9) . ?
Dy2 O6 2.322(8) . ?
Dy2 O8 2.332(10) 2_665 ?
Dy2 O7 2.338(9) 2_665 ?
Dy2 O12 2.461(9) . ?
Dy2 O10 2.501(7) . ?
Dy2 O13 2.522(9) . ?
Dy2 O9 2.560(8) . ?
Dy2 N2 2.910(9) . ?
Eu2 O7 2.335(3) . ?
Eu2 O6 2.339(4) . ?
Eu2 O8 2.351(3) 2_665 ?
Eu2 O5 2.362(4) 2_665 ?
Eu2 O16 2.436(4) . ?
Eu2 O18 2.460(3) . ?
Eu2 N4 2.551(4) . ?
Eu2 O15 2.557(3) . ?
Eu2 N3 2.924(4) . ?
Dy1 O7 2.335(9) . ?
Dy1 O6 2.335(10) . ?
Dy1 O8 2.341(8) 2_665 ?
Dy1 O5 2.356(9) 2_665 ?
Dy1 O16 2.446(9) . ?
Dy1 O18 2.468(8) . ?
Dy1 N4 2.554(10) . ?
Dy1 O15 2.561(8) . ?
Dy1 N3 2.932(9) . ?
Si1 O5 1.6149(14) . ?
Si1 O4 1.6329(15) . ?
Si1 O1 1.6408(15) . ?
Si1 C1 1.855(2) . ?
Si2 O6 1.6187(14) . ?
Si2 O2 1.6358(15) . ?
Si2 O1 1.6394(15) . ?
Si2 C7 1.861(2) . ?
Si3 O7 1.6185(14) . ?
Si3 O2 1.6359(15) . ?
Si3 O3 1.6378(15) . ?
Si3 C13 1.860(2) . ?
Si4 O8 1.6182(14) . ?
Si4 O4 1.6327(15) . ?
Si4 O3 1.6411(15) . ?
Si4 C19 1.856(2) . ?
O9 N1 1.276(2) . ?
O10 N1 1.276(3) . ?
O11 N1 1.217(2) . ?
O12 N2 1.282(2) . ?
O13 N2 1.260(2) . ?
O14 N2 1.222(2) . ?
O15 N3 1.258(2) . ?
O16 N3 1.292(2) . ?
O17 N3 1.222(2) . ?
O18 C25 1.444(3) . ?
O18 H18O 0.76(3) . ?
N4 C27 1.140(3) . ?
C1 C6 1.398(3) . ?
C1 C2 1.402(3) . ?
C2 C3 1.393(3) . ?
C2 H2 0.9500 . ?
C3 C4 1.378(3) . ?
C3 H3 0.9500 . ?
C4 C5 1.383(3) . ?
C4 H4 0.9500 . ?
C5 C6 1.384(3) . ?
C5 H5 0.9500 . ?
C6 H6 0.9500 . ?
C7 C8 1.396(3) . ?
C7 C12 1.397(3) . ?
C8 C9 1.397(3) . ?
C8 H8 0.9500 . ?
C9 C10 1.384(4) . ?
C9 H9 0.9500 . ?
C10 C11 1.383(3) . ?
C10 H10 0.9500 . ?
C11 C12 1.392(3) . ?
C11 H11 0.9500 . ?
C12 H12 0.9500 . ?
C13 C18 1.392(3) . ?
C13 C14 1.398(3) . ?
C14 C15 1.392(3) . ?
C14 H14 0.9500 . ?
C15 C16 1.382(4) . ?
C15 H15 0.9500 . ?
C16 C17 1.390(4) . ?
C16 H16 0.9500 . ?
C17 C18 1.389(3) . ?
C17 H17 0.9500 . ?
C18 H18 0.9500 . ?
C19 C20 1.400(3) . ?
C19 C24 1.404(3) . ?
C20 C21 1.396(3) . ?
C20 H20 0.9500 . ?
C21 C22 1.389(3) . ?
C21 H21 0.9500 . ?
C22 C23 1.384(3) . ?
C22 H22 0.9500 . ?
C23 C24 1.392(3) . ?
C23 H23 0.9500 . ?
C24 H24 0.9500 . ?
C25 C26 1.495(4) . ?
C25 H25A 0.9900 . ?
C25 H25B 0.9900 . ?
C26 H26A 0.9800 . ?
C26 H26B 0.9800 . ?
C26 H26C 0.9800 . ?
C27 C28 1.456(3) . ?
C28 H28A 0.9800 . ?
C28 H28B 0.9800 . ?
C28 H28C 0.9800 . ?
N5 C35' 1.474(3) . ?
N5 C33 1.475(3) . ?
N5 C29' 1.481(3) . ?
N5 C29 1.481(3) . ?
N5 C35 1.483(3) . ?
N5 C31' 1.487(3) . ?
N5 C31 1.505(3) . ?
N5 C33' 1.512(3) . ?
C29 C30 1.516(3) . ?
C29 H29A 0.9900 . ?
C29 H29B 0.9900 . ?
C30 H30A 0.9800 . ?
C30 H30B 0.9800 . ?
C30 H30C 0.9800 . ?
C31 C32 1.521(3) . ?
C31 H31A 0.9900 . ?
C31 H31B 0.9900 . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32 H32C 0.9800 . ?
C33 C34 1.521(3) . ?
C33 H33A 0.9900 . ?
C33 H33B 0.9900 . ?
C34 H34A 0.9800 . ?
C34 H34B 0.9800 . ?
C34 H34C 0.9800 . ?
C35 C36 1.517(3) . ?
C35 H35A 0.9900 . ?
C35 H35B 0.9900 . ?
C36 H36A 0.9800 . ?
C36 H36B 0.9800 . ?
C36 H36C 0.9800 . ?
C29' C30' 1.516(3) . ?
C29' H29C 0.9900 . ?
C29' H29D 0.9900 . ?
C30' H30D 0.9800 . ?
C30' H30E 0.9800 . ?
C30' H30F 0.9800 . ?
C31' C32' 1.526(3) . ?
C31' H31C 0.9900 . ?
C31' H31D 0.9900 . ?
C32' H32D 0.9800 . ?
C32' H32E 0.9800 . ?
C32' H32F 0.9800 . ?
C33' C34' 1.514(3) . ?
C33' H33C 0.9900 . ?
C33' H33D 0.9900 . ?
C34' H34D 0.9800 . ?
C34' H34E 0.9800 . ?
C34' H34F 0.9800 . ?
C35' C36' 1.515(3) . ?
C35' H35C 0.9900 . ?
C35' H35D 0.9900 . ?
C36' H36D 0.9800 . ?
C36' H36E 0.9800 . ?
C36' H36F 0.9800 . ?
N6 C37 1.141(2) . ?
C37 C38 1.456(2) . ?
C38 H38A 0.9800 . ?
C38 H38B 0.9800 . ?
C38 H38C 0.9800 . ?
N7 C39 1.139(2) . ?
C39 C40 1.459(2) . ?
C40 H40A 0.9800 . ?
C40 H40B 0.9800 . ?
C40 H40C 0.9800 . ?
N7' C39' 1.142(2) . ?
C39' C40' 1.460(2) . ?
C40' H40D 0.9800 . ?
C40' H40E 0.9800 . ?
C40' H40F 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O8 Eu1 O5 123.25(12) 2_665 . ?
O8 Eu1 O6 72.91(10) 2_665 . ?
O5 Eu1 O6 80.76(10) . . ?
O8 Eu1 O7 81.46(12) 2_665 2_665 ?
O5 Eu1 O7 71.55(10) . 2_665 ?
O6 Eu1 O7 122.13(12) . 2_665 ?
O8 Eu1 O12 128.88(14) 2_665 . ?
O5 Eu1 O12 98.14(14) . . ?
O6 Eu1 O12 87.38(12) . . ?
O7 Eu1 O12 144.98(15) 2_665 . ?
O8 Eu1 O10 96.95(13) 2_665 . ?
O5 Eu1 O10 127.95(14) . . ?
O6 Eu1 O10 147.69(15) . . ?
O7 Eu1 O10 85.07(11) 2_665 . ?
O12 Eu1 O10 75.22(9) . . ?
O8 Eu1 O13 78.06(11) 2_665 . ?
O5 Eu1 O13 143.33(17) . . ?
O6 Eu1 O13 78.09(10) . . ?
O7 Eu1 O13 145.00(16) 2_665 . ?
O12 Eu1 O13 51.52(8) . . ?
O10 Eu1 O13 69.74(9) . . ?
O8 Eu1 O9 141.50(15) 2_665 . ?
O5 Eu1 O9 78.24(11) . . ?
O6 Eu1 O9 145.56(17) . . ?
O7 Eu1 O9 75.99(10) 2_665 . ?
O12 Eu1 O9 69.09(10) . . ?
O10 Eu1 O9 50.77(7) . . ?
O13 Eu1 O9 103.68(10) . . ?
O8 Eu1 N2 103.47(12) 2_665 . ?
O5 Eu1 N2 122.21(15) . . ?
O6 Eu1 N2 82.89(11) . . ?
O7 Eu1 N2 154.43(12) 2_665 . ?
O12 Eu1 N2 25.97(6) . . ?
O10 Eu1 N2 69.49(8) . . ?
O13 Eu1 N2 25.58(6) . . ?
O9 Eu1 N2 85.58(10) . . ?
O8 Eu1 N1 120.81(13) 2_665 . ?
O5 Eu1 N1 103.63(12) . . ?
O6 Eu1 N1 155.56(15) . . ?
O7 Eu1 N1 81.52(10) 2_665 . ?
O12 Eu1 N1 68.24(8) . . ?
O10 Eu1 N1 25.36(6) . . ?
O13 Eu1 N1 84.99(9) . . ?
O9 Eu1 N1 25.55(6) . . ?
N2 Eu1 N1 74.40(8) . . ?
O5 Dy2 O6 81.3(3) . . ?
O5 Dy2 O8 123.5(3) . 2_665 ?
O6 Dy2 O8 72.8(3) . 2_665 ?
O5 Dy2 O7 71.8(2) . 2_665 ?
O6 Dy2 O7 122.4(3) . 2_665 ?
O8 Dy2 O7 81.1(3) 2_665 2_665 ?
O5 Dy2 O12 98.8(4) . . ?
O6 Dy2 O12 87.7(3) . . ?
O8 Dy2 O12 128.4(4) 2_665 . ?
O7 Dy2 O12 145.2(4) 2_665 . ?
O5 Dy2 O10 128.2(4) . . ?
O6 Dy2 O10 147.2(4) . . ?
O8 Dy2 O10 96.2(3) 2_665 . ?
O7 Dy2 O10 84.7(3) 2_665 . ?
O12 Dy2 O10 75.0(2) . . ?
O5 Dy2 O13 144.0(5) . . ?
O6 Dy2 O13 78.0(3) . . ?
O8 Dy2 O13 77.6(3) 2_665 . ?
O7 Dy2 O13 144.1(4) 2_665 . ?
O12 Dy2 O13 51.45(17) . . ?
O10 Dy2 O13 69.4(2) . . ?
O5 Dy2 O9 78.6(3) . . ?
O6 Dy2 O9 146.4(5) . . ?
O8 Dy2 O9 140.7(4) 2_665 . ?
O7 Dy2 O9 76.0(2) 2_665 . ?
O12 Dy2 O9 69.2(2) . . ?
O10 Dy2 O9 50.66(15) . . ?
O13 Dy2 O9 103.5(3) . . ?
O5 Dy2 N2 122.8(4) . . ?
O6 Dy2 N2 83.0(3) . . ?
O8 Dy2 N2 103.0(3) 2_665 . ?
O7 Dy2 N2 153.9(3) 2_665 . ?
O12 Dy2 N2 25.92(10) . . ?
O10 Dy2 N2 69.26(19) . . ?
O13 Dy2 N2 25.56(10) . . ?
O9 Dy2 N2 85.6(2) . . ?
O7 Eu2 O6 78.53(12) . . ?
O7 Eu2 O8 119.55(14) . 2_665 ?
O6 Eu2 O8 72.15(9) . 2_665 ?
O7 Eu2 O5 70.99(9) . 2_665 ?
O6 Eu2 O5 119.29(14) . 2_665 ?
O8 Eu2 O5 79.28(11) 2_665 2_665 ?
O7 Eu2 O16 94.46(12) . . ?
O6 Eu2 O16 84.98(13) . . ?
O8 Eu2 O16 132.63(13) 2_665 . ?
O5 Eu2 O16 146.73(13) 2_665 . ?
O7 Eu2 O18 73.01(9) . . ?
O6 Eu2 O18 140.32(15) . . ?
O8 Eu2 O18 146.75(18) 2_665 . ?
O5 Eu2 O18 76.54(10) 2_665 . ?
O16 Eu2 O18 70.54(9) . . ?
O7 Eu2 N4 142.77(14) . . ?
O6 Eu2 N4 138.70(12) . . ?
O8 Eu2 N4 81.68(11) 2_665 . ?
O5 Eu2 N4 85.16(13) 2_665 . ?
O16 Eu2 N4 90.22(12) . . ?
O18 Eu2 N4 73.90(11) . . ?
O7 Eu2 O15 139.20(16) . . ?
O6 Eu2 O15 77.12(10) . . ?
O8 Eu2 O15 82.86(9) 2_665 . ?
O5 Eu2 O15 149.80(16) 2_665 . ?
O16 Eu2 O15 51.30(8) . . ?
O18 Eu2 O15 107.75(13) . . ?
N4 Eu2 O15 68.22(10) . . ?
O7 Eu2 N3 118.20(14) . . ?
O6 Eu2 N3 80.93(11) . . ?
O8 Eu2 N3 107.85(11) 2_665 . ?
O5 Eu2 N3 159.71(16) 2_665 . ?
O16 Eu2 N3 25.89(6) . . ?
O18 Eu2 N3 88.66(10) . . ?
N4 Eu2 N3 77.35(10) . . ?
O15 Eu2 N3 25.43(6) . . ?
O7 Dy1 O6 78.6(3) . . ?
O7 Dy1 O8 120.0(4) . 2_665 ?
O6 Dy1 O8 72.4(2) . 2_665 ?
O7 Dy1 O5 71.1(2) . 2_665 ?
O6 Dy1 O5 119.7(4) . 2_665 ?
O8 Dy1 O5 79.6(3) 2_665 2_665 ?
O7 Dy1 O16 94.2(3) . . ?
O6 Dy1 O16 84.8(3) . . ?
O8 Dy1 O16 132.6(3) 2_665 . ?
O5 Dy1 O16 146.4(3) 2_665 . ?
O7 Dy1 O18 72.9(2) . . ?
O6 Dy1 O18 140.0(4) . . ?
O8 Dy1 O18 146.9(5) 2_665 . ?
O5 Dy1 O18 76.5(3) 2_665 . ?
O16 Dy1 O18 70.2(2) . . ?
O7 Dy1 N4 142.6(4) . . ?
O6 Dy1 N4 138.8(3) . . ?
O8 Dy1 N4 81.8(3) 2_665 . ?
O5 Dy1 N4 85.2(3) 2_665 . ?
O16 Dy1 N4 89.9(3) . . ?
O18 Dy1 N4 73.7(3) . . ?
O7 Dy1 O15 138.9(4) . . ?
O6 Dy1 O15 77.1(3) . . ?
O8 Dy1 O15 83.0(2) 2_665 . ?
O5 Dy1 O15 149.9(4) 2_665 . ?
O16 Dy1 O15 51.14(18) . . ?
O18 Dy1 O15 107.4(3) . . ?
N4 Dy1 O15 68.1(2) . . ?
O7 Dy1 N3 117.9(4) . . ?
O6 Dy1 N3 80.8(3) . . ?
O8 Dy1 N3 107.9(3) 2_665 . ?
O5 Dy1 N3 159.4(4) 2_665 . ?
O16 Dy1 N3 25.82(10) . . ?
O18 Dy1 N3 88.3(3) . . ?
N4 Dy1 N3 77.2(2) . . ?
O15 Dy1 N3 25.35(10) . . ?
O5 Si1 O4 110.94(7) . . ?
O5 Si1 O1 108.29(7) . . ?
O4 Si1 O1 107.96(8) . . ?
O5 Si1 C1 111.92(8) . . ?
O4 Si1 C1 107.22(8) . . ?
O1 Si1 C1 110.45(8) . . ?
O6 Si2 O2 109.42(7) . . ?
O6 Si2 O1 108.54(7) . . ?
O2 Si2 O1 109.79(8) . . ?
O6 Si2 C7 115.76(8) . . ?
O2 Si2 C7 107.06(8) . . ?
O1 Si2 C7 106.15(8) . . ?
O7 Si3 O2 108.88(7) . . ?
O7 Si3 O3 108.86(7) . . ?
O2 Si3 O3 109.76(8) . . ?
O7 Si3 C13 113.20(8) . . ?
O2 Si3 C13 107.72(9) . . ?
O3 Si3 C13 108.39(8) . . ?
O8 Si4 O4 110.41(7) . . ?
O8 Si4 O3 109.44(7) . . ?
O4 Si4 O3 107.58(8) . . ?
O8 Si4 C19 112.07(8) . . ?
O4 Si4 C19 108.76(8) . . ?
O3 Si4 C19 108.46(8) . . ?
Si2 O1 Si1 129.30(9) . . ?
Si2 O2 Si3 134.06(9) . . ?
Si3 O3 Si4 129.19(9) . . ?
Si4 O4 Si1 134.48(9) . . ?
Si1 O5 Dy2 125.3(2) . . ?
Si1 O5 Eu1 125.57(11) . . ?
Si1 O5 Dy1 125.9(2) . 2_665 ?
Dy2 O5 Dy1 107.4(3) . 2_665 ?
Si1 O5 Eu2 125.94(11) . 2_665 ?
Eu1 O5 Eu2 107.23(13) . 2_665 ?
Si2 O6 Dy2 124.8(3) . . ?
Si2 O6 Eu1 125.27(12) . . ?
Si2 O6 Dy1 127.4(2) . . ?
Dy2 O6 Dy1 106.0(3) . . ?
Si2 O6 Eu2 127.13(10) . . ?
Eu1 O6 Eu2 105.89(13) . . ?
Si3 O7 Dy1 127.3(2) . . ?
Si3 O7 Eu2 127.10(11) . . ?
Si3 O7 Eu1 124.12(11) . 2_665 ?
Eu2 O7 Eu1 107.91(12) . 2_665 ?
Si3 O7 Dy2 124.6(2) . 2_665 ?
Dy1 O7 Dy2 107.2(3) . 2_665 ?
Si4 O8 Eu1 124.52(11) . 2_665 ?
Si4 O8 Dy2 124.8(2) . 2_665 ?
Si4 O8 Dy1 127.4(3) . 2_665 ?
Dy2 O8 Dy1 105.5(3) 2_665 2_665 ?
Si4 O8 Eu2 127.34(12) . 2_665 ?
Eu1 O8 Eu2 105.88(13) 2_665 2_665 ?
N1 O9 Dy2 94.8(2) . . ?
N1 O9 Eu1 94.39(14) . . ?
N1 O10 Eu1 98.03(14) . . ?
N1 O10 Dy2 97.7(3) . . ?
N2 O12 Dy2 97.0(3) . . ?
N2 O12 Eu1 96.61(14) . . ?
N2 O13 Eu1 95.01(14) . . ?
N2 O13 Dy2 94.7(3) . . ?
N3 O15 Eu2 93.81(13) . . ?
N3 O15 Dy1 94.0(2) . . ?
N3 O16 Eu2 98.68(13) . . ?
N3 O16 Dy1 98.6(2) . . ?
C25 O18 Eu2 132.75(15) . . ?
C25 O18 Dy1 132.8(3) . . ?
C25 O18 H18O 109(2) . . ?
Eu2 O18 H18O 111(2) . . ?
Dy1 O18 H18O 110(2) . . ?
O11 N1 O10 121.5(2) . . ?
O11 N1 O9 122.3(2) . . ?
O10 N1 O9 116.16(17) . . ?
O11 N1 Eu1 172.05(19) . . ?
O10 N1 Eu1 56.61(12) . . ?
O9 N1 Eu1 60.05(12) . . ?
O14 N2 O13 122.1(2) . . ?
O14 N2 O12 121.14(19) . . ?
O13 N2 O12 116.71(17) . . ?
O14 N2 Dy2 176.2(2) . . ?
O13 N2 Dy2 59.7(2) . . ?
O12 N2 Dy2 57.1(2) . . ?
O14 N2 Eu1 176.18(17) . . ?
O13 N2 Eu1 59.41(12) . . ?
O12 N2 Eu1 57.42(12) . . ?
O17 N3 O15 123.26(19) . . ?
O17 N3 O16 120.65(19) . . ?
O15 N3 O16 116.09(17) . . ?
O17 N3 Eu2 174.78(17) . . ?
O15 N3 Eu2 60.76(11) . . ?
O16 N3 Eu2 55.43(11) . . ?
O17 N3 Dy1 174.9(2) . . ?
O15 N3 Dy1 60.62(18) . . ?
O16 N3 Dy1 55.56(18) . . ?
C27 N4 Eu2 167.18(19) . . ?
C27 N4 Dy1 167.0(2) . . ?
C6 C1 C2 117.49(19) . . ?
C6 C1 Si1 121.63(15) . . ?
C2 C1 Si1 120.71(16) . . ?
C3 C2 C1 120.9(2) . . ?
C3 C2 H2 119.6 . . ?
C1 C2 H2 119.6 . . ?
C4 C3 C2 120.4(2) . . ?
C4 C3 H3 119.8 . . ?
C2 C3 H3 119.8 . . ?
C3 C4 C5 119.5(2) . . ?
C3 C4 H4 120.3 . . ?
C5 C4 H4 120.3 . . ?
C4 C5 C6 120.5(2) . . ?
C4 C5 H5 119.8 . . ?
C6 C5 H5 119.8 . . ?
C5 C6 C1 121.3(2) . . ?
C5 C6 H6 119.4 . . ?
C1 C6 H6 119.4 . . ?
C8 C7 C12 118.25(19) . . ?
C8 C7 Si2 120.30(16) . . ?
C12 C7 Si2 121.44(15) . . ?
C7 C8 C9 120.8(2) . . ?
C7 C8 H8 119.6 . . ?
C9 C8 H8 119.6 . . ?
C10 C9 C8 119.9(2) . . ?
C10 C9 H9 120.0 . . ?
C8 C9 H9 120.0 . . ?
C11 C10 C9 119.9(2) . . ?
C11 C10 H10 120.0 . . ?
C9 C10 H10 120.0 . . ?
C10 C11 C12 120.2(2) . . ?
C10 C11 H11 119.9 . . ?
C12 C11 H11 119.9 . . ?
C11 C12 C7 120.8(2) . . ?
C11 C12 H12 119.6 . . ?
C7 C12 H12 119.6 . . ?
C18 C13 C14 117.6(2) . . ?
C18 C13 Si3 121.73(16) . . ?
C14 C13 Si3 120.63(16) . . ?
C15 C14 C13 121.3(2) . . ?
C15 C14 H14 119.4 . . ?
C13 C14 H14 119.4 . . ?
C16 C15 C14 120.1(2) . . ?
C16 C15 H15 120.0 . . ?
C14 C15 H15 120.0 . . ?
C15 C16 C17 119.6(2) . . ?
C15 C16 H16 120.2 . . ?
C17 C16 H16 120.2 . . ?
C18 C17 C16 120.1(2) . . ?
C18 C17 H17 120.0 . . ?
C16 C17 H17 120.0 . . ?
C17 C18 C13 121.4(2) . . ?
C17 C18 H18 119.3 . . ?
C13 C18 H18 119.3 . . ?
C20 C19 C24 117.92(18) . . ?
C20 C19 Si4 120.55(14) . . ?
C24 C19 Si4 121.53(16) . . ?
C21 C20 C19 121.03(19) . . ?
C21 C20 H20 119.5 . . ?
C19 C20 H20 119.5 . . ?
C22 C21 C20 119.9(2) . . ?
C22 C21 H21 120.0 . . ?
C20 C21 H21 120.0 . . ?
C23 C22 C21 119.98(19) . . ?
C23 C22 H22 120.0 . . ?
C21 C22 H22 120.0 . . ?
C22 C23 C24 120.2(2) . . ?
C22 C23 H23 119.9 . . ?
C24 C23 H23 119.9 . . ?
C23 C24 C19 121.0(2) . . ?
C23 C24 H24 119.5 . . ?
C19 C24 H24 119.5 . . ?
O18 C25 C26 111.5(2) . . ?
O18 C25 H25A 109.3 . . ?
C26 C25 H25A 109.3 . . ?
O18 C25 H25B 109.3 . . ?
C26 C25 H25B 109.3 . . ?
H25A C25 H25B 108.0 . . ?
C25 C26 H26A 109.5 . . ?
C25 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
C25 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
N4 C27 C28 178.5(3) . . ?
C27 C28 H28A 109.5 . . ?
C27 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
C27 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
C35' N5 C29' 110.3(3) . . ?
C33 N5 C29 112.1(3) . . ?
C33 N5 C35 114.9(3) . . ?
C29 N5 C35 109.1(4) . . ?
C35' N5 C31' 111.8(3) . . ?
C29' N5 C31' 114.7(3) . . ?
C33 N5 C31 106.7(3) . . ?
C29 N5 C31 109.9(4) . . ?
C35 N5 C31 103.8(4) . . ?
C35' N5 C33' 110.1(3) . . ?
C29' N5 C33' 104.1(3) . . ?
C31' N5 C33' 105.3(3) . . ?
N5 C29 C30 112.3(3) . . ?
N5 C29 H29A 109.1 . . ?
C30 C29 H29A 109.1 . . ?
N5 C29 H29B 109.1 . . ?
C30 C29 H29B 109.1 . . ?
H29A C29 H29B 107.9 . . ?
C29 C30 H30A 109.5 . . ?
C29 C30 H30B 109.5 . . ?
H30A C30 H30B 109.5 . . ?
C29 C30 H30C 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
N5 C31 C32 111.1(3) . . ?
N5 C31 H31A 109.4 . . ?
C32 C31 H31A 109.4 . . ?
N5 C31 H31B 109.4 . . ?
C32 C31 H31B 109.4 . . ?
H31A C31 H31B 108.0 . . ?
C31 C32 H32A 109.5 . . ?
C31 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
C31 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
N5 C33 C34 111.8(3) . . ?
N5 C33 H33A 109.3 . . ?
C34 C33 H33A 109.3 . . ?
N5 C33 H33B 109.3 . . ?
C34 C33 H33B 109.3 . . ?
H33A C33 H33B 107.9 . . ?
C33 C34 H34A 109.5 . . ?
C33 C34 H34B 109.5 . . ?
H34A C34 H34B 109.5 . . ?
C33 C34 H34C 109.5 . . ?
H34A C34 H34C 109.5 . . ?
H34B C34 H34C 109.5 . . ?
N5 C35 C36 112.1(3) . . ?
N5 C35 H35A 109.2 . . ?
C36 C35 H35A 109.2 . . ?
N5 C35 H35B 109.2 . . ?
C36 C35 H35B 109.2 . . ?
H35A C35 H35B 107.9 . . ?
C35 C36 H36A 109.5 . . ?
C35 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
C35 C36 H36C 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
N5 C29' C30' 112.4(2) . . ?
N5 C29' H29C 109.1 . . ?
C30' C29' H29C 109.1 . . ?
N5 C29' H29D 109.1 . . ?
C30' C29' H29D 109.1 . . ?
H29C C29' H29D 107.9 . . ?
C29' C30' H30D 109.5 . . ?
C29' C30' H30E 109.5 . . ?
H30D C30' H30E 109.5 . . ?
C29' C30' H30F 109.5 . . ?
H30D C30' H30F 109.5 . . ?
H30E C30' H30F 109.5 . . ?
N5 C31' C32' 111.7(3) . . ?
N5 C31' H31C 109.3 . . ?
C32' C31' H31C 109.3 . . ?
N5 C31' H31D 109.3 . . ?
C32' C31' H31D 109.3 . . ?
H31C C31' H31D 107.9 . . ?
C31' C32' H32D 109.5 . . ?
C31' C32' H32E 109.5 . . ?
H32D C32' H32E 109.5 . . ?
C31' C32' H32F 109.5 . . ?
H32D C32' H32F 109.5 . . ?
H32E C32' H32F 109.5 . . ?
N5 C33' C34' 111.2(2) . . ?
N5 C33' H33C 109.4 . . ?
C34' C33' H33C 109.4 . . ?
N5 C33' H33D 109.4 . . ?
C34' C33' H33D 109.4 . . ?
H33C C33' H33D 108.0 . . ?
C33' C34' H34D 109.5 . . ?
C33' C34' H34E 109.5 . . ?
H34D C34' H34E 109.5 . . ?
C33' C34' H34F 109.5 . . ?
H34D C34' H34F 109.5 . . ?
H34E C34' H34F 109.5 . . ?
N5 C35' C36' 112.9(2) . . ?
N5 C35' H35C 109.0 . . ?
C36' C35' H35C 109.0 . . ?
N5 C35' H35D 109.0 . . ?
C36' C35' H35D 109.0 . . ?
H35C C35' H35D 107.8 . . ?
C35' C36' H36D 109.5 . . ?
C35' C36' H36E 109.5 . . ?
H36D C36' H36E 109.5 . . ?
C35' C36' H36F 109.5 . . ?
H36D C36' H36F 109.5 . . ?
H36E C36' H36F 109.5 . . ?
N6 C37 C38 179.4(4) . . ?
C37 C38 H38A 109.5 . . ?
C37 C38 H38B 109.5 . . ?
H38A C38 H38B 109.5 . . ?
C37 C38 H38C 109.5 . . ?
H38A C38 H38C 109.5 . . ?
H38B C38 H38C 109.5 . . ?
N7 C39 C40 178.9(10) . . ?
C39 C40 H40A 109.5 . . ?
C39 C40 H40B 109.5 . . ?
H40A C40 H40B 109.5 . . ?
C39 C40 H40C 109.5 . . ?
H40A C40 H40C 109.5 . . ?
H40B C40 H40C 109.5 . . ?
N7' C39' C40' 176.5(10) . . ?
C39' C40' H40D 109.5 . . ?
C39' C40' H40E 109.5 . . ?
H40D C40' H40E 109.5 . . ?
C39' C40' H40F 109.5 . . ?
H40D C40' H40F 109.5 . . ?
H40E C40' H40F 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O6 Si2 O1 Si1 48.65(13) . . . . ?
O2 Si2 O1 Si1 -70.91(13) . . . . ?
C7 Si2 O1 Si1 173.70(11) . . . . ?
O5 Si1 O1 Si2 -48.48(13) . . . . ?
O4 Si1 O1 Si2 71.70(13) . . . . ?
C1 Si1 O1 Si2 -171.36(11) . . . . ?
O6 Si2 O2 Si3 -30.78(15) . . . . ?
O1 Si2 O2 Si3 88.24(13) . . . . ?
C7 Si2 O2 Si3 -156.94(12) . . . . ?
O7 Si3 O2 Si2 29.44(15) . . . . ?
O3 Si3 O2 Si2 -89.63(13) . . . . ?
C13 Si3 O2 Si2 152.55(12) . . . . ?
O7 Si3 O3 Si4 -46.43(14) . . . . ?
O2 Si3 O3 Si4 72.65(13) . . . . ?
C13 Si3 O3 Si4 -169.95(11) . . . . ?
O8 Si4 O3 Si3 48.67(14) . . . . ?
O4 Si4 O3 Si3 -71.30(13) . . . . ?
C19 Si4 O3 Si3 171.22(11) . . . . ?
O8 Si4 O4 Si1 -26.27(15) . . . . ?
O3 Si4 O4 Si1 93.09(14) . . . . ?
C19 Si4 O4 Si1 -149.63(13) . . . . ?
O5 Si1 O4 Si4 24.38(16) . . . . ?
O1 Si1 O4 Si4 -94.12(14) . . . . ?
C1 Si1 O4 Si4 146.87(13) . . . . ?
O4 Si1 O5 Dy2 -136.0(3) . . . . ?
O1 Si1 O5 Dy2 -17.7(3) . . . . ?
C1 Si1 O5 Dy2 104.3(3) . . . . ?
O4 Si1 O5 Eu1 -135.96(12) . . . . ?
O1 Si1 O5 Eu1 -17.66(14) . . . . ?
C1 Si1 O5 Eu1 104.32(13) . . . . ?
O4 Si1 O5 Dy1 29.3(3) . . . 2_665 ?
O1 Si1 O5 Dy1 147.6(3) . . . 2_665 ?
C1 Si1 O5 Dy1 -90.4(3) . . . 2_665 ?
O4 Si1 O5 Eu2 29.57(15) . . . 2_665 ?
O1 Si1 O5 Eu2 147.88(12) . . . 2_665 ?
C1 Si1 O5 Eu2 -90.15(14) . . . 2_665 ?
O2 Si2 O6 Dy2 136.8(3) . . . . ?
O1 Si2 O6 Dy2 17.0(3) . . . . ?
C7 Si2 O6 Dy2 -102.2(3) . . . . ?
O2 Si2 O6 Eu1 137.07(12) . . . . ?
O1 Si2 O6 Eu1 17.28(14) . . . . ?
C7 Si2 O6 Eu1 -101.90(14) . . . . ?
O2 Si2 O6 Dy1 -25.7(3) . . . . ?
O1 Si2 O6 Dy1 -145.5(3) . . . . ?
C7 Si2 O6 Dy1 95.3(3) . . . . ?
O2 Si2 O6 Eu2 -25.92(15) . . . . ?
O1 Si2 O6 Eu2 -145.71(13) . . . . ?
C7 Si2 O6 Eu2 95.11(14) . . . . ?
O2 Si3 O7 Dy1 28.5(3) . . . . ?
O3 Si3 O7 Dy1 148.1(3) . . . . ?
C13 Si3 O7 Dy1 -91.3(3) . . . . ?
O2 Si3 O7 Eu2 28.77(15) . . . . ?
O3 Si3 O7 Eu2 148.40(13) . . . . ?
C13 Si3 O7 Eu2 -91.00(14) . . . . ?
O2 Si3 O7 Eu1 -139.26(12) . . . 2_665 ?
O3 Si3 O7 Eu1 -19.63(14) . . . 2_665 ?
C13 Si3 O7 Eu1 100.97(13) . . . 2_665 ?
O2 Si3 O7 Dy2 -139.3(3) . . . 2_665 ?
O3 Si3 O7 Dy2 -19.7(3) . . . 2_665 ?
C13 Si3 O7 Dy2 100.9(3) . . . 2_665 ?
O4 Si4 O8 Eu1 134.23(12) . . . 2_665 ?
O3 Si4 O8 Eu1 16.01(14) . . . 2_665 ?
C19 Si4 O8 Eu1 -104.35(13) . . . 2_665 ?
O4 Si4 O8 Dy2 133.9(3) . . . 2_665 ?
O3 Si4 O8 Dy2 15.7(3) . . . 2_665 ?
C19 Si4 O8 Dy2 -104.6(3) . . . 2_665 ?
O4 Si4 O8 Dy1 -26.0(3) . . . 2_665 ?
O3 Si4 O8 Dy1 -144.3(3) . . . 2_665 ?
C19 Si4 O8 Dy1 95.4(3) . . . 2_665 ?
O4 Si4 O8 Eu2 -26.22(15) . . . 2_665 ?
O3 Si4 O8 Eu2 -144.45(13) . . . 2_665 ?
C19 Si4 O8 Eu2 95.19(14) . . . 2_665 ?
Dy2 O10 N1 O11 170.8(3) . . . . ?
Eu1 O10 N1 O9 -8.1(2) . . . . ?
Dy2 O10 N1 O9 -8.2(3) . . . . ?
Dy2 O10 N1 Eu1 -0.1(3) . . . . ?
Dy2 O9 N1 O11 -171.0(3) . . . . ?
Eu1 O9 N1 O11 -171.1(2) . . . . ?
Dy2 O9 N1 O10 7.9(3) . . . . ?
Eu1 O9 N1 O10 7.8(2) . . . . ?
Dy2 O9 N1 Eu1 0.2(3) . . . . ?
Eu1 O13 N2 O14 -175.9(2) . . . . ?
Dy2 O13 N2 O14 -176.2(3) . . . . ?
Eu1 O13 N2 O12 3.9(2) . . . . ?
Dy2 O13 N2 O12 3.6(3) . . . . ?
Eu1 O13 N2 Dy2 0.3(2) . . . . ?
Dy2 O13 N2 Eu1 -0.3(2) . . . . ?
Dy2 O12 N2 O14 176.1(3) . . . . ?
Eu1 O12 N2 O14 175.84(19) . . . . ?
Dy2 O12 N2 O13 -3.7(3) . . . . ?
Eu1 O12 N2 O13 -4.0(2) . . . . ?
Eu1 O12 N2 Dy2 -0.3(2) . . . . ?
Dy2 O12 N2 Eu1 0.3(2) . . . . ?
Eu2 O15 N3 O17 176.1(2) . . . . ?
Dy1 O15 N3 O17 176.2(3) . . . . ?
Eu2 O15 N3 O16 -3.4(2) . . . . ?
Dy1 O15 N3 O16 -3.3(3) . . . . ?
Dy1 O15 N3 Eu2 0.1(3) . . . . ?
Eu2 O15 N3 Dy1 -0.1(3) . . . . ?
Eu2 O16 N3 O17 -175.91(19) . . . . ?
Dy1 O16 N3 O17 -176.0(3) . . . . ?
Eu2 O16 N3 O15 3.6(2) . . . . ?
Dy1 O16 N3 O15 3.5(3) . . . . ?
Dy1 O16 N3 Eu2 -0.1(3) . . . . ?
Eu2 O16 N3 Dy1 0.1(3) . . . . ?
O5 Si1 C1 C6 -40.5(2) . . . . ?
O4 Si1 C1 C6 -162.33(17) . . . . ?
O1 Si1 C1 C6 80.28(19) . . . . ?
O5 Si1 C1 C2 134.69(17) . . . . ?
O4 Si1 C1 C2 12.8(2) . . . . ?
O1 Si1 C1 C2 -104.57(18) . . . . ?
C6 C1 C2 C3 -0.7(3) . . . . ?
Si1 C1 C2 C3 -176.00(19) . . . . ?
C1 C2 C3 C4 0.6(4) . . . . ?
C2 C3 C4 C5 0.0(4) . . . . ?
C3 C4 C5 C6 -0.4(4) . . . . ?
C4 C5 C6 C1 0.3(4) . . . . ?
C2 C1 C6 C5 0.3(3) . . . . ?
Si1 C1 C6 C5 175.56(19) . . . . ?
O6 Si2 C7 C8 82.46(19) . . . . ?
O2 Si2 C7 C8 -155.25(17) . . . . ?
O1 Si2 C7 C8 -38.02(19) . . . . ?
O6 Si2 C7 C12 -98.39(17) . . . . ?
O2 Si2 C7 C12 23.90(19) . . . . ?
O1 Si2 C7 C12 141.13(16) . . . . ?
C12 C7 C8 C9 1.2(3) . . . . ?
Si2 C7 C8 C9 -179.61(19) . . . . ?
C7 C8 C9 C10 -0.6(4) . . . . ?
C8 C9 C10 C11 -0.4(4) . . . . ?
C9 C10 C11 C12 0.9(4) . . . . ?
C10 C11 C12 C7 -0.3(3) . . . . ?
C8 C7 C12 C11 -0.7(3) . . . . ?
Si2 C7 C12 C11 -179.90(17) . . . . ?
O7 Si3 C13 C18 -99.01(19) . . . . ?
O2 Si3 C13 C18 140.56(18) . . . . ?
O3 Si3 C13 C18 21.9(2) . . . . ?
O7 Si3 C13 C14 79.77(19) . . . . ?
O2 Si3 C13 C14 -40.66(19) . . . . ?
O3 Si3 C13 C14 -159.36(17) . . . . ?
C18 C13 C14 C15 0.2(3) . . . . ?
Si3 C13 C14 C15 -178.67(19) . . . . ?
C13 C14 C15 C16 0.4(4) . . . . ?
C14 C15 C16 C17 -0.4(4) . . . . ?
C15 C16 C17 C18 -0.1(4) . . . . ?
C16 C17 C18 C13 0.7(4) . . . . ?
C14 C13 C18 C17 -0.7(4) . . . . ?
Si3 C13 C18 C17 178.1(2) . . . . ?
O8 Si4 C19 C20 5.98(19) . . . . ?
O4 Si4 C19 C20 128.34(16) . . . . ?
O3 Si4 C19 C20 -114.95(16) . . . . ?
O8 Si4 C19 C24 -174.31(16) . . . . ?
O4 Si4 C19 C24 -51.95(19) . . . . ?
O3 Si4 C19 C24 64.77(18) . . . . ?
C24 C19 C20 C21 -0.9(3) . . . . ?
Si4 C19 C20 C21 178.80(16) . . . . ?
C19 C20 C21 C22 0.0(3) . . . . ?
C20 C21 C22 C23 0.8(3) . . . . ?
C21 C22 C23 C24 -0.6(4) . . . . ?
C22 C23 C24 C19 -0.4(3) . . . . ?
C20 C19 C24 C23 1.1(3) . . . . ?
Si4 C19 C24 C23 -178.61(17) . . . . ?
Eu2 O18 C25 C26 170.4(2) . . . . ?
Dy1 O18 C25 C26 170.6(3) . . . . ?
C33 N5 C29 C30 175.5(4) . . . . ?
C35 N5 C29 C30 -56.1(6) . . . . ?
C31 N5 C29 C30 57.0(6) . . . . ?
C33 N5 C31 C32 -70.7(7) . . . . ?
C29 N5 C31 C32 51.0(8) . . . . ?
C35 N5 C31 C32 167.5(7) . . . . ?
C29 N5 C33 C34 69.4(7) . . . . ?
C35 N5 C33 C34 -55.8(7) . . . . ?
C31 N5 C33 C34 -170.3(6) . . . . ?
C33 N5 C35 C36 -45.4(7) . . . . ?
C29 N5 C35 C36 -172.2(6) . . . . ?
C31 N5 C35 C36 70.7(7) . . . . ?
C35' N5 C29' C30' -178.0(5) . . . . ?
C31' N5 C29' C30' -50.7(6) . . . . ?
C33' N5 C29' C30' 63.9(5) . . . . ?
C35' N5 C31' C32' 70.7(8) . . . . ?
C29' N5 C31' C32' -55.9(8) . . . . ?
C33' N5 C31' C32' -169.8(7) . . . . ?
C35' N5 C33' C34' 53.5(5) . . . . ?
C29' N5 C33' C34' 171.8(4) . . . . ?
C31' N5 C33' C34' -67.2(5) . . . . ?
C29' N5 C35' C36' -61.1(6) . . . . ?
C31' N5 C35' C36' 170.0(5) . . . . ?
C33' N5 C35' C36' 53.3(6) . . . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O18 H18O O9 0.76(3) 2.12(3) 2.871(2) 171(3) 2_665

_refine_diff_density_max         1.580
_refine_diff_density_min         -1.583
_refine_diff_density_rms         0.131

_shelxl_version_number           2013-4

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_2
_database_code_depnum_ccdc_archive 'CCDC 2240603'
loop_
_audit_author_name
_audit_author_address
'Victor Khrustalev'
;Peoples Friendship University of Russia (RUDN University, Moscow)
Russia
;
_audit_update_record             
;
2023-02-08 deposited with the CCDC.	2023-08-29 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2013
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         
'C56 H58 Dy3 N8 O36 Si8 Tb, 2(C8 H20 N), 4(C2 H3 N)'
_chemical_formula_sum            'C80 H110 Dy3 N14 O36 Si8 Tb'
_chemical_formula_weight         2714.97

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Tb Tb -0.1723 4.1537 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   13.2584(2)
_cell_length_b                   13.3275(2)
_cell_length_c                   16.0668(2)
_cell_angle_alpha                68.1098(15)
_cell_angle_beta                 85.3999(14)
_cell_angle_gamma                80.1109(15)
_cell_volume                     2594.78(7)
_cell_formula_units_Z            1
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    57543
_cell_measurement_theta_min      2.1
_cell_measurement_theta_max      35.4

_exptl_crystal_description       prism
_exptl_crystal_colour            colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.737
_exptl_crystal_F_000             1351
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.15
_exptl_absorpt_coefficient_mu    2.987
_shelx_estimated_absorpt_T_min   0.615
_shelx_estimated_absorpt_T_max   0.663
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.523
_exptl_absorpt_correction_T_max  0.632
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.41.117a (Rigaku Oxford Diffraction, 2021)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_measurement_device_type  'XtaLAB Synergy, Dualflex, HyPix'
_diffrn_measurement_method       'φ and ω'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            97988
_diffrn_reflns_av_unetI/netI     0.0457
_diffrn_reflns_av_R_equivalents  0.0611
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_theta_min         2.055
_diffrn_reflns_theta_max         35.427
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.909
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.909
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.909
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             21453
_reflns_number_gt                17586
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'CrysAlisPro 1.171.41.117a (Rigaku OD, 2021)'
_computing_cell_refinement       'CrysAlisPro 1.171.41.117a (Rigaku OD, 2021)'
_computing_data_reduction        'CrysAlisPro 1.171.41.117a (Rigaku OD, 2021)'
_computing_structure_solution    'SHELXT (Sheldrick, 2015)'
_computing_structure_refinement  'SHELXL (Sheldrick, 2015)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2015)'
_computing_publication_material  'SHELXTL (Sheldrick, 2015)'

_refine_special_details          
;
 ?
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0394P)²+4.0849P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     difmap
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         21453
_refine_ls_number_parameters     758
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0491
_refine_ls_R_factor_gt           0.0354
_refine_ls_wR_factor_ref         0.0891
_refine_ls_wR_factor_gt          0.0821
_refine_ls_goodness_of_fit_ref   1.031
_refine_ls_restrained_S_all      1.031
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.001

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.5091(2) 0.36034(16) 0.16341(16) 0.01050(11) Uani 0.75 1 d . . P A 1
Tb2 Tb 0.5089(6) 0.3680(5) 0.1624(5) 0.01050(11) Uani 0.25 1 d . . P A 2
Dy2 Dy 0.2975(2) 0.5139(2) 0.0101(2) 0.01077(10) Uani 0.75 1 d . . P A 1
Tb1 Tb 0.2941(7) 0.5188(7) 0.0081(6) 0.01077(10) Uani 0.25 1 d . . P A 2
Si1 Si 0.60430(5) 0.59484(6) 0.15480(4) 0.01263(11) Uani 1 1 d . . . . .
Si2 Si 0.37851(5) 0.61275(6) 0.16578(4) 0.01273(11) Uani 1 1 d . . . . .
Si3 Si 0.36687(5) 0.77233(5) -0.02508(4) 0.01189(11) Uani 1 1 d . . . . .
Si4 Si 0.59252(5) 0.75666(5) -0.03524(4) 0.01217(11) Uani 1 1 d . . . . .
O1 O 0.49165(13) 0.60751(15) 0.20310(12) 0.0143(3) Uani 1 1 d . . . . .
O2 O 0.34734(13) 0.72992(14) 0.08339(11) 0.0137(3) Uani 1 1 d . . . . .
O3 O 0.47465(13) 0.82224(14) -0.05056(12) 0.0144(3) Uani 1 1 d . . . . .
O4 O 0.61406(13) 0.71048(14) 0.07220(11) 0.0142(3) Uani 1 1 d . . . . .
O5 O 0.61220(13) 0.49605(14) 0.11785(11) 0.0134(3) Uani 1 1 d . . . . .
O6 O 0.38393(13) 0.51408(14) 0.12915(11) 0.0133(3) Uani 1 1 d . . . . .
O7 O 0.37488(13) 0.66943(14) -0.05703(11) 0.0124(3) Uani 1 1 d . . . . .
O8 O 0.60435(13) 0.65605(14) -0.07056(11) 0.0134(3) Uani 1 1 d . . . . .
O9 O 0.67063(15) 0.26227(17) 0.25180(13) 0.0205(4) Uani 1 1 d . . . . .
O10 O 0.55695(15) 0.16469(16) 0.24893(13) 0.0205(4) Uani 1 1 d . . . . .
O11 O 0.6861(2) 0.0898(2) 0.33881(17) 0.0375(6) Uani 1 1 d . . . . .
O12 O 0.48608(15) 0.34649(17) 0.31962(13) 0.0208(4) Uani 1 1 d . . . . .
O13 O 0.36827(15) 0.29009(17) 0.26987(12) 0.0196(4) Uani 1 1 d . . . . .
O14 O 0.36703(18) 0.2694(2) 0.41096(14) 0.0302(5) Uani 1 1 d . . . . .
O15 O 0.18137(16) 0.43347(17) 0.14379(13) 0.0216(4) Uani 1 1 d . . . . .
O16 O 0.15229(15) 0.60777(16) 0.06800(13) 0.0208(4) Uani 1 1 d . . . . .
O17 O 0.04747(16) 0.5336(2) 0.17655(15) 0.0282(5) Uani 1 1 d . . . . .
O18 O 0.18839(14) 0.64107(16) -0.11375(12) 0.0188(4) Uani 1 1 d . . . . .
H18O H 0.2218 0.6854 -0.1602 0.028 Uiso 1 1 d R U . A .
N1 N 0.64003(19) 0.1692(2) 0.28160(16) 0.0216(4) Uani 1 1 d . . . . .
N2 N 0.40552(18) 0.30065(19) 0.33566(15) 0.0192(4) Uani 1 1 d . . . . .
N3 N 0.12496(17) 0.52398(19) 0.13183(15) 0.0177(4) Uani 1 1 d . . . . .
N4 N 0.17905(17) 0.40322(19) -0.02127(16) 0.0195(4) Uani 1 1 d . . . . .
C1 C 0.70738(19) 0.5716(2) 0.23454(16) 0.0153(4) Uani 1 1 d . . . . .
C2 C 0.7377(2) 0.4682(2) 0.29995(18) 0.0210(5) Uani 1 1 d . . . . .
H2 H 0.7016 0.4098 0.3067 0.025 Uiso 1 1 calc R U . . .
C3 C 0.8201(2) 0.4498(2) 0.35539(18) 0.0227(5) Uani 1 1 d . . . . .
H3 H 0.8398 0.3791 0.3993 0.027 Uiso 1 1 calc R U . . .
C4 C 0.8730(2) 0.5335(2) 0.34680(18) 0.0213(5) Uani 1 1 d . . . . .
H4 H 0.9289 0.5207 0.3847 0.026 Uiso 1 1 calc R U . . .
C5 C 0.8445(2) 0.6362(2) 0.2829(2) 0.0252(6) Uani 1 1 d . . . . .
H5 H 0.8807 0.6941 0.2772 0.030 Uiso 1 1 calc R U . . .
C6 C 0.7627(2) 0.6552(2) 0.2268(2) 0.0216(5) Uani 1 1 d . . . . .
H6 H 0.7443 0.7260 0.1827 0.026 Uiso 1 1 calc R U . . .
C7 C 0.28609(19) 0.6107(2) 0.25940(16) 0.0157(4) Uani 1 1 d . . . . .
C8 C 0.3129(2) 0.5460(2) 0.34823(18) 0.0248(6) Uani 1 1 d . . . . .
H8 H 0.3788 0.5030 0.3603 0.030 Uiso 1 1 calc R U . . .
C9 C 0.2443(3) 0.5439(3) 0.41912(19) 0.0306(7) Uani 1 1 d . . . . .
H9 H 0.2635 0.4993 0.4789 0.037 Uiso 1 1 calc R U . . .
C10 C 0.1479(2) 0.6069(3) 0.4024(2) 0.0269(6) Uani 1 1 d . . . . .
H10 H 0.1008 0.6045 0.4505 0.032 Uiso 1 1 calc R U . . .
C11 C 0.1206(2) 0.6735(3) 0.31522(19) 0.0234(5) Uani 1 1 d . . . . .
H11 H 0.0554 0.7181 0.3038 0.028 Uiso 1 1 calc R U . . .
C12 C 0.1893(2) 0.6748(2) 0.24423(17) 0.0193(5) Uani 1 1 d . . . . .
H12 H 0.1698 0.7201 0.1846 0.023 Uiso 1 1 calc R U . . .
C13 C 0.26079(18) 0.8844(2) -0.07768(16) 0.0148(4) Uani 1 1 d . . . . .
C14 C 0.1597(2) 0.8762(2) -0.0458(2) 0.0214(5) Uani 1 1 d . . . . .
H14 H 0.1457 0.8130 0.0034 0.026 Uiso 1 1 calc R U . . .
C15 C 0.0796(2) 0.9593(3) -0.0853(2) 0.0282(6) Uani 1 1 d . . . . .
H15 H 0.0117 0.9527 -0.0624 0.034 Uiso 1 1 calc R U . . .
C16 C 0.0981(3) 1.0510(3) -0.1575(3) 0.0330(7) Uani 1 1 d . . . . .
H16 H 0.0432 1.1074 -0.1844 0.040 Uiso 1 1 calc R U . . .
C17 C 0.1973(3) 1.0604(3) -0.1905(3) 0.0349(8) Uani 1 1 d . . . . .
H17 H 0.2104 1.1231 -0.2406 0.042 Uiso 1 1 calc R U . . .
C18 C 0.2777(2) 0.9780(2) -0.1505(2) 0.0246(6) Uani 1 1 d . . . . .
H18 H 0.3454 0.9858 -0.1733 0.029 Uiso 1 1 calc R U . . .
C19 C 0.68130(18) 0.8553(2) -0.09445(16) 0.0139(4) Uani 1 1 d . . . . .
C20 C 0.6899(2) 0.9433(2) -0.06852(18) 0.0196(5) Uani 1 1 d . . . . .
H20 H 0.6505 0.9516 -0.0188 0.024 Uiso 1 1 calc R U . . .
C21 C 0.7551(2) 1.0186(2) -0.1143(2) 0.0233(5) Uani 1 1 d . . . . .
H21 H 0.7597 1.0776 -0.0960 0.028 Uiso 1 1 calc R U . . .
C22 C 0.8137(2) 1.0069(2) -0.1873(2) 0.0231(5) Uani 1 1 d . . . . .
H22 H 0.8580 1.0582 -0.2190 0.028 Uiso 1 1 calc R U . . .
C23 C 0.8069(2) 0.9202(2) -0.21345(19) 0.0207(5) Uani 1 1 d . . . . .
H23 H 0.8470 0.9121 -0.2629 0.025 Uiso 1 1 calc R U . . .
C24 C 0.7414(2) 0.8446(2) -0.16745(17) 0.0174(4) Uani 1 1 d . . . . .
H24 H 0.7376 0.7854 -0.1859 0.021 Uiso 1 1 calc R U . . .
C25 C 0.0921(2) 0.6367(3) -0.1461(2) 0.0256(6) Uani 1 1 d . . . . .
H25A H 0.0432 0.6155 -0.0950 0.031 Uiso 1 1 calc R U . . .
H25B H 0.1017 0.5798 -0.1730 0.031 Uiso 1 1 calc R U . . .
C26 C 0.0484(3) 0.7436(3) -0.2142(3) 0.0364(8) Uani 1 1 d . . . . .
H26A H -0.0192 0.7384 -0.2316 0.055 Uiso 1 1 calc R U . . .
H26B H 0.0939 0.7619 -0.2671 0.055 Uiso 1 1 calc R U . . .
H26C H 0.0415 0.8007 -0.1887 0.055 Uiso 1 1 calc R U . . .
C27 C 0.1356(2) 0.3378(2) -0.02394(19) 0.0191(5) Uani 1 1 d . . . . .
C28 C 0.0809(2) 0.2522(3) -0.0249(2) 0.0274(6) Uani 1 1 d . . . . .
H28A H 0.1298 0.1858 -0.0186 0.041 Uiso 1 1 calc R U . . .
H28B H 0.0450 0.2769 -0.0817 0.041 Uiso 1 1 calc R U . . .
H28C H 0.0312 0.2364 0.0251 0.041 Uiso 1 1 calc R U . . .
N5 N 0.5441(2) 0.1553(2) 0.62887(17) 0.0274(5) Uani 1 1 d . . . . .
C29 C 0.4508(7) 0.2403(6) 0.5972(5) 0.0314(16) Uani 0.5 1 d . . P B 1
H29A H 0.4590 0.2813 0.5321 0.038 Uiso 0.5 1 calc R U P B 1
H29B H 0.4469 0.2928 0.6280 0.038 Uiso 0.5 1 calc R U P B 1
C30 C 0.3487(5) 0.1940(7) 0.6137(4) 0.0393(18) Uani 0.5 1 d . . P B 1
H30A H 0.2920 0.2542 0.5912 0.059 Uiso 0.5 1 calc R U P B 1
H30B H 0.3386 0.1550 0.6781 0.059 Uiso 0.5 1 calc R U P B 1
H30C H 0.3508 0.1433 0.5821 0.059 Uiso 0.5 1 calc R U P B 1
C31 C 0.6020(8) 0.2267(6) 0.5504(6) 0.049(2) Uani 0.5 1 d . . P B 1
H31A H 0.5769 0.2254 0.4944 0.058 Uiso 0.5 1 calc R U P B 1
H31B H 0.5856 0.3030 0.5481 0.058 Uiso 0.5 1 calc R U P B 1
C32 C 0.7160(9) 0.1952(10) 0.5519(9) 0.072(3) Uani 0.5 1 d . . P B 1
H32A H 0.7464 0.2453 0.4981 0.108 Uiso 0.5 1 calc R U P B 1
H32B H 0.7338 0.1202 0.5531 0.108 Uiso 0.5 1 calc R U P B 1
H32C H 0.7426 0.1996 0.6054 0.108 Uiso 0.5 1 calc R U P B 1
C33 C 0.5708(5) 0.1841(5) 0.7128(4) 0.0296(13) Uani 0.5 1 d . . P B 1
H33A H 0.6433 0.1540 0.7288 0.036 Uiso 0.5 1 calc R U P B 1
H33B H 0.5630 0.2646 0.6947 0.036 Uiso 0.5 1 calc R U P B 1
C34 C 0.503(3) 0.138(2) 0.796(2) 0.027(4) Uani 0.5 1 d . . P B 1
H34A H 0.5222 0.1588 0.8446 0.040 Uiso 0.5 1 calc R U P B 1
H34B H 0.5114 0.0585 0.8158 0.040 Uiso 0.5 1 calc R U P B 1
H34C H 0.4308 0.1688 0.7814 0.040 Uiso 0.5 1 calc R U P B 1
C35 C 0.5802(6) 0.0373(6) 0.6532(5) 0.0370(15) Uani 0.5 1 d . . P B 1
H35A H 0.5399 -0.0039 0.7057 0.044 Uiso 0.5 1 calc R U P B 1
H35B H 0.6528 0.0210 0.6708 0.044 Uiso 0.5 1 calc R U P B 1
C36 C 0.5705(8) -0.0004(7) 0.5774(5) 0.0446(19) Uani 0.5 1 d . . P B 1
H36A H 0.6031 -0.0768 0.5936 0.067 Uiso 0.5 1 calc R U P B 1
H36B H 0.6042 0.0454 0.5234 0.067 Uiso 0.5 1 calc R U P B 1
H36C H 0.4979 0.0056 0.5656 0.067 Uiso 0.5 1 calc R U P B 1
C29' C 0.4325(6) 0.1875(10) 0.6139(5) 0.044(2) Uani 0.5 1 d . . P B 2
H29C H 0.3974 0.1408 0.6675 0.053 Uiso 0.5 1 calc R U P B 2
H29D H 0.4167 0.1687 0.5628 0.053 Uiso 0.5 1 calc R U P B 2
C30' C 0.3848(9) 0.3035(10) 0.5958(6) 0.081(5) Uani 0.5 1 d . . P B 2
H30D H 0.3111 0.3115 0.5871 0.122 Uiso 0.5 1 calc R U P B 2
H30E H 0.4161 0.3517 0.5415 0.122 Uiso 0.5 1 calc R U P B 2
H30F H 0.3960 0.3235 0.6468 0.122 Uiso 0.5 1 calc R U P B 2
C31' C 0.6384(6) 0.2048(6) 0.6107(5) 0.0373(16) Uani 0.5 1 d . . P B 2
H31C H 0.6967 0.1462 0.6361 0.045 Uiso 0.5 1 calc R U P B 2
H31D H 0.6331 0.2562 0.6427 0.045 Uiso 0.5 1 calc R U P B 2
C32' C 0.6625(8) 0.2662(9) 0.5121(6) 0.052(2) Uani 0.5 1 d . . P B 2
H32D H 0.7232 0.3009 0.5071 0.079 Uiso 0.5 1 calc R U P B 2
H32E H 0.6041 0.3224 0.4851 0.079 Uiso 0.5 1 calc R U P B 2
H32F H 0.6755 0.2147 0.4806 0.079 Uiso 0.5 1 calc R U P B 2
C33' C 0.5353(4) 0.0785(5) 0.7254(4) 0.0201(10) Uani 0.5 1 d . . P B 2
H33C H 0.4803 0.0346 0.7309 0.024 Uiso 0.5 1 calc R U P B 2
H33D H 0.6004 0.0275 0.7428 0.024 Uiso 0.5 1 calc R U P B 2
C34' C 0.512(3) 0.140(2) 0.788(2) 0.033(6) Uani 0.5 1 d . . P B 2
H34D H 0.5087 0.0876 0.8496 0.049 Uiso 0.5 1 calc R U P B 2
H34E H 0.4464 0.1879 0.7723 0.049 Uiso 0.5 1 calc R U P B 2
H34F H 0.5664 0.1835 0.7822 0.049 Uiso 0.5 1 calc R U P B 2
C35' C 0.5493(5) 0.0784(5) 0.5718(4) 0.0230(10) Uani 0.5 1 d . . P B 2
H35C H 0.4882 0.0410 0.5870 0.028 Uiso 0.5 1 calc R U P B 2
H35D H 0.5460 0.1252 0.5073 0.028 Uiso 0.5 1 calc R U P B 2
C36' C 0.6457(6) -0.0088(7) 0.5867(5) 0.0373(16) Uani 0.5 1 d . . P B 2
H36D H 0.6458 -0.0476 0.5455 0.056 Uiso 0.5 1 calc R U P B 2
H36E H 0.6457 -0.0610 0.6487 0.056 Uiso 0.5 1 calc R U P B 2
H36F H 0.7069 0.0267 0.5753 0.056 Uiso 0.5 1 calc R U P B 2
N6 N 0.0970(4) 0.2972(4) 0.5341(3) 0.0587(11) Uani 1 1 d . . . . .
C37 C 0.1113(3) 0.3177(4) 0.4593(3) 0.0402(8) Uani 1 1 d . . . . .
C38 C 0.1275(3) 0.3447(4) 0.3638(3) 0.0417(9) Uani 1 1 d . . . . .
H38A H 0.0612 0.3658 0.3342 0.063 Uiso 1 1 calc R U . . .
H38B H 0.1655 0.2809 0.3527 0.063 Uiso 1 1 calc R U . . .
H38C H 0.1667 0.4057 0.3397 0.063 Uiso 1 1 calc R U . . .
N7 N 1.0977(7) 0.9125(10) 0.4306(7) 0.074(3) Uani 0.5 1 d . . P C 1
C39 C 1.0142(7) 0.9422(8) 0.4138(6) 0.048(2) Uani 0.5 1 d . . P C 1
C40 C 0.909(2) 0.983(2) 0.3907(18) 0.063(7) Uani 0.5 1 d . . P C 1
H40A H 0.8772 1.0201 0.4311 0.095 Uiso 0.5 1 calc R U P C 1
H40B H 0.8732 0.9227 0.3965 0.095 Uiso 0.5 1 calc R U P C 1
H40C H 0.9052 1.0358 0.3287 0.095 Uiso 0.5 1 calc R U P C 1
N7' N 0.8715(9) 0.9399(9) 0.5515(7) 0.077(3) Uani 0.5 1 d . . P D 2
C39' C 0.8950(8) 0.9488(8) 0.4799(7) 0.054(2) Uani 0.5 1 d . . P D 2
C40' C 0.926(2) 0.963(2) 0.3880(15) 0.053(5) Uani 0.5 1 d . . P D 2
H40D H 0.9429 0.8911 0.3826 0.080 Uiso 0.5 1 calc R U P D 2
H40E H 0.9855 1.0009 0.3713 0.080 Uiso 0.5 1 calc R U P D 2
H40F H 0.8690 1.0063 0.3480 0.080 Uiso 0.5 1 calc R U P D 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O8 2.291(3) 2_665 ?
Dy1 O7 2.307(3) 2_665 ?
Dy1 O5 2.319(3) . ?
Dy1 O6 2.322(3) . ?
Dy1 O12 2.445(3) . ?
Dy1 O10 2.447(3) . ?
Dy1 O13 2.486(3) . ?
Dy1 O9 2.541(3) . ?
Dy1 N2 2.881(3) . ?
Dy1 N1 2.918(3) . ?
Tb2 O5 2.243(8) . ?
Tb2 O6 2.254(7) . ?
Tb2 O8 2.326(9) 2_665 ?
Tb2 O7 2.331(8) 2_665 ?
Tb2 O12 2.434(8) . ?
Tb2 O13 2.520(8) . ?
Tb2 O10 2.534(7) . ?
Tb2 O9 2.567(8) . ?
Tb2 N2 2.895(8) . ?
Dy2 O8 2.306(3) 2_665 ?
Dy2 O6 2.309(4) . ?
Dy2 O7 2.324(4) . ?
Dy2 O5 2.330(4) 2_665 ?
Dy2 O16 2.428(4) . ?
Dy2 O18 2.456(3) . ?
Dy2 N4 2.524(4) . ?
Dy2 O15 2.541(4) . ?
Dy2 N3 2.907(4) . ?
Tb1 O7 2.295(10) . ?
Tb1 O6 2.337(11) . ?
Tb1 O5 2.343(10) 2_665 ?
Tb1 O8 2.376(8) 2_665 ?
Tb1 O16 2.380(10) . ?
Tb1 O18 2.394(8) . ?
Tb1 N4 2.527(12) . ?
Tb1 O15 2.548(9) . ?
Tb1 N3 2.885(10) . ?
Si1 O5 1.6193(19) . ?
Si1 O4 1.6338(19) . ?
Si1 O1 1.6391(19) . ?
Si1 C1 1.856(2) . ?
Si2 O6 1.6183(19) . ?
Si2 O2 1.6390(19) . ?
Si2 O1 1.6406(18) . ?
Si2 C7 1.857(3) . ?
Si3 O7 1.6191(18) . ?
Si3 O2 1.6331(18) . ?
Si3 O3 1.6376(19) . ?
Si3 C13 1.858(2) . ?
Si4 O8 1.6203(19) . ?
Si4 O4 1.6331(18) . ?
Si4 O3 1.6427(19) . ?
Si4 C19 1.854(2) . ?
O9 N1 1.277(3) . ?
O10 N1 1.277(3) . ?
O11 N1 1.216(3) . ?
O12 N2 1.282(3) . ?
O13 N2 1.265(3) . ?
O14 N2 1.223(3) . ?
O15 N3 1.262(3) . ?
O16 N3 1.287(3) . ?
O17 N3 1.222(3) . ?
O18 C25 1.434(3) . ?
O18 H18O 0.8998 . ?
N4 C27 1.138(3) . ?
C1 C6 1.399(4) . ?
C1 C2 1.401(4) . ?
C2 C3 1.396(4) . ?
C2 H2 0.9500 . ?
C3 C4 1.376(4) . ?
C3 H3 0.9500 . ?
C4 C5 1.381(4) . ?
C4 H4 0.9500 . ?
C5 C6 1.394(4) . ?
C5 H5 0.9500 . ?
C6 H6 0.9500 . ?
C7 C12 1.398(4) . ?
C7 C8 1.402(4) . ?
C8 C9 1.394(4) . ?
C8 H8 0.9500 . ?
C9 C10 1.389(5) . ?
C9 H9 0.9500 . ?
C10 C11 1.387(4) . ?
C10 H10 0.9500 . ?
C11 C12 1.398(4) . ?
C11 H11 0.9500 . ?
C12 H12 0.9500 . ?
C13 C18 1.393(4) . ?
C13 C14 1.403(4) . ?
C14 C15 1.392(4) . ?
C14 H14 0.9500 . ?
C15 C16 1.378(5) . ?
C15 H15 0.9500 . ?
C16 C17 1.387(5) . ?
C16 H16 0.9500 . ?
C17 C18 1.391(4) . ?
C17 H17 0.9500 . ?
C18 H18 0.9500 . ?
C19 C24 1.402(4) . ?
C19 C20 1.408(4) . ?
C20 C21 1.393(4) . ?
C20 H20 0.9500 . ?
C21 C22 1.396(4) . ?
C21 H21 0.9500 . ?
C22 C23 1.387(4) . ?
C22 H22 0.9500 . ?
C23 C24 1.399(4) . ?
C23 H23 0.9500 . ?
C24 H24 0.9500 . ?
C25 C26 1.490(5) . ?
C25 H25A 0.9900 . ?
C25 H25B 0.9900 . ?
C26 H26A 0.9800 . ?
C26 H26B 0.9800 . ?
C26 H26C 0.9800 . ?
C27 C28 1.458(4) . ?
C28 H28A 0.9800 . ?
C28 H28B 0.9800 . ?
C28 H28C 0.9800 . ?
N5 C31' 1.472(7) . ?
N5 C35 1.472(8) . ?
N5 C29' 1.481(8) . ?
N5 C29 1.504(8) . ?
N5 C31 1.513(8) . ?
N5 C33' 1.515(6) . ?
N5 C35' 1.599(7) . ?
N5 C33 1.613(7) . ?
C29 C30 1.546(12) . ?
C29 H29A 0.9900 . ?
C29 H29B 0.9900 . ?
C30 H30A 0.9800 . ?
C30 H30B 0.9800 . ?
C30 H30C 0.9800 . ?
C31 C32 1.497(15) . ?
C31 H31A 0.9900 . ?
C31 H31B 0.9900 . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32 H32C 0.9800 . ?
C33 C34 1.54(4) . ?
C33 H33A 0.9900 . ?
C33 H33B 0.9900 . ?
C34 H34A 0.9800 . ?
C34 H34B 0.9800 . ?
C34 H34C 0.9800 . ?
C35 C36 1.503(11) . ?
C35 H35A 0.9900 . ?
C35 H35B 0.9900 . ?
C36 H36A 0.9800 . ?
C36 H36B 0.9800 . ?
C36 H36C 0.9800 . ?
C29' C30' 1.495(15) . ?
C29' H29C 0.9900 . ?
C29' H29D 0.9900 . ?
C30' H30D 0.9800 . ?
C30' H30E 0.9800 . ?
C30' H30F 0.9800 . ?
C31' C32' 1.524(11) . ?
C31' H31C 0.9900 . ?
C31' H31D 0.9900 . ?
C32' H32D 0.9800 . ?
C32' H32E 0.9800 . ?
C32' H32F 0.9800 . ?
C33' C34' 1.49(3) . ?
C33' H33C 0.9900 . ?
C33' H33D 0.9900 . ?
C34' H34D 0.9800 . ?
C34' H34E 0.9800 . ?
C34' H34F 0.9800 . ?
C35' C36' 1.541(9) . ?
C35' H35C 0.9900 . ?
C35' H35D 0.9900 . ?
C36' H36D 0.9800 . ?
C36' H36E 0.9800 . ?
C36' H36F 0.9800 . ?
N6 C37 1.137(5) . ?
C37 C38 1.446(5) . ?
C38 H38A 0.9800 . ?
C38 H38B 0.9800 . ?
C38 H38C 0.9800 . ?
N7 C39 1.128(12) . ?
C39 C40 1.43(3) . ?
C40 H40A 0.9800 . ?
C40 H40B 0.9800 . ?
C40 H40C 0.9800 . ?
N7' C39' 1.134(13) . ?
C39' C40' 1.45(3) . ?
C40' H40D 0.9800 . ?
C40' H40E 0.9800 . ?
C40' H40F 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O8 Dy1 O7 81.84(10) 2_665 2_665 ?
O8 Dy1 O5 123.06(11) 2_665 . ?
O7 Dy1 O5 71.48(10) 2_665 . ?
O8 Dy1 O6 72.82(10) 2_665 . ?
O7 Dy1 O6 121.96(11) 2_665 . ?
O5 Dy1 O6 80.24(9) . . ?
O8 Dy1 O12 129.38(13) 2_665 . ?
O7 Dy1 O12 144.94(13) 2_665 . ?
O5 Dy1 O12 96.99(11) . . ?
O6 Dy1 O12 86.71(10) . . ?
O8 Dy1 O10 97.05(10) 2_665 . ?
O7 Dy1 O10 85.21(10) 2_665 . ?
O5 Dy1 O10 128.31(13) . . ?
O6 Dy1 O10 147.85(13) . . ?
O12 Dy1 O10 76.35(9) . . ?
O8 Dy1 O13 78.14(10) 2_665 . ?
O7 Dy1 O13 145.63(12) 2_665 . ?
O5 Dy1 O13 142.78(13) . . ?
O6 Dy1 O13 77.99(10) . . ?
O12 Dy1 O13 52.13(8) . . ?
O10 Dy1 O13 70.02(9) . . ?
O8 Dy1 O9 142.41(12) 2_665 . ?
O7 Dy1 O9 76.18(10) 2_665 . ?
O5 Dy1 O9 77.98(10) . . ?
O6 Dy1 O9 144.76(13) . . ?
O12 Dy1 O9 68.98(9) . . ?
O10 Dy1 O9 51.45(8) . . ?
O13 Dy1 O9 103.92(10) . . ?
O8 Dy1 N2 103.90(11) 2_665 . ?
O7 Dy1 N2 154.87(11) 2_665 . ?
O5 Dy1 N2 121.47(12) . . ?
O6 Dy1 N2 82.80(10) . . ?
O12 Dy1 N2 26.25(7) . . ?
O10 Dy1 N2 69.88(9) . . ?
O13 Dy1 N2 25.94(7) . . ?
O9 Dy1 N2 85.35(9) . . ?
O8 Dy1 N1 121.25(10) 2_665 . ?
O7 Dy1 N1 81.59(9) 2_665 . ?
O5 Dy1 N1 103.69(11) . . ?
O6 Dy1 N1 155.50(13) . . ?
O12 Dy1 N1 68.86(9) . . ?
O10 Dy1 N1 25.67(7) . . ?
O13 Dy1 N1 85.29(9) . . ?
O9 Dy1 N1 25.91(7) . . ?
N2 Dy1 N1 74.50(8) . . ?
O5 Tb2 O6 83.4(2) . . ?
O5 Tb2 O8 125.0(3) . 2_665 ?
O6 Tb2 O8 73.4(2) . 2_665 ?
O5 Tb2 O7 72.4(2) . 2_665 ?
O6 Tb2 O7 123.9(3) . 2_665 ?
O8 Tb2 O7 80.6(3) 2_665 2_665 ?
O5 Tb2 O12 99.4(3) . . ?
O6 Tb2 O12 88.5(3) . . ?
O8 Tb2 O12 128.2(4) 2_665 . ?
O7 Tb2 O12 143.9(4) 2_665 . ?
O5 Tb2 O13 145.9(4) . . ?
O6 Tb2 O13 78.5(3) . . ?
O8 Tb2 O13 76.8(2) 2_665 . ?
O7 Tb2 O13 141.4(3) 2_665 . ?
O12 Tb2 O13 51.84(17) . . ?
O5 Tb2 O10 127.7(4) . . ?
O6 Tb2 O10 146.3(4) . . ?
O8 Tb2 O10 93.8(3) 2_665 . ?
O7 Tb2 O10 82.8(2) 2_665 . ?
O12 Tb2 O10 75.0(2) . . ?
O13 Tb2 O10 68.12(18) . . ?
O5 Tb2 O9 78.8(3) . . ?
O6 Tb2 O9 148.0(4) . . ?
O8 Tb2 O9 138.4(3) 2_665 . ?
O7 Tb2 O9 75.2(2) 2_665 . ?
O12 Tb2 O9 68.7(2) . . ?
O13 Tb2 O9 102.2(3) . . ?
O10 Tb2 O9 50.26(15) . . ?
O5 Tb2 N2 123.9(3) . . ?
O6 Tb2 N2 83.6(3) . . ?
O8 Tb2 N2 102.6(3) 2_665 . ?
O7 Tb2 N2 151.2(3) 2_665 . ?
O12 Tb2 N2 26.03(10) . . ?
O13 Tb2 N2 25.84(10) . . ?
O10 Tb2 N2 68.55(18) . . ?
O9 Tb2 N2 84.6(2) . . ?
O8 Dy2 O6 72.81(10) 2_665 . ?
O8 Dy2 O7 120.45(14) 2_665 . ?
O6 Dy2 O7 78.58(13) . . ?
O8 Dy2 O5 80.02(12) 2_665 2_665 ?
O6 Dy2 O5 119.99(15) . 2_665 ?
O7 Dy2 O5 70.98(10) . 2_665 ?
O8 Dy2 O16 132.64(14) 2_665 . ?
O6 Dy2 O16 84.81(13) . . ?
O7 Dy2 O16 93.96(13) . . ?
O5 Dy2 O16 145.84(13) 2_665 . ?
O8 Dy2 O18 146.85(18) 2_665 . ?
O6 Dy2 O18 139.71(16) . . ?
O7 Dy2 O18 72.66(9) . . ?
O5 Dy2 O18 76.24(11) 2_665 . ?
O16 Dy2 O18 69.95(10) . . ?
O8 Dy2 N4 82.06(12) 2_665 . ?
O6 Dy2 N4 138.99(14) . . ?
O7 Dy2 N4 142.40(15) . . ?
O5 Dy2 N4 85.63(14) 2_665 . ?
O16 Dy2 N4 89.30(13) . . ?
O18 Dy2 N4 73.42(12) . . ?
O8 Dy2 O15 82.42(10) 2_665 . ?
O6 Dy2 O15 76.89(11) . . ?
O7 Dy2 O15 138.97(17) . . ?
O5 Dy2 O15 150.01(17) 2_665 . ?
O16 Dy2 O15 51.60(9) . . ?
O18 Dy2 O15 107.69(13) . . ?
N4 Dy2 O15 67.95(11) . . ?
O8 Dy2 N3 107.70(12) 2_665 . ?
O6 Dy2 N3 80.79(11) . . ?
O7 Dy2 N3 117.80(14) . . ?
O5 Dy2 N3 159.20(16) 2_665 . ?
O16 Dy2 N3 25.97(7) . . ?
O18 Dy2 N3 88.22(11) . . ?
N4 Dy2 N3 76.62(11) . . ?
O15 Dy2 N3 25.67(7) . . ?
O7 Tb1 O6 78.6(4) . . ?
O7 Tb1 O5 71.3(3) . 2_665 ?
O6 Tb1 O5 118.3(4) . 2_665 ?
O7 Tb1 O8 118.7(4) . 2_665 ?
O6 Tb1 O8 71.0(2) . 2_665 ?
O5 Tb1 O8 78.3(3) 2_665 2_665 ?
O7 Tb1 O16 96.0(4) . . ?
O6 Tb1 O16 85.3(4) . . ?
O5 Tb1 O16 148.7(4) 2_665 . ?
O8 Tb1 O16 131.4(4) 2_665 . ?
O7 Tb1 O18 74.3(2) . . ?
O6 Tb1 O18 142.0(5) . . ?
O5 Tb1 O18 77.2(3) 2_665 . ?
O8 Tb1 O18 146.2(5) 2_665 . ?
O16 Tb1 O18 71.8(2) . . ?
O7 Tb1 N4 144.3(4) . . ?
O6 Tb1 N4 137.1(4) . . ?
O5 Tb1 N4 85.3(4) 2_665 . ?
O8 Tb1 N4 80.6(3) 2_665 . ?
O16 Tb1 N4 90.3(3) . . ?
O18 Tb1 N4 74.4(3) . . ?
O7 Tb1 O15 140.3(5) . . ?
O6 Tb1 O15 76.3(3) . . ?
O5 Tb1 O15 148.3(5) 2_665 . ?
O8 Tb1 O15 80.9(3) 2_665 . ?
O16 Tb1 O15 52.0(2) . . ?
O18 Tb1 O15 109.4(4) . . ?
N4 Tb1 O15 67.8(3) . . ?
O7 Tb1 N3 119.7(4) . . ?
O6 Tb1 N3 80.8(3) . . ?
O5 Tb1 N3 160.5(5) 2_665 . ?
O8 Tb1 N3 106.4(3) 2_665 . ?
O16 Tb1 N3 26.11(12) . . ?
O18 Tb1 N3 90.0(3) . . ?
N4 Tb1 N3 77.0(3) . . ?
O15 Tb1 N3 25.92(11) . . ?
O5 Si1 O4 110.73(9) . . ?
O5 Si1 O1 108.43(10) . . ?
O4 Si1 O1 107.95(10) . . ?
O5 Si1 C1 112.28(11) . . ?
O4 Si1 C1 107.03(11) . . ?
O1 Si1 C1 110.34(10) . . ?
O6 Si2 O2 109.22(9) . . ?
O6 Si2 O1 108.42(9) . . ?
O2 Si2 O1 109.81(10) . . ?
O6 Si2 C7 116.18(11) . . ?
O2 Si2 C7 106.89(11) . . ?
O1 Si2 C7 106.19(10) . . ?
O7 Si3 O2 108.84(9) . . ?
O7 Si3 O3 108.81(9) . . ?
O2 Si3 O3 109.69(9) . . ?
O7 Si3 C13 113.68(10) . . ?
O2 Si3 C13 107.52(10) . . ?
O3 Si3 C13 108.25(10) . . ?
O8 Si4 O4 110.25(9) . . ?
O8 Si4 O3 109.49(9) . . ?
O4 Si4 O3 107.44(10) . . ?
O8 Si4 C19 112.33(11) . . ?
O4 Si4 C19 108.67(10) . . ?
O3 Si4 C19 108.52(10) . . ?
Si1 O1 Si2 128.84(11) . . ?
Si3 O2 Si2 133.68(12) . . ?
Si3 O3 Si4 128.82(11) . . ?
Si4 O4 Si1 134.10(12) . . ?
Si1 O5 Tb2 124.4(2) . . ?
Si1 O5 Dy1 125.72(12) . . ?
Si1 O5 Dy2 125.87(13) . 2_665 ?
Dy1 O5 Dy2 107.19(13) . 2_665 ?
Si1 O5 Tb1 126.7(3) . 2_665 ?
Tb2 O5 Tb1 107.7(3) . 2_665 ?
Si2 O6 Tb2 124.3(2) . . ?
Si2 O6 Dy2 127.76(12) . . ?
Si2 O6 Dy1 125.73(11) . . ?
Dy2 O6 Dy1 105.03(12) . . ?
Si2 O6 Tb1 126.2(2) . . ?
Tb2 O6 Tb1 107.7(3) . . ?
Si3 O7 Tb1 126.7(3) . . ?
Si3 O7 Dy1 123.98(11) . 2_665 ?
Si3 O7 Dy2 127.33(13) . . ?
Dy1 O7 Dy2 107.83(12) 2_665 . ?
Si3 O7 Tb2 126.2(2) . 2_665 ?
Tb1 O7 Tb2 106.4(3) . 2_665 ?
Si4 O8 Dy1 124.18(11) . 2_665 ?
Si4 O8 Dy2 127.52(13) . 2_665 ?
Dy1 O8 Dy2 106.13(13) 2_665 2_665 ?
Si4 O8 Tb2 126.2(2) . 2_665 ?
Si4 O8 Tb1 127.4(3) . 2_665 ?
Tb2 O8 Tb1 104.1(3) 2_665 2_665 ?
N1 O9 Dy1 93.77(15) . . ?
N1 O9 Tb2 95.7(2) . . ?
N1 O10 Dy1 98.20(16) . . ?
N1 O10 Tb2 97.3(2) . . ?
N2 O12 Tb2 97.5(2) . . ?
N2 O12 Dy1 96.24(15) . . ?
N2 O13 Dy1 94.74(16) . . ?
N2 O13 Tb2 93.9(2) . . ?
N3 O15 Dy2 93.63(16) . . ?
N3 O15 Tb1 92.1(2) . . ?
N3 O16 Tb1 99.4(3) . . ?
N3 O16 Dy2 98.32(16) . . ?
C25 O18 Tb1 133.3(3) . . ?
C25 O18 Dy2 133.03(19) . . ?
C25 O18 H18O 107.4 . . ?
Tb1 O18 H18O 115.1 . . ?
Dy2 O18 H18O 115.0 . . ?
O11 N1 O10 121.8(3) . . ?
O11 N1 O9 122.2(3) . . ?
O10 N1 O9 116.0(2) . . ?
O11 N1 Dy1 172.2(2) . . ?
O10 N1 Dy1 56.12(13) . . ?
O9 N1 Dy1 60.33(13) . . ?
O14 N2 O13 122.2(2) . . ?
O14 N2 O12 121.2(2) . . ?
O13 N2 O12 116.6(2) . . ?
O14 N2 Dy1 175.5(2) . . ?
O13 N2 Dy1 59.32(14) . . ?
O12 N2 Dy1 57.51(13) . . ?
O14 N2 Tb2 176.4(2) . . ?
O13 N2 Tb2 60.3(2) . . ?
O12 N2 Tb2 56.4(2) . . ?
O17 N3 O15 123.1(2) . . ?
O17 N3 O16 120.6(2) . . ?
O15 N3 O16 116.3(2) . . ?
O17 N3 Tb1 173.2(2) . . ?
O15 N3 Tb1 62.0(2) . . ?
O16 N3 Tb1 54.5(2) . . ?
O17 N3 Dy2 174.42(19) . . ?
O15 N3 Dy2 60.71(14) . . ?
O16 N3 Dy2 55.71(13) . . ?
C27 N4 Dy2 167.6(2) . . ?
C27 N4 Tb1 169.1(3) . . ?
C6 C1 C2 117.7(2) . . ?
C6 C1 Si1 120.81(19) . . ?
C2 C1 Si1 121.36(19) . . ?
C3 C2 C1 120.9(2) . . ?
C3 C2 H2 119.6 . . ?
C1 C2 H2 119.6 . . ?
C4 C3 C2 120.3(3) . . ?
C4 C3 H3 119.8 . . ?
C2 C3 H3 119.8 . . ?
C3 C4 C5 119.8(2) . . ?
C3 C4 H4 120.1 . . ?
C5 C4 H4 120.1 . . ?
C4 C5 C6 120.2(3) . . ?
C4 C5 H5 119.9 . . ?
C6 C5 H5 119.9 . . ?
C5 C6 C1 121.0(3) . . ?
C5 C6 H6 119.5 . . ?
C1 C6 H6 119.5 . . ?
C12 C7 C8 118.0(2) . . ?
C12 C7 Si2 121.58(19) . . ?
C8 C7 Si2 120.4(2) . . ?
C9 C8 C7 121.0(3) . . ?
C9 C8 H8 119.5 . . ?
C7 C8 H8 119.5 . . ?
C10 C9 C8 120.0(3) . . ?
C10 C9 H9 120.0 . . ?
C8 C9 H9 120.0 . . ?
C11 C10 C9 120.0(3) . . ?
C11 C10 H10 120.0 . . ?
C9 C10 H10 120.0 . . ?
C10 C11 C12 119.9(3) . . ?
C10 C11 H11 120.1 . . ?
C12 C11 H11 120.1 . . ?
C11 C12 C7 121.1(2) . . ?
C11 C12 H12 119.4 . . ?
C7 C12 H12 119.4 . . ?
C18 C13 C14 117.6(2) . . ?
C18 C13 Si3 121.9(2) . . ?
C14 C13 Si3 120.53(19) . . ?
C15 C14 C13 120.9(3) . . ?
C15 C14 H14 119.5 . . ?
C13 C14 H14 119.5 . . ?
C16 C15 C14 120.4(3) . . ?
C16 C15 H15 119.8 . . ?
C14 C15 H15 119.8 . . ?
C15 C16 C17 119.6(3) . . ?
C15 C16 H16 120.2 . . ?
C17 C16 H16 120.2 . . ?
C16 C17 C18 120.1(3) . . ?
C16 C17 H17 119.9 . . ?
C18 C17 H17 119.9 . . ?
C17 C18 C13 121.3(3) . . ?
C17 C18 H18 119.3 . . ?
C13 C18 H18 119.3 . . ?
C24 C19 C20 118.0(2) . . ?
C24 C19 Si4 120.57(19) . . ?
C20 C19 Si4 121.46(19) . . ?
C21 C20 C19 121.3(3) . . ?
C21 C20 H20 119.3 . . ?
C19 C20 H20 119.3 . . ?
C20 C21 C22 119.8(3) . . ?
C20 C21 H21 120.1 . . ?
C22 C21 H21 120.1 . . ?
C23 C22 C21 119.8(3) . . ?
C23 C22 H22 120.1 . . ?
C21 C22 H22 120.1 . . ?
C22 C23 C24 120.4(3) . . ?
C22 C23 H23 119.8 . . ?
C24 C23 H23 119.8 . . ?
C23 C24 C19 120.7(2) . . ?
C23 C24 H24 119.6 . . ?
C19 C24 H24 119.6 . . ?
O18 C25 C26 112.1(3) . . ?
O18 C25 H25A 109.2 . . ?
C26 C25 H25A 109.2 . . ?
O18 C25 H25B 109.2 . . ?
C26 C25 H25B 109.2 . . ?
H25A C25 H25B 107.9 . . ?
C25 C26 H26A 109.5 . . ?
C25 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
C25 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
N4 C27 C28 178.4(3) . . ?
C27 C28 H28A 109.5 . . ?
C27 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
C27 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
C31' N5 C29' 139.9(6) . . ?
C35 N5 C29 141.8(5) . . ?
C35 N5 C31 113.8(5) . . ?
C29 N5 C31 87.5(5) . . ?
C31' N5 C33' 112.6(4) . . ?
C29' N5 C33' 95.9(4) . . ?
C31' N5 C35' 108.4(4) . . ?
C29' N5 C35' 90.1(5) . . ?
C33' N5 C35' 104.3(3) . . ?
C35 N5 C33 105.7(4) . . ?
C29 N5 C33 98.4(4) . . ?
C31 N5 C33 104.5(5) . . ?
N5 C29 C30 114.6(6) . . ?
N5 C29 H29A 108.6 . . ?
C30 C29 H29A 108.6 . . ?
N5 C29 H29B 108.6 . . ?
C30 C29 H29B 108.6 . . ?
H29A C29 H29B 107.6 . . ?
C29 C30 H30A 109.5 . . ?
C29 C30 H30B 109.5 . . ?
H30A C30 H30B 109.5 . . ?
C29 C30 H30C 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
C32 C31 N5 115.6(8) . . ?
C32 C31 H31A 108.4 . . ?
N5 C31 H31A 108.4 . . ?
C32 C31 H31B 108.4 . . ?
N5 C31 H31B 108.4 . . ?
H31A C31 H31B 107.4 . . ?
C31 C32 H32A 109.5 . . ?
C31 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
C31 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
C34 C33 N5 113.3(13) . . ?
C34 C33 H33A 108.9 . . ?
N5 C33 H33A 108.9 . . ?
C34 C33 H33B 108.9 . . ?
N5 C33 H33B 108.9 . . ?
H33A C33 H33B 107.7 . . ?
C33 C34 H34A 109.5 . . ?
C33 C34 H34B 109.5 . . ?
H34A C34 H34B 109.5 . . ?
C33 C34 H34C 109.5 . . ?
H34A C34 H34C 109.5 . . ?
H34B C34 H34C 109.5 . . ?
N5 C35 C36 112.2(6) . . ?
N5 C35 H35A 109.2 . . ?
C36 C35 H35A 109.2 . . ?
N5 C35 H35B 109.2 . . ?
C36 C35 H35B 109.2 . . ?
H35A C35 H35B 107.9 . . ?
C35 C36 H36A 109.5 . . ?
C35 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
C35 C36 H36C 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
N5 C29' C30' 119.5(10) . . ?
N5 C29' H29C 107.4 . . ?
C30' C29' H29C 107.4 . . ?
N5 C29' H29D 107.4 . . ?
C30' C29' H29D 107.4 . . ?
H29C C29' H29D 107.0 . . ?
C29' C30' H30D 109.5 . . ?
C29' C30' H30E 109.5 . . ?
H30D C30' H30E 109.5 . . ?
C29' C30' H30F 109.5 . . ?
H30D C30' H30F 109.5 . . ?
H30E C30' H30F 109.5 . . ?
N5 C31' C32' 115.6(6) . . ?
N5 C31' H31C 108.4 . . ?
C32' C31' H31C 108.4 . . ?
N5 C31' H31D 108.4 . . ?
C32' C31' H31D 108.4 . . ?
H31C C31' H31D 107.4 . . ?
C31' C32' H32D 109.5 . . ?
C31' C32' H32E 109.5 . . ?
H32D C32' H32E 109.5 . . ?
C31' C32' H32F 109.5 . . ?
H32D C32' H32F 109.5 . . ?
H32E C32' H32F 109.5 . . ?
C34' C33' N5 111.6(13) . . ?
C34' C33' H33C 109.3 . . ?
N5 C33' H33C 109.3 . . ?
C34' C33' H33D 109.3 . . ?
N5 C33' H33D 109.3 . . ?
H33C C33' H33D 108.0 . . ?
C33' C34' H34D 109.5 . . ?
C33' C34' H34E 109.5 . . ?
H34D C34' H34E 109.5 . . ?
C33' C34' H34F 109.5 . . ?
H34D C34' H34F 109.5 . . ?
H34E C34' H34F 109.5 . . ?
C36' C35' N5 114.8(5) . . ?
C36' C35' H35C 108.6 . . ?
N5 C35' H35C 108.6 . . ?
C36' C35' H35D 108.6 . . ?
N5 C35' H35D 108.6 . . ?
H35C C35' H35D 107.5 . . ?
C35' C36' H36D 109.5 . . ?
C35' C36' H36E 109.5 . . ?
H36D C36' H36E 109.5 . . ?
C35' C36' H36F 109.5 . . ?
H36D C36' H36F 109.5 . . ?
H36E C36' H36F 109.5 . . ?
N6 C37 C38 178.9(5) . . ?
C37 C38 H38A 109.5 . . ?
C37 C38 H38B 109.5 . . ?
H38A C38 H38B 109.5 . . ?
C37 C38 H38C 109.5 . . ?
H38A C38 H38C 109.5 . . ?
H38B C38 H38C 109.5 . . ?
N7 C39 C40 178.0(16) . . ?
C39 C40 H40A 109.5 . . ?
C39 C40 H40B 109.5 . . ?
H40A C40 H40B 109.5 . . ?
C39 C40 H40C 109.5 . . ?
H40A C40 H40C 109.5 . . ?
H40B C40 H40C 109.5 . . ?
N7' C39' C40' 178.7(16) . . ?
C39' C40' H40D 109.5 . . ?
C39' C40' H40E 109.5 . . ?
H40D C40' H40E 109.5 . . ?
C39' C40' H40F 109.5 . . ?
H40D C40' H40F 109.5 . . ?
H40E C40' H40F 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O5 Si1 O1 Si2 -47.77(17) . . . . ?
O4 Si1 O1 Si2 72.23(16) . . . . ?
C1 Si1 O1 Si2 -171.13(14) . . . . ?
O6 Si2 O1 Si1 47.88(17) . . . . ?
O2 Si2 O1 Si1 -71.38(16) . . . . ?
C7 Si2 O1 Si1 173.39(14) . . . . ?
O7 Si3 O2 Si2 29.05(18) . . . . ?
O3 Si3 O2 Si2 -89.90(17) . . . . ?
C13 Si3 O2 Si2 152.60(15) . . . . ?
O6 Si2 O2 Si3 -30.28(18) . . . . ?
O1 Si2 O2 Si3 88.49(17) . . . . ?
C7 Si2 O2 Si3 -156.73(15) . . . . ?
O7 Si3 O3 Si4 -45.66(17) . . . . ?
O2 Si3 O3 Si4 73.30(16) . . . . ?
C13 Si3 O3 Si4 -169.66(14) . . . . ?
O8 Si4 O3 Si3 47.86(17) . . . . ?
O4 Si4 O3 Si3 -71.88(16) . . . . ?
C19 Si4 O3 Si3 170.79(14) . . . . ?
O8 Si4 O4 Si1 -25.90(19) . . . . ?
O3 Si4 O4 Si1 93.35(17) . . . . ?
C19 Si4 O4 Si1 -149.42(16) . . . . ?
O5 Si1 O4 Si4 24.07(19) . . . . ?
O1 Si1 O4 Si4 -94.48(17) . . . . ?
C1 Si1 O4 Si4 146.75(16) . . . . ?
O4 Si1 O5 Tb2 -135.5(3) . . . . ?
O1 Si1 O5 Tb2 -17.2(3) . . . . ?
C1 Si1 O5 Tb2 105.0(3) . . . . ?
O4 Si1 O5 Dy1 -136.50(13) . . . . ?
O1 Si1 O5 Dy1 -18.24(16) . . . . ?
C1 Si1 O5 Dy1 103.93(15) . . . . ?
O4 Si1 O5 Dy2 29.24(17) . . . 2_665 ?
O1 Si1 O5 Dy2 147.49(13) . . . 2_665 ?
C1 Si1 O5 Dy2 -90.33(16) . . . 2_665 ?
O4 Si1 O5 Tb1 31.1(3) . . . 2_665 ?
O1 Si1 O5 Tb1 149.3(3) . . . 2_665 ?
C1 Si1 O5 Tb1 -88.5(3) . . . 2_665 ?
O2 Si2 O6 Tb2 136.4(3) . . . . ?
O1 Si2 O6 Tb2 16.7(3) . . . . ?
C7 Si2 O6 Tb2 -102.7(3) . . . . ?
O2 Si2 O6 Dy2 -26.39(17) . . . . ?
O1 Si2 O6 Dy2 -146.01(14) . . . . ?
C7 Si2 O6 Dy2 94.56(17) . . . . ?
O2 Si2 O6 Dy1 137.60(13) . . . . ?
O1 Si2 O6 Dy1 17.97(16) . . . . ?
C7 Si2 O6 Dy1 -101.45(15) . . . . ?
O2 Si2 O6 Tb1 -26.5(3) . . . . ?
O1 Si2 O6 Tb1 -146.1(3) . . . . ?
C7 Si2 O6 Tb1 94.4(3) . . . . ?
O2 Si3 O7 Tb1 30.3(3) . . . . ?
O3 Si3 O7 Tb1 149.8(3) . . . . ?
C13 Si3 O7 Tb1 -89.5(3) . . . . ?
O2 Si3 O7 Dy1 -139.62(13) . . . 2_665 ?
O3 Si3 O7 Dy1 -20.13(15) . . . 2_665 ?
C13 Si3 O7 Dy1 100.58(15) . . . 2_665 ?
O2 Si3 O7 Dy2 28.44(17) . . . . ?
O3 Si3 O7 Dy2 147.94(14) . . . . ?
C13 Si3 O7 Dy2 -91.36(16) . . . . ?
O2 Si3 O7 Tb2 -138.7(3) . . . 2_665 ?
O3 Si3 O7 Tb2 -19.2(3) . . . 2_665 ?
C13 Si3 O7 Tb2 101.5(3) . . . 2_665 ?
O4 Si4 O8 Dy1 134.49(13) . . . 2_665 ?
O3 Si4 O8 Dy1 16.49(16) . . . 2_665 ?
C19 Si4 O8 Dy1 -104.15(14) . . . 2_665 ?
O4 Si4 O8 Dy2 -26.38(18) . . . 2_665 ?
O3 Si4 O8 Dy2 -144.38(14) . . . 2_665 ?
C19 Si4 O8 Dy2 94.99(16) . . . 2_665 ?
O4 Si4 O8 Tb2 133.2(3) . . . 2_665 ?
O3 Si4 O8 Tb2 15.2(3) . . . 2_665 ?
C19 Si4 O8 Tb2 -105.4(3) . . . 2_665 ?
O4 Si4 O8 Tb1 -26.5(3) . . . 2_665 ?
O3 Si4 O8 Tb1 -144.5(3) . . . 2_665 ?
C19 Si4 O8 Tb1 94.8(3) . . . 2_665 ?
Dy1 O10 N1 O11 171.1(3) . . . . ?
Tb2 O10 N1 O11 170.6(3) . . . . ?
Dy1 O10 N1 O9 -7.7(3) . . . . ?
Tb2 O10 N1 O9 -8.2(3) . . . . ?
Tb2 O10 N1 Dy1 -0.5(2) . . . . ?
Dy1 O9 N1 O11 -171.4(3) . . . . ?
Tb2 O9 N1 O11 -170.7(3) . . . . ?
Dy1 O9 N1 O10 7.3(2) . . . . ?
Tb2 O9 N1 O10 8.0(3) . . . . ?
Tb2 O9 N1 Dy1 0.7(2) . . . . ?
Dy1 O13 N2 O14 -175.1(2) . . . . ?
Tb2 O13 N2 O14 -177.0(3) . . . . ?
Dy1 O13 N2 O12 5.2(2) . . . . ?
Tb2 O13 N2 O12 3.3(3) . . . . ?
Tb2 O13 N2 Dy1 -1.9(2) . . . . ?
Dy1 O13 N2 Tb2 1.9(2) . . . . ?
Tb2 O12 N2 O14 176.8(3) . . . . ?
Dy1 O12 N2 O14 175.0(2) . . . . ?
Tb2 O12 N2 O13 -3.4(3) . . . . ?
Dy1 O12 N2 O13 -5.3(2) . . . . ?
Tb2 O12 N2 Dy1 1.9(2) . . . . ?
Dy1 O12 N2 Tb2 -1.9(2) . . . . ?
Dy2 O15 N3 O17 175.2(2) . . . . ?
Tb1 O15 N3 O17 174.8(3) . . . . ?
Dy2 O15 N3 O16 -3.7(2) . . . . ?
Tb1 O15 N3 O16 -4.2(3) . . . . ?
Dy2 O15 N3 Tb1 0.4(3) . . . . ?
Tb1 O15 N3 Dy2 -0.4(3) . . . . ?
Tb1 O16 N3 O17 -174.5(3) . . . . ?
Dy2 O16 N3 O17 -175.1(2) . . . . ?
Tb1 O16 N3 O15 4.5(4) . . . . ?
Dy2 O16 N3 O15 3.9(2) . . . . ?
Dy2 O16 N3 Tb1 -0.6(4) . . . . ?
Tb1 O16 N3 Dy2 0.6(4) . . . . ?
O5 Si1 C1 C6 133.7(2) . . . . ?
O4 Si1 C1 C6 12.0(3) . . . . ?
O1 Si1 C1 C6 -105.2(2) . . . . ?
O5 Si1 C1 C2 -41.4(3) . . . . ?
O4 Si1 C1 C2 -163.1(2) . . . . ?
O1 Si1 C1 C2 79.7(2) . . . . ?
C6 C1 C2 C3 0.1(4) . . . . ?
Si1 C1 C2 C3 175.4(2) . . . . ?
C1 C2 C3 C4 0.2(5) . . . . ?
C2 C3 C4 C5 -0.1(5) . . . . ?
C3 C4 C5 C6 -0.3(5) . . . . ?
C4 C5 C6 C1 0.7(5) . . . . ?
C2 C1 C6 C5 -0.6(4) . . . . ?
Si1 C1 C6 C5 -175.9(2) . . . . ?
O6 Si2 C7 C12 -98.6(2) . . . . ?
O2 Si2 C7 C12 23.6(2) . . . . ?
O1 Si2 C7 C12 140.8(2) . . . . ?
O6 Si2 C7 C8 82.9(2) . . . . ?
O2 Si2 C7 C8 -154.9(2) . . . . ?
O1 Si2 C7 C8 -37.7(3) . . . . ?
C12 C7 C8 C9 1.3(5) . . . . ?
Si2 C7 C8 C9 179.9(3) . . . . ?
C7 C8 C9 C10 -0.4(5) . . . . ?
C8 C9 C10 C11 -1.1(5) . . . . ?
C9 C10 C11 C12 1.6(5) . . . . ?
C10 C11 C12 C7 -0.6(5) . . . . ?
C8 C7 C12 C11 -0.8(4) . . . . ?
Si2 C7 C12 C11 -179.4(2) . . . . ?
O7 Si3 C13 C18 -99.8(2) . . . . ?
O2 Si3 C13 C18 139.7(2) . . . . ?
O3 Si3 C13 C18 21.2(3) . . . . ?
O7 Si3 C13 C14 79.0(2) . . . . ?
O2 Si3 C13 C14 -41.5(2) . . . . ?
O3 Si3 C13 C14 -159.9(2) . . . . ?
C18 C13 C14 C15 -0.5(4) . . . . ?
Si3 C13 C14 C15 -179.4(2) . . . . ?
C13 C14 C15 C16 0.8(5) . . . . ?
C14 C15 C16 C17 -0.2(5) . . . . ?
C15 C16 C17 C18 -0.5(6) . . . . ?
C16 C17 C18 C13 0.8(6) . . . . ?
C14 C13 C18 C17 -0.2(5) . . . . ?
Si3 C13 C18 C17 178.6(3) . . . . ?
O8 Si4 C19 C24 6.4(2) . . . . ?
O4 Si4 C19 C24 128.7(2) . . . . ?
O3 Si4 C19 C24 -114.8(2) . . . . ?
O8 Si4 C19 C20 -174.24(19) . . . . ?
O4 Si4 C19 C20 -52.0(2) . . . . ?
O3 Si4 C19 C20 64.6(2) . . . . ?
C24 C19 C20 C21 0.8(4) . . . . ?
Si4 C19 C20 C21 -178.6(2) . . . . ?
C19 C20 C21 C22 -0.2(4) . . . . ?
C20 C21 C22 C23 -0.3(4) . . . . ?
C21 C22 C23 C24 0.3(4) . . . . ?
C22 C23 C24 C19 0.2(4) . . . . ?
C20 C19 C24 C23 -0.7(4) . . . . ?
Si4 C19 C24 C23 178.7(2) . . . . ?
Tb1 O18 C25 C26 169.1(4) . . . . ?
Dy2 O18 C25 C26 170.2(2) . . . . ?
C35 N5 C29 C30 19.5(11) . . . . ?
C31 N5 C29 C30 146.3(7) . . . . ?
C33 N5 C29 C30 -109.5(6) . . . . ?
C35 N5 C31 C32 -44.1(10) . . . . ?
C29 N5 C31 C32 168.7(9) . . . . ?
C33 N5 C31 C32 70.6(9) . . . . ?
C35 N5 C33 C34 -71.6(14) . . . . ?
C29 N5 C33 C34 78.5(14) . . . . ?
C31 N5 C33 C34 168.1(14) . . . . ?
C29 N5 C35 C36 58.9(10) . . . . ?
C31 N5 C35 C36 -60.1(8) . . . . ?
C33 N5 C35 C36 -174.1(6) . . . . ?
C31' N5 C29' C30' -20.9(11) . . . . ?
C33' N5 C29' C30' 115.3(7) . . . . ?
C35' N5 C29' C30' -140.3(7) . . . . ?
C29' N5 C31' C32' -59.0(12) . . . . ?
C33' N5 C31' C32' 169.2(7) . . . . ?
C35' N5 C31' C32' 54.4(8) . . . . ?
C31' N5 C33' C34' 72.1(16) . . . . ?
C29' N5 C33' C34' -79.0(16) . . . . ?
C35' N5 C33' C34' -170.6(15) . . . . ?
C31' N5 C35' C36' 54.5(6) . . . . ?
C29' N5 C35' C36' -161.7(6) . . . . ?
C33' N5 C35' C36' -65.6(6) . . . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O18 H18O O9 0.90 1.98 2.847(3) 161 2_665

_refine_diff_density_max         2.749
_refine_diff_density_min         -2.495
_refine_diff_density_rms         0.171

_shelxl_version_number           2013-4

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_3
_database_code_depnum_ccdc_archive 'CCDC 2240604'
loop_
_audit_author_name
_audit_author_address
'Victor Khrustalev'
;Peoples Friendship University of Russia (RUDN University, Moscow)
Russia
;
_audit_update_record             
;
2023-02-08 deposited with the CCDC.	2023-08-29 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2013
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C56 H58 Eu N8 O36 Si8 Tb Y2, 2(C8 H20 N)'
_chemical_formula_sum            'C72 H98 Eu N10 O36 Si8 Tb Y2'
_chemical_formula_weight         2393.05

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Y Y -2.7962 3.5667 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Tb Tb -0.1723 4.1537 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   12.8840(2)
_cell_length_b                   13.9471(2)
_cell_length_c                   15.3005(2)
_cell_angle_alpha                67.2399(15)
_cell_angle_beta                 82.6403(13)
_cell_angle_gamma                86.2713(13)
_cell_volume                     2514.08(7)
_cell_formula_units_Z            1
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    26876
_cell_measurement_theta_min      2.2
_cell_measurement_theta_max      34.3

_exptl_crystal_description       prism
_exptl_crystal_colour            colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.581
_exptl_crystal_F_000             1206
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.09
_exptl_crystal_size_mid          0.09
_exptl_crystal_size_min          0.06
_exptl_absorpt_coefficient_mu    2.631
_shelx_estimated_absorpt_T_min   0.798
_shelx_estimated_absorpt_T_max   0.858
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.752
_exptl_absorpt_correction_T_max  0.844
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.41.117a (Rigaku Oxford Diffraction, 2021)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_measurement_device_type  'XtaLAB Synergy, Dualflex, HyPix'
_diffrn_measurement_method       'φ and ω'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            66219
_diffrn_reflns_av_unetI/netI     0.1300
_diffrn_reflns_av_R_equivalents  0.1160
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_theta_min         2.190
_diffrn_reflns_theta_max         35.386
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.885
_diffrn_measured_fraction_theta_full 0.992
_diffrn_reflns_Laue_measured_fraction_max 0.885
_diffrn_reflns_Laue_measured_fraction_full 0.992
_diffrn_reflns_point_group_measured_fraction_max 0.885
_diffrn_reflns_point_group_measured_fraction_full 0.992
_reflns_number_total             20143
_reflns_number_gt                12723
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'CrysAlisPro 1.171.41.117a (Rigaku OD, 2021)'
_computing_cell_refinement       'CrysAlisPro 1.171.41.117a (Rigaku OD, 2021)'
_computing_data_reduction        'CrysAlisPro 1.171.41.117a (Rigaku OD, 2021)'
_computing_structure_solution    'SHELXT (Sheldrick, 2015)'
_computing_structure_refinement  'SHELXL (Sheldrick, 2015)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2015)'
_computing_publication_material  'SHELXTL (Sheldrick, 2015)'

_refine_special_details          SQUEEZE
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.01P)²+15P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     difmap
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         20143
_refine_ls_number_parameters     544
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1274
_refine_ls_R_factor_gt           0.0883
_refine_ls_wR_factor_ref         0.2038
_refine_ls_wR_factor_gt          0.1886
_refine_ls_goodness_of_fit_ref   1.030
_refine_ls_restrained_S_all      1.030
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Tb1 Tb 0.48276(8) 0.38058(6) 0.17734(7) 0.0239(3) Uani 0.5 1 d . . P A 1
Y1 Y 0.4824(3) 0.3808(3) 0.1764(2) 0.0598(12) Uani 0.5 1 d . . P A 2
Eu1 Eu 0.29259(12) 0.49235(9) 0.00022(10) 0.0232(3) Uani 0.5 1 d . . P A 1
Y2 Y 0.2974(3) 0.4934(3) 0.0003(2) 0.0449(12) Uani 0.5 1 d . . P A 2
Si1 Si 0.57483(13) 0.61884(12) 0.15725(11) 0.0332(3) Uani 1 1 d . . . . .
Si2 Si 0.34520(13) 0.61121(12) 0.15731(11) 0.0337(3) Uani 1 1 d . . . . .
Si3 Si 0.36664(12) 0.75241(11) -0.05061(11) 0.0330(3) Uani 1 1 d . . . . .
Si4 Si 0.59728(12) 0.75887(11) -0.05048(11) 0.0317(3) Uani 1 1 d . . . . .
O1 O 0.4529(3) 0.6235(4) 0.1989(3) 0.0422(10) Uani 1 1 d . . . . .
O2 O 0.3315(3) 0.7165(3) 0.0639(3) 0.0395(9) Uani 1 1 d . . . . .
O3 O 0.4806(3) 0.8086(3) -0.0739(3) 0.0357(8) Uani 1 1 d . . . . .
O4 O 0.6034(3) 0.7248(3) 0.0631(3) 0.0344(8) Uani 1 1 d . . . . .
O5 O 0.5920(3) 0.5193(3) 0.1265(3) 0.0360(8) Uani 1 1 d . . . . .
O6 O 0.3557(3) 0.5106(3) 0.1290(3) 0.0324(8) Uani 1 1 d . . . . .
O7 O 0.3762(3) 0.6534(3) -0.0794(3) 0.0307(7) Uani 1 1 d . . . . .
O8 O 0.6145(3) 0.6602(3) -0.0804(3) 0.0325(8) Uani 1 1 d . . . . .
O9 O 0.4260(4) 0.3862(5) 0.3354(3) 0.0587(14) Uani 1 1 d . . . . .
O10 O 0.3272(4) 0.2986(4) 0.2909(3) 0.0507(11) Uani 1 1 d . . . . .
O11 O 0.2912(6) 0.3073(7) 0.4310(4) 0.092(2) Uani 1 1 d . . . . .
O12 O 0.6294(4) 0.3194(5) 0.2818(3) 0.0580(13) Uani 1 1 d . . . . .
O13 O 0.5314(5) 0.2019(4) 0.2779(4) 0.0605(14) Uani 1 1 d . . . . .
O14 O 0.6596(6) 0.1549(6) 0.3665(5) 0.094(2) Uani 1 1 d . . . . .
O15 O 0.1761(4) 0.3636(4) -0.0064(4) 0.0577(13) Uani 1 1 d . . . . .
O16 O 0.1601(4) 0.3876(4) 0.1278(4) 0.0526(12) Uani 1 1 d . . . . .
O17 O 0.0556(5) 0.2779(5) 0.1083(5) 0.0774(19) Uani 1 1 d . . . . .
O18 O 0.2044(4) 0.5694(4) -0.1440(4) 0.0530(12) Uani 1 1 d . . . . .
H18O H 0.2570 0.5830 -0.1917 0.079 Uiso 1 1 d R U . A .
N1 N 0.3467(5) 0.3291(6) 0.3547(4) 0.0627(19) Uani 1 1 d . . . . .
N2 N 0.6073(6) 0.2235(6) 0.3103(4) 0.0658(19) Uani 1 1 d . . . . .
N3 N 0.1261(5) 0.3400(5) 0.0789(5) 0.0558(15) Uani 1 1 d . . . . .
N4 N 0.1464(5) 0.6042(4) 0.0317(4) 0.0479(13) Uani 1 1 d . . . . .
C1 C 0.6543(5) 0.6165(5) 0.2506(4) 0.0413(13) Uani 1 1 d . . . . .
C2 C 0.6211(7) 0.5617(6) 0.3473(5) 0.0563(19) Uani 1 1 d . . . . .
H2 H 0.5576 0.5244 0.3654 0.068 Uiso 1 1 calc R U . . .
C3 C 0.6810(8) 0.5617(7) 0.4177(5) 0.063(2) Uani 1 1 d . . . . .
H3 H 0.6583 0.5236 0.4831 0.075 Uiso 1 1 calc R U . . .
C4 C 0.7724(7) 0.6166(8) 0.3928(6) 0.063(2) Uani 1 1 d . . . . .
H4 H 0.8124 0.6170 0.4407 0.075 Uiso 1 1 calc R U . . .
C5 C 0.8053(6) 0.6708(7) 0.2981(6) 0.059(2) Uani 1 1 d . . . . .
H5 H 0.8688 0.7080 0.2807 0.071 Uiso 1 1 calc R U . . .
C6 C 0.7466(5) 0.6719(6) 0.2274(5) 0.0467(15) Uani 1 1 d . . . . .
H6 H 0.7699 0.7111 0.1624 0.056 Uiso 1 1 calc R U . . .
C7 C 0.2343(4) 0.6051(5) 0.2497(4) 0.0380(12) Uani 1 1 d . . . . .
C8 C 0.1645(7) 0.5225(7) 0.2874(6) 0.064(2) Uani 1 1 d . . . . .
H8 H 0.1727 0.4675 0.2650 0.077 Uiso 1 1 calc R U . . .
C9 C 0.0833(8) 0.5201(8) 0.3571(6) 0.071(3) Uani 1 1 d . . . . .
H9 H 0.0368 0.4633 0.3827 0.085 Uiso 1 1 calc R U . . .
C10 C 0.0701(6) 0.6004(7) 0.3892(5) 0.0566(19) Uani 1 1 d . . . . .
H10 H 0.0140 0.5994 0.4364 0.068 Uiso 1 1 calc R U . . .
C11 C 0.1377(7) 0.6808(7) 0.3533(6) 0.062(2) Uani 1 1 d . . . . .
H11 H 0.1300 0.7353 0.3765 0.074 Uiso 1 1 calc R U . . .
C12 C 0.2175(6) 0.6835(6) 0.2831(6) 0.0563(18) Uani 1 1 d . . . . .
H12 H 0.2624 0.7416 0.2571 0.068 Uiso 1 1 calc R U . . .
C13 C 0.2676(7) 0.8524(6) -0.1094(9) 0.0807(13) Uani 1 1 d . . . . .
C14 C 0.2580(7) 0.9427(6) -0.0909(9) 0.0807(13) Uani 1 1 d . . . . .
H14 H 0.3055 0.9546 -0.0536 0.097 Uiso 1 1 calc R U . . .
C15 C 0.1807(7) 1.0146(6) -0.1259(9) 0.0807(13) Uani 1 1 d . . . . .
H15 H 0.1750 1.0757 -0.1122 0.097 Uiso 1 1 calc R U . . .
C16 C 0.1123(7) 1.0001(6) -0.1796(9) 0.0807(13) Uani 1 1 d . . . . .
H16 H 0.0602 1.0515 -0.2047 0.097 Uiso 1 1 calc R U . . .
C17 C 0.1183(7) 0.9130(6) -0.1973(9) 0.0807(13) Uani 1 1 d . . . . .
H17 H 0.0684 0.9012 -0.2325 0.097 Uiso 1 1 calc R U . . .
C18 C 0.1976(7) 0.8393(6) -0.1642(9) 0.0807(13) Uani 1 1 d . . . . .
H18 H 0.2032 0.7794 -0.1798 0.097 Uiso 1 1 calc R U . . .
C19 C 0.6937(5) 0.8624(5) -0.1147(5) 0.0442(14) Uani 1 1 d . . . . .
C20 C 0.7038(8) 0.9415(6) -0.0811(7) 0.069(2) Uani 1 1 d . . . . .
H20 H 0.6642 0.9397 -0.0237 0.083 Uiso 1 1 calc R U . . .
C21 C 0.7725(10) 1.0232(8) -0.1328(9) 0.099(4) Uani 1 1 d . . . . .
H21 H 0.7785 1.0768 -0.1100 0.119 Uiso 1 1 calc R U . . .
C22 C 0.8308(8) 1.0274(7) -0.2146(9) 0.086(3) Uani 1 1 d . . . . .
H22 H 0.8765 1.0837 -0.2492 0.103 Uiso 1 1 calc R U . . .
C23 C 0.8229(7) 0.9497(6) -0.2463(8) 0.079(3) Uani 1 1 d . . . . .
H23 H 0.8642 0.9512 -0.3029 0.095 Uiso 1 1 calc R U . . .
C24 C 0.7549(6) 0.8680(5) -0.1964(6) 0.0532(17) Uani 1 1 d . . . . .
H24 H 0.7508 0.8145 -0.2198 0.064 Uiso 1 1 calc R U . . .
C25 C 0.1114(8) 0.5562(8) -0.1774(8) 0.075(3) Uani 1 1 d . . . . .
H25A H 0.0518 0.5558 -0.1295 0.090 Uiso 1 1 calc R U . . .
H25B H 0.1147 0.4874 -0.1825 0.090 Uiso 1 1 calc R U . . .
C26 C 0.0907(13) 0.6362(13) -0.2702(10) 0.131(6) Uani 1 1 d . . . . .
H26A H 0.0207 0.6267 -0.2839 0.196 Uiso 1 1 calc R U . . .
H26B H 0.1431 0.6300 -0.3202 0.196 Uiso 1 1 calc R U . . .
H26C H 0.0945 0.7053 -0.2682 0.196 Uiso 1 1 calc R U . . .
C27 C 0.0918(7) 0.6659(7) 0.0500(6) 0.061(2) Uani 1 1 d . . . . .
C28 C 0.0258(8) 0.7456(8) 0.0715(9) 0.080(3) Uani 1 1 d . . . . .
H28A H -0.0163 0.7822 0.0189 0.121 Uiso 1 1 calc R U . . .
H28B H 0.0703 0.7954 0.0795 0.121 Uiso 1 1 calc R U . . .
H28C H -0.0207 0.7125 0.1304 0.121 Uiso 1 1 calc R U . . .
N5 N 0.5114(5) 0.1243(4) 0.6452(4) 0.0519(14) Uani 1 1 d . . . . .
C29 C 0.6010(10) 0.1978(8) 0.6183(9) 0.0904(17) Uani 1 1 d . . . . .
H29A H 0.5956 0.2309 0.6655 0.108 Uiso 1 1 calc R U . . .
H29B H 0.6665 0.1556 0.6257 0.108 Uiso 1 1 calc R U . . .
C30 C 0.6120(12) 0.2784(9) 0.5259(9) 0.102(2) Uani 1 1 d . . . . .
H30A H 0.6473 0.3374 0.5282 0.153 Uiso 1 1 calc R U . . .
H30B H 0.5426 0.3008 0.5047 0.153 Uiso 1 1 calc R U . . .
H30C H 0.6536 0.2525 0.4811 0.153 Uiso 1 1 calc R U . . .
C31 C 0.5132(10) 0.0444(8) 0.7476(9) 0.0904(17) Uani 1 1 d . . . . .
H31A H 0.5832 0.0105 0.7559 0.108 Uiso 1 1 calc R U . . .
H31B H 0.4609 -0.0099 0.7612 0.108 Uiso 1 1 calc R U . . .
C32 C 0.4862(12) 0.1041(10) 0.8202(9) 0.102(2) Uani 1 1 d . . . . .
H32A H 0.4831 0.0534 0.8861 0.153 Uiso 1 1 calc R U . . .
H32B H 0.4184 0.1404 0.8093 0.153 Uiso 1 1 calc R U . . .
H32C H 0.5408 0.1547 0.8090 0.153 Uiso 1 1 calc R U . . .
C33 C 0.4067(10) 0.1763(8) 0.6273(9) 0.0904(17) Uani 1 1 d . . . . .
H33A H 0.4110 0.2262 0.5602 0.108 Uiso 1 1 calc R U . . .
H33B H 0.3910 0.2168 0.6683 0.108 Uiso 1 1 calc R U . . .
C34 C 0.3144(11) 0.1027(10) 0.6457(9) 0.102(2) Uani 1 1 d . . . . .
H34A H 0.2516 0.1439 0.6235 0.153 Uiso 1 1 calc R U . . .
H34B H 0.3011 0.0610 0.7142 0.153 Uiso 1 1 calc R U . . .
H34C H 0.3320 0.0565 0.6111 0.153 Uiso 1 1 calc R U . . .
C35 C 0.5324(10) 0.0549(8) 0.5840(9) 0.0904(17) Uani 1 1 d . . . . .
H35A H 0.4737 0.0061 0.6015 0.108 Uiso 1 1 calc R U . . .
H35B H 0.5310 0.1008 0.5160 0.108 Uiso 1 1 calc R U . . .
C36 C 0.6273(11) -0.0038(10) 0.5930(9) 0.102(2) Uani 1 1 d . . . . .
H36A H 0.6344 -0.0393 0.5484 0.153 Uiso 1 1 calc R U . . .
H36B H 0.6267 -0.0554 0.6584 0.153 Uiso 1 1 calc R U . . .
H36C H 0.6863 0.0428 0.5786 0.153 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Tb1 O5 2.289(4) . ?
Tb1 O8 2.306(4) 2_665 ?
Tb1 O6 2.325(4) . ?
Tb1 O7 2.347(4) 2_665 ?
Tb1 O13 2.459(5) . ?
Tb1 O9 2.464(5) . ?
Tb1 O10 2.492(5) . ?
Tb1 O12 2.522(5) . ?
Tb1 N1 2.897(6) . ?
Tb1 N2 2.906(7) . ?
Y1 O5 2.290(5) . ?
Y1 O8 2.293(5) 2_665 ?
Y1 O6 2.318(5) . ?
Y1 O7 2.343(5) 2_665 ?
Y1 O13 2.467(6) . ?
Y1 O9 2.475(6) . ?
Y1 O10 2.495(6) . ?
Y1 O12 2.534(6) . ?
Y1 N1 2.905(7) . ?
Y1 N2 2.916(8) . ?
Eu1 O6 2.331(4) . ?
Eu1 O5 2.339(4) 2_665 ?
Eu1 O8 2.343(4) 2_665 ?
Eu1 O7 2.356(4) . ?
Eu1 O18 2.442(5) . ?
Eu1 O15 2.453(5) . ?
Eu1 O16 2.474(5) . ?
Eu1 N4 2.486(6) . ?
Eu1 N3 2.918(6) . ?
Y2 O6 2.296(5) . ?
Y2 O5 2.313(5) 2_665 ?
Y2 O7 2.317(5) . ?
Y2 O8 2.321(5) 2_665 ?
Y2 O18 2.477(6) . ?
Y2 O15 2.506(6) . ?
Y2 O16 2.518(6) . ?
Y2 N4 2.520(7) . ?
Y2 N3 2.972(7) . ?
Si1 O1 1.625(4) . ?
Si1 O5 1.624(4) . ?
Si1 O4 1.638(4) . ?
Si1 C1 1.850(7) . ?
Si2 O6 1.614(4) . ?
Si2 O2 1.624(5) . ?
Si2 O1 1.644(5) . ?
Si2 C7 1.858(6) . ?
Si3 O7 1.598(4) . ?
Si3 O2 1.634(4) . ?
Si3 O3 1.642(4) . ?
Si3 C13 1.864(9) . ?
Si4 O8 1.604(4) . ?
Si4 O4 1.625(4) . ?
Si4 O3 1.637(4) . ?
Si4 C19 1.849(6) . ?
O9 N1 1.271(8) . ?
O10 N1 1.263(8) . ?
O11 N1 1.227(8) . ?
O12 N2 1.275(9) . ?
O13 N2 1.253(9) . ?
O14 N2 1.240(8) . ?
O15 N3 1.306(8) . ?
O16 N3 1.303(8) . ?
O17 N3 1.215(8) . ?
O18 C25 1.410(11) . ?
O18 H18O 0.9000 . ?
N4 C27 1.170(10) . ?
C1 C6 1.392(9) . ?
C1 C2 1.401(9) . ?
C2 C3 1.403(10) . ?
C2 H2 0.9500 . ?
C3 C4 1.376(13) . ?
C3 H3 0.9500 . ?
C4 C5 1.374(11) . ?
C4 H4 0.9500 . ?
C5 C6 1.391(9) . ?
C5 H5 0.9500 . ?
C6 H6 0.9500 . ?
C7 C12 1.369(9) . ?
C7 C8 1.399(9) . ?
C8 C9 1.388(10) . ?
C8 H8 0.9500 . ?
C9 C10 1.379(11) . ?
C9 H9 0.9500 . ?
C10 C11 1.358(11) . ?
C10 H10 0.9500 . ?
C11 C12 1.380(10) . ?
C11 H11 0.9500 . ?
C12 H12 0.9500 . ?
C13 C18 1.373(13) . ?
C13 C14 1.388(13) . ?
C14 C15 1.370(12) . ?
C14 H14 0.9500 . ?
C15 C16 1.354(13) . ?
C15 H15 0.9500 . ?
C16 C17 1.339(12) . ?
C16 H16 0.9500 . ?
C17 C18 1.396(12) . ?
C17 H17 0.9500 . ?
C18 H18 0.9500 . ?
C19 C24 1.367(10) . ?
C19 C20 1.404(11) . ?
C20 C21 1.400(11) . ?
C20 H20 0.9500 . ?
C21 C22 1.357(17) . ?
C21 H21 0.9500 . ?
C22 C23 1.361(15) . ?
C22 H22 0.9500 . ?
C23 C24 1.391(10) . ?
C23 H23 0.9500 . ?
C24 H24 0.9500 . ?
C25 C26 1.470(16) . ?
C25 H25A 0.9900 . ?
C25 H25B 0.9900 . ?
C26 H26A 0.9800 . ?
C26 H26B 0.9800 . ?
C26 H26C 0.9800 . ?
C27 C28 1.469(13) . ?
C28 H28A 0.9800 . ?
C28 H28B 0.9800 . ?
C28 H28C 0.9800 . ?
N5 C33 1.495(13) . ?
N5 C29 1.502(13) . ?
N5 C31 1.534(13) . ?
N5 C35 1.579(13) . ?
C29 C30 1.422(15) . ?
C29 H29A 0.9900 . ?
C29 H29B 0.9900 . ?
C30 H30A 0.9800 . ?
C30 H30B 0.9800 . ?
C30 H30C 0.9800 . ?
C31 C32 1.619(16) . ?
C31 H31A 0.9900 . ?
C31 H31B 0.9900 . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32 H32C 0.9800 . ?
C33 C34 1.548(16) . ?
C33 H33A 0.9900 . ?
C33 H33B 0.9900 . ?
C34 H34A 0.9800 . ?
C34 H34B 0.9800 . ?
C34 H34C 0.9800 . ?
C35 C36 1.418(16) . ?
C35 H35A 0.9900 . ?
C35 H35B 0.9900 . ?
C36 H36A 0.9800 . ?
C36 H36B 0.9800 . ?
C36 H36C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O5 Tb1 O8 124.68(14) . 2_665 ?
O5 Tb1 O6 82.76(14) . . ?
O8 Tb1 O6 72.84(14) 2_665 . ?
O5 Tb1 O7 73.10(14) . 2_665 ?
O8 Tb1 O7 82.76(14) 2_665 2_665 ?
O6 Tb1 O7 126.37(13) . 2_665 ?
O5 Tb1 O13 124.25(18) . . ?
O8 Tb1 O13 97.57(18) 2_665 . ?
O6 Tb1 O13 149.67(17) . . ?
O7 Tb1 O13 79.02(17) 2_665 . ?
O5 Tb1 O9 95.56(17) . . ?
O8 Tb1 O9 128.29(16) 2_665 . ?
O6 Tb1 O9 83.04(17) . . ?
O7 Tb1 O9 145.05(16) 2_665 . ?
O13 Tb1 O9 80.9(2) . . ?
O5 Tb1 O10 143.46(16) . . ?
O8 Tb1 O10 78.68(15) 2_665 . ?
O6 Tb1 O10 78.23(16) . . ?
O7 Tb1 O10 142.54(16) 2_665 . ?
O13 Tb1 O10 71.62(18) . . ?
O9 Tb1 O10 51.54(17) . . ?
O5 Tb1 O12 75.16(17) . . ?
O8 Tb1 O12 144.46(18) 2_665 . ?
O6 Tb1 O12 142.59(18) . . ?
O7 Tb1 O12 75.38(16) 2_665 . ?
O13 Tb1 O12 51.3(2) . . ?
O9 Tb1 O12 69.73(18) . . ?
O10 Tb1 O12 102.25(17) . . ?
O5 Tb1 N1 120.28(19) . . ?
O8 Tb1 N1 103.72(17) 2_665 . ?
O6 Tb1 N1 80.28(17) . . ?
O7 Tb1 N1 152.93(18) 2_665 . ?
O13 Tb1 N1 74.1(2) . . ?
O9 Tb1 N1 25.83(18) . . ?
O10 Tb1 N1 25.73(18) . . ?
O12 Tb1 N1 85.24(17) . . ?
O5 Tb1 N2 100.2(2) . . ?
O8 Tb1 N2 121.3(2) 2_665 . ?
O6 Tb1 N2 156.77(18) . . ?
O7 Tb1 N2 75.92(17) 2_665 . ?
O13 Tb1 N2 25.3(2) . . ?
O9 Tb1 N2 73.7(2) . . ?
O10 Tb1 N2 86.43(18) . . ?
O12 Tb1 N2 26.0(2) . . ?
N1 Tb1 N2 78.40(19) . . ?
O5 Y1 O8 125.20(19) . 2_665 ?
O5 Y1 O6 82.88(18) . . ?
O8 Y1 O6 73.19(17) 2_665 . ?
O5 Y1 O7 73.15(17) . 2_665 ?
O8 Y1 O7 83.11(16) 2_665 2_665 ?
O6 Y1 O7 126.89(19) . 2_665 ?
O5 Y1 O13 123.8(2) . . ?
O8 Y1 O13 97.7(2) 2_665 . ?
O6 Y1 O13 149.6(2) . . ?
O7 Y1 O13 78.94(19) 2_665 . ?
O5 Y1 O9 95.2(2) . . ?
O8 Y1 O9 128.3(2) 2_665 . ?
O6 Y1 O9 82.9(2) . . ?
O7 Y1 O9 144.5(2) 2_665 . ?
O13 Y1 O9 80.6(2) . . ?
O5 Y1 O10 143.1(2) . . ?
O8 Y1 O10 78.84(18) 2_665 . ?
O6 Y1 O10 78.30(19) . . ?
O7 Y1 O10 142.6(2) 2_665 . ?
O13 Y1 O10 71.4(2) . . ?
O9 Y1 O10 51.39(18) . . ?
O5 Y1 O12 74.9(2) . . ?
O8 Y1 O12 144.5(2) 2_665 . ?
O6 Y1 O12 142.2(2) . . ?
O7 Y1 O12 75.21(19) 2_665 . ?
O13 Y1 O12 51.0(2) . . ?
O9 Y1 O12 69.4(2) . . ?
O10 Y1 O12 101.8(2) . . ?
O5 Y1 N1 119.9(2) . . ?
O8 Y1 N1 103.8(2) 2_665 . ?
O6 Y1 N1 80.2(2) . . ?
O7 Y1 N1 152.6(2) 2_665 . ?
O13 Y1 N1 73.8(2) . . ?
O9 Y1 N1 25.76(19) . . ?
O10 Y1 N1 25.64(18) . . ?
O12 Y1 N1 84.86(19) . . ?
O5 Y1 N2 99.8(2) . . ?
O8 Y1 N2 121.4(2) 2_665 . ?
O6 Y1 N2 156.3(2) . . ?
O7 Y1 N2 75.75(19) 2_665 . ?
O13 Y1 N2 25.2(2) . . ?
O9 Y1 N2 73.4(2) . . ?
O10 Y1 N2 86.1(2) . . ?
O12 Y1 N2 25.9(2) . . ?
N1 Y1 N2 78.1(2) . . ?
O6 Eu1 O5 120.64(15) . 2_665 ?
O6 Eu1 O8 72.04(14) . 2_665 ?
O5 Eu1 O8 79.66(15) 2_665 2_665 ?
O6 Eu1 O7 80.36(13) . . ?
O5 Eu1 O7 72.04(14) 2_665 . ?
O8 Eu1 O7 121.76(15) 2_665 . ?
O6 Eu1 O18 148.91(17) . . ?
O5 Eu1 O18 72.41(17) 2_665 . ?
O8 Eu1 O18 138.75(17) 2_665 . ?
O7 Eu1 O18 77.59(15) . . ?
O6 Eu1 O15 131.17(17) . . ?
O5 Eu1 O15 91.95(17) 2_665 . ?
O8 Eu1 O15 80.50(17) 2_665 . ?
O7 Eu1 O15 147.85(18) . . ?
O18 Eu1 O15 70.95(19) . . ?
O6 Eu1 O16 81.71(16) . . ?
O5 Eu1 O16 140.11(16) 2_665 . ?
O8 Eu1 O16 76.92(16) 2_665 . ?
O7 Eu1 O16 147.75(17) . . ?
O18 Eu1 O16 106.26(18) . . ?
O15 Eu1 O16 52.70(18) . . ?
O6 Eu1 N4 83.26(18) . . ?
O5 Eu1 N4 140.07(18) 2_665 . ?
O8 Eu1 N4 140.25(18) 2_665 . ?
O7 Eu1 N4 82.50(17) . . ?
O18 Eu1 N4 72.4(2) . . ?
O15 Eu1 N4 94.0(2) . . ?
O16 Eu1 N4 68.92(18) . . ?
O6 Eu1 N3 106.89(17) . . ?
O5 Eu1 N3 116.83(18) 2_665 . ?
O8 Eu1 N3 78.08(17) 2_665 . ?
O7 Eu1 N3 160.09(18) . . ?
O18 Eu1 N3 88.02(18) . . ?
O15 Eu1 N3 26.37(18) . . ?
O16 Eu1 N3 26.35(18) . . ?
N4 Eu1 N3 80.06(19) . . ?
O6 Y2 O5 123.4(2) . 2_665 ?
O6 Y2 O7 81.92(17) . . ?
O5 Y2 O7 73.20(17) 2_665 . ?
O6 Y2 O8 73.09(18) . 2_665 ?
O5 Y2 O8 80.65(19) 2_665 2_665 ?
O7 Y2 O8 124.5(2) . 2_665 ?
O6 Y2 O18 149.0(2) . . ?
O5 Y2 O18 72.19(19) 2_665 . ?
O7 Y2 O18 77.60(18) . . ?
O8 Y2 O18 137.9(2) 2_665 . ?
O6 Y2 O15 130.2(2) . . ?
O5 Y2 O15 91.2(2) 2_665 . ?
O7 Y2 O15 146.6(2) . . ?
O8 Y2 O15 79.81(19) 2_665 . ?
O18 Y2 O15 69.5(2) . . ?
O6 Y2 O16 81.47(18) . . ?
O5 Y2 O16 139.0(2) 2_665 . ?
O7 Y2 O16 147.3(2) . . ?
O8 Y2 O16 76.46(18) 2_665 . ?
O18 Y2 O16 103.9(2) . . ?
O15 Y2 O16 51.62(19) . . ?
O6 Y2 N4 83.2(2) . . ?
O5 Y2 N4 139.5(2) 2_665 . ?
O7 Y2 N4 82.5(2) . . ?
O8 Y2 N4 139.5(2) 2_665 . ?
O18 Y2 N4 71.3(2) . . ?
O15 Y2 N4 91.9(2) . . ?
O16 Y2 N4 67.7(2) . . ?
O6 Y2 N3 106.2(2) . . ?
O5 Y2 N3 115.7(2) 2_665 . ?
O7 Y2 N3 158.2(2) . . ?
O8 Y2 N3 77.27(19) 2_665 . ?
O18 Y2 N3 86.2(2) . . ?
O15 Y2 N3 25.84(18) . . ?
O16 Y2 N3 25.79(18) . . ?
N4 Y2 N3 78.5(2) . . ?
O1 Si1 O5 108.5(2) . . ?
O1 Si1 O4 109.8(2) . . ?
O5 Si1 O4 108.9(2) . . ?
O1 Si1 C1 106.8(3) . . ?
O5 Si1 C1 115.1(3) . . ?
O4 Si1 C1 107.7(3) . . ?
O6 Si2 O2 110.5(2) . . ?
O6 Si2 O1 109.7(2) . . ?
O2 Si2 O1 106.9(2) . . ?
O6 Si2 C7 113.7(3) . . ?
O2 Si2 C7 108.3(3) . . ?
O1 Si2 C7 107.4(2) . . ?
O7 Si3 O2 110.1(2) . . ?
O7 Si3 O3 110.1(2) . . ?
O2 Si3 O3 107.4(2) . . ?
O7 Si3 C13 115.1(3) . . ?
O2 Si3 C13 105.4(4) . . ?
O3 Si3 C13 108.4(3) . . ?
O8 Si4 O4 111.0(2) . . ?
O8 Si4 O3 108.5(2) . . ?
O4 Si4 O3 108.1(2) . . ?
O8 Si4 C19 113.5(3) . . ?
O4 Si4 C19 107.6(3) . . ?
O3 Si4 C19 107.9(2) . . ?
Si1 O1 Si2 130.4(3) . . ?
Si2 O2 Si3 135.2(3) . . ?
Si4 O3 Si3 130.6(2) . . ?
Si4 O4 Si1 134.2(3) . . ?
Si1 O5 Tb1 125.3(2) . . ?
Si1 O5 Y1 125.5(2) . . ?
Si1 O5 Y2 127.3(2) . 2_665 ?
Y1 O5 Y2 105.65(19) . 2_665 ?
Si1 O5 Eu1 126.4(2) . 2_665 ?
Tb1 O5 Eu1 106.93(16) . 2_665 ?
Si2 O6 Y2 127.8(2) . . ?
Si2 O6 Y1 124.4(2) . . ?
Y2 O6 Y1 104.43(19) . . ?
Si2 O6 Tb1 124.1(2) . . ?
Si2 O6 Eu1 127.6(2) . . ?
Tb1 O6 Eu1 105.38(16) . . ?
Si3 O7 Y2 128.3(2) . . ?
Si3 O7 Y1 124.5(2) . 2_665 ?
Y2 O7 Y1 103.81(19) . 2_665 ?
Si3 O7 Tb1 124.6(2) . 2_665 ?
Si3 O7 Eu1 128.1(2) . . ?
Tb1 O7 Eu1 104.51(15) 2_665 . ?
Si4 O8 Y1 126.8(2) . 2_665 ?
Si4 O8 Tb1 126.7(2) . 2_665 ?
Si4 O8 Y2 126.2(2) . 2_665 ?
Y1 O8 Y2 104.40(19) 2_665 2_665 ?
Si4 O8 Eu1 125.5(2) . 2_665 ?
Tb1 O8 Eu1 105.61(15) 2_665 2_665 ?
N1 O9 Tb1 96.5(4) . . ?
N1 O9 Y1 96.4(4) . . ?
N1 O10 Tb1 95.4(4) . . ?
N1 O10 Y1 95.6(4) . . ?
N2 O12 Tb1 94.0(4) . . ?
N2 O12 Y1 94.0(4) . . ?
N2 O13 Tb1 97.7(4) . . ?
N2 O13 Y1 97.9(5) . . ?
N3 O15 Eu1 97.1(4) . . ?
N3 O15 Y2 97.5(4) . . ?
N3 O16 Eu1 96.2(4) . . ?
N3 O16 Y2 97.0(4) . . ?
C25 O18 Eu1 138.5(5) . . ?
C25 O18 Y2 139.7(5) . . ?
C25 O18 H18O 109.1 . . ?
Eu1 O18 H18O 103.9 . . ?
Y2 O18 H18O 102.7 . . ?
O11 N1 O10 122.5(7) . . ?
O11 N1 O9 120.9(7) . . ?
O10 N1 O9 116.5(5) . . ?
O11 N1 Tb1 178.4(6) . . ?
O10 N1 Tb1 58.9(3) . . ?
O9 N1 Tb1 57.7(3) . . ?
O11 N1 Y1 178.6(6) . . ?
O10 N1 Y1 58.7(3) . . ?
O9 N1 Y1 57.9(3) . . ?
O14 N2 O13 121.7(8) . . ?
O14 N2 O12 121.3(8) . . ?
O13 N2 O12 117.0(6) . . ?
O14 N2 Tb1 178.6(7) . . ?
O13 N2 Tb1 57.0(3) . . ?
O12 N2 Tb1 60.0(3) . . ?
O14 N2 Y1 178.5(7) . . ?
O13 N2 Y1 56.9(4) . . ?
O12 N2 Y1 60.1(4) . . ?
O17 N3 O16 124.6(7) . . ?
O17 N3 O15 121.5(7) . . ?
O16 N3 O15 113.9(5) . . ?
O17 N3 Eu1 177.5(6) . . ?
O16 N3 Eu1 57.4(3) . . ?
O15 N3 Eu1 56.5(3) . . ?
O17 N3 Y2 178.0(6) . . ?
O16 N3 Y2 57.2(3) . . ?
O15 N3 Y2 56.7(3) . . ?
C27 N4 Eu1 167.8(6) . . ?
C27 N4 Y2 166.5(6) . . ?
C6 C1 C2 117.9(6) . . ?
C6 C1 Si1 121.3(5) . . ?
C2 C1 Si1 120.8(5) . . ?
C1 C2 C3 120.4(8) . . ?
C1 C2 H2 119.8 . . ?
C3 C2 H2 119.8 . . ?
C4 C3 C2 120.5(7) . . ?
C4 C3 H3 119.8 . . ?
C2 C3 H3 119.8 . . ?
C3 C4 C5 119.4(7) . . ?
C3 C4 H4 120.3 . . ?
C5 C4 H4 120.3 . . ?
C4 C5 C6 120.8(8) . . ?
C4 C5 H5 119.6 . . ?
C6 C5 H5 119.6 . . ?
C5 C6 C1 120.9(7) . . ?
C5 C6 H6 119.5 . . ?
C1 C6 H6 119.5 . . ?
C12 C7 C8 117.2(6) . . ?
C12 C7 Si2 120.4(5) . . ?
C8 C7 Si2 122.4(5) . . ?
C9 C8 C7 120.7(7) . . ?
C9 C8 H8 119.6 . . ?
C7 C8 H8 119.6 . . ?
C10 C9 C8 119.9(7) . . ?
C10 C9 H9 120.0 . . ?
C8 C9 H9 120.0 . . ?
C11 C10 C9 119.8(7) . . ?
C11 C10 H10 120.1 . . ?
C9 C10 H10 120.1 . . ?
C10 C11 C12 120.1(7) . . ?
C10 C11 H11 120.0 . . ?
C12 C11 H11 120.0 . . ?
C7 C12 C11 122.2(7) . . ?
C7 C12 H12 118.9 . . ?
C11 C12 H12 118.9 . . ?
C18 C13 C14 117.4(8) . . ?
C18 C13 Si3 124.1(7) . . ?
C14 C13 Si3 118.3(7) . . ?
C15 C14 C13 120.5(9) . . ?
C15 C14 H14 119.7 . . ?
C13 C14 H14 119.7 . . ?
C16 C15 C14 121.1(9) . . ?
C16 C15 H15 119.4 . . ?
C14 C15 H15 119.4 . . ?
C15 C16 C17 119.8(8) . . ?
C15 C16 H16 120.1 . . ?
C17 C16 H16 120.1 . . ?
C16 C17 C18 120.3(9) . . ?
C16 C17 H17 119.8 . . ?
C18 C17 H17 119.8 . . ?
C13 C18 C17 120.8(9) . . ?
C13 C18 H18 119.6 . . ?
C17 C18 H18 119.6 . . ?
C24 C19 C20 117.5(6) . . ?
C24 C19 Si4 122.9(5) . . ?
C20 C19 Si4 119.6(6) . . ?
C21 C20 C19 119.6(10) . . ?
C21 C20 H20 120.2 . . ?
C19 C20 H20 120.2 . . ?
C22 C21 C20 121.5(10) . . ?
C22 C21 H21 119.2 . . ?
C20 C21 H21 119.2 . . ?
C23 C22 C21 119.0(8) . . ?
C23 C22 H22 120.5 . . ?
C21 C22 H22 120.5 . . ?
C22 C23 C24 120.5(10) . . ?
C22 C23 H23 119.7 . . ?
C24 C23 H23 119.7 . . ?
C19 C24 C23 121.8(8) . . ?
C19 C24 H24 119.1 . . ?
C23 C24 H24 119.1 . . ?
O18 C25 C26 114.9(9) . . ?
O18 C25 H25A 108.6 . . ?
C26 C25 H25A 108.6 . . ?
O18 C25 H25B 108.6 . . ?
C26 C25 H25B 108.6 . . ?
H25A C25 H25B 107.5 . . ?
C25 C26 H26A 109.5 . . ?
C25 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
C25 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
N4 C27 C28 178.2(9) . . ?
C27 C28 H28A 109.5 . . ?
C27 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
C27 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
C33 N5 C29 114.5(7) . . ?
C33 N5 C31 112.6(8) . . ?
C29 N5 C31 110.7(7) . . ?
C33 N5 C35 107.7(8) . . ?
C29 N5 C35 107.7(8) . . ?
C31 N5 C35 102.8(7) . . ?
C30 C29 N5 119.0(10) . . ?
C30 C29 H29A 107.6 . . ?
N5 C29 H29A 107.6 . . ?
C30 C29 H29B 107.6 . . ?
N5 C29 H29B 107.6 . . ?
H29A C29 H29B 107.0 . . ?
C29 C30 H30A 109.5 . . ?
C29 C30 H30B 109.5 . . ?
H30A C30 H30B 109.5 . . ?
C29 C30 H30C 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
N5 C31 C32 108.5(8) . . ?
N5 C31 H31A 110.0 . . ?
C32 C31 H31A 110.0 . . ?
N5 C31 H31B 110.0 . . ?
C32 C31 H31B 110.0 . . ?
H31A C31 H31B 108.4 . . ?
C31 C32 H32A 109.5 . . ?
C31 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
C31 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
N5 C33 C34 115.6(8) . . ?
N5 C33 H33A 108.4 . . ?
C34 C33 H33A 108.4 . . ?
N5 C33 H33B 108.4 . . ?
C34 C33 H33B 108.4 . . ?
H33A C33 H33B 107.5 . . ?
C33 C34 H34A 109.5 . . ?
C33 C34 H34B 109.5 . . ?
H34A C34 H34B 109.5 . . ?
C33 C34 H34C 109.5 . . ?
H34A C34 H34C 109.5 . . ?
H34B C34 H34C 109.5 . . ?
C36 C35 N5 116.6(10) . . ?
C36 C35 H35A 108.1 . . ?
N5 C35 H35A 108.1 . . ?
C36 C35 H35B 108.1 . . ?
N5 C35 H35B 108.1 . . ?
H35A C35 H35B 107.3 . . ?
C35 C36 H36A 109.5 . . ?
C35 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
C35 C36 H36C 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O5 Si1 O1 Si2 -45.9(5) . . . . ?
O4 Si1 O1 Si2 73.0(4) . . . . ?
C1 Si1 O1 Si2 -170.6(4) . . . . ?
O6 Si2 O1 Si1 47.6(5) . . . . ?
O2 Si2 O1 Si1 -72.3(4) . . . . ?
C7 Si2 O1 Si1 171.7(4) . . . . ?
O6 Si2 O2 Si3 -27.4(5) . . . . ?
O1 Si2 O2 Si3 92.0(4) . . . . ?
C7 Si2 O2 Si3 -152.5(4) . . . . ?
O7 Si3 O2 Si2 27.7(5) . . . . ?
O3 Si3 O2 Si2 -92.2(4) . . . . ?
C13 Si3 O2 Si2 152.3(4) . . . . ?
O8 Si4 O3 Si3 46.8(4) . . . . ?
O4 Si4 O3 Si3 -73.7(4) . . . . ?
C19 Si4 O3 Si3 170.2(4) . . . . ?
O7 Si3 O3 Si4 -46.8(4) . . . . ?
O2 Si3 O3 Si4 73.1(4) . . . . ?
C13 Si3 O3 Si4 -173.4(5) . . . . ?
O8 Si4 O4 Si1 -30.5(4) . . . . ?
O3 Si4 O4 Si1 88.4(4) . . . . ?
C19 Si4 O4 Si1 -155.3(4) . . . . ?
O1 Si1 O4 Si4 -88.8(4) . . . . ?
O5 Si1 O4 Si4 29.9(4) . . . . ?
C1 Si1 O4 Si4 155.3(4) . . . . ?
O1 Si1 O5 Tb1 -18.7(4) . . . . ?
O4 Si1 O5 Tb1 -138.2(3) . . . . ?
C1 Si1 O5 Tb1 100.8(3) . . . . ?
O1 Si1 O5 Y1 -18.3(4) . . . . ?
O4 Si1 O5 Y1 -137.8(3) . . . . ?
C1 Si1 O5 Y1 101.2(3) . . . . ?
O1 Si1 O5 Y2 145.1(3) . . . 2_665 ?
O4 Si1 O5 Y2 25.6(4) . . . 2_665 ?
C1 Si1 O5 Y2 -95.3(4) . . . 2_665 ?
O1 Si1 O5 Eu1 146.6(3) . . . 2_665 ?
O4 Si1 O5 Eu1 27.1(4) . . . 2_665 ?
C1 Si1 O5 Eu1 -93.8(3) . . . 2_665 ?
O2 Si2 O6 Y2 -23.6(4) . . . . ?
O1 Si2 O6 Y2 -141.3(3) . . . . ?
C7 Si2 O6 Y2 98.5(3) . . . . ?
O2 Si2 O6 Y1 132.4(3) . . . . ?
O1 Si2 O6 Y1 14.8(3) . . . . ?
C7 Si2 O6 Y1 -105.5(3) . . . . ?
O2 Si2 O6 Tb1 132.6(2) . . . . ?
O1 Si2 O6 Tb1 15.0(3) . . . . ?
C7 Si2 O6 Tb1 -105.3(3) . . . . ?
O2 Si2 O6 Eu1 -25.3(3) . . . . ?
O1 Si2 O6 Eu1 -142.9(3) . . . . ?
C7 Si2 O6 Eu1 96.8(3) . . . . ?
O2 Si3 O7 Y2 22.7(4) . . . . ?
O3 Si3 O7 Y2 140.9(3) . . . . ?
C13 Si3 O7 Y2 -96.2(5) . . . . ?
O2 Si3 O7 Y1 -133.1(3) . . . 2_665 ?
O3 Si3 O7 Y1 -14.9(3) . . . 2_665 ?
C13 Si3 O7 Y1 107.9(5) . . . 2_665 ?
O2 Si3 O7 Tb1 -133.5(2) . . . 2_665 ?
O3 Si3 O7 Tb1 -15.3(3) . . . 2_665 ?
C13 Si3 O7 Tb1 107.5(5) . . . 2_665 ?
O2 Si3 O7 Eu1 24.3(3) . . . . ?
O3 Si3 O7 Eu1 142.5(3) . . . . ?
C13 Si3 O7 Eu1 -94.6(5) . . . . ?
O4 Si4 O8 Y1 134.4(3) . . . 2_665 ?
O3 Si4 O8 Y1 15.8(3) . . . 2_665 ?
C19 Si4 O8 Y1 -104.2(3) . . . 2_665 ?
O4 Si4 O8 Tb1 134.6(2) . . . 2_665 ?
O3 Si4 O8 Tb1 16.0(3) . . . 2_665 ?
C19 Si4 O8 Tb1 -104.0(3) . . . 2_665 ?
O4 Si4 O8 Y2 -24.3(3) . . . 2_665 ?
O3 Si4 O8 Y2 -143.0(3) . . . 2_665 ?
C19 Si4 O8 Y2 97.1(3) . . . 2_665 ?
O4 Si4 O8 Eu1 -25.9(3) . . . 2_665 ?
O3 Si4 O8 Eu1 -144.6(2) . . . 2_665 ?
C19 Si4 O8 Eu1 95.5(3) . . . 2_665 ?
Tb1 O10 N1 O11 -179.1(8) . . . . ?
Y1 O10 N1 O11 -179.2(8) . . . . ?
Tb1 O10 N1 O9 2.7(7) . . . . ?
Y1 O10 N1 O9 2.5(7) . . . . ?
Y1 O10 N1 Tb1 -0.17(10) . . . . ?
Tb1 O10 N1 Y1 0.17(10) . . . . ?
Tb1 O9 N1 O11 179.0(8) . . . . ?
Y1 O9 N1 O11 179.2(8) . . . . ?
Tb1 O9 N1 O10 -2.7(7) . . . . ?
Y1 O9 N1 O10 -2.5(7) . . . . ?
Y1 O9 N1 Tb1 0.18(10) . . . . ?
Tb1 O9 N1 Y1 -0.18(10) . . . . ?
Tb1 O13 N2 O14 -179.6(7) . . . . ?
Y1 O13 N2 O14 -179.4(7) . . . . ?
Tb1 O13 N2 O12 -0.4(7) . . . . ?
Y1 O13 N2 O12 -0.3(7) . . . . ?
Y1 O13 N2 Tb1 0.17(9) . . . . ?
Tb1 O13 N2 Y1 -0.17(9) . . . . ?
Tb1 O12 N2 O14 179.6(7) . . . . ?
Y1 O12 N2 O14 179.4(7) . . . . ?
Tb1 O12 N2 O13 0.4(7) . . . . ?
Y1 O12 N2 O13 0.3(7) . . . . ?
Y1 O12 N2 Tb1 -0.16(9) . . . . ?
Tb1 O12 N2 Y1 0.16(9) . . . . ?
Eu1 O16 N3 O17 -178.3(7) . . . . ?
Y2 O16 N3 O17 -179.0(7) . . . . ?
Eu1 O16 N3 O15 2.6(6) . . . . ?
Y2 O16 N3 O15 1.8(6) . . . . ?
Y2 O16 N3 Eu1 -0.78(13) . . . . ?
Eu1 O16 N3 Y2 0.78(13) . . . . ?
Eu1 O15 N3 O17 178.2(6) . . . . ?
Y2 O15 N3 O17 179.0(7) . . . . ?
Eu1 O15 N3 O16 -2.6(6) . . . . ?
Y2 O15 N3 O16 -1.8(6) . . . . ?
Y2 O15 N3 Eu1 0.79(13) . . . . ?
Eu1 O15 N3 Y2 -0.79(13) . . . . ?
O1 Si1 C1 C6 -140.5(6) . . . . ?
O5 Si1 C1 C6 99.0(6) . . . . ?
O4 Si1 C1 C6 -22.6(6) . . . . ?
O1 Si1 C1 C2 37.0(7) . . . . ?
O5 Si1 C1 C2 -83.5(6) . . . . ?
O4 Si1 C1 C2 154.9(6) . . . . ?
C6 C1 C2 C3 -1.4(12) . . . . ?
Si1 C1 C2 C3 -178.9(6) . . . . ?
C1 C2 C3 C4 0.9(13) . . . . ?
C2 C3 C4 C5 -0.6(14) . . . . ?
C3 C4 C5 C6 0.8(13) . . . . ?
C4 C5 C6 C1 -1.3(13) . . . . ?
C2 C1 C6 C5 1.6(11) . . . . ?
Si1 C1 C6 C5 179.2(6) . . . . ?
O6 Si2 C7 C12 177.9(6) . . . . ?
O2 Si2 C7 C12 -58.8(6) . . . . ?
O1 Si2 C7 C12 56.4(6) . . . . ?
O6 Si2 C7 C8 -2.6(7) . . . . ?
O2 Si2 C7 C8 120.7(6) . . . . ?
O1 Si2 C7 C8 -124.2(6) . . . . ?
C12 C7 C8 C9 -1.3(13) . . . . ?
Si2 C7 C8 C9 179.2(7) . . . . ?
C7 C8 C9 C10 0.7(15) . . . . ?
C8 C9 C10 C11 -0.9(14) . . . . ?
C9 C10 C11 C12 1.7(13) . . . . ?
C8 C7 C12 C11 2.1(12) . . . . ?
Si2 C7 C12 C11 -178.4(7) . . . . ?
C10 C11 C12 C7 -2.4(14) . . . . ?
O7 Si3 C13 C18 8.0(13) . . . . ?
O2 Si3 C13 C18 -113.5(11) . . . . ?
O3 Si3 C13 C18 131.7(10) . . . . ?
O7 Si3 C13 C14 -177.3(9) . . . . ?
O2 Si3 C13 C14 61.2(10) . . . . ?
O3 Si3 C13 C14 -53.6(11) . . . . ?
C18 C13 C14 C15 0.5(19) . . . . ?
Si3 C13 C14 C15 -174.5(10) . . . . ?
C13 C14 C15 C16 -0.4(19) . . . . ?
C14 C15 C16 C17 1.6(19) . . . . ?
C15 C16 C17 C18 -2.9(19) . . . . ?
C14 C13 C18 C17 -1.8(19) . . . . ?
Si3 C13 C18 C17 172.9(10) . . . . ?
C16 C17 C18 C13 3.1(19) . . . . ?
O8 Si4 C19 C24 16.7(7) . . . . ?
O4 Si4 C19 C24 139.9(6) . . . . ?
O3 Si4 C19 C24 -103.7(6) . . . . ?
O8 Si4 C19 C20 -165.4(6) . . . . ?
O4 Si4 C19 C20 -42.1(7) . . . . ?
O3 Si4 C19 C20 74.3(6) . . . . ?
C24 C19 C20 C21 1.7(13) . . . . ?
Si4 C19 C20 C21 -176.4(8) . . . . ?
C19 C20 C21 C22 -0.6(17) . . . . ?
C20 C21 C22 C23 -0.8(18) . . . . ?
C21 C22 C23 C24 1.1(16) . . . . ?
C20 C19 C24 C23 -1.5(11) . . . . ?
Si4 C19 C24 C23 176.5(6) . . . . ?
C22 C23 C24 C19 0.1(14) . . . . ?
Eu1 O18 C25 C26 172.5(9) . . . . ?
Y2 O18 C25 C26 172.9(9) . . . . ?
C33 N5 C29 C30 -50.8(14) . . . . ?
C31 N5 C29 C30 -179.4(11) . . . . ?
C35 N5 C29 C30 69.0(12) . . . . ?
C33 N5 C31 C32 -61.3(11) . . . . ?
C29 N5 C31 C32 68.3(12) . . . . ?
C35 N5 C31 C32 -176.9(10) . . . . ?
C29 N5 C33 C34 174.6(10) . . . . ?
C31 N5 C33 C34 -57.7(12) . . . . ?
C35 N5 C33 C34 54.9(12) . . . . ?
C33 N5 C35 C36 -178.3(11) . . . . ?
C29 N5 C35 C36 57.8(12) . . . . ?
C31 N5 C35 C36 -59.1(13) . . . . ?

loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 0.000 0.000 0.500 248 52 ' '
_platon_squeeze_void_probe_radius 1.20
_platon_squeeze_details          ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O18 H18O O12 0.90 2.05 2.860(8) 149.8 2_665

_refine_diff_density_max         2.758
_refine_diff_density_min         -2.895
_refine_diff_density_rms         0.230

_shelxl_version_number           2013-4



# start Validation Reply Form
_vrf_PLAT973_3                   
;
PROBLEM: Check Calcd Positive Resid. Density on       Eu1       3.00 eA-3  
RESPONSE: There are the relatively high positive and negative electron 
density residues near the Eu, Tb and Y metal atoms due to the significant 
structure disorder as well as absorption effects, which can not be corrected 
completely.
;
_vrf_PLAT971_3                   
;
PROBLEM: Check Calcd Resid. Dens.  0.93Ang From Eu1             2.64 eA-3  
RESPONSE: There are the relatively high positive and negative electron 
density residues near the Eu, Tb and Y metal atoms due to the significant 
structure disorder as well as absorption effects, which can not be corrected 
completely.
;
_vrf_PLAT972_3                   
;
PROBLEM: Check Calcd Resid. Dens.  0.96Ang From Y2             -2.65 eA-3  
RESPONSE: There are the relatively high positive and negative electron 
density residues near the Eu, Tb and Y metal atoms due to the significant 
structure disorder as well as absorption effects, which can not be corrected 
completely.
;
_vrf_PLAT975_3                   
;
PROBLEM: Check Calcd Resid. Dens.  0.93Ang From O15     .       1.67 eA-3  
RESPONSE: There is the relatively high positive electron density residue 
near the O15 atom due to the significant structure disorder.
;
# end Validation Reply Form
