# Electronic Supplementary Material (ESI) for Chemical Science.
# This journal is © The Royal Society of Chemistry 2023

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_s
_database_code_depnum_ccdc_archive 'CCDC 2213499'
loop_
_audit_author_name
_audit_author_address
'Xiaohan Zhu'
;SHAANXI NORMAL UNIVERSITY
China
;
_audit_update_record             
;
2022-10-17 deposited with the CCDC.	2023-07-14 downloaded from the CCDC.
;
_audit_creation_date             2022-10-07
_audit_creation_method           
;
Olex2 1.5-alpha
(compiled 2022.06.10 svn.r3fa896fb for OlexSys, GUI svn.r6535)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C30 H22 N2 O'
_chemical_formula_sum            'C30 H22 N2 O'
_chemical_formula_weight         426.49
_chemical_absolute_configuration rmad
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           19
_space_group_name_H-M_alt        'P 21 21 21'
_space_group_name_Hall           'P 2ac 2ab'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'

_cell_length_a                   9.5313(3)
_cell_length_b                   14.4824(5)
_cell_length_c                   16.6299(5)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     2295.53(13)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9796
_cell_measurement_temperature    180.00
_cell_measurement_theta_max      68.249
_cell_measurement_theta_min      2.657
_shelx_estimated_absorpt_T_max   0.944
_shelx_estimated_absorpt_T_min   0.779
_exptl_absorpt_coefficient_mu    0.586
_exptl_absorpt_correction_T_max  0.7531
_exptl_absorpt_correction_T_min  0.6739
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1140 before and 0.0532 after correction.
The Ratio of minimum to maximum transmission is 0.8948.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear light colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.234
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             896
_exptl_crystal_size_max          0.45
_exptl_crystal_size_mid          0.3
_exptl_crystal_size_min          0.1
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0316
_diffrn_reflns_av_unetI/netI     0.0149
_diffrn_reflns_Laue_measured_fraction_full 0.989
_diffrn_reflns_Laue_measured_fraction_max 0.989
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            34480
_diffrn_reflns_point_group_measured_fraction_full 0.992
_diffrn_reflns_point_group_measured_fraction_max 0.991
_diffrn_reflns_theta_full        67.679
_diffrn_reflns_theta_max         68.280
_diffrn_reflns_theta_min         4.048
_diffrn_ambient_temperature      180.00
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.989
_diffrn_measured_fraction_theta_max 0.989
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_source                   ?
_diffrn_source_current           50.0
_diffrn_source_power             2.5
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.759
_reflns_Friedel_fraction_full    0.995
_reflns_Friedel_fraction_max     0.994
_reflns_number_gt                4037
_reflns_number_total             4169
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.40A (Bruker, 2019)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.40A (Bruker, 2019)'
_computing_molecular_graphics    'Olex2 1.5-alpha (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5-alpha (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         0.154
_refine_diff_density_min         -0.142
_refine_diff_density_rms         0.025
_refine_ls_abs_structure_details 
;
 Flack x determined using 1718 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   -0.03(7)
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.067
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     299
_refine_ls_number_reflns         4169
_refine_ls_number_restraints     93
_refine_ls_R_factor_all          0.0301
_refine_ls_R_factor_gt           0.0288
_refine_ls_restrained_S_all      1.059
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0378P)²+0.2602P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0732
_refine_ls_wR_factor_ref         0.0747
_refine_special_details          ?
_olex2_refinement_description    
;
1. Rigid bond restraints
 All non-hydrogen atoms
 with sigma for 1-2 distances of 0.005 and sigma for 1-3 distances of 0.005
2.a Aromatic/amide H refined with riding coordinates:
 C14(H14), C18(H18), C22(H22), C24(H24), C26(H26), C28(H28), C30(H30), C2(H2),
 C17(H17), C9(H9), C19(H19), C5(H5), C23(H23), C3(H3), C25(H25), C13(H13),
 C27(H27), C7(H7), C29(H29)
2.b Idealised Me refined as rotating group:
 C21(H21A,H21B,H21C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
O1 O 0.57693(16) 0.39276(9) 0.40753(8) 0.0522(3) Uani 1 1 d . U . . .
N1 N 0.56749(15) 0.48404(9) 0.51871(8) 0.0367(3) Uani 1 1 d . U . . .
N2 N 0.66383(15) 0.42572(10) 0.55525(9) 0.0402(3) Uani 1 1 d . U . . .
C1 C 0.55390(18) 0.56522(11) 0.64924(9) 0.0358(4) Uani 1 1 d . U . . .
C4 C 0.53054(18) 0.46212(12) 0.43940(10) 0.0392(4) Uani 1 1 d . U . . .
C6 C 0.43856(17) 0.52962(12) 0.40092(10) 0.0378(4) Uani 1 1 d . U . . .
C8 C 0.38238(17) 0.60393(12) 0.44433(10) 0.0373(3) Uani 1 1 d . U . . .
C10 C 0.41472(17) 0.61451(11) 0.52912(9) 0.0351(3) Uani 1 1 d . U . . .
C12 C 0.50888(16) 0.55663(11) 0.56379(9) 0.0341(3) Uani 1 1 d . U . . .
C14 C 0.6905(2) 0.58882(12) 0.66933(11) 0.0423(4) Uani 1 1 d . U . . .
H14 H 0.759022 0.595864 0.628282 0.051 Uiso 1 1 calc R U . . .
C16 C 0.34960(18) 0.69005(12) 0.57771(10) 0.0392(4) Uani 1 1 d . U . . .
C18 C 0.30013(19) 0.66846(13) 0.40236(12) 0.0448(4) Uani 1 1 d . U . . .
H18 H 0.260229 0.719192 0.430438 0.054 Uiso 1 1 calc R U . . .
C20 C 0.8070(2) 0.43110(12) 0.54103(10) 0.0416(4) Uani 1 1 d . U . . .
C22 C 0.4546(2) 0.55531(12) 0.71003(10) 0.0444(4) Uani 1 1 d . U . . .
H22 H 0.360667 0.539429 0.696951 0.053 Uiso 1 1 calc R U . . .
C24 C 0.4129(2) 0.52057(14) 0.31816(11) 0.0468(4) Uani 1 1 d . U . . .
H24 H 0.450371 0.469469 0.289487 0.056 Uiso 1 1 calc R U . . .
C26 C 0.8850(2) 0.49987(15) 0.50419(10) 0.0481(4) Uani 1 1 d . U . . .
H26 H 0.841806 0.553903 0.483324 0.058 Uiso 1 1 calc R U . . .
C28 C 0.4280(2) 0.76426(12) 0.60382(13) 0.0506(4) Uani 1 1 d . U . . .
H28 H 0.522907 0.769851 0.587135 0.061 Uiso 1 1 calc R U . . .
C30 C 0.4928(2) 0.56859(14) 0.78968(11) 0.0525(5) Uani 1 1 d . U . . .
H30 H 0.424870 0.561393 0.831014 0.063 Uiso 1 1 calc R U . . .
C15 C 0.8667(2) 0.35072(14) 0.57279(11) 0.0532(5) Uani 1 1 d . U . . .
C2 C 0.7538(3) 0.29684(13) 0.60372(14) 0.0625(6) Uani 1 1 d . U . . .
H2 H 0.763270 0.238499 0.629278 0.075 Uiso 1 1 calc R U . . .
C17 C 0.7275(2) 0.60218(13) 0.74927(11) 0.0504(5) Uani 1 1 d . U . . .
H17 H 0.821263 0.618266 0.762748 0.060 Uiso 1 1 calc R U . . .
C9 C 0.6284(3) 0.59214(13) 0.80919(11) 0.0547(5) Uani 1 1 d . U . . .
H9 H 0.653881 0.601480 0.863821 0.066 Uiso 1 1 calc R U . . .
C19 C 0.2104(2) 0.68553(17) 0.60135(14) 0.0584(5) Uani 1 1 d . U . . .
H19 H 0.153086 0.635990 0.583408 0.070 Uiso 1 1 calc R U . . .
C5 C 1.0286(2) 0.48653(18) 0.49906(13) 0.0617(6) Uani 1 1 d . U . . .
H5 H 1.085030 0.532166 0.473817 0.074 Uiso 1 1 calc R U . . .
C21 C 0.4827(3) 0.31766(16) 0.60801(15) 0.0667(6) Uani 1 1 d . U . . .
H21A H 0.437989 0.368229 0.637617 0.100 Uiso 1 1 calc R U . . .
H21B H 0.479452 0.261198 0.640434 0.100 Uiso 1 1 calc R U . . .
H21C H 0.432758 0.307520 0.557265 0.100 Uiso 1 1 calc R U . . .
C11 C 0.6304(2) 0.34185(12) 0.59099(11) 0.0491(4) Uani 1 1 d . U . . .
C23 C 0.3336(2) 0.58564(15) 0.27848(11) 0.0518(5) Uani 1 1 d . U . . .
H23 H 0.317942 0.580238 0.222260 0.062 Uiso 1 1 calc R U . . .
C3 C 0.2765(2) 0.65908(15) 0.32081(12) 0.0523(5) Uani 1 1 d . U . . .
H3 H 0.220679 0.703407 0.293457 0.063 Uiso 1 1 calc R U . . .
C25 C 0.3709(3) 0.83078(15) 0.65388(14) 0.0665(6) Uani 1 1 d . U . . .
H25 H 0.427304 0.880885 0.671650 0.080 Uiso 1 1 calc R U . . .
C13 C 1.0142(3) 0.34031(19) 0.56666(15) 0.0727(7) Uani 1 1 d . U . . .
H13 H 1.059200 0.287013 0.587706 0.087 Uiso 1 1 calc R U . . .
C27 C 0.1543(3) 0.7532(2) 0.65124(15) 0.0752(7) Uani 1 1 d . U . . .
H27 H 0.058629 0.749381 0.666982 0.090 Uiso 1 1 calc R U . . .
C7 C 1.0911(3) 0.4086(2) 0.52974(16) 0.0755(7) Uani 1 1 d . U . . .
H7 H 1.189943 0.401765 0.525352 0.091 Uiso 1 1 calc R U . . .
C29 C 0.2344(3) 0.82487(18) 0.67784(14) 0.0716(7) Uani 1 1 d . U . . .
H29 H 0.195635 0.870179 0.712671 0.086 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
O1 C4 1.219(2) . ?
N1 N2 1.3877(19) . ?
N1 C4 1.402(2) . ?
N1 C12 1.407(2) . ?
N2 C20 1.387(2) . ?
N2 C11 1.389(2) . ?
C1 C12 1.490(2) . ?
C1 C14 1.387(3) . ?
C1 C22 1.392(2) . ?
C4 C6 1.461(2) . ?
C6 C8 1.402(2) . ?
C6 C24 1.404(2) . ?
C8 C10 1.452(2) . ?
C8 C18 1.405(2) . ?
C10 C12 1.357(2) . ?
C10 C16 1.495(2) . ?
C14 H14 0.9500 . ?
C14 C17 1.389(3) . ?
C16 C28 1.379(3) . ?
C16 C19 1.385(3) . ?
C18 H18 0.9500 . ?
C18 C3 1.381(3) . ?
C20 C26 1.386(3) . ?
C20 C15 1.399(3) . ?
C22 H22 0.9500 . ?
C22 C30 1.387(3) . ?
C24 H24 0.9500 . ?
C24 C23 1.377(3) . ?
C26 H26 0.9500 . ?
C26 C5 1.385(3) . ?
C28 H28 0.9500 . ?
C28 C25 1.384(3) . ?
C30 H30 0.9500 . ?
C30 C9 1.376(3) . ?
C15 C2 1.425(3) . ?
C15 C13 1.417(3) . ?
C2 H2 0.9500 . ?
C2 C11 1.362(3) . ?
C17 H17 0.9500 . ?
C17 C9 1.381(3) . ?
C9 H9 0.9500 . ?
C19 H19 0.9500 . ?
C19 C27 1.391(3) . ?
C5 H5 0.9500 . ?
C5 C7 1.374(4) . ?
C21 H21A 0.9800 . ?
C21 H21B 0.9800 . ?
C21 H21C 0.9800 . ?
C21 C11 1.478(3) . ?
C23 H23 0.9500 . ?
C23 C3 1.386(3) . ?
C3 H3 0.9500 . ?
C25 H25 0.9500 . ?
C25 C29 1.364(4) . ?
C13 H13 0.9500 . ?
C13 C7 1.376(4) . ?
C27 H27 0.9500 . ?
C27 C29 1.363(4) . ?
C7 H7 0.9500 . ?
C29 H29 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N2 N1 C4 116.14(13) . . ?
N2 N1 C12 118.96(13) . . ?
C4 N1 C12 124.81(14) . . ?
N1 N2 C11 124.59(15) . . ?
C20 N2 N1 122.83(14) . . ?
C20 N2 C11 110.34(15) . . ?
C14 C1 C12 121.38(15) . . ?
C14 C1 C22 119.24(16) . . ?
C22 C1 C12 119.24(16) . . ?
O1 C4 N1 120.31(16) . . ?
O1 C4 C6 125.36(16) . . ?
N1 C4 C6 114.30(14) . . ?
C8 C6 C4 121.15(15) . . ?
C8 C6 C24 120.65(16) . . ?
C24 C6 C4 118.13(16) . . ?
C6 C8 C10 120.01(15) . . ?
C6 C8 C18 117.89(16) . . ?
C18 C8 C10 122.05(16) . . ?
C8 C10 C16 120.95(14) . . ?
C12 C10 C8 119.21(15) . . ?
C12 C10 C16 119.81(14) . . ?
N1 C12 C1 117.15(14) . . ?
C10 C12 N1 119.87(14) . . ?
C10 C12 C1 122.98(14) . . ?
C1 C14 H14 119.9 . . ?
C1 C14 C17 120.21(18) . . ?
C17 C14 H14 119.9 . . ?
C28 C16 C10 121.04(16) . . ?
C28 C16 C19 117.79(17) . . ?
C19 C16 C10 121.09(17) . . ?
C8 C18 H18 119.6 . . ?
C3 C18 C8 120.86(18) . . ?
C3 C18 H18 119.6 . . ?
N2 C20 C15 106.80(17) . . ?
C26 C20 N2 130.06(17) . . ?
C26 C20 C15 123.14(18) . . ?
C1 C22 H22 120.0 . . ?
C30 C22 C1 120.07(19) . . ?
C30 C22 H22 120.0 . . ?
C6 C24 H24 119.9 . . ?
C23 C24 C6 120.10(18) . . ?
C23 C24 H24 119.9 . . ?
C20 C26 H26 121.4 . . ?
C5 C26 C20 117.2(2) . . ?
C5 C26 H26 121.4 . . ?
C16 C28 H28 119.4 . . ?
C16 C28 C25 121.3(2) . . ?
C25 C28 H28 119.4 . . ?
C22 C30 H30 119.8 . . ?
C9 C30 C22 120.39(19) . . ?
C9 C30 H30 119.8 . . ?
C20 C15 C2 106.54(18) . . ?
C20 C15 C13 117.7(2) . . ?
C13 C15 C2 135.8(2) . . ?
C15 C2 H2 125.2 . . ?
C11 C2 C15 109.51(17) . . ?
C11 C2 H2 125.2 . . ?
C14 C17 H17 119.9 . . ?
C9 C17 C14 120.16(19) . . ?
C9 C17 H17 119.9 . . ?
C30 C9 C17 119.92(17) . . ?
C30 C9 H9 120.0 . . ?
C17 C9 H9 120.0 . . ?
C16 C19 H19 119.9 . . ?
C16 C19 C27 120.3(2) . . ?
C27 C19 H19 119.9 . . ?
C26 C5 H5 119.3 . . ?
C7 C5 C26 121.4(2) . . ?
C7 C5 H5 119.3 . . ?
H21A C21 H21B 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C11 C21 H21A 109.5 . . ?
C11 C21 H21B 109.5 . . ?
C11 C21 H21C 109.5 . . ?
N2 C11 C21 120.50(18) . . ?
C2 C11 N2 106.68(19) . . ?
C2 C11 C21 132.82(18) . . ?
C24 C23 H23 120.1 . . ?
C24 C23 C3 119.81(17) . . ?
C3 C23 H23 120.1 . . ?
C18 C3 C23 120.67(19) . . ?
C18 C3 H3 119.7 . . ?
C23 C3 H3 119.7 . . ?
C28 C25 H25 119.8 . . ?
C29 C25 C28 120.4(2) . . ?
C29 C25 H25 119.8 . . ?
C15 C13 H13 120.5 . . ?
C7 C13 C15 119.0(2) . . ?
C7 C13 H13 120.5 . . ?
C19 C27 H27 119.5 . . ?
C29 C27 C19 121.0(2) . . ?
C29 C27 H27 119.5 . . ?
C5 C7 C13 121.7(2) . . ?
C5 C7 H7 119.2 . . ?
C13 C7 H7 119.2 . . ?
C25 C29 H29 120.4 . . ?
C27 C29 C25 119.2(2) . . ?
C27 C29 H29 120.4 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O1 C4 C6 C8 175.36(16) . . . . ?
O1 C4 C6 C24 -7.5(3) . . . . ?
N1 N2 C20 C26 13.7(3) . . . . ?
N1 N2 C20 C15 -167.07(14) . . . . ?
N1 N2 C11 C2 166.97(16) . . . . ?
N1 N2 C11 C21 -13.3(3) . . . . ?
N1 C4 C6 C8 -6.3(2) . . . . ?
N1 C4 C6 C24 170.78(15) . . . . ?
N2 N1 C4 O1 3.5(2) . . . . ?
N2 N1 C4 C6 -174.92(13) . . . . ?
N2 N1 C12 C1 -0.7(2) . . . . ?
N2 N1 C12 C10 179.87(14) . . . . ?
N2 C20 C26 C5 179.42(17) . . . . ?
N2 C20 C15 C2 1.79(19) . . . . ?
N2 C20 C15 C13 -179.17(17) . . . . ?
C1 C14 C17 C9 -0.1(3) . . . . ?
C1 C22 C30 C9 0.4(3) . . . . ?
C4 N1 N2 C20 79.4(2) . . . . ?
C4 N1 N2 C11 -81.98(19) . . . . ?
C4 N1 C12 C1 175.70(15) . . . . ?
C4 N1 C12 C10 -3.7(2) . . . . ?
C4 C6 C8 C10 -0.3(2) . . . . ?
C4 C6 C8 C18 177.06(15) . . . . ?
C4 C6 C24 C23 -176.21(17) . . . . ?
C6 C8 C10 C12 5.6(2) . . . . ?
C6 C8 C10 C16 -176.49(15) . . . . ?
C6 C8 C18 C3 -0.5(2) . . . . ?
C6 C24 C23 C3 -1.4(3) . . . . ?
C8 C6 C24 C23 0.9(3) . . . . ?
C8 C10 C12 N1 -3.7(2) . . . . ?
C8 C10 C12 C1 176.86(14) . . . . ?
C8 C10 C16 C28 -108.90(19) . . . . ?
C8 C10 C16 C19 74.3(2) . . . . ?
C8 C18 C3 C23 0.0(3) . . . . ?
C10 C8 C18 C3 176.86(17) . . . . ?
C10 C16 C28 C25 -175.05(18) . . . . ?
C10 C16 C19 C27 175.5(2) . . . . ?
C12 N1 N2 C20 -103.93(18) . . . . ?
C12 N1 N2 C11 94.73(19) . . . . ?
C12 N1 C4 O1 -173.01(15) . . . . ?
C12 N1 C4 C6 8.6(2) . . . . ?
C12 C1 C14 C17 175.84(16) . . . . ?
C12 C1 C22 C30 -176.09(16) . . . . ?
C12 C10 C16 C28 69.0(2) . . . . ?
C12 C10 C16 C19 -107.8(2) . . . . ?
C14 C1 C12 N1 66.9(2) . . . . ?
C14 C1 C12 C10 -113.68(19) . . . . ?
C14 C1 C22 C30 -0.3(3) . . . . ?
C14 C17 C9 C30 0.2(3) . . . . ?
C16 C10 C12 N1 178.35(14) . . . . ?
C16 C10 C12 C1 -1.0(2) . . . . ?
C16 C28 C25 C29 -0.8(3) . . . . ?
C16 C19 C27 C29 -0.1(4) . . . . ?
C18 C8 C10 C12 -171.66(16) . . . . ?
C18 C8 C10 C16 6.2(2) . . . . ?
C20 N2 C11 C2 3.6(2) . . . . ?
C20 N2 C11 C21 -176.64(18) . . . . ?
C20 C26 C5 C7 -0.4(3) . . . . ?
C20 C15 C2 C11 0.4(2) . . . . ?
C20 C15 C13 C7 -0.4(3) . . . . ?
C22 C1 C12 N1 -117.37(17) . . . . ?
C22 C1 C12 C10 62.0(2) . . . . ?
C22 C1 C14 C17 0.1(3) . . . . ?
C22 C30 C9 C17 -0.3(3) . . . . ?
C24 C6 C8 C10 -177.37(16) . . . . ?
C24 C6 C8 C18 0.0(2) . . . . ?
C24 C23 C3 C18 0.9(3) . . . . ?
C26 C20 C15 C2 -178.88(17) . . . . ?
C26 C20 C15 C13 0.2(3) . . . . ?
C26 C5 C7 C13 0.2(3) . . . . ?
C28 C16 C19 C27 -1.4(3) . . . . ?
C28 C25 C29 C27 -0.7(4) . . . . ?
C15 C20 C26 C5 0.3(3) . . . . ?
C15 C2 C11 N2 -2.4(2) . . . . ?
C15 C2 C11 C21 177.9(2) . . . . ?
C15 C13 C7 C5 0.2(3) . . . . ?
C2 C15 C13 C7 178.3(2) . . . . ?
C19 C16 C28 C25 1.8(3) . . . . ?
C19 C27 C29 C25 1.1(4) . . . . ?
C11 N2 C20 C26 177.36(17) . . . . ?
C11 N2 C20 C15 -3.38(19) . . . . ?
C13 C15 C2 C11 -178.4(2) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
