# Electronic Supplementary Material (ESI) for Journal of Materials Chemistry B.
# This journal is © The Royal Society of Chemistry 2023

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_GD1_0m_a
_database_code_depnum_ccdc_archive 'CCDC 2260190'
loop_
_audit_author_name
_audit_author_address
'Riya Mallik'
;Indian Institute of Technology Guwahati
India
;
_audit_update_record             
;
2023-05-02 deposited with the CCDC.	2023-07-31 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C34 H38 Cl2 Mn2 N6 Na2 O12, 2(H2 O)'
_chemical_formula_sum            'C34 H42 Cl2 Mn2 N6 Na2 O14'
_chemical_formula_weight         985.49

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mn Mn 0.3368 0.7283 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Na Na 0.0362 0.0249 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           4
_space_group_name_H-M_alt        'P 21'
_space_group_name_Hall           'P 2yb'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z'

_cell_length_a                   9.1405(3)
_cell_length_b                   13.8564(5)
_cell_length_c                   16.7601(6)
_cell_angle_alpha                90
_cell_angle_beta                 105.4930(10)
_cell_angle_gamma                90
_cell_volume                     2045.61(12)
_cell_formula_units_Z            2
_cell_measurement_temperature    273(2)
_cell_measurement_reflns_used    9971
_cell_measurement_theta_min      2.93
_cell_measurement_theta_max      27.28

_exptl_crystal_description       needle
_exptl_crystal_colour            colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_density_diffrn    1.600
_exptl_crystal_F_000             1012
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.32
_exptl_crystal_size_min          0.30
_exptl_absorpt_coefficient_mu    0.843
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.6402
_exptl_absorpt_correction_T_max  0.7455
_exptl_absorpt_process_details   
;SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1268 before and 0.0527 after correction.
The Ratio of minimum to maximum transmission is 0.8588.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      273(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            48385
_diffrn_reflns_av_unetI/netI     0.0168
_diffrn_reflns_av_R_equivalents  0.0257
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_theta_min         2.312
_diffrn_reflns_theta_max         24.999
_diffrn_reflns_theta_full        24.999
_diffrn_measured_fraction_theta_max 0.989
_diffrn_measured_fraction_theta_full 0.989
_diffrn_reflns_Laue_measured_fraction_max 0.989
_diffrn_reflns_Laue_measured_fraction_full 0.989
_diffrn_reflns_point_group_measured_fraction_max 0.986
_diffrn_reflns_point_group_measured_fraction_full 0.986
_reflns_number_total             7098
_reflns_number_gt                6849
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.909
_reflns_Friedel_fraction_max     0.983
_reflns_Friedel_fraction_full    0.983

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences. Completness statistics refer to single and
 composite reflections containing twin component 1 only.
;

_computing_data_collection       ?
_computing_cell_refinement       'SAINT V8.40B (?, 2016)'
_computing_data_reduction        'SAINT V8.40B (?, 2016)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          'Refined as a 2-component inversion twin.,Twin'
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0295P)²+0.4774P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_abs_structure_details 
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.046(15)
_chemical_absolute_configuration unk
_refine_ls_number_reflns         7098
_refine_ls_number_parameters     578
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.0225
_refine_ls_R_factor_gt           0.0211
_refine_ls_wR_factor_ref         0.0565
_refine_ls_wR_factor_gt          0.0552
_refine_ls_goodness_of_fit_ref   1.062
_refine_ls_restrained_S_all      1.062
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Mn2 Mn 0.61118(5) 0.63766(3) 0.43138(3) 0.02493(12) Uani 1 1 d . . . . .
Mn1 Mn 0.89324(5) 0.36330(3) 0.06429(3) 0.02527(12) Uani 1 1 d . . . . .
Cl1 Cl 0.81085(10) 0.21097(7) 0.11745(6) 0.0431(2) Uani 1 1 d . . . . .
Cl2 Cl 0.69987(10) 0.78762(7) 0.37667(6) 0.0402(2) Uani 1 1 d . . . . .
Na1 Na 0.96416(14) 0.52886(11) 0.23512(8) 0.0354(3) Uani 1 1 d . . . . .
O10 O 0.1868(2) 0.61802(18) 0.24299(13) 0.0310(5) Uani 1 1 d . . . . .
O4 O 1.0710(2) 0.39563(18) 0.18373(13) 0.0295(5) Uani 1 1 d . . . . .
Na2 Na 0.53712(14) 0.46839(11) 0.26027(7) 0.0343(3) Uani 1 1 d . . . . .
O21 O 0.2491(3) 0.4573(2) 0.38900(16) 0.0381(6) Uani 1 1 d . . . . .
O7 O 0.7234(2) 0.5238(2) 0.37167(14) 0.0330(5) Uani 1 1 d . . . . .
O1 O 0.5506(3) 0.5339(2) 0.13018(14) 0.0409(6) Uani 1 1 d . . . . .
N5 N 0.6302(3) 0.6825(2) 0.57855(17) 0.0280(6) Uani 1 1 d . . . . .
O8 O 0.5131(3) 0.51255(18) 0.49138(16) 0.0338(5) Uani 1 1 d . . . . .
N3 N 1.1156(3) 0.3019(2) 0.05427(16) 0.0254(6) Uani 1 1 d . . . . .
O2 O 0.7686(2) 0.4638(2) 0.12939(13) 0.0343(5) Uani 1 1 d . . . . .
N1 N 0.6620(3) 0.3991(2) -0.02229(15) 0.0264(6) Uani 1 1 d . . . . .
O12 O 0.7115(3) 0.3294(2) 0.26883(18) 0.0465(7) Uani 1 1 d . . . . .
H12A H 0.798573 0.346326 0.291793 0.070 Uiso 1 1 calc R U . . .
N4 N 0.8460(3) 0.6044(2) 0.51563(15) 0.0267(6) Uani 1 1 d . . . . .
C7 C 0.7318(4) 0.3063(3) -0.1277(2) 0.0360(8) Uani 1 1 d . . . . .
H7A H 0.712340 0.239841 -0.115577 0.043 Uiso 1 1 calc R U . . .
H7B H 0.716771 0.311925 -0.187051 0.043 Uiso 1 1 calc R U . . .
O3 O 0.9605(3) 0.50336(18) 0.01204(15) 0.0368(6) Uani 1 1 d . . . . .
C19 C 0.9304(3) 0.5387(3) 0.48975(19) 0.0261(7) Uani 1 1 d . . . . .
O11 O 0.7861(3) 0.6600(2) 0.23019(18) 0.0476(7) Uani 1 1 d . . . . .
H11A H 0.699899 0.641500 0.207303 0.071 Uiso 1 1 calc R U . . .
C34 C 0.2981(3) 0.6335(3) 0.30371(18) 0.0253(6) Uani 1 1 d . . . . .
O9 O 0.4318(2) 0.60543(17) 0.31098(13) 0.0285(5) Uani 1 1 d . . . . .
O22 O 0.2408(3) 0.5516(2) 0.09923(17) 0.0410(7) Uani 1 1 d . . . . .
C30 C 0.2384(4) 0.7795(3) 0.5143(2) 0.0398(9) Uani 1 1 d . . . . .
H30 H 0.230368 0.808765 0.562873 0.048 Uiso 1 1 calc R U . . .
N6 N 0.3920(3) 0.7049(2) 0.43815(16) 0.0261(6) Uani 1 1 d . . . . .
C22 C 1.0306(4) 0.6122(3) 0.6455(2) 0.0356(8) Uani 1 1 d . . . . .
H22 H 1.063930 0.639101 0.698063 0.043 Uiso 1 1 calc R U . . .
C1 C 0.6345(4) 0.4874(3) 0.09573(19) 0.0299(7) Uani 1 1 d . . . . .
O6 O 0.9411(3) 0.4564(2) 0.36701(14) 0.0423(7) Uani 1 1 d . . . . .
C31 C 0.1114(4) 0.7664(3) 0.4486(2) 0.0421(9) Uani 1 1 d . . . . .
H31 H 0.016755 0.787465 0.452161 0.050 Uiso 1 1 calc R U . . .
C3 C 0.4335(4) 0.4898(3) -0.0434(2) 0.0389(9) Uani 1 1 d . . . . .
H3A H 0.372384 0.531022 -0.022525 0.047 Uiso 1 1 calc R U . . .
C33 C 0.2701(3) 0.6904(3) 0.3753(2) 0.0263(7) Uani 1 1 d . . . . .
C23 C 0.8945(3) 0.6413(3) 0.59172(19) 0.0280(7) Uani 1 1 d . . . . .
C28 C 0.5229(4) 0.7634(3) 0.5738(2) 0.0371(8) Uani 1 1 d . . . . .
H28A H 0.570622 0.822818 0.563180 0.045 Uiso 1 1 calc R U . . .
H28B H 0.499179 0.770060 0.626574 0.045 Uiso 1 1 calc R U . . .
N2 N 0.8896(3) 0.3308(2) -0.08535(16) 0.0292(6) Uani 1 1 d . . . . .
C16 C 1.2372(4) 0.3134(2) 0.11995(19) 0.0247(7) Uani 1 1 d . . . . .
C12 C 1.1328(4) 0.2580(2) -0.01342(19) 0.0280(7) Uani 1 1 d . . . . .
C15 C 1.3786(4) 0.2796(3) 0.1195(2) 0.0319(8) Uani 1 1 d . . . . .
H15 H 1.461003 0.287514 0.165573 0.038 Uiso 1 1 calc R U . . .
C32 C 0.1265(4) 0.7217(3) 0.3774(2) 0.0352(8) Uani 1 1 d . . . . .
H32 H 0.042862 0.712806 0.332105 0.042 Uiso 1 1 calc R U . . .
C29 C 0.3777(4) 0.7484(2) 0.5065(2) 0.0302(7) Uani 1 1 d . . . . .
C18 C 0.8608(3) 0.5037(3) 0.40299(19) 0.0283(7) Uani 1 1 d . . . . .
C11 C 0.9905(4) 0.2473(3) -0.0828(2) 0.0338(8) Uani 1 1 d . . . . .
H11C H 1.016697 0.242203 -0.135057 0.041 Uiso 1 1 calc R U . . .
H11D H 0.938188 0.188604 -0.074981 0.041 Uiso 1 1 calc R U . . .
O5 O 1.3158(2) 0.38333(18) 0.25305(13) 0.0315(5) Uani 1 1 d . . . . .
C21 C 1.1158(4) 0.5425(3) 0.6197(2) 0.0390(9) Uani 1 1 d . . . . .
H21 H 1.206374 0.520968 0.655140 0.047 Uiso 1 1 calc R U . . .
C26 C 0.5613(5) 0.6130(4) 0.7046(2) 0.0579(11) Uani 1 1 d . . . . .
H26A H 0.638290 0.653507 0.738684 0.087 Uiso 1 1 calc R U . . .
H26B H 0.558489 0.552561 0.732054 0.087 Uiso 1 1 calc R U . . .
H26C H 0.464434 0.644306 0.694852 0.087 Uiso 1 1 calc R U . . .
C6 C 0.6206(4) 0.3710(3) -0.10164(19) 0.0298(7) Uani 1 1 d . . . . .
C8 C 0.9531(4) 0.4181(3) -0.1158(2) 0.0365(8) Uani 1 1 d . . . . .
H8A H 1.063732 0.410798 -0.098094 0.044 Uiso 1 1 calc R U . . .
C25 C 0.5977(4) 0.5950(3) 0.62167(19) 0.0336(7) Uani 1 1 d . . . . .
H25 H 0.689925 0.555548 0.633862 0.040 Uiso 1 1 calc R U . . .
C20 C 1.0653(4) 0.5050(3) 0.5404(2) 0.0334(8) Uani 1 1 d . . . . .
H20 H 1.121214 0.458152 0.521807 0.040 Uiso 1 1 calc R U . . .
C4 C 0.3898(4) 0.4595(4) -0.1247(2) 0.0441(10) Uani 1 1 d . . . . .
H4 H 0.297956 0.480206 -0.159431 0.053 Uiso 1 1 calc R U . . .
C14 C 1.3960(4) 0.2335(3) 0.0493(2) 0.0395(9) Uani 1 1 d . . . . .
H14 H 1.490321 0.209536 0.047914 0.047 Uiso 1 1 calc R U . . .
C17 C 1.2055(3) 0.3682(3) 0.19135(17) 0.0248(6) Uani 1 1 d . . . . .
C13 C 1.2733(4) 0.2235(3) -0.0179(2) 0.0381(8) Uani 1 1 d . . . . .
H13 H 1.283641 0.194085 -0.065939 0.046 Uiso 1 1 calc R U . . .
C2 C 0.5703(3) 0.4574(3) 0.00593(19) 0.0284(7) Uani 1 1 d . . . . .
C5 C 0.4822(4) 0.3984(3) -0.1547(2) 0.0393(9) Uani 1 1 d . . . . .
H5 H 0.452592 0.376186 -0.209001 0.047 Uiso 1 1 calc R U . . .
C24 C 0.7893(4) 0.7137(3) 0.6138(2) 0.0351(8) Uani 1 1 d . . . . .
H24A H 0.810591 0.719068 0.673486 0.042 Uiso 1 1 calc R U . . .
H24B H 0.804749 0.776583 0.591843 0.042 Uiso 1 1 calc R U . . .
C27 C 0.4733(3) 0.5349(2) 0.56649(18) 0.0350(7) Uani 1 1 d . . . . .
H27A H 0.460135 0.475743 0.594715 0.042 Uiso 1 1 calc R U . . .
H27B H 0.378290 0.570274 0.553817 0.042 Uiso 1 1 calc R U . . .
C10 C 0.9180(4) 0.5109(2) -0.07605(19) 0.0394(7) Uani 1 1 d . . . . .
H10A H 0.972403 0.564039 -0.092570 0.047 Uiso 1 1 calc R U . . .
H10B H 0.810186 0.524464 -0.095424 0.047 Uiso 1 1 calc R U . . .
C9 C 0.9112(6) 0.4281(4) -0.2103(3) 0.0715(14) Uani 1 1 d . . . . .
H9A H 0.934039 0.368918 -0.234257 0.107 Uiso 1 1 calc R U . . .
H9B H 0.968480 0.479812 -0.225245 0.107 Uiso 1 1 calc R U . . .
H9C H 0.804683 0.441677 -0.230545 0.107 Uiso 1 1 calc R U . . .
H8 H 0.443(4) 0.499(2) 0.4646(19) 0.020(9) Uiso 1 1 d . . . . .
H3 H 1.056(5) 0.530(4) 0.036(3) 0.083(16) Uiso 1 1 d . . . . .
H21A H 0.170(4) 0.457(3) 0.387(2) 0.026(10) Uiso 1 1 d . . . . .
H21B H 0.251(4) 0.433(3) 0.343(3) 0.053(13) Uiso 1 1 d . . . . .
H22A H 0.234(4) 0.561(3) 0.143(3) 0.044(12) Uiso 1 1 d . . . . .
H22B H 0.338(6) 0.545(4) 0.104(3) 0.072(16) Uiso 1 1 d . . . . .
H12B H 0.731(4) 0.303(3) 0.235(2) 0.047(14) Uiso 1 1 d . . . . .
H11B H 0.765(6) 0.691(5) 0.269(3) 0.09(2) Uiso 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Mn2 N6 2.240(3) . ?
Mn2 O7 2.256(2) . ?
Mn2 O9 2.279(2) . ?
Mn2 N4 2.279(3) . ?
Mn2 O8 2.303(3) . ?
Mn2 Cl2 2.4926(10) . ?
Mn2 N5 2.504(3) . ?
Mn2 Na2 3.6259(14) . ?
Mn1 N3 2.250(3) . ?
Mn1 O2 2.256(2) . ?
Mn1 O4 2.261(2) . ?
Mn1 N1 2.276(3) . ?
Mn1 O3 2.280(3) . ?
Mn1 Cl1 2.4848(10) . ?
Mn1 N2 2.540(2) . ?
Mn1 Na1 3.5901(14) . ?
Na1 O2 2.336(3) . ?
Na1 O10 2.354(3) 1_655 ?
Na1 O4 2.357(3) . ?
Na1 O11 2.426(3) . ?
Na1 O6 2.487(3) . ?
Na1 Na2 4.1225(13) . ?
O10 C34 1.251(4) . ?
O4 C17 1.260(4) . ?
Na2 O7 2.297(3) . ?
Na2 O5 2.316(3) 1_455 ?
Na2 O9 2.386(3) . ?
Na2 O1 2.395(3) . ?
Na2 O12 2.480(3) . ?
Na2 C1 3.127(3) . ?
O21 H21A 0.71(4) . ?
O21 H21B 0.85(4) . ?
O7 C18 1.256(4) . ?
O1 C1 1.254(4) . ?
N5 C28 1.478(4) . ?
N5 C24 1.480(4) . ?
N5 C25 1.481(4) . ?
O8 C27 1.434(4) . ?
O8 H8 0.70(3) . ?
N3 C12 1.333(4) . ?
N3 C16 1.349(4) . ?
O2 C1 1.248(4) . ?
N1 C2 1.338(4) . ?
N1 C6 1.340(4) . ?
O12 H12A 0.8200 . ?
O12 H12B 0.74(4) . ?
N4 C23 1.335(4) . ?
N4 C19 1.338(4) . ?
C7 N2 1.467(4) . ?
C7 C6 1.505(5) . ?
C7 H7A 0.9700 . ?
C7 H7B 0.9700 . ?
O3 C10 1.427(4) . ?
O3 H3 0.93(5) . ?
C19 C20 1.379(4) . ?
C19 C18 1.503(4) . ?
O11 H11A 0.8200 . ?
O11 H11B 0.84(5) . ?
C34 O9 1.257(4) . ?
C34 C33 1.514(4) . ?
O22 H22A 0.76(4) . ?
O22 H22B 0.87(5) . ?
C30 C31 1.382(5) . ?
C30 C29 1.383(4) . ?
C30 H30 0.9300 . ?
N6 C33 1.328(4) . ?
N6 C29 1.331(4) . ?
C22 C21 1.380(5) . ?
C22 C23 1.387(5) . ?
C22 H22 0.9300 . ?
C1 C2 1.520(4) . ?
O6 C18 1.252(4) . ?
C31 C32 1.384(5) . ?
C31 H31 0.9300 . ?
C3 C2 1.378(4) . ?
C3 C4 1.379(5) . ?
C3 H3A 0.9300 . ?
C33 C32 1.392(4) . ?
C23 C24 1.503(5) . ?
C28 C29 1.509(5) . ?
C28 H28A 0.9700 . ?
C28 H28B 0.9700 . ?
N2 C11 1.473(4) . ?
N2 C8 1.491(4) . ?
C16 C15 1.376(4) . ?
C16 C17 1.510(4) . ?
C12 C13 1.391(4) . ?
C12 C11 1.503(4) . ?
C15 C14 1.384(5) . ?
C15 H15 0.9300 . ?
C32 H32 0.9300 . ?
C11 H11C 0.9700 . ?
C11 H11D 0.9700 . ?
O5 C17 1.254(3) . ?
C21 C20 1.386(5) . ?
C21 H21 0.9300 . ?
C26 C25 1.533(4) . ?
C26 H26A 0.9600 . ?
C26 H26B 0.9600 . ?
C26 H26C 0.9600 . ?
C6 C5 1.391(5) . ?
C8 C10 1.521(5) . ?
C8 C9 1.532(5) . ?
C8 H8A 0.9800 . ?
C25 C27 1.510(4) . ?
C25 H25 0.9800 . ?
C20 H20 0.9300 . ?
C4 C5 1.382(5) . ?
C4 H4 0.9300 . ?
C14 C13 1.368(5) . ?
C14 H14 0.9300 . ?
C13 H13 0.9300 . ?
C5 H5 0.9300 . ?
C24 H24A 0.9700 . ?
C24 H24B 0.9700 . ?
C27 H27A 0.9700 . ?
C27 H27B 0.9700 . ?
C10 H10A 0.9700 . ?
C10 H10B 0.9700 . ?
C9 H9A 0.9600 . ?
C9 H9B 0.9600 . ?
C9 H9C 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N6 Mn2 O7 146.33(9) . . ?
N6 Mn2 O9 71.62(9) . . ?
O7 Mn2 O9 77.00(8) . . ?
N6 Mn2 N4 139.45(9) . . ?
O7 Mn2 N4 70.67(9) . . ?
O9 Mn2 N4 147.66(9) . . ?
N6 Mn2 O8 80.40(10) . . ?
O7 Mn2 O8 86.76(9) . . ?
O9 Mn2 O8 88.12(9) . . ?
N4 Mn2 O8 89.40(10) . . ?
N6 Mn2 Cl2 93.15(8) . . ?
O7 Mn2 Cl2 100.87(7) . . ?
O9 Mn2 Cl2 93.75(7) . . ?
N4 Mn2 Cl2 92.94(7) . . ?
O8 Mn2 Cl2 172.36(7) . . ?
N6 Mn2 N5 71.01(9) . . ?
O7 Mn2 N5 133.63(9) . . ?
O9 Mn2 N5 139.92(8) . . ?
N4 Mn2 N5 68.51(9) . . ?
O8 Mn2 N5 71.89(9) . . ?
Cl2 Mn2 N5 102.23(7) . . ?
N6 Mn2 Na2 109.19(7) . . ?
O7 Mn2 Na2 37.62(6) . . ?
O9 Mn2 Na2 40.06(6) . . ?
N4 Mn2 Na2 107.78(7) . . ?
O8 Mn2 Na2 81.15(7) . . ?
Cl2 Mn2 Na2 104.99(3) . . ?
N5 Mn2 Na2 152.70(7) . . ?
N3 Mn1 O2 148.45(9) . . ?
N3 Mn1 O4 72.01(8) . . ?
O2 Mn1 O4 77.64(8) . . ?
N3 Mn1 N1 137.57(9) . . ?
O2 Mn1 N1 70.79(8) . . ?
O4 Mn1 N1 147.87(9) . . ?
N3 Mn1 O3 87.23(9) . . ?
O2 Mn1 O3 83.30(9) . . ?
O4 Mn1 O3 88.15(9) . . ?
N1 Mn1 O3 82.50(10) . . ?
N3 Mn1 Cl1 94.12(8) . . ?
O2 Mn1 Cl1 96.32(8) . . ?
O4 Mn1 Cl1 93.77(7) . . ?
N1 Mn1 Cl1 95.44(7) . . ?
O3 Mn1 Cl1 177.92(7) . . ?
N3 Mn1 N2 68.47(8) . . ?
O2 Mn1 N2 135.40(9) . . ?
O4 Mn1 N2 136.58(8) . . ?
N1 Mn1 N2 69.15(9) . . ?
O3 Mn1 N2 72.88(9) . . ?
Cl1 Mn1 N2 106.14(7) . . ?
N3 Mn1 Na1 109.08(7) . . ?
O2 Mn1 Na1 39.38(6) . . ?
O4 Mn1 Na1 39.94(6) . . ?
N1 Mn1 Na1 107.96(7) . . ?
O3 Mn1 Na1 75.68(7) . . ?
Cl1 Mn1 Na1 105.32(4) . . ?
N2 Mn1 Na1 148.53(7) . . ?
O2 Na1 O10 136.07(9) . 1_655 ?
O2 Na1 O4 74.23(8) . . ?
O10 Na1 O4 89.72(9) 1_655 . ?
O2 Na1 O11 83.86(10) . . ?
O10 Na1 O11 99.83(11) 1_655 . ?
O4 Na1 O11 156.08(11) . . ?
O2 Na1 O6 106.79(10) . . ?
O10 Na1 O6 116.05(9) 1_655 . ?
O4 Na1 O6 98.65(10) . . ?
O11 Na1 O6 96.74(10) . . ?
O2 Na1 Mn1 37.79(6) . . ?
O10 Na1 Mn1 110.45(7) 1_655 . ?
O4 Na1 Mn1 38.01(6) . . ?
O11 Na1 Mn1 118.36(8) . . ?
O6 Na1 Mn1 114.25(8) . . ?
O2 Na1 Na2 56.32(6) . . ?
O10 Na1 Na2 158.26(7) 1_655 . ?
O4 Na1 Na2 111.98(7) . . ?
O11 Na1 Na2 60.72(8) . . ?
O6 Na1 Na2 61.31(6) . . ?
Mn1 Na1 Na2 88.71(3) . . ?
C34 O10 Na1 129.71(19) . 1_455 ?
C17 O4 Mn1 118.74(19) . . ?
C17 O4 Na1 133.4(2) . . ?
Mn1 O4 Na1 102.05(9) . . ?
O7 Na2 O5 131.30(9) . 1_455 ?
O7 Na2 O9 74.12(9) . . ?
O5 Na2 O9 89.64(9) 1_455 . ?
O7 Na2 O1 113.96(10) . . ?
O5 Na2 O1 113.69(9) 1_455 . ?
O9 Na2 O1 98.42(10) . . ?
O7 Na2 O12 83.51(10) . . ?
O5 Na2 O12 98.45(11) 1_455 . ?
O9 Na2 O12 155.77(10) . . ?
O1 Na2 O12 99.11(10) . . ?
O7 Na2 C1 111.40(9) . . ?
O5 Na2 C1 116.55(9) 1_455 . ?
O9 Na2 C1 118.96(10) . . ?
O1 Na2 C1 21.45(9) . . ?
O12 Na2 C1 77.66(10) . . ?
O7 Na2 Mn2 36.84(6) . . ?
O5 Na2 Mn2 110.27(7) 1_455 . ?
O9 Na2 Mn2 37.93(6) . . ?
O1 Na2 Mn2 115.52(9) . . ?
O12 Na2 Mn2 118.38(8) . . ?
C1 Na2 Mn2 127.31(8) . . ?
O7 Na2 Na1 59.91(6) . . ?
O5 Na2 Na1 159.34(7) 1_455 . ?
O9 Na2 Na1 110.96(6) . . ?
O1 Na2 Na1 63.23(6) . . ?
O12 Na2 Na1 63.39(8) . . ?
C1 Na2 Na1 52.59(7) . . ?
Mn2 Na2 Na1 88.14(3) . . ?
H21A O21 H21B 102(4) . . ?
C18 O7 Mn2 119.5(2) . . ?
C18 O7 Na2 135.0(2) . . ?
Mn2 O7 Na2 105.55(9) . . ?
C1 O1 Na2 114.3(2) . . ?
C28 N5 C24 111.5(3) . . ?
C28 N5 C25 115.5(3) . . ?
C24 N5 C25 110.4(3) . . ?
C28 N5 Mn2 105.32(19) . . ?
C24 N5 Mn2 105.53(18) . . ?
C25 N5 Mn2 107.93(18) . . ?
C27 O8 Mn2 116.11(19) . . ?
C27 O8 H8 102(3) . . ?
Mn2 O8 H8 109(3) . . ?
C12 N3 C16 119.3(3) . . ?
C12 N3 Mn1 123.4(2) . . ?
C16 N3 Mn1 117.30(19) . . ?
C1 O2 Mn1 120.3(2) . . ?
C1 O2 Na1 134.6(2) . . ?
Mn1 O2 Na1 102.83(9) . . ?
C2 N1 C6 119.3(3) . . ?
C2 N1 Mn1 118.0(2) . . ?
C6 N1 Mn1 122.5(2) . . ?
Na2 O12 H12A 109.5 . . ?
Na2 O12 H12B 129(3) . . ?
H12A O12 H12B 95.5 . . ?
C23 N4 C19 119.8(3) . . ?
C23 N4 Mn2 122.1(2) . . ?
C19 N4 Mn2 117.8(2) . . ?
N2 C7 C6 112.0(3) . . ?
N2 C7 H7A 109.2 . . ?
C6 C7 H7A 109.2 . . ?
N2 C7 H7B 109.2 . . ?
C6 C7 H7B 109.2 . . ?
H7A C7 H7B 107.9 . . ?
C10 O3 Mn1 115.63(19) . . ?
C10 O3 H3 112(3) . . ?
Mn1 O3 H3 119(3) . . ?
N4 C19 C20 122.0(3) . . ?
N4 C19 C18 113.7(3) . . ?
C20 C19 C18 124.3(3) . . ?
Na1 O11 H11A 109.5 . . ?
Na1 O11 H11B 130(4) . . ?
H11A O11 H11B 97.7 . . ?
O10 C34 O9 125.8(3) . . ?
O10 C34 C33 117.4(3) . . ?
O9 C34 C33 116.8(3) . . ?
C34 O9 Mn2 118.44(19) . . ?
C34 O9 Na2 133.3(2) . . ?
Mn2 O9 Na2 102.01(9) . . ?
H22A O22 H22B 106(4) . . ?
C31 C30 C29 118.8(3) . . ?
C31 C30 H30 120.6 . . ?
C29 C30 H30 120.6 . . ?
C33 N6 C29 119.8(3) . . ?
C33 N6 Mn2 118.0(2) . . ?
C29 N6 Mn2 121.8(2) . . ?
C21 C22 C23 118.9(3) . . ?
C21 C22 H22 120.6 . . ?
C23 C22 H22 120.6 . . ?
O2 C1 O1 125.0(3) . . ?
O2 C1 C2 116.6(3) . . ?
O1 C1 C2 118.4(3) . . ?
O2 C1 Na2 93.20(18) . . ?
O1 C1 Na2 44.29(16) . . ?
C2 C1 Na2 136.5(2) . . ?
C18 O6 Na1 114.6(2) . . ?
C30 C31 C32 119.3(3) . . ?
C30 C31 H31 120.3 . . ?
C32 C31 H31 120.3 . . ?
C2 C3 C4 118.1(3) . . ?
C2 C3 H3A 121.0 . . ?
C4 C3 H3A 121.0 . . ?
N6 C33 C32 122.0(3) . . ?
N6 C33 C34 115.1(3) . . ?
C32 C33 C34 122.9(3) . . ?
N4 C23 C22 121.4(3) . . ?
N4 C23 C24 114.8(3) . . ?
C22 C23 C24 123.8(3) . . ?
N5 C28 C29 112.0(3) . . ?
N5 C28 H28A 109.2 . . ?
C29 C28 H28A 109.2 . . ?
N5 C28 H28B 109.2 . . ?
C29 C28 H28B 109.2 . . ?
H28A C28 H28B 107.9 . . ?
C7 N2 C11 111.1(3) . . ?
C7 N2 C8 116.4(3) . . ?
C11 N2 C8 110.5(2) . . ?
C7 N2 Mn1 105.70(18) . . ?
C11 N2 Mn1 105.54(18) . . ?
C8 N2 Mn1 106.90(18) . . ?
N3 C16 C15 121.7(3) . . ?
N3 C16 C17 114.5(3) . . ?
C15 C16 C17 123.7(3) . . ?
N3 C12 C13 121.6(3) . . ?
N3 C12 C11 115.4(3) . . ?
C13 C12 C11 123.0(3) . . ?
C16 C15 C14 118.9(3) . . ?
C16 C15 H15 120.6 . . ?
C14 C15 H15 120.6 . . ?
C31 C32 C33 118.2(3) . . ?
C31 C32 H32 120.9 . . ?
C33 C32 H32 120.9 . . ?
N6 C29 C30 121.8(3) . . ?
N6 C29 C28 115.9(3) . . ?
C30 C29 C28 122.3(3) . . ?
O6 C18 O7 124.3(3) . . ?
O6 C18 C19 118.9(3) . . ?
O7 C18 C19 116.8(3) . . ?
N2 C11 C12 110.5(3) . . ?
N2 C11 H11C 109.5 . . ?
C12 C11 H11C 109.5 . . ?
N2 C11 H11D 109.5 . . ?
C12 C11 H11D 109.5 . . ?
H11C C11 H11D 108.1 . . ?
C17 O5 Na2 128.82(19) . 1_655 ?
C22 C21 C20 119.4(3) . . ?
C22 C21 H21 120.3 . . ?
C20 C21 H21 120.3 . . ?
C25 C26 H26A 109.5 . . ?
C25 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
C25 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
N1 C6 C5 121.5(3) . . ?
N1 C6 C7 115.3(3) . . ?
C5 C6 C7 123.1(3) . . ?
N2 C8 C10 112.9(2) . . ?
N2 C8 C9 114.5(3) . . ?
C10 C8 C9 110.7(3) . . ?
N2 C8 H8A 106.0 . . ?
C10 C8 H8A 106.0 . . ?
C9 C8 H8A 106.0 . . ?
N5 C25 C27 111.6(2) . . ?
N5 C25 C26 115.5(3) . . ?
C27 C25 C26 109.6(3) . . ?
N5 C25 H25 106.5 . . ?
C27 C25 H25 106.5 . . ?
C26 C25 H25 106.5 . . ?
C19 C20 C21 118.5(3) . . ?
C19 C20 H20 120.7 . . ?
C21 C20 H20 120.7 . . ?
C3 C4 C5 120.2(3) . . ?
C3 C4 H4 119.9 . . ?
C5 C4 H4 119.9 . . ?
C13 C14 C15 119.4(3) . . ?
C13 C14 H14 120.3 . . ?
C15 C14 H14 120.3 . . ?
O5 C17 O4 125.5(3) . . ?
O5 C17 C16 117.1(3) . . ?
O4 C17 C16 117.4(3) . . ?
C14 C13 C12 119.1(3) . . ?
C14 C13 H13 120.4 . . ?
C12 C13 H13 120.4 . . ?
N1 C2 C3 122.6(3) . . ?
N1 C2 C1 113.8(3) . . ?
C3 C2 C1 123.6(3) . . ?
C4 C5 C6 118.3(3) . . ?
C4 C5 H5 120.8 . . ?
C6 C5 H5 120.8 . . ?
N5 C24 C23 109.3(3) . . ?
N5 C24 H24A 109.8 . . ?
C23 C24 H24A 109.8 . . ?
N5 C24 H24B 109.8 . . ?
C23 C24 H24B 109.8 . . ?
H24A C24 H24B 108.3 . . ?
O8 C27 C25 109.3(2) . . ?
O8 C27 H27A 109.8 . . ?
C25 C27 H27A 109.8 . . ?
O8 C27 H27B 109.8 . . ?
C25 C27 H27B 109.8 . . ?
H27A C27 H27B 108.3 . . ?
O3 C10 C8 111.2(3) . . ?
O3 C10 H10A 109.4 . . ?
C8 C10 H10A 109.4 . . ?
O3 C10 H10B 109.4 . . ?
C8 C10 H10B 109.4 . . ?
H10A C10 H10B 108.0 . . ?
C8 C9 H9A 109.5 . . ?
C8 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
C8 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C23 N4 C19 C20 2.0(5) . . . . ?
Mn2 N4 C19 C20 -171.8(2) . . . . ?
C23 N4 C19 C18 179.8(3) . . . . ?
Mn2 N4 C19 C18 6.0(3) . . . . ?
Na1 O10 C34 O9 115.9(3) 1_455 . . . ?
Na1 O10 C34 C33 -63.6(4) 1_455 . . . ?
O10 C34 O9 Mn2 -177.1(3) . . . . ?
C33 C34 O9 Mn2 2.4(4) . . . . ?
O10 C34 O9 Na2 -30.4(5) . . . . ?
C33 C34 O9 Na2 149.1(2) . . . . ?
Mn1 O2 C1 O1 171.8(3) . . . . ?
Na1 O2 C1 O1 -28.6(5) . . . . ?
Mn1 O2 C1 C2 -8.6(4) . . . . ?
Na1 O2 C1 C2 151.0(2) . . . . ?
Mn1 O2 C1 Na2 138.54(16) . . . . ?
Na1 O2 C1 Na2 -61.9(3) . . . . ?
Na2 O1 C1 O2 -51.6(4) . . . . ?
Na2 O1 C1 C2 128.8(3) . . . . ?
C29 C30 C31 C32 0.8(6) . . . . ?
C29 N6 C33 C32 1.9(5) . . . . ?
Mn2 N6 C33 C32 174.0(3) . . . . ?
C29 N6 C33 C34 -175.5(3) . . . . ?
Mn2 N6 C33 C34 -3.3(4) . . . . ?
O10 C34 C33 N6 -179.9(3) . . . . ?
O9 C34 C33 N6 0.6(5) . . . . ?
O10 C34 C33 C32 2.8(5) . . . . ?
O9 C34 C33 C32 -176.7(3) . . . . ?
C19 N4 C23 C22 -0.7(5) . . . . ?
Mn2 N4 C23 C22 172.8(3) . . . . ?
C19 N4 C23 C24 -179.6(3) . . . . ?
Mn2 N4 C23 C24 -6.1(4) . . . . ?
C21 C22 C23 N4 -1.0(5) . . . . ?
C21 C22 C23 C24 177.8(3) . . . . ?
C24 N5 C28 C29 154.0(3) . . . . ?
C25 N5 C28 C29 -79.0(4) . . . . ?
Mn2 N5 C28 C29 40.0(3) . . . . ?
C6 C7 N2 C11 156.1(3) . . . . ?
C6 C7 N2 C8 -76.4(3) . . . . ?
C6 C7 N2 Mn1 42.1(3) . . . . ?
C12 N3 C16 C15 -1.1(5) . . . . ?
Mn1 N3 C16 C15 -179.1(3) . . . . ?
C12 N3 C16 C17 177.2(3) . . . . ?
Mn1 N3 C16 C17 -0.9(4) . . . . ?
C16 N3 C12 C13 0.2(5) . . . . ?
Mn1 N3 C12 C13 178.1(3) . . . . ?
C16 N3 C12 C11 179.1(3) . . . . ?
Mn1 N3 C12 C11 -3.0(4) . . . . ?
N3 C16 C15 C14 0.7(5) . . . . ?
C17 C16 C15 C14 -177.4(3) . . . . ?
C30 C31 C32 C33 0.8(6) . . . . ?
N6 C33 C32 C31 -2.2(6) . . . . ?
C34 C33 C32 C31 174.9(4) . . . . ?
C33 N6 C29 C30 -0.2(5) . . . . ?
Mn2 N6 C29 C30 -172.0(3) . . . . ?
C33 N6 C29 C28 -178.9(3) . . . . ?
Mn2 N6 C29 C28 9.3(4) . . . . ?
C31 C30 C29 N6 -1.1(6) . . . . ?
C31 C30 C29 C28 177.5(4) . . . . ?
N5 C28 C29 N6 -35.8(4) . . . . ?
N5 C28 C29 C30 145.5(3) . . . . ?
Na1 O6 C18 O7 59.4(4) . . . . ?
Na1 O6 C18 C19 -121.3(3) . . . . ?
Mn2 O7 C18 O6 -165.6(3) . . . . ?
Na2 O7 C18 O6 15.7(6) . . . . ?
Mn2 O7 C18 C19 15.0(4) . . . . ?
Na2 O7 C18 C19 -163.6(2) . . . . ?
N4 C19 C18 O6 166.9(3) . . . . ?
C20 C19 C18 O6 -15.4(5) . . . . ?
N4 C19 C18 O7 -13.7(4) . . . . ?
C20 C19 C18 O7 163.9(3) . . . . ?
C7 N2 C11 C12 -157.5(3) . . . . ?
C8 N2 C11 C12 71.8(3) . . . . ?
Mn1 N2 C11 C12 -43.4(3) . . . . ?
N3 C12 C11 N2 34.3(4) . . . . ?
C13 C12 C11 N2 -146.9(3) . . . . ?
C23 C22 C21 C20 1.4(6) . . . . ?
C2 N1 C6 C5 -2.2(5) . . . . ?
Mn1 N1 C6 C5 -176.2(3) . . . . ?
C2 N1 C6 C7 179.4(3) . . . . ?
Mn1 N1 C6 C7 5.4(4) . . . . ?
N2 C7 C6 N1 -34.7(4) . . . . ?
N2 C7 C6 C5 146.9(3) . . . . ?
C7 N2 C8 C10 85.8(3) . . . . ?
C11 N2 C8 C10 -146.4(3) . . . . ?
Mn1 N2 C8 C10 -32.0(3) . . . . ?
C7 N2 C8 C9 -42.1(4) . . . . ?
C11 N2 C8 C9 85.8(4) . . . . ?
Mn1 N2 C8 C9 -159.8(3) . . . . ?
C28 N5 C25 C27 79.5(3) . . . . ?
C24 N5 C25 C27 -152.9(3) . . . . ?
Mn2 N5 C25 C27 -38.0(3) . . . . ?
C28 N5 C25 C26 -46.5(4) . . . . ?
C24 N5 C25 C26 81.1(3) . . . . ?
Mn2 N5 C25 C26 -164.1(3) . . . . ?
N4 C19 C20 C21 -1.6(5) . . . . ?
C18 C19 C20 C21 -179.1(3) . . . . ?
C22 C21 C20 C19 -0.1(5) . . . . ?
C2 C3 C4 C5 -0.1(6) . . . . ?
C16 C15 C14 C13 0.6(6) . . . . ?
Na2 O5 C17 O4 -118.5(3) 1_655 . . . ?
Na2 O5 C17 C16 60.8(4) 1_655 . . . ?
Mn1 O4 C17 O5 178.1(3) . . . . ?
Na1 O4 C17 O5 30.1(5) . . . . ?
Mn1 O4 C17 C16 -1.2(4) . . . . ?
Na1 O4 C17 C16 -149.2(2) . . . . ?
N3 C16 C17 O5 -178.0(3) . . . . ?
C15 C16 C17 O5 0.3(5) . . . . ?
N3 C16 C17 O4 1.4(4) . . . . ?
C15 C16 C17 O4 179.6(3) . . . . ?
C15 C14 C13 C12 -1.5(6) . . . . ?
N3 C12 C13 C14 1.1(6) . . . . ?
C11 C12 C13 C14 -177.7(4) . . . . ?
C6 N1 C2 C3 0.3(5) . . . . ?
Mn1 N1 C2 C3 174.6(3) . . . . ?
C6 N1 C2 C1 -177.2(3) . . . . ?
Mn1 N1 C2 C1 -2.9(4) . . . . ?
C4 C3 C2 N1 0.9(6) . . . . ?
C4 C3 C2 C1 178.1(3) . . . . ?
O2 C1 C2 N1 7.5(4) . . . . ?
O1 C1 C2 N1 -172.9(3) . . . . ?
Na2 C1 C2 N1 -120.7(3) . . . . ?
O2 C1 C2 C3 -170.0(3) . . . . ?
O1 C1 C2 C3 9.7(5) . . . . ?
Na2 C1 C2 C3 61.9(5) . . . . ?
C3 C4 C5 C6 -1.7(6) . . . . ?
N1 C6 C5 C4 2.9(6) . . . . ?
C7 C6 C5 C4 -178.8(4) . . . . ?
C28 N5 C24 C23 -161.2(3) . . . . ?
C25 N5 C24 C23 69.0(3) . . . . ?
Mn2 N5 C24 C23 -47.4(3) . . . . ?
N4 C23 C24 N5 38.4(4) . . . . ?
C22 C23 C24 N5 -140.5(3) . . . . ?
Mn2 O8 C27 C25 -43.9(3) . . . . ?
N5 C25 C27 O8 54.9(3) . . . . ?
C26 C25 C27 O8 -175.9(3) . . . . ?
Mn1 O3 C10 C8 -44.8(3) . . . . ?
N2 C8 C10 O3 51.8(4) . . . . ?
C9 C8 C10 O3 -178.4(3) . . . . ?

_refine_diff_density_max         0.202
_refine_diff_density_min         -0.227
_refine_diff_density_rms         0.033



_exptl_crystal_recrystallization_method 'Vapour deposition'
