# Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C.
# This journal is © The Royal Society of Chemistry 2023

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_220826h2_autored
_database_code_depnum_ccdc_archive 'CCDC 2241221'
loop_
_audit_author_name
_audit_author_address
'wenchao lin'
;Guangxi University
China
;
_audit_update_record             
;
2023-02-11 deposited with the CCDC.	2023-03-23 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C26 H60 Cl6 N2 Sn'
_chemical_formula_weight         732.15

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sn Sn -0.6537 1.4246 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   9.8400(6)
_cell_length_b                   10.8858(7)
_cell_length_c                   18.0546(9)
_cell_angle_alpha                105.944(5)
_cell_angle_beta                 97.101(5)
_cell_angle_gamma                91.271(5)
_cell_volume                     1842.08(19)
_cell_formula_units_Z            2
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    ?
_cell_measurement_theta_min      ?
_cell_measurement_theta_max      ?

_exptl_crystal_description       ?
_exptl_crystal_colour            ?
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.320
_exptl_crystal_F_000             764
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          ?
_exptl_crystal_size_mid          ?
_exptl_crystal_size_min          ?
_exptl_absorpt_coefficient_mu    1.146
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  ?
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            11745
_diffrn_reflns_av_unetI/netI     0.0293
_diffrn_reflns_av_R_equivalents  0.0138
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_theta_min         2.089
_diffrn_reflns_theta_max         30.419
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.781
_diffrn_measured_fraction_theta_full 0.989
_diffrn_reflns_Laue_measured_fraction_max 0.781
_diffrn_reflns_Laue_measured_fraction_full 0.989
_diffrn_reflns_point_group_measured_fraction_max 0.781
_diffrn_reflns_point_group_measured_fraction_full 0.989
_reflns_number_total             8721
_reflns_number_gt                6444
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0636P)²+1.1812P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         8721
_refine_ls_number_parameters     362
_refine_ls_number_restraints     8
_refine_ls_R_factor_all          0.0726
_refine_ls_R_factor_gt           0.0500
_refine_ls_wR_factor_ref         0.1298
_refine_ls_wR_factor_gt          0.1184
_refine_ls_goodness_of_fit_ref   1.020
_refine_ls_restrained_S_all      1.024
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Sn1 Sn 0.25401(2) 0.34119(2) 0.71408(2) 0.05077(10) Uani 1 1 d . . . . .
Cl1 Cl 0.07218(10) 0.46459(11) 0.66959(7) 0.0707(3) Uani 1 1 d . . . . .
Cl2 Cl 0.22670(16) 0.19298(13) 0.58466(8) 0.0948(4) Uani 1 1 d . . . . .
Cl3 Cl 0.08398(12) 0.21085(12) 0.74931(9) 0.0886(4) Uani 1 1 d . . . . .
Cl4 Cl 0.42316(11) 0.46791(12) 0.67596(8) 0.0823(3) Uani 1 1 d . . . . .
Cl5 Cl 0.27426(14) 0.49161(13) 0.84221(7) 0.0883(4) Uani 1 1 d . . . . .
Cl6 Cl 0.43328(11) 0.21910(12) 0.75801(8) 0.0824(3) Uani 1 1 d . . . . .
N1 N 0.7969(3) 0.4815(4) 0.8480(2) 0.0734(10) Uani 1 1 d . . . . .
C2 C 0.9703(8) 0.7815(7) 0.8192(5) 0.141(3) Uani 1 1 d . . . . .
H2A H 0.992497 0.823442 0.874409 0.169 Uiso 1 1 calc R U . . .
H2B H 1.051801 0.742141 0.800682 0.169 Uiso 1 1 calc R U . . .
C3 C 0.6188(12) 0.8155(9) 1.0469(7) 0.214(5) Uani 1 1 d . . . . .
H3A H 0.627208 0.879000 1.019586 0.321 Uiso 1 1 calc R U . . .
H3B H 0.704538 0.812582 1.077968 0.321 Uiso 1 1 calc R U . . .
H3C H 0.548435 0.837064 1.079826 0.321 Uiso 1 1 calc R U . . .
C5 C 0.9312(11) 0.8747(10) 0.7793(6) 0.191(4) Uani 1 1 d . . . . .
H5A H 0.926689 0.836985 0.724280 0.286 Uiso 1 1 calc R U . . .
H5B H 0.997657 0.946017 0.795660 0.286 Uiso 1 1 calc R U . . .
H5C H 0.842845 0.903662 0.791177 0.286 Uiso 1 1 calc R U . . .
C7 C 0.8627(9) 0.2104(7) 0.9472(5) 0.144(3) Uani 1 1 d . . . . .
H7A H 0.936598 0.174794 0.918661 0.173 Uiso 1 1 calc R U . . .
H7B H 0.903961 0.267309 0.996697 0.173 Uiso 1 1 calc R U . . .
C9 C 0.7021(7) 0.6273(8) 0.9627(4) 0.145(3) Uani 1 1 d . . . . .
H9A H 0.738105 0.578858 0.997764 0.174 Uiso 1 1 calc R U . . .
H9B H 0.773245 0.690449 0.962770 0.174 Uiso 1 1 calc R U . . .
C10 C 0.9028(5) 0.5820(5) 0.8475(3) 0.0887(15) Uani 1 1 d . . . . .
H10A H 0.937864 0.626983 0.900958 0.106 Uiso 1 1 calc R U . . .
H10B H 0.978557 0.539630 0.823526 0.106 Uiso 1 1 calc R U . . .
C14 C 0.7527(5) 0.4026(5) 0.7655(3) 0.0871(15) Uani 1 1 d . . . . .
H14A H 0.710322 0.455907 0.735886 0.131 Uiso 1 1 calc R U . . .
H14B H 0.688200 0.334816 0.765004 0.131 Uiso 1 1 calc R U . . .
H14C H 0.831330 0.366725 0.742871 0.131 Uiso 1 1 calc R U . . .
C18 C 0.8680(5) 0.3979(5) 0.8936(3) 0.0873(15) Uani 1 1 d . . . . .
H18A H 0.945786 0.362983 0.868371 0.105 Uiso 1 1 calc R U . . .
H18B H 0.903738 0.451564 0.945080 0.105 Uiso 1 1 calc R U . . .
C19 C 0.7832(11) 0.1043(9) 0.9623(6) 0.186(4) Uani 1 1 d . . . . .
H19A H 0.727070 0.057229 0.915286 0.279 Uiso 1 1 calc R U . . .
H19B H 0.725829 0.138904 1.001483 0.279 Uiso 1 1 calc R U . . .
H19C H 0.845253 0.048332 0.979985 0.279 Uiso 1 1 calc R U . . .
C20 C 0.6706(5) 0.5380(5) 0.8822(3) 0.0854(14) Uani 1 1 d . . . . .
H20A H 0.624202 0.583821 0.848302 0.103 Uiso 1 1 calc R U . . .
H20B H 0.608130 0.468580 0.883402 0.103 Uiso 1 1 calc R U . . .
C21 C 0.5838(9) 0.6941(8) 0.9925(5) 0.158(3) Uani 1 1 d . . . . .
H21A H 0.521738 0.705324 0.949025 0.190 Uiso 1 1 calc R U . . .
H21B H 0.535286 0.640841 1.016979 0.190 Uiso 1 1 calc R U . . .
C22 C 0.8560(6) 0.6787(6) 0.8064(4) 0.1069(19) Uani 1 1 d . . . . .
H22A H 0.775093 0.717115 0.826329 0.128 Uiso 1 1 calc R U . . .
H22B H 0.832250 0.637361 0.751245 0.128 Uiso 1 1 calc R U . . .
C24 C 0.7804(7) 0.2880(6) 0.9024(4) 0.1068(18) Uani 1 1 d . . . . .
H24A H 0.703864 0.321432 0.929317 0.128 Uiso 1 1 calc R U . . .
H24B H 0.743571 0.233330 0.851364 0.128 Uiso 1 1 calc R U . . .
N2 N 0.2080(4) 0.7859(4) 0.5640(2) 0.0754(10) Uani 1 1 d . . . . .
C1 C 0.2776(4) 0.5651(4) 0.4916(3) 0.0710(11) Uani 1 1 d . . . . .
H1A H 0.320844 0.596586 0.454341 0.085 Uiso 1 1 calc R U . . .
H1B H 0.346628 0.567122 0.535216 0.085 Uiso 1 1 calc R U . . .
C4 C 0.1636(4) 0.6501(4) 0.5194(3) 0.0717(11) Uani 1 1 d . . . . .
H4A H 0.098776 0.651190 0.474556 0.086 Uiso 1 1 calc R U . . .
H4B H 0.115399 0.612039 0.552156 0.086 Uiso 1 1 calc R U . . .
C6 C 0.2236(6) 0.8576(5) 0.4440(3) 0.0940(16) Uani 1 1 d . . . . .
H6A H 0.144040 0.908649 0.450465 0.113 Uiso 1 1 calc R U . . .
H6B H 0.194128 0.772820 0.410393 0.113 Uiso 1 1 calc R U . . .
C8 C 0.2206(5) 0.4307(5) 0.4543(3) 0.0835(13) Uani 1 1 d . . . . .
H8A H 0.150879 0.429592 0.411154 0.100 Uiso 1 1 calc R U . . .
H8B H 0.177232 0.400003 0.491814 0.100 Uiso 1 1 calc R U . . .
C11 C 0.3163(14) 0.8943(10) 0.7012(6) 0.114(4) Uani 0.601(12) 1 d D . P A 1
H11A H 0.235740 0.944294 0.704162 0.137 Uiso 0.601(12) 1 calc R U P A 1
H11B H 0.388473 0.941209 0.686440 0.137 Uiso 0.601(12) 1 calc R U P A 1
C12 C 0.2914(5) 0.8499(5) 0.5200(3) 0.0841(14) Uani 1 1 d . . . . .
H12A H 0.318788 0.936148 0.552060 0.101 Uiso 1 1 calc R U . . .
H12B H 0.374370 0.804434 0.511745 0.101 Uiso 1 1 calc R U . . .
C13 C 0.2828(10) 0.7639(8) 0.6412(5) 0.068(2) Uani 0.601(12) 1 d . . P A 1
H13A H 0.223996 0.710886 0.660736 0.081 Uiso 0.601(12) 1 calc R U P A 1
H13B H 0.366595 0.720649 0.631172 0.081 Uiso 0.601(12) 1 calc R U P A 1
C15 C 0.3343(8) 0.9227(7) 0.4083(4) 0.125(2) Uani 1 1 d . . . . .
H15A H 0.377731 0.997717 0.447318 0.151 Uiso 1 1 calc R U . . .
H15B H 0.404610 0.863329 0.393039 0.151 Uiso 1 1 calc R U . . .
C16 C 0.0810(5) 0.8578(6) 0.5811(3) 0.0959(16) Uani 1 1 d . . . . .
H16A H 0.023367 0.852576 0.533269 0.144 Uiso 1 1 calc R U . . .
H16B H 0.106856 0.945934 0.607824 0.144 Uiso 1 1 calc R U . . .
H16C H 0.031843 0.820754 0.613234 0.144 Uiso 1 1 calc R U . . .
C17 C 0.2741(9) 0.9586(7) 0.3432(5) 0.142(3) Uani 1 1 d . . . . .
H17A H 0.229570 0.884691 0.304949 0.212 Uiso 1 1 calc R U . . .
H17B H 0.343859 0.995079 0.321516 0.212 Uiso 1 1 calc R U . . .
H17C H 0.207840 1.020724 0.358766 0.212 Uiso 1 1 calc R U . . .
C23 C 0.5067(15) 0.847(2) 0.7874(11) 0.193(9) Uani 0.601(12) 1 d D . P A 1
H23A H 0.519512 0.764106 0.753488 0.289 Uiso 0.601(12) 1 calc R U P A 1
H23B H 0.539931 0.848934 0.840067 0.289 Uiso 0.601(12) 1 calc R U P A 1
H23C H 0.556501 0.911316 0.772844 0.289 Uiso 0.601(12) 1 calc R U P A 1
C25 C 0.3639(16) 0.8704(15) 0.7812(7) 0.127(5) Uani 0.601(12) 1 d D . P A 1
H25A H 0.348104 0.944547 0.822775 0.153 Uiso 0.601(12) 1 calc R U P A 1
H25B H 0.311314 0.797317 0.786177 0.153 Uiso 0.601(12) 1 calc R U P A 1
C26 C 0.3312(6) 0.3410(5) 0.4249(4) 0.1032(17) Uani 1 1 d . . . . .
H26A H 0.372731 0.369685 0.386710 0.155 Uiso 1 1 calc R U . . .
H26B H 0.290586 0.255878 0.401790 0.155 Uiso 1 1 calc R U . . .
H26C H 0.399821 0.340887 0.467535 0.155 Uiso 1 1 calc R U . . .
C25A C 0.383(3) 0.832(2) 0.8291(13) 0.164(11) Uani 0.399(12) 1 d D . P A 2
H25C H 0.285196 0.813625 0.817564 0.245 Uiso 0.399(12) 1 calc R U P A 2
H25D H 0.402027 0.908641 0.871539 0.245 Uiso 0.399(12) 1 calc R U P A 2
H25E H 0.425640 0.762108 0.843212 0.245 Uiso 0.399(12) 1 calc R U P A 2
C23A C 0.435(2) 0.851(2) 0.7615(9) 0.119(8) Uani 0.399(12) 1 d D . P A 2
H23D H 0.509756 0.796810 0.746546 0.143 Uiso 0.399(12) 1 calc R U P A 2
H23E H 0.462161 0.939587 0.767522 0.143 Uiso 0.399(12) 1 calc R U P A 2
C11A C 0.2958(19) 0.804(2) 0.7045(10) 0.134(9) Uani 0.399(12) 1 d D . P A 2
H11C H 0.277490 0.712553 0.693847 0.160 Uiso 0.399(12) 1 calc R U P A 2
H11D H 0.218959 0.848074 0.726187 0.160 Uiso 0.399(12) 1 calc R U P A 2
C13A C 0.3209(15) 0.8372(17) 0.6357(8) 0.093(5) Uani 0.399(12) 1 d D . P A 2
H13C H 0.407755 0.804501 0.621470 0.112 Uiso 0.399(12) 1 calc R U P A 2
H13D H 0.330057 0.929713 0.647669 0.112 Uiso 0.399(12) 1 calc R U P A 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Sn1 Cl6 2.4175(10) . ?
Sn1 Cl4 2.4187(11) . ?
Sn1 Cl5 2.4214(12) . ?
Sn1 Cl3 2.4229(11) . ?
Sn1 Cl2 2.4269(12) . ?
Sn1 Cl1 2.4485(10) . ?
N1 C10 1.496(6) . ?
N1 C14 1.506(5) . ?
N1 C18 1.515(6) . ?
N1 C20 1.523(6) . ?
C2 C5 1.431(11) . ?
C2 C22 1.520(9) . ?
C2 H2A 0.9700 . ?
C2 H2B 0.9700 . ?
C3 C21 1.419(11) . ?
C3 H3A 0.9600 . ?
C3 H3B 0.9600 . ?
C3 H3C 0.9600 . ?
C5 H5A 0.9600 . ?
C5 H5B 0.9600 . ?
C5 H5C 0.9600 . ?
C7 C19 1.485(11) . ?
C7 C24 1.506(9) . ?
C7 H7A 0.9700 . ?
C7 H7B 0.9700 . ?
C9 C21 1.466(9) . ?
C9 C20 1.501(8) . ?
C9 H9A 0.9700 . ?
C9 H9B 0.9700 . ?
C10 C22 1.496(8) . ?
C10 H10A 0.9700 . ?
C10 H10B 0.9700 . ?
C14 H14A 0.9600 . ?
C14 H14B 0.9600 . ?
C14 H14C 0.9600 . ?
C18 C24 1.514(8) . ?
C18 H18A 0.9700 . ?
C18 H18B 0.9700 . ?
C19 H19A 0.9600 . ?
C19 H19B 0.9600 . ?
C19 H19C 0.9600 . ?
C20 H20A 0.9700 . ?
C20 H20B 0.9700 . ?
C21 H21A 0.9700 . ?
C21 H21B 0.9700 . ?
C22 H22A 0.9700 . ?
C22 H22B 0.9700 . ?
C24 H24A 0.9700 . ?
C24 H24B 0.9700 . ?
N2 C12 1.493(6) . ?
N2 C4 1.502(6) . ?
N2 C16 1.509(6) . ?
N2 C13A 1.563(14) . ?
N2 C13 1.575(8) . ?
C1 C8 1.496(6) . ?
C1 C4 1.516(6) . ?
C1 H1A 0.9700 . ?
C1 H1B 0.9700 . ?
C4 H4A 0.9700 . ?
C4 H4B 0.9700 . ?
C6 C12 1.474(7) . ?
C6 C15 1.580(9) . ?
C6 H6A 0.9700 . ?
C6 H6B 0.9700 . ?
C8 C26 1.525(7) . ?
C8 H8A 0.9700 . ?
C8 H8B 0.9700 . ?
C11 C13 1.531(13) . ?
C11 C25 1.555(11) . ?
C11 H11A 0.9700 . ?
C11 H11B 0.9700 . ?
C12 H12A 0.9700 . ?
C12 H12B 0.9700 . ?
C13 H13A 0.9700 . ?
C13 H13B 0.9700 . ?
C15 C17 1.405(10) . ?
C15 H15A 0.9700 . ?
C15 H15B 0.9700 . ?
C16 H16A 0.9600 . ?
C16 H16B 0.9600 . ?
C16 H16C 0.9600 . ?
C17 H17A 0.9600 . ?
C17 H17B 0.9600 . ?
C17 H17C 0.9600 . ?
C23 C25 1.430(12) . ?
C23 H23A 0.9600 . ?
C23 H23B 0.9600 . ?
C23 H23C 0.9600 . ?
C25 H25A 0.9700 . ?
C25 H25B 0.9700 . ?
C26 H26A 0.9600 . ?
C26 H26B 0.9600 . ?
C26 H26C 0.9600 . ?
C25A C23A 1.443(17) . ?
C25A H25C 0.9600 . ?
C25A H25D 0.9600 . ?
C25A H25E 0.9600 . ?
C23A C11A 1.590(17) . ?
C23A H23D 0.9700 . ?
C23A H23E 0.9700 . ?
C11A C13A 1.432(17) . ?
C11A H11C 0.9700 . ?
C11A H11D 0.9700 . ?
C13A H13C 0.9700 . ?
C13A H13D 0.9700 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Cl6 Sn1 Cl4 90.13(4) . . ?
Cl6 Sn1 Cl5 90.83(5) . . ?
Cl4 Sn1 Cl5 90.92(5) . . ?
Cl6 Sn1 Cl3 89.89(4) . . ?
Cl4 Sn1 Cl3 178.69(5) . . ?
Cl5 Sn1 Cl3 90.39(5) . . ?
Cl6 Sn1 Cl2 90.91(5) . . ?
Cl4 Sn1 Cl2 89.60(5) . . ?
Cl5 Sn1 Cl2 178.18(5) . . ?
Cl3 Sn1 Cl2 89.09(5) . . ?
Cl6 Sn1 Cl1 179.91(4) . . ?
Cl4 Sn1 Cl1 89.96(4) . . ?
Cl5 Sn1 Cl1 89.20(4) . . ?
Cl3 Sn1 Cl1 90.03(4) . . ?
Cl2 Sn1 Cl1 89.06(5) . . ?
C10 N1 C14 108.4(4) . . ?
C10 N1 C18 106.0(4) . . ?
C14 N1 C18 109.2(4) . . ?
C10 N1 C20 112.7(4) . . ?
C14 N1 C20 108.4(3) . . ?
C18 N1 C20 112.1(4) . . ?
C5 C2 C22 111.2(8) . . ?
C5 C2 H2A 109.4 . . ?
C22 C2 H2A 109.4 . . ?
C5 C2 H2B 109.4 . . ?
C22 C2 H2B 109.4 . . ?
H2A C2 H2B 108.0 . . ?
C21 C3 H3A 109.5 . . ?
C21 C3 H3B 109.5 . . ?
H3A C3 H3B 109.5 . . ?
C21 C3 H3C 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
C2 C5 H5A 109.5 . . ?
C2 C5 H5B 109.5 . . ?
H5A C5 H5B 109.5 . . ?
C2 C5 H5C 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
C19 C7 C24 114.8(7) . . ?
C19 C7 H7A 108.6 . . ?
C24 C7 H7A 108.6 . . ?
C19 C7 H7B 108.6 . . ?
C24 C7 H7B 108.6 . . ?
H7A C7 H7B 107.5 . . ?
C21 C9 C20 114.2(6) . . ?
C21 C9 H9A 108.7 . . ?
C20 C9 H9A 108.7 . . ?
C21 C9 H9B 108.7 . . ?
C20 C9 H9B 108.7 . . ?
H9A C9 H9B 107.6 . . ?
C22 C10 N1 116.1(4) . . ?
C22 C10 H10A 108.3 . . ?
N1 C10 H10A 108.3 . . ?
C22 C10 H10B 108.3 . . ?
N1 C10 H10B 108.3 . . ?
H10A C10 H10B 107.4 . . ?
N1 C14 H14A 109.5 . . ?
N1 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
N1 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C24 C18 N1 115.9(4) . . ?
C24 C18 H18A 108.3 . . ?
N1 C18 H18A 108.3 . . ?
C24 C18 H18B 108.3 . . ?
N1 C18 H18B 108.3 . . ?
H18A C18 H18B 107.4 . . ?
C7 C19 H19A 109.5 . . ?
C7 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
C7 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C9 C20 N1 113.8(4) . . ?
C9 C20 H20A 108.8 . . ?
N1 C20 H20A 108.8 . . ?
C9 C20 H20B 108.8 . . ?
N1 C20 H20B 108.8 . . ?
H20A C20 H20B 107.7 . . ?
C3 C21 C9 113.9(8) . . ?
C3 C21 H21A 108.8 . . ?
C9 C21 H21A 108.8 . . ?
C3 C21 H21B 108.8 . . ?
C9 C21 H21B 108.8 . . ?
H21A C21 H21B 107.7 . . ?
C10 C22 C2 109.3(6) . . ?
C10 C22 H22A 109.8 . . ?
C2 C22 H22A 109.8 . . ?
C10 C22 H22B 109.8 . . ?
C2 C22 H22B 109.8 . . ?
H22A C22 H22B 108.3 . . ?
C7 C24 C18 111.0(5) . . ?
C7 C24 H24A 109.4 . . ?
C18 C24 H24A 109.4 . . ?
C7 C24 H24B 109.4 . . ?
C18 C24 H24B 109.4 . . ?
H24A C24 H24B 108.0 . . ?
C12 N2 C4 112.2(3) . . ?
C12 N2 C16 109.8(4) . . ?
C4 N2 C16 108.0(4) . . ?
C12 N2 C13A 87.7(7) . . ?
C4 N2 C13A 129.1(7) . . ?
C16 N2 C13A 107.8(7) . . ?
C12 N2 C13 117.0(5) . . ?
C4 N2 C13 99.9(4) . . ?
C16 N2 C13 109.3(5) . . ?
C8 C1 C4 110.0(4) . . ?
C8 C1 H1A 109.7 . . ?
C4 C1 H1A 109.7 . . ?
C8 C1 H1B 109.7 . . ?
C4 C1 H1B 109.7 . . ?
H1A C1 H1B 108.2 . . ?
N2 C4 C1 115.7(4) . . ?
N2 C4 H4A 108.4 . . ?
C1 C4 H4A 108.4 . . ?
N2 C4 H4B 108.4 . . ?
C1 C4 H4B 108.4 . . ?
H4A C4 H4B 107.4 . . ?
C12 C6 C15 105.9(5) . . ?
C12 C6 H6A 110.6 . . ?
C15 C6 H6A 110.6 . . ?
C12 C6 H6B 110.6 . . ?
C15 C6 H6B 110.6 . . ?
H6A C6 H6B 108.7 . . ?
C1 C8 C26 112.1(4) . . ?
C1 C8 H8A 109.2 . . ?
C26 C8 H8A 109.2 . . ?
C1 C8 H8B 109.2 . . ?
C26 C8 H8B 109.2 . . ?
H8A C8 H8B 107.9 . . ?
C13 C11 C25 107.8(10) . . ?
C13 C11 H11A 110.1 . . ?
C25 C11 H11A 110.1 . . ?
C13 C11 H11B 110.1 . . ?
C25 C11 H11B 110.1 . . ?
H11A C11 H11B 108.5 . . ?
C6 C12 N2 116.0(4) . . ?
C6 C12 H12A 108.3 . . ?
N2 C12 H12A 108.3 . . ?
C6 C12 H12B 108.3 . . ?
N2 C12 H12B 108.3 . . ?
H12A C12 H12B 107.4 . . ?
C11 C13 N2 108.5(7) . . ?
C11 C13 H13A 110.0 . . ?
N2 C13 H13A 110.0 . . ?
C11 C13 H13B 110.0 . . ?
N2 C13 H13B 110.0 . . ?
H13A C13 H13B 108.4 . . ?
C17 C15 C6 111.1(7) . . ?
C17 C15 H15A 109.4 . . ?
C6 C15 H15A 109.4 . . ?
C17 C15 H15B 109.4 . . ?
C6 C15 H15B 109.4 . . ?
H15A C15 H15B 108.0 . . ?
N2 C16 H16A 109.5 . . ?
N2 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
N2 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C15 C17 H17A 109.5 . . ?
C15 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C15 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C25 C23 H23A 109.5 . . ?
C25 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
C25 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C23 C25 C11 109.7(13) . . ?
C23 C25 H25A 109.7 . . ?
C11 C25 H25A 109.7 . . ?
C23 C25 H25B 109.7 . . ?
C11 C25 H25B 109.7 . . ?
H25A C25 H25B 108.2 . . ?
C8 C26 H26A 109.5 . . ?
C8 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
C8 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
C23A C25A H25C 109.5 . . ?
C23A C25A H25D 109.5 . . ?
H25C C25A H25D 109.5 . . ?
C23A C25A H25E 109.5 . . ?
H25C C25A H25E 109.5 . . ?
H25D C25A H25E 109.5 . . ?
C25A C23A C11A 95.1(18) . . ?
C25A C23A H23D 112.7 . . ?
C11A C23A H23D 112.7 . . ?
C25A C23A H23E 112.7 . . ?
C11A C23A H23E 112.7 . . ?
H23D C23A H23E 110.2 . . ?
C13A C11A C23A 103.2(15) . . ?
C13A C11A H11C 111.1 . . ?
C23A C11A H11C 111.1 . . ?
C13A C11A H11D 111.1 . . ?
C23A C11A H11D 111.1 . . ?
H11C C11A H11D 109.1 . . ?
C11A C13A N2 115.2(15) . . ?
C11A C13A H13C 108.5 . . ?
N2 C13A H13C 108.5 . . ?
C11A C13A H13D 108.5 . . ?
N2 C13A H13D 108.5 . . ?
H13C C13A H13D 107.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C14 N1 C10 C22 63.8(6) . . . . ?
C18 N1 C10 C22 -179.1(4) . . . . ?
C20 N1 C10 C22 -56.2(6) . . . . ?
C10 N1 C18 C24 179.8(5) . . . . ?
C14 N1 C18 C24 -63.5(6) . . . . ?
C20 N1 C18 C24 56.6(6) . . . . ?
C21 C9 C20 N1 173.0(7) . . . . ?
C10 N1 C20 C9 -55.6(7) . . . . ?
C14 N1 C20 C9 -175.6(6) . . . . ?
C18 N1 C20 C9 63.8(7) . . . . ?
C20 C9 C21 C3 -151.4(9) . . . . ?
N1 C10 C22 C2 173.6(5) . . . . ?
C5 C2 C22 C10 178.6(7) . . . . ?
C19 C7 C24 C18 177.0(7) . . . . ?
N1 C18 C24 C7 178.9(5) . . . . ?
C12 N2 C4 C1 54.4(5) . . . . ?
C16 N2 C4 C1 175.6(4) . . . . ?
C13A N2 C4 C1 -51.6(9) . . . . ?
C13 N2 C4 C1 -70.2(5) . . . . ?
C8 C1 C4 N2 175.2(4) . . . . ?
C4 C1 C8 C26 179.8(4) . . . . ?
C15 C6 C12 N2 -177.5(4) . . . . ?
C4 N2 C12 C6 59.5(5) . . . . ?
C16 N2 C12 C6 -60.7(5) . . . . ?
C13A N2 C12 C6 -168.8(7) . . . . ?
C13 N2 C12 C6 174.0(5) . . . . ?
C25 C11 C13 N2 169.2(9) . . . . ?
C12 N2 C13 C11 68.1(9) . . . . ?
C4 N2 C13 C11 -170.7(8) . . . . ?
C16 N2 C13 C11 -57.5(10) . . . . ?
C12 C6 C15 C17 -168.1(6) . . . . ?
C13 C11 C25 C23 83.9(16) . . . . ?
C25A C23A C11A C13A 170.2(19) . . . . ?
C23A C11A C13A N2 172.1(13) . . . . ?
C12 N2 C13A C11A 179.6(16) . . . . ?
C4 N2 C13A C11A -63.4(17) . . . . ?
C16 N2 C13A C11A 69.5(17) . . . . ?

_refine_diff_density_max         0.629
_refine_diff_density_min         -0.966
_refine_diff_density_rms         0.072



