# Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C.
# This journal is © The Royal Society of Chemistry 2023

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_eu-mof
_database_code_depnum_ccdc_archive 'CCDC 2292095'
loop_
_audit_author_name
_audit_author_address
'Jingwen Hu'
;College of Chemistry and Chemical Engineering, Henan Polytechnic University
China
;
_audit_update_record             
;
2023-08-31 deposited with the CCDC.	2023-09-26 downloaded from the CCDC.
;
_audit_creation_date             2023-06-10
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2017/1
_chemical_name_common            ?
_chemical_name_systematic        HPU-99
_chemical_formula_moiety         'C63 H39 Eu4 N O29, 1.75(C3 H7 N O), 3(H2 O)'
_chemical_formula_sum            'C68.25 H57.25 Eu4 N2.75 O33.75'
_chemical_formula_weight         2063.75
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0137 0.0067 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -2.6997 10.5010 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0241 0.0134 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0389 0.0241 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/n 1'
_space_group_name_Hall           '-P 2yn'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   13.6608(10)
_cell_length_b                   43.285(3)
_cell_length_c                   13.8948(11)
_cell_angle_alpha                90
_cell_angle_beta                 105.598(2)
_cell_angle_gamma                90
_cell_volume                     7913.4(10)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9122
_cell_measurement_temperature    152.00
_cell_measurement_theta_max      72.27
_cell_measurement_theta_min      2.66
_shelx_estimated_absorpt_T_max   0.284
_shelx_estimated_absorpt_T_min   0.134
_exptl_absorpt_coefficient_mu    16.796
_exptl_absorpt_correction_T_max  0.7536
_exptl_absorpt_correction_T_min  0.4693
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1292 before and 0.0967 after correction.
The Ratio of minimum to maximum transmission is 0.6227.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.732
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       needle
_exptl_crystal_F_000             4032
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.1
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0671
_diffrn_reflns_av_unetI/netI     0.0429
_diffrn_reflns_Laue_measured_fraction_full 0.995
_diffrn_reflns_Laue_measured_fraction_max 0.837
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       54
_diffrn_reflns_limit_k_min       -56
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            109310
_diffrn_reflns_point_group_measured_fraction_full 0.995
_diffrn_reflns_point_group_measured_fraction_max 0.837
_diffrn_reflns_theta_full        53.594
_diffrn_reflns_theta_max         72.470
_diffrn_reflns_theta_min         3.007
_diffrn_ambient_temperature      152.0
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.837
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           GaK\a
_diffrn_radiation_wavelength     1.34138
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                18866
_reflns_number_total             19930
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.40B (?, 2016)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.40B (?, 2016)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_refine_diff_density_max         3.418
_refine_diff_density_min         -2.589
_refine_diff_density_rms         0.186
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.055
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1101
_refine_ls_number_reflns         19930
_refine_ls_number_restraints     255
_refine_ls_R_factor_all          0.0495
_refine_ls_R_factor_gt           0.0471
_refine_ls_restrained_S_all      1.061
_refine_ls_shift/su_max          0.005
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0513P)²+65.0564P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1233
_refine_ls_wR_factor_ref         0.1247
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups, All O(H,H) groups
2. Restrained distances
 C73-N4
 1.47 with sigma of 0.02
 N4-C67
 1.3 with sigma of 0.02
 C3-C0AA
 1.5 with sigma of 0.02
 C67-C73
 2.5 with sigma of 0.04
 H25A-O33
 1.8 with sigma of 0.04
 H33B-O30
 1.8 with sigma of 0.04
 H32A-O29
 1.8 with sigma of 0.04
 H32B-O8_$1
 1.8 with sigma of 0.04
 H34B_$2-O31_$2
 2 with sigma of 0.04
 Eu4-H26A \\sim Eu4-H26B
 with sigma of 0.02
 Eu1-H28A \\sim Eu1-H28B
 with sigma of 0.02
3. Rigid bond restraints
 C6, C5, C1, C2, C3, C4, C0AA, C9, C10, C9A
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.01
4. Uiso/Uaniso restraints and constraints
O29 \\sim C61 \\sim N2 \\sim H61 \\sim C62 \\sim C63 \\sim H62A \\sim H62B
\\sim H62C \\sim H63A \\sim H63B \\sim H63C: within 2A with sigma of 0.04 and
sigma for terminal atoms of 0.08
Uanis(C10) \\sim Ueq, Uanis(C9) \\sim Ueq: with sigma of 0.01 and sigma for
terminal atoms of 0.02
Uanis(N4) \\sim Ueq, Uanis(C73) \\sim Ueq, Uanis(C68) \\sim Ueq, Uanis(C63)
\\sim Ueq, Uanis(O23) \\sim Ueq, Uanis(C61) \\sim Ueq, Uanis(N2) \\sim Ueq:
with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(O30) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(O2) \\sim Ueq, Uanis(O23) \\sim Ueq: with sigma of 0.01 and sigma for
terminal atoms of 0.02
Uanis(O23) \\sim Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.002
Uanis(O29) \\sim Ueq, Uanis(C61) \\sim Ueq, Uanis(N2) \\sim Ueq: with sigma of
0.01 and sigma for terminal atoms of 0.02
Uanis(C10) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(C0AA) \\sim Ueq, Uanis(C9A) \\sim Ueq, Uanis(C10) \\sim Ueq, Uanis(C9)
\\sim Ueq, Uanis(C3) \\sim Ueq, Uanis(C4) \\sim Ueq, Uanis(C2) \\sim Ueq,
Uanis(C1) \\sim Ueq, Uanis(C5) \\sim Ueq, Uanis(C6) \\sim Ueq: with sigma of
0.1 and sigma for terminal atoms of 0.2
Uanis(C3) \\sim Ueq, Uanis(C2) \\sim Ueq, Uanis(C4) \\sim Ueq, Uanis(C5) \\sim
Ueq, Uanis(C6) \\sim Ueq, Uanis(C1) \\sim Ueq, Uanis(C9) \\sim Ueq, Uanis(C0AA)
\\sim Ueq, Uanis(C9A) \\sim Ueq, Uanis(C10) \\sim Ueq: with sigma of 0.1 and
sigma for terminal atoms of 0.2
Uanis(C9A) \\sim Ueq, Uanis(C0AA) \\sim Ueq, Uanis(C3) \\sim Ueq, Uanis(C4)
\\sim Ueq, Uanis(C2) \\sim Ueq, Uanis(C9) \\sim Ueq, Uanis(C10) \\sim Ueq: with
sigma of 0.001 and sigma for terminal atoms of 0.002
5. Others
 Sof(H22A)=Sof(H24A)=Sof(C72)=Sof(C74)=Sof(C75)=Sof(H75)=1-FVAR(1)
 Sof(H22)=Sof(H24)=Sof(C23)=Sof(C29)=Sof(C30)=Sof(H30)=FVAR(1)
 Fixed Sof: C9(0.6) C10(0.6) H10(0.6) O29(0.75) N2(0.75) C61(0.75) H61(0.75)
 C62(0.75) H62A(0.75) H62B(0.75) H62C(0.75) C63(0.75) H63A(0.75) H63B(0.75)
 H63C(0.75) O30(0.5) N4(0.5) C67(0.5) H67(0.5) C68(0.5) H68A(0.5) H68B(0.5)
 H68C(0.5) C73(0.5) H73A(0.5) H73B(0.5) H73C(0.5) O31(0.5) N3(0.5) C64(0.5)
 H64(0.5) C65(0.5) H65A(0.5) H65B(0.5) H65C(0.5) C66(0.5) H66A(0.5) H66B(0.5)
 H66C(0.5) C9A(0.4) H9A(0.4) C0AA(0.4)
6.a Riding coordinates:
 O32(H32A,H32B), O34(H34A,H34B)
6.b Free rotating group:
 O26(H26A,H26B), O28(H28A,H28B), O33(H33A,H33B)
6.c Rotating group:
 O25(H25A,H25B), O27(H27A,H27B)
6.d Aromatic/amide H refined with riding coordinates:
 C2(H2), C4(H4), C6(H6), C12(H12), C14(H14), C16(H16), C22(H22), C22(H22A),
 C24(H24), C24(H24A), C26(H26), C32(H32), C34(H34), C36(H36), C42(H42),
 C44(H44), C46(H46), C52(H52), C54(H54), C56(H56), C69(H69), C61(H61), C67(H67),
  C64(H64)
6.e Idealised Me refined as rotating group:
 C70(H70A,H70B,H70C), C71(H71A,H71B,H71C), C62(H62A,H62B,H62C), C63(H63A,H63B,
 H63C), C68(H68A,H68B,H68C), C73(H73A,H73B,H73C), C65(H65A,H65B,H65C), C66(H66A,
 H66B,H66C)
6.f :
 C10(H10), C20(H20), C40(H40), C50(H50), C60(H60), C30(H30), C75(H75), C9A(H9A)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 1.00207(2) 0.66911(2) 0.82907(2) 0.01468(6) Uani 1 1 d D . . . .
Eu2 Eu 0.71687(2) 0.65323(2) 0.62059(2) 0.01812(6) Uani 1 1 d . . . . .
Eu3 Eu 0.46317(2) 0.57783(2) 0.64012(2) 0.01538(6) Uani 1 1 d . . . . .
Eu4 Eu 0.29693(2) 0.56021(2) 0.81265(2) 0.01712(6) Uani 1 1 d D . . . .
O1 O 0.4791(3) 0.62966(9) 0.6697(3) 0.0304(9) Uani 1 1 d . . . . .
O2 O 0.5686(5) 0.67001(14) 0.6516(7) 0.077(2) Uani 1 1 d . U . . .
O3 O 0.1660(3) 0.65969(8) 0.7945(3) 0.0210(7) Uani 1 1 d . . . . .
O4 O 0.0771(3) 0.69858(9) 0.7144(3) 0.0256(8) Uani 1 1 d . . . . .
O5 O 0.7818(3) 0.70273(8) 0.6458(3) 0.0232(8) Uani 1 1 d . . . . .
O6 O 0.8966(3) 0.71262(8) 0.7904(3) 0.0242(8) Uani 1 1 d . . . . .
O7 O 0.6017(3) 0.78971(9) 0.4343(3) 0.0272(8) Uani 1 1 d . . . . .
O8 O 0.6144(3) 0.83618(9) 0.5001(3) 0.0265(8) Uani 1 1 d D . . . .
O9 O 0.6355(3) 0.56762(11) 0.6968(3) 0.0313(9) Uani 1 1 d . . . . .
O10 O 0.7469(3) 0.60255(10) 0.6778(3) 0.0319(9) Uani 1 1 d . . . . .
O11 O 1.1129(3) 0.57356(8) 0.7627(3) 0.0221(8) Uani 1 1 d . . . . .
O12 O 1.1535(3) 0.52481(9) 0.7528(4) 0.0297(9) Uani 1 1 d . . . . .
O13 O 0.8284(3) 0.65081(10) 0.5175(3) 0.0230(8) Uani 1 1 d . . . . .
O14 O 0.9308(3) 0.64566(9) 0.6696(3) 0.0204(7) Uani 1 1 d . . . . .
O15 O 1.2781(3) 0.59503(9) 0.6700(3) 0.0204(7) Uani 1 1 d . . . . .
O16 O 1.3111(3) 0.59141(13) 0.5233(3) 0.0379(11) Uani 1 1 d . . . . .
O17 O 0.5096(3) 0.58619(8) 0.4939(3) 0.0193(7) Uani 1 1 d . . . . .
O18 O 0.6314(3) 0.61975(8) 0.4889(3) 0.0203(7) Uani 1 1 d . . . . .
O19 O 0.5374(3) 0.47670(9) 0.4018(4) 0.0288(9) Uani 1 1 d . . . . .
O20 O 0.6558(3) 0.46347(9) 0.3310(3) 0.0249(8) Uani 1 1 d . . . . .
O21 O 0.4759(3) 0.57852(9) 0.8094(3) 0.0229(8) Uani 1 1 d . . . . .
O22 O 0.4502(3) 0.57279(10) 0.9570(3) 0.0269(8) Uani 1 1 d . . . . .
O23 O 0.7793(5) 0.65229(15) 0.7963(5) 0.0601(16) Uani 1 1 d . U . . .
O24 O 0.8919(4) 0.65735(10) 0.9365(4) 0.0389(11) Uani 1 1 d . . . . .
O25 O 0.6253(4) 0.68249(10) 0.4722(4) 0.0426(12) Uani 1 1 d . . . . .
H25A H 0.652662 0.702012 0.469958 0.064 Uiso 1 1 d DGR . . . .
H25B H 0.559112 0.687076 0.473107 0.064 Uiso 1 1 d GR . . . .
O26 O 0.2941(3) 0.61274(9) 0.8715(3) 0.0229(8) Uani 1 1 d . . . . .
H26A H 0.257450 0.628109 0.841456 0.034 Uiso 1 1 d DG . . . .
H26B H 0.326821 0.620101 0.929493 0.034 Uiso 1 1 d DG . . . .
O27 O 0.2413(3) 0.55303(11) 0.9630(3) 0.0322(9) Uani 1 1 d . . . . .
H27A H 0.180036 0.545440 0.947144 0.048 Uiso 1 1 d GR . . . .
H27B H 0.235292 0.571007 0.989226 0.048 Uiso 1 1 d GR . . . .
O28 O 1.0272(3) 0.61481(9) 0.8656(3) 0.0260(8) Uani 1 1 d . . . . .
H28A H 0.990242 0.603627 0.894341 0.039 Uiso 1 1 d DG . . . .
H28B H 1.050454 0.601738 0.829499 0.039 Uiso 1 1 d DG . . . .
O35 O 0.3732(4) 0.51179(11) 0.8689(4) 0.0386(11) Uani 1 1 d . . . . .
N1 N 0.4955(4) 0.47931(14) 0.8431(4) 0.0364(12) Uani 1 1 d . . . . .
C1 C 0.4013(6) 0.67877(14) 0.6558(6) 0.0363(15) Uani 1 1 d . U . . .
C2 C 0.3970(6) 0.70624(19) 0.6050(6) 0.0472(16) Uani 1 1 d . U . . .
H2 H 0.451130 0.711849 0.577628 0.057 Uiso 1 1 calc R . . . .
C3 C 0.3139(7) 0.72589(19) 0.5934(6) 0.0490(17) Uani 1 1 d D U . . .
C4 C 0.2361(6) 0.71754(18) 0.6365(6) 0.0416(15) Uani 1 1 d . U . . .
H4 H 0.179364 0.730859 0.629659 0.050 Uiso 1 1 calc R . . . .
C5 C 0.2407(5) 0.69025(13) 0.6887(5) 0.0288(12) Uani 1 1 d . U . . .
C6 C 0.3228(5) 0.67055(13) 0.6969(5) 0.0266(12) Uani 1 1 d . U . . .
H6 H 0.325281 0.651356 0.730608 0.032 Uiso 1 1 calc R . . . .
C7 C 0.4892(6) 0.65784(15) 0.6602(6) 0.0383(16) Uani 1 1 d . . . . .
C8 C 0.1561(5) 0.68233(12) 0.7346(4) 0.0234(11) Uani 1 1 d . . . . .
C9 C 0.3233(11) 0.7545(3) 0.5490(11) 0.042(2) Uani 0.6 1 d . U P A 1
C10 C 0.3264(12) 0.7762(4) 0.4998(12) 0.052(3) Uani 0.6 1 d . U P A 1
H10 H 0.328955 0.793886 0.459840 0.062 Uiso 0.6 1 calc R . P A 1
C11 C 0.8030(4) 0.75438(11) 0.7016(4) 0.0201(10) Uani 1 1 d . . . . .
C12 C 0.8464(4) 0.77549(12) 0.7774(4) 0.0213(10) Uani 1 1 d . . . . .
H12 H 0.894008 0.768612 0.836744 0.026 Uiso 1 1 calc R . . . .
C13 C 0.8195(4) 0.80668(12) 0.7658(4) 0.0219(10) Uani 1 1 d . . . . .
C14 C 0.7502(4) 0.81666(12) 0.6775(4) 0.0209(10) Uani 1 1 d . . . . .
H14 H 0.731183 0.837819 0.669907 0.025 Uiso 1 1 calc R . . . .
C15 C 0.7092(4) 0.79599(12) 0.6013(4) 0.0200(10) Uani 1 1 d . . . . .
C16 C 0.7347(4) 0.76472(12) 0.6134(4) 0.0215(10) Uani 1 1 d . . . . .
H16 H 0.705631 0.750447 0.561706 0.026 Uiso 1 1 calc R . . . .
C17 C 0.8298(4) 0.72070(12) 0.7146(4) 0.0203(10) Uani 1 1 d . . . . .
C18 C 0.6378(4) 0.80791(12) 0.5064(4) 0.0200(10) Uani 1 1 d . . . . .
C19 C 0.8635(4) 0.82950(12) 0.8408(4) 0.0243(11) Uani 1 1 d . . . . .
C20 C 0.8957(5) 0.85037(14) 0.8966(5) 0.0312(13) Uani 1 1 d . . . . .
H20 H 0.921218 0.866964 0.941007 0.037 Uiso 1 1 calc R . . . .
C21 C 0.8021(4) 0.55097(14) 0.7035(4) 0.0220(10) Uani 1 1 d . . . . .
C22 C 0.7750(5) 0.52000(15) 0.7043(5) 0.0355(15) Uani 1 1 d . . . . .
H22 H 0.705288 0.514298 0.688112 0.043 Uiso 0.61(2) 1 calc R . P B 1
H22A H 0.711501 0.513981 0.714165 0.043 Uiso 0.39(2) 1 calc R . P B 2
C24 C 0.9511(5) 0.50545(15) 0.7288(7) 0.0427(18) Uani 1 1 d . . . . .
H24 H 1.001108 0.490219 0.728520 0.051 Uiso 0.61(2) 1 calc R . P B 1
H24A H 0.999471 0.489468 0.751515 0.051 Uiso 0.39(2) 1 calc R . P B 2
C25 C 0.9773(4) 0.53638(13) 0.7277(4) 0.0228(10) Uani 1 1 d . . . . .
C26 C 0.9024(4) 0.55922(13) 0.7142(4) 0.0212(10) Uani 1 1 d . . . . .
H26 H 0.920375 0.580372 0.712431 0.025 Uiso 1 1 calc R . . . .
C27 C 0.7224(4) 0.57536(14) 0.6923(4) 0.0236(11) Uani 1 1 d . . . . .
C28 C 1.0863(4) 0.54541(13) 0.7480(4) 0.0220(10) Uani 1 1 d . . . . .
C31 C 0.9973(4) 0.63854(12) 0.5267(4) 0.0170(9) Uani 1 1 d . . . . .
C32 C 1.0871(4) 0.62411(12) 0.5777(4) 0.0171(9) Uani 1 1 d . . . . .
H32 H 1.099482 0.619347 0.646724 0.020 Uiso 1 1 calc R . . . .
C33 C 1.1585(4) 0.61672(13) 0.5266(4) 0.0210(10) Uani 1 1 d . . . . .
C34 C 1.1417(4) 0.62412(15) 0.4261(4) 0.0274(12) Uani 1 1 d . . . . .
H34 H 1.191776 0.619258 0.392445 0.033 Uiso 1 1 calc R . . . .
C35 C 1.0526(4) 0.63849(15) 0.3747(4) 0.0264(12) Uani 1 1 d . . . . .
C36 C 0.9795(4) 0.64554(13) 0.4248(4) 0.0226(10) Uani 1 1 d . . . . .
H36 H 0.917496 0.655087 0.389794 0.027 Uiso 1 1 calc R . . . .
C37 C 0.9152(4) 0.64563(11) 0.5750(4) 0.0166(9) Uani 1 1 d . . . . .
C38 C 1.2542(4) 0.60000(13) 0.5771(4) 0.0231(11) Uani 1 1 d . . . . .
C39 C 1.0334(5) 0.64559(17) 0.2692(4) 0.0318(13) Uani 1 1 d . . . . .
C40 C 1.0181(5) 0.6509(2) 0.1829(5) 0.0425(17) Uani 1 1 d . . . . .
H40 H 1.005798 0.655093 0.113596 0.051 Uiso 1 1 calc R . . . .
C41 C 0.6551(4) 0.56697(12) 0.4522(4) 0.0182(9) Uani 1 1 d . . . . .
C42 C 0.7557(4) 0.57175(13) 0.4506(4) 0.0241(11) Uani 1 1 d . . . . .
H42 H 0.784918 0.591769 0.462830 0.029 Uiso 1 1 calc R . . . .
C43 C 0.8136(4) 0.54694(14) 0.4310(5) 0.0273(12) Uani 1 1 d . . . . .
C44 C 0.7681(4) 0.51813(13) 0.4052(4) 0.0253(11) Uani 1 1 d . . . . .
H44 H 0.805537 0.501693 0.386825 0.030 Uiso 1 1 calc R . . . .
C45 C 0.6671(4) 0.51363(12) 0.4066(4) 0.0197(10) Uani 1 1 d . . . . .
C46 C 0.6120(4) 0.53779(12) 0.4328(4) 0.0187(9) Uani 1 1 d . . . . .
H46 H 0.544775 0.534291 0.437472 0.022 Uiso 1 1 calc R . . . .
C47 C 0.5944(4) 0.59299(11) 0.4801(3) 0.0157(9) Uani 1 1 d . . . . .
C48 C 0.6178(4) 0.48323(11) 0.3787(4) 0.0198(10) Uani 1 1 d . . . . .
C49 C 0.9206(5) 0.55086(15) 0.4372(6) 0.0372(15) Uani 1 1 d . . . . .
C50 C 1.0081(6) 0.5530(2) 0.4413(7) 0.054(2) Uani 1 1 d . . . . .
H50 H 1.078290 0.554727 0.444586 0.065 Uiso 1 1 calc R . . . .
C51 C 0.5908(4) 0.60427(13) 0.9495(4) 0.0220(10) Uani 1 1 d . . . . .
C52 C 0.6518(4) 0.61767(13) 0.8942(4) 0.0235(11) Uani 1 1 d . . . . .
H52 H 0.637767 0.613987 0.824372 0.028 Uiso 1 1 calc R . . . .
C53 C 0.7334(4) 0.63646(13) 0.9424(4) 0.0231(11) Uani 1 1 d . . . . .
C54 C 0.7509(4) 0.64306(14) 1.0437(4) 0.0246(11) Uani 1 1 d . . . . .
H54 H 0.805734 0.656178 1.075712 0.030 Uiso 1 1 calc R . . . .
C55 C 0.6882(4) 0.63050(16) 1.0989(4) 0.0270(12) Uani 1 1 d . . . . .
C56 C 0.6087(4) 0.61082(14) 1.0501(4) 0.0241(11) Uani 1 1 d . . . . .
H56 H 0.566427 0.601854 1.086860 0.029 Uiso 1 1 calc R . . . .
C57 C 0.5020(4) 0.58370(12) 0.9040(4) 0.0199(10) Uani 1 1 d . . . . .
C58 C 0.8052(6) 0.64991(14) 0.8876(5) 0.0314(14) Uani 1 1 d . . . . .
C59 C 0.7036(5) 0.63705(18) 1.2036(5) 0.0353(15) Uani 1 1 d . . . . .
C60 C 0.7104(5) 0.6422(2) 1.2885(5) 0.0429(17) Uani 1 1 d . . . . .
H60 H 0.715842 0.646405 1.356911 0.051 Uiso 1 1 calc R . . . .
C69 C 0.4017(6) 0.48622(17) 0.8409(5) 0.0402(16) Uani 1 1 d . . . . .
H69 H 0.351112 0.470954 0.816492 0.048 Uiso 1 1 calc R . . . .
C70 C 0.5780(6) 0.5017(2) 0.8781(7) 0.057(2) Uani 1 1 d . . . . .
H70A H 0.601482 0.508958 0.821229 0.085 Uiso 1 1 calc GR . . . .
H70B H 0.634513 0.491867 0.927184 0.085 Uiso 1 1 calc GR . . . .
H70C H 0.553159 0.519329 0.909091 0.085 Uiso 1 1 calc GR . . . .
C71 C 0.5251(7) 0.4496(2) 0.8109(6) 0.053(2) Uani 1 1 d . . . . .
H71A H 0.464567 0.436661 0.786271 0.079 Uiso 1 1 calc GR . . . .
H71B H 0.572360 0.439262 0.867497 0.079 Uiso 1 1 calc GR . . . .
H71C H 0.558288 0.452727 0.757343 0.079 Uiso 1 1 calc GR . . . .
C23 C 0.8547(13) 0.4959(4) 0.7303(11) 0.024(3) Uani 0.61(2) 1 d . . P B 1
C29 C 0.8332(9) 0.4642(2) 0.7436(11) 0.031(3) Uani 0.61(2) 1 d . . P B 1
C30 C 0.8155(11) 0.4379(3) 0.7605(12) 0.050(4) Uani 0.61(2) 1 d . . P B 1
H30 H 0.801522 0.417075 0.773855 0.060 Uiso 0.61(2) 1 calc R . P B 1
C72 C 0.840(2) 0.4997(6) 0.691(2) 0.032(5) Uani 0.39(2) 1 d . . P B 2
C74 C 0.7995(15) 0.4681(5) 0.673(2) 0.047(6) Uani 0.39(2) 1 d . . P B 2
C75 C 0.7605(18) 0.4443(5) 0.660(3) 0.076(11) Uani 0.39(2) 1 d . . P B 2
H75 H 0.728499 0.424633 0.648311 0.092 Uiso 0.39(2) 1 calc R . P B 2
O29 O 0.3884(4) 0.63705(16) 1.0597(4) 0.0361(14) Uani 0.75 1 d D U P . .
N2 N 0.4764(8) 0.6818(2) 1.0670(7) 0.051(2) Uani 0.75 1 d . U P . .
C61 C 0.4442(6) 0.6583(2) 1.1053(7) 0.037(2) Uani 0.75 1 d . U P . .
H61 H 0.464797 0.656875 1.176149 0.045 Uiso 0.75 1 calc R U P . .
C62 C 0.5427(10) 0.7050(3) 1.1294(9) 0.061(3) Uani 0.75 1 d . U P . .
H62A H 0.510490 0.725408 1.116642 0.091 Uiso 0.75 1 calc GR U P . .
H62B H 0.608195 0.705501 1.113159 0.091 Uiso 0.75 1 calc GR U P . .
H62C H 0.553652 0.699719 1.200096 0.091 Uiso 0.75 1 calc GR U P . .
C63 C 0.4493(15) 0.6855(4) 0.9599(10) 0.088(5) Uani 0.75 1 d . U P . .
H63A H 0.426458 0.665699 0.927674 0.133 Uiso 0.75 1 calc GR U P . .
H63B H 0.508582 0.692778 0.939322 0.133 Uiso 0.75 1 calc GR U P . .
H63C H 0.394321 0.700735 0.939837 0.133 Uiso 0.75 1 calc GR U P . .
O30 O 0.7919(15) 0.7201(4) 0.2813(11) 0.083(5) Uani 0.5 1 d D U P . .
N4 N 0.9404(13) 0.7227(4) 0.3736(12) 0.072(4) Uani 0.5 1 d D U P . .
C67 C 0.8773(14) 0.7219(4) 0.2898(12) 0.057(5) Uani 0.5 1 d D . P . .
H67 H 0.900982 0.722678 0.231558 0.069 Uiso 0.5 1 calc R . P . .
C68 C 0.9158(19) 0.7235(4) 0.4669(17) 0.072(6) Uani 0.5 1 d . U P . .
H68A H 0.978216 0.725973 0.521147 0.108 Uiso 0.5 1 calc GR . P . .
H68B H 0.882303 0.704114 0.476307 0.108 Uiso 0.5 1 calc GR . P . .
H68C H 0.870067 0.740856 0.467506 0.108 Uiso 0.5 1 calc GR . P . .
C73 C 1.0453(15) 0.7255(5) 0.3771(19) 0.085(7) Uani 0.5 1 d D U P . .
H73A H 1.080679 0.706238 0.402177 0.128 Uiso 0.5 1 calc GR . P . .
H73B H 1.075394 0.742560 0.421706 0.128 Uiso 0.5 1 calc GR . P . .
H73C H 1.051923 0.729700 0.309829 0.128 Uiso 0.5 1 calc GR . P . .
O31 O 0.9219(9) 0.57714(19) 0.9603(7) 0.042(3) Uani 0.5 1 d D . P . .
N3 N 0.8567(8) 0.5624(2) 1.0847(8) 0.028(2) Uani 0.5 1 d . . P . .
C64 C 0.9134(12) 0.5800(3) 1.0433(13) 0.043(3) Uani 0.5 1 d . . P . .
H64 H 0.950497 0.596222 1.082792 0.051 Uiso 0.5 1 calc R . P . .
C65 C 0.7953(12) 0.5391(3) 1.0306(12) 0.043(3) Uani 0.5 1 d . . P . .
H65A H 0.825388 0.518940 1.053134 0.064 Uiso 0.5 1 calc GR . P . .
H65B H 0.790088 0.541663 0.959320 0.064 Uiso 0.5 1 calc GR . P . .
H65C H 0.727457 0.540389 1.041414 0.064 Uiso 0.5 1 calc GR . P . .
C66 C 0.8540(13) 0.5683(4) 1.1856(11) 0.045(4) Uani 0.5 1 d . . P . .
H66A H 0.786230 0.575640 1.185854 0.068 Uiso 0.5 1 calc GR . P . .
H66B H 0.904594 0.584121 1.215101 0.068 Uiso 0.5 1 calc GR . P . .
H66C H 0.869512 0.549241 1.224686 0.068 Uiso 0.5 1 calc GR . P . .
O32 O 0.2202(6) 0.60601(16) 1.0725(5) 0.072(2) Uani 1 1 d . . . . .
H32A H 0.279407 0.612183 1.067971 0.108 Uiso 1 1 d DR . . . .
H32B H 0.177997 0.619943 1.040371 0.108 Uiso 1 1 d DR . . . .
O33 O 0.6435(7) 0.73105(13) 0.3667(4) 0.067(2) Uani 1 1 d D . . . .
H33A H 0.623501 0.750154 0.365497 0.100 Uiso 1 1 d G . . . .
H33B H 0.679864 0.730447 0.324160 0.100 Uiso 1 1 d DG . . . .
O34 O 1.0671(9) 0.5270(3) 0.9889(11) 0.160(6) Uani 1 1 d . . . . .
H34A H 1.063113 0.511493 1.027825 0.240 Uiso 1 1 d R . . . .
H34B H 1.028883 0.541193 1.004175 0.240 Uiso 1 1 d DR . . . .
C9A C 0.2769(18) 0.7728(5) 0.4554(18) 0.054(4) Uani 0.4 1 d . U P A 2
H9A H 0.270537 0.789209 0.408857 0.065 Uiso 0.4 1 calc R . P A 2
C0AA C 0.2852(16) 0.7515(4) 0.5156(14) 0.042(3) Uani 0.4 1 d D U P A 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O3 2.447(4) 1_655 ?
Eu1 O4 2.468(4) 1_655 ?
Eu1 O6 2.344(4) . ?
Eu1 O7 2.469(4) 4_676 ?
Eu1 O8 2.468(4) 4_676 ?
Eu1 O14 2.393(4) . ?
Eu1 O23 3.042(7) . ?
Eu1 O24 2.441(5) . ?
Eu1 O28 2.410(4) . ?
Eu1 C8 2.821(6) 1_655 ?
Eu1 C18 2.836(5) 4_676 ?
Eu1 C58 3.124(6) . ?
Eu2 O2 2.299(6) . ?
Eu2 O5 2.310(4) . ?
Eu2 O10 2.332(4) . ?
Eu2 O13 2.358(4) . ?
Eu2 O14 2.835(4) . ?
Eu2 O18 2.380(3) . ?
Eu2 O23 2.360(7) . ?
Eu2 O25 2.457(5) . ?
Eu2 C37 2.962(5) . ?
Eu3 Eu4 3.7964(4) . ?
Eu3 O1 2.281(4) . ?
Eu3 O9 2.315(4) . ?
Eu3 O15 2.772(4) 1_455 ?
Eu3 O16 2.342(4) 1_455 ?
Eu3 O17 2.313(4) . ?
Eu3 O19 2.431(4) 3_666 ?
Eu3 O20 2.519(4) 3_666 ?
Eu3 O21 2.312(4) . ?
Eu3 C38 2.915(5) 1_455 ?
Eu3 C48 2.850(5) 3_666 ?
Eu4 O11 2.490(4) 1_455 ?
Eu4 O12 2.450(4) 1_455 ?
Eu4 O15 2.448(4) 1_455 ?
Eu4 O20 2.479(4) 3_666 ?
Eu4 O21 2.581(4) . ?
Eu4 O22 2.538(4) . ?
Eu4 O26 2.421(4) . ?
Eu4 O27 2.428(4) . ?
Eu4 O35 2.377(4) . ?
Eu4 C28 2.847(6) 1_455 ?
Eu4 C57 2.929(5) . ?
O1 C7 1.239(8) . ?
O2 C7 1.240(9) . ?
O3 C8 1.270(6) . ?
O4 C8 1.255(7) . ?
O5 C17 1.269(6) . ?
O6 C17 1.245(7) . ?
O7 C18 1.266(6) . ?
O8 C18 1.262(7) . ?
O9 C27 1.252(7) . ?
O10 C27 1.254(7) . ?
O11 C28 1.272(7) . ?
O12 C28 1.269(6) . ?
O13 C37 1.259(6) . ?
O14 C37 1.274(6) . ?
O15 C38 1.262(7) . ?
O16 C38 1.270(7) . ?
O17 C47 1.259(6) . ?
O18 C47 1.257(6) . ?
O19 C48 1.256(6) . ?
O20 C48 1.275(6) . ?
O21 C57 1.285(6) . ?
O22 C57 1.244(7) . ?
O23 C58 1.227(9) . ?
O24 C58 1.239(9) . ?
O25 H25A 0.9278 . ?
O25 H25B 0.9288 . ?
O26 H26A 0.8688 . ?
O26 H26B 0.8699 . ?
O27 H27A 0.8708 . ?
O27 H27B 0.8724 . ?
O28 H28A 0.8703 . ?
O28 H28B 0.8705 . ?
O35 C69 1.269(9) . ?
N1 C69 1.308(9) . ?
N1 C70 1.468(11) . ?
N1 C71 1.456(10) . ?
C1 C2 1.376(10) . ?
C1 C6 1.390(8) . ?
C1 C7 1.492(9) . ?
C2 H2 0.9500 . ?
C2 C3 1.392(12) . ?
C3 C4 1.401(11) . ?
C3 C9 1.406(16) . ?
C3 C0AA 1.526(15) . ?
C4 H4 0.9500 . ?
C4 C5 1.379(9) . ?
C5 C6 1.389(8) . ?
C5 C8 1.502(8) . ?
C6 H6 0.9500 . ?
C9 C10 1.17(2) . ?
C10 H10 0.9500 . ?
C11 C12 1.400(7) . ?
C11 C16 1.399(7) . ?
C11 C17 1.502(7) . ?
C12 H12 0.9500 . ?
C12 C13 1.397(7) . ?
C13 C14 1.400(7) . ?
C13 C19 1.445(7) . ?
C14 H14 0.9500 . ?
C14 C15 1.385(7) . ?
C15 C16 1.396(7) . ?
C15 C18 1.505(7) . ?
C16 H16 0.9500 . ?
C19 C20 1.195(8) . ?
C20 H20 0.9500 . ?
C21 C22 1.392(8) . ?
C21 C26 1.386(7) . ?
C21 C27 1.494(8) . ?
C22 H22 0.9500 . ?
C22 H22A 0.9500 . ?
C22 C23 1.480(18) . ?
C22 C72 1.30(3) . ?
C24 H24 0.9500 . ?
C24 H24A 0.9500 . ?
C24 C25 1.387(8) . ?
C24 C23 1.385(18) . ?
C24 C72 1.49(3) . ?
C25 C26 1.398(8) . ?
C25 C28 1.491(8) . ?
C26 H26 0.9500 . ?
C31 C32 1.389(7) . ?
C31 C36 1.403(7) . ?
C31 C37 1.487(7) . ?
C32 H32 0.9500 . ?
C32 C33 1.390(7) . ?
C33 C34 1.391(7) . ?
C33 C38 1.493(7) . ?
C34 H34 0.9500 . ?
C34 C35 1.382(8) . ?
C35 C36 1.395(7) . ?
C35 C39 1.451(7) . ?
C36 H36 0.9500 . ?
C39 C40 1.183(9) . ?
C40 H40 0.9500 . ?
C41 C42 1.396(7) . ?
C41 C46 1.389(7) . ?
C41 C47 1.508(7) . ?
C42 H42 0.9500 . ?
C42 C43 1.404(8) . ?
C43 C44 1.396(8) . ?
C43 C49 1.451(8) . ?
C44 H44 0.9500 . ?
C44 C45 1.399(7) . ?
C45 C46 1.393(7) . ?
C45 C48 1.482(7) . ?
C46 H46 0.9500 . ?
C49 C50 1.185(10) . ?
C50 H50 0.9500 . ?
C51 C52 1.403(8) . ?
C51 C56 1.382(7) . ?
C51 C57 1.500(7) . ?
C52 H52 0.9500 . ?
C52 C53 1.397(8) . ?
C53 C54 1.392(7) . ?
C53 C58 1.511(7) . ?
C54 H54 0.9500 . ?
C54 C55 1.403(8) . ?
C55 C56 1.404(8) . ?
C55 C59 1.442(8) . ?
C56 H56 0.9500 . ?
C59 C60 1.180(9) . ?
C60 H60 0.9500 . ?
C69 H69 0.9500 . ?
C70 H70A 0.9800 . ?
C70 H70B 0.9800 . ?
C70 H70C 0.9800 . ?
C71 H71A 0.9800 . ?
C71 H71B 0.9800 . ?
C71 H71C 0.9800 . ?
C23 C29 1.429(19) . ?
C29 C30 1.199(16) . ?
C30 H30 0.9500 . ?
C72 C74 1.47(3) . ?
C74 C75 1.15(3) . ?
C75 H75 0.9500 . ?
O29 C61 1.254(11) . ?
N2 C61 1.277(14) . ?
N2 C62 1.471(13) . ?
N2 C63 1.444(16) . ?
C61 H61 0.9500 . ?
C62 H62A 0.9800 . ?
C62 H62B 0.9800 . ?
C62 H62C 0.9800 . ?
C63 H63A 0.9800 . ?
C63 H63B 0.9800 . ?
C63 H63C 0.9800 . ?
O30 C67 1.14(2) . ?
N4 C67 1.249(16) . ?
N4 C68 1.42(3) . ?
N4 C73 1.426(16) . ?
C67 H67 0.9500 . ?
C68 H68A 0.9800 . ?
C68 H68B 0.9800 . ?
C68 H68C 0.9800 . ?
C73 H73A 0.9800 . ?
C73 H73B 0.9800 . ?
C73 H73C 0.9800 . ?
O31 C64 1.195(18) . ?
N3 C64 1.322(17) . ?
N3 C65 1.394(19) . ?
N3 C66 1.435(17) . ?
C64 H64 0.9500 . ?
C65 H65A 0.9800 . ?
C65 H65B 0.9800 . ?
C65 H65C 0.9800 . ?
C66 H66A 0.9800 . ?
C66 H66B 0.9800 . ?
C66 H66C 0.9800 . ?
O32 H32A 0.8696 . ?
O32 H32B 0.8703 . ?
O33 H33A 0.8693 . ?
O33 H33B 0.8694 . ?
O34 H34A 0.8711 . ?
O34 H34B 0.8701 . ?
C9A H9A 0.9500 . ?
C9A C0AA 1.23(3) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O3 Eu1 O4 53.06(13) 1_655 1_655 ?
O3 Eu1 O7 81.29(14) 1_655 4_676 ?
O3 Eu1 O8 78.96(14) 1_655 4_676 ?
O3 Eu1 O23 149.56(16) 1_655 . ?
O3 Eu1 C8 26.70(14) 1_655 1_655 ?
O3 Eu1 C18 79.05(15) 1_655 4_676 ?
O3 Eu1 C58 154.67(15) 1_655 . ?
O4 Eu1 O7 75.56(14) 1_655 4_676 ?
O4 Eu1 O23 126.81(16) 1_655 . ?
O4 Eu1 C8 26.38(15) 1_655 1_655 ?
O4 Eu1 C18 95.26(15) 1_655 4_676 ?
O4 Eu1 C58 147.27(17) 1_655 . ?
O6 Eu1 O3 128.85(13) . 1_655 ?
O6 Eu1 O4 76.88(14) . 1_655 ?
O6 Eu1 O7 76.26(13) . 4_676 ?
O6 Eu1 O8 118.67(14) . 4_676 ?
O6 Eu1 O14 93.24(13) . . ?
O6 Eu1 O23 68.25(16) . . ?
O6 Eu1 O24 82.28(15) . . ?
O6 Eu1 O28 151.17(15) . . ?
O6 Eu1 C8 102.68(15) . 1_655 ?
O6 Eu1 C18 97.75(15) . 4_676 ?
O6 Eu1 C58 75.78(16) . . ?
O7 Eu1 O23 129.15(16) 4_676 . ?
O7 Eu1 C8 76.56(15) 4_676 1_655 ?
O7 Eu1 C18 26.46(14) 4_676 4_676 ?
O7 Eu1 C58 114.45(15) 4_676 . ?
O8 Eu1 O4 114.25(14) 4_676 1_655 ?
O8 Eu1 O7 52.84(13) 4_676 4_676 ?
O8 Eu1 O23 117.39(16) 4_676 . ?
O8 Eu1 C8 96.79(16) 4_676 1_655 ?
O8 Eu1 C18 26.38(14) 4_676 4_676 ?
O8 Eu1 C58 94.62(16) 4_676 . ?
O14 Eu1 O3 85.06(13) . 1_655 ?
O14 Eu1 O4 75.99(13) . 1_655 ?
O14 Eu1 O7 151.23(13) . 4_676 ?
O14 Eu1 O8 147.66(13) . 4_676 ?
O14 Eu1 O23 67.55(16) . . ?
O14 Eu1 O24 108.27(16) . . ?
O14 Eu1 O28 77.34(13) . . ?
O14 Eu1 C8 79.87(15) . 1_655 ?
O14 Eu1 C18 164.05(14) . 4_676 ?
O14 Eu1 C58 87.92(15) . . ?
O23 Eu1 C58 22.90(17) . . ?
O24 Eu1 O3 146.32(15) . 1_655 ?
O24 Eu1 O4 158.98(14) . 1_655 ?
O24 Eu1 O7 96.93(16) . 4_676 ?
O24 Eu1 O8 73.61(16) . 4_676 ?
O24 Eu1 O23 44.39(18) . . ?
O24 Eu1 C8 170.41(18) . 1_655 ?
O24 Eu1 C18 84.73(17) . 4_676 ?
O24 Eu1 C58 21.58(18) . . ?
O28 Eu1 O3 78.03(13) . 1_655 ?
O28 Eu1 O4 125.42(13) . 1_655 ?
O28 Eu1 O7 123.70(14) . 4_676 ?
O28 Eu1 O8 71.95(14) . 4_676 ?
O28 Eu1 O23 83.02(17) . . ?
O28 Eu1 O24 75.19(14) . . ?
O28 Eu1 C8 102.36(15) . 1_655 ?
O28 Eu1 C18 97.84(15) . 4_676 ?
O28 Eu1 C58 76.69(16) . . ?
C8 Eu1 O23 145.08(17) 1_655 . ?
C8 Eu1 C18 86.44(16) 1_655 4_676 ?
C8 Eu1 C58 167.62(17) 1_655 . ?
C18 Eu1 O23 127.45(17) 4_676 . ?
C18 Eu1 C58 105.93(16) 4_676 . ?
O2 Eu2 Eu1 121.0(2) . . ?
O2 Eu2 O5 90.02(18) . . ?
O2 Eu2 O10 108.5(2) . . ?
O2 Eu2 O13 150.9(2) . . ?
O2 Eu2 O14 153.4(2) . . ?
O2 Eu2 O18 93.5(2) . . ?
O2 Eu2 O23 84.4(3) . . ?
O2 Eu2 O25 73.7(3) . . ?
O2 Eu2 C37 167.92(18) . . ?
O5 Eu2 Eu1 60.05(10) . . ?
O5 Eu2 O10 142.72(15) . . ?
O5 Eu2 O13 81.30(14) . . ?
O5 Eu2 O14 75.02(13) . . ?
O5 Eu2 O18 140.41(13) . . ?
O5 Eu2 O23 80.89(19) . . ?
O5 Eu2 O25 74.77(15) . . ?
O5 Eu2 C37 78.42(14) . . ?
O10 Eu2 Eu1 82.78(11) . . ?
O10 Eu2 O13 94.70(15) . . ?
O10 Eu2 O14 74.56(13) . . ?
O10 Eu2 O18 72.21(15) . . ?
O10 Eu2 O23 69.5(2) . . ?
O10 Eu2 O25 140.76(16) . . ?
O10 Eu2 C37 83.16(14) . . ?
O13 Eu2 Eu1 78.30(9) . . ?
O13 Eu2 O14 49.32(12) . . ?
O13 Eu2 O18 76.64(13) . . ?
O13 Eu2 O23 121.00(19) . . ?
O13 Eu2 O25 77.25(17) . . ?
O13 Eu2 C37 24.14(13) . . ?
O14 Eu2 Eu1 32.46(7) . . ?
O14 Eu2 C37 25.26(12) . . ?
O18 Eu2 Eu1 142.64(9) . . ?
O18 Eu2 O14 112.03(12) . . ?
O18 Eu2 O25 68.56(14) . . ?
O18 Eu2 C37 93.19(13) . . ?
O23 Eu2 Eu1 44.43(16) . . ?
O23 Eu2 O14 71.77(18) . . ?
O23 Eu2 O18 138.70(18) . . ?
O23 Eu2 O25 146.9(2) . . ?
O23 Eu2 C37 97.03(19) . . ?
O25 Eu2 Eu1 131.07(11) . . ?
O25 Eu2 O14 121.37(15) . . ?
O25 Eu2 C37 99.59(17) . . ?
C37 Eu2 Eu1 55.85(10) . . ?
O1 Eu3 Eu4 97.37(11) . . ?
O1 Eu3 O9 95.01(17) . . ?
O1 Eu3 O15 75.85(14) . 1_455 ?
O1 Eu3 O16 84.38(18) . 1_455 ?
O1 Eu3 O17 88.22(15) . . ?
O1 Eu3 O19 172.96(15) . 3_666 ?
O1 Eu3 O20 134.73(14) . 3_666 ?
O1 Eu3 O21 80.01(15) . . ?
O1 Eu3 C38 76.63(16) . 1_455 ?
O1 Eu3 C48 160.86(16) . 3_666 ?
O9 Eu3 Eu4 118.21(11) . . ?
O9 Eu3 O15 152.27(13) . 1_455 ?
O9 Eu3 O16 156.25(15) . 1_455 ?
O9 Eu3 O19 80.43(16) . 3_666 ?
O9 Eu3 O20 116.78(15) . 3_666 ?
O9 Eu3 C38 171.63(17) . 1_455 ?
O9 Eu3 C48 100.85(16) . 3_666 ?
O15 Eu3 Eu4 40.08(8) 1_455 . ?
O15 Eu3 C38 25.49(13) 1_455 1_455 ?
O15 Eu3 C48 85.17(13) 1_455 3_666 ?
O16 Eu3 Eu4 85.31(11) 1_455 . ?
O16 Eu3 O15 50.31(12) 1_455 1_455 ?
O16 Eu3 O19 97.61(18) 1_455 3_666 ?
O16 Eu3 O20 78.37(17) 1_455 3_666 ?
O16 Eu3 C38 25.06(15) 1_455 1_455 ?
O16 Eu3 C48 85.35(18) 1_455 3_666 ?
O17 Eu3 Eu4 159.66(10) . . ?
O17 Eu3 O9 80.50(14) . . ?
O17 Eu3 O15 124.48(12) . 1_455 ?
O17 Eu3 O16 75.76(14) . 1_455 ?
O17 Eu3 O19 85.73(13) . 3_666 ?
O17 Eu3 O20 126.27(13) . 3_666 ?
O17 Eu3 C38 99.35(14) . 1_455 ?
O17 Eu3 C48 104.81(14) . 3_666 ?
O19 Eu3 Eu4 89.54(9) 3_666 . ?
O19 Eu3 O15 110.62(12) 3_666 1_455 ?
O19 Eu3 O20 52.28(12) 3_666 3_666 ?
O19 Eu3 C38 107.92(15) 3_666 1_455 ?
O19 Eu3 C48 25.99(14) 3_666 3_666 ?
O20 Eu3 Eu4 40.18(8) 3_666 . ?
O20 Eu3 O15 60.89(12) 3_666 1_455 ?
O20 Eu3 C38 70.12(15) 3_666 1_455 ?
O20 Eu3 C48 26.56(13) 3_666 3_666 ?
O21 Eu3 Eu4 41.76(10) . . ?
O21 Eu3 O9 82.23(15) . . ?
O21 Eu3 O15 70.49(12) . 1_455 ?
O21 Eu3 O16 120.79(14) . 1_455 ?
O21 Eu3 O17 158.13(14) . . ?
O21 Eu3 O19 104.52(15) . 3_666 ?
O21 Eu3 O20 73.87(13) . 3_666 ?
O21 Eu3 C38 95.79(15) . 1_455 ?
O21 Eu3 C48 91.52(15) . 3_666 ?
C38 Eu3 Eu4 63.38(11) 1_455 . ?
C48 Eu3 Eu4 65.69(11) 3_666 . ?
C48 Eu3 C38 87.31(16) 3_666 1_455 ?
O11 Eu4 Eu3 120.54(9) 1_455 . ?
O11 Eu4 O21 144.48(12) 1_455 . ?
O11 Eu4 O22 136.61(13) 1_455 . ?
O11 Eu4 C28 26.51(14) 1_455 1_455 ?
O11 Eu4 C57 144.74(13) 1_455 . ?
O12 Eu4 Eu3 118.08(11) 1_455 . ?
O12 Eu4 O11 52.79(12) 1_455 1_455 ?
O12 Eu4 O20 79.96(13) 1_455 3_666 ?
O12 Eu4 O21 149.38(13) 1_455 . ?
O12 Eu4 O22 144.77(14) 1_455 . ?
O12 Eu4 C28 26.38(14) 1_455 1_455 ?
O12 Eu4 C57 161.55(14) 1_455 . ?
O15 Eu4 Eu3 46.81(9) 1_455 . ?
O15 Eu4 O11 75.71(12) 1_455 1_455 ?
O15 Eu4 O12 102.11(15) 1_455 1_455 ?
O15 Eu4 O20 66.18(13) 1_455 3_666 ?
O15 Eu4 O21 71.99(12) 1_455 . ?
O15 Eu4 O22 113.11(13) 1_455 . ?
O15 Eu4 C28 90.33(14) 1_455 1_455 ?
O15 Eu4 C57 90.97(13) 1_455 . ?
O20 Eu4 Eu3 40.97(9) 3_666 . ?
O20 Eu4 O11 109.52(13) 3_666 1_455 ?
O20 Eu4 O21 70.12(12) 3_666 . ?
O20 Eu4 O22 112.75(14) 3_666 . ?
O20 Eu4 C28 96.50(14) 3_666 1_455 ?
O20 Eu4 C57 93.81(14) 3_666 . ?
O21 Eu4 Eu3 36.62(8) . . ?
O21 Eu4 C28 160.90(14) . 1_455 ?
O21 Eu4 C57 26.00(13) . . ?
O22 Eu4 Eu3 87.11(9) . . ?
O22 Eu4 O21 50.52(12) . . ?
O22 Eu4 C28 147.81(14) . 1_455 ?
O22 Eu4 C57 25.01(13) . . ?
O26 Eu4 Eu3 95.23(10) . . ?
O26 Eu4 O11 76.66(13) . 1_455 ?
O26 Eu4 O12 128.20(13) . 1_455 ?
O26 Eu4 O15 71.78(13) . 1_455 ?
O26 Eu4 O20 133.77(13) . 3_666 ?
O26 Eu4 O21 79.55(13) . . ?
O26 Eu4 O22 67.43(14) . . ?
O26 Eu4 O27 78.01(15) . . ?
O26 Eu4 C28 102.20(14) . 1_455 ?
O26 Eu4 C57 68.15(14) . . ?
O27 Eu4 Eu3 161.43(11) . . ?
O27 Eu4 O11 75.12(14) . 1_455 ?
O27 Eu4 O12 78.79(16) . 1_455 ?
O27 Eu4 O15 141.87(14) . 1_455 ?
O27 Eu4 O20 148.18(14) . 3_666 ?
O27 Eu4 O21 124.82(14) . . ?
O27 Eu4 O22 74.32(14) . . ?
O27 Eu4 C28 73.69(15) . 1_455 ?
O27 Eu4 C57 98.96(15) . . ?
O35 Eu4 Eu3 95.79(12) . . ?
O35 Eu4 O11 128.09(15) . 1_455 ?
O35 Eu4 O12 78.48(16) . 1_455 ?
O35 Eu4 O15 138.62(15) . 1_455 ?
O35 Eu4 O20 73.39(16) . 3_666 ?
O35 Eu4 O21 86.72(15) . . ?
O35 Eu4 O22 74.56(16) . . ?
O35 Eu4 O26 139.69(16) . . ?
O35 Eu4 O27 79.35(16) . . ?
O35 Eu4 C28 102.83(17) . 1_455 ?
O35 Eu4 C57 83.10(16) . . ?
C28 Eu4 Eu3 124.85(11) 1_455 . ?
C28 Eu4 C57 169.23(15) 1_455 . ?
C57 Eu4 Eu3 62.55(10) . . ?
C7 O1 Eu3 163.2(5) . . ?
C7 O2 Eu2 136.2(5) . . ?
C8 O3 Eu1 93.3(3) . 1_455 ?
C8 O4 Eu1 92.7(3) . 1_455 ?
C17 O5 Eu2 141.5(4) . . ?
C17 O6 Eu1 133.3(3) . . ?
C18 O7 Eu1 93.1(3) . 4_575 ?
C18 O8 Eu1 93.3(3) . 4_575 ?
C27 O9 Eu3 145.4(4) . . ?
C27 O10 Eu2 155.1(4) . . ?
C28 O11 Eu4 92.6(3) . 1_655 ?
C28 O12 Eu4 94.6(3) . 1_655 ?
C37 O13 Eu2 105.9(3) . . ?
Eu1 O14 Eu2 108.06(13) . . ?
C37 O14 Eu1 150.4(3) . . ?
C37 O14 Eu2 82.9(3) . . ?
Eu4 O15 Eu3 93.12(12) 1_655 1_655 ?
C38 O15 Eu3 83.6(3) . 1_655 ?
C38 O15 Eu4 151.1(4) . 1_655 ?
C38 O16 Eu3 103.6(3) . 1_655 ?
C47 O17 Eu3 130.7(3) . . ?
C47 O18 Eu2 137.5(3) . . ?
C48 O19 Eu3 96.0(3) . 3_666 ?
Eu4 O20 Eu3 98.84(13) 3_666 3_666 ?
C48 O20 Eu3 91.3(3) . 3_666 ?
C48 O20 Eu4 157.9(4) . 3_666 ?
Eu3 O21 Eu4 101.62(14) . . ?
C57 O21 Eu3 165.1(4) . . ?
C57 O21 Eu4 92.3(3) . . ?
C57 O22 Eu4 95.4(3) . . ?
Eu2 O23 Eu1 102.7(2) . . ?
C58 O23 Eu1 82.3(5) . . ?
C58 O23 Eu2 174.3(6) . . ?
C58 O24 Eu1 112.0(4) . . ?
Eu2 O25 H25A 112.2 . . ?
Eu2 O25 H25B 112.1 . . ?
H25A O25 H25B 102.0 . . ?
Eu4 O26 H26A 128.0 . . ?
Eu4 O26 H26B 127.3 . . ?
H26A O26 H26B 104.5 . . ?
Eu4 O27 H27A 109.4 . . ?
Eu4 O27 H27B 109.4 . . ?
H27A O27 H27B 104.5 . . ?
Eu1 O28 H28A 124.9 . . ?
Eu1 O28 H28B 124.5 . . ?
H28A O28 H28B 104.5 . . ?
C69 O35 Eu4 144.3(5) . . ?
C69 N1 C70 121.1(7) . . ?
C69 N1 C71 123.1(7) . . ?
C71 N1 C70 115.7(7) . . ?
C2 C1 C6 120.0(7) . . ?
C2 C1 C7 118.0(6) . . ?
C6 C1 C7 121.9(6) . . ?
C1 C2 H2 119.7 . . ?
C1 C2 C3 120.6(8) . . ?
C3 C2 H2 119.7 . . ?
C2 C3 C4 118.8(8) . . ?
C2 C3 C9 115.0(9) . . ?
C2 C3 C0AA 125.0(10) . . ?
C4 C3 C9 125.8(9) . . ?
C4 C3 C0AA 114.2(10) . . ?
C3 C4 H4 119.5 . . ?
C5 C4 C3 120.9(7) . . ?
C5 C4 H4 119.5 . . ?
C4 C5 C6 119.3(6) . . ?
C4 C5 C8 119.2(6) . . ?
C6 C5 C8 121.5(5) . . ?
C1 C6 H6 119.8 . . ?
C5 C6 C1 120.3(6) . . ?
C5 C6 H6 119.8 . . ?
O1 C7 O2 123.6(7) . . ?
O1 C7 C1 119.4(6) . . ?
O2 C7 C1 117.0(6) . . ?
O3 C8 Eu1 60.0(3) . 1_455 ?
O3 C8 C5 119.7(5) . . ?
O4 C8 Eu1 60.9(3) . 1_455 ?
O4 C8 O3 120.9(5) . . ?
O4 C8 C5 119.4(5) . . ?
C5 C8 Eu1 177.2(4) . 1_455 ?
C10 C9 C3 170.8(16) . . ?
C9 C10 H10 180.0 . . ?
C12 C11 C17 120.2(5) . . ?
C16 C11 C12 119.9(5) . . ?
C16 C11 C17 120.0(5) . . ?
C11 C12 H12 120.1 . . ?
C13 C12 C11 119.9(5) . . ?
C13 C12 H12 120.1 . . ?
C12 C13 C14 119.6(5) . . ?
C12 C13 C19 122.1(5) . . ?
C14 C13 C19 118.2(5) . . ?
C13 C14 H14 119.7 . . ?
C15 C14 C13 120.6(5) . . ?
C15 C14 H14 119.7 . . ?
C14 C15 C16 119.8(5) . . ?
C14 C15 C18 118.8(5) . . ?
C16 C15 C18 121.3(5) . . ?
C11 C16 H16 119.9 . . ?
C15 C16 C11 120.1(5) . . ?
C15 C16 H16 119.9 . . ?
O5 C17 C11 116.4(5) . . ?
O6 C17 O5 125.3(5) . . ?
O6 C17 C11 118.3(5) . . ?
O7 C18 Eu1 60.4(3) . 4_575 ?
O7 C18 C15 120.2(5) . . ?
O8 C18 Eu1 60.3(3) . 4_575 ?
O8 C18 O7 120.7(5) . . ?
O8 C18 C15 119.1(5) . . ?
C15 C18 Eu1 179.2(4) . 4_575 ?
C20 C19 C13 174.0(6) . . ?
C19 C20 H20 180.0 . . ?
C22 C21 C27 119.6(5) . . ?
C26 C21 C22 120.3(5) . . ?
C26 C21 C27 120.1(5) . . ?
C21 C22 H22 120.0 . . ?
C21 C22 H22A 121.3 . . ?
C21 C22 C23 120.0(8) . . ?
C23 C22 H22 120.0 . . ?
C72 C22 C21 117.3(12) . . ?
C72 C22 H22A 121.3 . . ?
C25 C24 H24 118.8 . . ?
C25 C24 H24A 123.2 . . ?
C25 C24 C72 113.6(12) . . ?
C23 C24 H24 118.8 . . ?
C23 C24 C25 122.4(9) . . ?
C72 C24 H24A 123.2 . . ?
C24 C25 C26 120.1(5) . . ?
C24 C25 C28 119.9(5) . . ?
C26 C25 C28 119.8(5) . . ?
C21 C26 C25 120.0(5) . . ?
C21 C26 H26 120.0 . . ?
C25 C26 H26 120.0 . . ?
O9 C27 O10 123.8(5) . . ?
O9 C27 C21 118.7(5) . . ?
O10 C27 C21 117.5(5) . . ?
O11 C28 Eu4 60.9(3) . 1_655 ?
O11 C28 C25 120.6(5) . . ?
O12 C28 Eu4 59.1(3) . 1_655 ?
O12 C28 O11 119.6(5) . . ?
O12 C28 C25 119.8(5) . . ?
C25 C28 Eu4 172.6(4) . 1_655 ?
C32 C31 C36 120.2(5) . . ?
C32 C31 C37 122.1(4) . . ?
C36 C31 C37 117.6(5) . . ?
C31 C32 H32 120.4 . . ?
C31 C32 C33 119.1(5) . . ?
C33 C32 H32 120.4 . . ?
C32 C33 C34 120.8(5) . . ?
C32 C33 C38 121.2(5) . . ?
C34 C33 C38 118.1(5) . . ?
C33 C34 H34 119.8 . . ?
C35 C34 C33 120.4(5) . . ?
C35 C34 H34 119.8 . . ?
C34 C35 C36 119.4(5) . . ?
C34 C35 C39 120.8(5) . . ?
C36 C35 C39 119.8(5) . . ?
C31 C36 H36 119.9 . . ?
C35 C36 C31 120.1(5) . . ?
C35 C36 H36 119.9 . . ?
O13 C37 Eu2 50.0(2) . . ?
O13 C37 O14 121.5(5) . . ?
O13 C37 C31 116.5(4) . . ?
O14 C37 Eu2 71.8(3) . . ?
O14 C37 C31 122.0(5) . . ?
C31 C37 Eu2 164.7(3) . . ?
O15 C38 Eu3 70.9(3) . 1_655 ?
O15 C38 O16 121.4(5) . . ?
O15 C38 C33 121.1(5) . . ?
O16 C38 Eu3 51.4(3) . 1_655 ?
O16 C38 C33 117.5(5) . . ?
C33 C38 Eu3 164.5(4) . 1_655 ?
C40 C39 C35 178.8(9) . . ?
C39 C40 H40 180.0 . . ?
C42 C41 C47 120.3(5) . . ?
C46 C41 C42 119.9(5) . . ?
C46 C41 C47 119.7(5) . . ?
C41 C42 H42 120.0 . . ?
C41 C42 C43 119.9(5) . . ?
C43 C42 H42 120.0 . . ?
C42 C43 C49 120.7(5) . . ?
C44 C43 C42 119.9(5) . . ?
C44 C43 C49 119.4(5) . . ?
C43 C44 H44 120.2 . . ?
C43 C44 C45 119.5(5) . . ?
C45 C44 H44 120.2 . . ?
C44 C45 C48 120.0(5) . . ?
C46 C45 C44 120.3(5) . . ?
C46 C45 C48 119.7(5) . . ?
C41 C46 C45 120.2(5) . . ?
C41 C46 H46 119.9 . . ?
C45 C46 H46 119.9 . . ?
O17 C47 C41 117.1(4) . . ?
O18 C47 O17 124.3(5) . . ?
O18 C47 C41 118.6(4) . . ?
O19 C48 Eu3 58.0(3) . 3_666 ?
O19 C48 O20 119.2(5) . . ?
O19 C48 C45 120.0(5) . . ?
O20 C48 Eu3 62.1(3) . 3_666 ?
O20 C48 C45 120.8(5) . . ?
C45 C48 Eu3 170.3(4) . 3_666 ?
C50 C49 C43 177.7(7) . . ?
C49 C50 H50 180.0 . . ?
C52 C51 C57 123.1(5) . . ?
C56 C51 C52 120.0(5) . . ?
C56 C51 C57 116.8(5) . . ?
C51 C52 H52 120.2 . . ?
C53 C52 C51 119.5(5) . . ?
C53 C52 H52 120.2 . . ?
C52 C53 C58 121.6(5) . . ?
C54 C53 C52 120.2(5) . . ?
C54 C53 C58 118.2(5) . . ?
C53 C54 H54 119.7 . . ?
C53 C54 C55 120.6(5) . . ?
C55 C54 H54 119.7 . . ?
C54 C55 C56 118.6(5) . . ?
C54 C55 C59 122.1(5) . . ?
C56 C55 C59 119.3(5) . . ?
C51 C56 C55 121.0(5) . . ?
C51 C56 H56 119.5 . . ?
C55 C56 H56 119.5 . . ?
O21 C57 Eu4 61.7(3) . . ?
O21 C57 C51 120.4(5) . . ?
O22 C57 Eu4 59.6(3) . . ?
O22 C57 O21 119.5(5) . . ?
O22 C57 C51 120.0(5) . . ?
C51 C57 Eu4 163.6(4) . . ?
O23 C58 Eu1 74.8(4) . . ?
O23 C58 O24 120.8(6) . . ?
O23 C58 C53 120.5(6) . . ?
O24 C58 Eu1 46.4(3) . . ?
O24 C58 C53 118.6(6) . . ?
C53 C58 Eu1 162.7(5) . . ?
C60 C59 C55 176.3(7) . . ?
C59 C60 H60 180.0 . . ?
O35 C69 N1 124.8(7) . . ?
O35 C69 H69 117.6 . . ?
N1 C69 H69 117.6 . . ?
N1 C70 H70A 109.5 . . ?
N1 C70 H70B 109.5 . . ?
N1 C70 H70C 109.5 . . ?
H70A C70 H70B 109.5 . . ?
H70A C70 H70C 109.5 . . ?
H70B C70 H70C 109.5 . . ?
N1 C71 H71A 109.5 . . ?
N1 C71 H71B 109.5 . . ?
N1 C71 H71C 109.5 . . ?
H71A C71 H71B 109.5 . . ?
H71A C71 H71C 109.5 . . ?
H71B C71 H71C 109.5 . . ?
C24 C23 C22 115.3(12) . . ?
C24 C23 C29 121.1(13) . . ?
C29 C23 C22 123.0(13) . . ?
C30 C29 C23 176.2(15) . . ?
C29 C30 H30 180.0 . . ?
C22 C72 C24 120.5(19) . . ?
C22 C72 C74 114(2) . . ?
C74 C72 C24 121(2) . . ?
C75 C74 C72 175(2) . . ?
C74 C75 H75 180.0 . . ?
C61 N2 C62 121.6(10) . . ?
C61 N2 C63 119.9(10) . . ?
C63 N2 C62 118.5(11) . . ?
O29 C61 N2 127.1(9) . . ?
O29 C61 H61 116.4 . . ?
N2 C61 H61 116.4 . . ?
N2 C62 H62A 109.5 . . ?
N2 C62 H62B 109.5 . . ?
N2 C62 H62C 109.5 . . ?
H62A C62 H62B 109.5 . . ?
H62A C62 H62C 109.5 . . ?
H62B C62 H62C 109.5 . . ?
N2 C63 H63A 109.5 . . ?
N2 C63 H63B 109.5 . . ?
N2 C63 H63C 109.5 . . ?
H63A C63 H63B 109.5 . . ?
H63A C63 H63C 109.5 . . ?
H63B C63 H63C 109.5 . . ?
C67 N4 C68 125.2(19) . . ?
C67 N4 C73 118.0(19) . . ?
C68 N4 C73 116.6(17) . . ?
O30 C67 N4 121.9(19) . . ?
O30 C67 H67 119.1 . . ?
N4 C67 H67 119.1 . . ?
N4 C68 H68A 109.5 . . ?
N4 C68 H68B 109.5 . . ?
N4 C68 H68C 109.5 . . ?
H68A C68 H68B 109.5 . . ?
H68A C68 H68C 109.5 . . ?
H68B C68 H68C 109.5 . . ?
N4 C73 H73A 109.5 . . ?
N4 C73 H73B 109.5 . . ?
N4 C73 H73C 109.5 . . ?
H73A C73 H73B 109.5 . . ?
H73A C73 H73C 109.5 . . ?
H73B C73 H73C 109.5 . . ?
C64 N3 C65 121.3(12) . . ?
C64 N3 C66 119.6(13) . . ?
C65 N3 C66 119.1(12) . . ?
O31 C64 N3 125.5(14) . . ?
O31 C64 H64 117.3 . . ?
N3 C64 H64 117.3 . . ?
N3 C65 H65A 109.5 . . ?
N3 C65 H65B 109.5 . . ?
N3 C65 H65C 109.5 . . ?
H65A C65 H65B 109.5 . . ?
H65A C65 H65C 109.5 . . ?
H65B C65 H65C 109.5 . . ?
N3 C66 H66A 109.5 . . ?
N3 C66 H66B 109.5 . . ?
N3 C66 H66C 109.5 . . ?
H66A C66 H66B 109.5 . . ?
H66A C66 H66C 109.5 . . ?
H66B C66 H66C 109.5 . . ?
H32A O32 H32B 104.5 . . ?
H33A O33 H33B 104.4 . . ?
H34A O34 H34B 104.5 . . ?
C0AA C9A H9A 180.0 . . ?
C9A C0AA C3 171(2) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Eu1 O3 C8 O4 -1.9(6) 1_455 . . . ?
Eu1 O3 C8 C5 176.8(5) 1_455 . . . ?
Eu1 O4 C8 O3 1.9(6) 1_455 . . . ?
Eu1 O4 C8 C5 -176.8(5) 1_455 . . . ?
Eu1 O6 C17 O5 20.9(9) . . . . ?
Eu1 O6 C17 C11 -158.7(4) . . . . ?
Eu1 O7 C18 O8 -0.4(6) 4_575 . . . ?
Eu1 O7 C18 C15 179.5(4) 4_575 . . . ?
Eu1 O8 C18 O7 0.4(6) 4_575 . . . ?
Eu1 O8 C18 C15 -179.5(4) 4_575 . . . ?
Eu1 O14 C37 Eu2 -114.4(6) . . . . ?
Eu1 O14 C37 O13 -109.0(7) . . . . ?
Eu1 O14 C37 C31 72.9(8) . . . . ?
Eu1 O23 C58 O24 6.0(6) . . . . ?
Eu1 O23 C58 C53 -171.1(6) . . . . ?
Eu1 O24 C58 O23 -8.1(8) . . . . ?
Eu1 O24 C58 C53 169.2(4) . . . . ?
Eu2 O2 C7 O1 12.9(16) . . . . ?
Eu2 O2 C7 C1 -165.3(7) . . . . ?
Eu2 O5 C17 O6 34.3(9) . . . . ?
Eu2 O5 C17 C11 -146.1(4) . . . . ?
Eu2 O10 C27 O9 -24.3(13) . . . . ?
Eu2 O10 C27 C21 155.0(7) . . . . ?
Eu2 O13 C37 O14 -6.7(6) . . . . ?
Eu2 O13 C37 C31 171.5(3) . . . . ?
Eu2 O14 C37 O13 5.4(5) . . . . ?
Eu2 O14 C37 C31 -172.7(4) . . . . ?
Eu2 O18 C47 O17 78.7(7) . . . . ?
Eu2 O18 C47 C41 -100.6(5) . . . . ?
Eu3 O1 C7 O2 -69(2) . . . . ?
Eu3 O1 C7 C1 109.3(15) . . . . ?
Eu3 O9 C27 O10 31.6(10) . . . . ?
Eu3 O9 C27 C21 -147.7(5) . . . . ?
Eu3 O15 C38 O16 9.9(6) 1_655 . . . ?
Eu3 O15 C38 C33 -169.0(5) 1_655 . . . ?
Eu3 O16 C38 O15 -12.0(7) 1_655 . . . ?
Eu3 O16 C38 C33 167.0(4) 1_655 . . . ?
Eu3 O17 C47 O18 -79.9(6) . . . . ?
Eu3 O17 C47 C41 99.4(5) . . . . ?
Eu3 O19 C48 O20 11.3(6) 3_666 . . . ?
Eu3 O19 C48 C45 -168.9(4) 3_666 . . . ?
Eu3 O20 C48 O19 -10.9(6) 3_666 . . . ?
Eu3 O20 C48 C45 169.3(5) 3_666 . . . ?
Eu3 O21 C57 Eu4 159.6(15) . . . . ?
Eu3 O21 C57 O22 174.8(11) . . . . ?
Eu3 O21 C57 C51 -1.7(18) . . . . ?
Eu4 O11 C28 O12 -6.9(5) 1_655 . . . ?
Eu4 O11 C28 C25 171.6(5) 1_655 . . . ?
Eu4 O12 C28 O11 7.0(6) 1_655 . . . ?
Eu4 O12 C28 C25 -171.5(4) 1_655 . . . ?
Eu4 O15 C38 Eu3 -84.8(7) 1_655 . . 1_655 ?
Eu4 O15 C38 O16 -75.0(9) 1_655 . . . ?
Eu4 O15 C38 C33 106.1(7) 1_655 . . . ?
Eu4 O20 C48 Eu3 117.8(9) 3_666 . . 3_666 ?
Eu4 O20 C48 O19 107.0(9) 3_666 . . . ?
Eu4 O20 C48 C45 -72.8(11) 3_666 . . . ?
Eu4 O21 C57 O22 15.2(5) . . . . ?
Eu4 O21 C57 C51 -161.3(4) . . . . ?
Eu4 O22 C57 O21 -15.5(5) . . . . ?
Eu4 O22 C57 C51 161.0(4) . . . . ?
Eu4 O35 C69 N1 100.3(9) . . . . ?
C1 C2 C3 C4 1.6(13) . . . . ?
C1 C2 C3 C9 173.9(9) . . . . ?
C1 C2 C3 C0AA -161.3(12) . . . . ?
C2 C1 C6 C5 -1.4(11) . . . . ?
C2 C1 C7 O1 -152.9(7) . . . . ?
C2 C1 C7 O2 25.4(11) . . . . ?
C2 C3 C4 C5 -0.6(12) . . . . ?
C3 C4 C5 C6 -1.3(11) . . . . ?
C3 C4 C5 C8 179.4(7) . . . . ?
C4 C5 C6 C1 2.3(10) . . . . ?
C4 C5 C8 O3 -169.9(6) . . . . ?
C4 C5 C8 O4 8.8(9) . . . . ?
C6 C1 C2 C3 -0.6(12) . . . . ?
C6 C1 C7 O1 23.9(11) . . . . ?
C6 C1 C7 O2 -157.8(8) . . . . ?
C6 C5 C8 O3 10.8(9) . . . . ?
C6 C5 C8 O4 -170.5(6) . . . . ?
C7 C1 C2 C3 176.3(7) . . . . ?
C7 C1 C6 C5 -178.1(6) . . . . ?
C8 C5 C6 C1 -178.4(6) . . . . ?
C9 C3 C4 C5 -172.1(10) . . . . ?
C11 C12 C13 C14 -0.8(9) . . . . ?
C11 C12 C13 C19 -178.7(6) . . . . ?
C12 C11 C16 C15 -0.5(9) . . . . ?
C12 C11 C17 O5 175.0(5) . . . . ?
C12 C11 C17 O6 -5.4(8) . . . . ?
C12 C13 C14 C15 -0.8(9) . . . . ?
C13 C14 C15 C16 1.8(8) . . . . ?
C13 C14 C15 C18 -177.9(5) . . . . ?
C14 C15 C16 C11 -1.2(8) . . . . ?
C14 C15 C18 O7 177.7(5) . . . . ?
C14 C15 C18 O8 -2.5(8) . . . . ?
C16 C11 C12 C13 1.5(9) . . . . ?
C16 C11 C17 O5 -5.1(8) . . . . ?
C16 C11 C17 O6 174.5(5) . . . . ?
C16 C15 C18 O7 -2.0(8) . . . . ?
C16 C15 C18 O8 177.8(5) . . . . ?
C17 C11 C12 C13 -178.6(5) . . . . ?
C17 C11 C16 C15 179.6(5) . . . . ?
C18 C15 C16 C11 178.6(5) . . . . ?
C19 C13 C14 C15 177.1(5) . . . . ?
C21 C22 C23 C24 -15.0(15) . . . . ?
C21 C22 C23 C29 172.7(10) . . . . ?
C21 C22 C72 C24 33(3) . . . . ?
C21 C22 C72 C74 -168.9(16) . . . . ?
C22 C21 C26 C25 -1.2(8) . . . . ?
C22 C21 C27 O9 9.2(8) . . . . ?
C22 C21 C27 O10 -170.1(6) . . . . ?
C24 C25 C26 C21 1.0(9) . . . . ?
C24 C25 C28 O11 -169.0(6) . . . . ?
C24 C25 C28 O12 9.6(9) . . . . ?
C25 C24 C23 C22 15.3(17) . . . . ?
C25 C24 C23 C29 -172.3(11) . . . . ?
C25 C24 C72 C22 -32(3) . . . . ?
C25 C24 C72 C74 171.3(19) . . . . ?
C26 C21 C22 C23 8.4(11) . . . . ?
C26 C21 C22 C72 -16.2(17) . . . . ?
C26 C21 C27 O9 -170.1(5) . . . . ?
C26 C21 C27 O10 10.5(8) . . . . ?
C26 C25 C28 O11 6.8(8) . . . . ?
C26 C25 C28 O12 -174.7(5) . . . . ?
C27 C21 C22 C23 -170.9(8) . . . . ?
C27 C21 C22 C72 164.4(16) . . . . ?
C27 C21 C26 C25 178.1(5) . . . . ?
C28 C25 C26 C21 -174.7(5) . . . . ?
C31 C32 C33 C34 1.1(8) . . . . ?
C31 C32 C33 C38 -177.4(5) . . . . ?
C32 C31 C36 C35 -1.1(8) . . . . ?
C32 C31 C37 Eu2 -135.9(11) . . . . ?
C32 C31 C37 O13 -161.4(5) . . . . ?
C32 C31 C37 O14 16.8(8) . . . . ?
C32 C33 C34 C35 -1.1(9) . . . . ?
C32 C33 C38 Eu3 -145.6(12) . . . 1_655 ?
C32 C33 C38 O15 -7.7(9) . . . . ?
C32 C33 C38 O16 173.3(6) . . . . ?
C33 C34 C35 C36 0.0(10) . . . . ?
C33 C34 C35 C39 -178.5(6) . . . . ?
C34 C33 C38 Eu3 35.9(17) . . . 1_655 ?
C34 C33 C38 O15 173.7(6) . . . . ?
C34 C33 C38 O16 -5.2(8) . . . . ?
C34 C35 C36 C31 1.1(9) . . . . ?
C36 C31 C32 C33 0.0(8) . . . . ?
C36 C31 C37 Eu2 40.9(15) . . . . ?
C36 C31 C37 O13 15.4(7) . . . . ?
C36 C31 C37 O14 -166.4(5) . . . . ?
C37 C31 C32 C33 176.7(5) . . . . ?
C37 C31 C36 C35 -178.0(5) . . . . ?
C38 C33 C34 C35 177.4(6) . . . . ?
C39 C35 C36 C31 179.6(6) . . . . ?
C41 C42 C43 C44 5.2(9) . . . . ?
C41 C42 C43 C49 -174.8(6) . . . . ?
C42 C41 C46 C45 -3.4(8) . . . . ?
C42 C41 C47 O17 -170.2(5) . . . . ?
C42 C41 C47 O18 9.1(7) . . . . ?
C42 C43 C44 C45 -4.9(9) . . . . ?
C43 C44 C45 C46 0.5(9) . . . . ?
C43 C44 C45 C48 179.6(5) . . . . ?
C44 C45 C46 C41 3.7(8) . . . . ?
C44 C45 C48 O19 163.3(6) . . . . ?
C44 C45 C48 O20 -17.0(8) . . . . ?
C46 C41 C42 C43 -1.0(8) . . . . ?
C46 C41 C47 O17 6.7(7) . . . . ?
C46 C41 C47 O18 -174.0(5) . . . . ?
C46 C45 C48 O19 -17.7(8) . . . . ?
C46 C45 C48 O20 162.1(5) . . . . ?
C47 C41 C42 C43 175.9(5) . . . . ?
C47 C41 C46 C45 179.7(5) . . . . ?
C48 C45 C46 C41 -175.4(5) . . . . ?
C49 C43 C44 C45 175.1(6) . . . . ?
C51 C52 C53 C54 -3.2(9) . . . . ?
C51 C52 C53 C58 176.4(6) . . . . ?
C52 C51 C56 C55 -0.8(9) . . . . ?
C52 C51 C57 Eu4 -95.4(13) . . . . ?
C52 C51 C57 O21 -2.8(8) . . . . ?
C52 C51 C57 O22 -179.3(5) . . . . ?
C52 C53 C54 C55 1.2(9) . . . . ?
C52 C53 C58 Eu1 -129.3(11) . . . . ?
C52 C53 C58 O23 20.8(10) . . . . ?
C52 C53 C58 O24 -156.4(6) . . . . ?
C53 C54 C55 C56 0.9(9) . . . . ?
C53 C54 C55 C59 -179.5(6) . . . . ?
C54 C53 C58 Eu1 50.2(15) . . . . ?
C54 C53 C58 O23 -159.7(7) . . . . ?
C54 C53 C58 O24 23.1(9) . . . . ?
C54 C55 C56 C51 -1.1(9) . . . . ?
C56 C51 C52 C53 2.9(9) . . . . ?
C56 C51 C57 Eu4 82.0(14) . . . . ?
C56 C51 C57 O21 174.6(5) . . . . ?
C56 C51 C57 O22 -1.8(8) . . . . ?
C57 C51 C52 C53 -179.7(5) . . . . ?
C57 C51 C56 C55 -178.3(5) . . . . ?
C58 C53 C54 C55 -178.3(6) . . . . ?
C59 C55 C56 C51 179.2(6) . . . . ?
C70 N1 C69 O35 -1.1(11) . . . . ?
C71 N1 C69 O35 179.5(6) . . . . ?
C23 C24 C25 C26 -8.8(13) . . . . ?
C23 C24 C25 C28 166.9(9) . . . . ?
C72 C24 C25 C26 13.9(15) . . . . ?
C72 C24 C25 C28 -170.4(13) . . . . ?
C62 N2 C61 O29 -179.4(9) . . . . ?
C63 N2 C61 O29 -0.6(18) . . . . ?
C68 N4 C67 O30 -4(3) . . . . ?
C73 N4 C67 O30 -178.6(19) . . . . ?
C65 N3 C64 O31 -4(2) . . . . ?
C66 N3 C64 O31 179.6(15) . . . . ?
C0AA C3 C4 C5 164.0(11) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
