# Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C.
# This journal is © The Royal Society of Chemistry 2024

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_exp_1902
_database_code_depnum_ccdc_archive 'CCDC 2219729'
loop_
_audit_author_name
_audit_author_address
'Yunshan Zhou' 'Beijing University of Chemical Technology'
_audit_update_record             
;
2022-11-15 deposited with the CCDC.	2024-01-02 downloaded from the CCDC.
;
_audit_creation_date             2021-12-03
_audit_creation_method           
;
Olex2 1.5
(compiled 2021.11.18 svn.ra9532c28 for OlexSys, GUI svn.r6429)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C48 H46 Eu2 N4 O16, 1.5(C3 H7 N O)'
_chemical_formula_sum            'C52.50 H56.50 Eu2 N5.50 O17.50'
_chemical_formula_weight         1348.45
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   11.3797(5)
_cell_length_b                   11.4685(8)
_cell_length_c                   23.1474(17)
_cell_angle_alpha                78.490(6)
_cell_angle_beta                 87.392(5)
_cell_angle_gamma                62.339(6)
_cell_volume                     2618.0(3)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    7451
_cell_measurement_temperature    100
_cell_measurement_theta_max      29.2740
_cell_measurement_theta_min      2.9780
_shelx_estimated_absorpt_T_max   0.908
_shelx_estimated_absorpt_T_min   0.710
_exptl_absorpt_coefficient_mu    2.453
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.86013
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.11 (release 16-05-2011 CrysAlis171 .NET)
(compiled May 16 2011,17:55:39)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.711
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       plate
_exptl_crystal_F_000             1352
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.11
_exptl_crystal_size_min          0.04
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0291
_diffrn_reflns_av_unetI/netI     0.0501
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.837
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_number            21429
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.837
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         29.338
_diffrn_reflns_theta_min         2.985
_diffrn_ambient_temperature      100
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.837
_diffrn_measurement_device_type  CCD
_diffrn_measurement_method       ?
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_special_details          ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                10311
_reflns_number_total             12031
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT  (Sheldrick, 2015)'
_refine_diff_density_max         1.200
_refine_diff_density_min         -0.978
_refine_diff_density_rms         0.121
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.051
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     780
_refine_ls_number_reflns         12031
_refine_ls_number_restraints     165
_refine_ls_R_factor_all          0.0397
_refine_ls_R_factor_gt           0.0312
_refine_ls_restrained_S_all      1.065
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0170P)²+3.0127P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0648
_refine_ls_wR_factor_ref         0.0688
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 C55-C56
 2.4 with sigma of 0.02
 C55-N52 = N52-C56
 1.4 with sigma of 0.02
3. Uiso/Uaniso restraints and constraints
Uanis(C49) \\sim Ueq, Uanis(N17) \\sim Ueq, Uanis(C50) \\sim Ueq, Uanis(C51)
\\sim Ueq, Uanis(O20) \\sim Ueq: with sigma of 0.01 and sigma for terminal
atoms of 0.02
Uanis(N52) \\sim Ueq, Uanis(O18) \\sim Ueq, Uanis(C53) \\sim Ueq, Uanis(C55)
\\sim Ueq, Uanis(C56) \\sim Ueq, Uanis(O21) \\sim Ueq, Uanis(C52) \\sim Ueq,
Uanis(C54) \\sim Ueq, Uanis(N53) \\sim Ueq, Uanis(C58) \\sim Ueq: with sigma of
0.01 and sigma for terminal atoms of 0.02
4. Rigid body (RIGU) restrains
 O18, N52, C53, C55, C56, O20, N17, C49, C50, C51, O21, N53, C52, C54, C58
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
5. Others
 Fixed Sof: O18(0.5) N52(0.5) C53(0.5) H53(0.5) C55(0.5) H55A(0.5) H55B(0.5)
 H55C(0.5) C56(0.5) H56A(0.5) H56B(0.5) H56C(0.5) O20(0.5) N17(0.5) C49(0.5)
 H49A(0.5) H49B(0.5) H49C(0.5) C50(0.5) H50A(0.5) H50B(0.5) H50C(0.5) C51(0.5)
 H51(0.5) O21(0.5) N53(0.5) C52(0.5) H52A(0.5) H52B(0.5) H52C(0.5) C54(0.5)
 H54(0.5) C58(0.5) H58A(0.5) H58B(0.5) H58C(0.5)
6.a Aromatic/amide H refined with riding coordinates:
 C3(H3), C4(H4), C9(H9), C10(H10), C11(H11), C12(H12), C15(H15), C16(H16),
 C21(H21), C22(H22), C23(H23), C24(H24), C27(H27), C28(H28), C33(H33), C34(H34),
  C35(H35), C36(H36), C37(H37), C40(H40), C43(H43), C46(H46), C53(H53),
 C51(H51), C54(H54)
6.b Idealised Me refined as rotating group:
 C38(H38A,H38B,H38C), C39(H39A,H39B,H39C), C41(H41A,H41B,H41C), C42(H42A,H42B,
 H42C), C44(H44A,H44B,H44C), C45(H45A,H45B,H45C), C47(H47A,H47B,H47C), C48(H48A,
 H48B,H48C), C55(H55A,H55B,H55C), C56(H56A,H56B,H56C), C49(H49A,H49B,H49C),
 C50(H50A,H50B,H50C), C52(H52A,H52B,H52C), C58(H58A,H58B,H58C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 1.06874(2) -0.16380(2) 0.80630(2) 0.00694(5) Uani 1 1 d . . . . .
Eu2 Eu 0.90937(2) 0.19165(2) 0.69059(2) 0.00694(5) Uani 1 1 d . . . . .
O1 O 0.8674(2) 0.2919(2) 0.78224(10) 0.0154(5) Uani 1 1 d . . . . .
O2 O 0.9475(2) 0.0723(2) 0.80200(10) 0.0104(5) Uani 1 1 d . . . . .
O3 O 1.0407(2) 0.1600(2) 1.09822(10) 0.0142(5) Uani 1 1 d . . . . .
O4 O 0.8448(2) 0.1671(2) 1.09788(10) 0.0152(5) Uani 1 1 d . . . . .
O5 O 0.7516(2) 0.1104(2) 0.71754(11) 0.0142(5) Uani 1 1 d . . . . .
O6 O 0.8439(2) -0.0961(2) 0.77555(10) 0.0110(5) Uani 1 1 d . . . . .
O7 O 0.1311(2) 0.1294(2) 0.72400(10) 0.0111(5) Uani 1 1 d . . . . .
O8 O 0.2226(2) -0.0800(2) 0.77845(10) 0.0124(5) Uani 1 1 d . . . . .
O9 O 1.0323(2) 0.1776(2) 0.59795(10) 0.0160(5) Uani 1 1 d . . . . .
O10 O 0.8317(2) 0.1964(2) 0.59403(10) 0.0179(6) Uani 1 1 d . . . . .
O11 O 0.8927(2) 0.2627(2) 0.28405(10) 0.0164(5) Uani 1 1 d . . . . .
O12 O 0.9734(2) 0.0437(2) 0.30577(10) 0.0106(5) Uani 1 1 d . . . . .
O13 O 1.2921(2) -0.3529(2) 0.82076(11) 0.0161(5) Uani 1 1 d . . . . .
O14 O 1.0473(2) -0.3692(2) 0.83415(12) 0.0207(6) Uani 1 1 d . . . . .
O15 O 0.9283(2) 0.3969(2) 0.66107(12) 0.0201(6) Uani 1 1 d . . . . .
O16 O 0.6856(2) 0.3836(2) 0.67676(11) 0.0154(5) Uani 1 1 d . . . . .
N1 N 1.4619(3) -0.5596(3) 0.81847(14) 0.0173(7) Uani 1 1 d . . . . .
N2 N 0.8703(3) -0.4053(3) 0.85821(17) 0.0272(8) Uani 1 1 d . . . . .
N3 N 1.1061(3) 0.4359(3) 0.64799(16) 0.0255(8) Uani 1 1 d . . . . .
N4 N 0.5208(3) 0.5899(3) 0.68432(14) 0.0189(7) Uani 1 1 d . . . . .
C1 C 0.9120(3) 0.1821(3) 0.81870(15) 0.0106(7) Uani 1 1 d . . . . .
C2 C 0.9235(3) 0.1804(3) 0.88312(14) 0.0114(7) Uani 1 1 d . . . . .
C3 C 0.8457(3) 0.1435(3) 0.92139(15) 0.0120(7) Uani 1 1 d . . . . .
H3 H 0.786247 0.117554 0.907057 0.014 Uiso 1 1 calc R U . . .
C4 C 0.8535(3) 0.1437(3) 0.98201(15) 0.0121(7) Uani 1 1 d . . . . .
H4 H 0.797138 0.120172 1.007796 0.015 Uiso 1 1 calc R U . . .
C5 C 0.9407(3) 0.1772(3) 1.00465(14) 0.0105(7) Uani 1 1 d . . . . .
C6 C 0.9430(3) 0.1677(3) 1.07075(14) 0.0107(7) Uani 1 1 d . . . . .
C7 C 1.0153(3) 0.2157(3) 0.90440(14) 0.0104(7) Uani 1 1 d . . . . .
C8 C 1.0262(3) 0.2134(3) 0.96599(15) 0.0114(7) Uani 1 1 d . . . . .
C9 C 1.1211(3) 0.2476(3) 0.98511(15) 0.0154(7) Uani 1 1 d . . . . .
H9 H 1.130238 0.246801 1.025791 0.019 Uiso 1 1 calc R U . . .
C10 C 1.1997(4) 0.2817(4) 0.94594(17) 0.0195(8) Uani 1 1 d . . . . .
H10 H 1.261771 0.305035 0.959769 0.023 Uiso 1 1 calc R U . . .
C11 C 1.1894(3) 0.2823(4) 0.88570(16) 0.0182(8) Uani 1 1 d . . . . .
H11 H 1.245257 0.304673 0.859092 0.022 Uiso 1 1 calc R U . . .
C12 C 1.0992(3) 0.2510(3) 0.86525(16) 0.0163(7) Uani 1 1 d . . . . .
H12 H 1.092313 0.252708 0.824311 0.020 Uiso 1 1 calc R U . . .
C13 C 0.7471(3) 0.0097(3) 0.74910(15) 0.0113(7) Uani 1 1 d . . . . .
C14 C 0.6109(3) 0.0164(3) 0.75361(15) 0.0130(7) Uani 1 1 d . . . . .
C15 C 0.5308(3) 0.0629(4) 0.70278(16) 0.0171(8) Uani 1 1 d . . . . .
H15 H 0.560815 0.092074 0.666476 0.021 Uiso 1 1 calc R U . . .
C16 C 0.4047(3) 0.0677(4) 0.70404(16) 0.0164(8) Uani 1 1 d . . . . .
H16 H 0.350546 0.100952 0.668555 0.020 Uiso 1 1 calc R U . . .
C17 C 0.3593(3) 0.0257(3) 0.75496(15) 0.0111(7) Uani 1 1 d . . . . .
C18 C 0.2266(3) 0.0256(3) 0.75255(14) 0.0095(7) Uani 1 1 d . . . . .
C19 C 0.4360(3) -0.0176(3) 0.80981(15) 0.0112(7) Uani 1 1 d . . . . .
C20 C 0.5637(3) -0.0209(3) 0.80860(15) 0.0107(7) Uani 1 1 d . . . . .
C21 C 0.6344(3) -0.0520(3) 0.86355(16) 0.0168(8) Uani 1 1 d . . . . .
H21 H 0.719878 -0.056605 0.863797 0.020 Uiso 1 1 calc R U . . .
C22 C 0.5802(3) -0.0753(4) 0.91594(16) 0.0224(9) Uani 1 1 d . . . . .
H22 H 0.627244 -0.092423 0.952082 0.027 Uiso 1 1 calc R U . . .
C23 C 0.4560(4) -0.0741(4) 0.91704(17) 0.0255(9) Uani 1 1 d . . . . .
H23 H 0.419999 -0.090630 0.953753 0.031 Uiso 1 1 calc R U . . .
C24 C 0.3867(3) -0.0492(4) 0.86514(16) 0.0184(8) Uani 1 1 d . . . . .
H24 H 0.305041 -0.053026 0.866203 0.022 Uiso 1 1 calc R U . . .
C25 C 0.9369(3) 0.1861(3) 0.56916(15) 0.0141(7) Uani 1 1 d . . . . .
C26 C 0.9437(3) 0.1818(3) 0.50424(15) 0.0131(7) Uani 1 1 d . . . . .
C27 C 0.8569(3) 0.1477(3) 0.48162(15) 0.0138(7) Uani 1 1 d . . . . .
H27 H 0.794310 0.133091 0.506496 0.017 Uiso 1 1 calc R U . . .
C28 C 0.8587(3) 0.1339(3) 0.42257(15) 0.0137(7) Uani 1 1 d . . . . .
H28 H 0.799516 0.107465 0.408366 0.016 Uiso 1 1 calc R U . . .
C29 C 0.9454(3) 0.1583(3) 0.38547(15) 0.0104(7) Uani 1 1 d . . . . .
C30 C 0.9371(3) 0.1546(3) 0.32127(15) 0.0106(7) Uani 1 1 d . . . . .
C31 C 1.0383(3) 0.2048(3) 0.46679(15) 0.0138(7) Uani 1 1 d . . . . .
C32 C 1.0379(3) 0.1935(3) 0.40662(15) 0.0136(7) Uani 1 1 d . . . . .
C33 C 1.1304(3) 0.2158(4) 0.36871(16) 0.0186(8) Uani 1 1 d . . . . .
H33 H 1.131436 0.205583 0.328920 0.022 Uiso 1 1 calc R U . . .
C34 C 1.2177(4) 0.2515(4) 0.38853(18) 0.0259(9) Uani 1 1 d . . . . .
H34 H 1.278828 0.266491 0.362696 0.031 Uiso 1 1 calc R U . . .
C35 C 1.2166(4) 0.2661(5) 0.44768(19) 0.0302(10) Uani 1 1 d . . . . .
H35 H 1.276364 0.292543 0.461273 0.036 Uiso 1 1 calc R U . . .
C36 C 1.1309(4) 0.2426(4) 0.48582(18) 0.0244(9) Uani 1 1 d . . . . .
H36 H 1.133037 0.251733 0.525608 0.029 Uiso 1 1 calc R U . . .
C37 C 1.3358(3) -0.4674(3) 0.81047(15) 0.0148(7) Uani 1 1 d . . . . .
H37 H 1.274410 -0.490529 0.795831 0.018 Uiso 1 1 calc R U . . .
C38 C 1.5063(4) -0.6932(4) 0.8059(2) 0.0310(10) Uani 1 1 d . . . . .
H38A H 1.431461 -0.697364 0.788865 0.047 Uiso 1 1 calc R U . . .
H38B H 1.540573 -0.760705 0.842638 0.047 Uiso 1 1 calc R U . . .
H38C H 1.576860 -0.711239 0.777881 0.047 Uiso 1 1 calc R U . . .
C39 C 1.5614(3) -0.5333(4) 0.84227(18) 0.0231(9) Uani 1 1 d . . . . .
H39A H 1.588603 -0.584303 0.882874 0.035 Uiso 1 1 calc R U . . .
H39B H 1.523842 -0.437054 0.841978 0.035 Uiso 1 1 calc R U . . .
H39C H 1.638889 -0.560819 0.817961 0.035 Uiso 1 1 calc R U . . .
C40 C 0.9767(3) -0.3962(3) 0.87072(17) 0.0181(8) Uani 1 1 d . . . . .
H40 H 1.001350 -0.411597 0.911269 0.022 Uiso 1 1 calc R U . . .
C41 C 0.8241(5) -0.3808(5) 0.7975(2) 0.0516(16) Uani 1 1 d . . . . .
H41A H 0.882332 -0.356769 0.770888 0.077 Uiso 1 1 calc R U . . .
H41B H 0.733126 -0.306939 0.791065 0.077 Uiso 1 1 calc R U . . .
H41C H 0.825444 -0.462220 0.789532 0.077 Uiso 1 1 calc R U . . .
C42 C 0.7935(5) -0.4378(5) 0.9047(3) 0.0514(15) Uani 1 1 d . . . . .
H42A H 0.701782 -0.365402 0.900292 0.077 Uiso 1 1 calc R U . . .
H42B H 0.832943 -0.447733 0.943278 0.077 Uiso 1 1 calc R U . . .
H42C H 0.794045 -0.522167 0.901837 0.077 Uiso 1 1 calc R U . . .
C43 C 1.0093(4) 0.4193(3) 0.62931(18) 0.0197(8) Uani 1 1 d . . . . .
H43 H 1.000212 0.424925 0.588120 0.024 Uiso 1 1 calc R U . . .
C44 C 1.1967(4) 0.4598(5) 0.6066(3) 0.0516(16) Uani 1 1 d . . . . .
H44A H 1.170585 0.461826 0.566478 0.077 Uiso 1 1 calc R U . . .
H44B H 1.287497 0.387619 0.617123 0.077 Uiso 1 1 calc R U . . .
H44C H 1.193028 0.546197 0.608238 0.077 Uiso 1 1 calc R U . . .
C45 C 1.1292(5) 0.4276(4) 0.7098(2) 0.0468(14) Uani 1 1 d . . . . .
H45A H 1.219395 0.356993 0.722977 0.070 Uiso 1 1 calc R U . . .
H45B H 1.064700 0.406177 0.732755 0.070 Uiso 1 1 calc R U . . .
H45C H 1.119106 0.513976 0.715727 0.070 Uiso 1 1 calc R U . . .
C46 C 0.6471(3) 0.4948(3) 0.69015(15) 0.0142(7) Uani 1 1 d . . . . .
H46 H 0.711387 0.513175 0.705467 0.017 Uiso 1 1 calc R U . . .
C47 C 0.4180(3) 0.5684(4) 0.66007(19) 0.0278(10) Uani 1 1 d . . . . .
H47A H 0.451836 0.472348 0.660945 0.042 Uiso 1 1 calc R U . . .
H47B H 0.393454 0.618462 0.619220 0.042 Uiso 1 1 calc R U . . .
H47C H 0.339758 0.599940 0.683758 0.042 Uiso 1 1 calc R U . . .
C48 C 0.4798(4) 0.7185(4) 0.70148(19) 0.0266(9) Uani 1 1 d . . . . .
H48A H 0.439045 0.791624 0.666997 0.040 Uiso 1 1 calc R U . . .
H48B H 0.557586 0.720428 0.716851 0.040 Uiso 1 1 calc R U . . .
H48C H 0.415198 0.729958 0.732111 0.040 Uiso 1 1 calc R U . . .
O18 O 0.3998(6) 0.5025(7) 0.4750(3) 0.054(2) Uani 0.5 1 d . U P A -1
N52 N 0.5242(9) 0.3235(11) 0.5543(5) 0.070(3) Uani 0.5 1 d D U P A -1
C53 C 0.5043(9) 0.4417(10) 0.5207(4) 0.039(2) Uani 0.5 1 d . U P A -1
H53 H 0.556717 0.483286 0.526815 0.047 Uiso 0.5 1 calc R U P A -1
C55 C 0.585(2) 0.290(2) 0.6083(9) 0.203(10) Uani 0.5 1 d D U P A -1
H55A H 0.668918 0.206441 0.611013 0.305 Uiso 0.5 1 calc R U P A -1
H55B H 0.527295 0.276194 0.638684 0.305 Uiso 0.5 1 calc R U P A -1
H55C H 0.603463 0.361984 0.614463 0.305 Uiso 0.5 1 calc R U P A -1
C56 C 0.4593(8) 0.2558(10) 0.5531(4) 0.040(2) Uani 0.5 1 d D U P A -1
H56A H 0.371091 0.316031 0.533623 0.061 Uiso 0.5 1 calc R U P A -1
H56B H 0.449678 0.216521 0.593571 0.061 Uiso 0.5 1 calc R U P A -1
H56C H 0.508061 0.183923 0.531228 0.061 Uiso 0.5 1 calc R U P A -1
O20 O 0.4330(8) 0.3586(8) 0.9813(4) 0.066(2) Uani 0.5 1 d . U P B -1
N17 N 0.5215(11) 0.4846(15) 1.0026(8) 0.026(2) Uani 0.5 1 d . U P B -1
C49 C 0.4143(12) 0.5969(12) 0.9675(5) 0.072(4) Uani 0.5 1 d . U P B -1
H49A H 0.448335 0.630403 0.931832 0.108 Uiso 0.5 1 calc R U P B -1
H49B H 0.370405 0.668127 0.990108 0.108 Uiso 0.5 1 calc R U P B -1
H49C H 0.350261 0.569478 0.956180 0.108 Uiso 0.5 1 calc R U P B -1
C50 C 0.6141(9) 0.5048(10) 1.0320(4) 0.037(2) Uani 0.5 1 d . U P B -1
H50A H 0.679877 0.511017 1.004464 0.056 Uiso 0.5 1 calc R U P B -1
H50B H 0.658944 0.429218 1.065149 0.056 Uiso 0.5 1 calc R U P B -1
H50C H 0.567767 0.588392 1.046870 0.056 Uiso 0.5 1 calc R U P B -1
C51 C 0.5315(9) 0.3531(10) 1.0159(5) 0.039(2) Uani 0.5 1 d . U P B -1
H51 H 0.593495 0.277193 1.043030 0.047 Uiso 0.5 1 calc R U P B -1
O21 O 0.5742(10) 0.1192(13) 0.4331(6) 0.125(5) Uani 0.5 1 d . U P C -2
N53 N 0.4907(14) 0.0309(9) 0.5061(6) 0.049(3) Uani 0.5 1 d . U P C -2
C52 C 0.5161(15) 0.1023(14) 0.5434(7) 0.088(4) Uani 0.5 1 d . U P C -2
H52A H 0.588952 0.038845 0.572298 0.131 Uiso 0.5 1 calc R U P C -2
H52B H 0.436025 0.149767 0.564075 0.131 Uiso 0.5 1 calc R U P C -2
H52C H 0.540920 0.167357 0.519443 0.131 Uiso 0.5 1 calc R U P C -2
C54 C 0.5305(16) 0.031(2) 0.4490(8) 0.079(5) Uani 0.5 1 d . U P C -2
H54 H 0.526591 -0.024459 0.424701 0.095 Uiso 0.5 1 calc R U P C -2
C58 C 0.4242(16) -0.0436(14) 0.5316(7) 0.068(4) Uani 0.5 1 d . U P C -2
H58A H 0.330508 0.018115 0.535330 0.102 Uiso 0.5 1 calc R U P C -2
H58B H 0.465590 -0.095345 0.570783 0.102 Uiso 0.5 1 calc R U P C -2
H58C H 0.430496 -0.105246 0.506345 0.102 Uiso 0.5 1 calc R U P C -2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 Eu2 4.0374(4) . ?
Eu1 O2 2.383(2) . ?
Eu1 O3 2.485(2) 2_757 ?
Eu1 O4 2.454(2) 2_757 ?
Eu1 O6 2.399(2) . ?
Eu1 O8 2.370(2) 1_655 ?
Eu1 O11 2.501(2) 2_756 ?
Eu1 O12 2.633(2) 2_756 ?
Eu1 O13 2.439(2) . ?
Eu1 O14 2.437(2) . ?
Eu1 C6 2.836(3) 2_757 ?
Eu1 C30 2.936(3) 2_756 ?
Eu2 O1 2.534(2) . ?
Eu2 O2 2.618(2) . ?
Eu2 O5 2.388(2) . ?
Eu2 O7 2.400(2) 1_655 ?
Eu2 O9 2.497(2) . ?
Eu2 O10 2.422(2) . ?
Eu2 O12 2.377(2) 2_756 ?
Eu2 O15 2.423(2) . ?
Eu2 O16 2.453(2) . ?
Eu2 C1 2.947(3) . ?
Eu2 C25 2.824(3) . ?
O1 C1 1.255(4) . ?
O2 C1 1.268(4) . ?
O3 C6 1.264(4) . ?
O4 C6 1.259(4) . ?
O5 C13 1.259(4) . ?
O6 C13 1.259(4) . ?
O7 C18 1.259(4) . ?
O8 C18 1.259(4) . ?
O9 C25 1.254(4) . ?
O10 C25 1.270(4) . ?
O11 C30 1.252(4) . ?
O12 C30 1.264(4) . ?
O13 C37 1.240(4) . ?
O14 C40 1.234(4) . ?
O15 C43 1.241(4) . ?
O16 C46 1.241(4) . ?
N1 C37 1.322(4) . ?
N1 C38 1.460(4) . ?
N1 C39 1.456(5) . ?
N2 C40 1.312(5) . ?
N2 C41 1.450(6) . ?
N2 C42 1.455(6) . ?
N3 C43 1.307(5) . ?
N3 C44 1.458(5) . ?
N3 C45 1.443(6) . ?
N4 C46 1.333(4) . ?
N4 C47 1.458(5) . ?
N4 C48 1.459(5) . ?
C1 C2 1.498(5) . ?
C2 C3 1.370(5) . ?
C2 C7 1.420(5) . ?
C3 H3 0.9500 . ?
C3 C4 1.411(5) . ?
C4 H4 0.9500 . ?
C4 C5 1.374(5) . ?
C5 C6 1.512(4) . ?
C5 C8 1.438(5) . ?
C7 C8 1.431(5) . ?
C7 C12 1.425(5) . ?
C8 C9 1.421(5) . ?
C9 H9 0.9500 . ?
C9 C10 1.373(5) . ?
C10 H10 0.9500 . ?
C10 C11 1.403(5) . ?
C11 H11 0.9500 . ?
C11 C12 1.363(5) . ?
C12 H12 0.9500 . ?
C13 C14 1.515(4) . ?
C14 C15 1.377(5) . ?
C14 C20 1.423(5) . ?
C15 H15 0.9500 . ?
C15 C16 1.410(5) . ?
C16 H16 0.9500 . ?
C16 C17 1.356(5) . ?
C17 C18 1.514(4) . ?
C17 C19 1.438(4) . ?
C19 C20 1.435(4) . ?
C19 C24 1.423(5) . ?
C20 C21 1.427(5) . ?
C21 H21 0.9500 . ?
C21 C22 1.370(5) . ?
C22 H22 0.9500 . ?
C22 C23 1.406(5) . ?
C23 H23 0.9500 . ?
C23 C24 1.373(5) . ?
C24 H24 0.9500 . ?
C25 C26 1.511(5) . ?
C26 C27 1.374(5) . ?
C26 C31 1.439(5) . ?
C27 H27 0.9500 . ?
C27 C28 1.405(5) . ?
C28 H28 0.9500 . ?
C28 C29 1.368(5) . ?
C29 C30 1.503(4) . ?
C29 C32 1.426(5) . ?
C31 C32 1.425(5) . ?
C31 C36 1.426(5) . ?
C32 C33 1.421(5) . ?
C33 H33 0.9500 . ?
C33 C34 1.364(5) . ?
C34 H34 0.9500 . ?
C34 C35 1.411(6) . ?
C35 H35 0.9500 . ?
C35 C36 1.369(5) . ?
C36 H36 0.9500 . ?
C37 H37 0.9500 . ?
C38 H38A 0.9800 . ?
C38 H38B 0.9800 . ?
C38 H38C 0.9800 . ?
C39 H39A 0.9800 . ?
C39 H39B 0.9800 . ?
C39 H39C 0.9800 . ?
C40 H40 0.9500 . ?
C41 H41A 0.9800 . ?
C41 H41B 0.9800 . ?
C41 H41C 0.9800 . ?
C42 H42A 0.9800 . ?
C42 H42B 0.9800 . ?
C42 H42C 0.9800 . ?
C43 H43 0.9500 . ?
C44 H44A 0.9800 . ?
C44 H44B 0.9800 . ?
C44 H44C 0.9800 . ?
C45 H45A 0.9800 . ?
C45 H45B 0.9800 . ?
C45 H45C 0.9800 . ?
C46 H46 0.9500 . ?
C47 H47A 0.9800 . ?
C47 H47B 0.9800 . ?
C47 H47C 0.9800 . ?
C48 H48A 0.9800 . ?
C48 H48B 0.9800 . ?
C48 H48C 0.9800 . ?
O18 C53 1.438(10) . ?
N52 C53 1.343(14) . ?
N52 C55 1.354(14) . ?
N52 C56 1.301(11) . ?
C53 H53 0.9500 . ?
C55 H55A 0.9800 . ?
C55 H55B 0.9800 . ?
C55 H55C 0.9800 . ?
C56 H56A 0.9800 . ?
C56 H56B 0.9800 . ?
C56 H56C 0.9800 . ?
O20 C51 1.376(12) . ?
N17 C49 1.422(14) . ?
N17 C50 1.407(18) . ?
N17 C51 1.429(19) . ?
C49 H49A 0.9800 . ?
C49 H49B 0.9800 . ?
C49 H49C 0.9800 . ?
C50 H50A 0.9800 . ?
C50 H50B 0.9800 . ?
C50 H50C 0.9800 . ?
C51 H51 0.9500 . ?
O21 C54 1.30(2) . ?
N53 C52 1.421(17) . ?
N53 C54 1.38(2) . ?
N53 C58 1.42(2) . ?
C52 H52A 0.9800 . ?
C52 H52B 0.9800 . ?
C52 H52C 0.9800 . ?
C54 H54 0.9500 . ?
C58 H58A 0.9800 . ?
C58 H58B 0.9800 . ?
C58 H58C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O2 Eu1 Eu2 38.18(5) . . ?
O2 Eu1 O3 79.47(8) . 2_757 ?
O2 Eu1 O4 83.75(8) . 2_757 ?
O2 Eu1 O6 73.28(8) . . ?
O2 Eu1 O11 122.11(7) . 2_756 ?
O2 Eu1 O12 72.37(7) . 2_756 ?
O2 Eu1 O13 142.90(8) . . ?
O2 Eu1 O14 141.55(8) . . ?
O2 Eu1 C6 81.48(8) . 2_757 ?
O2 Eu1 C30 97.31(8) . 2_756 ?
O3 Eu1 Eu2 114.33(5) 2_757 . ?
O3 Eu1 O11 142.17(8) 2_757 2_756 ?
O3 Eu1 O12 142.62(7) 2_757 2_756 ?
O3 Eu1 C6 26.46(8) 2_757 2_757 ?
O3 Eu1 C30 150.00(8) 2_757 2_756 ?
O4 Eu1 Eu2 116.77(6) 2_757 . ?
O4 Eu1 O3 52.73(7) 2_757 2_757 ?
O4 Eu1 O11 148.40(7) 2_757 2_756 ?
O4 Eu1 O12 143.24(8) 2_757 2_756 ?
O4 Eu1 C6 26.30(8) 2_757 2_757 ?
O4 Eu1 C30 157.16(8) 2_757 2_756 ?
O6 Eu1 Eu2 68.23(5) . . ?
O6 Eu1 O3 77.74(7) . 2_757 ?
O6 Eu1 O4 128.53(8) . 2_757 ?
O6 Eu1 O11 79.85(8) . 2_756 ?
O6 Eu1 O12 71.02(7) . 2_756 ?
O6 Eu1 O13 143.38(8) . . ?
O6 Eu1 O14 76.01(8) . . ?
O6 Eu1 C6 103.54(9) . 2_757 ?
O6 Eu1 C30 72.84(8) . 2_756 ?
O8 Eu1 Eu2 66.77(5) 1_655 . ?
O8 Eu1 O2 74.58(8) 1_655 . ?
O8 Eu1 O3 125.90(8) 1_655 2_757 ?
O8 Eu1 O4 77.65(8) 1_655 2_757 ?
O8 Eu1 O6 134.74(7) 1_655 . ?
O8 Eu1 O11 91.30(8) 1_655 2_756 ?
O8 Eu1 O12 69.40(7) 1_655 2_756 ?
O8 Eu1 O13 71.66(8) 1_655 . ?
O8 Eu1 O14 143.54(8) 1_655 . ?
O8 Eu1 C6 102.25(9) 1_655 2_757 ?
O8 Eu1 C30 80.64(9) 1_655 2_756 ?
O11 Eu1 Eu2 84.36(5) 2_756 . ?
O11 Eu1 O12 50.45(7) 2_756 2_756 ?
O11 Eu1 C6 155.55(8) 2_756 2_757 ?
O11 Eu1 C30 25.01(8) 2_756 2_756 ?
O12 Eu1 Eu2 34.19(5) 2_756 . ?
O12 Eu1 C6 153.78(8) 2_756 2_757 ?
O12 Eu1 C30 25.49(8) 2_756 2_756 ?
O13 Eu1 Eu2 132.22(6) . . ?
O13 Eu1 O3 108.60(8) . 2_757 ?
O13 Eu1 O4 74.50(8) . 2_757 ?
O13 Eu1 O11 73.93(8) . 2_756 ?
O13 Eu1 O12 108.70(8) . 2_756 ?
O13 Eu1 C6 90.97(9) . 2_757 ?
O13 Eu1 C30 92.02(8) . 2_756 ?
O14 Eu1 Eu2 140.63(6) . . ?
O14 Eu1 O3 71.82(8) . 2_757 ?
O14 Eu1 O4 98.05(9) . 2_757 ?
O14 Eu1 O11 73.42(9) . 2_756 ?
O14 Eu1 O12 118.09(8) . 2_756 ?
O14 Eu1 O13 72.33(8) . . ?
O14 Eu1 C6 83.82(9) . 2_757 ?
O14 Eu1 C30 95.15(9) . 2_756 ?
C6 Eu1 Eu2 119.61(6) 2_757 . ?
C6 Eu1 C30 176.38(9) 2_757 2_756 ?
C30 Eu1 Eu2 59.38(6) 2_756 . ?
O1 Eu2 Eu1 84.35(5) . . ?
O1 Eu2 O2 50.46(7) . . ?
O1 Eu2 C1 25.06(8) . . ?
O1 Eu2 C25 156.94(9) . . ?
O2 Eu2 Eu1 34.25(5) . . ?
O2 Eu2 C1 25.47(8) . . ?
O2 Eu2 C25 151.89(8) . . ?
O5 Eu2 Eu1 67.72(5) . . ?
O5 Eu2 O1 90.76(8) . . ?
O5 Eu2 O2 69.30(7) . . ?
O5 Eu2 O7 135.73(7) . 1_655 ?
O5 Eu2 O9 126.85(8) . . ?
O5 Eu2 O10 79.45(8) . . ?
O5 Eu2 O15 142.34(8) . . ?
O5 Eu2 O16 71.35(8) . . ?
O5 Eu2 C1 80.44(9) . . ?
O5 Eu2 C25 103.60(9) . . ?
O7 Eu2 Eu1 68.56(5) 1_655 . ?
O7 Eu2 O1 78.42(8) 1_655 . ?
O7 Eu2 O2 70.93(7) 1_655 . ?
O7 Eu2 O9 76.31(8) 1_655 . ?
O7 Eu2 O10 128.28(8) 1_655 . ?
O7 Eu2 O15 75.97(8) 1_655 . ?
O7 Eu2 O16 140.79(8) 1_655 . ?
O7 Eu2 C1 71.77(8) 1_655 . ?
O7 Eu2 C25 102.24(9) 1_655 . ?
O9 Eu2 Eu1 111.42(5) . . ?
O9 Eu2 O1 142.18(8) . . ?
O9 Eu2 O2 139.87(7) . . ?
O9 Eu2 C1 147.92(8) . . ?
O9 Eu2 C25 26.36(9) . . ?
O10 Eu2 Eu1 117.65(6) . . ?
O10 Eu2 O1 149.11(7) . . ?
O10 Eu2 O2 144.45(8) . . ?
O10 Eu2 O9 52.98(8) . . ?
O10 Eu2 O15 95.34(9) . . ?
O10 Eu2 O16 76.32(8) . . ?
O10 Eu2 C1 158.87(9) . . ?
O10 Eu2 C25 26.62(9) . . ?
O12 Eu2 Eu1 38.50(5) 2_756 . ?
O12 Eu2 O1 122.63(7) 2_756 . ?
O12 Eu2 O2 72.74(7) 2_756 . ?
O12 Eu2 O5 74.41(8) 2_756 . ?
O12 Eu2 O7 75.97(8) 2_756 1_655 ?
O12 Eu2 O9 77.40(8) 2_756 . ?
O12 Eu2 O10 83.10(8) 2_756 . ?
O12 Eu2 O15 142.52(8) 2_756 . ?
O12 Eu2 O16 142.59(8) 2_756 . ?
O12 Eu2 C1 97.71(8) 2_756 . ?
O12 Eu2 C25 79.15(8) 2_756 . ?
O15 Eu2 Eu1 141.72(6) . . ?
O15 Eu2 O1 74.68(8) . . ?
O15 Eu2 O2 119.71(8) . . ?
O15 Eu2 O9 72.20(8) . . ?
O15 Eu2 O16 71.19(8) . . ?
O15 Eu2 C1 96.58(9) . . ?
O15 Eu2 C25 83.07(10) . . ?
O16 Eu2 Eu1 132.38(6) . . ?
O16 Eu2 O1 72.78(7) . . ?
O16 Eu2 O2 107.84(7) . . ?
O16 Eu2 O9 112.18(8) . . ?
O16 Eu2 C1 91.12(8) . . ?
O16 Eu2 C25 94.56(9) . . ?
C1 Eu2 Eu1 59.31(6) . . ?
C25 Eu2 Eu1 117.64(6) . . ?
C25 Eu2 C1 173.85(9) . . ?
C1 O1 Eu2 96.2(2) . . ?
Eu1 O2 Eu2 107.57(8) . . ?
C1 O2 Eu1 156.8(2) . . ?
C1 O2 Eu2 91.91(19) . . ?
C6 O3 Eu1 92.4(2) . 2_757 ?
C6 O4 Eu1 94.02(19) . 2_757 ?
C13 O5 Eu2 139.0(2) . . ?
C13 O6 Eu1 136.7(2) . . ?
C18 O7 Eu2 136.3(2) . 1_455 ?
C18 O8 Eu1 140.82(19) . 1_455 ?
C25 O9 Eu2 91.5(2) . . ?
C25 O10 Eu2 94.6(2) . . ?
C30 O11 Eu1 97.4(2) . 2_756 ?
Eu2 O12 Eu1 107.30(8) 2_756 2_756 ?
C30 O12 Eu1 90.80(19) . 2_756 ?
C30 O12 Eu2 158.8(2) . 2_756 ?
C37 O13 Eu1 130.8(2) . . ?
C40 O14 Eu1 129.5(2) . . ?
C43 O15 Eu2 129.8(2) . . ?
C46 O16 Eu2 128.5(2) . . ?
C37 N1 C38 121.7(3) . . ?
C37 N1 C39 121.1(3) . . ?
C39 N1 C38 117.2(3) . . ?
C40 N2 C41 121.0(4) . . ?
C40 N2 C42 121.2(4) . . ?
C41 N2 C42 117.8(4) . . ?
C43 N3 C44 120.4(4) . . ?
C43 N3 C45 121.6(4) . . ?
C45 N3 C44 118.0(4) . . ?
C46 N4 C47 120.5(3) . . ?
C46 N4 C48 122.0(3) . . ?
C47 N4 C48 117.5(3) . . ?
O1 C1 Eu2 58.75(18) . . ?
O1 C1 O2 121.1(3) . . ?
O1 C1 C2 119.6(3) . . ?
O2 C1 Eu2 62.62(18) . . ?
O2 C1 C2 119.2(3) . . ?
C2 C1 Eu2 174.8(2) . . ?
C3 C2 C1 119.5(3) . . ?
C3 C2 C7 120.3(3) . . ?
C7 C2 C1 120.2(3) . . ?
C2 C3 H3 119.9 . . ?
C2 C3 C4 120.2(3) . . ?
C4 C3 H3 119.9 . . ?
C3 C4 H4 119.2 . . ?
C5 C4 C3 121.6(3) . . ?
C5 C4 H4 119.2 . . ?
C4 C5 C6 116.1(3) . . ?
C4 C5 C8 119.7(3) . . ?
C8 C5 C6 124.1(3) . . ?
O3 C6 Eu1 61.11(17) . 2_757 ?
O3 C6 C5 121.2(3) . . ?
O4 C6 Eu1 59.68(17) . 2_757 ?
O4 C6 O3 120.7(3) . . ?
O4 C6 C5 118.1(3) . . ?
C5 C6 Eu1 176.4(2) . 2_757 ?
C2 C7 C8 120.0(3) . . ?
C2 C7 C12 120.8(3) . . ?
C12 C7 C8 119.2(3) . . ?
C7 C8 C5 118.2(3) . . ?
C9 C8 C5 124.1(3) . . ?
C9 C8 C7 117.7(3) . . ?
C8 C9 H9 119.3 . . ?
C10 C9 C8 121.3(3) . . ?
C10 C9 H9 119.3 . . ?
C9 C10 H10 119.7 . . ?
C9 C10 C11 120.6(3) . . ?
C11 C10 H10 119.7 . . ?
C10 C11 H11 119.9 . . ?
C12 C11 C10 120.2(3) . . ?
C12 C11 H11 119.9 . . ?
C7 C12 H12 119.5 . . ?
C11 C12 C7 120.9(3) . . ?
C11 C12 H12 119.5 . . ?
O5 C13 O6 126.7(3) . . ?
O5 C13 C14 115.9(3) . . ?
O6 C13 C14 117.4(3) . . ?
C15 C14 C13 118.2(3) . . ?
C15 C14 C20 119.9(3) . . ?
C20 C14 C13 121.9(3) . . ?
C14 C15 H15 119.7 . . ?
C14 C15 C16 120.7(3) . . ?
C16 C15 H15 119.7 . . ?
C15 C16 H16 119.4 . . ?
C17 C16 C15 121.2(3) . . ?
C17 C16 H16 119.4 . . ?
C16 C17 C18 118.5(3) . . ?
C16 C17 C19 120.4(3) . . ?
C19 C17 C18 121.1(3) . . ?
O7 C18 O8 125.9(3) . . ?
O7 C18 C17 117.4(3) . . ?
O8 C18 C17 116.7(3) . . ?
C20 C19 C17 118.3(3) . . ?
C24 C19 C17 122.5(3) . . ?
C24 C19 C20 119.1(3) . . ?
C14 C20 C19 119.4(3) . . ?
C14 C20 C21 122.3(3) . . ?
C21 C20 C19 118.2(3) . . ?
C20 C21 H21 119.6 . . ?
C22 C21 C20 120.7(3) . . ?
C22 C21 H21 119.6 . . ?
C21 C22 H22 119.5 . . ?
C21 C22 C23 121.0(3) . . ?
C23 C22 H22 119.5 . . ?
C22 C23 H23 119.9 . . ?
C24 C23 C22 120.1(4) . . ?
C24 C23 H23 119.9 . . ?
C19 C24 H24 119.7 . . ?
C23 C24 C19 120.7(3) . . ?
C23 C24 H24 119.7 . . ?
O9 C25 Eu2 62.14(18) . . ?
O9 C25 O10 120.9(3) . . ?
O9 C25 C26 121.5(3) . . ?
O10 C25 Eu2 58.74(18) . . ?
O10 C25 C26 117.6(3) . . ?
C26 C25 Eu2 176.2(3) . . ?
C27 C26 C25 116.5(3) . . ?
C27 C26 C31 119.6(3) . . ?
C31 C26 C25 123.8(3) . . ?
C26 C27 H27 119.2 . . ?
C26 C27 C28 121.6(3) . . ?
C28 C27 H27 119.2 . . ?
C27 C28 H28 119.9 . . ?
C29 C28 C27 120.2(3) . . ?
C29 C28 H28 119.9 . . ?
C28 C29 C30 119.2(3) . . ?
C28 C29 C32 120.6(3) . . ?
C32 C29 C30 120.2(3) . . ?
O11 C30 Eu1 57.63(18) . 2_756 ?
O11 C30 O12 121.2(3) . . ?
O11 C30 C29 118.9(3) . . ?
O12 C30 Eu1 63.70(18) . 2_756 ?
O12 C30 C29 120.0(3) . . ?
C29 C30 Eu1 174.9(2) . 2_756 ?
C32 C31 C26 118.6(3) . . ?
C32 C31 C36 117.5(3) . . ?
C36 C31 C26 123.8(3) . . ?
C31 C32 C29 119.4(3) . . ?
C33 C32 C29 120.9(3) . . ?
C33 C32 C31 119.8(3) . . ?
C32 C33 H33 119.5 . . ?
C34 C33 C32 121.1(3) . . ?
C34 C33 H33 119.5 . . ?
C33 C34 H34 120.3 . . ?
C33 C34 C35 119.5(4) . . ?
C35 C34 H34 120.3 . . ?
C34 C35 H35 119.5 . . ?
C36 C35 C34 121.1(4) . . ?
C36 C35 H35 119.5 . . ?
C31 C36 H36 119.5 . . ?
C35 C36 C31 121.1(4) . . ?
C35 C36 H36 119.5 . . ?
O13 C37 N1 124.5(4) . . ?
O13 C37 H37 117.7 . . ?
N1 C37 H37 117.7 . . ?
N1 C38 H38A 109.5 . . ?
N1 C38 H38B 109.5 . . ?
N1 C38 H38C 109.5 . . ?
H38A C38 H38B 109.5 . . ?
H38A C38 H38C 109.5 . . ?
H38B C38 H38C 109.5 . . ?
N1 C39 H39A 109.5 . . ?
N1 C39 H39B 109.5 . . ?
N1 C39 H39C 109.5 . . ?
H39A C39 H39B 109.5 . . ?
H39A C39 H39C 109.5 . . ?
H39B C39 H39C 109.5 . . ?
O14 C40 N2 125.3(4) . . ?
O14 C40 H40 117.3 . . ?
N2 C40 H40 117.3 . . ?
N2 C41 H41A 109.5 . . ?
N2 C41 H41B 109.5 . . ?
N2 C41 H41C 109.5 . . ?
H41A C41 H41B 109.5 . . ?
H41A C41 H41C 109.5 . . ?
H41B C41 H41C 109.5 . . ?
N2 C42 H42A 109.5 . . ?
N2 C42 H42B 109.5 . . ?
N2 C42 H42C 109.5 . . ?
H42A C42 H42B 109.5 . . ?
H42A C42 H42C 109.5 . . ?
H42B C42 H42C 109.5 . . ?
O15 C43 N3 125.2(4) . . ?
O15 C43 H43 117.4 . . ?
N3 C43 H43 117.4 . . ?
N3 C44 H44A 109.5 . . ?
N3 C44 H44B 109.5 . . ?
N3 C44 H44C 109.5 . . ?
H44A C44 H44B 109.5 . . ?
H44A C44 H44C 109.5 . . ?
H44B C44 H44C 109.5 . . ?
N3 C45 H45A 109.5 . . ?
N3 C45 H45B 109.5 . . ?
N3 C45 H45C 109.5 . . ?
H45A C45 H45B 109.5 . . ?
H45A C45 H45C 109.5 . . ?
H45B C45 H45C 109.5 . . ?
O16 C46 N4 123.9(3) . . ?
O16 C46 H46 118.1 . . ?
N4 C46 H46 118.1 . . ?
N4 C47 H47A 109.5 . . ?
N4 C47 H47B 109.5 . . ?
N4 C47 H47C 109.5 . . ?
H47A C47 H47B 109.5 . . ?
H47A C47 H47C 109.5 . . ?
H47B C47 H47C 109.5 . . ?
N4 C48 H48A 109.5 . . ?
N4 C48 H48B 109.5 . . ?
N4 C48 H48C 109.5 . . ?
H48A C48 H48B 109.5 . . ?
H48A C48 H48C 109.5 . . ?
H48B C48 H48C 109.5 . . ?
C53 N52 C55 116.7(14) . . ?
C56 N52 C53 129.3(10) . . ?
C56 N52 C55 109.8(13) . . ?
O18 C53 H53 121.5 . . ?
N52 C53 O18 116.9(10) . . ?
N52 C53 H53 121.5 . . ?
N52 C55 H55A 109.5 . . ?
N52 C55 H55B 109.5 . . ?
N52 C55 H55C 109.5 . . ?
H55A C55 H55B 109.5 . . ?
H55A C55 H55C 109.5 . . ?
H55B C55 H55C 109.5 . . ?
N52 C56 H56A 109.5 . . ?
N52 C56 H56B 109.5 . . ?
N52 C56 H56C 109.5 . . ?
H56A C56 H56B 109.5 . . ?
H56A C56 H56C 109.5 . . ?
H56B C56 H56C 109.5 . . ?
C49 N17 C51 123.0(13) . . ?
C50 N17 C49 119.3(14) . . ?
C50 N17 C51 117.2(10) . . ?
N17 C49 H49A 109.5 . . ?
N17 C49 H49B 109.5 . . ?
N17 C49 H49C 109.5 . . ?
H49A C49 H49B 109.5 . . ?
H49A C49 H49C 109.5 . . ?
H49B C49 H49C 109.5 . . ?
N17 C50 H50A 109.5 . . ?
N17 C50 H50B 109.5 . . ?
N17 C50 H50C 109.5 . . ?
H50A C50 H50B 109.5 . . ?
H50A C50 H50C 109.5 . . ?
H50B C50 H50C 109.5 . . ?
O20 C51 N17 106.1(9) . . ?
O20 C51 H51 127.0 . . ?
N17 C51 H51 127.0 . . ?
C54 N53 C52 122.3(15) . . ?
C54 N53 C58 121.7(13) . . ?
C58 N53 C52 116.1(14) . . ?
N53 C52 H52A 109.5 . . ?
N53 C52 H52B 109.5 . . ?
N53 C52 H52C 109.5 . . ?
H52A C52 H52B 109.5 . . ?
H52A C52 H52C 109.5 . . ?
H52B C52 H52C 109.5 . . ?
O21 C54 N53 110.5(18) . . ?
O21 C54 H54 124.7 . . ?
N53 C54 H54 124.7 . . ?
N53 C58 H58A 109.5 . . ?
N53 C58 H58B 109.5 . . ?
N53 C58 H58C 109.5 . . ?
H58A C58 H58B 109.5 . . ?
H58A C58 H58C 109.5 . . ?
H58B C58 H58C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Eu1 O2 C1 Eu2 147.5(6) . . . . ?
Eu1 O2 C1 O1 153.1(4) . . . . ?
Eu1 O2 C1 C2 -27.0(7) . . . . ?
Eu1 O3 C6 O4 -3.4(3) 2_757 . . . ?
Eu1 O3 C6 C5 176.9(3) 2_757 . . . ?
Eu1 O4 C6 O3 3.4(3) 2_757 . . . ?
Eu1 O4 C6 C5 -176.8(2) 2_757 . . . ?
Eu1 O6 C13 O5 18.4(6) . . . . ?
Eu1 O6 C13 C14 -163.8(2) . . . . ?
Eu1 O8 C18 O7 -9.8(6) 1_455 . . . ?
Eu1 O8 C18 C17 171.7(2) 1_455 . . . ?
Eu1 O11 C30 O12 -5.0(3) 2_756 . . . ?
Eu1 O11 C30 C29 175.7(2) 2_756 . . . ?
Eu1 O12 C30 O11 4.8(3) 2_756 . . . ?
Eu1 O12 C30 C29 -176.0(3) 2_756 . . . ?
Eu1 O13 C37 N1 177.3(2) . . . . ?
Eu1 O14 C40 N2 107.5(4) . . . . ?
Eu2 O1 C1 O2 -5.8(3) . . . . ?
Eu2 O1 C1 C2 174.3(3) . . . . ?
Eu2 O2 C1 O1 5.6(3) . . . . ?
Eu2 O2 C1 C2 -174.5(3) . . . . ?
Eu2 O5 C13 O6 -6.7(6) . . . . ?
Eu2 O5 C13 C14 175.4(2) . . . . ?
Eu2 O7 C18 O8 -8.3(5) 1_455 . . . ?
Eu2 O7 C18 C17 170.2(2) 1_455 . . . ?
Eu2 O9 C25 O10 -0.2(3) . . . . ?
Eu2 O9 C25 C26 -179.0(3) . . . . ?
Eu2 O10 C25 O9 0.2(3) . . . . ?
Eu2 O10 C25 C26 179.1(2) . . . . ?
Eu2 O12 C30 Eu1 149.0(6) 2_756 . . 2_756 ?
Eu2 O12 C30 O11 153.7(4) 2_756 . . . ?
Eu2 O12 C30 C29 -27.1(8) 2_756 . . . ?
Eu2 O15 C43 N3 -107.3(4) . . . . ?
Eu2 O16 C46 N4 -175.4(2) . . . . ?
O1 C1 C2 C3 113.7(4) . . . . ?
O1 C1 C2 C7 -66.9(4) . . . . ?
O2 C1 C2 C3 -66.2(4) . . . . ?
O2 C1 C2 C7 113.2(4) . . . . ?
O5 C13 C14 C15 44.0(5) . . . . ?
O5 C13 C14 C20 -134.5(3) . . . . ?
O6 C13 C14 C15 -134.1(3) . . . . ?
O6 C13 C14 C20 47.4(5) . . . . ?
O9 C25 C26 C27 159.3(3) . . . . ?
O9 C25 C26 C31 -17.7(5) . . . . ?
O10 C25 C26 C27 -19.5(4) . . . . ?
O10 C25 C26 C31 163.5(3) . . . . ?
C1 C2 C3 C4 -178.8(3) . . . . ?
C1 C2 C7 C8 -179.7(3) . . . . ?
C1 C2 C7 C12 -1.1(4) . . . . ?
C2 C3 C4 C5 -1.7(5) . . . . ?
C2 C7 C8 C5 -1.1(4) . . . . ?
C2 C7 C8 C9 179.0(3) . . . . ?
C2 C7 C12 C11 -178.7(3) . . . . ?
C3 C2 C7 C8 -0.3(5) . . . . ?
C3 C2 C7 C12 178.4(3) . . . . ?
C3 C4 C5 C6 -177.5(3) . . . . ?
C3 C4 C5 C8 0.2(5) . . . . ?
C4 C5 C6 O3 160.6(3) . . . . ?
C4 C5 C6 O4 -19.2(4) . . . . ?
C4 C5 C8 C7 1.2(4) . . . . ?
C4 C5 C8 C9 -179.0(3) . . . . ?
C5 C8 C9 C10 -179.8(3) . . . . ?
C6 C5 C8 C7 178.7(3) . . . . ?
C6 C5 C8 C9 -1.5(5) . . . . ?
C7 C2 C3 C4 1.7(5) . . . . ?
C7 C8 C9 C10 0.0(5) . . . . ?
C8 C5 C6 O3 -17.0(5) . . . . ?
C8 C5 C6 O4 163.3(3) . . . . ?
C8 C7 C12 C11 0.0(5) . . . . ?
C8 C9 C10 C11 -0.7(5) . . . . ?
C9 C10 C11 C12 1.0(5) . . . . ?
C10 C11 C12 C7 -0.7(5) . . . . ?
C12 C7 C8 C5 -179.8(3) . . . . ?
C12 C7 C8 C9 0.3(4) . . . . ?
C13 C14 C15 C16 178.2(3) . . . . ?
C13 C14 C20 C19 -177.5(3) . . . . ?
C13 C14 C20 C21 7.3(5) . . . . ?
C14 C15 C16 C17 -0.6(6) . . . . ?
C14 C20 C21 C22 173.9(3) . . . . ?
C15 C14 C20 C19 4.0(5) . . . . ?
C15 C14 C20 C21 -171.2(3) . . . . ?
C15 C16 C17 C18 -176.3(3) . . . . ?
C15 C16 C17 C19 3.7(5) . . . . ?
C16 C17 C18 O7 -47.1(4) . . . . ?
C16 C17 C18 O8 131.5(3) . . . . ?
C16 C17 C19 C20 -2.9(5) . . . . ?
C16 C17 C19 C24 173.3(3) . . . . ?
C17 C19 C20 C14 -1.0(5) . . . . ?
C17 C19 C20 C21 174.4(3) . . . . ?
C17 C19 C24 C23 -172.0(3) . . . . ?
C18 C17 C19 C20 177.2(3) . . . . ?
C18 C17 C19 C24 -6.7(5) . . . . ?
C19 C17 C18 O7 132.9(3) . . . . ?
C19 C17 C18 O8 -48.5(4) . . . . ?
C19 C20 C21 C22 -1.3(5) . . . . ?
C20 C14 C15 C16 -3.3(5) . . . . ?
C20 C19 C24 C23 4.2(5) . . . . ?
C20 C21 C22 C23 2.4(6) . . . . ?
C21 C22 C23 C24 -0.1(6) . . . . ?
C22 C23 C24 C19 -3.2(6) . . . . ?
C24 C19 C20 C14 -177.3(3) . . . . ?
C24 C19 C20 C21 -1.9(5) . . . . ?
C25 C26 C27 C28 -176.8(3) . . . . ?
C25 C26 C31 C32 177.9(3) . . . . ?
C25 C26 C31 C36 -4.1(5) . . . . ?
C26 C27 C28 C29 -1.9(5) . . . . ?
C26 C31 C32 C29 -0.8(5) . . . . ?
C26 C31 C32 C33 -180.0(3) . . . . ?
C26 C31 C36 C35 -178.5(4) . . . . ?
C27 C26 C31 C32 1.0(5) . . . . ?
C27 C26 C31 C36 179.0(3) . . . . ?
C27 C28 C29 C30 -174.7(3) . . . . ?
C27 C28 C29 C32 2.1(5) . . . . ?
C28 C29 C30 O11 108.2(4) . . . . ?
C28 C29 C30 O12 -71.1(4) . . . . ?
C28 C29 C32 C31 -0.8(5) . . . . ?
C28 C29 C32 C33 178.4(3) . . . . ?
C29 C32 C33 C34 179.0(3) . . . . ?
C30 C29 C32 C31 176.0(3) . . . . ?
C30 C29 C32 C33 -4.8(5) . . . . ?
C31 C26 C27 C28 0.4(5) . . . . ?
C31 C32 C33 C34 -1.8(5) . . . . ?
C32 C29 C30 O11 -68.7(4) . . . . ?
C32 C29 C30 O12 112.1(4) . . . . ?
C32 C31 C36 C35 -0.5(6) . . . . ?
C32 C33 C34 C35 0.3(6) . . . . ?
C33 C34 C35 C36 1.1(6) . . . . ?
C34 C35 C36 C31 -1.0(6) . . . . ?
C36 C31 C32 C29 -178.9(3) . . . . ?
C36 C31 C32 C33 1.9(5) . . . . ?
C38 N1 C37 O13 179.4(4) . . . . ?
C39 N1 C37 O13 1.7(6) . . . . ?
C41 N2 C40 O14 -1.2(6) . . . . ?
C42 N2 C40 O14 180.0(3) . . . . ?
C44 N3 C43 O15 179.1(3) . . . . ?
C45 N3 C43 O15 0.8(6) . . . . ?
C47 N4 C46 O16 -1.1(6) . . . . ?
C48 N4 C46 O16 179.1(4) . . . . ?
C55 N52 C53 O18 -157.1(15) . . . . ?
C56 N52 C53 O18 -2.6(16) . . . . ?
C49 N17 C51 O20 9(2) . . . . ?
C50 N17 C51 O20 -179.1(12) . . . . ?
C52 N53 C54 O21 -9(2) . . . . ?
C58 N53 C54 O21 172.2(12) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
