# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2024

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_B22315_a
_database_code_depnum_ccdc_archive 'CCDC 2329446'
loop_
_audit_author_name
_audit_author_address
'Abolghasem Bakhoda'
;Towson University
United States of America
;
_audit_update_record             
;
2024-01-29 deposited with the CCDC.	2024-06-06 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C31 H45 Au N4 Si, C7 H8'
_chemical_formula_sum            'C38 H53 Au N4 Si'
_chemical_formula_weight         790.90

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   13.0228(18)
_cell_length_b                   16.875(3)
_cell_length_c                   18.996(2)
_cell_angle_alpha                76.362(5)
_cell_angle_beta                 79.196(5)
_cell_angle_gamma                70.713(4)
_cell_volume                     3801.6(9)
_cell_formula_units_Z            4
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    9832
_cell_measurement_theta_min      2.22
_cell_measurement_theta_max      25.37
_exptl_crystal_description       block
_exptl_crystal_colour            yellow
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_density_diffrn    1.382
_exptl_crystal_F_000             1608
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.232
_exptl_crystal_size_mid          0.191
_exptl_crystal_size_min          0.126
_exptl_absorpt_coefficient_mu    3.931
_shelx_estimated_absorpt_T_min   0.462
_shelx_estimated_absorpt_T_max   0.637
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.37369
_exptl_absorpt_correction_T_max  0.61990
_exptl_absorpt_process_details   'SADABS V2016/2 (Bruker, 2016)'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'microfocus sealed tube'
_diffrn_radiation_monochromator  'multilayer mirrors'
_diffrn_measurement_device_type  'Bruker D8 Quest/Photon 100'
_diffrn_measurement_method       'profile data from φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            206616
_diffrn_reflns_av_unetI/netI     0.0190
_diffrn_reflns_av_R_equivalents  0.0525
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_theta_min         1.782
_diffrn_reflns_theta_max         25.460
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             14031
_reflns_number_gt                12746
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'APEX3 V2016.5-0 (Bruker, 2016)'
_computing_cell_refinement       'SAINT V8.37A (Bruker, 2005)'
_computing_data_reduction        
; 
SAINT V8.37A, XPREP v2014/2, SADABS V2016/2 (Bruker, 2016) 
;
_computing_structure_solution    'SHELX-2014-5 (Sheldrick, 2015)'
_computing_structure_refinement  'SHELX-2018-3 (Sheldrick, 2015)'
_computing_molecular_graphics    'SHELXLE v932 (Hubschle, 2011)'
_computing_publication_material  'XCIF V2014-2 (Bruker, 2014)'

_refine_special_details          
; 
Structure was phased by intrinsic methods (Sheldrick, 2015).  Systematic 
conditions suggested the ambiguous space group.  The space group choice was 
confirmed by successful convergence of the full-matrix least-squares 
refinement on F².  The final map had no significant features.  A final 
analysis of variance between observed and calculated structure factors 
showed little dependence on amplitude and resolution. 
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0110P)²+3.8909P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     intrinsic
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         14031
_refine_ls_number_parameters     817
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0210
_refine_ls_R_factor_gt           0.0172
_refine_ls_wR_factor_ref         0.0384
_refine_ls_wR_factor_gt          0.0372
_refine_ls_goodness_of_fit_ref   1.046
_refine_ls_restrained_S_all      1.046
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.33160(2) 0.23221(2) 0.73390(2) 0.01333(3) Uani 1 1 d . . . . .
Au2 Au 0.81724(2) 0.24605(2) 0.22967(2) 0.01362(3) Uani 1 1 d . . . . .
Si1 Si 0.40546(5) 0.15375(4) 0.90271(3) 0.01843(13) Uani 1 1 d . . . . .
Si2 Si 0.89683(5) 0.18629(4) 0.39810(3) 0.01737(13) Uani 1 1 d . . . . .
N1 N 0.45646(14) 0.21084(11) 0.58529(9) 0.0125(4) Uani 1 1 d . . . . .
N2 N 0.28432(14) 0.24828(10) 0.57983(9) 0.0116(3) Uani 1 1 d . . . . .
N3 N 0.23224(16) 0.29166(12) 0.87043(10) 0.0199(4) Uani 1 1 d . . . . .
N4 N 0.15988(17) 0.34154(13) 0.89655(11) 0.0261(5) Uani 1 1 d . . . . .
N5 N 0.94292(14) 0.27965(11) 0.08071(9) 0.0118(3) Uani 1 1 d . . . . .
N6 N 0.77027(14) 0.33050(11) 0.07445(9) 0.0128(4) Uani 1 1 d . . . . .
N7 N 0.71710(16) 0.16314(12) 0.36440(10) 0.0205(4) Uani 1 1 d . . . . .
N8 N 0.64507(16) 0.13540(13) 0.38874(11) 0.0247(4) Uani 1 1 d . . . . .
C1 C 0.35865(17) 0.22833(12) 0.62713(11) 0.0128(4) Uani 1 1 d . . . . .
C2 C 0.44386(18) 0.21966(13) 0.51279(11) 0.0153(4) Uani 1 1 d . . . . .
H2 H 0.500492 0.210623 0.473290 0.018 Uiso 1 1 calc R U . . .
C3 C 0.33514(17) 0.24362(13) 0.50954(11) 0.0145(4) Uani 1 1 d . . . . .
H3 H 0.300098 0.255124 0.467073 0.017 Uiso 1 1 calc R U . . .
C4 C 0.55879(17) 0.18013(14) 0.61566(11) 0.0147(4) Uani 1 1 d . . . . .
C5 C 0.60420(18) 0.23867(15) 0.62865(12) 0.0195(5) Uani 1 1 d . . . . .
C6 C 0.69948(19) 0.20565(17) 0.66214(13) 0.0250(5) Uani 1 1 d . . . . .
H6 H 0.732361 0.243671 0.672257 0.030 Uiso 1 1 calc R U . . .
C7 C 0.74744(19) 0.11842(17) 0.68106(13) 0.0279(6) Uani 1 1 d . . . . .
H7 H 0.812412 0.097246 0.704197 0.034 Uiso 1 1 calc R U . . .
C8 C 0.70159(19) 0.06209(16) 0.66656(13) 0.0247(5) Uani 1 1 d . . . . .
H8 H 0.735950 0.002355 0.679289 0.030 Uiso 1 1 calc R U . . .
C9 C 0.60541(18) 0.09141(14) 0.63345(12) 0.0183(5) Uani 1 1 d . . . . .
C10 C 0.5525(2) 0.33427(15) 0.60679(14) 0.0256(5) Uani 1 1 d . . . . .
H10 H 0.482367 0.343196 0.587445 0.031 Uiso 1 1 calc R U . . .
C11 C 0.5240(3) 0.3787(2) 0.67188(19) 0.0534(9) Uani 1 1 d . . . . .
H11A H 0.591512 0.374481 0.690162 0.080 Uiso 1 1 calc R U . . .
H11B H 0.478598 0.351268 0.710517 0.080 Uiso 1 1 calc R U . . .
H11C H 0.483477 0.439040 0.656921 0.080 Uiso 1 1 calc R U . . .
C12 C 0.6254(3) 0.3727(2) 0.54561(18) 0.0478(8) Uani 1 1 d . . . . .
H12A H 0.638944 0.344372 0.503846 0.072 Uiso 1 1 calc R U . . .
H12B H 0.695257 0.364669 0.562744 0.072 Uiso 1 1 calc R U . . .
H12C H 0.589005 0.433952 0.530808 0.072 Uiso 1 1 calc R U . . .
C13 C 0.5527(2) 0.02980(14) 0.61925(13) 0.0230(5) Uani 1 1 d . . . . .
H13 H 0.486856 0.064785 0.594020 0.028 Uiso 1 1 calc R U . . .
C14 C 0.5127(2) -0.02100(16) 0.69049(14) 0.0296(6) Uani 1 1 d . . . . .
H14A H 0.477645 -0.059367 0.679826 0.044 Uiso 1 1 calc R U . . .
H14B H 0.459635 0.018425 0.719963 0.044 Uiso 1 1 calc R U . . .
H14C H 0.575076 -0.054730 0.717513 0.044 Uiso 1 1 calc R U . . .
C15 C 0.6293(2) -0.02809(17) 0.56807(15) 0.0360(6) Uani 1 1 d . . . . .
H15A H 0.648311 0.007027 0.521583 0.054 Uiso 1 1 calc R U . . .
H15B H 0.592542 -0.066471 0.559404 0.054 Uiso 1 1 calc R U . . .
H15C H 0.696182 -0.061957 0.590399 0.054 Uiso 1 1 calc R U . . .
C16 C 0.16719(17) 0.27200(13) 0.60000(11) 0.0125(4) Uani 1 1 d . . . . .
C17 C 0.11497(17) 0.20889(13) 0.61218(11) 0.0149(4) Uani 1 1 d . . . . .
C18 C 0.00146(19) 0.23406(15) 0.62926(13) 0.0210(5) Uani 1 1 d . . . . .
H18 H -0.037014 0.193103 0.637259 0.025 Uiso 1 1 calc R U . . .
C19 C -0.05597(18) 0.31797(15) 0.63473(13) 0.0220(5) Uani 1 1 d . . . . .
H19 H -0.133433 0.334280 0.645919 0.026 Uiso 1 1 calc R U . . .
C20 C -0.00121(18) 0.37798(14) 0.62399(13) 0.0209(5) Uani 1 1 d . . . . .
H20 H -0.041699 0.435142 0.628580 0.025 Uiso 1 1 calc R U . . .
C21 C 0.11209(18) 0.35671(13) 0.60658(12) 0.0166(5) Uani 1 1 d . . . . .
C22 C 0.17934(19) 0.11551(14) 0.61186(13) 0.0192(5) Uani 1 1 d . . . . .
H22 H 0.252788 0.113341 0.583461 0.023 Uiso 1 1 calc R U . . .
C23 C 0.1246(2) 0.07071(16) 0.57647(15) 0.0321(6) Uani 1 1 d . . . . .
H23A H 0.110478 0.102822 0.527275 0.048 Uiso 1 1 calc R U . . .
H23B H 0.055111 0.067611 0.605827 0.048 Uiso 1 1 calc R U . . .
H23C H 0.172803 0.012783 0.573475 0.048 Uiso 1 1 calc R U . . .
C24 C 0.1972(2) 0.06789(16) 0.68982(14) 0.0321(6) Uani 1 1 d . . . . .
H24A H 0.242658 0.008749 0.688947 0.048 Uiso 1 1 calc R U . . .
H24B H 0.126287 0.068198 0.718529 0.048 Uiso 1 1 calc R U . . .
H24C H 0.234241 0.096214 0.711964 0.048 Uiso 1 1 calc R U . . .
C25 C 0.17140(19) 0.42309(14) 0.59680(13) 0.0208(5) Uani 1 1 d . . . . .
H25 H 0.251588 0.394428 0.585863 0.025 Uiso 1 1 calc R U . . .
C26 C 0.1539(2) 0.45723(15) 0.66748(14) 0.0281(6) Uani 1 1 d . . . . .
H26A H 0.197293 0.496507 0.661547 0.042 Uiso 1 1 calc R U . . .
H26B H 0.177005 0.409388 0.707672 0.042 Uiso 1 1 calc R U . . .
H26C H 0.076078 0.487623 0.678402 0.042 Uiso 1 1 calc R U . . .
C27 C 0.1358(2) 0.49599(15) 0.53266(13) 0.0269(5) Uani 1 1 d . . . . .
H27A H 0.146879 0.472482 0.488357 0.040 Uiso 1 1 calc R U . . .
H27B H 0.179516 0.535279 0.525428 0.040 Uiso 1 1 calc R U . . .
H27C H 0.058051 0.526902 0.543117 0.040 Uiso 1 1 calc R U . . .
C28 C 0.31214(18) 0.23551(14) 0.84185(12) 0.0191(5) Uani 1 1 d . . . . .
C29 C 0.5495(2) 0.1536(2) 0.86938(14) 0.0363(7) Uani 1 1 d . . . . .
H29A H 0.566651 0.146273 0.818392 0.054 Uiso 1 1 calc R U . . .
H29B H 0.599345 0.106483 0.899247 0.054 Uiso 1 1 calc R U . . .
H29C H 0.558148 0.207988 0.872960 0.054 Uiso 1 1 calc R U . . .
C30 C 0.3945(3) 0.04692(17) 0.90169(17) 0.0439(8) Uani 1 1 d . . . . .
H30A H 0.317578 0.047882 0.913479 0.066 Uiso 1 1 calc R U . . .
H30B H 0.437803 0.003762 0.937940 0.066 Uiso 1 1 calc R U . . .
H30C H 0.422294 0.032813 0.853123 0.066 Uiso 1 1 calc R U . . .
C31 C 0.3637(2) 0.17562(16) 0.99733(12) 0.0261(5) Uani 1 1 d . . . . .
H31A H 0.376061 0.229214 0.999352 0.039 Uiso 1 1 calc R U . . .
H31B H 0.407207 0.128676 1.031097 0.039 Uiso 1 1 calc R U . . .
H31C H 0.285784 0.180472 1.011280 0.039 Uiso 1 1 calc R U . . .
C32 C 0.84456(17) 0.29073(13) 0.12266(11) 0.0133(4) Uani 1 1 d . . . . .
C33 C 0.93031(18) 0.31195(13) 0.00773(11) 0.0151(4) Uani 1 1 d . . . . .
H33 H 0.987086 0.311932 -0.031801 0.018 Uiso 1 1 calc R U . . .
C34 C 0.82195(18) 0.34334(13) 0.00384(11) 0.0151(4) Uani 1 1 d . . . . .
H34 H 0.787305 0.369404 -0.039184 0.018 Uiso 1 1 calc R U . . .
C35 C 1.04579(17) 0.24212(13) 0.11089(11) 0.0133(4) Uani 1 1 d . . . . .
C36 C 1.09349(18) 0.29710(14) 0.12768(11) 0.0161(4) Uani 1 1 d . . . . .
C37 C 1.19041(18) 0.25980(15) 0.15983(12) 0.0201(5) Uani 1 1 d . . . . .
H37 H 1.225380 0.295215 0.172003 0.024 Uiso 1 1 calc R U . . .
C38 C 1.23617(19) 0.17235(16) 0.17419(12) 0.0238(5) Uani 1 1 d . . . . .
H38 H 1.301870 0.148100 0.196518 0.029 Uiso 1 1 calc R U . . .
C39 C 1.18716(19) 0.11953(15) 0.15633(12) 0.0212(5) Uani 1 1 d . . . . .
H39 H 1.219800 0.059342 0.166348 0.025 Uiso 1 1 calc R U . . .
C40 C 1.09074(18) 0.15355(14) 0.12390(12) 0.0172(5) Uani 1 1 d . . . . .
C41 C 1.04237(19) 0.39340(14) 0.11361(12) 0.0184(5) Uani 1 1 d . . . . .
H41 H 0.975591 0.406425 0.089033 0.022 Uiso 1 1 calc R U . . .
C42 C 1.0052(2) 0.42671(16) 0.18522(14) 0.0313(6) Uani 1 1 d . . . . .
H42A H 0.968691 0.488416 0.174922 0.047 Uiso 1 1 calc R U . . .
H42B H 1.069062 0.415299 0.210537 0.047 Uiso 1 1 calc R U . . .
H42C H 0.954031 0.397771 0.216128 0.047 Uiso 1 1 calc R U . . .
C43 C 1.1194(2) 0.43886(16) 0.06214(15) 0.0315(6) Uani 1 1 d . . . . .
H43A H 1.139353 0.417574 0.016168 0.047 Uiso 1 1 calc R U . . .
H43B H 1.185675 0.427612 0.084842 0.047 Uiso 1 1 calc R U . . .
H43C H 1.082428 0.500525 0.052428 0.047 Uiso 1 1 calc R U . . .
C44 C 1.0383(2) 0.09495(14) 0.10389(13) 0.0230(5) Uani 1 1 d . . . . .
H44 H 0.973088 0.131701 0.078713 0.028 Uiso 1 1 calc R U . . .
C45 C 1.1172(2) 0.04054(17) 0.05084(15) 0.0340(6) Uani 1 1 d . . . . .
H45A H 1.080076 0.005835 0.036587 0.051 Uiso 1 1 calc R U . . .
H45B H 1.181371 0.002969 0.074565 0.051 Uiso 1 1 calc R U . . .
H45C H 1.140589 0.077951 0.007366 0.051 Uiso 1 1 calc R U . . .
C46 C 0.9984(3) 0.03868(17) 0.17171(16) 0.0399(7) Uani 1 1 d . . . . .
H46A H 0.947799 0.074830 0.204762 0.060 Uiso 1 1 calc R U . . .
H46B H 1.061225 0.000509 0.196571 0.060 Uiso 1 1 calc R U . . .
H46C H 0.960551 0.004583 0.157353 0.060 Uiso 1 1 calc R U . . .
C47 C 0.65309(17) 0.35150(14) 0.09519(11) 0.0153(4) Uani 1 1 d . . . . .
C48 C 0.60512(18) 0.28589(15) 0.10655(12) 0.0192(5) Uani 1 1 d . . . . .
C49 C 0.4920(2) 0.30726(17) 0.12599(13) 0.0277(6) Uani 1 1 d . . . . .
H49 H 0.456283 0.264492 0.134366 0.033 Uiso 1 1 calc R U . . .
C50 C 0.4314(2) 0.38955(19) 0.13322(14) 0.0336(6) Uani 1 1 d . . . . .
H50 H 0.354410 0.402961 0.146434 0.040 Uiso 1 1 calc R U . . .
C51 C 0.4815(2) 0.45269(17) 0.12145(14) 0.0316(6) Uani 1 1 d . . . . .
H51 H 0.438066 0.509245 0.126068 0.038 Uiso 1 1 calc R U . . .
C52 C 0.59417(19) 0.43525(15) 0.10296(12) 0.0209(5) Uani 1 1 d . . . . .
C53 C 0.6717(2) 0.19587(15) 0.09768(13) 0.0234(5) Uani 1 1 d . . . . .
H53 H 0.750809 0.192093 0.093614 0.028 Uiso 1 1 calc R U . . .
C54 C 0.6486(3) 0.12983(17) 0.16431(15) 0.0382(7) Uani 1 1 d . . . . .
H54A H 0.572857 0.129123 0.167854 0.057 Uiso 1 1 calc R U . . .
H54B H 0.659320 0.145021 0.208549 0.057 Uiso 1 1 calc R U . . .
H54C H 0.698872 0.073115 0.159149 0.057 Uiso 1 1 calc R U . . .
C55 C 0.6533(2) 0.17679(18) 0.02733(14) 0.0340(6) Uani 1 1 d . . . . .
H55A H 0.672938 0.218203 -0.014270 0.051 Uiso 1 1 calc R U . . .
H55B H 0.575946 0.180977 0.029240 0.051 Uiso 1 1 calc R U . . .
H55C H 0.699003 0.118923 0.021763 0.051 Uiso 1 1 calc R U . . .
C56 C 0.6513(2) 0.50220(15) 0.09715(14) 0.0294(6) Uani 1 1 d . . . . .
H56 H 0.720223 0.487955 0.062837 0.035 Uiso 1 1 calc R U . . .
C57 C 0.6830(3) 0.49877(17) 0.17139(16) 0.0382(7) Uani 1 1 d . . . . .
H57A H 0.728957 0.440965 0.189445 0.057 Uiso 1 1 calc R U . . .
H57B H 0.616662 0.513519 0.205857 0.057 Uiso 1 1 calc R U . . .
H57C H 0.723884 0.539609 0.166565 0.057 Uiso 1 1 calc R U . . .
C58 C 0.5827(3) 0.59264(17) 0.06774(17) 0.0513(9) Uani 1 1 d . . . . .
H58A H 0.556091 0.593319 0.022598 0.077 Uiso 1 1 calc R U . . .
H58B H 0.627850 0.631342 0.057700 0.077 Uiso 1 1 calc R U . . .
H58C H 0.520222 0.611420 0.104015 0.077 Uiso 1 1 calc R U . . .
C59 C 0.79712(18) 0.19431(14) 0.33733(12) 0.0188(5) Uani 1 1 d . . . . .
C60 C 0.8986(2) 0.29560(17) 0.40002(16) 0.0350(6) Uani 1 1 d . . . . .
H60A H 0.921127 0.323163 0.350753 0.052 Uiso 1 1 calc R U . . .
H60B H 0.950433 0.291760 0.432898 0.052 Uiso 1 1 calc R U . . .
H60C H 0.825095 0.329426 0.417422 0.052 Uiso 1 1 calc R U . . .
C61 C 1.0368(2) 0.12531(17) 0.36132(14) 0.0289(6) Uani 1 1 d . . . . .
H61A H 1.054324 0.152539 0.310890 0.043 Uiso 1 1 calc R U . . .
H61B H 1.038920 0.066420 0.362537 0.043 Uiso 1 1 calc R U . . .
H61C H 1.090678 0.125001 0.391245 0.043 Uiso 1 1 calc R U . . .
C62 C 0.8559(2) 0.13333(16) 0.49234(12) 0.0257(5) Uani 1 1 d . . . . .
H62A H 0.777106 0.157924 0.505634 0.039 Uiso 1 1 calc R U . . .
H62B H 0.896439 0.142382 0.526812 0.039 Uiso 1 1 calc R U . . .
H62C H 0.872767 0.071905 0.494016 0.039 Uiso 1 1 calc R U . . .
C63 C 0.3971(2) 0.34856(16) 0.33132(14) 0.0295(6) Uani 1 1 d . . . . .
C64 C 0.4013(2) 0.27038(16) 0.31801(13) 0.0295(6) Uani 1 1 d . . . . .
H64 H 0.470352 0.230597 0.306771 0.035 Uiso 1 1 calc R U . . .
C65 C 0.3074(2) 0.24937(16) 0.32076(13) 0.0310(6) Uani 1 1 d . . . . .
H65 H 0.312345 0.195263 0.311399 0.037 Uiso 1 1 calc R U . . .
C66 C 0.2057(2) 0.30568(17) 0.33693(14) 0.0316(6) Uani 1 1 d . . . . .
H66 H 0.140837 0.290915 0.338491 0.038 Uiso 1 1 calc R U . . .
C67 C 0.2000(2) 0.38315(16) 0.35068(14) 0.0326(6) Uani 1 1 d . . . . .
H67 H 0.130512 0.422246 0.362395 0.039 Uiso 1 1 calc R U . . .
C68 C 0.2942(2) 0.40512(16) 0.34770(14) 0.0337(6) Uani 1 1 d . . . . .
H68 H 0.288747 0.459395 0.356912 0.040 Uiso 1 1 calc R U . . .
C69 C 0.5007(3) 0.3703(2) 0.3284(2) 0.0564(9) Uani 1 1 d . . . . .
H69A H 0.532012 0.344043 0.374528 0.085 Uiso 1 1 calc R U . . .
H69B H 0.484486 0.432521 0.320818 0.085 Uiso 1 1 calc R U . . .
H69C H 0.553339 0.348637 0.288112 0.085 Uiso 1 1 calc R U . . .
C70 C 0.9345(2) 0.26027(16) 0.83432(13) 0.0259(5) Uani 1 1 d . . . . .
C71 C 0.8388(2) 0.24225(18) 0.83224(14) 0.0343(6) Uani 1 1 d . . . . .
H71 H 0.837299 0.184700 0.845301 0.041 Uiso 1 1 calc R U . . .
C72 C 0.7456(2) 0.3064(2) 0.81154(15) 0.0379(7) Uani 1 1 d . . . . .
H72 H 0.681007 0.292595 0.810166 0.046 Uiso 1 1 calc R U . . .
C73 C 0.7461(2) 0.39049(19) 0.79283(14) 0.0358(6) Uani 1 1 d . . . . .
H73 H 0.682447 0.434729 0.778124 0.043 Uiso 1 1 calc R U . . .
C74 C 0.8402(2) 0.40938(17) 0.79580(14) 0.0324(6) Uani 1 1 d . . . . .
H74 H 0.841032 0.467116 0.783741 0.039 Uiso 1 1 calc R U . . .
C75 C 0.9331(2) 0.34520(16) 0.81610(13) 0.0259(5) Uani 1 1 d . . . . .
H75 H 0.997396 0.359330 0.817658 0.031 Uiso 1 1 calc R U . . .
C76 C 1.0369(3) 0.19067(18) 0.85506(17) 0.0421(7) Uani 1 1 d . . . . .
H76A H 1.018883 0.137499 0.877158 0.063 Uiso 1 1 calc R U . . .
H76B H 1.068757 0.207049 0.890179 0.063 Uiso 1 1 calc R U . . .
H76C H 1.089762 0.182044 0.811387 0.063 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

_exptl_special_details           
; 
One distinct cell was identified using APEX3 (Bruker, 2016).  Eight 
frame series were integrated and filtered for statistical outliers 
using SAINT (Bruker, 2016) then corrected for absorption by integration 
using SAINT/SADABS v2014/2 (Bruker, 2016) to sort, merge, and scale 
the combined data.  No decay correction was applied.    
;

loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
0.00 1.00 0.00 0.0790
0.00 -1.00 0.00 0.0910
1.00 0.00 -1.00 0.0910
-1.00 0.00 1.00 0.0930
0.00 0.00 -1.00 0.0330
0.00 0.00 1.00 0.0630
-1.00 0.00 -1.00 0.0750
1.00 0.00 1.00 0.0710
0.00 1.00 1.00 0.0820
0.00 -1.00 -1.00 0.0850
-2.00 -1.00 -1.00 0.1130
1.00 1.00 1.00 0.1040

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 C1 2.005(2) . ?
Au1 C28 2.030(2) . ?
Au2 C32 2.003(2) . ?
Au2 C59 2.030(2) . ?
Si1 C28 1.839(2) . ?
Si1 C30 1.860(3) . ?
Si1 C29 1.863(3) . ?
Si1 C31 1.864(2) . ?
Si2 C59 1.846(2) . ?
Si2 C60 1.861(3) . ?
Si2 C62 1.868(2) . ?
Si2 C61 1.869(2) . ?
N1 C1 1.351(3) . ?
N1 C2 1.385(3) . ?
N1 C4 1.438(3) . ?
N2 C1 1.351(3) . ?
N2 C3 1.382(3) . ?
N2 C16 1.444(3) . ?
N3 N4 1.158(3) . ?
N3 C28 1.286(3) . ?
N5 C32 1.356(3) . ?
N5 C33 1.384(3) . ?
N5 C35 1.442(3) . ?
N6 C32 1.356(3) . ?
N6 C34 1.386(3) . ?
N6 C47 1.447(3) . ?
N7 N8 1.157(3) . ?
N7 C59 1.289(3) . ?
C2 C3 1.347(3) . ?
C2 H2 0.9500 . ?
C3 H3 0.9500 . ?
C4 C5 1.393(3) . ?
C4 C9 1.401(3) . ?
C5 C6 1.388(3) . ?
C5 C10 1.517(3) . ?
C6 C7 1.383(4) . ?
C6 H6 0.9500 . ?
C7 C8 1.377(4) . ?
C7 H7 0.9500 . ?
C8 C9 1.396(3) . ?
C8 H8 0.9500 . ?
C9 C13 1.516(3) . ?
C10 C11 1.520(4) . ?
C10 C12 1.520(4) . ?
C10 H10 1.0000 . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
C13 C14 1.524(3) . ?
C13 C15 1.528(3) . ?
C13 H13 1.0000 . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 C21 1.395(3) . ?
C16 C17 1.398(3) . ?
C17 C18 1.393(3) . ?
C17 C22 1.522(3) . ?
C18 C19 1.384(3) . ?
C18 H18 0.9500 . ?
C19 C20 1.379(3) . ?
C19 H19 0.9500 . ?
C20 C21 1.392(3) . ?
C20 H20 0.9500 . ?
C21 C25 1.518(3) . ?
C22 C23 1.519(3) . ?
C22 C24 1.529(3) . ?
C22 H22 1.0000 . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C25 C27 1.530(3) . ?
C25 C26 1.533(3) . ?
C25 H25 1.0000 . ?
C26 H26A 0.9800 . ?
C26 H26B 0.9800 . ?
C26 H26C 0.9800 . ?
C27 H27A 0.9800 . ?
C27 H27B 0.9800 . ?
C27 H27C 0.9800 . ?
C29 H29A 0.9800 . ?
C29 H29B 0.9800 . ?
C29 H29C 0.9800 . ?
C30 H30A 0.9800 . ?
C30 H30B 0.9800 . ?
C30 H30C 0.9800 . ?
C31 H31A 0.9800 . ?
C31 H31B 0.9800 . ?
C31 H31C 0.9800 . ?
C33 C34 1.343(3) . ?
C33 H33 0.9500 . ?
C34 H34 0.9500 . ?
C35 C40 1.393(3) . ?
C35 C36 1.394(3) . ?
C36 C37 1.395(3) . ?
C36 C41 1.517(3) . ?
C37 C38 1.377(3) . ?
C37 H37 0.9500 . ?
C38 C39 1.384(3) . ?
C38 H38 0.9500 . ?
C39 C40 1.390(3) . ?
C39 H39 0.9500 . ?
C40 C44 1.519(3) . ?
C41 C42 1.528(3) . ?
C41 C43 1.528(3) . ?
C41 H41 1.0000 . ?
C42 H42A 0.9800 . ?
C42 H42B 0.9800 . ?
C42 H42C 0.9800 . ?
C43 H43A 0.9800 . ?
C43 H43B 0.9800 . ?
C43 H43C 0.9800 . ?
C44 C46 1.526(3) . ?
C44 C45 1.529(3) . ?
C44 H44 1.0000 . ?
C45 H45A 0.9800 . ?
C45 H45B 0.9800 . ?
C45 H45C 0.9800 . ?
C46 H46A 0.9800 . ?
C46 H46B 0.9800 . ?
C46 H46C 0.9800 . ?
C47 C52 1.396(3) . ?
C47 C48 1.399(3) . ?
C48 C49 1.394(3) . ?
C48 C53 1.511(3) . ?
C49 C50 1.376(4) . ?
C49 H49 0.9500 . ?
C50 C51 1.379(4) . ?
C50 H50 0.9500 . ?
C51 C52 1.391(3) . ?
C51 H51 0.9500 . ?
C52 C56 1.519(3) . ?
C53 C55 1.524(3) . ?
C53 C54 1.532(3) . ?
C53 H53 1.0000 . ?
C54 H54A 0.9800 . ?
C54 H54B 0.9800 . ?
C54 H54C 0.9800 . ?
C55 H55A 0.9800 . ?
C55 H55B 0.9800 . ?
C55 H55C 0.9800 . ?
C56 C58 1.524(4) . ?
C56 C57 1.525(4) . ?
C56 H56 1.0000 . ?
C57 H57A 0.9800 . ?
C57 H57B 0.9800 . ?
C57 H57C 0.9800 . ?
C58 H58A 0.9800 . ?
C58 H58B 0.9800 . ?
C58 H58C 0.9800 . ?
C60 H60A 0.9800 . ?
C60 H60B 0.9800 . ?
C60 H60C 0.9800 . ?
C61 H61A 0.9800 . ?
C61 H61B 0.9800 . ?
C61 H61C 0.9800 . ?
C62 H62A 0.9800 . ?
C62 H62B 0.9800 . ?
C62 H62C 0.9800 . ?
C63 C64 1.383(4) . ?
C63 C68 1.394(4) . ?
C63 C69 1.500(4) . ?
C64 C65 1.370(4) . ?
C64 H64 0.9500 . ?
C65 C66 1.380(4) . ?
C65 H65 0.9500 . ?
C66 C67 1.368(4) . ?
C66 H66 0.9500 . ?
C67 C68 1.382(4) . ?
C67 H67 0.9500 . ?
C68 H68 0.9500 . ?
C69 H69A 0.9800 . ?
C69 H69B 0.9800 . ?
C69 H69C 0.9800 . ?
C70 C71 1.386(4) . ?
C70 C75 1.388(3) . ?
C70 C76 1.502(4) . ?
C71 C72 1.382(4) . ?
C71 H71 0.9500 . ?
C72 C73 1.381(4) . ?
C72 H72 0.9500 . ?
C73 C74 1.378(4) . ?
C73 H73 0.9500 . ?
C74 C75 1.378(4) . ?
C74 H74 0.9500 . ?
C75 H75 0.9500 . ?
C76 H76A 0.9800 . ?
C76 H76B 0.9800 . ?
C76 H76C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Au1 C28 177.18(9) . . ?
C32 Au2 C59 176.55(9) . . ?
C28 Si1 C30 108.97(13) . . ?
C28 Si1 C29 109.83(12) . . ?
C30 Si1 C29 108.31(15) . . ?
C28 Si1 C31 108.90(11) . . ?
C30 Si1 C31 108.98(13) . . ?
C29 Si1 C31 111.81(12) . . ?
C59 Si2 C60 109.14(12) . . ?
C59 Si2 C62 109.59(11) . . ?
C60 Si2 C62 109.34(12) . . ?
C59 Si2 C61 109.36(11) . . ?
C60 Si2 C61 108.12(13) . . ?
C62 Si2 C61 111.25(12) . . ?
C1 N1 C2 111.45(17) . . ?
C1 N1 C4 122.37(17) . . ?
C2 N1 C4 125.98(17) . . ?
C1 N2 C3 111.12(17) . . ?
C1 N2 C16 124.42(17) . . ?
C3 N2 C16 124.47(17) . . ?
N4 N3 C28 179.3(3) . . ?
C32 N5 C33 111.35(17) . . ?
C32 N5 C35 122.74(17) . . ?
C33 N5 C35 125.86(17) . . ?
C32 N6 C34 110.94(17) . . ?
C32 N6 C47 123.35(17) . . ?
C34 N6 C47 125.62(17) . . ?
N8 N7 C59 179.8(3) . . ?
N1 C1 N2 104.36(17) . . ?
N1 C1 Au1 127.14(15) . . ?
N2 C1 Au1 128.35(15) . . ?
C3 C2 N1 106.18(19) . . ?
C3 C2 H2 126.9 . . ?
N1 C2 H2 126.9 . . ?
C2 C3 N2 106.88(18) . . ?
C2 C3 H3 126.6 . . ?
N2 C3 H3 126.6 . . ?
C5 C4 C9 123.4(2) . . ?
C5 C4 N1 119.34(19) . . ?
C9 C4 N1 117.23(19) . . ?
C6 C5 C4 117.1(2) . . ?
C6 C5 C10 121.3(2) . . ?
C4 C5 C10 121.6(2) . . ?
C7 C6 C5 121.2(2) . . ?
C7 C6 H6 119.4 . . ?
C5 C6 H6 119.4 . . ?
C8 C7 C6 120.4(2) . . ?
C8 C7 H7 119.8 . . ?
C6 C7 H7 119.8 . . ?
C7 C8 C9 121.0(2) . . ?
C7 C8 H8 119.5 . . ?
C9 C8 H8 119.5 . . ?
C8 C9 C4 116.9(2) . . ?
C8 C9 C13 121.3(2) . . ?
C4 C9 C13 121.8(2) . . ?
C5 C10 C11 111.7(2) . . ?
C5 C10 C12 110.8(2) . . ?
C11 C10 C12 111.9(2) . . ?
C5 C10 H10 107.4 . . ?
C11 C10 H10 107.4 . . ?
C12 C10 H10 107.4 . . ?
C10 C11 H11A 109.5 . . ?
C10 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
C10 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
C10 C12 H12A 109.5 . . ?
C10 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
C10 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
C9 C13 C14 111.1(2) . . ?
C9 C13 C15 111.5(2) . . ?
C14 C13 C15 112.2(2) . . ?
C9 C13 H13 107.3 . . ?
C14 C13 H13 107.3 . . ?
C15 C13 H13 107.3 . . ?
C13 C14 H14A 109.5 . . ?
C13 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C13 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C13 C15 H15A 109.5 . . ?
C13 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C13 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C21 C16 C17 123.43(19) . . ?
C21 C16 N2 118.24(18) . . ?
C17 C16 N2 118.32(18) . . ?
C18 C17 C16 117.16(19) . . ?
C18 C17 C22 121.0(2) . . ?
C16 C17 C22 121.73(19) . . ?
C19 C18 C17 120.8(2) . . ?
C19 C18 H18 119.6 . . ?
C17 C18 H18 119.6 . . ?
C20 C19 C18 120.3(2) . . ?
C20 C19 H19 119.9 . . ?
C18 C19 H19 119.9 . . ?
C19 C20 C21 121.5(2) . . ?
C19 C20 H20 119.3 . . ?
C21 C20 H20 119.3 . . ?
C20 C21 C16 116.8(2) . . ?
C20 C21 C25 120.80(19) . . ?
C16 C21 C25 122.44(19) . . ?
C23 C22 C17 113.07(19) . . ?
C23 C22 C24 109.8(2) . . ?
C17 C22 C24 109.90(19) . . ?
C23 C22 H22 108.0 . . ?
C17 C22 H22 108.0 . . ?
C24 C22 H22 108.0 . . ?
C22 C23 H23A 109.5 . . ?
C22 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
C22 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C22 C24 H24A 109.5 . . ?
C22 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
C22 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C21 C25 C27 111.51(19) . . ?
C21 C25 C26 110.46(19) . . ?
C27 C25 C26 111.06(19) . . ?
C21 C25 H25 107.9 . . ?
C27 C25 H25 107.9 . . ?
C26 C25 H25 107.9 . . ?
C25 C26 H26A 109.5 . . ?
C25 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
C25 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
C25 C27 H27A 109.5 . . ?
C25 C27 H27B 109.5 . . ?
H27A C27 H27B 109.5 . . ?
C25 C27 H27C 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
N3 C28 Si1 117.97(17) . . ?
N3 C28 Au1 121.65(16) . . ?
Si1 C28 Au1 120.30(12) . . ?
Si1 C29 H29A 109.5 . . ?
Si1 C29 H29B 109.5 . . ?
H29A C29 H29B 109.5 . . ?
Si1 C29 H29C 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
Si1 C30 H30A 109.5 . . ?
Si1 C30 H30B 109.5 . . ?
H30A C30 H30B 109.5 . . ?
Si1 C30 H30C 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
Si1 C31 H31A 109.5 . . ?
Si1 C31 H31B 109.5 . . ?
H31A C31 H31B 109.5 . . ?
Si1 C31 H31C 109.5 . . ?
H31A C31 H31C 109.5 . . ?
H31B C31 H31C 109.5 . . ?
N6 C32 N5 104.24(17) . . ?
N6 C32 Au2 128.34(15) . . ?
N5 C32 Au2 127.09(15) . . ?
C34 C33 N5 106.46(19) . . ?
C34 C33 H33 126.8 . . ?
N5 C33 H33 126.8 . . ?
C33 C34 N6 107.02(18) . . ?
C33 C34 H34 126.5 . . ?
N6 C34 H34 126.5 . . ?
C40 C35 C36 123.3(2) . . ?
C40 C35 N5 119.02(19) . . ?
C36 C35 N5 117.64(18) . . ?
C35 C36 C37 117.1(2) . . ?
C35 C36 C41 122.33(19) . . ?
C37 C36 C41 120.6(2) . . ?
C38 C37 C36 121.0(2) . . ?
C38 C37 H37 119.5 . . ?
C36 C37 H37 119.5 . . ?
C37 C38 C39 120.5(2) . . ?
C37 C38 H38 119.7 . . ?
C39 C38 H38 119.7 . . ?
C38 C39 C40 120.8(2) . . ?
C38 C39 H39 119.6 . . ?
C40 C39 H39 119.6 . . ?
C39 C40 C35 117.3(2) . . ?
C39 C40 C44 120.3(2) . . ?
C35 C40 C44 122.4(2) . . ?
C36 C41 C42 110.95(18) . . ?
C36 C41 C43 111.7(2) . . ?
C42 C41 C43 111.6(2) . . ?
C36 C41 H41 107.4 . . ?
C42 C41 H41 107.4 . . ?
C43 C41 H41 107.4 . . ?
C41 C42 H42A 109.5 . . ?
C41 C42 H42B 109.5 . . ?
H42A C42 H42B 109.5 . . ?
C41 C42 H42C 109.5 . . ?
H42A C42 H42C 109.5 . . ?
H42B C42 H42C 109.5 . . ?
C41 C43 H43A 109.5 . . ?
C41 C43 H43B 109.5 . . ?
H43A C43 H43B 109.5 . . ?
C41 C43 H43C 109.5 . . ?
H43A C43 H43C 109.5 . . ?
H43B C43 H43C 109.5 . . ?
C40 C44 C46 111.4(2) . . ?
C40 C44 C45 111.1(2) . . ?
C46 C44 C45 110.9(2) . . ?
C40 C44 H44 107.8 . . ?
C46 C44 H44 107.8 . . ?
C45 C44 H44 107.8 . . ?
C44 C45 H45A 109.5 . . ?
C44 C45 H45B 109.5 . . ?
H45A C45 H45B 109.5 . . ?
C44 C45 H45C 109.5 . . ?
H45A C45 H45C 109.5 . . ?
H45B C45 H45C 109.5 . . ?
C44 C46 H46A 109.5 . . ?
C44 C46 H46B 109.5 . . ?
H46A C46 H46B 109.5 . . ?
C44 C46 H46C 109.5 . . ?
H46A C46 H46C 109.5 . . ?
H46B C46 H46C 109.5 . . ?
C52 C47 C48 123.6(2) . . ?
C52 C47 N6 118.79(19) . . ?
C48 C47 N6 117.63(19) . . ?
C49 C48 C47 116.9(2) . . ?
C49 C48 C53 121.0(2) . . ?
C47 C48 C53 122.0(2) . . ?
C50 C49 C48 120.8(2) . . ?
C50 C49 H49 119.6 . . ?
C48 C49 H49 119.6 . . ?
C49 C50 C51 120.6(2) . . ?
C49 C50 H50 119.7 . . ?
C51 C50 H50 119.7 . . ?
C50 C51 C52 121.3(2) . . ?
C50 C51 H51 119.3 . . ?
C52 C51 H51 119.3 . . ?
C51 C52 C47 116.6(2) . . ?
C51 C52 C56 121.7(2) . . ?
C47 C52 C56 121.6(2) . . ?
C48 C53 C55 110.7(2) . . ?
C48 C53 C54 111.7(2) . . ?
C55 C53 C54 111.8(2) . . ?
C48 C53 H53 107.5 . . ?
C55 C53 H53 107.5 . . ?
C54 C53 H53 107.5 . . ?
C53 C54 H54A 109.5 . . ?
C53 C54 H54B 109.5 . . ?
H54A C54 H54B 109.5 . . ?
C53 C54 H54C 109.5 . . ?
H54A C54 H54C 109.5 . . ?
H54B C54 H54C 109.5 . . ?
C53 C55 H55A 109.5 . . ?
C53 C55 H55B 109.5 . . ?
H55A C55 H55B 109.5 . . ?
C53 C55 H55C 109.5 . . ?
H55A C55 H55C 109.5 . . ?
H55B C55 H55C 109.5 . . ?
C52 C56 C58 113.3(2) . . ?
C52 C56 C57 110.0(2) . . ?
C58 C56 C57 109.7(2) . . ?
C52 C56 H56 107.9 . . ?
C58 C56 H56 107.9 . . ?
C57 C56 H56 107.9 . . ?
C56 C57 H57A 109.5 . . ?
C56 C57 H57B 109.5 . . ?
H57A C57 H57B 109.5 . . ?
C56 C57 H57C 109.5 . . ?
H57A C57 H57C 109.5 . . ?
H57B C57 H57C 109.5 . . ?
C56 C58 H58A 109.5 . . ?
C56 C58 H58B 109.5 . . ?
H58A C58 H58B 109.5 . . ?
C56 C58 H58C 109.5 . . ?
H58A C58 H58C 109.5 . . ?
H58B C58 H58C 109.5 . . ?
N7 C59 Si2 118.27(16) . . ?
N7 C59 Au2 120.96(16) . . ?
Si2 C59 Au2 120.71(12) . . ?
Si2 C60 H60A 109.5 . . ?
Si2 C60 H60B 109.5 . . ?
H60A C60 H60B 109.5 . . ?
Si2 C60 H60C 109.5 . . ?
H60A C60 H60C 109.5 . . ?
H60B C60 H60C 109.5 . . ?
Si2 C61 H61A 109.5 . . ?
Si2 C61 H61B 109.5 . . ?
H61A C61 H61B 109.5 . . ?
Si2 C61 H61C 109.5 . . ?
H61A C61 H61C 109.5 . . ?
H61B C61 H61C 109.5 . . ?
Si2 C62 H62A 109.5 . . ?
Si2 C62 H62B 109.5 . . ?
H62A C62 H62B 109.5 . . ?
Si2 C62 H62C 109.5 . . ?
H62A C62 H62C 109.5 . . ?
H62B C62 H62C 109.5 . . ?
C64 C63 C68 117.7(3) . . ?
C64 C63 C69 120.4(3) . . ?
C68 C63 C69 121.9(3) . . ?
C65 C64 C63 121.1(2) . . ?
C65 C64 H64 119.5 . . ?
C63 C64 H64 119.5 . . ?
C64 C65 C66 120.9(2) . . ?
C64 C65 H65 119.5 . . ?
C66 C65 H65 119.5 . . ?
C67 C66 C65 118.8(3) . . ?
C67 C66 H66 120.6 . . ?
C65 C66 H66 120.6 . . ?
C66 C67 C68 120.7(3) . . ?
C66 C67 H67 119.7 . . ?
C68 C67 H67 119.7 . . ?
C67 C68 C63 120.8(2) . . ?
C67 C68 H68 119.6 . . ?
C63 C68 H68 119.6 . . ?
C63 C69 H69A 109.5 . . ?
C63 C69 H69B 109.5 . . ?
H69A C69 H69B 109.5 . . ?
C63 C69 H69C 109.5 . . ?
H69A C69 H69C 109.5 . . ?
H69B C69 H69C 109.5 . . ?
C71 C70 C75 117.8(2) . . ?
C71 C70 C76 121.5(2) . . ?
C75 C70 C76 120.7(2) . . ?
C72 C71 C70 121.3(3) . . ?
C72 C71 H71 119.4 . . ?
C70 C71 H71 119.4 . . ?
C73 C72 C71 120.1(3) . . ?
C73 C72 H72 119.9 . . ?
C71 C72 H72 119.9 . . ?
C74 C73 C72 119.1(3) . . ?
C74 C73 H73 120.4 . . ?
C72 C73 H73 120.4 . . ?
C75 C74 C73 120.5(3) . . ?
C75 C74 H74 119.7 . . ?
C73 C74 H74 119.7 . . ?
C74 C75 C70 121.2(2) . . ?
C74 C75 H75 119.4 . . ?
C70 C75 H75 119.4 . . ?
C70 C76 H76A 109.5 . . ?
C70 C76 H76B 109.5 . . ?
H76A C76 H76B 109.5 . . ?
C70 C76 H76C 109.5 . . ?
H76A C76 H76C 109.5 . . ?
H76B C76 H76C 109.5 . . ?

_refine_diff_density_max         1.490
_refine_diff_density_min         -0.725
_refine_diff_density_rms         0.065



_chemical_properties_physical    
Air-sensitive,Moisture-sensitive,Light-sensitive,Photo-sensitive
