# Supplementary Information (SI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2024

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 2345482'
loop_
_audit_author_name
_audit_author_address
'feng hua'
;Northwest normal university
China
;
_audit_update_record             
;
2024-04-03 deposited with the CCDC.	2024-08-26 downloaded from the CCDC.
;
_audit_creation_date             2023-07-12
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6408)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C25 H27 N O2'
_chemical_formula_sum            'C25 H27 N O2'
_chemical_formula_weight         373.47
_chemical_melting_point          113-115
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   11.3592(3)
_cell_length_b                   8.7279(2)
_cell_length_c                   21.5003(5)
_cell_angle_alpha                90
_cell_angle_beta                 93.1090(10)
_cell_angle_gamma                90
_cell_volume                     2128.44(9)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9474
_cell_measurement_temperature    150.0
_cell_measurement_theta_max      40.20
_cell_measurement_theta_min      3.06
_shelx_estimated_absorpt_T_max   0.994
_shelx_estimated_absorpt_T_min   0.987
_exptl_absorpt_coefficient_mu    0.073
_exptl_absorpt_correction_T_max  0.7479
_exptl_absorpt_correction_T_min  0.7096
_exptl_absorpt_correction_type   none
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.0513 before and 0.0413 after correction.
The Ratio of minimum to maximum transmission is 0.9488.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.165
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             800
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.08
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0163
_diffrn_reflns_av_unetI/netI     0.0079
_diffrn_reflns_Laue_measured_fraction_full 0.985
_diffrn_reflns_Laue_measured_fraction_max 0.988
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            44504
_diffrn_reflns_point_group_measured_fraction_full 0.985
_diffrn_reflns_point_group_measured_fraction_max 0.988
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.484
_diffrn_reflns_theta_min         2.682
_diffrn_ambient_temperature      150.0
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.985
_diffrn_measured_fraction_theta_max 0.988
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                4537
_reflns_number_total             4819
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.38A (Bruker, 2018)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.38A (Bruker, 2018)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         0.591
_refine_diff_density_min         -0.573
_refine_diff_density_rms         0.039
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.037
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     255
_refine_ls_number_reflns         4819
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0502
_refine_ls_R_factor_gt           0.0480
_refine_ls_restrained_S_all      1.037
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0598P)²+0.9766P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1244
_refine_ls_wR_factor_ref         0.1265
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups, All N(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Ternary CH refined with riding coordinates:
 C6(H6), C12(H12)
2.b Secondary CH2 refined with riding coordinates:
 C14(H14A,H14B), C18(H18A,H18B)
2.c Aromatic/amide H refined with riding coordinates:
 N(H), C10(H10), C16(H16), C22(H22), C24(H24), C25(H25), C13(H13), C15(H15),
 C2(H2), C17(H17), C19(H19), C5(H5), C21(H21), C11(H11), C23(H23)
2.d Idealised Me refined as rotating group:
 C7(H7A,H7B,H7C), C3(H3A,H3B,H3C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
O1 O 0.35934(8) 0.87225(10) 0.43264(4) 0.0267(2) Uani 1 1 d . . . . .
O2 O 0.45695(8) 0.72805(10) 0.50488(4) 0.0284(2) Uani 1 1 d . . . . .
N N 0.54530(8) 0.54656(11) 0.40898(4) 0.0235(2) Uani 1 1 d . . . . .
H H 0.535263 0.447653 0.414634 0.028 Uiso 1 1 calc R U . . .
C1 C 0.42349(10) 0.75150(12) 0.45136(5) 0.0210(2) Uani 1 1 d . . . . .
C4 C 0.65915(10) 0.60731(13) 0.41166(5) 0.0227(2) Uani 1 1 d . . . . .
C6 C 0.44414(10) 0.64359(12) 0.39710(5) 0.0212(2) Uani 1 1 d . . . . .
H6 H 0.456901 0.706563 0.359195 0.025 Uiso 1 1 calc R U . . .
C8 C 0.36215(10) 0.53086(14) 0.26970(5) 0.0246(2) Uani 1 1 d . . . . .
C10 C 0.68527(11) 0.75309(14) 0.38916(6) 0.0276(3) Uani 1 1 d . . . . .
H10 H 0.623227 0.816732 0.372772 0.033 Uiso 1 1 calc R U . . .
C12 C 0.33582(10) 0.44322(13) 0.32882(5) 0.0223(2) Uani 1 1 d . . . . .
H12 H 0.403201 0.371306 0.337647 0.027 Uiso 1 1 calc R U . . .
C14 C 0.33053(10) 0.54887(13) 0.38538(5) 0.0242(2) Uani 1 1 d . . . . .
H14A H 0.317194 0.486267 0.422743 0.029 Uiso 1 1 calc R U . . .
H14B H 0.262765 0.619476 0.378874 0.029 Uiso 1 1 calc R U . . .
C16 C 0.75346(11) 0.51782(14) 0.43584(6) 0.0281(3) Uani 1 1 d . . . . .
H16 H 0.738702 0.418321 0.451557 0.034 Uiso 1 1 calc R U . . .
C18 C 0.32142(11) 0.97646(14) 0.48085(5) 0.0282(3) Uani 1 1 d . . . . .
H18A H 0.389477 1.006992 0.508836 0.034 Uiso 1 1 calc R U . . .
H18B H 0.262085 0.926208 0.506060 0.034 Uiso 1 1 calc R U . . .
C20 C 0.22556(10) 0.34470(14) 0.31709(5) 0.0262(2) Uani 1 1 d . . . . .
C22 C 0.46185(12) 0.49437(15) 0.23857(6) 0.0310(3) Uani 1 1 d . . . . .
H22 H 0.516111 0.421076 0.255868 0.037 Uiso 1 1 calc R U . . .
C24 C 0.80076(12) 0.80612(16) 0.39045(6) 0.0342(3) Uani 1 1 d . . . . .
H24 H 0.816096 0.905079 0.374367 0.041 Uiso 1 1 calc R U . . .
C25 C 0.86787(11) 0.57305(17) 0.43705(6) 0.0351(3) Uani 1 1 d . . . . .
H25 H 0.930182 0.510122 0.453641 0.042 Uiso 1 1 calc R U . . .
C13 C 0.28601(12) 0.64295(16) 0.24499(6) 0.0345(3) Uani 1 1 d . . . . .
H13 H 0.218597 0.671358 0.266611 0.041 Uiso 1 1 calc R U . . .
C7 C 0.26906(13) 1.11386(15) 0.44797(6) 0.0351(3) Uani 1 1 d . . . . .
H7A H 0.205682 1.081070 0.418177 0.053 Uiso 1 1 calc R U . . .
H7B H 0.330210 1.166718 0.425709 0.053 Uiso 1 1 calc R U . . .
H7C H 0.237043 1.183642 0.478513 0.053 Uiso 1 1 calc R U . . .
C15 C 0.23075(12) 0.22496(17) 0.27474(6) 0.0358(3) Uani 1 1 d . . . . .
H15 H 0.300549 0.209767 0.253115 0.043 Uiso 1 1 calc R U . . .
C2 C 0.12115(11) 0.36632(17) 0.34726(7) 0.0365(3) Uani 1 1 d . . . . .
H2 H 0.114821 0.449063 0.375595 0.044 Uiso 1 1 calc R U . . .
C17 C 0.40551(15) 0.67203(18) 0.15685(6) 0.0437(4) Uani 1 1 d . . . . .
H17 H 0.418886 0.717455 0.117707 0.052 Uiso 1 1 calc R U . . .
C9 C 0.89432(11) 0.71819(18) 0.41465(7) 0.0374(3) Uani 1 1 d . . . . .
C19 C 0.48323(14) 0.56426(17) 0.18210(6) 0.0403(3) Uani 1 1 d . . . . .
H19 H 0.551520 0.537736 0.160859 0.048 Uiso 1 1 calc R U . . .
C5 C 0.30807(14) 0.71345(18) 0.18890(7) 0.0439(4) Uani 1 1 d . . . . .
H5 H 0.256042 0.790418 0.172485 0.053 Uiso 1 1 calc R U . . .
C21 C 0.13560(14) 0.12720(19) 0.26353(8) 0.0453(4) Uani 1 1 d . . . . .
H21 H 0.140616 0.046007 0.234362 0.054 Uiso 1 1 calc R U . . .
C11 C 0.02592(12) 0.26716(19) 0.33609(9) 0.0468(4) Uani 1 1 d . . . . .
H11 H -0.044498 0.282333 0.357196 0.056 Uiso 1 1 calc R U . . .
C23 C 0.03321(13) 0.14785(18) 0.29485(8) 0.0464(4) Uani 1 1 d . . . . .
H23 H -0.031465 0.079892 0.287804 0.056 Uiso 1 1 calc R U . . .
C3 C 1.01917(14) 0.7787(2) 0.41595(12) 0.0644(5) Uani 1 1 d . . . . .
H3A H 1.050593 0.766714 0.374666 0.097 Uiso 1 1 calc R U . . .
H3B H 1.068352 0.721147 0.446661 0.097 Uiso 1 1 calc R U . . .
H3C H 1.019480 0.887400 0.427353 0.097 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
O1 C1 1.3312(13) . ?
O1 C18 1.4614(13) . ?
O2 C1 1.2095(14) . ?
N H 0.8800 . ?
N C4 1.3960(15) . ?
N C6 1.4391(14) . ?
C1 C6 1.5274(15) . ?
C4 C10 1.3988(17) . ?
C4 C16 1.4027(16) . ?
C6 H6 1.0000 . ?
C6 C14 1.5419(15) . ?
C8 C12 1.5268(15) . ?
C8 C22 1.3835(17) . ?
C8 C13 1.3919(18) . ?
C10 H10 0.9500 . ?
C10 C24 1.3899(18) . ?
C12 H12 1.0000 . ?
C12 C14 1.5299(15) . ?
C12 C20 1.5289(15) . ?
C14 H14A 0.9900 . ?
C14 H14B 0.9900 . ?
C16 H16 0.9500 . ?
C16 C25 1.3851(18) . ?
C18 H18A 0.9900 . ?
C18 H18B 0.9900 . ?
C18 C7 1.4987(17) . ?
C20 C15 1.3894(18) . ?
C20 C2 1.3952(18) . ?
C22 H22 0.9500 . ?
C22 C19 1.3918(18) . ?
C24 H24 0.9500 . ?
C24 C9 1.3889(19) . ?
C25 H25 0.9500 . ?
C25 C9 1.394(2) . ?
C13 H13 0.9500 . ?
C13 C5 1.3887(19) . ?
C7 H7A 0.9800 . ?
C7 H7B 0.9800 . ?
C7 H7C 0.9800 . ?
C15 H15 0.9500 . ?
C15 C21 1.3878(19) . ?
C2 H2 0.9500 . ?
C2 C11 1.3960(19) . ?
C17 H17 0.9500 . ?
C17 C19 1.381(2) . ?
C17 C5 1.383(2) . ?
C9 C3 1.512(2) . ?
C19 H19 0.9500 . ?
C5 H5 0.9500 . ?
C21 H21 0.9500 . ?
C21 C23 1.387(2) . ?
C11 H11 0.9500 . ?
C11 C23 1.373(2) . ?
C23 H23 0.9500 . ?
C3 H3A 0.9800 . ?
C3 H3B 0.9800 . ?
C3 H3C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 O1 C18 117.11(9) . . ?
C4 N H 119.6 . . ?
C4 N C6 120.85(9) . . ?
C6 N H 119.6 . . ?
O1 C1 C6 111.19(9) . . ?
O2 C1 O1 124.08(10) . . ?
O2 C1 C6 124.68(10) . . ?
N C4 C10 123.00(10) . . ?
N C4 C16 119.40(10) . . ?
C10 C4 C16 117.56(11) . . ?
N C6 C1 112.42(9) . . ?
N C6 H6 108.6 . . ?
N C6 C14 111.51(9) . . ?
C1 C6 H6 108.6 . . ?
C1 C6 C14 107.08(9) . . ?
C14 C6 H6 108.6 . . ?
C22 C8 C12 119.33(11) . . ?
C22 C8 C13 119.03(11) . . ?
C13 C8 C12 121.61(11) . . ?
C4 C10 H10 119.5 . . ?
C24 C10 C4 120.91(11) . . ?
C24 C10 H10 119.5 . . ?
C8 C12 H12 106.9 . . ?
C8 C12 C14 112.19(9) . . ?
C8 C12 C20 109.89(9) . . ?
C14 C12 H12 106.9 . . ?
C20 C12 H12 106.9 . . ?
C20 C12 C14 113.76(9) . . ?
C6 C14 H14A 109.1 . . ?
C6 C14 H14B 109.1 . . ?
C12 C14 C6 112.61(9) . . ?
C12 C14 H14A 109.1 . . ?
C12 C14 H14B 109.1 . . ?
H14A C14 H14B 107.8 . . ?
C4 C16 H16 119.7 . . ?
C25 C16 C4 120.67(12) . . ?
C25 C16 H16 119.7 . . ?
O1 C18 H18A 110.4 . . ?
O1 C18 H18B 110.4 . . ?
O1 C18 C7 106.74(9) . . ?
H18A C18 H18B 108.6 . . ?
C7 C18 H18A 110.4 . . ?
C7 C18 H18B 110.4 . . ?
C15 C20 C12 117.88(11) . . ?
C15 C20 C2 118.28(12) . . ?
C2 C20 C12 123.83(11) . . ?
C8 C22 H22 119.8 . . ?
C8 C22 C19 120.48(13) . . ?
C19 C22 H22 119.8 . . ?
C10 C24 H24 119.1 . . ?
C9 C24 C10 121.71(12) . . ?
C9 C24 H24 119.1 . . ?
C16 C25 H25 119.0 . . ?
C16 C25 C9 121.97(12) . . ?
C9 C25 H25 119.0 . . ?
C8 C13 H13 119.8 . . ?
C5 C13 C8 120.34(13) . . ?
C5 C13 H13 119.8 . . ?
C18 C7 H7A 109.5 . . ?
C18 C7 H7B 109.5 . . ?
C18 C7 H7C 109.5 . . ?
H7A C7 H7B 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
C20 C15 H15 119.5 . . ?
C21 C15 C20 121.06(14) . . ?
C21 C15 H15 119.5 . . ?
C20 C2 H2 119.8 . . ?
C20 C2 C11 120.43(14) . . ?
C11 C2 H2 119.8 . . ?
C19 C17 H17 120.2 . . ?
C19 C17 C5 119.60(12) . . ?
C5 C17 H17 120.2 . . ?
C24 C9 C25 117.18(12) . . ?
C24 C9 C3 120.78(14) . . ?
C25 C9 C3 122.04(14) . . ?
C22 C19 H19 119.9 . . ?
C17 C19 C22 120.23(13) . . ?
C17 C19 H19 119.9 . . ?
C13 C5 H5 119.9 . . ?
C17 C5 C13 120.25(14) . . ?
C17 C5 H5 119.9 . . ?
C15 C21 H21 120.0 . . ?
C23 C21 C15 120.09(15) . . ?
C23 C21 H21 120.0 . . ?
C2 C11 H11 119.7 . . ?
C23 C11 C2 120.52(14) . . ?
C23 C11 H11 119.7 . . ?
C21 C23 H23 120.2 . . ?
C11 C23 C21 119.59(13) . . ?
C11 C23 H23 120.2 . . ?
C9 C3 H3A 109.5 . . ?
C9 C3 H3B 109.5 . . ?
C9 C3 H3C 109.5 . . ?
H3A C3 H3B 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O1 C1 C6 N 158.24(9) . . . . ?
O1 C1 C6 C14 -78.96(11) . . . . ?
O2 C1 C6 N -24.41(15) . . . . ?
O2 C1 C6 C14 98.39(13) . . . . ?
N C4 C10 C24 -177.25(11) . . . . ?
N C4 C16 C25 177.70(11) . . . . ?
N C6 C14 C12 -60.73(12) . . . . ?
C1 O1 C18 C7 170.89(10) . . . . ?
C1 C6 C14 C12 175.91(9) . . . . ?
C4 N C6 C1 -69.26(12) . . . . ?
C4 N C6 C14 170.47(9) . . . . ?
C4 C10 C24 C9 -0.8(2) . . . . ?
C4 C16 C25 C9 0.1(2) . . . . ?
C6 N C4 C10 -15.54(16) . . . . ?
C6 N C4 C16 166.79(10) . . . . ?
C8 C12 C14 C6 -56.02(12) . . . . ?
C8 C12 C20 C15 65.49(14) . . . . ?
C8 C12 C20 C2 -115.78(13) . . . . ?
C8 C22 C19 C17 0.62(19) . . . . ?
C8 C13 C5 C17 0.5(2) . . . . ?
C10 C4 C16 C25 -0.09(17) . . . . ?
C10 C24 C9 C25 0.7(2) . . . . ?
C10 C24 C9 C3 -179.60(15) . . . . ?
C12 C8 C22 C19 175.10(11) . . . . ?
C12 C8 C13 C5 -175.60(12) . . . . ?
C12 C20 C15 C21 177.52(12) . . . . ?
C12 C20 C2 C11 -177.09(12) . . . . ?
C14 C12 C20 C15 -167.79(11) . . . . ?
C14 C12 C20 C2 10.94(16) . . . . ?
C16 C4 C10 C24 0.46(17) . . . . ?
C16 C25 C9 C24 -0.4(2) . . . . ?
C16 C25 C9 C3 179.98(15) . . . . ?
C18 O1 C1 O2 -4.08(16) . . . . ?
C18 O1 C1 C6 173.28(9) . . . . ?
C20 C12 C14 C6 178.47(9) . . . . ?
C20 C15 C21 C23 -0.1(2) . . . . ?
C20 C2 C11 C23 -0.6(2) . . . . ?
C22 C8 C12 C14 120.26(12) . . . . ?
C22 C8 C12 C20 -112.14(12) . . . . ?
C22 C8 C13 C5 2.01(19) . . . . ?
C13 C8 C12 C14 -62.14(14) . . . . ?
C13 C8 C12 C20 65.47(14) . . . . ?
C13 C8 C22 C19 -2.56(18) . . . . ?
C15 C20 C2 C11 1.6(2) . . . . ?
C15 C21 C23 C11 1.2(2) . . . . ?
C2 C20 C15 C21 -1.3(2) . . . . ?
C2 C11 C23 C21 -0.8(2) . . . . ?
C19 C17 C5 C13 -2.4(2) . . . . ?
C5 C17 C19 C22 1.9(2) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
_exptl_crystal_recrystallization_method 
'Re-crystallisation from solvent: ????????'
